WO2023232087A1 - Clean product set prepared by using energy grass as raw material, and preparation method therefor - Google Patents

Clean product set prepared by using energy grass as raw material, and preparation method therefor Download PDF

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WO2023232087A1
WO2023232087A1 PCT/CN2023/097506 CN2023097506W WO2023232087A1 WO 2023232087 A1 WO2023232087 A1 WO 2023232087A1 CN 2023097506 W CN2023097506 W CN 2023097506W WO 2023232087 A1 WO2023232087 A1 WO 2023232087A1
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Prior art keywords
product
water
energy grass
grass
weight
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PCT/CN2023/097506
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French (fr)
Chinese (zh)
Inventor
唐禹豪
陈汇宏
胡嘉庆
唐宏玮
沙良宝
Original Assignee
唐禹豪
陈汇宏
胡嘉庆
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Priority claimed from CN202210727265.6A external-priority patent/CN115431432A/en
Application filed by 唐禹豪, 陈汇宏, 胡嘉庆 filed Critical 唐禹豪
Publication of WO2023232087A1 publication Critical patent/WO2023232087A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00Making granules
    • B29B9/02Making granules by dividing preformed material
    • B29B9/06Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02Separating plastics from other materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/04Disintegrating plastics, e.g. by milling
    • B29B17/0412Disintegrating plastics, e.g. by milling to large particles, e.g. beads, granules, flakes, slices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00Making granules
    • B29B9/12Making granules characterised by structure or composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/02Cellulose; Modified cellulose
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/06Polystyrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02Separating plastics from other materials
    • B29B2017/0213Specific separating techniques
    • B29B2017/0217Mechanical separating techniques; devices therefor
    • B29B2017/0237Mechanical separating techniques; devices therefor using density difference
    • B29B2017/0241Mechanical separating techniques; devices therefor using density difference in gas, e.g. air flow
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2511/00Use of natural products or their composites, not provided for in groups B29K2401/00 - B29K2509/00, as filler
    • B29K2511/14Wood, e.g. woodboard or fibreboard

Definitions

  • the present invention provides a collection of cleaning products and a manufacturing method using energy grass as raw materials, which involves classifying some grain, cotton, oil and other crops that produce huge amounts of straw or branches into the high-level name of energy grass, and then They all use energy grass as the upper name, and introduce the process of integrating clean production in series and parallel through processing sub-paths and combined equipment or device array using it as the main raw material, and finally produce a collection of clean products, which belong to straw and giant fungus grass.
  • Energy grass is not the name of a plant grass.
  • Tall perennial herbs or semi-shrubs including sweet sorghum, switchgrass, Miscanthus crops and other tall herbs can be labeled as energy grasses; energy grasses are mostly resistant to drought, salt and alkali, barrenness and adaptability.
  • Grass seeds are simple to plant and manage, and can be planted in arid and semi-arid areas, low-lying areas prone to waterlogging and saline-alkali areas, mountainous areas with poor soil, and semi-mountainous areas; energy grass does not have high requirements for soil quality and climate, and is cold-resistant, frost-resistant, and adaptable. It is strong, fast growing and has high yield.
  • the maximum annual hay output per mu of farmland can reach more than three tons. After one sowing, the grass production period can be as long as 10 to 15 years.
  • the inventor believes that the deep processing and comprehensive utilization of energy grass can at least provide some product collections and clean production methods that are more beneficial to large-scale, raw material and convenient downstream motorization applications. This is the energy grass. Comprehensive utilization required in this field.
  • the purpose of the present invention is to provide a collection and preparation method of cleaning products using energy grass as raw materials in view of the current situation that the existing application technology for energy grass may be few or insufficient.
  • the main product A in the "product set" is hydrophilic and decomposable fiber, whose physical properties can at least replace or partially replace traditional recycled pulp, which is used as a raw material for papermaking or further processing to make bleached pulp, etc.; by-products, One is the wood-plastic composite recycled coarse particle product B, or/and the other is the lignin/resin mixture product C; moreover, it can also include a group of auxiliary products D, E, F, G, H, and I.
  • the main product is surrounded by by-products or/and auxiliary products, and all the by-products produced in the preparation of the main product are squeezed out.
  • the idea of the present invention is to provide a set of products and a clean manufacturing method that are convenient for large-scale, raw material and downstream motorized applications.
  • the above-mentioned "clean production method” not only needs to clean up the snow in front of the house, but also greenly utilize all resources such as waste liquid produced during the comprehensive utilization of energy grass; it must also take away the frost on other people's tiles, which is not only for Wastes such as cow dung around the implementation site or discarded agricultural mulch films in the fields are also absorbed and used for green utilization of resources.
  • the invention also borrows the high-level name of energy grass to convert some grain, cotton, oil, etc.
  • a collection of clean products using energy grass as raw material which is characterized by: using energy grass, or energy grass and cow dung as the starting main raw materials, the series and parallel integration of clean production processes and combined equipment or device arrays through processing sub-paths , and finally a cleaning product set is obtained.
  • the "product set” is specifically composed of the main product A as described below, or a combination of the main product A and any one or two of the by-products B and C; or the main product A or by-product B/C, and a combination of any one or more of auxiliary products D, E, F, G, H, and I:
  • the main product A - hydrophilic decomposable fiber characterized by: using the aforementioned "energy grass, or energy grass and cow dung", crushed by any one or more combinations of sawing/milling/cutting/hammering and then sieving to obtain the "Elongated fiber bundles of any mesh size that pass through a sieve ranging from 3 mesh to no more than 28 mesh" are used as raw materials; the brown/black liquor will be discharged during the preparation process, and the "brown/black liquor” will be discharged.
  • the "whisker additive" added to 100 parts by weight of the absolutely dry fiber in the main product A is ⁇ 1 to 3 ⁇ 5 ⁇ 9 parts by weight, either ⁇ 1 part by weight or ⁇ 3 parts by weight or ⁇ 5 parts by weight or ⁇ 9 parts by weight; the main product A - a hydrophilic and decomposable fiber product, cannot be dissolved after being put into water or stirred again. floating surface;
  • the main product A can be subdivided into the main product A-1--a hydrophilic decomposable fiber controlled to have a low hydrophilicity of beating degree ⁇ 16°SR, and the main product A-2--controlled to be Hydrophilic and decomposable fiber with high hydrophilic beating degree ⁇ 16°SR;
  • By-product B - wood-plastic composite regenerated coarse particles; characterized by: at least the above-mentioned "energy grass” is crushed by any one or more combinations of sawing/milling/cutting/hammering, and then screened.
  • the other part “Fine materials or/and crushed materials that pass through a 28-mesh sieve, or crushed materials that are mixed with coarse and fine materials that pass through a 3-mesh sieve", and then use them as raw materials together with "waste plastics", or mix them with those in A
  • the "brown/black liquor” has a mass transfer connection and is pelletized using a biomass fuel pellet machine;
  • By-product C - lignin/resin mixture characterized by: It is produced using the "brown/black liquor" mentioned in A as raw material. It is a hydrophilic liquid in the color of black brown at room temperature, or in the form of a paste-like brown or Nearly black colloid, or in the form of coffee or nearly black powder or granules, or in the form of rosin-like solid; the by-product C, which can be subdivided into by-product C-1-edible or medical grade lignin/resin mixture, By-product C-2--feed or industrial grade lignin/resin mixture;
  • Auxiliary product D - solid organic soil conditioner characterized by: the remaining material after extracting "energy grass, or energy grass and cow dung" that does not pass the 28-mesh sieve to make the main product A. Energy grass powder or fine cow dung sediment, As one of the ingredients in solid organic soil amendment;
  • Auxiliary product E - liquid organic soil conditioner characterized by: utilizing the brown/black liquor discharged during the preparation of the hydrophilic decomposable fiber main product A, or/and utilizing the discharged liquid due to the upgrading of the main product A and by-product C Pressed liquid or/and washing liquid or/and elutriated liquid, products blended according to the soil requirements of the crops and fields to be applied; the "discharged pressed liquid or/and washing liquid or/and elutriated liquid” Or “brown/black liquor”, with a pH value in the range of 5.0 to 9.4, and the ratio of the gram moles of Na + or/and K + or/and Mg 2+ contained in it to the liter volume of the water contained therein is ⁇ 0.034 mol /L, or the total wt% concentration of the soluble sodium salt, potassium salt, and magnesium salt contained therein is ⁇ 0.20% (wt%), or the total concentration of the soluble sodium salt, potassium salt, and magnesium salt contained therein is consistent
  • Auxiliary product F - fermented feed characterized by: the product is mixed with the "brown/black liquor" discharged during the preparation process of main product A;
  • Auxiliary product G - pellet feed characterized by: the energy grass dry material is only crushed and sieved to obtain a fine powder that passes through a 28 mesh sieve, or/and a particle size with a small soil content that passes through a 28 to less than 150 mesh sieve.
  • the energy grass fiber powder in the center is used as one of the ingredients of pellet feed;
  • Auxiliary product H - biomass pellet fuel characterized by: the fine powder obtained by crushing and sieving the energy grass to remove the crude fiber that has not passed the 28 mesh sieve, or the full-component crushed energy grass as ingredients. components, or waste plastics are added; the "waste plastics” include at least any one or combination of waste agricultural plastic films, waste foam plastics, waste chemical fiber fabrics or/and chemical fiber cotton batting, and the "waste plastics" “Additional” accounts for less than 5% of the total weight of auxiliary product H, or does not exceed 22%;
  • Auxiliary product I - Edible fungus planting stick/block characterized by: the remaining material after extracting the main product A from "energy grass, or energy grass and cow dung" with a mesh size of no more than 28 mesh, and passing through a 28 mesh sieve.
  • the energy grass powder or fine cow dung sediment of the hole is used as one of the ingredients in the edible fungus planting sticks/blocks.
  • Raw materials used including Echinacea, Liba, lemongrass, Arundodis, reeds, reeds, zebra grass, elephant grass, king grass, king bamboo grass, giant fungus grass, five-jointed miscanthus, rice grass, purple elephant grass , dwarf elephant grass, red elephant grass, sweet elephant grass, grass shoots, grass sugarcane, pseudosorghum, sweet sorghum, Peter grass, Sudan grass, Taiwan sweet grass, Pennisetum alterniflora, Spartina alterniflora hybrid, American wolftail Energy grasses of any one or more combinations of grasses and hybrid pennisetum, grain, cotton, and oil crops that produce a large amount of straw - rice, wheat, corn, cotton, rape, soybean, oil peony, oil peony, sunflower, Energy grass of any one or more combinations of castor straws, or any one or more combinations of willows, bamboo willows, poplars, mulberry trees, and wolfberry trees that
  • By-product materials By-product material 1: Brown/black liquor discharged from the hot water delignification/resin process.
  • the brown/black liquor is discharged by pressing/squeezing; the "brown/black liquor” has a weight part W of the brown/black liquor and a weight part W of the absolute dry fiber containing no more than 15% water in the main product A obtained
  • the volume ratio per liter is ⁇ 0.034mol/L, or/and the total wt% concentration of the soluble inorganic sodium salts, potassium salts, and magnesium salts contained in the water is ⁇ 0.20% (wt%), or the soluble inorganic salts and potassium salt
  • Or by-product material 2 fresh juice obtained from fresh energy grass or fresh energy grass washed with water and then squeezed; or juice obtained from dried energy grass washed with water and then boiled and squeezed;
  • Or and by-product material 3 using cow dung as the starting material, the washing/washing liquid discharged after washing/washing the cow dung;
  • Or and by-product material 4 Use activated carbon and acidic clay to adsorb, decolorize and purify the aforementioned "brown/black liquor”.
  • Or and by-product material 5 decolorized precipitated sludge obtained by precipitation and purification of the aforementioned "brown/black liquor” or/and “washing liquor” using chemical or biochemical methods;
  • the dosage form of the main product A can be a loose meat floss-like moist material with a water content of not more than 75%, a wet paper-like material with a water content of not more than 75%, a dry meat floss-like material with a water content of not more than 20%, and a water-based material. Any of paper-like dry materials containing no more than 20% water, compacted brick-shaped dry materials containing no more than 20% water, and compacted granular dry materials containing no more than 20% water;
  • -1 and A-2 are two sets of materials that can be blended easily and arbitrarily; when compared with the standard sample dough - the feces of beetle larvae or wood beetle moth larvae eating willow stems, the dough is compared with the dough.
  • the hardness of A-1 or A-2 ⁇ the hardness of the standard sample; or in the test of rubbing the dough with the standard sample for at least 10 times, it can be seen with the naked eye or Use a balance to weigh and compare, the amount of scattered chips of A-1 or A-2 is not more than 5 times the amount of scattered chips of the standard sample;
  • the ratio of the gram moles of Na + or/and K + or/and Mg 2+ contained in the water involved to the liter volume of "water” is ⁇ 0.034 mol/L; and adopt Impregnate the fiber material with water of not less than 70°C at least twice to remove the lignin/resin in the fiber; the flow direction of the gradually thickening brown/black liquor in the "water” flow is consistent with the flow direction of the fiber material in the production process The flow direction in the product is countercurrent; or water-insoluble or poorly soluble substances are added as whisker additives, and the amount added is ⁇ 1 ⁇ 3 ⁇ 5 ⁇ 9 parts by weight for 100 parts by weight of absolute dry fiber in the main product A or its intermediate product parts by weight, either ⁇ 1 part by weight or ⁇ 3 parts by weight or ⁇ 5 parts by weight or ⁇ 9 parts by weight, implement low-ash whisker grafting/coating on the fiber surface; among the additives used, caustic alkali,
  • the "by-product B - wood-plastic composite regenerated coarse particles" described in technical solution 1 is more characterized by: the characteristics of "wood” are the following 3-1 or the combination of 3-1 and 3-2, wherein The characteristics of "plastic” are the following 3-3 or the combination of 3-3 and 3-4, and the product dosage form characteristics are the following 3-5 to 3-8:
  • the “wood” includes part of the energy grass: fine materials or/and crushed materials that pass through a 28-mesh sieve, or crushed materials mixed with coarse and fine materials that pass through a 3-mesh sieve;
  • the "part" as described in 3-1 above is the dry basis weight of the "wood” containing 15% of equilibrium water after natural drying in the air, accounting for 5% to 5% of the total weight of by-product B. Between 78% (wt%);
  • the raw materials for "plastic" are all selected from waste plastics
  • waste plastics as described in 3-3 above, including at least any one or a combination of more as described below: waste paper recycling The discarded miscellaneous waste plastic film slag, including the floating plastic-containing materials or/and submerged plastic-containing materials obtained by water flotation of the "miscellaneous waste plastic film slag"; plastic film waste packaging bags and plastic film packaging of commodities Cut/punch edge materials in bag production, waste composite plastic film materials, plastic film composite release paper/film discarded in the production/use of trademark labels, waste aluminum-plastic composite film, waste agricultural plastic film; processed from waste tires Crushed and separated polymer fibers containing impurities, waste chemical fiber flannel removed from cars, waste chemical fiber carpets, waste chemical fiber fabrics, waste chemical fiber meltblown cloth, waste chemical fiber filter paper; waste wire plastic skins, waste plastic packaging tapes, waste Plastic woven bags, waste geotextiles, waste/old plastic shoes, waste plastic flooring products, waste plastic toys, waste plastic barrels, waste plastic bottles, waste plastic geotextiles, waste/old plastic
  • the dosage form of by-product B can be at least set into the first group of A, B, C, and D, or/and the second group of E, Ji, Geng, and Xin, or/and the third group of Ren and Gui. , that is, any one or more of A to Gui in the first to third groups can be blended and combined in any ratio to easily make the downstream plastic particles or coarse particles of wood-plastic composite regeneration.
  • the total weight input of "wood” in A includes 76%, and the total weight input of waste plastics and softeners accounts for 24%;
  • the total weight input of "wood” in B is 35%, and the total weight input of waste plastics and softeners is 65%;
  • the total weight input of "wood” in C is 25%, and the total weight input of waste plastics and softeners is 75%;
  • the total weight input of "wood” in D is 5, and the total weight input of waste plastics and softeners is 95%;
  • the total weight input of "wood” in E includes 77%, and the total weight input of waste plastics and softeners accounts for 23%;
  • the update includes that the total weight input of "wood” accounts for 23%, and the total weight input of waste plastics and softeners accounts for 77%;
  • the total weight input of "wood” in Xin is 10, and the total weight input of waste plastics and softeners is 90%;
  • the "wood-plastic composite recycled coarse particles” are composed of materials according to the "first group” or/and the "second group” or/and the "third group” mentioned in item 3-5.
  • the ingredients from A to Gui are combined and fed. After being processed by a coarse granulator, the resulting texture is low-strength coarse granules that can be directly pulled/pulled/pinched/teared/grabbed with fingers/palms.
  • the "low-strength coarse granules” "Strength", at least the standard sample specimen of plastic with tensile strength ⁇ 3PMa;
  • the "coarse granulator” mentioned in item 3-7 above specifically refers to any feed pellet machine, organic fertilizer granulator, or biomass fuel pellet machine with continuous feeding/discharging function. , or a spiral granulator and intermediate crusher can be connected in series after the aforementioned "granulator”/"granulator”.
  • Step 1 - Pretreatment and preparation of materials First classify the energy grass dry materials, or further remove the metals or/and masonry blocks or/and bark impurities contained in the classified materials, and then The classified and impurity-free energy grass is then subjected to any one or more combinations of sawing/grinding/cutting/hammering, and then sieved; the crushed energy grass that passes through a 28-mesh sieve is discharged for further use;
  • backup energy grass crumbs prepared for step 2 are obtained.
  • This "backup energy grass crumbs” material is called natural absolutely dry material based on its naturally adsorbed equilibrium water content in the air of 15% (wt). ;
  • Step 2 First batching: Take 100 parts by weight of the natural dry material of the "Standby Energy Grass Crushed Material” obtained in Step 1, and mix in the "Second Solid-Liquid Separation" described in the subsequent Step 7.
  • the amount of water is Active agent: any one or combination of sodium butylnaphthalene sulfonate, sodium dodecylbenzene sulfonate, sodium lauryl sulfate, or/and coconut oil fatty acid diethanolamide, fatty alcohol polyoxyethylene Any one or a combination of multiple ethers; the "2x" corresponds to 100 parts by weight of the natural dry material of crushed energy grass materials: in the range of 25 to 50 to 300 parts by weight;
  • Step 3 Heating and dissolution: Add the aforementioned "100 parts by weight of the natural dry material of the 'Standby Energy Grass Crushed Material' material" and "the extruded water obtained from the 'second solid-liquid separation' described in the subsequent step 7": "2x parts by weight”, or "0.1 to 0.3% by weight of 'surfactant' of '2x parts by weight' of 'squeezed water'”, place these materials in a tank that can be stirred, mixed, heated and kept warm. During the process, the material is uniformly stirred and heated to above 70°C, and kept warm for at least 5 minutes, or sampled and analyzed. When the color of the extruded liquid no longer changes to a darker color, the heating and heat preservation operations can be stopped;
  • Step 4 The first solid-liquid separation: Introduce the material after the above "heating and heat preservation operations" into a screw or roller extruder, perform a mechanical kneading treatment on the fiber bundles of the material, and then knead it.
  • the materials are introduced into a solid-liquid separator for solid/liquid separation; or the materials after the above-mentioned heating and heat preservation operations are directly introduced into a solid-liquid separator for solid/liquid separation; thereby obtaining the "pressed/extruded brown material" as described in technical solution 1. / black liquor", and the moisture material of the hydrophilic decomposed fiber intermediate product A to be treated, which has initially removed the water solute in the fiber;
  • the "pressed/extruded brown/black liquor” obtained is naturally separated from the hydrophilic decomposable fiber intermediate product A by the weight portion of the discharged brown/black liquor.
  • Step 5 - Second batching It is determined that the free water carried by 100 parts by weight of the natural dry material in the solid phase of the "moist material for the hydrophilic decomposable fiber intermediate product A" described in step 4 is x parts by weight. Then, take 100 parts by weight of the natural dry material contained in the "moist material of the hydrophilic decomposable fiber intermediate product A to be treated" and x parts by weight of free water, and then mix in the "third solidification step" described in the subsequent step ten.
  • the extruded water obtained by "liquid separation” is not less than: Whisker auxiliary, the “whisker auxiliary” is at least any one of saturated aqueous calcium hydroxide solution, silica sol, etc., or/and newly generated calcium hydroxide, aluminum hydroxide, hydrated silicic acid in the aqueous phase , any one or a combination of calcium silicate, magnesium silicate, aluminum silicate, calcium carbonate, calcium sulfate dihydrate, ferric hydroxide, etc., or/and ultrafinely pulverized to the point where it cannot naturally dissolve in water within half an hour. Any one or combination of kaolin, clay, fly ash, wollastonite, etc.
  • the "whisker additive" the amount added to 100 parts by weight of absolute dry fiber in the "moist material of hydrophilic decomposable fiber intermediate product A" is ⁇ 1 to 3 ⁇ 5 ⁇ 9 parts by weight, that is, the added amount is ⁇ 1 part by weight or ⁇ 3 parts by weight or ⁇ 5 parts by weight or ⁇ 9 parts by weight;
  • Step 6 Grinding and latent elimination: Introduce the "materials to be processed into high-concentration grinding" obtained in step 5 into high-concentration grinding; or then use the heat to introduce the heat-generating materials from high-concentration grinding into a disinfection machine with heat preservation settings. Insulate or heat in a submersible tank, and let it stand at a temperature of no less than 70°C to relax the kinks and curls of the fibers produced during the high-concentration grinding process, and to dissolve the hydrophobic lipids in the fibers; After processing in step 6, the material after grinding or processing is obtained and is subject to solid-liquid separation;
  • Step 7 The second solid-liquid separation: Introduce the above-mentioned "material after grinding or processing” into a screw or roller squeezer, and then perform mechanical kneading treatment on the fiber bundles of the material, and then Then the material is introduced into the solid-liquid separator for solid/liquid separation; or mechanical softening is omitted, and the above-mentioned "materials after grinding or processing” are directly introduced into the solid-liquid separator for solid/liquid separation; thus, we get As described in the previous “Step 2", "the extruded water obtained from the 'second solid-liquid separation'" and the wet material of the hydrophilic decomposable fiber intermediate product B to be treated are finally washed with new water;
  • Step 8 - The third batching: It is determined that the free water carried by 100 parts by weight of the natural dry material in the solid phase of the "moist material of the hydrophilic decomposable fiber intermediate product B to be treated" described in step 7 is x parts by weight. Then, take 100 parts by weight of the natural dry material contained in the "moist material to be processed for the hydrophilic decomposable fiber intermediate product B" and x parts by weight of free water, and then mix in new water or a small amount of recycled water for decolorization and impurities.
  • any of calcium hydroxide, aluminum hydroxide, silica sol, etc., or/and newly generated calcium hydroxide, aluminum hydroxide, hydrated silicic acid, calcium silicate, magnesium silicate, aluminum silicate in the water phase any one or a combination of calcium carbonate, calcium sulfate dihydrate, ferric hydroxide, etc., or kaolin, clay, fly ash that has been ultrafinely pulverized to the point where it is difficult to naturally precipitate to a clear surface in water within half an hour. , any one or more combinations of wollastonite, etc., or any one or more combinations of kaolin, clay, fly ash, wollastonite, etc.
  • the "whisker additive” the added amount of 100 parts by weight of absolute dry fiber in the "moist material of hydrophilic decomposable fiber intermediate product B" is ⁇ 1 ⁇ 3 ⁇ 5 ⁇ 9 parts by weight, that is, the added amount is ⁇ 1 part by weight or ⁇ 3 parts by weight or ⁇ 5 parts by weight or ⁇ 9 parts by weight; add water and whisker additives according to the measurement in step eight to obtain the third batch of ingredients to be sent to step nine;
  • Step 9 Stirring and washing: Introduce the "third batching" of the above step 8 into the screw or roller extruder, and then perform mechanical kneading treatment on the fiber bundles of the material, and then introduce the material to be finalized.
  • the squeezed material is temporarily stored in a temporary storage tank; or the above-mentioned "third batching" is directly introduced into the mixer for stirring, so that the new water, or the moisture content of the solid-phase fiber mixed with the whisker additive and the hydrophilic decomposable fiber intermediate product B is The old water-containing material is fully mixed, and then the material is introduced into the temporary storage tank for the material to be finally squeezed dry; through the processing in step nine, the material to be sent to step ten to be finally squeezed dry is obtained;
  • Step 10 - The third solid-liquid separation or final modification: Introduce the "material to be finally squeezed dry" in the above-mentioned step 9 into the solid-liquid separator for solid/liquid separation; thus obtain the material as in the previous "step five"
  • the obtained fresh juice can be heated to 100-105°C for 3-5 minutes, cooled and canned to obtain a liquid black brown edible or medical grade lignin/resin mixture product C- 1; If the "fresh juice” is subjected to an evaporation and concentration operation while heating, the steamed and concentrated material of the "fresh juice” can be cooled to room temperature under the control process parameters of controlling the amount of steamed water.
  • the edible or medical grade lignin/resin mixture product C-1 can be in the form of a paste-like tan colloid, or a coffee-colored powder or granules, or a rosin-like solid block;
  • the moisture content of the residue is below 20% (wt%), and the liquid squeezed out is the by-product material 2 described in item ii of technical solution 2 - "dry energy grass is washed with water and then boiled and pressed.”
  • the concentrated material When the concentrated material is cooled to room temperature, it can be in the form of a tan colloid in the form of pasta, or in the form of coffee-colored powder or granules, or in the form of rosin-like solid blocks, edible or medical grade lignin/resin mixture product C-1;
  • the squeezed liquid is either the by-product material 2 described in item ii of technical solution 2 - "fresh energy grass” and “fresh juice obtained by pressing”; or the “fresh juice” "Heat to 100 ⁇ 105°C and hold for 3 ⁇ 5 minutes, cool and can the liquid black brown feed or industrial grade lignin/resin mixture product C-2; if it is heated at the same time, then "fresh” "Juice” is subjected to an evaporation and concentration operation, and under the control of process parameters that control the amount of steamed water, the steamed and concentrated material of "fresh juice” can be in the form of a brown colloid like a pasta sauce when it is cooled to room temperature, or Feed or industrial grade lignin/resin mixture product C-2 in
  • the liquid squeezed out is either the by-product material 1 described in item ii of the technical solution 2 - the brown/black liquor discharged from the hot water delignification/resin process; or the "brown liquor” /Black liquor” is heated to 100 ⁇ 105°C for 3 ⁇ 5 minutes, cooled and canned to obtain a liquid black brown feed or industrial grade lignin/resin mixture product C-2; if it is heated at the same time, then The "brown/black liquor” is subjected to an evaporation and concentration operation, and under the control of process parameters that control the amount of steamed water, the "brown/black liquor” can be evaporated and concentrated, and then when cooled to room temperature, it can be turned into a pasta sauce
  • the feed or industrial grade lignin/resin mixture product C-2 is in the form of brown colloid, or coffee-colored powder or granules, or rosin-like solid block;
  • the moisture content of the slag is below 20% (wt%), and the liquid squeezed out is the by-product material 1 described in item ii of the technical solution 2 - the brown/black liquor discharged from the hot water delignification/resin process; or Heat the "brown/black liquor” to 100-105°C for 3-5 minutes, cool it, and can it to form a liquid black brown feed or industrial grade lignin/resin mixture product C-2; if it is heated At the same time, the "brown/black liquor” is subjected to an evaporation and concentration operation, and the "brown/black liquor” can be evaporated and concentrated under the control process parameters of controlling the amount of steamed water.
  • the washed/washed liquid discharged after the washing/washing treatment can at least be used as direct irrigation water for planting the fertilizer-resistant and water-consuming Giant Junca grass;
  • the slag mentioned in the above 5-1 to 5-5 "It is better to control the moisture content of the slag after pressing to be below 20% (wt%)" can be soaked into a solid content of 25%.
  • the loose floss-like material is sifted out and the particle size classification or mixed elongated fiber bundles ranging from 3 mesh to no more than 28 mesh can be obtained as described in step 4 of technical solution 4.
  • the moisture material of the hydrophilic decomposable fiber intermediate product A to be treated to remove the water solute in the fiber can be followed by the fifth to tenth steps in the technical solution 4, and finally the hydrophilic decomposable fiber product A-1 or A-2;
  • the water containing cow dung produced by "washing cow dung” and “washing and sieving with water” described in the aforementioned 5-5 is the “water containing cow dung” described in item ii of technical solution 2.
  • By-product material 3 "The washing liquid produced by washing cow dung” can be directed to be one of the ingredients of the "auxiliary product E--liquid organic soil conditioner" described in the technical solution 1.
  • Fiber powder the "materials with more nutrients", in terms of measurement, are materials that cannot withstand the mechanical crushing force and are more finely crushed after being crushed or cut into pieces once, and pass through a sieve ranging from 28 to no more than 150 mesh.
  • Granulation The materials prepared by the scale are passed through the mixing aggregate bin, and then transported by machinery, and put into the "coarse granulator" described in 3-7 and 3-8 of Technical Plan 3 to form Granules; the machinery used in the "coarse granulator” is: any of the feed pellet machine, organic fertilizer granulator, biomass fuel pellet machine with continuous inlet/output function, or any of the above-mentioned
  • the "granulator”/"granulator” is then connected in series with a spiral granulator and intermediate crusher; the aforementioned “granulator”/"granulator” discharges the material in the form of segmented granules formed by the through-hole die.
  • the aforementioned “granulator”/"granulator” The “segmented granular” “materials” are then processed by the spiral granulator in series, and then the materials come out of the machine as irregular particles; the materials during granulation are heated by mechanical extrusion/friction, and can be used to feed the materials or /The water is added to the interlayer in the machine to control the outgoing material to not exceed 110°C; the "coarse wood-plastic composite recycled material” produced by this operation has a texture that can be directly pulled/pulled by human fingers/palms/ Low strength when kneaded/torn into pieces; its granulated shape at least includes segmented granules or irregular particles formed by a through-hole mold; the hole shape of the "hole mold” includes at least equilateral or unequal side lengths Any one of 3 to 12 sides, or round; the size of the "grain” is classified or mixed in any aperture ranging from 25mm to less than 2.0mm mesh;
  • Inbound quality inspection Put the packaged products into the warehouse in order, and provide quality inspection reports for each batch of incoming products for archiving according to the indicators that market customers need to know.
  • auxiliary product D - solid organic soil conditioner product described in technical solution 1 is at least characterized in that: when using energy grass, or energy grass and cow dung as the starting main raw materials, use extracted The remaining materials after making the main product A, including energy grass powder or fine cow dung sediment that has passed through a 28-mesh sieve, are used as one of the ingredients in "auxiliary product D";
  • the preparation method of "auxiliary product E--liquid organic soil conditioner product” described in technical solution 1, is at least characterized by: using energy grass, or energy grass and cow dung as the starting main raw materials, during the preparation of " When the main product A - hydrophilic decomposable fiber product” and “by-product C - lignin/resin mixture product", the pressing liquid or/and washing liquid or/and elutriation liquid discharged from the upgraded products A and C ; Then the liquid organic soil conditioner product obtained by blending the "pressed liquid or/and washing liquid or/and elutriation liquid” according to the soil improvement requirements of the crops and plots being applied; the “discharge” The press liquid or/and washing liquid or/and elutriation liquid”, the pH value does not exceed the range of 5.0 to 9.4, and the gram moles of Na + or/and K + or/and Mg 2+ contained therein are equal to those of the The liter volume ratio of water is ⁇ 0.034mol/L, or the total
  • auxiliary product G - pellet feed product described in technical solution 1 is at least characterized in that: when using unpressed dry energy grass as the starting main raw material, the main raw material is screened out.
  • the remaining materials after using the raw materials for Product A are "fine powder passed through a 28 mesh sieve", or/and "energy grass fiber powder with a small soil content and a medium particle size passed through a 28 mesh to no more than 150 mesh sieve", as particles.
  • auxiliary product H--biomass pellet fuel product described in technical solution 1 is at least characterized by: using energy grass to crush and sieve to remove fine fibers that have not passed the 28-mesh sieve.
  • the "waste plastics” include at least waste agricultural plastic films and waste foam plastics , any one or more combinations of waste chemical fiber fabrics or/and chemical fiber wadding, the "addition” accounting for less than 5% of the total weight of the auxiliary product H, or up to no more than 22%;
  • auxiliary product I - edible fungus planting stick/block product described in technical solution 1 is at least characterized in that: when using energy grass, or energy grass and cow dung as the starting main raw materials, use The remaining materials after sifting out the raw materials for the main product A, namely energy grass powder or fine cow manure sediment that has passed through a 28-mesh sieve, are used as ingredients in the edible fungus planting stick/block product.
  • step one to “step ten” described in technical solution 4 involves setting up combination machinery I to Machinery I, which at least includes: crushing machinery 1, any one or more combinations of saw/mill/cut/hammer crusher 2, air separation machinery 3, and mechanical screen 4 to crush the energy straw bundles Machine, any one or more combinations of sawing/milling/cutting/hammer crushing machine processing, and then through air selection and screening, screen out any energy grass crushed materials that pass the 3 mesh to the 28 mesh sieve range.
  • One-mesh classification or mixed particle size elongated fiber bundles; or an expansion machine 5 is installed after the mechanical screen 4;
  • the combined machine II for the "first batching" of the “step two” described in the technical solution 4 at least includes: a batching bin 6 for placing the “backup energy grass crumbs", containing the "first batching” described in the subsequent step seven.
  • the combined machine III for implementing the "heated dissolution” of "step three" described in technical solution 4 at least includes: a tank 11 for stirring, mixing, heating and insulation;
  • the combined machinery IV for implementing the "first solid-liquid separation” of "step four" described in technical solution 4 at least includes: a conveying machine 12, a screw or roller squeezer 13, and a solid-liquid separator 14, Storage tank 15 for storing the "pressed/extruded brown/black liquor” obtained from the "first solid-liquid separation”;
  • the combined machine V for the "second batching" of the "step five” described in the technical solution 4 at least includes: a storage bin 16 for "tidal material to be processed of the hydrophilic decomposable fiber intermediate product A", containing The liquid tank 17 of the extruded water obtained in the "third solid-liquid separation” described in the subsequent step ten, or the silo 18 for storing the "whisker additive", the weighing scale 19, and the "third solid-liquid separation” are set up.
  • the material storage bin 22 is provided with a conveying mechanism or conveying machinery 23 between the storage bin 22 and the high-consistency refiner 21; after the outlet of the high-consistency refiner 21, a heat preservation or heating function is provided
  • the submersion elimination tank 24 is provided with a conveying mechanism or conveying machinery 25 between the outlet of the high-consistency refiner 21 and the feed inlet of the submersion elimination tank 24;
  • the combined machinery VII for implementing the "second solid-liquid separation” of "step seven" described in technical solution 4 at least includes: a conveying machine 26, a screw or roller squeezer 27, and a solid-liquid separator 28, Storage tank 19 for storing the "extruded water obtained from the 'second solid-liquid separation'" described in step seven of technical solution 3;
  • the combined machine VIII for the "third batching" of "step eight” described in the technical solution 4 which at least includes: setting up and storing the moisture of the "hydrophilic decomposable fiber intermediate product B to be processed” described in the seventh step of the technical solution 4.
  • the combined machinery X for implementing the "third solid-liquid separation or final modification" of "step ten" described in technical solution 4, at least includes: setting up a conveying mechanism or conveying machine 37, a solid-liquid separator 38, and setting up a storage cover
  • the combined machinery XI used to implement the "co-production of A and C-1" described in 5-1 and 5-2 of technical solution 5, at least includes: for the specific production method described in 5-1 of technical solution 5, set An operating machine 41 is used to remove roots and leaves of fresh energy grass.
  • a cleaning machine 42 is provided for washing, dehydrating and drying the fresh energy grass.
  • a press 43 is provided for squeezing and extracting juice from the fresh energy grass.
  • Set up a storage tank 44 to store the fresh juice of pressed energy grass, or set up a distillation kettle 45 for heating the fresh juice to boiling or evaporation and concentration, and set up cooling and canning machinery 46;
  • an operating machine 47 for removing roots and blades of dry energy grass is provided, or a combined machine 48 for crushing and screening the dry energy grass material is provided.
  • set up a cleaning machine 49 for washing and dehydrating the dried energy grass a combined machine 50 that can add water, heat it to boiling, and then extract the juice, and a storage tank 51 for storing the squeezed energy grass juice
  • the "energy grass juice” is also the by-product material 1 described in item ii of the technical solution 2 - the brown/black liquor discharged from the hot water delignification/resin process; or it is further configured to process the "energy grass juice” Heat to boiling or steam
  • the concentrated distillation kettle 52 is equipped with cooling and canning machinery 53;
  • the combined machinery XII used to implement the "co-production of A and C-2" described in 5-3 to 5-5 of technical solution 5, which at least includes: for the specific production method described in 5-3 of technical solution 5, set An operating machine 54 for removing roots and leaves of fresh energy grass is provided, a press 55 for pressing fresh energy grass to extract juice is provided, a storage tank 56 for storing the fresh juice of the pressed energy grass is provided, or a press 55 for extracting juice from the fresh energy grass is provided.
  • the distillation kettle 57 is heated to boiling or evaporated for concentration, and is equipped with cooling and canning machinery 58;
  • an operating machine 59 for removing roots and blades of dry energy grass is provided, or a combined machine 60 for crushing and screening the dry energy grass material is provided.
  • a storage tank 65 is provided for storing the dewatered water after "cleaning" the energy grass in the combined machine XI, and a storage tank 65 is provided.
  • the equipment used to implement the "Preparation Method" of "B" mentioned in Technical Solution 6 involves setting up sub-assembly machines XIV to XVII, including:
  • the equipment used to implement the "manufacturing method" of the "auxiliary products" described in Technical Solution 7 involves setting up sub-assembly machines XVIII to IIIII, including:
  • auxiliary product F--fermented feed in the technical solution 7, which is characterized in that: it includes a set of assembly device 89 for preparing fermented feed products;
  • each unit of machinery from 1 to 88 as described in 8-1 to 8-4 above can be arranged neatly into a standard container.
  • the "Main Product A - Hydrophilic Decomposable Fiber” described in Technical Schemes 1 and 2 can at least be used to prepare rice paper, corrugated paper, cardboard, or/and include egg trays and convenient dinner plates/bowls. It can be used as an alternative material to partially or completely replace waste paper recycled pulp in paper molded products such as paper seedling pots/bowls, etc.; it can also be used as a new starting material for further processing, such as making bleached pulp; or It is used as raw material for preparing cellulose ether;
  • the "by-product B - wood-plastic composite recycled coarse particles" described in technical solutions 1 and 3 can be used at least as wood plastic particles to be modified or/and refined for hot extrusion of wood-plastic products.
  • raw material or directly used as a new formulation raw material for hot extrusion wood plastic products, or as a granular fuel for heating;
  • the "by-product C-1 - edible or medical grade lignin/resin mixture" described in technical solution 1 can be used at least as a raw material for preparing beverages or/and traditional Chinese medicine preparations;
  • the "by-product C-2 - feed or industrial grade lignin/resin mixture" described in technical solution 1 can be used at least as a feed raw material, or/and as a water-reducing agent for concrete and rubber. /Any kind of softener in plastics;
  • the "products”, “preparation methods” and “equipment” described in technical solutions 1 to 8 can at least be used for the "raw materials” described in item i of technical solution 2, including Giant Juncao, etc. Processing; or be expanded to the processing of bamboo, sugar cane peel, etc.;
  • One enterprise can independently implement the commercial operation of "products” or/and “manufacturing methods”;
  • the business model of self-operated or outsourced manufacturing can be used to implement the commercial operation of "products” or/and “manufacturing methods";
  • Figure 1 is a black and white photo of the elongated fiber bundles of Mulberry branch Ya, one of the mixed energy grasses with particle sizes ranging from 3 mesh to 28 mesh.
  • Figure 2 is a black and white photo of the elongated fiber bundles of rice straw, one of the mixed energy grasses, which has passed through a sieve of 3 mesh to 28 mesh.
  • Figure 3 is a black and white photo of a dry mass sample of hydrophilic and decomposable fiber A-1, which was prepared in the laboratory from Paeonia oleifera straw, one of the energy grasses.
  • Figure 4 is a black and white photo of a dry mass sample of hydrophilic decomposable fiber A-2, which was prepared in the laboratory from mulberry branch Ya, one of the energy grasses.
  • Figure 5 is a black-and-white photo of the actual broken paper after being made from wheat straw, one of the energy grasses, into hydrophilic decomposable fiber A-2 in the laboratory. The paper was folded and unfolded after being grasped once. .
  • Figure 6 is a black and white photo of by-product C-2, a feed or industrial grade lignin/resin mixture that can be formulated for application Feed additives, plant nutrients, or used as rubber/plastic additives, etc.
  • Figure 7 is a black-and-white photo of plastic film materials discarded from waste paper to recycled pulp.
  • Figure 8 is a black and white photo of wood plastic composite recycled coarse grain B.
  • Figure 9 is a black and white photo of a dry dough standard sample.
  • Figure 10 is the "standard sample” described in Figure 9, which is derived from the feces of beetle larvae or wood moth larvae that eat the willow stems accumulated on the ground under a willow tree in nature. This is the “feces” under the willow tree. The black and white photo, the arrow in the photo points to the "feces”.
  • Figure 11 is a black and white photo of what the "standard sample” described in Figures 9 and 10 looks like when it is collected in the laboratory and has not been screened or processed. Its true color is brown.
  • Figure 12 is a black and white photo of the scraps produced by comparing the standard sample in Figure 9 and the sample in Figure 4.
  • Figure 13 is a schematic block diagram of the ten steps for preparing "main product A--hydrophilic and decomposable fiber”.
  • Figure 14 is a block schematic diagram of the process equipment flow used in the product assembly manufacturing method of the present invention, in which I to X located in the ⁇ block surrounded by " ⁇ -" are the process equipment flow used to prepare the main product A, as shown in XI to to XVII are the process equipment flows used to prepare by-product B, and XVIII to II III in the block surrounded by " ⁇ -" are the process equipment flows used to prepare auxiliary products D to I.
  • the definition of the numbers in the figure is:
  • I is the sub-combination machinery for "pretreatment and preparation” of "Step 1" in the preparation of main product A, which at least includes: 1--crushing machinery, 2--any or more combinations of sawing/milling/cutting/hammer crushing Chemical machine, 3--Wind separation machinery, 4--Mechanical screen, 5--Puffing machinery;
  • III is the sub-assembly machinery for the "heating and dissolution" of "Step 3" in the preparation of main product A, which at least includes: 11--tanks for stirring, mixing, heating and insulation;
  • Step IV is the sub-assembly machinery used for the "first solid-liquid separation" in "Step 4" in the preparation of main product A, which at least includes: 12--conveying machinery, 13--screw or roller extruder, 14-- Solid-liquid separator, 15--a storage tank that stores the "pressed/extruded brown/black liquor" obtained from the "first solid-liquid separation”;
  • V is the sub-assembly machine for preparing the "second batching" of "Step 5" in the main product A, which at least includes: 16--the storage bin of "the moisture material of the hydrophilic decomposable fiber intermediate product A to be processed", 17 --The liquid tank containing the extruded water obtained from the "third solid-liquid separation” described in the subsequent step ten, 18--The silo storing the "whisker additive", 19--Weighing and measuring instruments, 20 --Mixing mixer 20 after "second batching";
  • VI is the sub-assembly machine for "grinding and latent elimination" in "Step 6" in the preparation of main product A, which at least includes: 21--high-consistency refiner, 22--storage silo for materials to be processed, 23-- Conveying mechanism or conveying machinery 23; 24--submersible tank with insulation or heating function 25--conveying mechanism or conveying machinery;
  • Step VII is the sub-assembly machinery for the "second solid-liquid separation" in "Step 7" in the preparation of main product A, which at least includes: 26--conveying machinery, 27--screw or roller extruder, 28-- Solid-liquid separator;
  • VIII is a sub-assembly machine for the "third batching" of "Step 8" in the preparation of main product A, which at least includes: 29--a storage silo for storing "the moisture material of the hydrophilic decomposable fiber intermediate product B to be processed", 30 is a storage tank for measuring and storing new water and circulating purified water, 31--silo for storing whisker additives, 32--weighing instrument, 33--stirring and mixing tank;
  • IX is a sub-assembly machine for "stirring and washing” in “Step 9" in the preparation of main product A, which at least includes: 34--conveying mechanism or conveying machinery 34, 35--screw or roller squeezer, 36-- Material temporary storage tank;
  • X is the combined machinery for the "third solid-liquid separation or final modification" in "Step 10" in the preparation of the main product A, which at least includes: 37--conveying mechanism or conveying machinery, 38--solid-liquid separator, 39 --Trough for storing iron/manganese ion masking additives, 40--Trough for storing anti-mildew additives;
  • XIMachines and sub-combinations used in the co-production method of main product A and by-product C-1 including at least: 41--operating machinery for removing roots and leaves of fresh energy grass 41, 42--for fresh energy Cleaning machinery for washing, dehydrating and drying grass, 43--a press for squeezing and extracting juice from "fresh energy grass after washing with water", 44--a storage tank for storing the fresh juice of pressed energy grass, 45 --Stills for heating fresh juice to boiling or evaporating and thickening it, 46--cooling and canning machinery;
  • 47--A machine for removing roots and leaves from dry energy grass. 47, 48--A combined machine for crushing and screening dry energy grass material. 49--A machine for washing and dehydrating dry energy grass. Cleaning machinery, 50--a combined machine that can add water, heat it to boiling, and then squeeze it out, 51--a storage tank for storing squeezed energy grass juice, 52--heat the "energy grass juice” to boiling Or distillation kettle for evaporation and concentration, 53--cooling and canning machinery;
  • XII Machinery used in the joint production of main product A and by-product C-2 and sub-combination machinery including at least: 54--operating machinery for removing roots and leaves of fresh energy grass, 55--making fresh energy grass A press for squeezing and extracting juice, 56 - a storage tank for storing the fresh juice of pressed energy grass, 57 - a distillation kettle for heating the fresh juice to boiling or evaporation and concentration, 58 - cooling and canning machinery;
  • 59--A machine for removing roots and leaves from dry energy grass
  • 60--A combined machine for crushing and screening dry energy grass materials
  • 61--It can add water, heat it to boiling, and then make juice.
  • Combined machinery for extracting and squeezing 62--storage tank for storing pressed energy grass juice, 63--distillation kettle for heating "energy grass juice” to boiling or evaporation and concentration, 64--cooling and canning machinery;
  • XIII is a sub-assembly of machinery used for "subsequent" diversion treatment in the co-production method of main product A and by-product C, which at least includes: 71--Setting up a classification collection bin, 72--Breaking the "slag after pressing" into Combined machinery for stirring and heating loose floss-like materials with a solid content of 25%; 73--mechanical screen, 74--collection bin; 75--conveying machinery, 76--collection tank;
  • X IV is a sub-assembly device for "material preparation" in the production method of by-product B, which also includes: 77--mechanical screen, 78--crushing machinery, 79--wind separation machinery;
  • X V is the "ingredient" sub-assembly device in the by-product B production method, which also includes: 80--weighing instrument, 81--respectively store the "wood” and “plastic” in the composition of the "wood-plastic composite recycled material coarse particles” "And the storage silo of softener, 82--the mixing tank after metering and batching;
  • X VI is the "granulation" sub-assembly device in the by-product B production method, which also includes: 83--conveying machinery, 84--coarse granulator;
  • X VII is the "homogenization mixing" and "weighing packaging" sub-assembly device in the by-product B production method, which also includes: 85--homogenization mixer, 86--weighing packaging machinery;
  • X VIII is the sub-assembly machinery used in the preparation method of auxiliary product D, including: 87-contains a set of assembly equipment for preparing solid organic soil conditioner;
  • X IX is a sub-assembly of machinery used in the preparation method of auxiliary product E, including: 88 - a set of assembly devices for preparing liquid organic soil conditioner products;
  • auxiliary product F is the sub-assembly machines used in the preparation method of auxiliary product F, including: 89-including a set of assembly devices for preparing fermented feed products;
  • II I is the sub-assembly machinery used in the preparation method of auxiliary product G, including: 90-including a set of assembly equipment for preparing pellet feed products;
  • II II is the sub-assembly machinery used in the preparation method of auxiliary product H, including: 91-including a set of assembly equipment for preparing biomass pellet fuel products;
  • auxiliary product II and III are sub-assembly machines used in the preparation method of auxiliary product I, including: 92-including a set of combined devices for preparing edible fungus planting sticks/block products.
