WO2024016858A1 - Symbiotic agricultural/photovoltaic/gas system based on drought stress scenario - Google Patents

Symbiotic agricultural/photovoltaic/gas system based on drought stress scenario Download PDF

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Publication number
WO2024016858A1
WO2024016858A1 PCT/CN2023/098046 CN2023098046W WO2024016858A1 WO 2024016858 A1 WO2024016858 A1 WO 2024016858A1 CN 2023098046 W CN2023098046 W CN 2023098046W WO 2024016858 A1 WO2024016858 A1 WO 2024016858A1
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Prior art keywords
hydrogen
photovoltaic
water
tank
drought stress
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PCT/CN2023/098046
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French (fr)
Chinese (zh)
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余汉华
鲁国文
吕云青
韩冬
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上海能源建设工程设计研究有限公司
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Publication of WO2024016858A1 publication Critical patent/WO2024016858A1/en

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G24/00Growth substrates; Culture media; Apparatus or methods therefor
    • A01G24/10Growth substrates; Culture media; Apparatus or methods therefor based on or containing inorganic material
    • A01G24/12Growth substrates; Culture media; Apparatus or methods therefor based on or containing inorganic material containing soil minerals
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G25/00Watering gardens, fields, sports grounds or the like
    • A01G25/02Watering arrangements located above the soil which make use of perforated pipe-lines or pipe-lines with dispensing fittings, e.g. for drip irrigation
    • A01G25/023Dispensing fittings for drip irrigation, e.g. drippers
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/60Constructional parts of cells
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/60Constructional parts of cells
    • C25B9/65Means for supplying current; Electrode connections; Electric inter-cell connections
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02SGENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S20/00Supporting structures for PV modules
    • H02S20/20Supporting structures directly fixed to an immovable object
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P60/00Technologies relating to agriculture, livestock or agroalimentary industries
    • Y02P60/12Technologies relating to agriculture, livestock or agroalimentary industries using renewable energies, e.g. solar water pumping

Definitions

  • the invention relates to the technical field of comprehensive energy application, and in particular to an agro-phosgene symbiosis system based on drought stress scenarios.
  • the technical problem to be solved by the present invention is how to provide an agro-phosgene symbiosis system suitable for drought stress scenarios.
  • the agro-photovoltaic symbiosis system based on drought stress scenarios provided by the present invention includes compound soil, a photovoltaic system, a siphon cleaning drip irrigation system, a hydrogen production system, and a hydrogen mixing pipeline.
  • the compound soil is located below the photovoltaic system, so The compound soil is configured to plant understory crops, the siphon cleaning drip irrigation system is configured to drip water to the photovoltaic system, the compound soil receives the water, and the photovoltaic system supplies water to the hydrogen production system. Electric energy is provided, the hydrogen production system is configured to produce hydrogen gas, and the hydrogen mixing pipeline is connected to the hydrogen production system.
  • the compound soil is made of red mud and sandy soil in a ratio of 1:9.
  • the compound soil is a soil aggregate formed from red mud and sandy soil through dry and wet cycles and pressurized stirring.
  • the photovoltaic system consists of fixed cement pouring piles, high brackets, frameless photovoltaic modules, and cathodic protection grounding connections.
  • the siphon cleaning drip irrigation system includes a storage tank, a main water inlet pipe, an auxiliary water inlet pipe, and an outlet pipe.
  • One end of the main water inlet pipe and the auxiliary water inlet pipe are respectively placed in the storage tank, and the main water inlet pipe is placed in the storage tank.
  • the water pipe and the other end of the auxiliary water inlet pipe are respectively connected to the water outlet pipe through an overflow tee.
  • the main water inlet pipe is provided with a first pneumatic valve and a limit switch, and the auxiliary water inlet pipe is provided with a float ball.
  • the water outlet pipe is provided with a second pneumatic valve.
  • the siphon cleaning drip irrigation system also includes a water storage tower, and the water storage tower is connected to the water storage tank through a conductive cascade water diversion conduit.
  • the water in the siphon cleaning drip irrigation system is compound water with silicon-resistant organic cementitious substances added.
  • the hydrogen production system includes a demineralized water storage tank, an electrolyzer, a drying tank, a hydrogen buffer tank, a compressor, a hydrogen replenishing device, and a hydrogen storage bottle group connected in sequence.
  • the electrolytic tank, drying tank, compressor It is also connected to a cooling device, and the electrolytic tank and drying tank are also connected to a nitrogen storage bottle group.
  • electrolytic tank, drying tank, hydrogen buffer tank, compressor, hydrogen replenishing device, and hydrogen storage bottle group are connected with a flame arrester, and the demineralized water storage tank, electrolytic tank, drying tank, and hydrogen buffer tank are equipped with Drain pipe.
  • the hydrogen mixing pipe is a 316 stainless steel pipe with a nickel content greater than 12%.
  • the present invention realizes an agro-photogas symbiosis system in drought stress scenarios, realizes soil improvement of desert land resources, and can be suitable for Plants grow, and the clean water from the photovoltaic system is used to irrigate the plants.
  • the solar energy converted by the photovoltaic system is used for photovoltaic hydrogen production and the hydrogen mixing ratio of the hydrogen mixing pipeline, which solves the problem of energy transmission and realizes the use of solar energy in desert areas. Conversion absorption.
  • Figure 1 is an overall schematic diagram of the agro-phosgene symbiosis system provided by the embodiment of the present invention
  • Figure 2 is a schematic flow diagram of a siphon cleaning drip irrigation system provided by an embodiment of the present invention.
  • Figure 3 is a schematic flow diagram of a hydrogen production system provided by an embodiment of the present invention.
  • the present invention provides an agro-phosgene symbiosis system based on a drought stress scenario.
  • the agro-phosgene symbiosis system of the present invention consists of a compound soil 1, a photovoltaic system 2, a siphon cleaning drip irrigation system 3, and a hydrogen production system. 4. It consists of 5 hydrogen mixing pipelines.
  • the photovoltaic system 2 receives solar energy and is used for solar power generation.
  • the water stored in the siphon cleaning drip irrigation system 3 is used to clean the photovoltaic system 2.
  • the compound soil 1 is located under the photovoltaic system 2 and is used for planting forests.
  • the hydrogen production system 4 is used to produce hydrogen, and the electricity converted by the photovoltaic system 2 is used by the hydrogen production system 4 Energy input is provided, and the hydrogen produced by the hydrogen production system 4 is output through the hydrogen mixing pipeline 5 .
  • the agro-photovoltaic symbiosis system based on the drought stress scenario provided by the present invention realizes the soil improvement of desert land resources, can be suitable for plant growth, and uses the cleaning water of the photovoltaic system 2 to realize the irrigation of the plants, and the photovoltaic system 2 transforms
  • the solar energy is also used for photovoltaic hydrogen production and the hydrogen mixing ratio of the hydrogen mixing pipeline 5, which solves the problem of energy transmission.
  • the compound soil 1 of this embodiment is made of red mud and sandy soil mixed in a ratio of 1:9, and is formed into soil aggregates through three dry and wet cycles combined with pressurized stirring at 250 r/min, where
  • the quantitative physical indicators of the ratio of red mud and sandy soil are composed of bulk density, fractal dimension, porosity, moisture content, water retention and water stability macroaggregates, and the quantitative chemical indicators are composed of organic matter content, electrical conductivity, pH value, available phosphorus , hydrolyzable nitrogen and available potassium.
  • the understory crops 7 planted on the compound soil 1 are mainly alfalfa, shallots, potatoes and other crops.
  • Photovoltaic system 2 is composed of fixed cement cast piles, high brackets, frameless photovoltaic modules and cathodic protection grounding materials.
  • the structure composed of fixed cement cast piles and high brackets ensures that the height of the photovoltaic modules from the ground is not less than 1.8m to facilitate Growth of understory crops 7.
  • the siphon cleaning drip irrigation system 3 uses the siphon principle to realize endogenous circulation of fluid potential energy.
  • the process of the siphon cleaning drip irrigation system 3 is shown in Figure 2.
  • the siphon cleaning drip irrigation system 3 is pre-started, the second pneumatic valve b1 is opened, the first pneumatic valve b5 is closed, and the third pneumatic valve b4 is opened;
  • the water storage tank b10 stores water and pumps it in from the guide port
  • the water outlet pipe b2 works, the auxiliary water inlet b9 works in conjunction under the pressure difference, and the water level of the storage tank b10 drops; after the limit switch b7 acts, the pipe filling water is unbalanced Until the pipe is flush with the water level of the water tank b10.
  • the siphon cleaning drip irrigation system 3 When the siphon cleaning drip irrigation system 3 is started, the first pneumatic valve b5 on the main water inlet pipe b6 is started, and the cascade water diversion conduit a9 and the water storage tower a11 are opened to divert water to the storage tank b10, so that the water level of the storage tank b10 reaches the overflow tee b3 port And the air in the pipe is evacuated, and the siphon system officially works.
  • the water replenishment of the conduction cascade water diversion pipe a9 and the water storage tower a11 is completed, the limit switch b7 is activated, and the pipeline water flows backward until the float b8 of the auxiliary water inlet pipe b9 intercepts the water.
  • the main water inlet pipe b6 stops working when water inflows, and the outlet pipe b2 is drained, waiting for the storage tank.
  • the water level of b10 is balanced with the main water inlet pipe b6, and the float b8 of the auxiliary water inlet pipe b9 rises to the water level balance of the storage tank b10, the main water inlet pipe b6 and the auxiliary water inlet pipe b9, and finally realizes the endogenous circulation of water potential energy.
  • the water in the siphon cleaning drip irrigation system 3 is compound water with silicon-soluble organic cementitious substances added, which cooperates with the microbial activity and metabolic cycle of the compound soil 1 aggregates.
  • the cleaning cycle is coordinated by the first pneumatic valve b5 and the third pneumatic valve b4. It is completed in conjunction with the 7 growth cycles of understory crops.
  • hydrogen production system 4 consists of main material pipe A1, auxiliary material pipe A2, demineralized water storage tank B1, cooling device A3, nitrogen storage bottle group A4, electrolyzer B2, drying tank B3, hydrogen buffer tank B4, compression It consists of machine B5, hydrogen replenishing device B6, hydrogen storage bottle group B7 and flame arrester B8.
  • the desalted water is sent to the desalted water storage tank B1 and the cooling device A3 through the main material pipe A1.
  • the desalted water from the desalted water storage tank B1 enters the electrolyzer.
  • B2 produces hydrogen by electrolysis and drying tank B3 is dried.
  • the hydrogen and oxygen in electrolytic tank B2 and drying tank B3 are purged and replaced by nitrogen to separate oxygen and hydrogen.
  • Oxygen is released in electrolytic tank B2 through drain pipe C1, and crude hydrogen is produced. Then it enters the drying tank B3 for processing, and then goes through the compressor B5, the hydrogen supplementing device B6, the hydrogen storage B7 or the hydrogen use process, including the electrolytic tank B2, the drying tank B3, the hydrogen buffer tank B4, the compressor B5, the hydrogen supplementing Device B6 and hydrogen storage bottle group B7 are equipped with flame arrester B8.
  • the desalted water from cooling device A3 cools the electrolyzer B2, drying tank B3 and compressor B5 through the refrigerated water supply pipe D1 and return pipe D2, and removes the demineralized water through the auxiliary material pipe A2.
  • Waste water from brine storage tank B1, electrolyzer B2, drying tank B3, and hydrogen buffer tank B4 is discharged.
  • the water resistivity of the desalted water storage tank B1 is not less than 5 megabytes.
  • the equipment, pipes and valves in contact with gas and liquid media are made of 321SS.
  • the stainless steel pipes are welded by argon arc welding, and the hydrogen and oxygen pipes are degreased.
  • the mixed hydrogen pipeline 5 is composed of 316 in-service natural gas stainless steel pipeline with a nickel content of more than 12%.
  • the composition of O2, N2, CO2, mixed H2 ratio, pipeline compatibility, hydrogen embrittlement sensitivity, hydrogen safety factor, terminal stove adaptability and hydrogen separation economic indicators construct an evaluation index system. First, the original data characteristics of the cases are collected and sorted.
  • the sample content consists of the chemical composition of C, Si, Mn, P, S, Cr, Mo, Ni of stainless steel materials of natural gas pipelines and the target ratio of natural gas CH4, C2H6, C3H8, O2, N2, CO2 and mixed H2
  • the information parameters are composed of pipeline compatibility, hydrogen embrittlement susceptibility, hydrogen safety factor, terminal stove adaptability and hydrogen separation economic index task attribute parameters; based on a typical sample library with limited data, through sample feature extraction and derivation network, a consistent
  • the multi-objective information parameters and task attribute parameters of typical sample library rules expand the sample library; based on the specific target information parameter excitation, after classification and identification by the fuzzy membership attribute least squares support vector machine optimized by FOA parameters, the specific target information parameter excitation is determined.
  • the task attribute parameter category is given according to the task attribute parameter category.
  • the corresponding sample library index number N is given. According to the sample library index number N, the corresponding rule N sample library is matched in the derived extended sample library, and the rule N sample library is retrieved with the specific input target.
  • the information parameter has the smallest Euclidean distance and a suitable matching degree with a nickel content of more than 12% that meets the task attribute parameter requirements. 316 samples of in-service natural gas stainless steel pipelines and hydrogen mixing proportion plans, extract and output the best proportion attribute parameters, and it is completed.
  • An intelligent decision-making process for pipe materials that is suitable for hydrogen mixing ratio and stainless steel pipe material based on fuzzy membership attribute least squares support vector machine.
  • the selected hydrogen mixing pipeline 5 mixes the hydrogen produced by the hydrogen production system 4 with the natural gas in the natural gas storage tank 6 and then outputs it to the outside, providing a new external delivery route.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
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Abstract

Disclosed is a symbiotic agricultural/photovoltaic/gas system based on a drought stress scenario. The system comprises: compound soil, a photovoltaic system, a siphon cleaning drip irrigation system, a hydrogen production system, and a hydrogen mixing pipeline. The compound soil is disposed below the photovoltaic system, the compound soil is configured for planting understory crops, the siphon cleaning drip irrigation system is configured to sprinkle moisture toward the photovoltaic system, the compound soil receives the moisture, the photovoltaic system provides electrical energy to the hydrogen production system, the hydrogen production system is configured to produce hydrogen gas, and the hydrogen mixing pipeline is connected to the hydrogen production system. The symbiotic agricultural/photovoltaic/gas system based on a drought stress scenario provided by the present invention achieves soil improvement of desert land resources, solves the problem of energy delivery, and facilitates the consumption of solar energy converted in desert areas.

Description

一种基于干旱胁迫场景的农光气共生系统An agro-photon symbiosis system based on drought stress scenarios 技术领域Technical field
本发明涉及能源综合应用技术领域,尤其涉及一种基于干旱胁迫场景的农光气共生系统。The invention relates to the technical field of comprehensive energy application, and in particular to an agro-phosgene symbiosis system based on drought stress scenarios.
背景技术Background technique
在能源转型的大背景下,有土地面积优势的大西北荒漠、戈壁滩、沙漠提供了丰富的光能,逐渐成为了风光资源开发的热点。沙漠地带虽然土地面积丰富,但受制于土壤成分、气候等条件,沙漠地区不适于种植作物,这样就使得对风光资源的开发利用形式受限,无法实现资源的综合利用。除此之外,沙漠地区产业有限,对电能等的需求有限,无法消纳通过风光资源转化的电能等。局限于就地消纳能力以及电力外送渠道限制,如何开拓新的外送路由和实现土地的综合利用是当下面临的主要难题。In the context of energy transformation, the northwest desert, Gobi desert, and deserts with land area advantages provide abundant light energy and have gradually become a hot spot for the development of wind and solar resources. Although the desert area is rich in land area, it is not suitable for growing crops due to soil composition, climate and other conditions. This limits the development and utilization of scenery resources and makes it impossible to achieve comprehensive utilization of resources. In addition, desert areas have limited industries and limited demand for electric energy, and cannot absorb the electric energy converted through wind and solar resources. Limited by local consumption capacity and limited power delivery channels, how to develop new delivery routes and achieve comprehensive utilization of land are the main problems currently faced.
因此,本领域的技术人员致力于提供一种基于干旱胁迫场景的农光气共生系统,以沙漠环境的土地资源进行土壤环境改良,使之适宜于植物生长并通过光伏系统的清洗水实现植物滴灌,满足光伏运维要求,并提供植物生长所需要的水分和营养,再结合光伏制氢以及在役天然气管道混氢配比开发,解决能源外送问题。Therefore, those skilled in the art are committed to providing an agro-photon symbiosis system based on drought stress scenarios, using land resources in the desert environment to improve the soil environment, making it suitable for plant growth, and realizing plant drip irrigation through the cleaning water of the photovoltaic system , meet the requirements of photovoltaic operation and maintenance, and provide the water and nutrients needed for plant growth, combined with photovoltaic hydrogen production and the development of hydrogen mixing ratio for in-service natural gas pipelines, to solve the problem of energy transmission.
发明内容Contents of the invention
有鉴于现有技术上的缺陷,本发明所要解决的技术问题是如何提供一种适用于干旱胁迫场景的农光气共生系统。In view of the shortcomings of the existing technology, the technical problem to be solved by the present invention is how to provide an agro-phosgene symbiosis system suitable for drought stress scenarios.
本发明提供的基于干旱胁迫场景的农光气共生系统,包括复配土壤、光伏系统、虹吸清洗滴灌系统、制氢系统、混氢管道,所述复配土壤设在所述光伏系统下方,所述复配土壤被配置为种植林下作物,所述虹吸清洗滴灌系统被配置为向所述光伏系统滴撒水分,所述复配土壤接收所述水分,所述光伏系统向所述制氢系统提供电能,所述制氢系统被配置为制取氢气,所述混氢管道与所述制氢系统连接。The agro-photovoltaic symbiosis system based on drought stress scenarios provided by the present invention includes compound soil, a photovoltaic system, a siphon cleaning drip irrigation system, a hydrogen production system, and a hydrogen mixing pipeline. The compound soil is located below the photovoltaic system, so The compound soil is configured to plant understory crops, the siphon cleaning drip irrigation system is configured to drip water to the photovoltaic system, the compound soil receives the water, and the photovoltaic system supplies water to the hydrogen production system. Electric energy is provided, the hydrogen production system is configured to produce hydrogen gas, and the hydrogen mixing pipeline is connected to the hydrogen production system.
优选地,所述复配土壤由红泥和沙性土以1:9的配比混合而成。Preferably, the compound soil is made of red mud and sandy soil in a ratio of 1:9.
优选地,所述复配土壤为由红泥和沙性土经干、湿循环并加压搅拌形成的土壤团聚体。Preferably, the compound soil is a soil aggregate formed from red mud and sandy soil through dry and wet cycles and pressurized stirring.
进一步地,所述光伏系统由固定水泥灌注桩、高支架、无边框光伏组件、阴极保护接地连接组成。Further, the photovoltaic system consists of fixed cement pouring piles, high brackets, frameless photovoltaic modules, and cathodic protection grounding connections.
进一步地,所述虹吸清洗滴灌系统包括储水池、主进水管、副进水管、出水管,所述主进水管、所述副进水管的一端分别置于所述储水池内,所述主进水管、所述副进水管的另一端分别通过溢水三通与所述出水管连接,所述主进水管上设有第一气动阀、限位开关,所述副进水管上设有浮球,所述出水管上设有第二气动阀。Further, the siphon cleaning drip irrigation system includes a storage tank, a main water inlet pipe, an auxiliary water inlet pipe, and an outlet pipe. One end of the main water inlet pipe and the auxiliary water inlet pipe are respectively placed in the storage tank, and the main water inlet pipe is placed in the storage tank. The water pipe and the other end of the auxiliary water inlet pipe are respectively connected to the water outlet pipe through an overflow tee. The main water inlet pipe is provided with a first pneumatic valve and a limit switch, and the auxiliary water inlet pipe is provided with a float ball. The water outlet pipe is provided with a second pneumatic valve.
进一步地,所述虹吸清洗滴灌系统还包括储水塔,所述储水塔与所述储水池通过传导级联引水导管连接。Further, the siphon cleaning drip irrigation system also includes a water storage tower, and the water storage tower is connected to the water storage tank through a conductive cascade water diversion conduit.
进一步地,所述虹吸清洗滴灌系统中的水分为添加抗硅溶性有机胶结物质复合水。Further, the water in the siphon cleaning drip irrigation system is compound water with silicon-resistant organic cementitious substances added.
进一步地,所述制氢系统包括依次连接的除盐水储罐、电解槽、干燥罐、氢气缓冲罐、压缩机、充补氢装置、储氢瓶组,所述电解槽、干燥罐、压缩机还与冷却装置连接,所述电解槽、干燥罐还与储氮瓶组连接。Further, the hydrogen production system includes a demineralized water storage tank, an electrolyzer, a drying tank, a hydrogen buffer tank, a compressor, a hydrogen replenishing device, and a hydrogen storage bottle group connected in sequence. The electrolytic tank, drying tank, compressor It is also connected to a cooling device, and the electrolytic tank and drying tank are also connected to a nitrogen storage bottle group.
进一步地,所述电解槽、干燥罐、氢气缓冲罐、压缩机、充补氢装置、储氢瓶组连接有阻火器,所述除盐水储罐、电解槽、干燥罐、氢气缓冲罐设有排水管。Further, the electrolytic tank, drying tank, hydrogen buffer tank, compressor, hydrogen replenishing device, and hydrogen storage bottle group are connected with a flame arrester, and the demineralized water storage tank, electrolytic tank, drying tank, and hydrogen buffer tank are equipped with Drain pipe.
进一步地,所述混氢管道为镍含量大于12%的316不锈钢管。Further, the hydrogen mixing pipe is a 316 stainless steel pipe with a nickel content greater than 12%.
本发明至少具有如下有益技术效果:The present invention has at least the following beneficial technical effects:
本发明通过复配土壤、光伏系统、虹吸清洗滴灌系统、制氢系统以及混氢管道的结合,实现了干旱胁迫场景的农光气共生系统,实现了对沙漠土地资源的土壤改良,能够适宜于植物生长,并利用光伏系统的清洗水实现了对植物的灌溉,光伏系统转化的太阳能用于光伏制氢和混氢管道的混氢配比,解决了能源外送问题,实现了沙漠地区太阳能能源转换的消纳。Through the combination of compound soil, photovoltaic system, siphon cleaning drip irrigation system, hydrogen production system and hydrogen mixing pipeline, the present invention realizes an agro-photogas symbiosis system in drought stress scenarios, realizes soil improvement of desert land resources, and can be suitable for Plants grow, and the clean water from the photovoltaic system is used to irrigate the plants. The solar energy converted by the photovoltaic system is used for photovoltaic hydrogen production and the hydrogen mixing ratio of the hydrogen mixing pipeline, which solves the problem of energy transmission and realizes the use of solar energy in desert areas. Conversion absorption.
以下将结合附图对本发明的构思、具体结构及产生的技术效果作进一步说明,以充分地了解本发明的目的、特征和效果。The concept, specific structure and technical effects of the present invention will be further described below in conjunction with the accompanying drawings to fully understand the purpose, features and effects of the present invention.
 
附图说明Description of drawings
图1是本发明实施例提供的农光气共生系统整体示意图;Figure 1 is an overall schematic diagram of the agro-phosgene symbiosis system provided by the embodiment of the present invention;
图2是本发明实施例提供的虹吸清洗滴灌系统流程示意图;Figure 2 is a schematic flow diagram of a siphon cleaning drip irrigation system provided by an embodiment of the present invention;
图3是本发明实施例提供的制氢系统流程示意图。Figure 3 is a schematic flow diagram of a hydrogen production system provided by an embodiment of the present invention.
实施方式Implementation
以下参考说明书附图介绍本发明的多个优选实施例,使其技术内容更加清楚和便于理解。本发明可以通过许多不同形式的实施例来得以体现,本发明的保护范围并非仅限于文中提到的实施例。The following describes multiple preferred embodiments of the present invention with reference to the accompanying drawings to make the technical content clearer and easier to understand. The present invention can be embodied in many different forms of embodiments, and the protection scope of the present invention is not limited to the embodiments mentioned herein.
在附图中,结构相同的部件以相同数字标号表示,各处结构或功能相似的组件以相似数字标号表示。附图所示的每一组件的尺寸和厚度是任意示出的,本发明并没有限定每个组件的尺寸和厚度。为了使图示更清晰,附图中有些地方适当夸大了部件的厚度。In the drawings, components with the same structure are denoted by the same numerals, and components with similar structures or functions are denoted by similar numerals. The size and thickness of each component shown in the drawings are arbitrarily shown, and the present invention does not limit the size and thickness of each component. In order to make the illustrations clearer, the thickness of components is exaggerated in some places in the drawings.
本发明提供了一种基于干旱胁迫场景的农光气共生系统,如图1所示,本发明的农光气共生系统由复配土壤1、光伏系统2、虹吸清洗滴灌系统3、制氢系统4、混氢管道5组成,光伏系统2接收太阳能,用于太阳能发电,虹吸清洗滴灌系统3内储存的水分用于清洗光伏系统2,复配土壤1设在光伏系统2下,用于种植林下作物7,光伏系统2清洗后的水分滴落在复配土壤1里,实现对林下作物7的灌溉,制氢系统4用于制取氢气,光伏系统2转化的电能为制氢系统4提供能量输入,制氢系统4制取的氢气通过混氢管道5输出。本发明提供的基于干旱胁迫场景的农光气共生系统,实现了对沙漠土地资源的土壤改良,能够适宜于植物生长,并利用光伏系统2的清洗水实现了对植物的灌溉,光伏系统2转化的太阳能还用于光伏制氢和混氢管道5的混氢配比,解决了能源外送问题。The present invention provides an agro-phosgene symbiosis system based on a drought stress scenario. As shown in Figure 1, the agro-phosgene symbiosis system of the present invention consists of a compound soil 1, a photovoltaic system 2, a siphon cleaning drip irrigation system 3, and a hydrogen production system. 4. It consists of 5 hydrogen mixing pipelines. The photovoltaic system 2 receives solar energy and is used for solar power generation. The water stored in the siphon cleaning drip irrigation system 3 is used to clean the photovoltaic system 2. The compound soil 1 is located under the photovoltaic system 2 and is used for planting forests. Under the crops 7, the water cleaned by the photovoltaic system 2 drips into the compound soil 1 to realize the irrigation of the understory crops 7. The hydrogen production system 4 is used to produce hydrogen, and the electricity converted by the photovoltaic system 2 is used by the hydrogen production system 4 Energy input is provided, and the hydrogen produced by the hydrogen production system 4 is output through the hydrogen mixing pipeline 5 . The agro-photovoltaic symbiosis system based on the drought stress scenario provided by the present invention realizes the soil improvement of desert land resources, can be suitable for plant growth, and uses the cleaning water of the photovoltaic system 2 to realize the irrigation of the plants, and the photovoltaic system 2 transforms The solar energy is also used for photovoltaic hydrogen production and the hydrogen mixing ratio of the hydrogen mixing pipeline 5, which solves the problem of energy transmission.
本实施例的复配土壤1,由红泥、沙性土以1:9的配比混合而成,通过3次干、湿循环并结合250 r/min的加压搅拌形成土壤团聚体,其中红泥、沙性土配比定量物理指标由容重、分形维数、孔隙度、含水率、保水性以及水稳性大团聚体构成,定量化学指标由有机质含量、电导率、pH值、有效磷、水解性氮以及速效钾构成。复配土壤1上种植的林下作物7以苜蓿、沙葱以及土豆等作物为主。The compound soil 1 of this embodiment is made of red mud and sandy soil mixed in a ratio of 1:9, and is formed into soil aggregates through three dry and wet cycles combined with pressurized stirring at 250 r/min, where The quantitative physical indicators of the ratio of red mud and sandy soil are composed of bulk density, fractal dimension, porosity, moisture content, water retention and water stability macroaggregates, and the quantitative chemical indicators are composed of organic matter content, electrical conductivity, pH value, available phosphorus , hydrolyzable nitrogen and available potassium. The understory crops 7 planted on the compound soil 1 are mainly alfalfa, shallots, potatoes and other crops.
光伏系统2由固定水泥灌注桩、高支架、无边框光伏组件以及含阴极保护接地材质组合而成,固定水泥灌注桩和高支架组成的结构使光伏组件的离地高度不小于1.8m,以利于林下作物7的生长。Photovoltaic system 2 is composed of fixed cement cast piles, high brackets, frameless photovoltaic modules and cathodic protection grounding materials. The structure composed of fixed cement cast piles and high brackets ensures that the height of the photovoltaic modules from the ground is not less than 1.8m to facilitate Growth of understory crops 7.
本实施例中,虹吸清洗滴灌系统3借助虹吸原理实现流体势能内生循环,虹吸清洗滴灌系统3的流程如图2所示。虹吸清洗滴灌系统3预启动时,第二气动阀b1开启,第一气动阀b5关闭,第三气动阀b4开启;虹吸清洗滴灌系统3预工作时,储水池b10储水且从引导口泵入填充水后关闭第三气动阀b4及第二气动阀b1;出水管b2工作,副进水b9在压差作用下联动工作,储水池b10水位下降;限位开关b7动作后,管道填充水失衡直至管道与储水池b10水位齐平。虹吸清洗滴灌系统3启动时,主进水管b6上的第一气动阀b5启动,传导级联引水导管a9、储水塔a11开闸引水至储水池b10,使储水池b10水位达到溢水三通b3口并排空管道空气,虹吸系统正式工作。传导级联引水导管a9、储水塔a11补水完成,限位开关b7动作,管道水逆流直至副进水管b9的浮球b8截流,主进水管b6进水停止工作,出水管b2排水,待储水池b10与主进水管b6水位平衡,副进水管b9的浮球b8上升至储水池b10、主进水管b6以及副进水管b9水位平衡,最终实现水势能内生循环。In this embodiment, the siphon cleaning drip irrigation system 3 uses the siphon principle to realize endogenous circulation of fluid potential energy. The process of the siphon cleaning drip irrigation system 3 is shown in Figure 2. When the siphon cleaning drip irrigation system 3 is pre-started, the second pneumatic valve b1 is opened, the first pneumatic valve b5 is closed, and the third pneumatic valve b4 is opened; when the siphon cleaning drip irrigation system 3 is pre-started, the water storage tank b10 stores water and pumps it in from the guide port After filling with water, close the third pneumatic valve b4 and the second pneumatic valve b1; the water outlet pipe b2 works, the auxiliary water inlet b9 works in conjunction under the pressure difference, and the water level of the storage tank b10 drops; after the limit switch b7 acts, the pipe filling water is unbalanced Until the pipe is flush with the water level of the water tank b10. When the siphon cleaning drip irrigation system 3 is started, the first pneumatic valve b5 on the main water inlet pipe b6 is started, and the cascade water diversion conduit a9 and the water storage tower a11 are opened to divert water to the storage tank b10, so that the water level of the storage tank b10 reaches the overflow tee b3 port And the air in the pipe is evacuated, and the siphon system officially works. The water replenishment of the conduction cascade water diversion pipe a9 and the water storage tower a11 is completed, the limit switch b7 is activated, and the pipeline water flows backward until the float b8 of the auxiliary water inlet pipe b9 intercepts the water. The main water inlet pipe b6 stops working when water inflows, and the outlet pipe b2 is drained, waiting for the storage tank. The water level of b10 is balanced with the main water inlet pipe b6, and the float b8 of the auxiliary water inlet pipe b9 rises to the water level balance of the storage tank b10, the main water inlet pipe b6 and the auxiliary water inlet pipe b9, and finally realizes the endogenous circulation of water potential energy.
虹吸清洗滴灌系统3的水分为添加抗硅溶性有机胶结物质复合水,其与复配土壤1团聚体微生物活性及其代谢周期相配合,清洗周期由第一气动阀b5、第三气动阀b4协同配合林下作物7生长周期完成。The water in the siphon cleaning drip irrigation system 3 is compound water with silicon-soluble organic cementitious substances added, which cooperates with the microbial activity and metabolic cycle of the compound soil 1 aggregates. The cleaning cycle is coordinated by the first pneumatic valve b5 and the third pneumatic valve b4. It is completed in conjunction with the 7 growth cycles of understory crops.
如图3所示,制氢系统4由主料管A1、辅料管A2、除盐水储罐B1、冷却装置A3、储氮瓶组A4、电解槽B2、干燥罐B3、氢气缓冲罐B4、压缩机B5、充补氢装置B6、储氢瓶组B7以及阻火器B8构成,除盐水经主料管A1送入除盐水储罐B1以及冷却装置A3,除盐水储罐B1的除盐水进入电解槽B2电解制氢和干燥罐B3干燥,其中电解槽B2和干燥罐B3中氢、氧经氮气吹扫和置换,将氧与氢分离,氧气在电解槽B2经排空管C1释放,粗制氢气则进入干燥罐B3处理,再经压缩机B5、充补氢装置B6、储氢B7或用氢等工艺流程,其中电解槽B2、干燥罐B3、氢气缓冲罐B4、压缩机B5、充补氢装置B6、储氢瓶组B7都配置阻火器B8,冷却装置A3的除盐水经冷冻供水管D1、回水管D2对电解槽B2、干燥罐B3、压缩机B5进行冷却并通过辅料管A2将除盐水储罐B1、电解槽B2、干燥罐B3、氢气缓冲罐B4废水排出。除盐水储罐B1水质电阻率不小于5兆,与气液介质接触设备、管道以及阀门材质为321SS,不锈钢管为氩弧焊焊接,氢、氧管道脱脂处理。As shown in Figure 3, hydrogen production system 4 consists of main material pipe A1, auxiliary material pipe A2, demineralized water storage tank B1, cooling device A3, nitrogen storage bottle group A4, electrolyzer B2, drying tank B3, hydrogen buffer tank B4, compression It consists of machine B5, hydrogen replenishing device B6, hydrogen storage bottle group B7 and flame arrester B8. The desalted water is sent to the desalted water storage tank B1 and the cooling device A3 through the main material pipe A1. The desalted water from the desalted water storage tank B1 enters the electrolyzer. B2 produces hydrogen by electrolysis and drying tank B3 is dried. The hydrogen and oxygen in electrolytic tank B2 and drying tank B3 are purged and replaced by nitrogen to separate oxygen and hydrogen. Oxygen is released in electrolytic tank B2 through drain pipe C1, and crude hydrogen is produced. Then it enters the drying tank B3 for processing, and then goes through the compressor B5, the hydrogen supplementing device B6, the hydrogen storage B7 or the hydrogen use process, including the electrolytic tank B2, the drying tank B3, the hydrogen buffer tank B4, the compressor B5, the hydrogen supplementing Device B6 and hydrogen storage bottle group B7 are equipped with flame arrester B8. The desalted water from cooling device A3 cools the electrolyzer B2, drying tank B3 and compressor B5 through the refrigerated water supply pipe D1 and return pipe D2, and removes the demineralized water through the auxiliary material pipe A2. Waste water from brine storage tank B1, electrolyzer B2, drying tank B3, and hydrogen buffer tank B4 is discharged. The water resistivity of the desalted water storage tank B1 is not less than 5 megabytes. The equipment, pipes and valves in contact with gas and liquid media are made of 321SS. The stainless steel pipes are welded by argon arc welding, and the hydrogen and oxygen pipes are degreased.
混氢管道5由镍含量12%以上的316在役天然气不锈钢管道组成,其不锈钢材质中C、Si、Mn、P 、S、Cr、Mo、Ni的化学成分、天然气中CH4、C2H6、C3H8、O2、N2、CO2的成分、混H2配比以管道相容性、氢脆敏感性、氢安全系数、终端灶具适应性以及氢分离经济性指标构造评价指标体系,首先通过收集整理案例原始数据特性信息样本,其样本内容由在役天然气管道不锈钢材质C、Si、Mn、P 、S、Cr、Mo、Ni化学成分与天然气CH4、C2H6、C3H8、O2、N2、CO2以及混H2配比的目标信息参数与管道相容性、氢脆敏感性、氢安全系数、终端灶具适应性以及氢分离经济性指标任务属性参数组成;基于有限数据的典型样本库,通过样本特征提取与派生网络,生成符合典型样本库规则的多目标信息参数与任务属性参数扩展样本库;基于特定目标信息参数激励,经FOA参数优化模糊隶属度属性最小二乘支持向量机进行分类识别后,确定特定目标信息参数激励所属的任务属性参数类别,根据该任务属性参数类别给出呼应样本库索引号N,根据样本库索引号N在派生扩展样本库中匹配对应规则N样本库,在规则N样本库检索与特定输入目标信息参数欧氏距离最小且匹配度合适的符合任务属性参数要求的镍含量12%以上316在役天然气不锈钢管道与混氢配比方案样本,萃取并输出其中最佳配比属性参数,即完成了一次基于模糊隶属度属性最小二乘支持向量机的符合混氢配比与不锈钢管道材质适宜的管材智能决策过程。筛选出的混氢管道5将制氢系统4制取的氢气与天然气储罐6内的天然气混合后向外输出,提供了新的外送路由。The mixed hydrogen pipeline 5 is composed of 316 in-service natural gas stainless steel pipeline with a nickel content of more than 12%. The chemical composition of C, Si, Mn, P, S, Cr, Mo, Ni in the stainless steel material, CH4, C2H6, C3H8, The composition of O2, N2, CO2, mixed H2 ratio, pipeline compatibility, hydrogen embrittlement sensitivity, hydrogen safety factor, terminal stove adaptability and hydrogen separation economic indicators construct an evaluation index system. First, the original data characteristics of the cases are collected and sorted. Information sample, the sample content consists of the chemical composition of C, Si, Mn, P, S, Cr, Mo, Ni of stainless steel materials of natural gas pipelines and the target ratio of natural gas CH4, C2H6, C3H8, O2, N2, CO2 and mixed H2 The information parameters are composed of pipeline compatibility, hydrogen embrittlement susceptibility, hydrogen safety factor, terminal stove adaptability and hydrogen separation economic index task attribute parameters; based on a typical sample library with limited data, through sample feature extraction and derivation network, a consistent The multi-objective information parameters and task attribute parameters of typical sample library rules expand the sample library; based on the specific target information parameter excitation, after classification and identification by the fuzzy membership attribute least squares support vector machine optimized by FOA parameters, the specific target information parameter excitation is determined. The task attribute parameter category is given according to the task attribute parameter category. The corresponding sample library index number N is given. According to the sample library index number N, the corresponding rule N sample library is matched in the derived extended sample library, and the rule N sample library is retrieved with the specific input target. The information parameter has the smallest Euclidean distance and a suitable matching degree with a nickel content of more than 12% that meets the task attribute parameter requirements. 316 samples of in-service natural gas stainless steel pipelines and hydrogen mixing proportion plans, extract and output the best proportion attribute parameters, and it is completed. An intelligent decision-making process for pipe materials that is suitable for hydrogen mixing ratio and stainless steel pipe material based on fuzzy membership attribute least squares support vector machine. The selected hydrogen mixing pipeline 5 mixes the hydrogen produced by the hydrogen production system 4 with the natural gas in the natural gas storage tank 6 and then outputs it to the outside, providing a new external delivery route.
以上详细描述了本发明的较佳具体实施例。应当理解,本领域的普通技术无需创造性劳动就可以根据本发明的构思作出诸多修改和变化。因此,凡本技术领域中技术人员依本发明的构思在现有技术的基础上通过逻辑分析、推理或者有限的实验可以得到的技术方案,皆应在由权利要求书所确定的保护范围内。The preferred embodiments of the present invention are described in detail above. It should be understood that those skilled in the art can make many modifications and changes according to the concept of the present invention without creative efforts. Therefore, any technical solutions that can be obtained by those skilled in the art through logical analysis, reasoning or limited experiments based on the concept of the present invention and on the basis of the prior art should be within the scope of protection determined by the claims.

Claims (10)

  1. 一种基于干旱胁迫场景的农光气共生系统,其特征在于,包括复配土壤、光伏系统、虹吸清洗滴灌系统、制氢系统、混氢管道,所述复配土壤设在所述光伏系统下方,所述复配土壤被配置为种植林下作物,所述虹吸清洗滴灌系统被配置为向所述光伏系统滴撒水分,所述复配土壤接收所述水分,所述光伏系统向所述制氢系统提供电能,所述制氢系统被配置为制取氢气,所述混氢管道与所述制氢系统连接。An agro-photovoltaic symbiosis system based on drought stress scenarios, characterized by including compound soil, a photovoltaic system, a siphon cleaning drip irrigation system, a hydrogen production system, and a hydrogen mixing pipeline, and the compound soil is located below the photovoltaic system , the compound soil is configured to plant understory crops, the siphon cleaning drip irrigation system is configured to drip water to the photovoltaic system, the compound soil receives the water, and the photovoltaic system supplies water to the system. The hydrogen system provides electrical energy, the hydrogen production system is configured to produce hydrogen gas, and the hydrogen mixing pipeline is connected to the hydrogen production system.
  2. 根据权利要求1所述的基于干旱胁迫场景的农光气共生系统,其特征在于,所述复配土壤由红泥和沙性土以1:9的配比混合而成。The agro-photon symbiosis system based on drought stress scenarios according to claim 1, wherein the compound soil is made of red mud and sandy soil mixed in a ratio of 1:9.
  3. 根据权利要求2所述的基于干旱胁迫场景的农光气共生系统,其特征在于,所述复配土壤为由红泥和沙性土经干、湿循环并加压搅拌形成的土壤团聚体。The agro-photon symbiosis system based on a drought stress scenario according to claim 2, characterized in that the compound soil is a soil aggregate formed by red mud and sandy soil through dry and wet cycles and pressurized stirring.
  4. 如权利要求1所述的基于干旱胁迫场景的农光气共生系统,其特征在于,所述光伏系统由固定水泥灌注桩、高支架、无边框光伏组件、阴极保护接地连接组成。The agro-photovoltaic symbiosis system based on drought stress scenarios according to claim 1, characterized in that the photovoltaic system consists of fixed cement cast-in-place piles, high brackets, frameless photovoltaic modules, and cathodic protection grounding connections.
  5. 如权利要求1所述的基于干旱胁迫场景的农光气共生系统,其特征在于,所述虹吸清洗滴灌系统包括储水池、主进水管、副进水管、出水管,所述主进水管、所述副进水管的一端分别置于所述储水池内,所述主进水管、所述副进水管的另一端分别通过溢水三通与所述出水管连接,所述主进水管上设有第一气动阀、限位开关,所述副进水管上设有浮球,所述出水管上设有第二气动阀。The agro-photon symbiosis system based on a drought stress scenario according to claim 1, wherein the siphon cleaning drip irrigation system includes a storage tank, a main water inlet pipe, an auxiliary water inlet pipe, and a water outlet pipe, and the main water inlet pipe, the One end of the auxiliary water inlet pipe is placed in the storage tank, and the other ends of the main water inlet pipe and the auxiliary water inlet pipe are respectively connected to the water outlet pipe through an overflow tee. There is a third water inlet pipe on the main water inlet pipe. A pneumatic valve and a limit switch, the auxiliary water inlet pipe is provided with a float ball, and the water outlet pipe is provided with a second pneumatic valve.
  6. 如权利要求5所述的基于干旱胁迫场景的农光气共生系统,其特征在于,所述虹吸清洗滴灌系统还包括储水塔,所述储水塔与所述储水池通过传导级联引水导管连接。The agro-photon symbiosis system based on a drought stress scenario according to claim 5, wherein the siphon cleaning drip irrigation system further includes a water storage tower, and the water storage tower is connected to the water storage tank through a conductive cascade water diversion conduit.
  7. 如权利要求5所述的基于干旱胁迫场景的农光气共生系统,其特征在于,所述虹吸清洗滴灌系统中的水分为添加抗硅溶性有机胶结物质复合水。The agro-photon symbiosis system based on a drought stress scenario according to claim 5, wherein the water in the siphon cleaning drip irrigation system is compound water with silicon-soluble organic cementitious substances added.
  8. 如权利要求1所述的基于干旱胁迫场景的农光气共生系统,其特征在于,所述制氢系统包括依次连接的除盐水储罐、电解槽、干燥罐、氢气缓冲罐、压缩机、充补氢装置、储氢瓶组,所述电解槽、干燥罐、压缩机还与冷却装置连接,所述电解槽、干燥罐还与储氮瓶组连接。The agro-phosgene symbiosis system based on drought stress scenario according to claim 1, characterized in that the hydrogen production system includes a demineralized water storage tank, an electrolytic tank, a drying tank, a hydrogen buffer tank, a compressor, a charging tank, and a demineralized water storage tank, which are connected in sequence. Hydrogen replenishing device and hydrogen storage bottle group, the electrolytic tank, drying tank, and compressor are also connected to the cooling device, and the electrolytic tank and drying tank are also connected to the nitrogen storage bottle group.
  9. 如权利要求8所述的基于干旱胁迫场景的农光气共生系统,其特征在于,所述电解槽、干燥罐、氢气缓冲罐、压缩机、充补氢装置、储氢瓶组连接有阻火器,所述除盐水储罐、电解槽、干燥罐、氢气缓冲罐设有排水管。The agro-phosgene symbiosis system based on drought stress scenario according to claim 8, characterized in that the electrolyzer, drying tank, hydrogen buffer tank, compressor, hydrogen replenishing device, and hydrogen storage bottle group are connected with a flame arrester , the desalted water storage tank, electrolyzer, drying tank, and hydrogen buffer tank are equipped with drainage pipes.
  10. 如权利要求1所述的基于干旱胁迫场景的农光气共生系统,其特征在于,所述混氢管道为镍含量大于12%的316不锈钢管。The agro-phosgene symbiosis system based on a drought stress scenario as claimed in claim 1, wherein the hydrogen mixing pipe is a 316 stainless steel pipe with a nickel content greater than 12%.
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