ZA200205320B - Method and device for effluent treatment. - Google Patents

Method and device for effluent treatment. Download PDF

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Publication number
ZA200205320B
ZA200205320B ZA200205320A ZA200205320A ZA200205320B ZA 200205320 B ZA200205320 B ZA 200205320B ZA 200205320 A ZA200205320 A ZA 200205320A ZA 200205320 A ZA200205320 A ZA 200205320A ZA 200205320 B ZA200205320 B ZA 200205320B
Authority
ZA
South Africa
Prior art keywords
flushing
dead
membrane filtration
filtration unit
filtrate
Prior art date
Application number
ZA200205320A
Inventor
Josef Lahnsteiner
Babak Pouresmaeil
Original Assignee
Va Tech Wabag Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Va Tech Wabag Gmbh filed Critical Va Tech Wabag Gmbh
Publication of ZA200205320B publication Critical patent/ZA200205320B/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14Ultrafiltration; Microfiltration
    • B01D61/145Ultrafiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14Ultrafiltration; Microfiltration
    • B01D61/147Microfiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14Ultrafiltration; Microfiltration
    • B01D61/16Feed pretreatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D65/00Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/02Membrane cleaning or sterilisation ; Membrane regeneration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2311/00Details relating to membrane separation process operations and control
    • B01D2311/04Specific process operations in the feed stream; Feed pretreatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2311/00Details relating to membrane separation process operations and control
    • B01D2311/06Specific process operations in the permeate stream
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/04Backflushing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/16Use of chemical agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/16Use of chemical agents
    • B01D2321/162Use of acids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/16Use of chemical agents
    • B01D2321/168Use of other chemical agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60WCONJOINT CONTROL OF VEHICLE SUB-UNITS OF DIFFERENT TYPE OR DIFFERENT FUNCTION; CONTROL SYSTEMS SPECIALLY ADAPTED FOR HYBRID VEHICLES; ROAD VEHICLE DRIVE CONTROL SYSTEMS FOR PURPOSES NOT RELATED TO THE CONTROL OF A PARTICULAR SUB-UNIT
    • B60W2710/00Output or target parameters relating to a particular sub-units
    • B60W2710/06Combustion engines, Gas turbines
    • B60W2710/0644Engine speed
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/04Aerobic processes using trickle filters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A10/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE at coastal zones; at river basins
    • Y02A10/30Flood prevention; Flood or storm water management, e.g. using flood barriers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Landscapes

  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Biological Treatment Of Waste Water (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Description