  • Embodiment 1 A collection of clean products using energy grass as raw material, characterized in that: using energy grass, or energy grass and cow dung as the starting main raw materials, the process and combined equipment of clean production are integrated in series and parallel through processing sub-paths, or The device array finally produces a set of cleaning products.
  • the "product set” is specifically composed of the main product A as described below, or a combination of the main product A and any one or two of the by-products B and C; or Main product A or by-product B/C, combined with any one or more of auxiliary products D, E, F, G, H, I:
  • the main product A - hydrophilic decomposable fiber characterized by: using the aforementioned "energy grass, or energy grass and cow dung", crushed by any or more combinations of sawing/milling/cutting/hammering and then sieving to obtain the "Elongated fiber bundles of any mesh size that pass through a sieve ranging from 3 mesh to no more than 28 mesh" are used as raw materials; the brown/black liquor will be discharged during the preparation process, and the "brown/black liquor” will be discharged.
  • the "whisker additive" can be used for the main product A or its intermediate product
  • the added amount of absolute dry fiber in 100 parts by weight is ⁇ 1 ⁇ 3 ⁇ 5 ⁇ 9 parts by weight, which is ⁇ 1 part by weight or ⁇ 3 parts by weight or ⁇ 5 parts by weight or ⁇ 9 parts by weight;
  • the main product A ——Hydrophilic and decomposable fiber products that do not float to the surface after being put into water or stirred;
  • the main product A can be subdivided into the main product A-1--a hydrophilic decomposable fiber controlled to have a low hydrophilicity of beating degree ⁇ 16°SR, and the main product A-2--controlled to be Hydrophilic and decomposable fiber with high hydrophilic beating degree ⁇ 16°SR;
  • By-product B - wood-plastic composite regenerated coarse particles; characterized by: at least the above-mentioned "energy grass” is crushed by any one or more combinations of sawing/milling/cutting/hammering, and then screened.
  • the other part “Fine materials or/and crushed materials that pass through a 28-mesh sieve, or crushed materials that are mixed with coarse and fine materials that pass through a 3-mesh sieve", and then use them with "waste plastics" as raw materials, or mix them with those in A
  • the above-mentioned "brown/black liquor” has a mass transfer connection and is pelletized using a biomass fuel pellet machine;
  • By-product C - lignin/resin mixture characterized by: It is produced using the "brown/black liquor" mentioned in A as raw material. It is a hydrophilic liquid in the color of black brown at room temperature, or in the form of a paste-like brown or Nearly black colloid, or in the form of coffee or nearly black powder or granules, or in the form of rosin-like solid; the by-product C, which can be subdivided into by-product C-1-edible or medical grade lignin/resin mixture, By-product C-2--feed or industrial grade lignin/resin mixture;
  • Auxiliary product D - solid organic soil conditioner characterized by: the remaining material after extracting "energy grass, or energy grass and cow dung" that does not pass the 28-mesh sieve to make the main product A.
  • Energy grass powder or fine cow dung sediment is used as one of the ingredients in the solid organic soil conditioner;
  • Auxiliary product E - liquid organic soil conditioner characterized by: utilizing the brown/black liquor discharged during the preparation of the hydrophilic decomposable fiber main product A, or/and utilizing the discharged liquid due to the upgrading of the main product A and by-product C Pressed liquid or/and washing liquid or/and elutriated liquid, products blended according to the soil quality requirements of the crops and fields to be applied; the "discharged pressed liquid or/and and washing liquid or/and elutriation liquid" or "brown/black liquor", its pH value is in the range of 5.0 to 9.4, and the gram mole of Na + or/and K + or/and Mg 2+ contained therein is the same as that contained in it.
  • the liter volume ratio of water is ⁇ 0.034mol/L, or the total wt% concentration of soluble sodium salts, potassium salts, and magnesium salts contained therein is ⁇ 0.20% (wt%), or the soluble sodium salts, potassium salts contained therein are
  • the difference between the total concentration of salt and magnesium salt and the total concentration of soluble sodium salt, potassium salt and magnesium salt in the water source taken from the production site is ⁇ 0.01% (wt%);
  • the weight ratio of auxiliary product E to main product A is Control within the range of W E /W A ⁇ 500/100 or ⁇ or 2000/100 ⁇ or 3000/100;
  • Auxiliary product F - fermented feed characterized by: the product is mixed with the "brown/black liquor" discharged during the preparation process of main product A;
  • Auxiliary product G - pellet feed characterized by: the energy grass dry material is only crushed and sieved to obtain a fine powder that passes through a 28 mesh sieve, or/and a particle size with a small soil content that passes through a 28 to less than 150 mesh sieve.
  • the energy grass fiber powder in the center is used as one of the ingredients of pellet feed;
  • Auxiliary product H - biomass pellet fuel characterized by: the fine powder obtained by crushing and sieving the energy grass to remove the crude fiber that has not passed the 28 mesh sieve, or the full-component crushed energy grass as ingredients. components, or waste plastics are added; the "waste plastics” include at least any one or combination of waste agricultural plastic films, waste foam plastics, waste chemical fiber fabrics or/and chemical fiber cotton batting, and the "waste plastics" “Additional” accounts for less than 5% of the total weight of auxiliary product H, or does not exceed 22%;
  • Auxiliary product I - Edible fungus planting stick/block characterized by: the remaining material after extracting the main product A from "energy grass, or energy grass and cow dung" with a mesh size of no more than 28 mesh, and passing through a 28 mesh sieve.
  • the energy grass powder or fine cow dung sediment of the hole is used as one of the ingredients in the edible fungus planting sticks/blocks.
  • Embodiment 2 The "main product A--hydrophilic and decomposable fiber" described in Embodiment 1, its characteristics include at least the following i to vi, or a combination with vii:
  • Raw materials used including Echinacea, Liba, lemongrass, Arundodis, reeds, reeds, zebra grass, elephant grass, king grass, king bamboo grass, giant fungus grass, five-jointed miscanthus, rice grass, purple elephant grass , dwarf elephant grass, red elephant grass, sweet elephant grass, grass shoots, grass sugarcane, pseudosorghum, sweet sorghum, Peter grass, Sudan grass, Taiwan sweet grass, Pennisetum alterniflora, Spartina alterniflora hybrid, American wolftail Energy grasses of any one or more combinations of grasses and hybrid pennisetum, grain, cotton, and oil crops that produce a large amount of straw - rice, wheat, corn, cotton, rape, soybean, oil peony, oil peony, sunflower, grizzly Energy grass composed of any one or more combinations of hemp straws, or any one or more combinations of willows, bamboo willows, poplars, mulberry trees, and
  • By-product materials By-product material 1: Brown/black liquor discharged from the hot water delignification/resin process.
  • the brown/black liquor is discharged by pressing/squeezing; the "brown/black liquor” has a weight part W of the brown/black liquor and a weight part W of the absolute dry fiber containing no more than 15% water in the main product A obtained
  • the volume ratio per liter is ⁇ 0.034mol/L, or/and the total wt% concentration of the soluble inorganic sodium salts, potassium salts, and magnesium salts contained in the water is ⁇ 0.20% (wt%), or the soluble inorganic salts and potassium salt
  • Or by-product material 2 fresh juice obtained from fresh energy grass or fresh energy grass washed with water and then squeezed; or juice obtained from dried energy grass washed with water and then boiled and squeezed;
  • Or and by-product material 3 using cow dung as the starting material, the washing/washing liquid discharged after washing/washing the cow dung;
  • Or and by-product material 4 use activated carbon and acidic clay to adsorb and decolorize impurities in the aforementioned "brown/black liquor", and purify circulating water to obtain the decolorized adsorption sludge; or use the aforementioned "brown/black liquor",
  • the decolorized adsorption sludge is obtained by adding sulfuric acid dropwise to acidify until the pH value does not exceed 7.0, and using activated carbon or activated carbon and acid clay to purify circulating water;
  • Or and by-product material 5 Use chemical or biochemical methods to precipitate the aforementioned "brown/black liquor” or/and “washing liquor” Decolorized precipitated sludge obtained from purification treatment;
  • the dosage form of the main product A can be a loose meat floss-like moist material with a water content of not more than 75%, a wet paper-like material with a water content of not more than 75%, a dry meat floss-like material with a water content of not more than 20%, and a water-based material. Any of paper-like dry materials containing no more than 20% water, compacted brick-shaped dry materials containing no more than 20% water, and compacted granular dry materials containing no more than 20% water;
  • -1 and A-2 are two sets of materials that can be blended easily and arbitrarily; when compared with the standard sample dough - the feces of beetle larvae or wood beetle moth larvae eating willow stems, the dough is compared with the dough.
  • the hardness of A-1 or A-2 ⁇ the hardness of the standard sample; or in the test of rubbing the dough with the standard sample for at least 10 times, it can be seen with the naked eye or Use a balance to weigh and compare, the amount of scattered chips of A-1 or A-2 is not more than 5 times the amount of scattered chips of the standard sample;
  • the ratio of the gram moles of Na + or/and K + or/and Mg 2+ contained in the water involved to the liter volume of "water” is ⁇ 0.034 mol/L; and adopt Impregnate the fiber material with water of not less than 70°C at least twice to remove the lignin/resin in the fiber; the flow direction of the gradually thickening brown/black liquor in the "water” flow is consistent with the flow direction of the fiber material in the production process The flow direction is countercurrent; or water-insoluble or poorly soluble substances are added as whisker additives, and the amount added accounts for 100 parts by weight of the absolute dry fiber in the main product A or its intermediate product, and is ⁇ 1 ⁇ 3 ⁇ 5 ⁇ 9 parts by weight parts by weight, either ⁇ 1 part by weight or ⁇ 3 parts by weight or ⁇ 5 parts by weight or ⁇ 9 parts by weight, implement low-ash whisker grafting/coating on the fiber surface; among the additives used, caustic alkali
  • Embodiment 3 The "by-product B--wood-plastic composite regenerated coarse particles" described in Embodiment 1 is more characterized by: the characteristics of "wood” are as follows: Example 3-1 or Example 3-1 and Example 3- 2, in which the characteristic of "plastic” is the following Example 3-3 or the combination of Example 3-3 and Example 3-4, and the product dosage form characteristics are the following Examples 3-5 to 3-8:
  • Example 3-1 The “wood” includes a part derived from energy grass: fine materials or/and crushed materials that pass through a 28-mesh sieve, or crushed materials mixed with coarse and fine materials that pass through a 3-mesh sieve;
  • Example 3-2 The "part” as described in 3-1 above is the dry basis weight of the "wood” containing 15% of equilibrium water after natural drying in the air, accounting for 5% of the total weight of by-product B. to 78% (wt%);
  • Example 3-3 The raw materials for “plastic” are all selected from waste plastics;
  • Example 3-4 The "waste plastics" as described in Example 3-3 above include at least any one or more combinations as described below: Miscellaneous waste plastic film residue discarded from waste paper recycling, including the "miscellaneous waste”"Plastic film residue” obtained by water flotation and floating plastic-containing materials or/and submerged plastic-containing materials; commercial plastic film waste packaging bags, cutting/punching edge materials, and waste composite plastic film materials in the production of plastic film packaging bags , trademark labeling student Plastic film composite release paper/film, waste aluminum-plastic composite film, and waste agricultural plastic film discarded during production/use; impurity-containing polymer fibers separated from broken tires, waste chemical fiber flannel removed from cars , waste chemical fiber carpets, waste chemical fiber fabrics, waste chemical fiber meltblown cloth, waste chemical fiber filter paper; waste wire plastic skins, waste plastic packaging tapes, waste plastic woven bags, waste geotextiles, waste/old plastic shoes, waste plastic flooring products , waste plastic toys, waste plastic barrels, waste plastic bottles, waste plastic geotextiles, waste/old plastic
  • Example 3-5 The dosage form of by-product B can be set to at least the first group of A, B, C, and D, or/and the second group of E, Ji, Geng, and Xin, or/and the third group of Ren and Gui. Group, you can choose any one or more of A to Gui in the first to third groups and mix them in any ratio to make the wood-plastic composite regenerated coarse-grained downstream plastic particles easily.
  • the total weight input of "wood” in A includes 76%, and the total weight input of waste plastics and softeners accounts for 24%;
  • the total weight input of "wood” in B is 35%, and the total weight input of waste plastics and softeners is 65%;
  • the total weight input of "wood” in C is 25%, and the total weight input of waste plastics and softeners is 75%;
  • the total weight input of "wood” in D is 5, and the total weight input of waste plastics and softeners is 95%;
  • the total weight input of "wood” in E includes 77%, and the total weight input of waste plastics and softeners accounts for 23%;
  • the update includes that the total weight input of "wood” accounts for 23%, and the total weight input of waste plastics and softeners accounts for 77%;
  • the total weight input of "wood” in Xin is 10, and the total weight input of waste plastics and softeners is 90%;
  • Example 3-6 Or as described in Example 3-5, "Add any one or more of A to Gui in the first to third groups to control the coarse particles in wood-plastic composite regenerated matter.
  • the total weight input of “wood” in the downstream plastic particles or products is in the range of 5% to 78%, and the total weight input of “plastic” and softener is in the range of 22% to 95%,
  • Example 3-5 The proportion of the total weight of "wood” in each of the feeding combinations of A to Gui in the "first group", “second group” and “third group” is proportional to the total weight of "plastic” and softener. The proportion can be determined according to the customization of market customers;
  • Example 3-7 The "Wood-Plastic Composite Regenerated Coarse Grain” is composed of materials according to the "First Group” or/and “Second Group” or/and “Third Group” mentioned in Example 3-5. "A to Gui components in the combined ingredients are fed, and after being processed by a coarse granulator, the texture is low-strength coarse granules that can be directly pulled/pulled/pinched/teared/grabbed by human fingers/palms, as described "Low strength” refers to at least the standard sample specimen of plastic with tensile strength ⁇ 3PMa;
  • Example 3-8 As mentioned in the above example 3-7, the "coarse granulator” specifically refers to any feed pellet machine, organic fertilizer granulator, or biomass fuel pellet machine with continuous feeding/discharging function. One, or a spiral granulator and intermediate crusher can be connected in series after the aforementioned "granulator”/"granulator”.
  • Example 4 For the preparation method of "main product A--hydrophilic decomposable fiber product" in the product set described in Example 1, please refer to Figure 13--10 steps for preparing "main product A--hydrophilic decomposable fiber”.
  • Step 1 - Pretreatment and preparation of materials First classify the energy grass dry materials, or further remove the metals or/and masonry blocks or/and bark impurities contained in the classified materials, and then The classified and impurity-free energy grass is then subjected to any one or more combinations of sawing/grinding/cutting/hammering, and then sieved; the crushed energy grass that passes through a 28-mesh sieve is discharged for further use;
  • backup energy grass crumbs prepared for step 2 are obtained.
  • This "backup energy grass crumbs” material is called natural absolutely dry material based on its naturally adsorbed equilibrium water content in the air of 15% (wt). ;
  • Step 2 First batching: Take 100 parts by weight of the natural dry material of the "Standby Energy Grass Crushed Material” obtained in Step 1, and mix in the "Second Solid-Liquid Separation" described in the subsequent Step 7.
  • the amount of water is Active agent: any one or combination of sodium butylnaphthalene sulfonate, sodium dodecylbenzene sulfonate, sodium lauryl sulfate, or/and coconut oil fatty acid diethanolamide, fatty alcohol polyoxyethylene Any one or a combination of multiple ethers; the "2x" corresponds to 100 parts by weight of the natural dry material of the energy grass saw crushed material: in the range of 25 to 50 to 300 parts by weight;
  • Step 3 Heating and dissolution: Add the aforementioned "100 parts by weight of the natural dry material of the 'Standby Energy Grass Crushed Material' material" and "the extruded water obtained from the 'second solid-liquid separation' described in the subsequent step 7": "2x parts by weight”, or "0.1 to 0.3% by weight of 'surfactant' of '2x parts by weight' of 'squeezed water'”, place these materials in a tank that can be stirred, mixed, heated and kept warm. During the process, the material is uniformly stirred and heated to above 70°C, and kept warm for at least 5 minutes, or sampled and analyzed. When the color of the extruded liquid no longer changes to a darker color, the heating and heat preservation operations can be stopped;
  • Step 4 The first solid-liquid separation: Introduce the material after the above "heating and heat preservation operations" into a screw or roller extruder, perform a mechanical kneading treatment on the fiber bundles of the material, and then knead it.
  • the materials are introduced into a solid-liquid separator for solid/liquid separation; or the materials after the above-mentioned heating and heat preservation operations are directly introduced into a solid-liquid separator for solid/liquid separation; thereby obtaining the "pressed/extruded brown” as described in Example 1. / black liquor", and the moisture material of the hydrophilic decomposed fiber intermediate product A to be treated, which has initially removed the water solute in the fiber;
  • the "pressed/extruded brown/black liquor” obtained is naturally separated from the hydrophilic decomposable fiber intermediate product A by the weight portion of the discharged brown/black liquor.
  • Step 5 - Second batching It is determined that the free water carried by 100 parts by weight of the natural dry material in the solid phase of the "moist material for the hydrophilic decomposable fiber intermediate product A" described in step 4 is x parts by weight. Then, take 100 parts by weight of the natural dry material contained in the "moist material of the hydrophilic decomposable fiber intermediate product A to be treated” and x parts by weight of free water, and then mix in the "third solidification step” described in the subsequent step ten.
  • the extruded water obtained by "liquid separation” is not less than: Add a whisker auxiliary.
  • the "whisker auxiliary" is at least any one of saturated aqueous calcium hydroxide solution, silica sol, etc., or/and newly generated calcium hydroxide, aluminum hydroxide, and hydrated silicon in the aqueous phase. Any one or combination of acids, calcium silicate, magnesium silicate, aluminum silicate, calcium carbonate, calcium sulfate dihydrate, ferric hydroxide, etc., or/and ultrafinely crushed to the point where it cannot be dissolved in water within half an hour. Any one or combination of kaolin, clay, fly ash, wollastonite, etc.
  • the "whisker additive" the amount added to 100 parts by weight of absolute dry fiber in the "moist material of hydrophilic decomposable fiber intermediate product A" is ⁇ 1 to 3 ⁇ 5 ⁇ 9 parts by weight, that is, the added amount is ⁇ 1 part by weight or ⁇ 3 parts by weight or ⁇ 5 parts by weight or ⁇ 9 parts by weight; mix the second ingredients described in step 5 in the mixing tank first, The materials are ready to be processed by high-concentration grinding;
  • Step 6 Grinding and latent elimination: Introduce the "materials to be processed into high-concentration grinding" obtained in step 5 into high-concentration grinding; or then use the heat to introduce the heat-generating materials from high-concentration grinding into a disinfection machine with heat preservation settings. Insulate or heat in a submersible tank, and let it stand at a temperature of no less than 70°C to relax the kinks and curls of the fibers produced during the high-concentration grinding process, and to dissolve the hydrophobic lipids in the fibers; After processing in step 6, the material after grinding or processing is obtained and is subject to solid-liquid separation;
  • Step 7 The second solid-liquid separation: Introduce the above-mentioned "material after grinding or processing” into a screw or roller squeezer, and then perform mechanical kneading treatment on the fiber bundles of the material, and then Then the material is introduced into the solid-liquid separator for solid/liquid separation; or mechanical softening is omitted, and the above-mentioned "materials after grinding or processing” are directly introduced into the solid-liquid separator for solid/liquid separation; thus, we get As described in the previous “Step 2", "the extruded water obtained from the 'second solid-liquid separation'" and the wet material of the hydrophilic decomposable fiber intermediate product B to be treated are finally washed with new water;
  • Step 8 - The third batching: It is determined that the free water carried by 100 parts by weight of the natural dry material in the solid phase of the "moist material of the hydrophilic decomposable fiber intermediate product B to be treated" described in step 7 is x parts by weight. Then, take 100 parts by weight of the natural dry material contained in the "moist material to be processed for the hydrophilic decomposable fiber intermediate product B" and x parts by weight of free water, and then mix in new water or a small amount of recycled water for decolorization and impurities.
  • any of calcium hydroxide, aluminum hydroxide, silica sol, etc., or/and newly generated calcium hydroxide, aluminum hydroxide, hydrated silicic acid, calcium silicate, magnesium silicate, aluminum silicate in the water phase any one or a combination of calcium carbonate, calcium sulfate dihydrate, ferric hydroxide, etc., or kaolin, clay, fly ash that has been ultrafinely pulverized to the point where it is difficult to naturally precipitate to a clear surface in water within half an hour. , any one or more combinations of wollastonite, etc., or any one or more combinations of kaolin, clay, fly ash, wollastonite, etc.
  • the "whisker additive” the added amount of 100 parts by weight of absolute dry fiber in the "moist material of hydrophilic decomposable fiber intermediate product B" is ⁇ 1 ⁇ 3 ⁇ 5 ⁇ 9 parts by weight, that is, the added amount is ⁇ 1 part by weight or ⁇ 3 parts by weight or ⁇ 5 parts by weight or ⁇ 9 parts by weight; add water and whisker additives according to the measurement in step eight to obtain the third batch of ingredients to be sent to step nine;
  • Step 9 Stirring and washing: Introduce the "third batching" of the above step 8 into the screw or roller extruder, and then perform mechanical kneading treatment on the fiber bundles of the material, and then introduce the material to be finalized.
  • the squeezed material is temporarily stored in a temporary storage tank; or the above-mentioned "third batching" is directly introduced into the mixer for stirring, so that the new water, or the moisture content of the solid-phase fiber mixed with the whisker additive and the hydrophilic decomposable fiber intermediate product B is The old water-containing material is fully mixed, and then the material is introduced into the temporary storage tank for the material to be finally squeezed dry; through the processing in step nine, the material to be sent to step ten to be finally squeezed dry is obtained;
  • Step 10 - The third solid-liquid separation or final modification: Introduce the "material to be finally squeezed dry" in the above-mentioned step 9 into the solid-liquid separator for solid/liquid separation; thus obtain the material as in the previous "step five"
  • the flow direction of the aqueous solution shown by the dotted line in Figure 13 is from the bottom of Figure 13 to upwards, and the direction of the fiber is from the top of Figure 13 to downwards.
  • the brown color in the water flow /The flow direction of black liquor and the direction of fiber are on the contrary, if the amount of water added as mentioned above and the dehydration amount of three solid-liquid separations are controlled well, the hydrophilic and decomposable fiber A product can be pressed/extruded in the hot water delignification/resin process.
  • Figure 1 is a black and white photo of the elongated fiber bundles of mulberry branch Ya, one of the mixed energy grasses with a particle size ranging from 3 mesh to no more than 28 mesh. It is made of mulberry branch Ya branches discarded from the sericulture industry and is sawed/ground/cut. / Mechanical crushing treatment of any or more combinations of hammers, and obtained after sieving, this "reduced elongated fiber bundles of mulberry branches and twigs with a particle size that has passed through a sieve of 3 mesh to less than 28 mesh” , generally accounting for at least 35% of the total "broken mulberry branches";
  • Figure 2 is a black and white photo of the elongated fiber bundles of rice straw, one of the mixed energy grasses with particle sizes ranging from 3 mesh to no more than 28 mesh.
  • the rice straw is shredded by a machine and screened.
  • the obtained "slender fiber bundle fragments of rice straw mixed with a particle size of not more than 3 mesh to no more than 28 mesh sieve" can generally account for more than 30% of the total "rice straw fragments";
  • Figure 3 is a black and white photo of a dry mass sample of hydrophilic decomposable fiber A-1, which is produced in the laboratory from peony straw, one of the energy grasses: follow the process of Figure 13, and finally squeeze and dehydrate by hand. , the wet material still containing 75% moisture is obtained after natural drying at room temperature. It can be seen from the photo: Although the fibers in the dry dough are thick and straight, the fibers are not as soft and bendy as traditional pulp fibers and often have bifurcations, but the thick and straight fibers are firmly in contact with each other. This can be seen from the material.
  • the aggregated group shape is not a form that can support the stable aggregation of such thick straight fibers and has a hard feeling when pinched by hand, and it is not in the shape of crumbs. It can be inferred that if the present invention uses a small amount of whisker additives, the whiskers It realizes the surface grafting/coating of the fiber, roughens the surface of the fiber, and then achieves the purpose of making the fiber in the water like Velcro to make the fiber collide or wind up smoothly to form a ball/paper.
  • the whisker additive used in "stirring in new water or regenerated water with decolorized impurities” is calcium hydroxide, that is, “Stir in new water or regenerated water with decolorized impurities” and "x parts by weight” to prepare a saturated aqueous solution of calcium hydroxide, and then perform the batching operation as in step 8 in Example 4.
  • the maximum dissolution constant of calcium hydroxide in 100g of water is 0.185g.
  • the sample in Figure 3 does not float when it enters the water.
  • Figure 4 is a black and white photo of a dry mass sample of hydrophilic decomposable fiber A-2, which is produced in the laboratory from Mulberry branch Ya, one of the energy grasses: follow the process of Figure 13, and finally squeeze and dehydrate by hand. First obtain the wet material that still contains 75% moisture, then press it tightly with your fingers to shape it in a disposable plastic cup, pour it out, and dry it naturally at room temperature. In the sample shown in Figure 4, the crystal The additive is wollastonite that has passed through a 320-mesh sieve. Add water to form a suspension with a solid content of no more than 20%.
  • Figure 5 is a paper sheet made from wheat straw, one of the energy grasses, which was made into hydrophilic and decomposable fiber A-2 in the laboratory. After natural drying, the paper sheet was folded and unfolded after being grasped only once. Black and white photo of the actual broken specimen.
  • the whisker solid material in the sample in Figure 5 is 100% of the absolute dry fiber in the final main product.
  • the maximum added amount is 3 ⁇ 3 parts by weight, which is ⁇ 9 parts by weight.
  • Embodiment 5 The co-production method of "main product A - hydrophilic decomposable fiber product” and "by-product C - lignin/resin mixture product” in the product set described in Example 1, the characteristics of which at least include: To co-produce A and C-1, you can first go through the steps of Example 5-1 or/and Example 5-2; or to co-produce A and C-2, you can go through the following Example 5-3 or/and Example 5-4 first. Or/and Example 5-5 steps; in the end, all are achieved by taking steps 5-6:
  • Example 5-1 Use fresh energy grass to remove the whole plant with roots and leaves or peel off the stem parts of the leaves, wash it with clean water, dehydrate and dry it, and then squeeze it into a juicer. It is better to control The moisture content of the residue after pressing is below 20% (wt%), and the liquid squeezed out is the by-product material 2 described in item ii in Example 2 - "fresh energy grass washed with water first and then pressed "The obtained fresh juice”; or this "fresh juice” can be heated to 100-105°C for 3-5 minutes, cooled, and canned to obtain a liquid black brown edible or medical grade lignin/resin mixture product C -1; If the "fresh juice” is subjected to an evaporation and concentration operation while heating, then under the control process parameters of controlling the amount of steamed water, the steamed and concentrated material of the "fresh juice” can be cooled to At room temperature, edible or medical grade lignin/resin mixture product C-1 can be in the form of a paste-like tan
  • Example 5-2 Use the whole plant with roots and leaves or remove the stem part of the leaves from the sun-dried or naturally dried energy grass, or use the energy grass dry material to remove it through crushing and sieving. After sieving the coarse material into fine powder with a 28-mesh mesh, wash it with clean water. You can add water ranging from 0.7 to 5.7 times the weight of the dry material, heat it to 70°C or even boil it, and then press it into a juicer. It is better to control the pressing. The moisture content of the final slag is below 20% (wt%), and the liquid squeezed out is the by-product material 2 described in item ii in Example 2 - "dry energy grass is washed with water and then boiled and pressed.
  • Example 5-3 Use fresh energy grass wet material, the whole plant with roots and leaves removed or the stem part with the leaves removed, and then put it into a juicer for squeezing. It is better to control the moisture content of the slag after squeezing.
  • the liquid squeezed out is either the by-product material 2 described in item ii of Example 2 - "fresh energy grass” and “fresh juice obtained by pressing”; or the “fresh juice obtained by pressing”;
  • “Juice” is heated to 100 ⁇ 105°C for 3 ⁇ 5 minutes, cooled and canned to obtain a liquid black brown feed or industrial grade lignin/resin mixture product C-2; if it is heated at the same time, then " “Fresh juice” is subjected to an evaporation and concentration operation, and under the control of process parameters that control the amount of steamed water, the steamed and concentrated material of "fresh juice” can be turned into a brown paste-like colloid when cooled to room temperature. Or feed or industrial grade lignin/resin mixture product C-2 in the form of brown powder or granules, or rosin-like solid blocks;
  • Example 5-4 Use the whole plant with roots and leaves removed from the energy grass that has been sun-dried or naturally dried or oven-dried, or use the stem material with the leaves removed, or use the dry energy grass material that has only been crushed and screened. After removing the coarse material from the 28-mesh sieve, you can add 0.7 to 5.7 times the weight of the dry material with clean water, heat it to 70°C or even boil it, and then press it into a juicer. It is better to control the content of the residue after pressing.
  • the water content is below 20% (wt%), and the liquid squeezed out is the by-product material 1 described in item ii in Example 2 - the brown/black liquor discharged from the hot water delignification/resin process; or the " “Brown/Black Liquor” is heated to 100-105°C for 3-5 minutes, cooled, and canned to obtain a liquid black brown feed or industrial-grade lignin/resin mixture product C-2; if heated at the same time, Then the "brown/black liquor” is subjected to an evaporation and concentration operation, and under the control of process parameters that control the amount of steamed water, the "brown/black liquor” can be evaporated and concentrated, and then when cooled to room temperature, it can be presented as noodles. Feed or industrial grade lignin/resin mixture product C-2 in the form of paste-like brown colloid, or coffee-colored powder or granules, or rosin-like solid block;
  • Example 5-5 Collect the water removed after "washing with clean water” as described in the above Example 5-1 or/and Example 5-2, use this water to wash the cow dung, and remove the 28-mesh sieve Impurities, pick up the crude fiber that has not passed 28 sieves after being washed with water, boil it to kill the cellulolytic enzymes in it, and then put it into a juicer for squeezing. It is better to control the squeezing.
  • the moisture content of the final residue is below 20% (wt%), and the liquid squeezed out is the by-product material 1 described in item ii in Example 2 - the brown/black liquor discharged from the hot water delignification/resin process.
  • Feed or industrial grade lignin/resin mixture product C-2 which can be in the form of a paste-like tan colloid, or a coffee-colored powder or granules, or a rosin-like solid block; washed/washed cow dung
  • the washed/washing liquid discharged after treatment which is the "by-product material 3" described in item ii of Example 2, can be used as direct irrigation water for fertilizer-resistant and water-consuming giant fungus grass, etc.;
  • Example 5-6 The slag described in the aforementioned Examples 5-1 to 5-5 "It is better to control the moisture content of the slag after pressing to be below 20% (wt%)" can be soaked into water containing Consolidate 25% of the loose floss-like material, sieve out the particle size classification or mixed elongated fiber bundles ranging from 3 mesh to 28 mesh, and obtain the fiber bundle described in step 4 of Example 4.
  • the moisture material to be treated as the hydrophilic decomposable fiber intermediate product A after initially removing the water solute in the fiber can be followed by the fifth to tenth steps in Example 4, and finally the hydrophilic decomposable fiber product A can be obtained -1 or A-2; the water containing cow dung produced by "washing cow dung” and “washing and sifting with water” described in the aforementioned 5-5 is the same as item ii in Example 2.
  • the above-mentioned "by-product material 3: washing/washing liquid produced by washing/washing cow dung” can be directed to be one of the ingredients of the "auxiliary product E--liquid organic soil conditioner" described in Example 1.
  • Figure 6 is a black and white photo of by-product C-2 - feed or industrial grade lignin/resin mixture, which can be formulated as feed additives, plant nutrients, or used as rubber/plastic additives, etc. It is used
  • the brown/black liquor discharged from the hot water delignification/resin process in the production of hydrophilic decomposable fiber A is directly evaporated in a beaker on an electric stove in the laboratory, dehydrated and concentrated to dryness.
  • Embodiment 6 The preparation method of "B--wood-plastic composite recycled coarse-grained product" in the product set described in Embodiment 1 is characterized by the following Examples 6-1 to 6-6:
  • Example 6-1 Material preparation: For any one of Example 5-1 to Example 5-5 in Example 5, “It is better to control the moisture content of the residue after pressing to be below 20% (wt%)" The slag is used as the “wood” material in “wood-plastic composite recycled material coarse particles”;
  • Fiber powder the "materials with more nutrients", in terms of measurement, are materials that cannot withstand the mechanical crushing force and are more finely crushed after being crushed or cut into pieces once, and pass through a sieve ranging from 28 to no more than 150 mesh.
  • Example 6-2 Ingredients: According to the composition of the "wood-plastic composite recycled coarse particles" described in Example 3-4 or Example 3-5 in Example 3, "wood", “plastic” and softener are included in the total weight of the product. The proportion of feeding materials and weighing the ingredients;
  • Example 6-3 Granulation: The materials prepared by the scale are passed through the mixing and collecting bin, then transported by machinery, and put into the "coarse granulator” described in Examples 3-7 and 3-8 in Example 3.
  • "Medium granulation; the machinery used in the "coarse granulator” is: any one of a feed pellet machine, an organic fertilizer granulator, a biomass fuel pellet machine with continuous feeding/discharging functions, or After the aforementioned "granulator”/"granulator", a spiral granulator and a secondary crusher are connected in series; the aforementioned “granulator”/”granulator” discharges the material in the form of segmented granules formed by the through-hole mold.
  • the materials will appear as irregular particles when they are discharged from the machine; the materials during granulation are heated by mechanical extrusion/friction and can be used Add water to the material or/and the interlayer in the machine to control the outgoing material to not exceed 110°C; the "coarse wood-plastic composite recycled material” produced by this operation has a texture that can be directly pulled by human fingers/palms / pull / pinch / tear into pieces of low strength; its granulated shape at least includes segmented granules or irregular particles formed by the through-hole mold; the hole shape of the "hole mold” includes at least equilateral or irregular Any of 3 to 12 sides with equal sides, or a circle; the size of the "grain” is classified or mixed in any aperture ranging from 25mm to less than 2.0mm mesh;
  • Example 6-4 Homogenization and mixing: If the "wood-plastic composite recycled coarse particles" obtained in Example 6-3 have obvious quality defects such as inhomogeneous packaging after subsequent packaging, they can be weighed before packaging. Add a mixing and homogenizing process. The process is to use a mechanical roller to introduce the "wood-plastic composite recycled coarse particles” obtained in Example 5-3, and tumble and mix evenly;
  • Example 6-5 Weighing and packaging: The "Wood Plastic Composite Regenerated Coarse Granules" obtained in Example 6-3 or/and Example 6-4 that meet the quality requirements are weighed and then introduced into packaging bags with specifications approved by market customers. middle;
  • Example 6-6 Inbound quality inspection: Put the packaged products into the warehouse in order, and provide quality inspection reports for each batch of incoming products for archiving according to the indicators that market customers need to know.
  • Figure 7 is a black-and-white photo of plastic film materials discarded from recycled pulp made from waste paper. It contains impurities such as aluminum-plastic composite molds. This is the most difficult to be greened among mixed waste plastics. It is a type of continuous reuse that our country has banned the import of foreign waste paper because of the problem of waste plastic recycling pollution.
  • Figure 8 is a black and white photo of wood-plastic composite recycled coarse grain B, which is made of the "miscellaneous" material shown in Figure 7.
  • "Waste plastic film material” is mixed with energy grass crumbs passed through a 28-mesh sieve, or with "C-2" described in Example 5-3 to Example 5-5 in Example 5, and then the current common biomass granule production process is used. Produced by granulator.
  • Embodiment 7 The preparation method of "auxiliary products" D to I in the product set described in Embodiment 1, which is characterized by the following:
  • Example 7-1 The preparation method of "auxiliary product D - solid organic soil conditioner product" described in Example 1 is at least characterized by: using energy grass, or energy grass and cow dung as the starting main raw materials, using extraction The remaining materials after preparing the raw materials for main product A, namely energy grass powder or fine cow dung sediment that has passed through a 28-mesh sieve, are used as one of the ingredients in "auxiliary product D";
  • Example 7-2 The preparation method of "auxiliary product E--liquid organic soil conditioner product" described in Example 1, is at least characterized in that: energy grass, or energy grass and cow dung are used as the starting main raw materials.
  • main product A - hydrophilic decomposable fiber product and “by-product C - lignin/resin mixture product”
  • the pressing liquid or/and washing liquid or/and elutriation discharged from the upgraded products A and C liquid
  • the liquid organic soil conditioner product obtained by blending the "pressed liquid or/and washing liquid or/and elutriation liquid” according to the soil improvement requirements of the crops and plots to be applied;
  • the pH value of the discharged pressing liquid or/and washing liquid or/and elutriation liquid does not exceed the range of 5.0 to 9.4, and the gram mole of Na + or/and K + or/and Mg 2+ contained therein is equal to that of the The ratio of water to liter volume is ⁇ 0.034mol/L, or the total wt% concentration
  • the difference between the total concentration of potassium salt and magnesium salt and the total concentration of soluble sodium salt, potassium salt and magnesium salt in the water source taken from the production site is ⁇ 0.01% (wt%); the weight ratio of auxiliary product E to main product A Controlled within the range of product E/product A ⁇ 100/100 ⁇ 300/100, that is, ⁇ 100/100 or ⁇ 300/100;
  • Example 7-3 The preparation method of "auxiliary product F - fermented feed product" described in Example 1, which is at least characterized in that: the "by-product material 1: hot water delignification/ "Brown/black liquor discharged from the resin process” or/and "or by-product material 2: The fresh juice obtained by squeezing the fresh energy grass will be mixed with the energy grass that has only been broken/crushed, and then fermented to obtain auxiliary materials Product F;
  • Example 7-4 The preparation method of "auxiliary product G - pellet feed product" described in Example 1 is at least characterized in that: when using dry energy grass that has not been pressed as the starting main raw material, sieved The remaining materials after using the raw materials for the main product A are "fine powder passed through a 28 mesh sieve", or/and "energy grass fiber powder with a small soil content and a medium particle size passed through a 28 to less than 150 mesh sieve", as Ingredients in pellet feed products;
  • Example 7-5 The preparation method of "auxiliary product H--biomass pellet fuel product" described in Example 1 is at least characterized in that: the energy grass is crushed and sieved to remove crude fibers that have not passed the 28-mesh sieve. Fine powder, or full-component energy grass pulverization as ingredients, or biomass pellet fuel products added with waste plastics; the "waste plastics” include at least waste agricultural plastic films and waste foam Any one or more combinations of plastics, waste chemical fiber fabrics or/and chemical fiber wadding, the "addition” mentioned above accounts for less than 5% of the total weight of the auxiliary product H, or can be as high as no more than 22%;
  • Example 7-6 The preparation method of "auxiliary product I - edible fungus planting stick/block product" described in Example 1 is at least characterized in that: when energy grass, or energy grass and cow dung are used as the starting main raw materials, The remaining material after sifting out the raw materials for the main product A is the energy grass powder or fine cow dung sediment that has passed through a 28-mesh sieve, and is used as an ingredient in the edible fungus planting stick/block product.
  • Embodiment 8 For the equipment used in the "preparation method" described in Embodiments 4 to 7, please refer to Figure 14 - a block diagram of the flow of process equipment used in the production method of the product set of the present invention. It is also characterized by the following Examples 8-1 to 8-4 or as described in Example 8-5:
  • Example 8-1 Implementing "Step 1" to “Step 10" described in Example 4 involves setting up combined machinery I to X. Please refer to the ⁇ block surrounded by " ⁇ -" in Figure 14, which includes:
  • a crushing machine 1 any one or more combination crushers 2 of saw/mill/cut/hammer
  • Air separation machinery 3 and mechanical screening 4 are used to process the energy straw bundles through any one or more combinations of crushers, saws/mills/cuts/hammers, and then through air selection and screening.
  • the combined machine II for the "first batching" of the "Step 2" described in Embodiment 4 at least includes: a batching bin 6 for placing the “backup energy grass crumbs", containing the "first batching” described in the subsequent Step 7.
  • "Extruded water obtained from the 'second solid-liquid separation' described in the subsequent step seven”: “2x parts by weight” , or with "0.1 to 0.3% by weight of 'surfactant' of 'extruded water' '2x parts by weight'” place these materials in a tank 11 that can be stirred, mixed, heated and insulated, and the materials Implement uniform stirring and heating to above 70°C, and keep warm;
  • the combined machinery IV for the "first solid-liquid separation” of "Step 4" described in Embodiment 4 at least includes: a conveying machine 12, a screw or roller squeezer 13, and a solid-liquid separator 14, Storage tank 15 for storing the "pressed/extruded brown/black liquor” obtained from the "first solid-liquid separation”; with the mechanical settings of 12, 13, 14, and 15, the steps described in step 4 of Example 4 are realized.
  • the material after heating and heat preservation operations is introduced into a screw or roller extruder, and the fiber bundles of the material are mechanically kneaded by crushing and extrusion, and then the material is introduced into a solid-liquid separator for solid/liquid separation.” Or directly introduce the materials after the above heating and heat preservation operations into the solid-liquid separator for solid/liquid separation”;
  • the combined machine V for the "second batching" of the "step five” described in Example 4 at least includes: a storage bin 16 for placing the "moist material of the hydrophilic decomposable fiber intermediate product A to be processed".
  • the mixing stirrer 20 after “the second batching”; thus, the mechanical settings of 16, 17, 18, 19, and 20 realize the mechanized operation of "Step 5" in Embodiment 4;
  • the material storage bin 22 is provided with a conveying mechanism or conveying machinery 23 between the storage bin 22 and the high-consistency refiner 21; after the outlet of the high-consistency refiner 21, a heat preservation or heating function is provided
  • the submersion elimination tank 24 is provided with a conveying mechanism or conveying machinery 25 between the outlet of the high-consistency refiner 21 and the feed inlet of the submersion elimination tank 24; thus, the machinery of 21, 22, 23, 24, 25 Set up to realize the mechanized operation of "Step 6" in Embodiment 4;
  • the combined machinery VII for the "second solid-liquid separation” of "Step 7" in Embodiment 4 at least includes: a conveying machine 26, a screw or roller squeezer 27, and a solid-liquid separator 28,
  • Example 4 Use the combined machine VIII for the "third batching" of "Step 8" described in Example 4, which at least includes: setting up and storing the moisture of the "hydrophilic decomposable fiber intermediate product B to be treated” described in Step 7 of Example 4.
  • the combined machine IX for "stirring and washing” of "Step 9" described in Embodiment 4 at least includes: a conveying mechanism or conveying machine 34, screw or roller extruder is provided after the aforementioned "stirring and mixing tank 33" Pulp machine 35, material temporary storage tank 36; from this, the mechanical settings of 34, 35, 36 realize the process purpose described in step nine in Example 4: introduce the "'third batching'" into the screw or roller squeezer , the fiber bundles of the material are mechanically kneaded by crushing and extrusion, and then the material is introduced into the temporary storage tank for the material to be finally squeezed dry; or the above-mentioned 'third batching' is directly introduced into the mixer for mixing, so that the new water and The old water originally contained in the moisture solid phase fiber of the hydrophilic decomposable fiber intermediate product B is fully mixed, and then Introduce the material into the temporary storage tank for the material to be finally squeezed out";
  • Example 8-2 The equipment used in implementing the "joint production method" described in Example 5 involves setting up combined machinery XI to XIII. Please refer to XI in the ⁇ block surrounded by " ⁇ -" in Figure 14. to XIII, including:
  • the combined machinery XI used in the "co-production of A and C-1" described in Example 5-1 and Example 5-2 in Example 5 includes at least: the specific preparation method described in Example 5-1 in Example 5.
  • the press 43 for squeezing and extracting juice from "grass” is equipped with a storage tank 44 for storing the fresh juice of the grass, which is the energy source of the squeeze, or a distillation kettle 45 for heating the fresh juice to boiling or evaporation and concentration, and a cooling and canning machine 46;
  • a storage tank 44 for storing the fresh juice of the grass which is the energy source of the squeeze, or a distillation kettle 45 for heating the fresh juice to boiling or evaporation and concentration, and a cooling and canning machine 46;
  • Through the settings 41, 42, 43, 44, 45, and 46 it is possible to extract
  • lignin/resin mixture by-product C-1 which can be in the form of a paste-like tan colloid, or a coffee-colored powder or granule, or a rosin-like solid block;
  • an operating machine 47 for removing roots and blades of dry energy grass is provided, or a combined machine for crushing and screening the dry energy grass material is provided.
  • 48. Set up a cleaning machine 49 for washing and dehydrating the dry energy grass.
  • the "energy grass juice” is also the by-product material 2 described in item ii of Example 2 - "the juice obtained by washing the dry energy grass with water and then boiling and pressing it”; or it can be set again
  • the "energy grass juice” is heated to boiling or evaporated to concentrate the distillation kettle 52, and a cooling and canning machine 53 is installed; through the 47, 48, 49, 50, 51, 52, 53 set up here, the energy grass is dried, After removing roots, removing leaves, crushing, sifting, washing, dehydrating, soaking in hot water, pressing to extract juice, and then heating and sterilizing, evaporating and thickening, cooling, filling, or mechanical processing until heating and evaporation to dryness, the product can be obtained.
  • Edible or medical grade lignin/resin mixture by-product C-1 in the form of pasta-like tan colloid, coffee-colored powder or granules, or rosin-like solid block;
  • Method set up an operating machine 54 for removing roots and stripping leaves of fresh energy grass, set up a press 55 for pressing and extracting juice from fresh energy grass, set up a storage tank 56 for storing the fresh juice of pressed energy grass, or set up another
  • the fresh juice is heated to boiling or evaporated and concentrated in the distillation kettle 57, and cooling and canning machinery 58 are set up; through the 54, 55, 56, 57, 58 set up here, the fresh juice can be obtained from the fresh juice through root removal, leaf removal, Press and extract the juice, then heat and sterilize, evaporate and concentrate, cool, fill, or mechanically process until it is heated and evaporated to dryness to obtain a tan colloid in the form of a paste, or a coffee-colored powder or granule, or a rosin-like solid.
  • an operating machine 59 for removing roots and blades from the dry energy grass is provided, or a combined machine 60 for crushing and screening the dry energy grass material is provided.
  • a combined machine 61 that can add water, heat to boiling, and then perform juice extraction, and is provided with a storage tank 62 for storing the squeezed energy grass juice.
  • the "energy grass juice” is also the item ii in Embodiment 2.
  • the above-mentioned by-product material 1--the brown/black liquor discharged from the hot water delignification/resin process; or a distillation kettle 63 for heating the "energy grass juice” to boiling or evaporation and concentration, and cooling and canning is provided.
  • a storage tank 65 is provided for storing the dewatered water after "cleaning" the energy grass in the combined machine XI, and a storage tank 65 is provided.
  • the "energy grass juice” is also the by-product material 1 described in item ii of Example 2 - the brown/black liquor discharged from the hot water delignification/resin process; or the "energy grass juice” is heated to
  • the distillation kettle 69 for boiling or evaporation concentration is equipped with cooling and canning machinery 70; through the 65, 66, 67, 68, 69, 70 set up here, the cow dung can be washed, screened, soaked in hot water, and pressed.
  • Juice then heated and sterilized, evaporated and concentrated, cooled, filled, or mechanically processed until heated and evaporated to dryness, to obtain a tan colloid in the form of a paste, or a coffee-colored powder or granules, or a rosin-like solid block.
  • the combined machine XIII used in the details of "can be walked again” and “can be guided later" described in Example 5-6 of Embodiment 5 at least includes: setting up a classification collection bin 71 to collect the combined machine XI, XII
  • the energy grass or cow dung exported is "pressed and dregs out”;
  • a combined mixing and heating machine 72 is provided to bubble the aforementioned "pressed dregs” into a loose floss-like material with a solid content of 25%;
  • Mechanical sieve 73 is used to sift out the elongated fiber bundles in the particle size classification or mixing range of the foamed material that have a size ranging from 3 mesh to no more than 28 mesh sieve holes; it is set to collect the particle size ranging from 3 mesh to no more than 28 mesh sieve holes.
