WO2024044906A1 - Vacuum-encapsulated semiconductor chip and manufacturing method therefor - Google Patents

Vacuum-encapsulated semiconductor chip and manufacturing method therefor Download PDF

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Publication number
WO2024044906A1
WO2024044906A1 PCT/CN2022/115575 CN2022115575W WO2024044906A1 WO 2024044906 A1 WO2024044906 A1 WO 2024044906A1 CN 2022115575 W CN2022115575 W CN 2022115575W WO 2024044906 A1 WO2024044906 A1 WO 2024044906A1
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vacuum
cathode
substrate
semiconductor chip
anode
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PCT/CN2022/115575
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French (fr)
Chinese (zh)
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罗志鹏
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华为技术有限公司
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Priority to PCT/CN2022/115575 priority Critical patent/WO2024044906A1/en
Publication of WO2024044906A1 publication Critical patent/WO2024044906A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J1/00Details of electrodes, of magnetic control means, of screens, or of the mounting or spacing thereof, common to two or more basic types of discharge tubes or lamps
    • H01J1/02Main electrodes
    • H01J1/30Cold cathodes, e.g. field-emissive cathode
    • H01J1/304Field-emissive cathodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J9/00Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
    • H01J9/02Manufacture of electrodes or electrode systems

Definitions

  • the present application relates to the field of vacuum packaging technology, and in particular, to a vacuum-packaged semiconductor chip and a manufacturing method thereof.
  • Vacuum electron tubes have good performance and efficiency, and can prepare nanoscale vacuum electronic structures through micro-nano processing technology to solve the problems of large size and high voltage.
  • a vacuum micro-nano electron tube in the related art includes a cathode and an anode, and there is an interelectrode vacuum channel between the cathode and the anode. Under the action of the electric field, electrons are emitted from the cathode and reach the anode through the interelectrode vacuum channel, thereby forming an electric current. The electrons form ballistic transport during conduction in the interpolar vacuum channel, which does not reduce efficiency due to collisions between electrons and atoms in semiconductors. Moreover, the nanoscale inter-electrode vacuum channel can significantly reduce the operating voltage of vacuum micro-nano electron tubes. At the same time, in the nanoscale inter-electrode vacuum channel, the number of gas particles is extremely small, which can reduce the requirements for vacuum packaging.
  • both the cathode and the anode need to be disposed on the substrate through a dielectric layer. Affected by parameters such as dielectric layer material, thickness, and manufacturing process, the dielectric layer cannot guarantee to provide excellent insulation properties for vacuum micro-nano electron tubes, resulting in a certain leakage current of vacuum micro-nano electron tubes on the substrate.
  • the inter-electrode vacuum channel in the vacuum micro-nano electron tube needs to be produced using processes such as electron beam lithography or ion beam etching.
  • electron beam lithography or ion beam etching processes cannot be used for mass production and manufacturing, so vacuum micro-nano electron tubes cannot be integrated into the manufacturing process.
  • Embodiments of the present application provide a vacuum-encapsulated semiconductor chip and a manufacturing method thereof, which can solve the problem in the prior art that vacuum micro-nano electron tubes have leakage current on the substrate and cannot be integratedly manufactured.
  • the present application provides a vacuum-encapsulated semiconductor chip.
  • the semiconductor chip can be a discrete device, such as a vacuum diode, a vacuum triode, etc., or an integrated chip made of multiple discrete devices and vacuum-packaged, or a chip that is vacuum-packaged with other chips and circuits, such as It has functional chips such as power conversion and signal processing.
  • a semiconductor chip includes one or more (multiple refers to two or more) semiconductor devices.
  • the semiconductor device includes a substrate, a plurality of insulating supports, a cathode structure and an anode structure. Wherein, a plurality of insulating support parts are arranged on the substrate in the same layer and at intervals.
  • the cathode structure is disposed on one or more insulating supports. Moreover, the cathode structure is only provided on part of the insulating support parts, not all of the insulating support parts. A part of the anode structure is disposed on one or more of the remaining insulating supports, and another part of the anode structure is disposed suspended above the cathode structure, so that a vacuum gap is formed between the anode structure and the cathode structure. Therefore, the semiconductor device is a vacuum semiconductor device (such as a vacuum electron tube).
  • the anode structure by designing the anode structure to be suspended above the cathode structure, only part of the anode structure is disposed on the substrate through the insulating support part, and the remaining parts of the anode structure are spaced apart from the substrate. Therefore, some areas of the anode structure can be vacuum isolated from the substrate, reducing the contact area between the anode structure and the substrate. Therefore, the insulation of the semiconductor device is improved and the leakage current on the substrate is reduced.
  • the vacuum gap between the anode structure and the cathode structure can be formed by making a sacrificial layer using the existing complementary metal oxide semiconductor (COMS) process, thereby enabling the integrated production of vacuum-encapsulated semiconductor devices.
  • COMPOS complementary metal oxide semiconductor
  • the above-mentioned cathode structure includes a cathode array, and the cathode array is formed by an array arrangement of a plurality of electron emitting parts. Furthermore, the plurality of electron emission parts and the anode structure are arranged opposite to each other. A cathode array having a plurality of electron emitting parts has more electron emitting positions, thereby increasing the total current of the cathode structure. Moreover, the cathode structure has a small area and a compact structure.
  • the cathode structure further includes a connecting portion, and the connecting portion is disposed on the insulating support portion. Furthermore, the connecting portion is connected to the plurality of electron-emitting portions in the cathode array, so that the cathode array is suspended above the substrate.
  • the connection part can serve as a support structure for multiple electron emitting parts in the cathode array, so that the multiple electron emitting parts can be completely suspended on the substrate, thereby reducing the contact area between the cathode array and the substrate.
  • the cathode array can be vacuum isolated from the substrate. As a result, the insulation of the semiconductor device is further improved and leakage problems are reduced.
  • the electron emitting part may emit electrons in a linear emission or angular emission manner. Therefore, the electron emitting part in the embodiment of the present application may be in a long strip shape, or may be in a shape composed of multiple circles or multiple rounded rectangles connected in sequence, or may be in a serpentine coiled shape, etc. All three shapes achieve line emission of electrons. In some embodiments, the above-mentioned electron emitting part may be in a shape composed of multiple triangles connected in sequence, and this shape can realize emitting electrons in an angular emission manner. Thus, different physical property requirements for cathode structures are met.
  • the above-mentioned cathode structure may also include only one electron emitting part.
  • the electron emission part may be arranged in a serpentine shape above the substrate, and a part of the electron emission part may be arranged on the insulating support part.
  • the electron-emitting part coiled in a serpentine shape has more emission sites and a larger emission current, and is suspended on the substrate and has less leakage current on the substrate.
  • the electron emitting part may also be directly wound around an insulating support part.
  • the above-mentioned semiconductor device includes an anode support part, and the anode support part is disposed between the insulating support part and the anode structure.
  • adding an anode support part can reduce the thickness of the anode structure that needs to be manufactured.
  • the above-mentioned anode support part and the cathode structure are made of the same layer and the same material. Therefore, the anode support part and the cathode structure can be manufactured through a patterning process, and the process flow is simple.
  • the semiconductor device in the above embodiment is a vacuum diode, and the semiconductor device in the embodiment of the present application can also be used to make a vacuum triode.
  • the above-mentioned semiconductor device further includes a gate structure, and the gate structure is disposed on the substrate.
  • the gate structure is in the same layer as the cathode structure and is spaced apart, and is diffracted outside the cathode structure. Therefore, the semiconductor device is a vacuum triode.
  • the electric field strength of the cathode structure can be modulated by applying different voltages to the gate structure in the vacuum triode.
  • the emission intensity of the electron flow in the cathode structure is changed.
  • the magnitude and switching of the current in the semiconductor device are controlled.
  • the gate structure in the above-mentioned semiconductor device can also exchange positions with the cathode structure.
  • the gate structure is suspended on the substrate, while the cathode structure is directly placed on the substrate.
  • the semiconductor chip includes a plurality of semiconductor devices, and a plurality of semiconductor device arrays are arranged on the substrate.
  • the semiconductor chip can produce multiple semiconductor devices with vertical cathode structures and anode structures on a substrate through existing CMOS processes, thereby improving the integration of vacuum-encapsulated semiconductor devices.
  • the vacuum gap between the cathode structure and the anode structure in multiple vacuum-packaged semiconductor devices can be precisely controlled through the same atomic layer deposition (ALD) process.
  • ALD atomic layer deposition
  • embodiments of the present application also include a method for manufacturing a vacuum-encapsulated semiconductor chip.
  • the manufacturing method includes the following steps: obtaining a substrate with a cathode material layer, an insulating layer, and a substrate stacked sequentially from top to bottom.
  • a cathode structure is formed on the layer of cathode material in the substrate.
  • a sacrificial portion for supporting the suspended region of the anode structure is formed on the cathode structure and the insulating layer.
  • An anode structure is formed above the sacrificial portion.
  • the sacrificial part is removed to obtain a cathode structure, an anode structure suspended on the cathode structure, and a vacuum gap between the anode structure and the cathode structure. Partial areas of the insulating layer are removed to obtain multiple insulating support parts.
  • the manufacturing method of the embodiment of the present application can realize the manufacturing of the vacuum-encapsulated semiconductor chip in the above embodiment. Among them, by arranging the sacrificial part, the fabrication of the suspended anode structure and the fabrication of the vacuum gap between the anode structure and the cathode structure are realized.
  • forming the sacrificial portion corresponding to the suspended area of the anode structure on the cathode structure and the insulating layer specifically includes: forming a first sacrificial layer on the layer where the cathode structure is located through a spin coating process and a polishing process.
  • a second sacrificial layer is formed on the first sacrificial layer and the cathode structure through an atomic layer deposition process.
  • a sacrificial portion for supporting the suspended region of the anode structure is formed on the second sacrificial layer through a photolithography process.
  • the atomic layer deposition process can precisely control the material composition and morphology of the second sacrificial layer at the nanometer scale, thereby accurately controlling the vacuum gap between the anode structure and the cathode structure.
  • removing a portion of the insulating layer to obtain a plurality of insulating support portions includes: removing a portion of the insulating layer below the cathode structure to obtain a suspended cathode structure.
  • forming the cathode structure on the cathode material layer in the substrate specifically includes: forming the cathode structure and the anode support part on the cathode material layer in the substrate through a photolithography process.
  • the cathode structure and the anode support part can be manufactured using the same photolithography process, and the process flow is simple.
  • the above-mentioned substrate can be obtained directly, or can be produced through special processing technology. Therefore, in some embodiments, the above-mentioned substrate is an SOI (silicon-on-insulator, silicon on insulating substrate) substrate.
  • SOI silicon-on-insulator, silicon on insulating substrate
  • the SOI substrate can be obtained directly without using multiple processing techniques to manufacture, reducing the processing flow.
  • the above-mentioned obtaining of a substrate having a cathode material layer, an insulating layer, and a substrate that are stacked sequentially from top to bottom specifically includes: obtaining the substrate.
  • a gate structure is formed on the substrate.
  • An insulating layer is formed above the substrate, above the gate structure and on the sidewalls.
  • a layer of cathode material is formed on the insulating layer. The above manufacturing steps can first form a gate structure on the substrate, so that the vacuum triode can be manufactured.
  • forming the anode structure above the sacrificial part specifically includes: forming the anode structure above the sacrificial part through a lift-off process.
  • the anode structure adopts a peel-off process, which can save the etching step and reduce the production cost of vacuum-encapsulated semiconductor chips.
  • Figure 1 is a schematic three-dimensional structural diagram of a semiconductor chip according to an embodiment of the present application.
  • Figure 2 is a schematic cross-sectional view of a semiconductor chip in related art 1;
  • Figure 3 is a schematic three-dimensional structural diagram of a semiconductor device in a semiconductor chip according to an embodiment of the present application
  • Figure 4 is a cross-sectional view along line A-A in Figure 3;
  • Figure 5 is a current-voltage characteristic diagram in a linear coordinate system in which the semiconductor device in the semiconductor chip of the embodiment of the present application is a vacuum micro-nano diode;
  • Figure 6 is a current-voltage characteristic diagram in a logarithmic coordinate system in which the semiconductor device in the semiconductor chip of the embodiment of the present application is a vacuum micro-nano diode;
  • FIG. 7 is a schematic structural diagram of a cathode structure of a semiconductor device including multiple elongated electron emission parts in a semiconductor chip according to an embodiment of the present application;
  • FIG. 8 is a schematic structural diagram of a semiconductor device having a cathode structure with multiple elongated electron emission parts in a semiconductor chip according to an embodiment of the present application;
  • Figure 9 is a schematic structural diagram of a cathode structure in which a semiconductor device in a semiconductor chip according to an embodiment of the present application includes a plurality of electron-emitting portions composed of a plurality of circles connected in sequence;
  • Figure 10 is a schematic structural diagram of a cathode structure in which a semiconductor device in a semiconductor chip according to an embodiment of the present application includes a plurality of electron-emitting portions composed of a plurality of rounded rectangles connected in sequence;
  • Figure 11 is a schematic structural diagram of a cathode structure in which a semiconductor device in a semiconductor chip according to an embodiment of the present application includes a plurality of electron-emitting portions composed of multiple triangles connected in sequence;
  • Figure 12 is a perspective view of a semiconductor device having multiple electron emitting parts arranged in a rectangular array in a semiconductor chip according to an embodiment of the present application;
  • Figure 13 is a perspective view of a semiconductor device having multiple electron emitting parts arranged in a circular array in a semiconductor chip according to an embodiment of the present application;
  • Figure 14 is a perspective view of a semiconductor device having a serpentine coiled electron emission portion integrally disposed on an insulating support portion in a semiconductor chip according to an embodiment of the present application;
  • Figure 15 is a perspective view of a semiconductor device having a serpentine coiled electron emission portion partially disposed on an insulating support portion in the semiconductor chip according to the embodiment of the present application;
  • Figure 16 is a schematic structural diagram of a semiconductor device with an anode support part in a semiconductor chip according to an embodiment of the present application
  • Figure 17 is a schematic diagram of the B-B cross-section in Figure 16.
  • Figure 18 is a schematic structural diagram of a semiconductor device with an anode structure in which the area opposite to the cathode structure 2 is recessed downward in the semiconductor chip according to the embodiment of the present application;
  • Figure 19 is a schematic cross-sectional view of C-C in Figure 18;
  • Figure 20 is a schematic three-dimensional structural diagram of a semiconductor chip with multiple vacuum micro-nano diodes according to an embodiment of the present application
  • Figure 21 is a top view of a semiconductor chip with multiple vacuum micro-nano diodes according to an embodiment of the present application.
  • Figure 24 is a schematic structural diagram of a semiconductor chip with an anode structure supported by a second sacrificial portion in an embodiment of the present application;
  • Figure 26 is a schematic three-dimensional structural diagram of a vacuum triode as the semiconductor device in the semiconductor chip according to the embodiment of the present application;
  • Figure 27 is a schematic diagram of the D-D cross-section in Figure 26;
  • Figure 28 is an output characteristic diagram of a vacuum micro-nano transistor in which the semiconductor device in the semiconductor chip according to the embodiment of the present application is at different gate voltages;
  • Figure 29 is a transfer characteristic diagram of a vacuum micro-nano transistor where the semiconductor device in the semiconductor chip according to the embodiment of the present application;
  • Figure 30 is a schematic cross-sectional view of a semiconductor device with a suspended cathode structure in a semiconductor chip according to an embodiment of the present application
  • Figure 31 is a partial structural schematic diagram of a vacuum micro-nano triode with multiple circular electron-emitting parts in a semiconductor chip according to an embodiment of the present application;
  • Figure 32 is a partial structural schematic diagram of a vacuum micro-nano triode with multiple rounded rectangular electron emission parts in a semiconductor chip according to an embodiment of the present application;
  • Figure 33 is a partial structural schematic diagram of a vacuum micro-nano triode with multiple triangular electron-emitting parts in a semiconductor chip according to an embodiment of the present application;
  • Figure 34 is a partial structural schematic diagram of a vacuum micro-nano triode with a serpentine coiled electron emission part in a semiconductor chip according to an embodiment of the present application;
  • Figure 35 is a schematic three-dimensional structural diagram of a semiconductor chip with multiple vacuum micro-nano transistors according to an embodiment of the present application.
  • Figure 36 is a top view of a semiconductor chip with multiple vacuum micro-nano transistors according to an embodiment of the present application.
  • Figure 37 is a schematic cross-sectional view of a semiconductor chip in related art 2;
  • 1000-semiconductor chip 100-semiconductor device, 1-substrate, 10-base, 01-dielectric layer, 2-cathode structure, 20-cathode material layer, 21-cathode array, 211-electron emission part, 22, 22a , 22b-connection part, 3-anode structure, 4-insulation support part, 40, 40a, 40b-insulation layer, 5-anode support part, 6-gate structure, 7-sacrificial part, 71-first sacrificial part, 72a-transitional sacrificial part, 72-second sacrificial part, 701, 701a-first sacrificial layer, 702-second sacrificial layer, 703-third sacrificial layer, 101, 102, 103-photoresist pattern.
  • At least one (item) refers to one or more, and “plurality” refers to two or more.
  • “And/or” is used to describe the relationship between associated objects, indicating that there can be three relationships. For example, “A and/or B” can mean: only A exists, only B exists, and A and B exist simultaneously. , where A and B can be singular or plural. The character “/” generally indicates that the related objects are in an "or” relationship. “At least one of the following” or similar expressions thereof refers to any combination of these items, including any combination of a single item (items) or a plurality of items (items).
