WO2023272873A1 - 塑料模具钢板及其生产方法 - Google Patents
塑料模具钢板及其生产方法 Download PDFInfo
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- WO2023272873A1 WO2023272873A1 PCT/CN2021/110563 CN2021110563W WO2023272873A1 WO 2023272873 A1 WO2023272873 A1 WO 2023272873A1 CN 2021110563 W CN2021110563 W CN 2021110563W WO 2023272873 A1 WO2023272873 A1 WO 2023272873A1
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 47
- 229910001214 P-type tool steel Inorganic materials 0.000 title claims abstract description 35
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 297
- 239000010959 steel Substances 0.000 claims abstract description 297
- 238000001816 cooling Methods 0.000 claims abstract description 126
- 238000005096 rolling process Methods 0.000 claims abstract description 99
- 238000010438 heat treatment Methods 0.000 claims abstract description 83
- 229910001562 pearlite Inorganic materials 0.000 claims abstract description 32
- 238000002791 soaking Methods 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims description 82
- 230000008569 process Effects 0.000 claims description 78
- 239000010410 layer Substances 0.000 claims description 34
- 239000000126 substance Substances 0.000 claims description 19
- 229910052804 chromium Inorganic materials 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 18
- 238000005496 tempering Methods 0.000 claims description 14
- 229910052759 nickel Inorganic materials 0.000 claims description 13
- 229910052748 manganese Inorganic materials 0.000 claims description 12
- 229910052750 molybdenum Inorganic materials 0.000 claims description 12
- 229910052710 silicon Inorganic materials 0.000 claims description 11
- 239000002344 surface layer Substances 0.000 claims description 10
- 239000012535 impurity Substances 0.000 claims description 8
- 238000007664 blowing Methods 0.000 claims description 5
- 238000003303 reheating Methods 0.000 claims description 3
- 230000009466 transformation Effects 0.000 description 22
- 229910001563 bainite Inorganic materials 0.000 description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 230000009286 beneficial effect Effects 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 238000005204 segregation Methods 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 229910001566 austenite Inorganic materials 0.000 description 4
- 238000009749 continuous casting Methods 0.000 description 4
- 238000005265 energy consumption Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 230000007704 transition Effects 0.000 description 4
- 229910052720 vanadium Inorganic materials 0.000 description 4
- 229910000859 α-Fe Inorganic materials 0.000 description 4
- 230000007547 defect Effects 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000004512 die casting Methods 0.000 description 3
- 238000005242 forging Methods 0.000 description 3
- 238000005457 optimization Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000010791 quenching Methods 0.000 description 3
- 230000000171 quenching effect Effects 0.000 description 3
- 238000009529 body temperature measurement Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229910052758 niobium Inorganic materials 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 229910001182 Mo alloy Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910052840 fayalite Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000009916 joint effect Effects 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 238000011112 process operation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000033764 rhythmic process Effects 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
- C21D1/19—Hardening; Quenching with or without subsequent tempering by interrupted quenching
- C21D1/20—Isothermal quenching, e.g. bainitic hardening
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/26—Methods of annealing
- C21D1/28—Normalising
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/68—Temporary coatings or embedding materials applied before or during heat treatment
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/005—Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/021—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving a particular fabrication or treatment of ingot or slab
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0273—Final recrystallisation annealing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/009—Pearlite
Definitions
- the Rockwell hardness difference between the surface layer and the core of the obtained steel plate is ⁇ 1.6HRC.
- the cross-stacking is: both the bottom layer and the top layer are ferritic pearlitic steel plates, and the steel plates and ferritic pearlitic steel plates are stacked layer by layer at intervals.
- one embodiment of the present invention provides a plastic mold steel plate, the production method of which includes the following steps,
- Fig. 3 is the microstructure diagram of the cross section of the steel plate in Example 3 of the present invention; wherein, Fig. 3a is at the 1/4 position of the cross section of the steel plate, and Fig. 3b is at the 1/2 position of the cross section of the steel plate;
- P, S impurity elements.
