WO2024042900A1 - Electrolytic hydrogen aspirator having heating-type aromatic gas aspiration function - Google Patents

Electrolytic hydrogen aspirator having heating-type aromatic gas aspiration function Download PDF

Info

Publication number
WO2024042900A1
WO2024042900A1 PCT/JP2023/025697 JP2023025697W WO2024042900A1 WO 2024042900 A1 WO2024042900 A1 WO 2024042900A1 JP 2023025697 W JP2023025697 W JP 2023025697W WO 2024042900 A1 WO2024042900 A1 WO 2024042900A1
Authority
WO
WIPO (PCT)
Prior art keywords
hydrogen
positive
battery
negative electrodes
aromatic gas
Prior art date
Application number
PCT/JP2023/025697
Other languages
French (fr)
Japanese (ja)
Inventor
隆 竹原
Original Assignee
隆 竹原
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 隆 竹原 filed Critical 隆 竹原
Publication of WO2024042900A1 publication Critical patent/WO2024042900A1/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61MDEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
    • A61M15/00Inhalators
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00Operating or servicing cells

Definitions

  • the present invention relates to an electrolytic hydrogen suction device with a heating aromatic gas suction function that is portable and capable of safely and stably supplying hydrogen gas while maintaining generation of a predetermined amount of hydrogen gas during suction.
  • active oxygen hydroxyl radicals
  • Patent Document 1 there is a method of ingesting hydrogen into the body by inhalation, and there is an electrolytic hydrogen inhalation device that electrolyzes electrolyzed water to generate hydrogen and inhales the hydrogen orally.
  • Patent Document 2 an electrolytic hydrogen inhalation device that electrolyzes electrolyzed water to generate hydrogen and inhales the hydrogen orally.
  • Patent Document 3rd and 4th grade a portable hydrogen suction device using a rechargeable battery that makes it easy to obtain health-promoting effects and can inhale an appropriate amount of hydrogen on a daily basis.
  • Patent Document See 3rd and 4th grade.
  • a portable hydrogen suction device with a heated aromatic gas suction function has been provided.
  • it is possible to configure a portable hydrogen suction and supply device by combining an existing heating type circuit configuration with a power supply circuit for electrolysis for hydrogen generation, which can follow existing technology and is easy to develop.
  • heated aromatic gas suction devices and electronic cigarette suction devices use electrical circuit configurations that are relatively easy to design, as the amount of suction required changes depending on the user's preference.
  • the operation was performed at a "constant voltage" according to the electromotive force. Therefore, especially at a stage when the effectiveness of hydrogen was unclear, the electric circuit configuration of conventional heated aromatic gas suction devices was followed, and the amount of hydrogen supplied was not precisely managed.
  • the inventor has provided the results of clinical trials regarding the health effects of hydrogen, and it was desired to develop and provide a hydrogen supply device that effectively obtains the health promoting effects based on those clinical trials.
  • an appropriate amount of hydrogen suction is required. It is necessary to maintain the amount of hydrogen generated at a predetermined amount.
  • the resistance value increases due to deterioration of the electrodes and changes in the electrolyzed water, and the current value changes, so the amount of hydrogen supplied depends on the current value.
  • the hydrogen generated from the electrolyzer is a flammable gas, so the selection of batteries and electrodes should be done at the initial design stage to limit the amount of hydrogen supplied to a safe concentration (4% or less). It is necessary to set the distance.
  • hydrogen suction device with a heated aromatic gas suction function hydrogen is generated by electrolysis in the electrolytic cell, and at the same time separate steam is generated using a heated aromatic gas generation cartridge, etc., so the heat source ( There is always a heat source (heating element), and we do not want the hydrogen supply flow path to the suction part to be close to such a heat source.
  • the present invention was created in view of the above circumstances, and is designed to maintain a predetermined amount of hydrogen supply in order to obtain the health-promoting effect of hydrogen suction even if it is small and space-saving and continues to be used on a daily basis. It is an object of the present invention to provide a specific configuration of an electrolytic hydrogen suction device with a heated aromatic gas suction function that can sufficiently ensure safety during the production of flammable hydrogen.
  • the electrolytic hydrogen suction device with heating aromatic gas suction function of the present invention has the following features: A control means for controlling power supply from a built-in rechargeable battery when the power is on, a pair of positive and negative electrodes to which power is supplied or stopped from the battery by the control means, and the pair of positive and negative electrodes.
  • the control means includes an electrode control circuit that maintains constant current power supplied from the battery to the pair of positive and negative electrodes.
  • the heated aromatic gas electrolysis hydrogen suction device of the present invention (hereinafter also simply referred to as "hydrogen suction device”) is a hydrogen suction device that generates hydrogen by electrolyzing electrolyzed water in an electrolytic cell with a pair of positive and negative electrodes. It is a portable device that can simultaneously suck in aroma gas generated by a heated aroma gas emitting device, and it is controlled to maintain a "constant current" power from the battery that is supplied to the positive and negative electrodes that perform electrolysis. It has a circuit.
  • the electrolytic hydrogen suction device with heating aromatic gas suction function of the present invention has the following features: a valve member disposed in the upper part of the electrolytic cell that opens against an elastic force when the internal pressure of the electrolytic cell increases and closes due to the elastic force when the internal pressure decreases; Hydrogen generated by electrolyzing electrolyzed water with a pair of positive and negative electrodes in the electrolytic cell is separated from the aromatic gas emitting device and is guided to the nozzle portion. It is preferable.
  • this hydrogen suction device when the electrolytic cell is filled with hydrogen and the internal pressure rises, it is equipped with a valve member that opens to the outside with elastic force and vents the hydrogen, so that hydrogen does not fill when not suctioning. , safety is ensured. As a result, there is no need to add a control configuration that supplies power to the positive and negative electrodes only when the electrolytic cell is in a sealed state to prevent it from being filled with hydrogen. It is possible to reduce the causes of electrical troubles due to miniaturization) and the adoption of complex controls.
  • this hydrogen suction tool ensures safety at all times, regardless of whether it is not inhaling or inhaling.
  • the control means is an electrode control circuit that stops the power supply from the battery to the pair of positive and negative electrodes and terminates electrolysis when the load resistance value of the pair of positive and negative electrodes becomes equal to or less than a predetermined value. It is preferable to have the following.
  • this hydrogen suction tool In order to increase the portability of this hydrogen suction device and make hydrogen suction available for regular use, the electrolytic cell needs to be made smaller, and the gap between the anodes also needs to be narrowed, which prevents corrosion from attaching to the electrodes. There is also an increased possibility that the positive and negative electrodes will be short-circuited.
  • this hydrogen suction tool is equipped with an electrode control circuit that prevents short circuits between the pair of positive and negative electrodes in the electrolytic cell, which reduces the gap between the positive and negative electrodes, allowing the electrolytic cell to be made smaller. I have to. As a result, the load resistance values of the positive and negative electrodes are also reduced, so that the output voltage of the battery that can ensure a "constant current" can also be reduced, and the battery can also be made smaller.
  • the control means includes an electrode control circuit that stops the power supply from the battery to the pair of positive and negative electrodes and terminates electrolysis when the load resistance value of the aromatic gas emitting device exceeds a predetermined value. is preferred.
  • the control means is configured to turn off or turn off the power to the hydrogen suction tool when a predetermined period of time has elapsed after the start of supply of power from the battery to the pair of positive and negative electrodes, or when the battery voltage of the battery has become equal to or lower than a predetermined value.
  • a predetermined period of time has elapsed after the start of supply of power from the battery to the pair of positive and negative electrodes, or when the battery voltage of the battery has become equal to or lower than a predetermined value.
  • power supply from the battery to the pair of positive and negative electrodes is stopped.
  • this hydrogen suction tool when hydrogen is generated by electrolysis, the power is turned off after a predetermined period of time has passed after the start of electrolysis, and it is necessary to restart the device to start electrolysis again.
  • safety can be ensured by not releasing more than necessary flammable hydrogen while ensuring the amount of hydrogen necessary to obtain the health-promoting effects of hydrogen suction.
  • a “constant current” is ensured for the positive and negative electrodes, but “constant current” is not maintained unless the lowest electromotive voltage of the battery is ensured by charging, so if the battery voltage of the battery falls below a predetermined value, the power is turned off or Power supply to the positive and negative electrodes is stopped, and electrolysis ends.
  • the control means is configured to stop power supply from the battery to the pair of positive and negative electrodes when the gyro sensor detects a tilt of the hydrogen supply tool in either direction by a predetermined angle or more; It is preferable that the electrode control circuit has an electrode control circuit that restarts power supply from the battery to the pair of positive and negative electrodes when it is detected that the inclination of the electrode has become less than a predetermined angle.
  • this hydrogen suction device by adopting a control configuration that terminates electrolysis when the main body is tilted at a predetermined angle or more regardless of direction, electrolyzed water leaks in the electrolytic cell and some of the positive and negative electrodes are not electrolyzed. It is possible to prevent the hydrogen supply amount from being insufficient to obtain the effective effect of hydrogen suction without being immersed in water.
  • the electrolytic hydrogen suction device with heated aromatic gas suction function of the present invention although it is small and space-saving, it still requires a predetermined amount of hydrogen supply to obtain the health-promoting effect of hydrogen suction even when used on a daily basis. Furthermore, it is possible to sufficiently ensure safety during the production of flammable hydrogen.
  • FIG. 1 is a block diagram schematically showing an example of the overall configuration of an electrolytic hydrogen suction tool with a heated aromatic gas suction function of the present invention.
  • FIG. 2 shows a hexagonal view of a typical example of the electrolytic hydrogen suction device with a heated aromatic gas suction function shown in FIG. 1.
  • FIG. FIG. 3 is an exploded view showing an electrolytic cell that generates hydrogen, a lid member that plays a role in hydrogen propagation, and peripheral members thereof in the electrolytic hydrogen suction tool with heating aromatic gas suction function of FIG. 2;
  • 2 is a half-sectional view showing the external appearance and a part of the internal structure of the electrolytic hydrogen suction device with heating aroma gas suction function of FIG. 2 taken from the same viewpoint as FIG. 2(e).
  • FIGS. 1 to 6 a typical embodiment of an electrolytic hydrogen suction device with a heated aromatic gas suction function according to the present invention will be described in detail with reference to FIGS. 1 to 6. Needless to say, there is no limit. Further, since each drawing is for conceptually explaining the present invention, dimensions, ratios, or numbers may be exaggerated or simplified as necessary to facilitate understanding. Furthermore, in the following description, the same or corresponding parts are denoted by the same reference numerals, and overlapping description may be omitted.
  • FIG. 1 illustrates and explains the overall configuration of an electrolytic hydrogen suction tool (hereinafter also simply referred to as a "hydrogen suction tool") 100 with a heated aroma gas suction function of the present invention.
  • FIG. 1 is a block diagram schematically showing the overall configuration of the hydrogen suction tool 100
  • FIG. 2 is a six-sided view of a typical example of the hydrogen suction tool 100 shown in FIG. 1
  • FIG. FIG. 4 is an exploded view showing the electrolytic cell in which hydrogen is generated, the lid member that plays a role in hydrogen propagation, and its surrounding components. A half-sectional view showing a part of the internal structure is shown.
  • the smoking and hydrogen suction device of the present invention is not limited to what is shown in the drawings, but also includes those in which the contents of the drawings and description are modified within the scope of common knowledge.
  • the present hydrogen suction device 100 includes a rechargeable battery 104 that is supplied with power via an external input terminal 122, an LED 116, a control means 117, an electrolytic cell 103, an aromatic gas discharge device 105, It is generally composed of a lid member 14 and a nozzle part 108.
  • a pair of positive and negative electrodes 8a and 8b are arranged in the electrolytic cell 103.
  • the positive and negative electrodes 8a and 8b are supplied with power from the battery 104 via a control board 117, and an LED 116 that displays the power supply status and the like is connected to the battery 4.
  • the control board 117 includes a power supply means (power supply circuit) 117d, an electrode control circuit 117a that controls power supply to the positive and negative electrodes 8a and 8b via the power supply means 117d, and a power supply means (power supply circuit) 117d.
  • a heater control circuit 117b that controls the power supply to the heater (evaporation chamber) in the aromatic gas emitting device 105, and an LED control circuit 117c that controls the power supply to the LED 116 via the power supply means 117d are provided. ing.
  • a pressure sensor switch 119 is provided on the attachment that supplies power to the aromatic gas emitting device 105, and when the lower end of the aromatic gas emitting device 105 presses the pressure sensor switch 119, the power supply means 117d of the control board 117 supplies the power to the battery 104. is supplied to the aroma gas emitting device 105.
  • the electrode control circuit 117d controls energization/cutoff to the pair of electrodes 8a and 8b in the electrolytic cell 103, and the power supply means 117d varies the amount of power supplied from the battery 104 to supply power to the positive and negative electrodes 8a and 8b.
  • the power supply means 117d varies the amount of power supplied from the battery 104 to supply power to the positive and negative electrodes 8a and 8b.
  • Hydrogen generated from the negative electrode 8b is guided to the nozzle part 108 via an attachment on the upper part of the electrolytic cell 103 and a dedicated hydrogen guide channel provided in the lid member 14. Further, oxygen generated from the positive electrode 8a is vented (details will be described later).
  • aromatic gas emitting device 105 becomes in a state where the electric power can be supplied from the battery 104 to the heater in the aromatic gas emitting device 105 by the power supply means 117d, and the power is supplied. and heats the fragrance cartridge attached to the internal steam chamber, generating fragrance-containing vapor (also referred to as "fragrance gas").
  • aromatic gases include not only general aromatics such as mint, but also gases that have a health-promoting effect such as xylitol and vitamins, as long as they can be released as a gas by heating.
  • the aromatic agent-containing vapor generated by the aromatic gas discharge device 105 is discharged into the mouth by suctioning the nozzle part 8. At this time, due to the negative pressure generated by suction, hydrogen and aromatic gas pass through the hydrogen guide channel in the lid member 14 and the gap between the aromatic gas release device 105 and the nozzle part 108, and the hydrogen and aroma The gas mixes with the air inside the lid member 14 and is guided into the mouth.
  • the electrolytic cell 103 is composed of an electrolytic cell main body 1 and an electrolytic cell lid 3.
  • the electrolytic cell main body 1 is a container for storing electrolyte solution extending in the vertical direction, and is an integrally formed container that is fluidly connected to each other internally, and as an example, here, the lower part has a shape that is smaller in diameter than the upper part. .
  • the electrolytic cell main body 1 can be injected with water from an upper opening, and is closed by inserting a plate-shaped separator 5 with a through hole in the upper part of the opening and attaching an electrolytic cell lid 3.
  • the electrolytic cell lid part 3 is a case that penetrates vertically, and has a two-stage shape in which the diameter of the lower hem part increases and the diameter of the upper part decreases.
  • the electrolytic cell lid part 3 forms a bottom part by fixing the lower part to the separator 5 by a lock lever 7. Further, the opening at the top of the electrolytic cell cover 3 is formed into a counterbore shape in order to receive a first transmission member 2 of a permeation device to be described later.
  • the lower part of the electrolytic cell body 1 is smaller in diameter than the upper part, even if the aqueous solution accumulated inside is electrolyzed and the amount of water stored is reduced, most of the pair of positive and negative electrodes 8 will remain in the electrolytic solution. Electrolyte accumulates to the extent that it is immersed in water. This reduces the air layer at the top of the electrolytic cell body 1 and ensures electrolysis performance, but on the other hand, even taking into account the presence of the separator 5, the level of the electrolyte has risen to the limit, and electrolysis When the viscosity increases, bubbles generated by electrolysis enter and remain in the air layer and the electrolytic cell lid 3.
  • Two pairs of anode and cathode electrodes (mesh electrodes) 8 are arranged vertically in parallel upward, forming anode and cathode respectively, and are supplied with power from the battery 104. Moreover, the upper part of the positive and negative electrodes 8 is larger than the lower part so as to correspond to the reduced diameter part and the enlarged diameter part of the electrolytic cell body 1.
  • a rod-shaped titanium electrode 9 is connected to the lower end of the positive and negative electrodes 8 so as to stand up on the terminal board 24 for electrical connection.
  • a socket 25 made of resin such as silicone
  • an O is installed around the titanium electrode 9. Rings 10 and 11 (made of resin such as silicone; hereinafter referred to as O-rings) are provided.
  • a permeation device is attached to the top of the electrolytic cell lid 3.
  • the first transmission member 2 is attached to the upper part of the electrolytic cell lid 3.
  • the first permeable member 2 has a lower portion that is reduced in diameter and protrudes downward so as to fit vertically into the electrolytic cell lid portion 3, and an upper portion that is largely opened upward.
  • the reduced diameter portion of the first transmission member 2 is closed at the bottom and connected to the opening at the top, and is formed to form a liquid pool.
  • the enlarged diameter part at the upper part of the first permeable member 2 is connected to the opening of the liquid pool on the side of the reduced diameter part described above, and has a through hole that is fluidly connected to the opening of the electrolytic cell lid part 3.
  • the lower end of the through hole is inserted and connected using the opening of the electrolytic cell lid 3 as a counterbore.
  • an O-ring 23 to prevent water leakage is disposed between the through hole of the first permeable member 2 and the opening of the electrolytic cell cover 3.
  • a permeable membrane 12 is disposed in the through hole of the first permeable member 2 by a permeable membrane holder 6 to close the through hole.
  • This permeable membrane 12 is a porous resin membrane (tetrafluoroethylene resin porous membrane (the same applies to the second permeable membrane 12 described later)) that has selective permeability that allows gas to pass through and blocks liquid while adjusting the internal pressure with micropores. be.
  • the permeable membrane 12 blocks the bubbles of the electrolytic solution that have reached the inside of the electrolytic cell lid 3.
  • the permeable membrane 12 expands and the micropores expand, allowing the foamy electrolyte to permeate, or the gasified electrolyte permeates into the first permeable member 2.
  • the first permeable member 2 is designed to overlook the electrolyte permeation to some extent. , the electrolyte is stored in the reduced diameter portion of the first permeable member 2 as a liquid reservoir.
  • a second transparent member 4 is attached to the upper part of the first transparent member 2.
  • the second transparent member 4 opens downward and matches the upper opening of the first transparent member 2 to form an internal space.
  • a through hole is formed in the upper part of the second permeable member 4 at a position that looks into the through hole of the electrolytic cell lid 3 and the through hole of the first permeable member 2. This through hole is closed with a permeable membrane 12 similar to the permeable membrane 12 of the first permeable member 2, and sealed with an O-ring 22.
  • the permeable membrane 12 of the second permeable member 4 is also a porous resin membrane (in this case, a porous polytetrafluoroethylene resin membrane) that has selective permeability that allows gas to pass through and blocks liquid. are using.
  • a porous resin membrane in this case, a porous polytetrafluoroethylene resin membrane
  • the penetration of the electrolyte into the electrolytic cell is generally blocked by the permeable membrane 12 of the first permeable member 2, but in the second stage, the electrolytic solution is further blocked by the permeable membrane 12 of the second permeable member 4. Prevents release to the outside.
  • the second permeable member 4 is provided with a hole for draining the electrolytic solution stored in the liquid reservoir of the first permeable member 2, and the hole is closed with a screw 13 via a packing 21. When draining, the screw 13 is removed to enable disposal of the electrolyte.
  • a lid member 14 is attached to the upper part of the second transparent member 4 from above.
  • a through hole is provided above the permeable membrane 12 of the second permeable member 4 in the upper part of the lid member 14, and the valve shaft 17 is inserted into the through hole and closed.
  • the tip of the valve shaft 17 is connected to a base 18 sandwiched between packings 18 by a pin 20, and the through hole is opened under normal conditions (when not suctioning) by the action of a spring 19, and the nozzle portion 108 is closed when suctioning the lid member.
  • negative pressure acts inside the dedicated hydrogen guide channel 30 (see FIG. 4) in the hydrogen guide channel 14, it closes.
  • the flammable hydrogen-containing air passes through the dedicated hydrogen guide flow path 30 and is guided to the nozzle part 108, without passing near the heating element such as the aromatic gas discharge device 105, and when not suctioned.
  • the control board 117 etc. can be miniaturized (as a result, this hydrogen suction tool It is possible to reduce the causes of electrical troubles due to miniaturization of 100 mm) and the adoption of complicated controls.
  • control circuit configuration of the control board (control means) 117 of the hydrogen suction tool 100 will be explained with reference to control flow diagrams (FIGS. 5 and 6).
  • the power is turned on (STEP 1), and when the power is turned on, the power supply circuit (power supply means) 117d of the control board (control means) 117 starts to smell.
  • the gas is supplied to the gas release tool 105, and the heating time and heating control are executed by the heating control circuit 117b (STEP 2).
  • Electrolysis within the electrolytic cell 103 is performed by supplying a "constant current" to the positive and negative electrodes 8. This is to maintain an effective amount of hydrogen supply based on clinical trials even if the resistance value changes due to deterioration of the positive and negative electrodes 8, such as when used for a long period of time as described above.
  • Constant current is a constant current circuit that uses voltage-current conversion, and typically uses (1) a circuit using a transistor, (2) a circuit using an operational amplifier, and (3) feedback control.
  • the load resistance value R of the aromatic gas discharge unit 105 is less than a predetermined value (R1: 1.8 ⁇ in this embodiment)
  • the power is turned off (STEP 15 to circle Z in FIG. 6).
  • the electrolysis will operate normally (STEP 15 to circle Y in FIG. 6).
  • the power is originally OFF, it will not turn ON.
  • the heating time of the aromatic gas discharge part 105 is set to (1) a predetermined time t2. or (2) when a predetermined time t3 has elapsed since the previous time, the heater control circuit 117c stops the power supply to the aromatic gas discharge unit 105 (STEP11, STEP12, and STEP10 to STEP14). This is to prevent a decrease in safety due to overheating of the aromatic gas emitting section 105 by (1) limiting the heating time for one time and (2) limiting continuous use in a short period of time.
  • control is also performed to turn off the power when the temperature of the control circuit (control means) 117 reaches a predetermined temperature (for example, 80° C.) or higher.
  • this hydrogen supply device 100 is equipped with a gyro sensor (not shown), and the gyro sensor is tilted at a predetermined angle or more regardless of the direction of the main body (for example, 75 degrees or more (up to 15 degrees or less with respect to the horizontal direction)). ) is detected, the electrode control circuit 117a stops the power supply to the positive and negative electrodes 8, and the electrolysis ends (STEP13 to STEP9). This is to prevent leakage of electrolyzed water in the electrolytic cell 103 and failure to ensure a hydrogen supply amount sufficient to obtain an effective effect of hydrogen suction due to a portion of the positive and negative electrodes 8 not being immersed in the electrolyzed water. Note that, although not shown, when the gyro sensor detects that the tilt angle has returned to within the operable range, electrolysis resumes.
  • the electrode control circuit 117a stops the power supply to the positive and negative electrodes 8, and the electrolysis ends (STEP 16 to STEP 9).
  • the electrode control circuit 117a stops the power supply to the positive and negative electrodes 8, and the electrolysis ends (STEP 16 to STEP 9).
  • a control configuration that prevents the positive and negative electrodes 8 in the electrolytic cell 103 from being short-circuited.
  • This control configuration not only reduces the size of the electrolytic cell 103 by narrowing the gap between the anode 8a and the cathode 8b, but also reduces the load resistance value, thereby reducing the output voltage of the battery 104 that can ensure a "constant current”. This also contributes to miniaturization of the battery 104.
  • the electrolytic hydrogen suction device with heated aromatic gas suction function of the present invention although it is small and space-saving, it still requires a predetermined amount of hydrogen supply to obtain the health-promoting effect of hydrogen suction even when used on a daily basis. Furthermore, aromatic gas can also be sucked while ensuring sufficient safety during the production of flammable hydrogen.
  • Electrolytic cell body First permeable member 3
  • Electrolytic cell lid 4
  • Second permeable member 4
  • Separator 6
  • Permeable membrane holder 7
  • Lock lever Positive and negative electrodes 8a
  • Anode 8b Cathode 9 Titanium electrodes 10, 11, 22 O-ring 12 Permeable membrane 13 Screw 14
  • Lid member 16
  • Base 17 Valve shaft 18 Packing 19
  • Spring 20
  • Pin 21 Packing 23
  • O-ring 24 Terminal board 25
  • Socket 30
  • Hydrogen guide channel 100
  • Electrolytic hydrogen suction device with heated aromatic gas suction function (hydrogen suction device)
  • Electrolytic cell 104
  • Aromatic gas release tool 108
  • Nozzle part 114
  • Transmission device 116
  • LED Control means (control board)
  • Electrode control circuit 117b
  • Heater control circuit 117c
  • LED control circuit 117d
  • Power supply means 118
  • Pressure sensor switch 122

