WO2024027541A1 - Downpour flooding-resistant recycled pervious concrete suitable for heavy-load traffic pavement, and preparation method therefor - Google Patents

Downpour flooding-resistant recycled pervious concrete suitable for heavy-load traffic pavement, and preparation method therefor Download PDF

Info

Publication number
WO2024027541A1
WO2024027541A1 PCT/CN2023/109378 CN2023109378W WO2024027541A1 WO 2024027541 A1 WO2024027541 A1 WO 2024027541A1 CN 2023109378 W CN2023109378 W CN 2023109378W WO 2024027541 A1 WO2024027541 A1 WO 2024027541A1
Authority
WO
WIPO (PCT)
Prior art keywords
parts
water
permeable concrete
heavy
waterlogging
Prior art date
Application number
PCT/CN2023/109378
Other languages
French (fr)
Chinese (zh)
Inventor
朱平华
史志浩
陈春红
刘惠
王新杰
彭明国
Original Assignee
常州大学
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 常州大学 filed Critical 常州大学
Publication of WO2024027541A1 publication Critical patent/WO2024027541A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00284Materials permeable to liquids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • C04B2201/52High compression strength concretes, i.e. with a compression strength higher than about 55 N/mm2, e.g. reactive powder concrete [RPC]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Definitions

  • the invention belongs to the technical field of building materials, and specifically relates to a heavy rain waterlogging-resistant regenerated permeable concrete suitable for heavy-duty traffic pavements and a preparation method thereof.
  • permeable concrete faces several challenges, including low strength, poor durability, difficult porosity control, easy clogging, and inconvenient maintenance. And strength is negatively correlated with water permeability and water purification capacity. Permeable concrete with lower porosity will obtain higher strength, but water permeability and water purification capacity will be significantly reduced; increasing porosity will obtain high permeability and water purification capacity. It also significantly reduces the strength of permeable concrete. Therefore, how to ensure that permeable concrete can quickly drain water while having high strength and water purification functions is the development trend of new roads in sponge cities.
  • the purpose of the present invention is to provide a regenerated permeable concrete suitable for heavy-duty traffic pavements that is resistant to heavy rain and waterlogging and a preparation method thereof.
  • the permeable concrete has the characteristics of high strength and rapid waterlogging, which is beneficial to alleviating the problem.
  • Urban waterlogging solves the problem that permeable concrete cannot be widely used on heavy-duty traffic pavements.
  • the present invention optimizes the number and distribution of pores in permeable concrete, including the use of artificial pore formation, optimal porosity, pore diameter and pore distribution, so that the prepared permeable concrete has sufficient water permeability and water purification capabilities while ensuring high strength. .
  • a method for preparing regenerated permeable concrete that is suitable for heavy-duty traffic pavements and is suitable for heavy rain and waterlogging is determined according to the rainstorm intensity, waterlogging depth and rainfall duration in each region, and the porosity of the permeable concrete is calculated based on the water permeability coefficient.
  • the permeable concrete includes the following components by weight: 748 to 901 parts of recycled coarse aggregate, 732 to 827 parts of river sand, 600 to 630 parts of Portland cement, and silica fume 80 to 100 parts, fly ash 160 to 180 parts, steel fiber 80 to 120 parts, water reducing agent 1.2 to 1.5 parts and water 180 to 189 parts.
  • the water permeability coefficient k is determined by the relationship between rainstorm intensity i, waterlogging depth H, and rainfall duration t, k ⁇ i+t/h, and k ⁇ 0.5mm/s; the rainstorm intensity i is based on The rainstorm intensity formula of each city is determined, and the rainstorm intensity formula of each city can be obtained by looking up the table ("China's New Generation of Rainstorm Intensity Formula"); the waterlogging depth H is based on the waterlogging depth ( ⁇ 150mm) specified in the outdoor drainage design specification GB 50014-2006. Determine; the rainfall time t is determined by the different anti-waterlogging design standards of each city. For example: the maximum waterlogging depth allowed on the main roads in Guangzhou is 15cm, and the maximum time to dissipate the waterlogging is 30 minutes.
  • the pore diameter and the pollutant removal rate form a Wilbur distribution.
  • the pollutant removal rate is 50%
  • the upper and lower limits of the pore diameter are 0.5mm and 3mm respectively
  • the pollutant removal rate (initial concentration of pollutants - final concentration of pollutants)/initial concentration of pollutants.
  • k is the water permeability coefficient
  • p is the porosity
  • d is the pore diameter
  • is the density of water
  • is the viscosity of water
  • g is the acceleration of gravity.
  • the number of pores on a single cross-section is determined by the relationship between the pore diameter and the height of permeable concrete: a ⁇ 10d/h, where a is the number of pores on a single cross-section; h is the height of permeable concrete, and d is the pore diameter.
  • the recycled coarse aggregate is the first-class recycled coarse aggregate or the second-class recycled coarse aggregate specified in GB/T25177-2010, with a particle size of 5 to 16 mm;
  • the strength grade of the Portland cement is not less than 52.5;
  • the river sand is medium sand with a fineness modulus of 2.4 to 2.6;
  • the water-reducing agent is a polycarboxylic acid-based water-reducing agent or a naphthalene-based water-reducing agent, and the water-reducing efficiency is not less than 30%.
  • weight ratio of Portland cement, silica fume and fly ash is 7:1:2.
  • preparation method of permeable concrete includes the following steps:
  • Step 1 Add the recycled coarse aggregate and river sand to the mixer and dry mix for 30 seconds;
  • Step 2 Add half of the water to the blender and mix for 30 seconds;
  • Step 3 Add Portland cement, silica fume, and fly ash to the mixer and stir for 30 seconds;
  • Step 4 Add the polycarboxylate water-reducing agent and the remaining water to the mixer and stir for 120 seconds. Mix evenly to obtain fresh concrete;
  • Step 5 Calculate the hole distribution spacing on the mold based on the total number of holes in the concrete.
  • the number and diameter of the steel bars are equal to the number and diameter of the holes. Fix the steel bars in the mold, pour the fresh concrete into the mold, and pull out after initial setting. Permeable concrete can be obtained by removing the steel bars.
  • the invention also provides a regenerated permeable concrete suitable for heavy-duty traffic pavements that is resistant to heavy rain and waterlogging, and is prepared by the above method.
  • the mixing ratio of the present invention is reasonable, and the prepared regenerated permeable concrete that is suitable for heavy-duty traffic pavements and is suitable for heavy rain and waterlogging has a slump greater than 645mm, a compressive strength greater than 90MPa, and a flexural strength greater than 14MPa, and has achieved mechanical strength, water permeability and purification properties. performance balance. Taking Guangzhou as an example, under the influence of heavy rains with return periods of 20, 50 and 100 years respectively, the permeable concrete did not accumulate water throughout the process and did not cause waterlogging. The removal rate of Cu 2+ exceeds 80%, the removal rate of COD and P exceeds 60%, and the removal rate of N exceeds 40%, and the purification performance is good.
  • the permeable concrete effectively reduces the content of chemical oxygen demand (COD), heavy metals (Cu 2+ ), nitrogen (N) and phosphorus (P) and other pollutants in runoff, solving environmental pollution problems caused by rainfall.
  • COD chemical oxygen demand
  • Cu 2+ heavy metals
  • N nitrogen
  • P phosphorus
  • Figure 1 is a schematic structural diagram of permeable concrete
  • Figure 2 shows the relationship between strength and porosity;
  • Figure a) is the compressive strength and
  • Figure b) is the flexural strength;
  • Figure 3 shows the relationship between the removal rate of each pollutant and the porosity: a) COD; b) P; c) N; d) Cu 2+ ;
  • Figure 4 shows the relationship between pollutant removal rate and pore size.
  • An embodiment of the present invention provides a regenerated permeable concrete suitable for heavy-duty traffic pavements that is resistant to heavy rain and waterlogging. It is characterized in that the intensity of heavy rain in each city is divided into three levels with a recurrence period of 20 years, 50 years and 100 years. For example, Guangzhou The city's return period is 20 years, and the one-hour peak rainstorm intensity in 50 years and 100 years is 5.5mm/min, 6.1mm/min, and 6.5mm/min respectively. The maximum waterlogging depth is selected as 0mm.
  • the appropriate water permeability coefficient k is selected based on the rainstorm intensity i and the prescribed maximum waterlogging depth H of each city, and k ⁇ 0.5 mm/s.
  • the pore size and pollutant removal rate form a Wilbu distribution.
  • the diameter of the hole in the present invention is selected to be 0.8mm, 1mm or 2mm.
  • the relation 1 Determine porosity.
  • k is the water permeability coefficient
  • p is the porosity
  • d is the pore diameter
  • is the density of water
  • is the viscosity of water
  • g is the acceleration of gravity.
  • n pV/V p
  • V p the volume of a single pore
  • V p ⁇ hd 2 /4
  • n the number of pores
  • p the porosity
  • V the volume of the concrete specimen
  • h the height of the permeable concrete.
  • the number of holes on a single cross-section is determined by the relationship equation 4a ⁇ 10d/h. Based on the total number of holes and the number of holes on a single cross-section, three types of hole distribution spacing are determined, which are 5mm ⁇ 5mm and 5mm ⁇ 4mm respectively. and 3mm ⁇ 4mm.
  • a kind of regenerated permeable concrete suitable for heavy-duty traffic pavement to resist heavy rain and waterlogging including the following components by weight: 748 to 901 parts of recycled coarse aggregate, 732 to 827 parts of river sand, 600 to 630 parts of Portland cement, silicon 80 to 100 parts of ash, 160 to 180 parts of fly ash, 80 to 120 parts of steel fiber, 1.2 to 1.5 parts of water reducing agent and 180 to 189 parts of water.
  • Portland cement, silica fume, and fly ash are used as cementitious materials.
  • the obtained permeable concrete is shown in Figure 1.
  • Self-compacting concrete is used as the matrix of permeable concrete, and the vertical channels are used as permeable pores.
  • Self-compacting concrete has good workability, and the aggregates are wrapped and tightly bound by cement slurry. Steel fibers effectively build the internal structure of concrete, giving concrete better self-compacting properties and having a great positive impact on the strength of concrete. Permeable concrete maintains good strength even when porosity and pore size reach high levels.
  • the Portland cement has a strength rating of not less than 52.5.
  • the weight ratio of Portland cement, silica fume and fly ash is 7:1:2.
  • the ratio of the weight of water to the total weight of cementitious materials is 0.20 to 0.23.
  • the river sand is medium sand, and the fineness modulus is 2.4 to 2.6.
  • the water-reducing agent is a polycarboxylic acid-based water-reducing agent or a naphthalene-based water-reducing agent, and the water-reducing efficiency is not less than 30%.
  • polycarboxylic acid-based water reducing agents are preferred.
  • Preparing permeable concrete involves the following steps:
  • Step 1 Add the recycled coarse aggregate and river sand to the mixer and dry mix for 30 seconds.
  • Step 2 Add half of the water to the blender and mix for 30 seconds.
  • Step 3 Add Portland cement, silica fume, and fly ash to the mixer and stir for 30 seconds.
  • Step 4 Add the polycarboxylate water-reducing agent and the remaining water to the mixer and stir for 120 seconds. Mix evenly to obtain fresh concrete.
  • Step 5 Pre-fix the steel bars of the preferred diameter on the mold according to the preferred hole distribution spacing, pour the fresh concrete into the mold, and remove the steel bars after initial setting to obtain permeable concrete.
  • the mixing container is a mixer.
  • the present invention measures the slump of concrete in accordance with the "Standard for Test Methods for Performance of Ordinary Concrete Mixtures GB/T50080-2016", determines the allowable waterlogging depth in accordance with the “Exterior Drainage Design Specification GB 50014-2006”, and determines the allowable waterlogging depth in accordance with the "Mechanical Performance Test of Ordinary Concrete”
  • the 28d compressive strength and 28d flexural strength measured according to the method standard GB/T50081-2019, and the Cu 2+ , COD, N and The removal rate of P is used to characterize the performance of the prepared permeable concrete.
  • Step 1 Select the rainfall intensity of Guangzhou City with a return period of 20 years as 0.09mm/s, the allowable waterlogging depth as 0mm, the permeability coefficient as 1.0mm/s, and the pore diameter as 0.8mm. According to the relationship between permeability coefficient and porosity According to relational formula 1, the porosity is selected as 0.126%.
  • Step 2 Determine that 25 water-permeable holes are evenly arranged every 100cm2 according to the relational expression 3. Determine the number of holes in a single cross-section to be 5 according to the relational expression 4, and select the hole distribution as 5mm ⁇ 5mm. Pre-fix the steel bars with the preferred diameter on the mold according to the hole distribution spacing selected in the above step.