+ The invention relates to a method for waste water purification, in which the waste water which is to be purified is biologically purified and the outflow from the fixed bed is subjected to dead-end membrane filtration, whereas the retained solids are removed by back-flushing; and to a corresponding apparatus.
In countries where water resources are scarce, waste water represents an important potential source of non-drinkable water. Replacing fresh water with purified waste water on the one hand allows better utilization of the water reserves which there are and on the other hand the natural water sources are retained for use as drinking water. To ensure safe reuse of purified waste water, in particular of communal waste water, however, a number of fundamental requirements must be satisfied.
One requirement is that the residual contamination from organic pollutants be as low as possible. According to the prior art, this is achieved in a technically simple manner with the aid of a fixed bed, such as for example with trickling or percolating filter stages, which on account of their simple structure are particularly suitable for industrially relatively undeveloped regions of the world. The second, even more important requirement, which cannot satisfactorily be fulfilled with a fixed bed, relates to the hygiene quality of the treated waste water, since waste water represents a major source of spreading infectious diseases.
According to the prior art, although the outflow quality from a fixed bed can be improved by the use of sand filters, the filtrate quality is still not adequate for reuse. In addition, a large amount of chlorine has to be metered in for hygiene reasons, which may contribute to hazardous organochlorine substances (THM) being formed.
From US-A-5 230 803 a method and an apparatus for the purification of waste water is known in which the waste water is biologically purified in a fixed bed and then subjected to dead end filtration.
It is an object of the present invention to purify waste water using a fixed bed in such a manner that the abovementioned drawbacks are avoided and the quality of the purified waste water allows it to be reused as non-drinkable water, in particular for irrigation purposes.
The method according to the invention is characterized in Claim 1. The corresponding apparatus is characterized in Claim 5.
Amended Sheet - 2003-08-27
, - A400647.WO English translation of originally filed WO-Application . 5 20 2. =
Both microfiltration membranes and ultrafiltration membranes can be used for dead-end membrane filtration. On account of this operating mode, and since the membranes retain solids, during filtration the solids concentration in the membrane module or membrane modules of the membrane filtration unit rises. These solids are, preferably periodically, flushed off the membrane surface by means of dedicated devices and removed from the system.
The invention can be used irrespective of the type of membrane modules (tubular, cush- ion, plate and hollow-fibre modules) employed.
Further advantageous embodiments of the apparatus according to the invention are given in the dependent claims.
Membrane filtration after a biological waste water treatment offers the following advan- tages: - membranes represent an absolute barrier according to the appropriate pore diameter, - suspended organic solids are completely retained and the outflow is particle-free, - pathogenic germs are reliably eliminated, and the number of virus particles is also re- duced to a decisive extent, - in terms of hygiene quality, the outflow from the unit satisfies the WHO requirements for unrestricted irrigation purposes.
Moreover, filtration using the dead-end principle has the advantage that the outlay on en- ergy compared to membrane filtration in cross-flow mode is low and that a dead-end membrane filtration unit takes up less space than final sedimentation tanks and sand fil- ters, which are usually arranged downstream of a fixed bed, in particular a trickling filter stage.
In addition, the purified waste water (filtrate) can be used for periodic back-flushing, so that the freshwater consumption is reduced considerably.
In order for the module to be cleaned more successfully, the back-flushing is assisted by the introduction of gas, in particular air. A vertical arrangement of modules in this case effects uniform and more effective distribution and mixing of flushing air and liquid.
At least some of the flushing liquid, which has a high solids content, is fed to a primary clarification stage connected upstream of the fixed-bed reactor.
Alternatively, or for a partial stream of the flushing liquid, it is possible for the fiushing liquid produced during the back-flushing to be drained off as excess sludge. It is thus possible to relieve the load on the primary clarification stage of the fixed bed.
Adding flocculants to the outflow from the fixed bed leads to the solids agglomerating to form larger flocs, so that the waste water can be filtered more easily and the modules of the membrane filtration unit can be back-flushed more successfully.
The cleaning of the membranes is carried out in a time-saving and cost-effective manner during the back-flushing, by metering in cleaning agents and/or disinfectants.
When the outflow from the fixed bed, in order for solids to be separated out, is fed to a final sedimentation stage and then to the dead-end membrane filtration, the filtration capacity is increased on account of the lower solids concentration in the waste water and the intervals between back-flushing operations and cleaning operations are extended. As a result, a final sedimentation stage which is already present can be incorporated in the method according to the invention.
The invention is explained by way of example with reference to the figure, which illustrates the integration of a membrane filtration unit, referred to below as filtration unit for short, in a clarification unit.
Amended Sheet — 2003-08-27
The filtration unit 2 is used to treat the biologically purified waste water. In this clarification unit, the crude waste water 6 passes through a rake mechanism 30, a grit basin 31 and a primary clarification tank 4, which is designed as an Imhoff tank with sludge drain 7. The waste water 8, which has undergone preliminary settling, is fed to the trickling filter reactor 1 with the filter bed 11. The outflow 12 from the trickling filter reactor 1 is removed in constant amounts from a shaft (not shown) directly beneath the trickling filter reactor 1 and/or directly, via a line 36, from a final sedimentation tank 22 using a submersible pump 26. The outflow 12 passes into the flocculation tank 23, into which flocculant is metered from a flocculant vessel 25 by means of a metering pump 34. The filtration unit 2 is fed from this flocculation tank 23 via a centrifugal pump 13.
The line for feed 35 can be blocked by means of shut-off cock 20 during the back-flushing.
At the upper end of the filter module 14 there is a two-way valve 19 (flushing water valve).
During filtration, the flushing water valve 19 is closed, so that the so-called “dead end” is formed. Since the membrane of the filter module 14 retains solids, an additional filter layer of suspended solids is formed. The filtrate 15 passes radially through the membrane and flows through the filtrate valve 18 into the filtrate vessel 3. The filtrate 15 flows over a flowmeter (not shown) and is collected in a filtrate vessel 3. The filtrate can be drained off via the filtrate outlet 21.
During the back-flushing, filtrate is forced into the filter module 14 in the reverse direction by means of a back-flushing pump 17 which is situated in the filtrate vessel 3 and is designed, for example, as a submersible pump. A three-way valve (filtrate valve 18) switches between the two directions of flow. The flushing water valve 19 is opened during the back-flushing in order to discharge the flushing water 16. The amount of flushing water 16 can be determined using the flowmeter 32.
Before the back-flushing, a better cleaning action can be achieved by draining the liquid out of the filter module 14 during the subsequent back-flushing. During this draining, the shut-off cock 20 is closed and the flushing water valve 19 and the shut-off cock 37 are open.
Amended Sheet - 2003-08-27
‘ - A400647.WO English translation of originally filed WO-Application . a R 3 20
The required back-flow rate of 0,5 -1 in the trickling filter reactor 1 can be achieved, in order to ensure hydraulic discharge of the biomass, by returning the flushing water 16 to the primary clarification tank 4.
By modifying the back-flushing, it was possible to eliminate the original problems of the modules becoming blocked, which were caused by high solids contents in the waste wa- ter.
The modified back-flushing is distinguished by combined flushing with air and water. In this modified arrangement, large amounts of air are blown into the module on the feed side before the back-flushing and during the back-flushing. As a result, the solid cake is loosened and can be removed more easily. For this purpose, an inlet for flushing air 27 is situated in front of the module entry. Through this inlet, in back-flushing mode auxiliary air can be blown in by means of compressor 28, in addition to the feed stream. With suitable membranes, it is also possible for air to be introduced on the filtrate side.
The filter module 14 may be arranged horizontally, but to provide better distribution of the flushing air 27 may also be arranged vertically. In the latter arrangement, with the modified back-flushing using the following mode of operation, no blockages were recorded even with high levels of solids: - 20 - 30 min. production time (filtering) - 20 sec. forward flushing with feed - 20 sec. filtrate back flushing - 20 sec. filtrate back-flushing and forward flushing with feed + air mixture.
The simultaneous use of chemicals further improves the back-flushing. In this way, the inorganic, organic and biological fouling of the membrane can additionally be greatly re- duced.
Various chemicals in various concentrations can be used depending on the nature and intensity of the fouling. In the unit illustrated in the figure, an acid back-flushing with subsequent hypochlorite flushing has proven extremely effective.
During the chemical back-flushing, chemical cleaning agent and/or disinfectant 29 is metered into the back-flushing stream via a diaphragm pump 33. The duration of and intervals between the chemical back-flushing are adjustable and depend on the degree of contamination of the waste water and the ambient temperature.
The unit which has been described by way of example also has the following features:
The outflow from the trickling bed reactor 1 contains 80-100 mg.I"" of substances which can be filtered out and has a COD of 100-150 mg.I"* The outflow from the final sedimentation tank 22 contains 10 - 60 mg." of substances which can be filtered out and a COD of 55-90 mg.I"". The flocculation time is 15-20 min. A peristaltic pump is used as metering pump 34 for the flocculant.
The filtration unit 2 comprises a filter module 14 with a total membrane surface area of 5.1 m? The membrane material is PVDF (Polyvinylidene fluoride).
On account of prior knowledge gained from laboratory tests, the filtrate stream is kept constant during production. The rising membrane resistance is compensated for by increasing the feed pressure. The mean feed pressure is preferably from 0.3 to 0.6 bar, but at most 0.8 bar.
The unit “bar” which is used in the specification and which is not in accordance with the metric system may be converted with the aid of the following conversion factor: 1bar=1x10°Pa
Amended Sheet — 2003-08-27