- the mass percentage of P is controlled below 0.014%, preferably 0.008-0.014%; the mass percentage of S is controlled below 0.004%, preferably 0.002-0.004%.
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- Chemical & Material Sciences (AREA)
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- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
Abstract
Description
Claims (15)
- 一种塑料模具钢板的生产方法,其特征在于,包括以下工序,第一次加热:将钢坯送入加热炉中进行三段式加热,预热段温度为850~950℃,预热段停留时间≥60min,加热段温度为1100~1220℃,均热段温度为1210~1250℃,在炉时间≥240min;第二次加热:将所述第一次加热工序中出炉后的钢坯重新加热,均热段温度为1140~1170℃,在炉时间≥200min;轧制:将所述第二次加热工序中出炉后的钢坯轧制成钢板,开轧温度为1060~1140℃,终轧温度为980~1050℃;轧后冷却:将终轧所得钢板移至冷床上空冷至200℃以下;正火:将所述轧后冷却工序中冷却完成的钢板进行正火处理,正火温度T N为Ac 3+60℃≤T N≤Ac 3+90℃;正火后冷却:将所述正火工序所出的钢板移至冷床上空冷至T F,B f-50℃≤T F≤B f-20℃;交叉堆垛自回火:将钢板与温度为450~550℃的铁素体珠光体钢板进行交叉堆垛,堆垛期间钢板自回火,直至钢板的温度重新降低至T M,B f-50℃≤T M≤B f-20℃;之后拆垛并自然空冷至室温;其中,所述交叉堆垛为:底层和顶层均为铁素体珠光体钢板,且钢板和铁素体珠光体钢板逐层间隔层叠。
- 根据权利要求1所述的塑料模具钢板的生产方法,其特征在于,所述钢板的长度L 2、宽度W 2、厚度H 2与所述铁素体珠光体钢板的长度L 1、宽度W 1、厚度H 1满足:L 1≥L 2+500mm,W 1≥W 2+300mm,H 1≥H 2。
- 根据权利要求1所述的塑料模具钢板的生产方法,其特征在于,所述第二次加热工序中,钢坯进行三段式加热,入炉温度≥700℃,预热段温度为950~1000℃,加热段温度为1100~1150℃。
- 根据权利要求1所述的塑料模具钢板的生产方法,其特征在于,所述轧制工序中,将钢坯轧制成厚度≥80mm的钢板。
- 根据权利要求1所述的塑料模具钢板的生产方法,其特征在于,所述轧后冷却工序和所述正火后冷却工序中的任一者或二者包括:首先,将钢板移至冷床上自然空冷,直至钢板的上表面温度降低至T A, B s+15℃≤T A≤B s+35℃;而后,开启风扇并通过风扇扰动钢板下方的空气,以控制钢板的上表面温度和下表面温度的差值≤5℃,直至钢板的上表面温度降低至T F;其中,风扇的吹风方向平行于钢板的下表面或者斜向下远离钢板的下表面。
- 根据权利要求5所述的塑料模具钢板的生产方法,其特征在于,所得钢板的不平度≤4mm/2m。
- 根据权利要求1所述的塑料模具钢板的生产方法,其特征在于,所述轧后冷却中,终冷温度为100~200℃;所述正火工序的入炉温度≥100℃。
- 根据权利要求1所述的塑料模具钢板的生产方法,其特征在于,所用钢坯的化学成分以质量百分比计为:C 0.33~0.38%、Si 0.11~0.19%、Mn 0.70~0.90%、P≤0.014%、S≤0.004%、Cr 1.40~1.80%、Ni 0.70~0.90%、Mo 0.16~0.24%,且Cr/Mn比值为2±0.05,Cr/(Mn+Ni)比值为1±0.05,Mn+Cr+Ni+Mo 3.0%~3.8%,其余为Fe和不可避免的杂质。
- 根据权利要求1所述的塑料模具钢板的生产方法,其特征在于,所得钢板的屈服强度≥700MPa,抗拉强度≥1050MPa,V型夏比冲击功≥15J,洛氏硬度为31~34HRC且表层和心部的洛氏硬度差值≤1.6HRC。
- 一种塑料模具钢板的生产方法,其特征在于,包括以下工序,加热:将钢坯送入加热炉中进行三段式加热,预热段温度为850~950℃,预热段停留时间≥60min,加热段温度为1100~1220℃,均热段温度为1210~1250℃,在炉时间≥240min;轧制:将所述加热工序中出炉后的钢坯轧制成钢板,开轧温度为1060~1140℃,终轧温度为980~1050℃;轧后冷却:将终轧所得钢板移至冷床上空冷至200℃以下;正火:将所述轧后冷却工序中冷却完成的钢板进行正火处理,正火温度T N为Ac 3+60℃≤T N≤Ac 3+90℃;正火后冷却:将所述正火工序所出的钢板移至冷床上空冷至T F,B f-50℃≤T F≤B f-20℃;交叉堆垛自回火:将钢板与温度为450~550℃的铁素体珠光体钢板进行交叉堆垛,堆垛期间钢板自回火,直至钢板的温度重新降低至T M,B f-50℃≤T M≤B f-20℃;之后拆垛并自然空冷至室温;其中,所述交叉堆垛为:底层和顶层均为铁素体珠光体钢板,且钢板和铁素体珠光体钢板逐层间隔层叠。
- 根据权利要求10所述的塑料模具钢板的生产方法,其特征在于,所述钢板的长度L 2、宽度W 2、厚度H 2与所述铁素体珠光体钢板的长度L 1、宽度W 1、厚度H 1满足:L 1≥L 2+500mm,W 1≥W 2+300mm,H 1≥H 2。
- 根据权利要求10所述的塑料模具钢板的生产方法,其特征在于,所述轧后冷却工序和所述正火后冷却工序中的任一者或二者包括:首先,将钢板移至冷床上自然空冷,直至钢板的上表面温度降低至T A,B s+15℃≤T A≤B s+35℃;而后,开启风扇并通过风扇扰动钢板下方的空气,以控制钢板的上表面温度和下表面温度的差值≤5℃,直至钢板的上表面温度降低至T F;其中,风扇的吹风方向平行于钢板的下表面或者斜向下远离钢板的下表面。
- 根据权利要求10所述的塑料模具钢板的生产方法,其特征在于,所用钢坯的化学成分以质量百分比计为:C 0.33~0.38%、Si 0.11~0.19%、Mn 0.70~0.90%、P≤0.014%、S≤0.004%、Cr 1.40~1.80%、Ni 0.70~0.90%、Mo 0.16~0.24%,且Cr/Mn比值为2±0.05,Cr/(Mn+Ni)比值为1±0.05,Mn+Cr+Ni+Mo 3.0%~3.8%,其余为Fe和不可避免的杂质。
- 根据权利要求10所述的塑料模具钢板的生产方法,其特征在于,所得钢板的屈服强度≥700MPa,抗拉强度≥1050MPa,V型夏比冲击功≥15J,洛氏硬度为31~34HRC,表层和心部的洛氏硬度差值≤1.6HRC。
- 一种塑料模具钢板,其特征在于,采用权利要求1所述的生产方法制备而成。
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JP2023579865A JP2024523939A (ja) | 2021-06-30 | 2021-08-04 | プラスチック金型鋼板及びその製造方法 |
EP21947815.3A EP4365317A4 (en) | 2021-06-30 | 2021-08-04 | STEEL PLATE FOR PLASTIC MOLD AND PRODUCTION METHOD THEREFOR |
KR1020237044341A KR20240017853A (ko) | 2021-06-30 | 2021-08-04 | 플라스틱 금형 강판 및 그 생산 방법 |
US18/575,724 US20240336988A1 (en) | 2021-06-30 | 2021-08-04 | Plastic mold steel plate and method for producing same |
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Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH0215117A (ja) * | 1988-07-01 | 1990-01-18 | Kobe Steel Ltd | プラスチック成形用プレハードン金型鋼の製造方法 |
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