  • Step 3 Prepare 901 parts of recycled coarse aggregate, 827 parts of river sand, 630 parts of ordinary Portland cement, 90 parts of silica fume, 180 parts of fly ash, 98 parts of steel fiber, 189 parts of water, and polycarboxylic acid according to the weight parts 1.2 parts of water reducing agent.
  • the particle size of recycled coarse aggregate is 5 ⁇ 16mm.
  • the river sand is medium sand with a fineness modulus of 2.6.
  • the strength grade of ordinary Portland cement is 52.5.
  • the mass ratio of ordinary Portland cement, silica fume and fly ash to the total cementitious materials is 7:1:2, and the water-cement ratio is 0.21.
  • the water reducing efficiency of polycarboxylate water reducing agent is 30%.
  • Step 4 Put each component into a mixer to prepare fresh concrete and pour it into the mold. After initial setting, remove the steel bars to obtain permeable concrete. Cure it at room temperature for 24 hours to demould, and place it in a standard curing room (20 ⁇ 2°C , relative humidity >95%) curing for 28 days.
  • Step 5 After 28 days of curing, conduct compressive strength, flexural strength, water purification capacity and heavy rain simulation tests.
  • the purification test is to put it into a water tank containing different pollutants and let it stand for 720 minutes. After 720 minutes, the concentration of each pollutant in the water tank is tested.
  • the heavy rain simulation test selected rainfall with return periods of 20, 50, and 100 years in Guangzhou, and placed permeable concrete on a heavy rain machine to conduct a heavy rain simulation test.
  • Step 1 Select the rainfall intensity with a return period of 50 years in Guangzhou as 0.11mm/s, the allowable waterlogging depth as 0mm, the permeability coefficient as 1.5mm/s, and the pore diameter as 1mm. According to the relationship between permeability coefficient and porosity For formula 1, the porosity is selected as 0.196%.
  • Step 2 Determine that 20 water-permeable holes are evenly arranged every 100cm2 according to the relational expression 3. Determine the number of holes in a single section to be 4 according to the relational expression 4, and select the hole distribution as 5mm ⁇ 4mm. Pre-fix the steel bars with the preferred diameter on the mold according to the hole distribution spacing selected in the above step.
  • Step 3 Prepare 901 parts of recycled coarse aggregate, 827 parts of river sand, 630 parts of ordinary Portland cement, 90 parts of silica fume, 180 parts of fly ash, 98 parts of steel fiber, 189 parts of water, and polycarboxylic acid according to the weight parts 1.2 parts of water reducing agent.
  • the particle size of recycled coarse aggregate is 5 ⁇ 16mm.
  • the river sand is medium sand with a fineness modulus of 2.6.
  • the strength grade of ordinary Portland cement is 52.5.
  • the mass ratio of ordinary Portland cement, silica fume and fly ash to the total cementitious materials is 7:1:2, and the water-cement ratio is 0.21.
  • the water reducing efficiency of polycarboxylate water reducing agent is 30%.
  • Step 4 Put each component into a mixer to prepare fresh concrete and pour it into the mold. After initial setting, remove the steel bars to obtain permeable concrete. Cure it at room temperature for 24 hours to demould, and place it in a standard curing room (20 ⁇ 2°C , relative humidity >95%) curing for 28 days.
  • Step 5 After 28 days of curing, conduct compressive strength, flexural strength, water purification capacity and heavy rain simulation tests.
  • the purification test is to put it into a water tank containing different pollutants and let it stand for 720 minutes. After 720 minutes, the concentration of each pollutant in the water tank is tested.
  • the heavy rain simulation test selected rainfall with return periods of 20, 50, and 100 years in Guangzhou, and placed permeable concrete on a heavy rain machine to conduct a heavy rain simulation test.
  • Step 1 Select the rainfall intensity with a return period of 100 years in Guangzhou to be 0.12mm/s, the allowable waterlogging depth to be 0mm, the permeability coefficient to be 3mm/s, and the pore diameter to be 2mm. According to the relationship between permeability coefficient and porosity, , the porosity is chosen to be 0.377%.
  • Step 2 Determine that 12 water permeable holes are evenly arranged every 100cm2 according to the relational expression 3. Determine the number of holes in a single section to be 3 according to the relational expression 4, and select the hole distribution as 4mm ⁇ 3mm. Pre-fix the steel bars with the preferred diameter on the mold according to the hole distribution spacing selected in the above step.
  • Step 3 Prepare 901 parts of recycled coarse aggregate, 827 parts of river sand, 630 parts of ordinary Portland cement, 90 parts of silica fume, 180 parts of fly ash, 98 parts of steel fiber, 189 parts of water, and polycarboxylic acid according to the weight parts 1.2 parts of water reducing agent.
  • the particle size of recycled coarse aggregate is 5 ⁇ 16mm.
  • the river sand is medium sand with a fineness modulus of 2.6.
  • the strength grade of ordinary Portland cement is 52.5.
  • the mass ratio of ordinary Portland cement, silica fume and fly ash to the total cementitious materials is 7:1:2, and the water-cement ratio is 0.21.
  • the water reducing efficiency of polycarboxylate water reducing agent is 30%.
  • Step 4 Put each component into a mixer to prepare fresh concrete and pour it into the mold. After initial setting, remove the steel bars to obtain permeable concrete. Cure it at room temperature for 24 hours to demould, and place it in a standard curing room (20 ⁇ 2°C , relative humidity >95%) curing for 28 days.
  • Step 5 After 28 days of curing, conduct compressive strength, flexural strength, water purification capacity and heavy rain simulation tests.
  • the purification test is to put it into a water tank containing different pollutants and let it stand for 720 minutes. After 720 minutes, the concentration of each pollutant in the water tank is tested.
  • the heavy rain simulation test selected rainfall with return periods of 20, 50, and 100 years in Guangzhou, and placed permeable concrete on a heavy rain machine to conduct a heavy rain simulation test.
  • Step 1 Prepare 901 parts of recycled coarse aggregate, 827 parts of river sand, 630 parts of ordinary Portland cement, 90 parts of silica fume, 180 parts of fly ash, 98 parts of steel fiber, 189 parts of water, and polycarboxylic acid according to the weight parts 1.2 parts of water reducing agent.
  • regenerating thick bone The particle size of the material is 5 ⁇ 16mm.
  • the river sand is medium sand with a fineness modulus of 2.6.
  • the strength grade of ordinary Portland cement is 52.5.
  • the mass ratio of ordinary Portland cement, silica fume and fly ash to the total cementitious materials is 7:1:2, and the water-cement ratio is 0.21.
  • the water reducing efficiency of polycarboxylate water reducing agent is 30%.
  • Step 2 Select the porosity to be 0.08%, the pore diameter to be 0.8mm, and the pore distribution to be 4mm ⁇ 4mm.
  • Step 3 Put each component into a mixer to prepare fresh concrete and pour it into the mold. After initial setting, remove the steel bars to obtain permeable concrete. Cure it at room temperature for 24 hours to demould, and place it in a standard curing room (20 ⁇ 2°C , relative humidity >95%) curing for 28 days.
  • Step 4 After 28 days of curing, conduct compressive strength, flexural strength, water purification capacity and heavy rain simulation tests.
  • the purification test is to put it into a water tank containing different pollutants and let it stand for 720 minutes. After 720 minutes, the concentration of each pollutant in the water tank is tested.
  • the heavy rain simulation test selected rainfall with return periods of 20, 50, and 100 years in Guangzhou, and placed permeable concrete on a heavy rain machine to conduct a heavy rain simulation test.
  • Step 1 Prepare 901 parts of recycled coarse aggregate, 827 parts of river sand, 630 parts of ordinary Portland cement, 90 parts of silica fume, 180 parts of fly ash, 98 parts of steel fiber, 189 parts of water, and polycarboxylic acid according to the weight parts 1.2 parts of water reducing agent.
  • the particle size of recycled coarse aggregate is 5 ⁇ 16mm.
  • the river sand is medium sand with a fineness modulus of 2.6.
  • the strength grade of ordinary Portland cement is 52.5.
  • the mass ratio of ordinary Portland cement, silica fume and fly ash to the total cementitious materials is 7:1:2, and the water-cement ratio is 0.21.
  • the water reducing efficiency of polycarboxylate water reducing agent is 30%.
  • Step 2 Select the porosity to be 2.011%, the pore diameter to be 4mm, and the pore distribution to be 4mm ⁇ 4mm.
  • Step 3 Put each component into a mixer to prepare fresh concrete and pour it into the mold. After initial setting, remove the steel bars to obtain permeable concrete. Cure it at room temperature for 24 hours to demould, and place it in a standard curing room (20 ⁇ 2°C , relative humidity >95%) curing for 28 days.
  • Step 4 After 28 days of curing, conduct compressive strength, flexural strength, water purification capacity and heavy rain simulation tests.
  • the purification test is to put it into a water tank containing different pollutants and let it stand for 720 minutes. After 720 minutes, the concentration of each pollutant in the water tank is tested.
  • the heavy rain simulation test selected rainfall with return periods of 20, 50, and 100 years in Guangzhou, and placed permeable concrete on a heavy rain machine to conduct a heavy rain simulation test.
  • Step 1 Prepare 754 parts of recycled coarse aggregate, 741 parts of river sand, 630 parts of ordinary Portland cement, 90 parts of silica fume, 180 parts of fly ash, 98 parts of steel fiber, 180 parts of water, and polycarboxylic acid according to the weight parts 1.4 parts of water reducing agent.
  • the particle size of recycled coarse aggregate is 5 ⁇ 16mm.
  • the river sand is medium sand with a fineness modulus of 2.6.
  • the strength grade of ordinary Portland cement is 52.5.
  • the mass ratio of Portland cement, silica fume and fly ash to the total cementitious materials is 7:1:2, and the water-cement ratio is 0.21.
  • the water reducing efficiency of polycarboxylate water reducing agent is 30%.
  • Step 2 Select the porosity to be 2.36%, the pore diameter to be 4mm, and the pore distribution to be 4mm ⁇ 5mm.
  • Step 3 Put each component into a mixer to prepare fresh concrete and pour it into the mold. After initial setting, remove the steel bars to obtain permeable concrete. Cure it at room temperature for 24 hours to demould, and place it in a standard curing room (20 ⁇ 2°C , relative humidity >95%) curing for 28 days.
  • Step 4 After 28 days of curing, conduct compressive strength, flexural strength, water purification capacity and heavy rain simulation tests.
  • the purification test is to put it into a water tank containing different pollutants and let it stand for 720 minutes. After 720 minutes, the concentration of each pollutant in the water tank is tested.
  • the heavy rain simulation test selected rainfall with return periods of 20, 50, and 100 years in Guangzhou, and placed permeable concrete on a heavy rain machine to conduct a heavy rain simulation test.
  • permeable concrete usually relies on adsorption to remove pollutants, and larger porosity provides more contact area. It provides more places for the adsorption of pollutants; the surface of the recycled coarse aggregate used is rough and porous, and a lot of old mortar adheres to it, which increases the specific surface area for the adhesion of harmful substances to the concrete, and also plays a certain role in improving the purification ability.
  • the small porosity cannot provide sufficient permeability coefficient.
  • the permeable concrete of Comparative Examples 2 and 3 has high purification performance and permeability, but excessive porosity leads to a significant reduction in flexural strength. This is because permeable concrete mainly relies on cross-sectional area to provide cross-sectional resistance, and high porosity The area of the tensile area is reduced, thereby significantly reducing the flexural strength. Especially in Comparative Example 3, the flexural strength cannot meet the requirements of heavy-load pavement.
  • the embodiment establishes the relationship between rainstorm intensity and porosity, so that under the influence of rainfall at different return periods, it can be ensured that no water will accumulate on the road surface during the rainstorm.
  • a determined and reasonable pore structure can also ensure that permeable concrete has a high purification capacity.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Porous Artificial Stone Or Porous Ceramic Products (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The present invention relates to the technical field of building materials, and provides a downpour flooding-resistant recycled pervious concrete suitable for a heavy-load traffic pavement, and a preparation method therefor. The method comprises: determining the water permeability coefficient of a pervious concrete according to the rainfall intensity, the depth of flooding water, and a rainfall duration of each region, calculating the porosity of the pervious concrete according to the water permeability coefficient, and finally calculating the total number of pore channels of the concrete according to the porosity. The pervious concrete comprises the following components in parts by weight: 748-901 parts of recycled coarse aggregates, 732-827 parts of river sands, 600-630 parts of Portland cement, 80-100 parts of silica fume, 160-180 parts of fly ash, 80-120 parts of a steel fiber, 1.2-1.5 parts of a water-reducing admixture, and 180-189 parts of water. The pervious concrete provided by the present invention has high strength and excellent downpour flooding resistance for different rainfall intensities, and can also purify pollutants in runoff, and the compressive strength and breaking strength of the pervious concrete far exceed the requirements for a heavy-load pavement.