Claims (11)

PATENT CLAIMS
1. Method for waste water purification, in which the waste water which is to be purified is biologically purified and the outflow from the fixed bed is subjected to dead-end membrane filtration, whereas the retained solids are removed by back-flushing, characterized in that the biological purification takes place in a trickling filter stage, whereas during the back-flushing flocculants are added to the outflow from the trickling filter stage, that chemical cleaning agents and/or disinfectants are added, that the back-flushing is assisted by the introduction of gas and that flushing liquid which is produced during the back-flushing is fed to a primary clarification stage connected upstream of the trickling filter stage.
2. Method according to Claim 1, characterized in that the gas is air.
3. Method according to Claim 1 or 2, characterized in that the back-flushing is carried out using filtrate from the dead-end-membrane filtration.
4. Method according to one of Claims 1 to 3, characterized in that flushing liquid which is produced during the back-flushing is drained off as excess sludge.
5. Apparatus for waste water purification, comprising a fixed-bed reactor for biological purification, whereas a dead-end membrane filtration unit is provided on the outlet side, downstream of the fixed-bed reactor, for purifying the outflow from the fixed-bed reactor, characterized in that the fixed-bed reactor is a trickling filter reactor, that the dead-end membrane filtration unit, in order to discharge the flushing liquid, is connected to a primary clarification tank of the trickling filter reactor, that a device for adding flocculant to the outflow is provided on the outlet side, downstream of the trickling filter reactor, that a device, which has a device for adding chemical cleaning agent and/or disinfectant, for the back-flushing of the retained solids is provided and that to assist the back-flushing a device for the introduction of gas into the dead-end membrane filtration unit is provided.
6. Apparatus according to Claim 5, characterized in that the gas is air.
7. Apparatus according to Claim 5 or 6, characterized in that the dead-end membrane filtration unit has microfiltration or ultrafiltration membranes.
8. Apparatus according to one of Claims 5 to 7, characterized in that a filtrate vessel is provided for collecting the filtrate from the dead-end membrane filtration unit, which filtrate vessel is connected to the device for back-flushing. Amended Sheet —- 2003-08-27
9. Apparatus according to one of Claims 5 to 8, characterized in that the dead-end membrane filtration unit has vertically arranged filter modules.
10. Method according to claim 1 substantially as herein described.
11. Apparatus according to claim 5 substantially as herein described with reference to the accompanying drawing. Amended Sheet - 2003-08-27
ZA200205320A 2000-03-10 2002-07-03 Method and device for effluent treatment. ZA200205320B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
AT0040500A AT408750B (en) 2000-03-10 2000-03-10 METHOD AND DEVICE FOR WASTE WATER TREATMENT