  • At least one of a, b or c can mean: a, b, c, "a and b", “a and c", “b and c", or "a and b and c” ”, where a, b, c can be single or multiple.
  • Embodiments of the present application include a vacuum-encapsulated semiconductor chip.
  • the semiconductor chip can be a discrete device, such as a vacuum diode, a vacuum triode, etc., or it can be an integrated chip made of multiple discrete devices and vacuum-packaged, or it can be a chip mold that is vacuum-packaged with other chips and circuits. Groups, such as functional element chips with power conversion, signal processing, etc.
  • the semiconductor chip of the embodiment of the present application may include only one semiconductor device.
  • the semiconductor chip in the embodiment of the present application includes multiple semiconductor devices.
  • the semiconductor device 100 includes a substrate 1, a cathode structure 2 and an anode structure 3.
  • the substrate 1 can be any one of intrinsic semiconductor material, reverse PN junction or insulating material.
  • Both the cathode structure 2 and the anode structure 3 can be made of any one of single crystal silicon, metal materials, N-type semiconductor materials, polycrystalline silicon, etc.
  • the work function or Fermi level can be adjusted by selecting appropriate electrode materials or doping the semiconductor electrode, thereby adjusting different cathode structures 2
  • the difficulty of electrons escaping increases the one-way conductivity of the semiconductor device 100 and reduces the operating voltage of the semiconductor device 100 .
  • the plane of the substrate 1 shown in Figure 1 can be an XY plane.
  • the X axis can be the length direction of the substrate 1
  • the Y axis can be the length direction of the substrate 1.
  • the Z-axis is perpendicular or approximately perpendicular to the substrate 1 within the manufacturing tolerance range. It can be understood that the width dimension of the substrate 1 is smaller than the length dimension of the substrate 1 .
  • the cathode structure 2 and the anode structure 3 are arranged on the same layer and are both arranged on the substrate 1 through the dielectric layer 01, the dielectric layer will be affected by the material, thickness, manufacturing process and other parameters of the dielectric layer 01. Layer 01 cannot guarantee good insulation properties between cathode structure 2, anode structure 3 and substrate 1. Therefore, the cathode structure 2 and the anode structure 3 will have a certain leakage current on the substrate 1 .
  • the semiconductor device 100 in the embodiment of the present application also includes a plurality of insulating support parts 4 as shown in FIG. 3 .
  • the plurality of insulating support parts 4 are arranged in the same layer and spaced apart on the substrate 1 .
  • the insulating support part 4 can be made of SiO 2 material.
  • the above-mentioned cathode structure 2 is provided on one or more of the above-mentioned insulating supports 4 .
  • the cathode structure 2 is only provided on some of the above-mentioned insulating support parts 4 , rather than on all of the insulating support parts 4 .
  • a part of the anode structure 3 is disposed on the remaining part of the insulating support part 4 as the support area of the anode structure 3 .
  • Another part of the anode structure 3 is suspended above the cathode structure 2, so that a vacuum gap ⁇ as shown in Figure 4 is formed between the anode structure 3 and the cathode structure 2.
  • the anode structure 3 and the cathode structure 2 are vertical structures.
  • the cathode structure 2 is grounded, and when a positive voltage is applied to the anode structure 3, a certain electric field is generated on the surface of the cathode structure 2. When the electric field is strong enough, electrons escape from the cathode structure 2 and reach the anode structure 3 to generate current. Thus, the function of a vacuum electron tube is realized.
  • the semiconductor chip 1000 is vacuum-packaged, only part of the anode structure 3 is disposed on the substrate 1 through the insulating support part 4 , and other parts of the anode structure 3 are suspended above the cathode structure 2 . Therefore, the partial area provided in the air on the anode structure 3 can be isolated from the substrate 1 by vacuum, thereby reducing the contact area between the anode structure 3 and the substrate 1 .
  • the insulating properties of vacuum are better than those of dielectric layer 01. Therefore, the insulation performance of the semiconductor device 100 can be improved, and the leakage current on the substrate 1 can be reduced.
  • the plurality of insulating support portions 4, cathode structures 2 and anode structures 3 in the semiconductor device 100 in the embodiment of the present application can all be integrated and manufactured using the existing COMS process.
  • the vertical structure of the anode structure 3 and the cathode structure 2 can enable more semiconductor devices 100 to be integrated on the same area of the substrate 1, thereby increasing the integration level of the semiconductor chip 1000.
  • the suspended anode structure 3 can be formed by making a sacrificial layer. Therefore, the semiconductor device 100 can be manufactured at the nanoscale, that is, the semiconductor device 100 is a vacuum micro-nano electron tube.
  • the vacuum micro-nano electron tube having only the cathode structure 2 and the anode structure 3 is a vacuum micro-nano diode.
  • Figure 5 shows the current-voltage relationship of a vacuum micro-nano diode in linear coordinates.
  • Figure 6 shows the current-voltage relationship of a vacuum micro-nano diode in logarithmic coordinates. It can be seen from Figure 5 that in linear coordinates, the relationship between the current and voltage of the vacuum micro-nano diode is super linear. As can be seen from Figure 6, in logarithmic coordinates, the relationship between current and voltage is between the exponential relationship and the linear straight-line relationship.
  • the above-mentioned cathode structure 2 may be directly disposed on the substrate as shown in FIG. 3 , or may be disposed partially on the substrate 1 as shown in FIG. 7 . Therefore, the cathode structure 2 shown in Figure 7 is suspended on the substrate 1, which reduces the contact area between the cathode structure 2 and the substrate 1.
  • the cathode structure 2 can also be isolated from the substrate 1 in a vacuum. Therefore, the insulation of the semiconductor device 100 is further improved and leakage problems are reduced.
  • the cathode structure 2 in the above-mentioned vacuum micro-nano electron (diode) tube can be made into a variety of structures.
  • the accumulation of the electric field in the cathode structure 2 can be changed, thereby changing the electrical properties of the semiconductor device 100. performance. This application does not limit this.
  • the cathode structure 2 is suspended on the substrate 1 for illustration below.
  • the cathode structure 2 includes a cathode array 21 , and the cathode array 21 is formed by an array arrangement of a plurality of electron emitting parts 211 . Furthermore, the plurality of electron emission parts 211 and the anode structure 3 are arranged opposite to each other.
  • the cathode array 21 having multiple electron emitting parts 211 has a longer side length and more electron emitting positions, thereby increasing the total current of the cathode structure 2 .
  • the cathode structure 2 has a small area, compact structure, and high processing output.
  • the above-mentioned cathode structure 2 further includes a connection part 22 as shown in FIG. 7 , and the connection part 22 is connected to the plurality of electron emission parts 211 in the cathode array 21 .
  • the connection part 22 is directly provided on the insulating support part 4, and the connection part 22 can be used as a support structure of the cathode structure 2, as shown in Figure 8, so that the plurality of electron emission parts 211 in the cathode array 21 are suspended on the substrate. above 1. Therefore, the plurality of electron emission parts 211 can be completely suspended on the substrate 1 , thereby reducing the contact area between the cathode structure 2 and the substrate 1 .
  • the plurality of electron emission parts 211 may be vacuum isolated from the substrate 1 . Therefore, the insulation of the semiconductor device 100 is further improved and leakage problems are reduced.
  • the electron emission part 211 in the above-mentioned cathode array 21 can be designed to have a shape with sharp edges and corners, so that electrons can easily escape from the cathode structure 2 .
  • the electron emitting part 211 can emit electrons in a linear emission or angular emission manner, which can be selected according to actual electron emission requirements.
  • the electron emission part 211 may be in a long strip shape as shown in FIG. 8 , or may be in a shape composed of a plurality of circles connected in sequence as shown in FIG. 9 , or may be in a shape of a plurality of circles as shown in FIG. 10 .
  • the shape formed by connecting rounded rectangles in sequence can also be a shape formed by connecting multiple triangles in sequence as shown in Figure 11. The electric field is more easily concentrated at the corners of the triangle, resulting in higher electron emission efficiency.
  • the plurality of electron emission parts 211 may be distributed in parallel and spaced apart.
  • the plurality of electron emission parts 211 shown in FIGS. 8 to 10 are all arranged at intervals along the direction of the X-axis.
  • the cathode structure 2 may include two connection parts 22a and 22b, which are respectively provided at both ends of the plurality of electron emission parts 211.
  • One connection part 22a is connected to one end of the plurality of electron emitting parts 211
  • the other connection part 22b is connected to the other ends of the plurality of electron emitting parts 211.
  • the plurality of electron emission parts 211 in the above-mentioned cathode array 21 may also be distributed in other forms.
  • the plurality of electron emission parts 211 shown in FIG. 12 are distributed in a rectangular array.
  • the plurality of electron emission parts 211 shown in FIG. 13 are distributed in a rectangular array and a circular array.
  • the cathode structure 2 has a plurality of connecting portions 22 , and the plurality of connecting portions 22 respectively connect two adjacent electron emission portions 211 .
  • This application does not limit the distribution form of the plurality of electron emission parts 211 .
  • the above-mentioned cathode structure 2 only includes one electron emission part 211, and the electron emission part 211 may adopt a shape with more emission sites.
  • the electron emission portion 211 has various shapes such as a serpentine coil.
  • the electron emission part 211 shown in FIG. 14 has a rectangular shape and is extended and coiled in the width direction of the substrate 1 .
  • the electron emission part 211 may also be coiled on the substrate 1 from the inside to the outside in a circular shape. This application does not limit this.
  • the electron-emitting part 211 coiled in a serpentine shape may be integrally disposed on the insulating support part 4, as shown in FIG. 14 .
  • a part of the electron emission part 211 may be provided on the insulating support part 4 as a support point. Therefore, other partial areas of the electron emission part 211 can be suspended on the substrate 1 , which can also reduce the leakage current on the substrate 1 .
  • the anode structure 3 can be made into an approximate "gate" shape as shown in FIG. 15 .
  • the surface of the anode structure 3 is flat, the electric field is uniform and small in value, and it is difficult for electrons to escape, so no current will be generated.
  • the above-mentioned anode structure 3 can be manufactured using a peel-off process. Since the anode structure 3 is directly fabricated on the insulating support part 4, the thickness of the anode structure 3 that needs to be fabricated is relatively large. Therefore, in some embodiments of the present application, the semiconductor device 100 includes the anode support 5 as shown in FIGS. 16 and 17 , and the anode support 5 is disposed between the insulating support 4 and the anode structure 3 . When the anode structure 3 is made on the anode support part 5 through a peel-off process, the thickness of the anode structure 3 that needs to be made is smaller, thereby saving material.
  • the above-mentioned anode support part 5 and the cathode structure 2 are made of the same layer and the same material.
  • the anode support part 5 and the cathode structure 2 are made through a patterning process, and the process flow is simple.
  • the patterning process may include a photolithography process, or include a photolithography process and an etching step; the photolithography process may refer to a process using photolithography including film formation, exposure, development, etc. Glue, mask, exposure machine, etc. are used to form patterns.
  • the corresponding patterning process can be selected according to the structure formed in this application.
  • the one-time patterning process in the embodiment of the present application is to form different exposure areas through a mask exposure process, and then perform multiple etching, ashing and other removal processes on the different exposure areas to finally obtain the expected pattern. instructions.
  • “Same layer” refers to a layer structure formed by using the same film-forming process to form a film layer for forming a specific pattern, and then using the same mask to form a patterning process.
  • the same patterning process may include multiple exposure, development or etching processes, and the specific patterns in the formed layer structure may be continuous or discontinuous, and these specific patterns may also be at different heights. Or have different thicknesses.
  • the anode structure 2 may also be designed to be recessed downward only in the area opposite to the cathode structure 2 , as shown in FIGS. 18 and 19 . This application does not limit this.
  • the semiconductor chip 1000 includes a plurality of the above-mentioned semiconductor devices 100 configured as vacuum diodes, and an array of multiple semiconductor devices 100 arranged on substrate 1.
  • Multiple semiconductor devices 100 in the semiconductor chip 1000 can be integrated and manufactured using the existing COMS process, and have better dimensional consistency, higher production efficiency, higher output and higher lifespan. Therefore, the semiconductor chip 1000 can integrate higher density semiconductor devices 100 on the same area of the substrate 1, and the integration level is high, which increases the total current of the semiconductor chip 1000.
  • the semiconductor chip 1000 having a plurality of the above vacuum diodes can be manufactured using the following manufacturing method. As shown in Figure 22, the production method includes the following steps:
  • the substrate 10 can be obtained directly.
  • the processing flow can be reduced.
  • the material of the cathode material layer 20 and the material of the substrate 1 are both single crystal silicon, and the insulating layer 40 is an oxide layer.
  • the oxide layer is SiO 2 material.
  • S200 Form the cathode structure 2 on the cathode material layer 20 in the substrate 10.
  • the cathode structure 2 is formed on the cathode material layer 20 in the substrate 10 through a photolithography process.
  • a photoresist pattern 101 may be first formed on the cathode material layer 20 in the substrate 10 by dry etching. Afterwards, as shown in (c) of FIG. 22 , the photoresist pattern 101 is transferred to the cathode material layer 20 to form the cathode structure 2 .
  • the cathode structure 2 can be formed simultaneously on the cathode material layer 20 in the substrate 10 through the same photolithography process as shown in FIG. 22(c) and anode support part 5.
  • S300 Form the sacrificial portion 7 for supporting the suspended area of the anode structure 3 on the cathode structure 2 and the insulating layer 40.
  • a sacrificial portion 7 for supporting the suspended region of the anode structure 3 can be formed on the cathode structure 2 and the insulating layer 40 through multiple processes.
  • the anode structure 3 as shown in (e) in FIG. 22 can be formed above the sacrificial part 7 through a lift-off process.
  • the anode structure 3 is manufactured using a peel-off process, which can save the etching step and reduce the manufacturing cost of the vacuum-encapsulated semiconductor chip 1000.
  • S500 Remove the sacrificial part 7 to obtain the cathode structure 2, the anode structure 3 suspended on the cathode structure 2, and the vacuum gap ⁇ between the anode structure 3 and the cathode structure 2.
  • the sacrificial portion 7 can be removed through an etching process. Thereby, the cathode structure 2, the anode structure 3 suspended on the cathode structure 2, and the vacuum gap ⁇ between the anode structure 3 and the cathode structure 2 are obtained.
  • S600 Form a plurality of insulating support portions 4 on the insulating layer 40 in the substrate 10.
  • part of the insulating layer 40 may be removed through an etching process. Thereby, a plurality of insulating support portions 4 are obtained. At the same time, during the etching process, a portion of the insulating layer 40 located below the cathode structure 2 can also be removed, thereby obtaining the cathode structure 2 arranged in the air.
  • the above S300 specifically includes:
  • S301 Form the first sacrificial layer 70 on the layer where the cathode structure 2 is located through a spin coating process and a polishing process.
  • the first sacrificial layer 701a is first formed on the layer where the cathode structure 2 is located through a spin coating process.
  • the first sacrificial layer 701a can completely fill the gaps between the plurality of electron emission parts 211 in the cathode structure 2, and the upper surface of the first sacrificial layer 701a is higher than the cathode structure 2.
  • the first sacrificial layer 701a can be made of SiN material.
  • the first sacrificial layer 701a can be planarized through a chemical mechanical polishing process, and the top surfaces of the cathode structure 2 and the anode support 5 can be exposed to obtain the first sacrificial layer 701 as shown in (b) of FIG. 23 .
  • S302 Form the second sacrificial layer 702 on the first sacrificial layer 701 and the cathode structure 2 through an atomic layer deposition process.
  • the second sacrificial layer 702 may be formed on the cathode structure 2 and the first sacrificial layer 701 through an atomic layer deposition process.
  • the material of the second sacrificial layer 702 may also be SiN material.
  • the atomic layer deposition process can precisely control the material composition and morphology of the second sacrificial layer 702 on the nanometer scale, thereby accurately controlling the size of the vacuum gap ⁇ between the anode structure 3 and the cathode structure 2 .
  • first sacrificial layer 701 and the second sacrificial layer 702 need to be formed, which can be used to fabricate the anode structure 3 with an approximately "gate"-shaped cross section.
  • anode structure 3 which has a "gate” shape in cross section and is recessed downward in the area opposite to the cathode structure 2, as shown in (a) to (d) in Figure 25, in addition to making the first sacrificial layer 701 and the For the second sacrificial layer 702, it is also necessary to form a third sacrificial layer 703 on the second sacrificial layer 702.
  • the third sacrificial material layer 703 may specifically be SiO 2 .
  • S303 Form the sacrificial portion 7 for supporting the suspended area of the anode structure 3 on the second sacrificial layer 702 through a photolithography process.
  • the photoresist pattern 102 may first be formed on the second sacrificial layer 702 by dry etching. Afterwards, as shown in (e) of FIG. 23 , the photoresist pattern 102 can be transferred to the second sacrificial layer 702 to form the sacrificial portion 7 .
  • the sacrificial part 7 is used to support the anode structure 3 as shown in Figure 24.
  • the photoresist pattern 102 may be first formed on the second sacrificial layer 702 and the third sacrificial layer 703 by dry etching. After that, as shown in (f) of FIG. 25 , the photoresist pattern 102 can be transferred to the second sacrificial layer 702 and the third sacrificial layer 703 to obtain the first sacrificial part 71 and the transition sacrificial part 72a. Then, as shown in (g) of FIG. 26 , a photoresist pattern 103 may be formed on the transition sacrificial portion 72 a by dry etching. Finally, as shown in (h) of FIG.
  • the photoresist pattern 103 can be transferred to the transition sacrificial portion 72 a to obtain the second sacrificial portion 72 .
  • the sacrificial part 7 having the first sacrificial part 71 and the second sacrificial part 72 is used to support the anode structure 3 as shown in (e) of FIG. 22 .
  • FIG. 22 , FIG. 23 , FIG. 24 and FIG. 25 only show the production of one semiconductor device in the semiconductor chip 1000 . It can be understood that the structures of each layer of the multiple semiconductor devices in the semiconductor chip 1000 can be fabricated simultaneously under the same process, and will not be described in detail here.
  • the above embodiments are all described by taking the semiconductor device 100 as a vacuum diode as an example.
  • the semiconductor device 100 may also be a vacuum triode. Therefore, in some embodiments of the present application, the above-mentioned semiconductor device 100 further includes a gate structure 6 as shown in FIGS. 26 and 27 , and the gate structure 6 is disposed on the substrate 1 . Moreover, the gate structure 6 is in the same layer as the cathode structure 2 and is arranged at intervals, and is diffracted outside the cathode structure 2 . Thus, a vacuum three-stage tube is obtained.
  • the intensity of the electron flow emitted by the cathode structure 2 can be changed by applying different voltages to the gate structure 6 to modulate the electric field intensity of the cathode structure 2 .
  • the input voltage of the gate structure 6 should be between the input voltage of the cathode structure 2 and the input voltage of the anode structure 3 .
  • the vacuum triode can also be made using existing CMOS technology to achieve nanoscale technology. Therefore, the vacuum triode is a vacuum micro-nano triode.
  • Figure 28 shows the output characteristics of the vacuum micro-nano triode.
  • the gate voltages of line 1 to line 6 in Figure 28 are different.
  • the gate voltage of line 1 is the largest, and the gate voltage of line 6 is the smallest.
  • the vacuum micro-nano triode has the following physical characteristics: the greater the voltage of the gate structure 6, the lower the voltage of the anode structure 3 required for the cathode structure 2 to emit electrons, and the faster the current of the cathode structure 2 increases.
  • Figure 29 shows the transfer characteristics of the vacuum micro-nano triode. It can be seen from Figure 29 that the vacuum micro-nano triode has the following physical characteristics: the greater the voltage of the gate structure 6, the greater the current of the cathode structure 2.
  • the above-mentioned cathode structure 2 is directly disposed on the substrate 1 .
  • the gate structure 6 is suspended on the substrate 1 and is provided in the same layer and material as the anode support 5 .
  • the above-mentioned gate structure 6 may be interchanged with the cathode structure 2 .
  • the gate structure 6 is directly provided on the substrate 1 .
  • the cathode structure 2 is suspended on the substrate 1 and is of the same layer and material as the anode support part 5 . This application does not limit this.
  • the structure and shape of the cathode structure 2 in the above-mentioned vacuum triode may be similar to the structure and shape of the cathode structure 2 in the vacuum diode.
  • FIG. 31 shows that the cathode structure 2 in the vacuum triode includes a plurality of circular electron-emitting parts 211.
  • FIG. 32 shows that the cathode structure 2 in the vacuum triode includes a plurality of rounded rectangular electron emission parts 211 .
  • FIG. 33 shows that the cathode structure 2 in the vacuum triode includes a plurality of triangular electron-emitting parts 211.
  • Figure 34 shows that the cathode structure 2 in the vacuum triode includes a serpentine coiled electron emission part 211.
  • the above semiconductor chip 1000 includes a plurality of the above semiconductor devices 100 configured as vacuum triodes, and the plurality of semiconductor devices 100 are arranged in an array. on substrate 1.
  • Multiple semiconductor devices 100 in the semiconductor chip 1000 can be integrated and manufactured using the existing COMS process, and have better dimensional consistency, higher production efficiency, higher output and higher lifespan. Therefore, the semiconductor chip 1000 can integrate higher density semiconductor devices 100 on the same area of the substrate 1 , and the integration level is high, which increases the total current of the semiconductor chip 1000 .
  • the anode structure 3 and the cathode structure 2 in the semiconductor device 100 are arranged on the same layer, and at the same time, tips for discharge are processed on the opposite surfaces of the anode structure 3 and the cathode structure 2 structure. Since the thickness of the cathode structure 2 and the anode structure 3 is small (the thickness direction is the Z-axis direction in FIG. 37), it is more difficult to process the tip structure. However, the cathode structure 2 and the anode structure 3 in the semiconductor device 100 in the embodiment of the present application do not need to be finely processed on their own sides, and the processing difficulty is relatively low.
  • the semiconductor chip 1000 in the embodiment of the present application may also include a plurality of the above-mentioned semiconductor devices 100 configured as vacuum triodes, and a plurality of the above-mentioned vacuum diodes. Moreover, the semiconductor chip 1000 may also include other semiconductor devices, which is not limited in this application.
  • embodiments of the present application also include a method of manufacturing a semiconductor chip 1000 having a plurality of the above vacuum triodes.
  • (a) to (g) in FIG. 38 are schematic structural diagrams corresponding to various process steps in the manufacturing method of the semiconductor chip 1000 of the vacuum triode.
  • (a) to (h) in FIG. 39 are schematic structural diagrams corresponding to various process steps of the sacrificial portion in the manufacturing method of the semiconductor chip 1000 of the vacuum triode.
  • the manufacturing method of the semiconductor chip 1000 having multiple vacuum triodes is similar to the manufacturing method of the semiconductor chip 1000 having multiple vacuum diodes. The difference is that in the manufacturing method of the semiconductor chip 1000 having a plurality of the above-mentioned vacuum triodes, referring to FIG. 40, the above-mentioned step S100 specifically includes:
  • the above-mentioned S100 specifically includes:
  • the substrate 1 can be a silicon substrate, and the upper surface 1a of the substrate 1 is heavily doped with N-type to ensure the conductivity of the upper surface of the silicon substrate 1. properties and a higher Fermi level.
  • the gate structure 6 as shown in (b) of FIG. 40 can be formed on the substrate 1 through a photolithography process.
  • S103 Form an insulating layer 40 above the substrate 1, above the gate structure 6 and on the side walls.
  • the insulating layer 40a as shown in (c) in FIG. 40 may be first formed on the substrate 1 having the gate structure 6 through a spin coating process.
  • the insulation layer can be made of glass material. So, in other words, the insulating layer 40a is formed on the substrate 1 having the gate structure 6 using a spin on glass (SOG) method.
  • SOG spin on glass
  • the insulating layer 40a is thicker at the recesses (ie, on the substrate 1), while the insulating layer 40a is thinner at the protrusions (ie, on the gate structure 6).
  • the insulating layer 40a on the substrate 1 can be thinned through an etching back process, while the insulating layer 40a on the gate structure 6 is retained, to obtain the insulating layer 40b as shown in (d) of FIG. 40 .
  • an atomic layer deposition process can be used to form an insulating layer 40 above and on the sidewalls of the gate structure 6 .
  • the insulating layer 40 is formed above the substrate 1, above the gate structure 6, and on the side walls.
  • the atomic layer deposition process can accurately control the thickness of the insulating layer 40 formed, thereby accurately controlling the gap between the gate structure 6 and the cathode structure 2 .
  • the cathode material layer 20 can be first formed through a deposition process (such as a physical vapor deposition process or a chemical vapor deposition process).
  • the cathode material layer 20 can completely fill the gap in the insulating layer 40 .
  • the cathode material layer 20 may be polysilicon material.
  • the cathode material layer 20 can be planarized through a chemical mechanical polishing (CMP) process as shown in (g) of FIG. 40 , and the top surface of the gate structure 6 can be exposed. Thereby, the cathode material layer 20 is obtained.
  • CMP chemical mechanical polishing
  • the substrate 10 having the cathode material layer 20, the insulating layer 40 and the substrate 1 stacked sequentially from top to bottom can be manufactured through the above-mentioned multi-channel CMOS process.

Abstract

The present application relates to the technical field of vacuum encapsulation, and provides a vacuum-encapsulated semiconductor chip and a manufacturing method therefor, for use in solving the problems in the prior art that vacuum micro-nano-electronic tubes have leakage currents on substrates thereof and cannot be integrally manufactured. The semiconductor chip comprises at least one semiconductor device. The semiconductor device comprises a substrate, a plurality of insulating supporting portions, a cathode structure, and an anode structure. The plurality of insulating supporting portions are arranged in a same layer and are arranged on the substrate at intervals. The cathode structure is arranged on at least one of the insulating supporting portions. A part of the anode structure is arranged on an insulating supporting portion, and the other part of the anode structure is suspended above the cathode structure, so that a vacuum gap is formed between the anode structure and the cathode structure. Because the anode structure is designed to be suspended above the cathode structure, part of the anode structure can be vacuum isolated from the substrate, thereby reducing the contact area between the anode structure and the substrate. Thus, the insulation of the semiconductor device is improved, and the leakage current on the substrate is reduced.

Description

一种真空封装的半导体芯片及其制作方法Vacuum-encapsulated semiconductor chip and manufacturing method thereof 技术领域Technical field
本申请涉及真空封装技术领域,尤其涉及一种真空封装的半导体芯片及其制作方法。The present application relates to the field of vacuum packaging technology, and in particular, to a vacuum-packaged semiconductor chip and a manufacturing method thereof.
背景技术Background technique
随着半导体技术的广泛应用,对半导体芯片提出了更高的性能及效率的要求。以真空电子管为例,真空电子管具备良好的性能和效率,并可以通过微纳加工技术制备纳米级的真空电子结构,以解决了尺寸大、电压高的问题。With the widespread application of semiconductor technology, higher performance and efficiency requirements have been put forward for semiconductor chips. Take vacuum electron tubes as an example. Vacuum electron tubes have good performance and efficiency, and can prepare nanoscale vacuum electronic structures through micro-nano processing technology to solve the problems of large size and high voltage.
相关技术中的一种真空微纳电子管包括阴极和阳极,阴极与阳极之间具有极间真空通道。在电场作用下,电子从阴极发射并通过极间真空通道到达阳极,从而形成电流。电子在极间真空通道传导期间形成弹道输运,不会像半导体中电子与原子产生碰撞而降低效率。并且,纳米级的极间真空通道可以明显降低真空微纳电子管的工作电压。同时,在纳米级的极间真空通道中,气体粒子的数量极少,可以降低真空封装的要求。A vacuum micro-nano electron tube in the related art includes a cathode and an anode, and there is an interelectrode vacuum channel between the cathode and the anode. Under the action of the electric field, electrons are emitted from the cathode and reach the anode through the interelectrode vacuum channel, thereby forming an electric current. The electrons form ballistic transport during conduction in the interpolar vacuum channel, which does not reduce efficiency due to collisions between electrons and atoms in semiconductors. Moreover, the nanoscale inter-electrode vacuum channel can significantly reduce the operating voltage of vacuum micro-nano electron tubes. At the same time, in the nanoscale inter-electrode vacuum channel, the number of gas particles is extremely small, which can reduce the requirements for vacuum packaging.
但是,上述真空微纳电子管中阴极和阳极均需要通过介电层设置在衬底上。受介电层材料、厚度及制作工艺等参数影响,介电层不能保证可以给真空微纳电子管提供优秀的绝缘性能,使得真空微纳电子管在衬底上会存在一定的漏电流。并且,真空微纳电子管中的极间真空通道需要采用如电子束光刻或离子束刻蚀工艺制作。而电子束光刻或离子束刻蚀工艺不能用于大规模生产制造,所以,真空微纳电子管不能实现集成制造。However, in the above-mentioned vacuum micro-nano electron tube, both the cathode and the anode need to be disposed on the substrate through a dielectric layer. Affected by parameters such as dielectric layer material, thickness, and manufacturing process, the dielectric layer cannot guarantee to provide excellent insulation properties for vacuum micro-nano electron tubes, resulting in a certain leakage current of vacuum micro-nano electron tubes on the substrate. Moreover, the inter-electrode vacuum channel in the vacuum micro-nano electron tube needs to be produced using processes such as electron beam lithography or ion beam etching. However, electron beam lithography or ion beam etching processes cannot be used for mass production and manufacturing, so vacuum micro-nano electron tubes cannot be integrated into the manufacturing process.
发明内容Contents of the invention
本申请实施例提供一种真空封装的半导体芯片及其制作方法,能够解决现有技术中真空微纳电子管在衬底上存在漏电流且不能集成制造的问题。Embodiments of the present application provide a vacuum-encapsulated semiconductor chip and a manufacturing method thereof, which can solve the problem in the prior art that vacuum micro-nano electron tubes have leakage current on the substrate and cannot be integratedly manufactured.
第一方面,本申请提供一种真空封装的半导体芯片。该半导体芯片可以为分立器件,如真空二极管、真空三级管等,也可以为由多个分立器件集成制作且真空封装的集成芯片,还可以与其他芯片、电路真空封装在一起的芯片,如具有功率转换、信号处理等功能性芯片。半导体芯片包括一个或多个(多个是指两个或两个以上)半导体器件。半导体器件包括衬底、多个绝缘支撑部、阴极结构及阳极结构。其中,多个绝缘支撑部同层且间隔设置在衬底上。阴极结构设置在一个或多个绝缘支撑部上。并且,阴极结构仅设置在部分绝缘支撑部上,而不是所有的绝缘支撑部上。阳极结构的一部分设置在剩余绝缘支撑部中的一个或多个上,阳极结构的另一部分悬空设置在阴极结构的上方,以使阳极结构与阴极结构之间形成真空间隙。所以,半导体器件为真空半导体器件(如真空电子管)。并且,通过将阳极结构悬空设计在阴极结构的上方,阳极结构上仅部分区域通过绝缘支撑部设置在衬底上,阳极结构的其他剩余部分均与衬底间隔设置。所以,阳极结构的部分区域可以与衬底真空隔离,减少了阳极结构与衬底的接触面积。从而,提高了半导体器件的绝缘性,减少了衬底上的漏电流。并且,阳极结构和阴极结构之间的真空间隙可以通过现有互补金属氧化物半导体(complementary metal oxide semiconductor,COMS)工艺制作牺牲层来形成,从而可以实现真空封装的半导体器件的集成制作。In a first aspect, the present application provides a vacuum-encapsulated semiconductor chip. The semiconductor chip can be a discrete device, such as a vacuum diode, a vacuum triode, etc., or an integrated chip made of multiple discrete devices and vacuum-packaged, or a chip that is vacuum-packaged with other chips and circuits, such as It has functional chips such as power conversion and signal processing. A semiconductor chip includes one or more (multiple refers to two or more) semiconductor devices. The semiconductor device includes a substrate, a plurality of insulating supports, a cathode structure and an anode structure. Wherein, a plurality of insulating support parts are arranged on the substrate in the same layer and at intervals. The cathode structure is disposed on one or more insulating supports. Moreover, the cathode structure is only provided on part of the insulating support parts, not all of the insulating support parts. A part of the anode structure is disposed on one or more of the remaining insulating supports, and another part of the anode structure is disposed suspended above the cathode structure, so that a vacuum gap is formed between the anode structure and the cathode structure. Therefore, the semiconductor device is a vacuum semiconductor device (such as a vacuum electron tube). Moreover, by designing the anode structure to be suspended above the cathode structure, only part of the anode structure is disposed on the substrate through the insulating support part, and the remaining parts of the anode structure are spaced apart from the substrate. Therefore, some areas of the anode structure can be vacuum isolated from the substrate, reducing the contact area between the anode structure and the substrate. Therefore, the insulation of the semiconductor device is improved and the leakage current on the substrate is reduced. Moreover, the vacuum gap between the anode structure and the cathode structure can be formed by making a sacrificial layer using the existing complementary metal oxide semiconductor (COMS) process, thereby enabling the integrated production of vacuum-encapsulated semiconductor devices.
在一些实施例中,上述阴极结构包括阴极阵列,阴极阵列由多个电子发射部阵列排布形成。并且,多个电子发射部与阳极结构均相对设置。具有多个电子发射部的阴极阵列的电子发射位置增多,从而增大了阴极结构的总电流。并且,阴极结构的面积小、结构紧凑。In some embodiments, the above-mentioned cathode structure includes a cathode array, and the cathode array is formed by an array arrangement of a plurality of electron emitting parts. Furthermore, the plurality of electron emission parts and the anode structure are arranged opposite to each other. A cathode array having a plurality of electron emitting parts has more electron emitting positions, thereby increasing the total current of the cathode structure. Moreover, the cathode structure has a small area and a compact structure.
基于具有阴极阵列的阴极结构,在一些实施例中,该阴极结构还包括连接部,连接部设置在绝缘支撑部上。并且,连接部与阴极阵列中的多个电子发射部均连接,以使阴极阵列悬空设置在衬底的上方。连接部可以作为阴极阵列中多个电子发射部的支撑结构,使得多个电子发射部可以完全悬空设置在衬底上,减少了阴极阵列与衬底的接触面积。阴极阵列可以与衬底真空隔离。从而,进一步提高了半导体器件的绝缘性,减少了漏电问题。Based on the cathode structure having a cathode array, in some embodiments, the cathode structure further includes a connecting portion, and the connecting portion is disposed on the insulating support portion. Furthermore, the connecting portion is connected to the plurality of electron-emitting portions in the cathode array, so that the cathode array is suspended above the substrate. The connection part can serve as a support structure for multiple electron emitting parts in the cathode array, so that the multiple electron emitting parts can be completely suspended on the substrate, thereby reducing the contact area between the cathode array and the substrate. The cathode array can be vacuum isolated from the substrate. As a result, the insulation of the semiconductor device is further improved and leakage problems are reduced.
上述电子发射部可以采用线发射或角发射的方式发射电子。所以,本申请实施例中的电子发射部可以为长条形,也可以为由多个圆形或多个圆角矩形依次连接组成的形状,还可以呈蛇形盘绕的形状等。这三种形状均实现线发射方式发射电子。在一些实施例中,上述电子发射部可以为由多个三角形依次连接组成的形状,这种形状可以实现角发射方式发射电子。从而,满足对阴极结构不同的物理特性需求。The electron emitting part may emit electrons in a linear emission or angular emission manner. Therefore, the electron emitting part in the embodiment of the present application may be in a long strip shape, or may be in a shape composed of multiple circles or multiple rounded rectangles connected in sequence, or may be in a serpentine coiled shape, etc. All three shapes achieve line emission of electrons. In some embodiments, the above-mentioned electron emitting part may be in a shape composed of multiple triangles connected in sequence, and this shape can realize emitting electrons in an angular emission manner. Thus, different physical property requirements for cathode structures are met.
此外,在本申请的其他一些实施例中,上述阴极结构还可以仅包括一个电子发射部。该电子发射部可以呈蛇形盘绕设置在衬底上方,并且电子发射部的一部分设置在绝缘支撑部上。呈蛇形盘绕的电子发射部的发射位点较多,发射电流较大,并且悬空设置在衬底上,衬底上的漏电流较少。此外,该电子发射部也可以直接盘绕设置在一个绝缘支撑部上。In addition, in some other embodiments of the present application, the above-mentioned cathode structure may also include only one electron emitting part. The electron emission part may be arranged in a serpentine shape above the substrate, and a part of the electron emission part may be arranged on the insulating support part. The electron-emitting part coiled in a serpentine shape has more emission sites and a larger emission current, and is suspended on the substrate and has less leakage current on the substrate. In addition, the electron emitting part may also be directly wound around an insulating support part.
为了便于制作阳极结构,在本申请的一些实施例中,上述半导体器件包括阳极支撑部,该阳极支撑部设置在绝缘支撑部与阳极结构之间。在采用揭开-剥离(lift-off)工艺制作阳极结构时,增设了阳极支撑部可以减少所需制作的阳极结构的厚度。In order to facilitate the production of the anode structure, in some embodiments of the present application, the above-mentioned semiconductor device includes an anode support part, and the anode support part is disposed between the insulating support part and the anode structure. When the anode structure is manufactured using a lift-off process, adding an anode support part can reduce the thickness of the anode structure that needs to be manufactured.
并且,在一些实施例中,上述阳极支撑部与阴极结构同层同材料,从而,阳极支撑部和阴极结构可以通过一道构图工艺制作,工艺流程简单。Moreover, in some embodiments, the above-mentioned anode support part and the cathode structure are made of the same layer and the same material. Therefore, the anode support part and the cathode structure can be manufactured through a patterning process, and the process flow is simple.
上述实施例中的半导体器件为真空二极管,本申请实施例的半导体器件还可以用于制作真空三极管。在一些实施例中,上述半导体器件还包括栅极结构,该栅极结构设置衬底上。栅极结构与阴极结构同层且间隔设置,且绕射在阴极结构外。从而,该半导体器件为真空三极管。在阳极结构施加电压时,阴极结构的表面产生电场,电子从阴极结构逸出,通过真空间隙到达阳极结构,从而形成电流。真空三极管中的栅极结构施加不同的电压,可以调制阴极结构的电场强度。从而,改变阴极结构电子流的发射强度。进而,控制了半导体器件中电流的大小及开关。The semiconductor device in the above embodiment is a vacuum diode, and the semiconductor device in the embodiment of the present application can also be used to make a vacuum triode. In some embodiments, the above-mentioned semiconductor device further includes a gate structure, and the gate structure is disposed on the substrate. The gate structure is in the same layer as the cathode structure and is spaced apart, and is diffracted outside the cathode structure. Therefore, the semiconductor device is a vacuum triode. When a voltage is applied to the anode structure, an electric field is generated on the surface of the cathode structure, and electrons escape from the cathode structure and reach the anode structure through the vacuum gap, thereby forming an electric current. The electric field strength of the cathode structure can be modulated by applying different voltages to the gate structure in the vacuum triode. Thus, the emission intensity of the electron flow in the cathode structure is changed. Furthermore, the magnitude and switching of the current in the semiconductor device are controlled.
在一些实施例中,上述半导体器件中的栅极结构也可以与阴极结构相互交换位置。换句话说,栅极结构悬空设置在衬底上,而阴极结构直接设置在衬底上。In some embodiments, the gate structure in the above-mentioned semiconductor device can also exchange positions with the cathode structure. In other words, the gate structure is suspended on the substrate, while the cathode structure is directly placed on the substrate.
基于上述实施例中的半导体器件的结构,在本申请的一些实施例中,半导体芯片包括多个半导体器件,多个半导体器件阵列排布在衬底上。该半导体芯片可以通过现有CMOS工艺在衬底上制作多个具有垂直结构的阴极结构和阳极结构的半导体器件,从而提高了真空封装的半导体器件的集成度。其中,多个真空封装的半导体器件中阴极结构与阳极结构之间的真空间隙可以通过同一道原子层沉积(atomic layer deposition,ALD)工艺进行精确控制。Based on the structure of the semiconductor device in the above embodiments, in some embodiments of the present application, the semiconductor chip includes a plurality of semiconductor devices, and a plurality of semiconductor device arrays are arranged on the substrate. The semiconductor chip can produce multiple semiconductor devices with vertical cathode structures and anode structures on a substrate through existing CMOS processes, thereby improving the integration of vacuum-encapsulated semiconductor devices. Among them, the vacuum gap between the cathode structure and the anode structure in multiple vacuum-packaged semiconductor devices can be precisely controlled through the same atomic layer deposition (ALD) process.
第二方面,本申请实施例还包括一种真空封装的半导体芯片的制作方法。该制作方法包括以下步骤:获取具有由上至下依次层叠设置的阴极材料层、绝缘层、衬底的基底。在 基底中的阴极材料层上形成阴极结构。在阴极结构和绝缘层上形成用于支撑阳极结构的悬空区域的牺牲部。在牺牲部的上方形成阳极结构。去除牺牲部,获得阴极结构、悬空设置在阴极结构上的阳极结构、及阳极结构与阴极结构之间的真空间隙。去除绝缘层的部分区域,获得多个绝缘支撑部。In a second aspect, embodiments of the present application also include a method for manufacturing a vacuum-encapsulated semiconductor chip. The manufacturing method includes the following steps: obtaining a substrate with a cathode material layer, an insulating layer, and a substrate stacked sequentially from top to bottom. A cathode structure is formed on the layer of cathode material in the substrate. A sacrificial portion for supporting the suspended region of the anode structure is formed on the cathode structure and the insulating layer. An anode structure is formed above the sacrificial portion. The sacrificial part is removed to obtain a cathode structure, an anode structure suspended on the cathode structure, and a vacuum gap between the anode structure and the cathode structure. Partial areas of the insulating layer are removed to obtain multiple insulating support parts.
本申请实施例的制作方法可以实现上述实施例中真空封装的半导体芯片的制作。其中,通过设置牺牲部实现了悬空阳极结构的制作、以及阳极结构与阴极结构之间真空间隙的制作。The manufacturing method of the embodiment of the present application can realize the manufacturing of the vacuum-encapsulated semiconductor chip in the above embodiment. Among them, by arranging the sacrificial part, the fabrication of the suspended anode structure and the fabrication of the vacuum gap between the anode structure and the cathode structure are realized.
在一些实施例中,上述在阴极结构和绝缘层上形成用于与阳极结构的悬空区域对应的牺牲部具体包括:在阴极结构的所在层上通过旋涂工艺和抛光工艺形成第一牺牲层。在第一牺牲层和阴极结构上通过原子层沉积工艺形成第二牺牲层。在第二牺牲层上通过光刻工艺形成用于支撑阳极结构的悬空区域的牺牲部。原子层沉积工艺可以在纳米级尺度上精确控制第二牺牲层的物质成分和形貌,从而精确控制阳极结构与阴极结构之间的真空间隙。In some embodiments, forming the sacrificial portion corresponding to the suspended area of the anode structure on the cathode structure and the insulating layer specifically includes: forming a first sacrificial layer on the layer where the cathode structure is located through a spin coating process and a polishing process. A second sacrificial layer is formed on the first sacrificial layer and the cathode structure through an atomic layer deposition process. A sacrificial portion for supporting the suspended region of the anode structure is formed on the second sacrificial layer through a photolithography process. The atomic layer deposition process can precisely control the material composition and morphology of the second sacrificial layer at the nanometer scale, thereby accurately controlling the vacuum gap between the anode structure and the cathode structure.
在一些实施例中,上述去除绝缘层的部分区域,获得多个绝缘支撑部包括:去除绝缘层上位于阴极结构的下方的一部分区域,获得悬空设置的阴极结构。In some embodiments, removing a portion of the insulating layer to obtain a plurality of insulating support portions includes: removing a portion of the insulating layer below the cathode structure to obtain a suspended cathode structure.
在一些实施例中,上述在基底中的阴极材料层上形成阴极结构具体包括:在基底中的阴极材料层上通过光刻工艺形成阴极结构及阳极支撑部。阴极结构和阳极支撑部可以采用同一道光刻工艺制作,工艺流程简单。In some embodiments, forming the cathode structure on the cathode material layer in the substrate specifically includes: forming the cathode structure and the anode support part on the cathode material layer in the substrate through a photolithography process. The cathode structure and the anode support part can be manufactured using the same photolithography process, and the process flow is simple.
上述基底可以为直接获取,也可以通过专门的加工工艺制作形成。因此,在一些实施例中,上述基底为SOI(silicon-on-insulator,绝缘衬底上的硅)衬底。SOI衬底可以直接获取,而不需再采用多重加工工艺制造,减少了加工流程。The above-mentioned substrate can be obtained directly, or can be produced through special processing technology. Therefore, in some embodiments, the above-mentioned substrate is an SOI (silicon-on-insulator, silicon on insulating substrate) substrate. The SOI substrate can be obtained directly without using multiple processing techniques to manufacture, reducing the processing flow.
在另一些实施例中,上述获取具有由上至下依次层叠设置的阴极材料层、绝缘层、衬底的基底具体包括:获取衬底。在衬底上形成栅极结构。在衬底的上方、栅极结构的上方及侧壁上形成绝缘层。在绝缘层上形成阴极材料层。上述制作步骤可以先在衬底上形成栅极结构,从而可以实现真空三极管的制作。In other embodiments, the above-mentioned obtaining of a substrate having a cathode material layer, an insulating layer, and a substrate that are stacked sequentially from top to bottom specifically includes: obtaining the substrate. A gate structure is formed on the substrate. An insulating layer is formed above the substrate, above the gate structure and on the sidewalls. A layer of cathode material is formed on the insulating layer. The above manufacturing steps can first form a gate structure on the substrate, so that the vacuum triode can be manufactured.
并且,上述在牺牲部的上方形成阳极结构具体包括:在牺牲部的上方通过揭开-剥离工艺形成阳极结构。阳极结构采用揭开-剥离工艺,可以省掉刻蚀步骤,降低了真空封装的半导体芯片的制作成本。Furthermore, forming the anode structure above the sacrificial part specifically includes: forming the anode structure above the sacrificial part through a lift-off process. The anode structure adopts a peel-off process, which can save the etching step and reduce the production cost of vacuum-encapsulated semiconductor chips.
附图说明Description of drawings
图1为本申请实施例半导体芯片的立体结构示意图;Figure 1 is a schematic three-dimensional structural diagram of a semiconductor chip according to an embodiment of the present application;
图2为相关技术一中半导体芯片的截面示意图;Figure 2 is a schematic cross-sectional view of a semiconductor chip in related art 1;
图3为本申请实施例半导体芯片中半导体器件的立体结构示意图;Figure 3 is a schematic three-dimensional structural diagram of a semiconductor device in a semiconductor chip according to an embodiment of the present application;
图4为图3中的A-A截面图;Figure 4 is a cross-sectional view along line A-A in Figure 3;
图5为本申请实施例半导体芯片中半导体器件为真空微纳二极管在线性坐标系下的电流-电压特性图;Figure 5 is a current-voltage characteristic diagram in a linear coordinate system in which the semiconductor device in the semiconductor chip of the embodiment of the present application is a vacuum micro-nano diode;
图6为本申请实施例半导体芯片中半导体器件为真空微纳二极管在对数坐标系下的电流-电压特性图;Figure 6 is a current-voltage characteristic diagram in a logarithmic coordinate system in which the semiconductor device in the semiconductor chip of the embodiment of the present application is a vacuum micro-nano diode;
图7为本申请实施例半导体芯片中半导体器件包括多个长条形的电子发射部的阴极结构的结构示意图;7 is a schematic structural diagram of a cathode structure of a semiconductor device including multiple elongated electron emission parts in a semiconductor chip according to an embodiment of the present application;
图8为本申请实施例半导体芯片中具有多个长条形的电子发射部的阴极结构的半导体器件的结构示意图;8 is a schematic structural diagram of a semiconductor device having a cathode structure with multiple elongated electron emission parts in a semiconductor chip according to an embodiment of the present application;
图9为本申请实施例半导体芯片中半导体器件包括多个由多个圆形依次连接组成的电子发射部的阴极结构的结构示意图;Figure 9 is a schematic structural diagram of a cathode structure in which a semiconductor device in a semiconductor chip according to an embodiment of the present application includes a plurality of electron-emitting portions composed of a plurality of circles connected in sequence;
图10为本申请实施例半导体芯片中半导体器件包括多个由多个圆角矩形依次连接组成的电子发射部的阴极结构的结构示意图;Figure 10 is a schematic structural diagram of a cathode structure in which a semiconductor device in a semiconductor chip according to an embodiment of the present application includes a plurality of electron-emitting portions composed of a plurality of rounded rectangles connected in sequence;
图11为本申请实施例半导体芯片中半导体器件包括多个由多个三角形依次连接组成的电子发射部的阴极结构的结构示意图;Figure 11 is a schematic structural diagram of a cathode structure in which a semiconductor device in a semiconductor chip according to an embodiment of the present application includes a plurality of electron-emitting portions composed of multiple triangles connected in sequence;
图12为本申请实施例半导体芯片中具有多个电子发射部呈矩形阵列排布的半导体器件的透视图;Figure 12 is a perspective view of a semiconductor device having multiple electron emitting parts arranged in a rectangular array in a semiconductor chip according to an embodiment of the present application;
图13为本申请实施例半导体芯片中具有多个电子发射部呈圆形阵列排布的半导体器件的透视图;Figure 13 is a perspective view of a semiconductor device having multiple electron emitting parts arranged in a circular array in a semiconductor chip according to an embodiment of the present application;
图14为本申请实施例半导体芯片中具有蛇形盘绕的电子发射部整体设置在绝缘支撑部上的半导体器件的透视图;Figure 14 is a perspective view of a semiconductor device having a serpentine coiled electron emission portion integrally disposed on an insulating support portion in a semiconductor chip according to an embodiment of the present application;
图15为本申请实施例半导体芯片中具有蛇形盘绕的电子发射部部分区域设置在绝缘支撑部上的半导体器件的透视图;Figure 15 is a perspective view of a semiconductor device having a serpentine coiled electron emission portion partially disposed on an insulating support portion in the semiconductor chip according to the embodiment of the present application;
图16为本申请实施例半导体芯片中具有阳极支撑部的半导体器件的结构示意图;Figure 16 is a schematic structural diagram of a semiconductor device with an anode support part in a semiconductor chip according to an embodiment of the present application;
图17为图16中B-B截面示意图;Figure 17 is a schematic diagram of the B-B cross-section in Figure 16;
图18为本申请实施例半导体芯片中具有与阴极结构2相对的区域向下凹陷的阳极结构的半导体器件的结构示意图;Figure 18 is a schematic structural diagram of a semiconductor device with an anode structure in which the area opposite to the cathode structure 2 is recessed downward in the semiconductor chip according to the embodiment of the present application;
图19为图18中的C-C截面示意图;Figure 19 is a schematic cross-sectional view of C-C in Figure 18;
图20为本申请实施例具有多个真空微纳二极管的半导体芯片的立体结构示意图;Figure 20 is a schematic three-dimensional structural diagram of a semiconductor chip with multiple vacuum micro-nano diodes according to an embodiment of the present application;
图21为本申请实施例具有多个真空微纳二极管的半导体芯片的俯视图;Figure 21 is a top view of a semiconductor chip with multiple vacuum micro-nano diodes according to an embodiment of the present application;
图22中(a)、(b)、(c)、(d)、(e)、(f)、(g)分别为本申请实施例具有多个真空微纳二极管的半导体芯片的制作方法中各种工艺步骤对应的结构示意图;(a), (b), (c), (d), (e), (f), and (g) in Figure 22 are respectively the manufacturing method of a semiconductor chip with multiple vacuum micro-nano diodes according to the embodiment of the present application. Structural diagrams corresponding to various process steps;
图23中(a)、(b)、(c)、(d)、(e)分别为本申请实施例具有多个真空微纳二极管的半导体芯片中第一种牺牲部的制作方法中各种工艺步骤对应的结构示意图;In Figure 23, (a), (b), (c), (d), and (e) are respectively various methods for manufacturing the first sacrificial portion in a semiconductor chip with multiple vacuum micro-nano diodes according to the embodiment of the present application. Structural diagram corresponding to the process steps;
图24为本申请实施例中第二种牺牲部支撑的阳极结构的半导体芯片的结构示意图;Figure 24 is a schematic structural diagram of a semiconductor chip with an anode structure supported by a second sacrificial portion in an embodiment of the present application;
图25中(a)、(b)、(c)、(d)、(e)、(f)、(g)、(h)分别为本申请实施例具有多个真空微纳二极管的半导体芯片中第二种牺牲部的制作方法中各种工艺步骤对应的结构示意图;(a), (b), (c), (d), (e), (f), (g), and (h) in Figure 25 are semiconductor chips with multiple vacuum micro-nano diodes according to embodiments of the present application. Structural diagrams corresponding to various process steps in the second sacrificial part manufacturing method;
图26为本申请实施例半导体芯片中半导体器件为真空三极管的立体结构示意图;Figure 26 is a schematic three-dimensional structural diagram of a vacuum triode as the semiconductor device in the semiconductor chip according to the embodiment of the present application;
图27为图26中D-D截面示意图;Figure 27 is a schematic diagram of the D-D cross-section in Figure 26;
图28为本申请实施例半导体芯片中半导体器件为真空微纳三极管在不同栅极电压下的输出特性图;Figure 28 is an output characteristic diagram of a vacuum micro-nano transistor in which the semiconductor device in the semiconductor chip according to the embodiment of the present application is at different gate voltages;
图29为本申请实施例半导体芯片中半导体器件为真空微纳三极管的转移特性图;Figure 29 is a transfer characteristic diagram of a vacuum micro-nano transistor where the semiconductor device in the semiconductor chip according to the embodiment of the present application;
图30为本申请实施例半导体芯片中具有悬空设置的阴极结构的半导体器件的截面示意图;Figure 30 is a schematic cross-sectional view of a semiconductor device with a suspended cathode structure in a semiconductor chip according to an embodiment of the present application;
图31为本申请实施例半导体芯片中具有多个圆形的电子发射部的真空微纳三极管的 部分结构示意图;Figure 31 is a partial structural schematic diagram of a vacuum micro-nano triode with multiple circular electron-emitting parts in a semiconductor chip according to an embodiment of the present application;
图32为本申请实施例半导体芯片中具有多个圆角矩形的电子发射部的真空微纳三极管的部分结构示意图;Figure 32 is a partial structural schematic diagram of a vacuum micro-nano triode with multiple rounded rectangular electron emission parts in a semiconductor chip according to an embodiment of the present application;
图33为本申请实施例半导体芯片中具有多个三角形的电子发射部的真空微纳三极管的部分结构示意图;Figure 33 is a partial structural schematic diagram of a vacuum micro-nano triode with multiple triangular electron-emitting parts in a semiconductor chip according to an embodiment of the present application;
图34为本申请实施例半导体芯片中具有呈蛇形盘绕的电子发射部的真空微纳三极管的部分结构示意图;Figure 34 is a partial structural schematic diagram of a vacuum micro-nano triode with a serpentine coiled electron emission part in a semiconductor chip according to an embodiment of the present application;
图35为本申请实施例具有多个真空微纳三极管的半导体芯片的立体结构示意图;Figure 35 is a schematic three-dimensional structural diagram of a semiconductor chip with multiple vacuum micro-nano transistors according to an embodiment of the present application;
图36为本申请实施例具有多个真空微纳三极管的半导体芯片的俯视图;Figure 36 is a top view of a semiconductor chip with multiple vacuum micro-nano transistors according to an embodiment of the present application;
图37为相关技术二中半导体芯片的截面示意图;Figure 37 is a schematic cross-sectional view of a semiconductor chip in related art 2;
图38中(a)、(b)、(c)、(d)、(e)、(f)、(g)分别为本申请实施例具有多个真空微纳三极管的半导体芯片的制作方法中各种工艺步骤对应的结构示意图;(a), (b), (c), (d), (e), (f), and (g) in Figure 38 are respectively the manufacturing method of a semiconductor chip with multiple vacuum micro-nano transistors according to the embodiment of the present application. Structural diagrams corresponding to various process steps;
图39中(a)、(b)、(c)、(d)、(e)、(f)、(g)、(h)分别为本申请实施例具有多个真空微纳三极管的半导体芯片中牺牲部的制作方法中各种工艺步骤对应的结构示意图;(a), (b), (c), (d), (e), (f), (g), and (h) in Figure 39 are respectively semiconductor chips with multiple vacuum micro-nano transistors according to embodiments of the present application. Structural diagram corresponding to various process steps in the manufacturing method of the sacrificial part;
图40中(a)、(b)、(c)、(d)、(e)、(f)、(g)分别为本申请实施例具有多个真空微纳三极管的半导体芯片中基底的制作方法中各种工艺步骤对应的结构示意图。(a), (b), (c), (d), (e), (f), and (g) in Figure 40 are respectively the fabrication of the substrate in the semiconductor chip with multiple vacuum micro-nano transistors according to the embodiment of the present application. Structural diagram corresponding to various process steps in the method.
附图标记:Reference signs:
1000-半导体芯片,100-半导体器件,1-衬底,10-基底,01-介电层,2-阴极结构,20-阴极材料层,21-阴极阵列,211-电子发射部,22、22a、22b-连接部,3-阳极结构,4-绝缘支撑部,40、40a、40b-绝缘层,5-阳极支撑部,6-栅极结构,7-牺牲部,71-第一牺牲部,72a-过渡牺牲部,72-第二牺牲部,701、701a-第一牺牲层,702-第二牺牲层,703-第三牺牲层,101、102、103-光刻胶图案。1000-semiconductor chip, 100-semiconductor device, 1-substrate, 10-base, 01-dielectric layer, 2-cathode structure, 20-cathode material layer, 21-cathode array, 211-electron emission part, 22, 22a , 22b-connection part, 3-anode structure, 4-insulation support part, 40, 40a, 40b-insulation layer, 5-anode support part, 6-gate structure, 7-sacrificial part, 71-first sacrificial part, 72a-transitional sacrificial part, 72-second sacrificial part, 701, 701a-first sacrificial layer, 702-second sacrificial layer, 703-third sacrificial layer, 101, 102, 103-photoresist pattern.
具体实施方式Detailed ways
为使本申请的目的、技术方案和优点更加清楚,下面将结合本申请中的附图,对本申请中的技术方案进行清楚地描述,显然,所描述的实施例是本申请一部分实施例,而不是全部的实施例。基于本申请中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本申请保护的范围。In order to make the purpose, technical solutions and advantages of this application more clear, the technical solutions in this application will be clearly described below in conjunction with the drawings in this application. Obviously, the described embodiments are part of the embodiments of this application, and Not all examples. Based on the embodiments in this application, all other embodiments obtained by those of ordinary skill in the art without creative efforts fall within the scope of protection of this application.
本申请的说明书实施例和权利要求书及附图中的术语“第一”、“第二”等仅用于区分描述的目的,而不能理解为指示或暗示相对重要性,也不能理解为指示或暗示顺序。“连接”、“相连”等类似的词语,用于表达不同组件之间的互通或互相作用,可以包括直接相连或通过其他组件间接相连。此外,术语“包括”和“具有”以及他们的任何变形,意图在于覆盖不排他的包含,例如,包含了一系列步骤或单元。方法、系统、产品或设备不必限于清楚地列出的那些步骤或单元,而是可包括没有清楚地列出的或对于这些过程、方法、产品或设备固有的其它步骤或单元。“上”、“下”、“左”、“右”等仅用于相对于附图中的部件的方位而言的,这些方向性术语是相对的概念,它们用于相对于的描述和澄清,其可以根据附图中的部件所放置的方位的变化而相应地发生变化。The terms "first", "second", etc. in the description, embodiments, claims and drawings of this application are only used for the purpose of distinguishing and describing, and cannot be understood as indicating or implying relative importance, nor can they be understood as indicating. Or suggestive order. "Connect", "connect" and other similar words are used to express the interconnection or interaction between different components, which can include direct connection or indirect connection through other components. Furthermore, the terms "including" and "having" and any variations thereof are intended to cover a non-exclusive inclusion, for example, the inclusion of a series of steps or units. Methods, systems, products or devices are not necessarily limited to those steps or elements expressly listed, but may include other steps or elements not expressly listed or inherent to such processes, methods, products or devices. "Up", "down", "left", "right", etc. are only used relative to the orientation of the components in the drawings. These directional terms are relative concepts and are used for relative description and clarification. , which may change accordingly according to changes in the orientation in which the components in the drawings are placed.
应当理解,在本申请中,“至少一个(项)”是指一个或者多个,“多个”是指两个或两个以上。“和/或”,用于描述关联对象的关联关系,表示可以存在三种关系,例如,“A和/或B”可以表示:只存在A,只存在B以及同时存在A和B三种情况,其中A,B可以是单数或者复数。字符“/”一般表示前后关联对象是一种“或”的关系。“以下至少一项(个)”或其类似表达,是指这些项中的任意组合,包括单项(个)或复数项(个)的任意组合。例如,a,b或c中的至少一项(个),可以表示:a,b,c,“a和b”,“a和c”,“b和c”,或“a和b和c”,其中a,b,c可以是单个,也可以是多个。It should be understood that in this application, "at least one (item)" refers to one or more, and "plurality" refers to two or more. "And/or" is used to describe the relationship between associated objects, indicating that there can be three relationships. For example, "A and/or B" can mean: only A exists, only B exists, and A and B exist simultaneously. , where A and B can be singular or plural. The character "/" generally indicates that the related objects are in an "or" relationship. “At least one of the following” or similar expressions thereof refers to any combination of these items, including any combination of a single item (items) or a plurality of items (items). For example, at least one of a, b or c can mean: a, b, c, "a and b", "a and c", "b and c", or "a and b and c" ”, where a, b, c can be single or multiple.
本申请实施例包括一种真空封装的半导体芯片。该半导体芯片可以为分立器件、如真空二极管、真空三级管等,也可以为由多个分立器件集成制作且真空封装的集成芯片,还可以为与其他芯片、电路真空封装在一起的芯片模组,如具有功率转换、信号处理等功能性元芯片。作为分立器件,本申请实施例的半导体芯片可以仅包括一个半导体器件。作为集成电路芯片,本申请实施例的半导体芯片中包括多个半导体器件。Embodiments of the present application include a vacuum-encapsulated semiconductor chip. The semiconductor chip can be a discrete device, such as a vacuum diode, a vacuum triode, etc., or it can be an integrated chip made of multiple discrete devices and vacuum-packaged, or it can be a chip mold that is vacuum-packaged with other chips and circuits. Groups, such as functional element chips with power conversion, signal processing, etc. As a discrete device, the semiconductor chip of the embodiment of the present application may include only one semiconductor device. As an integrated circuit chip, the semiconductor chip in the embodiment of the present application includes multiple semiconductor devices.
以图1示出的半导体芯片中半导体器件为真空电子管为例。本申请实施例的半导体器件100的结构,该半导体器件100包括衬底1、阴极结构2及阳极结构3。其中,衬底1可以为本征半导体材料、反向PN结或绝缘材料中的任一种。阴极结构2和阳极结构3均可以采用单晶硅、金属材料、N型半导体材料、多晶硅中的任一种等。为了扩大半导体器件100的单向导通特性、以及确保电子只在阴极结构2逸出,可以通过选择合适的电极材料或者对半导体电极掺杂调整功函数或费米能级,从而调整不同阴极结构2的电子逸出难度,增大了半导体器件100的单向导通性和降低半导体器件100的工作电压。Take the semiconductor device in the semiconductor chip shown in Figure 1 as a vacuum electron tube as an example. The structure of the semiconductor device 100 according to the embodiment of the present application, the semiconductor device 100 includes a substrate 1, a cathode structure 2 and an anode structure 3. Among them, the substrate 1 can be any one of intrinsic semiconductor material, reverse PN junction or insulating material. Both the cathode structure 2 and the anode structure 3 can be made of any one of single crystal silicon, metal materials, N-type semiconductor materials, polycrystalline silicon, etc. In order to expand the one-way conduction characteristics of the semiconductor device 100 and ensure that electrons only escape from the cathode structure 2 , the work function or Fermi level can be adjusted by selecting appropriate electrode materials or doping the semiconductor electrode, thereby adjusting different cathode structures 2 The difficulty of electrons escaping increases the one-way conductivity of the semiconductor device 100 and reduces the operating voltage of the semiconductor device 100 .
为了方便下文对描述,可以在部分附图中建立X、Y、Z坐标系。图1所示的衬底1的所在平面可以为XY平面,以图1中示出的衬底1为长方形为例,X轴可以为衬底1的长度方向,Y轴可以为衬底1的宽度方向,Z轴为垂直于或在制作公差范围内近似垂直于衬底1的方向。可以理解的是,衬底1的宽度的尺寸小于衬底1的长度的尺寸。In order to facilitate the following description, X, Y, and Z coordinate systems can be established in some drawings. The plane of the substrate 1 shown in Figure 1 can be an XY plane. Taking the substrate 1 shown in Figure 1 as a rectangle as an example, the X axis can be the length direction of the substrate 1, and the Y axis can be the length direction of the substrate 1. In the width direction, the Z-axis is perpendicular or approximately perpendicular to the substrate 1 within the manufacturing tolerance range. It can be understood that the width dimension of the substrate 1 is smaller than the length dimension of the substrate 1 .
如图2所示,若阴极结构2和阳极结构3同层设置且均通过介电层01设置在衬底1上,则受介电层01的材料、厚度、制作工艺等参数影响,介电层01不能保证阴极结构2、阳极结构3与衬底1具有良好的绝缘性能。所以,阴极结构2、阳极结构3会在衬底1上会存在一定漏电流。As shown in Figure 2, if the cathode structure 2 and the anode structure 3 are arranged on the same layer and are both arranged on the substrate 1 through the dielectric layer 01, the dielectric layer will be affected by the material, thickness, manufacturing process and other parameters of the dielectric layer 01. Layer 01 cannot guarantee good insulation properties between cathode structure 2, anode structure 3 and substrate 1. Therefore, the cathode structure 2 and the anode structure 3 will have a certain leakage current on the substrate 1 .
为了解决该问题,本申请实施例中的半导体器件100还包括多个如图3所示的绝缘支撑部4,多个绝缘支撑部4同层且间隔设置在衬底1上。该绝缘支撑部4可以具体采用SiO 2材料制作。上述阴极结构2设置在一个或多个上述绝缘支撑部4上。并且,阴极结构2仅设置在上述部分绝缘支撑部4上,而不是所有的绝缘支撑部4上。阳极结构3的一部分设置在上述剩余的部分绝缘支撑部4上,作为阳极结构3的支撑区。阳极结构3的另一部分悬空设置在阴极结构2的上方,以使阳极结构3与阴极结构2之间形成如图4所示的真空间隙δ。阳极结构3与阴极结构2为垂直结构。将阴极结构2接地,当阳极结构3施加正电压时,阴极结构2的表面产生一定的电场。当电场足够强时,电子从阴极结构2逸出,到达阳极结构3而产生电流。从而,实现真空电子管的功能。 In order to solve this problem, the semiconductor device 100 in the embodiment of the present application also includes a plurality of insulating support parts 4 as shown in FIG. 3 . The plurality of insulating support parts 4 are arranged in the same layer and spaced apart on the substrate 1 . The insulating support part 4 can be made of SiO 2 material. The above-mentioned cathode structure 2 is provided on one or more of the above-mentioned insulating supports 4 . Moreover, the cathode structure 2 is only provided on some of the above-mentioned insulating support parts 4 , rather than on all of the insulating support parts 4 . A part of the anode structure 3 is disposed on the remaining part of the insulating support part 4 as the support area of the anode structure 3 . Another part of the anode structure 3 is suspended above the cathode structure 2, so that a vacuum gap δ as shown in Figure 4 is formed between the anode structure 3 and the cathode structure 2. The anode structure 3 and the cathode structure 2 are vertical structures. The cathode structure 2 is grounded, and when a positive voltage is applied to the anode structure 3, a certain electric field is generated on the surface of the cathode structure 2. When the electric field is strong enough, electrons escape from the cathode structure 2 and reach the anode structure 3 to generate current. Thus, the function of a vacuum electron tube is realized.
所以,在半导体芯片1000进行真空封装后,由于阳极结构3上仅部分区域通过绝缘支撑部4设置在衬底1上,阳极结构3的其他部分区域悬空设置在阴极结构2的上方。所以,阳极结构3上悬空设置的部分区域与衬底1可以通过真空隔离开,减少了阳极结构3 与衬底1的接触面积。真空的绝缘性能比介电层01的绝缘性能更好。从而,可以提高半导体器件100的绝缘性能,减少了衬底1上的漏电流。Therefore, after the semiconductor chip 1000 is vacuum-packaged, only part of the anode structure 3 is disposed on the substrate 1 through the insulating support part 4 , and other parts of the anode structure 3 are suspended above the cathode structure 2 . Therefore, the partial area provided in the air on the anode structure 3 can be isolated from the substrate 1 by vacuum, thereby reducing the contact area between the anode structure 3 and the substrate 1 . The insulating properties of vacuum are better than those of dielectric layer 01. Therefore, the insulation performance of the semiconductor device 100 can be improved, and the leakage current on the substrate 1 can be reduced.
并且,本申请实施例半导体器件100中的多个绝缘支撑部4、阴极结构2及阳极结构3均可以采用现有COMS工艺进行集成制作。并且,垂直结构的阳极结构3和阴极结构2可以使得在相同面积的衬底1上可以集成更多的半导体器件100,增大半导体芯片1000的集成度。其中,悬空结构的阳极结构3可以通过制作牺牲层来形成。因此,半导体器件100可以实现纳米级制造,即半导体器件100为真空微纳电子管。其中,仅具有阴极结构2和阳极结构3的真空微纳电子管为真空微纳二极管。Moreover, the plurality of insulating support portions 4, cathode structures 2 and anode structures 3 in the semiconductor device 100 in the embodiment of the present application can all be integrated and manufactured using the existing COMS process. Moreover, the vertical structure of the anode structure 3 and the cathode structure 2 can enable more semiconductor devices 100 to be integrated on the same area of the substrate 1, thereby increasing the integration level of the semiconductor chip 1000. Among them, the suspended anode structure 3 can be formed by making a sacrificial layer. Therefore, the semiconductor device 100 can be manufactured at the nanoscale, that is, the semiconductor device 100 is a vacuum micro-nano electron tube. Among them, the vacuum micro-nano electron tube having only the cathode structure 2 and the anode structure 3 is a vacuum micro-nano diode.
图5示出了真空微纳二极管在线性坐标中电流-电压关系。图6示出了真空微纳二极管在对数坐标中电流-电压关系。从图5中可以看出,在线性坐标中,真空微纳二极管的电流与电压的关系为超线形。从图6中可以看出,在对数坐标中,电流与电压的关系介于指数关系与线性直线关系之间。Figure 5 shows the current-voltage relationship of a vacuum micro-nano diode in linear coordinates. Figure 6 shows the current-voltage relationship of a vacuum micro-nano diode in logarithmic coordinates. It can be seen from Figure 5 that in linear coordinates, the relationship between the current and voltage of the vacuum micro-nano diode is super linear. As can be seen from Figure 6, in logarithmic coordinates, the relationship between current and voltage is between the exponential relationship and the linear straight-line relationship.
此外,上述阴极结构2可以如图3所示直接设置在衬底上,也可以如图7所示部分区域设置在衬底1上。因此,图7所示的阴极结构2悬空设置在衬底1上,减少了阴极结构2与衬底1的接触面积,阴极结构2也可以与衬底1真空隔离开。从而,进一步提高了半导体器件100的绝缘性,减少了漏电问题。In addition, the above-mentioned cathode structure 2 may be directly disposed on the substrate as shown in FIG. 3 , or may be disposed partially on the substrate 1 as shown in FIG. 7 . Therefore, the cathode structure 2 shown in Figure 7 is suspended on the substrate 1, which reduces the contact area between the cathode structure 2 and the substrate 1. The cathode structure 2 can also be isolated from the substrate 1 in a vacuum. Therefore, the insulation of the semiconductor device 100 is further improved and leakage problems are reduced.
并且,上述真空微纳电子(二极)管中的阴极结构2可以制作为多种结构,通过改变阴极结构2的形状,可以改变电场在阴极结构2的聚集情况,从而改变半导体器件100的电学性能。本申请对此不作限制。以下阴极结构2悬空设置衬底1上进行举例说明。Moreover, the cathode structure 2 in the above-mentioned vacuum micro-nano electron (diode) tube can be made into a variety of structures. By changing the shape of the cathode structure 2, the accumulation of the electric field in the cathode structure 2 can be changed, thereby changing the electrical properties of the semiconductor device 100. performance. This application does not limit this. The cathode structure 2 is suspended on the substrate 1 for illustration below.
在一些实施例中,如图7所示,阴极结构2包括阴极阵列21,阴极阵列21由多个电子发射部211阵列排布形成。并且,多个电子发射部211与阳极结构3均相对设置。具有多个电子发射部211的阴极阵列21的边线长度较长,电子发射位置增多,从而增大了阴极结构2的总电流。并且,阴极结构2的面积小、结构紧凑,加工产量较高。In some embodiments, as shown in FIG. 7 , the cathode structure 2 includes a cathode array 21 , and the cathode array 21 is formed by an array arrangement of a plurality of electron emitting parts 211 . Furthermore, the plurality of electron emission parts 211 and the anode structure 3 are arranged opposite to each other. The cathode array 21 having multiple electron emitting parts 211 has a longer side length and more electron emitting positions, thereby increasing the total current of the cathode structure 2 . Moreover, the cathode structure 2 has a small area, compact structure, and high processing output.
并且,在一些示例中,上述阴极结构2还包括如图7所示的连接部22,连接部22与阴极阵列21中的多个电子发射部211均连接。并且,连接部22直接设置在绝缘支撑部4上,连接部22可以作为阴极结构2的支撑结构,如图8所示,以使阴极阵列21中的多个电子发射部211悬空设置在衬底1的上方。所以,多个电子发射部211可以完全悬空设置在衬底1上,减少了阴极结构2与衬底1的接触面积。多个电子发射部211可以与衬底1真空隔离开。从而,进一步提高了半导体器件100的绝缘性,减少了漏电问题。Moreover, in some examples, the above-mentioned cathode structure 2 further includes a connection part 22 as shown in FIG. 7 , and the connection part 22 is connected to the plurality of electron emission parts 211 in the cathode array 21 . Moreover, the connection part 22 is directly provided on the insulating support part 4, and the connection part 22 can be used as a support structure of the cathode structure 2, as shown in Figure 8, so that the plurality of electron emission parts 211 in the cathode array 21 are suspended on the substrate. above 1. Therefore, the plurality of electron emission parts 211 can be completely suspended on the substrate 1 , thereby reducing the contact area between the cathode structure 2 and the substrate 1 . The plurality of electron emission parts 211 may be vacuum isolated from the substrate 1 . Therefore, the insulation of the semiconductor device 100 is further improved and leakage problems are reduced.
上述阴极阵列21中的电子发射部211可以设计为边、角具有尖端结构的形状,使得电子容易从阴极结构2逸出。电子发射部211可以采用线发射或角发射的方式发射电子,具体可以根据实际电子发射要求进行选择。The electron emission part 211 in the above-mentioned cathode array 21 can be designed to have a shape with sharp edges and corners, so that electrons can easily escape from the cathode structure 2 . The electron emitting part 211 can emit electrons in a linear emission or angular emission manner, which can be selected according to actual electron emission requirements.
因此,电子发射部211可以为如图8所示的长条形,也可以为如图9所示的由多个圆形依次连接组成的形状,还可以为如图10所示的由多个圆角矩形依次连接组成的形状,还可以为如图11所示的由多个三角形依次连接组成的形状。在三角形的角处电场更容易聚集,具有更高的电子发射效率。并且,上述多个电子发射部211可以均平行间隔分布。图8至图10所示的多个电子发射部211均沿X轴所在方向间隔排布。相应地,阴极结构2可以包括两个连接部22a和22b,两个连接部22a和22b分别设置在多个电子发射部211的两端。一个连接部22a与多个电子发射部211的一端均连接,另一个连接部22b与多个 电子发射部211的另一端均连接。此外,上述阴极阵列21中的多个电子发射部211也可以呈其他形式分布。例如,图12所示的多个电子发射部211呈矩形阵列分布。又如,图13所示的多个电子发射部211呈矩形阵列分布圆形阵列分布。并且,图12和图13中阴极结构2的连接部22为多个,多个连接部22分别将相邻两个电子发射部211连接。本申请对多个电子发射部211的分布形式此不作限制。在另一些实施例中,上述阴极结构2仅包括一个电子发射部211,该电子发射部211可以采用发射位点较多的形状。例如,电子发射部211为呈蛇形盘绕的各种形状。图14示出的电子发射部211呈矩形,且沿衬底1的宽度方向延伸盘绕。此外,电子发射部211还可以呈圆形由内至外盘绕在衬底1上。本申请对此不作限制。Therefore, the electron emission part 211 may be in a long strip shape as shown in FIG. 8 , or may be in a shape composed of a plurality of circles connected in sequence as shown in FIG. 9 , or may be in a shape of a plurality of circles as shown in FIG. 10 . The shape formed by connecting rounded rectangles in sequence can also be a shape formed by connecting multiple triangles in sequence as shown in Figure 11. The electric field is more easily concentrated at the corners of the triangle, resulting in higher electron emission efficiency. Furthermore, the plurality of electron emission parts 211 may be distributed in parallel and spaced apart. The plurality of electron emission parts 211 shown in FIGS. 8 to 10 are all arranged at intervals along the direction of the X-axis. Correspondingly, the cathode structure 2 may include two connection parts 22a and 22b, which are respectively provided at both ends of the plurality of electron emission parts 211. One connection part 22a is connected to one end of the plurality of electron emitting parts 211, and the other connection part 22b is connected to the other ends of the plurality of electron emitting parts 211. In addition, the plurality of electron emission parts 211 in the above-mentioned cathode array 21 may also be distributed in other forms. For example, the plurality of electron emission parts 211 shown in FIG. 12 are distributed in a rectangular array. As another example, the plurality of electron emission parts 211 shown in FIG. 13 are distributed in a rectangular array and a circular array. Furthermore, in FIGS. 12 and 13 , the cathode structure 2 has a plurality of connecting portions 22 , and the plurality of connecting portions 22 respectively connect two adjacent electron emission portions 211 . This application does not limit the distribution form of the plurality of electron emission parts 211 . In other embodiments, the above-mentioned cathode structure 2 only includes one electron emission part 211, and the electron emission part 211 may adopt a shape with more emission sites. For example, the electron emission portion 211 has various shapes such as a serpentine coil. The electron emission part 211 shown in FIG. 14 has a rectangular shape and is extended and coiled in the width direction of the substrate 1 . In addition, the electron emission part 211 may also be coiled on the substrate 1 from the inside to the outside in a circular shape. This application does not limit this.
并且,呈蛇形盘绕的电子发射部211可以整体设置在绝缘支撑部4上,如图14所示。或者,由于该电子发射部211的尺寸较大,所以,如图15所示,可以将电子发射部211的一部分区域设置在绝缘支撑部4上作为支撑点。从而,将电子发射部211的其他部分区域可以悬空设置在衬底1上,同样可以减少衬底1上的漏电流。Furthermore, the electron-emitting part 211 coiled in a serpentine shape may be integrally disposed on the insulating support part 4, as shown in FIG. 14 . Alternatively, since the size of the electron emission part 211 is relatively large, as shown in FIG. 15 , a part of the electron emission part 211 may be provided on the insulating support part 4 as a support point. Therefore, other partial areas of the electron emission part 211 can be suspended on the substrate 1 , which can also reduce the leakage current on the substrate 1 .
上述主要说明了阴极结构2的结构,以下对本申请实施例中的阳极结构3进行说明。在一些实施例中,阳极结构3可以制作为如图15所示的近似“门”形。阳极结构3的表面平整,电场均匀且数值小,电子难以逸出,因此不会产生电流。The above mainly describes the structure of the cathode structure 2, and the anode structure 3 in the embodiment of the present application will be described below. In some embodiments, the anode structure 3 can be made into an approximate "gate" shape as shown in FIG. 15 . The surface of the anode structure 3 is flat, the electric field is uniform and small in value, and it is difficult for electrons to escape, so no current will be generated.
并且,上述阳极结构3可以采用揭开-剥离工艺制作。由于在绝缘支撑部4上直接制作阳极结构3,需要制作的阳极结构3厚度较大。所以,在本申请的一些实施例中,半导体器件100包括如图16和图17所示的阳极支撑部5,该阳极支撑部5设置在绝缘支撑部4与阳极结构3之间。在阳极支撑部5上通过揭开-剥离工艺制作阳极结构3时,所需制作的阳极结构3的厚度较小,从而节省材料。Moreover, the above-mentioned anode structure 3 can be manufactured using a peel-off process. Since the anode structure 3 is directly fabricated on the insulating support part 4, the thickness of the anode structure 3 that needs to be fabricated is relatively large. Therefore, in some embodiments of the present application, the semiconductor device 100 includes the anode support 5 as shown in FIGS. 16 and 17 , and the anode support 5 is disposed between the insulating support 4 and the anode structure 3 . When the anode structure 3 is made on the anode support part 5 through a peel-off process, the thickness of the anode structure 3 that needs to be made is smaller, thereby saving material.
并且,在一些实施例中,上述阳极支撑部5与阴极结构2同层同材料。阳极支撑部5和阴极结构2通过一道构图工艺制作,工艺流程简单。在本申请的一些实施例中,构图工艺,可指包括光刻工艺,或,包括光刻工艺以及刻蚀步骤;光刻工艺,是指包括成膜、曝光、显影等工艺过程的利用光刻胶、掩模板、曝光机等形成图形的工艺。可根据本申请中所形成的结构选择相应的构图工艺。Moreover, in some embodiments, the above-mentioned anode support part 5 and the cathode structure 2 are made of the same layer and the same material. The anode support part 5 and the cathode structure 2 are made through a patterning process, and the process flow is simple. In some embodiments of the present application, the patterning process may include a photolithography process, or include a photolithography process and an etching step; the photolithography process may refer to a process using photolithography including film formation, exposure, development, etc. Glue, mask, exposure machine, etc. are used to form patterns. The corresponding patterning process can be selected according to the structure formed in this application.
其中,本申请的实施例中的一次构图工艺,是以通过一次掩膜曝光工艺形成不同的曝光区域,然后对不同的曝光区域进行多次刻蚀、灰化等去除工艺最终得到预期图案为例进行的说明。Among them, the one-time patterning process in the embodiment of the present application is to form different exposure areas through a mask exposure process, and then perform multiple etching, ashing and other removal processes on the different exposure areas to finally obtain the expected pattern. instructions.
“同层”指的是采用同一成膜工艺形成用于形成特定图形的膜层,然后利用同一掩模板通过一次构图工艺形成的层结构。根据特定图形的不同,同一构图工艺可能包括多次曝光、显影或刻蚀工艺,而形成的层结构中的特定图形可以是连续的也可以是不连续的,这些特定图形还可能处于不同的高度或者具有不同的厚度。"Same layer" refers to a layer structure formed by using the same film-forming process to form a film layer for forming a specific pattern, and then using the same mask to form a patterning process. Depending on the specific pattern, the same patterning process may include multiple exposure, development or etching processes, and the specific patterns in the formed layer structure may be continuous or discontinuous, and these specific patterns may also be at different heights. Or have different thicknesses.
此外,阳极结构2除了可以设置为如图17所示的形状,还可以设计为仅在与阴极结构2相对的区域向下凹陷的形状,如图18和图19所示。本申请对此不作限制。In addition, in addition to the shape shown in FIG. 17 , the anode structure 2 may also be designed to be recessed downward only in the area opposite to the cathode structure 2 , as shown in FIGS. 18 and 19 . This application does not limit this.
以上仅说明了单独的半导体器件100结构,在本申请一些实施例中,如图20和图21所示,半导体芯片1000包括多个上述设置为真空二极管的半导体器件100,多个半导体器件100阵列排布在衬底1上。该半导体芯片1000中的多个半导体器件100可以现有COMS工艺集成制造,具备较好的尺寸一致性,较高的生产效率,产量和寿命均较高。从 而,半导体芯片1000在相同面积的衬底1可以集成更高密度的半导体器件100,集成度高,提高了半导体芯片1000的总电流。The above only describes the structure of a single semiconductor device 100. In some embodiments of the present application, as shown in Figures 20 and 21, the semiconductor chip 1000 includes a plurality of the above-mentioned semiconductor devices 100 configured as vacuum diodes, and an array of multiple semiconductor devices 100 arranged on substrate 1. Multiple semiconductor devices 100 in the semiconductor chip 1000 can be integrated and manufactured using the existing COMS process, and have better dimensional consistency, higher production efficiency, higher output and higher lifespan. Therefore, the semiconductor chip 1000 can integrate higher density semiconductor devices 100 on the same area of the substrate 1, and the integration level is high, which increases the total current of the semiconductor chip 1000.
需要说明的是,具有多个上述真空二极管的半导体芯片1000可以采用以下制作方法进行制作。如图22所示,该制作方法包括以下步骤:It should be noted that the semiconductor chip 1000 having a plurality of the above vacuum diodes can be manufactured using the following manufacturing method. As shown in Figure 22, the production method includes the following steps:
S100:获取具有由上至下依次层叠设置的阴极材料层20、绝缘层40、衬底1的基底10。S100: Obtain the substrate 10 with the cathode material layer 20, the insulating layer 40 and the substrate 1 stacked in sequence from top to bottom.
示例的,如图22中(a)所示,基底10可以直接获取,如基底10为SOI衬底,可以减少加工流程。阴极材料层20的材料和衬底1的材料均为单晶硅,绝缘层40为氧化层,如氧化层为SiO 2材料。 For example, as shown in (a) of FIG. 22 , the substrate 10 can be obtained directly. For example, if the substrate 10 is an SOI substrate, the processing flow can be reduced. The material of the cathode material layer 20 and the material of the substrate 1 are both single crystal silicon, and the insulating layer 40 is an oxide layer. For example, the oxide layer is SiO 2 material.
S200:在基底10中的阴极材料层20上形成阴极结构2。S200: Form the cathode structure 2 on the cathode material layer 20 in the substrate 10.
示例的,如图22中(b)和(c)所示,在基底10中的阴极材料层20上通过光刻工艺形成阴极结构2。如图22中(b)所示,可以先在基底10中的阴极材料层20上通过干法刻蚀形成光刻胶图案101。之后,如图22中(c)所示,将光刻胶图案101转移至阴极材料层20上,以形成阴极结构2。For example, as shown in (b) and (c) in FIG. 22 , the cathode structure 2 is formed on the cathode material layer 20 in the substrate 10 through a photolithography process. As shown in (b) of FIG. 22 , a photoresist pattern 101 may be first formed on the cathode material layer 20 in the substrate 10 by dry etching. Afterwards, as shown in (c) of FIG. 22 , the photoresist pattern 101 is transferred to the cathode material layer 20 to form the cathode structure 2 .
需要说明的是,若需制作具有阳极支撑部5的半导体芯片1000,则如图22中(c)所示可以在基底10中的阴极材料层20上通过同一道光刻工艺同时形成阴极结构2和阳极支撑部5。It should be noted that if it is necessary to manufacture the semiconductor chip 1000 with the anode support part 5, the cathode structure 2 can be formed simultaneously on the cathode material layer 20 in the substrate 10 through the same photolithography process as shown in FIG. 22(c) and anode support part 5.
S300:在阴极结构2和绝缘层40上形成用于支撑阳极结构3的悬空区域的牺牲部7。S300: Form the sacrificial portion 7 for supporting the suspended area of the anode structure 3 on the cathode structure 2 and the insulating layer 40.
示例的,如图22中(d)所示,可以经多道工艺在阴极结构2和绝缘层40上形成用于支撑阳极结构3的悬空区域的牺牲部7。For example, as shown in (d) of FIG. 22 , a sacrificial portion 7 for supporting the suspended region of the anode structure 3 can be formed on the cathode structure 2 and the insulating layer 40 through multiple processes.
S400:在牺牲部7的上方形成阳极结构3。S400: Form the anode structure 3 above the sacrificial part 7.
示例的,可以在牺牲部7的上方通过揭开-剥离工艺形成如图22中(e)所示的阳极结构3。阳极结构3采用揭开-剥离工艺制作,可以省掉刻蚀步骤,降低了真空封装的半导体芯片1000的制作成本。For example, the anode structure 3 as shown in (e) in FIG. 22 can be formed above the sacrificial part 7 through a lift-off process. The anode structure 3 is manufactured using a peel-off process, which can save the etching step and reduce the manufacturing cost of the vacuum-encapsulated semiconductor chip 1000.
S500:去除牺牲部7,获得阴极结构2、悬空设置在阴极结构2上的阳极结构3及阳极结构3与阴极结构2之间的真空间隙δ。S500: Remove the sacrificial part 7 to obtain the cathode structure 2, the anode structure 3 suspended on the cathode structure 2, and the vacuum gap δ between the anode structure 3 and the cathode structure 2.
示例的,如图22中(f)所示,可以通过腐蚀工艺去除牺牲部7。从而,获得阴极结构2、悬空设置在阴极结构2上的阳极结构3及阳极结构3与阴极结构2之间的真空间隙δ。For example, as shown in (f) of FIG. 22 , the sacrificial portion 7 can be removed through an etching process. Thereby, the cathode structure 2, the anode structure 3 suspended on the cathode structure 2, and the vacuum gap δ between the anode structure 3 and the cathode structure 2 are obtained.
S600:在基底10中的绝缘层40上形成多个绝缘支撑部4。S600: Form a plurality of insulating support portions 4 on the insulating layer 40 in the substrate 10.
示例的,如图22中(g)所示,可以通过腐蚀工艺将绝缘层40中的部分区域去除。从而,获得多个绝缘支撑部4。同时,在腐蚀过程中,还可以去除绝缘层40上位于阴极结构2的下方的一部分区域,从而获得悬空设置的阴极结构2。For example, as shown in (g) of FIG. 22 , part of the insulating layer 40 may be removed through an etching process. Thereby, a plurality of insulating support portions 4 are obtained. At the same time, during the etching process, a portion of the insulating layer 40 located below the cathode structure 2 can also be removed, thereby obtaining the cathode structure 2 arranged in the air.
在一些实施例中,如图23所示,上述S300具体包括:In some embodiments, as shown in Figure 23, the above S300 specifically includes:
S301:在阴极结构2的所在层上通过旋涂工艺和抛光工艺形成第一牺牲层70。S301: Form the first sacrificial layer 70 on the layer where the cathode structure 2 is located through a spin coating process and a polishing process.
示例的,如图23中(a)所示,先在阴极结构2的所在层上通过旋涂工艺形成第一牺牲层701a。第一牺牲层701a可以将阴极结构2中多个电子发射部211之间的间隙完全填满,且第一牺牲层701a的上表面高于阴极结构2。该第一牺牲层701a具体可以采用SiN材料制作。For example, as shown in FIG. 23(a) , the first sacrificial layer 701a is first formed on the layer where the cathode structure 2 is located through a spin coating process. The first sacrificial layer 701a can completely fill the gaps between the plurality of electron emission parts 211 in the cathode structure 2, and the upper surface of the first sacrificial layer 701a is higher than the cathode structure 2. The first sacrificial layer 701a can be made of SiN material.
之后,可以通过化学机械抛光工艺对第一牺牲层701a进行平坦化,并使阴极结构2和阳极支撑部5的顶面暴露,以获得如图23中(b)所示的第一牺牲层701。After that, the first sacrificial layer 701a can be planarized through a chemical mechanical polishing process, and the top surfaces of the cathode structure 2 and the anode support 5 can be exposed to obtain the first sacrificial layer 701 as shown in (b) of FIG. 23 .
S302:在第一牺牲层701和阴极结构2上通过原子层沉积工艺形成第二牺牲层702。S302: Form the second sacrificial layer 702 on the first sacrificial layer 701 and the cathode structure 2 through an atomic layer deposition process.
示例的,如图23中(c)所示,可以通过原子层沉积工艺在阴极结构2和第一牺牲层701上形成第二牺牲层702。具体地,该第二牺牲层702的材料也可以为SiN材料。原子层沉积工艺可以在纳米级尺度上精确控制第二牺牲层702的物质成分和形貌,从而精确控制阳极结构3与阴极结构2之间的真空间隙δ的尺寸。For example, as shown in (c) of FIG. 23 , the second sacrificial layer 702 may be formed on the cathode structure 2 and the first sacrificial layer 701 through an atomic layer deposition process. Specifically, the material of the second sacrificial layer 702 may also be SiN material. The atomic layer deposition process can precisely control the material composition and morphology of the second sacrificial layer 702 on the nanometer scale, thereby accurately controlling the size of the vacuum gap δ between the anode structure 3 and the cathode structure 2 .
需要说明的是,仅需形成第一牺牲层701和第二牺牲层702,可以用于制作截面呈近似“门”形的阳极结构3。而对于截面呈“门”形且在与阴极结构2相对的区域向下凹陷的形状的阳极结构3,如图25中(a)至(d)所示,除了制作第一牺牲层701和第二牺牲层702,还需要在第二牺牲层702上形成第三牺牲层703。第三牺牲材料层703具体可以为SiO 2It should be noted that only the first sacrificial layer 701 and the second sacrificial layer 702 need to be formed, which can be used to fabricate the anode structure 3 with an approximately "gate"-shaped cross section. As for the anode structure 3 which has a "gate" shape in cross section and is recessed downward in the area opposite to the cathode structure 2, as shown in (a) to (d) in Figure 25, in addition to making the first sacrificial layer 701 and the For the second sacrificial layer 702, it is also necessary to form a third sacrificial layer 703 on the second sacrificial layer 702. The third sacrificial material layer 703 may specifically be SiO 2 .
S303:在第二牺牲层702上通过光刻工艺形成用于支撑阳极结构3的悬空区域的牺牲部7。S303: Form the sacrificial portion 7 for supporting the suspended area of the anode structure 3 on the second sacrificial layer 702 through a photolithography process.
示例的,在一些实施例中,如图23中(d)所示,可以先在第二牺牲层702上通过干法刻蚀形成光刻胶图案102。之后,如图23中(e)所示,可以将光刻胶图案102转移至第二牺牲层702上,形成牺牲部7。该牺牲部7用于支撑如图24所示的阳极结构3。For example, in some embodiments, as shown in (d) of FIG. 23 , the photoresist pattern 102 may first be formed on the second sacrificial layer 702 by dry etching. Afterwards, as shown in (e) of FIG. 23 , the photoresist pattern 102 can be transferred to the second sacrificial layer 702 to form the sacrificial portion 7 . The sacrificial part 7 is used to support the anode structure 3 as shown in Figure 24.
在另一些实施例中,如图25中(e)所示,可以先在第二牺牲层702和第三牺牲层703上通过干法刻蚀形成光刻胶图案102。之后,如图25中(f)所示,可以将光刻胶图案102转移至第二牺牲层702和第三牺牲层703上,获得第一牺牲部71和过渡牺牲部72a。然后,如图26中(g)所示,可以在过渡牺牲部72a上通过干法刻蚀形成光刻胶图案103。最后,如图26中(h)所示,可以将光刻胶图案103转移至过渡牺牲部72a上,获得第二牺牲部72。具有第一牺牲部71和第二牺牲部72的牺牲部7用于支撑如图22中(e)所示的阳极结构3。In other embodiments, as shown in (e) of FIG. 25 , the photoresist pattern 102 may be first formed on the second sacrificial layer 702 and the third sacrificial layer 703 by dry etching. After that, as shown in (f) of FIG. 25 , the photoresist pattern 102 can be transferred to the second sacrificial layer 702 and the third sacrificial layer 703 to obtain the first sacrificial part 71 and the transition sacrificial part 72a. Then, as shown in (g) of FIG. 26 , a photoresist pattern 103 may be formed on the transition sacrificial portion 72 a by dry etching. Finally, as shown in (h) of FIG. 26 , the photoresist pattern 103 can be transferred to the transition sacrificial portion 72 a to obtain the second sacrificial portion 72 . The sacrificial part 7 having the first sacrificial part 71 and the second sacrificial part 72 is used to support the anode structure 3 as shown in (e) of FIG. 22 .
需要说明的是,图22、图23、图24及图25均仅示出了半导体芯片1000中的一个半导体器件的制作。可以理解的是,半导体芯片1000中的多个半导体器件中各层结构均可以在同一道工艺下同时制作的,此处不在详细说明。It should be noted that FIG. 22 , FIG. 23 , FIG. 24 and FIG. 25 only show the production of one semiconductor device in the semiconductor chip 1000 . It can be understood that the structures of each layer of the multiple semiconductor devices in the semiconductor chip 1000 can be fabricated simultaneously under the same process, and will not be described in detail here.
以上实施例均是以半导体器件100为真空二极管为例进行说明,上述半导体器件100还可以为真空三级管。因此,在本申请的一些实施例中,上述半导体器件100还包括如图26和图27所示的栅极结构6,栅极结构6设置在衬底1上。并且,栅极结构6与阴极结构2同层且间隔设置,并绕射在阴极结构2外。从而,获得真空三级管。The above embodiments are all described by taking the semiconductor device 100 as a vacuum diode as an example. The semiconductor device 100 may also be a vacuum triode. Therefore, in some embodiments of the present application, the above-mentioned semiconductor device 100 further includes a gate structure 6 as shown in FIGS. 26 and 27 , and the gate structure 6 is disposed on the substrate 1 . Moreover, the gate structure 6 is in the same layer as the cathode structure 2 and is arranged at intervals, and is diffracted outside the cathode structure 2 . Thus, a vacuum three-stage tube is obtained.
在阳极结构3施加电压时,阴极结构2的表面产生电场,电子从阴极结构2逸出,通过真空间隙δ到达阳极结构3形成电流。在上述过程中,可以通过给栅极结构6施加不同电压来调制阴极结构2的电场强度来改变阴极结构2发射电子流的强度。从而,控制半导体器件100中电流的大小和开关。其中,上述栅极结构6的输入电压应位于阴极结构2的输入电压与阳极结构3的输入电压之间。该真空三级管同样可以采用现有CMOS工艺制作,实现纳米级工艺。因此,该真空三级管为真空微纳三极管。When a voltage is applied to the anode structure 3, an electric field is generated on the surface of the cathode structure 2, and electrons escape from the cathode structure 2 and reach the anode structure 3 through the vacuum gap δ to form a current. In the above process, the intensity of the electron flow emitted by the cathode structure 2 can be changed by applying different voltages to the gate structure 6 to modulate the electric field intensity of the cathode structure 2 . Thereby, the magnitude and switching of the current in the semiconductor device 100 are controlled. The input voltage of the gate structure 6 should be between the input voltage of the cathode structure 2 and the input voltage of the anode structure 3 . The vacuum triode can also be made using existing CMOS technology to achieve nanoscale technology. Therefore, the vacuum triode is a vacuum micro-nano triode.
图28示出了真空微纳三极管的输出特性。图28中的线条1至线条6的栅极电压不同,线条1的栅极电压最大,线条6的栅极电压最小。从图28可以看出,真空微纳三极管具 有如下物理特性:栅极结构6的电压越大,阴极结构2发射电子所需的阳极结构3电压越低,且阴极结构2的电流增大越快。图29示出了真空微纳三极管的转移特性。从图29可以看出,真空微纳三极管具有如下物理特性:栅极结构6的电压越大,阴极结构2的电流越大。Figure 28 shows the output characteristics of the vacuum micro-nano triode. The gate voltages of line 1 to line 6 in Figure 28 are different. The gate voltage of line 1 is the largest, and the gate voltage of line 6 is the smallest. It can be seen from Figure 28 that the vacuum micro-nano triode has the following physical characteristics: the greater the voltage of the gate structure 6, the lower the voltage of the anode structure 3 required for the cathode structure 2 to emit electrons, and the faster the current of the cathode structure 2 increases. . Figure 29 shows the transfer characteristics of the vacuum micro-nano triode. It can be seen from Figure 29 that the vacuum micro-nano triode has the following physical characteristics: the greater the voltage of the gate structure 6, the greater the current of the cathode structure 2.
需要注意的是,在一些实施例中,如图27所示,上述阴极结构2直接设置在衬底1上。栅极结构6悬空设置在在衬底1上,且与阳极支撑部5同层同材料设置。在另一些实施例中,上述栅极结构6可以与阴极结构2位置交换。如图30所示,栅极结构6直接设置在衬底1上。阴极结构2悬空设置在衬底1上,且与阳极支撑部5同层同材料。本申请对此不作限制。It should be noted that in some embodiments, as shown in FIG. 27 , the above-mentioned cathode structure 2 is directly disposed on the substrate 1 . The gate structure 6 is suspended on the substrate 1 and is provided in the same layer and material as the anode support 5 . In other embodiments, the above-mentioned gate structure 6 may be interchanged with the cathode structure 2 . As shown in FIG. 30 , the gate structure 6 is directly provided on the substrate 1 . The cathode structure 2 is suspended on the substrate 1 and is of the same layer and material as the anode support part 5 . This application does not limit this.
并且,如图31至图34所示,上述真空三极管中阴极结构2的结构和形状可以与真空二极管中的阴极结构2的结构和形状类似。图31中示出了真空三极管中的阴极结构2包括多个圆形的电子发射部211。图32中示出了真空三极管中的阴极结构2包括多个圆角矩形的电子发射部211。图33中示出了真空三极管中的阴极结构2包括多个三角形的电子发射部211。图34示出了示出了真空三极管中的阴极结构2包括一个呈蛇形盘绕的电子发射部211。Moreover, as shown in FIGS. 31 to 34 , the structure and shape of the cathode structure 2 in the above-mentioned vacuum triode may be similar to the structure and shape of the cathode structure 2 in the vacuum diode. FIG. 31 shows that the cathode structure 2 in the vacuum triode includes a plurality of circular electron-emitting parts 211. FIG. 32 shows that the cathode structure 2 in the vacuum triode includes a plurality of rounded rectangular electron emission parts 211 . FIG. 33 shows that the cathode structure 2 in the vacuum triode includes a plurality of triangular electron-emitting parts 211. Figure 34 shows that the cathode structure 2 in the vacuum triode includes a serpentine coiled electron emission part 211.
对于上述结构的半导体器件100,在本申请一些实施例中,如图35和图36所示,上述半导体芯片1000包括多个上述设置为真空三极管的半导体器件100,多个半导体器件100阵列排布在衬底1上。该半导体芯片1000中的多个半导体器件100可以现有COMS工艺集成制造,具备较好的尺寸一致性,较高的生产效率,产量和寿命均较高。从而,半导体芯片1000在相同面积的衬底1可以集成更高密度的半导体器件100,集成度高,提高了半导体芯片1000的总电流。For the semiconductor device 100 with the above structure, in some embodiments of the present application, as shown in FIGS. 35 and 36 , the above semiconductor chip 1000 includes a plurality of the above semiconductor devices 100 configured as vacuum triodes, and the plurality of semiconductor devices 100 are arranged in an array. on substrate 1. Multiple semiconductor devices 100 in the semiconductor chip 1000 can be integrated and manufactured using the existing COMS process, and have better dimensional consistency, higher production efficiency, higher output and higher lifespan. Therefore, the semiconductor chip 1000 can integrate higher density semiconductor devices 100 on the same area of the substrate 1 , and the integration level is high, which increases the total current of the semiconductor chip 1000 .
并且,相较于图37所示的半导体器件100,该半导体器件100中的阳极结构3和阴极结构2同层设置,同时在阳极结构3和阴极结构2的相对面上加工用于放电的尖端结构。由于阴极结构2和阳极结构3的厚度(厚度方向为图37中的Z轴方向)较小,所以,加工尖端结构的难度较大。而本申请实施例中的半导体器件100中的阴极结构2和阳极结构3不需在自身侧面上进行精细的加工,加工难度较低。Moreover, compared with the semiconductor device 100 shown in FIG. 37 , the anode structure 3 and the cathode structure 2 in the semiconductor device 100 are arranged on the same layer, and at the same time, tips for discharge are processed on the opposite surfaces of the anode structure 3 and the cathode structure 2 structure. Since the thickness of the cathode structure 2 and the anode structure 3 is small (the thickness direction is the Z-axis direction in FIG. 37), it is more difficult to process the tip structure. However, the cathode structure 2 and the anode structure 3 in the semiconductor device 100 in the embodiment of the present application do not need to be finely processed on their own sides, and the processing difficulty is relatively low.
需要说明的是,本申请实施例的半导体芯片1000还可以既包括多个上述设置为真空三极管的半导体器件100,还包括多个上述设置的真空二极管。并且,该半导体芯片1000还可以包括其他半导体器件,本申请对此不作限制。It should be noted that the semiconductor chip 1000 in the embodiment of the present application may also include a plurality of the above-mentioned semiconductor devices 100 configured as vacuum triodes, and a plurality of the above-mentioned vacuum diodes. Moreover, the semiconductor chip 1000 may also include other semiconductor devices, which is not limited in this application.
此外,本申请实施例还包括一种具有多个上述真空三极管的半导体芯片1000的制作方法。图38中(a)至(g)分别为真空三极管的半导体芯片1000的制作方法中各种工艺步骤对应的结构示意图。图39中(a)至(h)为真空三极管的半导体芯片1000的制作方法中牺牲部的各种工艺步骤对应的结构示意图。从图38和图39可以看出,上述具有多个上述真空三极管的半导体芯片1000的制作方法与具有多个上述真空二极管的半导体芯片1000的制作方法类似。区别在于,在具有多个上述真空三极管的半导体芯片1000的制作方法中,参照图40,上述步骤S100具体包括:In addition, embodiments of the present application also include a method of manufacturing a semiconductor chip 1000 having a plurality of the above vacuum triodes. (a) to (g) in FIG. 38 are schematic structural diagrams corresponding to various process steps in the manufacturing method of the semiconductor chip 1000 of the vacuum triode. (a) to (h) in FIG. 39 are schematic structural diagrams corresponding to various process steps of the sacrificial portion in the manufacturing method of the semiconductor chip 1000 of the vacuum triode. It can be seen from FIG. 38 and FIG. 39 that the manufacturing method of the semiconductor chip 1000 having multiple vacuum triodes is similar to the manufacturing method of the semiconductor chip 1000 having multiple vacuum diodes. The difference is that in the manufacturing method of the semiconductor chip 1000 having a plurality of the above-mentioned vacuum triodes, referring to FIG. 40, the above-mentioned step S100 specifically includes:
上述S100具体包括:The above-mentioned S100 specifically includes:
S101:获取衬底1。S101: Obtain substrate 1.
示例的,如图40中(a)所示,衬底1可以为硅衬底,并在衬底1的上表面1a上进 行N型重掺杂,以保证硅衬底1的上表面的导电性和较高的费米能级。For example, as shown in (a) of Figure 40, the substrate 1 can be a silicon substrate, and the upper surface 1a of the substrate 1 is heavily doped with N-type to ensure the conductivity of the upper surface of the silicon substrate 1. properties and a higher Fermi level.
S102:在衬底1上形成栅极结构6。S102: Form gate structure 6 on substrate 1.
示例的,可以通过光刻工艺在衬底1上形成如图40中(b)所示的栅极结构6。For example, the gate structure 6 as shown in (b) of FIG. 40 can be formed on the substrate 1 through a photolithography process.
S103:在衬底1的上方、栅极结构6的上方及侧壁上形成绝缘层40。S103: Form an insulating layer 40 above the substrate 1, above the gate structure 6 and on the side walls.
示例的,可以先在具有栅极结构6的衬底1上通过旋涂工艺形成如图40中(c)所示的绝缘层40a。绝缘层可以为玻璃材料。所以,换句话说,采用旋涂玻璃法(spin on glass,SOG)在具有栅极结构6的衬底1上形成绝缘层40a。在凹陷处(即衬底1上)的绝缘层40a更厚,而在凸起处(即栅极结构6上)的绝缘层40a较薄。For example, the insulating layer 40a as shown in (c) in FIG. 40 may be first formed on the substrate 1 having the gate structure 6 through a spin coating process. The insulation layer can be made of glass material. So, in other words, the insulating layer 40a is formed on the substrate 1 having the gate structure 6 using a spin on glass (SOG) method. The insulating layer 40a is thicker at the recesses (ie, on the substrate 1), while the insulating layer 40a is thinner at the protrusions (ie, on the gate structure 6).
然后,可以通过回刻蚀工艺将衬底1上的绝缘层40a减薄,而将栅极结构6上的绝缘层40a保留,获得如图40中(d)所示的绝缘层40b。Then, the insulating layer 40a on the substrate 1 can be thinned through an etching back process, while the insulating layer 40a on the gate structure 6 is retained, to obtain the insulating layer 40b as shown in (d) of FIG. 40 .
之后,可以如图40中(e)所示采用原子层沉积工艺在栅极结构6的上方及侧壁上形成绝缘层40。从而,完成在衬底1的上方、栅极结构6的上方及侧壁上形成绝缘层40。其中,原子层沉积工艺可以精确控制所形成绝缘层40的厚度,从而精确控制栅极结构6与阴极结构2之间的间隙。Afterwards, as shown in (e) of FIG. 40 , an atomic layer deposition process can be used to form an insulating layer 40 above and on the sidewalls of the gate structure 6 . Thus, the insulating layer 40 is formed above the substrate 1, above the gate structure 6, and on the side walls. Among them, the atomic layer deposition process can accurately control the thickness of the insulating layer 40 formed, thereby accurately controlling the gap between the gate structure 6 and the cathode structure 2 .
S104:在绝缘层40上形成阴极材料层20。S104: Form the cathode material layer 20 on the insulating layer 40.
示例的,可以如图40中(f)所示先通过沉积工艺(如物理气象沉积工艺或化学气象沉积工艺)形成阴极材料层20。阴极材料层20可以将绝缘层40中的间隙完全填满。具体地,该阴极材料层20可以为多晶硅材料。For example, as shown in (f) of FIG. 40 , the cathode material layer 20 can be first formed through a deposition process (such as a physical vapor deposition process or a chemical vapor deposition process). The cathode material layer 20 can completely fill the gap in the insulating layer 40 . Specifically, the cathode material layer 20 may be polysilicon material.
之后,可以如图40中(g)所示通过化学机械抛光(chemical mechanical polishing,CMP)工艺对阴极材料层20进行平坦化,并使栅极结构6的顶面暴露。从而,获得阴极材料层20。After that, the cathode material layer 20 can be planarized through a chemical mechanical polishing (CMP) process as shown in (g) of FIG. 40 , and the top surface of the gate structure 6 can be exposed. Thereby, the cathode material layer 20 is obtained.
因此,通过上述多道CMOS工艺可以制作具有由上至下依次层叠设置的阴极材料层20、绝缘层40、衬底1的基底10。Therefore, the substrate 10 having the cathode material layer 20, the insulating layer 40 and the substrate 1 stacked sequentially from top to bottom can be manufactured through the above-mentioned multi-channel CMOS process.
以上所述,仅为本申请的具体实施方式,但本申请的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本申请揭露的技术范围内,可轻易想到变化或替换,都应涵盖在本申请的保护范围之内。因此,本申请的保护范围应以所述权利要求的保护范围为准。The above are only specific embodiments of the present application, but the protection scope of the present application is not limited thereto. Any person familiar with the technical field can easily think of changes or substitutions within the technical scope disclosed in the present application. should be covered by the protection scope of this application. Therefore, the protection scope of this application should be subject to the protection scope of the claims.

Claims (16)

  1. 一种真空封装的半导体芯片,其特征在于,包括至少一个半导体器件,所述半导体器件包括:A vacuum-encapsulated semiconductor chip is characterized in that it includes at least one semiconductor device, and the semiconductor device includes:
    衬底;substrate;
    多个同层且间隔设置的绝缘支撑部,所述多个绝缘支撑部均设置在所述衬底上;A plurality of insulating support parts in the same layer and spaced apart, the plurality of insulating support parts are all provided on the substrate;
    阴极结构,所述阴极结构设置在至少一个所述绝缘支撑部上;a cathode structure, the cathode structure being disposed on at least one of the insulating supports;
    阳极结构,所述阳极结构的一部分设置在所述绝缘支撑部上,所述阳极结构的另一部分悬空设置在所述阴极结构的上方,以使所述阳极结构与所述阴极结构之间形成真空间隙。An anode structure, a part of the anode structure is arranged on the insulating support part, and the other part of the anode structure is suspended above the cathode structure, so that a vacuum is formed between the anode structure and the cathode structure gap.
  2. 根据权利要求1所述的真空封装的半导体芯片,其特征在于,所述阴极结构包括:The vacuum-encapsulated semiconductor chip according to claim 1, wherein the cathode structure includes:
    阴极阵列,所述阴极阵列由多个电子发射部阵列排布形成,且所述多个电子发射部与所述阳极结构均相对设置。The cathode array is formed by an array arrangement of a plurality of electron emitting parts, and the plurality of electron emitting parts are arranged opposite to the anode structure.
  3. 根据权利要求2所述的真空封装的半导体芯片,其特征在于,所述阴极结构还包括:The vacuum-encapsulated semiconductor chip according to claim 2, wherein the cathode structure further includes:
    连接部,所述连接部设置在所述绝缘支撑部上,且与所述阴极阵列中的多个电子发射部均连接,以使所述阴极阵列悬空设置在所述衬底的上方。A connection part is provided on the insulating support part and is connected to a plurality of electron emission parts in the cathode array, so that the cathode array is suspended above the substrate.
  4. 根据权利要求2或3所述的真空封装的半导体芯片,其特征在于,所述电子发射部均为长条形、或者由多个三角形、多个圆形及多个圆角矩形中任一种依次连接组成的形状。The vacuum-encapsulated semiconductor chip according to claim 2 or 3, characterized in that the electron emission parts are all in a long strip shape, or are composed of any one of a plurality of triangles, a plurality of circles and a plurality of rounded rectangles. Connect the resulting shapes in sequence.
  5. 根据权利要求1所述的真空封装的半导体芯片,其特征在于,所述阴极结构包括呈蛇形盘绕设置的电子发射部,所述电子发射部的一部分设置在所述绝缘支撑部上。The vacuum-encapsulated semiconductor chip according to claim 1, wherein the cathode structure includes an electron-emitting part arranged in a serpentine coil, and a part of the electron-emitting part is arranged on the insulating support part.
  6. 根据权利要求1-5中任一项所述的真空封装的半导体芯片,其特征在于,所述半导体器件包括:The vacuum-encapsulated semiconductor chip according to any one of claims 1-5, wherein the semiconductor device includes:
    阳极支撑部,所述阳极支撑部设置在所述绝缘支撑部与所述阳极结构之间。An anode support part is provided between the insulating support part and the anode structure.
  7. 根据权利要6所述的真空封装的半导体芯片,其特征在于,所述阴极结构与所述阳极支撑部同层同材料。The vacuum-encapsulated semiconductor chip according to claim 6, wherein the cathode structure and the anode support part are in the same layer and made of the same material.
  8. 根据权利要求1-7所述的真空封装的半导体芯片,其特征在于,所述半导体器件还包括:The vacuum-encapsulated semiconductor chip according to claims 1-7, wherein the semiconductor device further includes:
    栅极结构,所述栅极结构设置在所述衬底上;所述栅极结构与所述阴极结构同层且间隔设置,并绕射在所述阴极结构外。A gate structure is provided on the substrate; the gate structure is in the same layer and spaced apart from the cathode structure, and is diffracted outside the cathode structure.
  9. 根据权利要求1-8中任一项所述的真空封装的半导体芯片,其特征在于,包括多个所述半导体器件,多个所述半导体器件阵列分布在所述衬底上。The vacuum-encapsulated semiconductor chip according to any one of claims 1 to 8, characterized in that it includes a plurality of the semiconductor devices, and a plurality of the semiconductor device arrays are distributed on the substrate.
  10. 一种用于制作上述权利要求1-9中任一项所述的真空封装的半导体芯片的制作方法,其特征在于,包括以下步骤:A manufacturing method for manufacturing the vacuum-encapsulated semiconductor chip according to any one of the above claims 1-9, characterized in that it includes the following steps:
    获取具有由上至下依次层叠设置的阴极材料层、绝缘层、衬底的基底;Obtain a substrate with a cathode material layer, an insulating layer, and a substrate stacked sequentially from top to bottom;
    在所述基底中的阴极材料层上形成阴极结构;forming a cathode structure on the cathode material layer in the substrate;
    在所述阴极结构和所述绝缘层上形成用于支撑阳极结构的悬空区域的牺牲部;forming a sacrificial portion for supporting a suspended region of the anode structure on the cathode structure and the insulating layer;
    在所述牺牲部的上方形成阳极结构;forming an anode structure above the sacrificial part;
    去除所述牺牲部,获得阴极结构、悬空设置在所述阴极结构上的阳极结构、及所述阳极结构与所述阴极结构之间的真空间隙;Remove the sacrificial part to obtain a cathode structure, an anode structure suspended on the cathode structure, and a vacuum gap between the anode structure and the cathode structure;
    去除所述绝缘层的部分区域,获得多个所述绝缘支撑部。Partial areas of the insulating layer are removed to obtain a plurality of insulating support parts.
  11. 根据权利要求10所述的真空封装的半导体芯片的制作方法,其特征在于,所述在所述阴极结构和所述绝缘层上形成用于与阳极结构的悬空区域对应的牺牲部具体包括:The method of manufacturing a vacuum-encapsulated semiconductor chip according to claim 10, wherein forming a sacrificial portion corresponding to the suspended region of the anode structure on the cathode structure and the insulating layer specifically includes:
    在所述阴极结构的所在层上通过旋涂工艺和抛光工艺形成第一牺牲层;Form a first sacrificial layer on the layer where the cathode structure is located through a spin coating process and a polishing process;
    在所述第一牺牲层和所述阴极结构上通过原子层沉积工艺形成第二牺牲层;forming a second sacrificial layer on the first sacrificial layer and the cathode structure through an atomic layer deposition process;
    在所述第二牺牲层上通过光刻工艺形成用于支撑阳极结构的悬空区域的牺牲部。A sacrificial portion for supporting the suspended region of the anode structure is formed on the second sacrificial layer through a photolithography process.
  12. 根据权利要求10或11所述的真空封装的半导体芯片的制作方法,其特征在于,所述去除所述绝缘层的部分区域,获得多个所述绝缘支撑部包括:The method for manufacturing a vacuum-encapsulated semiconductor chip according to claim 10 or 11, wherein removing part of the insulating layer to obtain a plurality of insulating support parts includes:
    去除所述绝缘层上位于所述阴极结构的下方的一部分区域,获得悬空设置的阴极结构。A portion of the insulating layer located below the cathode structure is removed to obtain a suspended cathode structure.
  13. 根据权利要求10或11所述的真空封装的半导体芯片的制作方法,其特征在于,所述在所述基底中的阴极材料层上形成阴极结构具体包括:The method for manufacturing a vacuum-encapsulated semiconductor chip according to claim 10 or 11, wherein forming a cathode structure on the cathode material layer in the substrate specifically includes:
    在所述基底中的阴极材料层上通过光刻工艺形成阴极结构和阳极支撑部。A cathode structure and an anode support are formed on the cathode material layer in the substrate through a photolithography process.
  14. 根据权利要求10-13中任一项所述的真空封装的半导体芯片的制作方法,其特征在于,所述基底为SOI衬底。The method for manufacturing a vacuum-encapsulated semiconductor chip according to any one of claims 10 to 13, wherein the substrate is an SOI substrate.
  15. 根据权利要求10-13中任一项所述的真空封装的半导体芯片的制作方法,其特征在于,所述获取具有由上至下依次层叠设置的阴极材料层、绝缘层、衬底的基底具体包括:The method for manufacturing a vacuum-encapsulated semiconductor chip according to any one of claims 10 to 13, wherein the step of obtaining a substrate having a cathode material layer, an insulating layer, and a substrate that are stacked sequentially from top to bottom is specifically include:
    获取衬底;Get the substrate;
    在所述衬底上形成栅极结构;forming a gate structure on the substrate;
    在所述衬底的上方、所述栅极结构的上方及侧壁上形成绝缘层;forming an insulating layer above the substrate, above the gate structure and on the sidewalls;
    在所述绝缘层上形成阴极材料层。A layer of cathode material is formed on the insulating layer.
  16. 根据权利要求10-15中任一项所述的真空封装的半导体芯片的制作方法,其特征在于,所述在所述牺牲部的上方形成阳极结构具体包括:The method for manufacturing a vacuum-encapsulated semiconductor chip according to any one of claims 10 to 15, wherein forming an anode structure above the sacrificial part specifically includes:
    在所述牺牲部的上方通过揭开-剥离工艺形成阳极结构。An anode structure is formed above the sacrificial part through a lift-off process.
PCT/CN2022/115575 2022-08-29 2022-08-29 Vacuum-encapsulated semiconductor chip and manufacturing method therefor WO2024044906A1 (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05159696A (en) * 1991-12-03 1993-06-25 Sharp Corp Electric field emission type electron element
US20030146689A1 (en) * 2002-02-04 2003-08-07 Innosys, Inc. Solid state vacuum devices and method for making the same
CN1643636A (en) * 2001-06-14 2005-07-20 海珀里昂催化国际有限公司 Field emission devices using modified carbon nanotubes
US8814622B1 (en) * 2011-11-17 2014-08-26 Sandia Corporation Method of manufacturing a fully integrated and encapsulated micro-fabricated vacuum diode

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05159696A (en) * 1991-12-03 1993-06-25 Sharp Corp Electric field emission type electron element
CN1643636A (en) * 2001-06-14 2005-07-20 海珀里昂催化国际有限公司 Field emission devices using modified carbon nanotubes
US20030146689A1 (en) * 2002-02-04 2003-08-07 Innosys, Inc. Solid state vacuum devices and method for making the same
US8814622B1 (en) * 2011-11-17 2014-08-26 Sandia Corporation Method of manufacturing a fully integrated and encapsulated micro-fabricated vacuum diode

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