  • the produced water containing cow dung is the "by-product material 3: the washing/washing liquid produced by washing/washing cow dung" described in item ii in Example 2, and can subsequently be directed to be used as in Example 1.
  • Example 8-3 The equipment used to perform the "preparation method" of "B" described in Example 6 involves setting up sub-assembly machines XIV to XVII. Please refer to the area surrounded by " ⁇ -" in Figure 14 XIV to XVII in the block, including:
  • Example 6 Set up the "ingredients" sub-assembly device XV of Example 6-2 in Example 6, which also includes: a weighing scale 80, respectively storing "wood” and “plastic” in the composition of the "wood-plastic composite recycled material coarse particles”. ” and softener storage bin 81, and mixing tank 82 after metering and batching;
  • Example 6 Set up the "granulation" sub-assembly device XVI of Example 6-3 in Example 6, which also includes: a conveying machine 83 and a coarse granulator 84;
  • Example 6 Set up the "homogenizing mixing” and "weighing packaging" sub-assembly devices XVII of Examples 6-4 to 6-5 in Example 6, which further include: a homogenizing mixing machine 85 and a weighing and packaging machine 86;
  • Example 8-4 The equipment used to implement the "manufacturing method" of the "auxiliary products” described in Example 7 involves setting up sub-assembly machines XVIII to IIIII. Please refer to the ⁇ surrounded by " ⁇ -" in Figure 14. XVIII to IIIII in the block, including:
  • auxiliary product D--solid organic soil conditioner in Example 7, which is characterized in that: it includes a set of assembly devices 87 for preparing solid organic soil conditioner;
  • assembly devices 87 for preparing solid organic soil conditioner;
  • the remaining materials after extracting the raw materials for making the main product A are used, which are energy grass powder or fine cattle that have passed through a 28-mesh sieve.
  • Fecal sediment used as an ingredient in "auxiliary product D" for technological purposes;
  • auxiliary product E--liquid organic soil conditioner product in Example 7, which is characterized in that: it includes a set of assembly devices 88 for preparing liquid organic soil conditioner product ;
  • Example 7 Set up the sub-assembly device II X used in the preparation method of Example 7-3 "auxiliary product F--fermented feed" in Example 7, which is characterized in that: it includes a set of assembly devices 89 for preparing fermented feed products; to realize the use of Embodiment 2 The purpose of the process of adding "by-product material 1" or/and “or by-product material 2" mentioned in item ii to the energy grass that has only been broken/pulverized and then fermenting it to obtain auxiliary product F;
  • Example 7 Set up the sub-assembly device II used in the preparation method of Example 7-4 "auxiliary product G--pellet feed” in Example 7, which is characterized in that: it includes a set of assembly devices 90 for preparing pellet feed products; to achieve sifting out
  • the remaining materials after using the raw materials for the main product A are "fine powder passed through a 28 mesh sieve", or/and "energy grass fiber powder with a small soil content and a medium particle size passed through a 28 to less than 150 mesh sieve", The technological purpose as an ingredient in pellet feed products;
  • auxiliary product H--biomass pellet fuel in Example 7, which is characterized in that: it includes a set of assembly devices 91 for preparing biomass pellet fuel products; to achieve "The energy grass is crushed and sieved to remove the coarse fiber that has not passed the 28-mesh sieve to remove the fine powder, or the full-component energy grass crushing material is used as the ingredient, or waste plastic is added.”
  • Example 7 Set up the sub-assembly device II III used in the preparation method of Example 7-6 "auxiliary product H--biomass pellet fuel" in Example 7, which is characterized in that: it includes a set of assembly device 92 for preparing edible fungus planting rods/block products; In order to realize "using energy grass, or energy grass and cow dung as the starting main raw materials, the remaining material after sifting out the raw materials for the main product A is the energy grass powder or fine cow dung that has passed through a 28-mesh sieve. Fecal sediment, as an ingredient component in edible fungus planting sticks/block products” process purpose;
  • Example 8-5 each of the machine units 1 to 88 described in the previous Examples 8-1 to 8-4 can be arranged neatly into a standard container.
  • Example 9 Introducing a standard sample for comparison and various comparisons between this standard sample and hydrophilic decomposable fiber A. Please refer to the attached figures 9 to 12:
  • Figure 9 is a black and white photo of a dry mass standard sample. It is made of willow dung, commonly known as willow dung by orchid planting enthusiasts - beetle larvae or wood beetle moth larvae that eat the willow stems. The dung is screened in the laboratory to remove particles larger than Impurities of 3 mesh and finer than 28 mesh are boiled in water to eliminate enzymes, then dehydrated but still containing 75% moisture by hand, pressed tightly into a disposable plastic cup, poured out, and kept at room temperature.
  • willow dung commonly known as willow dung by orchid planting enthusiasts - beetle larvae or wood beetle moth larvae that eat the willow stems.
  • the dung is screened in the laboratory to remove particles larger than Impurities of 3 mesh and finer than 28 mesh are boiled in water to eliminate enzymes, then dehydrated but still containing 75% moisture by hand, pressed tightly into a disposable plastic cup, poured out, and kept at room temperature.
  • this standard sample is pinched or compared with the dry mass of the hydrophilic decomposable fiber A sample of the present invention, and it can be qualitatively determined that the hydrophilic decomposable fiber A of the present invention is different from the standard sample.
  • the relative hardness of the sample, or the physical properties such as the intertwining and interlocking strength of the tested sample fibers, can then be used to see the practicability of the hydrophilic and decomposable fiber of the present invention.
  • the color of the standard sample in Figure 9 is brown.
  • Figure 10 is the "standard sample” described in Figure 9, which is a black-and-white photo of the accumulation on the ground under a willow tree in nature.
  • the white on the grass and leaves at the base of the willow tree trunk is "willow dung", and its real color is brown.
  • Figure 11 is a black and white photo of what the "standard sample” described in Figures 9 and 10 looks like when it is collected in the laboratory and has not been screened or processed. Its true color is brown.
  • the standard sample shown in Figures 9 to 11 above - commonly known as willow manure is a typical fiber that has been digested and degraded by enzymes in the digestive tract of wood-eating insects that can decompose cellulose/resin nutrients in wood; in the industry Technical personnel can know that wood fiber can be enzymatically produced into pulp; the dry dough standard sample shown in Figure 9 only needs to use a wooden stick hammer such as that used in ancient papermaking to beat the moisture material of this standard sample to produce Using paper pulp, you can make ordinary kraft paper or rough paper for calligraphy that are commonly seen on the market.
  • the material hardness of the dry mass of hydrophilic and decomposable fiber A-1 is lower than that of the standard sample
  • the material hardness of the dry mass of hydrophilic decomposable fiber A-2 is lower than that of the standard sample. After rubbing it with the standard sample for at least 10 times, comparing the amount of damage caused by the rubbing of the two samples, it can be seen that: Equivalent to the standard sample, or no more than 5% of the missing amount of the standard sample times.
  • the "energy grass crushed material" proposed by the present invention can also achieve the same effect as the present invention in the production water involved without inorganic soluble salts in the water, but the reduction is as described in item ii of Example 2.
  • the "brown/black liquor”, its weight part W brown/black liquor , and the weight part W A of the absolute dry fiber containing no more than 15% water in the main product A is W brown/black liquor /W A " In terms of reduction, there is no feature superior to the present invention; and the process operation after inoculating the material with enzyme is obviously more troublesome than the present invention, and the softening and grinding operations of the fiber cannot be significantly reduced. .
  • the dry dough standard sample of Example 9 is used for quality inspection. If the technical solution proposed by the present invention is industrialized and market customers want to improve their standards, the fibers of the standard sample can be finely divided to make the standard sample The strength increases; if you want to lower the standard, you can increase the number of fallen chips to "not more than the number of chips dropped by the standard sample" after rubbing the tested sample and the standard sample at least 10 times. In order to identify the color difference of the scraps dropped when the sample to be tested is rubbed against the standard sample, the standard sample can also be dyed with blue ink and other color liquids. The shape of the mass of the standard sample and the sample to be tested can also break through the constraints of Figures 3, 4, and 9. However, when comparing dry mass materials by pinching and rubbing, it is more fair and reasonable to use the same or similar surface contact.
  • Embodiment 10 The uses of the "product” or/and “preparation method” or/and “equipment” described in embodiments 1 to 8, at least include any one or a combination of more of the following:
  • Example 10-1 The "Main Product A - Hydrophilic Decomposable Fiber" described in Examples 1 and 2 can be used at least to prepare seedling paper, corrugated paper, cardboard, or/and include egg trays and convenient dinner plates/ It can be used as an alternative material to partially or completely replace waste paper recycled pulp in paper molded products such as bowls, paper seedling pots/bowls, etc.; it can also be used as a new starting material for further processing, such as making bleached pulp; Or as raw material for preparing cellulose ether;
  • Example 10-2 The "by-product B - wood plastic composite recycled coarse particles" described in Examples 1 and 3 can be used at least as wood plastic particles to be modified or/and used for hot extrusion of wood plastic products. Refined raw materials, or directly used as a new formulation raw material for hot-extruded wood-plastic products, or as a granular fuel for heating;
  • Example 10-3 The "by-product C-1 - edible or medical grade lignin/resin mixture" described in Example 1 can be used at least as a raw material for preparing beverages or/and traditional Chinese medicine preparations;
  • Example 10-4 The "by-product C-2--feed or industrial grade lignin/resin mixture" described in Example 1 can be used at least as a feed raw material, or/and as a water-reducing agent for concrete. Any softener in rubber/plastic;
  • Example 10-5 The "products”, “preparation methods” and “equipment” described in Examples 1 to 8 can at least be used to prepare the "raw materials” described in Item 1 of Technical Solution 2 including Giant Juncao, etc. "Processing; or be expanded to the processing of bamboo, sugar cane bark, palm oil fruit bunch branches, etc.;
  • Example 10-6 The "products”, “production methods” and “equipment” described in Examples 1 to 8 can all become independent commodities.
  • Embodiment 11 The business operation model of the "product” or/and “preparation method” described in any one or more of Embodiments 1 to 9, at least including any one or a combination of the following:
  • Example 11-1 A company can independently implement the commercial operations of “products” or/and “manufacturing methods”;
  • Example 11-2 Multiple companies can divide “product” varieties, or/and segment “manufacturing” processes to collaboratively implement commercial operations;
  • Example 11-3 The business model of self-operated or outsourced manufacturing can be used to implement the commercial operation of "products” or/and “manufacturing methods";
  • Example 10-4 The commercial operation described in Example 10-4 uses agricultural products including solid/liquid organic soil conditioners, and barters energy grasses including straw from grain, cotton and oil fields with farmers or farming operators.
  • the positive significance of the present invention is at least:
  • the present invention provides a collection of cleaning products and a manufacturing method using energy grass as raw materials.
  • the "product collection” consists of main product A, Or the main product A is combined with any one or two of the by-products B and C, or the main product A is combined with the by-product B/C, and then is combined with any of the auxiliary products D, E, F, G, H, and I. It consists of a combination of one or more products; secondly, it provides a method for making the proposed "product set".
  • the positive meaning contained in the main product A of the present invention is at least that: some grain, cotton, oil and other crops that produce huge amounts of straw or branches are also classified into the upper code name of energy grass, and then all use energy grass as the upper code name. Name, the introduction is based on the aforementioned "energy grass, or energy grass and cow dung", which are crushed by any or more combinations of sawing/milling/cutting/hammering and then sieved to obtain the range of "passing 3 mesh to not passing 28 mesh” The slender fiber bundles of any mesh size are classified or mixed with particle sizes, and the main product A-hydrophilic decomposable fiber is prepared through cleaning.
  • the total content of one or more species is 0. This is the green utilization of “brown/black liquor” resources that contain no more than 3 tons of dissolved salt and are harmless to vegetation per ton of main product A, and leads to the green utilization of “brown/black liquor” resources in this industry. siltation bottleneck.
  • the "product set” provided by the present invention surrounds the main product A - hydrophilic decomposable fiber, and sets two strains of by-products B, C, or/and auxiliary products D, E, F, G, H, and I. Combination walls.
  • the positive significance of this "strain combination wall" is that around the core main product A, two lines of defense are set up to absorb various "waste" discharged in the process of preparing A, and can jointly integrate the main production Miscellaneous plastic waste and/or livestock and poultry manure surrounding the implementation site of Product A are also captured and collaboratively used for green resource utilization.
  • the main product A of the present invention has a small amount of “brown/black liquor” discharged during the production process and is harmless to vegetation, which makes it possible for the industrial implementation of the present invention to be carried out in areas near fields; Since it can be implemented near field areas, it also brings the possibility of obtaining energy grass materials with low transportation costs, including grain, cotton, and oil field straw.
  • This also includes the use of auxiliary products D-solid organic soil improvement.
  • the agent, or/and the auxiliary product E-liquid organic soil conditioner can also be used to obtain energy grass materials such as straw and other energy grass materials through barter with farmers nearby at low cost.
  • Carbon dioxide is fixed into the straw by grain, cotton, and oil crops, and the straw is made into a collection of products A, B, C, D, E, F, G, H, and I, and finally is buried in the field without hindrance. But it is a good way to solve the problem of field failure year after year due to only applying organic fertilizer for many years. If this method is used to plant sea rice and giant rice in saline-alkali land, the saline-alkali land that is seriously lacking in organic matter will mature faster and become fertile land.
  • the by-product C-1 obtained is a type a-1 technological innovation, which is a type of technological innovation such as the use of Juicyrus gigantea stalks to squeeze juice into beverages. raw material products for application; from a practical point of view, it can save the downstream enterprises of various uses from having to develop raw materials. All the troubles of starting a product.
  • Giant Juncao is derived from the "washing liquid" of cow dung, and then returns to this "Giant Juncao"
  • the circular chain of "planting plots” This circular chain not only makes the giant fungus planted on barren land become more lush, but also makes the land quickly turn from barren to fertile.
  • the cattle raising industry brought about by the Juncao planting industry more subsequent utilization and processing industries of Juncao and their benefits have been added in a green way; this will make many barren wastelands in our country less likely to grow giant Juncao. The grass quickly becomes fertile soil with multiple benefits.
  • the first type that is, "or" uses the general sentence pattern: A or B, which means: choose one of the two types - A or B.
  • the second type namely "or/and" uses the general sentence pattern: A or/and B, which means: choose any one from three types - A, B, A and B.
  • the fourth type uses the general sentence pattern: A or and B, which means: choose any one from the two types - A, A and B; it is also equivalent to "A or then and B" B" or "A, or again and B".
  • the fifth type is "or again”, which is equivalent to any expression of "or and", “or and again”, “or again and”.

Abstract

Provided in the present invention are a clean product set prepared by using energy grass as a raw material, and a preparation method therefor. The "product set" is characterized in that energy grass, or energy grass and cow dung are used as starting main raw materials, processing sub-paths are connected in series or parallel for integration into a process and a combined apparatus or device array for clean production, and ultimately a clean product set is prepared. The "product set" is specifically composed of a main product A, or a combination of the main product A and any one or two of by-products B and C, or a combination of the main product A, the by-product B/C and any one or more of auxiliary products D, E, F, G, H and I, wherein A is hydrophilic de-fibered fibers, B is coarse grains of wood-plastic composite regenerated substances, C is a lignin/resin mixture, D is a solid organic soil conditioner, E is a liquid organic soil conditioner, F is fermented feed, G is pellet feed, H is a biomass pellet fuel, and I is edible fungus planting rods/blocks.

Description

以能源草为原料的清洁化产品集合及制法Collection and preparation methods of cleaning products using energy grass as raw materials 技术领域Technical field
本发明提供一种以能源草为原料的清洁化产品集合及制法,涉及包括将一些粮、棉、油等会产生巨量秸秆或枝条的农作物也归类入能源草这一上位代称,然后皆以能源草为上位代称名,介绍以其为主原料,经加工子路径的串并联集成清洁生产之工艺及组合设备或装置阵,最后制得清洁化产品集合,属于秸秆、巨菌草之草类等的综合利用的技术领域。The present invention provides a collection of cleaning products and a manufacturing method using energy grass as raw materials, which involves classifying some grain, cotton, oil and other crops that produce huge amounts of straw or branches into the high-level name of energy grass, and then They all use energy grass as the upper name, and introduce the process of integrating clean production in series and parallel through processing sub-paths and combined equipment or device array using it as the main raw material, and finally produce a collection of clean products, which belong to straw and giant fungus grass. The technical field of comprehensive utilization of grasses, etc.
背景技术Background technique
按网上百度百科的解释:能源草并不是一种植物草的名称。以多年生高大草本植物或半灌木,包括甜高粱、柳枝稷、芒属作物等高大草本都可被冠在能源草的名下;能源草多为耐旱、耐盐碱、耐瘠薄、适应性强的草种,种植和管理简单,在干旱、半干旱地区、低洼易涝和盐碱地区、土壤贫瘠的山区和半山区均能种植;能源草对土质和气候要求不高,耐寒、抗冻、适应性强,生长快,产量高,农田每亩一年干草最高产量可达三吨以上,一次播种后,产草期可长达10至15年。According to the explanation of the online Baidu Encyclopedia: Energy grass is not the name of a plant grass. Tall perennial herbs or semi-shrubs, including sweet sorghum, switchgrass, Miscanthus crops and other tall herbs can be labeled as energy grasses; energy grasses are mostly resistant to drought, salt and alkali, barrenness and adaptability. Grass seeds are simple to plant and manage, and can be planted in arid and semi-arid areas, low-lying areas prone to waterlogging and saline-alkali areas, mountainous areas with poor soil, and semi-mountainous areas; energy grass does not have high requirements for soil quality and climate, and is cold-resistant, frost-resistant, and adaptable. It is strong, fast growing and has high yield. The maximum annual hay output per mu of farmland can reach more than three tons. After one sowing, the grass production period can be as long as 10 to 15 years.
以本申请案开始写作的当日既2021年10月19日计,从中国专利网站的“soopat官网”输入“能源草”一词检索,所获得的发明和实用新型的总数还仅有不破百的81项;既,至少是在我国,以能源草为上位代称的专利申请还不多。Counting from October 19, 2021, the day when this application was started to be written, the total number of inventions and utility models obtained by entering the word "energy grass" from the "soopat official website" of the Chinese patent website is only less than a hundred. 81 items; that is, at least in our country, there are not many patent applications with energy grass as the upper name.
从前述的网上百度百科的解释可知:能源草具有“对土质和气候要求不高,耐寒、抗冻、适应性强,生长快,产量高”的特点。但这种特点如何被应用于能源草在后续利用中作净水等用途,还未见有文献报道。From the aforementioned explanation on Baidu Encyclopedia, we can know that energy grass has the characteristics of "low requirements on soil quality and climate, cold and frost resistance, strong adaptability, fast growth and high yield". However, there is no literature report on how this characteristic can be applied to energy grass for water purification and other purposes in subsequent uses.
在能源草的利用中,就如何既不产生污染,还能消纳社会环境中的如牛粪、废塑料等的污染,或又在能源草的后续利用中,将所生成的洗涤等废水如何作资源绿色化利用,也未见有文献的系统报道。In the use of energy grass, how can we not produce pollution, but also absorb pollution in the social environment such as cow dung, waste plastics, etc., or how to use the generated washing and other wastewater in the subsequent use of energy grass. There is no systematic report in the literature on the green utilization of resources.
故经本发明人的初步了解后认为:对能源草的深加工综合利用,至少可提供些更有益于规模化、原料化和便利下游机动化应用的产品集合及清洁化制法,这是能源草综合利用的本领域所需的。Therefore, after preliminary understanding, the inventor believes that the deep processing and comprehensive utilization of energy grass can at least provide some product collections and clean production methods that are more beneficial to large-scale, raw material and convenient downstream motorization applications. This is the energy grass. Comprehensive utilization required in this field.
另外,当今粮、棉、油等农作物在收割后,会产生巨量的秸秆废弃物,现时的主流应用方式之一,就是将其制成生物质颗粒燃料,既作能源化利用,故将这些会大量产生秸秆的农作物归类入能源草这一上位代称名下也无不妥。In addition, today's grain, cotton, oil and other crops will produce a huge amount of straw waste after harvesting. One of the current mainstream applications is to make biomass pellet fuel for energy use, so these straw wastes are used There is nothing wrong with classifying crops that produce a large amount of straw under the high-level name of energy grass.
再有,从前述半灌木可被冠上能源草之名,而从半灌木的网上百度的词条解释有:“半灌木与灌木不同的是:仅在枝条的下部为多年生,并有木栓组织保护,上部是1年生的。因此在寒冷的冬天,上部的枝条枯萎或死亡,常被农人砍伐作为柴薪。”,本发明人借此解释,扩展地将人工矮化种植且年年要修剪除上部枝条的柳树、竹柳、杨树、桑树、枸树等也归类入能源草这一上位代称名下。Furthermore, from the aforementioned semi-shrubs, they can be named as energy grasses, and from the online Baidu entry of semi-shrubs, the explanation is: "The difference between semi-shrubs and shrubs is that only the lower parts of the branches are perennial and have corks. Tissue protection, the upper parts are 1-year-old. Therefore, in the cold winter, the upper branches wither or die, and are often cut down by farmers for firewood." The inventor explained that artificial dwarf planting will be expanded and planted every year. Willow trees, bamboo willows, poplar trees, mulberry trees, medlar trees, etc. whose upper branches need to be pruned are also classified under the upper name of energy grass.
发明内容Contents of the invention
本发明的目的:针对现有对能源草的应用技术可能还很少或仍有不足的现状,提供一种以能源草为原料的清洁化产品集合及制法。所述“产品集合”中的主产品A是亲水疏解纤维,其物性至少可被替代或部分替代传统再生纸浆被用作抄纸,或被做进一步深加工制漂白纸浆等的原料;副产品,其一是木塑复合再生质粗粒产品B,或/和其二是木素/树脂混合物产品C;更多地还可包括D、E、F、G、H、I的一组辅助产品。在“产品集合”中,由副产品或/和辅助产品围绕主产品,吃干榨尽主产品在制备中所产生的种种副产物。最后,对所 提供的产品、制法、设备等,也提供其具体方向性的用途。The purpose of the present invention is to provide a collection and preparation method of cleaning products using energy grass as raw materials in view of the current situation that the existing application technology for energy grass may be few or insufficient. The main product A in the "product set" is hydrophilic and decomposable fiber, whose physical properties can at least replace or partially replace traditional recycled pulp, which is used as a raw material for papermaking or further processing to make bleached pulp, etc.; by-products, One is the wood-plastic composite recycled coarse particle product B, or/and the other is the lignin/resin mixture product C; moreover, it can also include a group of auxiliary products D, E, F, G, H, and I. In the "product collection", the main product is surrounded by by-products or/and auxiliary products, and all the by-products produced in the preparation of the main product are squeezed out. Finally, for all The products, manufacturing methods, equipment, etc. provided also provide their specific directional uses.
本发明的构思是:提供一组便于规模化、原料化和便利下游机动化应用的产品集合及清洁化制法。所述“清洁化制法”,不但要自扫门前雪,既对能源草综合利用过程中所产废液等要悉数资源绿色化利用;也要顺手带走别家的瓦上霜,既对实施地周边的牛粪或田间的废弃农用地膜等废物也被消纳后作资源绿色化利用等;当然,本发明也借用了能源草这一上位名称,将一些粮、棉、油等含秸秆或枝条量巨大的农作物也归类其中,以希望本发明的技术方案能被应用于更多的草本类或人工矮化种植且年年要修剪上部枝条的树类品种;在对制主产品A既亲水疏解纤维的助剂使用上,摒弃传统的“苛性碱、氨、铵盐、过氧化物、生物酶等的任一或多种组合”之用料集合,另走使用少量晶须等助剂实现纤维的表面接枝/包覆等毛糙化改性的新路,使纤维表面毛糙化而实现使其在水中,能实现纤维间的碰搭或和缠绕结合而成纸的目的。最后再对本发明所述的产品及制法,提供些明确或举一反三式的扩展化用途。The idea of the present invention is to provide a set of products and a clean manufacturing method that are convenient for large-scale, raw material and downstream motorized applications. The above-mentioned "clean production method" not only needs to clean up the snow in front of the house, but also greenly utilize all resources such as waste liquid produced during the comprehensive utilization of energy grass; it must also take away the frost on other people's tiles, which is not only for Wastes such as cow dung around the implementation site or discarded agricultural mulch films in the fields are also absorbed and used for green utilization of resources. Of course, the invention also borrows the high-level name of energy grass to convert some grain, cotton, oil, etc. containing straw Or crops with huge branches are also classified among them, in the hope that the technical solution of the present invention can be applied to more herbaceous or artificial dwarf tree species whose upper branches need to be pruned every year; in the preparation of the main product A In terms of the use of hydrophilic fiber-dissolving additives, the traditional material collection of "any or multiple combinations of caustic alkali, ammonia, ammonium salts, peroxides, biological enzymes, etc." is replaced by a small amount of whiskers, etc. Additives are a new way to achieve roughening modification such as surface grafting/coating of fibers, roughening the surface of fibers and making them in water, which can achieve the purpose of collision between fibers or combining with winding to form paper. Finally, some specific or extended uses of the products and preparation methods described in the present invention are provided.
本发明的构思是通过以下技术方案来实现上述目的:The idea of the present invention is to achieve the above objects through the following technical solutions:
1.以能源草为原料的清洁化产品集合,其特征在于:以能源草,或能源草和牛粪为起始主原料,经加工子路径的串并联集成清洁生产之工艺及组合设备或装置阵,最后制得清洁化产品集合,所述“产品集合”具体由如下所述的主产品A,或主产品A再与副产品B、C的任一或两种产品的组合所构成;或主产品A或和副产品B/C,再与辅助产品D、E、F、G、H、I的任一或多种产品的组合所构成:1. A collection of clean products using energy grass as raw material, which is characterized by: using energy grass, or energy grass and cow dung as the starting main raw materials, the series and parallel integration of clean production processes and combined equipment or device arrays through processing sub-paths , and finally a cleaning product set is obtained. The "product set" is specifically composed of the main product A as described below, or a combination of the main product A and any one or two of the by-products B and C; or the main product A or by-product B/C, and a combination of any one or more of auxiliary products D, E, F, G, H, and I:
主产品A--亲水疏解纤维,特征是:以前述“能源草,或能源草和牛粪”经锯/碾/切/锤的任一或多种组合碎化再过筛处理,获得其中的“过3目至不过28目筛范围的任一目数的分级或混合粒径的细长状纤维束”碎化物,以其为原料;制备过程中会排出棕/黑液,所述“棕/黑液”的重量份W棕/黑液,与所获主产品A中含水不超15%的绝干纤维之重量份WA的比例在W棕/黑液/WA=90~100~300/100范围;且“棕/黑液”中所含Na+或/和K+或/和Mg2+的克摩尔与其所含水的升体积之比为≤0.034mol/L,其pH值在5.0~9.4范围;使用的助剂中,所含苛性碱、氨、铵盐、过氧化物、生物酶的任一或多种的总含量为0;或和制备中使用水不溶或难溶性物质做晶须助剂,对纤维表面实施低灰分的晶须接枝/包覆,所述“晶须助剂”,对主产品A中绝干纤维100重量份的添加量,为≤1~3~5~9重量份,既≤1重量份或≤3重量份或≤5重量份或≤9重量份;所述主产品A——亲水疏解纤维产品,其入水或再经搅拌后能不浮水面;The main product A - hydrophilic decomposable fiber, characterized by: using the aforementioned "energy grass, or energy grass and cow dung", crushed by any one or more combinations of sawing/milling/cutting/hammering and then sieving to obtain the "Elongated fiber bundles of any mesh size that pass through a sieve ranging from 3 mesh to no more than 28 mesh" are used as raw materials; the brown/black liquor will be discharged during the preparation process, and the "brown/black liquor" will be discharged. The ratio of the weight part W brown/black liquor of "black liquor" to the weight part W A of the absolute dry fiber containing no more than 15% water in the main product A is W brown/black liquor /W A = 90~100~300 /100 range; and the ratio of the gram moles of Na + or/and K + or/and Mg 2+ contained in the "brown/black liquor" to the liter volume of the water contained is ≤0.034mol/L, and its pH value is within 5.0~9.4 range; the total content of any one or more of caustic alkali, ammonia, ammonium salts, peroxides, and biological enzymes in the additives used is 0; or the water-insoluble or poorly soluble substances used in the preparation To make a whisker additive, implement low-ash whisker grafting/coating on the fiber surface. The "whisker additive" added to 100 parts by weight of the absolutely dry fiber in the main product A is ≤ 1 to 3 ~5~9 parts by weight, either ≤1 part by weight or ≤3 parts by weight or ≤5 parts by weight or ≤9 parts by weight; the main product A - a hydrophilic and decomposable fiber product, cannot be dissolved after being put into water or stirred again. floating surface;
所述主产品A,其又可被细分有主产品A-1--被控制为低亲水之打浆度<16°SR的亲水疏解纤维,和主产品A-2--被控制呈高亲水之打浆度≥16°SR的亲水疏解纤维;The main product A can be subdivided into the main product A-1--a hydrophilic decomposable fiber controlled to have a low hydrophilicity of beating degree <16°SR, and the main product A-2--controlled to be Hydrophilic and decomposable fiber with high hydrophilic beating degree ≥16°SR;
副产品B--木塑复合再生质粗粒;特征是:至少以前述“能源草”经锯/碾/切/锤的任一或多种组合碎化,再经筛分处理后所获其中的另一部分:“过28目筛的细屑料或/和粉碎物,或和过3目筛的粗细混合的碎化物”,再取其与“废塑料”共为原料,或和再与A中所述“棕/黑液”存在传质联系,使用生物质燃料颗粒机制粒;By-product B - wood-plastic composite regenerated coarse particles; characterized by: at least the above-mentioned "energy grass" is crushed by any one or more combinations of sawing/milling/cutting/hammering, and then screened. The other part: "Fine materials or/and crushed materials that pass through a 28-mesh sieve, or crushed materials that are mixed with coarse and fine materials that pass through a 3-mesh sieve", and then use them as raw materials together with "waste plastics", or mix them with those in A The "brown/black liquor" has a mass transfer connection and is pelletized using a biomass fuel pellet machine;
副产品C--木素/树脂混合物,特征是:以A中所述“棕/黑液”为原料所制获,在室温下呈红茶色的亲水性液体,或呈面酱状棕褐或近黑色胶体,或呈咖啡或近黑色粉体或颗粒,或呈松香状固体;所述副产品C,其中又可被细分有副产品C-1--食用或医用级的木素/树脂混合物,副产品C-2--饲用或工业级的木素/树脂混合物;By-product C - lignin/resin mixture, characterized by: It is produced using the "brown/black liquor" mentioned in A as raw material. It is a hydrophilic liquid in the color of black brown at room temperature, or in the form of a paste-like brown or Nearly black colloid, or in the form of coffee or nearly black powder or granules, or in the form of rosin-like solid; the by-product C, which can be subdivided into by-product C-1-edible or medical grade lignin/resin mixture, By-product C-2--feed or industrial grade lignin/resin mixture;
辅助产品D--固态有机土壤改良剂,特征是:在提取了“能源草,或能源草和牛粪”中不过28目筛孔料制主产品A后的余料,既过28目筛孔的能源草之粉料或和细牛粪沉渣, 作为固态有机土壤改良剂中的配料之一;Auxiliary product D - solid organic soil conditioner, characterized by: the remaining material after extracting "energy grass, or energy grass and cow dung" that does not pass the 28-mesh sieve to make the main product A. Energy grass powder or fine cow dung sediment, As one of the ingredients in solid organic soil amendment;
辅助产品E--液态有机土壤改良剂,特征是:利用在制备亲水疏解纤维主产品A的过程中会排出棕/黑液,或/和利用因提质主产品A和副产品C而排出的压榨液或/和洗涤液或/和淘洗液,按所被施农作物和田块的土质需要所搀兑出的产品;所述“排出的压榨液或/和洗涤液或/和淘洗液”或“棕/黑液”,其pH值在5.0~9.4范围,和其中所含Na+或/和K+或/和Mg2+的克摩尔与其所含水的升体积之比为≤0.034mol/L,或其中所含的可溶性钠盐、钾盐、镁盐的wt%总浓度≤0.20%(wt%),或其中所含的可溶性钠盐、钾盐、镁盐的总浓度与生产实施地所取水源中的可溶性钠盐、钾盐、镁盐的总浓度之差≤0.01%(wt%);辅助产品E与主产品A的重量之比被控制在WE/WA≤500/100,或≤或2000/100≤或3000/100范围;Auxiliary product E - liquid organic soil conditioner, characterized by: utilizing the brown/black liquor discharged during the preparation of the hydrophilic decomposable fiber main product A, or/and utilizing the discharged liquid due to the upgrading of the main product A and by-product C Pressed liquid or/and washing liquid or/and elutriated liquid, products blended according to the soil requirements of the crops and fields to be applied; the "discharged pressed liquid or/and washing liquid or/and elutriated liquid" Or "brown/black liquor", with a pH value in the range of 5.0 to 9.4, and the ratio of the gram moles of Na + or/and K + or/and Mg 2+ contained in it to the liter volume of the water contained therein is ≤0.034 mol /L, or the total wt% concentration of the soluble sodium salt, potassium salt, and magnesium salt contained therein is ≤ 0.20% (wt%), or the total concentration of the soluble sodium salt, potassium salt, and magnesium salt contained therein is consistent with the production implementation The difference in the total concentration of soluble sodium salts, potassium salts, and magnesium salts in the water source taken from the local area is ≤0.01% (wt%); the weight ratio of auxiliary product E and main product A is controlled at W E /W A ≤500/ 100, or ≤ or 2000/100 ≤ or 3000/100 range;
辅助产品F--发酵饲料,特征是:在产品里掺入了主产品A制备过程中所排出的“棕/黑液”;Auxiliary product F - fermented feed, characterized by: the product is mixed with the "brown/black liquor" discharged during the preparation process of main product A;
辅助产品G--颗粒饲料,特征是:用能源草干料仅经破碎过筛所获的过28目筛细粉,或/和过28至不过150目筛范围的含土量微的粒径居中的能源草纤维粉屑,用其作为颗粒饲料的配料组份之一;Auxiliary product G - pellet feed, characterized by: the energy grass dry material is only crushed and sieved to obtain a fine powder that passes through a 28 mesh sieve, or/and a particle size with a small soil content that passes through a 28 to less than 150 mesh sieve. The energy grass fiber powder in the center is used as one of the ingredients of pellet feed;
辅助产品H--生物质颗粒燃料,特征是:以能源草被破碎、过筛脱除了未过28目筛之粗纤维后的细粉料,或是全组份的能源草粉碎物,为配料组份,或再配加了废塑料;所述“废塑料”,至少包括废农用塑膜、废泡沫塑料、废化纤织物或/和化纤棉絮的任一或多种的组合,所述的“配加”占辅助产品H之总重量的5%以下,或至高不超22%;Auxiliary product H - biomass pellet fuel, characterized by: the fine powder obtained by crushing and sieving the energy grass to remove the crude fiber that has not passed the 28 mesh sieve, or the full-component crushed energy grass as ingredients. components, or waste plastics are added; the "waste plastics" include at least any one or combination of waste agricultural plastic films, waste foam plastics, waste chemical fiber fabrics or/and chemical fiber cotton batting, and the "waste plastics" "Additional" accounts for less than 5% of the total weight of auxiliary product H, or does not exceed 22%;
辅助产品I--食用菌种植棒/块,特征是:在提取了“能源草,或能源草和牛粪”中之不过28目筛孔料制主产品A后的余料,既过28目筛孔的能源草之粉料或和细牛粪沉渣,作为食用菌种植棒/块中的配料组份之一。Auxiliary product I - Edible fungus planting stick/block, characterized by: the remaining material after extracting the main product A from "energy grass, or energy grass and cow dung" with a mesh size of no more than 28 mesh, and passing through a 28 mesh sieve. The energy grass powder or fine cow dung sediment of the hole is used as one of the ingredients in the edible fungus planting sticks/blocks.
2.技术方案1所述的“主产品A--亲水疏解纤维”,其特征至少还包括如下ⅰ至ⅵ,或再与ⅶ的组合:2. The "main product A--hydrophilic and decomposable fiber" described in technical solution 1, its characteristics include at least the following ⅰ to ⅵ, or a combination with ⅶ:
ⅰ.所用原料:包括芒萁、里白、香茅、芦竹、芦苇、类芦、斑茅、象草、王草、皇竹草、巨菌草、五节芒、大米草、紫象草、矮象草、红象草、甜象草、牧草笋、牧草蔗、拟高粱、甜高粱、彼特草、苏丹草、台湾甜草、交狼尾草、互花米草杂、美洲狼尾草、杂交狼尾草的任一种或多种组合的能源草,产生大量秸秆的粮、棉、油农作物--稻、麦、玉米、棉花、油菜、大豆、油牡丹、油芍药、向日葵、蓖麻的任一种或多种秸秆组合的能源草,或由人工矮化种植且常年要修剪上部枝条的柳树、竹柳、杨树、桑树、枸树的任一种或多种组合的能源草;经锯/碾/切/锤的任一或多种组合碎化再过筛处理,获得其中的一部分:过3目至不过28目筛范围的任一目数的分级或混合粒径的细长状纤维束碎化物;ⅰ. Raw materials used: including Echinacea, Liba, lemongrass, Arundodis, reeds, reeds, zebra grass, elephant grass, king grass, king bamboo grass, giant fungus grass, five-jointed miscanthus, rice grass, purple elephant grass , dwarf elephant grass, red elephant grass, sweet elephant grass, grass shoots, grass sugarcane, pseudosorghum, sweet sorghum, Peter grass, Sudan grass, Taiwan sweet grass, Pennisetum alterniflora, Spartina alterniflora hybrid, American wolftail Energy grasses of any one or more combinations of grasses and hybrid pennisetum, grain, cotton, and oil crops that produce a large amount of straw - rice, wheat, corn, cotton, rape, soybean, oil peony, oil peony, sunflower, Energy grass of any one or more combinations of castor straws, or any one or more combinations of willows, bamboo willows, poplars, mulberry trees, and wolfberry trees that are artificially planted in dwarfs and whose upper branches need to be pruned all year round. Grass; crushed by any one or more combinations of sawing/grinding/cutting/hammering and then sieved, a part of it is obtained: fine particles with any mesh size ranging from 3 mesh to no more than 28 mesh sieve or mixed particle size Fragments of long fiber bundles;
ⅱ.副产物料:副产物料1:热水脱木素/树脂工序所排棕/黑液,在制所述的“A”时,会在用干料在热水脱木素/树脂工序,经压/挤排出棕/黑液;所述的“棕/黑液”,其重量份W棕/黑液,与所获主产品A中含水不超15%的绝干纤维之重量份WA的比例在W棕/黑液/WA=90~100~300/100范围;所述“棕/黑液”中所含Na+或/和K+或/和Mg2+的克摩尔与其升体积之比为≤0.034mol/L,或/和所含的可溶性无机钠盐、钾盐、镁盐的wt%总浓度≤0.20%(wt%),或水中所含的可溶性无机盐、钾盐、镁盐的wt%总浓度与生产实施地所取水源中的总浓度之差≤0.01%(wt%),“棕/黑液”之pH值在5.0~9.4范围;ⅱ. By-product materials: By-product material 1: Brown/black liquor discharged from the hot water delignification/resin process. When making the "A" mentioned above, dry materials will be used in the hot water delignification/resin process. , the brown/black liquor is discharged by pressing/squeezing; the "brown/black liquor" has a weight part W of the brown/black liquor and a weight part W of the absolute dry fiber containing no more than 15% water in the main product A obtained The ratio of A is in the range of W brown/black liquor /W A =90~100~300/100; the gram moles of Na + or/and K + or/and Mg 2+ contained in the "brown/black liquor" are equal to The volume ratio per liter is ≤0.034mol/L, or/and the total wt% concentration of the soluble inorganic sodium salts, potassium salts, and magnesium salts contained in the water is ≤0.20% (wt%), or the soluble inorganic salts and potassium salts contained in the water The difference between the total wt% concentration of salt and magnesium salt and the total concentration in the water source taken from the production site is ≤0.01% (wt%), and the pH value of the "brown/black liquor" is in the range of 5.0 to 9.4;
或副产物料2:用鲜能源草或先用水洗净后的鲜能源草再经压榨所获的鲜汁液;或干能源草经水洗净后再水煮、压榨所获的汁液;Or by-product material 2: fresh juice obtained from fresh energy grass or fresh energy grass washed with water and then squeezed; or juice obtained from dried energy grass washed with water and then boiled and squeezed;
或和副产物料3:以牛粪为起始原料,对牛粪做淘/洗后所排出的淘/洗液;Or and by-product material 3: using cow dung as the starting material, the washing/washing liquid discharged after washing/washing the cow dung;
或和副产物料4:使用活性炭和酸性白土,对前述“棕/黑液”做吸附脱色杂,制净 化循环用水后,所获的脱色吸附渣泥;或对前述“棕/黑液”,滴加硫酸酸化至pH值不超出7.0条件下,使用活性炭或活性炭和酸性白土制净化循环用水后所获的脱色吸附渣泥;Or and by-product material 4: Use activated carbon and acidic clay to adsorb, decolorize and purify the aforementioned "brown/black liquor". The decolorized adsorption sludge obtained after purifying circulating water; or the aforementioned "brown/black liquor", obtained by adding sulfuric acid dropwise to acidify it until the pH value does not exceed 7.0, and using activated carbon or activated carbon and acidic clay to purify circulating water. Decolorization and adsorption of sludge;
或和副产物料5:使用化学或生化法,对前述“棕/黑液”或/和“淘/洗液”做沉淀净化处理所获得的脱色沉淀渣泥;Or and by-product material 5: decolorized precipitated sludge obtained by precipitation and purification of the aforementioned "brown/black liquor" or/and "washing liquor" using chemical or biochemical methods;
ⅲ.残留色度:主产品A入清水,以产品绝干料与清水按重量比=1:6所加热至70℃泡化5至10分钟后所挤获未蒸发失重清液料,以比色管直观或比色仪检测色度不浓于ⅱ项所述“棕/黑液”被清水稀释16倍的色度,或仪器检测其COD或BOD值不高于ⅱ项所述“棕/黑液”被清水体积稀释16倍的COD或BOD值,或用容量滴定法测其高锰酸钾退色消耗量值不高于ⅱ项所述“棕/黑液”被清水体积稀释16倍的高锰酸钾退色消耗量值;ⅲ. Residual color: Add the main product A into clean water, heat the product to 70°C and bubble it for 5 to 10 minutes, then squeeze out the clear liquid material that has not evaporated and lost weight. The color of the color tube intuitively or the colorimeter detects is not thicker than the color of the "brown/black liquid" mentioned in item ⅱ diluted 16 times with clean water, or the instrument detects that its COD or BOD value is not higher than the "brown/black liquor" mentioned in item ⅱ The COD or BOD value of the "black liquor" diluted 16 times by the volume of clean water, or the discoloration consumption value of potassium permanganate measured by volumetric titration is not higher than the value of the "brown/black liquor" diluted 16 times by the volume of clean water as described in item ⅱ Potassium permanganate fading consumption value;
ⅳ.产品剂型:主产品A的剂型可为含水不多于75%呈松散肉松状潮料、含水不多于75%呈潮纸状料、含水不多于20%的肉松状干料、含水不多于20%的纸状干料、含水不多于20%的呈压实砖状干料、含水不多于20%的呈压实颗粒状干料的任一种;ⅳ. Product dosage form: The dosage form of the main product A can be a loose meat floss-like moist material with a water content of not more than 75%, a wet paper-like material with a water content of not more than 75%, a dry meat floss-like material with a water content of not more than 20%, and a water-based material. Any of paper-like dry materials containing no more than 20% water, compacted brick-shaped dry materials containing no more than 20% water, and compacted granular dry materials containing no more than 20% water;
ⅴ.物性特征:被控制为低亲水之打浆度<16°SR的主产品A-1,或A-1与控制呈高亲水之打浆度≥16°SR的主产品A-2,A-1与A-2呈可被方便任意掺配的两组料;在与标样团料--天牛幼虫或木蠹蛾幼虫蛀食柳树杆的粪便所制标样,做团料对团料的对掐测试中,A-1或A-2的硬度≤标样的硬度;或和在与标样团料,做团料对团料的对搓至少10次测试中,以裸眼看或用天平秤重比较,A-1或A-2的散落屑量不多于标样散落屑量的5倍;ⅴ. Physical properties: Main product A-1 controlled to have a low hydrophilicity with a beating degree of <16°SR, or A-1 and main product A-2, A controlled to have a high hydrophilicity with a beating degree of ≥16°SR. -1 and A-2 are two sets of materials that can be blended easily and arbitrarily; when compared with the standard sample dough - the feces of beetle larvae or wood beetle moth larvae eating willow stems, the dough is compared with the dough. In the pinch test of the material, the hardness of A-1 or A-2 ≤ the hardness of the standard sample; or in the test of rubbing the dough with the standard sample for at least 10 times, it can be seen with the naked eye or Use a balance to weigh and compare, the amount of scattered chips of A-1 or A-2 is not more than 5 times the amount of scattered chips of the standard sample;
ⅵ.产程特征:生产过程里,所涉水中,所含Na+或/和K+或/和Mg2+的克摩尔与“水”的升体积之比为≤0.034mol/L;和采用不低于70℃的水至少2次浸渍纤维物料,以脱除纤维中的木素/树脂;所述的“水”流中之逐级渐浓的棕/黑液流向与纤维物料在生产过程中的流向呈逆流;或和添加水不溶或难溶性物质做晶须助剂,其添加量对主产品A或其中间产物里绝干纤维100重量份,为≤1~3~5~9重量份,既≤1重量份或≤3重量份或≤5重量份或≤9重量份,对纤维表面实施低灰分的晶须接枝/包覆;使用的助剂中,所含苛性碱、氨、铵盐、过氧化物、生物酶的任一或多种的总含量为0;ⅵ. Production process characteristics: During the production process, the ratio of the gram moles of Na + or/and K + or/and Mg 2+ contained in the water involved to the liter volume of "water" is ≤0.034 mol/L; and adopt Impregnate the fiber material with water of not less than 70°C at least twice to remove the lignin/resin in the fiber; the flow direction of the gradually thickening brown/black liquor in the "water" flow is consistent with the flow direction of the fiber material in the production process The flow direction in the product is countercurrent; or water-insoluble or poorly soluble substances are added as whisker additives, and the amount added is ≤1~3~5~9 parts by weight for 100 parts by weight of absolute dry fiber in the main product A or its intermediate product parts by weight, either ≤1 part by weight or ≤3 parts by weight or ≤5 parts by weight or ≤9 parts by weight, implement low-ash whisker grafting/coating on the fiber surface; among the additives used, caustic alkali, ammonia The total content of any one or more of ammonium salts, peroxides, and biological enzymes is 0;
ⅶ.较佳参数:或ⅱ项所述的“其排出的重量份W棕/黑液,与含水不超15%的绝干主产品A的总获重量份WA的比例在W棕/黑液/WA=100~120~150/100范围;或和ⅵ项所述的“添加水不溶或难溶性物质做晶须助剂,其添加量对主产品A或其中间产物里绝干纤维100重量份”“为≤1~3~5重量份”,“既≤1重量份或≤3重量份或≤5重量份”;所述的“晶须助剂”至少是氢氧化钙饱和水溶液、硅溶胶等的任一种,或/和在水相中新生成的氢氧化钙、氢氧化铝、水合硅酸、硅酸钙、硅酸镁、硅酸铝、碳酸钙、二水合硫酸钙、氢氧化铁等的任一或多种的组合,或和经超细粉碎至在水中难以在半小时里自然沉淀至表层水清的高岭土、粘土、粉煤灰、硅灰石等的任一或多种的组合,或和粉碎至过320目的高岭土、粘土、粉煤灰、硅灰石等的任一或多种的组合。ⅶ. Preferable parameters: or "The ratio of the discharged weight part W brown/black liquor and the total obtained weight part W A of the absolutely dry main product A with a water content not exceeding 15% as described in item ⅱ is W brown/black Liquid /W A = 100~120~150/100 range; or "adding water-insoluble or poorly soluble substances as whisker additives as described in item ⅵ, the amount added is equivalent to the absolute dry fiber in the main product A or its intermediate product "100 parts by weight""is ≤1~3~5 parts by weight", "either ≤1 part by weight or ≤3 parts by weight or ≤5 parts by weight"; the "whisker additive" is at least a saturated aqueous solution of calcium hydroxide , any of silica sol, etc., or/and newly generated calcium hydroxide, aluminum hydroxide, hydrated silicic acid, calcium silicate, magnesium silicate, aluminum silicate, calcium carbonate, and calcium sulfate dihydrate in the aqueous phase , iron hydroxide, etc., or any combination of kaolin, clay, fly ash, wollastonite, etc. that has been ultrafinely pulverized to the point where it is difficult to naturally precipitate in water to a clear surface within half an hour. Or a combination of more, or a combination of any one or more of kaolin, clay, fly ash, wollastonite, etc. crushed to 320 mesh.