Publications (1)

Publication Number Publication Date
ZA200205320B true ZA200205320B (en) 2003-09-02

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ID=3673652

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA200205320A ZA200205320B (en) 2000-03-10 2002-07-03 Method and device for effluent treatment.

Country Status (15)

Country Link
EP (1) EP1265819B1 (en)
CN (1) CN1238278C (en)
AT (1) AT408750B (en)
AU (1) AU2001235492A1 (en)
BR (1) BR0109103B1 (en)
DE (1) DE50100578D1 (en)
DZ (1) DZ3314A1 (en)
EG (1) EG22803A (en)
ES (1) ES2202278T3 (en)
MX (1) MXPA02008685A (en)
SA (1) SA01220120B1 (en)
TN (1) TNSN01037A1 (en)
TR (1) TR200202065T2 (en)
WO (1) WO2001068536A1 (en)
ZA (1) ZA200205320B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1329314C (en) * 2004-02-05 2007-08-01 哈尔滨工业大学 Multipurpose bio-trickling filter deordorization device
WO2014027122A1 (en) * 2012-08-16 2014-02-20 Acciona Agua, S.A.U. Water treatment system and method
AU2013317919B2 (en) * 2012-09-21 2017-04-27 D.C. Water & Sewer Authority Method and apparatus for water treatment using screens
CN106904706A (en) * 2017-03-06 2017-06-30 王刚 A kind of waste water solid separation equipment and system
CN111871989B (en) * 2020-06-16 2022-03-22 力合科技(湖南)股份有限公司 Water sample pretreatment system
CN116947146B (en) * 2023-07-12 2024-02-23 苏州登峰环境工程有限公司 Integrated high-efficiency ozone aerodynamic sewage treatment device

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Publication number Priority date Publication date Assignee Title
EP0470931A3 (en) * 1990-08-08 1992-05-13 Ciba-Geigy Ag Soil and waste water treatment
US5221479A (en) * 1991-02-15 1993-06-22 Fuji Photo Film Co., Ltd. Filtration system
JP3107950B2 (en) * 1993-07-07 2000-11-13 オルガノ株式会社 Biological treatment apparatus and water treatment method using the same
NL9400647A (en) * 1994-04-22 1995-12-01 Stork Friesland Bv Membrane filtration system, method for subjecting a liquid to membrane filtration and method for cleaning such a membrane filtration system.
KR0154384B1 (en) * 1995-07-03 1998-10-15 박원훈 Water treatment apparatus using membrane
DE19718028C1 (en) * 1997-04-29 1998-06-04 Hydac Filtertechnik Gmbh Fluid filter assembly having membrane modules arranged in parallel
DE19731887A1 (en) * 1997-07-24 1999-01-28 Gerd Thon Sterile filtration assembly for treating e.g. rain water
JPH1157710A (en) * 1997-08-27 1999-03-02 Kurita Water Ind Ltd Device for treating waste water with membrane

Also Published As

Publication number Publication date
TNSN01037A1 (en) 2003-04-03
MXPA02008685A (en) 2004-09-06
AT408750B (en) 2002-02-25
EP1265819A1 (en) 2002-12-18
DZ3314A1 (en) 2001-09-20
DE50100578D1 (en) 2003-10-09
EP1265819B1 (en) 2003-09-03
BR0109103A (en) 2002-12-03
WO2001068536A1 (en) 2001-09-20
CN1238278C (en) 2006-01-25
AU2001235492A1 (en) 2001-09-24
CN1416406A (en) 2003-05-07
ES2202278T3 (en) 2004-04-01
BR0109103B1 (en) 2010-10-05
SA01220120B1 (en) 2006-11-14
ATA4052000A (en) 2001-07-15
EG22803A (en) 2003-08-31
TR200202065T2 (en) 2003-01-21

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