WO2024164243A1 - 储能装置及用电设备 - Google Patents
储能装置及用电设备 Download PDFInfo
- Publication number
- WO2024164243A1 WO2024164243A1 PCT/CN2023/075254 CN2023075254W WO2024164243A1 WO 2024164243 A1 WO2024164243 A1 WO 2024164243A1 CN 2023075254 W CN2023075254 W CN 2023075254W WO 2024164243 A1 WO2024164243 A1 WO 2024164243A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- energy storage
- storage device
- explosion
- pressure value
- pressing block
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/147—Lids or covers
- H01M50/148—Lids or covers characterised by their shape
- H01M50/15—Lids or covers characterised by their shape for prismatic or rectangular cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/30—Arrangements for facilitating escape of gases
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/533—Electrode connections inside a battery casing characterised by the shape of the leads or tabs
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/543—Terminals
- H01M50/552—Terminals characterised by their shape
- H01M50/553—Terminals adapted for prismatic, pouch or rectangular cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/572—Means for preventing undesired use or discharge
- H01M50/574—Devices or arrangements for the interruption of current
- H01M50/578—Devices or arrangements for the interruption of current in response to pressure
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the present application relates to the field of energy storage technology, and in particular to an energy storage device and electrical equipment.
- Energy storage devices such as batteries usually have explosion-proof valves or explosion-proof discs on the end cap assembly, so that when the internal gas pressure of the energy storage device increases, the explosion-proof valve or explosion-proof disc can be exploded in time to release the pressure.
- the explosion-proof valve or explosion-proof disc is exploded, it is easy to cause electrolyte leakage and pollution.
- an embodiment of the present application provides an energy storage device that prevents electrolyte leakage.
- the first aspect of the present application provides an energy storage device, which includes: an electrode assembly, a transfer sheet and an end cap assembly; the transfer sheet is electrically connected to the electrode assembly; the end cap assembly is arranged on a side of the transfer sheet away from the electrode assembly, and the end cap assembly includes:
- a pole assembly comprising a metal pressing block, the metal pressing block being electrically connected to the adapter, and the metal pressing block having a preset surface;
- a top cover is arranged at intervals on the preset surface of the metal pressing block, the top cover has through holes and explosion-proof holes arranged at intervals, and the orthographic projection of the through holes on the preset surface falls within the range of the preset surface;
- a stressor closing the through hole and connected to the top cover, wherein when the energy storage device reaches a first pressure value, the stressor abuts against the metal pressure block to short-circuit the energy storage device;
- An explosion-proof assembly comprising an explosion-proof disk, the explosion-proof disk is used to close the explosion-proof hole and is connected to the top cover, and when the energy storage device reaches a second pressure value, the explosion-proof disk explodes;
- the ratio of the first pressure value P1 to the second pressure value P2 is in the range of 0.4 ⁇ P1/P2 ⁇ 0.87; and the thickness of the stressing member is in the range of 0.1 mm to 6.2 mm.
- the difference between the second pressure value P2 and the first pressure value P1 is in the range of: 0.1Mpa ⁇ P2-P1 ⁇ 0.3Mpa.
- the range of the first pressure value P1 is 0.35 MPa ⁇ P1 ⁇ 0.65 MPa; the range of the second pressure value P2 is: 0.75 MPa ⁇ P2 ⁇ 1.05 MPa.
- the pole assembly includes a positive pole assembly and a negative pole assembly
- the stressor includes a positive stressor and a negative stressor
- the first sub-pressure value P11 when the energy storage device reaches a first sub-pressure value P11, the positive stressor is deformed and abuts against the metal pressure block of the positive pole assembly; when the energy storage device reaches a second sub-pressure value P12, the negative stressor is deformed and abuts against the metal pressure block of the negative pole assembly; wherein, P12 ⁇ P11; wherein, the first pressure value P1 includes the first sub-pressure value P11 and the second sub-pressure value P12.
- the minimum thickness d1 of the deformation portion is in the range of 0.3 mm ⁇ d1 ⁇ 1.0 mm.
- the minimum thickness d2 of the explosion-proof disk is in the range of 0.05 mm ⁇ d2 ⁇ 0.15 mm.
- the thickness d3 of the supporting portion is in the range of 1.6 mm ⁇ d3 ⁇ 3.4 mm; the thickness d4 of the connecting portion is in the range of 0.45 mm ⁇ d4 ⁇ 1.5 mm.
- the electrode assembly includes an electrically connected electrode plate and an electrode tab, wherein the electrode tab has a welding portion welded to the adapter plate, and the orthographic projection of the welding portion on the preset surface falls within the range of the orthographic projection of the stressor on the preset surface.
- the stress piece of the energy storage device will not flip over too early, short-circuit the energy storage device and affect the normal use of the energy storage device; at the same time, the flipping pressure of the stress piece and the bursting pressure of the explosion-proof piece are separated by a certain difference, so that the explosion-proof piece will not explode when or before the stress piece flips over.
- the explosion-proof double insurance function of the energy storage device can be better realized.
- FIG. 1 is a schematic structural diagram of an energy storage device according to an embodiment of the present application.
- FIG. 3 is a schematic diagram of a partial structure of an end cover assembly according to an embodiment of the present application.
- FIG. 4 is a schematic diagram of a partial explosion structure of an end cover assembly according to an embodiment of the present application.
- FIG5 is a schematic diagram of a partial cross-sectional structure of an end cover assembly according to an embodiment of the present application along the A-A direction in FIG3 .
- FIG6 is a schematic diagram of a partial cross-sectional structure along the A-A direction in FIG1 after a stress member and a metal pressure block are short-circuited and connected in an embodiment of the present application.
- FIG. 7 is a schematic structural diagram of an end cover assembly according to an embodiment of the present application.
- FIG. 8 is a schematic diagram of an exploded structure of an end cover assembly according to an embodiment of the present application.
- FIG. 9 is a schematic structural diagram of a stressor according to an embodiment of the present application.
- FIG. 10 is a schematic cross-sectional view of the stressing member according to an embodiment of the present application along the AA direction in FIG. 3 .
- FIG. 11 is a schematic cross-sectional view of the explosion-proof disk according to an embodiment of the present application along the A-A direction in FIG. 3 .
- FIG. 12 is a schematic structural diagram of a metal pressing block according to an embodiment of the present application.
- FIG. 13 is a schematic diagram of the structure of a pole according to an embodiment of the present application.
- FIG. 14 is a schematic structural diagram of a sealing member according to an embodiment of the present application.
- Figure 15 is a schematic diagram of the cross-sectional structure of the top cover of one embodiment of the present application along the A-A direction in Figure 3.
- FIG. 16 is an enlarged view of the dotted frame I in FIG. 15 .
- FIG17 is a schematic diagram of the structure of an electrical equipment according to an embodiment of the present application, wherein the energy storage device and the electrical equipment body are in a separated state.
- Energy storage devices such as batteries usually have explosion-proof valves or explosion-proof discs on the end cap assemblies, so that when the internal air pressure of the energy storage device increases, the explosion-proof valve or explosion-proof disc can be exploded in time to release the pressure. However, when the explosion-proof valve or explosion-proof disc is exploded, it is easy to cause the electrolyte to splash everywhere.
- a stressor is provided on the end cap assembly, so that when the internal pressure of the energy storage device increases but before the explosion pressure of the explosion-proof valve or explosion-proof disc is reached, the positive and negative poles of the energy storage device are short-circuited by the stressor deforming and flipping, preventing the energy storage device from continuing to charge and discharge, so as to avoid the pressure in the energy storage device from continuing to increase, and when the explosion-proof valve or explosion-proof disc is exploded, it is easy to cause the electrolyte to splash everywhere.
- the design structure of the existing stressor is unreasonable and often fails.
- the embodiment of the present application provides an energy storage device 200, which includes: an electrode assembly 230, a transfer plate 210 and an end cap assembly 100; the transfer plate 210 is electrically connected to the electrode assembly 230; the end cap assembly 100 is arranged on the side of the transfer plate 210 away from the electrode assembly 230, and the end cap assembly 100 includes: a pole assembly 30, a top cover 10, a stress piece 33 and an explosion-proof assembly 70.
- the pole assembly 30 includes a metal pressing block 31, the metal pressing block 31 is electrically connected to the transfer plate 210, and the metal pressing block 31 has a preset surface 301.
- the top cover 10 is arranged at intervals on the preset surface 301 of the metal pressing block 31, and the top cover 10 has a through hole 11 and an explosion-proof hole 15 arranged at intervals, and the through hole 11 is projected on the preset surface 301 and falls within the range of the preset surface 301.
- the stressor 33 closes the through hole 11 and is connected to the top cover 10. When the energy storage device 200 reaches a first pressure value, the stressor 33 abuts against the metal pressure block 31 to short-circuit the energy storage device 200.
- the explosion-proof assembly 70 includes an explosion-proof disc 71, which is used to close the explosion-proof hole 15 and is connected to the top cover 10.
- the explosion-proof disc 71 explodes; wherein the ratio of the first pressure value P1 to the second pressure value P2 is in the range of: 0.4 ⁇ P1/P2 ⁇ 0.87; the thickness of the stressor 33 is in the range of 0.1mm to 6.2mm.
- the energy storage device 200 of the embodiment of the present application can be applied to, but is not limited to, energy storage devices such as lithium-ion secondary batteries, lithium-ion primary batteries, lithium-sulfur batteries, sodium-lithium-ion batteries, sodium-ion batteries or magnesium-ion batteries, and energy storage batteries.
- energy storage devices such as lithium-ion secondary batteries, lithium-ion primary batteries, lithium-sulfur batteries, sodium-lithium-ion batteries, sodium-ion batteries or magnesium-ion batteries, and energy storage batteries.
- the adapter sheet 210 is disposed on the side of the top cover 10 away from the metal pressing block 31, specifically, the adapter sheet 210 is disposed on the side of the lower plastic part 50 away from the top cover 10. It can be understood that the adapter sheet 210 is stacked and disposed on the surface of the lower plastic part 50 away from the top cover 10, and one end of the first flange portion 371 of the pole 37 of the adapter sheet 210 facing the lower plastic part 50 is electrically connected (such as welded) to the first flange portion 371. One end of the adapter sheet 210 away from the surface of the lower plastic part 50 and away from the pole 37 is electrically connected (such as welded) to the pole ear 231 of the electrode assembly 230.
- the stressor 33 seals the through hole 11 . It can be understood that the stressor 33 is located in the through hole 11 to close the through hole 11 and electrically connect the stressor 33 to the top cover 10 .
- the “first pressure value” is the pressure value of the air pressure generated inside the energy storage device 200 that causes the stressor 33 to deform. In other words, when the stressor 33 deforms (or bends) and moves in the direction close to the metal pressing block 31, the pressure value in the direction of the metal pressing block 31 is applied; that is, the pressure value required for the stressor 33 to flip over.
- the “second pressure value” refers to the pressure value of the air pressure generated inside the energy storage device 200 that causes the explosion-proof disc 71 to explode; in other words, the pressure value when the explosion-proof disc 71 explodes and the energy storage device 200 is depressurized.
- the first pressure value is the force applied to the stressor 33 toward the metal pressing block 31 due to the increase in air pressure inside the energy storage device 200.
- the second pressure value is the force applied to the explosion-proof disc 71 toward the metal pressing block 31 due to the increase in air pressure inside the energy storage device 200.
- the range of the ratio of the first pressure value P1 to the second pressure value P2 is: 0.4 ⁇ P1/P2 ⁇ 0.87.
- the ratio P1/P2 of the first pressure value to the second pressure value can be, but is not limited to, 0.4, 0.5, 0.6, 0.7, 0.8, 0.87, etc.
- the energy storage device 200 will have a short circuit connection when it still has a large pressure difference from the bursting pressure (i.e., the second pressure value) and is still within the safe use range, thereby affecting the normal use of the energy storage device 200; when the ratio of the first pressure value to the second pressure value is too large, the overturning pressure of the stress member 33 is too close to the bursting pressure of the explosion-proof plate 71 (i.e., the first pressure value and the second pressure value), and the explosion-proof plate 71 may have exploded when the stress member 33 is overturned or even before it is overturned, which may easily cause the storage device 200 to be short-circuited.
- the electrolyte in the energy storage device 200 splashes or the corrosive gas overflows and corrodes the surrounding energy storage devices 200, affecting the safety of the use of the energy storage device 200 and making it difficult to achieve double insurance.
- the thickness of the stressor 33 is uneven. Along the extension direction of the top cover 10, the thickness of the stressor 33 at any position is in the range of 0.1 mm to 6.2 mm. The thickness of the stressor 33 is determined by a random 5-point method or a random 10-point method, and the average thickness is taken. In some cases, the stressor 33 includes a positive stressor disposed on the positive pole column assembly and a negative stressor disposed on the negative pole column assembly. It should be understood that the average thickness of the positive stressor and the negative stressor is in the range of 0.1 mm to 6.2 mm. The positive stressor may abut against the metal pressing block 31 before the negative stressor, or the negative stressor may abut against the metal pressing block 31 before the positive stressor.
- the energy storage device 200 of the embodiment of the present application includes an end cap assembly 100, and the end cap assembly 100 includes a stress member 33.
- the stress member 33 is deformed, and the middle part of the stress member 33 moves toward the direction close to the metal pressing block 31 and turns over until it abuts against the metal pressing block 31.
- the energy storage device 200 is short-circuited (short-circuited for short), so that the energy storage device 200 stops charging or discharging, thereby preventing the pressure inside the energy storage device 200 from continuing to increase, causing the energy storage device 200 to explode, and improving the safety of the use of the energy storage device 200.
- the flipping of the stress member 33 fails to short-circuit the energy storage device 200 or the energy storage device 200 is short-circuited but the internal pressure of the energy storage device 200 continues to increase, when the internal pressure of the energy storage device 200 increases to the bursting pressure of the explosion-proof plate 71 (i.e., the second pressure value), the explosion-proof plate 71 will explode, thereby relieving the pressure of the energy storage device 200 to control the released energy within a safe range, thereby realizing the double insurance function and improving the safety of the use of the energy storage device 200.
- the stress member 33 of the energy storage device 200 will not flip over too early, short-circuit the energy storage device 200 and affect the normal use of the energy storage device 200; at the same time, the flipping pressure of the stress member 33 and the bursting pressure of the explosion-proof plate 71 have a certain difference, so that the explosion-proof plate 71 will not explode when or before the stress member 33 flips over.
- the explosion-proof double insurance function of the energy storage device 200 can be better realized.
- the range of the difference between the second pressure value P2 and the first pressure value P1 is: 0.1Mpa ⁇ P2-P1 ⁇ 0.3Mpa.
- the difference between the second pressure value P2 and the first pressure value P1 can be, but is not limited to, 0.1Mpa, 0.15Mpa, 0.2Mpa, 0.25Mpa, 0.3Mpa, etc. If the difference between the second pressure value P2 and the first pressure value P1 is too small, the explosion-proof disc 71 is likely to explode when or before the stress member 33 flips over.
- the explosion-proof double insurance function of the energy storage device 200 can be better realized; if the difference between the second pressure value P2 and the first pressure value P1 is too large, the stress member 33 is likely to flip over prematurely, causing the energy storage device 200 to be short-circuited, and affecting the normal use of the energy storage device 200.
- the range of the first pressure value P1 is 0.35Mpa ⁇ P1 ⁇ 0.65Mpa.
- the first pressure value can be, but is not limited to, 0.35Mpa, 0.4Mpa, 0.45Mpa, 0.5Mpa, 0.55Mpa, 0.6Mpa, 0.65Mpa, etc.
- the stress member 33 may have flipped when the energy storage device 200 is still in a safe working environment, abutting against the metal pressure block 31, and short-circuiting the energy storage device 200, thereby affecting the normal use of the energy storage device 200; if the first pressure value is too large, the pressure required for the stress member 33 to flip is too large, and when or before the stress member 33 flips, the explosion-proof plate 71 may also explode, which may easily cause the electrolyte in the energy storage device 200 to splash or the corrosive gas to overflow and corrode the surrounding energy storage device 200, affecting the realization of the double insurance function of the end cover assembly 100.
- the range of the second pressure value P2 is 0.75MPa ⁇ P2 ⁇ 1.05Mpa.
- the second pressure value can be, but is not limited to, 0.75MPa, 0.8Mpa, 0.85MPa, 0.9Mpa, 0.95MPa, 1.0Mpa, 1.05Mpa, etc. If the second pressure value is too small, the explosion-proof disc 71 will explode when the energy storage device 200 is still in a safe working environment, and the energy storage device 200 will be short-circuited, thereby affecting the normal use of the energy storage device 200.
- the second pressure value cannot be different from the first pressure value, affecting the realization of the double insurance function; if the second pressure value is too large, the pressure required for the explosion-proof disc 71 to explode is too large.
- the explosion-proof plate 71 explodes, it is easy to cause serious splashing of electrolyte in the energy storage device 200, and even cause the explosion fragments to splash, resulting in a safety accident and affecting the safety of the energy storage device 200.
- the pole assembly 30 includes a positive pole assembly 30a and a negative pole assembly 30b
- the stressor 33 includes a positive stressor 33a and a negative stressor 33b
- the positive stressor 33a is deformed and abuts against the metal pressing block 31 of the positive pole assembly 30a
- the energy storage device 200 reaches a second sub-pressure value P12
- the negative stressor 33b is deformed and abuts against the metal pressing block 31 of the negative pole assembly 30b
- P12 ⁇ P11 wherein, the first pressure value P1 includes the first sub-pressure value P11 and the second sub-pressure value P12.
- both the positive electrode post assembly 30 a and the negative electrode post assembly 30 b include a metal pressing block 31 .
- the range of the ratio of the first sub-pressure value P11 to the second pressure value P2 is: 0.4 ⁇ P11/P2 ⁇ 0.87; the range of the ratio of the second sub-pressure value P12 to the second pressure value P2 is: 0.4 ⁇ P12/P2 ⁇ 0.87.
- the positive pole assembly 30a and the negative pole assembly 30b are respectively arranged on opposite sides of the explosion-proof hole 15. It can also be understood that the positive pole assembly 30a, the explosion-proof hole 15 and the negative pole assembly 30b are arranged in sequence along the extension direction (i.e., the long side direction) of the end cover assembly 100. The positive stressor 33a and the negative stressor 33b are respectively arranged on opposite sides of the explosion-proof hole 15 along the extension direction (i.e., the long side direction) of the top cover 10.
- the stressor 33 includes a supporting portion 331, a deformation portion 333 and a connecting portion 335 that are bent and connected in sequence, the deformation portion 333 is arranged around the outer periphery of the supporting portion 331, and the connecting portion 335 is arranged around the outer periphery of the deformation portion 333; the connecting portion 335 is connected to the top cover 10, and the deformation portion 333 is bent from one end of the connecting portion 335 away from the top cover 10 toward a direction away from the metal pressure block 31; when the energy storage device 200 reaches a first pressure value, the supporting portion 331 abuts against the metal pressure block 31 to short-circuit the energy storage device 200; the minimum thickness of the deformation portion 333 is less than the thickness of the supporting portion 331 and less than the thickness of the connecting portion 335; the ratio of the minimum thickness d1 of the deformation portion 333 to the minimum thickness d2 of the explosion-proof plate 71 is in the range of: 2 ⁇ d1/d
- the deformation portion 333 is deformed under the action of the internal pressure of the energy storage device 200, and the abutting portion 331 moves toward the direction close to the metal pressing block 31 until it abuts against the metal pressing block 31.
- the metal pressing block 31 of the positive electrode column assembly 30a and the metal pressing block 31 of the negative electrode column assembly 30b are both electrically connected to the top cover 10, and then the positive electrode column assembly 30a and the negative electrode column assembly 30b of the energy storage device 200 are short-circuited (short-circuited for short), so that the energy storage device 200 stops charging or discharging, thereby preventing the pressure inside the energy storage device 200 from continuing to increase, causing the energy storage device 200 to explode, and improving the safety of the use of the energy storage device 200.
- the ratio d1/d2 of the minimum thickness d1 of the deformation portion 333 to the minimum thickness d2 of the explosion-proof disc 71 may be, but is not limited to, 2, 2.2, 2.4, 2.6, 2.8, 3.0, etc.
- the deformation portion 333 will be deformed too early, causing the stress member 33 to flip over too early, short-circuiting the energy storage device 200 and affecting the normal use of the energy storage device 200; if the ratio of the minimum thickness d1 of the deformation portion 333 to the minimum thickness d2 of the explosion-proof disc 71 is too large, the flipping pressure of the stress member 33 and the bursting pressure of the explosion-proof disc 71 are difficult to stagger, thus losing the purpose of setting the stress member 33 and making it difficult to achieve the double insurance function.
- the thickness of the deformation portion 333 may be uniform or non-uniform.
- the thickness of the abutting portion 331 and the connecting portion 335 are both uniform.
- the thickness d1 of the deformation portion 333 is in the range of 0.3mm ⁇ d1 ⁇ 1.0mm.
- the thickness d1 of the deformation portion 333 may be, but is not limited to, 0.3mm, 0.35mm, 0.4mm, 0.5mm, 0.55mm, 0.6mm, 0.65mm, 0.7mm, 0.75mm, 0.85mm, 1.0mm, etc. If the thickness of the deformation portion 333 is too thin, deformation may occur prematurely, causing the energy storage device 200 to short-circuit, thus affecting the normal application of the energy storage device 200.
- the deformation part 333 can have a certain strength and will not deform when the internal pressure of the energy storage device 200 is still relatively small, and can also deform in time to abut against the metal pressing block 31 when the internal pressure of the energy storage device 200 reaches the first pressure value, thereby short-circuiting the energy storage device 200 and stopping charging and discharging.
- the minimum thickness d2 of the explosion-proof sheet 71 is in the range of 0.05 mm ⁇ d2 ⁇ 0.15 mm.
- the minimum thickness d2 of the explosion-proof sheet 71 may be, but is not limited to, 0.05 mm, 0.07 mm, 0.09 mm, 0.11 mm, 0.13 mm, 0.15 mm, etc. If the minimum thickness of the explosion-proof sheet 71 is too small, the explosion-proof sheet 71 will explode when the second pressure value inside the energy storage device 200 is still relatively small, affecting the normal use of the energy storage device 200.
- the second pressure value of the explosion is too large, which may easily cause droplets of electrolyte or corrosive gas in the energy storage device 200 to splash during the explosion, corroding the safety of the surrounding energy storage device 200 or batteries.
- the explosion-proof disc 71 has notches, so that when the internal pressure of the energy storage device 200 increases to a second pressure value, the disc 71 ruptures to explode, thereby relieving the pressure of the energy storage device 200, so as to control the energy released by the explosion of the explosion-proof assembly 70 within a safe range, thereby improving the safety of the use of the energy storage device 200.
- the minimum thickness d2 of the explosion-proof disc 71 refers to the minimum thickness of the position of the explosion-proof disc 71 with the notches.
- the thickness of the explosion-proof disc 71 is uneven.
- the thickness of the portion of the explosion-proof disc 71 connected to or welded to the top cover 10 ranges from 0.5 mm to 0.6 mm; in other words, the thickness of the outer peripheral portion of the explosion-proof disc 71 ranges from 0.5 mm to 0.6 mm, such as 0.5 mm, 0.52 mm, 0.54 mm, 0.56 mm, 0.58 mm, 0.6 mm, etc.
- the thickness of the explosion-proof disc 71 excluding the outer peripheral portion and the scored portion ranges from 0.25 mm to 0.35 mm, such as 0.25 mm, 0.28 mm, 0.3 mm, 0.32 mm, 0.35 mm, etc.
- the thickness of the part of the explosion-proof plate 71 connected to or welded to the top cover 10 is greater than the thickness of the middle part, which can improve the connection strength between the explosion-proof plate 71 and the top cover 10 and enhance the stability of the connection between the explosion-proof plate 71 and the top cover 10 before explosion; the thickness of the middle part within the outer periphery is greater than the thickness of the scored part, which can control the position of the explosion of the explosion-proof plate 71 when the explosion-proof plate 71 explodes, thereby controlling the safety problems caused by the explosion of the energy storage device 200 to a lower range.
- the thickness d3 of the abutting portion 331 is in the range of 1.6 mm ⁇ d3 ⁇ 3.4 mm.
- the thickness d3 of the abutting portion 331 may be, but is not limited to, 1.6 mm, 1.8 mm, 1.9 mm, 2.0 mm, 2.2 mm, 2.4 mm, 2.8 mm, 3.0 mm, 3.2 mm, 3.4 mm, etc.
- the abutting portion 331 can be better embedded between the upper and lower surfaces of the top cover 10 (i.e., the surface facing the metal pressing block 31 and the surface facing away from the metal pressing block 31).
- the thickness d4 of the connecting portion 335 is in the range of: 0.45mm ⁇ d4 ⁇ 1.5mm.
- the thickness d4 of the connecting portion 335 may be, but is not limited to, 0.45mm, 0.6mm, 0.8mm, 1.0mm, 1.2mm, 1.4mm, 1.5mm, etc. If the thickness of the connecting portion 335 is too small, when the stress member 33 is deformed by pressure, the connecting portion 335 may be damaged during the deformation of the deformation portion 333, causing damage to the energy storage device 200.
- the stress member 33 exceeds the two opposite surfaces of the top cover 10, and it is easy to accidentally touch the stress member 33 during the subsequent assembly of other components of the end cover assembly 100, resulting in an inaccurate pressure value when the stress member 33 is flipped over.
- the range of the angle ⁇ between the stacking direction of the metal pressing block 31 and the stress piece 33 and the surface of the deformation portion 333 facing the metal pressing block 31 is: 25° ⁇ 75°.
- the range of the angle ⁇ between the direction perpendicular to the metal pressing block 31 or the top cover 10 and the deformation portion 333 is: 25° ⁇ 75°.
- the angle ⁇ between the stacking direction of the metal pressing block 31 and the stress piece 33 and the deformation portion 333 can be but is not limited to 25°, 30°, 35°, 40°, 45°, 50°, 55°, 60°, 65°, 70°, 75°, etc.
- this will greatly increase the distance that the supporting portion 331 needs to move when the stress piece 33 is flipped, and increase the flipping time of the stress piece 33, which is not conducive to short-circuiting the energy storage device 200.
- the angle between the stacking direction of the metal pressing block 31 and the stress piece 33 and the deforming portion 333 is too large, the maximum distance that the supporting portion 331 can move toward the direction close to the metal pressing block 31 is limited, so that when the stress piece 33 is flipped, the moving distance of the supporting portion 331 is not enough, and the metal pressing block 31 cannot be well supported, which affects the electrical connection between the metal pressing block 31 and the stress piece 33, so that the energy storage device 200 cannot be short-circuited in time, which increases the safety hazard of using the energy storage device 200.
- the supporting portion 331 can have a sufficient maximum movable distance, and the distance that the supporting portion 331 needs to move when the stress member 33 is flipped can be reduced, so that the energy storage device 200 can be short-circuited in time, thereby improving the safety performance of the energy storage device 200.
- the metal pressing block 31 includes a first part 311 and a second part 313 that are connected.
- the first part 311 is used to abut against the abutting part 331 when the abutting part 331 moves toward the metal pressing block 31, so that the metal pressing block 31 is electrically connected to the top cover 10; the second part 313 is used to electrically connect to an external electrical device.
- the orthographic projection of the abutting portion 331 on the surface of the first portion 311 facing the stressing member 33 falls within the range of the surface of the first portion 311 facing the stressing member 33.
- the second portion 313 and the stressing member 33 are staggered.
- the metal pressing block 31 may be, but is not limited to, aluminum or the like.
- the pole assembly 30 further includes an upper plastic part 35, a pole 37 and a sealing part 39.
- the upper plastic part 35 is at least partially located between the metal pressing block 31 and the top cover 10, and is used to insulate the metal pressing block 31 from the top cover 10.
- the upper plastic part 35 is sleeved on a portion of the metal pressing block 31, and a surface of the first portion 311 facing the stressing member 33 is partially exposed to the upper plastic part 35, and a surface of the second portion 313 facing away from the top cover 10 is exposed to the upper plastic part 35.
- the pole 37 is provided through the top cover 10 and the upper plastic part 35, and is electrically connected to the second portion 313 of the metal pressing block 31.
- the end of the pole 37 away from the metal pressing block 31 is used to electrically connect the electrode assembly 230 of the energy storage device 200 (that is, the pole 37 is electrically connected to the electrode assembly 230 through the adapter 210).
- the pole 37 is insulated from the top cover 10.
- the sealing member 39 is sleeved on the outer periphery of the pole 37, and is used to insulate the pole 37 from the top cover 10.
- the sealing member 39 is also used to close the gap between the pole 37 and the top cover 10 to improve the air tightness of the top cover 10.
- the positive pole assembly 30a includes a metal pressing block 31, an upper plastic part 35, a pole 37 and a seal 39.
- the negative pole assembly 30b also includes a metal pressing block 31, an upper plastic part 35, a pole 37 and a seal 39.
- the surface of the first part 311 facing away from the stress member 33 is wrapped by the upper plastic part 35, and the surface of the second part 313 facing the top cover 10 is provided with the upper plastic part 35, so that the upper plastic part 35 can protect the first part 311, and prevent the first part 311 from being deformed in the direction close to the stress member 33 after being hit, thereby accidentally contacting with the abutting part 331.
- the pole 37 includes a first flange portion 371 and a first penetration portion 373 protruding from the surface of the first flange portion 371.
- the first flange portion 371 is located on the side of the top cover 10 away from the metal pressing block 31.
- the first penetration portion 373 is penetrated through the top cover 10, the upper plastic part 35 and the second portion 313 of the metal pressing block 31 in sequence, and is connected to the second portion 313 (for example, riveted, etc.).
- the sealing member 39 is sleeved on the outer periphery of the first penetration portion 373 to seal the pole 37 with the top cover 10.
- the sealing member 39 is also used to seal the gap between the first penetration portion 373 and the top cover 10 to improve the air tightness of the top cover 10.
- the seal 39 includes a second flange portion 391 and a second penetration portion 393 protruding from the surface of the second flange portion 391, the second flange portion 391 is located between the first flange portion 371 and the top cover 10, the second penetration portion 393 is penetrated through the top cover 10, and the second flange portion 391 and the second penetration portion 393 are both sleeved on the outer periphery of the first penetration portion 373 of the pole 37, so that the pole 37 is insulated from the top cover 10.
- the first penetration portion 373 sequentially passes through the seal 39, the top cover 10, the upper plastic part 35 and the metal pressing block 31, and is electrically connected to the metal pressing block 31.
- the top cover 10 may be, but is not limited to, an aluminum plate or the like.
- the through hole 11 includes a first sub-hole 111 and a second sub-hole 113 that are connected.
- the first sub-hole 111 is closer to the metal pressure block 31 than the second sub-hole 113.
- the radial dimension of the first sub-hole 111 is larger than the radial dimension of the second sub-hole 113.
- the stress member 33 is arranged in the first sub-hole 111, and the connecting portion 335 abuts against the bottom wall of the first sub-hole 111 defined by the top cover 10 and connects the side wall of the first sub-hole 111 defined by the top cover 10.
- first sub-hole 111 and the second sub-hole 113 are arranged along the stacking direction of the metal block 31 and the top cover 10, the first sub-hole 111 passes through the surface of the top cover 10 facing the metal block 31, and the second sub-hole 113 passes through the surface of the top cover 10 away from the metal block 31.
- the first sub-hole 111 and the second sub-hole 113 form a step hole, and the stress piece 33 is arranged in the first sub-hole 111. This can better avoid squeezing the stress piece 33 during assembly of the end cover assembly 100, causing the stress piece 33 to deform and flip prematurely, thereby affecting the performance of the energy storage device 200 using the end cover assembly 100.
- the stress member 33 is arranged in the first sub-hole 111, that is, in the through hole 11, near the position of the metal pressure block 31. This can reduce the moving distance of the supporting portion 331 when the stress member 33 is deformed and flipped, so that when the internal pressure of the energy storage device 200 increases to a certain level, the stress member 33 can be flipped more promptly and in a shorter time, so that the supporting portion 331 can abut the metal pressure block 31, so that the energy storage device 200 can be short-circuited more promptly, thereby improving the safety of the use of the energy storage device 200.
- the depth of the first sub-hole 111 ranges from 0.3 mm to 1.35 mm.
- the depth of the first sub-hole 111 may be, but is not limited to, 0.3 mm, 0.4 mm, 0.5 mm, 0.6 mm, 0.7 mm, 0.8 mm, 0.9 mm, 1.0 mm, 1.1 mm, 1.2 mm, 1.3 mm, 1.35 mm, etc.
- the depth of the first sub-hole 111 is too shallow.
- the connecting part 335 After the connecting part 335 is welded to the top cover 10, it cannot be ensured that the surface of the connecting part 335 facing the metal pressing block 31 is lower than (i.e., recessed in) the surface of the top cover 10 facing the metal pressing block 31; if the depth of the first sub-hole 111 is too deep, the surface of the connecting part 335 away from the metal pressing block 31 will be lower than (i.e., protruding out) the surface of the top cover 10 away from the metal pressing block 31, which may easily lead to accidental touching of the stress part 33 when assembling other parts of the end cover assembly 100, causing its deformation and failure.
- the explosion-proof hole 15 is arranged in the middle position of the top cover 10, and the air pressure at the middle position corresponding to the energy storage device 200 is the largest.
- the explosion-proof plate 71 is arranged in the middle position of the top cover 10. When the internal pressure of the energy storage device 200 reaches the preset explosion pressure, it can be exploded in time to relieve the pressure of the energy storage device 200.
- the top cover 10 further has a penetration hole 13, which is disposed adjacent to the through hole 11 on a side away from the explosion-proof hole 15, and is used to set a first penetration portion 373 of the pole 37 and a second penetration portion 393 of the seal 39.
- the top cover 10 is a long strip plate-like structure, that is, the top cover 10 has a long side and a short side, the perforated hole 13 and the through hole 11 are arranged at intervals along the long side direction of the top cover 10, and the perforated hole 13 is arranged closer to the end of the top cover 10 than the through hole 11. It can be understood that the end cover assembly 100 is a long strip structure.
- the explosion-proof sheet 71 is disposed on one side of the explosion-proof hole 15 close to the lower plastic part and is welded to the top cover 10.
- the explosion-proof assembly 70 further includes a protective sheet 73, which is disposed on the surface of the top cover 10 facing the metal pressing block 31 and is used to close the opening of the explosion-proof hole 15 facing the metal pressing block 31 to prevent foreign objects from hitting the metal pressing block 31.
- the explosion-proof plate 71 is damaged, causing the electrolyte inside the energy storage device 200 to overflow.
- the end cover assembly 100 of the embodiment of the present application further includes a lower plastic part 50, which is disposed on a side of the top cover 10 away from the metal pressing block 31.
- the lower plastic part 50 is closer to the electrode assembly 230 of the energy storage device 200 than the top cover 10, and is used to insulate the top cover 10 from the electrode assembly 230 of the energy storage device 200.
- the first flange portion 371 of the pole 37 is arranged on the side of the lower plastic part 50 away from the top cover 10, and the lower plastic part 50 is arranged between the first flange portion 371 and the top cover 10. It can be understood that when the pole 37 is assembled, the first penetration portion 373 of the pole 37 passes through the sealing member 39, the lower plastic part 50, the top cover 10, the upper plastic part 35 and the metal pressing block 31 in sequence, and is electrically connected to the metal pressing block 31. It can be understood that the pole 37 is electrically connected to the metal pressing block 31, but is insulated from the top cover 10 and the stressor 33.
- the lower plastic part 50 has a first vent hole 51 at a position where it overlaps with the stressor 33, and the first vent hole 51 is used to connect the stressor 33 with the gas path of the electrode assembly 230 of the energy storage device 200, so that when the pressure inside the energy storage device 200 increases, the pressure can be promptly transmitted to the stressor 33.
- the lower plastic part 50 has a second vent hole 53 at a position where it overlaps with the explosion-proof assembly 70, so as to connect the gas path between the explosion-proof assembly 70 and the energy storage device 200.
- the electrode assembly 230 further includes an electrically connected electrode plate 232 and a tab 231, wherein the tab 231 is electrically connected to an end of the adapter plate 210 away from the pole 37.
- the electrode plate 232 includes a current collector and an electrode active layer disposed on the surface of the current collector, wherein the current collector is electrically connected to the tab 231. It can be understood that the electrode plate 232 may include a positive electrode plate and a negative electrode plate.
- the pole assembly 30 is a positive pole assembly 30a
- the pole 37 is a positive pole 37
- the adapter plate 210 is a positive adapter plate 210
- the pole ear 231 is a positive pole ear 231
- the electrode plate 232 is a positive pole plate
- the pole assembly 30 is a negative pole assembly 30b
- the pole 37 is a negative pole 37
- the adapter plate 210 is a negative adapter plate 210
- the pole ear 231 is a negative pole ear 231
- the electrode plate 232 is a negative pole plate.
- the pole ear 231 has a welding portion 2311 welded to the adapter 210, and the orthographic projection of the welding portion 2311 on the preset surface 301 falls within the range of the orthographic projection of the stressor 33 on the preset surface 301. It can be understood that the stressor 33 and the welding portion 2311 are at least partially overlapped.
- the pole 37 and the stressor 33 of the end cover assembly 100 are spaced apart along the extension direction of the top cover 10, and the adapter 210 is welded to the pole 37 at one end and welded to the pole ear 231 at the other end.
- the welding portion 2311 is arranged below the stressor 33, which can save space of the end cover assembly 100 along the extension direction of the top cover 10 or the end cover assembly 100, and reduce the length of the end cover assembly 100.
- the embodiment of the present application further provides an electric device 300 , which includes: an electric device body 310 ; and the energy storage device 200 described in the embodiment of the present application, wherein the energy storage device 200 supplies power to the electric device body 310 .
- the power-consuming device 300 of the embodiment of the present application may be, but is not limited to, a portable electronic device such as a mobile phone, a tablet computer, a laptop computer, a desktop computer, a smart bracelet, a smart watch, an electronic reader, a game console, etc. It may also be a vehicle such as a car, a truck, a car, a truck, a truck, a motor vehicle, a high-speed train, an electric vehicle, etc. In addition, it may also be various household appliances, etc.
- the electrical equipment 300 described in this embodiment is merely a form of the electrical equipment 300 used by the end cover assembly 100, and should not be understood as a limitation on the electrical equipment 300 provided in the present application, nor should it be understood as a limitation on the end cover assembly 100 provided in each embodiment of the present application.
- references to “embodiments” and “implementation methods” in this application mean that the specific features, structures, or characteristics described in conjunction with the embodiments may be included in at least one embodiment of the present application.
- the appearance of the phrases in various locations in the specification does not necessarily refer to the same embodiment, nor is it an independent or alternative embodiment that is mutually exclusive with other embodiments. It is explicitly and implicitly understood by those skilled in the art that the embodiments described in this application may be combined with other embodiments.
- the features, structures or characteristics described in the various embodiments of the present application can be arbitrarily combined without contradiction to form another embodiment without departing from the spirit and scope of the technical solution of the present application.
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Abstract
Description
Claims (11)
- 一种储能装置(200),其包括:电极组件(230)、转接片(210)及端盖组件(100);所述转接片(210)电连接所述电极组件(230);所述端盖组件(100)设置于所述转接片(210)背离所述电极组件(230)的一侧,所述端盖组件(100)包括:极柱组件(30),所述极柱组件(30)包括金属压块(31),所述金属压块(31)电连接所述转接片(210),所述金属压块(31)具有预设表面(301);顶盖(10),间隔设置于所述金属压块(31)的预设表面(301),所述顶盖(10)具有间隔设置的通孔(11)及防爆孔(15),所述通孔(11)在所述预设表面(301)正投影落入所述预设表面(301)的范围内;应激件(33),封闭所述通孔(11)且连接所述顶盖(10),当所述储能装置(200)达到第一压力值时,所述应激件(33)抵持所述金属压块(31),以使所述储能装置(200)短路连接;以及防爆组件(70),包括防爆片(71),所述防爆片(71)用于封闭所述防爆孔(15)且与所述顶盖(10)连接,当所述储能装置(200)达到第二压力值时,所述防爆片(71)发生爆破;其中,所述第一压力值P1与所述第二压力值P2的比值的范围为:0.4≤P1/P2≤0.87;所述应激件(33)的厚度的范围值为0.1mm至6.2mm。
- 根据权利要求1所述的储能装置(200),其中,所述第二压力值P2与所述第一压力值P1的差值的范围为:0.1Mpa≤P2-P1≤0.3Mpa。
- 根据权利要求1或2所述的储能装置(200),其中,所述第一压力值P1的范围为0.35Mpa≤P1≤0.65Mpa;所述第二压力值P2的范围为:0.75MPa≤P2≤1.05Mpa。
- 根据权利要求1-3任一项所述的储能装置(200),其中,所述极柱组件(30)包括正极极柱组件(30a)及负极极柱组件(30b),所述应激件(33)包括正极应激件(33a)及负极应激件(33b);当所述储能装置(200)达到第一子压力值P11时,所述正极应激件(33a)发生形变并抵接所述正极极柱组件(30a)的所述金属压块(31);当所述储能装置(200)达到第二子压力值P12时,所述负极应激件(33b)发生形变并抵接所述负极极柱组件(30b)的所述金属压块(31);其中,P12<P11;其中,所述第一压力值P1包括所述第一子压力值P11及所述第二子压力值P12。
- 根据权利要求1-4任一项所述的储能装置(200),其中,所述应激件(33)包括依次弯折相连的抵持部(331)、变形部(333)及连接部(335),所述变形部(333)环绕所述抵持部(331)的外周设置,所述连接部(335)环绕所述变形部(333)的外周设置;所述连接部(335)连接所述顶盖(10),所述变形部(333)自所述连接部(335)背离所述顶盖(10)的一端朝向背离所述金属压块(31)的方向弯折;当所述储能装置(200)达到第一压力值时,所述抵持部(331)抵接所述金属压块(31),以使所述储能装置(200)短路连接;所述变形部(333)的最小厚度小于所述抵持部(331)的厚度且小于所述连接部(335)的厚度;所述 变形部(333)的最小厚度d1与所述防爆片(71)的最小厚度d2的比值的范围为:2≤d1/d2≤3。
- 根据权利要求5所述的储能装置(200),其中,所述变形部(333)的最小厚度d1的范围为:0.3mm≤d1≤1.0mm。
- 根据权利要求5或6所述的储能装置(200),其中,所述防爆片(71)的最小厚度d2的范围为:0.05mm≤d2≤0.15mm。
- 根据权利要求5-7任一项所述的储能装置(200),其中,所述金属压块(31)与应激件(33)的层叠方向与所述变形部(333)面向所述金属压块(31)的表面之间的角度α的范围为:25°≤α≤75°。
- 根据权利要求5-8任一项所述的储能装置(200),其中,所述抵持部(331)的厚度d3的范围为1.6mm≤d3≤3.4mm;所述连接部(335)的厚度d4的范围为0.45mm≤d4≤1.5mm。
- 根据权利要求1-9任一项所述的储能装置(200),其中,所述极柱组件(30)还包括极柱(37),所述极柱(37)穿设于所述顶盖(10)且与所述顶盖(10)绝缘设置,所述极柱(37)分别与所述金属压块(31)及所述转接片(210)电连接;电极组件(230)包括电连接的电极极片(232)及极耳(231),所述极耳(231)具有焊接于所述转接片(210)的焊接部(2311),所述焊接部(2311)在所述预设表面(301)的正投影落在所述应激件(33)在所述预设表面(301)的正投影的范围内。
- 一种用电设备(300),其包括:用电设备本体(310);以及权利要求1-10任一项所述的储能装置(200),所述储能装置(200)为所述用电设备本体(310)进行供电。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2023/075254 WO2024164243A1 (zh) | 2023-02-09 | 2023-02-09 | 储能装置及用电设备 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2023/075254 WO2024164243A1 (zh) | 2023-02-09 | 2023-02-09 | 储能装置及用电设备 |
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| Publication Number | Publication Date |
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| WO2024164243A1 true WO2024164243A1 (zh) | 2024-08-15 |
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| Application Number | Title | Priority Date | Filing Date |
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| PCT/CN2023/075254 Ceased WO2024164243A1 (zh) | 2023-02-09 | 2023-02-09 | 储能装置及用电设备 |
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| WO (1) | WO2024164243A1 (zh) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105932181A (zh) * | 2016-07-15 | 2016-09-07 | 东莞永蓝电子科技有限公司 | 一种动力电池顶盖及使用该顶盖的动力电池 |
| KR20180005455A (ko) * | 2016-07-06 | 2018-01-16 | 주식회사 엘지화학 | 캡 조립체 및 이를 이용한 이차 전지 |
| CN207896195U (zh) * | 2018-03-16 | 2018-09-21 | 宁德时代新能源科技股份有限公司 | 电池模组 |
| US20190237728A1 (en) * | 2016-06-29 | 2019-08-01 | Sanyo Electric Co., Ltd. | Secondary battery |
-
2023
- 2023-02-09 WO PCT/CN2023/075254 patent/WO2024164243A1/zh not_active Ceased
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20190237728A1 (en) * | 2016-06-29 | 2019-08-01 | Sanyo Electric Co., Ltd. | Secondary battery |
| KR20180005455A (ko) * | 2016-07-06 | 2018-01-16 | 주식회사 엘지화학 | 캡 조립체 및 이를 이용한 이차 전지 |
| CN105932181A (zh) * | 2016-07-15 | 2016-09-07 | 东莞永蓝电子科技有限公司 | 一种动力电池顶盖及使用该顶盖的动力电池 |
| CN207896195U (zh) * | 2018-03-16 | 2018-09-21 | 宁德时代新能源科技股份有限公司 | 电池模组 |
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