Description

一种适用于重载交通路面的抗暴雨内涝再生透水混凝土及其制备方法A kind of regenerated permeable concrete suitable for heavy-duty traffic pavement to resist heavy rain and waterlogging and its preparation method 技术领域Technical field
本发明属于建筑材料技术领域,具体涉及一种适用于重载交通路面的抗暴雨内涝再生透水混凝土及其制备方法。The invention belongs to the technical field of building materials, and specifically relates to a heavy rain waterlogging-resistant regenerated permeable concrete suitable for heavy-duty traffic pavements and a preparation method thereof.
背景技术Background technique
近几十年来,极端暴雨频发,这种突发性的降雨历时短、强度大,短时间内会使城市排水系统的压力骤增。而在传统城市建设中不透水路面不断延伸,可渗透的天然地表不断减少,这导致城市应对突发降雨的能力减弱。这些雨水在不透水路面形成地表径流并逐渐积累形成内涝,一定深度的内涝会使城市道路网受到严重干扰和破坏,造成交通堵塞和事故,甚至威胁到人民的生命财产安全。此外,内涝中含有许多污染物,如重金属(Cu2+)、有机物,氮和磷等,这些污染物随地表径流进入城市河流,破坏生态环境。建设海绵城市是实现城市雨水自由流动、应对暴雨内涝等自然灾害的有效措施,而铺设透水混凝土道路是建设海绵城市的关键。In recent decades, extreme rainstorms have occurred frequently. Such sudden rainfalls are short-duration and high-intensity, which can cause a sudden increase in pressure on urban drainage systems in a short period of time. In traditional urban construction, impermeable pavements continue to extend and the permeable natural surface continues to decrease, which leads to a weakening of the city's ability to cope with sudden rainfall. This rainwater forms surface runoff on impermeable pavement and gradually accumulates to form waterlogging. Waterlogging of a certain depth will seriously interfere with and damage the urban road network, causing traffic jams and accidents, and even threatening people's lives and property. In addition, waterlogging contains many pollutants, such as heavy metals (Cu 2+ ), organic matter, nitrogen and phosphorus, etc. These pollutants enter urban rivers with surface runoff, damaging the ecological environment. Building a sponge city is an effective measure to realize the free flow of urban rainwater and respond to natural disasters such as heavy rains and waterlogging, and laying permeable concrete roads is the key to building a sponge city.
然而,传统的透水混凝土面临着一些挑战,包括强度低、耐久性差、孔隙率控制困难,易堵塞和维护不便。并且强度和透水能力、净水能力成负相关,较低孔隙率的透水混凝土会获得较高的强度,但透水能力和净水能力会明显降低;提高孔隙率获得高渗透率和净水能力却又显著降低透水混凝土的强度。因此,如何保证透水混凝土能够迅速排涝,同时又具有较高的强度和净水功能是海绵城市新型道路的发展趋势。However, traditional permeable concrete faces several challenges, including low strength, poor durability, difficult porosity control, easy clogging, and inconvenient maintenance. And strength is negatively correlated with water permeability and water purification capacity. Permeable concrete with lower porosity will obtain higher strength, but water permeability and water purification capacity will be significantly reduced; increasing porosity will obtain high permeability and water purification capacity. It also significantly reduces the strength of permeable concrete. Therefore, how to ensure that permeable concrete can quickly drain water while having high strength and water purification functions is the development trend of new roads in sponge cities.
发明内容Contents of the invention
为解决现有技术的不足,本发明的目的是提供一种适用于重载交通路面的抗暴雨内涝再生透水混凝土及其制备方法,该透水混凝土具有高强度、排涝迅速的特点,有利于缓解了城市内涝,解决了透水混凝土不能在重载交通路面广泛应用的问题。本发明通过优化透水混凝土的孔道数量和分布,包括采用人工成孔方式、优选孔隙率、孔隙直径及孔隙分布,使得制备的透水混凝土在保证高强度的同时,有足够的透水能力和净水能力。In order to solve the deficiencies of the existing technology, the purpose of the present invention is to provide a regenerated permeable concrete suitable for heavy-duty traffic pavements that is resistant to heavy rain and waterlogging and a preparation method thereof. The permeable concrete has the characteristics of high strength and rapid waterlogging, which is beneficial to alleviating the problem. Urban waterlogging solves the problem that permeable concrete cannot be widely used on heavy-duty traffic pavements. The present invention optimizes the number and distribution of pores in permeable concrete, including the use of artificial pore formation, optimal porosity, pore diameter and pore distribution, so that the prepared permeable concrete has sufficient water permeability and water purification capabilities while ensuring high strength. .
为解决现有技术的不足,本发明提供的技术方案为:In order to solve the deficiencies of the existing technology, the technical solutions provided by the present invention are:
一种适用于重载交通路面的抗暴雨内涝再生透水混凝土的制备方法,根据各个地区的暴雨强度、内涝深度和降雨持续时间确定透水混凝土的透水系数,根据透水系数计算透水混凝土的孔隙率,最后根据孔隙率计算混凝土的总孔道个数;所述透水混凝土包括以下重量份的组分:再生粗骨料748~901份,河砂732~827份,硅酸盐水泥600~630份,硅灰80~100份,粉煤灰160~180份,钢纤维80~120份,减水剂1.2~1.5份和水180~189份。 A method for preparing regenerated permeable concrete that is suitable for heavy-duty traffic pavements and is suitable for heavy rain and waterlogging. The water permeability coefficient of the permeable concrete is determined according to the rainstorm intensity, waterlogging depth and rainfall duration in each region, and the porosity of the permeable concrete is calculated based on the water permeability coefficient. Finally, Calculate the total number of pores in concrete based on porosity; the permeable concrete includes the following components by weight: 748 to 901 parts of recycled coarse aggregate, 732 to 827 parts of river sand, 600 to 630 parts of Portland cement, and silica fume 80 to 100 parts, fly ash 160 to 180 parts, steel fiber 80 to 120 parts, water reducing agent 1.2 to 1.5 parts and water 180 to 189 parts.
进一步的,所述的透水系数k通过暴雨强度i、内涝深度H、降雨持续时间t的关系式二k≥i+t/h确定,且k≥0.5mm/s;所述的暴雨强度i根据各城市暴雨强度公式确定,各城市暴雨强度公式可查表获得(《中国新一代暴雨强度公式》);所述的内涝深度H根据室外排水设计规范GB 50014-2006规定的内涝深度(<150mm)确定;所述降雨时间t由各城市不同的抗内涝设计标准确定,例如:广州市主干路允许的最大内涝深度为15cm,消散内涝的最大时间为30分钟。Further, the water permeability coefficient k is determined by the relationship between rainstorm intensity i, waterlogging depth H, and rainfall duration t, k≥i+t/h, and k≥0.5mm/s; the rainstorm intensity i is based on The rainstorm intensity formula of each city is determined, and the rainstorm intensity formula of each city can be obtained by looking up the table ("China's New Generation of Rainstorm Intensity Formula"); the waterlogging depth H is based on the waterlogging depth (<150mm) specified in the outdoor drainage design specification GB 50014-2006. Determine; the rainfall time t is determined by the different anti-waterlogging design standards of each city. For example: the maximum waterlogging depth allowed on the main roads in Guangzhou is 15cm, and the maximum time to dissipate the waterlogging is 30 minutes.
进一步的,所述所述孔径与污染物去除率成威尔布分布,当污染物去除率为50%时,孔径的上下限分别为0.5mm和3mm,污染物去除率=(污染物初始浓度-污染物最终浓度)/污染物初始浓度。Further, the pore diameter and the pollutant removal rate form a Wilbur distribution. When the pollutant removal rate is 50%, the upper and lower limits of the pore diameter are 0.5mm and 3mm respectively, and the pollutant removal rate = (initial concentration of pollutants - final concentration of pollutants)/initial concentration of pollutants.
进一步的,所述孔隙率的计算方法为:其中,k为透水系数;p为孔隙率;d为孔径;ρ为水的密度;μ为水的粘度;g为重力加速度。Further, the calculation method of the porosity is: Among them, k is the water permeability coefficient; p is the porosity; d is the pore diameter; ρ is the density of water; μ is the viscosity of water; g is the acceleration of gravity.
进一步的,所述总孔道个数n和孔隙率p的关系式三为n=pV/Vp,其中,Vp为单个孔径的体积,Vp=πhd2/4;n为总孔道个数;p为孔隙率,V为混凝土试件的体积,h为透水混凝土高度,d为孔径。Furthermore, the third relationship between the total number of pores n and the porosity p is n=pV/V p , where V p is the volume of a single pore, V p =πhd 2 /4; n is the total number of pores. ; p is the porosity, V is the volume of the concrete specimen, h is the height of the permeable concrete, and d is the pore diameter.
进一步的,单一截面上的孔道个数通过孔径和透水混凝土高度的关系式四a≤10d/h确定,其中,a为单一截面上孔道的个数;h为透水混凝土的高度,d为孔径。Furthermore, the number of pores on a single cross-section is determined by the relationship between the pore diameter and the height of permeable concrete: a≤10d/h, where a is the number of pores on a single cross-section; h is the height of permeable concrete, and d is the pore diameter.
进一步的,所述再生粗骨料为GB/T25177—2010规定的一类再生粗骨料或二类再生粗骨料,粒径为5~16mm;所述硅酸盐水泥的强度等级不低于52.5;所述河砂为中砂,细度模数为2.4~2.6;所述减水剂为聚羧酸系减水剂或萘系减水剂,减水效率不低于30%。Further, the recycled coarse aggregate is the first-class recycled coarse aggregate or the second-class recycled coarse aggregate specified in GB/T25177-2010, with a particle size of 5 to 16 mm; the strength grade of the Portland cement is not less than 52.5; the river sand is medium sand with a fineness modulus of 2.4 to 2.6; the water-reducing agent is a polycarboxylic acid-based water-reducing agent or a naphthalene-based water-reducing agent, and the water-reducing efficiency is not less than 30%.
进一步的,所述硅酸盐水泥、硅灰和粉煤灰的重量比为7:1:2。Further, the weight ratio of Portland cement, silica fume and fly ash is 7:1:2.
进一步的,所述透水混凝土的制备方法包含以下步骤:Further, the preparation method of permeable concrete includes the following steps:
步骤一:将再生粗骨料与河砂加入搅拌机干搅30s;Step 1: Add the recycled coarse aggregate and river sand to the mixer and dry mix for 30 seconds;
步骤二:将一半的水加入搅拌机搅拌30s;Step 2: Add half of the water to the blender and mix for 30 seconds;
步骤三:将硅酸盐水泥、硅灰、粉煤灰加入搅拌机搅拌30s;Step 3: Add Portland cement, silica fume, and fly ash to the mixer and stir for 30 seconds;
步骤四:将聚羧酸减水剂和剩下的水加入搅拌机搅拌120s,混合均匀即得新拌混凝土;Step 4: Add the polycarboxylate water-reducing agent and the remaining water to the mixer and stir for 120 seconds. Mix evenly to obtain fresh concrete;
步骤五:在模具上根据混凝土的总孔道个数计算孔分布间距,钢筋的数量和直径等于孔道的数量和直径,将钢筋固定在模具中,将新拌混凝土倒入模具中,初凝后拔去钢筋即可得到透水混凝土。Step 5: Calculate the hole distribution spacing on the mold based on the total number of holes in the concrete. The number and diameter of the steel bars are equal to the number and diameter of the holes. Fix the steel bars in the mold, pour the fresh concrete into the mold, and pull out after initial setting. Permeable concrete can be obtained by removing the steel bars.
本发明还提供一种适用于重载交通路面的抗暴雨内涝再生透水混凝土,由上述方法制备而成。 The invention also provides a regenerated permeable concrete suitable for heavy-duty traffic pavements that is resistant to heavy rain and waterlogging, and is prepared by the above method.
有益效果beneficial effects
本发明的配合比合理,制备的适用于重载交通路面的抗暴雨内涝再生透水混凝土其坍落度大于645mm,抗压强度大于90MPa,抗折强度大于14MPa,取得了力学强度、透水性能和净化性能的平衡关系。以广州市为例,在重现期分别为20,50和100年暴雨作用下,透水混凝土全程未出现积水,均不会产生内涝。对Cu2+去除率超过80%,COD和P的去除率超过60%,N的去除率超过40%,净化性能良好。可广泛应用于重载交通地区路面。该透水混凝土有效降低了径流中的化学需氧量(COD),重金属(Cu2+),氮(N)和磷(P)等污染物含量,解决了降雨时所引起的环境污染问题。The mixing ratio of the present invention is reasonable, and the prepared regenerated permeable concrete that is suitable for heavy-duty traffic pavements and is suitable for heavy rain and waterlogging has a slump greater than 645mm, a compressive strength greater than 90MPa, and a flexural strength greater than 14MPa, and has achieved mechanical strength, water permeability and purification properties. performance balance. Taking Guangzhou as an example, under the influence of heavy rains with return periods of 20, 50 and 100 years respectively, the permeable concrete did not accumulate water throughout the process and did not cause waterlogging. The removal rate of Cu 2+ exceeds 80%, the removal rate of COD and P exceeds 60%, and the removal rate of N exceeds 40%, and the purification performance is good. It can be widely used on roads in heavy-duty traffic areas. The permeable concrete effectively reduces the content of chemical oxygen demand (COD), heavy metals (Cu 2+ ), nitrogen (N) and phosphorus (P) and other pollutants in runoff, solving environmental pollution problems caused by rainfall.
附图说明Description of the drawings
图1为透水混凝土的结构示意图;Figure 1 is a schematic structural diagram of permeable concrete;
图2为强度与孔隙率关系;其中图a)为抗压强度,图b)为抗折强度;Figure 2 shows the relationship between strength and porosity; Figure a) is the compressive strength and Figure b) is the flexural strength;
图3为各污染物去除率与孔隙率关系a)COD;b)P;c)N;d)Cu2+Figure 3 shows the relationship between the removal rate of each pollutant and the porosity: a) COD; b) P; c) N; d) Cu 2+ ;
图4为污染物去除率与孔径的关系。Figure 4 shows the relationship between pollutant removal rate and pore size.
附图标记:1、孔道;2、基体。Reference signs: 1. Channel; 2. Base body.
具体实施方式Detailed ways
下面结合实施方式对本发明作进一步描述。以下实施方式仅用于更加清楚地说明本发明的技术方案,而不能以此来限制本发明的保护范围。The present invention will be further described below in conjunction with the embodiments. The following embodiments are only used to illustrate the technical solutions of the present invention more clearly, but cannot be used to limit the scope of the present invention.
本发明实施例提供一种适用于重载交通路面的抗暴雨内涝再生透水混凝土,其特征在于,各个城市的暴雨强度分为重现期为20年,50年和100年三个等级,例如广州市重现期为20年,50年和100年的1小时峰值暴雨强度分别为5.5mm/min,6.1mm/min,6.5mm/min。最大内涝深度选择为0mm。An embodiment of the present invention provides a regenerated permeable concrete suitable for heavy-duty traffic pavements that is resistant to heavy rain and waterlogging. It is characterized in that the intensity of heavy rain in each city is divided into three levels with a recurrence period of 20 years, 50 years and 100 years. For example, Guangzhou The city's return period is 20 years, and the one-hour peak rainstorm intensity in 50 years and 100 years is 5.5mm/min, 6.1mm/min, and 6.5mm/min respectively. The maximum waterlogging depth is selected as 0mm.
通过各个城市的暴雨强度i和规定的最大内涝深度H选择合适的透水系数k,且k≥0.5mm/s。The appropriate water permeability coefficient k is selected based on the rainstorm intensity i and the prescribed maximum waterlogging depth H of each city, and k ≥ 0.5 mm/s.
根据图4可知,孔径与污染物去除率成威尔布分布。随着孔径的增大,污染物的去除率先增加后降低,当污染物去除率为50%时,孔径的上下限分为0.5mm和3mm。因此为了获得较高的污染物去除率,本发明中孔道的直径选择为0.8mm,1mm或2mm。根据关系式一确定孔隙率。其中,k为透水系数;p为孔隙率;d为孔径;ρ为水的密度;μ为水的粘度;g为重力加速度。According to Figure 4, it can be seen that the pore size and pollutant removal rate form a Wilbu distribution. As the pore diameter increases, the removal of pollutants first increases and then decreases. When the pollutant removal rate is 50%, the upper and lower limits of the pore diameter are divided into 0.5mm and 3mm. Therefore, in order to obtain a higher pollutant removal rate, the diameter of the hole in the present invention is selected to be 0.8mm, 1mm or 2mm. According to the relation 1 Determine porosity. Among them, k is the water permeability coefficient; p is the porosity; d is the pore diameter; ρ is the density of water; μ is the viscosity of water; g is the acceleration of gravity.
总孔道个数n和孔隙率p的关系式三为n=pV/Vp,其中,Vp为单个孔径的体积,Vp=πhd2/4;n为孔道个数;p为孔隙率,V为混凝土试件的体积,h为透水混凝土高度。 The third relationship between the total number of pores n and the porosity p is n = pV/V p , where V p is the volume of a single pore, V p = πhd 2 /4; n is the number of pores; p is the porosity, V is the volume of the concrete specimen, and h is the height of the permeable concrete.
单一截面上孔道的个数通过关系式四a≤10d/h确定,根据总孔道个数和单一截面上孔道个数确定了三种孔左右及上下分布间距,分别为5mm×5mm、5mm×4mm和3mm×4mm。The number of holes on a single cross-section is determined by the relationship equation 4a≤10d/h. Based on the total number of holes and the number of holes on a single cross-section, three types of hole distribution spacing are determined, which are 5mm×5mm and 5mm×4mm respectively. and 3mm×4mm.
一种适用于重载交通路面的抗暴雨内涝再生透水混凝土,包括以下重量份的组分:再生粗骨料748~901份,河砂732~827份,硅酸盐水泥600~630份,硅灰80~100份,粉煤灰160~180份,钢纤维80~120份,减水剂1.2~1.5份和水180~189份。硅酸盐水泥,硅灰,粉煤灰作为胶凝材料,得到的透水混凝土如图1所示,自密实混凝土作为透水混凝土的基体,上下直通的孔道作为透水孔隙。自密实混凝土具有很好的和易性,骨料被水泥浆包裹并紧密结合。钢纤维有效地构筑了混凝土的内部结构,使混凝土具有更好的自密实性能,对混凝土的强度有很大的积极影响。即使孔隙率和孔径达到较高水平,透水混凝土仍能保持良好的强度。A kind of regenerated permeable concrete suitable for heavy-duty traffic pavement to resist heavy rain and waterlogging, including the following components by weight: 748 to 901 parts of recycled coarse aggregate, 732 to 827 parts of river sand, 600 to 630 parts of Portland cement, silicon 80 to 100 parts of ash, 160 to 180 parts of fly ash, 80 to 120 parts of steel fiber, 1.2 to 1.5 parts of water reducing agent and 180 to 189 parts of water. Portland cement, silica fume, and fly ash are used as cementitious materials. The obtained permeable concrete is shown in Figure 1. Self-compacting concrete is used as the matrix of permeable concrete, and the vertical channels are used as permeable pores. Self-compacting concrete has good workability, and the aggregates are wrapped and tightly bound by cement slurry. Steel fibers effectively build the internal structure of concrete, giving concrete better self-compacting properties and having a great positive impact on the strength of concrete. Permeable concrete maintains good strength even when porosity and pore size reach high levels.
在本发明的可选实施例中,硅酸盐水泥的强度等级不低于52.5。In an alternative embodiment of the invention, the Portland cement has a strength rating of not less than 52.5.
在本发明的可选实施例中,硅酸盐水泥、硅灰和粉煤灰的重量比为7:1:2。In an optional embodiment of the present invention, the weight ratio of Portland cement, silica fume and fly ash is 7:1:2.
在本发明的可选实施例中,水的重量与胶凝材料(硅酸盐水泥、硅灰、粉煤灰以及矿渣)的总重量之比为0.20~0.23。In an optional embodiment of the present invention, the ratio of the weight of water to the total weight of cementitious materials (Portland cement, silica fume, fly ash and slag) is 0.20 to 0.23.
在本发明的可选实施例中,河砂为中砂,细度模数为2.4~2.6。In an optional embodiment of the present invention, the river sand is medium sand, and the fineness modulus is 2.4 to 2.6.
在本发明的可选实施例中,减水剂为聚羧酸系减水剂或萘系减水剂,减水效率不低于30%。其中,聚羧酸系减水剂为优选的减水剂。In an optional embodiment of the present invention, the water-reducing agent is a polycarboxylic acid-based water-reducing agent or a naphthalene-based water-reducing agent, and the water-reducing efficiency is not less than 30%. Among them, polycarboxylic acid-based water reducing agents are preferred.
制备透水混凝土包含以下步骤:Preparing permeable concrete involves the following steps:
步骤一:将再生粗骨料与河砂加入搅拌机干搅30s。Step 1: Add the recycled coarse aggregate and river sand to the mixer and dry mix for 30 seconds.
步骤二:将一半的水加入搅拌机搅拌30s。Step 2: Add half of the water to the blender and mix for 30 seconds.
步骤三:将硅酸盐水泥、硅灰、粉煤灰加入搅拌机搅拌30s。Step 3: Add Portland cement, silica fume, and fly ash to the mixer and stir for 30 seconds.
步骤四:将聚羧酸减水剂和剩下的水加入搅拌机搅拌120s,混合均匀即得新拌混凝土。Step 4: Add the polycarboxylate water-reducing agent and the remaining water to the mixer and stir for 120 seconds. Mix evenly to obtain fresh concrete.
步骤五:在模具上根据优选的孔分布间距预先固定优选直径的钢筋,将新拌混凝土倒入模具中,初凝后拔去钢筋即可得到透水混凝土。Step 5: Pre-fix the steel bars of the preferred diameter on the mold according to the preferred hole distribution spacing, pour the fresh concrete into the mold, and remove the steel bars after initial setting to obtain permeable concrete.
在本发明的可选实施例中,搅拌容器为搅拌机。In an optional embodiment of the invention, the mixing container is a mixer.
本发明依据《普通混凝土拌合物性能试验方法标准GB/T50080-2016》测量混凝土的坍落度,依据《室外排水设计规范GB 50014-2006》确定允许的内涝深度,依据《普通混凝土力学性能试验方法标准GB/T50081—2019》测量得到的28d抗压强度、28d抗折强度,以及依据《城镇污水水质标准检验方法GJ/T 51-2018》测量得到720分钟后Cu2+、COD、N和P的去除率来表征所制备的透水混凝土的性能。The present invention measures the slump of concrete in accordance with the "Standard for Test Methods for Performance of Ordinary Concrete Mixtures GB/T50080-2016", determines the allowable waterlogging depth in accordance with the "Exterior Drainage Design Specification GB 50014-2006", and determines the allowable waterlogging depth in accordance with the "Mechanical Performance Test of Ordinary Concrete" The 28d compressive strength and 28d flexural strength measured according to the method standard GB/T50081-2019, and the Cu 2+ , COD, N and The removal rate of P is used to characterize the performance of the prepared permeable concrete.
实施例一Embodiment 1
按照以下步骤制备透水混凝土: Follow these steps to prepare permeable concrete:
步骤一、选取广州市重现期为20年的降雨强度为0.09mm/s,允许的内涝深度为0mm,选择透水系数为1.0mm/s,孔径选择为0.8mm,根据透水系数与孔隙率的关系式一,孔隙率选择为0.126%。Step 1. Select the rainfall intensity of Guangzhou City with a return period of 20 years as 0.09mm/s, the allowable waterlogging depth as 0mm, the permeability coefficient as 1.0mm/s, and the pore diameter as 0.8mm. According to the relationship between permeability coefficient and porosity According to relational formula 1, the porosity is selected as 0.126%.
步骤二、根据关系式三确定每100cm2上均匀布置25个透水孔,根据关系式四确定单一截面上孔道的个数为5个,孔分布选择为5mm×5mm。在模具上根据以上步骤选择的孔分布间距预先固定优选直径的钢筋。Step 2: Determine that 25 water-permeable holes are evenly arranged every 100cm2 according to the relational expression 3. Determine the number of holes in a single cross-section to be 5 according to the relational expression 4, and select the hole distribution as 5mm×5mm. Pre-fix the steel bars with the preferred diameter on the mold according to the hole distribution spacing selected in the above step.
步骤三、按照重量份准备再生粗骨料901份,河砂827份,普通硅酸盐水泥630份,硅灰90份,粉煤灰180份,钢纤维98份,水189份,聚羧酸减水剂1.2份。其中,再生粗骨料粒径为5~16mm。河砂为中砂,细度模数为2.6。普通硅酸盐水泥的强度等级为52.5,普通硅酸盐水泥、硅灰、粉煤灰的质量占总胶凝材料的比例为7:1:2,水胶比为0.21。聚羧酸减水剂的减水效率为30%。Step 3: Prepare 901 parts of recycled coarse aggregate, 827 parts of river sand, 630 parts of ordinary Portland cement, 90 parts of silica fume, 180 parts of fly ash, 98 parts of steel fiber, 189 parts of water, and polycarboxylic acid according to the weight parts 1.2 parts of water reducing agent. Among them, the particle size of recycled coarse aggregate is 5~16mm. The river sand is medium sand with a fineness modulus of 2.6. The strength grade of ordinary Portland cement is 52.5. The mass ratio of ordinary Portland cement, silica fume and fly ash to the total cementitious materials is 7:1:2, and the water-cement ratio is 0.21. The water reducing efficiency of polycarboxylate water reducing agent is 30%.
步骤四、将各组成分放入搅拌机制备新拌混凝土并倒入模具中,初凝后拔去钢筋即可得到透水混凝土,在常温中养护24h脱模,放入标准养护室(20±2℃,相对湿度>95%)养护28天。Step 4: Put each component into a mixer to prepare fresh concrete and pour it into the mold. After initial setting, remove the steel bars to obtain permeable concrete. Cure it at room temperature for 24 hours to demould, and place it in a standard curing room (20±2℃ , relative humidity >95%) curing for 28 days.
步骤五、养护28天后进行抗压强度、抗折强度、水净化能力和暴雨模拟试验。净化试验为放入装有不同污染物的水箱内静置,720分钟后测试水箱中各污染物浓度。暴雨模拟试验选择广州市重现期为20、50、100年的降雨,将透水混凝土放到暴雨机器上进行暴雨模拟试验。Step 5: After 28 days of curing, conduct compressive strength, flexural strength, water purification capacity and heavy rain simulation tests. The purification test is to put it into a water tank containing different pollutants and let it stand for 720 minutes. After 720 minutes, the concentration of each pollutant in the water tank is tested. The heavy rain simulation test selected rainfall with return periods of 20, 50, and 100 years in Guangzhou, and placed permeable concrete on a heavy rain machine to conduct a heavy rain simulation test.
实施例二Embodiment 2
按照以下步骤制备透水混凝土:Follow these steps to prepare permeable concrete:
步骤一、选取广州市重现期为50年的降雨强度为0.11mm/s,允许的内涝深度为0mm,选择透水系数为1.5mm/s,孔径选择为1mm,根据透水系数与孔隙率的关系式一,孔隙率选择为0.196%。Step 1. Select the rainfall intensity with a return period of 50 years in Guangzhou as 0.11mm/s, the allowable waterlogging depth as 0mm, the permeability coefficient as 1.5mm/s, and the pore diameter as 1mm. According to the relationship between permeability coefficient and porosity For formula 1, the porosity is selected as 0.196%.
步骤二、根据关系式三确定每100cm2上均匀布置20个透水孔,根据关系式四确定单一截面上孔道的个数为4个,孔分布选择为5mm×4mm。在模具上根据以上步骤选择的孔分布间距预先固定优选直径的钢筋。Step 2: Determine that 20 water-permeable holes are evenly arranged every 100cm2 according to the relational expression 3. Determine the number of holes in a single section to be 4 according to the relational expression 4, and select the hole distribution as 5mm×4mm. Pre-fix the steel bars with the preferred diameter on the mold according to the hole distribution spacing selected in the above step.
步骤三、按照重量份准备再生粗骨料901份,河砂827份,普通硅酸盐水泥630份,硅灰90份,粉煤灰180份,钢纤维98份,水189份,聚羧酸减水剂1.2份。其中,再生粗骨料粒径为5~16mm。河砂为中砂,细度模数为2.6。普通硅酸盐水泥的强度等级为52.5,普通硅酸盐水泥、硅灰、粉煤灰的质量占总胶凝材料的比例为7:1:2,水胶比为0.21。聚羧酸减水剂的减水效率为30%。 Step 3: Prepare 901 parts of recycled coarse aggregate, 827 parts of river sand, 630 parts of ordinary Portland cement, 90 parts of silica fume, 180 parts of fly ash, 98 parts of steel fiber, 189 parts of water, and polycarboxylic acid according to the weight parts 1.2 parts of water reducing agent. Among them, the particle size of recycled coarse aggregate is 5~16mm. The river sand is medium sand with a fineness modulus of 2.6. The strength grade of ordinary Portland cement is 52.5. The mass ratio of ordinary Portland cement, silica fume and fly ash to the total cementitious materials is 7:1:2, and the water-cement ratio is 0.21. The water reducing efficiency of polycarboxylate water reducing agent is 30%.
步骤四、将各组成分放入搅拌机制备新拌混凝土并倒入模具中,初凝后拔去钢筋即可得到透水混凝土,在常温中养护24h脱模,放入标准养护室(20±2℃,相对湿度>95%)养护28天。Step 4: Put each component into a mixer to prepare fresh concrete and pour it into the mold. After initial setting, remove the steel bars to obtain permeable concrete. Cure it at room temperature for 24 hours to demould, and place it in a standard curing room (20±2℃ , relative humidity >95%) curing for 28 days.
步骤五、养护28天后进行抗压强度、抗折强度、水净化能力和暴雨模拟试验。净化试验为放入装有不同污染物的水箱内静置,720分钟后测试水箱中各污染物浓度。暴雨模拟试验选择广州市重现期为20、50、100年的降雨,将透水混凝土放到暴雨机器上进行暴雨模拟试验。Step 5: After 28 days of curing, conduct compressive strength, flexural strength, water purification capacity and heavy rain simulation tests. The purification test is to put it into a water tank containing different pollutants and let it stand for 720 minutes. After 720 minutes, the concentration of each pollutant in the water tank is tested. The heavy rain simulation test selected rainfall with return periods of 20, 50, and 100 years in Guangzhou, and placed permeable concrete on a heavy rain machine to conduct a heavy rain simulation test.
实施例三Embodiment 3
按照以下步骤制备透水混凝土:Follow these steps to prepare permeable concrete:
步骤一、选取广州市重现期为100年的降雨强度为0.12mm/s,允许的内涝深度为0mm,选择透水系数为3mm/s,孔径选择为2mm,根据透水系数与孔隙率的关系式,孔隙率选择为0.377%。Step 1. Select the rainfall intensity with a return period of 100 years in Guangzhou to be 0.12mm/s, the allowable waterlogging depth to be 0mm, the permeability coefficient to be 3mm/s, and the pore diameter to be 2mm. According to the relationship between permeability coefficient and porosity, , the porosity is chosen to be 0.377%.
步骤二、根据关系式三确定每100cm2上均匀布置12个透水孔,根据关系式四确定单一截面上孔道的个数为3个,孔分布选择为4mm×3mm。在模具上根据以上步骤选择的孔分布间距预先固定优选直径的钢筋。Step 2: Determine that 12 water permeable holes are evenly arranged every 100cm2 according to the relational expression 3. Determine the number of holes in a single section to be 3 according to the relational expression 4, and select the hole distribution as 4mm×3mm. Pre-fix the steel bars with the preferred diameter on the mold according to the hole distribution spacing selected in the above step.
步骤三、按照重量份准备再生粗骨料901份,河砂827份,普通硅酸盐水泥630份,硅灰90份,粉煤灰180份,钢纤维98份,水189份,聚羧酸减水剂1.2份。其中,再生粗骨料粒径为5~16mm。河砂为中砂,细度模数为2.6。普通硅酸盐水泥的强度等级为52.5,普通硅酸盐水泥、硅灰、粉煤灰的质量占总胶凝材料的比例为7:1:2,水胶比为0.21。聚羧酸减水剂的减水效率为30%。Step 3: Prepare 901 parts of recycled coarse aggregate, 827 parts of river sand, 630 parts of ordinary Portland cement, 90 parts of silica fume, 180 parts of fly ash, 98 parts of steel fiber, 189 parts of water, and polycarboxylic acid according to the weight parts 1.2 parts of water reducing agent. Among them, the particle size of recycled coarse aggregate is 5~16mm. The river sand is medium sand with a fineness modulus of 2.6. The strength grade of ordinary Portland cement is 52.5. The mass ratio of ordinary Portland cement, silica fume and fly ash to the total cementitious materials is 7:1:2, and the water-cement ratio is 0.21. The water reducing efficiency of polycarboxylate water reducing agent is 30%.
步骤四、将各组成分放入搅拌机制备新拌混凝土并倒入模具中,初凝后拔去钢筋即可得到透水混凝土,在常温中养护24h脱模,放入标准养护室(20±2℃,相对湿度>95%)养护28天。Step 4: Put each component into a mixer to prepare fresh concrete and pour it into the mold. After initial setting, remove the steel bars to obtain permeable concrete. Cure it at room temperature for 24 hours to demould, and place it in a standard curing room (20±2℃ , relative humidity >95%) curing for 28 days.
步骤五、养护28天后进行抗压强度、抗折强度、水净化能力和暴雨模拟试验。净化试验为放入装有不同污染物的水箱内静置,720分钟后测试水箱中各污染物浓度。暴雨模拟试验选择广州市重现期为20、50、100年的降雨,将透水混凝土放到暴雨机器上进行暴雨模拟试验。Step 5: After 28 days of curing, conduct compressive strength, flexural strength, water purification capacity and heavy rain simulation tests. The purification test is to put it into a water tank containing different pollutants and let it stand for 720 minutes. After 720 minutes, the concentration of each pollutant in the water tank is tested. The heavy rain simulation test selected rainfall with return periods of 20, 50, and 100 years in Guangzhou, and placed permeable concrete on a heavy rain machine to conduct a heavy rain simulation test.
对比例一Comparative Example 1
按照以下步骤制备透水混凝土:Follow these steps to prepare permeable concrete:
步骤一、按照重量份准备再生粗骨料901份,河砂827份,普通硅酸盐水泥630份,硅灰90份,粉煤灰180份,钢纤维98份,水189份,聚羧酸减水剂1.2份。其中,再生粗骨 料粒径为5~16mm。河砂为中砂,细度模数为2.6。普通硅酸盐水泥的强度等级为52.5,普通硅酸盐水泥、硅灰、粉煤灰的质量占总胶凝材料的比例为7:1:2,水胶比为0.21。聚羧酸减水剂的减水效率为30%。Step 1. Prepare 901 parts of recycled coarse aggregate, 827 parts of river sand, 630 parts of ordinary Portland cement, 90 parts of silica fume, 180 parts of fly ash, 98 parts of steel fiber, 189 parts of water, and polycarboxylic acid according to the weight parts 1.2 parts of water reducing agent. Among them, regenerating thick bone The particle size of the material is 5~16mm. The river sand is medium sand with a fineness modulus of 2.6. The strength grade of ordinary Portland cement is 52.5. The mass ratio of ordinary Portland cement, silica fume and fly ash to the total cementitious materials is 7:1:2, and the water-cement ratio is 0.21. The water reducing efficiency of polycarboxylate water reducing agent is 30%.
步骤二、孔隙率选择为0.08%,孔径为0.8mm,孔分布选择为4mm×4mm。Step 2: Select the porosity to be 0.08%, the pore diameter to be 0.8mm, and the pore distribution to be 4mm×4mm.
步骤三、将各组成分放入搅拌机制备新拌混凝土并倒入模具中,初凝后拔去钢筋即可得到透水混凝土,在常温中养护24h脱模,放入标准养护室(20±2℃,相对湿度>95%)养护28天。Step 3: Put each component into a mixer to prepare fresh concrete and pour it into the mold. After initial setting, remove the steel bars to obtain permeable concrete. Cure it at room temperature for 24 hours to demould, and place it in a standard curing room (20±2℃ , relative humidity >95%) curing for 28 days.
步骤四、养护28天后进行抗压强度、抗折强度、水净化能力和暴雨模拟试验。净化试验为放入装有不同污染物的水箱内静置,720分钟后测试水箱中各污染物浓度。暴雨模拟试验选择广州市重现期为20、50、100年的降雨,将透水混凝土放到暴雨机器上进行暴雨模拟试验。Step 4: After 28 days of curing, conduct compressive strength, flexural strength, water purification capacity and heavy rain simulation tests. The purification test is to put it into a water tank containing different pollutants and let it stand for 720 minutes. After 720 minutes, the concentration of each pollutant in the water tank is tested. The heavy rain simulation test selected rainfall with return periods of 20, 50, and 100 years in Guangzhou, and placed permeable concrete on a heavy rain machine to conduct a heavy rain simulation test.
对比例二Comparative Example 2
按照以下步骤制备混凝土:Follow these steps to prepare concrete:
步骤一、按照重量份准备再生粗骨料901份,河砂827份,普通硅酸盐水泥630份,硅灰90份,粉煤灰180份,钢纤维98份,水189份,聚羧酸减水剂1.2份。其中,再生粗骨料粒径为5~16mm。河砂为中砂,细度模数为2.6。普通硅酸盐水泥的强度等级为52.5,普通硅酸盐水泥、硅灰、粉煤灰的质量占总胶凝材料的比例为7:1:2,水胶比为0.21。聚羧酸减水剂的减水效率为30%。Step 1. Prepare 901 parts of recycled coarse aggregate, 827 parts of river sand, 630 parts of ordinary Portland cement, 90 parts of silica fume, 180 parts of fly ash, 98 parts of steel fiber, 189 parts of water, and polycarboxylic acid according to the weight parts 1.2 parts of water reducing agent. Among them, the particle size of recycled coarse aggregate is 5~16mm. The river sand is medium sand with a fineness modulus of 2.6. The strength grade of ordinary Portland cement is 52.5. The mass ratio of ordinary Portland cement, silica fume and fly ash to the total cementitious materials is 7:1:2, and the water-cement ratio is 0.21. The water reducing efficiency of polycarboxylate water reducing agent is 30%.
步骤二、孔隙率选择为2.011%,孔径为4mm,孔分布选择为4mm×4mm。Step 2: Select the porosity to be 2.011%, the pore diameter to be 4mm, and the pore distribution to be 4mm×4mm.
步骤三、将各组成分放入搅拌机制备新拌混凝土并倒入模具中,初凝后拔去钢筋即可得到透水混凝土,在常温中养护24h脱模,放入标准养护室(20±2℃,相对湿度>95%)养护28天。Step 3: Put each component into a mixer to prepare fresh concrete and pour it into the mold. After initial setting, remove the steel bars to obtain permeable concrete. Cure it at room temperature for 24 hours to demould, and place it in a standard curing room (20±2℃ , relative humidity >95%) curing for 28 days.
步骤四、养护28天后进行抗压强度、抗折强度、水净化能力和暴雨模拟试验。净化试验为放入装有不同污染物的水箱内静置,720分钟后测试水箱中各污染物浓度。暴雨模拟试验选择广州市重现期为20、50、100年的降雨,将透水混凝土放到暴雨机器上进行暴雨模拟试验。Step 4: After 28 days of curing, conduct compressive strength, flexural strength, water purification capacity and heavy rain simulation tests. The purification test is to put it into a water tank containing different pollutants and let it stand for 720 minutes. After 720 minutes, the concentration of each pollutant in the water tank is tested. The heavy rain simulation test selected rainfall with return periods of 20, 50, and 100 years in Guangzhou, and placed permeable concrete on a heavy rain machine to conduct a heavy rain simulation test.
对比例三Comparative Example 3
按照以下步骤制备混凝土:Follow these steps to prepare concrete:
步骤一、按照重量份准备再生粗骨料754份,河砂741份,普通硅酸盐水泥630份,硅灰90份,粉煤灰180份,钢纤维98份,水180份,聚羧酸减水剂1.4份。其中,再生粗骨料粒径为5~16mm。河砂为中砂,细度模数为2.6。普通硅酸盐水泥的强度等级为52.5,普通 硅酸盐水泥、硅灰、粉煤灰的质量占总胶凝材料的比例为7:1:2,水胶比为0.21。聚羧酸减水剂的减水效率为30%。Step 1. Prepare 754 parts of recycled coarse aggregate, 741 parts of river sand, 630 parts of ordinary Portland cement, 90 parts of silica fume, 180 parts of fly ash, 98 parts of steel fiber, 180 parts of water, and polycarboxylic acid according to the weight parts 1.4 parts of water reducing agent. Among them, the particle size of recycled coarse aggregate is 5~16mm. The river sand is medium sand with a fineness modulus of 2.6. The strength grade of ordinary Portland cement is 52.5. The mass ratio of Portland cement, silica fume and fly ash to the total cementitious materials is 7:1:2, and the water-cement ratio is 0.21. The water reducing efficiency of polycarboxylate water reducing agent is 30%.
步骤二、孔隙率选择为2.36%,孔径为4mm,孔分布选择为4mm×5mm。Step 2: Select the porosity to be 2.36%, the pore diameter to be 4mm, and the pore distribution to be 4mm×5mm.
步骤三、将各组成分放入搅拌机制备新拌混凝土并倒入模具中,初凝后拔去钢筋即可得到透水混凝土,在常温中养护24h脱模,放入标准养护室(20±2℃,相对湿度>95%)养护28天。Step 3: Put each component into a mixer to prepare fresh concrete and pour it into the mold. After initial setting, remove the steel bars to obtain permeable concrete. Cure it at room temperature for 24 hours to demould, and place it in a standard curing room (20±2℃ , relative humidity >95%) curing for 28 days.
步骤四、养护28天后进行抗压强度、抗折强度、水净化能力和暴雨模拟试验。净化试验为放入装有不同污染物的水箱内静置,720分钟后测试水箱中各污染物浓度。暴雨模拟试验选择广州市重现期为20、50、100年的降雨,将透水混凝土放到暴雨机器上进行暴雨模拟试验。Step 4: After 28 days of curing, conduct compressive strength, flexural strength, water purification capacity and heavy rain simulation tests. The purification test is to put it into a water tank containing different pollutants and let it stand for 720 minutes. After 720 minutes, the concentration of each pollutant in the water tank is tested. The heavy rain simulation test selected rainfall with return periods of 20, 50, and 100 years in Guangzhou, and placed permeable concrete on a heavy rain machine to conduct a heavy rain simulation test.
试验结果如表1和表2所示,污染物的类型和初始浓度如表3所示,在水净化实验之前,在实验室制备污水。分别以邻苯二甲酸氢钾、磷酸二氢钾、硝酸钾和无水硫酸铜为碳源、磷源、氮源和铜源。The test results are shown in Tables 1 and 2, and the types and initial concentrations of pollutants are shown in Table 3. Before the water purification experiment, sewage was prepared in the laboratory. Potassium hydrogen phthalate, potassium dihydrogen phosphate, potassium nitrate and anhydrous copper sulfate were used as carbon source, phosphorus source, nitrogen source and copper source respectively.
表1透水混凝土的力学、净化和透水性能数据
Table 1 Mechanical, purification and water permeability performance data of permeable concrete
表2 60分钟降雨作用下的积水深度(mm)

Table 2 Water accumulation depth under 60 minutes of rainfall (mm)

表3污染物的初始浓度
Table 3 Initial concentrations of pollutants
结果表明,图2中显示实施例中抗压强度和抗折强度均远远超过重载道路对道路强度的要求;在净化能力方面,如图3所示,透水混凝土对Cu2+去除率超过80%,COD和P的去除率超过60%,N的去除率超过40%,净化性能良好。在模拟暴雨的整个过程中,重现期为20、50和100年的三种暴雨水平下,透水混凝土试件表面均无积水现象,满足抗暴雨内涝要求。尽管对比例一的透水混凝土拥有较高的力学性能,但孔隙率过小导致净化性能较差,这是因为透水混凝土通常依靠吸附去除污染物,较大的孔隙率提供了更多的接触面积,为污染物的吸附提供了更多的场所;采用的再生粗骨料其表面粗糙多孔,粘附了很多旧砂浆,增加了混凝土黏附有害物质的比表面积,对净化能力也起到了一定提升作用。The results show that the compressive strength and flexural strength in the embodiment shown in Figure 2 far exceed the road strength requirements of heavy-duty roads; in terms of purification capacity, as shown in Figure 3, the Cu 2+ removal rate of permeable concrete exceeds 80%, COD and P removal rate exceeds 60%, N removal rate exceeds 40%, and the purification performance is good. During the entire process of simulating heavy rains, under three heavy rain levels with return periods of 20, 50 and 100 years, there was no water accumulation on the surface of the permeable concrete specimens, meeting the requirements for resisting heavy rain flooding. Although the permeable concrete of Comparative Example 1 has high mechanical properties, the porosity is too small, resulting in poor purification performance. This is because permeable concrete usually relies on adsorption to remove pollutants, and larger porosity provides more contact area. It provides more places for the adsorption of pollutants; the surface of the recycled coarse aggregate used is rough and porous, and a lot of old mortar adheres to it, which increases the specific surface area for the adhesion of harmful substances to the concrete, and also plays a certain role in improving the purification ability.
此外,较小的孔隙率无法提供足够的渗透系数,当渗透系数小于暴雨强度时,雨水不能及时通过透水混凝土流入地下,导致路面积水状况发生。对比例二和对比例三的透水混凝土拥有较高的净化性能和渗透率,但孔隙率过大导致抗折强度显著降低,这是因为透水混凝土主要依靠截面面积提供截面抵抗能力,而高孔隙率减小了受拉区域的面积,从而使抗折强度显著降低,尤其是对比例三,其抗折强度已经无法满足重载路面的要求。实施例建立了暴雨强度与孔隙率的关系,因此在不同重现期降雨作用下可以保证暴雨期间全程路面无积水产生。确定的合理的孔隙结构也可以保证透水混凝土拥有较高的净化能力。通过上述分析,该发明可以根据所处地区的抗暴雨内涝要求,确定了不同暴雨强度的最佳孔隙率,设计适合的孔隙结构,取得透水混凝土透水性能、力学性能和净化能力之间较好的平衡关系。In addition, the small porosity cannot provide sufficient permeability coefficient. When the permeability coefficient is less than the intensity of rainstorm, rainwater cannot flow into the ground through the permeable concrete in time, resulting in water accumulation on the road. The permeable concrete of Comparative Examples 2 and 3 has high purification performance and permeability, but excessive porosity leads to a significant reduction in flexural strength. This is because permeable concrete mainly relies on cross-sectional area to provide cross-sectional resistance, and high porosity The area of the tensile area is reduced, thereby significantly reducing the flexural strength. Especially in Comparative Example 3, the flexural strength cannot meet the requirements of heavy-load pavement. The embodiment establishes the relationship between rainstorm intensity and porosity, so that under the influence of rainfall at different return periods, it can be ensured that no water will accumulate on the road surface during the rainstorm. A determined and reasonable pore structure can also ensure that permeable concrete has a high purification capacity. Through the above analysis, this invention can determine the optimal porosity of different rainstorm intensities according to the requirements of the area to resist heavy rain and waterlogging, design a suitable pore structure, and achieve better permeability, mechanical properties and purification capabilities of permeable concrete. Balance the relationship.
以上所述仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明技术原理的前提下,还可以做出若干改进和变形,这些改进和变形也应视为本发明的保护范围。 The above are only preferred embodiments of the present invention. It should be noted that those of ordinary skill in the art can also make several improvements and modifications without departing from the technical principles of the present invention. These improvements and modifications It should also be regarded as the protection scope of the present invention.

Claims (7)

  1. 一种适用于重载交通路面的抗暴雨内涝再生透水混凝土的制备方法,其特征在于,根据各个地区的暴雨强度、内涝深度和降雨持续时间确定透水混凝土的透水系数,根据透水系数计算透水混凝土的孔隙率,最后根据孔隙率计算混凝土的总孔道个数;所述透水混凝土包括以下重量份的组分:再生粗骨料748~901份,河砂732~827份,硅酸盐水泥600~630份,硅灰80~100份,粉煤灰160~180份,钢纤维80~120份,减水剂1.2~1.5份和水180~189份;A method for preparing regenerated permeable concrete that is suitable for heavy-duty traffic pavements and is characterized by determining the permeability coefficient of the permeable concrete based on the intensity of heavy rain, the depth of waterlogging, and the duration of rainfall in each region, and calculating the permeable concrete based on the permeability coefficient. Porosity, and finally calculate the total number of pores in the concrete based on the porosity; the permeable concrete includes the following components by weight: 748 to 901 parts of recycled coarse aggregate, 732 to 827 parts of river sand, and 600 to 630 parts of Portland cement. parts, 80 to 100 parts of silica fume, 160 to 180 parts of fly ash, 80 to 120 parts of steel fiber, 1.2 to 1.5 parts of water reducing agent and 180 to 189 parts of water;
    所述的透水系数k通过暴雨强度i、内涝深度H、降雨持续时间t的关系式k≥i+H/t确定,且k≥0.5mm/s;The water permeability coefficient k is determined by the relationship between rainstorm intensity i, waterlogging depth H, and rainfall duration t, k≥i+H/t, and k≥0.5mm/s;
    所述孔隙率的计算方法为:其中,k为透水系数;p为孔隙率;d为孔径;ρ为水的密度;μ为水的粘度;g为重力加速度;The calculation method of the porosity is: Among them, k is the water permeability coefficient; p is the porosity; d is the pore diameter; ρ is the density of water; μ is the viscosity of water; g is the acceleration of gravity;
    所述总孔道个数n和孔隙率p的关系式为n=pV/Vp,其中,Vp为单个孔径的体积,Vp=πhd2/4;n为总孔道个数;p为孔隙率,V为混凝土试件的体积,h为透水混凝土高度,d为孔径;The relationship between the total number of pores n and the porosity p is n = pV/V p , where V p is the volume of a single pore, V p = πhd 2 /4; n is the total number of pores; p is the pore rate, V is the volume of the concrete specimen, h is the height of the permeable concrete, and d is the pore diameter;
    单一截面上的孔道个数通过孔径和透水混凝土高度的关系式a≤10d/h确定,其中,a为单一截面上孔道的个数;h为透水混凝土的高度,d为孔径。The number of pores on a single cross-section is determined by the relationship between the pore diameter and the height of permeable concrete, a≤10d/h, where a is the number of pores on a single cross-section; h is the height of permeable concrete, and d is the pore diameter.
  2. 根据权利要求1所述的适用于重载交通路面的抗暴雨内涝再生透水混凝土的制备方法,其特征在于,所述的暴雨强度i根据各城市暴雨强度公式确定;所述的内涝深度H根据室外排水设计规范GB 50014-2006规定的内涝深度确定;所述降雨时间t由各城市不同的抗内涝设计标准确定。The method for preparing regenerated permeable concrete that is suitable for heavy-duty traffic pavements and is suitable for heavy rainstorms and waterlogging, characterized in that the rainstorm intensity i is determined according to the rainstorm intensity formula of each city; the waterlogging depth H is determined according to the outdoor rainstorm intensity formula. The depth of waterlogging specified in the drainage design specification GB 50014-2006 is determined; the rainfall time t is determined by the different anti-waterlogging design standards of each city.
  3. 根据权利要求1所述的适用于重载交通路面的抗暴雨内涝再生透水混凝土的制备方法,其特征在于,所述孔径与污染物去除率成威尔布分布,当污染物去除率为50%时,孔径的上下限分别为0.5mm和3mm,污染物去除率=(污染物初始浓度-污染物最终浓度)/污染物初始浓度。The method for preparing regenerated permeable concrete suitable for heavy-duty traffic pavements to resist heavy rain and waterlogging according to claim 1, characterized in that the pore size and the pollutant removal rate form a Wilbur distribution. When the pollutant removal rate is 50% When , the upper and lower limits of the pore diameter are 0.5mm and 3mm respectively, and the pollutant removal rate = (initial concentration of pollutants - final concentration of pollutants) / initial concentration of pollutants.
  4. 根据权利要求1所述的适用于重载交通路面的抗暴雨内涝再生透水混凝土的制备方法,其特征在于,所述再生粗骨料为GB/T25177—2010规定的一类再生粗骨料或二类再生粗骨料,粒径为5~16mm;所述硅酸盐水泥的强度等级不低于52.5;所述河砂为中砂,细度模数为2.4~2.6;所述减水剂为聚羧酸系减水剂或萘系减水剂,减水效率不低于30%。The preparation method of regenerated permeable concrete suitable for heavy-duty traffic pavements to resist heavy rain and waterlogging according to claim 1, characterized in that the regenerated coarse aggregate is a type of recycled coarse aggregate or type II regenerated coarse aggregate specified in GB/T25177-2010. Regenerated coarse aggregate with a particle size of 5 to 16 mm; the strength grade of the Portland cement is not less than 52.5; the river sand is medium sand with a fineness modulus of 2.4 to 2.6; the water reducing agent is Polycarboxylic acid-based water-reducing agent or naphthalene-based water-reducing agent, the water-reducing efficiency is not less than 30%.
  5. 根据权利要求1所述的适用于重载交通路面的抗暴雨内涝再生透水混凝土的制备方法,其特征在于,所述硅酸盐水泥、硅灰和粉煤灰的重量比为7:1:2。The method for preparing regenerated permeable concrete suitable for heavy-duty traffic pavements to resist heavy rain and waterlogging according to claim 1, characterized in that the weight ratio of Portland cement, silica fume and fly ash is 7:1:2 .
  6. 根据权利要求1所述的适用于重载交通路面的抗暴雨内涝再生透水混凝土的制备方法,其特征在于,所述透水混凝土的制备方法包含以下步骤: The method for preparing regenerated permeable concrete suitable for heavy-duty traffic pavements to resist heavy rain and waterlogging according to claim 1, characterized in that the preparation method of permeable concrete includes the following steps:
    步骤一:将再生粗骨料与河砂加入搅拌机干搅30s;Step 1: Add the recycled coarse aggregate and river sand to the mixer and dry mix for 30 seconds;
    步骤二:将一半的水加入搅拌机搅拌30s;Step 2: Add half of the water to the blender and mix for 30 seconds;
    步骤三:将硅酸盐水泥、硅灰、粉煤灰加入搅拌机搅拌30s;Step 3: Add Portland cement, silica fume, and fly ash to the mixer and stir for 30 seconds;
    步骤四:将聚羧酸减水剂和剩下的水加入搅拌机搅拌120s,混合均匀即得新拌混凝土;Step 4: Add the polycarboxylate water-reducing agent and the remaining water to the mixer and stir for 120 seconds. Mix evenly to obtain fresh concrete;
    步骤五:在模具上根据混凝土的总孔道个数计算孔分布间距,钢筋的数量和直径等于孔道的数量和直径,将钢筋固定在模具中,将新拌混凝土倒入模具中,初凝后拔去钢筋即可得到透水混凝土。Step 5: Calculate the hole distribution spacing on the mold based on the total number of holes in the concrete. The number and diameter of the steel bars are equal to the number and diameter of the holes. Fix the steel bars in the mold, pour the fresh concrete into the mold, and pull out after initial setting. Permeable concrete can be obtained by removing the steel bars.
  7. 一种适用于重载交通路面的抗暴雨内涝再生透水混凝土,其特征在于,由权利要求1~6任一项所述方法制备而成。 A regenerated permeable concrete suitable for heavy-duty traffic pavements that is resistant to heavy rain and waterlogging, and is characterized in that it is prepared by the method described in any one of claims 1 to 6.
PCT/CN2023/109378 2022-08-05 2023-07-26 Downpour flooding-resistant recycled pervious concrete suitable for heavy-load traffic pavement, and preparation method therefor WO2024027541A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN202210937785.XA CN115215616B (en) 2022-08-05 2022-08-05 Anti-rainstorm waterlogging regenerated permeable concrete applicable to heavy traffic pavement and preparation method thereof
CN202210937785.X 2022-08-05

Publications (1)

Publication Number Publication Date
WO2024027541A1 true WO2024027541A1 (en) 2024-02-08

Family

ID=83616634

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2023/109378 WO2024027541A1 (en) 2022-08-05 2023-07-26 Downpour flooding-resistant recycled pervious concrete suitable for heavy-load traffic pavement, and preparation method therefor

Country Status (2)

Country Link
CN (1) CN115215616B (en)
WO (1) WO2024027541A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115215616B (en) * 2022-08-05 2023-06-06 常州大学 Anti-rainstorm waterlogging regenerated permeable concrete applicable to heavy traffic pavement and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100557454B1 (en) * 2005-05-14 2006-03-10 충남대학교산학협력단 Manufacturing method of high-performance permeable polymer concrete for pavement using recycled aggregates and industrial by-products
CN106227976A (en) * 2016-08-04 2016-12-14 山东交通学院 A kind of laboratory mixing proportion design method of permeable regenerated aggregate concrete
CN109711634A (en) * 2018-12-29 2019-05-03 浙江大学 A kind of regenerative pervious brick mixing proportion design method based on target coefficient of permeability
CN111848040A (en) * 2020-07-23 2020-10-30 常州大学 Design method of anti-rainstorm waterlogging regeneration permeable concrete pavement
CN114580200A (en) * 2022-03-21 2022-06-03 湖南大学 Design method of high-performance recycled aggregate pervious concrete
CN115215616A (en) * 2022-08-05 2022-10-21 常州大学 Rainstorm waterlogging-resistant regenerated pervious concrete suitable for heavy-load traffic pavement and preparation method thereof

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007022872A (en) * 2005-07-19 2007-02-01 Taiheiyo Cement Corp Water-permeable concrete member
CN106830972A (en) * 2017-02-04 2017-06-13 华润水泥技术研发有限公司 A kind of high-intensity fine aggregate pervious concrete and application thereof
CN109543350B (en) * 2018-12-20 2023-03-24 哈尔滨工业大学(深圳) Permeable concrete performance prediction method and system based on mesoscopic model reconstruction
CN110423068A (en) * 2019-08-21 2019-11-08 华南理工大学 A kind of superelevation is strong, high pervious concrete building block and preparation method thereof
CN111116136A (en) * 2019-12-30 2020-05-08 宁波大学 Pervious concrete mix proportion design method based on optimal volume slurry-to-bone ratio
CN112125700B (en) * 2020-09-28 2021-10-22 上海交通大学 Water purification type pervious concrete capable of removing nitrogen and phosphorus and preparation method thereof
CN113984527A (en) * 2021-11-11 2022-01-28 四川靓固科技集团有限公司 Method for calculating compressive strength of pervious concrete

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100557454B1 (en) * 2005-05-14 2006-03-10 충남대학교산학협력단 Manufacturing method of high-performance permeable polymer concrete for pavement using recycled aggregates and industrial by-products
CN106227976A (en) * 2016-08-04 2016-12-14 山东交通学院 A kind of laboratory mixing proportion design method of permeable regenerated aggregate concrete
CN109711634A (en) * 2018-12-29 2019-05-03 浙江大学 A kind of regenerative pervious brick mixing proportion design method based on target coefficient of permeability
CN111848040A (en) * 2020-07-23 2020-10-30 常州大学 Design method of anti-rainstorm waterlogging regeneration permeable concrete pavement
CN114580200A (en) * 2022-03-21 2022-06-03 湖南大学 Design method of high-performance recycled aggregate pervious concrete
CN115215616A (en) * 2022-08-05 2022-10-21 常州大学 Rainstorm waterlogging-resistant regenerated pervious concrete suitable for heavy-load traffic pavement and preparation method thereof

Also Published As

Publication number Publication date
CN115215616A (en) 2022-10-21
CN115215616B (en) 2023-06-06

Similar Documents

Publication Publication Date Title
WO2024027541A1 (en) Downpour flooding-resistant recycled pervious concrete suitable for heavy-load traffic pavement, and preparation method therefor
WO2021129020A1 (en) Preparation and construction method of porous coral aggregate permeable purified concrete
CN107382125B (en) Permeable concrete reinforcing agent and preparation method thereof
CN109111155B (en) Pervious concrete system prepared from construction waste and preparation method thereof
US11370707B1 (en) Asphalt modified with red mud for porous pavement material and application thereof
CN113461380B (en) Plastic concrete for vertical antifouling barrier
CN105236839A (en) Fiber concrete for anticracking impervious superthin plate shell/tube member, and preparation method and application thereof
CN107902987A (en) Decontamination pervious concrete and preparation method
CN106544941B (en) Permeable pavement with purification performance
CN110950610A (en) Sponge body pervious concrete and preparation method and application thereof
CN113651575A (en) Preparation method of high-durability iron tailing waste rock permeable concrete
CN110041005A (en) A kind of pervious concrete reinforcing agent and preparation method thereof and construction technology
Haji et al. Experimental investigation of pervious concrete with use of fly ash and silica fume as admixture
CN105130343A (en) Railway traffic sound-absorption and -insulation fireproof light-weight water-permeable material and preparation method thereof
CN116924748B (en) Solid waste resource recycling type permeable pavement paving material and preparation method and application thereof
CN108793896A (en) A kind of pervious concrete and preparation method thereof
CN114249559A (en) Full-solid waste base water permeable brick with adsorption performance and preparation method thereof
Patil et al. No fine concrete
Liu et al. Analysis on pore structure of non-dispersible underwater concrete in saline soil area
CN113800858A (en) Binder for microporous ecological pavement and construction method thereof
CN108726975A (en) A kind of preparation method of pervious concrete pavement pavement material
CN107902944A (en) A kind of road porous pavement concrete admixture
CN114933455A (en) Novel concrete
CN110451866B (en) Pumpable tough concrete and application thereof in bridge deck continuous plate structure
CN112979249A (en) Composite doped silica fume and nano SiO2Antifreezing water-permeable recycled concrete and preparation method thereof

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 23849249

Country of ref document: EP

Kind code of ref document: A1