WO2024090175A1 - スラリー濃化システム、焼結鉱原料粒子の製造システム、焼結鉱の製造システム、スラリー濃化方法、焼結鉱原料粒子の製造方法及び焼結鉱の製造方法 - Google Patents
スラリー濃化システム、焼結鉱原料粒子の製造システム、焼結鉱の製造システム、スラリー濃化方法、焼結鉱原料粒子の製造方法及び焼結鉱の製造方法 Download PDFInfo
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- WO2024090175A1 WO2024090175A1 PCT/JP2023/036479 JP2023036479W WO2024090175A1 WO 2024090175 A1 WO2024090175 A1 WO 2024090175A1 JP 2023036479 W JP2023036479 W JP 2023036479W WO 2024090175 A1 WO2024090175 A1 WO 2024090175A1
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- Prior art keywords
- slurry
- thickening
- concentration
- thickened
- solid matter
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/16—Sintering; Agglomerating
- C22B1/20—Sintering; Agglomerating in sintering machines with movable grates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/16—Sintering; Agglomerating
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
Definitions
- the present invention relates to a slurry thickening system, a sintered ore raw material particle manufacturing system, a sintered ore manufacturing system, a slurry thickening method, a sintered ore raw material particle manufacturing method, and a sintered ore manufacturing method.
- Sintered ore is obtained by mixing iron ore powder with various additives, granulating the raw material particles, and sintering them (see, for example, Patent Document 1). At this time, it is known that the granulation properties of the raw material particles can be improved by adding fine powder containing an iron compound to the iron ore powder.
- methods that can be considered include, for example, storing the slurry in a tank and leaving it to stand to allow the fine powder to settle naturally, passing the slurry through a centrifugal separator (such as a thickener), or centrifuging the slurry using a decanter.
- a centrifugal separator such as a thickener
- Slurry produced at steelworks is considered appropriate as a slurry for granulation, but because the concentration of fine powder in steel slurry varies, the concentration of fine powder in the thickened slurry obtained by the thickening method described above also varies. On the other hand, the effect of improving granulation properties differs depending on the amount of fine powder added during granulation, so if the concentration of fine powder in the thickened slurry is added without adjusting it, the effect of improving granulation properties cannot be stably achieved.
- the present invention provides a slurry thickening system that can stably adjust the concentration after thickening when thickening a slurry, a sintered ore raw material particle manufacturing system, a sintered ore manufacturing system, a slurry thickening method, a sintered ore raw material particle manufacturing method, and a sintered ore manufacturing method.
- a slurry thickening system includes a measurement unit that measures the concentration of solid matter in the slurry before thickening, a thickening unit that obtains a thickened slurry having an increased concentration of solid matter from the slurry before thickening, and a determination unit that determines the amount of diluent to be added to the thickened slurry based on the concentration of solid matter in the slurry before thickening measured in the measurement unit, or determines the thickening conditions in the thickening unit.
- the present invention may be provided in the following aspects:
- a slurry thickening system comprising: a measuring unit that measures the concentration of solid matter in a slurry before thickening; a thickening unit that obtains a thickened slurry having an increased concentration of solid matter from the slurry before thickening; and a determination unit that determines the amount of diluent to be added to the thickened slurry based on the concentration of solid matter in the slurry before thickening measured in the measuring unit, or determines the thickening conditions in the thickening unit.
- the determination unit further determines the amount of diluent to be added to the thickened slurry based on a relationship model showing the relationship between the concentration of solid matter in the pre-thickening slurry and the concentration of solid matter in the thickened slurry and/or the amount of diluent to be added to the thickened slurry.
- a slurry thickening system according to any one of (1) to (3) above, in which a radial gamma ray densitometer and/or an ultrasonic densitometer is used as the measurement unit.
- a slurry thickening system according to any one of (1) to (4) above, in which the pre-thickening slurry contains iron compounds generated in a steelworks as solid substances.
- a slurry thickening system according to any one of (1) to (4) above, wherein the pre-thickening slurry contains steelmaking slurry from a steelworks.
- a method for thickening a slurry comprising: a measuring step for measuring the concentration of solid matter in a slurry before thickening; a thickening step for obtaining a thickened slurry having an increased concentration of solid matter from the slurry before thickening; and a determining step for determining the amount of diluent to be added to the thickened slurry based on the concentration of solid matter in the slurry before thickening measured in the measuring step, or for determining thickening conditions in the thickening step.
- a system for producing sintered ore raw material particles comprising: a measuring unit for measuring the concentration of solid matter in a pre-thickening slurry; a thickening unit for obtaining a thickened slurry having an increased concentration of solid matter from the pre-thickening slurry; a determining unit for determining the amount of diluent to be added to the thickened slurry based on the concentration of solid matter in the pre-thickening slurry measured in the measuring unit, or for determining the thickening conditions in the thickening unit; a diluting unit for adding the diluent to the thickened slurry to obtain a diluted slurry; and a granulating unit for adding the diluted slurry to iron ore powder to granulate pre-sintered particles.