3.技术方案1所述“副产品B--木塑复合再生质粗粒”,其更多特征在于:其中“木”之特征为如下3-1或3-1与3-2的组合,其中“塑”之特征为如下3-3或3-3与3-4的组合,其产品剂型特征为如下3-5至3-8:3. The "by-product B - wood-plastic composite regenerated coarse particles" described in technical solution 1 is more characterized by: the characteristics of "wood" are the following 3-1 or the combination of 3-1 and 3-2, wherein The characteristics of "plastic" are the following 3-3 or the combination of 3-3 and 3-4, and the product dosage form characteristics are the following 3-5 to 3-8:
3-1.其中的“木”,含来源于能源草之中的一部分:过28目筛的细屑料或/和粉碎物,或和过3目筛的粗细混合的碎化物;3-1. The “wood” includes part of the energy grass: fine materials or/and crushed materials that pass through a 28-mesh sieve, or crushed materials mixed with coarse and fine materials that pass through a 3-mesh sieve;
3-2.由如上3-1所述的“一部分”,为所述“木”在空气中自然干燥后含15%平衡水量之干基重,在副产品B的总重量中占比5%至78%(wt%)之间;3-2. The "part" as described in 3-1 above is the dry basis weight of the "wood" containing 15% of equilibrium water after natural drying in the air, accounting for 5% to 5% of the total weight of by-product B. Between 78% (wt%);
3-3.其中的“塑”之原料,皆选材于废塑料;3-3. The raw materials for "plastic" are all selected from waste plastics;
3-4.如上3-3所述“废塑料”,至少包括如后所述的任一或多种的组合:废纸再生 所弃的杂废塑膜渣,包括所述“杂废塑膜渣”经水浮选所获浮水含塑物或/和沉水含塑物;商品的塑膜质废包装袋、塑膜包装袋生产中的切/冲边料、废复合塑膜材、商标标贴生产/使用中所弃的塑膜复合离型纸/膜、废铝塑复合膜、废农用塑膜;由废旧轮胎经破碎分离出的含杂聚合物纤维,从汽车中拆除出的废化纤绒布,废化纤地毯、废化纤织物、废化纤熔喷布、废化纤过滤纸;废电线塑料皮、废塑料包装带、废塑料编织袋、废土工布、废/旧塑料鞋、废塑料铺地制品、废塑料玩具、废塑料桶、废塑料瓶、废塑料土工布、废/旧塑料草坪、废杂塑料建材、废塑料管、废塑料板、废塑料文具、废塑料箱/包、废塑料杂件;废PVC人造革、废PU人造革;废泡沫塑料;3-4. "Waste plastics" as described in 3-3 above, including at least any one or a combination of more as described below: waste paper recycling The discarded miscellaneous waste plastic film slag, including the floating plastic-containing materials or/and submerged plastic-containing materials obtained by water flotation of the "miscellaneous waste plastic film slag"; plastic film waste packaging bags and plastic film packaging of commodities Cut/punch edge materials in bag production, waste composite plastic film materials, plastic film composite release paper/film discarded in the production/use of trademark labels, waste aluminum-plastic composite film, waste agricultural plastic film; processed from waste tires Crushed and separated polymer fibers containing impurities, waste chemical fiber flannel removed from cars, waste chemical fiber carpets, waste chemical fiber fabrics, waste chemical fiber meltblown cloth, waste chemical fiber filter paper; waste wire plastic skins, waste plastic packaging tapes, waste Plastic woven bags, waste geotextiles, waste/old plastic shoes, waste plastic flooring products, waste plastic toys, waste plastic barrels, waste plastic bottles, waste plastic geotextiles, waste/old plastic lawns, waste plastic building materials, waste plastics Pipes, waste plastic boards, waste plastic stationery, waste plastic boxes/bags, waste plastic miscellaneous items; waste PVC artificial leather, waste PU artificial leather; waste foam plastics;
3-5.副产品B的剂型至少可被设置呈甲、乙、丙、丁之第一组,或/和戊、己、更、辛之第二组,或/和壬、癸之第三组,即可在第一至第三组中的甲至癸中任取一或多种以任意比的作搀兑联用,就能方便地使木塑复合再生质粗粒的下游之塑料粒子或制品中的“木”或携“杂质”的“木”总重量投料占比为5%至78%范围;前述“携‘杂质’的‘木’”中的两者重量之比为W杂质/W=0~10/100,所述的“木”,为含水量不高于15%的绝干料,所述的“杂质”为如技术方案2中ⅱ里所述“副产物料4”或/和“副产物料5”;“塑”和软化剂总重量投料占比为22%至95%范围,前述“‘塑’和软化剂”中的两者重量之比,即W废塑料/W软化剂=100/0~100:3-5. The dosage form of by-product B can be at least set into the first group of A, B, C, and D, or/and the second group of E, Ji, Geng, and Xin, or/and the third group of Ren and Gui. , that is, any one or more of A to Gui in the first to third groups can be blended and combined in any ratio to easily make the downstream plastic particles or coarse particles of wood-plastic composite regeneration. The total weight of "wood" or "wood" carrying "impurities" in the product ranges from 5% to 78%; the weight ratio of the two in the aforementioned "wood carrying 'impurities'" is W impurities / W wood = 0 ~ 10/100, the "wood" is an absolutely dry material with a moisture content of no more than 15%, and the "impurities" are "by-product materials 4" as described in ⅱ of the technical solution 2 ” or/and “by-product material 5”; the total weight input ratio of “plastic” and softener is in the range of 22% to 95%, and the weight ratio of the two in the aforementioned “plastic” and softener” is W waste Plastic /W softener =100/0~100:
第一组:First group:
甲中包括“木”总重量投料占比为76%,废塑料和软化剂总重量投料占比为24%;The total weight input of "wood" in A includes 76%, and the total weight input of waste plastics and softeners accounts for 24%;
乙中包括“木”总重量投料占比为35%,废塑料和软化剂总重量投料占比为65%;The total weight input of "wood" in B is 35%, and the total weight input of waste plastics and softeners is 65%;
丙中包括“木”总重量投料占比为25%,废塑料和软化剂总重量投料占比为75%;The total weight input of "wood" in C is 25%, and the total weight input of waste plastics and softeners is 75%;
丁中包括“木”总重量投料占比为5,废塑料和软化剂总重量投料占比为95%;The total weight input of "wood" in D is 5, and the total weight input of waste plastics and softeners is 95%;
第二组:Second Group:
戊中包括“木”总重量投料占比为77%,废塑料和软化剂总重量投料占比为23%;The total weight input of "wood" in E includes 77%, and the total weight input of waste plastics and softeners accounts for 23%;
己中包括“木”总重量投料占比为38%,废塑料和软化剂总重量投料占比为62%;The total weight input of "wood" accounts for 38%, and the total weight input of waste plastics and softeners accounts for 62%;
更中包括“木”总重量投料占比为23%,废塑料和软化剂总重量投料占比为77%;The update includes that the total weight input of "wood" accounts for 23%, and the total weight input of waste plastics and softeners accounts for 77%;
辛中包括“木”总重量投料占比为10,废塑料和软化剂总重量投料占比为90%;The total weight input of "wood" in Xin is 10, and the total weight input of waste plastics and softeners is 90%;
第三组:The third group:
壬中包括“木”总重量投料占比为78%,废塑料和软化剂总重量投料占比为22%;The total weight input of "wood" in Renzhong accounts for 78%, and the total weight input of waste plastics and softeners accounts for 22%;
癸中包括“木”总重量投料占比为15%,废塑料和软化剂总重量投料占比为85%;The total weight input of "wood" in Guizhong accounts for 15%, and the total weight input of waste plastics and softeners accounts for 85%;
3-6.或在3-5项所述的“在第一至第三组中的甲至癸中任取一或多种搀兑联用,控制了在木塑复合再生质粗粒的下游塑料粒子或制品中的“木”总重量投料占比为5%至78%范围,“塑”和软化剂总重量投料占比为22%至95%范围”内,3-5项所述的“第一组”、“第二组”、“第三组”中的甲至癸的各投料组合中的“木”总重量投料占比,与“塑”和软化剂总重量投料占比,皆可按市场客户的定制来定;3-6. Or as described in item 3-5, "select one or more of the A to Gui in the first to third groups and use them in combination to control the downstream coarse particles of the wood-plastic composite regenerated material. The total weight of "wood" in plastic particles or products is in the range of 5% to 78%, and the total weight of "plastic" and softener is in the range of 22% to 95%", items 3-5 The proportion of the total weight of "wood" in each feeding combination from A to Gui in the "first group", "second group" and "third group", and the proportion of the total weight of "plastic" and softener, All can be customized according to market customers;
3-7.所述的“木塑复合再生质粗粒”,其组成的物料按3-5项前述的“第一组”或/和“第二组”或/和“第三组”中的甲至癸各分组合配料投料,经粗粒造粒机处理后,得质地呈可被人手指/掌直接拉/扳/捏/撕/抓得碎的低强度粗粒,所述“低强度”,至少是抗拉强度≤3PMa的塑料之标样试片;3-7. The "wood-plastic composite recycled coarse particles" are composed of materials according to the "first group" or/and the "second group" or/and the "third group" mentioned in item 3-5. The ingredients from A to Gui are combined and fed. After being processed by a coarse granulator, the resulting texture is low-strength coarse granules that can be directly pulled/pulled/pinched/teared/grabbed with fingers/palms. The "low-strength coarse granules" "Strength", at least the standard sample specimen of plastic with tensile strength ≤3PMa;
3-8.如上3-7项所述“粗粒造粒机”,具体是指具有连续式进/出料功能的饲料颗粒机、有机肥造粒机、生物质燃料颗粒机的任一种,或再在前述“颗粒机”/“造粒机”之后再串联螺旋切粒中碎机。3-8. The "coarse granulator" mentioned in item 3-7 above specifically refers to any feed pellet machine, organic fertilizer granulator, or biomass fuel pellet machine with continuous feeding/discharging function. , or a spiral granulator and intermediate crusher can be connected in series after the aforementioned "granulator"/"granulator".
4.技术方案1所述产品集合中的“主产品A--亲水疏解纤维产品”的制法,其特征 可包括如下步骤一至十:4. The manufacturing method of "main product A--hydrophilic and decomposable fiber products" in the product set described in technical solution 1, and its characteristics May include the following steps one to ten:
步骤一——预处理备料:对能源草干料先做品种归类,或再对已归类料中所含金属或/和砖石块或/和树皮杂质作进一步的脱杂处理,然后再对已归类、脱杂的能源草实施锯/碾/切/锤的任一或多种组合碎化再过筛处理处理;排出另作利用的过28目筛的能源草碎化物;Step 1 - Pretreatment and preparation of materials: First classify the energy grass dry materials, or further remove the metals or/and masonry blocks or/and bark impurities contained in the classified materials, and then The classified and impurity-free energy grass is then subjected to any one or more combinations of sawing/grinding/cutting/hammering, and then sieved; the crushed energy grass that passes through a 28-mesh sieve is discharged for further use;
筛取能源草碎化物料中的过3目至不过28目筛范围的任一目数的分级或混和粒径的细长状纤维束;Sieve out the elongated fiber bundles with classified or mixed particle sizes in any mesh range from 3 mesh to 28 mesh in the energy grass crushed material;
或对已获脱杂净化的细长状纤维束能源草碎化物,再施机械膨化处理;Or the slender fiber bundle energy grass crumbs that have been removed and purified are subjected to mechanical expansion processing;
由此获得备做步骤二处理的备用能源草碎化物,此“备用能源草碎化物”料以其在空气中自然吸附的平衡水量15%(wt)计的,被称之为自然绝干料;Thus, the backup energy grass crumbs prepared for step 2 are obtained. This "backup energy grass crumbs" material is called natural absolutely dry material based on its naturally adsorbed equilibrium water content in the air of 15% (wt). ;
步骤二——第一次配料:取经步骤一所获的“备用能源草碎化物”料之自然绝干料:100重量份,拌入后续步骤七所述“第二次固液分离”所获的挤出水,所述“拌入”“挤出水”,在测知后续步骤四所述“第一次固液分离”所获固相中之自然绝干料100重量份所携的游离水为x重量份,则“拌入”的“挤出水”为不少于:2x重量份;或再拌入前述“挤出水”“2x重量份”的0.1~0.3%重量份之表面活性剂:丁基萘磺酸钠、十二烷基苯磺酸钠、十二烷基硫酸钠的任一种或多种的组合,或/和椰子油脂肪酸二乙醇酰胺、脂肪醇聚氧乙烯醚的任一或多种的组合;所述的“2x”对应能源草碎化物料之自然绝干料100重量份:在25~50~300重量份范围;Step 2 - First batching: Take 100 parts by weight of the natural dry material of the "Standby Energy Grass Crushed Material" obtained in Step 1, and mix in the "Second Solid-Liquid Separation" described in the subsequent Step 7. The extruded water, the "stirring in" and "extruded water", after measuring the free content carried by 100 parts by weight of the natural bone-dry material in the solid phase obtained by the "first solid-liquid separation" described in the subsequent step 4 If the amount of water is Active agent: any one or combination of sodium butylnaphthalene sulfonate, sodium dodecylbenzene sulfonate, sodium lauryl sulfate, or/and coconut oil fatty acid diethanolamide, fatty alcohol polyoxyethylene Any one or a combination of multiple ethers; the "2x" corresponds to 100 parts by weight of the natural dry material of crushed energy grass materials: in the range of 25 to 50 to 300 parts by weight;
步骤三——加热溶出:将前述“‘备用能源草碎化物’料之自然绝干料100重量份”、“后续步骤七所述‘第二次固液分离’所获的挤出水”:“2x重量份”,或和“‘挤出水’‘2x重量份’的0.1~0.3%重量份之‘表面活性剂’”,将这些物料置于一可被搅拌混合和加热且保温的罐中,对物料实施均匀搅拌和加热至70℃以上,并保温滞留至少5分钟,或被取样分析,当不见有挤出液的颜色更变深色时,即可停止此加热、保温操作;Step 3 - Heating and dissolution: Add the aforementioned "100 parts by weight of the natural dry material of the 'Standby Energy Grass Crushed Material' material" and "the extruded water obtained from the 'second solid-liquid separation' described in the subsequent step 7": "2x parts by weight", or "0.1 to 0.3% by weight of 'surfactant' of '2x parts by weight' of 'squeezed water'", place these materials in a tank that can be stirred, mixed, heated and kept warm. During the process, the material is uniformly stirred and heated to above 70°C, and kept warm for at least 5 minutes, or sampled and analyzed. When the color of the extruded liquid no longer changes to a darker color, the heating and heat preservation operations can be stopped;
步骤四——第一次固液分离:将上述“加热、保温操作”后的物料,导入螺杆或扎辊式挤浆机,对物料的纤维束作碾挤的机械揉化处理,然后再将物料导入固液分离机作固/液分离;或直接将上述加热、保温操作后的物料导入固液分离机作固/液分离;由此得到如技术方案1所述的“压/挤出棕/黑液”,和初脱除纤维中水溶质的待处理亲水疏解纤维中间产物甲的潮料;Step 4 - The first solid-liquid separation: Introduce the material after the above "heating and heat preservation operations" into a screw or roller extruder, perform a mechanical kneading treatment on the fiber bundles of the material, and then knead it. The materials are introduced into a solid-liquid separator for solid/liquid separation; or the materials after the above-mentioned heating and heat preservation operations are directly introduced into a solid-liquid separator for solid/liquid separation; thereby obtaining the "pressed/extruded brown material" as described in technical solution 1. / black liquor", and the moisture material of the hydrophilic decomposed fiber intermediate product A to be treated, which has initially removed the water solute in the fiber;
本“第一次固液分离”,所获的“压/挤出棕/黑液”,其排出的重量份W压/挤出棕/黑液,与亲水疏解纤维中间产物甲之自然绝干料重量份W亲水疏解纤维中间产物甲的比例,可使用常规的固液分离机械,被控制在W压/挤出棕/黑液/W亲水疏解纤维中间产物甲=25~100~300/100范围,既本“第一次固液分离”,所获潮料中“亲水疏解纤维中间产物甲”之自然绝干料重量百分含量,能被控制在80%~50%~25%范围;In this "first solid-liquid separation", the "pressed/extruded brown/black liquor" obtained is naturally separated from the hydrophilic decomposable fiber intermediate product A by the weight portion of the discharged brown/black liquor. The proportion of dry material weight part W hydrophilic decomposable fiber intermediate product A can be controlled by using conventional solid-liquid separation machinery at W pressing/extrusion brown/black liquor /W hydrophilic decomposable fiber intermediate product A =25~100~ In the range of 300/100, in this "first solid-liquid separation", the weight percentage of the natural absolute dry material of the "hydrophilic and decomposable fiber intermediate product A" in the obtained moisture material can be controlled between 80% and 50%. 25% range;
步骤五——第二次配料:在测知步骤四所述“待处理亲水疏解纤维中间产物甲的潮料”固相中之自然绝干料100重量份所携的游离水为x重量份后,取“待处理亲水疏解纤维中间产物甲的潮料”所含之自然绝干料100重量份和所携的游离水x重量份,再拌入后续步骤十所述“第三次固液分离”所获的挤出水不少于:x重量份;或和再按技术方案1中项所述“A-1”与“A-2”的差异性要求,再差别化地配加晶须助剂,所述“晶须助剂”至少是氢氧化钙饱和水溶液、硅溶胶等的任一种,或/和在水相中新生成的氢氧化钙、氢氧化铝、水合硅酸、硅酸钙、硅酸镁、硅酸铝、碳酸钙、二水合硫酸钙、氢氧化铁等的任一或多种的组合,或/和经超细粉碎至在水中不能在半小时里自然沉淀至表层水清的高岭土、粘土、粉煤灰、硅灰石等的任一或多种的组合,或和粉碎至过320目的高岭土、粘土、粉煤灰、硅灰 石等的任一或多种的组合;所述“晶须助剂”,其对“亲水疏解纤维中间产物甲的潮料”中绝干纤维100重量份的添加量,为≤1~3~5~9重量份,既添加量≤1重量份或≤重量3份或≤5重量份或≤9重量份;Step 5 - Second batching: It is determined that the free water carried by 100 parts by weight of the natural dry material in the solid phase of the "moist material for the hydrophilic decomposable fiber intermediate product A" described in step 4 is x parts by weight. Then, take 100 parts by weight of the natural dry material contained in the "moist material of the hydrophilic decomposable fiber intermediate product A to be treated" and x parts by weight of free water, and then mix in the "third solidification step" described in the subsequent step ten. The extruded water obtained by "liquid separation" is not less than: Whisker auxiliary, the "whisker auxiliary" is at least any one of saturated aqueous calcium hydroxide solution, silica sol, etc., or/and newly generated calcium hydroxide, aluminum hydroxide, hydrated silicic acid in the aqueous phase , any one or a combination of calcium silicate, magnesium silicate, aluminum silicate, calcium carbonate, calcium sulfate dihydrate, ferric hydroxide, etc., or/and ultrafinely pulverized to the point where it cannot naturally dissolve in water within half an hour. Any one or combination of kaolin, clay, fly ash, wollastonite, etc. that has been precipitated until the surface water is clear, or kaolin, clay, fly ash, silica fume, etc. that are crushed to 320 mesh Any one or a combination of stones, etc.; the "whisker additive", the amount added to 100 parts by weight of absolute dry fiber in the "moist material of hydrophilic decomposable fiber intermediate product A" is ≤ 1 to 3 ~5~9 parts by weight, that is, the added amount is ≤1 part by weight or ≤3 parts by weight or ≤5 parts by weight or ≤9 parts by weight;
将本步骤五所述的第二次配料,先在搅拌槽中混匀,即成待入高浓磨处理的物料;Mix the second batching ingredients described in step 5 in the mixing tank first to form the materials to be processed by high-concentration grinding;
步骤六——碾磨消潜:将步骤五所得的“待入高浓磨处理的物料”,导入高浓磨处理;或再将出高浓磨的发热物料,乘热导入带保温设置的消潜罐中保温或和加热,以不低于70℃之温静置,以松弛经高浓磨处理过程中产生的对纤维的扭结、卷曲,和对纤维中的憎水性脂类的溶出;由此步骤六处理后,获得又待固液分离之碾磨或和消遣操作后的物料;Step 6 - Grinding and latent elimination: Introduce the "materials to be processed into high-concentration grinding" obtained in step 5 into high-concentration grinding; or then use the heat to introduce the heat-generating materials from high-concentration grinding into a disinfection machine with heat preservation settings. Insulate or heat in a submersible tank, and let it stand at a temperature of no less than 70°C to relax the kinks and curls of the fibers produced during the high-concentration grinding process, and to dissolve the hydrophobic lipids in the fibers; After processing in step 6, the material after grinding or processing is obtained and is subject to solid-liquid separation;
步骤七——第二次固液分离:将上述“碾磨或和消遣操作后的物料”导入螺杆或扎辊式挤浆机,对物料的纤维束再作碾挤的机械揉化处理,然后再将物料导入固液分离机作固/液分离;或省去机械柔化,就将上述“碾磨或和消遣操作后的物料”直接导入固液分离机作固/液分离;由此得到如前“步骤二”中所述的“‘第二次固液分离’所获的挤出水”,和尚待最后再作新水洗涤之待处理亲水疏解纤维中间产物乙的潮料;Step 7 - The second solid-liquid separation: Introduce the above-mentioned "material after grinding or processing" into a screw or roller squeezer, and then perform mechanical kneading treatment on the fiber bundles of the material, and then Then the material is introduced into the solid-liquid separator for solid/liquid separation; or mechanical softening is omitted, and the above-mentioned "materials after grinding or processing" are directly introduced into the solid-liquid separator for solid/liquid separation; thus, we get As described in the previous "Step 2", "the extruded water obtained from the 'second solid-liquid separation'" and the wet material of the hydrophilic decomposable fiber intermediate product B to be treated are finally washed with new water;
步骤八——第三次配料:在测知步骤七所述“待处理亲水疏解纤维中间产物乙的潮料”固相中之自然绝干料100重量份所携的游离水为x重量份后,取“待处理亲水疏解纤维中间产物乙的潮料”所含之自然绝干料100重量份和所携的游离水x重量份,再拌入新水或和脱色杂的再生水不少于:x重量份;或和再配加晶须助剂,所述“晶须助剂”至少是包括氢氧化钙饱和水溶液、硅溶胶等的任一种,或/和在水相中新生成的氢氧化钙、氢氧化铝、硅溶胶等的任一种,或/和在水相中新生成的氢氧化钙、氢氧化铝、水合硅酸、硅酸钙、硅酸镁、硅酸铝、碳酸钙、二水合硫酸钙、氢氧化铁等的任一或多种的组合,或和经超细粉碎至在水中难以在半小时里自然沉淀至表层水清的高岭土、粘土、粉煤灰、硅灰石等的任一或多种的组合,或和粉碎至过320目的高岭土、粘土、粉煤灰、硅灰石等的任一或多种的组合;所述“晶须助剂”,对“亲水疏解纤维中间产物乙的潮料”中绝干纤维100重量份的添加量,为≤1~3~5~9重量份,既添加量≤1重量份或≤3重量份或≤5重量份或≤9重量份;由此步骤八的计量加水和晶须助剂,获待送步骤九处理的第三次配料;Step 8 - The third batching: It is determined that the free water carried by 100 parts by weight of the natural dry material in the solid phase of the "moist material of the hydrophilic decomposable fiber intermediate product B to be treated" described in step 7 is x parts by weight. Then, take 100 parts by weight of the natural dry material contained in the "moist material to be processed for the hydrophilic decomposable fiber intermediate product B" and x parts by weight of free water, and then mix in new water or a small amount of recycled water for decolorization and impurities. In: Any of calcium hydroxide, aluminum hydroxide, silica sol, etc., or/and newly generated calcium hydroxide, aluminum hydroxide, hydrated silicic acid, calcium silicate, magnesium silicate, aluminum silicate in the water phase , any one or a combination of calcium carbonate, calcium sulfate dihydrate, ferric hydroxide, etc., or kaolin, clay, fly ash that has been ultrafinely pulverized to the point where it is difficult to naturally precipitate to a clear surface in water within half an hour. , any one or more combinations of wollastonite, etc., or any one or more combinations of kaolin, clay, fly ash, wollastonite, etc. crushed to over 320 mesh; the "whisker additive" , the added amount of 100 parts by weight of absolute dry fiber in the "moist material of hydrophilic decomposable fiber intermediate product B" is ≤1~3~5~9 parts by weight, that is, the added amount is ≤1 part by weight or ≤3 parts by weight or ≤5 parts by weight or ≤9 parts by weight; add water and whisker additives according to the measurement in step eight to obtain the third batch of ingredients to be sent to step nine;
步骤九——搅拌洗涤:将上述步骤八的“第三次配料”导入螺杆或扎辊式挤浆机,对物料的纤维束再作碾挤的机械揉化处理,然后再将物料导入待最后挤干的物料暂储槽;或将上述“第三次配料”直接导入搅拌机作搅拌,使新水,或和晶须助剂与亲水疏解纤维中间产物乙的潮料固相纤维中本来所含的旧水物料,实现充分的混合,然后再将物料导入待最后挤干的物料暂储槽;由此步骤九的处理,获得待送步骤十处理的待最后挤干的物料;Step 9 - Stirring and washing: Introduce the "third batching" of the above step 8 into the screw or roller extruder, and then perform mechanical kneading treatment on the fiber bundles of the material, and then introduce the material to be finalized. The squeezed material is temporarily stored in a temporary storage tank; or the above-mentioned "third batching" is directly introduced into the mixer for stirring, so that the new water, or the moisture content of the solid-phase fiber mixed with the whisker additive and the hydrophilic decomposable fiber intermediate product B is The old water-containing material is fully mixed, and then the material is introduced into the temporary storage tank for the material to be finally squeezed dry; through the processing in step nine, the material to be sent to step ten to be finally squeezed dry is obtained;
步骤十——第三次固液分离或和最后修饰:将上述步骤九的“待最后挤干的物料”导入固液分离机作固/液分离;由此得到如前“步骤五”中所述的“‘第三次固液分离’所获的挤出水”,和最后产品--包括A-1或/和A-2之亲水疏解纤维A产品;或和再对最后产品添加掩蔽铁/锰离子的助剂:草酸、草酸钠、草酸钾、草酸铵、乙二胺四乙酸、乙二胺四乙酸钠、四乙酰乙二胺、柠檬酸、柠檬酸钠、酒石酸、酒石酸钠、葡萄糖酸、二亚乙基三胺五乙酸、二亚乙基三胺五亚甲基膦酸、二乙烯三胺五乙酸五钠、次氨基三乙酸钠的任一或以上种的组合物料,所述组合物料,其可被配成掩蔽助剂水溶液:组合物料的总摩尔加入量在0.1~1.2mol/L范围,添加掩蔽助剂水溶液的量可控制在绝干亲水疏解纤维A 100重量份,加掩蔽助剂水溶液1至2重量份;或和再对最后产品添加常规量的普通防霉助剂。Step 10 - The third solid-liquid separation or final modification: Introduce the "material to be finally squeezed dry" in the above-mentioned step 9 into the solid-liquid separator for solid/liquid separation; thus obtain the material as in the previous "step five" The above-mentioned "extrusion water obtained from the 'third solid-liquid separation'", and the final product - the hydrophilic and decomposable fiber A product including A-1 or/and A-2; or and then adding masking to the final product Iron/manganese ion additives: oxalic acid, sodium oxalate, potassium oxalate, ammonium oxalate, ethylenediaminetetraacetic acid, sodium ethylenediaminetetraacetate, tetraacetylethylenediamine, citric acid, sodium citrate, tartaric acid, sodium tartrate, A combination of any one or more of gluconic acid, diethylenetriaminepentaacetic acid, diethylenetriaminepentamethylenephosphonic acid, pentasodium diethylenetriaminepentacetate, and sodium nitrilotriacetate, so The above composition material can be formulated into a masking aid aqueous solution: the total molar addition amount of the composition material is in the range of 0.1 to 1.2 mol/L, and the amount of the masking aid aqueous solution added can be controlled to 100 parts by weight of absolute dry hydrophilic decomposable fiber A , add 1 to 2 parts by weight of the masking additive aqueous solution; or add a regular amount of ordinary anti-mold additives to the final product.
5.技术方案1所述产品集合中的“主产品A--亲水疏解纤维产品”和“副产品C--木素/树脂混合物产品”的联产制法,其特征至少包括:制A与C-1联产,可先经如下5-1或/和5-2步骤;或制A与C-2联产,可先经如下5-3或/和5-4或/和5-5步骤;最后都走 5-6步骤而获实现:5. The co-production method of "main product A--hydrophilic decomposable fiber product" and "by-product C--lignin/resin mixture product" in the product set described in technical solution 1, the characteristics of which at least include: making A and C-1 can be co-produced by going through the following steps 5-1 or/and 5-2; or A and C-2 can be co-produced by going through the following steps 5-3 or/and 5-4 or/and 5-5. step; take last 5-6 steps to achieve:
5-1.用新鲜的能源草之去根带叶的整株或剥除叶片的茎秆部料,用清水洗净,脱水、晾干,然后进榨汁机压榨,较佳的是控制压榨后的出渣含水量在20%(wt%)以下,压榨出之液体既为技术方案2中ⅱ项所述的副产物料2--“先用水洗净后的鲜能源草再经压榨所获的鲜汁液”;或再将此“鲜汁液”加热至100~105℃保持3~5分钟,冷却、装罐即成液体状红茶色之食用或医用级的木素/树脂混合物产品C-1;若在加热的同时,再对“鲜汁液”施以蒸发提浓操作,则在控制蒸出水多少的操控工艺参数条件下,可使“鲜汁液”的被蒸浓料再在冷至室温时,可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的食用或医用级木素/树脂混合物产品C-1;5-1. Use fresh energy grass to remove the whole plant with roots and leaves or peel off the stem parts of the leaves, wash it with clean water, dehydrate and dry it, and then press it into a juicer. It is better to control the pressing. The moisture content of the final slag is below 20% (wt%), and the liquid squeezed out is the by-product material 2 described in item ii of technical solution 2 - "fresh energy grass washed with water first and then pressed. "The obtained fresh juice"; or this "fresh juice" can be heated to 100-105℃ for 3-5 minutes, cooled and canned to obtain a liquid black brown edible or medical grade lignin/resin mixture product C- 1; If the "fresh juice" is subjected to an evaporation and concentration operation while heating, the steamed and concentrated material of the "fresh juice" can be cooled to room temperature under the control process parameters of controlling the amount of steamed water. The edible or medical grade lignin/resin mixture product C-1 can be in the form of a paste-like tan colloid, or a coffee-colored powder or granules, or a rosin-like solid block;
5-2.用经晒干或自然晾干或烘干的能源草之去根带叶的整株或剥除叶片的茎秆部,或是用能源草干料经破碎过筛脱除过28目筛细粉后的粗料,用清水洗净,可再加入干料重量的0.7至5.7倍范围的清水,加热到70℃乃至煮沸,然后进榨汁机压榨,较佳的是控制压榨后的出渣含水量在20%(wt%)以下,压榨出之液体既为技术方案2中ⅱ项所述的副产物料2--“干能源草经水洗净后再水煮、压榨所获的汁液”;或再将此“能源草”“汁液”加热至100~105℃保持3~5分钟,冷却、装罐即成液体状红茶色之食用或医用级的木素/树脂混合物产品C-1;若在加热的同时,再对“能源草”“汁液”施以蒸发提浓操作,则在控制蒸出水多少的操控工艺参数条件下,可使“能源草”“汁液”被蒸浓料再在冷至室温时,可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的食用或医用级木素/树脂混合物产品C-1;5-2. Use the energy grass that has been sun-dried or naturally dried or oven-dried to remove the whole plant with roots and leaves or remove the stem part of the leaves, or use the dry energy grass material to remove 28% by crushing and screening After sieving the coarse material into fine powder, wash it with clean water. You can add water ranging from 0.7 to 5.7 times the weight of the dry material, heat it to 70°C or even boil it, and then press it into a juicer. It is better to control the amount of water after squeezing. The moisture content of the residue is below 20% (wt%), and the liquid squeezed out is the by-product material 2 described in item ii of technical solution 2 - "dry energy grass is washed with water and then boiled and pressed." "Obtained juice"; or heat the "energy grass" "juice" to 100-105℃ for 3-5 minutes, cool and can it to become a liquid black brown edible or medical grade lignin/resin mixture product C-1; If the "energy grass" and "juice" are subjected to an evaporation and concentration operation while heating, the "energy grass" and "juice" can be evaporated under the control of process parameters that control the amount of steamed water. When the concentrated material is cooled to room temperature, it can be in the form of a tan colloid in the form of pasta, or in the form of coffee-colored powder or granules, or in the form of rosin-like solid blocks, edible or medical grade lignin/resin mixture product C-1;
5-3.用新鲜的能源草湿料的去根带叶的整株或剥除叶片的茎秆部料,然后进榨汁机压榨,较佳的是控制压榨后的出渣含水量在20%(wt%)以下,压榨出之液体既为技术方案2中ⅱ项所述的副产物料2--“用鲜能源草”“经压榨所获的鲜汁液”;或再将“鲜汁液”加热至100~105℃保持3~5分钟,冷却、装罐即成液体状红茶色之饲用或工业级的木素/树脂混合物产品C-2;若在加热的同时,再对“鲜汁液”施以蒸发提浓操作,则在控制蒸出水多少的操控工艺参数条件下,可使“鲜汁液”的被蒸浓料再在冷至室温时,可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的饲用或工业级的木素/树脂混合物产品C-2;5-3. Use fresh energy grass wet material to remove the roots and leaves of the whole plant or remove the stem parts of the leaves, and then squeeze it into a juicer. It is better to control the moisture content of the residue after pressing to be 20 % (wt%) or less, the squeezed liquid is either the by-product material 2 described in item ii of technical solution 2 - "fresh energy grass" and "fresh juice obtained by pressing"; or the "fresh juice" "Heat to 100~105℃ and hold for 3~5 minutes, cool and can the liquid black brown feed or industrial grade lignin/resin mixture product C-2; if it is heated at the same time, then "fresh" "Juice" is subjected to an evaporation and concentration operation, and under the control of process parameters that control the amount of steamed water, the steamed and concentrated material of "fresh juice" can be in the form of a brown colloid like a pasta sauce when it is cooled to room temperature, or Feed or industrial grade lignin/resin mixture product C-2 in the form of brown powder or granules, or rosin-like solid blocks;
5-4.用经晒干或自然晾干或烘干的能源草之去根带叶的整株或剥除叶片的茎秆部料,或是用能源草干料仅经破碎过筛脱除过28目筛细粉后的粗料,可加入干料重量的0.7至5.7倍的清水,加热到70℃乃至煮沸,然后进榨汁机压榨,较佳的是控制压榨后的出渣含水量在20%(wt%)以下,压榨出之液体既为技术方案2中ⅱ项所述的副产物料1--热水脱木素/树脂工序所排棕/黑液;或再将“棕/黑液”加热至100~105℃保持3~5分钟,冷却、装罐即成液体状红茶色之饲用或工业级的木素/树脂混合物产品C-2;若在加热的同时,再对“棕/黑液”施以蒸发提浓操作,则在控制蒸出水多少的操控工艺参数条件下,可使“棕/黑液”被蒸浓料再在冷至室温时,可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的饲用或工业级的木素/树脂混合物产品C-2;5-4. Use the whole plant with roots and leaves removed from the energy grass that has been sun-dried or naturally dried or oven-dried, or use the stem material with the leaves peeled off, or use the dry energy grass material only after crushing and screening. After passing through a 28-mesh sieve, the coarse material can be added with 0.7 to 5.7 times the weight of the dry material in water, heated to 70°C or even boiled, and then pressed in a juicer. It is better to control the moisture content of the residue after pressing. Below 20% (wt%), the liquid squeezed out is either the by-product material 1 described in item ii of the technical solution 2 - the brown/black liquor discharged from the hot water delignification/resin process; or the "brown liquor" /Black liquor" is heated to 100~105℃ for 3~5 minutes, cooled and canned to obtain a liquid black brown feed or industrial grade lignin/resin mixture product C-2; if it is heated at the same time, then The "brown/black liquor" is subjected to an evaporation and concentration operation, and under the control of process parameters that control the amount of steamed water, the "brown/black liquor" can be evaporated and concentrated, and then when cooled to room temperature, it can be turned into a pasta sauce The feed or industrial grade lignin/resin mixture product C-2 is in the form of brown colloid, or coffee-colored powder or granules, or rosin-like solid block;
5-5.收集前述5-1或/和5-2项中所述“清水洗净”后脱除水,用此种水对牛粪作洗选,脱除过28目筛的杂质,撩获由水淘洗过筛后未过28筛的粗纤维,对其作煮沸处理,杀灭其中的纤维素分解酶,再对其做进榨汁机压榨,较佳的是控制压榨后的出渣含水量在20%(wt%)以下,压榨出之液体既为技术方案2中ⅱ项所述的副产物料1--热水脱木素/树脂工序所排棕/黑液;或再将“棕/黑液”加热至100~105℃保持3~5分钟,冷却、装罐即成液体状红茶色之饲用或工业级的木素/树脂混合物产品C-2;若在加热的同时,再对“棕/黑液”施以蒸发提浓操作,则在控制蒸出水多少的操控工艺参数条件下,可使“棕/黑液”被蒸浓料 再在冷至室温时,可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的饲用或工业级的木素/树脂混合物产品C-2;对牛粪所做淘/洗处理后排出的淘/洗液,则至少可作耐肥耗水的巨菌草种植所用的直接浇灌用水;5-5. Collect and remove the water after "washing with clean water" mentioned in item 5-1 or/and 5-2 above, use this water to wash the cow dung, remove impurities that pass through a 28-mesh sieve, and remove Obtain the crude fiber that has not passed 28 sieves after being washed with water, boil it to kill the cellulolytic enzymes in it, and then put it into a juicer for squeezing. It is better to control the output after squeezing. The moisture content of the slag is below 20% (wt%), and the liquid squeezed out is the by-product material 1 described in item ii of the technical solution 2 - the brown/black liquor discharged from the hot water delignification/resin process; or Heat the "brown/black liquor" to 100-105°C for 3-5 minutes, cool it, and can it to form a liquid black brown feed or industrial grade lignin/resin mixture product C-2; if it is heated At the same time, the "brown/black liquor" is subjected to an evaporation and concentration operation, and the "brown/black liquor" can be evaporated and concentrated under the control process parameters of controlling the amount of steamed water. When cooled to room temperature, it can be a feed or industrial-grade lignin/resin mixture product C-2 that is in the form of a paste-like brown colloid, or a coffee-colored powder or granule, or a rosin-like solid block; for cow dung The washed/washed liquid discharged after the washing/washing treatment can at least be used as direct irrigation water for planting the fertilizer-resistant and water-consuming Giant Junca grass;
5-6.将前述5-1至5-5所述的“较佳的是控制压榨后的出渣含水量在20%(wt%)以下”之渣,可再用水泡化成含固25%的呈松散肉松状物料,筛取其中大小在过3目至不过28目筛孔范围的粒度分级或混合的细长状纤维束,既可获如技术方案4中步骤四所述的“初脱除纤维中水溶质的待处理亲水疏解纤维中间产物甲的潮料”,后续可再走技术方案4中第五至第十步骤的操作,最后就能获亲水疏解纤维产品A-1或A-2;对前述5-5中所述的“对牛粪作洗选”“由水淘洗过筛”所产生的含牛粪之水,既为技术方案2中ⅱ项所述的“副产物料3:淘/洗牛粪所产生的淘/洗液”,可被导送做技术方案1所述“辅助产品E--液态有机土壤改良剂”的配料之一。5-6. The slag mentioned in the above 5-1 to 5-5 "It is better to control the moisture content of the slag after pressing to be below 20% (wt%)" can be soaked into a solid content of 25%. The loose floss-like material is sifted out and the particle size classification or mixed elongated fiber bundles ranging from 3 mesh to no more than 28 mesh can be obtained as described in step 4 of technical solution 4. "The moisture material of the hydrophilic decomposable fiber intermediate product A to be treated to remove the water solute in the fiber" can be followed by the fifth to tenth steps in the technical solution 4, and finally the hydrophilic decomposable fiber product A-1 or A-2; The water containing cow dung produced by "washing cow dung" and "washing and sieving with water" described in the aforementioned 5-5 is the "water containing cow dung" described in item ii of technical solution 2. By-product material 3: "The washing liquid produced by washing cow dung" can be directed to be one of the ingredients of the "auxiliary product E--liquid organic soil conditioner" described in the technical solution 1.
6.技术方案1所述产品集合中的“B--木塑复合再生质粗粒产品”之制法,其特征在于如下6-1至6-6:6. The preparation method of "B--wood-plastic composite recycled coarse-grained product" in the product set described in technical solution 1 is characterized by the following 6-1 to 6-6:
6-1.备料:对技术方案5中5-1至5-5里的任一所述的“较佳的是控制压榨后的出渣含水量在20%(wt%)以下”之渣,做“木塑复合再生质粗粒”中的“木”备料;6-1. Material preparation: For the slag mentioned in any one of 5-1 to 5-5 in Technical Solution 5, "It is better to control the moisture content of the slag after pressing to be below 20% (wt%)", Prepare the "wood" material in "Wood Plastic Composite Regenerated Coarse Grains";
或/和用未经压榨处理的干能源草,仅经一次的破碎或切段粉碎后之风选或/和筛分,选出养分较少的物料做“木塑复合再生质粗粒”中的“木”备料,和剩余出的养分较多物料另做有机肥或/和饲料的备料;所述“养分较少的物料”,计量地讲,是将在经一次的破碎或切段粉碎后,能经受住机械破碎力而未被更细碎化的过3至不过28目筛范围的能源草粗纤维,和过150目筛的之能源草粉碎物中含土量较多的精细能源草纤维粉;所述“养分较多的物料”,计量地讲,就是在仅经一次的破碎或切段粉碎后,不能经受住机械破碎力而被更细碎化的过28至不过150目筛范围的含土量微的粒径居中的能源草纤维粉屑;Or/and use dry energy grass that has not been pressed, and only crush or cut into sections once, then winnow or/and screen, and select materials with less nutrients to make "Wood-Plastic Composite Regenerated Coarse Grain" The "wood" is prepared, and the remaining materials with more nutrients are used as organic fertilizer or/and feed materials; the "materials with less nutrients", in terms of measurement, are the materials that have been crushed or cut into pieces after one Finally, the crude energy grass fiber that can withstand the mechanical crushing force without being more finely divided and passes through a sieve ranging from 3 to 28 mesh, and the fine energy grass that has a higher soil content in the crushed energy grass that passes through a 150 mesh sieve. Fiber powder; the "materials with more nutrients", in terms of measurement, are materials that cannot withstand the mechanical crushing force and are more finely crushed after being crushed or cut into pieces once, and pass through a sieve ranging from 28 to no more than 150 mesh. Energy grass fiber powder with small soil content and medium particle size;
对购入或/和免费收集来的废塑料原料,对其呈压缩打包态或/和其中杂有大块金属、砖块类固体的原料,则须先经破碎、风选,以开松物料和脱除其中的金属、砖块类硬质固体;将脱除了杂质的蓬松废塑料作为“木塑复合再生质粗粒”中的“塑”备料;Waste plastic raw materials purchased or/and collected for free, which are in a compressed and packaged state or/and which contain large pieces of metal or brick-like solids, must first be crushed and winnowed to loosen the materials. and remove hard solids such as metal and bricks; use the fluffy waste plastic with impurities removed as the "plastic" material in "wood-plastic composite recycled coarse particles";
6-2.配料:按技术方案3中3-4或3-5所述“木塑复合再生质粗粒”的组成中“木”与“塑”和软化剂在产品总重量中的投料占比,秤重配料;6-2. Ingredients: According to the proportion of "wood", "plastic" and softener in the total weight of the product in the composition of "wood-plastic composite regenerated coarse particles" described in 3-4 or 3-5 in Technical Plan 3 Ratio, weigh ingredients;
6-3.造粒:将秤配好的料,经混合集料仓,再由机械输送,投于技术方案3中之3-7、3-8所述“粗粒造粒机”中成粒;所述“粗粒造粒机”所使用的机械是:具有连续式进/出料功能的饲料颗粒机、有机肥造粒机、生物质燃料颗粒机的任一种,或再在前述“颗粒机”/“造粒机”之后再串联螺旋切粒中碎机;前述的“颗粒机”/“造粒机”,出机物料呈过孔模所形成的段条粒状,如将前述“段条粒状”“物料”再经串联的螺旋切粒中碎机处理,则再出机物料就呈不规则颗粒;成粒时的物料被机械挤压/摩擦所发热升温,可用向物料或/和机械中的夹层中加水方式,来操控其出机物料不超过110℃;此操作所造成的“木塑复合再生质粗粒”,其质地呈可被人手指/掌直接拉/扳/捏/撕得碎的低强度;其成粒形状至少包括呈过孔模所形成的段条粒状或呈不规则颗粒;所述“孔模”的孔形,至少包括等边或不等边长的3至12边形的任一种,或圆形;所述“粒”的大小,在过25mm至不过2.0mm筛孔范围的任一孔径的分级或混合;6-3. Granulation: The materials prepared by the scale are passed through the mixing aggregate bin, and then transported by machinery, and put into the "coarse granulator" described in 3-7 and 3-8 of Technical Plan 3 to form Granules; the machinery used in the "coarse granulator" is: any of the feed pellet machine, organic fertilizer granulator, biomass fuel pellet machine with continuous inlet/output function, or any of the above-mentioned The "granulator"/"granulator" is then connected in series with a spiral granulator and intermediate crusher; the aforementioned "granulator"/"granulator" discharges the material in the form of segmented granules formed by the through-hole die. For example, the aforementioned "granulator"/"granulator" The "segmented granular" "materials" are then processed by the spiral granulator in series, and then the materials come out of the machine as irregular particles; the materials during granulation are heated by mechanical extrusion/friction, and can be used to feed the materials or /The water is added to the interlayer in the machine to control the outgoing material to not exceed 110°C; the "coarse wood-plastic composite recycled material" produced by this operation has a texture that can be directly pulled/pulled by human fingers/palms/ Low strength when kneaded/torn into pieces; its granulated shape at least includes segmented granules or irregular particles formed by a through-hole mold; the hole shape of the "hole mold" includes at least equilateral or unequal side lengths Any one of 3 to 12 sides, or round; the size of the "grain" is classified or mixed in any aperture ranging from 25mm to less than 2.0mm mesh;
6-4.均化混粒:若6-3项所获的“木塑复合再生质粗粒”在后续包装后有明显的包包不同质的质量瑕疵,则可在称重包装前加施混粒均化处理,所述的处理,既是用机械滚筒将5-3项所获的“木塑复合再生质粗粒”导入,滚翻混合匀即可;6-4. Homogenization and mixing: If the "wood-plastic composite recycled coarse particles" obtained in item 6-3 have obvious quality defects such as inhomogeneous packaging after subsequent packaging, they can be added before weighing and packaging. Mixing and homogenizing treatment, the above-mentioned treatment is to use a mechanical roller to introduce the "wood-plastic composite recycled coarse particles" obtained in item 5-3, and tumble and mix evenly;
6-5.称重包装:将符合质量要求的6-3或/和6-4项所获的“木塑复合再生质粗 粒”经称重后导入市场客户认可规格的包装袋中;6-5. Weighing and packaging: The "Wood-Plastic Composite Regenerated Coarse Quality" obtained in items 6-3 or/and 6-4 that meets the quality requirements "Particles" are weighed and then introduced into packaging bags with specifications approved by market customers;
6-6.入库质检:将包装好的产品按序入库,并按市场客户所需知的指标项,给出各批次入库产品的质检报告作存档。6-6. Inbound quality inspection: Put the packaged products into the warehouse in order, and provide quality inspection reports for each batch of incoming products for archiving according to the indicators that market customers need to know.