Abstract

[Problem] To provide an electrolytic hydrogen aspirator having a heating-type aromatic gas aspiration function which is portable and capable of safely and stably supplying hydrogen gas while maintaining the generation of a preset amount of hydrogen gas during aspiration. [Solution] An electrolytic hydrogen aspirator having a heating-type aromatic gas aspiration function that comprises: a control means which controls the supply of electric power from a built-in rechargeable battery when the power is ON; a pair of positive and negative electrodes to which electric power is supplied from the battery or shut off; an electrolytic tank that can store electrolytic water; an electrically heating-type aromatic gas emitter to which electric power is supplied from the battery or shut off; and a suction nozzle part through which hydrogen generated by electrolyzing the electrolytic water by the pair of the positive and negative electrodes in the electrolytic tank and the aromatic gas generated by the aromatic gas emitter are guided and emitted outside. The control means has an electrode control circuit that maintains the power supplied from the battery to the pair of the positive and negative electrodes at a constant current.

Description

加熱式芳香気体吸引機能付き電気分解式水素吸引具Electrolytic hydrogen suction device with heated aromatic gas suction function
 本発明は、携帯可能かつ吸引時に所定量の水素ガスの生成を維持しつつ安全かつ安定的に供給できる加熱式芳香気体吸引機能付き電気分解式水素吸引具に関する。 The present invention relates to an electrolytic hydrogen suction device with a heating aromatic gas suction function that is portable and capable of safely and stably supplying hydrogen gas while maintaining generation of a predetermined amount of hydrogen gas during suction.
 近年、神経変性疾患及び急性肺障害等の様々な動物疾患実験や、メタボリック症候群及び糖尿病等における人間の臨床実験で水素の有効性が示され、医療応用における種々の研究が盛んに行われている。水素は、老化の促進や動脈硬化及び癌等種々の疾患を引き起こす原因となっている悪玉活性酸素(=ヒドロキシルラジカル)のみを体内から除去し、体の組織や細胞に悪影響を及ぼさないことから、静脈投与、水溶液の経口投与、気体吸入等、体内へ取込む手法は幅広い。 In recent years, the effectiveness of hydrogen has been demonstrated in experiments on various animal diseases such as neurodegenerative diseases and acute lung injury, as well as human clinical experiments on metabolic syndrome and diabetes, and various research on medical applications is being actively conducted. . Hydrogen removes only bad active oxygen (=hydroxyl radicals) from the body, which is the cause of various diseases such as acceleration of aging and arteriosclerosis and cancer, and does not have a negative effect on the tissues and cells of the body. There are a wide range of methods for taking drugs into the body, including intravenous administration, oral administration of aqueous solutions, and gas inhalation.
 このうち水素を体内に摂取する方法として水素を吸引により摂取する方法があり、電解水を電気分解して水素発生させ、その水素を経口吸引する電気分解式水素吸引装置が存在し(特許文献1~2参照)、さらに発明者らも種々の治験の結果から健康促進効果を得やすくい適量の水素を日常吸引できるような充電池を用いた携帯式の水素吸引装置を提供してきた(特許文献3~4等参照)。また、無味無臭で吸引感に欠ける水素の継続的な吸引の実行を促進すべく芳香気体の加熱式の吸引機能付きの携帯式水素吸引装置も提供してきた。その際、既存の加熱式の回路構成に水素発生のための電気分解への電力供給回路を組み合わせて携帯式水素吸引供給装置を構成することが既存の技術を踏襲でき、開発容易である。 Among these methods, there is a method of ingesting hydrogen into the body by inhalation, and there is an electrolytic hydrogen inhalation device that electrolyzes electrolyzed water to generate hydrogen and inhales the hydrogen orally (Patent Document 1). 2), and based on the results of various clinical trials, the inventors have also provided a portable hydrogen suction device using a rechargeable battery that makes it easy to obtain health-promoting effects and can inhale an appropriate amount of hydrogen on a daily basis (Patent Document (See 3rd and 4th grade). Furthermore, in order to promote continuous suction of hydrogen, which is tasteless and odorless and lacks a feeling of suction, a portable hydrogen suction device with a heated aromatic gas suction function has been provided. In this case, it is possible to configure a portable hydrogen suction and supply device by combining an existing heating type circuit configuration with a power supply circuit for electrolysis for hydrogen generation, which can follow existing technology and is easy to develop.
 一般的に加熱式の芳香気体吸引装置や電子タバコ吸引装置では、ユーザの嗜好性に応じて要求される吸引量が変わるものであるため比較的設計容易な電気回路構成が採用され、充電池の起電圧にしたがって「定電圧」で動作を実行した。したがって、特に水素の効用が漠然としていた段階では、従来の加熱式の芳香気体吸引装置の電気回路構成を踏襲し、水素供給量の精緻な管理を行っていない現状があった。 In general, heated aromatic gas suction devices and electronic cigarette suction devices use electrical circuit configurations that are relatively easy to design, as the amount of suction required changes depending on the user's preference. The operation was performed at a "constant voltage" according to the electromotive force. Therefore, especially at a stage when the effectiveness of hydrogen was unclear, the electric circuit configuration of conventional heated aromatic gas suction devices was followed, and the amount of hydrogen supplied was not precisely managed.
 一方、発明者は上述するように水素の健康効果に対する治験結果を提供してきており、それらの治験に基づいた健康促進効果を有効に得る水素供給装置の開発提供が望まれた。すなわち、治験に基づく水素の医療的、健康促進的効果を得るには適正な水素の吸引量が要求されるものであるため、電気分解式の水素吸引装置を健康促進用装置として提供するには水素の発生量を所定量に維持させる必要がある。しかしながら、「定電圧」での電気分解が実行されると電極が劣化や電解水の変化により抵抗値が増加し、電流値が変化するため電流値に発生量が依存する水素の供給量を管理するには抵抗値が増加に対応して出力電圧を増加させていく必要があり、電池の最大出力電圧(定格)を超えると、それ以上の「定電流」を出力させることができなくなる。したがって、これを電極態様限界とせざるを得なくなり、電極の耐用を装置の耐用とせざるを得ないものとなり、自宅等での常用を前提する携帯式水素吸引装置として継続長期間使用するものとしては不適当である。 On the other hand, as mentioned above, the inventor has provided the results of clinical trials regarding the health effects of hydrogen, and it was desired to develop and provide a hydrogen supply device that effectively obtains the health promoting effects based on those clinical trials. In other words, in order to obtain the medical and health-promoting effects of hydrogen based on clinical trials, an appropriate amount of hydrogen suction is required. It is necessary to maintain the amount of hydrogen generated at a predetermined amount. However, when electrolysis is performed at a "constant voltage", the resistance value increases due to deterioration of the electrodes and changes in the electrolyzed water, and the current value changes, so the amount of hydrogen supplied depends on the current value. In order to do this, it is necessary to increase the output voltage in response to the increase in resistance value, and if the maximum output voltage (rated) of the battery is exceeded, it will no longer be possible to output a "constant current" beyond that. Therefore, this has no choice but to limit the electrode configuration, and the lifespan of the electrode has to be the lifespan of the device.As a portable hydrogen suction device that is intended for regular use at home, etc., and is intended to be used continuously for a long period of time, It's inappropriate.
 また、携帯式水素吸引装置においては電解槽から発生する水素は可燃性気体であり、安全濃度(4パーセント以下)になるよう水素供給量が制限するよう初期設計段階で電池や電極の選定や電極間距離を設定する必要がある。しかしながら、加熱式の芳香気体吸引機能付きの水素吸引装置の場合、電解槽内での電気分解で水素発生させると同時に加熱式の芳香気体発生用のカートリッジ等で別蒸気を発生させるため、熱源(発熱体)が必ずあり、吸引部までの水素供給流路をこのような熱源に接近させたくない。特に、電気分解式の水素吸引装置の場合、水素と酸素の混合気体が発生するため、水素の可燃濃度による管理以上の高度な管理設計が必要となる。その一方、背反して携帯式デバイスであり、省スペース化の要請に強く、これに応えるには単に水素供給流路を熱源から大きく離間させるだけの設計を行うことも難しい。 In addition, in portable hydrogen suction devices, the hydrogen generated from the electrolyzer is a flammable gas, so the selection of batteries and electrodes should be done at the initial design stage to limit the amount of hydrogen supplied to a safe concentration (4% or less). It is necessary to set the distance. However, in the case of a hydrogen suction device with a heated aromatic gas suction function, hydrogen is generated by electrolysis in the electrolytic cell, and at the same time separate steam is generated using a heated aromatic gas generation cartridge, etc., so the heat source ( There is always a heat source (heating element), and we do not want the hydrogen supply flow path to the suction part to be close to such a heat source. In particular, in the case of an electrolytic hydrogen suction device, a mixed gas of hydrogen and oxygen is generated, which requires a more sophisticated management design than that based on the combustible concentration of hydrogen. On the other hand, on the other hand, it is a portable device, and there is a strong demand for space saving, and in order to meet this demand, it is difficult to simply design the hydrogen supply channel to be far away from the heat source.
特開2004-41949号公報Japanese Patent Application Publication No. 2004-41949 特願2014-019640号公報Patent Application No. 2014-019640 国際公開公報WO2018/047889International Publication WO2018/047889 国際公開公報WO2018/151107International Publication Publication WO2018/151107
 本発明は、以上の事情に鑑みて創作されたものであり、小型・省スペースでありながら日常的に使用し続けても水素吸引による健康促進効果を得るに所定な水素供給量が維持することができ、さらに可燃性を有する水素生成時の安全を十分確保し得る加熱式芳香気体吸引機能付き電気分解式水素吸引具の具体的構成を提供することを目的としている。 The present invention was created in view of the above circumstances, and is designed to maintain a predetermined amount of hydrogen supply in order to obtain the health-promoting effect of hydrogen suction even if it is small and space-saving and continues to be used on a daily basis. It is an object of the present invention to provide a specific configuration of an electrolytic hydrogen suction device with a heated aromatic gas suction function that can sufficiently ensure safety during the production of flammable hydrogen.
 上記の課題を解決すべく、本発明の加熱式芳香気体吸引機能付き電気分解式水素吸引具は、
 電源ON状態のときに内蔵する充電可能な電池から電力供給を制御する制御手段と、該制御手段により前記電池からの電力が供給又は停止される一対の陽陰電極と、該一対の陽陰電極を内部に挿入配設される、電解水を貯水可能な電解槽と、前記制御手段により電池からの電力が供給又は停止される電気加熱式の芳香気体放出具と、前記電解槽内の一対の陽陰電極で電解水を電気分解することで生成された水素と前記芳香気体放出具で生成された芳香気体とが案内されて外部に放出する吸引用のノズル部とを備え、
 前記制御手段は、前記電池から一対の陽陰電極に供給する電力を定電流に維持する電極制御回路を有する。
In order to solve the above problems, the electrolytic hydrogen suction device with heating aromatic gas suction function of the present invention has the following features:
A control means for controlling power supply from a built-in rechargeable battery when the power is on, a pair of positive and negative electrodes to which power is supplied or stopped from the battery by the control means, and the pair of positive and negative electrodes. an electrolytic cell capable of storing electrolyzed water, which is inserted into the electrolytic cell; an electrically heated aromatic gas emitting device to which power from the battery is supplied or stopped by the control means; A suction nozzle portion that guides and discharges hydrogen generated by electrolyzing electrolyzed water with positive and negative electrodes and aromatic gas generated by the aromatic gas discharge device to the outside,
The control means includes an electrode control circuit that maintains constant current power supplied from the battery to the pair of positive and negative electrodes.