- a method for producing sintered ore raw material particles comprising: a measuring step for measuring the concentration of solid matter in a pre-thickening slurry; a thickening step for obtaining a thickened slurry having an increased concentration of solid matter from the pre-thickening slurry; a determining step for determining the amount of diluent to be added to the thickened slurry based on the concentration of solid matter in the pre-thickening slurry measured in the measuring step, or for determining thickening conditions in the thickening step; a diluting step for adding the diluent to the thickened slurry to obtain a diluted slurry; and a granulating step for adding the diluted slurry to iron ore powder to granulate pre-sintered particles.
- a sintered ore manufacturing system comprising: a measuring unit that measures the concentration of solid matter in a pre-thickened slurry; a thickening unit that obtains a thickened slurry having an increased concentration of solid matter from the pre-thickened slurry; a determining unit that determines the amount of diluent to be added to the thickened slurry based on the concentration of solid matter in the pre-thickened slurry measured in the measuring unit, or determines the thickening conditions in the thickening unit; a diluting unit that adds the diluent to the thickened slurry to obtain a diluted slurry; a granulating unit that adds the diluted slurry to iron ore powder to granulate pre-sintered particles; and a sintering unit that sinters the pre-sintered particles.
- a method for producing sintered ore comprising: a measuring step for measuring a concentration of solid substances in a pre-thickened slurry; a thickening step for obtaining a thickened slurry having an increased concentration of solid substances from the pre-thickened slurry; a determining step for determining an amount of diluent to be added to the thickened slurry based on the concentration of solid substances in the pre-thickened slurry measured in the measuring step, or for determining thickening conditions in the thickening step; a diluting step for adding the diluent to the thickened slurry to obtain a diluted slurry; a granulating step for adding the diluted slurry to iron ore powder to granulate pre-sintered particles; and a sintering step for sintering the pre-sintered particles.
- a measuring step for measuring a concentration of solid substances in a pre-thickened slurry
- a thickening step for obtaining
- the present invention provides a slurry thickening system capable of adjusting the concentration of the slurry after thickening to a constant level, a system for producing sintered ore raw material particles, a system for producing sintered ore, a method for thickening a slurry, a method for producing sintered ore raw material particles, and a method for producing sintered ore.
- FIG. 1 is a schematic diagram of a slurry thickening system according to an embodiment of the present invention.
- FIG. 2 is a diagram for explaining a specific configuration of the slurry thickening system according to the present embodiment.
- FIG. 11 is a diagram for explaining another specific configuration of the slurry thickening system according to the present embodiment.
- FIG. 1 is a schematic diagram of a slurry thickening test system used in the examples. 1 is a plot of the reading of the suspended solids concentration meter 2C versus the solids concentration of the slurry before thickening. 1 is a plot of the solids concentration of the thickened slurry versus the solids concentration of the slurry before thickening.
- 1 is a plot of the amount of solids in a thickened slurry versus the concentration of solids in a pre-thickened slurry. 1 is a plot of the amount of diluent required versus the concentration of solids in the pre-thickened slurry.
- a slurry thickening system a sintered ore raw material particle manufacturing system, a sintered ore manufacturing system, a slurry thickening method, a sintered ore raw material particle manufacturing method, and a sintered ore manufacturing method are described, but the present invention is not limited to the following embodiments, and can be implemented with appropriate modifications within the scope that does not impair the effects of the present invention.
- the configurations described in the following embodiments can be implemented in combination with each other.
- thickening refers to increasing the concentration of solid substances in the slurry.
- the specific means for “thickening” is not particularly limited.
- the slurry thickening system of this embodiment includes a measurement unit that measures the concentration of solid matter in the slurry before thickening, a thickening unit that obtains a thickened slurry having an increased concentration of solid matter from the slurry before thickening, and a determination unit that determines the amount of diluent to be added to the thickened slurry based on the concentration of solid matter in the slurry before thickening measured in the measurement unit, or determines the thickening conditions in the thickening unit.
- FIG. 1 is a schematic diagram of a slurry thickening system according to this embodiment.
- the slurry thickening system 1 shown in FIG. 1 includes a measurement unit 2, a thickening unit 3, and a determination unit 4.
- the slurry thickening system 1 includes a dilution unit 5 that adds the amount of diluent determined in the determination unit 4 to the thickened slurry to obtain a diluted slurry.
- the measuring section 2 measures the concentration of solid matter in the slurry before thickening.
- the measuring unit 2 is not particularly limited as long as it is a suspended solids concentration meter capable of measuring the concentration of suspended solids (SS) in the slurry, and examples that can be used include a radioactive gamma ray concentration meter, an ultrasonic concentration meter, a Coriolis concentration meter, a laser concentration meter, and a turbidity meter.
- a radioactive gamma ray density meter and/or an ultrasonic concentration meter as the measuring unit 2, since they can be attached to the outside of the slurry piping without contacting the slurry itself, and can measure the suspended solids concentration from a few percent to a high concentration of about 40%.
- the pre-thickening slurry is a slurry that is a target for increasing the concentration of solid matter using the slurry thickening system according to this embodiment.
- the pre-thickening slurry may contain iron compounds generated in a steelworks as solid substances.
- the pre-thickening slurry is not particularly limited, and may be, for example, a pig iron making slurry generated in the pig iron making process of a steelworks, a steel making slurry generated in the steel making process of a steelworks, or a rolling slurry generated in the rolling process of a steelworks.
- it is preferable to use a steel making slurry since the particle size of the solid substances (suspended substances) is particularly small and it has a large effect of improving granulation properties.