7.技术方案1所述产品集合中的“辅助产品”D至I的制法,其特征在于7-1至7-6所述:7. The preparation method of "auxiliary products" D to I in the product set described in technical solution 1, which is characterized by the following: 7-1 to 7-6:
7-1.技术方案1所述“辅助产品D--固态有机土壤改良剂产品”的制法,其特征至少在于:以能源草,或能源草和牛粪为起始主原料时,使用提取了制主产品A用原料后的余料,既过28目筛孔的能源草之粉料或和细牛粪沉渣,作为“辅助产品D”中的配料之一;7-1. The preparation method of "auxiliary product D - solid organic soil conditioner product" described in technical solution 1 is at least characterized in that: when using energy grass, or energy grass and cow dung as the starting main raw materials, use extracted The remaining materials after making the main product A, including energy grass powder or fine cow dung sediment that has passed through a 28-mesh sieve, are used as one of the ingredients in "auxiliary product D";
7-2.技术方案1所述“辅助产品E--液态有机土壤改良剂产品”的制法,,其特征至少在于:由能源草,或能源草和牛粪为起始主原料,在制备“主产品A--亲水疏解纤维产品”和“副产品C--木素/树脂混合物产品”时,由因提质产品A和C所排出的压榨液或/和洗涤液或/和淘洗液;再将“压榨液或/和洗涤液或/和淘洗液”按所被施农作物和地块的土质改良所需,经搀兑处理所获的液态有机土壤改良剂产品;所述“排出的压榨液或/和洗涤液或/和淘洗液”,其pH值皆不超出5.0~9.4范围,和其中所含Na+或/和K+或/和Mg2+的克摩尔与其所含水的升体积之比为≤0.034mol/L,或其中所含的可溶性钠盐、钾盐、镁盐的wt%总浓度≤0.20%(wt%),或其中所含的可溶性钠盐、钾盐、镁盐的总浓度与生产实施地所取水源中的可溶性钠盐、钾盐、镁盐的总浓度之差≤0.01%(wt%);辅助产品E与主产品A的重量之比被控制在产品E/产品A≤100/100~300/100范围,既≤100/100或≤300/100范围;7-2. The preparation method of "auxiliary product E--liquid organic soil conditioner product" described in technical solution 1, is at least characterized by: using energy grass, or energy grass and cow dung as the starting main raw materials, during the preparation of " When the main product A - hydrophilic decomposable fiber product" and "by-product C - lignin/resin mixture product", the pressing liquid or/and washing liquid or/and elutriation liquid discharged from the upgraded products A and C ; Then the liquid organic soil conditioner product obtained by blending the "pressed liquid or/and washing liquid or/and elutriation liquid" according to the soil improvement requirements of the crops and plots being applied; the "discharge" The press liquid or/and washing liquid or/and elutriation liquid”, the pH value does not exceed the range of 5.0 to 9.4, and the gram moles of Na + or/and K + or/and Mg 2+ contained therein are equal to those of the The liter volume ratio of water is ≤0.034mol/L, or the total wt% concentration of soluble sodium salts, potassium salts, and magnesium salts contained therein is ≤0.20% (wt%), or the soluble sodium salts, potassium salts contained therein are The difference between the total concentration of salt and magnesium salt and the total concentration of soluble sodium salt, potassium salt and magnesium salt in the water source taken from the production site is ≤0.01% (wt%); the weight ratio of auxiliary product E to main product A is Control within the range of product E/product A ≤ 100/100 ~ 300/100, that is, ≤ 100/100 or ≤ 300/100;
7-3.技术方案1所述“辅助产品F--发酵饲料产品”的制法,其特征至少在于:将技术方案2中ⅱ项所述“副产物料1:热水脱木素/树脂工序所排棕/黑液”或/和“或副产物料2:压榨鲜能源草所获的鲜汁液会”掺于仅经破/粉碎的能源草后,再经发酵,既可获得辅助产品F;7-3. The preparation method of "auxiliary product F - fermented feed product" described in technical solution 1, which is at least characterized in that: the "by-product material 1: hot water delignification/resin" described in item ii of technical solution 2 The brown/black liquor discharged from the process" or/and" or by-product material 2: The fresh juice obtained by squeezing the fresh energy grass will be mixed with the energy grass that has only been broken/crushed, and then fermented to obtain auxiliary products F;
7-4.技术方案1所述“辅助产品G--颗粒饲料产品”的制法,其特征至少在于:在以未经压榨处理的干能源草为起始主原料时,用筛取了主产品A用原料后的余料,既“过28目筛细粉”,或/和“过28至不过150目筛范围的含土量微的粒径居中的能源草纤维粉屑”,作为颗粒饲料产品中的配料组份;7-4. The preparation method of "auxiliary product G - pellet feed product" described in technical solution 1 is at least characterized in that: when using unpressed dry energy grass as the starting main raw material, the main raw material is screened out. The remaining materials after using the raw materials for Product A are "fine powder passed through a 28 mesh sieve", or/and "energy grass fiber powder with a small soil content and a medium particle size passed through a 28 mesh to no more than 150 mesh sieve", as particles. Ingredients in feed products;
7-5.技术方案1所述“辅助产品H--生物质颗粒燃料产品”的制法,其特征至少在于:以能源草被破碎、过筛脱除了未过28目筛之粗纤维的细粉料,或是全组份的能源草粉碎物,为配料组份,或再配加了废塑料的生物质颗粒燃料产品;所述“废塑料”,至少包括废农用塑膜、废泡沫塑料、废化纤织物或/和化纤棉絮的任一或多种的组合,所述的“配加”占辅助产品H之总重量的5%以下,或至可高不超22%;7-5. The preparation method of "auxiliary product H--biomass pellet fuel product" described in technical solution 1 is at least characterized by: using energy grass to crush and sieve to remove fine fibers that have not passed the 28-mesh sieve. Powder, or a full-component energy grass crushing material, as an ingredient component, or a biomass pellet fuel product with waste plastics added; the "waste plastics" include at least waste agricultural plastic films and waste foam plastics , any one or more combinations of waste chemical fiber fabrics or/and chemical fiber wadding, the "addition" accounting for less than 5% of the total weight of the auxiliary product H, or up to no more than 22%;
7-6.技术方案1所述“辅助产品I--食用菌种植棒/块产品”的制法,其特征至少在于:在以能源草,或能源草和牛粪为起始主原料时,用筛取了主产品A用原料后的余料,既过28目筛孔的能源草之粉料或和细牛粪沉渣,作为食用菌种植棒/块产品中的配料组份。7-6. The preparation method of "auxiliary product I - edible fungus planting stick/block product" described in technical solution 1 is at least characterized in that: when using energy grass, or energy grass and cow dung as the starting main raw materials, use The remaining materials after sifting out the raw materials for the main product A, namely energy grass powder or fine cow manure sediment that has passed through a 28-mesh sieve, are used as ingredients in the edible fungus planting stick/block product.
8.技术方案4至7所述“制法”所用及的设备,其特征还在于如下8-1至8-4或和8-5所述:8. The equipment used in the "preparation method" described in technical solutions 4 to 7 is also characterized by the following 8-1 to 8-4 or 8-5:
8-1.实施技术方案4所述“步骤一”至“步骤十”,涉及设置组合机械Ⅰ至Ⅹ:[0091]对实施技术方案4所述“步骤一”的“预处理备料”用组合机械Ⅰ,其中至少包括:设置破碎机械1、锯/碾/切/锤的任一或多种组合碎化机2、风选机械3、机械筛4,以对能源草干捆扎料在经破碎机,锯/碾/切/锤的任一或多种组合碎化机处理,再经风选、筛分后,筛取出能源草碎化物料中的过3目至不过28目筛范围的任一目数的分级或混和粒径的细长状纤维束;或在机械筛4之后再设置膨化机械5; 8-1. Implementing "step one" to "step ten" described in technical solution 4 involves setting up combination machinery I to Machinery Ⅰ, which at least includes: crushing machinery 1, any one or more combinations of saw/mill/cut/hammer crusher 2, air separation machinery 3, and mechanical screen 4 to crush the energy straw bundles Machine, any one or more combinations of sawing/milling/cutting/hammer crushing machine processing, and then through air selection and screening, screen out any energy grass crushed materials that pass the 3 mesh to the 28 mesh sieve range. One-mesh classification or mixed particle size elongated fiber bundles; or an expansion machine 5 is installed after the mechanical screen 4;
对实施技术方案4所述“步骤二”的“第一次配料”用组合机械Ⅱ,其中至少包括:设置放置“备用能源草碎化物”的配料仓6,盛载后续步骤七所述“第二次固液分离”所获的挤出水之液槽7,或和设置存放“表面活性剂”的料仓8,设置称重计量衡器9,设置对“第一次配料”后的混合搅拌器10;The combined machine II for the "first batching" of the "step two" described in the technical solution 4, at least includes: a batching bin 6 for placing the "backup energy grass crumbs", containing the "first batching" described in the subsequent step seven. A liquid tank 7 for the extruded water obtained from "secondary solid-liquid separation", or a bin 8 for storing "surfactant", a weighing scale 9, and a mixing and stirring device after the "first batching" device 10;
对实施技术方案4所述“步骤三”的“加热溶出”用组合机械Ⅲ,其中至少包括:设置搅拌混合和加热且保温的罐11;The combined machine III for implementing the "heated dissolution" of "step three" described in technical solution 4, at least includes: a tank 11 for stirring, mixing, heating and insulation;
对实施技术方案4所述“步骤四”的“第一次固液分离”用组合机械Ⅳ,其中至少包括:设置输送机械12、螺杆或扎辊式挤浆机13,固液分离机14,存放“第一次固液分离”所获的“压/挤出棕/黑液”的储槽15;The combined machinery IV for implementing the "first solid-liquid separation" of "step four" described in technical solution 4, at least includes: a conveying machine 12, a screw or roller squeezer 13, and a solid-liquid separator 14, Storage tank 15 for storing the "pressed/extruded brown/black liquor" obtained from the "first solid-liquid separation";
对实施技术方案4所述“步骤五”的“第二次配料”用组合机械Ⅴ,其中至少包括:设置“待处理亲水疏解纤维中间产物甲的潮料”的存料仓16,盛载后续步骤十所述“第三次固液分离”所获的挤出水之液槽17,或和设置存放“晶须助剂”的料仓18,设置称重计量衡器19,设置对“第二次配料”后的混合搅拌器20;The combined machine V for the "second batching" of the "step five" described in the technical solution 4, at least includes: a storage bin 16 for "tidal material to be processed of the hydrophilic decomposable fiber intermediate product A", containing The liquid tank 17 of the extruded water obtained in the "third solid-liquid separation" described in the subsequent step ten, or the silo 18 for storing the "whisker additive", the weighing scale 19, and the "third solid-liquid separation" are set up. Mixing mixer 20 after "secondary batching";
对实施技术方案4所述“步骤六”的“碾磨消潜”用组合机械Ⅵ,其中至少包括:设置高浓磨浆机21,在高浓磨浆机21的进料口之前设置待处理物料的储料仓22,在储料仓22与高浓磨浆机21之间,设置输送机构或输送机械23;在高浓磨浆机21的出料口之后,设置带保温或和加热功能的消潜罐24,在高浓磨浆机21的出料口与消潜罐24的进料口之间,设置输送机构或输送机械25;The combined machine VI for "grinding and latent elimination" in "step six" described in technical solution 4, which at least includes: setting up a high-consistency refiner 21, and setting a to-be-processed machine in front of the feed port of the high-consistency refiner 21 The material storage bin 22 is provided with a conveying mechanism or conveying machinery 23 between the storage bin 22 and the high-consistency refiner 21; after the outlet of the high-consistency refiner 21, a heat preservation or heating function is provided The submersion elimination tank 24 is provided with a conveying mechanism or conveying machinery 25 between the outlet of the high-consistency refiner 21 and the feed inlet of the submersion elimination tank 24;
对实施技术方案4所述“步骤七”的“第二次固液分离”用组合机械Ⅶ,其中至少包括:设置输送机械26、螺杆或扎辊式挤浆机27,固液分离机28,存放技术方案3中步骤七所述“‘第二次固液分离’所获的挤出水”之储槽19;The combined machinery VII for implementing the "second solid-liquid separation" of "step seven" described in technical solution 4 at least includes: a conveying machine 26, a screw or roller squeezer 27, and a solid-liquid separator 28, Storage tank 19 for storing the "extruded water obtained from the 'second solid-liquid separation'" described in step seven of technical solution 3;
对实施技术方案4所述对“步骤八”的“第三次配料”用组合机械Ⅷ,其中至少包括:设置存放技术方案4中步骤七所述“待处理亲水疏解纤维中间产物乙的潮料”之储料仓29,计量存放新水和循环净化水的储槽30,存放晶须助剂的料仓31,称量衡器32,搅拌混合槽33;The combined machine VIII for the "third batching" of "step eight" described in the technical solution 4, which at least includes: setting up and storing the moisture of the "hydrophilic decomposable fiber intermediate product B to be processed" described in the seventh step of the technical solution 4. The storage silo 29 of "material", the storage tank 30 for measuring and storing new water and circulating purified water, the silo 31 for storing whisker additives, the weighing scale 32, and the stirring and mixing tank 33;
对实施技术方案4所述对“步骤九”的“搅拌洗涤”用组合机械Ⅸ,其中至少包括:在前述的“搅拌混合槽33”后设置输送机构或输送机械34、螺杆或扎辊式挤浆机35,物料暂储槽36;The combined machine IX for "stirring and washing" of "step nine" described in technical solution 4, which at least includes: a conveying mechanism or conveying machine 34, screw or roller extruder is provided after the aforementioned "stirring and mixing tank 33" Pulp machine 35, material temporary storage tank 36;
对实施技术方案4所述“步骤十”的“第三次固液分离或和最后修饰”用组合机械Ⅹ,其中至少包括:设置输送机构或输送机械37、固液分离机38,设置存放掩蔽铁/锰离子助剂的料槽39、存放防霉助剂的料槽40;The combined machinery X for implementing the "third solid-liquid separation or final modification" of "step ten" described in technical solution 4, at least includes: setting up a conveying mechanism or conveying machine 37, a solid-liquid separator 38, and setting up a storage cover The trough 39 for iron/manganese ion additives and the trough 40 for storing anti-mildew additives;
8-2.实施技术方案5所述“联产制法”所用及的设备,涉及设置组合机械Ⅺ至Ⅹ Ⅲ:8-2. The equipment used to implement the "joint production method" described in technical solution 5 involves setting up combined machinery XI to XIII:
对实施技术方案5中5-1、5-2所述“制A与C-1联产”所用组合机械Ⅺ,其中至少包括:针对技术方案5中5-1所述的具体制法,设置对新鲜的能源草作去根、剥除叶片的操作机械41,设置再对新鲜能源草做清水洗净、脱水、晾干用清洗机械42,设置做新鲜能源草压榨取汁的压榨机43,设置储存压榨能源草鲜汁液的储料槽44,或再设置对鲜汁液做加热至沸或蒸发提浓的蒸馏釜45,设置冷却、装罐机械46;The combined machinery XI used to implement the "co-production of A and C-1" described in 5-1 and 5-2 of technical solution 5, at least includes: for the specific production method described in 5-1 of technical solution 5, set An operating machine 41 is used to remove roots and leaves of fresh energy grass. A cleaning machine 42 is provided for washing, dehydrating and drying the fresh energy grass. A press 43 is provided for squeezing and extracting juice from the fresh energy grass. Set up a storage tank 44 to store the fresh juice of pressed energy grass, or set up a distillation kettle 45 for heating the fresh juice to boiling or evaporation and concentration, and set up cooling and canning machinery 46;
和针对技术方案5中5-2所述的具体制法,设置对干能源草作去根、剥除叶片的操作机械47,或是设置对能源草干料做破碎、过筛的组合机械48,设置再对干能源草做清水洗净、脱水之清洗机械49,设置可再加水、加热至沸,然后做榨汁取榨的组合机械50,设置储存压榨能源草汁液的储料槽51,所述“能源草汁液”也既为技术方案2中ⅱ项所述的副产物料1--热水脱木素/树脂工序所排棕/黑液;或再设置对“能源草汁液”做加热至沸或蒸 发提浓的蒸馏釜52,设置冷却、装罐机械53;And for the specific production method described in 5-2 of technical solution 5, an operating machine 47 for removing roots and blades of dry energy grass is provided, or a combined machine 48 for crushing and screening the dry energy grass material is provided. , set up a cleaning machine 49 for washing and dehydrating the dried energy grass, a combined machine 50 that can add water, heat it to boiling, and then extract the juice, and a storage tank 51 for storing the squeezed energy grass juice, The "energy grass juice" is also the by-product material 1 described in item ii of the technical solution 2 - the brown/black liquor discharged from the hot water delignification/resin process; or it is further configured to process the "energy grass juice" Heat to boiling or steam The concentrated distillation kettle 52 is equipped with cooling and canning machinery 53;
对实施技术方案5中5-3至5-5所述“制A与C-2联产”所用组合机械Ⅻ,其中至少包括:针对技术方案5中5-3所述的具体制法,设置对新鲜的能源草作去根、剥除叶片的操作机械54,设置做新鲜能源草压榨取汁的压榨机55,设置储存压榨能源草鲜汁液的储料槽56,或再设置对鲜汁液做加热至沸或蒸发提浓的蒸馏釜57,设置冷却、装罐机械58;The combined machinery XII used to implement the "co-production of A and C-2" described in 5-3 to 5-5 of technical solution 5, which at least includes: for the specific production method described in 5-3 of technical solution 5, set An operating machine 54 for removing roots and leaves of fresh energy grass is provided, a press 55 for pressing fresh energy grass to extract juice is provided, a storage tank 56 for storing the fresh juice of the pressed energy grass is provided, or a press 55 for extracting juice from the fresh energy grass is provided. The distillation kettle 57 is heated to boiling or evaporated for concentration, and is equipped with cooling and canning machinery 58;
针对技术方案5中5-4所述的具体制法,设置对干能源草作去根、剥除叶片的操作机械59,或是设置对能源草干料做破碎、过筛的组合机械60,设置可再加水、加热至沸,然后做榨汁取榨的组合机械61,设置储存压榨能源草汁液的储料槽62;或再设置对“能源草汁液”做加热至沸或蒸发提浓的蒸馏釜63,设置冷却、装罐机械64;In view of the specific preparation method described in 5-4 of the technical solution 5, an operating machine 59 for removing roots and blades of dry energy grass is provided, or a combined machine 60 for crushing and screening the dry energy grass material is provided. Set up a combined machine 61 that can add water, heat it to boiling, and then extract the juice, and set up a storage tank 62 to store the squeezed energy grass juice; or set up a device that heats the "energy grass juice" to boiling or evaporates and thickens it. Distillation kettle 63, equipped with cooling and canning machinery 64;
针对技术方案5中5-5所述的具体制法,设置储存来源于组合机械Ⅺ中对能源草的“清水洗净”后的脱除水之用的储存槽65,设置用储存槽65的流出水对牛粪作淘洗、筛选的组合机械66,设置可再加水、加热至沸,然后做榨汁取榨的组合机械67,设置储存压榨能源草汁液的储料槽68;或再设置对“能源草汁液”做加热至沸或蒸发提浓的蒸馏釜69,设置冷却、装罐机械70;In view of the specific preparation method described in 5-5 of the technical solution 5, a storage tank 65 is provided for storing the dewatered water after "cleaning" the energy grass in the combined machine XI, and a storage tank 65 is provided. A combined machine 66 for washing and screening cow dung with outflow water, a combined machine 67 for adding water, heating to boiling, and then squeezing the juice, and a storage tank 68 for storing the squeezed energy grass juice; or A distillation kettle 69 for heating the "energy grass juice" to boiling or evaporation and concentration, and a cooling and canning machine 70;
对实施技术方案5中的5-6所述“后续可再走”、“后续可被导”细节所用组合机械Ⅹ Ⅲ,其中至少包括:设置分类收集仓71,设置将前述“压榨后的出渣”用水泡化成含固25%的呈松散肉松状物料之搅拌、加热的组合机械72;设置机械筛73,设置收集“过3目至不过28目筛孔范围的粒度分级或混合的细长状纤维束”的收集仓74;设置将收集仓74中的物料导送前述“组合机械Ⅴ”的“存料仓16”的输送机械75,设置收集槽76;The combined machinery XIII used to implement the details of "can be walked again" and "can be guided later" described in 5-6 of the technical solution 5, at least includes: setting up a classification collection bin 71, setting up the aforementioned "output after pressing" A combined machine 72 for stirring and heating the "slag" into a loose floss-like material with a solid content of 25%; a mechanical sieve 73 is set up to collect "slender and slender particles that pass through the 3 mesh to no more than 28 mesh sieve range for particle size classification or mixing" A collection bin 74 of "shaped fiber bundle"; a conveying mechanism 75 is provided to guide the materials in the collection bin 74 to the "storage bin 16" of the aforementioned "combined machine V", and a collection tank 76 is provided;
8-3.执行技术方案6所述“B”之“制法”所用及的设备,涉及设置子组合机械Ⅹ Ⅳ至Ⅹ Ⅶ,其中包括:8-3. The equipment used to implement the "Preparation Method" of "B" mentioned in Technical Solution 6 involves setting up sub-assembly machines XIV to XVII, including:
设置技术方案6中6-1的“备料”子组合装置Ⅹ Ⅳ,其中又包括:机械筛77,或再加破碎机械78、风选机械79;Set up the "material preparation" sub-assembly device XIV of 6-1 in the technical solution 6, which also includes: a mechanical screen 77, or a crushing machine 78 and a winnowing machine 79;
设置实施技术方案6中6-2的“配料”子组合装置Ⅹ Ⅴ,其中又包括:称重衡器80、分别存放所述“木塑复合再生质粗粒”组成中“木”与“塑”和软化剂的储料仓81,和计量配料后的混合槽82;Set up the "ingredients" sub-assembly device ⅩⅤ for implementing 6-2 in the technical solution 6, which also includes: a weighing scale 80, respectively storing "wood" and "plastic" in the composition of the "wood-plastic composite recycled material coarse particles" And the storage bin 81 of the softener, and the mixing tank 82 after metering and batching;
设置实施技术方案6中6-3的“造粒”子组合装置Ⅹ Ⅵ,其中又包括:输送机械83、粗粒造粒机84;Set up the "granulation" sub-assembly device XVI for implementing 6-3 in technical solution 6, which also includes: conveying machinery 83 and coarse granulator 84;
设置实施技术方案6中6-4至6-5的“均化混粒”、“称重包装”子组合装置Ⅹ Ⅶ其中又包括:均化混粒机85、称重包装机械86;Set up and implement the "homogenizing and mixing" and "weighing and packaging" sub-assembly devices XVII of 6-4 to 6-5 in the technical solution 6, which also include: a homogenizing and mixing machine 85 and a weighing and packaging machine 86;
8-4.执行技术方案7所述“辅助产品”之“制法”所用及的设备,涉及设置子组合机械Ⅹ Ⅷ至Ⅱ Ⅲ,其中包括:8-4. The equipment used to implement the "manufacturing method" of the "auxiliary products" described in Technical Solution 7 involves setting up sub-assembly machines XVIII to IIIII, including:
设置实施技术方案7中7-1“辅助产品D--固态有机土壤改良剂”制法所用子组合装置Ⅹ Ⅷ,其特征在于:包含一套制备固态有机土壤改良剂的组合装置87;Set up the sub-assembly device XVIII used in the preparation method of 7-1 "auxiliary product D--solid organic soil conditioner" in the technical solution 7, which is characterized in that: it includes a set of assembly devices 87 for preparing solid organic soil conditioner;
设置实施技术方案7中7-2“辅助产品E--液态有机土壤改良剂”制法所用子组合装置Ⅹ Ⅸ,其特征在于:包含一套制备液态有机土壤改良剂产品的组合装置88;Set up the sub-assembly device XIX used to implement the 7-2 "auxiliary product E--liquid organic soil conditioner" preparation method in the technical solution 7, which is characterized in that: it includes a set of assembly devices 88 for preparing liquid organic soil conditioner products;
设置实施技术方案7中7-3“辅助产品F--发酵饲料”制法所用子组合装置Ⅱ Ⅹ,其特征在于:包含一套制备发酵饲料产品的组合装置89;Set up the sub-assembly device II X used in the preparation method of 7-3 "auxiliary product F--fermented feed" in the technical solution 7, which is characterized in that: it includes a set of assembly device 89 for preparing fermented feed products;
设置实施技术方案7中7-4“辅助产品G--颗粒饲料”制法所用子组合装置Ⅱ Ⅰ,其特征在于:包含一套制备颗粒饲料产品的组合装置90;Set up the sub-assembly device II I used to implement the 7-4 "auxiliary product G-pellet feed" preparation method in the technical solution 7, which is characterized by: including a set of assembly devices 90 for preparing pellet feed products;
设置实施技术方案7中7-5“辅助产品H--生物质颗粒燃料”制法所用子组合装置Ⅱ Ⅱ,其特征在于:包含一套制备生物质颗粒燃料产品的组合装置91; Set up a sub-assembly device II II used to implement the preparation method of 7-5 "auxiliary product H - biomass pellet fuel" in the technical solution 7, which is characterized by: including a set of assembly devices 91 for preparing biomass pellet fuel products;
设置实施技术方案7中7-6“辅助产品H--生物质颗粒燃料”制法所用子组合装置Ⅱ Ⅲ,其特征在于:包含一套制备食用菌种植棒/块产品的组合装置92;Set up the sub-assembly device II III used to implement the 7-6 "auxiliary product H--biomass pellet fuel" preparation method in the technical solution 7, which is characterized by: including a set of assembly devices 92 for preparing edible fungus planting rods/block products;
8-5.或和可将如前8-1至8-4中所述1至88的各单元机械,规整设置入标准集装箱中。8-5. Alternatively, each unit of machinery from 1 to 88 as described in 8-1 to 8-4 above can be arranged neatly into a standard container.
9.技术方案1至8所述“产品”或/和“制法”或/和“设备”的用途,至少包括如下所述的任一或多种的组合:9. The uses of the “products” or/and “preparation methods” or/and “equipment” described in technical solutions 1 to 8 include at least any one or a combination of more of the following:
9-1.技术方案1、2所述“主产品A--亲水疏解纤维”,其用途至少可被用作制备育秧纸、瓦楞纸、纸板,或/和包括蛋托、方便餐盘/碗、纸质育苗盆/钵等在内的纸模塑制品中作部分或全部地替代废纸再生纸浆的一种替代材料;也可作为做进一步深加工,如制漂白纸浆的新起始原料;或是作为制备纤维素醚的原料;9-1. The "Main Product A - Hydrophilic Decomposable Fiber" described in Technical Schemes 1 and 2 can at least be used to prepare rice paper, corrugated paper, cardboard, or/and include egg trays and convenient dinner plates/bowls. It can be used as an alternative material to partially or completely replace waste paper recycled pulp in paper molded products such as paper seedling pots/bowls, etc.; it can also be used as a new starting material for further processing, such as making bleached pulp; or It is used as raw material for preparing cellulose ether;
9-2.技术方案1、3所述“副产品B--木塑复合再生质粗粒”,其用途至少可被用作热挤出木塑制品用木塑颗粒的待改性或/和精制的原料,或是直接用作热挤出木塑制品的一种新剂型原料,也可作为一种供热用的颗粒质燃料;9-2. The "by-product B - wood-plastic composite recycled coarse particles" described in technical solutions 1 and 3 can be used at least as wood plastic particles to be modified or/and refined for hot extrusion of wood-plastic products. raw material, or directly used as a new formulation raw material for hot extrusion wood plastic products, or as a granular fuel for heating;
9-3.技术方案1所述“副产品C-1--食用或医用级的木素/树脂混合物”,其用途至少可被用作制备饮料或/和中药制剂的原料;9-3. The "by-product C-1 - edible or medical grade lignin/resin mixture" described in technical solution 1 can be used at least as a raw material for preparing beverages or/and traditional Chinese medicine preparations;
9-4.技术方案1所述“副产品C-2--饲用或工业级的木素/树脂混合物”,其用途至少可被用作制备饲料原料,或/和混凝土的减水剂、橡胶/塑料中的软化剂的任一种;9-4. The "by-product C-2 - feed or industrial grade lignin/resin mixture" described in technical solution 1 can be used at least as a feed raw material, or/and as a water-reducing agent for concrete and rubber. /Any kind of softener in plastics;
9-5.技术方案1至8所述“产品”、“制法”、“设备”,至少可被用于对包括巨菌草等在内的技术方案2中ⅰ项里所述“原料”的加工;或被扩展地应用于对竹子、甘蔗皮等的加工;9-5. The "products", "preparation methods" and "equipment" described in technical solutions 1 to 8 can at least be used for the "raw materials" described in item i of technical solution 2, including Giant Juncao, etc. Processing; or be expanded to the processing of bamboo, sugar cane peel, etc.;
9-6.技术方案1至8所述“产品”、“制法”、“设备”,皆可成为独立的商品。9-6. The "products", "production methods" and "equipment" mentioned in technical solutions 1 to 8 can all become independent commodities.
10.技术方案1至9的任一或多项所述的“产品”或/和“制法”的商业运作模式,至少包括如下所述的任一或多种的组合:10. The business operation model of the “product” or/and “process” described in any one or more of technical solutions 1 to 9, at least includes any one or a combination of the following:
10-1.可由一家企业独立地实施“产品”或/和“制法”的商业运营;10-1. One enterprise can independently implement the commercial operation of "products" or/and "manufacturing methods";
10-2.可由多家企业分割“产品”品种,或/和分段“制法”过程来协同地实施商业运营;10-2. Multiple companies can divide "product" varieties, or/and segment "manufacturing" processes to collaboratively implement commercial operations;
10-3.可用自营或外发代工的商业模式实施“产品”或/和“制法”的商业运营;10-3. The business model of self-operated or outsourced manufacturing can be used to implement the commercial operation of "products" or/and "manufacturing methods";
10-4.所述的商业运营,其中使用包括固/液态有机土壤改良剂在内的涉农产品,与农户或农耕经营者易货包括粮棉油大田之秸秆在内的能源草。10-4. The described commercial operations, which use agricultural products including solid/liquid organic soil conditioners, and barter with farmers or farming operators for energy grass including straw from grain, cotton and oil fields.
附图说明Description of the drawings
图1为过3目至不过28目筛的粒径混合的能源草之一的桑树枝丫的细长状纤维束之黑白照片。Figure 1 is a black and white photo of the elongated fiber bundles of Mulberry branch Ya, one of the mixed energy grasses with particle sizes ranging from 3 mesh to 28 mesh.
图2为过3目至不过28目筛的粒径混合的能源草之一的水稻秸秆的细长状纤维束之黑白照片。Figure 2 is a black and white photo of the elongated fiber bundles of rice straw, one of the mixed energy grasses, which has passed through a sieve of 3 mesh to 28 mesh.
图3为亲水疏解纤维A-1之干团料样品的黑白照片,其是由能源草之一的油芍药秸秆在实验室中所制获。Figure 3 is a black and white photo of a dry mass sample of hydrophilic and decomposable fiber A-1, which was prepared in the laboratory from Paeonia oleifera straw, one of the energy grasses.
图4为亲水疏解纤维A-2之干团料样品的黑白照片,其是由能源草之一的桑树枝丫在实验室中所制获。Figure 4 is a black and white photo of a dry mass sample of hydrophilic decomposable fiber A-2, which was prepared in the laboratory from mulberry branch Ya, one of the energy grasses.
图5为用能源草之一的麦子秸秆在实验室中被制成亲水疏解纤维A-2后所抄纸片再仅经手抓一次被折再展开呈纸片被折破实样的黑白照片。Figure 5 is a black-and-white photo of the actual broken paper after being made from wheat straw, one of the energy grasses, into hydrophilic decomposable fiber A-2 in the laboratory. The paper was folded and unfolded after being grasped once. .
图6为副产品C-2--饲用或工业级的木素/树脂混合物的黑白照片,其可被配方施用 饲料添加剂、植物营养剂,或被用作橡/塑助剂等。Figure 6 is a black and white photo of by-product C-2, a feed or industrial grade lignin/resin mixture that can be formulated for application Feed additives, plant nutrients, or used as rubber/plastic additives, etc.
图7是废纸制再生纸浆所排弃杂废塑膜料的黑白照片。Figure 7 is a black-and-white photo of plastic film materials discarded from waste paper to recycled pulp.
图8是木塑复合再生质粗粒B的一张黑白照片。Figure 8 is a black and white photo of wood plastic composite recycled coarse grain B.
图9为一个干团料标样的黑白照片。Figure 9 is a black and white photo of a dry dough standard sample.
图10为图9所述“标样”,其来源于自然界的一棵柳树下之地面堆积的天牛幼虫或木蠹蛾幼虫蛀食柳树杆的粪便,这是所述“粪便”在柳树下的黑白照片,照片中箭头所指既是所述“粪便”。Figure 10 is the "standard sample" described in Figure 9, which is derived from the feces of beetle larvae or wood moth larvae that eat the willow stems accumulated on the ground under a willow tree in nature. This is the "feces" under the willow tree. The black and white photo, the arrow in the photo points to the "feces".
图11为图9、10所述“标样”,在被采集入实验室中在还未作筛选等处理时模样的黑白照片,其真实颜色为棕色。Figure 11 is a black and white photo of what the "standard sample" described in Figures 9 and 10 looks like when it is collected in the laboratory and has not been screened or processed. Its true color is brown.
图12是图9标样与图4样品做对搓比较俩者所掉屑料的黑白照片。Figure 12 is a black and white photo of the scraps produced by comparing the standard sample in Figure 9 and the sample in Figure 4.
图13是制备“主产品A--亲水疏解纤维”的十个步骤之方框示意图。Figure 13 is a schematic block diagram of the ten steps for preparing "main product A--hydrophilic and decomposable fiber".
图14是本发明所述产品集合制法所用及工艺设备流程的方框示意图,其中位于由“·-”所围δ区块中的Ⅰ至Ⅹ为制备主产品A所用的工艺设备流程,由“·-”所围ε区块中的Ⅺ至Ⅹ Ⅲ为主产品A与副产品C-1/C-2联产所用的工艺设备流程,由“·-”所围ζ区块中的Ⅹ Ⅳ至Ⅹ Ⅶ为制备副产品B所用的工艺设备流程,由“·-”所围η区块中的Ⅹ Ⅷ至Ⅱ Ⅲ为制备辅助产品D至I所用的工艺设备流程,图中编号的定义为:Figure 14 is a block schematic diagram of the process equipment flow used in the product assembly manufacturing method of the present invention, in which I to X located in the δ block surrounded by "·-" are the process equipment flow used to prepare the main product A, as shown in Ⅺ to to XVII are the process equipment flows used to prepare by-product B, and XVIII to II III in the block surrounded by "·-" are the process equipment flows used to prepare auxiliary products D to I. The definition of the numbers in the figure is:
Ⅰ为制备主产品A中“步骤一”的“预处理备料”用子组合机械,其中至少包括:1--破碎机械、2--锯/碾/切/锤的任一或多种组合碎化机、3--风选机械、4--机械筛,5--膨化机械;Ⅰ is the sub-combination machinery for "pretreatment and preparation" of "Step 1" in the preparation of main product A, which at least includes: 1--crushing machinery, 2--any or more combinations of sawing/milling/cutting/hammer crushing Chemical machine, 3--Wind separation machinery, 4--Mechanical screen, 5--Puffing machinery;
Ⅱ为制备主产品A中“步骤二”的“第一次配料”用子组合机械,其中至少包括:6--“备用能源草碎化物”的配料仓,7--盛载后续步骤七所述“第二次固液分离”所获的挤出水之液槽,8--存放“表面活性剂”的料仓,9--称重计量衡器,10--对“第一次配料”后的混合搅拌器;Ⅱ is a sub-assembly machine for preparing the "first batching" of "step two" in main product A, which at least includes: 6--the batching bin for "backup energy grass crumbs", 7--containing the ingredients for the subsequent step seven. The liquid tank of the extruded water obtained from the "second solid-liquid separation", 8--the silo storing the "surfactant", 9--the weighing and measuring instrument, 10--the "first batching" The final mixing agitator;
Ⅲ为制备主产品A中“步骤三”的“加热溶出”用子组合机械,其中至少包括:11--搅拌混合和加热且保温的罐;Ⅲ is the sub-assembly machinery for the "heating and dissolution" of "Step 3" in the preparation of main product A, which at least includes: 11--tanks for stirring, mixing, heating and insulation;
Ⅳ为制备主产品A中“步骤四”的“第一次固液分离”用子组合机械,其中至少包括:12--输送机械、13--螺杆或扎辊式挤浆机,14--固液分离机,15--存放“第一次固液分离”所获的“压/挤出棕/黑液”的储槽;Ⅳ is the sub-assembly machinery used for the "first solid-liquid separation" in "Step 4" in the preparation of main product A, which at least includes: 12--conveying machinery, 13--screw or roller extruder, 14-- Solid-liquid separator, 15--a storage tank that stores the "pressed/extruded brown/black liquor" obtained from the "first solid-liquid separation";
Ⅴ为制备主产品A中“步骤五”的“第二次配料”用子组合机械,其中至少包括:16--“待处理亲水疏解纤维中间产物甲的潮料”的存料仓,17--盛载后续步骤十所述“第三次固液分离”所获的挤出水之液槽,18--存放“晶须助剂”的料仓,19--称重计量衡器,20--对“第二次配料”后的混合搅拌器20;Ⅴ is the sub-assembly machine for preparing the "second batching" of "Step 5" in the main product A, which at least includes: 16--the storage bin of "the moisture material of the hydrophilic decomposable fiber intermediate product A to be processed", 17 --The liquid tank containing the extruded water obtained from the "third solid-liquid separation" described in the subsequent step ten, 18--The silo storing the "whisker additive", 19--Weighing and measuring instruments, 20 --Mixing mixer 20 after "second batching";
Ⅵ为制备主产品A中“步骤六”的“碾磨消潜”用子组合机械,其中至少包括:21--高浓磨浆机,22--待处理物料的储料仓,23--输送机构或输送机械23;24--带保温或和加热功能的消潜罐25--输送机构或输送机械;Ⅵ is the sub-assembly machine for "grinding and latent elimination" in "Step 6" in the preparation of main product A, which at least includes: 21--high-consistency refiner, 22--storage silo for materials to be processed, 23-- Conveying mechanism or conveying machinery 23; 24--submersible tank with insulation or heating function 25--conveying mechanism or conveying machinery;
Ⅶ为制备主产品A中“步骤七”的“第二次固液分离”用子组合机械,其中至少包括:26--输送机械、27--螺杆或扎辊式挤浆机,28--固液分离机;Ⅶ is the sub-assembly machinery for the "second solid-liquid separation" in "Step 7" in the preparation of main product A, which at least includes: 26--conveying machinery, 27--screw or roller extruder, 28-- Solid-liquid separator;
Ⅷ为制备主产品A中“步骤八”的“第三次配料”用子组合机械,其中至少包括:29--存放“待处理亲水疏解纤维中间产物乙的潮料”之储料仓,30计量存放新水和循环净化水的储槽,31--存放晶须助剂的料仓,32--称量衡器,33--搅拌混合槽;Ⅷ is a sub-assembly machine for the "third batching" of "Step 8" in the preparation of main product A, which at least includes: 29--a storage silo for storing "the moisture material of the hydrophilic decomposable fiber intermediate product B to be processed", 30 is a storage tank for measuring and storing new water and circulating purified water, 31--silo for storing whisker additives, 32--weighing instrument, 33--stirring and mixing tank;
Ⅸ为制备主产品A中“步骤九”的“搅拌洗涤”用子组合机械,其中至少包括:34--输送机构或输送机械34、35--螺杆或扎辊式挤浆机,36--物料暂储槽; Ⅸ is a sub-assembly machine for "stirring and washing" in "Step 9" in the preparation of main product A, which at least includes: 34--conveying mechanism or conveying machinery 34, 35--screw or roller squeezer, 36-- Material temporary storage tank;
Ⅹ为制备主产品A中“步骤十”的“第三次固液分离或和最后修饰”用组合机械,其中至少包括:37--输送机构或输送机械、38--固液分离机,39--存放掩蔽铁/锰离子助剂的料槽、40--存放防霉助剂的料槽;Ⅹ is the combined machinery for the "third solid-liquid separation or final modification" in "Step 10" in the preparation of the main product A, which at least includes: 37--conveying mechanism or conveying machinery, 38--solid-liquid separator, 39 --Trough for storing iron/manganese ion masking additives, 40--Trough for storing anti-mildew additives;
Ⅺ为主产品A与副产品C-1联产制法所用及子组合机械,其中至少包括:41--对新鲜的能源草作去根、剥除叶片的操作机械41,42--对新鲜能源草做清水洗净、脱水、晾干用清洗机械,43--做“水洗净后的鲜能源草”压榨取汁的压榨机,44--储存压榨能源草鲜汁液的储料槽,45--对鲜汁液做加热至沸或蒸发提浓的蒸馏釜,46--冷却、装罐机械;ⅪMachines and sub-combinations used in the co-production method of main product A and by-product C-1, including at least: 41--operating machinery for removing roots and leaves of fresh energy grass 41, 42--for fresh energy Cleaning machinery for washing, dehydrating and drying grass, 43--a press for squeezing and extracting juice from "fresh energy grass after washing with water", 44--a storage tank for storing the fresh juice of pressed energy grass, 45 --Stills for heating fresh juice to boiling or evaporating and thickening it, 46--cooling and canning machinery;
47--对干能源草作去根、剥除叶片的操作机械47,48--对能源草干料做破碎、过筛的组合机械,49--对干能源草做清水洗净、脱水之清洗机械,50--可再加水、加热至沸,然后做榨汁取榨的组合机械,51--储存压榨能源草汁液的储料槽,52--对“能源草汁液”做加热至沸或蒸发提浓的蒸馏釜,53--冷却、装罐机械;47--A machine for removing roots and leaves from dry energy grass. 47, 48--A combined machine for crushing and screening dry energy grass material. 49--A machine for washing and dehydrating dry energy grass. Cleaning machinery, 50--a combined machine that can add water, heat it to boiling, and then squeeze it out, 51--a storage tank for storing squeezed energy grass juice, 52--heat the "energy grass juice" to boiling Or distillation kettle for evaporation and concentration, 53--cooling and canning machinery;
Ⅻ为主产品A与副产品C-2联产制法所用及子组合机械,其中至少包括:54--对新鲜的能源草作去根、剥除叶片的操作机械,55--做新鲜能源草压榨取汁的压榨机,56--储存压榨能源草鲜汁液的储料槽,57--对鲜汁液做加热至沸或蒸发提浓的蒸馏釜,58--冷却、装罐机械;Ⅻ Machinery used in the joint production of main product A and by-product C-2 and sub-combination machinery, including at least: 54--operating machinery for removing roots and leaves of fresh energy grass, 55--making fresh energy grass A press for squeezing and extracting juice, 56 - a storage tank for storing the fresh juice of pressed energy grass, 57 - a distillation kettle for heating the fresh juice to boiling or evaporation and concentration, 58 - cooling and canning machinery;
59--对干能源草作去根、剥除叶片的操作机械,60--对能源草干料做破碎、过筛的组合机械,61--可再加水、加热至沸,然后做榨汁取榨的组合机械,62--储存压榨能源草汁液的储料槽,63--对“能源草汁液”做加热至沸或蒸发提浓的蒸馏釜,64--冷却、装罐机械;59--A machine for removing roots and leaves from dry energy grass, 60--A combined machine for crushing and screening dry energy grass materials, 61--It can add water, heat it to boiling, and then make juice. Combined machinery for extracting and squeezing, 62--storage tank for storing pressed energy grass juice, 63--distillation kettle for heating "energy grass juice" to boiling or evaporation and concentration, 64--cooling and canning machinery;
65--储存来源于组合机械Ⅺ中对能源草的“清水洗净”后的脱除水之用的储存槽,66--对牛粪作淘洗、筛选的组合机械,67--可再加水、加热至沸,然后做榨汁取榨的组合机械,68--储存压榨能源草汁液的储料槽,69--对“能源草汁液”做加热至沸或蒸发提浓的蒸馏釜,70--冷却、装罐机械;65--A storage tank used to store the water removed from the "clean water" of the energy grass in the combined machine XI, 66--A combined machine for washing and screening cow dung, 67--It can be reused Add water, heat to boiling, and then make a combined machine for squeezing and extracting juice, 68--a storage tank for storing the squeezed energy grass juice, 69--a still for heating the "energy grass juice" to boiling or evaporation and concentration, 70--Cooling and filling machinery;
Ⅹ Ⅲ为主产品A与副产品C联产制法中“后续”分流处置所用子组合机械,其中至少包括:71--设置分类收集仓,72--将“压榨后的出渣”用水泡化成含固25%的呈松散肉松状物料之搅拌、加热的组合机械;73--机械筛,74--收集仓;75--输送机械,76--收集槽;ⅩⅢ is a sub-assembly of machinery used for "subsequent" diversion treatment in the co-production method of main product A and by-product C, which at least includes: 71--Setting up a classification collection bin, 72--Breaking the "slag after pressing" into Combined machinery for stirring and heating loose floss-like materials with a solid content of 25%; 73--mechanical screen, 74--collection bin; 75--conveying machinery, 76--collection tank;
Ⅹ Ⅳ为副产品B制法中“备料”用子组合装置,其中又包括:77--机械筛,78--破碎机械、79--风选机械;Ⅹ Ⅳ is a sub-assembly device for "material preparation" in the production method of by-product B, which also includes: 77--mechanical screen, 78--crushing machinery, 79--wind separation machinery;
Ⅹ Ⅴ为副产品B制法中“配料”子组合装置,其中又包括:80--称重衡器、81--分别存放所述“木塑复合再生质粗粒”组成中“木”与“塑”和软化剂的储料仓,82--计量配料后的混合槽;Ⅹ Ⅴ is the "ingredient" sub-assembly device in the by-product B production method, which also includes: 80--weighing instrument, 81--respectively store the "wood" and "plastic" in the composition of the "wood-plastic composite recycled material coarse particles" "And the storage silo of softener, 82--the mixing tank after metering and batching;
Ⅹ Ⅵ为副产品B制法中“造粒”子组合装置,其中又包括:83--输送机械、84--粗粒造粒机;Ⅹ Ⅵ is the "granulation" sub-assembly device in the by-product B production method, which also includes: 83--conveying machinery, 84--coarse granulator;
Ⅹ Ⅶ为副产品B制法中“均化混粒”和“称重包装”子组合装置,其中又包括:85--均化混粒机、86--称重包装机械;Ⅹ Ⅶ is the "homogenization mixing" and "weighing packaging" sub-assembly device in the by-product B production method, which also includes: 85--homogenization mixer, 86--weighing packaging machinery;
Ⅹ Ⅷ为辅助产品D之制法所用及的子组合机械,其中包括:87--包含一套制备固态有机土壤改良剂的组合装置;Ⅹ Ⅷ is the sub-assembly machinery used in the preparation method of auxiliary product D, including: 87-contains a set of assembly equipment for preparing solid organic soil conditioner;
Ⅹ Ⅸ为辅助产品E之制法所用及的子组合机械,其中包括:88--包含一套制备液态有机土壤改良剂产品的组合装置;Ⅹ Ⅸ is a sub-assembly of machinery used in the preparation method of auxiliary product E, including: 88 - a set of assembly devices for preparing liquid organic soil conditioner products;
Ⅱ Ⅹ为辅助产品F之制法所用及的子组合机械,其中包括:89--包含一套制备发酵饲料产品的组合装置;Ⅱ and Ⅹ are the sub-assembly machines used in the preparation method of auxiliary product F, including: 89-including a set of assembly devices for preparing fermented feed products;
Ⅱ Ⅰ为辅助产品G之制法所用及的子组合机械,其中包括:90--包含一套制备颗粒饲料产品的组合装置; Ⅱ Ⅰ is the sub-assembly machinery used in the preparation method of auxiliary product G, including: 90-including a set of assembly equipment for preparing pellet feed products;
Ⅱ Ⅱ为辅助产品H之制法所用及的子组合机械,其中包括:91--包含一套制备生物质颗粒燃料产品的组合装置;Ⅱ Ⅱ is the sub-assembly machinery used in the preparation method of auxiliary product H, including: 91-including a set of assembly equipment for preparing biomass pellet fuel products;
Ⅱ Ⅲ为辅助产品I之制法所用及的子组合机械,其中包括:92--包含一套制备食用菌种植棒/块产品的组合装置。Ⅱ and Ⅲ are sub-assembly machines used in the preparation method of auxiliary product I, including: 92-including a set of combined devices for preparing edible fungus planting sticks/block products.