 本発明の加熱式芳香気電気分解式水素吸引具(以下、単に「水素吸引具」とも称する。)は、電解槽内の電解水を一対の陽陰電極で電気分解することで生成された水素と、加熱式の芳香気体放出具により生成された芳香気体とを同時に吸引可能な携帯式の装置であり、電気分解を行う陽陰電極に供給する電池から電力を「定電流」に維持する制御回路を有している。このように陽陰電極に「定電流」を供給することで充電量による電池からの出力電圧が変化した場合や、長期間使用して陽陰電極が劣化し負荷抵抗値が大きくなった場合でも、陽陰電極に供給される電力値は一定に維持される。近年、発明者等が行った種々の治験から健康促進等に効果を得るには所定の水素量を確保することが重要であることがわかってきており、電気分解の性質上、水素量は電流値に依存するものであるため本発明では、電池の起電圧や陽陰電極の抵抗値が変化しても所望の水素量を確保することができるようにしている。一方、電池の最大出力電圧は電池ごとに決まっているため「定電流」を維持する制御構成を採用しても陽陰電極の劣化が進行し、負荷抵抗値Rが過大になると、出力電流I=最大出力電圧Vmax/負荷抵抗値R であるため「定電流」を維持できなくなる。これに対して本水素吸引具において電流値を検知し、所定電流値より検出電流値が下回ることが検出された場合、陽陰電極の耐用限界に達したと判断することもでき、交換時期を判断する指標を提供できる点でも本水素吸引具は有利である。 The heated aromatic gas electrolysis hydrogen suction device of the present invention (hereinafter also simply referred to as "hydrogen suction device") is a hydrogen suction device that generates hydrogen by electrolyzing electrolyzed water in an electrolytic cell with a pair of positive and negative electrodes. It is a portable device that can simultaneously suck in aroma gas generated by a heated aroma gas emitting device, and it is controlled to maintain a "constant current" power from the battery that is supplied to the positive and negative electrodes that perform electrolysis. It has a circuit. By supplying a "constant current" to the positive and negative electrodes in this way, even if the output voltage from the battery changes depending on the amount of charge, or if the positive and negative electrodes deteriorate due to long-term use and the load resistance value increases. , the power value supplied to the positive and negative electrodes is maintained constant. In recent years, various clinical trials conducted by the inventors have revealed that it is important to secure a certain amount of hydrogen in order to obtain health promotion effects, and due to the nature of electrolysis, the amount of hydrogen depends on the current. Since the amount of hydrogen depends on the amount of hydrogen, the present invention makes it possible to ensure a desired amount of hydrogen even if the electromotive force of the battery and the resistance values of the positive and negative electrodes change. On the other hand, since the maximum output voltage of a battery is determined for each battery, even if a control configuration that maintains a "constant current" is adopted, deterioration of the positive and negative electrodes progresses and if the load resistance value R becomes excessive, the output current I = maximum output voltage Vmax/load resistance value R. Therefore, a "constant current" cannot be maintained. On the other hand, if this hydrogen suction device detects the current value and detects that the detected current value is lower than the predetermined current value, it can be determined that the positive and negative electrodes have reached their service life limits, and it is possible to determine when it is time to replace them. This hydrogen suction device is also advantageous in that it can provide indicators for judgment.
 また、本発明の加熱式芳香気体吸引機能付き電気分解式水素吸引具は、
 前記電解槽の上部に電解槽の内圧が上昇すると弾性力に抗して開放され、低下すると弾性力により閉鎖するバルブ部材と、
 前記電解槽内の一対の陽陰電極で電解水を電気分解することで生成された水素は、前記芳香気体放出具から離間して前記ノズル部まで案内する専用の水素案内流路と、を備えることが好ましい。
In addition, the electrolytic hydrogen suction device with heating aromatic gas suction function of the present invention has the following features:
a valve member disposed in the upper part of the electrolytic cell that opens against an elastic force when the internal pressure of the electrolytic cell increases and closes due to the elastic force when the internal pressure decreases;
Hydrogen generated by electrolyzing electrolyzed water with a pair of positive and negative electrodes in the electrolytic cell is separated from the aromatic gas emitting device and is guided to the nozzle portion. It is preferable.
 本水素吸引具によれば、電解槽内で水素が充満して内圧が上昇すると弾性力で外部に開放されて水素をベントするバルブ部材を備えることで、非吸引時には水素が充満しないようになり、安全性が確保される。その結果、電解槽内に水素が充満しないよう密閉状態のときのみに陽陰電極に電力供給するような制御構成を付加する必要もなく、制御手段等の小型化(ひいては本水素吸引具自体の小型化)や複雑な制御採用による電気トラブル原因を減らすことができる。 According to this hydrogen suction device, when the electrolytic cell is filled with hydrogen and the internal pressure rises, it is equipped with a valve member that opens to the outside with elastic force and vents the hydrogen, so that hydrogen does not fill when not suctioning. , safety is ensured. As a result, there is no need to add a control configuration that supplies power to the positive and negative electrodes only when the electrolytic cell is in a sealed state to prevent it from being filled with hydrogen. It is possible to reduce the causes of electrical troubles due to miniaturization) and the adoption of complex controls.
 また、本水素吸引具によれば電解槽内で生成された水素を専用の水素案内流路で吸引用のノズル部まで案内するので可燃性を有する水素が、芳香気体放出具等の発熱体近傍を可燃性の水素が通ることなく、本水素吸引具を小型化してもより高度に安全性を確保することができる。以上を総じて、本水素吸引具では非吸引時及び吸引時を問わず常時、安全性が確保されることとなる。 In addition, according to this hydrogen suction tool, the hydrogen generated in the electrolytic cell is guided to the suction nozzle through a dedicated hydrogen guide channel, so flammable hydrogen is transported near the heating element such as the aromatic gas release tool. Since flammable hydrogen does not pass through the hydrogen suction device, a higher level of safety can be ensured even if the hydrogen suction device is made smaller. In summary, this hydrogen suction tool ensures safety at all times, regardless of whether it is not inhaling or inhaling.
 また、本発明の水素吸引具において、
 前記制御手段は、前記一対の陽陰電極の負荷抵抗値が所定値以下になった場合に、前記電池から該一対の陽陰電極への電力供給が停止され、電気分解が終了する電極制御回路を有する、ことが好ましい。
Moreover, in the hydrogen suction tool of the present invention,
The control means is an electrode control circuit that stops the power supply from the battery to the pair of positive and negative electrodes and terminates electrolysis when the load resistance value of the pair of positive and negative electrodes becomes equal to or less than a predetermined value. It is preferable to have the following.
 本水素吸引具は、携帯性を高めて水素吸引を常用させるためには電解槽も小型化する必要があり、陽極と陽極の隙間も狭めていく必要があり、電極への腐食物の付着等を含め陽陰電極が短絡する可能性も高まる。これを防止するために本水素吸引具では電解槽内の一対の陽陰電極の短絡を防止する電極制御回路を備えることで、陽陰電極間の隙間も狭めることによる電解槽の小型化できるようにしている。その結果、陽陰電極の負荷抵抗値も低下するので「定電流」を確保し得る電池の出力電圧をも低減することができ、電池の小型化もすることができる。 In order to increase the portability of this hydrogen suction device and make hydrogen suction available for regular use, the electrolytic cell needs to be made smaller, and the gap between the anodes also needs to be narrowed, which prevents corrosion from attaching to the electrodes. There is also an increased possibility that the positive and negative electrodes will be short-circuited. In order to prevent this, this hydrogen suction tool is equipped with an electrode control circuit that prevents short circuits between the pair of positive and negative electrodes in the electrolytic cell, which reduces the gap between the positive and negative electrodes, allowing the electrolytic cell to be made smaller. I have to. As a result, the load resistance values of the positive and negative electrodes are also reduced, so that the output voltage of the battery that can ensure a "constant current" can also be reduced, and the battery can also be made smaller.
 また、本発明の水素吸引具において、
 前記制御手段は、前記芳香気体放出具の負荷抵抗値所定値を超える場合に、前記電池から該一対の陽陰電極への電力供給が停止され、電気分解が終了する電極制御回路を有する、ことが好ましい。
Moreover, in the hydrogen suction tool of the present invention,
The control means includes an electrode control circuit that stops the power supply from the battery to the pair of positive and negative electrodes and terminates electrolysis when the load resistance value of the aromatic gas emitting device exceeds a predetermined value. is preferred.
 前述した陽陰電極の負荷抵抗値の低下による「定電流」維持目的の制御構成と同様に、芳香気体放出具としての負荷抵抗値が過大にならないように制御して電池の出力電圧内で陽陰電極への定電流が確保するようにしている。 Similar to the control configuration that aims to maintain a "constant current" by decreasing the load resistance value of the positive and negative electrodes mentioned above, it is controlled so that the load resistance value as an aromatic gas emitting device does not become excessive, and the positive current is maintained within the output voltage of the battery. A constant current to the negative electrode is ensured.
 また、本発明の水素吸引具において、
 前記制御手段は、前記一対の陽陰電極への前記電池からの電力が供給開始後、所定時間経過する、又は前記電池の電池電圧が所定値以下になると、前記水素吸引具の電源がOFF又は前記電池から一対の陽陰電極への電力供給が停止される、ことが好ましい。
Moreover, in the hydrogen suction tool of the present invention,
The control means is configured to turn off or turn off the power to the hydrogen suction tool when a predetermined period of time has elapsed after the start of supply of power from the battery to the pair of positive and negative electrodes, or when the battery voltage of the battery has become equal to or lower than a predetermined value. Preferably, power supply from the battery to the pair of positive and negative electrodes is stopped.
 本水素吸引具によれば、電気分解による水素の生成は、電気分解開始後所定時間経過すると、電源OFFになり、再度電気分解開始するには再起動する必要がある。この制御構成により水素吸引による健康増進等の効果を得るに必要な分だけの水素量を確保しながら可燃性を有する水素を必要以上に放出させないことで安全性を確保し得る。また、陽陰電極には「定電流」が確保されるが、充電による電池の最低の起電圧が確保されないと「定電流」が維持されないため電池の電池電圧が所定値以下になると電源OFF又は陽陰電極への電力供給が停止され、電気分解が終了する。 According to this hydrogen suction tool, when hydrogen is generated by electrolysis, the power is turned off after a predetermined period of time has passed after the start of electrolysis, and it is necessary to restart the device to start electrolysis again. With this control configuration, safety can be ensured by not releasing more than necessary flammable hydrogen while ensuring the amount of hydrogen necessary to obtain the health-promoting effects of hydrogen suction. In addition, a "constant current" is ensured for the positive and negative electrodes, but "constant current" is not maintained unless the lowest electromotive voltage of the battery is ensured by charging, so if the battery voltage of the battery falls below a predetermined value, the power is turned off or Power supply to the positive and negative electrodes is stopped, and electrolysis ends.
 さらに、本発明の水素吸引具において、
 前記水素供給具の傾斜を検知するジャイロセンサーを備え、
 前記制御手段は、は、前記ジャイロセンサーにより前記水素供給具のいずれかの方向に所定角度以上の傾斜を検知すると前記電池から前記一対の陽陰電極への電力供給が停止され、いずれかの方向の傾斜も所定角度未満になったことを検知すると前記電池から前記一対の陽陰電極への電力供給を再開する電極制御回路を有する、ことが好ましい。
Furthermore, in the hydrogen suction tool of the present invention,
comprising a gyro sensor that detects the inclination of the hydrogen supply tool,
The control means is configured to stop power supply from the battery to the pair of positive and negative electrodes when the gyro sensor detects a tilt of the hydrogen supply tool in either direction by a predetermined angle or more; It is preferable that the electrode control circuit has an electrode control circuit that restarts power supply from the battery to the pair of positive and negative electrodes when it is detected that the inclination of the electrode has become less than a predetermined angle.