- the thickening section 3 obtains a thickened slurry having an increased concentration of solid matter from the pre-thickening slurry.
- the thickening section 3 is not particularly limited as long as it can increase the concentration of solid substances from the slurry before thickening, but for example, a tank (natural sedimentation), a thickener, a centrifugal separator (decanter, etc.), etc. can be used. Among them, it is preferable to use a centrifugal separator as the thickening section 3. Unlike thickening using a tank or thickener, thickening using a centrifugal separator can be processed in a short time and has a short retention time, so that the measurement results of the suspended solids concentration can be used relatively easily to control the dilution liquid without corrections considering time or inflow and outflow at that time.
- the tank, thickener, centrifugal separator, etc. can be appropriately selected from devices that can thicken the thickened slurry to a concentration equal to or higher than the set concentration, taking into account the supply amount range and concentration range of the supplied slurry.
- the solid substance concentration in the separated liquid is low.
- the solid substance concentration in the separated liquid can be controlled, for example, by the supply amount of pre-thickening slurry and the thickening conditions in the thickening section, and when a centrifuge is used, for example, it can be controlled by adjusting the rotation speed, differential speed, dam height, etc. When a centrifuge is used, it is particularly preferable to perform separation at a centrifugal force of 1500 G or more.
- the determination section 4 determines the amount of diluent to be added to the thickened slurry based on the concentration of solid matter in the pre-thickened slurry measured in the measurement section described above, or determines the thickening conditions in the thickening section.
- the determination unit 4 is not particularly limited as long as it can determine the amount of diluent to be added to the thickened slurry based on the concentration of solid matter in the pre-thickened slurry, or perform calculations to determine the thickening conditions in the thickening unit, and various calculation devices can be used.
- the determination unit 4 further determines the amount of diluent to be added to the thickened slurry based on a relationship model showing the relationship between the concentration of solid matter in the pre-thickened slurry and the concentration of solid matter in the thickened slurry and/or the amount of diluent to be added to the thickened slurry.
- a relationship model showing the relationship between the concentration of solid substances in the slurry before thickening and the concentration of solid substances in the thickened slurry examples include a function or lookup table showing the relationship between the concentration of solid substances in the slurry before thickening and the concentration of solid substances in the thickened slurry, or a learned model of the relationship between the concentration of solid substances in the slurry before thickening and the concentration of solid substances in the thickened slurry.
- the concentration of solid substances in the thickened slurry can be specified simply by measuring the concentration of solid substances in the slurry before thickening. Then, from the concentration of solid substances in the thickened slurry estimated in this way, the amount of diluent to be added to the thickened slurry to achieve a certain slurry concentration can be calculated.
- relationship models showing the relationship between the concentration of solid substances in the slurry before thickening and the amount of diluent added to the thickened slurry
- examples of such relationship models include a function or lookup table showing the relationship between the concentration of solid substances in the slurry before thickening and the amount of diluent added to the thickened slurry, or a learned model of the relationship between the concentration of solid substances in the slurry before thickening and the amount of diluent added to the thickened slurry.
- the determination unit 4 further determines the amount of diluent to be added to the thickened slurry based on a relationship model showing the relationship between the concentration of solid matter in the slurry before thickening and the thickening conditions in the thickening section.
- examples of such a relationship model include a function or lookup table showing the relationship between the concentration of solid substances in the slurry before thickening and the concentration of solid substances in the slurry before thickening and the thickening conditions in the thickening section, or a learned model of the relationship between the concentration of solid substances in the slurry before thickening and the concentration of solid substances in the slurry before thickening and the thickening conditions in the thickening section.
- the thickening conditions can be the supply amount of the slurry before thickening, and when using a centrifuge, the rotation speed, differential speed, dam height, etc. Only one thickening condition can be used, or two or more can be used.
- relationship models may be created in advance by operating the slurry thickening system 1, or may be created while the slurry thickening system 1 is in operation. Additionally, while the slurry thickening system 1 is in operation, the relationship models currently in use may be corrected or replaced using newly measured information.
- the dilution unit 5 adds the diluent in the amount determined in the determination unit 4 to the thickened slurry to obtain a diluted slurry.
- the diluent is added to the slurry after it has been thickened to reduce the concentration of the solid materials contained therein.
- the diluent is not particularly limited as long as it can reduce the concentration of solid substances in the thickened slurry by adding it.
- a slurry with a lower concentration of solid substances than the thickened slurry, including the slurry before thickening may be used, or industrial water, tap water, pure water, wastewater that can be mixed in without causing any problems, etc. may be used.
- the slurry before thickening contains solid substances, it may be difficult to adjust the amount to be added, and clogging may occur depending on the piping used for addition.
- wastewater may contain suspended solids, which may cause clogging depending on the piping used for addition due to precipitation of hardness components.
- tap water and pure water are expensive. For these reasons, it is preferable to use industrial water as the diluent.
- the location where the diluent is added to the thickened slurry is not particularly limited, but for example, when a decanter is used as the thickening section 3, it is preferable to add the diluent to the thickened slurry discharged from the rotating cylinder inside the casing of the decanter from the standpoint of uniformly mixing with the thickened slurry, but it may also be added after the slurry is discharged from the decanter while it is being transferred to a tank for storing water (including falling from the decanter), or it may be added inside the tank for storing water.
- the method for adjusting the amount of diluent added is not particularly limited, but may be, for example, by adjusting the valve opening or by inverter control of the pump. Furthermore, when adding the diluent to the thickened slurry discharged from the rotating cylinder inside the decanter casing, it is preferable to spray the diluent under high pressure using a nozzle or the like to promote uniform mixing with the thickened slurry. In this case, care must be taken to prevent clogging of the nozzle or the like.
- the diluted slurry thus obtained can be used for any purpose, but is not limited to this. For example, it can be used to improve granulation during the granulation of iron ore in steelworks.
- FIG. 2 is a diagram for explaining a specific configuration of the slurry thickening system according to this embodiment.
- the slurry system 1A shown in FIG. 2 includes a suspended solids concentration meter 2A, a decanter 3A, a calculation and control device 4A, a valve 5A, a pre-thickening slurry tank 6A, a dilution liquid tank 7A, a separation water tank 8A, a post-dilution slurry tank 9A, pumps 10A, 11A, 12A, 13A, and a suspended solids concentration meter 14A.
- the pre-thickened slurry stored in the pre-thickened slurry tank 6A is transferred to the decanter 3A by the pump 10A.
- a suspended solids concentration meter 2A is installed in the piping connecting the pre-thickened slurry tank 6A and the decanter 3A, and this suspended solids concentration meter 2A measures the solid matter concentration of the slurry flowing inside the piping.
- the pre-thickened slurry transferred to the decanter 3A has some of the water removed by the decanter, and the solid matter is thickened, resulting in a thickened slurry.
- Information on the concentration of solid matter measured by the suspended solids concentration meter 2A is sent to the calculation/control device 4A, which is connected in a state where it can communicate with the suspended solids concentration meter 2A.
- the calculation/control device 4A receives this information and determines the amount of diluent to be added to the thickened slurry based on the concentration of the solid matter.
- the calculation/control device 4A holds in advance a relationship model that shows the relationship between the concentration of solid matter in the pre-thickened slurry and the concentration of solid matter in the thickened slurry and/or the amount of diluent to be added to the thickened slurry, and determines the amount of diluent to be added to the thickened slurry either directly or via the concentration of solid matter in the thickened slurry from the measured concentration of solid matter.
- diluent tank 7A which stores diluent, is connected to decanter 3A by piping for transporting diluent, and diluent is transported by pump 11A provided on this piping.
- Valve 5A is provided midway along this piping, and the amount of diluent transported to decanter 3A is adjusted by opening and closing valve 5A.
- Valve 5A is connected in a state capable of communicating with calculation/control device 4A, and this calculation/control device controls the opening and closing and the degree of opening and closing based on the amount of diluent determined by calculation/control device 4A.
- the diluted liquid transferred to the decanter 3A is mixed with the thickened slurry that has been thickened in the decanter 3A, and is discharged from the decanter 3A as a diluted slurry, which is then stored in the diluted slurry tank 9A.
- the diluted slurry then has its solid matter concentration measured by the suspended solids concentration meter 14A, and is then transferred to the next process by the pump 13A.
- the water separated and removed from the pre-thickened slurry in decanter 3A is stored as separated water in separation water tank 8A and then transferred to the next process by pump 12A.
- pre-thickening slurry tank 6A, dilution liquid tank 7A, separation water tank 8A, and post-dilution slurry tank 9A may be provided with agitators (not shown) as necessary, and in particular in pre-thickening slurry tank 6A and post-dilution slurry tank 9A, the agitators are used to prevent settling or accumulation of solid substances.
- FIG. 3 is a diagram for explaining another specific configuration of the slurry thickening system according to the present embodiment.
- the slurry system 1B shown in FIG. 3 includes a suspended solids concentration meter 2B, a decanter 3B, a calculation and control device 4B, a valve 5B, a pre-dilution slurry tank 6B, a dilution liquid tank 7B, a separation water tank 8B, a post-dilution slurry tank 9B, pumps 10B, 11B, 12B, and 13B, and a suspended solids concentration meter 14B.
- the slurry system 1B differs from the slurry system 1A in that the diluted liquid stored in the dilution liquid tank 7A is transferred to the slurry tank 9B after dilution, and dilution is performed in this slurry tank 9B after dilution.
- the rest of the configuration is the same as that of the slurry system 1A.
- the method for thickening a slurry according to the present embodiment includes a measuring step for measuring the concentration of solid matter in the slurry before thickening, a thickening step for obtaining a thickened slurry having an increased concentration of solid matter from the slurry before thickening, and a determining step for determining the amount of diluent to be added to the thickened slurry based on the concentration of the solid matter in the slurry before thickening measured in the measuring step, or for determining thickening conditions in the thickening step.
- Such a slurry thickening method can be carried out, for example, by using the slurry thickening system described above.
- the specific operations in the measurement process are the same as the operation of the measurement section of the slurry thickening system, the specific operations in the thickening process are the same as the operation of the thickening section of the slurry thickening system, and the specific operations in the determination process are the same as the operation of the determination section of the slurry thickening system.
- the slurry thickening method may also include a dilution step in which the amount of diluent determined in the determination step is added to the thickened slurry to obtain a diluted slurry.
- the specific operations in the dilution step are the same as those in the dilution section of the slurry thickening system.
- the manufacturing system for sintered ore raw material particles includes a measurement unit that measures the concentration of solid matter in the pre-thickening slurry, a thickening unit that obtains a thickened slurry having an increased concentration of solid matter from the pre-thickening slurry, a determination unit that determines the amount of diluent to be added to the thickened slurry based on the concentration of solid matter in the pre-thickening slurry measured in the measurement unit or determines the thickening conditions in the thickening unit, a dilution unit that adds diluent to the thickened slurry to obtain a diluted slurry, and a granulation unit that adds the diluted slurry to iron ore powder to granulate pre-sintered particles.
- the measurement section, thickening section, determination section and dilution section are the same as the measurement section, thickening section, determination section and dilution section in the slurry thickening system, respectively.
- the granulation section is not particularly limited as long as it can add diluted slurry to iron ore powder and granulate pre-sintered particles, but for example, a drum mixer can be used. Also, a device that adds diluted slurry to iron ore powder, kneads and mixes it (such as a Lödige mixer) in combination with a device that granulates the powder (such as a disk pelletizer or pan pelletizer) can be used.
- additives such as powdered auxiliary raw materials such as limestone, silica, and serpentine, powdered miscellaneous raw materials such as dust, scale, and return ore, and solid fuels such as powdered coke may also be added.
- the method for producing sintered ore raw material particles includes a measurement step for measuring the concentration of solid matter in a pre-thickening slurry, a concentration step for obtaining a thickened slurry having an increased concentration of solid matter from the pre-thickening slurry, a determination step for determining the amount of diluent to be added to the thickened slurry based on the concentration of solid matter in the pre-thickening slurry measured in the measurement step or for determining the concentration conditions in the concentration step, a dilution step for adding a diluent to the thickened slurry to obtain a diluted slurry, and a granulation step for adding the diluted slurry to iron ore powder to granulate pre-sintered particles.
- Such a method for producing sintered ore raw material particles can be carried out, for example, by using the above-mentioned production system for sintered ore raw material particles.
- the specific operations in the measurement process are the same as those in the measurement section of the slurry thickening system
- the specific operations in the thickening process are the same as those in the thickening section of the slurry thickening system
- the specific operations in the determination process are the same as those in the determination section of the slurry thickening system
- the specific operations in the dilution process are the same as those in the dilution section of the slurry thickening system.
- the specific operations in the granulation process are the same as those in the granulation section of the production system for sintered ore raw material particles.
- the sintered ore manufacturing system of this embodiment includes a measurement unit that measures the concentration of solid substances in a pre-thickening slurry, a thickening unit that obtains a thickened slurry having an increased concentration of solid substances from the pre-thickening slurry, a determination unit that determines the amount of diluent to be added to the thickened slurry based on the concentration of solid substances in the pre-thickening slurry measured in the measurement unit or determines the thickening conditions in the thickening unit, a dilution unit that adds diluent to the thickened slurry to obtain a diluted slurry, a granulation unit that adds the diluted slurry to iron ore powder to granulate pre-sintered particles, and a sintering unit that sinters the pre-sintered particles.
- the measurement section, thickening section, determination section, and dilution section are the same as the measurement section, thickening section, determination section, and dilution section in the slurry thickening system, respectively.
- the granulation section is the same as the granulation section in the sintered ore raw material particle manufacturing system.
- the sintering section is not particularly limited as long as it can sinter the pre-sintered particles, but for example, a sintering furnace can be used. Specifically, this sintering section stacks the pre-sintered particles on a movable pallet, then ignites the upper surface of the stacked raw material, and oxidizes the coke and other materials while drawing air from above to below the stacked raw material, and uses the heat generated during oxidation to produce sintered ore.
- the method for producing sintered ore includes a measuring step for measuring the concentration of solid substances in a pre-thickened slurry, a thickening step for obtaining a thickened slurry having an increased concentration of solid substances from the pre-thickened slurry, a determining step for determining the amount of diluent to be added to the thickened slurry based on the concentration of solid substances in the pre-thickened slurry measured in the measuring step or for determining thickening conditions in the thickening step, a diluting step for adding diluent to the thickened slurry to obtain a diluted slurry, a granulating step for adding the diluted slurry to iron ore powder to granulate pre-sintered particles, and a sintering step for sintering the pre-sintered particles.
- Such a method for manufacturing sintered ore raw material particles can be carried out, for example, by using the above-mentioned manufacturing system for sintered ore raw material particles.
- the specific operations in the measurement process are the same as those in the measurement section of the slurry thickening system
- the specific operations in the thickening process are the same as those in the thickening section of the slurry thickening system
- the specific operations in the determination process are the same as those in the determination section of the slurry thickening system
- the specific operations in the dilution process are the same as those in the dilution section of the slurry thickening system.
- the specific operations in the granulation process are the same as those in the granulation section of the manufacturing system for sintered ore raw material particles.
- the specific operations in the sintering process are the same as those in the sintering section of the manufacturing system for sintered ore.
- Fig. 4 is a schematic diagram of the slurry thickening test system used in the examples.
- the slurry thickening test system 1C shown in Fig. 4 includes a pre-thickening slurry tank 6C, a pump 10C, a suspended solids concentration meter 2C, and a decanter 3C.
- the pre-thickened slurry is stored in a pre-thickened slurry tank 6C, and the pre-thickened slurry is transferred to a decanter 3C by a pump 10C.
- the pre-thickened slurry and the decanter 3C are connected by a pipe, and a suspended solids concentration meter 2C is placed in the middle of this pipe.
- the decanter 3C thickens the pre-thickened slurry to obtain a thickened slurry.
- Example 10 The solid matter concentration of the slurry before thickening was changed to 17 w/w%, 20 w/w%, 24 w/w%, 28 w/w%, and 33 w/w%, and the solid matter concentration of the thickened slurry and the amount generated per minute were measured. In each case, the amount of diluent required to make the thickened slurry 40% thick was calculated.
- Table 1 shows the solid matter concentration of the slurry before thickening and the readings of the suspended matter concentration meter 2C in the examples.
- Figure 5 is a plot of the reading of the suspended solids concentration meter 2C versus the solids concentration of the slurry before thickening.
- Table 2 also shows the concentration of solid matter in the slurry before thickening, the concentration of solid matter in the slurry after thickening, the mass of solid matter in the slurry after thickening, and the amount of dilution liquid required.
- FIG. 6 is a plot of the solids concentration of the thickened slurry versus the solids concentration of the slurry before thickening.
- FIG. 7 is a plot of the amount of solids in the thickened slurry versus the solids concentration of the slurry before thickening.
- FIG. 8 is a plot of the amount of diluent required versus the solids concentration of the slurry before thickening.
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Abstract
Description
もちろん、この限りではない。
本実施形態に係るスラリー濃化システムは、濃化前スラリーの固形物質の濃度を測定する測定部と、濃化前スラリーから、固形物質の濃度が高められた濃化後スラリーを得る濃化部と、測定部において測定した濃化前スラリーの固形物質の濃度に基づいて濃化後スラリーに添加する希釈液の量を決定するか、又は濃化部における濃化条件を決定する決定部とを備えるものである。
測定部2は、濃化前スラリーの固形物質の濃度を測定するものである。
濃化前スラリーは、本実施形態に係るスラリー濃化システムを用いて固形物質の濃度を高める対象としてのスラリーである。
濃化部3は、濃化前スラリーから、固形物質の濃度が高められた濃化後スラリーを得るものである。
決定部4は、上述した測定部において測定した濃化前スラリーの固形物質の濃度に基づいて濃化後スラリーに添加する希釈液の量を決定するか、又は濃化部における濃化条件を決定するものである。
一実施形態において、決定部4は、さらに、濃化前スラリーの固形物質の濃度と濃化後スラリーの固形物質の濃度及び/又は濃化後スラリーに添加する希釈液の量との関係を示す関係性モデルに基づいて、濃化後スラリーに添加する希釈液の量を決定する。
一実施形態において、決定部4は、さらに、濃化前スラリーの固形物質の濃度及び濃化前スラリーの固形物質の濃度と、濃化部における濃化条件との関係を示す関係性モデルに基づいて、濃化後スラリーに添加する希釈液の量を決定する。
希釈部5は、決定部4において決定した量の希釈液を濃化後スラリーに添加して希釈後スラリーを得るものである。
希釈液は、濃化後スラリーに添加することによってその中に含まれる固形物質の濃度を低下させるためのものである。
図2は、本実施形態に係るスラリー濃化システムの具体的な構成を説明するための図である。
図3は、本実施形態に係るスラリー濃化システムの他の具体的な構成を説明するための図である。
本実施形態に係るスラリー濃化方法は、濃化前スラリーの固形物質の濃度を測定する測定工程と、濃化前スラリーから、固形物質の濃度が高められた濃化後スラリーを得る濃化工程と、測定工程において測定した濃化前スラリーの固形物質の濃度に基づいて濃化後スラリーに添加する希釈液の量を決定するか。又は濃化工程における濃化条件を決定する決定工程とを備えるものである。
本実施形態に係る焼結鉱原料粒子の製造システムは、濃化前スラリーの固形物質の濃度を測定する測定部と、濃化前スラリーから、固形物質の濃度が高められた濃化後スラリーを得る濃化部と、測定部において測定した濃化前スラリーの固形物質の濃度に基づいて濃化後スラリーに添加する希釈液の量を決定するか、又は濃化部における濃化条件を決定する決定部と、濃化後スラリーに希釈液を添加して希釈後スラリーを得る希釈部と、鉄鉱石粉末に、希釈後スラリーを添加して焼結前粒子を造粒する造粒部とを備えるものである。
本実施形態に係る焼結鉱原料粒子の製造方法は、濃化前スラリーの固形物質の濃度を測定する測定工程と、濃化前スラリーから、固形物質の濃度が高められた濃化後スラリーを得る濃化工程と、測定工程において測定した濃化前スラリーの固形物質の濃度に基づいて濃化後スラリーに添加する希釈液の量を決定するか、又は濃化工程における濃化条件を決定する決定工程と、濃化後スラリーに希釈液を添加して希釈後スラリーを得る希釈工程と、鉄鉱石粉末に、希釈後スラリーを添加して焼結前粒子を造粒する造粒工程とを備えるものである。
本実施形態に係る焼結鉱の製造システムは、濃化前スラリーの固形物質の濃度を測定する測定部と、濃化前スラリーから、固形物質の濃度が高められた濃化後スラリーを得る濃化部と、測定部において測定した濃化前スラリーの固形物質の濃度に基づいて濃化後スラリーに添加する希釈液の量を決定するか、又は濃化部における濃化条件を決定する決定部と、濃化後スラリーに希釈液を添加して希釈後スラリーを得る希釈部と、鉄鉱石粉末に、希釈後スラリーを添加して焼結前粒子を造粒する造粒部と、焼結前粒子を焼結する焼結部とを備えるものである。
本実施形態に係る焼結鉱の製造方法は、濃化前スラリーの固形物質の濃度を測定する測定工程と、濃化前スラリーから、固形物質の濃度が高められた濃化後スラリーを得る濃化工程と、測定工程において測定した濃化前スラリーの固形物質の濃度に基づいて濃化後スラリーに添加する希釈液の量を決定するか、又は濃化工程における濃化条件を決定する決定工程と、濃化後スラリーに希釈液を添加して希釈後スラリーを得る希釈工程と、鉄鉱石粉末に、希釈後スラリーを添加して焼結前粒子を造粒する造粒工程と、焼結前粒子を焼結する焼結工程とを備えるものである。
〔実験装置〕
図4に示すスラリー濃化試験システムを構築した。図4は、実施例で用いたスラリー濃化試験システムの概略図である。具体的に、図4に示されるスラリー濃化試験システム1Cは、濃化前スラリー槽6C、ポンプ10C、懸濁物質濃度計2C及びデカンター3Cを備えるものである。
(濃化前スラリー槽6C)
・SUSタンク 200L
・付属攪拌機KP-4003
(ポンプ10C)
・兵神装備株式会社製 ヘイシンモーノポンプNHL15 PUN
(懸濁物質濃度計2C)
・ナノグレイ株式会社製 ガンマ線濃度計PH-1100A
(デカンター3C)
・巴工業株式会社製 デカンタ型遠心脱水機PTM006
・遠心力 1500G
・差速 40Δmin-1
・ダム高さ #4(最高高さ)
・供給量 300L/h
(実施例)
濃化前スラリーの固形物質の濃度を、17w/w%、20w/w%、24w/w%、28w/w%及び33w/w%に変化させて、濃化後スラリーの固形物質の濃度と1分間当たりの発生量を測定した。また、それぞれの場合において、濃化後スラリーの40%濃化スラリーとするために必要な希釈液の量を算出した。
(実施例)
表1に、実施例における濃化前スラリーの固形物質の濃度及び懸濁物質濃度計2Cの表示値を示す。
1C スラリー濃化試験システム
2 測定部
2A,2B,2C,14A,14B 懸濁物質濃度計
3 濃化部
3A,3B,3C デカンター
4 決定部
4A,4B 演算・制御装置
5 希釈部
5A,5B バルブ
6A,6B、6C 濃化前スラリー槽
7A,7B 希釈液槽
8A,8B 分離水槽
9A,9B 希釈後スラリー槽
10A,10B,10C,11A,11B,12A,12B,13A,13B ポンプ
Claims (13)
- スラリー濃化システムであって、
濃化前スラリーの固形物質の濃度を測定する測定部と、
前記濃化前スラリーから、固形物質の濃度が高められた濃化後スラリーを得る濃化部と、
前記測定部において測定した濃化前スラリーの固形物質の濃度に基づいて前記濃化後スラリーに添加する希釈液の量を決定するか、又は前記濃化部における濃化条件を決定する決定部とを備える
スラリー濃化システム。 - 請求項1に記載のスラリー濃化システムにおいて、
前記決定部は、さらに、前記濃化前スラリーの固形物質の濃度と前記濃化後スラリーの固形物質の濃度及び/又は前記濃化後スラリーに添加する希釈液の量との関係を示す関係性モデルに基づいて、前記濃化後スラリーに添加する希釈液の量を決定する
スラリー濃化システム。 - 請求項1又は請求項2に記載のスラリー濃化システムにおいて、
前記濃化部として、遠心分離装置を用いる
スラリー濃化システム。 - 請求項1~請求項3のいずれか1項に記載のスラリー濃化システムにおいて、
前記測定部として、放射式γ線濃度計及び/又は超音波濃度計を用いる
スラリー濃化システム。 - 請求項1~請求項4のいずれか1項に記載のスラリー濃化システムにおいて、
前記濃化前スラリーは、固形物質として製鉄所で発生する鉄化合物を含む
スラリー濃化システム。 - 請求項1~請求項4のいずれか1項に記載のスラリー濃化システムにおいて、
前記濃化前スラリーは、製鉄所の製鋼スラリーを含む
スラリー濃化システム。 - 請求項5又は請求項6に記載のスラリー濃化システムにおいて、
前記決定部において決定した量の前記希釈液を前記濃化後スラリーに添加して希釈後スラリーを得る希釈部をさらに備える
スラリー濃化システム。 - 請求項7に記載のスラリー濃化システムにおいて、
前記希釈後スラリーは、製鉄所の鉄鉱石造粒において造粒改善に用いるためのものである
スラリー濃化システム。 - スラリー濃化方法であって、
濃化前スラリーの固形物質の濃度を測定する測定工程と、
前記濃化前スラリーから、固形物質の濃度が高められた濃化後スラリーを得る濃化工程と、
前記測定工程において測定した濃化前スラリーの固形物質の濃度に基づいて前記濃化後スラリーに添加する希釈液の量を決定するか、又は前記濃化工程における濃化条件を決定する決定工程とを備える
スラリー濃化方法。 - 焼結鉱原料粒子の製造システムであって、
濃化前スラリーの固形物質の濃度を測定する測定部と、
前記濃化前スラリーから、固形物質の濃度が高められた濃化後スラリーを得る濃化部と、
前記測定部において測定した濃化前スラリーの固形物質の濃度に基づいて前記濃化後スラリーに添加する希釈液の量を決定するか、又は前記濃化部における濃化条件を決定する決定部と、
前記濃化後スラリーに前記希釈液を添加して希釈後スラリーを得る希釈部と、
鉄鉱石粉末に、前記希釈後スラリーを添加して焼結前粒子を造粒する造粒部とを備える
焼結鉱原料粒子の製造システム。 - 焼結鉱原料粒子の製造方法であって、
濃化前スラリーの固形物質の濃度を測定する測定工程と、
前記濃化前スラリーから、固形物質の濃度が高められた濃化後スラリーを得る濃化工程と、
前記測定工程において測定した濃化前スラリーの固形物質の濃度に基づいて前記濃化後スラリーに添加する希釈液の量を決定するか、又は前記濃化工程における濃化条件を決定する決定工程と、
前記濃化後スラリーに前記希釈液を添加して希釈後スラリーを得る希釈工程と、
鉄鉱石粉末に、前記希釈後スラリーを添加して焼結前粒子を造粒する造粒工程とを備える
焼結鉱原料粒子の製造方法。 - 焼結鉱の製造システムであって、
濃化前スラリーの固形物質の濃度を測定する測定部と、
前記濃化前スラリーから、固形物質の濃度が高められた濃化後スラリーを得る濃化部と、
前記測定部において測定した濃化前スラリーの固形物質の濃度に基づいて前記濃化後スラリーに添加する希釈液の量を決定するか、又は前記濃化部における濃化条件を決定する決定部と、
前記濃化後スラリーに前記希釈液を添加して希釈後スラリーを得る希釈部と、
鉄鉱石粉末に、前記希釈後スラリーを添加して焼結前粒子を造粒する造粒部と、
前記焼結前粒子を焼結する焼結部とを備える
焼結鉱の製造システム。 - 焼結鉱の製造方法であって、
濃化前スラリーの固形物質の濃度を測定する測定工程と、
前記濃化前スラリーから、固形物質の濃度が高められた濃化後スラリーを得る濃化工程と、
前記測定工程において測定した濃化前スラリーの固形物質の濃度に基づいて前記濃化後スラリーに添加する希釈液の量を決定するか、又は前記濃化工程における濃化条件を決定する決定工程と、
前記濃化後スラリーに前記希釈液を添加して希釈後スラリーを得る希釈工程と、
鉄鉱石粉末に、前記希釈後スラリーを添加して焼結前粒子を造粒する造粒工程と、
前記焼結前粒子を焼結する焼結工程とを備える
焼結鉱の製造方法。
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| JPS5111016A (ja) * | 1974-06-13 | 1976-01-28 | Kennecott Copper Corp | |
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| JP2004306023A (ja) * | 2003-03-24 | 2004-11-04 | Nippon Steel Corp | 脱水物の成形方法 |
| JP2009091643A (ja) * | 2007-10-12 | 2009-04-30 | Jfe Steel Kk | 製鉄ダストの処理方法 |
| JP2023018640A (ja) * | 2021-07-27 | 2023-02-08 | Jfeスチール株式会社 | 製鉄ダスト集塵水の濃化処理方法および焼結用造粒原料の製造方法 |
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| WO2007046050A1 (en) | 2005-10-17 | 2007-04-26 | Multotec Process Equipment (Pty) Limited | Spiral separator and control system |
| KR102181412B1 (ko) | 2018-12-03 | 2020-11-23 | 주식회사 레미 | 비가연성 친환경 냉매 |
| US12286686B2 (en) | 2021-02-24 | 2025-04-29 | Sherritt International Corporation | Co-processing of copper sulphide concentrate with nickel laterite ore |
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- 2023-10-06 CN CN202380074986.4A patent/CN120112664A/zh active Pending
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5111016A (ja) * | 1974-06-13 | 1976-01-28 | Kennecott Copper Corp | |
| JP2002285254A (ja) * | 2001-03-28 | 2002-10-03 | Sumitomo Metal Mining Co Ltd | 酸化亜鉛焼鉱または酸化亜鉛団鉱の製造方法 |
| JP2004306023A (ja) * | 2003-03-24 | 2004-11-04 | Nippon Steel Corp | 脱水物の成形方法 |
| JP2009091643A (ja) * | 2007-10-12 | 2009-04-30 | Jfe Steel Kk | 製鉄ダストの処理方法 |
| JP2023018640A (ja) * | 2021-07-27 | 2023-02-08 | Jfeスチール株式会社 | 製鉄ダスト集塵水の濃化処理方法および焼結用造粒原料の製造方法 |
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