具体实施方式Detailed ways
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明技术方案中的一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都应属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only some of the embodiments of the technical solutions of the present invention, not all of them. Example. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts should fall within the scope of protection of the present invention.
实施例1.以能源草为原料的清洁化产品集合,其特征在于:以能源草,或能源草和牛粪为起始主原料,经加工子路径的串并联集成清洁生产之工艺及组合设备或装置阵,最后制得清洁化产品集合,所述“产品集合”具体由如下所述的主产品A,或主产品A再与副产品B、C的任一或两种产品的组合所构成;或主产品A或和副产品B/C,再与辅助产品D、E、F、G、H、I的任一或多种产品的组合所构成:Embodiment 1. A collection of clean products using energy grass as raw material, characterized in that: using energy grass, or energy grass and cow dung as the starting main raw materials, the process and combined equipment of clean production are integrated in series and parallel through processing sub-paths, or The device array finally produces a set of cleaning products. The "product set" is specifically composed of the main product A as described below, or a combination of the main product A and any one or two of the by-products B and C; or Main product A or by-product B/C, combined with any one or more of auxiliary products D, E, F, G, H, I:
主产品A--亲水疏解纤维,特征是:以前述“能源草,或能源草和牛粪”经锯/碾/切/锤的任一或多种组合碎化再过筛处理,获得其中的“过3目至不过28目筛范围的任一目数的分级或混合粒径的细长状纤维束”碎化物,以其为原料;制备过程中会排出棕/黑液,所述“棕/黑液”的重量份W棕/黑液,与所获主产品A中含水不超15%的绝干纤维之重量份WA的比例在W棕/黑液/WA=90~100~300/100范围;且“棕/黑液”中所含Na+或/和K+或/和Mg2+的克摩尔与其所含水的升体积之比为≤0.034mol/L,其pH值在5.0~9.4范围,既各指标都未踏入盐碱地特征值范围;使用的助剂中,所含苛性碱、氨、铵盐、过氧化物、生物酶的任一或多种的总含量为0;或和制备中使用水不溶或难溶性物质做晶须助剂,对纤维表面实施低灰分的晶须接枝/包覆,所述“晶须助剂”,对主产品A或其中间产物里的绝干纤维100重量份的添加量,为≤1~3~5~9重量份,既≤1重量份或≤3重量份或≤5重量份或≤9重量份;所述主产品A——亲水疏解纤维产品,其入水或再经搅拌后能不浮水面;The main product A - hydrophilic decomposable fiber, characterized by: using the aforementioned "energy grass, or energy grass and cow dung", crushed by any or more combinations of sawing/milling/cutting/hammering and then sieving to obtain the "Elongated fiber bundles of any mesh size that pass through a sieve ranging from 3 mesh to no more than 28 mesh" are used as raw materials; the brown/black liquor will be discharged during the preparation process, and the "brown/black liquor" will be discharged. The ratio of the weight part W brown/black liquor of "black liquor" to the weight part W A of the absolute dry fiber containing no more than 15% water in the main product A is W brown/black liquor /W A = 90~100~300 /100 range; and the ratio of the gram moles of Na + or/and K + or/and Mg 2+ contained in the "brown/black liquor" to the liter volume of the water contained is ≤0.034mol/L, and its pH value is within In the range of 5.0 to 9.4, each indicator does not fall within the characteristic value range of saline-alkali land; among the additives used, the total content of any one or more of caustic alkali, ammonia, ammonium salts, peroxides, and biological enzymes is 0 ; Or use water-insoluble or poorly soluble substances as whisker additives during preparation, and implement low-ash whisker grafting/coating on the fiber surface. The "whisker additive" can be used for the main product A or its intermediate product The added amount of absolute dry fiber in 100 parts by weight is ≤1~3~5~9 parts by weight, which is ≤1 part by weight or ≤3 parts by weight or ≤5 parts by weight or ≤9 parts by weight; the main product A ——Hydrophilic and decomposable fiber products that do not float to the surface after being put into water or stirred;
所述主产品A,其又可被细分有主产品A-1--被控制为低亲水之打浆度<16°SR的亲水疏解纤维,和主产品A-2--被控制呈高亲水之打浆度≥16°SR的亲水疏解纤维;The main product A can be subdivided into the main product A-1--a hydrophilic decomposable fiber controlled to have a low hydrophilicity of beating degree <16°SR, and the main product A-2--controlled to be Hydrophilic and decomposable fiber with high hydrophilic beating degree ≥16°SR;
副产品B--木塑复合再生质粗粒;特征是:至少以前述“能源草”经锯/碾/切/锤的任一或多种组合碎化,再经筛分处理后所获其中的另一部分:“过28目筛的细屑料或/和粉碎物,或和过3目筛的粗细混合的碎化物”,再取其与“废塑料”为原料,或和再与A中所述“棕/黑液”存在传质联系,使用生物质燃料颗粒机制粒;By-product B - wood-plastic composite regenerated coarse particles; characterized by: at least the above-mentioned "energy grass" is crushed by any one or more combinations of sawing/milling/cutting/hammering, and then screened. The other part: "Fine materials or/and crushed materials that pass through a 28-mesh sieve, or crushed materials that are mixed with coarse and fine materials that pass through a 3-mesh sieve", and then use them with "waste plastics" as raw materials, or mix them with those in A The above-mentioned "brown/black liquor" has a mass transfer connection and is pelletized using a biomass fuel pellet machine;
副产品C--木素/树脂混合物,特征是:以A中所述“棕/黑液”为原料所制获,在室温下呈红茶色的亲水性液体,或呈面酱状棕褐或近黑色胶体,或呈咖啡或近黑色粉体或颗粒,或呈松香状固体;所述副产品C,其中又可被细分有副产品C-1--食用或医用级的木素/树脂混合物,副产品C-2--饲用或工业级的木素/树脂混合物;By-product C - lignin/resin mixture, characterized by: It is produced using the "brown/black liquor" mentioned in A as raw material. It is a hydrophilic liquid in the color of black brown at room temperature, or in the form of a paste-like brown or Nearly black colloid, or in the form of coffee or nearly black powder or granules, or in the form of rosin-like solid; the by-product C, which can be subdivided into by-product C-1-edible or medical grade lignin/resin mixture, By-product C-2--feed or industrial grade lignin/resin mixture;
辅助产品D--固态有机土壤改良剂,特征是:在提取了“能源草,或能源草和牛粪”中不过28目筛孔料制主产品A后的余料,既过28目筛孔的能源草之粉料或和细牛粪沉渣,作为固态有机土壤改良剂中的配料之一;Auxiliary product D - solid organic soil conditioner, characterized by: the remaining material after extracting "energy grass, or energy grass and cow dung" that does not pass the 28-mesh sieve to make the main product A. Energy grass powder or fine cow dung sediment is used as one of the ingredients in the solid organic soil conditioner;
辅助产品E--液态有机土壤改良剂,特征是:利用在制备亲水疏解纤维主产品A的过程中会排出棕/黑液,或/和利用因提质主产品A和副产品C而排出的压榨液或/和洗涤液或/和淘洗液,按所被施农作物和田块的土质需要所搀兑出的产品;所述“排出的压榨液或/ 和洗涤液或/和淘洗液”或“棕/黑液”,其pH值在5.0~9.4范围,和其中所含Na+或/和K+或/和Mg2+的克摩尔与其所含水的升体积之比为≤0.034mol/L,或其中所含的可溶性钠盐、钾盐、镁盐的wt%总浓度≤0.20%(wt%),或其中所含的可溶性钠盐、钾盐、镁盐的总浓度与生产实施地所取水源中的可溶性钠盐、钾盐、镁盐的总浓度之差≤0.01%(wt%);辅助产品E与主产品A的重量之比被控制在WE/WA≤500/100或≤或2000/100≤或3000/100范围;Auxiliary product E - liquid organic soil conditioner, characterized by: utilizing the brown/black liquor discharged during the preparation of the hydrophilic decomposable fiber main product A, or/and utilizing the discharged liquid due to the upgrading of the main product A and by-product C Pressed liquid or/and washing liquid or/and elutriated liquid, products blended according to the soil quality requirements of the crops and fields to be applied; the "discharged pressed liquid or/and and washing liquid or/and elutriation liquid" or "brown/black liquor", its pH value is in the range of 5.0 to 9.4, and the gram mole of Na + or/and K + or/and Mg 2+ contained therein is the same as that contained in it. The liter volume ratio of water is ≤0.034mol/L, or the total wt% concentration of soluble sodium salts, potassium salts, and magnesium salts contained therein is ≤0.20% (wt%), or the soluble sodium salts, potassium salts contained therein are The difference between the total concentration of salt and magnesium salt and the total concentration of soluble sodium salt, potassium salt and magnesium salt in the water source taken from the production site is ≤0.01% (wt%); the weight ratio of auxiliary product E to main product A is Control within the range of W E /W A ≤500/100 or ≤ or 2000/100 ≤ or 3000/100;
辅助产品F--发酵饲料,特征是:在产品里掺入了主产品A制备过程中所排出的“棕/黑液”;Auxiliary product F - fermented feed, characterized by: the product is mixed with the "brown/black liquor" discharged during the preparation process of main product A;
辅助产品G--颗粒饲料,特征是:用能源草干料仅经破碎过筛所获的过28目筛细粉,或/和过28至不过150目筛范围的含土量微的粒径居中的能源草纤维粉屑,用其作为颗粒饲料的配料组份之一;Auxiliary product G - pellet feed, characterized by: the energy grass dry material is only crushed and sieved to obtain a fine powder that passes through a 28 mesh sieve, or/and a particle size with a small soil content that passes through a 28 to less than 150 mesh sieve. The energy grass fiber powder in the center is used as one of the ingredients of pellet feed;
辅助产品H--生物质颗粒燃料,特征是:以能源草被破碎、过筛脱除了未过28目筛之粗纤维后的细粉料,或是全组份的能源草粉碎物,为配料组份,或再配加了废塑料;所述“废塑料”,至少包括废农用塑膜、废泡沫塑料、废化纤织物或/和化纤棉絮的任一或多种的组合,所述的“配加”占辅助产品H之总重量的5%以下,或至高不超22%;Auxiliary product H - biomass pellet fuel, characterized by: the fine powder obtained by crushing and sieving the energy grass to remove the crude fiber that has not passed the 28 mesh sieve, or the full-component crushed energy grass as ingredients. components, or waste plastics are added; the "waste plastics" include at least any one or combination of waste agricultural plastic films, waste foam plastics, waste chemical fiber fabrics or/and chemical fiber cotton batting, and the "waste plastics" "Additional" accounts for less than 5% of the total weight of auxiliary product H, or does not exceed 22%;
辅助产品I--食用菌种植棒/块,特征是:在提取了“能源草,或能源草和牛粪”中之不过28目筛孔料制主产品A后的余料,既过28目筛孔的能源草之粉料或和细牛粪沉渣,作为食用菌种植棒/块中的配料组份之一。Auxiliary product I - Edible fungus planting stick/block, characterized by: the remaining material after extracting the main product A from "energy grass, or energy grass and cow dung" with a mesh size of no more than 28 mesh, and passing through a 28 mesh sieve. The energy grass powder or fine cow dung sediment of the hole is used as one of the ingredients in the edible fungus planting sticks/blocks.
实施例2.实施例1所述的“主产品A--亲水疏解纤维”,其特征至少还包括如下ⅰ至ⅵ,或再与ⅶ的组合:Embodiment 2. The "main product A--hydrophilic and decomposable fiber" described in Embodiment 1, its characteristics include at least the following ⅰ to ⅵ, or a combination with ⅶ:
ⅰ.所用原料:包括芒萁、里白、香茅、芦竹、芦苇、类芦、斑茅、象草、王草、皇竹草、巨菌草、五节芒、大米草、紫象草、矮象草、红象草、甜象草、牧草笋、牧草蔗、拟高粱、甜高粱、彼特草、苏丹草、台湾甜草、交狼尾草、互花米草杂、美洲狼尾草、杂交狼尾草的任一或多种组合的能源草,产生大量秸秆的粮、棉、油农作物--稻、麦、玉米、棉花、油菜、大豆、油牡丹、油芍药、向日葵、蓖麻的任一种或多种秸秆组合的能源草,或由人工矮化种植且常年要修剪上部枝条的柳树、竹柳、杨树、桑树、枸树的任一或多种组合的能源草;经锯/碾/切/锤的任一或多种组合碎化再过筛处理,获得其中的一部分:过3目至不过28目筛范围的任一目数的分级或混合粒径的细长状纤维束碎化物;ⅰ. Raw materials used: including Echinacea, Liba, lemongrass, Arundodis, reeds, reeds, zebra grass, elephant grass, king grass, king bamboo grass, giant fungus grass, five-jointed miscanthus, rice grass, purple elephant grass , dwarf elephant grass, red elephant grass, sweet elephant grass, grass shoots, grass sugarcane, pseudosorghum, sweet sorghum, Peter grass, Sudan grass, Taiwan sweet grass, Pennisetum alterniflora, Spartina alterniflora hybrid, American wolftail Energy grasses of any one or more combinations of grasses and hybrid pennisetum, grain, cotton, and oil crops that produce a large amount of straw - rice, wheat, corn, cotton, rape, soybean, oil peony, oil peony, sunflower, grizzly Energy grass composed of any one or more combinations of hemp straws, or any one or more combinations of willows, bamboo willows, poplars, mulberry trees, and wolfberry trees that are artificially dwarfed and whose upper branches need to be pruned all year round; After being crushed by any one or more combinations of sawing/milling/cutting/hammering and then sieving, a part of it is obtained: an elongated shape with any mesh size ranging from 3 mesh to no more than 28 mesh sieve or mixed particle size. fiber bundle fragments;
ⅱ.副产物料:副产物料1:热水脱木素/树脂工序所排棕/黑液,在制所述的“A”时,会在用干料在热水脱木素/树脂工序,经压/挤排出棕/黑液;所述的“棕/黑液”,其重量份W棕/黑液,与所获主产品A中含水不超15%的绝干纤维之重量份WA的比例在W棕/黑液/WA=90~100~300/100范围;所述“棕/黑液”中所含Na+或/和K+或/和Mg2+的克摩尔与其升体积之比为≤0.034mol/L,或/和所含的可溶性无机钠盐、钾盐、镁盐的wt%总浓度≤0.20%(wt%),或水中所含的可溶性无机盐、钾盐、镁盐的wt%总浓度与生产实施地所取水源中的总浓度之差≤0.01%(wt%),“棕/黑液”之pH值在5.0~9.4范围;ⅱ. By-product materials: By-product material 1: Brown/black liquor discharged from the hot water delignification/resin process. When making the "A" mentioned above, dry materials will be used in the hot water delignification/resin process. , the brown/black liquor is discharged by pressing/squeezing; the "brown/black liquor" has a weight part W of the brown/black liquor and a weight part W of the absolute dry fiber containing no more than 15% water in the main product A obtained The ratio of A is in the range of W brown/black liquor /W A =90~100~300/100; the gram moles of Na + or/and K + or/and Mg 2+ contained in the "brown/black liquor" are equal to The volume ratio per liter is ≤0.034mol/L, or/and the total wt% concentration of the soluble inorganic sodium salts, potassium salts, and magnesium salts contained in the water is ≤0.20% (wt%), or the soluble inorganic salts and potassium salts contained in the water The difference between the total wt% concentration of salt and magnesium salt and the total concentration in the water source taken from the production site is ≤0.01% (wt%), and the pH value of the "brown/black liquor" is in the range of 5.0 to 9.4;
或副产物料2:用鲜能源草或先用水洗净后的鲜能源草再经压榨所获的鲜汁液;或干能源草经水洗净后再水煮、压榨所获的汁液;Or by-product material 2: fresh juice obtained from fresh energy grass or fresh energy grass washed with water and then squeezed; or juice obtained from dried energy grass washed with water and then boiled and squeezed;
或和副产物料3:以牛粪为起始原料,对牛粪做淘/洗后所排出的淘/洗液;Or and by-product material 3: using cow dung as the starting material, the washing/washing liquid discharged after washing/washing the cow dung;
或和副产物料4:使用活性炭和酸性白土,对前述“棕/黑液”做吸附脱色杂,制净化循环用水后,所获的脱色吸附渣泥;或对前述“棕/黑液”,滴加硫酸酸化至pH值不超出7.0条件下,使用活性炭或活性炭和酸性白土制净化循环用水后所获的脱色吸附渣泥;Or and by-product material 4: use activated carbon and acidic clay to adsorb and decolorize impurities in the aforementioned "brown/black liquor", and purify circulating water to obtain the decolorized adsorption sludge; or use the aforementioned "brown/black liquor", The decolorized adsorption sludge is obtained by adding sulfuric acid dropwise to acidify until the pH value does not exceed 7.0, and using activated carbon or activated carbon and acid clay to purify circulating water;
或和副产物料5:使用化学或生化法,对前述“棕/黑液”或/和“淘/洗液”做沉淀 净化处理所获得的脱色沉淀渣泥;Or and by-product material 5: Use chemical or biochemical methods to precipitate the aforementioned "brown/black liquor" or/and "washing liquor" Decolorized precipitated sludge obtained from purification treatment;
ⅲ.残留色度:主产品A入清水,以产品绝干料与清水按重量比=1:6所加热至70℃泡化5至10分钟后所挤获未蒸发失重清液料,以比色管直观或比色仪检测色度不浓于ⅱ项所述“棕/黑液”被清水稀释16倍的色度,或仪器检测其COD或BOD值不高于ⅱ项所述“棕/黑液”被清水体积稀释16倍的COD或BOD值,或用容量滴定法测其高锰酸钾退色消耗量值不高于ⅱ项所述“棕/黑液”被清水体积稀释16倍的高锰酸钾退色消耗量值;ⅲ. Residual color: Add the main product A into clean water, heat the product to 70°C and bubble it for 5 to 10 minutes, then squeeze out the clear liquid material that has not evaporated and lost weight. The color of the color tube intuitively or the colorimeter detects is not thicker than the color of the "brown/black liquid" mentioned in item ⅱ diluted 16 times with clean water, or the instrument detects that its COD or BOD value is not higher than the "brown/black liquor" mentioned in item ⅱ The COD or BOD value of the "black liquor" diluted 16 times by the volume of clean water, or the discoloration consumption value of potassium permanganate measured by volumetric titration is not higher than the value of the "brown/black liquor" diluted 16 times by the volume of clean water as described in item ⅱ Potassium permanganate fading consumption value;
ⅳ.产品剂型:主产品A的剂型可为含水不多于75%呈松散肉松状潮料、含水不多于75%呈潮纸状料、含水不多于20%的肉松状干料、含水不多于20%的纸状干料、含水不多于20%的呈压实砖状干料、含水不多于20%的呈压实颗粒状干料的任一种;ⅳ. Product dosage form: The dosage form of the main product A can be a loose meat floss-like moist material with a water content of not more than 75%, a wet paper-like material with a water content of not more than 75%, a dry meat floss-like material with a water content of not more than 20%, and a water-based material. Any of paper-like dry materials containing no more than 20% water, compacted brick-shaped dry materials containing no more than 20% water, and compacted granular dry materials containing no more than 20% water;
ⅴ.物性特征:被控制为低亲水之打浆度<16°SR的主产品A-1,或A-1与控制呈高亲水之打浆度≥16°SR的主产品A-2,A-1与A-2呈可被方便任意掺配的两组料;在与标样团料--天牛幼虫或木蠹蛾幼虫蛀食柳树杆的粪便所制标样,做团料对团料的对掐测试中,A-1或A-2的硬度≤标样的硬度;或和在与标样团料,做团料对团料的对搓至少10次测试中,以裸眼看或用天平秤重比较,A-1或A-2的散落屑量不多于标样散落屑量的5倍;ⅴ. Physical properties: Main product A-1 controlled to have a low hydrophilicity with a beating degree of <16°SR, or A-1 and main product A-2, A controlled to have a high hydrophilicity with a beating degree of ≥16°SR. -1 and A-2 are two sets of materials that can be blended easily and arbitrarily; when compared with the standard sample dough - the feces of beetle larvae or wood beetle moth larvae eating willow stems, the dough is compared with the dough. In the pinch test of the material, the hardness of A-1 or A-2 ≤ the hardness of the standard sample; or in the test of rubbing the dough with the standard sample for at least 10 times, it can be seen with the naked eye or Use a balance to weigh and compare, the amount of scattered chips of A-1 or A-2 is not more than 5 times the amount of scattered chips of the standard sample;
ⅵ.产程特征:生产过程里,所涉水中,所含Na+或/和K+或/和Mg2+的克摩尔与“水”的升体积之比为≤0.034mol/L;和采用不低于70℃的水至少2次浸渍纤维物料,以脱除纤维中的木素/树脂;所述的“水”流中之逐级渐浓的棕/黑液流向与纤维物料在生产过程中的流向呈逆流;或和添加水不溶或难溶性物质做晶须助剂,其添加量占主产品A或其中间产物里绝干纤维100重量份,为≤1~3~5~9重量份,既≤1重量份或≤3重量份或≤5重量份或≤9重量份,对纤维表面实施低灰分的晶须接枝/包覆;使用的助剂中,所含苛性碱、氨、铵盐、过氧化物、生物酶的任一或多种的总含量为0;ⅵ. Production process characteristics: During the production process, the ratio of the gram moles of Na + or/and K + or/and Mg 2+ contained in the water involved to the liter volume of "water" is ≤0.034 mol/L; and adopt Impregnate the fiber material with water of not less than 70°C at least twice to remove the lignin/resin in the fiber; the flow direction of the gradually thickening brown/black liquor in the "water" flow is consistent with the flow direction of the fiber material in the production process The flow direction is countercurrent; or water-insoluble or poorly soluble substances are added as whisker additives, and the amount added accounts for 100 parts by weight of the absolute dry fiber in the main product A or its intermediate product, and is ≤1~3~5~9 parts by weight parts by weight, either ≤1 part by weight or ≤3 parts by weight or ≤5 parts by weight or ≤9 parts by weight, implement low-ash whisker grafting/coating on the fiber surface; among the additives used, caustic alkali, ammonia The total content of any one or more of ammonium salts, peroxides, and biological enzymes is 0;
ⅶ.较佳参数:或ⅱ项所述的“其排出的重量份W棕/黑液,与含水不超15%的绝干主产品A的总获重量份WA的比例在W棕/黑液/WA=100~120~150/100范围;或和ⅵ项所述的“添加水不溶或难溶性物质做晶须助剂,其添加量对主产品A或其中间产物里绝干纤维100重量份”“为≤1~3~5重量份”,“既≤1重量份或≤3重量份或≤5重量份”;所述的“晶须助剂”至少是氢氧化钙饱和水溶液、硅溶胶等的任一种,或/和在水相中新生成的氢氧化钙、氢氧化铝、水合硅酸、硅酸钙、硅酸镁、硅酸铝、碳酸钙、二水合硫酸钙、氢氧化铁等的任一或多种的组合,或/和经超细粉碎至在水中不能在半小时里自然沉淀至表层水清的高岭土、粘土、粉煤灰、硅灰石等的任一或多种的组合,或和粉碎至过320目的高岭土、粘土、粉煤灰、硅灰石等的任一或多种的组合。ⅶ. Preferable parameters: or "The ratio of the discharged weight part W brown/black liquor and the total obtained weight part W A of the absolutely dry main product A with a water content not exceeding 15% as described in item ⅱ is W brown/black Liquid /W A = 100~120~150/100 range; or "adding water-insoluble or poorly soluble substances as whisker additives as described in item ⅵ, the amount added is equivalent to the absolute dry fiber in the main product A or its intermediate product "100 parts by weight""is ≤1~3~5 parts by weight", "either ≤1 part by weight or ≤3 parts by weight or ≤5 parts by weight"; the "whisker additive" is at least a saturated aqueous solution of calcium hydroxide , any of silica sol, etc., or/and newly generated calcium hydroxide, aluminum hydroxide, hydrated silicic acid, calcium silicate, magnesium silicate, aluminum silicate, calcium carbonate, and calcium sulfate dihydrate in the aqueous phase , ferric hydroxide, etc., or/and any kaolin, clay, fly ash, wollastonite, etc. that have been ultrafinely pulverized to the point that it cannot naturally precipitate to clear surface water within half an hour in water. One or more combinations, or any one or more combinations of kaolin, clay, fly ash, wollastonite, etc. crushed to 320 mesh.
实施例3.实施例1所述“副产品B--木塑复合再生质粗粒”,其更多特征在于:其中“木”之特征为如下例3-1或例3-1与例3-2的组合,其中“塑”之特征为如下例3-3或例3-3与例3-4的组合,其产品剂型特征为如下例3-5至例3-8:Embodiment 3. The "by-product B--wood-plastic composite regenerated coarse particles" described in Embodiment 1 is more characterized by: the characteristics of "wood" are as follows: Example 3-1 or Example 3-1 and Example 3- 2, in which the characteristic of "plastic" is the following Example 3-3 or the combination of Example 3-3 and Example 3-4, and the product dosage form characteristics are the following Examples 3-5 to 3-8:
例3-1.其中的“木”,含来源于能源草之中的一部分:过28目筛的细屑料或/和粉碎物,或和过3目筛的粗细混合的碎化物;Example 3-1. The “wood” includes a part derived from energy grass: fine materials or/and crushed materials that pass through a 28-mesh sieve, or crushed materials mixed with coarse and fine materials that pass through a 3-mesh sieve;
例3-2.由如上3-1所述的“一部分”,为所述“木”在空气中自然干燥后含15%平衡水量之干基重,在副产品B的总重量中占比5%至78%(wt%)之间;Example 3-2. The "part" as described in 3-1 above is the dry basis weight of the "wood" containing 15% of equilibrium water after natural drying in the air, accounting for 5% of the total weight of by-product B. to 78% (wt%);
例3-3.其中的“塑”之原料,皆选材于废塑料;Example 3-3. The raw materials for “plastic” are all selected from waste plastics;
例3-4.如上例3-3所述“废塑料”,至少包括如后所述的任一或多种的组合:废纸再生所弃的杂废塑膜渣,包括所述“杂废塑膜渣”经水浮选所获浮水含塑物或/和沉水含塑物;商品的塑膜质废包装袋、塑膜包装袋生产中的切/冲边料、废复合塑膜材、商标标贴生 产/使用中所弃的塑膜复合离型纸/膜、废铝塑复合膜、废农用塑膜;由废旧轮胎经破碎分离出的含杂聚合物纤维,从汽车中拆除出的废化纤绒布,废化纤地毯、废化纤织物、废化纤熔喷布、废化纤过滤纸;废电线塑料皮、废塑料包装带、废塑料编织袋、废土工布、废/旧塑料鞋、废塑料铺地制品、废塑料玩具、废塑料桶、废塑料瓶、废塑料土工布、废/旧塑料草坪、废杂塑料建材、废塑料管、废塑料板、废塑料文具、废塑料箱/包、废塑料杂件;废PVC人造革、废PU人造革;废泡沫塑料;Example 3-4. The "waste plastics" as described in Example 3-3 above include at least any one or more combinations as described below: Miscellaneous waste plastic film residue discarded from waste paper recycling, including the "miscellaneous waste""Plastic film residue" obtained by water flotation and floating plastic-containing materials or/and submerged plastic-containing materials; commercial plastic film waste packaging bags, cutting/punching edge materials, and waste composite plastic film materials in the production of plastic film packaging bags , trademark labeling student Plastic film composite release paper/film, waste aluminum-plastic composite film, and waste agricultural plastic film discarded during production/use; impurity-containing polymer fibers separated from broken tires, waste chemical fiber flannel removed from cars , waste chemical fiber carpets, waste chemical fiber fabrics, waste chemical fiber meltblown cloth, waste chemical fiber filter paper; waste wire plastic skins, waste plastic packaging tapes, waste plastic woven bags, waste geotextiles, waste/old plastic shoes, waste plastic flooring products , waste plastic toys, waste plastic barrels, waste plastic bottles, waste plastic geotextiles, waste/old plastic lawns, waste plastic building materials, waste plastic pipes, waste plastic boards, waste plastic stationery, waste plastic boxes/bags, waste plastic miscellaneous pieces; waste PVC artificial leather, waste PU artificial leather; waste foam plastic;
例3-5.副产品B的剂型至少可被设置呈甲、乙、丙、丁之第一组,或/和戊、己、更、辛之第二组,或/和壬、癸之第三组,即可在第一至第三组中的甲至癸中任取一或多种以任意比的作搀兑联用,就能方便地使木塑复合再生质粗粒的下游之塑料粒子或制品中的“木”或携“杂质”的“木”总重量投料占比为5%至78%范围;前述“携‘杂质’的‘木’”中的两者重量之比为W杂质/W=0~10/100,所述的“木”,为含水量不高于15%的绝干料,所述的“杂质”为如实施例2中ⅱ里所述“副产物料4”或/和“副产物料5”;“塑”和软化剂总重量投料占比为22%至95%范围,前述“‘塑’和软化剂”中的两者重量之比,即W 塑料/W软化剂=100/0~100:Example 3-5. The dosage form of by-product B can be set to at least the first group of A, B, C, and D, or/and the second group of E, Ji, Geng, and Xin, or/and the third group of Ren and Gui. Group, you can choose any one or more of A to Gui in the first to third groups and mix them in any ratio to make the wood-plastic composite regenerated coarse-grained downstream plastic particles easily. Or the total weight of "wood" or "wood" with "impurities" in the product is in the range of 5% to 78%; the weight ratio of the two in the aforementioned "wood with 'impurities'" is W Impurities /W wood =0~10/100, the “wood” is absolutely dry material with a moisture content of no more than 15%, and the “impurities” are “by-product materials” as described in ⅱ of Example 2 4" or/and "by-product material 5"; the total weight input ratio of "plastic" and softener is in the range of 22% to 95%, and the weight ratio of the two in the aforementioned "'plastic' and softener" is W Waste plastic /W softener =100/0~100:
第一组:First group:
甲中包括“木”总重量投料占比为76%,废塑料和软化剂总重量投料占比为24%;The total weight input of "wood" in A includes 76%, and the total weight input of waste plastics and softeners accounts for 24%;
乙中包括“木”总重量投料占比为35%,废塑料和软化剂总重量投料占比为65%;The total weight input of "wood" in B is 35%, and the total weight input of waste plastics and softeners is 65%;
丙中包括“木”总重量投料占比为25%,废塑料和软化剂总重量投料占比为75%;The total weight input of "wood" in C is 25%, and the total weight input of waste plastics and softeners is 75%;
丁中包括“木”总重量投料占比为5,废塑料和软化剂总重量投料占比为95%;The total weight input of "wood" in D is 5, and the total weight input of waste plastics and softeners is 95%;
第二组:Second Group:
戊中包括“木”总重量投料占比为77%,废塑料和软化剂总重量投料占比为23%;The total weight input of "wood" in E includes 77%, and the total weight input of waste plastics and softeners accounts for 23%;
己中包括“木”总重量投料占比为38%,废塑料和软化剂总重量投料占比为62%;The total weight input of "wood" accounts for 38%, and the total weight input of waste plastics and softeners accounts for 62%;
更中包括“木”总重量投料占比为23%,废塑料和软化剂总重量投料占比为77%;The update includes that the total weight input of "wood" accounts for 23%, and the total weight input of waste plastics and softeners accounts for 77%;
辛中包括“木”总重量投料占比为10,废塑料和软化剂总重量投料占比为90%;The total weight input of "wood" in Xin is 10, and the total weight input of waste plastics and softeners is 90%;
第三组:The third group:
壬中包括“木”总重量投料占比为78%,废塑料和软化剂总重量投料占比为22%;The total weight input of "wood" in Renzhong accounts for 78%, and the total weight input of waste plastics and softeners accounts for 22%;
癸中包括“木”总重量投料占比为15%,废塑料和软化剂总重量投料占比为85%;The total weight input of "wood" in Guizhong accounts for 15%, and the total weight input of waste plastics and softeners accounts for 85%;
例3-6.或在例3-5项所述的“在第一至第三组中的甲至癸中任取一或多种搀兑联用,控制了在木塑复合再生质粗粒的下游塑料粒子或制品中的“木”总重量投料占比为5%至78%范围,“塑”和软化剂总重量投料占比为22%至95%范围”内,例3-5项所述的“第一组”、“第二组”、“第三组”中的甲至癸的各投料组合中的“木”总重量投料占比,与“塑”和软化剂总重量投料占比,皆可按市场客户的定制来定;Example 3-6. Or as described in Example 3-5, "Add any one or more of A to Gui in the first to third groups to control the coarse particles in wood-plastic composite regenerated matter. The total weight input of “wood” in the downstream plastic particles or products is in the range of 5% to 78%, and the total weight input of “plastic” and softener is in the range of 22% to 95%, Example 3-5 The proportion of the total weight of "wood" in each of the feeding combinations of A to Gui in the "first group", "second group" and "third group" is proportional to the total weight of "plastic" and softener. The proportion can be determined according to the customization of market customers;
例3-7.所述的“木塑复合再生质粗粒”,其组成的物料按例3-5项前述的“第一组”或/和“第二组”或/和“第三组”中的甲至癸各分组合配料投料,经粗粒造粒机处理后,得质地呈可被人手指/掌直接拉/扳/捏/撕/抓得碎的低强度粗粒,所述“低强度”,至少是抗拉强度≤3PMa的塑料之标样试片;Example 3-7. The "Wood-Plastic Composite Regenerated Coarse Grain" is composed of materials according to the "First Group" or/and "Second Group" or/and "Third Group" mentioned in Example 3-5. "A to Gui components in the combined ingredients are fed, and after being processed by a coarse granulator, the texture is low-strength coarse granules that can be directly pulled/pulled/pinched/teared/grabbed by human fingers/palms, as described "Low strength" refers to at least the standard sample specimen of plastic with tensile strength ≤3PMa;
例3-8.如上例3-7项所述“粗粒造粒机”,具体是指具有连续式进/出料功能的饲料颗粒机、有机肥造粒机、生物质燃料颗粒机的任一种,或再在前述“颗粒机”/“造粒机”之后再串联螺旋切粒中碎机。Example 3-8. As mentioned in the above example 3-7, the "coarse granulator" specifically refers to any feed pellet machine, organic fertilizer granulator, or biomass fuel pellet machine with continuous feeding/discharging function. One, or a spiral granulator and intermediate crusher can be connected in series after the aforementioned "granulator"/"granulator".
实施例4.实施例1所述产品集合中的“主产品A--亲水疏解纤维产品”的制法,请参见附图13--制备“主产品A--亲水疏解纤维”的十个步骤之方框示意图,其特征可包括 如下步骤一至十:Example 4. For the preparation method of "main product A--hydrophilic decomposable fiber product" in the product set described in Example 1, please refer to Figure 13--10 steps for preparing "main product A--hydrophilic decomposable fiber". A block diagram of steps, which may include Follow steps one to ten below:
步骤一——预处理备料:对能源草干料先做品种归类,或再对已归类料中所含金属或/和砖石块或/和树皮杂质作进一步的脱杂处理,然后再对已归类、脱杂的能源草实施锯/碾/切/锤的任一或多种组合碎化再过筛处理处理;排出另作利用的过28目筛的能源草碎化物;Step 1 - Pretreatment and preparation of materials: First classify the energy grass dry materials, or further remove the metals or/and masonry blocks or/and bark impurities contained in the classified materials, and then The classified and impurity-free energy grass is then subjected to any one or more combinations of sawing/grinding/cutting/hammering, and then sieved; the crushed energy grass that passes through a 28-mesh sieve is discharged for further use;
筛取能源草碎化物料中的过3目至不过28目筛范围的任一目数的分级或混和粒径的细长状纤维束;Sieve out the elongated fiber bundles with classified or mixed particle sizes in any mesh range from 3 mesh to 28 mesh in the energy grass crushed material;
或对已获脱杂净化的能源草细长状纤维束碎化物,再施机械膨化处理;Or the shredded slender fiber bundles of energy grass that have been removed and purified are subjected to mechanical expansion processing;
由此获得备做步骤二处理的备用能源草碎化物,此“备用能源草碎化物”料以其在空气中自然吸附的平衡水量15%(wt)计的,被称之为自然绝干料;Thus, the backup energy grass crumbs prepared for step 2 are obtained. This "backup energy grass crumbs" material is called natural absolutely dry material based on its naturally adsorbed equilibrium water content in the air of 15% (wt). ;
步骤二——第一次配料:取经步骤一所获的“备用能源草碎化物”料之自然绝干料:100重量份,拌入后续步骤七所述“第二次固液分离”所获的挤出水,所述“拌入”“挤出水”,在测知后续步骤四所述“第一次固液分离”所获固相中之自然绝干料100重量份所携的游离水为x重量份,则“拌入”的“挤出水”为不少于:2x重量份;或再拌入前述“挤出水”“2x重量份”的0.1~0.3%重量份之表面活性剂:丁基萘磺酸钠、十二烷基苯磺酸钠、十二烷基硫酸钠的任一种或多种的组合,或/和椰子油脂肪酸二乙醇酰胺、脂肪醇聚氧乙烯醚的任一或多种的组合;所述的“2x”对应能源草锯碎化物料之自然绝干料100重量份:在25~50~300重量份范围;Step 2 - First batching: Take 100 parts by weight of the natural dry material of the "Standby Energy Grass Crushed Material" obtained in Step 1, and mix in the "Second Solid-Liquid Separation" described in the subsequent Step 7. The extruded water, the "stirring in" and "extruded water", after measuring the free content carried by 100 parts by weight of the natural bone-dry material in the solid phase obtained by the "first solid-liquid separation" described in the subsequent step 4 If the amount of water is Active agent: any one or combination of sodium butylnaphthalene sulfonate, sodium dodecylbenzene sulfonate, sodium lauryl sulfate, or/and coconut oil fatty acid diethanolamide, fatty alcohol polyoxyethylene Any one or a combination of multiple ethers; the "2x" corresponds to 100 parts by weight of the natural dry material of the energy grass saw crushed material: in the range of 25 to 50 to 300 parts by weight;
步骤三——加热溶出:将前述“‘备用能源草碎化物’料之自然绝干料100重量份”、“后续步骤七所述‘第二次固液分离’所获的挤出水”:“2x重量份”,或和“‘挤出水’‘2x重量份’的0.1~0.3%重量份之‘表面活性剂’”,将这些物料置于一可被搅拌混合和加热且保温的罐中,对物料实施均匀搅拌和加热至70℃以上,并保温滞留至少5分钟,或被取样分析,当不见有挤出液的颜色更变深色时,即可停止此加热、保温操作;Step 3 - Heating and dissolution: Add the aforementioned "100 parts by weight of the natural dry material of the 'Standby Energy Grass Crushed Material' material" and "the extruded water obtained from the 'second solid-liquid separation' described in the subsequent step 7": "2x parts by weight", or "0.1 to 0.3% by weight of 'surfactant' of '2x parts by weight' of 'squeezed water'", place these materials in a tank that can be stirred, mixed, heated and kept warm. During the process, the material is uniformly stirred and heated to above 70°C, and kept warm for at least 5 minutes, or sampled and analyzed. When the color of the extruded liquid no longer changes to a darker color, the heating and heat preservation operations can be stopped;
步骤四——第一次固液分离:将上述“加热、保温操作”后的物料,导入螺杆或扎辊式挤浆机,对物料的纤维束作碾挤的机械揉化处理,然后再将物料导入固液分离机作固/液分离;或直接将上述加热、保温操作后的物料导入固液分离机作固/液分离;由此得到如实施例1所述的“压/挤出棕/黑液”,和初脱除纤维中水溶质的待处理亲水疏解纤维中间产物甲的潮料;Step 4 - The first solid-liquid separation: Introduce the material after the above "heating and heat preservation operations" into a screw or roller extruder, perform a mechanical kneading treatment on the fiber bundles of the material, and then knead it. The materials are introduced into a solid-liquid separator for solid/liquid separation; or the materials after the above-mentioned heating and heat preservation operations are directly introduced into a solid-liquid separator for solid/liquid separation; thereby obtaining the "pressed/extruded brown" as described in Example 1. / black liquor", and the moisture material of the hydrophilic decomposed fiber intermediate product A to be treated, which has initially removed the water solute in the fiber;
本“第一次固液分离”,所获的“压/挤出棕/黑液”,其排出的重量份W压/挤出棕/黑液,与亲水疏解纤维中间产物甲之自然绝干料重量份W亲水疏解纤维中间产物甲的比例,可使用常规的固液分离机械,被控制在W压/挤出棕/黑液/W亲水疏解纤维中间产物甲=25~100~300/100范围,既本“第一次固液分离”,所获潮料中“亲水疏解纤维中间产物甲”之自然绝干料重量百分含量,能被控制在80%~50%~25%范围;In this "first solid-liquid separation", the "pressed/extruded brown/black liquor" obtained is naturally separated from the hydrophilic decomposable fiber intermediate product A by the weight portion of the discharged brown/black liquor. The proportion of dry material weight part W hydrophilic decomposable fiber intermediate product A can be controlled by using conventional solid-liquid separation machinery at W pressing/extrusion brown/black liquor /W hydrophilic decomposable fiber intermediate product A =25~100~ In the range of 300/100, in this "first solid-liquid separation", the weight percentage of the natural absolute dry material of the "hydrophilic and decomposable fiber intermediate product A" in the obtained moisture material can be controlled between 80% and 50%. 25% range;
步骤五——第二次配料:在测知步骤四所述“待处理亲水疏解纤维中间产物甲的潮料”固相中之自然绝干料100重量份所携的游离水为x重量份后,取“待处理亲水疏解纤维中间产物甲的潮料”所含之自然绝干料100重量份和所携的游离水x重量份,再拌入后续步骤十所述“第三次固液分离”所获的挤出水不少于:x重量份;或和再按实施例1中项所述“A-1”与“A-2”的差异性要求,有差别化地再配加晶须助剂,所述“晶须助剂”至少是氢氧化钙饱和水溶液、硅溶胶等的任一种,或/和在水相中新生成的氢氧化钙、氢氧化铝、水合硅酸、硅酸钙、硅酸镁、硅酸铝、碳酸钙、二水合硫酸钙、氢氧化铁等的任一或多种的组合,或/和经超细粉碎至在水中不能在半小时里自然沉淀至表层水清的高岭土、粘土、粉煤灰、硅灰石等的任一或多种的组合,或和粉碎至过320目的高岭土、粘土、粉煤灰、硅灰 石等的任一或多种的组合;所述“晶须助剂”,其对“亲水疏解纤维中间产物甲的潮料”中绝干纤维100重量份的添加量,为≤1~3~5~9重量份,既添加量≤1重量份或≤重量3份或≤5重量份或≤9重量份;将本步骤五所述的第二次配料,先在搅拌槽中混匀,即成待入高浓磨处理的物料;Step 5 - Second batching: It is determined that the free water carried by 100 parts by weight of the natural dry material in the solid phase of the "moist material for the hydrophilic decomposable fiber intermediate product A" described in step 4 is x parts by weight. Then, take 100 parts by weight of the natural dry material contained in the "moist material of the hydrophilic decomposable fiber intermediate product A to be treated" and x parts by weight of free water, and then mix in the "third solidification step" described in the subsequent step ten. The extruded water obtained by "liquid separation" is not less than: Add a whisker auxiliary. The "whisker auxiliary" is at least any one of saturated aqueous calcium hydroxide solution, silica sol, etc., or/and newly generated calcium hydroxide, aluminum hydroxide, and hydrated silicon in the aqueous phase. Any one or combination of acids, calcium silicate, magnesium silicate, aluminum silicate, calcium carbonate, calcium sulfate dihydrate, ferric hydroxide, etc., or/and ultrafinely crushed to the point where it cannot be dissolved in water within half an hour. Any one or combination of kaolin, clay, fly ash, wollastonite, etc. that have naturally precipitated to a clear surface layer, or kaolin, clay, fly ash, and silica fume that have been crushed to 320 mesh Any one or a combination of stones, etc.; the "whisker additive", the amount added to 100 parts by weight of absolute dry fiber in the "moist material of hydrophilic decomposable fiber intermediate product A" is ≤ 1 to 3 ~5~9 parts by weight, that is, the added amount is ≤1 part by weight or ≤3 parts by weight or ≤5 parts by weight or ≤9 parts by weight; mix the second ingredients described in step 5 in the mixing tank first, The materials are ready to be processed by high-concentration grinding;
步骤六——碾磨消潜:将步骤五所得的“待入高浓磨处理的物料”,导入高浓磨处理;或再将出高浓磨的发热物料,乘热导入带保温设置的消潜罐中保温或和加热,以不低于70℃之温静置,以松弛经高浓磨处理过程中产生的对纤维的扭结、卷曲,和对纤维中的憎水性脂类的溶出;由此步骤六处理后,获得又待固液分离之碾磨或和消遣操作后的物料;Step 6 - Grinding and latent elimination: Introduce the "materials to be processed into high-concentration grinding" obtained in step 5 into high-concentration grinding; or then use the heat to introduce the heat-generating materials from high-concentration grinding into a disinfection machine with heat preservation settings. Insulate or heat in a submersible tank, and let it stand at a temperature of no less than 70°C to relax the kinks and curls of the fibers produced during the high-concentration grinding process, and to dissolve the hydrophobic lipids in the fibers; After processing in step 6, the material after grinding or processing is obtained and is subject to solid-liquid separation;
步骤七——第二次固液分离:将上述“碾磨或和消遣操作后的物料”导入螺杆或扎辊式挤浆机,对物料的纤维束再作碾挤的机械揉化处理,然后再将物料导入固液分离机作固/液分离;或省去机械柔化,就将上述“碾磨或和消遣操作后的物料”直接导入固液分离机作固/液分离;由此得到如前“步骤二”中所述的“‘第二次固液分离’所获的挤出水”,和尚待最后再作新水洗涤之待处理亲水疏解纤维中间产物乙的潮料;Step 7 - The second solid-liquid separation: Introduce the above-mentioned "material after grinding or processing" into a screw or roller squeezer, and then perform mechanical kneading treatment on the fiber bundles of the material, and then Then the material is introduced into the solid-liquid separator for solid/liquid separation; or mechanical softening is omitted, and the above-mentioned "materials after grinding or processing" are directly introduced into the solid-liquid separator for solid/liquid separation; thus, we get As described in the previous "Step 2", "the extruded water obtained from the 'second solid-liquid separation'" and the wet material of the hydrophilic decomposable fiber intermediate product B to be treated are finally washed with new water;
步骤八——第三次配料:在测知步骤七所述“待处理亲水疏解纤维中间产物乙的潮料”固相中之自然绝干料100重量份所携的游离水为x重量份后,取“待处理亲水疏解纤维中间产物乙的潮料”所含之自然绝干料100重量份和所携的游离水x重量份,再拌入新水或和脱色杂的再生水不少于:x重量份;或和再配加晶须助剂,所述“晶须助剂”至少是包括氢氧化钙饱和水溶液、硅溶胶等的任一种,或/和在水相中新生成的氢氧化钙、氢氧化铝、硅溶胶等的任一种,或/和在水相中新生成的氢氧化钙、氢氧化铝、水合硅酸、硅酸钙、硅酸镁、硅酸铝、碳酸钙、二水合硫酸钙、氢氧化铁等的任一或多种的组合,或和经超细粉碎至在水中难以在半小时里自然沉淀至表层水清的高岭土、粘土、粉煤灰、硅灰石等的任一或多种的组合,或和粉碎至过320目的高岭土、粘土、粉煤灰、硅灰石等的任一或多种的组合;所述“晶须助剂”,对“亲水疏解纤维中间产物乙的潮料”中绝干纤维100重量份的添加量,为≤1~3~5~9重量份,既添加量≤1重量份或≤3重量份或≤5重量份或≤9重量份;由此步骤八的计量加水和晶须助剂,获待送步骤九处理的第三次配料;Step 8 - The third batching: It is determined that the free water carried by 100 parts by weight of the natural dry material in the solid phase of the "moist material of the hydrophilic decomposable fiber intermediate product B to be treated" described in step 7 is x parts by weight. Then, take 100 parts by weight of the natural dry material contained in the "moist material to be processed for the hydrophilic decomposable fiber intermediate product B" and x parts by weight of free water, and then mix in new water or a small amount of recycled water for decolorization and impurities. In: Any of calcium hydroxide, aluminum hydroxide, silica sol, etc., or/and newly generated calcium hydroxide, aluminum hydroxide, hydrated silicic acid, calcium silicate, magnesium silicate, aluminum silicate in the water phase , any one or a combination of calcium carbonate, calcium sulfate dihydrate, ferric hydroxide, etc., or kaolin, clay, fly ash that has been ultrafinely pulverized to the point where it is difficult to naturally precipitate to a clear surface in water within half an hour. , any one or more combinations of wollastonite, etc., or any one or more combinations of kaolin, clay, fly ash, wollastonite, etc. crushed to over 320 mesh; the "whisker additive" , the added amount of 100 parts by weight of absolute dry fiber in the "moist material of hydrophilic decomposable fiber intermediate product B" is ≤1~3~5~9 parts by weight, that is, the added amount is ≤1 part by weight or ≤3 parts by weight or ≤5 parts by weight or ≤9 parts by weight; add water and whisker additives according to the measurement in step eight to obtain the third batch of ingredients to be sent to step nine;
步骤九——搅拌洗涤:将上述步骤八的“第三次配料”导入螺杆或扎辊式挤浆机,对物料的纤维束再作碾挤的机械揉化处理,然后再将物料导入待最后挤干的物料暂储槽;或将上述“第三次配料”直接导入搅拌机作搅拌,使新水,或和晶须助剂与亲水疏解纤维中间产物乙的潮料固相纤维中本来所含的旧水物料,实现充分的混合,然后再将物料导入待最后挤干的物料暂储槽;由此步骤九的处理,获得待送步骤十处理的待最后挤干的物料;Step 9 - Stirring and washing: Introduce the "third batching" of the above step 8 into the screw or roller extruder, and then perform mechanical kneading treatment on the fiber bundles of the material, and then introduce the material to be finalized. The squeezed material is temporarily stored in a temporary storage tank; or the above-mentioned "third batching" is directly introduced into the mixer for stirring, so that the new water, or the moisture content of the solid-phase fiber mixed with the whisker additive and the hydrophilic decomposable fiber intermediate product B is The old water-containing material is fully mixed, and then the material is introduced into the temporary storage tank for the material to be finally squeezed dry; through the processing in step nine, the material to be sent to step ten to be finally squeezed dry is obtained;
步骤十——第三次固液分离或和最后修饰:将上述步骤九的“待最后挤干的物料”导入固液分离机作固/液分离;由此得到如前“步骤五”中所述的“‘第三次固液分离’所获的挤出水”,和最后产品--包括A-1或/和A-2之亲水疏解纤维A产品;或和再对最后产品添加掩蔽铁/锰离子的助剂:草酸、草酸钠、草酸钾、草酸铵、乙二胺四乙酸、乙二胺四乙酸钠、四乙酰乙二胺、柠檬酸、柠檬酸钠、酒石酸、酒石酸钠、葡萄糖酸、二亚乙基三胺五乙酸、二亚乙基三胺五亚甲基膦酸、二乙烯三胺五乙酸五钠、次氨基三乙酸钠的任一或以上种的组合物料,所述组合物料,其可被配成掩蔽助剂水溶液:组合物料的总摩尔加入量在0.1~1.2mol/L范围,添加掩蔽助剂水溶液的量可控制在绝干亲水疏解纤维A 100重量份,加掩蔽助剂水溶液1至2重量份;或和再对最后产品添加常规量的普通防霉助剂,具体用量与品种,可参见市场各商家的产品说明书。Step 10 - The third solid-liquid separation or final modification: Introduce the "material to be finally squeezed dry" in the above-mentioned step 9 into the solid-liquid separator for solid/liquid separation; thus obtain the material as in the previous "step five" The above-mentioned "extrusion water obtained from the 'third solid-liquid separation'", and the final product - the hydrophilic and decomposable fiber A product including A-1 or/and A-2; or and then adding masking to the final product Iron/manganese ion additives: oxalic acid, sodium oxalate, potassium oxalate, ammonium oxalate, ethylenediaminetetraacetic acid, sodium ethylenediaminetetraacetate, tetraacetylethylenediamine, citric acid, sodium citrate, tartaric acid, sodium tartrate, A combination of any one or more of gluconic acid, diethylenetriaminepentaacetic acid, diethylenetriaminepentamethylenephosphonic acid, pentasodium diethylenetriaminepentacetate, and sodium nitrilotriacetate, so The above composition material can be formulated into a masking aid aqueous solution: the total molar addition amount of the composition material is in the range of 0.1 to 1.2 mol/L, and the amount of the masking aid aqueous solution added can be controlled to 100 parts by weight of absolute dry hydrophilic decomposable fiber A , add 1 to 2 parts by weight of masking additive aqueous solution; or add a regular amount of ordinary anti-mold additives to the final product. For specific dosage and variety, please refer to the product instructions of each merchant in the market.
由联系附图13的如上所述,从图13中的虚线所示水溶液的流向是由附图13的下方,向上走,与纤维的走向是由附图13的上方向下走,水流中棕/黑液流向与纤维走向是呈 相反,若再控制好如上所述方式的加水量和3次的固液分离的脱水量,则可使亲水疏解纤维A产品,在其热水脱木素/树脂工序经压/挤排出棕/黑液之最后的所获重量份W棕/黑液,与含水不超15%的绝干纤维产品A的总获重量份WA的比例在W棕/黑液/WA=90~100~300/100范围。As mentioned above in connection with Figure 13, the flow direction of the aqueous solution shown by the dotted line in Figure 13 is from the bottom of Figure 13 to upwards, and the direction of the fiber is from the top of Figure 13 to downwards. The brown color in the water flow /The flow direction of black liquor and the direction of fiber are On the contrary, if the amount of water added as mentioned above and the dehydration amount of three solid-liquid separations are controlled well, the hydrophilic and decomposable fiber A product can be pressed/extruded in the hot water delignification/resin process. The ratio of the final obtained weight part W brown/black liquor to the total obtained weight part W A of the absolutely dry fiber product A with a moisture content not exceeding 15% is W brown/black liquor /W A = 90 to 100 ~300/100 range.
这里要指出的是:如是在实验室中做小样,即使是用手捏挤来实施固液分离,则W棕/黑液/WA=300/100也是可以实现的,而用机械则更无忧实现W棕/黑液/WA=90~100~300/100的范围指标;整个过程中纤维与水的混合物是被至少加热了2次,这就如生活中的病人所吃的中药被水煎2次后,再煎第3次总是煎不出有色药液成分一样的道理,可无忧本发明所述亲水疏解纤维在下游用户作造纸操作过程中再做高浓磨浆,会因所生成摩擦的高温而使水体被着色的。What should be pointed out here is: if a small sample is made in the laboratory, even if solid-liquid separation is carried out by squeezing by hand, W brown/black liquor /W A = 300/100 can be achieved, but it is even more difficult to use machinery. Worry about achieving the range index of W brown/black liquor /W A = 90~100~300/100; the mixture of fiber and water is heated at least twice during the whole process, which is just like the traditional Chinese medicine taken by patients in daily life. After decoction in water for two times, it is the same reason that the ingredients of the colored liquid cannot be obtained by decoction for the third time. You can worry about the hydrophilic decomposable fiber of the present invention being used for high-consistency refining during the papermaking operation of downstream users. The water will be colored due to the high temperature generated by the friction.
这里还可指出的是,如上制法中提到:“将上述加热、保温操作后的物料导入螺杆或扎辊式挤浆机,对物料的纤维束作碾挤的机械揉化处理”,和“入高浓磨处理”;而这种“对物料的纤维束作碾挤的机械揉化处理”和“入高浓磨处理”,其对纤维的断化功能要远弱于粉碎食品的仅带一个十字旋刀的家用食品粉碎机,而对纤维的柔化、散化功能则都远优于家用粉碎机。在明白了这一类比关系,则就能从图1至图5,看出本发明所述亲水疏解纤维A的实用价值了:What can also be pointed out here is that as mentioned in the above production method: "The material after the above heating and heat preservation operations is introduced into a screw or roller extruder, and the fiber bundles of the material are mechanically kneaded by crushing and extrusion", and "High-concentration grinding treatment"; and this "mechanical kneading treatment of crushing and squeezing the fiber bundles of the material" and "high-concentration grinding treatment", its fiber-breaking function is much weaker than the mere grinding of food. A household food grinder with a cross rotary knife, and its softening and dispersing functions of fiber are far better than that of a household grinder. After understanding this analogy relationship, the practical value of the hydrophilic decomposable fiber A of the present invention can be seen from Figures 1 to 5:
图1为过3目至不过28目筛的粒径混合的能源草之一的桑树枝丫的细长状纤维束之黑白照片,其是用蚕桑业所弃桑树枝丫条,经锯/碾/切/锤的任一或多种组合的机械碎化处理,又经筛分后所获,此“过3目至不过28目筛的粒径混合之桑树枝丫条的细长状纤维束碎化物”,一般至少可占到总“桑树枝丫条碎化物”的三成半以上;Figure 1 is a black and white photo of the elongated fiber bundles of mulberry branch Ya, one of the mixed energy grasses with a particle size ranging from 3 mesh to no more than 28 mesh. It is made of mulberry branch Ya branches discarded from the sericulture industry and is sawed/ground/cut. / Mechanical crushing treatment of any or more combinations of hammers, and obtained after sieving, this "reduced elongated fiber bundles of mulberry branches and twigs with a particle size that has passed through a sieve of 3 mesh to less than 28 mesh" , generally accounting for at least 35% of the total "broken mulberry branches";
图2为过3目至不过28目筛的粒径混合的能源草之一的水稻秸秆的细长状纤维束之黑白照片,其是用水稻秸秆经机切碎化处理,又经筛分后所获,此“过3目至不过28目筛的粒径混合之水稻秸秆的细长状纤维束碎化物”,一般可占到总“水稻秸秆碎化物”的三成以上;Figure 2 is a black and white photo of the elongated fiber bundles of rice straw, one of the mixed energy grasses with particle sizes ranging from 3 mesh to no more than 28 mesh. The rice straw is shredded by a machine and screened. The obtained "slender fiber bundle fragments of rice straw mixed with a particle size of not more than 3 mesh to no more than 28 mesh sieve" can generally account for more than 30% of the total "rice straw fragments";
图3为亲水疏解纤维A-1之干团料样品的黑白照片,其是由能源草之一的油芍药秸秆在实验室中所制获:按附图13的流程,最后用手捏脱水,获仍含75%水分的潮料,在室温下自然干燥后所获。从照片中可以看出:干团料中的纤维虽粗直,既纤维没有传统纸浆纤维的细软弯曲且多有分叉态,但其条条粗直纤维间的碰贴牢固,这可从物料所聚的团形并非是支撑此种粗直纤维能稳定聚集的形态和手捏有硬感,以及其没呈散屑状而推知:本发明若在使用少量晶须助剂后,用晶须实现了对纤维的表面接枝/包覆,使纤维表面毛糙化,进而实现使纤维在水中能如尼龙搭扣般地使纤维间的碰搭或和缠绕顺利结合成团/纸的目的。如图3所示的样品,在其进行如实施例4的步骤八中,在“拌入新水或和脱色杂的再生水”里所配加晶须助剂是用的氢氧化钙,既将“拌入新水或和脱色杂的再生水”“x重量份”配成氢氧化钙饱和水溶液,再如实施例4中的步骤八作配料操作。按加入的氢氧化钙饱和水溶液以水温0℃计,氢氧化钙的100g水中的最大溶解量常数是0.185g,在空气中吸收CO2最后都会转化为沉积/包覆于纤维表面的碳酸钙晶须;图3中干团料样品中的绝干纤维100g重量份随潮料所携300g水中氢氧化钙的溶解量≤300g(水)×0.185g/100g(水),既在空气中转化为碳酸钙的重量:W碳酸钙晶须≤【3×[0.185g/(40+2×17)氢氧化钙克分子量]×(40+12+3×16)碳酸钙克分子量=3×[0.185g/74氢氧化钙克分子量]×100碳酸钙克分子量=】0.75g;既图3样品中的晶须材质对主产品A中的绝干纤维100重量份的添加量,为≤1重量份。顺便一提的是图3样品,其入水不浮水面。Figure 3 is a black and white photo of a dry mass sample of hydrophilic decomposable fiber A-1, which is produced in the laboratory from peony straw, one of the energy grasses: follow the process of Figure 13, and finally squeeze and dehydrate by hand. , the wet material still containing 75% moisture is obtained after natural drying at room temperature. It can be seen from the photo: Although the fibers in the dry dough are thick and straight, the fibers are not as soft and bendy as traditional pulp fibers and often have bifurcations, but the thick and straight fibers are firmly in contact with each other. This can be seen from the material. The aggregated group shape is not a form that can support the stable aggregation of such thick straight fibers and has a hard feeling when pinched by hand, and it is not in the shape of crumbs. It can be inferred that if the present invention uses a small amount of whisker additives, the whiskers It realizes the surface grafting/coating of the fiber, roughens the surface of the fiber, and then achieves the purpose of making the fiber in the water like Velcro to make the fiber collide or wind up smoothly to form a ball/paper. For the sample shown in Figure 3, in Step 8 of Example 4, the whisker additive used in "stirring in new water or regenerated water with decolorized impurities" is calcium hydroxide, that is, "Stir in new water or regenerated water with decolorized impurities" and "x parts by weight" to prepare a saturated aqueous solution of calcium hydroxide, and then perform the batching operation as in step 8 in Example 4. According to the added saturated aqueous solution of calcium hydroxide and the water temperature is 0°C, the maximum dissolution constant of calcium hydroxide in 100g of water is 0.185g. When CO 2 is absorbed in the air, it will eventually be converted into calcium carbonate crystals deposited/coated on the surface of the fiber. Must; the dissolved amount of calcium hydroxide in 300g of water carried by 100g of absolutely dry fiber in the dry dough sample in Figure 3 is ≤300g (water) × 0.185g/100g (water) , which is converted into Weight of calcium carbonate: W calcium carbonate whiskers ≤ [3×[0.185g/(40+2×17) calcium hydroxide molecular weight ]×(40+12+3×16) calcium carbonate molecular weight =3×[0.185 g/74 molecular weight of calcium hydroxide ] × 100 molecular weight of calcium carbonate = ] 0.75g; that is, the amount of whisker material in the sample in Figure 3 added to 100 parts by weight of the absolute dry fiber in the main product A is ≤ 1 part by weight . By the way, the sample in Figure 3 does not float when it enters the water.
图4为亲水疏解纤维A-2之干团料样品的黑白照片,其是由能源草之一的桑树枝丫在实验室中所制获:按附图13的流程,最后用手捏脱水,先获仍含75%水分的潮料,再在一次性塑料杯中用手指按紧塑形,倒出,在室温下自然干燥后所获。图4所示的样品中,晶 须助剂是用过320目筛的硅灰石,加水先配成含固不超过20%的悬浊液,再加入接近等当量的硫酸或磺化废硫酸与之反应,生成水合硅酸与二水硫酸钙以及少量未反应完的硅灰石粉之组合物沉淀,待pH值变到5至8范围,既反应终止,再将本已含水的胶泥状反应后产物,再加水配成100重量份水中固含量不高于1.65份的稀悬浊液,然后将此“稀悬浊液”在如实施例4中的步骤八配料中作为“x重量份”加入,这样图4样品中的晶须固形物材质,对最后主产品中的绝干纤维100重量份的添加量,最大就为3×1.65重量份,既为≤5重量份。图4样品,其入水不浮水面。Figure 4 is a black and white photo of a dry mass sample of hydrophilic decomposable fiber A-2, which is produced in the laboratory from Mulberry branch Ya, one of the energy grasses: follow the process of Figure 13, and finally squeeze and dehydrate by hand. First obtain the wet material that still contains 75% moisture, then press it tightly with your fingers to shape it in a disposable plastic cup, pour it out, and dry it naturally at room temperature. In the sample shown in Figure 4, the crystal The additive is wollastonite that has passed through a 320-mesh sieve. Add water to form a suspension with a solid content of no more than 20%. Then add a nearly equivalent amount of sulfuric acid or sulfonated waste sulfuric acid to react with it to generate hydrated silicic acid and sulfonated waste sulfuric acid. The composition of calcium sulfate dihydrate and a small amount of unreacted wollastonite powder is precipitated. When the pH value changes to the range of 5 to 8, the reaction is terminated. Then the already watery cement-like reaction product is added with water to form a weight of 100 A dilute suspension with a solid content of no more than 1.65 parts in water, and then add this "thin suspension" as "x parts by weight" to the ingredients in Step 8 in Example 4, so that the crystals in the sample in Figure 4 The solid material is required. For 100 parts by weight of absolute dry fiber in the final main product, the maximum amount is 3×1.65 parts by weight, which is ≤5 parts by weight. Figure 4 is a sample that does not float when it enters water.
图5为用能源草之一的麦秸秆在实验室中被制成亲水疏解纤维A-2后所抄纸片,再自然干燥后,对纸片仅经手抓一次被折再展开呈纸片被折破实样的黑白照片。请注意:图5所示的“被折破实样”,其中的亲水疏解纤维虽会被折断但不会散,这说明本发明的包覆晶须的技术方案是有效的;“被折破实样”,其对麦秸秆质“亲水疏解纤维A-2”的磨散化处理所用的制样工具,是使用家用食品粉碎机,故此麦秸秆质“亲水疏解纤维A-2”样品中的纤维在被柔化、散化的同时,也大量地被切断化,由此造成此“被折破实样”在“经手抓一次被折”制样过程中,因纤维短而不耐折--有多处的裂口;但保守地讲,即使是按这样的有意被劣质化制备的质量来讲,用此种“亲水疏解纤维A-2”样品料来部分或全部地替代废纸再生纸浆,来作为纸业的一种新原料,也是具有应用市场的,如可被制瓦楞纸、水稻秧苗的育秧或播种纸、纸板、纸模塑制品等。图5所示的样品中,晶须助剂是用实施例2中ⅶ项所述的“氢氧化钙”与“粘土”,再加水配成100重量份水中固含量不高于3份的稀悬浊液,然后将此“稀悬浊液”在在如实施例4中的步骤八配料中加入,这样图5样品中的晶须固形物材质,对最后主产品中的绝干纤维100重量份的添加量,最大就为3×3重量份,既为≤9重量份。Figure 5 is a paper sheet made from wheat straw, one of the energy grasses, which was made into hydrophilic and decomposable fiber A-2 in the laboratory. After natural drying, the paper sheet was folded and unfolded after being grasped only once. Black and white photo of the actual broken specimen. Please note: In the "broken sample" shown in Figure 5, although the hydrophilic and decomposable fibers will be broken, they will not fall apart, which shows that the technical solution of the present invention for coating whiskers is effective; "Broken solid sample", the sample preparation tool used to grind and disperse the "hydrophilic and decomposable fiber A-2" of wheat straw is a household food grinder, so the "hydrophilic and decomposable fiber A-2" of wheat straw is used While the fibers in the sample are being softened and dispersed, they are also cut in large quantities. This causes the "broken sample" to be broken due to its short fiber length during the sample preparation process of "grabbing it once by hand". Folding resistance - there are many cracks; but conservatively speaking, even in terms of the quality of such intentionally inferior preparation, use this "hydrophilic decomposable fiber A-2" sample material to partially or completely replace Waste paper recycled pulp, as a new raw material for the paper industry, also has application markets, such as corrugated paper, rice seedling raising or sowing paper, cardboard, paper molded products, etc. In the sample shown in Figure 5, the whisker additive is made of the "calcium hydroxide" and "clay" described in item vii of Example 2, plus water to prepare a dilute solution with a solid content of no more than 3 parts in 100 parts by weight of water. suspension, and then add this "thin suspension" to the ingredients in step eight in Example 4, so that the whisker solid material in the sample in Figure 5 is 100% of the absolute dry fiber in the final main product. The maximum added amount is 3×3 parts by weight, which is ≤9 parts by weight.
再有,本技术方案所提供的晶须助剂中即使是用及了氢氧化钙,也因其量微,仅需暴露于空气中就能碳化生成碳酸钙,而无需刻意导加CO2Furthermore, even if calcium hydroxide is used in the whisker additive provided by this technical solution, due to its small amount, it can be carbonized to generate calcium carbonate only by exposure to the air, without the need to deliberately introduce CO 2 .
实施例5.实施例1所述产品集合中的“主产品A--亲水疏解纤维产品”和“副产品C--木素/树脂混合物产品”的联产制法,其特征至少包括:制A与C-1联产,可先经如下例5-1或/和例5-2步骤;或制A与C-2联产,可先经如下例5-3或/和例5-4或/和例5-5步骤;最后都走5-6步骤而获实现:Embodiment 5. The co-production method of "main product A - hydrophilic decomposable fiber product" and "by-product C - lignin/resin mixture product" in the product set described in Example 1, the characteristics of which at least include: To co-produce A and C-1, you can first go through the steps of Example 5-1 or/and Example 5-2; or to co-produce A and C-2, you can go through the following Example 5-3 or/and Example 5-4 first. Or/and Example 5-5 steps; in the end, all are achieved by taking steps 5-6:
例5-1.用新鲜的能源草之去根带叶的整株或剥除叶片的茎秆部料,用清水洗净,脱水、晾干,然后进榨汁机压榨,较佳的是控制压榨后的出渣含水量在20%(wt%)以下,压榨出之液体既为实施例2中ⅱ项所述的副产物料2--“先用水洗净后的鲜能源草再经压榨所获的鲜汁液”;或再将此“鲜汁液”加热至100~105℃保持3~5分钟,冷却、装罐即成液体状红茶色之食用或医用级的木素/树脂混合物产品C-1;若在加热的同时,再对“鲜汁液”施以蒸发提浓操作,则在控制蒸出水多少的操控工艺参数条件下,可使“鲜汁液”的被蒸浓料再在冷至室温时,可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的食用或医用级木素/树脂混合物产品C-1;Example 5-1. Use fresh energy grass to remove the whole plant with roots and leaves or peel off the stem parts of the leaves, wash it with clean water, dehydrate and dry it, and then squeeze it into a juicer. It is better to control The moisture content of the residue after pressing is below 20% (wt%), and the liquid squeezed out is the by-product material 2 described in item ii in Example 2 - "fresh energy grass washed with water first and then pressed "The obtained fresh juice"; or this "fresh juice" can be heated to 100-105°C for 3-5 minutes, cooled, and canned to obtain a liquid black brown edible or medical grade lignin/resin mixture product C -1; If the "fresh juice" is subjected to an evaporation and concentration operation while heating, then under the control process parameters of controlling the amount of steamed water, the steamed and concentrated material of the "fresh juice" can be cooled to At room temperature, edible or medical grade lignin/resin mixture product C-1 can be in the form of a paste-like tan colloid, or a coffee-colored powder or granules, or a rosin-like solid block;
例5-2.用经晒干或自然晾干或烘干的能源草之去根带叶的整株或剥除叶片的茎秆部,或是用能源草干料经破碎过筛脱除过28目筛细粉后的粗料,用清水洗净,可再加入干料重量的0.7至5.7倍范围的清水,加热到70℃乃至煮沸,然后进榨汁机压榨,较佳的是控制压榨后的出渣含水量在20%(wt%)以下,压榨出之液体既为实施例2中ⅱ项所述的副产物料2--“干能源草经水洗净后再水煮、压榨所获的汁液”;或再将此“汁液”加热至100~105℃保持3~5分钟,冷却、装罐即成液体状红茶色之食用或医用级的木素/树脂混合物产品C-1; 若在加热的同时,再对“汁液”施以蒸发提浓操作,则在控制蒸出水多少的操控工艺参数条件下,可使“汁液”被蒸浓料再在冷至室温时,可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的食用或医用级木素/树脂混合物产品C-1;Example 5-2. Use the whole plant with roots and leaves or remove the stem part of the leaves from the sun-dried or naturally dried energy grass, or use the energy grass dry material to remove it through crushing and sieving. After sieving the coarse material into fine powder with a 28-mesh mesh, wash it with clean water. You can add water ranging from 0.7 to 5.7 times the weight of the dry material, heat it to 70°C or even boil it, and then press it into a juicer. It is better to control the pressing. The moisture content of the final slag is below 20% (wt%), and the liquid squeezed out is the by-product material 2 described in item ii in Example 2 - "dry energy grass is washed with water and then boiled and pressed. "Obtained juice"; or this "juice" can be heated to 100-105°C for 3-5 minutes, cooled, and canned to obtain a liquid black brown edible or medical grade lignin/resin mixture product C-1 ; If the "juice" is subjected to an evaporation and concentration operation while heating, then under the control of process parameters that control the amount of steamed water, the "juice" can be evaporated and concentrated, and then when cooled to room temperature, it can be presented as noodles. Edible or medical grade lignin/resin mixture product C-1 in the form of paste-like brown colloid, or coffee-colored powder or granules, or rosin-like solid block;
例5-3.用新鲜的能源草湿料的去根带叶的整株或剥除叶片的茎秆部料,然后进榨汁机压榨,较佳的是控制压榨后的出渣含水量在20%(wt%)以下,压榨出之液体既为实施例2中ⅱ项所述的副产物料2--“用鲜能源草”“经压榨所获的鲜汁液”;或再将“鲜汁液”加热至100~105℃保持3~5分钟,冷却、装罐即成液体状红茶色之饲用或工业级的木素/树脂混合物产品C-2;若在加热的同时,再对“鲜汁液”施以蒸发提浓操作,则在控制蒸出水多少的操控工艺参数条件下,可使“鲜汁液”的被蒸浓料再在冷至室温时,可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的饲用或工业级的木素/树脂混合物产品C-2;Example 5-3. Use fresh energy grass wet material, the whole plant with roots and leaves removed or the stem part with the leaves removed, and then put it into a juicer for squeezing. It is better to control the moisture content of the slag after squeezing. 20% (wt%) or less, the liquid squeezed out is either the by-product material 2 described in item ii of Example 2 - "fresh energy grass" and "fresh juice obtained by pressing"; or the "fresh juice obtained by pressing"; "Juice" is heated to 100~105℃ for 3~5 minutes, cooled and canned to obtain a liquid black brown feed or industrial grade lignin/resin mixture product C-2; if it is heated at the same time, then " "Fresh juice" is subjected to an evaporation and concentration operation, and under the control of process parameters that control the amount of steamed water, the steamed and concentrated material of "fresh juice" can be turned into a brown paste-like colloid when cooled to room temperature. Or feed or industrial grade lignin/resin mixture product C-2 in the form of brown powder or granules, or rosin-like solid blocks;
例5-4.用经晒干或自然晾干或烘干的能源草之去根带叶的整株或剥除叶片的茎秆部料,或是用能源草干料仅经破碎过筛脱除过28目筛细粉后的粗料,可加入干料重量的0.7至5.7倍的清水,加热到70℃乃至煮沸,然后进榨汁机压榨,较佳的是控制压榨后的出渣含水量在20%(wt%)以下,压榨出之液体既为实施例2中ⅱ项所述的副产物料1--热水脱木素/树脂工序所排棕/黑液;或再将“棕/黑液”加热至100~105℃保持3~5分钟,冷却、装罐即成液体状红茶色之饲用或工业级的木素/树脂混合物产品C-2;若在加热的同时,再对“棕/黑液”施以蒸发提浓操作,则在控制蒸出水多少的操控工艺参数条件下,可使“棕/黑液”被蒸浓料再在冷至室温时,可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的饲用或工业级的木素/树脂混合物产品C-2;Example 5-4. Use the whole plant with roots and leaves removed from the energy grass that has been sun-dried or naturally dried or oven-dried, or use the stem material with the leaves removed, or use the dry energy grass material that has only been crushed and screened. After removing the coarse material from the 28-mesh sieve, you can add 0.7 to 5.7 times the weight of the dry material with clean water, heat it to 70°C or even boil it, and then press it into a juicer. It is better to control the content of the residue after pressing. The water content is below 20% (wt%), and the liquid squeezed out is the by-product material 1 described in item ii in Example 2 - the brown/black liquor discharged from the hot water delignification/resin process; or the " "Brown/Black Liquor" is heated to 100-105°C for 3-5 minutes, cooled, and canned to obtain a liquid black brown feed or industrial-grade lignin/resin mixture product C-2; if heated at the same time, Then the "brown/black liquor" is subjected to an evaporation and concentration operation, and under the control of process parameters that control the amount of steamed water, the "brown/black liquor" can be evaporated and concentrated, and then when cooled to room temperature, it can be presented as noodles. Feed or industrial grade lignin/resin mixture product C-2 in the form of paste-like brown colloid, or coffee-colored powder or granules, or rosin-like solid block;
例5-5.收集前述例5-1或/和例5-2项中所述“清水洗净”后脱除水,用此种水对牛粪作洗选,脱除过28目筛的杂质,撩获由水淘洗过筛后未过28筛的粗纤维,对其作煮沸处理,杀灭其中的纤维素分解酶,再对其做进榨汁机压榨,较佳的是控制压榨后的出渣含水量在20%(wt%)以下,压榨出之液体既为实施例2中ⅱ项所述的副产物料1--热水脱木素/树脂工序所排棕/黑液;或再将“棕/黑液”加热至100~105℃保持3~5分钟,冷却、装罐即成液体状红茶色之饲用或工业级的木素/树脂混合物产品C-2;若在加热的同时,再对“棕/黑液”施以蒸发提浓操作,则在控制蒸出水多少的操控工艺参数条件下,可使“棕/黑液”被蒸浓料再在冷至室温时,可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的饲用或工业级的木素/树脂混合物产品C-2;对牛粪所做淘/洗处理后排出的淘/洗液,既实施例2中ⅱ项里所述的“副产物料3”,则可作耐肥耗水的巨菌草等的直接浇灌用水等;Example 5-5. Collect the water removed after "washing with clean water" as described in the above Example 5-1 or/and Example 5-2, use this water to wash the cow dung, and remove the 28-mesh sieve Impurities, pick up the crude fiber that has not passed 28 sieves after being washed with water, boil it to kill the cellulolytic enzymes in it, and then put it into a juicer for squeezing. It is better to control the squeezing. The moisture content of the final residue is below 20% (wt%), and the liquid squeezed out is the by-product material 1 described in item ii in Example 2 - the brown/black liquor discharged from the hot water delignification/resin process. ; Or heat the "brown/black liquor" to 100-105°C for 3-5 minutes, cool it, and can it to form a liquid black brown feed or industrial-grade lignin/resin mixture product C-2; if While heating, the "brown/black liquor" is subjected to an evaporation and concentration operation. Under the control process parameters of controlling the amount of steamed water, the "brown/black liquor" can be evaporated and concentrated and then cooled to room temperature. Feed or industrial grade lignin/resin mixture product C-2, which can be in the form of a paste-like tan colloid, or a coffee-colored powder or granules, or a rosin-like solid block; washed/washed cow dung The washed/washing liquid discharged after treatment, which is the "by-product material 3" described in item ii of Example 2, can be used as direct irrigation water for fertilizer-resistant and water-consuming giant fungus grass, etc.;
例5-6.将前述例5-1至例5-5所述的“较佳的是控制压榨后的出渣含水量在20%(wt%)以下”之渣,可再用水泡化成含固25%的呈松散肉松状物料,筛取其中大小在过3目至不过28目筛孔范围的粒度分级或混合的细长状纤维束,既可获如实施例4中步骤四所述的“初脱除纤维中水溶质的待处理亲水疏解纤维中间产物甲的潮料”,后续可再走实施例4中第五至第十步骤的操作,最后就能获亲水疏解纤维产品A-1或A-2;对前述5-5中所述的“对牛粪作洗选”“由水淘洗过筛”所产生的含牛粪之水,既为实施例2中ⅱ项所述的“副产物料3:淘/洗牛粪所产生的淘/洗液”,可被导送做实施例1所述“辅助产品E--液态有机土壤改良剂”的配料之一。Example 5-6. The slag described in the aforementioned Examples 5-1 to 5-5 "It is better to control the moisture content of the slag after pressing to be below 20% (wt%)" can be soaked into water containing Consolidate 25% of the loose floss-like material, sieve out the particle size classification or mixed elongated fiber bundles ranging from 3 mesh to 28 mesh, and obtain the fiber bundle described in step 4 of Example 4. "The moisture material to be treated as the hydrophilic decomposable fiber intermediate product A after initially removing the water solute in the fiber" can be followed by the fifth to tenth steps in Example 4, and finally the hydrophilic decomposable fiber product A can be obtained -1 or A-2; the water containing cow dung produced by "washing cow dung" and "washing and sifting with water" described in the aforementioned 5-5 is the same as item ii in Example 2. The above-mentioned "by-product material 3: washing/washing liquid produced by washing/washing cow dung" can be directed to be one of the ingredients of the "auxiliary product E--liquid organic soil conditioner" described in Example 1.
图6为副产品C-2--饲用或工业级的木素/树脂混合物的黑白照片,其可被配方施用饲料添加剂、植物营养剂,或被用作橡/塑助剂等,其是用在制亲水疏解纤维A中的热水脱木素/树脂工序排出的棕/黑液,经在实验室中直接用烧杯在电炉上蒸发、脱水浓缩至干后所得。 Figure 6 is a black and white photo of by-product C-2 - feed or industrial grade lignin/resin mixture, which can be formulated as feed additives, plant nutrients, or used as rubber/plastic additives, etc. It is used The brown/black liquor discharged from the hot water delignification/resin process in the production of hydrophilic decomposable fiber A is directly evaporated in a beaker on an electric stove in the laboratory, dehydrated and concentrated to dryness.
实施例6.实施例1所述产品集合中的“B--木塑复合再生质粗粒产品”之制法,其特征在于如下例6-1至例6-6:Embodiment 6. The preparation method of "B--wood-plastic composite recycled coarse-grained product" in the product set described in Embodiment 1 is characterized by the following Examples 6-1 to 6-6:
例6-1.备料:对实施例5中例5-1至例5-5里的任一所述的“较佳的是控制压榨后的出渣含水量在20%(wt%)以下”之渣,做“木塑复合再生质粗粒”中的“木”备料;Example 6-1. Material preparation: For any one of Example 5-1 to Example 5-5 in Example 5, "It is better to control the moisture content of the residue after pressing to be below 20% (wt%)" The slag is used as the "wood" material in "wood-plastic composite recycled material coarse particles";
或/和用未经压榨处理的干能源草,仅经一次的破碎或切段粉碎后之风选或/和筛分,选出养分较少的物料做“木塑复合再生质粗粒”中的“木”备料,和剩余出的养分较多物料另做有机肥或/和饲料的备料;所述“养分较少的物料”,计量地讲,是将在经一次的破碎或切段粉碎后,能经受住机械破碎力而未被更细碎化的过3至不过28目筛范围的能源草粗纤维,和过150目筛的之能源草粉碎物中含土量较多的精细能源草纤维粉;所述“养分较多的物料”,计量地讲,就是在仅经一次的破碎或切段粉碎后,不能经受住机械破碎力而被更细碎化的过28至不过150目筛范围的含土量微的粒径居中的能源草纤维粉屑;Or/and use dry energy grass that has not been pressed, and only crush or cut into sections once, then winnow or/and screen, and select materials with less nutrients to make "Wood-Plastic Composite Regenerated Coarse Grain" The "wood" is prepared, and the remaining materials with more nutrients are used as organic fertilizer or/and feed materials; the "materials with less nutrients", in terms of measurement, are the materials that have been crushed or cut into pieces after one Finally, the crude energy grass fiber that can withstand the mechanical crushing force without being more finely divided and passes through a sieve ranging from 3 to 28 mesh, and the fine energy grass that has a higher soil content in the crushed energy grass that passes through a 150 mesh sieve. Fiber powder; the "materials with more nutrients", in terms of measurement, are materials that cannot withstand the mechanical crushing force and are more finely crushed after being crushed or cut into pieces once, and pass through a sieve ranging from 28 to no more than 150 mesh. Energy grass fiber powder with small soil content and medium particle size;
对购入或/和免费收集来的废塑料原料,对其呈压缩打包态或/和其中杂有大块金属、砖块类固体的原料,则须先经破碎、风选,以开松物料和脱除其中的金属、砖块类硬质固体;将脱除了杂质的蓬松废塑料作为“木塑复合再生质粗粒”中的“塑”备料;Waste plastic raw materials purchased or/and collected for free, which are in a compressed and packaged state or/and which contain large pieces of metal or brick-like solids, must first be crushed and winnowed to loosen the materials. and remove hard solids such as metal and bricks; use the fluffy waste plastic with impurities removed as the "plastic" material in "wood-plastic composite recycled coarse particles";
例6-2.配料:按实施例3中例3-4或例3-5所述“木塑复合再生质粗粒”的组成中“木”与“塑”和软化剂在产品总重量中的投料占比,秤重配料;Example 6-2. Ingredients: According to the composition of the "wood-plastic composite recycled coarse particles" described in Example 3-4 or Example 3-5 in Example 3, "wood", "plastic" and softener are included in the total weight of the product. The proportion of feeding materials and weighing the ingredients;
例6-3.造粒:将秤配好的料,经混合集料仓,再由机械输送,投于实施例3中之例3-7、例3-8所述“粗粒造粒机”中成粒;所述“粗粒造粒机”所使用的机械是:具有连续式进/出料功能的饲料颗粒机、有机肥造粒机、生物质燃料颗粒机的任一种,或再在前述“颗粒机”/“造粒机”之后再串联螺旋切粒中碎机;前述的“颗粒机”/“造粒机”,出机物料呈过孔模所形成的段条粒状,如将前述“段条粒状”“物料”再经串联的螺旋切粒中碎机处理,则再出机物料就呈不规则颗粒;成粒时的物料被机械挤压/摩擦所发热升温,可用向物料或/和机械中的夹层中加水方式,来操控其出机物料不超过110℃;此操作所造成的“木塑复合再生质粗粒”,其质地呈可被人手指/掌直接拉/扳/捏/撕得碎的低强度;其成粒形状至少包括呈过孔模所形成的段条粒状或呈不规则颗粒;所述“孔模”的孔形,至少包括等边或不等边长的3至12边形的任一种,或圆形;所述“粒”的大小,在过25mm至不过2.0mm筛孔范围的任一孔径的分级或混合;Example 6-3. Granulation: The materials prepared by the scale are passed through the mixing and collecting bin, then transported by machinery, and put into the "coarse granulator" described in Examples 3-7 and 3-8 in Example 3. "Medium granulation; the machinery used in the "coarse granulator" is: any one of a feed pellet machine, an organic fertilizer granulator, a biomass fuel pellet machine with continuous feeding/discharging functions, or After the aforementioned "granulator"/"granulator", a spiral granulator and a secondary crusher are connected in series; the aforementioned "granulator"/"granulator" discharges the material in the form of segmented granules formed by the through-hole mold. If the aforementioned "segmented granular" "materials" are processed by a series-connected spiral granulator and secondary crusher, the materials will appear as irregular particles when they are discharged from the machine; the materials during granulation are heated by mechanical extrusion/friction and can be used Add water to the material or/and the interlayer in the machine to control the outgoing material to not exceed 110°C; the "coarse wood-plastic composite recycled material" produced by this operation has a texture that can be directly pulled by human fingers/palms / pull / pinch / tear into pieces of low strength; its granulated shape at least includes segmented granules or irregular particles formed by the through-hole mold; the hole shape of the "hole mold" includes at least equilateral or irregular Any of 3 to 12 sides with equal sides, or a circle; the size of the "grain" is classified or mixed in any aperture ranging from 25mm to less than 2.0mm mesh;
例6-4.均化混粒:若例6-3项所获的“木塑复合再生质粗粒”在后续包装后有明显的包包不同质的质量瑕疵,则可在称重包装前加施混粒均化处理,所述的处理,既是用机械滚筒将例5-3项所获的“木塑复合再生质粗粒”导入,滚翻混合匀即可;Example 6-4. Homogenization and mixing: If the "wood-plastic composite recycled coarse particles" obtained in Example 6-3 have obvious quality defects such as inhomogeneous packaging after subsequent packaging, they can be weighed before packaging. Add a mixing and homogenizing process. The process is to use a mechanical roller to introduce the "wood-plastic composite recycled coarse particles" obtained in Example 5-3, and tumble and mix evenly;
例6-5.称重包装:将符合质量要求的例6-3或/和例6-4项所获的“木塑复合再生质粗粒”经称重后导入市场客户认可规格的包装袋中;Example 6-5. Weighing and packaging: The "Wood Plastic Composite Regenerated Coarse Granules" obtained in Example 6-3 or/and Example 6-4 that meet the quality requirements are weighed and then introduced into packaging bags with specifications approved by market customers. middle;
例6-6.入库质检:将包装好的产品按序入库,并按市场客户所需知的指标项,给出各批次入库产品的质检报告作存档。Example 6-6. Inbound quality inspection: Put the packaged products into the warehouse in order, and provide quality inspection reports for each batch of incoming products for archiving according to the indicators that market customers need to know.
请参见附图7、图8:图7是废纸制再生纸浆所排弃杂废塑膜料的黑白照片,其中含有铝塑复合模等杂质,这是混杂废塑料中最难被绿色化可持续再利用的品种,我国就是因此种废塑料再生污染难题而禁绝了国外废纸的进口;图8是木塑复合再生质粗粒B的一张黑白照片,其是用图7所示“杂废塑膜料”与过28目筛的能源草碎化物,或和实施例5中例5-3至例5-5所述“C-2”相混合后,用现时普通制生物质颗粒的造粒机所制获。Please refer to attached Figures 7 and 8: Figure 7 is a black-and-white photo of plastic film materials discarded from recycled pulp made from waste paper. It contains impurities such as aluminum-plastic composite molds. This is the most difficult to be greened among mixed waste plastics. It is a type of continuous reuse that our country has banned the import of foreign waste paper because of the problem of waste plastic recycling pollution. Figure 8 is a black and white photo of wood-plastic composite recycled coarse grain B, which is made of the "miscellaneous" material shown in Figure 7. "Waste plastic film material" is mixed with energy grass crumbs passed through a 28-mesh sieve, or with "C-2" described in Example 5-3 to Example 5-5 in Example 5, and then the current common biomass granule production process is used. Produced by granulator.
实施例7.实施例1所述产品集合中的“辅助产品”D至I的制法,其特征在于例7-1至例7-6所述: Embodiment 7. The preparation method of "auxiliary products" D to I in the product set described in Embodiment 1, which is characterized by the following:
例7-1.实施例1所述“辅助产品D--固态有机土壤改良剂产品”的制法,其特征至少在于:以能源草,或能源草和牛粪为起始主原料时,使用提取了制主产品A用原料后的余料,既过28目筛孔的能源草之粉料或和细牛粪沉渣,作为“辅助产品D”中的配料之一;Example 7-1. The preparation method of "auxiliary product D - solid organic soil conditioner product" described in Example 1 is at least characterized by: using energy grass, or energy grass and cow dung as the starting main raw materials, using extraction The remaining materials after preparing the raw materials for main product A, namely energy grass powder or fine cow dung sediment that has passed through a 28-mesh sieve, are used as one of the ingredients in "auxiliary product D";
例7-2.实施例1所述“辅助产品E--液态有机土壤改良剂产品”的制法,,其特征至少在于:由能源草,或能源草和牛粪为起始主原料,在制备“主产品A--亲水疏解纤维产品”和“副产品C--木素/树脂混合物产品”时,由因提质产品A和C所排出的压榨液或/和洗涤液或/和淘洗液;再将“压榨液或/和洗涤液或/和淘洗液”按所被施农作物和地块的土质改良所需,经搀兑处理所获的液态有机土壤改良剂产品;所述“排出的压榨液或/和洗涤液或/和淘洗液”,其pH值皆不超出5.0~9.4范围,和其中所含Na+或/和K+或/和Mg2+的克摩尔与其所含水的升体积之比为≤0.034mol/L,或其中所含的可溶性钠盐、钾盐、镁盐的wt%总浓度≤0.20%(wt%),或其中所含的可溶性钠盐、钾盐、镁盐的总浓度与生产实施地所取水源中的可溶性钠盐、钾盐、镁盐的总浓度之差≤0.01%(wt%);辅助产品E与主产品A的重量之比被控制在产品E/产品A≤100/100~300/100范围,既≤100/100或≤300/100范围;Example 7-2. The preparation method of "auxiliary product E--liquid organic soil conditioner product" described in Example 1, is at least characterized in that: energy grass, or energy grass and cow dung are used as the starting main raw materials. When "main product A - hydrophilic decomposable fiber product" and "by-product C - lignin/resin mixture product", the pressing liquid or/and washing liquid or/and elutriation discharged from the upgraded products A and C liquid; and then the liquid organic soil conditioner product obtained by blending the "pressed liquid or/and washing liquid or/and elutriation liquid" according to the soil improvement requirements of the crops and plots to be applied; the " The pH value of the discharged pressing liquid or/and washing liquid or/and elutriation liquid does not exceed the range of 5.0 to 9.4, and the gram mole of Na + or/and K + or/and Mg 2+ contained therein is equal to that of the The ratio of water to liter volume is ≤0.034mol/L, or the total wt% concentration of soluble sodium salts, potassium salts, and magnesium salts contained therein is ≤0.20% (wt%), or the soluble sodium salts, potassium salts, and magnesium salts contained therein are ≤0.20% (wt%). The difference between the total concentration of potassium salt and magnesium salt and the total concentration of soluble sodium salt, potassium salt and magnesium salt in the water source taken from the production site is ≤0.01% (wt%); the weight ratio of auxiliary product E to main product A Controlled within the range of product E/product A ≤ 100/100 ~ 300/100, that is, ≤ 100/100 or ≤ 300/100;
例7-3.实施例1所述“辅助产品F--发酵饲料产品”的制法,其特征至少在于:将实施例2中ⅱ项所述“副产物料1:热水脱木素/树脂工序所排棕/黑液”或/和“或副产物料2:压榨鲜能源草所获的鲜汁液会”掺于仅经破/粉碎的能源草后,再经发酵,既可获得辅助产品F;Example 7-3. The preparation method of "auxiliary product F - fermented feed product" described in Example 1, which is at least characterized in that: the "by-product material 1: hot water delignification/ "Brown/black liquor discharged from the resin process" or/and "or by-product material 2: The fresh juice obtained by squeezing the fresh energy grass will be mixed with the energy grass that has only been broken/crushed, and then fermented to obtain auxiliary materials Product F;
例7-4.实施例1所述“辅助产品G--颗粒饲料产品”的制法,其特征至少在于:在以未经压榨处理的干能源草为起始主原料时,用筛取了主产品A用原料后的余料,既“过28目筛细粉”,或/和“过28至不过150目筛范围的含土量微的粒径居中的能源草纤维粉屑”,作为颗粒饲料产品中的配料组份;Example 7-4. The preparation method of "auxiliary product G - pellet feed product" described in Example 1 is at least characterized in that: when using dry energy grass that has not been pressed as the starting main raw material, sieved The remaining materials after using the raw materials for the main product A are "fine powder passed through a 28 mesh sieve", or/and "energy grass fiber powder with a small soil content and a medium particle size passed through a 28 to less than 150 mesh sieve", as Ingredients in pellet feed products;
例7-5.实施例1所述“辅助产品H--生物质颗粒燃料产品”的制法,其特征至少在于:以能源草被破碎、过筛脱除了未过28目筛之粗纤维的细粉料,或是全组份的能源草粉碎物,为配料组份,或再配加了废塑料的生物质颗粒燃料产品;所述“废塑料”,至少包括废农用塑膜、废泡沫塑料、废化纤织物或/和化纤棉絮的任一或多种的组合,所述的“配加”占辅助产品H之总重量的5%以下,或至可高不超22%;Example 7-5. The preparation method of "auxiliary product H--biomass pellet fuel product" described in Example 1 is at least characterized in that: the energy grass is crushed and sieved to remove crude fibers that have not passed the 28-mesh sieve. Fine powder, or full-component energy grass pulverization as ingredients, or biomass pellet fuel products added with waste plastics; the "waste plastics" include at least waste agricultural plastic films and waste foam Any one or more combinations of plastics, waste chemical fiber fabrics or/and chemical fiber wadding, the "addition" mentioned above accounts for less than 5% of the total weight of the auxiliary product H, or can be as high as no more than 22%;
例7-6.实施例1所述“辅助产品I--食用菌种植棒/块产品”的制法,其特征至少在于:在以能源草,或能源草和牛粪为起始主原料时,用筛取了主产品A用原料后的余料,既过28目筛孔的能源草之粉料或和细牛粪沉渣,作为食用菌种植棒/块产品中的配料组份。Example 7-6. The preparation method of "auxiliary product I - edible fungus planting stick/block product" described in Example 1 is at least characterized in that: when energy grass, or energy grass and cow dung are used as the starting main raw materials, The remaining material after sifting out the raw materials for the main product A is the energy grass powder or fine cow dung sediment that has passed through a 28-mesh sieve, and is used as an ingredient in the edible fungus planting stick/block product.
实施例8.实施例4至7所述“制法”所用及的设备,请参见附图14--本发明所述产品集合制法所用及工艺设备流程的方框示意图,其特征还在于如下例8-1至例8-4或和例8-5所述:Embodiment 8. For the equipment used in the "preparation method" described in Embodiments 4 to 7, please refer to Figure 14 - a block diagram of the flow of process equipment used in the production method of the product set of the present invention. It is also characterized by the following Examples 8-1 to 8-4 or as described in Example 8-5:
例8-1.实施实施例4所述“步骤一”至“步骤十”,涉及设置组合机械Ⅰ至Ⅹ,请参见附图14中位于由“·-”所围δ区块,其中包括:Example 8-1. Implementing "Step 1" to "Step 10" described in Example 4 involves setting up combined machinery I to X. Please refer to the δ block surrounded by "·-" in Figure 14, which includes:
对实施实施例4所述“步骤一”的“预处理备料”用组合机械Ⅰ,其中至少包括:设置破碎机械1、锯/碾/切/锤的任一或多种组合碎化机2、风选机械3、机械筛4,以对能源草干捆扎料在经破碎机,锯/碾/切/锤的任一或多种组合碎化机处理,再经风选、筛分后,筛取出能源草碎化物料中的过3目至不过28目筛范围的任一目数的分级或混和粒径的细长状纤维束;或在机械筛4之后再设置膨化机械5,实现对已获脱杂净化和筛分后的细长状纤维束能源草碎化物,再施机械膨化处理;由此1、2、3、4、5的机械设置,实现对实施例4中步骤一的“预处理备料”之实现--获得可入步骤二再做加工的备用能源草碎化物; The combined machine Ⅰ for the "pretreatment and preparation" of "Step 1" described in Embodiment 4, which at least includes: a crushing machine 1, any one or more combination crushers 2 of saw/mill/cut/hammer, Air separation machinery 3 and mechanical screening 4 are used to process the energy straw bundles through any one or more combinations of crushers, saws/mills/cuts/hammers, and then through air selection and screening. Take out the elongated fiber bundles with any mesh size ranging from 3 mesh to no more than 28 mesh in the energy grass crushed material; or set up the expansion machine 5 after the mechanical screen 4 to realize the obtained The slender fiber bundle energy grass crumbs after removal of impurities, purification and screening are then subjected to mechanical expansion treatment; thus, the mechanical settings of 1, 2, 3, 4, and 5 realize the "preparation" of step one in Example 4. Realization of "Processing and Preparing Materials" - Obtaining backup energy grass crumbs that can be processed in step 2;
对实施实施例4所述“步骤二”的“第一次配料”用组合机械Ⅱ,其中至少包括:设置放置“备用能源草碎化物”的配料仓6,盛载后续步骤七所述“第二次固液分离”所获的挤出水之液槽7,或和设置存放“表面活性剂”的料仓8,设置称重计量衡器9,设置对“第一次配料”后的混合搅拌器10;由此6、7、8、9、10的机械设置,实现对实施例4中步骤二的“第一次配料”之实现;The combined machine II for the "first batching" of the "Step 2" described in Embodiment 4 at least includes: a batching bin 6 for placing the "backup energy grass crumbs", containing the "first batching" described in the subsequent Step 7. A liquid tank 7 for the extruded water obtained from "secondary solid-liquid separation", or a bin 8 for storing "surfactant", a weighing scale 9, and a mixing and stirring device after the "first batching" Device 10; with this mechanical arrangement of 6, 7, 8, 9, and 10, the "first batching" of step 2 in Example 4 is realized;
对实施实施例4所述“步骤三”的“加热溶出”用组合机械Ⅲ,其中至少包括:设置搅拌混合和加热且保温的罐11;以此11的机械设置,实现对实施例3中步骤三所述“‘备用能源草碎化物’料之自然绝干料:100重量份”、“后续步骤七所述‘第二次固液分离’所获的挤出水”:“2x重量份”,或和“‘挤出水’‘2x重量份’的0.1~0.3%重量份之‘表面活性剂’”,将这些物料置于一可被搅拌混合和加热且保温的罐11中,对物料实施均匀搅拌和加热至70℃以上,并保温滞留的操作;The combined machine III for "heating dissolution" of "Step 3" described in Embodiment 4, which at least includes: a tank 11 for stirring, mixing, heating and insulation; with the mechanical setting of 11, the steps in Embodiment 3 are realized. "Natural dry material of 'Standby Energy Grass Crushed Material' material as described in the third step: 100 parts by weight", "Extruded water obtained from the 'second solid-liquid separation' described in the subsequent step seven": "2x parts by weight" , or with "0.1 to 0.3% by weight of 'surfactant' of 'extruded water' '2x parts by weight'", place these materials in a tank 11 that can be stirred, mixed, heated and insulated, and the materials Implement uniform stirring and heating to above 70°C, and keep warm;
对实施实施例4所述“步骤四”的“第一次固液分离”用组合机械Ⅳ,其中至少包括:设置输送机械12、螺杆或扎辊式挤浆机13,固液分离机14,存放“第一次固液分离”所获的“压/挤出棕/黑液”的储槽15;由此12、13、14、15的机械设置,实现将实施例4中步骤四所述将“加热、保温操作后的物料导入螺杆或扎辊式挤浆机,对物料的纤维束作碾挤的机械揉化处理,然后再将物料导入固液分离机作固/液分离”,“或直接将上述加热、保温操作后的物料导入固液分离机作固/液分离”;The combined machinery IV for the "first solid-liquid separation" of "Step 4" described in Embodiment 4 at least includes: a conveying machine 12, a screw or roller squeezer 13, and a solid-liquid separator 14, Storage tank 15 for storing the "pressed/extruded brown/black liquor" obtained from the "first solid-liquid separation"; with the mechanical settings of 12, 13, 14, and 15, the steps described in step 4 of Example 4 are realized. "The material after heating and heat preservation operations is introduced into a screw or roller extruder, and the fiber bundles of the material are mechanically kneaded by crushing and extrusion, and then the material is introduced into a solid-liquid separator for solid/liquid separation." Or directly introduce the materials after the above heating and heat preservation operations into the solid-liquid separator for solid/liquid separation”;
对实施实施例4所述“步骤五”的“第二次配料”用组合机械Ⅴ,其中至少包括:设置放置“待处理亲水疏解纤维中间产物甲的潮料”的存料仓16,盛载后续步骤十所述“第三次固液分离”所获的挤出水之液槽17,或和设置存放“晶须助剂”的料仓18,设置称重计量衡器19,设置对“第二次配料”后的混合搅拌器20;由此16、17、18、19、20的机械设置实现对实施例4中“步骤五”的机械化操作;The combined machine V for the "second batching" of the "step five" described in Example 4 at least includes: a storage bin 16 for placing the "moist material of the hydrophilic decomposable fiber intermediate product A to be processed". A liquid tank 17 containing the extruded water obtained from the "third solid-liquid separation" described in the subsequent step ten, or a silo 18 for storing "whisker additives", a weighing scale 19, and a "whisker additive" The mixing stirrer 20 after "the second batching"; thus, the mechanical settings of 16, 17, 18, 19, and 20 realize the mechanized operation of "Step 5" in Embodiment 4;
对实施实施例4所述“步骤六”的“碾磨消潜”用组合机械Ⅵ,其中至少包括:设置高浓磨浆机21,在高浓磨浆机21的进料口之前设置待处理物料的储料仓22,在储料仓22与高浓磨浆机21之间,设置输送机构或输送机械23;在高浓磨浆机21的出料口之后,设置带保温或和加热功能的消潜罐24,在高浓磨浆机21的出料口与消潜罐24的进料口之间,设置输送机构或输送机械25;由此21、22、23、24、25的机械设置实现对实施例4中“步骤六”的机械化操作;The combined machine VI for "grinding and latent elimination" of "Step 6" described in Embodiment 4, which at least includes: setting up a high-consistency refiner 21, and setting a to-be-processed machine in front of the feed port of the high-consistency refiner 21 The material storage bin 22 is provided with a conveying mechanism or conveying machinery 23 between the storage bin 22 and the high-consistency refiner 21; after the outlet of the high-consistency refiner 21, a heat preservation or heating function is provided The submersion elimination tank 24 is provided with a conveying mechanism or conveying machinery 25 between the outlet of the high-consistency refiner 21 and the feed inlet of the submersion elimination tank 24; thus, the machinery of 21, 22, 23, 24, 25 Set up to realize the mechanized operation of "Step 6" in Embodiment 4;
对实施实施例4所述“步骤七”的“第二次固液分离”用组合机械Ⅶ,其中至少包括:设置输送机械26、螺杆或扎辊式挤浆机27,固液分离机28,存放实施例3中步骤七所述“‘第二次固液分离’所获的挤出水”之储槽19;由此26、27、28的机械设置实现对实施例4中“步骤七”的机械化操作;The combined machinery VII for the "second solid-liquid separation" of "Step 7" in Embodiment 4 at least includes: a conveying machine 26, a screw or roller squeezer 27, and a solid-liquid separator 28, The storage tank 19 for storing the "extruded water obtained from the 'second solid-liquid separation'" described in Step 7 of Example 3; thus the mechanical settings of 26, 27, and 28 realize the "Step Seven" of Example 4 mechanized operation;
对实施实施例4所述对“步骤八”的“第三次配料”用组合机械Ⅷ,其中至少包括:设置存放实施例4中步骤七所述“待处理亲水疏解纤维中间产物乙的潮料”之储料仓29,计量存放新水和循环净化水的储槽30,存放晶须助剂的料仓31,称量衡器32,搅拌混合槽33;由此29、30、31、32、33的机械设置实现对实施例4中“步骤八”的机械化操作;Use the combined machine VIII for the "third batching" of "Step 8" described in Example 4, which at least includes: setting up and storing the moisture of the "hydrophilic decomposable fiber intermediate product B to be treated" described in Step 7 of Example 4. Material storage bin 29, a storage tank 30 for measuring and storing new water and circulating purified water, a bin 31 for storing whisker additives, a weighing scale 32, and a mixing tank 33; thus 29, 30, 31, 32 , the mechanical setting of 33 realizes the mechanized operation of "Step 8" in Embodiment 4;
对实施实施例4所述对“步骤九”的“搅拌洗涤”用组合机械Ⅸ,其中至少包括:在前述的“搅拌混合槽33”后设置输送机构或输送机械34、螺杆或扎辊式挤浆机35,物料暂储槽36;由此34、35、36的机械设置,实现实施例4中步骤九所述工艺目的:将“‘第三次配料’导入螺杆或扎辊式挤浆机,对物料的纤维束再作碾挤的机械揉化处理,然后再将物料导入待最后挤干的物料暂储槽;或将上述‘第三次配料’直接导入搅拌机作搅拌,使新水与亲水疏解纤维中间产物乙的潮料固相纤维中本来所含的旧水,实现充分的混合,然后再 将物料导入待最后挤干的物料暂储槽”;The combined machine IX for "stirring and washing" of "Step 9" described in Embodiment 4 at least includes: a conveying mechanism or conveying machine 34, screw or roller extruder is provided after the aforementioned "stirring and mixing tank 33" Pulp machine 35, material temporary storage tank 36; from this, the mechanical settings of 34, 35, 36 realize the process purpose described in step nine in Example 4: introduce the "'third batching'" into the screw or roller squeezer , the fiber bundles of the material are mechanically kneaded by crushing and extrusion, and then the material is introduced into the temporary storage tank for the material to be finally squeezed dry; or the above-mentioned 'third batching' is directly introduced into the mixer for mixing, so that the new water and The old water originally contained in the moisture solid phase fiber of the hydrophilic decomposable fiber intermediate product B is fully mixed, and then Introduce the material into the temporary storage tank for the material to be finally squeezed out";
对实施实施例4所述“步骤十”的“第三次固液分离或和最后修饰”用组合机械Ⅹ,其中至少包括:设置输送机构或输送机械37、固液分离机38,设置存放掩蔽铁/锰离子助剂的料槽39、存放防霉助剂的料槽40;由此37、38、39、40的机械设置,实现实施例3中步骤十所述工艺目的:得到如实施例4中步骤五中所述的“‘第三次固液分离’所获的挤出水”,和最后产品--包括A-1或/和A-2之亲水疏解纤维A主产品;或和再做最后修饰,既减少产品的变色和被霉;The combined machine X for the "third solid-liquid separation or final modification" of "Step 10" described in Embodiment 4, which at least includes: a conveying mechanism or conveying machine 37, a solid-liquid separator 38, and a storage cover The trough 39 for iron/manganese ion additives and the trough 40 for storing anti-mildew additives; with the mechanical arrangement of 37, 38, 39, and 40, the purpose of the process described in step ten in Example 3 is achieved: to obtain the results as shown in Example 3 "The extruded water obtained from the 'third solid-liquid separation'" described in step five of 4, and the final product - the main product of hydrophilic and decomposable fiber A including A-1 or/and A-2; or and do final touches to reduce product discoloration and mildew;
例8-2.实施实施例5所述“联产制法”所用及的设备,涉及设置组合机械Ⅺ至Ⅹ Ⅲ,请参见附图14中由“·-”所围ε区块中的Ⅺ至Ⅹ Ⅲ,其中包括:Example 8-2. The equipment used in implementing the "joint production method" described in Example 5 involves setting up combined machinery XI to XIII. Please refer to XI in the ε block surrounded by "·-" in Figure 14. to XIII, including:
对实施实施例5中例5-1、例5-2所述“制A与C-1联产”所用组合机械Ⅺ,其中至少包括:针对实施例5中例5-1所述的具体制法,设置对新鲜的能源草作去根、剥除叶片的操作机械41,设置再对新鲜能源草做清水洗净、脱水、晾干用清洗机械42,设置做“水洗净后的鲜能源草”压榨取汁的压榨机43,设置储存压榨能源草鲜汁液的储料槽44,或再设置对鲜汁液做加热至沸或蒸发提浓的蒸馏釜45,设置冷却、装罐机械46;经此设置的41、42、43、44、45、46,实现从鲜能源草,经去根、除叶、水洗、脱水、压榨取汁,再加热灭菌、蒸发提浓、冷却、灌装,或直至加热蒸发至干的机械处理,获得可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的食用或医用级木素/树脂混合物副产品C-1;The combined machinery XI used in the "co-production of A and C-1" described in Example 5-1 and Example 5-2 in Example 5 includes at least: the specific preparation method described in Example 5-1 in Example 5. Method, set up operating machinery 41 for removing roots and leaves of fresh energy grass, set up cleaning machinery 42 for washing, dehydrating and drying fresh energy grass, and set up "fresh energy grass after washing with water" The press 43 for squeezing and extracting juice from "grass" is equipped with a storage tank 44 for storing the fresh juice of the grass, which is the energy source of the squeeze, or a distillation kettle 45 for heating the fresh juice to boiling or evaporation and concentration, and a cooling and canning machine 46; Through the settings 41, 42, 43, 44, 45, and 46, it is possible to extract juice from fresh energy grass by removing roots, removing leaves, washing, dehydrating, pressing, and then heating and sterilizing, evaporating and thickening, cooling, and filling. , or mechanical treatment until it is heated and evaporated to dryness, to obtain edible or medical grade lignin/resin mixture by-product C-1, which can be in the form of a paste-like tan colloid, or a coffee-colored powder or granule, or a rosin-like solid block;
和针对实施例5中例5-2所述的具体制法,设置对干能源草作去根、剥除叶片的操作机械47,或是设置对能源草干料做破碎、过筛的组合机械48,设置再对干能源草做清水洗净、脱水之清洗机械49,设置可再加水、加热至沸,然后做榨汁取榨的组合机械50,设置储存压榨能源草汁液的储料槽51,所述“能源草汁液”也既为实施例2中ⅱ项所述的副产物料2--“干能源草经水洗净后再水煮、压榨所获的汁液”;或再设置对“能源草汁液”做加热至沸或蒸发提浓的蒸馏釜52,设置冷却、装罐机械53;经此设置的47、48、49、50、51、52、53,实现从干能源草,经去根、除叶、破碎、过筛、水洗、脱水、热水浸渍、压榨取汁,再加热灭菌、蒸发提浓、冷却、灌装,或直至加热蒸发至干的机械处理,获得可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的食用或医用级木素/树脂混合物副产品C-1;And for the specific production method described in Example 5-2 in Embodiment 5, an operating machine 47 for removing roots and blades of dry energy grass is provided, or a combined machine for crushing and screening the dry energy grass material is provided. 48. Set up a cleaning machine 49 for washing and dehydrating the dry energy grass. Set up a combined machine 50 that can add water, heat it to boiling, and then extract the juice. Set up a storage tank 51 for storing the squeezed energy grass juice. , the "energy grass juice" is also the by-product material 2 described in item ii of Example 2 - "the juice obtained by washing the dry energy grass with water and then boiling and pressing it"; or it can be set again The "energy grass juice" is heated to boiling or evaporated to concentrate the distillation kettle 52, and a cooling and canning machine 53 is installed; through the 47, 48, 49, 50, 51, 52, 53 set up here, the energy grass is dried, After removing roots, removing leaves, crushing, sifting, washing, dehydrating, soaking in hot water, pressing to extract juice, and then heating and sterilizing, evaporating and thickening, cooling, filling, or mechanical processing until heating and evaporation to dryness, the product can be obtained. Edible or medical grade lignin/resin mixture by-product C-1 in the form of pasta-like tan colloid, coffee-colored powder or granules, or rosin-like solid block;
对实施实施例5中例5-3至例5-5所述“制A与C-2联产”所用组合机械Ⅻ,其中至少包括:针对实施例5中例5-3所述的具体制法,设置对新鲜的能源草作去根、剥除叶片的操作机械54,设置做新鲜能源草压榨取汁的压榨机55,设置储存压榨能源草鲜汁液的储料槽56,或再设置对鲜汁液做加热至沸或蒸发提浓的蒸馏釜57,设置冷却、装罐机械58;经此设置的54、55、56、57、58,实现从鲜能源草,经去根、除叶、压榨取汁,再加热灭菌、蒸发提浓、冷却、灌装,或直至加热蒸发至干的机械处理,获得可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的饲用或工业级的木素/树脂混合物产品C-2;The combined machinery XII used in the "coproduction of A and C-2" described in Examples 5-3 to 5-5 in Example 5, at least includes: the specific preparation method described in Example 5-3 in Example 5. Method, set up an operating machine 54 for removing roots and stripping leaves of fresh energy grass, set up a press 55 for pressing and extracting juice from fresh energy grass, set up a storage tank 56 for storing the fresh juice of pressed energy grass, or set up another The fresh juice is heated to boiling or evaporated and concentrated in the distillation kettle 57, and cooling and canning machinery 58 are set up; through the 54, 55, 56, 57, 58 set up here, the fresh juice can be obtained from the fresh juice through root removal, leaf removal, Press and extract the juice, then heat and sterilize, evaporate and concentrate, cool, fill, or mechanically process until it is heated and evaporated to dryness to obtain a tan colloid in the form of a paste, or a coffee-colored powder or granule, or a rosin-like solid. Feed or industrial grade lignin/resin mixture product C-2 in block form;
针对实施例5中例5-4所述的具体制法,设置对干能源草作去根、剥除叶片的操作机械59,或是设置对能源草干料做破碎、过筛的组合机械60,设置可再加水、加热至沸,然后做榨汁取榨的组合机械61,设置储存压榨能源草汁液的储料槽62,所述“能源草汁液”也既为实施例2中ⅱ项所述的副产物料1--热水脱木素/树脂工序所排棕/黑液;或再设置对“能源草汁液”做加热至沸或蒸发提浓的蒸馏釜63,设置冷却、装罐机械64;经此设置的59、60、61、62、63、64,实现从干能源草,经去根、除叶、破碎、过筛、热水浸渍、压榨取汁,再加热灭菌、蒸发提浓、冷却、灌装,或直至加热蒸发至干的机械处理,获得可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的食用或医用级木素/树脂混 合物副产品C-2;For the specific preparation method described in Example 5-4 in Embodiment 5, an operating machine 59 for removing roots and blades from the dry energy grass is provided, or a combined machine 60 for crushing and screening the dry energy grass material is provided. , is provided with a combined machine 61 that can add water, heat to boiling, and then perform juice extraction, and is provided with a storage tank 62 for storing the squeezed energy grass juice. The "energy grass juice" is also the item ii in Embodiment 2. The above-mentioned by-product material 1--the brown/black liquor discharged from the hot water delignification/resin process; or a distillation kettle 63 for heating the "energy grass juice" to boiling or evaporation and concentration, and cooling and canning is provided. Mechanical 64; through the 59, 60, 61, 62, 63, 64 set up here, it is possible to extract the juice from dry energy grass through root removal, leaf removal, crushing, sieving, hot water soaking, pressing, and then heating and sterilization. Evaporation and concentration, cooling, filling, or mechanical processing until heating and evaporation to dryness are used to obtain edible or medical grade lignin that can be in the form of a paste-like brown colloid, or a coffee-colored powder or granule, or a rosin-like solid block. /resin mix Compound by-product C-2;
针对实施例5中例5-5所述的具体制法,设置储存来源于组合机械Ⅺ中对能源草的“清水洗净”后的脱除水之用的储存槽65,设置用储存槽65的流出水对牛粪作淘洗、筛选的组合机械66,设置可再加水、加热至沸,然后做榨汁取榨的组合机械67,设置储存压榨能源草汁液的储料槽68,所述“能源草汁液”也既为实施例2中ⅱ项所述的副产物料1--热水脱木素/树脂工序所排棕/黑液;或再设置对“能源草汁液”做加热至沸或蒸发提浓的蒸馏釜69,设置冷却、装罐机械70;经此设置的65、66、67、68、69、70,实现对牛粪作淘洗、筛选、热水浸渍、压榨取汁,再加热灭菌、蒸发提浓、冷却、灌装,或直至加热蒸发至干的机械处理,获得可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的食用或医用级木素/树脂混合物副产品C-2;In view of the specific preparation method described in Example 5-5 in Embodiment 5, a storage tank 65 is provided for storing the dewatered water after "cleaning" the energy grass in the combined machine XI, and a storage tank 65 is provided. A combined machine 66 for washing and screening cow dung with outflow water, a combined machine 67 for adding water, heating to boiling, and then squeezing, and a storage tank 68 for storing the squeezed energy grass juice, are provided. The "energy grass juice" is also the by-product material 1 described in item ii of Example 2 - the brown/black liquor discharged from the hot water delignification/resin process; or the "energy grass juice" is heated to The distillation kettle 69 for boiling or evaporation concentration is equipped with cooling and canning machinery 70; through the 65, 66, 67, 68, 69, 70 set up here, the cow dung can be washed, screened, soaked in hot water, and pressed. Juice, then heated and sterilized, evaporated and concentrated, cooled, filled, or mechanically processed until heated and evaporated to dryness, to obtain a tan colloid in the form of a paste, or a coffee-colored powder or granules, or a rosin-like solid block. Food or medical grade lignin/resin mixture by-product C-2;
对实施实施例5中的例5-6所述“后续可再走”、“后续可被导”细节所用组合机械Ⅹ Ⅲ,其中至少包括:设置分类收集仓71,分别收集由组合机械Ⅺ、Ⅻ导出的能源草或和牛粪经“压榨后的出渣”;设置将前述“压榨后的出渣”用水泡化成含固25%的呈松散肉松状物料之搅拌、加热的组合机械72;设置机械筛73,以筛取泡化料中大小在过3目至不过28目筛孔范围的粒度分级或混合的细长状纤维束;设置收集“过3目至不过28目筛孔范围的粒度分级或混合的细长状纤维束”的收集仓74;设置将收集仓74中的物料导送前述“组合机械Ⅴ”的“存料仓16”的输送机械75,以使物料以实施例4中步骤四所述的“初脱除纤维中水溶质的待处理亲水疏解纤维中间产物甲的潮料”的归类,后续可再走实施例4中第五至第十步骤的操作,最后就能获亲水疏解纤维产品A-1或A-2;设置收集槽76,收集实施例5中例5-5里所述的“对牛粪作洗选”“由水淘洗过筛”所产生的含牛粪之水,既为实施例2中ⅱ项所述的“副产物料3:淘/洗牛粪所产生的淘/洗液”,后续可被导送做实施例1所述“辅助产品E--液态有机土壤改良剂”的配料之一;The combined machine XIII used in the details of "can be walked again" and "can be guided later" described in Example 5-6 of Embodiment 5 at least includes: setting up a classification collection bin 71 to collect the combined machine XI, Ⅻ The energy grass or cow dung exported is "pressed and dregs out"; a combined mixing and heating machine 72 is provided to bubble the aforementioned "pressed dregs" into a loose floss-like material with a solid content of 25%; Mechanical sieve 73 is used to sift out the elongated fiber bundles in the particle size classification or mixing range of the foamed material that have a size ranging from 3 mesh to no more than 28 mesh sieve holes; it is set to collect the particle size ranging from 3 mesh to no more than 28 mesh sieve holes. A collection bin 74 of "graded or mixed elongated fiber bundles"; a conveying mechanism 75 is provided to guide the materials in the collection bin 74 to the "storage bin 16" of the aforementioned "combined machine V", so that the materials can For the classification of the "moist material of the hydrophilic decomposed fiber intermediate product A to be treated after initially removing the water solute in the fiber" described in step 4, the operations of steps 5 to 10 in Example 4 can be followed. Finally, The hydrophilic decomposable fiber product A-1 or A-2 can be obtained; a collection tank 76 is provided to collect the "washing of cow dung" and "washing and sieving with water" described in Example 5-5 in Example 5. The produced water containing cow dung is the "by-product material 3: the washing/washing liquid produced by washing/washing cow dung" described in item ii in Example 2, and can subsequently be directed to be used as in Example 1. One of the ingredients of the above-mentioned "auxiliary product E--liquid organic soil conditioner";
例8-3.执行实施例6所述“B”之“制法”所用及的设备,涉及设置子组合机械Ⅹ Ⅳ至Ⅹ Ⅶ,请参见附图14中由“·-”所围ζ区块中的Ⅹ Ⅳ至Ⅹ Ⅶ,其中包括:Example 8-3. The equipment used to perform the "preparation method" of "B" described in Example 6 involves setting up sub-assembly machines XIV to XVII. Please refer to the area surrounded by "·-" in Figure 14 XIV to XVII in the block, including:
设置实施例6中例6-1的“备料”子组合装置Ⅹ Ⅳ,其中又包括:机械筛77,或再加破碎机械78、风选机械79;Set up the "material preparation" sub-assembly device XIV of Example 6-1 in Embodiment 6, which also includes: a mechanical screen 77, or a crushing machine 78 and a winnowing machine 79;
设置实施实施例6中例6-2的“配料”子组合装置Ⅹ Ⅴ,其中又包括:称重衡器80、分别存放所述“木塑复合再生质粗粒”组成中“木”与“塑”和软化剂的储料仓81,和计量配料后的混合槽82;Set up the "ingredients" sub-assembly device XV of Example 6-2 in Example 6, which also includes: a weighing scale 80, respectively storing "wood" and "plastic" in the composition of the "wood-plastic composite recycled material coarse particles". ” and softener storage bin 81, and mixing tank 82 after metering and batching;
设置实施实施例6中例6-3的“造粒”子组合装置Ⅹ Ⅵ,其中又包括:输送机械83、粗粒造粒机84;Set up the "granulation" sub-assembly device XVI of Example 6-3 in Example 6, which also includes: a conveying machine 83 and a coarse granulator 84;
设置实施实施例6中例6-4至例6-5的“均化混粒”、“称重包装”子组合装置Ⅹ Ⅶ其中又包括:均化混粒机85、称重包装机械86;Set up the "homogenizing mixing" and "weighing packaging" sub-assembly devices XVII of Examples 6-4 to 6-5 in Example 6, which further include: a homogenizing mixing machine 85 and a weighing and packaging machine 86;
例8-4.执行实施例7所述“辅助产品”之“制法”所用及的设备,涉及设置子组合机械Ⅹ Ⅷ至Ⅱ Ⅲ,请参见附图14中由“·-”所围η区块中的Ⅹ Ⅷ至Ⅱ Ⅲ,其中包括:Example 8-4. The equipment used to implement the "manufacturing method" of the "auxiliary products" described in Example 7 involves setting up sub-assembly machines XVIII to IIIII. Please refer to the η surrounded by "·-" in Figure 14. XVIII to IIIII in the block, including:
设置实施实施例7中例7-1“辅助产品D--固态有机土壤改良剂”制法所用子组合装置Ⅹ Ⅷ,其特征在于:包含一套制备固态有机土壤改良剂的组合装置87;以实现将“能源草,或能源草和牛粪”为起始主原料时,在使用提取了制主产品A用原料后的余料,既过28目筛孔的能源草之粉料或和细牛粪沉渣,作为“辅助产品D”中的配料之工艺目的;Set up the sub-assembly device XVIII used in the preparation method of Example 7-1 "auxiliary product D--solid organic soil conditioner" in Example 7, which is characterized in that: it includes a set of assembly devices 87 for preparing solid organic soil conditioner; When "energy grass, or energy grass and cow dung" are used as the starting main raw materials, the remaining materials after extracting the raw materials for making the main product A are used, which are energy grass powder or fine cattle that have passed through a 28-mesh sieve. Fecal sediment, used as an ingredient in "auxiliary product D" for technological purposes;
设置实施实施例7中例7-2“辅助产品E--液态有机土壤改良剂产品”制法所用子组合装置Ⅹ Ⅸ,其特征在于:包含一套制备液态有机土壤改良剂产品的组合装置88;以实现将实施例2中ⅱ项所述“副产物料1”或/和“副产物料3”,作为“辅助产品E”中的配料 之工艺目的;Set up the sub-assembly device XIX used in the preparation method of Example 7-2 "auxiliary product E--liquid organic soil conditioner product" in Example 7, which is characterized in that: it includes a set of assembly devices 88 for preparing liquid organic soil conditioner product ; To achieve the use of "by-product material 1" or/and "by-product material 3" described in item ii in Example 2 as an ingredient in "auxiliary product E" The purpose of the process;
设置实施实施例7中例7-3“辅助产品F--发酵饲料”制法所用子组合装置Ⅱ Ⅹ,其特征在于:包含一套制备发酵饲料产品的组合装置89;以实现将实施例2中ⅱ项所述“副产物料1”或/和“或副产物料2”,掺于仅经破/粉碎的能源草中再经发酵制获辅助产品F的工艺目的;Set up the sub-assembly device Ⅱ Ⅹ used in the preparation method of Example 7-3 "auxiliary product F--fermented feed" in Example 7, which is characterized in that: it includes a set of assembly devices 89 for preparing fermented feed products; to realize the use of Embodiment 2 The purpose of the process of adding "by-product material 1" or/and "or by-product material 2" mentioned in item ii to the energy grass that has only been broken/pulverized and then fermenting it to obtain auxiliary product F;
设置实施实施例7中例7-4“辅助产品G--颗粒饲料”制法所用子组合装置Ⅱ Ⅰ,其特征在于:包含一套制备颗粒饲料产品的组合装置90;以实现将用筛取了主产品A用原料后的余料,既“过28目筛细粉”,或/和“过28至不过150目筛范围的含土量微的粒径居中的能源草纤维粉屑”,作为颗粒饲料产品中的配料组份之工艺目的;Set up the sub-assembly device II used in the preparation method of Example 7-4 "auxiliary product G--pellet feed" in Example 7, which is characterized in that: it includes a set of assembly devices 90 for preparing pellet feed products; to achieve sifting out The remaining materials after using the raw materials for the main product A are "fine powder passed through a 28 mesh sieve", or/and "energy grass fiber powder with a small soil content and a medium particle size passed through a 28 to less than 150 mesh sieve", The technological purpose as an ingredient in pellet feed products;
设置实施实施例7中例7-5“辅助产品H--生物质颗粒燃料”制法所用子组合装置Ⅱ Ⅱ,其特征在于:包含一套制备生物质颗粒燃料产品的组合装置91;以实现将“以能源草被破碎、过筛脱除了未过28目筛之粗纤维的细粉料,或是全组份的能源草粉碎物,为配料组份,或再配加了废塑料”制生物质颗粒燃料产品的工艺目的;Set up the sub-assembly device II II used in the preparation method of Example 7-5 "auxiliary product H--biomass pellet fuel" in Example 7, which is characterized in that: it includes a set of assembly devices 91 for preparing biomass pellet fuel products; to achieve "The energy grass is crushed and sieved to remove the coarse fiber that has not passed the 28-mesh sieve to remove the fine powder, or the full-component energy grass crushing material is used as the ingredient, or waste plastic is added." The technological purpose of biomass pellet fuel products;
设置实施实施例7中例7-6“辅助产品H--生物质颗粒燃料”制法所用子组合装置Ⅱ Ⅲ,其特征在于:包含一套制备食用菌种植棒/块产品的组合装置92;以实现将“以能源草,或能源草和牛粪为起始主原料时,用筛取了主产品A用原料后的余料,既过28目筛孔的能源草之粉料或和细牛粪沉渣,作为食用菌种植棒/块产品中的配料组份”的工艺目的;Set up the sub-assembly device II III used in the preparation method of Example 7-6 "auxiliary product H--biomass pellet fuel" in Example 7, which is characterized in that: it includes a set of assembly device 92 for preparing edible fungus planting rods/block products; In order to realize "using energy grass, or energy grass and cow dung as the starting main raw materials, the remaining material after sifting out the raw materials for the main product A is the energy grass powder or fine cow dung that has passed through a 28-mesh sieve. Fecal sediment, as an ingredient component in edible fungus planting sticks/block products” process purpose;
例8-5.或和可将如前例8-1至例8-4中所述1至88的各单元机械,规整设置入标准集装箱中。Example 8-5. Alternatively, each of the machine units 1 to 88 described in the previous Examples 8-1 to 8-4 can be arranged neatly into a standard container.
实施例9.介绍一个对比用的标准样及用此标样与亲水疏解纤维A的诸多对比,请参见附图9至12:Example 9. Introducing a standard sample for comparison and various comparisons between this standard sample and hydrophilic decomposable fiber A. Please refer to the attached figures 9 to 12:
图9为一个干团料标样的黑白照片,其是用兰花种植爱好者俗称杨柳粪--天牛幼虫或木蠹蛾幼虫蛀食柳树杆后所屙粪便,经实验室作筛除粗于3目与细于28目的杂质,再经水煮灭酶后,又用手捏脱水但仍含75%水分的潮料,在一次性塑料杯中手按紧塑形,倒出,在室温下自然干燥后所获,此种标样经与本发明的亲水疏解纤维A试样的干团料作对掐,或和对搓比较,可定性地判定出本发明的亲水疏解纤维A与标样的相对硬度,或和被检测样纤维相互间缠绕和扣合强度等物性,进而可看出本发明亲水疏解纤维的实用性,图9标样的颜色为棕色。Figure 9 is a black and white photo of a dry mass standard sample. It is made of willow dung, commonly known as willow dung by orchid planting enthusiasts - beetle larvae or wood beetle moth larvae that eat the willow stems. The dung is screened in the laboratory to remove particles larger than Impurities of 3 mesh and finer than 28 mesh are boiled in water to eliminate enzymes, then dehydrated but still containing 75% moisture by hand, pressed tightly into a disposable plastic cup, poured out, and kept at room temperature. Obtained after natural drying, this standard sample is pinched or compared with the dry mass of the hydrophilic decomposable fiber A sample of the present invention, and it can be qualitatively determined that the hydrophilic decomposable fiber A of the present invention is different from the standard sample. The relative hardness of the sample, or the physical properties such as the intertwining and interlocking strength of the tested sample fibers, can then be used to see the practicability of the hydrophilic and decomposable fiber of the present invention. The color of the standard sample in Figure 9 is brown.
图10为图9所述“标样”,来源于自然界的一棵柳树下之地面堆积的黑白照片,照片中柳树树干根部草叶上呈白色的就是“杨柳粪”,其真实颜色为棕色。Figure 10 is the "standard sample" described in Figure 9, which is a black-and-white photo of the accumulation on the ground under a willow tree in nature. In the photo, the white on the grass and leaves at the base of the willow tree trunk is "willow dung", and its real color is brown.
图11为图9、10所述“标样”,在被采集入实验室中在还未作筛选等处理时模样的黑白照片,其真实颜色为棕色。Figure 11 is a black and white photo of what the "standard sample" described in Figures 9 and 10 looks like when it is collected in the laboratory and has not been screened or processed. Its true color is brown.
如上图9至11所述的标样--俗称的杨柳粪,是一种典型的已被食木虫消化道内的能分解木中纤维素/树脂养分的酶,所消化降解过的纤维;业内的技术人员可知道:木纤维可用酶法制出纸浆;如图9所示的干团料标样,仅需使用如古代造纸所用的木棒锤,经敲打此标样样品的潮料,制出的纸浆,就能抄造出如市场上常见的普通牛皮纸或书法用毛边纸。The standard sample shown in Figures 9 to 11 above - commonly known as willow manure, is a typical fiber that has been digested and degraded by enzymes in the digestive tract of wood-eating insects that can decompose cellulose/resin nutrients in wood; in the industry Technical personnel can know that wood fiber can be enzymatically produced into pulp; the dry dough standard sample shown in Figure 9 only needs to use a wooden stick hammer such as that used in ancient papermaking to beat the moisture material of this standard sample to produce Using paper pulp, you can make ordinary kraft paper or rough paper for calligraphy that are commonly seen on the market.
因本发明人在现时暂缺对产品抄纸试片作诸多质检的条件下,能使用如图9就所示标样,以物比物的方式,对本发明所述的亲水疏解纤维A,给出与标样比较的如下定性结论:Because the inventor is currently short of many quality inspections on product paper test pieces, he can use the standard sample as shown in Figure 9 to compare the hydrophilic decomposable fiber A of the present invention in an object-by-object manner. , giving the following qualitative conclusion compared with the standard sample:
如图3所示的亲水疏解纤维A-1的干团料的材质硬度比标样低;As shown in Figure 3, the material hardness of the dry mass of hydrophilic and decomposable fiber A-1 is lower than that of the standard sample;
如图4所示的亲水疏解纤维A-2的干团料的材质硬度比标样低,其与标样对搓至少10次后,比较两样对搓受损的缺失量,可看出:与标样相当,或至不多于标样缺失量的5 倍。As shown in Figure 4, the material hardness of the dry mass of hydrophilic decomposable fiber A-2 is lower than that of the standard sample. After rubbing it with the standard sample for at least 10 times, comparing the amount of damage caused by the rubbing of the two samples, it can be seen that: Equivalent to the standard sample, or no more than 5% of the missing amount of the standard sample times.
所述的“比较”,可以是用裸眼观察如图12——为图9标样与图4样品做对搓比较俩者所掉屑料的黑白照片,从图12可看出显棕色且长粗的纤维是来自图9标样,图中灰白色短细的纤维是来自图4样品,对搓时俩接触面都应选各较为光滑、紧实的部位;更佳的比较,可以使用天平以减量法测知做对搓比较俩者的各自失重。当然对图9的标样可制得其纤维要与被检测样的粗细长短、团聚的紧实性都更接近者,则比较结果也会更精准些。The "comparison" can be observed with the naked eye as shown in Figure 12 - a black and white photo of the scrap material from the standard sample in Figure 9 and the sample in Figure 4. From Figure 12, it can be seen that the material is brown and long. The thick fibers are from the standard sample in Figure 9, and the short and thin gray-white fibers in the picture are from the sample in Figure 4. When rubbing, both contact surfaces should choose the smoother and tighter parts; for a better comparison, you can use a balance to The weight reduction method is used to measure the weight loss of the two by rubbing them against each other. Of course, for the standard sample in Figure 9, the fiber thickness and length and the compactness of the agglomeration can be closer to that of the tested sample, and the comparison results will be more accurate.
再有,经本发明人在制备标样的过程中观察发现,即使是用“杨柳粪”做酶种,制出能分解木纤维中木质素/树脂的酶,再用此种酶制剂来处理本发明所提的“能源草碎化料”,其在所涉生产用水中也能做到与本发明一样的水中不含无机溶盐的效果,但在减少如实施例2中ⅱ项所述的“棕/黑液”,其重量份W棕/黑液,与所获主产品A中含水不超15%的绝干纤维之重量份WA的比例在W棕/黑液/WA”之减少上,并不会有优于本发明的特征;而其在对物料的接种酶后的工艺操作要明显烦于本发明,和其对纤维的柔化、碾磨操作也不能明显地减少。Furthermore, the inventor observed during the preparation of the standard sample that even if "willow dung" is used as the enzyme species, an enzyme that can decompose lignin/resin in the wood fiber can be produced, and then this enzyme preparation is used to process The "energy grass crushed material" proposed by the present invention can also achieve the same effect as the present invention in the production water involved without inorganic soluble salts in the water, but the reduction is as described in item ii of Example 2. The "brown/black liquor", its weight part W brown/black liquor , and the weight part W A of the absolute dry fiber containing no more than 15% water in the main product A is W brown/black liquor /W A " In terms of reduction, there is no feature superior to the present invention; and the process operation after inoculating the material with enzyme is obviously more troublesome than the present invention, and the softening and grinding operations of the fiber cannot be significantly reduced. .
使用本实施例9的干团料标样作质检,如本发明所提技术方案在产业化后,市场客户要提高标准,则可将标样的纤维作细散化处理,以使标样的强度上升;如要放低标准,则可在被检测样与标样对搓至少10次后,掉落的屑料与“不多于标样落屑的”“倍”数作出提高即可。为辨别被检测样与标样相搓所掉落的屑料的色泽差异,还可对标样使用蓝墨水等色液作染色处理。标样与被检测样的团料之形状也可突破图3、4、9的束缚,但干团料作对掐和对搓比较,则以相同或相近的表面碰触较为公平合理。The dry dough standard sample of Example 9 is used for quality inspection. If the technical solution proposed by the present invention is industrialized and market customers want to improve their standards, the fibers of the standard sample can be finely divided to make the standard sample The strength increases; if you want to lower the standard, you can increase the number of fallen chips to "not more than the number of chips dropped by the standard sample" after rubbing the tested sample and the standard sample at least 10 times. In order to identify the color difference of the scraps dropped when the sample to be tested is rubbed against the standard sample, the standard sample can also be dyed with blue ink and other color liquids. The shape of the mass of the standard sample and the sample to be tested can also break through the constraints of Figures 3, 4, and 9. However, when comparing dry mass materials by pinching and rubbing, it is more fair and reasonable to use the same or similar surface contact.
实施例10.实施例1至8所述“产品”或/和“制法”或/和“设备”的用途,至少包括如下所述的任一或多种的组合:Embodiment 10. The uses of the "product" or/and "preparation method" or/and "equipment" described in embodiments 1 to 8, at least include any one or a combination of more of the following:
例10-1.实施例1、2所述“主产品A--亲水疏解纤维”,其用途至少可被用作制备育秧纸、瓦楞纸、纸板,或/和包括蛋托、方便餐盘/碗、纸质育苗盆/钵等在内的纸模塑制品中作部分或全部地替代废纸再生纸浆的一种替代材料;也可作为做进一步深加工,如制漂白纸浆的新起始原料;或是作为制备纤维素醚的原料;Example 10-1. The "Main Product A - Hydrophilic Decomposable Fiber" described in Examples 1 and 2 can be used at least to prepare seedling paper, corrugated paper, cardboard, or/and include egg trays and convenient dinner plates/ It can be used as an alternative material to partially or completely replace waste paper recycled pulp in paper molded products such as bowls, paper seedling pots/bowls, etc.; it can also be used as a new starting material for further processing, such as making bleached pulp; Or as raw material for preparing cellulose ether;
例10-2.实施例1、3所述“副产品B--木塑复合再生质粗粒”,其用途至少可被用作热挤出木塑制品用木塑颗粒的待改性或/和精制的原料,或是直接用作热挤出木塑制品的一种新剂型原料,也可作为一种供热用的颗粒质燃料;Example 10-2. The "by-product B - wood plastic composite recycled coarse particles" described in Examples 1 and 3 can be used at least as wood plastic particles to be modified or/and used for hot extrusion of wood plastic products. Refined raw materials, or directly used as a new formulation raw material for hot-extruded wood-plastic products, or as a granular fuel for heating;
例10-3.实施例1所述“副产品C-1--食用或医用级的木素/树脂混合物”,其用途至少可被用作制备饮料或/和中药制剂的原料;Example 10-3. The "by-product C-1 - edible or medical grade lignin/resin mixture" described in Example 1 can be used at least as a raw material for preparing beverages or/and traditional Chinese medicine preparations;
例10-4.实施例1所述“副产品C-2--饲用或工业级的木素/树脂混合物”,其用途至少可被用作制备饲料原料,或/和混凝土的减水剂、橡胶/塑料中的软化剂的任一种;Example 10-4. The "by-product C-2--feed or industrial grade lignin/resin mixture" described in Example 1 can be used at least as a feed raw material, or/and as a water-reducing agent for concrete. Any softener in rubber/plastic;
例10-5.实施例1至8所述“产品”、“制法”、“设备”,至少可被用于对包括巨菌草等在内的技术方案2中ⅰ项里所述“原料”的加工;或被扩展地应用于对竹子、甘蔗皮、棕榈油果串枝杈等的加工;Example 10-5. The "products", "preparation methods" and "equipment" described in Examples 1 to 8 can at least be used to prepare the "raw materials" described in Item 1 of Technical Solution 2 including Giant Juncao, etc. "Processing; or be expanded to the processing of bamboo, sugar cane bark, palm oil fruit bunch branches, etc.;
例10-6.实施例1至8所述“产品”、“制法”、“设备”,皆可成为独立的商品。Example 10-6. The "products", "production methods" and "equipment" described in Examples 1 to 8 can all become independent commodities.
实施例11.实施例1至9的任一或多项所述的“产品”或/和“制法”的商业运作模式,至少包括如下所述的任一或多种的组合:Embodiment 11. The business operation model of the "product" or/and "preparation method" described in any one or more of Embodiments 1 to 9, at least including any one or a combination of the following:
例11-1.可由一家企业独立地实施“产品”或/和“制法”的商业运营;Example 11-1. A company can independently implement the commercial operations of “products” or/and “manufacturing methods”;
例11-2.可由多家企业分割“产品”品种,或/和分段“制法”过程来协同地实施商业运营;Example 11-2. