WO2024219419A1 - 光学ユニット、および、画像表示システム - Google Patents

光学ユニット、および、画像表示システム Download PDF

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Publication number
WO2024219419A1
WO2024219419A1 PCT/JP2024/015254 JP2024015254W WO2024219419A1 WO 2024219419 A1 WO2024219419 A1 WO 2024219419A1 JP 2024015254 W JP2024015254 W JP 2024015254W WO 2024219419 A1 WO2024219419 A1 WO 2024219419A1
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Prior art keywords
liquid crystal
light
crystal layer
optical unit
plane
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Ceased
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PCT/JP2024/015254
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English (en)
French (fr)
Japanese (ja)
Inventor
寛 佐藤
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Fujifilm Corp
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Fujifilm Corp
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Priority to JP2025515257A priority Critical patent/JPWO2024219419A1/ja
Priority to CN202480024057.7A priority patent/CN121002426A/zh
Publication of WO2024219419A1 publication Critical patent/WO2024219419A1/ja
Priority to US19/337,934 priority patent/US20260016716A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133504—Diffusing, scattering, diffracting elements
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
    • G02B27/02—Viewing or reading apparatus
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
    • G02B27/28—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00 for polarising
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/18—Diffraction gratings
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/32—Holograms used as optical elements
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133553—Reflecting elements
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1337—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers

Definitions

  • the present invention relates to an optical unit and an image display system.
  • Virtual reality display devices such as head mounted displays (HMDs) including AR (Augmented Reality) glasses, VR (Virtual Reality) glasses, and MR (Mixed Reality) glasses overlay virtual images and various information on the actual scene you are viewing.
  • HMDs head mounted displays
  • AR Algmented Reality
  • VR Virtual Reality
  • MR Magnetic Reality
  • an image display device has been proposed that has an image display panel and two partial reflection elements, and has an optical unit called a pancake lens that reduces the overall thickness of the headset by redirecting light emitted from the image display panel back and forth between the two partial reflection elements.
  • an image display device having such a pancake lens it is necessary to arrange a component that has a lens effect to converge light in order to widen the field of view (FOV), which is the area in which the image is displayed.
  • FOV field of view
  • a configuration in which a concave mirror is used to give this lens effect to at least one of the partial reflecting elements is also being considered.
  • a concave mirror is used to give this lens effect to at least one of the partial reflecting elements.
  • a general half mirror or the like is used as the partial reflecting element, it is necessary to mold the half mirror into a curved shape. In this case, since it is necessary to ensure a thickness in order to mold the half mirror into a curved shape, the thickness of the optical unit becomes thick, which in turn increases the thickness of the image display device.
  • Patent Document 1 describes the use of a hologram (diffraction element) with refractive power as one of the two partial reflection elements.
  • a hologram (diffraction element) with refractive power as the partial reflection element, it is possible to make it function as a concave mirror or convex mirror while maintaining its flat shape, making it possible to further reduce the thickness of the optical unit (image display device).
  • the reflective diffraction element needs to bend the light more significantly at the end.
  • the diffraction efficiency decreases as the diffraction angle increases. This causes a problem that when the reflective diffraction element is incorporated into an image display device, the brightness unevenness of the image displayed by the image display device becomes large.
  • the object of the present invention is to solve these problems with the conventional technology and to provide an optical unit and image display system that, when applied to an image display device, produces an image with little uneven brightness.
  • An optical unit having a first partially reflective element and a second partially reflective element, one of the first partially reflective element and the second partially reflective element comprises a cholesteric liquid crystal layer;
  • the cholesteric liquid crystal layer has a liquid crystal alignment pattern in which the direction of the optical axis derived from the liquid crystal compound changes while continuously rotating along at least one direction in the plane, When the length of an in-plane rotation of an optical axis derived from a liquid crystal compound is taken as one period, the length of one period in the liquid crystal alignment pattern is different in the in-plane region,
  • One of the first partially reflective element and the second partially reflective element has a first cholesteric liquid crystal layer, a second cholesteric liquid crystal layer, and a third cholesteric liquid crystal layer;
  • the first to third cholesteric liquid crystal layers have a length of one period and a helical pitch that are different from each other at any one point in the plane, When the lengths of one period at any one point in the plane of the first to third cholesteric liquid crystal layers are ⁇ 1, ⁇ 2, and ⁇ 3, respectively, having a region where ⁇ 1 ⁇ 2 ⁇ 3;
  • the optical unit according to any one of [1] to [4], wherein the first cholesteric liquid crystal layer has a region that diffracts blue light, the second cholesteric liquid crystal layer has a region that diffracts green light, and the third cholesteric liquid crystal layer has a region that diffracts red light.
  • a light emitting device comprising, in this order, a first partially reflective element, a second partially reflective element, and a first transmissive polarizing diffractive element;
  • the first transmission type polarizing diffraction element includes a liquid crystal layer formed using a liquid crystal composition containing a liquid crystal compound, the liquid crystal layer has a liquid crystal alignment pattern in which the direction of the optical axis derived from the liquid crystal compound changes while continuously rotating along at least one direction in the plane;
  • the length of an in-plane rotation of an optical axis derived from a liquid crystal compound is taken as one period, the length of one period in the liquid crystal alignment pattern is different in the in-plane region,
  • the optical unit according to [7] having a region in the plane where the optical axis rotates twisted in the thickness direction of the liquid crystal layer, and having a region where the total magnitude of the twist angle in the thickness direction is different.
  • a liquid crystal display comprising a first partially reflective element, a second partially reflective element, and a circular polarizer, in this order; The optical unit according to any one of [1] to [8], wherein the circular polarizing plate transmits a portion of the light that has transmitted through the second partially reflecting element.
  • An image display system comprising the optical unit according to any one of [1] to [9] and an image display element.
  • An optical element comprising a liquid crystal layer formed using a liquid crystal composition containing a liquid crystal compound, the liquid crystal layer has a liquid crystal alignment pattern in which the direction of the optical axis derived from the liquid crystal compound changes while continuously rotating along at least one direction in the plane;
  • the image display system described in [11] has an area in the plane where the length of one period in the liquid crystal orientation pattern is different, when the length of the optical axis direction derived from the liquid crystal compound rotates 180° in the plane is defined as one period.
  • An optical element comprising a liquid crystal layer formed using a liquid crystal composition containing a liquid crystal compound, the liquid crystal layer has a liquid crystal alignment pattern in which the direction of the optical axis derived from the liquid crystal compound changes while continuously rotating along at least one direction in the plane;
  • the image display system described in [12] has an area in the plane where the length of one period in the liquid crystal orientation pattern is different, when the length of the optical axis direction derived from the liquid crystal compound rotates 180° in the plane is defined as one period.
  • the present invention provides an optical unit and an image display system that, when applied to an image display device, produces images with little uneven brightness.
  • FIG. 1 is a diagram conceptually illustrating an example of an image display system including an optical unit of the present invention.
  • FIG. 2 is a conceptual diagram of the image display system shown in FIG. 1 .
  • FIG. 13 is a diagram conceptually showing an image display system including another example of the optical unit of the present invention.
  • FIG. 13 is a diagram conceptually showing an image display system including another example of the optical unit of the present invention.
  • FIG. 13 is a diagram conceptually showing an image display system including another example of the optical unit of the present invention.
  • FIG. 13 is a diagram conceptually showing an image display system including another example of the optical unit of the present invention.
  • FIG. 13 is a diagram conceptually showing an image display system including another example of the optical unit of the present invention.
  • FIG. 13 is a diagram conceptually showing an image display system including another example of the optical unit of the present invention.
  • FIG. 13 is a diagram conceptually showing an image display system including another example of the optical unit of the present invention.
  • FIG. 13 is a diagram
  • FIG. 13 is a conceptual diagram for explaining the function of the polarizing diffraction element shown in FIG. 12 .
  • 13 is a conceptual diagram for explaining the function of the polarizing diffraction element shown in FIG. 12 .
  • 13 is a conceptual diagram for explaining the function of the polarizing diffraction element shown in FIG. 12 .
  • 10 is a conceptual diagram for explaining another example of a liquid crystal layer included in the polarizing diffraction element.
  • FIG. 13 is a conceptual diagram of an example of an exposure apparatus for exposing an alignment film of the polarizing diffraction element shown in FIG. 12 .
  • FIG. 11 is a conceptual diagram for explaining another example of a polarizing diffraction element.
  • FIG. 20 is a conceptual diagram for explaining the polarizing diffraction element shown in FIG. 19 .
  • FIG. 1 is a conceptual diagram of an example of an exposure apparatus for producing a reflection type volume hologram.
  • optical unit and image display system of the present invention will be described in detail below based on the preferred embodiment shown in the attached drawings.
  • a numerical range expressed using “ ⁇ ” means a range that includes the numerical values written before and after " ⁇ " as the lower and upper limits.
  • (meth)acrylate is used to mean “either or both of acrylate and methacrylate.”
  • visible light refers to electromagnetic waves with wavelengths visible to the human eye, in the wavelength range of 380 to 780 nm.
  • Invisible light refers to light with wavelengths below 380 nm and above 780 nm.
  • Re( ⁇ ) represents the in-plane retardation at a wavelength ⁇ . Unless otherwise specified, the wavelength ⁇ is 550 nm.
  • the optical unit of the present invention comprises: An optical unit having a first partially reflective element and a second partially reflective element, one of the first partially reflective element and the second partially reflective element comprises a cholesteric liquid crystal layer;
  • the cholesteric liquid crystal layer has a liquid crystal alignment pattern in which the direction of the optical axis derived from the liquid crystal compound changes while continuously rotating along at least one direction in the plane, When the length of an in-plane rotation of an optical axis derived from a liquid crystal compound is taken as one period, the length of one period in the liquid crystal alignment pattern is different in the in-plane region,
  • the optical unit has regions in its plane where the helical pitch of the helical structure is different.
  • the image display system of the present invention further comprises:
  • the image display system includes the optical unit and an image display device.
  • FIG. 1 conceptually illustrates an example of an image display system having an optical unit of the present invention.
  • the image display system (virtual reality display device) 200 shown in FIG. 1 has, in this order, an image display element 202, a circular polarizer 204, and an optical unit 210.
  • the optical unit 210 has a first partial reflection element 211 and a second partial reflection element 213.
  • the image display element 202 is a known display.
  • Examples of the image display element 202 include a liquid crystal display element (LCD (Liquid Crystal Display)), an organic electroluminescence display element (OLED (Organic Light Emitting Diode)), a CRT (cathode-ray tube), a plasma display element, electronic paper, an LED (Light Emitting Diode) display element, a micro LED display element, DLP (Digital Light Processing), and a MEMS (Micro-Electro-Mechanical Systems) type display element.
  • the liquid crystal display element includes LCOS (Liquid Crystal On Silicon), etc.
  • the image display element may also be a transparent display that is capable of transmitting light.
  • the image display element may be one that displays monochrome images, two-tone images, or color images.
  • the light emitted by the image display element may be unpolarized, linearly polarized, or circularly polarized.
  • the display surface (viewing) side of the image display element may have an element (for example, a linear polarizer or a circular polarizing plate) that converts the polarization state of the light.
  • the display surface side of the image display element 202 has a circular polarizing plate 204.
  • the circular polarizing plate 204 has, for example, a linear polarizer 206 and a ⁇ /4 retardation plate 208, as shown in FIG. 2 described later.
  • the linear polarizer 206 may be a reflective polarizer or an absorptive polarizer, and various known linear polarizers can be used, such as iodine-based polarizers, dye-based polarizers using dichroic dyes, polyene-based polarizers, wire grid polarizers, and films made of stretched dielectric multilayer films as described in JP 2011-053705 A, etc.
  • ⁇ /4 retardation plate 208 there are no limitations on the ⁇ /4 retardation plate 208. Therefore, various known ⁇ /4 retardation plates can be used, such as a stretched polycarbonate film, a stretched norbornene-based polymer film, a transparent film containing and oriented inorganic particles having birefringence such as strontium carbonate, a thin film formed by obliquely depositing an inorganic dielectric on a support, a film in which a polymerizable liquid crystal compound is uniaxially oriented and oriented, and a film in which a liquid crystal compound is uniaxially oriented and oriented.
  • a stretched polycarbonate film such as a stretched norbornene-based polymer film, a transparent film containing and oriented inorganic particles having birefringence such as strontium carbonate, a thin film formed by obliquely depositing an inorganic dielectric on a support, a film in which a polymerizable liquid crystal compound is uniaxially oriented
  • a first partial reflecting element 211 and a second partial reflecting element 213 are arranged in this order on the side of the circular polarizing plate 204 opposite the image display element 202.
  • the first partial reflecting element 211 and the second partial reflecting element 213 are the optical unit 210 of the present invention.
  • the optical unit can increase the optical path length in a limited space by transmitting light back and forth between the first partial reflecting element 211 and the second partial reflecting element 213, thereby contributing to the miniaturization of the image display unit.
  • either the first partial reflection element 211 or the second partial reflection element 213 has a cholesteric liquid crystal layer.
  • This cholesteric liquid crystal layer has a liquid crystal orientation pattern in which the orientation of the optical axis derived from the liquid crystal compound changes while rotating continuously along at least one direction in the plane, and when the length of the optical axis orientation derived from the liquid crystal compound rotating 180° in the plane is one period, there are regions in the plane where the length of one period in the liquid crystal orientation pattern is different, and there are regions in the plane where the helical pitch of the helical structure is different.
  • Such a partial reflection element having a cholesteric liquid crystal layer has the effect of reflecting one circularly polarized light of incident light and transmitting the other circularly polarized light, and diffracting the reflected light. Therefore, it can function as a concave mirror while maintaining a flat shape, making it possible to make the optical unit (image display system) thinner.
  • a partial reflection element having such a cholesteric liquid crystal layer will also be referred to as a reflective liquid crystal diffraction element.
  • the first partial reflection element 211 is a reflective liquid crystal diffraction element
  • the second partial reflection element 213 is a partial reflection element that does not have a diffraction effect (lens effect), such as a general half mirror.
  • the first partial reflecting element 211 reflects the light reflected by the second partial reflecting element 213 to the second partial reflecting element 213 side.
  • the first partial reflecting element 211 acts as a concave mirror, diffracting (bending) the light at a larger angle toward the end so that the reflected light is concentrated.
  • a portion of the light reflected by the first partial reflecting element 211 passes through the second partial reflecting element 213 and is visually recognized as an image by the user U.
  • the first partially reflective element 211 acts as a concave mirror, so that the regions closer to the ends diffract (bend) light more than the central region.
  • the diffraction efficiency decreases as the diffraction angle increases. Therefore, in conventional image display systems, there was a problem in that the brightness of the image displayed by the image display system was high in the center and decreased toward the ends, resulting in large brightness unevenness within the surface.
  • the optical unit of the present invention has a cholesteric liquid crystal layer in one of the partial reflection elements (reflective liquid crystal diffraction element) that has the above-mentioned configuration, which makes it possible to increase the diffraction efficiency at the ends and make the diffraction efficiency more uniform within the plane. Therefore, an image display system equipped with the optical unit of the present invention can reduce unevenness in the brightness of the displayed image.
  • the image display system 200a shown in FIG. 2 has an image display element 202, a circular polarizer 204, and an optical unit 210a, in this order.
  • the optical unit 210a has, from the image display element 202 side, a reflective liquid crystal diffraction element 212 and a half mirror 214, in this order.
  • the reflective liquid crystal diffraction element 212 is the first partial reflection element 211
  • the half mirror 214 is the second partial reflection element 213.
  • the same reference numerals are used to designate the same parts as in the image display device shown in FIG. 1, and the following description will mainly focus on the different parts.
  • the image display element 202 emits unpolarized light. This also applies to the examples shown in FIGS. 3 to 7.
  • the circular polarizer 204 has a linear polarizer 206 and a ⁇ /4 retarder 208, and converts the unpolarized light irradiated by the image display element 202 into circularly polarized light. In doing so, the circular polarizer 204 converts the unpolarized light into circularly polarized light with a rotation direction opposite to that of the circularly polarized light reflected by the reflective liquid crystal diffraction element 212.
  • the circularly polarized light reflected by the reflective liquid crystal diffraction element 212 is referred to as right circularly polarized light
  • the circularly polarized light into which the circular polarizer 204 converts the unpolarized light is referred to as left circularly polarized light.
  • the left circularly polarized light converted by the circular polarizer 204 is incident on the reflective liquid crystal diffraction element 212, which is the first partially reflective element 211.
  • the reflective liquid crystal diffraction element 212 has the aforementioned cholesteric liquid crystal layer, and reflects right-handed circularly polarized light and transmits left-handed circularly polarized light. Therefore, it transmits the left-handed circularly polarized light that is incident on it.
  • a portion of the left-handed circularly polarized light that passes through the reflective liquid crystal diffraction element 212 is reflected by the half mirror 214 toward the reflective liquid crystal diffraction element 212, and the remainder passes through the half mirror 214. Furthermore, the reflection by the half mirror 214 converts the circularly polarized light into circularly polarized light with the opposite rotation direction. In this example, the light reflected by the half mirror 214 is converted into right-handed circularly polarized light.
  • the half mirror 214 a conventionally known half mirror that transmits a portion of the incident light and reflects the remainder can be used.
  • the reflectance of the half mirror is preferably 50 ⁇ 30%, more preferably 50 ⁇ 10%, and most preferably 50%.
  • the half mirror has a structure in which a reflective layer made of a metal such as silver or aluminum is provided on a substrate made of a transparent resin such as polyethylene terephthalate (PET), cycloolefin polymer (COP), polymethyl methacrylate (PMMA), or glass.
  • PET polyethylene terephthalate
  • COP cycloolefin polymer
  • PMMA polymethyl methacrylate
  • the reflective layer made of a metal such as silver or aluminum is formed on the surface of the substrate by deposition or the like.
  • the thickness of the reflective layer is preferably 1 to 20 nm, more preferably 2 to 10 nm, and even more preferably 3 to 6 nm.
  • the right-handed circularly polarized light reflected by the half mirror 214 enters the reflective liquid crystal diffraction element 212. Because the polarization state of the light has been changed by reflection by the half mirror 214, the light that enters the reflective liquid crystal diffraction element 212 is reflected by the reflective liquid crystal diffraction element 212. At that time, because the reflective liquid crystal diffraction element 212 acts as a concave mirror, the light is reflected in a manner that focuses it.
  • the light reflected by the reflective liquid crystal diffraction element 212 is incident on the half mirror 214.
  • a portion of the light incident on the half mirror 214 passes through the half mirror 214 and is irradiated to the user U.
  • the reflective liquid crystal diffraction element 212 acts as a concave mirror, focusing the reflected light and widening the field of view (FOV), which is the area in which the image is displayed.
  • FOV field of view
  • the reflective liquid crystal diffraction element 212 has the above-mentioned cholesteric liquid crystal layer, it is possible to suppress the decrease in diffraction efficiency at the ends where diffraction occurs at a large diffraction angle, and to reduce uneven brightness in the image displayed by the image display system.
  • the image display system 200b shown in FIG. 3 has an image display element 202, a circular polarizer 204, and an optical unit 210b, in this order.
  • the optical unit 210b has, from the image display element 202 side, a half mirror 214 and a reflective liquid crystal diffraction element 212, in this order.
  • the half mirror 214 is the first partial reflection element 211
  • the reflective liquid crystal diffraction element 212 is the second partial reflection element 213. That is, the optical unit 210b shown in FIG. 3 differs from the optical unit 210a shown in FIG. 2 in the arrangement order of the half mirror 214 and the reflective liquid crystal diffraction element 212.
  • the circular polarizer 204 converts unpolarized light into circularly polarized light that is reflected by the reflective liquid crystal diffraction element 212.
  • the circularly polarized light reflected by the reflective liquid crystal diffraction element 212 is assumed to be right-handed circularly polarized light, and the circular polarizer 204 converts unpolarized light into right-handed circularly polarized light.
  • the unpolarized light emitted by the image display element 202 passes through the circular polarizer 204 and is converted into right-handed circularly polarized light.
  • the right-handed circularly polarized light converted by the circular polarizer 204 is incident on the half mirror 214, which is the first partial reflection element 211.
  • a portion of the right-handed circularly polarized light that enters the half mirror 214 is transmitted, and the remainder is reflected by the half mirror 214 toward the image display element 202.
  • the right-handed circularly polarized light that passes through the half mirror 214 enters the reflective liquid crystal diffraction element 212. Because the reflective liquid crystal diffraction element 212 reflects right-handed circularly polarized light, the right-handed circularly polarized light that enters the reflective liquid crystal diffraction element 212 is reflected by the reflective liquid crystal diffraction element 212 toward the half mirror 214. At that time, because the reflective liquid crystal diffraction element 212 acts as a concave mirror, the light is reflected in a manner that concentrates it.
  • the light reflected by the reflective liquid crystal diffraction element 212 is incident on the half mirror 214.
  • a portion of the light incident on the half mirror 214 is reflected by the half mirror 214 towards the reflective liquid crystal diffraction element 212, and the remainder is transmitted through the half mirror 214.
  • the reflection by the half mirror 214 converts the circularly polarized light into circularly polarized light with the opposite rotation direction.
  • the light reflected by the half mirror 214 is converted into left-handed circularly polarized light.
  • the left-handed circularly polarized light reflected by the half mirror 214 is incident on the reflective liquid crystal diffraction element 212.
  • the reflective liquid crystal diffraction element 212 reflects right-handed circularly polarized light and transmits left-handed circularly polarized light, so the incident left-handed circularly polarized light is transmitted through the element, and the light is irradiated to the user U.
  • the light is reflected in a concentrated manner by the reflective liquid crystal diffraction element 212, so the field of view (FOV), which is the area in which the image is displayed, can be widened.
  • the reflective liquid crystal diffraction element 212 has the above-mentioned cholesteric liquid crystal layer, it is possible to suppress the decrease in diffraction efficiency at the ends where diffraction occurs at a large diffraction angle, and it is possible to reduce uneven brightness in the image displayed by the image display system.
  • the image display system 200c shown in FIG. 4 has, in this order, an image display element 202, a circular polarizer 204, and an optical unit 210c.
  • the optical unit 210c has, in this order from the image display element 202 side, a reflective volume hologram 215 and a reflective liquid crystal diffraction element 212.
  • the reflective volume hologram 215 is the first partial reflection element 211
  • the reflective liquid crystal diffraction element 212 is the second partial reflection element 213. That is, the optical unit 210c shown in FIG. 4 replaces the half mirror 214 of the optical unit 210b shown in FIG. 3 with a reflective volume hologram 215.
  • the reflective volume hologram 215 reflects a portion of the incident light and transmits the remainder. Upon reflection, it diffracts the light according to the recorded hologram, and can function as a concave or convex mirror while maintaining its flat shape.
  • a known reflection-type volume hologram can be used as the reflection volume hologram 215.
  • a reflection-type volume hologram diffraction element can be obtained, for example, by performing interference exposure on a hologram photosensitive material based on a profile that produces a different diffraction angle for each position in the surface. Reflection-type volume holograms are described in Proc. SPIE 7619, Practical Holography XXIV: Materials and Applications, 76190I, etc.
  • the reflective volume hologram 215 acts as a concave mirror. Also, the reflective liquid crystal diffraction element 212 acts as a concave mirror.
  • the unpolarized light emitted by the image display element 202 passes through the circular polarizer 204 and is converted into right-handed circularly polarized light.
  • the right-handed circularly polarized light converted by the circular polarizer 204 is incident on the reflective volume hologram 215, which is the first partially reflective element 211.
  • a portion of the right-handed circularly polarized light that enters the reflective volume hologram 215 is transmitted, and the remainder is reflected by the reflective volume hologram 215 toward the image display element 202.
  • the right-handed circularly polarized light that passes through the reflective volume hologram 215 enters the reflective liquid crystal diffraction element 212. Because the reflective liquid crystal diffraction element 212 reflects right-handed circularly polarized light, the right-handed circularly polarized light that enters the reflective liquid crystal diffraction element 212 is reflected by the reflective liquid crystal diffraction element 212 toward the reflective volume hologram 215. At that time, because the reflective liquid crystal diffraction element 212 acts as a concave mirror, the light is reflected in a manner that focuses it.
  • the light reflected by the reflective liquid crystal diffraction element 212 enters the reflective volume hologram 215.
  • a portion of the light that enters the reflective volume hologram 215 is reflected by the reflective volume hologram 215 towards the reflective liquid crystal diffraction element 212, and the remainder passes through the reflective volume hologram 215.
  • the circularly polarized light is converted into circularly polarized light with the opposite rotation direction.
  • the light reflected by the reflective volume hologram 215 is converted into left-handed circularly polarized light.
  • the reflective volume hologram 215 acts as a concave mirror, the light is reflected in a manner that focuses it.
  • the left-handed circularly polarized light reflected by the reflective volume hologram 215 is incident on the reflective liquid crystal diffraction element 212.
  • the reflective liquid crystal diffraction element 212 reflects right-handed circularly polarized light and transmits left-handed circularly polarized light, so the incident left-handed circularly polarized light is transmitted through the element, and the light is irradiated onto the user U.
  • the light is reflected in a concentrated manner by the reflective liquid crystal diffraction element 212, so the field of view (FOV), which is the area in which the image is displayed, can be widened.
  • the reflective liquid crystal diffraction element 212 has the above-mentioned cholesteric liquid crystal layer, it is possible to suppress the decrease in diffraction efficiency at the ends where diffraction occurs at a large diffraction angle, and it is possible to reduce uneven brightness in the image displayed by the image display system.
  • the first partially reflective element 211 is a reflective volume hologram 215, and the second partially reflective element 213 is a reflective liquid crystal diffraction element 212, i.e., the half mirror 214 in the example shown in FIG. 3 is replaced with a reflective volume hologram 215, but this is not limiting.
  • the half mirror 214 may be replaced with a reflective volume hologram 215.
  • the image display system 200d shown in FIG. 5 has an image display element 202, a circular polarizer 204, and an optical unit 210d, in this order.
  • the optical unit 210d has, from the image display element 202 side, a reflective liquid crystal diffraction element 212, a half mirror 214, and a circular polarizer 216, in this order.
  • the reflective liquid crystal diffraction element 212 is the first partial reflection element 211
  • the half mirror 214 is the second partial reflection element 213. That is, the optical unit 210d shown in FIG. 5 is a preferred embodiment in which a circular polarizer 216 is further provided in addition to the optical unit 210a shown in FIG. 2.
  • the circular polarizer 216 like the circular polarizer 204, is configured to have, for example, a linear polarizer and a ⁇ /4 retardation plate.
  • the circular polarizer 216 transmits the circularly polarized light reflected by the reflective liquid crystal diffraction element 212 and blocks (reflects or absorbs) the circularly polarized light of the opposite rotation direction.
  • the circularly polarized light reflected by the reflective liquid crystal diffraction element 212 is assumed to be right-handed circularly polarized light, and the circular polarizer 216 transmits right-handed circularly polarized light.
  • the unpolarized light emitted by the image display element 202 passes through the circular polarizer 204 and is converted into left-handed circularly polarized light.
  • the left-handed circularly polarized light converted by the circular polarizer 204 is incident on the reflective liquid crystal diffraction element 212, which is the first partially reflective element 211.
  • the reflective liquid crystal diffraction element 212 reflects right-handed circularly polarized light and transmits left-handed circularly polarized light. Therefore, it transmits the left-handed circularly polarized light that is incident on it.
  • a portion of the left-handed circularly polarized light that passes through the reflective liquid crystal diffraction element 212 is reflected by the half mirror 214 toward the reflective liquid crystal diffraction element 212, and the remainder passes through the half mirror 214. Furthermore, the reflection by the half mirror 214 converts the circularly polarized light into circularly polarized light with the opposite rotation direction. In this example, the light reflected by the half mirror 214 is converted into right-handed circularly polarized light.
  • the right-handed circularly polarized light reflected by the half mirror 214 enters the reflective liquid crystal diffraction element 212. Because the polarization state of the light has been changed by reflection by the half mirror 214, the light that enters the reflective liquid crystal diffraction element 212 is reflected by the reflective liquid crystal diffraction element 212. At that time, because the reflective liquid crystal diffraction element 212 acts as a concave mirror, the light is reflected in a manner that focuses it.
  • the right-handed circularly polarized light reflected by the reflective liquid crystal diffraction element 212 is incident on the half mirror 214.
  • a portion of the right-handed circularly polarized light that is incident on the half mirror 214 is transmitted through the half mirror 214.
  • the right-handed circularly polarized light that is transmitted through the half mirror 214 is incident on the circular polarizer 216.
  • the circular polarizer 216 transmits the right-handed circularly polarized light, and the light is irradiated to the user U.
  • the light is reflected in a concentrated manner by the reflective liquid crystal diffraction element 212, so the field of view (FOV), which is the area in which the image is displayed, can be widened.
  • the reflective liquid crystal diffraction element 212 has the above-mentioned cholesteric liquid crystal layer, it is possible to suppress the decrease in diffraction efficiency at the ends where diffraction occurs at a large diffraction angle, and it is possible to reduce uneven brightness in the image displayed by the image display system.
  • the optical unit 210d shown in FIG. 5 has a circular polarizer 216 on the side of the second partial reflection element 213 opposite the first partial reflection element 211, i.e., on the viewing side.
  • a portion of the light emitted from the image display element may reach the viewing side through an unintended optical path other than the optical path that goes back and forth between the first partially reflected photon and the second partially reflecting element due to disturbances in polarization and undesirable reflections on the surfaces of various components, resulting in leakage light.
  • leakage light can lead to the occurrence of double images and reduced contrast.
  • a circular polarizer 216 on the viewing side, it is possible to block the leakage light that has passed through an unintended optical path, thereby suppressing the occurrence of double images and reduced contrast.
  • the circular polarizer 216 transmits the circularly polarized light reflected by the reflective liquid crystal diffraction element 212 and blocks the circularly polarized light of the opposite rotation direction.
  • the circular polarizer 216 blocks the circularly polarized light reflected by the reflective liquid crystal diffraction element 212 and transmits the circularly polarized light of the opposite rotation direction.
  • the image display system 200e shown in FIG. 6 has an image display element 202, a circular polarizer 204, and an optical unit 210e, in this order.
  • the optical unit 210e has, from the image display element 202 side, a reflective liquid crystal diffraction element 212, a half mirror 214, and a first transmissive polarizing diffraction element 218, in this order.
  • the reflective liquid crystal diffraction element 212 is the first partial reflection element 211
  • the half mirror 214 is the second partial reflection element 213. That is, the optical unit 210e shown in FIG. 6 is a preferred embodiment in which the optical unit 210a shown in FIG. 2 is further provided with a first transmissive polarizing diffraction element 218.
  • the first transmissive polarizing diffraction element 218 transmits and refracts a portion of the light that has passed through the second partial reflection element 213.
  • the first transmissive polarizing diffraction element 218 diffracts (bends) light to a greater extent in the end regions compared to the central region, and acts as a focusing lens or diverging lens while maintaining a flat shape.
  • the first transmissive polarizing diffraction element 218 comprises a liquid crystal layer formed using a liquid crystal composition containing a liquid crystal compound, the liquid crystal layer having a liquid crystal orientation pattern in which the orientation of the optical axis derived from the liquid crystal compound changes while rotating continuously along at least one direction in the plane, and when the length of the orientation of the optical axis derived from the liquid crystal compound rotating 180° in the plane is defined as one period, the liquid crystal orientation pattern has regions in the plane having different lengths for one period of the pattern, the liquid crystal layer has regions in the plane in which the optical axis rotates twisted in the thickness direction of the liquid crystal layer, and has regions having different total magnitudes of twist angles in the thickness direction.
  • the first transmissive polarizing diffraction element 218 will be described in detail later.
  • the action of the path going back and forth between the image display element 202, the reflective liquid crystal diffraction element 212, and the half mirror 214 is the same as that of the image display system 200d shown in FIG. 5, so a description thereof will be omitted.
  • the right-handed circularly polarized light that is reflected by the reflective liquid crystal diffraction element 212 and transmitted through the half mirror 214 is incident on the first transmissive polarized diffraction element 218.
  • the first transmissive polarized diffraction element 218 acts as a focusing lens for the right-handed circularly polarized light, focusing the incident right-handed circularly polarized light. This makes it possible to further widen the field of view (FOV), which is the area in which an image is displayed.
  • FOV field of view
  • the image display system 200f shown in FIG. 7 has, in this order, an image display element 202, a circular polarizing plate 204, an optical element 220, and an optical unit 210a.
  • the optical unit 210a has a configuration similar to that of the optical unit 210a of the image display system 200a shown in FIG. 2.
  • the image display system 200f shown in FIG. 7 is a preferred embodiment of the image display system 200a shown in FIG. 2, in which the optical element 220 is between the image display element 202 and the optical unit 210a.
  • Optical element 220 has the function of refracting the light emitted from image display element 202, and has regions with different angles of refraction at different positions within the surface of optical element 220.
  • Optical element 220 diffracts (refracts) light more at the end regions than at the central region, and acts as a converging lens or diverging lens while maintaining a flat shape.
  • the optical element 220 comprises a liquid crystal layer formed using a liquid crystal composition containing a liquid crystal compound, and has a liquid crystal orientation pattern in which the orientation of the optical axis derived from the liquid crystal compound changes while rotating continuously along at least one direction in the plane, and the liquid crystal layer has regions in the plane in which the length of one period in the liquid crystal orientation pattern differs when the length of the optical axis orientation derived from the liquid crystal compound rotates 180° in the plane is defined as one period.
  • the optical element 220 including such a liquid crystal layer is a transmissive polarizing diffraction element.
  • the optical element 220 is also referred to as a second transmissive polarizing diffraction element. The second polarizing diffraction element will be described in detail later.
  • an optical element 220 having regions with different refraction angles at different positions in the plane is disposed between the image display element 202 and the optical unit 210a, and directivity is imparted to the light irradiated from the image display element 202 according to the position in the plane, thereby improving the brightness at the end side of the displayed image and making the brightness distribution uniform.
  • a configuration in which a transmissive liquid crystal diffraction element is used to adjust the luminance distribution of light emitted from an image display element in this manner is disclosed, for example, in Crystals 2021, 11, 107.
  • the optical element 220 is disposed between the image display element 202 and the optical unit 210a, but this is not limiting.
  • the image display system of the present invention may have an image display element and an optical unit, the image display element having a light source and an optical element, the optical element having a function of refracting light emitted from the light source, and having regions with different angles of refraction at different positions within the plane.
  • the optical element in this case may also be the second transmissive polarizing diffraction element described above.
  • the image display system may be configured to have an optical element (second transmissive polarized diffraction element) 220 between the optical unit 210e having the first and second partial reflection elements and the first transmissive polarized diffraction element 218 and the image display element 202.
  • the image display system may have an optical unit having the first and second partially reflective elements, the first transmissive polarizing diffraction element 218, and the circular polarizer 216, and an optical element (second transmissive polarizing diffraction element) 220 between the image display element 202.
  • Reflective liquid crystal diffraction element A partially reflective element (reflective liquid crystal diffraction element) having a cholesteric liquid crystal layer will be described below.
  • the reflective liquid crystal diffraction element has a cholesteric liquid crystal layer
  • the cholesteric liquid crystal layer has a liquid crystal orientation pattern in which the orientation of the optical axis derived from the liquid crystal compound changes while rotating continuously along at least one direction in the plane, and when the length of the optical axis orientation derived from the liquid crystal compound rotating 180° in the plane is defined as one period, there are regions in the plane where the length of one period in the liquid crystal orientation pattern differs, and there are regions in the plane where the helical pitch of the helical structure differs.
  • FIG. 8 conceptually shows an example of a reflective liquid crystal diffraction element.
  • the reflective liquid crystal diffraction element 18 shown in FIG. 8 has a support 20, an alignment film 24, and a cholesteric liquid crystal layer 26.
  • the cholesteric liquid crystal layer 26 of the illustrated reflective liquid crystal diffraction element 18 selectively reflects light of a specific wavelength, and reflects light in a direction different from regular reflection (mirror reflection).
  • reflecting light in a direction different from regular reflection is also referred to as diffracting (bending) the reflected light.
  • the reflective liquid crystal diffraction element 18 in the illustrated example has a support 20 and an alignment film 24, but the reflective liquid crystal diffraction element does not have to have the support 20 and the alignment film 24.
  • the reflective liquid crystal diffraction element may be configured with only the alignment film 24 and the cholesteric liquid crystal layer 26 by removing the support 20 from the above configuration, or may be configured with only the cholesteric liquid crystal layer 26 by removing the support 20 and the alignment film 24.
  • various layer configurations can be used for the reflective liquid crystal diffraction element as long as the cholesteric liquid crystal layer has a liquid crystal orientation pattern in which the direction of the optical axis derived from the liquid crystal compound changes while rotating continuously along at least one direction in the plane, and the pitch of the helical structure in the cholesteric liquid crystal layer has regions that are different in the plane, and when the length of the rotation of the optical axis derived from the liquid crystal compound by 180° in the plane is defined as one period, the length of one period is different, and the reflective liquid crystal diffraction element has regions that have different lengths.
  • the above points also apply to the reflective liquid crystal diffraction elements according to the various aspects of the present invention described below.
  • FIG. 9 is a plan view of the cholesteric liquid crystal layer shown in FIG. 8.
  • the cholesteric liquid crystal layer 26 conceptually shows only the liquid crystal compound 30 (liquid crystal compound molecules) on the surface of the alignment film.
  • FIG. 9 is a plan view of the cholesteric liquid crystal layer shown in FIG. 8.
  • the cholesteric liquid crystal layer 26 is described as a representative example, but the cholesteric liquid crystal layer described later also has a similar configuration and effect, except that the length ⁇ of one period of the liquid crystal orientation pattern described later and the reflection wavelength range are different.
  • cholesteric liquid crystal layers have wavelength-selective reflectivity.
  • the cholesteric liquid crystal layer 26 is a cholesteric liquid crystal layer that has a selective reflection center wavelength in the green wavelength region, it will reflect right-handed circularly polarized light of green light and transmit other light.
  • the cholesteric liquid crystal layer 26 has liquid crystal compounds 30 rotated and oriented in the plane direction, so it refracts (diffracts) and reflects the incident circularly polarized light in a direction in which the optical axis direction is continuously rotating.
  • the direction of diffraction differs depending on the rotation direction of the incident circularly polarized light.
  • the cholesteric liquid crystal layer 26 reflects right-handed or left-handed circularly polarized light of the selective reflection wavelength, and diffracts this reflected light.
  • the optical axis 30A derived from the liquid crystal compound 30 is the axis along which the refractive index of the liquid crystal compound 30 is the highest, that is, the slow axis.
  • the optical axis 30A is along the long axis direction of the rod shape.
  • the optical axis 30A is along the direction perpendicular to the disc surface.
  • the optical axis 30A derived from the liquid crystal compound 30 is also referred to as the "optical axis 30A of the liquid crystal compound 30" or the "optical axis 30A".
  • the liquid crystal compounds 30 constituting the cholesteric liquid crystal layer 26 are two-dimensionally aligned in a specific direction indicated by the arrow X and in a direction perpendicular to this direction (the direction of the arrow X) according to the alignment pattern formed on the underlying alignment film 24.
  • the direction perpendicular to the arrow X direction is referred to as the Y direction for the sake of convenience. That is, in FIG. 8 and FIG. 10 described later, the Y direction is the direction perpendicular to the paper surface.
  • the liquid crystal compound 30 forming the cholesteric liquid crystal layer 26 has a liquid crystal orientation pattern in which the orientation of the optical axis 30A changes while continuously rotating along the direction of the arrow X in the plane of the cholesteric liquid crystal layer 26.
  • the liquid crystal compound 30 has a liquid crystal orientation pattern in which the optical axis 30A of the liquid crystal compound 30 changes while continuously rotating in the clockwise direction along the direction of the arrow X.
  • the orientation of the optical axis 30A of the liquid crystal compound 30 changes while continuously rotating in the direction of the arrow X (a specific direction), specifically means that the angle between the optical axis 30A of the liquid crystal compound 30 aligned along the direction of the arrow X and the direction of the arrow X differs depending on the position in the direction of the arrow X, and the angle between the optical axis 30A and the direction of the arrow X changes sequentially from ⁇ to ⁇ +180° or ⁇ -180° along the direction of the arrow X.
  • the specific direction (direction of the arrow X) along which the orientation of the optical axis 30A is aligned so as to change while continuously rotating is also referred to as the alignment axis (direction).
  • the difference in angle between the optical axes 30A of the liquid crystal compounds 30 adjacent to each other in the direction of the arrow X is preferably 45° or less, more preferably 15° or less, and even more preferably a smaller angle.
  • the liquid crystal compound 30 forming the cholesteric liquid crystal layer 26 has the same orientation of the optical axis 30A in the Y direction perpendicular to the direction of the arrow X, i.e., in the Y direction perpendicular to the one direction in which the optical axis 30A continuously rotates.
  • the liquid crystal compound 30 forming the cholesteric liquid crystal layer 26 has the same angle between the optical axis 30A of the liquid crystal compound 30 and the direction of the arrow X in the Y direction.
  • the length (distance) over which the optical axis 30A of the liquid crystal compound 30 rotates 180° in the direction of the arrow X, in which the optical axis 30A continuously rotates and changes within the plane is defined as the length ⁇ of one period in the liquid crystal orientation pattern.
  • the distance between the centers in the direction of the arrow X of two liquid crystal compounds 30 that have the same angle with respect to the direction of the arrow X is defined as the length ⁇ of one period.
  • the distance between the centers in the direction of the arrow X of two liquid crystal compounds 30 whose directions of the optical axes 30A coincide with the direction of the arrow X is defined as the length ⁇ of one period.
  • this length ⁇ of one period is also referred to as "one period ⁇ ".
  • the liquid crystal orientation pattern of the cholesteric liquid crystal layer repeats this one period ⁇ in the direction of the arrow X, i.e., in one direction in which the direction of the optical axis 30A rotates and changes continuously.
  • the cholesteric liquid crystal layer 26 has a liquid crystal orientation pattern in which the optical axis 30A changes while continuously rotating in the direction of the arrow X (a specific direction) within the plane.
  • the cholesteric liquid crystal layer 26 having such a liquid crystal orientation pattern reflects incident light in a direction angled with the direction of the arrow X with respect to specular reflection.
  • the cholesteric liquid crystal layer 26 does not reflect light incident from the normal direction in the normal direction, but reflects it at an angle in the direction of the arrow X with respect to the normal direction.
  • Light incident from the normal direction is, in other words, light incident from the front, and is light incident perpendicular to the main surface.
  • the main surface is the largest surface of the sheet-like object.
  • the angle of reflection of light by a cholesteric liquid crystal layer having a liquid crystal orientation pattern varies depending on the length ⁇ of one period of the liquid crystal orientation pattern in which the optical axis 30A rotates 180° in the direction of the arrow X, i.e., one period ⁇ . Specifically, the shorter the one period ⁇ , the greater the angle of the reflected light relative to the incident light.
  • the cholesteric liquid crystal layer of the reflective liquid crystal diffraction element has regions in which the length ⁇ of one period of the liquid crystal orientation pattern in the cholesteric liquid crystal layer varies within the plane, as conceptually shown in FIG. 8. Furthermore, the cholesteric liquid crystal layer of the reflective liquid crystal diffraction element has regions in which the pitch of the helical structure in the cholesteric liquid crystal layer varies within the plane, as conceptually shown in FIG. 8.
  • the cholesteric liquid crystal layer 26 has a helical pitch PT2 in the right region in Fig. 8 that is longer than the helical pitch PT0 in the left region in Fig. 8, and a helical pitch PT1 (not shown) in the central region in the horizontal direction in Fig. 8 that is longer than the helical pitch PT0 and shorter than the helical pitch PT2 . That is, the helical pitch becomes longer from the left region to the right region in Fig. 8.
  • the helical pitch is the distance that the liquid crystal compound makes one helical rotation (360° rotation), but for simplicity in Fig. 8, the distance of half a rotation (180° rotation) is shown as PT0 and PT2 .
  • the cholesteric liquid crystal layer 26 has a period length ⁇ A2 in the right region in Fig. 8 that is shorter than the period length ⁇ A0 in the left region in Fig. 8, and a period length ⁇ A1 in the central region in the horizontal direction in Fig. 8 that is shorter than the period length ⁇ A0 and longer than the period length ⁇ A2 . That is, the cholesteric liquid crystal layer 26 has a period length ⁇ that is shorter from the left region to the right region in Fig. 8.
  • the function of the cholesteric liquid crystal layer will now be described in more detail with reference to FIG. 10, in order to clearly show the function of the reflective liquid crystal diffraction element 18, only the cholesteric liquid crystal layer 26 is shown. For the same reason, it is assumed that light is incident on the reflective liquid crystal diffraction element 18 from the normal direction (front). For the sake of explanation, it is assumed that the cholesteric liquid crystal layer 26 selectively reflects right-handed circularly polarized light G R of green light and transmits other light.
  • the cholesteric liquid crystal layer 26 has three regions A0, A1, and A2 from the left in FIG. 10, and the length of the helical pitch and the length of one period ⁇ are different in each region. Specifically, the helical pitch is longer in the order of regions A0, A1, and A2, and the length of one period ⁇ is shorter in the order of regions A0, A1, and A2.
  • FIG. 10 illustrates only a portion of the cholesteric liquid crystal layer 26, and the cholesteric liquid crystal layer 26 may have four or more regions with different lengths of the helical pitch and lengths of one period ⁇ .
  • one period ⁇ A2 of the liquid crystal orientation pattern in region A2 is shorter than one period ⁇ A1 of the liquid crystal orientation pattern in region A1, so that, as shown in Fig. 10, the angle of reflection of the incident light, ⁇ A2 , of the reflected light in region A2 is larger than the angle ⁇ A1 of the reflected light in region A1. Also, since one period ⁇ A0 of the liquid crystal orientation pattern in region A0 is longer than one period ⁇ A1 of the liquid crystal orientation pattern in region A1, as shown in Fig. 10, the angle of reflection of the incident light, ⁇ A0, of the reflected light in region A0 is smaller than the angle ⁇ A1 of the reflected light in region A1.
  • the configuration has regions with different lengths of one period in which the direction of the optical axis of the liquid crystal compound rotates 180 degrees in the plane, the reflection angle differs depending on the position of incidence of the light, and so the amount of reflected light differs depending on the position of incidence in the plane. In other words, regions in which the reflected light becomes darker are created depending on the position of incidence in the plane.
  • a reflective liquid crystal diffraction element has a cholesteric liquid crystal layer having regions with different helical pitches within the plane.
  • the pitch length PL A2 of the helical structure in region A2 of the cholesteric liquid crystal layer 26 is longer than the pitch length PL A1 of the helical structure in region A1
  • the pitch length PL A0 of the helical structure in region A0 is shorter than the pitch length PL A1 of the helical structure in region A1.
  • the pitch length of the helical structure by lengthening the pitch length of the helical structure and making the selectively reflected wavelength when blue shifted the same as the wavelength of the incident light, it is possible to increase the reflection efficiency at the wavelength of the incident light. Therefore, it is possible to suppress the occurrence of areas where the reflected light becomes dark depending on the incident position within the surface.
  • the reflection angle ⁇ A1 of the reflected light in the region A1 is larger than the reflection angle ⁇ A0 of the reflected light in the region A0. That is, the length of one period ⁇ A1 in the region A1 is shorter than the length of one period ⁇ A0 in the region A0. Therefore, the helical pitch PL A1 in the region A1 is made longer than the helical pitch PL A0 in the region A0. Also, the helical pitch PL A2 in the region A2 where the reflection angle ⁇ A2 of the reflected light is the largest, that is, where the length of one period ⁇ A2 is the shortest, is made longer than the helical pitches in the regions A0 and A1. This makes it possible to suppress a decrease in the amount of reflected light reflected in the regions A1 and A2, and to make the amount of reflected light uniform regardless of the incident position in the surface.
  • the reflective liquid crystal diffraction element 18 in areas within the plane where the reflection angle by the cholesteric liquid crystal layer is large, the incident light is reflected by areas with a long pitch of the helical structure. In contrast, in areas within the plane where the reflection angle by the cholesteric liquid crystal layer is small, the incident light is reflected by areas with a short pitch of the helical structure. In other words, in the reflective liquid crystal diffraction element 18, the reflected light of the incident light can be brightened by setting the length of the pitch of the helical structure within the plane according to the magnitude of the reflection angle by the cholesteric liquid crystal layer. Therefore, with the reflective liquid crystal diffraction element 18, the reflection angle dependency of the amount of reflected light within the plane can be reduced.
  • the present invention is not limited to this, and in a reflective liquid crystal diffraction element, in areas where the length of one period of the liquid crystal orientation pattern is different, there may be areas where the permutation of the length of one period matches the permutation of the pitch length of the helical structure.
  • the pitch length of the helical structure has a preferred range according to one period ⁇ of the in-plane liquid crystal orientation pattern, and may be set appropriately.
  • the cholesteric liquid crystal layer has a liquid crystal orientation pattern in which the direction of the optical axis derived from the liquid crystal compound changes while rotating continuously along at least one direction in the plane.
  • the pitch of the helical structure in the cholesteric liquid crystal phase By adjusting the pitch of the helical structure in the cholesteric liquid crystal phase, the inclined plane pitch of the inclined planes of the light and dark parts relative to the main surface observed when the cross section of the cholesteric liquid crystal layer is measured with a SEM (Scanning Electron Microscope) (the distance in the normal direction to the inclined planes from light part to light part or from dark part to dark part is defined as 1/2 plane pitch), can be adjusted, and the selective reflection central wavelength for oblique light can be adjusted.
  • SEM Sccanning Electron Microscope
  • the cholesteric liquid crystal layer preferably has a radial pattern in which the optical axis 30A of the liquid crystal compound 30 in the liquid crystal orientation pattern changes while continuously rotating radially from the inside to the outside.
  • FIG. 11 shows a plan view of a cholesteric liquid crystal layer with a radial liquid crystal orientation pattern.
  • FIG. 11 also shows only the liquid crystal compound 30 on the surface of the orientation film, but as mentioned above, in the cholesteric liquid crystal layer 34, the liquid crystal compound 30 on the surface of this orientation film has a helical structure in which the liquid crystal compound 30 is spirally stacked, starting from the liquid crystal compound 30 on the surface of the orientation film, as in the example shown in FIG. 8.
  • the optical axis (not shown) of the liquid crystal compound 30 is the longitudinal direction of the liquid crystal compound 30.
  • the direction of the optical axis of the liquid crystal compound 30 changes while continuously rotating along a number of directions from the center of the cholesteric liquid crystal layer 34 toward the outside, for example, the direction indicated by the arrow D1 , the direction indicated by the arrow D2 , the direction indicated by the arrow D3 , etc. That is, the cholesteric liquid crystal layer 34 has the arrow D direction radially from the inside to the outside.
  • the direction of the optical axis changes while rotating in the same direction radially from the center of the cholesteric liquid crystal layer 34.
  • the embodiment shown in Fig. 11 is a counterclockwise orientation.
  • the rotation direction of the optical axis becomes counterclockwise from the center toward the outside.
  • the lines connecting the liquid crystal compounds whose optical axes are oriented in the same direction are circular, and it can also be said that the lines form a concentric pattern in which the circular lines are arranged concentrically.
  • Such a cholesteric liquid crystal layer 34 having a radial liquid crystal orientation pattern can reflect incident light as divergent or convergent light depending on the rotation direction of the optical axis of the liquid crystal compound 30 and the direction of the circularly polarized light to be reflected. That is, by forming the liquid crystal orientation pattern of the cholesteric liquid crystal layer in a radial manner, the reflective liquid crystal diffraction element exhibits the function of, for example, a concave mirror or a convex mirror.
  • the liquid crystal orientation pattern of the cholesteric liquid crystal layer is concentric and the reflective liquid crystal diffraction element acts as a concave mirror, it is preferable to gradually shorten one period ⁇ in which the optical axis rotates by 180° in the liquid crystal orientation pattern from the center of the cholesteric liquid crystal layer 34 toward the outside in one direction in which the optical axis continuously rotates.
  • the shorter the period ⁇ of the liquid crystal orientation pattern the larger the reflection angle of light with respect to the incident direction.
  • the light can be more focused and the performance as a concave mirror can be improved.
  • a reflective liquid crystal diffraction element has regions in which the pitch of the helical structure of the cholesteric liquid crystal layer is different. In the example shown in Fig.
  • the pitch of the helical structure of the cholesteric liquid crystal layer 34 is gradually increased from the center toward the outside in one direction in which the optical axis continuously rotates, thereby suppressing a decrease in the amount of reflected light in the outer region of the cholesteric liquid crystal layer 34.
  • the reflective liquid crystal diffraction element when used as a convex mirror, it is preferable to rotate the continuous rotation direction of the optical axis in the liquid crystal orientation pattern from the center of the cholesteric liquid crystal layer 34 in the opposite direction to that in the case of the concave mirror described above.
  • the light from the cholesteric liquid crystal layer can be more divergent, improving the performance as a convex mirror.
  • the decrease in the amount of reflected light in the outer regions of the cholesteric liquid crystal layer 34 can be suppressed.
  • the reflective liquid crystal diffraction element when used as a convex mirror, it is preferable to reverse the direction of the circularly polarized light reflected by the cholesteric liquid crystal layer (sense of the helical structure) compared to the case of a concave mirror, i.e., to reverse the direction in which the cholesteric liquid crystal layer rotates helically.
  • the light reflected by the cholesteric liquid crystal layer can be more divergent, improving the performance as a convex mirror.
  • the reflective liquid crystal diffraction element can be made to function as a concave mirror.
  • ⁇ (r) ( ⁇ / ⁇ ) [(r 2 + f 2 ) 1/2 - f]...Equation (4)
  • ⁇ (r) represents the angle of the optical axis at distance r from the center
  • ⁇ represents the selective reflection central wavelength of the cholesteric liquid crystal layer
  • f represents the desired focal length.
  • the reflective liquid crystal diffraction element for example when it is desired to provide a light intensity distribution in the reflected light, it is also possible to use a configuration in which, rather than gradually changing one period ⁇ in one direction in which the optical axis rotates continuously, there are regions in which one period ⁇ differs partially in one direction in which the optical axis rotates continuously.
  • the exposure method and exposure device of the alignment film for orienting such a cholesteric liquid crystal layer can be the same as that of the first transmissive polarized diffraction element described later.
  • the material for forming the cholesteric liquid crystal layer can be the same as that of the first transmissive polarized diffraction element described later, except that a chiral agent (chiral agent) for helically cholesterically aligning the liquid crystal compound is added to the material for forming the liquid crystal layer of the first transmissive polarized diffraction element described later.
  • the method for forming the cholesteric liquid crystal layer can be the same as that of the first transmissive polarized diffraction element described later, except that the liquid crystal compound is cholesterically oriented.
  • the thickness of the cholesteric liquid crystal layer there is no limit to the thickness of the cholesteric liquid crystal layer, and the thickness that provides the required light reflectance can be set appropriately depending on the application of the reflective liquid crystal diffraction element 18, the light reflectance required for the cholesteric liquid crystal layer, and the material from which the cholesteric liquid crystal layer is formed, etc.
  • the reflective liquid crystal diffraction element 18 reflects and diffracts light at a larger diffraction angle near the end. Therefore, it is preferable that the cholesteric liquid crystal layer has a region where the length of one period ⁇ in the liquid crystal orientation pattern is less than 1.0 ⁇ m.
  • the reflective liquid crystal diffraction element 18 has one cholesteric liquid crystal layer, but this is not limited to this and may have two or more cholesteric liquid crystal layers. It may also have one or more cholesteric liquid crystal layers and one or more conventional cholesteric liquid crystal layers.
  • the reflective liquid crystal diffraction element 18 has a configuration having multiple cholesteric liquid crystal layers, it is preferable that the length of one period and the helical pitch of the multiple cholesteric liquid crystal layers are different from each other at any one point in the plane.
  • the reflective liquid crystal diffraction element 18 has three cholesteric liquid crystal layers, one for each color.
  • the first to third cholesteric liquid crystal layers have different lengths of one period and helical pitches at any one point in the plane, and preferably have a region where ⁇ 1 ⁇ ⁇ 2 ⁇ ⁇ 3, where ⁇ 1, ⁇ 2, and ⁇ 3 are the lengths of one period at any one point in the plane of the first to third cholesteric liquid crystal layers.
  • the first transmissive polarizing diffraction element has a liquid crystal layer formed using a liquid crystal composition containing a liquid crystal compound, and the liquid crystal layer has a liquid crystal orientation pattern in which the orientation of the optical axis derived from the liquid crystal compound changes while rotating continuously along at least one direction in the plane, and when the length of the orientation of the optical axis derived from the liquid crystal compound rotating 180° in the plane is defined as one period, the liquid crystal orientation pattern has a region in the plane where the length of one period is different, the liquid crystal layer has a region in the plane where the optical axis rotates twisted in the thickness direction of the liquid crystal layer, and preferably has a region where the total magnitude of the twist angle in the thickness direction is different.
  • the first transmissive polarizing diffraction element is a transmissive liquid crystal diffractive lens that selectively focuses right-handed or left-handed circularly polarized light.
  • the transmissive polarizing diffraction element is also simply referred to as the polarizing diffraction element.
  • Fig. 12 conceptually shows an example of the polarizing diffraction element 40.
  • Fig. 12 is a cross-sectional view in the thickness direction.
  • the plan view of this polarizing diffraction element 40 is similar to Fig. 11.
  • the polarizing diffraction element 40 has a liquid crystal layer 46 formed using a liquid crystal composition containing the liquid crystal compound 30 .
  • the liquid crystal layer 46 has a liquid crystal orientation pattern in which the direction of the optical axis derived from the liquid crystal compound 30 changes while continuously rotating along at least one direction in the plane.
  • the liquid crystal layer 46 has regions in the plane where the length of one period is different. Furthermore, the liquid crystal layer 46 has regions within its plane where the optical axis originating from the liquid crystal compound 30 is twisted and rotated in the thickness direction of the liquid crystal layer 46, and has regions where the total magnitude of the twist angle in the thickness direction is different.
  • the polarization diffraction element 40 has a substrate 42, an alignment film 44, and a liquid crystal layer 46.
  • the liquid crystal layer 46 acts as a polarization diffraction element. Therefore, the polarizing diffraction element 40 may be composed of only the liquid crystal layer 46, or may be composed of the alignment film 44 and the liquid crystal layer 46 after the substrate 42 has been peeled off, or may be composed of the liquid crystal layer 46 laminated to another substrate after the substrate 42 and alignment film 44 have been peeled off from the liquid crystal layer 46.
  • the liquid crystal layer 46 is a liquid crystal layer formed on an alignment film 44 using a composition containing a liquid crystal compound 30, and is formed by orienting and fixing the liquid crystal compound 30 in the liquid crystal alignment pattern described below.
  • the liquid crystal layer 46 has a liquid crystal orientation pattern in which the direction of the optical axis derived from the liquid crystal compound 30 changes while continuously rotating in one direction, radially from the inside to the outside. That is, the liquid crystal orientation pattern of the liquid crystal layer 46 shown in Figures 11 and 12 is a radial pattern in which the direction of the optical axis derived from the liquid crystal compound 30 changes while continuously rotating in one direction, radially from the inside to the outside.
  • the lines connecting the liquid crystal compounds whose optical axes are oriented in the same direction are circular, and it can also be said that the pattern is a concentric pattern in which the line segments of the circle are arranged concentrically.
  • Fig. 11 only shows the liquid crystal compound 30 at the interface of the liquid crystal layer 46 on the alignment film 44 side.
  • the liquid crystal layer 46 has a configuration in which the liquid crystal compound 30 is stacked in the thickness direction, similar to a liquid crystal layer formed using a composition containing a normal liquid crystal compound, as shown in Fig. 12.
  • the liquid crystal layer 46 has a region in its plane where the liquid crystal compound 30 is twisted and rotated in the thickness direction, and has a region where the total magnitude of the twist angle in the thickness direction is different, as described above.
  • a rod-like liquid crystal compound is exemplified as the liquid crystal compound 30 in FIGS. 11 and 12, the direction of the optical axis coincides with the longitudinal direction of the liquid crystal compound 30.
  • the direction of the optical axis of the liquid crystal compound 30 changes while continuously rotating along a number of directions from the center, i.e., the optical axis, of the liquid crystal layer 46 toward the outside, for example, the direction indicated by the arrow D1 , the direction indicated by the arrow D2 , the direction indicated by the arrow D3 , the direction indicated by the arrow D4, .... Therefore, the rotation direction of the optical axis of the liquid crystal compound 30 is the same in all directions (one direction) in the liquid crystal layer 46.
  • the rotation direction of the optical axis of the liquid crystal compound 30 is counterclockwise in all directions, including the direction indicated by the arrow D1 , the direction indicated by the arrow D2 , the direction indicated by the arrow D3, and the direction indicated by the arrow D4 . That is, when the arrows D1 and D4 are regarded as one straight line, the rotation direction of the optical axis of the liquid crystal compound 30 is reversed at the center of the liquid crystal layer 46 on this straight line. As an example, the straight line formed by the arrows D1 and D4 is directed to the right direction in the figure (the direction of the arrow D1 ).
  • the optical axis of the liquid crystal compound 30 first rotates clockwise from the outside of the liquid crystal layer 46 to the center, reverses the rotation direction at the center of the liquid crystal layer 46, and then rotates counterclockwise from the center of the liquid crystal layer 46 to the outside.
  • the center of the liquid crystal layer 46 is the optical axis of the polarizing diffraction element.
  • a liquid crystal layer having a liquid crystal orientation pattern in which the direction of the optical axis derived from the liquid crystal compound 30 changes while continuously rotating in one direction acts as a transmissive liquid crystal diffraction element that diffracts the incident circularly polarized light in one direction and the opposite direction of the rotation of the optical axis depending on the rotation direction of the optical axis and the rotation direction of the incident circularly polarized light.
  • the diffraction direction (refracting direction) of the transmitted light depends on the rotation direction of the optical axis of the liquid crystal compound 30. That is, in this liquid crystal orientation pattern, when the rotation direction of the optical axis of the liquid crystal compound 30 facing in one direction is reversed, the diffraction direction of the transmitted light becomes the opposite direction to the one direction in which the optical axis rotates.
  • the diffraction direction of the transmitted light differs depending on the rotation direction of the incident circularly polarized light. That is, in this liquid crystal orientation pattern, the diffraction direction of the transmitted light is reversed when the incident light is right-handed circularly polarized light and when it is left-handed circularly polarized light.
  • the liquid crystal layer 46 has the function of a typical ⁇ /2 plate, that is, the function of imparting a phase difference of half the wavelength, or 180°, to the polarized light component incident on the liquid crystal layer. Therefore, the direction of rotation of the circularly polarized light that is incident on and diffracted by the liquid crystal layer 46 is reversed. That is, right-handed circularly polarized light that is incident on and diffracted by the liquid crystal layer 46 exits as left-handed circularly polarized light, and left-handed circularly polarized light exits as right-handed circularly polarized light.
  • the length of one period when the length of one period is defined as the length of the optical axis direction originating from the liquid crystal compound rotating 180° in one direction in which the direction of the optical axis of the liquid crystal compound 30 changes while rotating continuously, the length of one period gradually becomes shorter from the inside to the outside.
  • the shorter the length of one period the larger the diffraction angle. Therefore, in the liquid crystal layer 46 having a concentric liquid crystal orientation pattern, the diffraction angle gradually increases from the center of the concentric circles toward the outside.
  • the liquid crystal layer 46 having a concentric liquid crystal orientation pattern in which the optical axis derived from the liquid crystal compound has a radially changing liquid crystal orientation pattern that continuously rotates can transmit incident light in a divergent or converging manner depending on the rotation direction of the optical axis of the liquid crystal compound 30 and the rotation direction of the incident circularly polarized light.
  • the polarization diffraction element 40 having such a liquid crystal layer 46 acts, for example, as a concave lens when right-handed circularly polarized light is incident, and as a convex lens when left-handed circularly polarized light is incident, depending on the rotation direction of the incident circularly polarized light.
  • the polarization diffraction element 40 acts as a convex lens when right-handed circularly polarized light is incident, and as a concave lens when left-handed circularly polarized light is incident.
  • the liquid crystal layer 46 acts as a convex lens when left-handed circularly polarized light is incident, and focuses the left-handed circularly polarized light.
  • a partially enlarged plan view of the liquid crystal layer 46 has the same configuration as that shown in FIG.
  • the function of the liquid crystal layer 46 will be described in detail with reference to a liquid crystal layer 46A having a liquid crystal orientation pattern in which the optical axis 30A derived from the liquid crystal compound 30 changes while continuously rotating in one direction as indicated by the arrow X, as shown in FIG.
  • the optical axis 30A originating from the liquid crystal compound 30 is also referred to as "the optical axis 30A of the liquid crystal compound 30" or "the optical axis 30A”.
  • the liquid crystal compound 30 is two-dimensionally aligned in a plane parallel to one direction indicated by an arrow X and a Y direction perpendicular to the arrow X.
  • the Y direction is perpendicular to the paper surface.
  • the direction indicated by the arrow X will also be simply referred to as "the direction of the arrow X”.
  • the circumferential direction of the concentric circles in the concentric liquid crystal alignment pattern corresponds to the Y direction in FIG.
  • the liquid crystal layer 46A has a liquid crystal alignment pattern in which the direction of the optical axis 30A derived from the liquid crystal compound 30 changes while continuously rotating along the direction of the arrow X within the plane of the liquid crystal layer 46A.
  • the direction of the optical axis 30A of the liquid crystal compound 30 changes while continuously rotating in the direction of the arrow X (a predetermined direction), specifically means that the angle between the optical axis 30A of the liquid crystal compound 30 aligned along the direction of the arrow X and the direction of the arrow X differs depending on the position in the direction of the arrow X, and the angle between the optical axis 30A and the direction of the arrow X changes sequentially from ⁇ to ⁇ +180° or ⁇ 180° along the direction of the arrow X.
  • the liquid crystal compounds 30 forming the liquid crystal layer 46A are arranged at equal intervals in the Y direction perpendicular to the direction of the arrow X, i.e., in the Y direction perpendicular to the one direction in which the optical axis 30A continuously rotates.
  • the angles between the optical axes 30A of the liquid crystal compounds 30 aligned in the Y direction are equal to each other and the direction of the arrow X.
  • regions in which the optical axis 30A faces in the same direction are formed in annular shapes that coincide with the center, forming a concentric liquid crystal orientation pattern.
  • the length (distance) over which the optical axis 30A of the liquid crystal compound 30 rotates by 180° is the length ⁇ of one period in the liquid crystal alignment pattern.
  • one period ⁇ in the liquid crystal orientation pattern is defined as the length (distance) over which the optical axis 30A of the liquid crystal compound 30 rotates 180° in the direction of the arrow X, in which the orientation of the optical axis 30A continuously rotates and changes within the plane.
  • one period ⁇ in the liquid crystal orientation pattern is defined as the distance from when the angle between the optical axis 30A of the liquid crystal compound 30 and the direction of the arrow X changes from ⁇ to ⁇ +180°. That is, one period ⁇ is the distance between the centers in the direction of the arrow X of two liquid crystal compounds 30 that are at the same angle with respect to the direction of the arrow X. Specifically, as shown in Fig. 9, one period ⁇ is the distance between the centers in the direction of the arrow X of two liquid crystal compounds 30 whose optical axes 30A coincide with the direction of the arrow X.
  • the liquid crystal orientation pattern repeats this one period ⁇ in the direction of the arrow X, that is, in one direction in which the direction of the optical axis 30A continuously rotates and changes.
  • the liquid crystal layer 46A having such a liquid crystal orientation pattern is also a transmission type liquid crystal diffraction element, and this one period ⁇ is the period (one period) of the diffraction structure.
  • the liquid crystal compounds aligned in the Y direction have the same angle between their optical axes 30A and the direction of the arrow X.
  • a region R is defined as a region in which the liquid crystal compounds 30 aligned in the Y direction have the same angle between their optical axes 30A and the direction of the arrow X.
  • the value of the in-plane retardation (Re) in each region R is preferably half the wavelength, i.e., ⁇ /2. This in-plane retardation is calculated by the product of the refractive index difference ⁇ n associated with the refractive index anisotropy of the region R and the thickness of the liquid crystal layer.
  • the refractive index difference associated with the refractive index anisotropy of the region R in the liquid crystal layer is a refractive index difference defined by the difference between the refractive index in the direction of the slow axis in the plane of the region R and the refractive index in the direction perpendicular to the direction of the slow axis. That is, the refractive index difference ⁇ n associated with the refractive index anisotropy of the region R is equal to the difference between the refractive index of the liquid crystal compound 30 in the direction of the optical axis 30A and the refractive index of the liquid crystal compound 30 in the direction perpendicular to the optical axis 30A in the plane of the region R.
  • the refractive index difference ⁇ n is equal to the refractive index difference of the liquid crystal compound.
  • the region formed in a circular ring shape with the same center and in which the optical axis 30A has the same direction corresponds to region R.
  • the incident light L1 which is left-handed circularly polarized
  • the transmitted light L2 which is right-handed circularly polarized and tilted at a certain angle in the direction of the arrow X with respect to the incident direction.
  • the transmitted light L5 travels in a different direction from that of the transmitted light L2 , that is, in the opposite direction to the direction of the arrow X with respect to the incident direction.
  • the incident light L4 is converted into the transmitted light L5 of left-handed circular polarization tilted at a certain angle in the direction of the arrow X with respect to the incident direction.
  • the in-plane retardation value of the multiple regions R is preferably a half wavelength
  • the in-plane retardation values of the multiple regions R in the liquid crystal layer 46A can be outside the range of the above formula (1).
  • the light can be separated into light traveling in the same direction as the incident light and light traveling in a direction different from the incident light.
  • ⁇ n 550 ⁇ d approaches 0 nm or 550 nm, the component of the light traveling in the same direction as the incident light increases, and the component of the light traveling in a direction different from the incident light decreases.
  • the formula (2) indicates that the liquid crystal compound 30 contained in the liquid crystal layer 46A has reverse dispersion. That is, when the formula (2) is satisfied, the liquid crystal layer 46A can accommodate incident light with a wide band of wavelengths.
  • the liquid crystal layer 46A can adjust the angles of diffraction of the transmitted light L2 and L5 by changing one period ⁇ of the formed liquid crystal orientation pattern. Specifically, the shorter one period ⁇ of the liquid crystal orientation pattern is, the stronger the interference between the lights that have passed through the adjacent liquid crystal compounds 30 becomes, so that the transmitted light L2 and L5 can be diffracted to a greater extent. Furthermore, in the liquid crystal layer 46A, the rotation direction of the optical axis 30A of the liquid crystal compound 30, which rotates along the direction of the arrow X, is reversed, so that the direction of diffraction of the transmitted light can be reversed. Furthermore, the liquid crystal layer 46A diffracts transmitted light in opposite directions depending on the rotation direction of the incident circularly polarized light.
  • the liquid crystal layer 46A diffracts transmitted light in opposite directions for right-handed circularly polarized light and left-handed circularly polarized light. As described above, the same can be said about the liquid crystal layer 46 having a concentric liquid crystal orientation pattern.
  • the liquid crystal layer 46 has regions in which the optical axis rotates in a twisted manner in the thickness direction of the liquid crystal layer 46, and has regions in which the twist angle in the thickness direction is different. This point will be described in more detail later.
  • the liquid crystal layer 46 is formed using a liquid crystal composition containing a rod-shaped liquid crystal compound or a discotic liquid crystal compound, and has a liquid crystal orientation pattern in which the optical axis of the rod-shaped liquid crystal compound or the optical axis of the discotic liquid crystal compound is oriented as described above.
  • An alignment film 44 having an alignment pattern corresponding to the above-mentioned liquid crystal alignment pattern is formed on a substrate 42, and a liquid crystal composition is applied onto the alignment film 44 and cured to form a liquid crystal layer 46 consisting of a cured layer of the liquid crystal composition.
  • the liquid crystal composition for forming the liquid crystal layer 46 contains a rod-shaped liquid crystal compound or a discotic liquid crystal compound, and may further contain other components such as a leveling agent, an alignment control agent, a polymerization initiator, and an alignment assistant.
  • the liquid crystal layer 46 is preferably broadband with respect to the wavelength of the incident light, and is preferably constructed using a liquid crystal material with a birefringence that exhibits reverse dispersion. It is also preferable to make the liquid crystal layer 46 substantially broadband with respect to the wavelength of the incident light by imparting a twist component to the liquid crystal composition and by laminating different retardation layers. For example, a method of realizing a patterned ⁇ /2 plate with a broadband by laminating two layers of liquid crystal with different twist directions in the liquid crystal layer 46 is shown in JP 2014-089476 A and the like, and can be preferably used in the present invention.
  • Rod-shaped liquid crystal compounds As the rod-shaped liquid crystal compound, azomethines, azoxys, cyanobiphenyls, cyanophenyl esters, benzoates, cyclohexane carboxylic acid phenyl esters, cyanophenylcyclohexanes, cyano-substituted phenylpyrimidines, alkoxy-substituted phenylpyrimidines, phenyldioxanes, tolanes, and alkenylcyclohexylbenzonitriles are preferably used. Not only the above-mentioned low molecular weight liquid crystal molecules, but also polymeric liquid crystal molecules can be used.
  • liquid crystal layer 46 it is more preferable to fix the orientation of the rod-shaped liquid crystal compound by polymerization, and an example of a polymerizable rod-shaped liquid crystal compound is Makromol. Chem. , Vol. 190, p. 2255 (1989), Advanced Materials, Vol. 5, p. 107 (1993), U.S. Patent Nos. 4,683,327, 5,622,648, and 5,770,107, International Publication Nos. 95/22586, 95/24455, 97/00600, 98/23580, and 98/52905, JP-A Nos. 1-272551, 6-16616, 7-110469, and 11-80081, and Japanese Patent Application No. 2001-64627 can be used.
  • rod-shaped liquid crystal compounds those described in, for example, JP-T-11-513019 and JP-A-2007-279688 can also be preferably used.
  • the discotic liquid crystal compound for example, those described in JP-A-2007-108732 and JP-A-2010-244038 can be preferably used.
  • the liquid crystal compound 30 stands up in the thickness direction in the liquid crystal layer, and the optical axis 30A originating from the liquid crystal compound is defined as an axis perpendicular to the disc surface, that is, a so-called fast axis.
  • the liquid crystal composition for forming the liquid crystal layer 46 may contain a photoreactive chiral agent.
  • the photoreactive chiral agent is, for example, a compound represented by the following general formula (I), and has the property of being able to control the orientation structure of a liquid crystal compound and also being able to change the helical pitch of the liquid crystal compound, i.e., the twisting power (HTP: helical twisting power) of the helical structure by irradiation with light.
  • the photoreactive chiral agent represented by the following general formula (I) can particularly greatly change the HTP of the liquid crystal molecule.
  • R represents a hydrogen atom, an alkoxy group having 1 to 15 carbon atoms, an acryloyloxyalkyloxy group having a total of 3 to 15 carbon atoms, or a methacryloyloxyalkyloxy group having a total of 4 to 15 carbon atoms.
  • the alkoxy group having 1 to 15 carbon atoms include a methoxy group, an ethoxy group, a propoxy group, a butoxy group, a hexyloxy group, and a dodecyloxy group.
  • an alkoxy group having 1 to 12 carbon atoms is preferred, and an alkoxy group having 1 to 8 carbon atoms is particularly preferred.
  • Examples of the acryloyloxyalkyloxy group having a total of 3 to 15 carbon atoms include an acryloyloxyethyloxy group, an acryloyloxybutyloxy group, and an acryloyloxydecyloxy group. Among these, an acryloyloxyalkyloxy group having 5 to 13 carbon atoms is preferred, and an acryloyloxyalkyloxy group having 5 to 11 carbon atoms is particularly preferred.
  • Examples of the methacryloyloxyalkyloxy group having a total of 4 to 15 carbon atoms include a methacryloyloxyethyloxy group, a methacryloyloxybutyloxy group, and a methacryloyloxydecyloxy group.
  • a methacryloyloxyalkyloxy group having 6 to 14 carbon atoms is preferred, and a methacryloyloxyalkyloxy group having 6 to 12 carbon atoms is particularly preferred.
  • the molecular weight of the photoreactive chiral agent represented by the above general formula (I) is preferably 300 or more.
  • the photoreactive chiral agent may be, for example, a photoreactive optically active compound represented by the following general formula (II):
  • R represents a hydrogen atom, an alkoxy group having 1 to 15 carbon atoms, an acryloyloxyalkyloxy group having a total of 3 to 15 carbon atoms, or a methacryloyloxyalkyloxy group having a total of 4 to 15 carbon atoms.
  • the alkoxy group having 1 to 15 carbon atoms include a methoxy group, an ethoxy group, a propoxy group, a butoxy group, a hexyloxy group, an octyloxy group, and a dodecyloxy group.
  • an alkoxy group having 1 to 10 carbon atoms is preferable, and an alkoxy group having 1 to 8 carbon atoms is particularly preferable.
  • Examples of the acryloyloxyalkyloxy group having a total of 3 to 15 carbon atoms include an acryloyloxy group, an acryloyloxyethyloxy group, an acryloyloxypropyloxy group, an acryloyloxyhexyloxy group, an acryloyloxybutyloxy group, and an acryloyloxydecyloxy group.
  • an acryloyloxyalkyloxy group having 3 to 13 carbon atoms is preferred, and an acryloyloxyalkyloxy group having 3 to 11 carbon atoms is particularly preferred.
  • Examples of the methacryloyloxyalkyloxy group having a total of 4 to 15 carbon atoms include a methacryloyloxy group, a methacryloyloxyethyloxy group, and a methacryloyloxyhexyloxy group.
  • a methacryloyloxyalkyloxy group having 4 to 14 carbon atoms is preferred, and a methacryloyloxyalkyloxy group having 4 to 12 carbon atoms is particularly preferred.
  • the molecular weight of the photoreactive optically active compound represented by the above general formula (II) is preferably 300 or more.
  • the compound has high solubility with the liquid crystal compound described below, and it is more preferable that the solubility parameter SP value is close to that of the liquid crystal compound.
  • photoreactive optically active compound represented by the above general formula (II) exemplary compounds (21) to (32) are shown below, but the present invention is not limited to these.
  • the photoreactive chiral agent can also be used in combination with a non-photoreactive chiral agent, such as a chiral compound whose twisting power is highly temperature-dependent.
  • a non-photoreactive chiral agent such as a chiral compound whose twisting power is highly temperature-dependent.
  • non-photoreactive chiral agents include the chiral agents described in JP-A No. 2000-44451, JP-T-10-509726, WO98/00428, JP-T-2000-506873, JP-T-9-506088, Liquid Crystals (1996, 21, 327), Liquid Crystals (1998, 24, 219), etc.
  • liquid crystal layer formed using a composition containing a liquid crystal compound and having a liquid crystal orientation pattern in which the direction of the optical axis 30A rotates along the direction of arrow X refracts circularly polarized light, and the smaller the period ⁇ of the liquid crystal orientation pattern, the larger the angle of refraction (diffraction). Therefore, for example, when a pattern is formed such that one period ⁇ of the liquid crystal orientation pattern is different in different regions in the plane, the brightness of the transmitted light changes depending on the angle of refraction when the light is incident on different regions in the plane and refracted at different angles. In particular, the transmitted light with a large angle of refraction becomes dark.
  • the liquid crystal layer 46 constituting the polarizing diffraction element 40 has a liquid crystal orientation pattern in which the direction of the optical axis derived from the liquid crystal compound rotates in one direction, and further has a region in which the optical axis rotates twisted in the thickness direction of the liquid crystal layer, and has a region in which the total magnitude of the rotational torsion angle is different in the plane.
  • the structure in which the optical axis of the liquid crystal compound rotates twisted in the thickness direction of the liquid crystal layer can be formed by adding the above-mentioned chiral agent to the liquid crystal composition.
  • a configuration in which the torsion angle in the thickness direction is different for each region in the plane can be formed by adding the above-mentioned photoreactive chiral agent to the liquid crystal composition and irradiating each region with a different amount of light.
  • a polarizing diffraction element having such a liquid crystal layer has a small dependence of the amount of transmitted light within the plane on the refraction angle, and for example, when incident light is refracted at different angles in different regions within the plane, the transmitted light can be made brighter.
  • the polarizing diffraction element 40 is basically only the liquid crystal layer that exerts an optical effect. Therefore, in order to simplify the drawing and clearly show the configuration and the effects, only the liquid crystal layer 46 of the polarization diffraction element 40 is shown in Fig. 16.
  • the liquid crystal layer 46 of the polarizing diffraction element 40 refracts the incident light in a predetermined direction and transmits it, targeting circularly polarized light.
  • the incident light is left-handed circularly polarized light.
  • the liquid crystal layer 46 has three regions E0, E1, and E2 from the left side in Fig. 16, and the length ⁇ of one period is different in each region. Specifically, the length ⁇ of one period is shorter in the order of regions E0, E1, and E2. Moreover, regions E1 and E2 have a structure in which the optical axis is twisted and rotated in the thickness direction of the liquid crystal layer. In the following description, this structure in which the optical axis is twisted and rotated in the thickness direction of the liquid crystal layer is also referred to as a "twisted structure.”
  • the twist angle in the thickness direction of region E1 is smaller than the twist angle in the thickness direction of region E2.
  • Region E0 does not have a twist structure. That is, region E0 has a twist angle of 0°. The twist angle is the twist angle in the entire thickness direction.
  • the polarizing diffraction element 40A when left-handed circularly polarized light LC1 is incident on the region E1 in the plane of the liquid crystal layer 46, as described above, it is refracted at a predetermined angle in the direction of the arrow X with respect to the incident direction, i.e., in one direction in which the direction of the optical axis of the liquid crystal compound changes while continuously rotating, and is then transmitted.
  • left-handed circularly polarized light LC2 is incident on the region E2 in the plane of the liquid crystal layer 46, it is refracted at a predetermined angle in the direction of the arrow X with respect to the incident direction and is then transmitted.
  • one period ⁇ E0 of the liquid crystal orientation pattern in region E0 is longer than one period ⁇ E1 of the liquid crystal orientation pattern in region E1
  • the angle of refraction of incident light is smaller for the angle ⁇ E0 of the transmitted light in region E0 than for the angle ⁇ E1 of the transmitted light in region E1, as shown in Fig. 14.
  • the liquid crystal layer is configured to have regions with different lengths of one period in which the direction of the optical axis of the liquid crystal compound rotates 180° in the plane, the diffraction angle differs depending on the position of incidence of the light, and thus the amount of diffracted light differs depending on the position of incidence in the plane. In other words, regions in which the transmitted and diffracted light becomes dark are created depending on the position of incidence in the plane.
  • the liquid crystal layer of the polarizing diffraction element has a region that is twisted and rotated in the thickness direction, and has regions with different magnitudes of twist angles in the thickness direction.
  • the twist angle ⁇ E2 in the thickness direction of the region E2 of the liquid crystal layer 46 is larger than the twist angle ⁇ E1 in the thickness direction of the region E1.
  • the region E0 does not have a twist structure in the thickness direction. This makes it possible to suppress a decrease in the diffraction efficiency of the refracted light.
  • the incident light is transmitted through a layer with a large twist angle in the thickness direction and refracted
  • the incident light is transmitted through a layer with a small twist angle in the thickness direction and refracted. That is, in the liquid crystal layer 46, by setting the twist angle in the thickness direction in the plane according to the magnitude of refraction by the liquid crystal layer, it is possible to make the transmitted light brighter than the incident light. This reduces the refraction angle dependency of the amount of transmitted light in the plane of the polarizing diffraction element 40. In other words, it reduces luminance unevenness in the plane of the polarizing diffraction element 40. Therefore, when used in an image display system such as a VR system, it is possible to display an image with less luminance unevenness in the observed image.
  • the angle of light refraction within the plane of the liquid crystal layer 46 increases as one period ⁇ of the liquid crystal orientation pattern becomes shorter.
  • the twist angle of the liquid crystal compound 30 in the thickness direction in the plane of the liquid crystal layer 46 is larger in a region with a short period ⁇ in which the direction of the optical axis 30A rotates 180° along the direction of the arrow X in the liquid crystal orientation pattern than in a region with a long period ⁇ .
  • the illustrated liquid crystal layer 46 as shown in Fig.
  • one period ⁇ E2 of the liquid crystal orientation pattern in the region E2 of the liquid crystal layer 46 is shorter than one period ⁇ E1 of the liquid crystal orientation pattern in the region E1, and the twist angle ⁇ E2 in the thickness direction is larger. That is, the region E2 of the liquid crystal layer 46 on the light incident side refracts light more. Therefore, by setting the in-plane twist angle ⁇ in the thickness direction for one period ⁇ of the target liquid crystal orientation pattern, it is possible to suitably brighten the transmitted light that is refracted at different angles in different regions in the plane.
  • the shorter the period of the liquid crystal alignment pattern is in an area the larger the twist angle of the liquid crystal compound 30 in the thickness direction (the larger the total twist angle is).
  • one period ⁇ of the liquid crystal orientation pattern becomes gradually shorter from the center toward the outside, so that it is preferable that the twist angle of the liquid crystal compound 30 in the thickness direction becomes gradually larger from the center toward the outside.
  • the change in the period ⁇ and/or the change in the twist angle in the thickness direction of the liquid crystal compound 30 may be either stepwise or continuous.
  • the present invention is not limited thereto, and the transmission type polarizing diffraction element may have a region in which the permutation of the length of one period of the liquid crystal orientation pattern is consistent with the permutation of the magnitude of the twist angle in the thickness direction in the region where the length of one period is different.
  • the twist angle in the thickness direction has a preferred range according to one period ⁇ of the in-plane liquid crystal orientation pattern, and may be set appropriately.
  • the liquid crystal layer 46 of the polarizing diffraction element 40 preferably has a region in which the twist angle in the thickness direction is 10° to 360°.
  • the twist angle in the thickness direction of the liquid crystal layer 46 of the polarizing diffraction element 40 may be appropriately set in accordance with one period ⁇ of the in-plane liquid crystal orientation pattern.
  • one period ⁇ of the liquid crystal orientation pattern in the liquid crystal layer 46 may be set appropriately according to the angle of refraction (diffraction) required for the polarizing diffraction element 40.
  • the liquid crystal layer 46 has a region in which the length of one period is 0.6 ⁇ m or less.
  • a configuration in which the liquid crystal layer 46 has regions with different twist angles of the in-plane twist structure can be formed by using a liquid crystal composition containing a liquid crystal compound and a photoreactive chiral agent whose helical structure's twisting power (HTP) changes when irradiated with the above-mentioned light, and irradiating each region with light of a wavelength that changes the HTP of the chiral agent before or during the curing of the liquid crystal composition that forms the liquid crystal layer 46, with different amounts of light being irradiated to each region.
  • HTP helical structure's twisting power
  • the HTP of the chiral agent decreases when irradiated with light.
  • the amount of light irradiation for each region for example, in a region with a large amount of irradiation, the HTP decreases significantly and the induction of the helix decreases, so the twist angle of the twisted structure decreases.
  • the decrease in HTP is small, so the twist angle of the twisted structure increases.
  • a gradation mask is a mask whose transmittance to the irradiated light varies within its surface.
  • the liquid crystal layer of the polarizing diffraction element may have regions that are twisted and rotated in the thickness direction (directions of twist angle) different from one another.
  • a liquid crystal layer may have a liquid crystal orientation pattern in which the optical axis rotates in one direction, and further have a region in which the optical axis twists and rotates in the thickness direction of the liquid crystal layer, and have regions in which the twist angle of rotation is different within the plane, and the regions may have mutually different directions of twisting and rotating in the thickness direction. In this way, by having regions that are twisted and rotated in different directions in the thickness direction, transmitted light can be refracted efficiently for incident light of various polarization states in the regions having a twist angle in the thickness direction.
  • a liquid crystal layer having the above-described liquid crystal orientation pattern has light and dark areas extending from one surface to the other surface in a cross-sectional image observed with a scanning electron microscope (SEM) at a cross section cut in the thickness direction along the direction in which the optical axis rotates continuously.
  • the bright and dark portions have different tilt directions and angles depending on the presence or absence of twist in the liquid crystal compound 30 in the thickness direction, the twist direction and angle, and one period of the liquid crystal alignment pattern. For example, like the above-mentioned region E0, when the liquid crystal compound 30 is not twisted and rotated in the thickness direction, it has light and dark parts extending in the thickness direction.
  • the liquid crystal compound 30 when the liquid crystal compound 30 is twisted and rotated in the thickness direction as in the above-mentioned regions E1 and E2, the light and dark portions are inclined with respect to the thickness direction.
  • the twist direction (rotation direction) of the liquid crystal compound when the twist direction (rotation direction) of the liquid crystal compound is reversed, the inclination directions of the light and dark portions are reversed.
  • a region 36b in which the liquid crystal compound 30 is not twisted in the thickness direction is sandwiched between regions 46a and 46c in which the liquid crystal compound 30 is twisted in the thickness direction, so that a region having light portions 52 and dark portions 54 extending in the thickness direction is sandwiched between regions in which the light portions 52 and dark portions 54 are inclined in the opposite directions.
  • the configuration in which the liquid crystal layer has a plurality of regions with different twist directions of the liquid crystal compound 30 is not limited to the region shown in FIG. 17, and various configurations can be used. That is, in the present invention, the liquid crystal layer can have various configurations, such as a configuration consisting of two regions, region 46a and region 46c, in which the twist directions of the liquid crystal compound 30 in the thickness direction are opposite, a configuration consisting of four regions obtained by stacking two of these two regions, a configuration consisting of two regions, region 46a and region 46b, in which the liquid crystal compound 30 is not twisted in the thickness direction, a configuration having a plurality of regions in which the inclination direction of the dark portions is the same but the inclination angles, i.e., the twist angles of the liquid crystal compound, are different, and a configuration in which region 46b in which the liquid crystal compound 30 is not twisted is further stacked on top of the three regions shown in FIG. 17.
  • the twist angle of the liquid crystal compound 30 in the liquid crystal layer is the sum of the twist angles of the respective regions.
  • the twist angle of the liquid crystal compound 30 in region 46 a is 80°
  • the twist angle of the liquid crystal compound 30 in the central region 46 b is 0°
  • the twist angle of the liquid crystal compound 30 in region 46 c is ⁇ 80°
  • the twist angle of the liquid crystal compound 30 in the liquid crystal layer is “(80)+(0)+( ⁇ 80)”, which is 0°.
  • the absolute value of the total twist angle of the liquid crystal compound 30 increases toward the periphery.
  • the polarizing diffraction element 40 has the substrate 42, the alignment film 44, and the liquid crystal layer 46 described above.
  • the substrate 42 constituting such a polarization diffraction element 40 may be made of various sheet-like materials as long as it can support the alignment film 44 and the liquid crystal layer 46 (described later).
  • the substrate 42 is preferably a transparent support, and examples of the support include a polyacrylic resin film such as polymethyl methacrylate, a cellulose resin film such as cellulose triacetate, a cycloolefin polymer film (for example, trade name "Arton” manufactured by JSR Corporation, or trade name "ZEONOR” manufactured by Zeon Corporation), polyethylene terephthalate (PET), polycarbonate, and polyvinyl chloride.
  • An alignment film 44 is formed on the surface of such a substrate 42 .
  • the liquid crystal orientation pattern in the liquid crystal layer 46 follows the orientation pattern formed in the orientation film 44. Therefore, the same orientation pattern as the liquid crystal orientation pattern in the liquid crystal layer 46 is formed in the orientation film 44 for forming a liquid crystal layer having such a liquid crystal orientation pattern.
  • Figure 18 conceptually shows an example of an exposure device that exposes a coating film that will become the alignment film 44 (photoalignment film) for forming a liquid crystal layer 46, to form an alignment pattern that corresponds to a concentric liquid crystal alignment pattern in which the optical axis continuously rotates radially and changes.
  • the exposure device 80 shown in Figure 18 has a light source 84 equipped with a laser 82, a polarizing beam splitter 86 that splits laser light M from the laser 82 into S-polarized light MS and P-polarized light MP, a mirror 90A arranged in the optical path of the P-polarized light MP and a mirror 90B arranged in the optical path of the S-polarized light MS, a lens 92 arranged in the optical path of the S-polarized light MS, a beam splitter 94, and a ⁇ /4 plate 96.
  • the P-polarized light MP split by the polarizing beam splitter 86 is reflected by a mirror 90A and enters a beam splitter 94.
  • the S-polarized light MS split by the polarizing beam splitter 86 is reflected by a mirror 90B, collected by a lens 92, and enters the beam splitter 94.
  • the P-polarized light MP and the S-polarized light MS are combined by the beam splitter 94 and converted by the ⁇ /4 plate 96 into right-handed circularly polarized light and left-handed circularly polarized light according to the polarization direction, and then enter the alignment film 44 on the substrate 42 .
  • the polarization state of the light irradiated onto the alignment film 44 changes periodically in the form of interference fringes.
  • an exposure pattern is obtained in which the pitch (one period) changes from the inside to the outside.
  • a radial (concentric) alignment pattern in which the alignment state changes periodically is obtained in the alignment film 44.
  • one period ⁇ of the liquid crystal orientation pattern in which the optical axis of the liquid crystal compound 30 continuously rotates 180° along one direction can be controlled by changing the refractive power of the lens 92, the focal length of the lens 92, and the distance between the lens 92 and the orientation film 44, etc.
  • the refractive power of the lens 92 the F-number of the lens 92
  • the length of one period of the liquid crystal alignment pattern can be changed in one direction in which the optical axis rotates continuously.
  • the length of one period of the liquid crystal orientation pattern can be changed in one direction in which the optical axis rotates continuously, depending on the spread angle of the light spread by the lens 92 that interferes with the parallel light.
  • the refractive power of the lens 92 when the refractive power of the lens 92 is weakened, the light approaches parallel light, and the length ⁇ of one period of the liquid crystal orientation pattern gradually shortens from the inside to the outside. Conversely, when the refractive power of the lens 92 is strengthened, the length ⁇ of one period of the liquid crystal orientation pattern suddenly shortens from the inside to the outside. That is, by adjusting the refractive index of the lens 92, it is possible to adjust the refractive index of the transmission type polarizing diffraction element (liquid crystal layer 46) which acts as a concave lens or a convex lens depending on the rotation direction of the incident circularly polarized light.
  • the transmission type polarizing diffraction element liquid crystal layer 46
  • a liquid crystal composition containing a liquid crystal compound and a photoreactive chiral agent for forming the above-mentioned liquid crystal layer 46 is applied to the exposed alignment film 44 thus formed, dried, and exposed using the gradation mask as described above, and further cured by ultraviolet irradiation or the like as necessary.
  • This allows the formation of a liquid crystal layer 46 having a concentric liquid crystal orientation pattern as described above, regions in the plane where the length of one period of the liquid crystal orientation pattern is different, regions in the plane where the liquid crystal compound twists and rotates in the thickness direction, and further regions where the total magnitude of the twist angle is different, thereby producing a polarizing diffraction element 40 as shown in Figures 11 and 12.
  • Photoalignment materials used in photoalignment films are described, for example, in JP-A-2006-285197, JP-A-2007-76839, JP-A-2007-138138, JP-A-2007-94071, JP-A-2007-121721, JP-A-2007-140465, and JP-A-2007-156439.
  • photocrosslinkable polyimides photocrosslinkable polyamides and photocrosslinkable esters described in JP-T-2003-520878, JP-T-2004-529220 and Japanese Patent No. 4162850
  • photodimerizable compounds described in JP-A-9-118717, JP-T-10-506420, JP-T-2003-505561, WO 2010 / 150748, JP-A-2013-177561 and JP-A-2014-12823, in particular cinnamate compounds, chalcone compounds and coumarin compounds are exemplified as preferred examples.
  • azo compounds photocrosslinkable polyimides, photocrosslinkable polyamides, photocrosslinkable esters, cinnamate compounds, and chalcone compounds are preferably used.
  • the present invention is not limited to this. That is, in the optical unit of the present invention, the polarizing diffraction element may have a plurality of liquid crystal layers.
  • a polarizing diffraction element having a plurality of liquid crystal layers and a wavelength-selective retardation layer provided between the liquid crystal layers is exemplified.
  • the wavelength-selective retardation layer is a member that converts circularly polarized light in a specific wavelength range into circularly polarized light having the opposite rotation direction.
  • the liquid crystal layer having the above-mentioned liquid crystal orientation pattern refracts and transmits circularly polarized light, but the refractive index differs depending on the wavelength of the transmitted light. That is, among red light, green light, and blue light, the refractive index (refractive angle) of red light, which has the longest wavelength, is the largest, and the refractive index of blue light, which has the shortest wavelength, is the smallest. Therefore, when red, green, and blue light corresponding to a full-color image are incident on one liquid crystal layer, the refractive index, i.e., the degree of focusing, of each light differs, which may result in color shifts in the observed image.
  • the refractive indexes i.e., the angles of refraction, of red light, green light, and blue light in the polarizing diffraction element can be made approximately equal.
  • FIG. 19 conceptually shows one example of this.
  • the polarization diffraction element 40A has a first liquid crystal layer 46C, a second liquid crystal layer 46D, and a third liquid crystal layer 46E in this order in the light traveling direction.
  • the period ⁇ of the liquid crystal orientation pattern is the shortest for the first liquid crystal layer 46C, and the longest for the second liquid crystal layer 46D.
  • the first liquid crystal layer 46C and the third liquid crystal layer 46E have the same rotation direction of the optical axis facing in one direction (the direction of the arrow X), while the second liquid crystal layer 46D has the opposite rotation direction.
  • the polarization diffraction element 40A has a wavelength-selective retardation layer 56R between the first liquid crystal layer 46C and the second liquid crystal layer 46D, and a wavelength-selective retardation layer 56G between the second liquid crystal layer 46D and the third liquid crystal layer 46E.
  • the wavelength-selective retardation layer 56R is a retardation layer that selectively converts the rotation direction of the circularly polarized light of red light.
  • the wavelength-selective retardation layer 56G is a retardation layer that selectively converts the rotation direction of the circularly polarized light of green light.
  • the circularly polarized light incident on the polarizing diffraction element 40A is right-handed circularly polarized light, and the light is therefore refracted in the opposite direction to the left-handed circularly polarized light described above.
  • the polarizing diffraction element 40A when right-handed circularly polarized red light R R , right-handed circularly polarized green light G R, and right-handed circularly polarized blue light B R are incident on the first liquid crystal layer 46C, each circularly polarized light is refracted as described above and converted into left-handed circularly polarized red light R 1L , left-handed circularly polarized green light G 1L, and left-handed circularly polarized blue light B 1L .
  • the angle of refraction by the first liquid crystal layer 46C is the largest for red light, which has the longest wavelength, and the smallest for blue light, which has the shortest wavelength. Therefore, as shown in Fig. 110, the angle of refraction of the incident light is the largest for red light (R), the intermediate angle ⁇ G1 for green light (G), and the smallest for blue light (B). Note that the first liquid crystal layer 46C has the shortest period ⁇ of the liquid crystal layer, so the angle of refraction of each light is largest when it passes through the first liquid crystal layer 46C.
  • the wavelength-selective retardation layer 56R converts only the circularly polarized light of red light into circularly polarized light having the opposite rotation direction, and transmits the other light as is (passes through).
  • the left-handed circularly polarized light R 1L of red light, the left-handed circularly polarized light G 1L of green light, and the left-handed circularly polarized light B 1L of blue light are incident on the wavelength-selective retardation layer 56R and transmitted therethrough, the left-handed circularly polarized light G 1L of green light and the left-handed circularly polarized light B 1L of blue light are transmitted as they are.
  • the left-handed circularly polarized light R 1L of red light is converted into the right-handed circularly polarized light R 1R of red light.
  • the right-handed circularly polarized red light R 1R , left-handed circularly polarized green light G 1L , and left-handed circularly polarized blue light B 1L that enter the second liquid crystal layer 46D are similarly refracted and converted into circularly polarized light with the opposite rotation direction, and are emitted as left-handed circularly polarized red light R 2L , right-handed circularly polarized green light G 2R, and right-handed circularly polarized blue light B 2R .
  • both the green light and the blue light incident on the second liquid crystal layer 46D are left-handed circularly polarized light, whereas the red light incident on the second liquid crystal layer 46D is right-handed circularly polarized light different from the green light and the blue light, the direction of which has been converted by the wavelength-selective retardation layer 56R.
  • the first liquid crystal layer 46C and the second liquid crystal layer 46D have the optical axis 30A of the liquid crystal compound 30 rotated in opposite directions.
  • the left-handed circularly polarized green light G2L and the left-handed circularly polarized blue light B2L that are incident on the second liquid crystal layer 46D are further refracted in the same direction as before, and are emitted at angles ⁇ G2 and ⁇ B2 relative to the incident light (right-handed circularly polarized green light G R and right-handed circularly polarized blue light B R ), as shown in Figure 20.
  • right-handed circularly polarized red light R1R which has an opposite rotation direction and is incident on the second liquid crystal layer 46D, is refracted in the opposite direction to that of the first liquid crystal layer 46C, as shown on the right side of Fig. 19.
  • left-handed circularly polarized red light R2L emitted from the second liquid crystal layer 46D is emitted at an angle ⁇ R2 smaller than the angle ⁇ R1 with respect to the incident light (right-handed circularly polarized red light R R ). Since the period ⁇ B of the second liquid crystal layer 46D is the longest, the angle of refraction of each light is smallest when it is transmitted through the second liquid crystal layer 46D.
  • the wavelength-selective retardation layer 56G converts only the circularly polarized green light into circularly polarized light having the opposite rotation direction, and transmits the other light as is.
  • the left-handed circularly polarized red light R2L , the right-handed circularly polarized green light G2R, and the right-handed circularly polarized blue light B2R enter the wavelength-selective retardation layer 56G and are transmitted therethrough, the left-handed circularly polarized red light R2L and the right-handed circularly polarized blue light B2R are transmitted as they are, whereas the right-handed circularly polarized green light G2R is converted to the left-handed circularly polarized green light G2L .
  • Left-handed circularly polarized red light R2L , left-handed circularly polarized green light G2L, and right-handed circularly polarized blue light B2R that enter the third liquid crystal layer 46E are similarly refracted and converted into circularly polarized light with the opposite rotation direction, and are emitted as right-handed circularly polarized red light R3R , right-handed circularly polarized green light G3R , and left-handed circularly polarized blue light B3L .
  • the blue light incident on the third liquid crystal layer 46E is right-handed circularly polarized blue light B2R . Since the direction of circular polarization of the red light has already been converted by the wavelength-selective retardation layer 56R, the red light incident on the third liquid crystal layer 46E is left-handed circularly polarized red light R2L, which has a different direction of circular polarization from that of the blue light. Furthermore, the green light incident on the third liquid crystal layer 46E is left-handed circularly polarized green light G2L , whose direction of circular polarization has been converted by the wavelength-selective retardation layer 56G.
  • the right-handed circularly polarized blue light B2R that enters the third liquid crystal layer 46E is further refracted in the same direction and, as shown in Figure 19, is emitted at an angle ⁇ B3 with respect to the incident light (right-handed circularly polarized blue light B R ).
  • left-handed circularly polarized red light R2L which has the opposite direction of circular polarization, is further refracted back when it enters the third liquid crystal layer 46E.
  • right-handed circularly polarized red light R3R exits the third liquid crystal layer 46E at an angle ⁇ R3 smaller than the previous angle ⁇ R2 with respect to the incident light (right-handed circularly polarized red light R R ).
  • left-handed circularly polarized green light G2L which has the opposite circular polarization to the blue light, enters the third liquid crystal layer 46E, it is refracted in the opposite direction as shown in the center of Fig. 20.
  • right-handed circularly polarized green light G3R emitted from the third liquid crystal layer 46E is emitted at an angle ⁇ G3 smaller than the angle ⁇ G2 with respect to the incident light (right-handed circularly polarized green light G R ).
  • red light which has the longest wavelength and is subject to the greatest refraction by the liquid crystal layer, is refracted by the first liquid crystal layer 46C, and then refracted twice in the opposite direction to the first liquid crystal layer 46C, by the second liquid crystal layer 46D and the third liquid crystal layer 46E.
  • green light which has the second longest wavelength and is refracted the second largest by the liquid crystal layers, is refracted in the same direction by the first liquid crystal layer 46C and the second liquid crystal layer 46D, and then refracted once in the opposite direction by the third liquid crystal layer 46E.
  • blue light which has the shortest wavelength and is least refracted by the liquid crystal layers, is refracted three times in the same direction by the first liquid crystal layer 46C, the second liquid crystal layer 46D, and the third liquid crystal layer 46E.
  • the polarizing diffraction element 40A first refracts all light in the same direction, and then refracts the longest wavelength light the greatest number of times in the opposite direction to the initial refraction according to the magnitude of refraction by the optically anisotropic layer depending on the wavelength, and as the wavelength of the light becomes shorter, the number of times of refraction in the opposite direction to the initial refraction is reduced, and the shortest wavelength light is refracted the least number of times in the opposite direction to the initial refraction.
  • the polarizing diffraction element 40A having a plurality of liquid crystal layers and wavelength-selective retardation layers can refract the incident red, blue and green light at approximately the same angles and emit them in approximately the same direction.
  • the design wavelength of the longest wavelength light is ⁇ a
  • the design wavelength of the intermediate wavelength light is ⁇ b
  • the design wavelength of the shortest wavelength light is ⁇ c ( ⁇ a> ⁇ b> ⁇ c)
  • one period of the liquid crystal orientation pattern in the first optically anisotropic layer is ⁇ 1
  • one period of the liquid crystal orientation pattern in the second optically anisotropic layer is ⁇ 2
  • one period of the liquid crystal orientation pattern in the third optically anisotropic layer is ⁇ 3
  • ⁇ 2 [( ⁇ a+ ⁇ c) ⁇ b/( ⁇ a- ⁇ b) ⁇ c] ⁇ 1
  • ⁇ 3 [( ⁇ a + ⁇ c) ⁇ b/( ⁇ b - ⁇ c) ⁇ a] ⁇ 1
  • either the first liquid crystal layer 46C or the third liquid crystal layer 46E may be the first layer.
  • the wavelength-selective retardation layer is a member that converts circularly polarized light in a specific wavelength range into circularly polarized light having the opposite rotation direction.
  • the wavelength-selective retardation layer shifts the phase by ⁇ only in a specific wavelength range.
  • Such a wavelength-selective retardation layer can also be called, for example, a ⁇ /2 plate that acts only in a specific wavelength range.
  • Such a wavelength-selective retardation layer can be produced, for example, by laminating a plurality of retardation plates having different retardations.
  • the wavelength selective retardation layer may be the wavelength selective retardation layer described in JP-A-2000-510961 and SID 99 DIGEST, pp. 1072-1075.
  • This wavelength-selective retardation layer converts linearly polarized light in a specific wavelength range into reverse linearly polarized light by stacking multiple retardation plates (retardation layers) with different slow axis angles (slow axis orientations).
  • the multiple retardation plates are not limited to a configuration in which all of the slow axis angles are different from each other, and it is sufficient that the slow axis angle of at least one layer is different from that of the other retardation plates.
  • At least one of the retardation plates preferably has normal dispersion.
  • a ⁇ /2 plate that acts only in a specific wavelength range can be realized by stacking a plurality of retardation plates with different slow axis angles.
  • the wavelength-selective retardation layer described in JP-A-2000-510961 and SID 99 DIGEST, pp. 1072-1075 selectively converts linearly polarized light into the opposite linearly polarized light.
  • the wavelength-selective retardation layer converts circularly polarized light in a specific wavelength range into circularly polarized light in the opposite rotation direction. Therefore, it is preferable to use the wavelength-selective retardation layer described in JP-T-2000-510961 and SID 99 DIGEST, pp.1072-1075, etc., by providing a ⁇ /4 plate on both sides.
  • a ⁇ /4 plate various retardation plates such as a polymer, a hardened layer of a liquid crystal compound, and a structural birefringent layer can be used.
  • the ⁇ /4 plate preferably has reverse dispersion, which allows it to handle incident light of a wide wavelength range.
  • a retardation layer that effectively functions as ⁇ /4 by laminating a plurality of retardation plates as the ⁇ /4 plate.
  • a ⁇ /4 plate that combines a ⁇ /2 plate and a ⁇ /4 plate to broaden the band can be used preferably because it can handle incident light with a wide band of wavelengths.
  • a polarizing diffraction element has multiple liquid crystal layers
  • a configuration that uses multiple liquid crystal layers that diffract polarized light in a specific wavelength range and does not diffract polarized light in a wavelength range different from the specific wavelength range.
  • a red liquid crystal layer that diffracts only red light and does not diffract light in other wavelength ranges a green liquid crystal layer that diffracts only green light and does not diffract light in other wavelength ranges, and a blue liquid crystal layer that diffracts only blue light and does not diffract light in other wavelength ranges are used, and the refractive indices (refractive angles) of the corresponding lights in the red liquid crystal layer, green liquid crystal layer, and blue liquid crystal layer are made to match.
  • a liquid crystal layer that diffracts polarized light in a specific wavelength range and does not diffract polarized light in a wavelength range different from the specific wavelength range can be produced, for example, by stacking multiple liquid crystal layers with different twist angles and/or film thicknesses.
  • a configuration using a plurality of liquid crystal layers as described in Proc. SPIE 11472, Liquid Crystals XXIV, 1147219 and the like can be used.
  • This polarizing diffraction element diffracts polarized light in a specific wavelength range and does not diffract polarized light in a wavelength range other than the specific wavelength range by stacking multiple liquid crystal layers with different twist angles and/or film thicknesses.
  • SPIE 11472, Liquid Crystals XXIV, 1147219, a polarizing diffraction element that diffracts polarized light in a specific wavelength range can be realized by alternately stacking liquid crystal layers with and without twist and appropriately setting the film thickness of each liquid crystal layer.
  • the second transmissive polarizing diffraction element comprises a liquid crystal layer formed using a liquid crystal composition containing a liquid crystal compound, and the liquid crystal layer has a liquid crystal orientation pattern in which the orientation of the optical axis derived from the liquid crystal compound changes while rotating continuously along at least one direction in the plane, and when the length of one period of the optical axis orientation derived from the liquid crystal compound rotating 180° in the plane is defined as one period, the liquid crystal layer has regions in the plane having different lengths of one period in the liquid crystal orientation pattern.
  • the second transmissive polarizing diffraction element is a transmissive liquid crystal diffractive lens that selectively diverges or focuses right-handed or left-handed circularly polarized light.
  • the polarizing diffraction element transmits incident light by diverging or focusing it depending on the rotation direction of the optical axis of the liquid crystal compound and the rotation direction of the incident circularly polarized light. Therefore, if the second transmissive polarizing diffraction element is appropriately set to diverge or focus incident light depending on the rotation direction of the target circularly polarized light, a polarizing diffraction element with the same configuration as the first transmissive polarizing diffraction element can be used.
  • the second transmissive polarizing diffraction element a polarizing diffraction element in which the liquid crystal layer does not have an area in the plane where the total magnitude of the twist angle in the thickness direction varies can also be used. Furthermore, as the second transmissive polarizing diffraction element, a polarizing diffraction element in which the liquid crystal layer does not have an area where the optical axis twists and rotates in the thickness direction of the liquid crystal layer can also be used.
  • optical unit and image display system of the present invention have been described in detail above, but the present invention is not limited to the above examples, and various improvements and modifications may of course be made without departing from the spirit of the present invention.
  • the following coating solution for forming an alignment film was applied onto the support by spin coating.
  • the support on which the coating film of the coating solution for forming an alignment film was formed was dried on a hot plate at 60° C. for 60 seconds to form an alignment film.
  • the alignment film was exposed using an exposure apparatus as shown in FIG. 20 to form an alignment film P-G1 having a radial alignment pattern.
  • the exposure device used was a laser emitting laser light with a wavelength of 355 nm.
  • the exposure dose of the interference light was 1000 mJ/cm 2 .
  • Composition G-1 Liquid crystal compound L-1 100.00 parts by mass Chiral agent C1 5.4 parts by mass Polymerization initiator I-1 3.00 parts by mass Surfactant F1 0.02 parts by mass Surfactant F2 0.20 parts by mass Methyl ethyl ketone 120.58 parts by mass Cyclopentanone 80.38 parts by mass
  • the cholesteric liquid crystal layer G1 was formed by applying the composition G-1 onto the photo-alignment film. Specifically, the composition G-1 was applied onto the photo-alignment film by spin coating, and the coating was heated on a hot plate at 120°C for 120 seconds. Thereafter, the coating was irradiated with ultraviolet light having a wavelength of 365 nm at an irradiation dose of 500 mJ/ cm2 using a high-pressure mercury lamp under a nitrogen atmosphere, thereby fixing the alignment of the liquid crystal compound, and forming a cholesteric liquid crystal layer G1 (reflective liquid crystal diffraction element G1).
  • the cholesteric liquid crystal layer G1 was confirmed by a polarizing microscope to have a periodic orientation pattern as shown in Figure 9.
  • the liquid crystal orientation pattern of the cholesteric liquid crystal layer G1 had a period ⁇ in which the optical axis of the liquid crystal compound rotated 180°, with one period ⁇ being 1.74 ⁇ m at a distance of 4 mm from the center, 0.64 ⁇ m at a distance of 15 mm from the center, and 0.59 ⁇ m at a distance of 18 mm from the center, resulting in a liquid crystal orientation pattern in which the period shortens toward the outside.
  • the length of one helical pitch (helical pitch P) in the cholesteric liquid crystal layer was 328 nm at any position in the plane.
  • a half mirror 1 was formed by depositing aluminum on the surface of a glass substrate opposite to the anti-reflection layer so that the reflectance was 40%.
  • the cholesteric liquid crystal layer G1 and half mirror 1 prepared above were arranged so that they faced each other.
  • the aluminum vapor deposition surface of the half mirror 1 was arranged on the side facing the cholesteric liquid crystal layer G1.
  • the cholesteric liquid crystal layer G1 and half mirror 1 were arranged in that order, and the distance between the cholesteric liquid crystal layer G1 and the aluminum vapor deposition surface was 3 mm, to prepare the optical unit 1.
  • An anti-reflection film was attached to the surface of the support opposite the surface on which the cholesteric liquid crystal layer G1 was formed.
  • Example 1 ⁇ Fabrication of Reflective Liquid Crystal Diffraction Element> (Formation of alignment film) In the same manner as in Comparative Example 1, an alignment film P-G1 was formed.
  • Composition G-2 Liquid crystal compound L-1 100.00 parts by mass Chiral agent C1 6.0 parts by mass Chiral agent C3 1.0 part by mass Polymerization initiator I-1 3.00 parts by mass Surfactant F1 0.02 parts by mass Surfactant F2 0.20 parts by mass Methyl ethyl ketone 120.58 parts by mass Cyclopentanone 80.38 parts by mass
  • the cholesteric liquid crystal layer G2 was formed by applying the composition G-2 onto the photo-alignment film. Specifically, the composition G-2 was applied onto the photo-alignment film by spin coating, and the coating film was heated on a hot plate at 120 ° C. for 120 seconds, and then the coating film was irradiated with ultraviolet light having a wavelength of 365 nm from an LED-UV exposure machine. At this time, the ultraviolet light was irradiated onto the coating film by changing the amount of irradiation within the plane. Specifically, the irradiation amount was changed within the plane so that the amount of irradiation decreased from the center to the end, and the coating film was irradiated. Thereafter, the coating film was heated to 120 ° C.
  • the coating film was irradiated with ultraviolet light having a wavelength of 365 nm at an irradiation amount of 500 mJ / cm 2 under a nitrogen atmosphere using a high-pressure mercury lamp, thereby fixing the orientation of the liquid crystal compound, and a cholesteric liquid crystal layer G2 (reflective liquid crystal diffraction element G2) was formed.
  • the cholesteric liquid crystal layer G2 was confirmed by a polarizing microscope to have a periodic orientation pattern as shown in Figure 9.
  • the liquid crystal orientation pattern of the cholesteric liquid crystal layer G2 had a period ⁇ in which the optical axis of the liquid crystal compound rotated 180°, with one period ⁇ being 1.74 ⁇ m at a distance of 4 mm from the center, 0.64 ⁇ m at a distance of 15 mm from the center, and 0.59 ⁇ m at a distance of 18 mm from the center, resulting in a liquid crystal orientation pattern in which the period shortens toward the outside.
  • the length of one helical pitch (helical pitch P) in the cholesteric liquid crystal layer was 328 nm at a distance of 4 mm from the center, 339 nm at a distance of 15 mm from the center, and 341 nm at a distance of 18 mm from the center.
  • An optical unit 2 was produced in the same manner as in the production of the optical unit 1 of Comparative Example 1, except that the cholesteric liquid crystal layer G2 was used instead of the cholesteric liquid crystal layer G1.
  • a film having a cellulose acylate film "Z-TAC”, an alignment film and an optically anisotropic layer was obtained in the same manner as the positive A plate described in paragraphs [0102] to [0126] of JP2019-215416A.
  • the optically anisotropic layer is a positive A plate (phase difference plate) having reverse wavelength dispersion, and the thickness of the positive A plate is controlled so that Re(550) is 138 nm.
  • composition QC-1 was applied to the positive A plate prepared above to form a coating film.
  • the applied coating film was heated to 70°C on a hot plate, and then cooled to 65°C.
  • the coating film was then irradiated with ultraviolet light having a wavelength of 365 nm at an exposure dose of 500 mJ/ cm2 using a high-pressure mercury lamp under a nitrogen atmosphere to fix the alignment of the liquid crystal compound and form a positive C plate 1.
  • a ⁇ /4 plate 1 having a positive A plate 1 and a positive C plate 1 was obtained.
  • the positive C plate 1 thus obtained had a retardation in the thickness direction, Rth(550), of ⁇ 69 nm.
  • Composition QC-1 Liquid crystal compound L-1 34.00 parts by mass Liquid crystal compound L-3 44.00 parts by mass Liquid crystal compound L-4 22.00 parts by mass Polymerization initiator PI-1 1.50 parts by mass Surfactant T-2 0.40 parts by mass Surfactant T-3 0.20 parts by mass Compound S-1 0.50 parts by mass Compound M-1 14.00 parts by mass Methyl ethyl Ketone 248.00 parts by mass ⁇
  • the film was further dried by conveying it between rolls of a heat treatment device to prepare an optical film having a thickness of 40 ⁇ m, which was used as cellulose acylate film 1.
  • the in-plane retardation of the obtained cellulose acylate film 1 was 0 nm.
  • the following coating solution for forming an alignment layer S-PA-1 was continuously applied onto the cellulose acylate film 1 using a wire bar.
  • the support on which the coating film was formed was dried with hot air at 140° C. for 120 seconds, and then the coating film was irradiated with polarized ultraviolet light (10 mJ/cm 2 , using an ultra-high pressure mercury lamp) to form a photoalignment layer PA1.
  • the film thickness was 0.3 ⁇ m.
  • the following coating solution S-P-1 for forming an optically absorbing anisotropic layer was continuously coated with a wire bar.
  • the coating layer P1 was heated at 140°C for 30 seconds, and the coating layer P1 was cooled to room temperature (23°C).
  • the film thickness was 1.6 ⁇ m.
  • the prepared ⁇ /4 plate 1 and a linear polarizer were laminated to obtain a circular polarizing plate 1.
  • the lambda/4 plate 1 was laminated so that the slow axis of the ⁇ /4 plate 1 and the absorption axis of the light absorption anisotropic layer P1 formed an angle of 45°.
  • the circular polarizer 1 and the optical unit prepared above were placed facing each other and evaluated.
  • the circular polarizer 1 and the optical unit were arranged in the order of the linear polarizer of the circular polarizer 1, the ⁇ /4 plate 1, the reflective liquid crystal diffraction element of the optical unit, and the half mirror.
  • the distance between the linear polarizer of the circular polarizer 1 and the half mirror of the optical unit was 12 mm, and light was incident from the linear polarizer side to perform the evaluation.
  • the light intensity of the light emitted from the optical unit when light was incident on the circular polarizer was evaluated.
  • the in-plane position of each element was expressed as a radial distance, with the intersection of the normal direction from the center of the concentric circles of the liquid crystal diffraction element and each element (linear polarizer, ⁇ /4 plate, half mirror, etc.) being taken as 0 mm from the center of the concentric circles of the liquid crystal diffraction element.
  • the angle of incidence was expressed as an angle relative to the perpendicular, with the direction perpendicular to the main surface of the circular polarizer 1 being taken as 0°.
  • a laser (wavelength: 532 nm) was incident at a position 3 mm into the circular polarizer 1 at an incident angle of -2.7°, and a photodetector was placed 12 mm away from the optical unit in the stacking direction to measure the light intensity of the light emitted from the optical unit.
  • the light intensity of the light emitted from the optical unit was measured when a laser (wavelength: 532 nm) was incident at a position 13 mm into the circular polarizer 1 at an incident angle of -7.4° and at a position 16 mm at an incident angle of -8°.
  • light emitted from a laser (wavelength: 532 nm) incident at a position 3 mm into the circular polarizer 1 at an incident angle of -2.7° is light that is emitted from the optical unit at a position 4 mm and an exit angle of 15°.
  • light that is incident from a laser (wavelength: 532 nm) at a position 13 mm into the circular polarizer 1 with an incident angle of -7.4° is emitted from the optical unit at a position 15 mm with an exit angle of 45°
  • light that is incident at a position 16 mm with an incident angle of -8° is emitted from the optical unit at a position 18 mm with an exit angle of 50°.
  • the above-prepared circular polarizing plate 1 was attached to the display of the "Huawei VR Glass” (the display, the circular polarizing plate 1 (linear polarizer, ⁇ /4 plate 1) were laminated in this order).
  • the optical unit 1 was placed on the front (the liquid crystal diffraction element was placed on the circular polarizing plate side), to prepare the virtual reality display device of Comparative Example 1. At this time, the distance between the linear polarizer of the polarizing plate 1 and the half mirror of the optical unit was arranged to be 12 mm.
  • the virtual reality display device of Example 1 was produced in the same manner as in Comparative Example 1, except that optical unit 1 was replaced with optical unit 2 produced in Example 1.
  • a green and black checkered pattern was displayed on the image display panel, and the brightness distribution of the display was visually evaluated.
  • the green display on the periphery was darker than in the center of the displayed image.
  • the brightness of the green display on the periphery was improved compared to Comparative Example 1, and the brightness distribution (viewing angle dependency) of the displayed image was improved.
  • the cholesteric liquid crystal layer G1 produced in Comparative Example 1 was disposed so as to face the half mirror 1.
  • the aluminum-deposited surface of the half mirror 1 was disposed on the side facing the cholesteric liquid crystal layer G1.
  • the half mirror 1 and the cholesteric liquid crystal layer G1 were disposed in this order, and the distance between the cholesteric liquid crystal layer G1 and the aluminum-deposited surface was 2 mm, to produce the optical unit 3.
  • An anti-reflection film was attached to the surface of the support opposite to the surface on which the cholesteric liquid crystal layer G1 was formed.
  • Example 2 An optical unit 4 was produced in the same manner as in the production of the optical unit 3 of Comparative Example 2, except that the cholesteric liquid crystal layer G2 was used instead of the cholesteric liquid crystal layer G1.
  • the circular polarizer 1 and the optical unit prepared above were placed facing each other and evaluated.
  • the circular polarizer 1 and the optical unit were arranged in the order of the linear polarizer of the circular polarizer 1, the ⁇ /4 plate 1, the half mirror of the optical unit, and the reflective liquid crystal diffraction element.
  • the distance between the linear polarizer of the circular polarizer 1 and the reflective liquid crystal diffraction element of the optical unit was arranged to be 15 mm, and light was incident from the linear polarizer side to perform the evaluation.
  • the light intensity of the light emitted from the optical unit when light was incident on the circular polarizer was evaluated.
  • the in-plane position of each element was expressed as a radial distance, with the intersection of the normal direction from the center of the concentric circles of the liquid crystal diffraction element and each element (linear polarizer, ⁇ /4 plate, half mirror, etc.) being taken as 0 mm from the center of the concentric circles of the liquid crystal diffraction element.
  • the angle of incidence was expressed as an angle relative to the perpendicular, with the direction perpendicular to the main surface of the circular polarizer 1 being taken as 0°.
  • a laser (wavelength: 532 nm) was incident at a position 3 mm from the circular polarizer 1 at an incident angle of -2.7°, and a photodetector was placed 11 mm away from the optical unit in the stacking direction to measure the light intensity of the light emitted from the optical unit.
  • the light intensity of the light emitted from the optical unit was measured when a laser (wavelength: 532 nm) was incident at a position 13 mm from the circular polarizer 1 at an incident angle of -7.4° and at a position 16 mm at an incident angle of -8°.
  • light emitted from a laser (wavelength: 532 nm) incident at a position 3 mm from the circular polarizer 1 at an incident angle of -2.7° is light that is emitted from the optical unit at a position 4 mm and an exit angle of 15°.
  • light that is incident from a laser (wavelength: 532 nm) at a position 13 mm into the circular polarizer 1 with an incident angle of -7.4° is emitted from the optical unit at a position 15 mm with an exit angle of 45°
  • light that is incident at a position 16 mm with an incident angle of -8° is emitted from the optical unit at a position 18 mm with an exit angle of 50°.
  • a virtual reality display device of Comparative Example 2 was produced in the same manner as in the production of the virtual reality display device of Comparative Example 1, except that optical unit 1 was changed to optical unit 3 produced in Comparative Example 2.
  • a half mirror was disposed on the circular polarizing plate side, and the distance between the linear polarizer and the liquid crystal diffraction element of the optical unit was arranged to be 15 mm.
  • the fabricated virtual reality display device In the fabricated virtual reality display device, a green and black checkered pattern was displayed on the image display panel, and the brightness distribution of the display was visually evaluated. In the virtual reality display device of Comparative Example 2, the green display on the periphery was darker than in the center of the displayed image. On the other hand, in the virtual reality display device of Example 2, the brightness of the green display on the periphery was improved compared to Comparative Example 2, and the brightness distribution (viewing angle dependency) of the displayed image was improved.
  • ⁇ Fabrication of reflection volume hologram> (Holographic photosensitive material)
  • a hologram photosensitive material "Litiholo C-RT20 (product name)" available from Liti Holographic Co.
  • This material is a laminate consisting of a substrate (glass, 2 mm thick)/hologram material layer (16 ⁇ m thick)/cover film (optically isotropic triacetyl cellulose film, 60 ⁇ m thick), and the hologram is recorded in the hologram material layer.
  • reference numerals 101a, 101b, and 101c denote laser light sources
  • reference numerals 102a, 102b, and 102c denote dichroic mirrors
  • reference numeral 103 denotes a polarizing beam splitter
  • reference numeral 104 denotes a plane mirror
  • reference numeral 105 denotes a beam expander
  • reference numeral 106 denotes a first aspherical lens
  • reference numeral 107 denotes a second aspherical lens
  • reference numeral 108 denotes a hologram photosensitive material
  • reference numeral 109 denotes the focus of the first aspherical lens
  • reference numeral 110 denotes a hologram lens
  • reference numeral 111 denotes a first light beam
  • reference numeral 112 denotes a second light beam.
  • the polarization state was adjusted using a wavelength plate and a polarizing plate (not shown).
  • interference exposure was performed for each wavelength using this exposure device, and the profile of the diffraction efficiency expression of the hologram material relative to the irradiation energy for each exposure wavelength was measured.
  • the illuminance of the light beam from each light source was then adjusted in advance using a filter (not shown) on the optical path from each light source so that the amount of diffraction efficiency expression of the hologram for each wavelength was approximately the same for the same exposure time.
  • the above-mentioned hologram photosensitive material 108 was set at a predetermined position, and the position of the first aspheric lens was adjusted so that the distance from the hologram material layer to the focusing point 109 of the first light beam was 100 mm, after which interference exposure was performed using the first light beam 111 and the second light beam 112.
  • the exposure amount and exposure time were determined using a profile of the diffraction efficiency expression of the hologram material for the exposure energy obtained in advance.
  • the exposed hologram photosensitive material was then exposed to a UV-LED surface light source through a diffusion film at an exposure dose of 1000 mJ/cm 2. In this manner, a reflection-type volume hologram lens 1 was produced.
  • the cholesteric liquid crystal layer G1 and the volume hologram lens 1 were arranged so as to face each other.
  • the surface on which the volume hologram lens 1 was formed was arranged so as to face the cholesteric liquid crystal layer G1.
  • the cholesteric liquid crystal layer G1 and the volume hologram lens 1 were arranged in this order, and the distance between the cholesteric liquid crystal layer G1 and the volume hologram lens 1 was 3 mm, to produce the optical unit 5.
  • An anti-reflection film was attached to the surface of the support opposite to the surface on which the cholesteric liquid crystal layer G1 was formed.
  • an anti-reflection film was attached to the surface of the base material opposite to the volume hologram lens 1.
  • Example 3 An optical unit 6 was produced in the same manner as in Comparative Example 3, except that the cholesteric liquid crystal layer G1 was changed to the cholesteric liquid crystal layer G2 produced in Example 1.
  • the circular polarizer 1 and the optical unit prepared above were placed facing each other and evaluated.
  • the circular polarizer 1 and the optical unit were placed in the following order: the linear polarizer of the circular polarizer 1, the ⁇ /4 plate 1, the reflective liquid crystal diffraction element of the optical unit, and the volume hologram.
  • the distance between the linear polarizer of the circular polarizer 1 and the volume hologram of the optical unit was 12 mm, and light was incident from the linear polarizer side to perform the evaluation.
  • the light intensity of the light emitted from the optical unit when light was incident on the circular polarizer was evaluated.
  • the in-plane position of each element was expressed as a radial distance, with the intersection of the normal direction from the center of the concentric circles of the liquid crystal diffraction element and each element (linear polarizer, ⁇ /4 plate, volume hologram, etc.) being taken as 0 mm, and the in-plane position of each element being expressed as a radial distance.
  • the angle of incidence was expressed as an angle relative to the perpendicular, with the direction perpendicular to the main surface of the circular polarizer 1 being taken as 0°.
  • a laser (wavelength: 532 nm) was incident at a position 3 mm from the circular polarizer 1 at an incident angle of -2.7°, and a photodetector was placed 12 mm away from the optical unit in the stacking direction to measure the light intensity of the light emitted from the optical unit.
  • the light intensity of the light emitted from the optical unit was measured when a laser (wavelength: 532 nm) was incident at a position 13 mm from the circular polarizer 1 at an incident angle of -7.4° and at a position 16 mm at an incident angle of -8°.
  • light emitted from a laser (wavelength: 532 nm) incident at a position 3 mm from the circular polarizer 1 at an incident angle of -2.7° is light that is emitted from the optical unit at a position 4 mm and an exit angle of 17°.
  • light that is incident from a laser (wavelength: 532 nm) at a position 13 mm into the circular polarizer 1 at an incident angle of -7.4° is emitted from the optical unit at a position 15 mm and an exit angle of 50°
  • light that is incident at a position 16 mm at an incident angle of -8° is emitted from the optical unit at a position 18 mm and an exit angle of 55°.
  • the virtual reality display device of Comparative Example 3 was produced in the same manner as in the production of the virtual reality display device of Comparative Example 1, except that optical unit 1 was changed to optical unit 5 produced in Comparative Example 3.
  • a liquid crystal diffraction element was disposed on the circular polarizing plate side, and was disposed so that the distance between the linear polarizer and the volume hologram of the optical unit was 12 mm.
  • the virtual reality display device of Example 3 was fabricated using the optical unit 6.
  • a green and black checkered pattern was displayed on the image display panel, and the brightness distribution of the display was visually evaluated.
  • the green display on the periphery was darker than in the center of the displayed image.
  • the brightness of the green display on the periphery was improved compared to Comparative Example 3, and the brightness distribution (viewing angle dependency) of the displayed image was improved.
  • Example 4 ⁇ Fabrication of Optical Unit> An optical unit 8 was produced in the same manner as in Example 3, except that the cholesteric liquid crystal layer G2 and the volume hologram lens 1 were arranged in the following order: volume hologram lens 1, cholesteric liquid crystal layer G2.
  • the circular polarizer 1 and the optical unit prepared above were placed facing each other and evaluated.
  • the circular polarizer 1 and the optical unit were arranged in the order of the linear polarizer of the circular polarizer 1, the ⁇ /4 plate 1, the volume hologram of the optical unit, and the reflective liquid crystal diffraction element.
  • the distance between the linear polarizer of the circular polarizer 1 and the reflective liquid crystal diffraction element of the optical unit was arranged to be 15 mm, and light was incident from the linear polarizer side to perform the evaluation.
  • the light intensity of the light emitted from the optical unit when light was incident on the circular polarizer was evaluated.
  • the in-plane position of each element was expressed as a radial distance, with the intersection of the normal direction from the center of the concentric circles of the liquid crystal diffraction element and each element (linear polarizer, ⁇ /4 plate, volume hologram, etc.) being taken as 0 mm, and the in-plane position of each element being expressed as a radial distance.
  • the angle of incidence was expressed as an angle relative to the perpendicular, with the direction perpendicular to the main surface of the circular polarizer 1 being taken as 0°.
  • a laser (wavelength: 532 nm) was incident at a position 3 mm from the circular polarizer 1 at an incident angle of -2.7°, and a photodetector was placed 11 mm away from the optical unit in the stacking direction to measure the light intensity of the light emitted from the optical unit.
  • the light intensity of the light emitted from the optical unit was measured when a laser (wavelength: 532 nm) was incident at a position 13 mm from the circular polarizer 1 at an incident angle of -7.4° and at a position 16 mm at an incident angle of -8°.
  • light emitted from a laser (wavelength: 532 nm) incident at a position 3 mm from the circular polarizer 1 at an incident angle of -2.7° is light that is emitted from the optical unit at a position 4 mm and an exit angle of 17°.
  • light that is incident from a laser (wavelength: 532 nm) at a position 13 mm into the circular polarizer 1 at an incident angle of -7.4° is emitted from the optical unit at a position 15 mm and an exit angle of 50°
  • light that is incident at a position 16 mm at an incident angle of -8° is emitted from the optical unit at a position 18 mm and an exit angle of 55°.
  • the virtual reality display device of Comparative Example 4 was produced in the same manner as in the production of the virtual reality display device of Comparative Example 1, except that optical unit 1 was changed to optical unit 7 produced in Comparative Example 4. Note that a volume hologram was disposed on the circular polarizing plate side, and the distance between the linear polarizer and the liquid crystal diffraction element of the optical unit was 15 mm.
  • a green and black checkered pattern was displayed on the image display panel, and the brightness distribution of the display was visually evaluated.
  • the green display on the periphery was darker than in the center of the displayed image.
  • the brightness of the green display on the periphery was improved compared to Comparative Example 4, and the brightness distribution (viewing angle dependency) of the displayed image was improved.
  • Example 5 ⁇ Formation of half mirror> A half mirror 2 was formed on the glass substrate by vapor deposition of aluminum so that the reflectance was 40%.
  • a circular polarizing plate 1 and an antireflection film were attached in this order to the surface opposite to the aluminum-deposited surface of the half mirror 2.
  • the circular polarizing plate 1 was laminated in this order to the half mirror 2, the ⁇ /4 plate 1, and the linear polarizer, and an antireflection film was attached to the surface of the linear polarizer to produce a half mirror laminate 1.
  • ⁇ Fabrication of Optical Unit> In the preparation of the optical unit 2 of Example 1, a half-mirror laminate 1 was used instead of the half mirror 1, and the reflective liquid crystal diffraction element G2 and the half-mirror laminate 1 (half mirror 2, ⁇ /4 plate 1, linear polarizer) were arranged in this order.
  • the optical unit 9 was prepared such that the distance between the reflective liquid crystal diffraction element and the aluminum deposition surface was 3 mm.
  • An anti-reflection film was attached to the surface opposite to the surface on which the cholesteric liquid crystal layer G2 was formed.
  • the circular polarizer 1 and the optical unit 9 prepared above were placed facing each other and evaluated.
  • the circular polarizer 1 and the optical unit were arranged in the following order: the linear polarizer of the circular polarizer 1, the ⁇ /4 plate 1, the reflective liquid crystal diffraction element 2 of the optical unit, the half mirror 2, the ⁇ /4 plate 1, and the linear polarizer.
  • the distance between the linear polarizer of the circular polarizer 1 and the half mirror of the optical unit was 12 mm, and light was incident from the linear polarizer side of the circular polarizer 1 to perform the evaluation.
  • the light intensity of the light emitted from the optical unit when light was incident on the circular polarizer was evaluated.
  • the in-plane position of each element was expressed as a radial distance, with the intersection of the normal direction from the center of the concentric circles of the liquid crystal diffraction element and each element (linear polarizer, ⁇ /4 plate, half mirror, etc.) being taken as 0 mm from the center of the concentric circles of the liquid crystal diffraction element.
  • the angle of incidence was expressed as an angle relative to the perpendicular, with the direction perpendicular to the main surface of the circular polarizer 1 being taken as 0°.
  • a laser (wavelength: 532 nm) was incident at a position 3 mm into the circular polarizer 1 at an incident angle of -2.7°, and a photodetector was placed 12 mm away from the optical unit in the stacking direction to measure the light intensity of the light emitted from the optical unit.
  • the light intensity of the light emitted from the optical unit was measured when a laser (wavelength: 532 nm) was incident at a position 13 mm into the circular polarizer 1 at an incident angle of -7.4° and at a position 16 mm at an incident angle of -8°.
  • light emitted from a laser (wavelength: 532 nm) incident at a position 3 mm into the circular polarizer 1 at an incident angle of -2.7° is light that is emitted from the optical unit at a position 4 mm and an exit angle of 15°.
  • light that is incident from a laser (wavelength: 532 nm) at a position 13 mm into the circular polarizer 1 with an incident angle of -7.4° is emitted from the optical unit at a position 15 mm with an exit angle of 45°
  • light that is incident at a position 16 mm with an incident angle of -8° is emitted from the optical unit at a position 18 mm with an exit angle of 50°.
  • the virtual reality display device of Example 5 was produced in the same manner as in the production of the virtual reality display device of Comparative Example 1, except that the optical unit 1 was changed to the optical unit 9 produced in Example 5.
  • a green and black checkered pattern was displayed on the image display panel, and the brightness distribution of the display was evaluated visually.
  • the green display in the peripheral area was darker than the center of the display image.
  • the brightness of the green display in the peripheral area was improved compared to Comparative Example 1, and the brightness distribution (viewing angle dependency) of the display image was improved.
  • a green and black checkered pattern was displayed on the image display panel of the manufactured virtual reality display device, and the ghost visibility was evaluated visually. A slight ghost image was visible in the virtual reality display device of Example 1, but the ghost image was reduced in the virtual reality display device of Example 5, and the ghost visibility was improved.
  • Example 6 ⁇ Preparation of Laminate 1 of Reflective Liquid Crystal Diffraction Element> A circular polarizer 1 and an antireflection film were attached in this order to the surface opposite to the surface on which the cholesteric liquid crystal layer was formed of the reflective liquid crystal diffraction element G2 produced in Example 2. The circular polarizer 1 was laminated in this order of the reflective liquid crystal diffraction element, the ⁇ /4 plate 1, and the linear polarizer, and an antireflection film was attached to the surface of the linear polarizer to produce a laminate 1 of the reflective liquid crystal diffraction element.
  • the reflective liquid crystal diffraction element laminate 1 was used instead of the reflective liquid crystal diffraction element G2, and the half mirror, the reflective liquid crystal diffraction element laminate 1 (the reflective liquid crystal diffraction element G2, the circular polarizer 1, and the anti-reflection film) were arranged in this order.
  • the optical unit 10 was prepared such that the distance between the reflective liquid crystal diffraction element and the aluminum vapor deposition surface was 2 mm.
  • the circular polarizer 1 and the optical unit 10 prepared above were placed facing each other and evaluated.
  • the circular polarizer 1 and the optical unit were arranged in the following order: the linear polarizer of the circular polarizer 1, the ⁇ /4 plate 1, the half mirror of the optical unit, the reflective liquid crystal diffraction element, the ⁇ /4 plate 1, and the linear polarizer.
  • the distance between the linear polarizer of the circular polarizer 1 and the reflective liquid crystal diffraction element of the optical unit was 15 mm, and light was incident from the linear polarizer side to perform the evaluation.
  • the light intensity of the light emitted from the optical unit when light was incident on the circular polarizer was evaluated.
  • the in-plane position of each element was expressed as a radial distance, with the intersection of the normal direction from the center of the concentric circles of the liquid crystal diffraction element and each element (linear polarizer, ⁇ /4 plate, half mirror, etc.) being taken as 0 mm from the center of the concentric circles of the liquid crystal diffraction element.
  • the angle of incidence was expressed as an angle relative to the perpendicular, with the direction perpendicular to the main surface of the circular polarizer 1 being taken as 0°.
  • a laser (wavelength: 532 nm) was incident at a position 3 mm into the circular polarizer 1 at an incidence angle of -2.7°, a photodetector was placed 11 mm away from the optical unit in the stacking direction, and the light intensity of the light emitted from the optical unit was measured.
  • the light intensity of the light emitted from the optical unit was measured when a laser (wavelength: 532 nm) was incident at a position 13 mm into the circular polarizer 1 at an incidence angle of -7.4°, and at a position 16 mm at an incidence angle of -8°.
  • light incident on the circular polarizer 1 at a position 3 mm into the laser (wavelength: 532 nm) at an incidence angle of -2.7° is light that is emitted from the optical unit at a position 4 mm and an emission angle of 15°.
  • light that is incident from a laser (wavelength: 532 nm) at a position 13 mm into the circular polarizer 1 with an incident angle of -7.4° is emitted from the optical unit at a position 15 mm with an exit angle of 45°
  • light that is incident at a position 16 mm with an incident angle of -8° is emitted from the optical unit at a position 18 mm with an exit angle of 50°.
  • the virtual reality display device of Example 6 was produced in the same manner as in the production of the virtual reality display device of Comparative Example 2, except that the optical unit 3 was changed to the optical unit 10 produced in Example 6.
  • a green and black checkered pattern was displayed on the image display panel, and the brightness distribution of the display was evaluated visually.
  • the green display in the peripheral area was darker than the center of the display image.
  • the brightness of the green display in the peripheral area was improved compared to Comparative Example 2, and the brightness distribution (viewing angle dependency) of the display image was improved.
  • a green and black checkered pattern was displayed on the image display panel of the manufactured virtual reality display device, and the ghost visibility was evaluated visually. A slight ghost image was visible in the virtual reality display device of Example 2, but the ghost image was reduced in the virtual reality display device of Example 6, and the ghost visibility was improved.
  • Example 7 ⁇ Fabrication of Optical Unit> An optical unit 11 was produced in the same manner as in the production of the optical unit 6 of Example 3, except that the ⁇ /4 plate 1, the linear polarizer, and the antireflection film were laminated in this order on the surface of the volume hologram.
  • the circular polarizer 1 and the optical unit prepared above were placed facing each other and evaluated.
  • the circular polarizer 1 and the optical unit were arranged in the following order: the linear polarizer of the circular polarizer 1, the ⁇ /4 plate 1, the reflective liquid crystal diffraction element of the optical unit, the volume hologram, the ⁇ /4 plate 1, and the linear polarizer.
  • the distance between the linear polarizer of the circular polarizer 1 and the volume hologram of the optical unit was 12 mm, and light was incident from the linear polarizer side of the circular polarizer 1 to perform the evaluation.
  • the light intensity of the light emitted from the optical unit when light was incident on the circular polarizer was evaluated.
  • the in-plane position of each element was expressed as a radial distance, with the intersection of the normal direction from the center of the concentric circles of the liquid crystal diffraction element and each element (linear polarizer, ⁇ /4 plate, half mirror, etc.) being taken as 0 mm from the center of the concentric circles of the liquid crystal diffraction element.
  • the angle of incidence was expressed as an angle relative to the perpendicular, with the direction perpendicular to the main surface of the circular polarizer 1 being taken as 0°.
  • a laser (wavelength: 532 nm) was incident at a position 3 mm from the circular polarizer 1 at an incident angle of -2.7°, and a photodetector was placed 12 mm away from the optical unit in the stacking direction to measure the light intensity of the light emitted from the optical unit.
  • the light intensity of the light emitted from the optical unit was measured when a laser (wavelength: 532 nm) was incident at a position 13 mm from the circular polarizer 1 at an incident angle of -7.4° and at a position 16 mm at an incident angle of -8°.
  • light emitted from a laser (wavelength: 532 nm) incident at a position 3 mm from the circular polarizer 1 at an incident angle of -2.7° is light that is emitted from the optical unit at a position 4 mm and an exit angle of 17°.
  • light that is incident from a laser (wavelength: 532 nm) at a position 13 mm into the circular polarizer 1 at an incident angle of -7.4° is emitted from the optical unit at a position 15 mm and an exit angle of 50°
  • light that is incident at a position 16 mm at an incident angle of -8° is emitted from the optical unit at a position 18 mm and an exit angle of 55°.
  • the virtual reality display device of Example 7 was produced in the same manner as in the production of the virtual reality display device of Comparative Example 1, except that the optical unit 1 was changed to the optical unit 11 produced in Example 7.
  • a reflective liquid crystal diffraction element was disposed on the circular polarizing plate side, and was disposed so that the distance between the linear polarizer and the volume hologram of the optical unit was 12 mm.
  • a green and black checkered pattern was displayed on the image display panel, and the brightness distribution of the display was evaluated visually.
  • the green display in the peripheral area was darker than the center of the display image.
  • the brightness of the green display in the peripheral area was improved compared to Comparative Example 3, and the brightness distribution (viewing angle dependency) of the display image was improved.
  • a green and black checkered pattern was displayed on the image display panel of the manufactured virtual reality display device, and the ghost visibility was evaluated visually. A slight ghost image was visible in the virtual reality display device of Example 3, but the ghost image was reduced in the virtual reality display device of Example 7, and the ghost visibility was improved.
  • Optical unit 12 was prepared in the same manner as in the preparation of optical unit 8 of Example 4, except that a ⁇ /4 plate 1, a linear polarizer, and an anti-reflection film were attached in that order to the surface of the support opposite the cholesteric liquid crystal layer G2 of the reflective liquid crystal diffraction element.
  • the circular polarizer 1 and the optical unit prepared above were placed facing each other and evaluated.
  • the circular polarizer 1 and the optical unit were arranged in the following order: the linear polarizer of the circular polarizer 1, the ⁇ /4 plate 1, the volume hologram of the optical unit, the reflective liquid crystal diffraction element, the ⁇ /4 plate 1, and the linear polarizer.
  • the distance between the linear polarizer of the circular polarizer 1 and the reflective liquid crystal diffraction element of the optical unit was arranged to be 15 mm, and light was incident from the linear polarizer side of the circular polarizer 1 to perform the evaluation.
  • the light intensity of the light emitted from the optical unit when light was incident on the circular polarizer was evaluated.
  • the in-plane position of each element was expressed as a radial distance, with the intersection of the normal direction from the center of the concentric circles of the liquid crystal diffraction element and each element (linear polarizer, ⁇ /4 plate, half mirror, etc.) being taken as 0 mm from the center of the concentric circles of the liquid crystal diffraction element.
  • the angle of incidence was expressed as an angle relative to the perpendicular, with the direction perpendicular to the main surface of the circular polarizer 1 being taken as 0°.
  • a laser (wavelength: 532 nm) was incident at a position 3 mm from the circular polarizer 1 at an incident angle of -2.7°, and a photodetector was placed 11 mm away from the optical unit in the stacking direction to measure the light intensity of the light emitted from the optical unit.
  • the light intensity of the light emitted from the optical unit was measured when a laser (wavelength: 532 nm) was incident at a position 13 mm from the circular polarizer 1 at an incident angle of -7.4° and at a position 16 mm at an incident angle of -8°.
  • light emitted from a laser (wavelength: 532 nm) incident at a position 3 mm from the circular polarizer 1 at an incident angle of -2.7° is light that is emitted from the optical unit at a position 4 mm and an exit angle of 17°.
  • light that is incident from a laser (wavelength: 532 nm) at a position 13 mm into the circular polarizer 1 at an incident angle of -7.4° is emitted from the optical unit at a position 15 mm and an exit angle of 50°
  • light that is incident at a position 16 mm at an incident angle of -8° is emitted from the optical unit at a position 18 mm and an exit angle of 55°.
  • the virtual reality display device of Example 8 was produced in the same manner as in the production of the virtual reality display device of Comparative Example 1, except that the optical unit 1 was changed to the optical unit 12 produced in Example 8. Note that a volume hologram was disposed on the circular polarizing plate side, and the distance between the linear polarizer of the circular polarizing plate 1 and the reflective liquid crystal diffraction element of the optical unit was arranged to be 15 mm.
  • a green and black checkered pattern was displayed on the image display panel, and the brightness distribution of the display was evaluated visually.
  • the green display in the peripheral area was darker than the center of the display image.
  • the brightness of the green display in the peripheral area was improved compared to Comparative Example 4, and the brightness distribution (viewing angle dependency) of the display image was improved.
  • a green and black checkered pattern was displayed on the image display panel of the manufactured virtual reality display device, and the ghost visibility was evaluated visually. A slight ghost image was visible in the virtual reality display device of Example 4, but the ghost image was reduced in the virtual reality display device of Example 8, and the ghost visibility was improved.
  • Example 9 ⁇ Fabrication of a transmissive liquid crystal diffraction element> (Exposure of Alignment Film)
  • an alignment film PA-1 having a radial alignment pattern was formed in the same manner as in the exposure of the alignment film using the exposure apparatus shown in Figure 20, except that one period of the in-plane alignment pattern was changed.
  • composition A-1 As a liquid crystal composition for forming a first optically anisotropic layer, the following composition A-1 was prepared.
  • the optically anisotropic layer was formed by applying composition A-1 in multiple layers onto the alignment film PA-1.
  • Multi-layer application refers to first applying composition A-1 as the first layer onto the alignment film, heating and curing with UV light to create a liquid crystal fixing layer, and then applying layers from the second layer onwards to the liquid crystal fixing layer, and similarly heating and curing with UV light, and repeating this process.
  • the orientation direction of the alignment film is reflected from the bottom surface to the top surface of the optically anisotropic layer, even when the total thickness of the optically anisotropic layer is large.
  • the above composition A-1 was applied onto the alignment film PA-1, the coating film was heated to 80°C on a hot plate, and then the coating film was irradiated with ultraviolet light having a wavelength of 365 nm at an exposure dose of 300 mJ/ cm2 using a high-pressure mercury lamp under a nitrogen atmosphere, thereby fixing the alignment of the liquid crystal compound.
  • the second and subsequent layers were applied over this liquid crystal fixation layer, heated under the same conditions as above, and then cured with ultraviolet light to create a liquid crystal fixation layer. In this way, the layers were repeatedly applied until the desired total thickness was reached, forming an optically anisotropic layer and producing a liquid crystal diffraction element.
  • the complex refractive index ⁇ n of the cured layer of liquid crystal composition A-1 was determined by measuring the retardation value and film thickness of the liquid crystal fixed layer (cured layer) obtained by applying liquid crystal composition A-1 onto a support with an alignment film for retardation measurement prepared separately, aligning the director of the liquid crystal compound so that it was horizontal to the substrate, and then irradiating with ultraviolet light to fix it.
  • ⁇ n can be calculated by dividing the retardation value by the film thickness.
  • the retardation value was measured at the desired wavelength using an Axoscan manufactured by Axometrix, and the film thickness was measured using a SEM.
  • the first optically anisotropic layer thus produced was confirmed by a polarizing microscope to have a liquid crystal ⁇ n 550 ⁇ thickness (Re(550)) of 160 nm and a periodic alignment surface.
  • the liquid crystal compound had a twist angle of -80° in the thickness direction.
  • the optical axis of the liquid crystal compound rotated 180° in one period, with one period at a distance of 3 mm from the center being 17.8 ⁇ m, one period at a distance of 13 mm from the center being 4.1 ⁇ m, and one period at a distance of 16 mm from the center being 3.4 ⁇ m, resulting in a liquid crystal alignment pattern in which the period became shorter toward the outside.
  • composition A-2 As a liquid crystal composition for forming a second optically anisotropic layer, the following composition A-2 was prepared.
  • Composition A-2 As a liquid crystal composition for forming a second optically anisotropic layer, the following composition A-2 was prepared.
  • Liquid crystal compound L-1 10.00 parts by mass Liquid crystal compound L-2 90.00 parts by mass Polymerization initiator (Irgacure OXE01, manufactured by BASF) 1.00 part by mass Surfactant F1 0.30 part by mass Methyl ethyl ketone 550.00 parts by mass Cyclopentanone 550.00 parts by mass ------------------------------------------------------------------
  • the second optically anisotropic layer was formed in the same manner as the first optically anisotropic layer, except that composition A-2 was used and the film thickness of the optically anisotropic layer was adjusted.
  • the second optically anisotropic layer thus prepared was confirmed by a polarizing microscope to have a liquid crystal ⁇ n 550 ⁇ thickness (Re(550)) of 330 nm and a periodic alignment surface.
  • the twist angle of the liquid crystal compound in the thickness direction in this optically anisotropic layer was 0°.
  • the optical axis of the liquid crystal compound rotated 180° in one period, with one period at a distance of 3 mm from the center being 17.8 ⁇ m, one period at a distance of 13 mm from the center being 4.1 ⁇ m, and one period at a distance of 16 mm from the center being 3.4 ⁇ m, and the period becoming shorter toward the outside.
  • composition A-3 was prepared as a liquid crystal composition for forming the third optically anisotropic layer.
  • Composition A-3 Liquid crystal compound L-1 10.00 parts by mass Liquid crystal compound L-2 90.00 parts by mass Chiral agent C4 0.62 parts by mass Polymerization initiator (manufactured by BASF, Irgacure OXE01) 1.00 parts by weight
  • Surfactant F1 0.30 parts by weight Methyl ethyl ketone 550.00 parts by weight Cyclopentanone 550.00 parts by weight
  • a third optically anisotropic layer was formed in the same manner as the first optically anisotropic layer, except that composition A-3 was used and the thickness of the optically anisotropic layer was adjusted, and the first to third optically anisotropic layers were laminated to obtain a transmissive liquid crystal diffraction element T1.
  • the third optically anisotropic layer thus produced was confirmed by a polarizing microscope to have a liquid crystal ⁇ n 550 ⁇ thickness (Re(550)) of 160 nm and a periodic alignment surface.
  • the twist angle of the liquid crystal compound in the thickness direction in this optically anisotropic layer was 80°.
  • the optical axis of the liquid crystal compound rotates 180° in one period, with one period at a distance of 3 mm from the center being 17.8 ⁇ m, one period at a distance of 13 mm from the center being 4.1 ⁇ m, and one period at a distance of 16 mm from the center being 3.4 ⁇ m, and the period becoming shorter toward the outside.
  • the linear polarizer and the ⁇ /4 plate 1 were laminated together with their slow axes rotated 90° to produce a circular polarizing plate, and then a transmissive liquid crystal diffraction element T1 was laminated to obtain a laminated optical body CG1.
  • the transmissive liquid crystal diffraction element T1 functioned as a diverging lens for the incident light from the ⁇ /4 plate.
  • Example 9 the laminated optical body CG1 prepared above and the optical unit 4 prepared in Example 2 were arranged facing each other and evaluated.
  • the laminated optical body CG1 and the optical unit were arranged in the order of the laminated optical body CG1 (linear polarizer, ⁇ /4 plate 1, transmissive liquid crystal diffraction element T1), and the optical unit (half mirror, reflective liquid crystal diffraction element G2).
  • the laminated optical body CG1 and the reflective liquid crystal diffraction element of the optical unit were arranged so that the distance between the linear polarizer of the laminated optical body CG1 and the reflective liquid crystal diffraction element of the optical unit was 15 mm, and light was incident from the side of the linear polarizer to perform the evaluation.
  • the light intensity of the light emitted from the optical unit when light was incident on the circular polarizer was evaluated.
  • the in-plane position of each element was expressed as a radial distance, with the intersection of the normal direction from the center of the concentric circles of the liquid crystal diffraction element and each element (linear polarizer, ⁇ /4 plate, half mirror, etc.) being taken as 0 mm from the center of the concentric circles of the liquid crystal diffraction element.
  • the angle of incidence was expressed as an angle relative to the perpendicular, with the direction perpendicular to the main surface of the circular polarizer 1 being taken as 0°.
  • a laser (wavelength: 532 nm) was incident at a position 3 mm from the circular polarizer 1 at an incident angle of -2.7°, and a photodetector was placed 11 mm away from the optical unit in the stacking direction to measure the light intensity of the light emitted from the optical unit.
  • the light intensity of the light emitted from the optical unit was measured when a laser (wavelength: 532 nm) was incident at a position 13 mm from the circular polarizer 1 at an incident angle of -7.4° and at a position 16 mm at an incident angle of -8°.
  • light emitted from a laser (wavelength: 532 nm) incident at a position 3 mm from the circular polarizer 1 at an incident angle of -2.7° is light that is emitted from the optical unit at a position 4 mm and an exit angle of 15°.
  • light that is incident from a laser (wavelength: 532 nm) at a position 13 mm into the circular polarizer 1 with an incident angle of -7.4° is emitted from the optical unit at a position 15 mm with an exit angle of 45°
  • light that is incident at a position 16 mm with an incident angle of -8° is emitted from the optical unit at a position 18 mm with an exit angle of 50°.
  • the laminated optical body CG1 prepared above was bonded to the display of "Huawei VR Glass” (the display, linear polarizer, ⁇ /4 plate 1, and transmissive liquid crystal diffraction element T1 were laminated in this order).
  • the optical unit 4 prepared in Example 2 was placed on the front (a half mirror was placed on the transmissive liquid crystal diffraction element T1 side), to prepare the virtual reality display device of Example 9.
  • the distance between the linear polarizer of the laminated optical body CG1 and the reflective liquid crystal diffraction element of the optical unit 4 was arranged to be 15 mm.
  • the virtual reality display device thus fabricated, a green and black checkered pattern was displayed on the image display panel, and the brightness distribution of the display was visually evaluated.
  • the peripheral green display was darker than the center of the displayed image.
  • the brightness of the peripheral green display was improved compared to Comparative Example 1, and the brightness distribution of the displayed image (viewing angle dependency) was improved.
  • the brightness of the peripheral green display was further improved compared to the virtual reality display device of Example 2, and the brightness distribution of the displayed image (viewing angle dependency) was further improved.
  • Example 10 An optical unit 13 was prepared by laminating the transmission type liquid crystal diffraction element T1 prepared in Example 9 on the reflection type liquid crystal diffraction element of the optical unit 4 prepared in Example 2.
  • the circular polarizer 1 and the optical unit prepared above were placed facing each other and evaluated.
  • the circular polarizer 1 and the optical unit were arranged in the order of the circular polarizer 1 (linear polarizer, ⁇ /4 plate 1), the optical unit (half mirror, reflective liquid crystal diffraction element, transmissive liquid crystal diffraction element T1).
  • the distance between the linear polarizer of the circular polarizer 1 and the reflective liquid crystal diffraction element of the optical unit was arranged to be 15 mm, and light was incident from the linear polarizer side to perform the evaluation.
  • the light intensity of the light emitted from the optical unit when light was incident on the circular polarizer was evaluated.
  • the in-plane position of each element was expressed as a radial distance, with the intersection of the normal direction from the center of the concentric circles of the liquid crystal diffraction element and each element (linear polarizer, ⁇ /4 plate, half mirror, etc.) being taken as 0 mm from the center of the concentric circles of the liquid crystal diffraction element.
  • the angle of incidence was expressed as an angle relative to the perpendicular, with the direction perpendicular to the main surface of the circular polarizer 1 being taken as 0°.
  • a laser (wavelength: 532 nm) was incident at a position 3 mm from the circular polarizer 1 at an incident angle of -2.7°, and a photodetector was placed 11 mm away from the optical unit in the stacking direction to measure the light intensity of the light emitted from the optical unit.
  • the exit light angle of the light emitted from the optical unit was measured when a laser (wavelength: 532 nm) was incident at a position 13 mm from the circular polarizer 1 at an incident angle of -7.4° and at a position 16 mm at an incident angle of -8°.
  • a virtual reality display device of Example 10 was produced in the same manner as in the production of the virtual reality display device of Example 2, except that the optical unit 4 was changed to the optical unit 13.
  • a half mirror was arranged on the circular polarizing plate side, and the distance between the linear polarizer and the liquid crystal diffraction element of the optical unit was arranged to be 15 mm.
  • a green and black checkered pattern was displayed on the image display panel, and the brightness distribution of the display was evaluated visually.
  • the viewing angle at which the virtual image was visible was expanded compared to Example 2.
  • Example 11 An optical unit 14 was prepared by laminating a ⁇ /4 plate 1 and a linear polarizer on the surface of the transmission type liquid crystal diffraction element T1 of the optical unit 13 prepared in Example 10.
  • the circular polarizer 1 and the optical unit prepared above were placed facing each other and evaluated.
  • the circular polarizer 1 and the optical unit were arranged in the order of the circular polarizer 1 (linear polarizer, ⁇ /4 plate 1), the optical unit (half mirror, reflective liquid crystal diffraction element, transmissive liquid crystal diffraction element T1).
  • the distance between the linear polarizer of the circular polarizer 1 and the reflective liquid crystal diffraction element of the optical unit was arranged to be 15 mm, and light was incident from the linear polarizer side to perform the evaluation.
  • a laser (wavelength: 532 nm) was incident at a position 3 mm from the circular polarizer 1 at an incidence angle of -2.7°, and a photodetector was placed 11 mm away from the optical unit in the stacking direction to measure the light intensity of the light emitted from the optical unit.
  • the light intensity of the light emitted from the optical unit was measured when a laser (wavelength: 532 nm) was incident at a position 13 mm from the circular polarizer 1 at an incidence angle of -7.4° and at a position 16 mm at an incidence angle of -8°.
  • the virtual reality display device of Example 11 was produced in the same manner as in the production of the virtual reality display device of Example 2, except that the optical unit 4 was changed to the optical unit 14.
  • a half mirror was disposed on the circular polarizing plate side, and the distance between the linear polarizer and the reflective liquid crystal diffraction element of the optical unit was arranged to be 15 mm.
  • the virtual reality display device thus fabricated, a green and black checkered pattern was displayed on the image display panel, and the brightness distribution of the display was evaluated visually. Compared to the virtual reality display device of Example 10, the virtual reality display device of Example 11 had reduced ghost images, and ghost visibility was improved.
  • composition B-1 was prepared in the same manner as composition G-1, except that the amount of chiral agent C1 added in composition G-1 was changed to 6.3 parts by mass, and the amount of methyl ethyl ketone was changed.
  • a cholesteric liquid crystal layer B1 was formed in the same manner as in the formation of the cholesteric liquid crystal layer G1, except that this composition B-1 was used.
  • the length of one helical pitch (helical pitch P) in the cholesteric liquid crystal layer was 277 nm at a distance of 4 mm from the center, 277 nm at a distance of 15 mm from the center, and 277 nm at a distance of 18 mm from the center.
  • composition R-1 was prepared in the same manner as composition G-1, except that the amount of chiral agent C1 added in composition G-1 was changed to 4.4 parts by mass, and the amounts of methyl ethyl ketone and cyclopentanone were changed.
  • a cholesteric liquid crystal layer R1 was formed in the same manner as in the formation of the cholesteric liquid crystal layer G1, except that the composition R-1 was used.
  • the length of one helical pitch (helical pitch P) in the cholesteric liquid crystal layer was 390 nm at a distance of 4 mm from the center, 390 nm at a distance of 15 mm from the center, and 390 nm at a distance of 18 mm from the center.
  • the prepared cholesteric liquid crystal layer R1 was laminated on the surface of the glass substrate opposite to the antireflection layer on which the antireflection layer was formed.
  • the cholesteric liquid crystal layer G1 and the cholesteric liquid crystal layer B1 were laminated in this order on the cholesteric liquid crystal layer R1 to prepare a reflective liquid crystal diffraction element which is a laminate of cholesteric liquid crystal layers.
  • the reflective liquid crystal diffraction element produced above was arranged to face the half mirror 1.
  • the aluminum vapor deposition surface of the half mirror 1 was arranged on the side facing the reflective liquid crystal diffraction element.
  • the half mirror 1 and the reflective liquid crystal diffraction element were arranged in this order, and the distance between the reflective liquid crystal diffraction element and the aluminum vapor deposition surface was set to 2 mm, to produce the optical unit 15.
  • Example 12 ⁇ Fabrication of Reflective Liquid Crystal Diffraction Element> (Formation and exposure of photo-alignment film for cholesteric liquid crystal layer B2) In the same manner as in the formation of the photo-alignment film for the cholesteric liquid crystal layer G2, a photo-alignment film was formed on the surface of the glass support. The formed photo-alignment film was exposed using the exposure apparatus shown in Figure 20 in the same manner as described above, except that the exposure was performed so as to change one period of the alignment pattern within the plane, thereby forming an alignment film P-B1 having a radial alignment pattern.
  • composition B-2 was prepared in the same manner as composition G-2, except that the amount of chiral agent C1 added in composition G-2 was changed to 7.0 parts by mass, and the amount of methyl ethyl ketone was changed to 202.99 parts by mass.
  • a cholesteric liquid crystal layer B2 was formed in the same manner as in the formation of the cholesteric liquid crystal layer G2, except that this composition B-2 was used.
  • the length of one helical pitch (helical pitch P) in the cholesteric liquid crystal layer was 277 nm at a distance of 4 mm from the center, 287 nm at a distance of 15 mm from the center, and 289 nm at a distance of 18 mm from the center.
  • composition R-2 was prepared in the same manner as composition G-2, except that the amount of the chiral agent added in composition G-2 was changed to 5.3 parts by mass, the amount of methyl ethyl ketone was changed to 119.90 parts by mass, and the amount of cyclopentanone was changed to 79.93 parts by mass.
  • a cholesteric liquid crystal layer R2 was formed in the same manner as in the formation of the cholesteric liquid crystal layer G2, except that the composition R-2 was used.
  • the length of one helical pitch (helical pitch P) in the cholesteric liquid crystal layer was 390 nm at a distance of 4 mm from the center, 403 nm at a distance of 15 mm from the center, and 406 nm at a distance of 18 mm from the center.
  • the prepared cholesteric liquid crystal layer R2 was laminated on the surface of the glass substrate opposite to the antireflection layer on which the antireflection layer was formed. In the same manner, the cholesteric liquid crystal layer G2 and the cholesteric liquid crystal layer B2 were laminated in this order on the cholesteric liquid crystal layer R2 to prepare a reflective liquid crystal diffraction element which is a laminate of cholesteric liquid crystal layers.
  • the reflective liquid crystal diffraction element produced above was arranged to face the half mirror 1.
  • the aluminum vapor deposition surface of the half mirror 1 was arranged on the side facing the reflective liquid crystal diffraction element.
  • the optical unit 16 was produced by arranging the half mirror 1 and the reflective liquid crystal diffraction element in this order, and setting the distance between the reflective liquid crystal diffraction element and the aluminum vapor deposition surface to 2 mm.
  • the circular polarizer 1 and the optical unit prepared above were placed facing each other and evaluated.
  • the circular polarizer 1 and the optical unit were placed in the order of the circular polarizer 1 (linear polarizer, ⁇ /4 plate 1) and the optical unit (half mirror, reflective liquid crystal diffraction element).
  • the distance between the linear polarizer of the circular polarizer 1 and the reflective liquid crystal diffraction element of the optical unit was 15 mm, and light was incident from the linear polarizer side to perform the evaluation.
  • the light intensity of the light emitted from the optical unit when light was incident on the circular polarizer was evaluated.
  • the in-plane position of each element was expressed as a radial distance, with the intersection of the normal direction from the center of the concentric circles of the liquid crystal diffraction element and each element (linear polarizer, ⁇ /4 plate, half mirror, etc.) being taken as 0 mm from the center of the concentric circles of the liquid crystal diffraction element.
  • the angle of incidence was expressed as an angle relative to the perpendicular, with the direction perpendicular to the main surface of the circular polarizer 1 being taken as 0°.
  • a laser (wavelength: 450 nm, 532 nm, 650 nm) was incident at a position 3 mm from the circular polarizer 1 at an incident angle of -2.7°, and a photodetector was placed 11 mm away from the optical unit in the stacking direction to measure the light intensity of the light emitted from the optical unit.
  • the light intensity of the light emitted from the optical unit was measured when a laser (wavelength: 450 nm, 532 nm, 650 nm) was incident at a position 13 mm from the circular polarizer 1 at an incident angle of -7.4° and at a position 16 mm at an incident angle of -8°.
  • the light emitted from the optical unit 4 mm from the position 3 mm from the circular polarizer 1 when a laser (wavelength: 450 nm, 532 nm, 650 nm) was incident at an incident angle of -2.7° is light that is emitted from the optical unit at a position 4 mm and an exit angle of 15°.
  • light incident from a laser (wavelengths: 450 nm, 532 nm, 650 nm) at an incident angle of -7.4° at a position 13 mm into the circular polarizer 1 is emitted from the optical unit at a position 15 mm and an emission angle of 45°, and light incident at a position 16 mm with an incident angle of -8° is emitted from the optical unit at a position 18 mm and an emission angle of 50°.
  • the amount of light (wavelength: average value of 450 nm, 532 nm, 650 nm) emitted from optical unit 16 produced in Example 12 was approximately the same as that of optical unit 15 produced in Comparative Example 12.
  • the amount of light (wavelength: average value of 450 nm, 532 nm, 650 nm) emitted from optical unit 16 produced in Example 12 was increased as compared to optical unit 15 in Comparative Example 12.
  • the virtual reality display device of Comparative Example 12 was produced in the same manner as in the production of the virtual reality display device of Comparative Example 2, except that the optical unit 3 was changed to the optical unit 15 produced in Comparative Example 12.
  • a half mirror was disposed on the circular polarizing plate side, and the distance between the linear polarizer and the liquid crystal diffraction element of the optical unit was arranged to be 15 mm.
  • the white display in the periphery was darker than the center of the display image.
  • the brightness of the white display in the periphery was improved compared to Comparative Example 12, and the brightness distribution (viewing angle dependency) of the display image was improved. From the above results, the effects of the present invention are clear.
  • Partially reflective element (reflective liquid crystal diffraction element) 20 Support 24 Alignment film 26, 34 Cholesteric liquid crystal layer 30 Liquid crystal compound 30A Optical axis 100 Exposure device 101a, 101b, 101c Laser light source 102a, 102b, 102c Dichroic mirror 103 Polarizing beam splitter 104 Plane mirror 105 Beam expander 106 First aspheric lens 107 Second aspheric lens 108 Hologram photosensitive material 109 Focus of first aspheric lens 110 Hologram lens 111 First light beam 112 Second light beam 113 Diffracted light 200, 200a to 200f Image display system 202 Image display element 204 Circular polarizer 206 Linear polarizer 208 ⁇ /4 retardation plate 210, 210a to 210f Optical unit 211 First partially reflecting element 213 Second partially reflecting element 212 Reflective liquid crystal diffraction element 214 Half mirror 215 Reflective volume hologram 216 Circular polarizing plate 218 First transmissive polarizing d

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