 本水素吸引具によれば、方向を問わず本体が所定角度以上の傾斜をすると電気分解を終了させる制御構成を採用することで電解槽内の電解水の漏出や陽陰電極の一部が電解水に浸されず水素吸引による有効な効果を得るだけの水素供給量が確保されないことを防止することができる。 According to this hydrogen suction device, by adopting a control configuration that terminates electrolysis when the main body is tilted at a predetermined angle or more regardless of direction, electrolyzed water leaks in the electrolytic cell and some of the positive and negative electrodes are not electrolyzed. It is possible to prevent the hydrogen supply amount from being insufficient to obtain the effective effect of hydrogen suction without being immersed in water.
 本発明の加熱式芳香気体吸引機能付き電気分解式水素吸引具によれば、小型・省スペースでありながら日常的に使用し続けても水素吸引による健康促進効果を得るに所定な水素供給量が維持することができ、さらに可燃性を有する水素生成時の安全を十分確保し得る。 According to the electrolytic hydrogen suction device with heated aromatic gas suction function of the present invention, although it is small and space-saving, it still requires a predetermined amount of hydrogen supply to obtain the health-promoting effect of hydrogen suction even when used on a daily basis. Furthermore, it is possible to sufficiently ensure safety during the production of flammable hydrogen.
本発明の加熱式芳香気体吸引機能付き電気分解式水素吸引具全体の構成例を模式的に表すブロック図である。FIG. 1 is a block diagram schematically showing an example of the overall configuration of an electrolytic hydrogen suction tool with a heated aromatic gas suction function of the present invention. 図1の加熱式芳香気体吸引機能付き電気分解式水素吸引具の代表例の六面図等を示している。FIG. 2 shows a hexagonal view of a typical example of the electrolytic hydrogen suction device with a heated aromatic gas suction function shown in FIG. 1. FIG. 図2の加熱式芳香気体吸引機能付き電気分解式水素吸引具において水素を発生される電解槽や水素伝搬の役割を有する蓋部材及びその周辺部材を示す組立分解図を示している。FIG. 3 is an exploded view showing an electrolytic cell that generates hydrogen, a lid member that plays a role in hydrogen propagation, and peripheral members thereof in the electrolytic hydrogen suction tool with heating aromatic gas suction function of FIG. 2; 図2の加熱式芳香気体吸引機能付き電気分解式水素吸引具の図2(e)と同視点の外観及び一部の内部構造を示す半断面図を示している。2 is a half-sectional view showing the external appearance and a part of the internal structure of the electrolytic hydrogen suction device with heating aroma gas suction function of FIG. 2 taken from the same viewpoint as FIG. 2(e). 加熱式芳香気体吸引機能付き電気分解式水素吸引具の制御基板(制御手段)での制御構成を示すフローである。It is a flow showing a control configuration on a control board (control means) of an electrolytic hydrogen suction tool with a heated aromatic gas suction function. 図5に続いて加熱式芳香気体吸引機能付き電気分解式水素吸引具の制御基板(制御手段)での制御構成を示すフローである。Continuing on from FIG. 5, this is a flowchart showing the control configuration of the control board (control means) of the electrolytic hydrogen suction device with heating aromatic gas suction function.
 以下、本発明の加熱式芳香気体吸引機能付き電気分解式水素吸引具に係る代表的な実施形態を、図1~図6を参照しながら詳細に説明するが、本発明は図示されるものに限られないことはいうまでもない。また、各図面は本発明を概念的に説明するためのものであるから、理解容易のために、必要に応じて寸法、比又は数を誇張又は簡略化して表している場合もある。更に、以下の説明では、同一又は相当部分には同一符号を付し、重複する説明は省略することもある。 Hereinafter, a typical embodiment of an electrolytic hydrogen suction device with a heated aromatic gas suction function according to the present invention will be described in detail with reference to FIGS. 1 to 6. Needless to say, there is no limit. Further, since each drawing is for conceptually explaining the present invention, dimensions, ratios, or numbers may be exaggerated or simplified as necessary to facilitate understanding. Furthermore, in the following description, the same or corresponding parts are denoted by the same reference numerals, and overlapping description may be omitted.
 図1は、本発明の加熱式芳香気体吸引機能付き電気分解式水素吸引具(以下、単に「水素吸引具」とも称する。)100全体の構成を例示説明する。図1には水素吸引具100全体の構成を模式的に表すブロック図、図2には図1の水素吸引具100の代表例の六面図等、図3は、図2の水素吸引具100において水素を発生される電解槽や水素伝搬の役割を有する蓋部材及びその周辺部材を示す組立分解図、図4は、図2の水素吸引具100の図2(e)と同視点の外観及び一部の内部構造を示す半断面図を示している。なお、本発明の喫煙兼水素吸引装置は、図示されるものに限られず、また図示及び説明の内容を一般常識の範囲内で改変したものをも含むことはいうまでもない。 FIG. 1 illustrates and explains the overall configuration of an electrolytic hydrogen suction tool (hereinafter also simply referred to as a "hydrogen suction tool") 100 with a heated aroma gas suction function of the present invention. FIG. 1 is a block diagram schematically showing the overall configuration of the hydrogen suction tool 100, FIG. 2 is a six-sided view of a typical example of the hydrogen suction tool 100 shown in FIG. 1, and FIG. FIG. 4 is an exploded view showing the electrolytic cell in which hydrogen is generated, the lid member that plays a role in hydrogen propagation, and its surrounding components. A half-sectional view showing a part of the internal structure is shown. It goes without saying that the smoking and hydrogen suction device of the present invention is not limited to what is shown in the drawings, but also includes those in which the contents of the drawings and description are modified within the scope of common knowledge.
 図1~図2に示すように、本水素吸引具100は、外部入力端子122を介して電力供給される充電式の電池104、LED116、制御手段117、電解槽103、芳香気体放出具105、蓋部材14、ノズル部108で概ね構成されている。電解槽103には一対の陽陰電極8a、8bが配設されている。陽陰電極8a、8bは、制御基板117を介して電池104からの電力が供給され、電力供給状態等を表示するLED116は電池4に接続されている。制御基板117には、電力供給手段(電力供給回路)117dと、電力供給手段117dを介して陽陰電極8a、8bへの電力供給を制御する電極制御回路117aと、電力供給手段117dを介して芳香気体放出具105内の加熱器(蒸発チャンバー)への電力供給を制御する加熱器制御回路117bと、電力供給手段117dを介してLED116への電力供給を制御するLED制御回路117cとが備えられている。 As shown in FIGS. 1 and 2, the present hydrogen suction device 100 includes a rechargeable battery 104 that is supplied with power via an external input terminal 122, an LED 116, a control means 117, an electrolytic cell 103, an aromatic gas discharge device 105, It is generally composed of a lid member 14 and a nozzle part 108. A pair of positive and negative electrodes 8a and 8b are arranged in the electrolytic cell 103. The positive and negative electrodes 8a and 8b are supplied with power from the battery 104 via a control board 117, and an LED 116 that displays the power supply status and the like is connected to the battery 4. The control board 117 includes a power supply means (power supply circuit) 117d, an electrode control circuit 117a that controls power supply to the positive and negative electrodes 8a and 8b via the power supply means 117d, and a power supply means (power supply circuit) 117d. A heater control circuit 117b that controls the power supply to the heater (evaporation chamber) in the aromatic gas emitting device 105, and an LED control circuit 117c that controls the power supply to the LED 116 via the power supply means 117d are provided. ing.
  また、芳香気体放出具105に電力供給するアタッチメントには圧力センサスイッチ119が設けられ、芳香気体放出具105の下端が圧力センサスイッチ119を押圧すると制御基板117の電力供給手段117dにより電池104の電力が芳香気体放出具105に供給される。 In addition, a pressure sensor switch 119 is provided on the attachment that supplies power to the aromatic gas emitting device 105, and when the lower end of the aromatic gas emitting device 105 presses the pressure sensor switch 119, the power supply means 117d of the control board 117 supplies the power to the battery 104. is supplied to the aroma gas emitting device 105.
  また、詳細には後述するが、ユーザが操作ボタン118を操作すると、これに応じて電極制御回路117dが電解槽103内の一対の電極8a、8bへの通電・遮断を制御し、電力供給手段117dにより電池104から供給される電力量を可変して陽陰電極8a、8bに電力を供給する。一対の陽陰電極8a、8bに電力が供給されると電解槽103内に貯留する水を電気分解し、陽電極8a側に酸素が発生し、陰電極8b側に水素が発生する。 Further, as will be described in detail later, when the user operates the operation button 118, the electrode control circuit 117d controls energization/cutoff to the pair of electrodes 8a and 8b in the electrolytic cell 103, and the power supply means 117d varies the amount of power supplied from the battery 104 to supply power to the positive and negative electrodes 8a and 8b. When power is supplied to the pair of positive and negative electrodes 8a and 8b, water stored in the electrolytic cell 103 is electrolyzed, and oxygen is generated on the positive electrode 8a side and hydrogen is generated on the negative electrode 8b side.
  陰電極8bから発生した水素は、電解槽103上部のアタッチメントを介して蓋部材14に設けられた専用の水素案内流路を介してノズル部108まで案内される。また、陽電極8aから発生した酸素は、ベントされる(詳細には後述)。 Hydrogen generated from the negative electrode 8b is guided to the nozzle part 108 via an attachment on the upper part of the electrolytic cell 103 and a dedicated hydrogen guide channel provided in the lid member 14. Further, oxygen generated from the positive electrode 8a is vented (details will be described later).
  また、芳香気体放出具105は、圧力センサスイッチ119がONになると電力供給手段117dにより芳香気体放出具105内の加熱器への電池104からの電力を供給可能な状態になり、電力供給されると内部の蒸気チャンバに取り付けられた芳香剤カートリッジを加熱し、芳香剤含有蒸気(「芳香気体」とも称する。)が発生する。なお、芳香気体には、ミント等の一般的な芳香剤のみならず、加熱により気体放出できるものであればキシリトールやビタミン等の健康促進効果を有する気体も含まれる。 Further, when the pressure sensor switch 119 is turned ON, the aromatic gas emitting device 105 becomes in a state where the electric power can be supplied from the battery 104 to the heater in the aromatic gas emitting device 105 by the power supply means 117d, and the power is supplied. and heats the fragrance cartridge attached to the internal steam chamber, generating fragrance-containing vapor (also referred to as "fragrance gas"). Note that aromatic gases include not only general aromatics such as mint, but also gases that have a health-promoting effect such as xylitol and vitamins, as long as they can be released as a gas by heating.
  芳香気体放出具105で発生した芳香剤含有蒸気は、ノズル部8を吸引することで口内に放出される。このとき吸引で発生する負圧により、蓋部材14内の水素案内流路や芳香気体放出具105とノズル部108との隙間を通過してノズル部108の上部(吸引口近傍)において水素、芳香気体、蓋部材14内の空気と混合して口内に案内される。 · The aromatic agent-containing vapor generated by the aromatic gas discharge device 105 is discharged into the mouth by suctioning the nozzle part 8. At this time, due to the negative pressure generated by suction, hydrogen and aromatic gas pass through the hydrogen guide channel in the lid member 14 and the gap between the aromatic gas release device 105 and the nozzle part 108, and the hydrogen and aroma The gas mixes with the air inside the lid member 14 and is guided into the mouth.
 次に、図3の組立分解図を参照しつつ、電解槽103、蓋部材14及びその周囲部材について説明する。電解槽103は、電解槽本体1と電解槽蓋部3とで構成される。電解槽本体1は、上下方向に延びた電解液の貯水用容器であり、互いに内部で流体的に接続する一体形成の容器であり、一例としてここでは下方が上方よりも縮径する形状を有する。電解槽本体1は上方の開口から注水可能になっており、開口上部に貫通孔を設けた板状のセパレータ5を挿入し、電解槽蓋部3を取り付けることで閉鎖される。電解槽蓋部3は上下に貫通するケースであり、下方の裾部の拡径し、上部が縮径する2段階形状を有する。電解槽蓋部3は下方をロックレバー7によりセパレータ5と固定することで底部をなしている。また、電解槽蓋部3の上部の開口を後述する透過装置の第一透過部材2を受容するために座グリ形状を形成している。 Next, the electrolytic cell 103, the lid member 14, and surrounding members will be described with reference to the exploded view of FIG. The electrolytic cell 103 is composed of an electrolytic cell main body 1 and an electrolytic cell lid 3. The electrolytic cell main body 1 is a container for storing electrolyte solution extending in the vertical direction, and is an integrally formed container that is fluidly connected to each other internally, and as an example, here, the lower part has a shape that is smaller in diameter than the upper part. . The electrolytic cell main body 1 can be injected with water from an upper opening, and is closed by inserting a plate-shaped separator 5 with a through hole in the upper part of the opening and attaching an electrolytic cell lid 3. The electrolytic cell lid part 3 is a case that penetrates vertically, and has a two-stage shape in which the diameter of the lower hem part increases and the diameter of the upper part decreases. The electrolytic cell lid part 3 forms a bottom part by fixing the lower part to the separator 5 by a lock lever 7. Further, the opening at the top of the electrolytic cell cover 3 is formed into a counterbore shape in order to receive a first transmission member 2 of a permeation device to be described later.
 また、電解槽本体1は、下方が上方より縮径しているため内部に溜まっている水溶液が電気分解され貯水量が減った場合であっても一対の陽陰電極8の大部分が電解液に浸される程度に電解液が貯留する。これにより電解槽本体1の上部の空気層は減り、電気分解性能は確保されるが、その一方、セパレータ5の存在を加味しても電解液の液面がギリギリまで上がっており、電気分解により粘性が高まった場合に空気層や電解槽蓋部3内に電気分解で発生した泡が侵入・滞留することとなる。 In addition, since the lower part of the electrolytic cell body 1 is smaller in diameter than the upper part, even if the aqueous solution accumulated inside is electrolyzed and the amount of water stored is reduced, most of the pair of positive and negative electrodes 8 will remain in the electrolytic solution. Electrolyte accumulates to the extent that it is immersed in water. This reduces the air layer at the top of the electrolytic cell body 1 and ensures electrolysis performance, but on the other hand, even taking into account the presence of the separator 5, the level of the electrolyte has risen to the limit, and electrolysis When the viscosity increases, bubbles generated by electrolysis enter and remain in the air layer and the electrolytic cell lid 3.
 陽陰電極(メッシュ電極)8は、2枚一対に上方に向かって長手に並列配置され、それぞれ陽陰極を形成し、電池104からの電力が供給される。また、陽陰電極8は電解槽本体1の縮径部と拡径部とに対応するように上部が下部より大きくなっている。陽陰電極8の下端は、端子基板24に起立させ電気的に接続できるように棒形状のチタン電極9が連結されている。陽陰電極8を起立させた状態で陽陰電極8と端子基板24とを遮水するために端子基板24上に装着するソケット25(シリコン等の樹脂製)とチタン電極9の周囲に取り付けるOリング10、11(シリコン等の樹脂製:以下、Oリングは同様)とが設けられている。 Two pairs of anode and cathode electrodes (mesh electrodes) 8 are arranged vertically in parallel upward, forming anode and cathode respectively, and are supplied with power from the battery 104. Moreover, the upper part of the positive and negative electrodes 8 is larger than the lower part so as to correspond to the reduced diameter part and the enlarged diameter part of the electrolytic cell body 1. A rod-shaped titanium electrode 9 is connected to the lower end of the positive and negative electrodes 8 so as to stand up on the terminal board 24 for electrical connection. In order to shield the positive and negative electrodes 8 and the terminal board 24 from water while the positive and negative electrodes 8 are standing up, a socket 25 (made of resin such as silicone) is installed on the terminal board 24 and an O is installed around the titanium electrode 9. Rings 10 and 11 (made of resin such as silicone; hereinafter referred to as O-rings) are provided.
 また、電解槽蓋部3の上部には透過装置が取り付けられる。まず、電解槽蓋部3の上部に第一透過部材2が装着される。第一透過部材2は、電解槽蓋部3と上下に嵌合するようにその下部が縮径して下方に突出し、上部が上方に大きく開口している。第一透過部材2の縮径部は底部が閉鎖されて上部の開口に繋がっており、液溜まりになるように形成されている。また、第一透過部材2の上部の拡径部は、前述の縮径部側の液溜まりの開口と繋がっており、電解槽蓋部3の開口と流体的に連結する貫通孔を有し、その貫通孔の下端が電解槽蓋部3の開口を座グリとして挿入・連結される。このとき第一透過部材2の貫通孔と電解槽蓋部3の開口との間には水漏れ防止のOリング23が配設される。 Additionally, a permeation device is attached to the top of the electrolytic cell lid 3. First, the first transmission member 2 is attached to the upper part of the electrolytic cell lid 3. The first permeable member 2 has a lower portion that is reduced in diameter and protrudes downward so as to fit vertically into the electrolytic cell lid portion 3, and an upper portion that is largely opened upward. The reduced diameter portion of the first transmission member 2 is closed at the bottom and connected to the opening at the top, and is formed to form a liquid pool. Further, the enlarged diameter part at the upper part of the first permeable member 2 is connected to the opening of the liquid pool on the side of the reduced diameter part described above, and has a through hole that is fluidly connected to the opening of the electrolytic cell lid part 3. The lower end of the through hole is inserted and connected using the opening of the electrolytic cell lid 3 as a counterbore. At this time, an O-ring 23 to prevent water leakage is disposed between the through hole of the first permeable member 2 and the opening of the electrolytic cell cover 3.
 また、上記第一透過部材2の貫通孔には透過膜押さえ6により透過膜12が配設され、貫通孔を閉鎖している。この透過膜12は微小孔で内圧を調整しながら気体を透過させ液体を遮断する選択透過性を有する樹脂多孔膜(四フッ化エチレン樹脂多孔膜(後述する第2透過膜12も同様))である。まず第一段階として透過膜12により、電解槽蓋部3の内部まで到達した電解液の泡が遮断される。ただし、電解槽本体1内部の内圧が上昇して透過膜12が伸びて微小孔が拡大して泡状の電解液を透過させたり、気体化した電解液が透過して第1透過部材2内に電解液が侵入することと、背反して透過膜12の孔径を小さくし過ぎて水素透過速度まで減退することとを防止すべく、第一透過部材2にはある程度、電解液侵入を看過し、第一透過部材2の縮径部を液溜まりとして電解液を貯留させることとしている。 Further, a permeable membrane 12 is disposed in the through hole of the first permeable member 2 by a permeable membrane holder 6 to close the through hole. This permeable membrane 12 is a porous resin membrane (tetrafluoroethylene resin porous membrane (the same applies to the second permeable membrane 12 described later)) that has selective permeability that allows gas to pass through and blocks liquid while adjusting the internal pressure with micropores. be. First, in the first step, the permeable membrane 12 blocks the bubbles of the electrolytic solution that have reached the inside of the electrolytic cell lid 3. However, when the internal pressure inside the electrolytic cell body 1 increases, the permeable membrane 12 expands and the micropores expand, allowing the foamy electrolyte to permeate, or the gasified electrolyte permeates into the first permeable member 2. In order to prevent the electrolyte from penetrating into the first permeable member 2 and to prevent the hydrogen permeation rate from decreasing due to the pore diameter of the permeable membrane 12 being made too small, the first permeable member 2 is designed to overlook the electrolyte permeation to some extent. , the electrolyte is stored in the reduced diameter portion of the first permeable member 2 as a liquid reservoir.
 さらに、第一透過部材2の上部に第二透過部材4が装着される。第二透過部材4は下方に開口し、第一透過部材2の上方の開口と合致して内部空間を構成する。第二透過部材4の上部には電解槽蓋部3の貫通孔、第一透過部材2の貫通孔を覗く位置に貫通孔が形成されている。この貫通孔には第一透過部材2の透過膜12の場合と同様の透過膜12で閉鎖され、Oリング22で封止している。この第二透過部材4の透過膜12も第一透過部材4の透過膜12と同様に気体を透過させ液体を遮断する選択透過性を有する樹脂多孔膜(ここでは四フッ化エチレン樹脂多孔膜)を使用している。 Furthermore, a second transparent member 4 is attached to the upper part of the first transparent member 2. The second transparent member 4 opens downward and matches the upper opening of the first transparent member 2 to form an internal space. A through hole is formed in the upper part of the second permeable member 4 at a position that looks into the through hole of the electrolytic cell lid 3 and the through hole of the first permeable member 2. This through hole is closed with a permeable membrane 12 similar to the permeable membrane 12 of the first permeable member 2, and sealed with an O-ring 22. Like the permeable membrane 12 of the first permeable member 4, the permeable membrane 12 of the second permeable member 4 is also a porous resin membrane (in this case, a porous polytetrafluoroethylene resin membrane) that has selective permeability that allows gas to pass through and blocks liquid. are using.
 したがって、第1段階で第一透過部材2の透過膜12により電解槽内の電解液の侵入は概ね遮断されているが第2段階として第二透過部材4の透過膜12により、さらに電解液が外部に放出されることを防止している。なお、第二透過部材4には第一透過部材2の液溜まりに貯留した電解液をドレンするための孔が設けられ、その孔はパッキン21を介してネジ13で封鎖される。ドレン時にはネジ13を取り外して電解液の廃棄を可能にしている。 Therefore, in the first stage, the penetration of the electrolyte into the electrolytic cell is generally blocked by the permeable membrane 12 of the first permeable member 2, but in the second stage, the electrolytic solution is further blocked by the permeable membrane 12 of the second permeable member 4. Prevents release to the outside. Note that the second permeable member 4 is provided with a hole for draining the electrolytic solution stored in the liquid reservoir of the first permeable member 2, and the hole is closed with a screw 13 via a packing 21. When draining, the screw 13 is removed to enable disposal of the electrolyte.
 第二透過部材4の上部には、蓋部材14が上方から取り付けられる。蓋部材14の上部には吸引用のノズル108部以外に第二透過部材4の透過膜12の上方に貫通孔が設けられ、バルブ軸17が挿入され閉鎖されている。バルブ軸17の先端はパッキン18で挟まれたベース18とピン20で連結されており、スプリング19の作用により通常時(非吸引時)に貫通孔を開放し、ノズル部108を吸引時に蓋部材14内の専用の水素案内流路30(図4参照)の内部に負圧が作用すると閉鎖する。したがって、吸引時には可燃性を有する水素含有空気は専用の水素案内流路30内を通過してノズル部108まで案内され、芳香気体放出具105等の発熱体近傍を通ることなく、さらに非吸引時には水素が充満しないようになり、安全性が確保される。その結果、電解槽内に水素が充満しないよう密閉状態のときのみに陽陰電極8に電力供給するような制御構成を付加する必要もなく、制御基板117等の小型化(ひいては本水素吸引具100の小型化)や複雑な制御採用による電気トラブル原因を減らすことができる。 A lid member 14 is attached to the upper part of the second transparent member 4 from above. In addition to the suction nozzle 108, a through hole is provided above the permeable membrane 12 of the second permeable member 4 in the upper part of the lid member 14, and the valve shaft 17 is inserted into the through hole and closed. The tip of the valve shaft 17 is connected to a base 18 sandwiched between packings 18 by a pin 20, and the through hole is opened under normal conditions (when not suctioning) by the action of a spring 19, and the nozzle portion 108 is closed when suctioning the lid member. When negative pressure acts inside the dedicated hydrogen guide channel 30 (see FIG. 4) in the hydrogen guide channel 14, it closes. Therefore, during suction, the flammable hydrogen-containing air passes through the dedicated hydrogen guide flow path 30 and is guided to the nozzle part 108, without passing near the heating element such as the aromatic gas discharge device 105, and when not suctioned. This prevents hydrogen from filling up, ensuring safety. As a result, there is no need to add a control configuration that supplies power to the positive and negative electrodes 8 only when the electrolytic cell is in a sealed state to prevent it from being filled with hydrogen, and the control board 117 etc. can be miniaturized (as a result, this hydrogen suction tool It is possible to reduce the causes of electrical troubles due to miniaturization of 100 mm) and the adoption of complicated controls.
 次に水素吸引具100の制御基板(制御手段)117での制御回路構成を制御フロー図(図5~図6)を参照して説明する。
 水素吸引具100の側部の操作ボタン118を例えば長押し等すると電源ONとなり(STEP1)、電源ONの状態になると制御基板(制御手段)117の電力供給回路(電力供給手段)117d電力が芳香気体放出具105に供給され、加熱制御回路117bにより加熱時間や加熱制御が実行される(STEP2)。水素吸引具100の電源がONになった状態で操作ボタン118を押圧すると陽陰電極8に電力が供給され、電解槽103内の電解水が電気分解され、水素と酸素を生成する(STEP3~STEP4)。なお、電池104は外部入力端子122から外部電力が供給されることで充電がなされ、電池104は、過充電防止のため電池電圧が4.25Vに達する場合や、充電開始してから11時間経過した場合にと充電が停止される。
Next, the control circuit configuration of the control board (control means) 117 of the hydrogen suction tool 100 will be explained with reference to control flow diagrams (FIGS. 5 and 6).
For example, by long pressing the operation button 118 on the side of the hydrogen suction device 100, the power is turned on (STEP 1), and when the power is turned on, the power supply circuit (power supply means) 117d of the control board (control means) 117 starts to smell. The gas is supplied to the gas release tool 105, and the heating time and heating control are executed by the heating control circuit 117b (STEP 2). When the operation button 118 is pressed while the power of the hydrogen suction device 100 is turned on, power is supplied to the positive and negative electrodes 8, and the electrolyzed water in the electrolytic cell 103 is electrolyzed to generate hydrogen and oxygen (STEP 3 ~ STEP 4). Note that the battery 104 is charged by external power being supplied from the external input terminal 122, and the battery 104 is charged when the battery voltage reaches 4.25V to prevent overcharging, or when 11 hours have passed since charging started. If this occurs, charging will be stopped.
 電解槽103内での電気分解は、陽陰電極8に「定電流」を供給することで行う。前述したように長期間使用した場合等、陽陰電極8の劣化による抵抗値が変化しても治験に基づく有効な水素量供給を維持するためである。「定電流」は、電圧電流変換を利用する定電流回路であり、代表的には(1)トランジスタを使った回路、(2)オペアンプを使った回路、(3)フィードバック制御が用いられるが、ここでは簡易な(1)トランジスタを使った回路、又はこれより「定電流」確保の精度が高く温度影響の小さい(2)オペアンプを使った回路を用いる。 Electrolysis within the electrolytic cell 103 is performed by supplying a "constant current" to the positive and negative electrodes 8. This is to maintain an effective amount of hydrogen supply based on clinical trials even if the resistance value changes due to deterioration of the positive and negative electrodes 8, such as when used for a long period of time as described above. "Constant current" is a constant current circuit that uses voltage-current conversion, and typically uses (1) a circuit using a transistor, (2) a circuit using an operational amplifier, and (3) feedback control. Here, we will use a simple (1) circuit using transistors, or (2) a circuit using operational amplifiers, which has higher accuracy in ensuring a "constant current" and is less affected by temperature.
 電気分解は、開始後所定時間(t1:本実施形態では5分)経過すると、電源OFFになり(図5のSTEP5及び丸囲みZ~図6の丸囲みZ及びSTEP14)、再度電気分解開始するには再起動(STEP1)する必要がある。また、陽陰電極8には「定電流」が確保されるが、充電による電池104の最低の起電圧が確保されないと「定電流」が維持されないため電池104の電池電圧V1が所定値以下(例えば3.2V以下)になると電源OFFになり、電気分解が終了する(図5のSTEP6及び丸囲みZ~図6の丸囲みZ及びSTEP14)。図5~図6では起電圧が所定値以下の場合、電源OFFになる制御が例示されるが、陽陰電極8への電力供給が停止され、電気分解が終了する制御構成でも良い。 When a predetermined time (t1: 5 minutes in this embodiment) has passed after the start of electrolysis, the power is turned off (STEP 5 and circle Z in FIG. 5 to circle Z and STEP 14 in FIG. 6), and electrolysis starts again. It is necessary to restart (STEP 1). Furthermore, although a "constant current" is ensured in the positive and negative electrodes 8, "constant current" is not maintained unless the lowest electromotive voltage of the battery 104 is ensured by charging, so that the battery voltage V1 of the battery 104 is lower than a predetermined value ( For example, 3.2 V or less), the power is turned off and the electrolysis ends (STEP 6 and circle Z in FIG. 5 to circle Z and STEP 14 in FIG. 6). Although FIGS. 5 and 6 exemplify control in which the power is turned off when the electromotive voltage is below a predetermined value, a control configuration in which power supply to the positive and negative electrodes 8 is stopped and electrolysis is completed may also be used.
 また、短絡保護のため芳香気体放出部105としての負荷抵抗値Rが所定値(R1:本実施形態では1.8Ω)以下の場合、電源OFFとなる(STEP15~図6の丸囲みZ)。但し、電気分解が正常に動作していると確認される場合には、電気分解は正常に動作する(STEP15~図6の丸囲みY)。ここでは図示しないが、そもそも電源OFFの場合はONにならない。 Further, for short circuit protection, if the load resistance value R of the aromatic gas discharge unit 105 is less than a predetermined value (R1: 1.8Ω in this embodiment), the power is turned off (STEP 15 to circle Z in FIG. 6). However, if it is confirmed that the electrolysis is operating normally, the electrolysis will operate normally (STEP 15 to circle Y in FIG. 6). Although not shown here, if the power is originally OFF, it will not turn ON.
 また、芳香気体放出具105としての負荷抵抗値Rが所定値(R2:本実施形態では3.5Ω)を超える場合も、電源OFFとなる(STEP8~STEP10~STEP14)。芳香気体放出具105としての負荷抵抗値Rが過大になると電池104の出力電圧内で陽陰電極8への定電流が確保できなくなるからである。但し、定電流が確保され、電気分解が正常に動作していると確認される場合には、電気分解は正常に動作する(STEP10~図6の丸囲みY)。 Also, when the load resistance value R of the aromatic gas emitting device 105 exceeds a predetermined value (R2: 3.5Ω in this embodiment), the power is turned off (STEP 8 to STEP 10 to STEP 14). This is because if the load resistance value R of the aromatic gas emitting device 105 becomes too large, a constant current to the positive and negative electrodes 8 cannot be ensured within the output voltage of the battery 104. However, if a constant current is ensured and it is confirmed that the electrolysis is operating normally, the electrolysis will operate normally (STEP 10 to circle Y in FIG. 6).
 また、水素の可燃性を考慮し水素吸引具100の安全性を確保するために特に芳香気体放出部105の過熱を防止すべく、芳香気体放出部105の加熱時間が、(1)所定時間t2経過した場合や、(2)前回から所定時間t3経過した場合に、加熱器制御回路117cにより芳香気体放出部105への電力供給が停止される(STEP11、STEP12及びSTEP10~STEP14)。(1)1回の加熱時間を制限したり、(2)短時間での連続使用を制限することで芳香気体放出部105の過熱による安全性の低下を防止するためである。但し、電気分解が正常に動作していると確認される場合には、電気分解は正常に動作する(STEP15~図6の丸囲みY)。 なお、図5~図6では図示しないが制御回路(制御手段)117の温度が所定温度(例えば80℃)以上になると電源OFFになる制御も行われる。 In addition, in order to ensure the safety of the hydrogen suction device 100 in consideration of the flammability of hydrogen, in order to prevent the aromatic gas discharge part 105 from overheating, the heating time of the aromatic gas discharge part 105 is set to (1) a predetermined time t2. or (2) when a predetermined time t3 has elapsed since the previous time, the heater control circuit 117c stops the power supply to the aromatic gas discharge unit 105 (STEP11, STEP12, and STEP10 to STEP14). This is to prevent a decrease in safety due to overheating of the aromatic gas emitting section 105 by (1) limiting the heating time for one time and (2) limiting continuous use in a short period of time. However, if it is confirmed that the electrolysis is operating normally, the electrolysis will operate normally (STEP 15 to circle Y in FIG. 6). Although not shown in FIGS. 5 and 6, control is also performed to turn off the power when the temperature of the control circuit (control means) 117 reaches a predetermined temperature (for example, 80° C.) or higher.
 また、本水素供給具100はジャイロセンサーが装備され(図示せず)、本体が方向を問わずジャイロセンサーが所定角度以上の傾斜(例えば75°以上(水平方向を基準にして15°以下まで))を検知すると、電極制御回路117aにより陽陰電極8への電力供給が停止され、電気分解が終了する(STEP13~STEP9)。電解槽103内の電解水の漏出や陽陰電極8の一部が電解水に浸されず水素吸引による有効な効果を得るだけの水素供給量が確保されないことを防止するためである。なお、図示しないがジャイロセンサーが動作可能範囲内に傾斜角度が復活したことを検知すると電気分解が再開する。 In addition, this hydrogen supply device 100 is equipped with a gyro sensor (not shown), and the gyro sensor is tilted at a predetermined angle or more regardless of the direction of the main body (for example, 75 degrees or more (up to 15 degrees or less with respect to the horizontal direction)). ) is detected, the electrode control circuit 117a stops the power supply to the positive and negative electrodes 8, and the electrolysis ends (STEP13 to STEP9). This is to prevent leakage of electrolyzed water in the electrolytic cell 103 and failure to ensure a hydrogen supply amount sufficient to obtain an effective effect of hydrogen suction due to a portion of the positive and negative electrodes 8 not being immersed in the electrolyzed water. Note that, although not shown, when the gyro sensor detects that the tilt angle has returned to within the operable range, electrolysis resumes.
 さらに、陽陰電極8の負荷抵抗値Rが所定値R3以下になった場合、電極制御回路117aにより陽陰電極8への電力供給が停止され、電気分解が終了する(STEP16~STEP9)。本水素供給具100の携帯性を高めて水素吸引を常用させるためには電解槽103も小型化する必要があり、陽極8aと陽極8bの隙間も狭めていく必要があり、電極への腐食物の付着等を含め陽陰電極8が短絡する可能性も高まる。これを防止するために電解槽103内の陽陰電極8の短絡を防止する制御構成を採用している。この制御構成は陽極8aと陰極8bの隙間も狭めることによる電解槽103の小型化のみならず、負荷抵抗値も低下するので「定電流」を確保し得る電池104の出力電圧を低減することができ、電池104の小型化にも寄与する。 Furthermore, when the load resistance value R of the positive and negative electrodes 8 becomes equal to or less than the predetermined value R3, the electrode control circuit 117a stops the power supply to the positive and negative electrodes 8, and the electrolysis ends (STEP 16 to STEP 9). In order to increase the portability of the present hydrogen supply device 100 and to use hydrogen suction regularly, it is necessary to downsize the electrolytic cell 103, and it is also necessary to narrow the gap between the anode 8a and the anode 8b, which prevents corrosive substances from forming on the electrodes. There is also an increased possibility that the positive and negative electrodes 8 will be short-circuited due to adhesion. In order to prevent this, a control configuration is adopted that prevents the positive and negative electrodes 8 in the electrolytic cell 103 from being short-circuited. This control configuration not only reduces the size of the electrolytic cell 103 by narrowing the gap between the anode 8a and the cathode 8b, but also reduces the load resistance value, thereby reducing the output voltage of the battery 104 that can ensure a "constant current". This also contributes to miniaturization of the battery 104.
 以上、本発明の加熱式芳香気体吸引機能付き電気分解式水素吸引具(水素吸引具)についてその実施形態を例示説明してきたが、本発明はこれに限定されるものではなく、特許請求の範囲および明細書等の記載の精神や教示を逸脱しない範囲で他の変形例や改良例が得られることが当業者は理解できるであろう。 Although the embodiments of the electrolytic hydrogen suction device (hydrogen suction device) with a heated aromatic gas suction function of the present invention have been described above, the present invention is not limited thereto, and the scope of the claims Those skilled in the art will understand that other modifications and improvements can be made without departing from the spirit and teachings of the specification and the like.
 本発明の加熱式芳香気体吸引機能付き電気分解式水素吸引具によれば、小型・省スペースでありながら日常的に使用し続けても水素吸引による健康促進効果を得るに所定な水素供給量が維持することができ、さらに可燃性を有する水素生成時の安全を十分確保しながら芳香気体をも吸引することができる。 According to the electrolytic hydrogen suction device with heated aromatic gas suction function of the present invention, although it is small and space-saving, it still requires a predetermined amount of hydrogen supply to obtain the health-promoting effect of hydrogen suction even when used on a daily basis. Furthermore, aromatic gas can also be sucked while ensuring sufficient safety during the production of flammable hydrogen.
1 電解槽本体
2 第一透過部材
3 電解槽蓋部
4 第二透過部材
5 セパレータ
6 透過膜押さえ
7 ロックレバー
8 陽陰電極
 8a 陽極
 8b 陰極
9 チタン電極
10、11、22 Oリング
12 透過膜
13 ネジ
14 蓋部材
16 ベース
17 バルブ軸
18 パッキン
19 スプリング
20 ピン
21 パッキン
23 Oリング
24 端子基板
25 ソケット
30 水素案内流路
100 加熱式芳香気体吸引機能付き電気分解式水素吸引具(水素吸引具)
103 電解槽
104 電池
105 芳香気体放出具
108 ノズル部
114 透過装置
116 LED
117 制御手段(制御基板)
 117a 電極制御回路
 117b 加熱器制御回路
 117c LED制御回路
 117d 電力供給手段
118 操作ボタン
119 圧力センサスイッチ
122 外部入力端子
1 Electrolytic cell body 2 First permeable member 3 Electrolytic cell lid 4 Second permeable member 5 Separator 6 Permeable membrane holder 7 Lock lever 8 Positive and negative electrodes 8a Anode 8b Cathode 9 Titanium electrodes 10, 11, 22 O-ring 12 Permeable membrane 13 Screw 14 Lid member 16 Base 17 Valve shaft 18 Packing 19 Spring 20 Pin 21 Packing 23 O-ring 24 Terminal board 25 Socket 30 Hydrogen guide channel 100 Electrolytic hydrogen suction device with heated aromatic gas suction function (hydrogen suction device)
103 Electrolytic cell 104 Battery 105 Aromatic gas release tool 108 Nozzle part 114 Transmission device 116 LED
117 Control means (control board)
117a Electrode control circuit 117b Heater control circuit 117c LED control circuit 117d Power supply means 118 Operation button 119 Pressure sensor switch 122 External input terminal

Claims (6)

  1.  電源ON状態のときに内蔵する充電可能な電池から電力供給を制御する制御手段と、該制御手段により前記電池からの電力が供給又は停止される一対の陽陰電極と、該一対の陽陰電極を内部に挿入配設される、電解水を貯水可能な電解槽と、前記制御手段により電池からの電力が供給又は停止される電気加熱式の芳香気体放出具と、前記電解槽内の一対の陽陰電極で電解水を電気分解することで生成された水素と前記芳香気体放出具で生成された芳香気体とが案内されて外部に放出する吸引用のノズル部とを備え、
     前記制御手段は、前記電池から一対の陽陰電極に供給する電力を定電流に維持する電極制御回路を有する、ことを特徴とする携帯可能な加熱式芳香気体吸引機能付き電気分解式水素吸引具。
    A control means for controlling power supply from a built-in rechargeable battery when the power is on, a pair of positive and negative electrodes to which power is supplied or stopped from the battery by the control means, and the pair of positive and negative electrodes. an electrolytic cell capable of storing electrolyzed water, which is inserted into the electrolytic cell; an electrically heated aromatic gas emitting device to which power from the battery is supplied or stopped by the control means; A suction nozzle portion that guides and discharges hydrogen generated by electrolyzing electrolyzed water with positive and negative electrodes and aromatic gas generated by the aromatic gas discharge device to the outside,
    The portable electrolytic hydrogen suction device with heating aromatic gas suction function is characterized in that the control means has an electrode control circuit that maintains the electric power supplied from the battery to the pair of positive and negative electrodes at a constant current. .
  2.  前記電解槽の上部に電解槽の内圧が上昇すると弾性力に抗して開放され、低下すると弾性力により閉鎖するバルブ部材と、
     前記電解槽内の一対の陽陰電極で電解水を電気分解することで生成された水素は、前記芳香気体放出具から離間して前記ノズル部まで案内する専用の水素案内流路と、を備えることを特徴とする請求項1に記載の加熱式芳香気体吸引機能付き電気分解式水素吸引具。
    a valve member disposed in the upper part of the electrolytic cell that opens against an elastic force when the internal pressure of the electrolytic cell increases and closes due to the elastic force when the internal pressure decreases;
    Hydrogen generated by electrolyzing electrolyzed water with a pair of positive and negative electrodes in the electrolytic cell is separated from the aromatic gas emitting device and is guided to the nozzle portion. The electrolytic hydrogen suction tool with heating aromatic gas suction function according to claim 1.
  3.  前記制御手段は、前記一対の陽陰電極の負荷抵抗値が所定値以下になった場合に、前記電池から該一対の陽陰電極への電力供給が停止され、電気分解が終了する電極制御回路を有する、ことを特徴とする請求項1又は2に記載の加熱式芳香気体吸引機能付き電気分解式水素吸引具。 The control means is an electrode control circuit that stops the power supply from the battery to the pair of positive and negative electrodes and terminates electrolysis when the load resistance value of the pair of positive and negative electrodes becomes equal to or less than a predetermined value. The electrolytic hydrogen suction device with heating aromatic gas suction function according to claim 1 or 2, comprising:
  4.  前記制御手段は、前記芳香気体放出具の負荷抵抗値所定値を超える場合に、前記電池から該一対の陽陰電極への電力供給が停止され、電気分解が終了する電極制御回路を有する、ことを特徴とする請求項1~3のいずれか1項に記載の加熱式芳香気体吸引機能付き電気分解式水素吸引具。 The control means includes an electrode control circuit that stops the power supply from the battery to the pair of positive and negative electrodes and terminates electrolysis when the load resistance value of the aromatic gas emitting device exceeds a predetermined value. The electrolytic hydrogen suction device with heating aromatic gas suction function according to any one of claims 1 to 3.
  5.  前記制御手段は、前記一対の陽陰電極への前記電池からの電力が供給開始後、所定時間経過する、又は前記電池の電池電圧が所定値以下になると、前記水素吸引具の電源がOFF又は前記電池から一対の陽陰電極への電力供給が停止される、ことを特徴とする請求項1~4のいずれか1項に記載の加熱式芳香気体吸引機能付き電気分解式水素吸引具。 The control means is configured to turn off or turn off the power to the hydrogen suction tool when a predetermined period of time has elapsed after the start of supply of power from the battery to the pair of positive and negative electrodes, or when the battery voltage of the battery has become equal to or lower than a predetermined value. The electrolytic hydrogen suction device with heating aromatic gas suction function according to any one of claims 1 to 4, wherein power supply from the battery to the pair of positive and negative electrodes is stopped.
  6.  前記加熱式芳香気体吸引機能付き電気分解式水素吸引具の傾斜を検知するジャイロセンサーを備え、
     前記制御手段は、は、前記ジャイロセンサーにより前記加熱式芳香気体吸引機能付き電気分解式水素吸引具のいずれかの方向に所定角度以上の傾斜を検知すると前記電池から前記一対の陽陰電極への電力供給が停止され、いずれかの方向の傾斜も所定角度未満になったことを検知すると前記電池から前記一対の陽陰電極への電力供給を再開する電極制御回路を有する、ことを特徴とする請求項1~4のいずれか1項に記載の加熱式芳香気体吸引機能付き電気分解式水素吸引具。
    comprising a gyro sensor that detects the inclination of the electrolytic hydrogen suction device with heating aromatic gas suction function;
    The control means, when the gyro sensor detects an inclination of the electrolytic hydrogen suction device with heated aromatic gas suction function by a predetermined angle or more in either direction, causes the control means to control the voltage from the battery to the pair of positive and negative electrodes. It is characterized by having an electrode control circuit that resumes power supply from the battery to the pair of positive and negative electrodes when it is detected that the power supply has been stopped and the inclination in either direction has become less than a predetermined angle. The electrolytic hydrogen suction device with heating aromatic gas suction function according to any one of claims 1 to 4.
PCT/JP2023/025697 2022-08-22 2023-07-12 Electrolytic hydrogen aspirator having heating-type aromatic gas aspiration function WO2024042900A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2022131819 2022-08-22
JP2022-131819 2022-08-22

Publications (1)

Publication Number Publication Date
WO2024042900A1 true WO2024042900A1 (en) 2024-02-29

Family

ID=90013061

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2023/025697 WO2024042900A1 (en) 2022-08-22 2023-07-12 Electrolytic hydrogen aspirator having heating-type aromatic gas aspiration function

Country Status (1)

Country Link
WO (1) WO2024042900A1 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017006569A (en) * 2015-06-26 2017-01-12 日本光電工業株式会社 Gas therapy apparatus
KR102118044B1 (en) * 2019-12-17 2020-06-03 유인수 IOT based hydrogen gas inhaler
WO2020116225A1 (en) * 2018-12-08 2020-06-11 隆 竹原 Living body improvement method, and electrolysis-type hydrogen generator for implementing said method
JP2021109988A (en) * 2020-01-08 2021-08-02 株式会社健明 Portable hydrogen suction apparatus

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017006569A (en) * 2015-06-26 2017-01-12 日本光電工業株式会社 Gas therapy apparatus
WO2020116225A1 (en) * 2018-12-08 2020-06-11 隆 竹原 Living body improvement method, and electrolysis-type hydrogen generator for implementing said method
KR102118044B1 (en) * 2019-12-17 2020-06-03 유인수 IOT based hydrogen gas inhaler
JP2021109988A (en) * 2020-01-08 2021-08-02 株式会社健明 Portable hydrogen suction apparatus

Similar Documents

Publication Publication Date Title
KR101795735B1 (en) Hydrogen Generation Device
KR102025039B1 (en) Electrolytic Hydrogen Gas Suction Tool
JP7251012B2 (en) Smoking and hydrogen suction device
JP2018525525A (en) Gas generator
JP6530151B2 (en) Electrolytic hydrogen and oxygen gas suction tool
US20180209050A1 (en) Hydrogen generation apparatus
CN106029582A (en) Apparatus for generating functional water
JP2021192608A (en) Aerosol generation system equipped with overheating prevention measures
JP2005087257A (en) Method of inhalation of hydrogen gas into body and its device
WO2024042900A1 (en) Electrolytic hydrogen aspirator having heating-type aromatic gas aspiration function
JP6963789B2 (en) Hydrogen gas generator and hydrogen gas inhalation device including it
WO2018190322A1 (en) Electrolytic gas suction tool
JP6786753B2 (en) Portable gas supply device
CN207159360U (en) Hydrogen generating device and the hydrogen suction apparatus including the hydrogen generating device
JP2015181996A (en) Electrode structure of hypochlorite generator and hypochlorite generator
US8939435B2 (en) Device for delivery of volatile liquids to gaseous environment utilizing a gas generating cell
JP4672232B2 (en) Fuel cell device
JP6503054B2 (en) Electrolyzed water generating device, electrode unit, and electrolytic water generating method
CN215426695U (en) Rich hydrogen ion functional assembly that atomizes
JP6964238B2 (en) Portable electrolyzer
US20220152369A1 (en) Wearable system and method for gas delivery to exterior surface of an eye
TWI655956B (en) Gas generator
JP2017190518A (en) Electrolytic hydrogen generator
CN115451506A (en) Air treatment device
CN117795262A (en) Air sterilization device and air humidification device

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 23857017

Country of ref document: EP

Kind code of ref document: A1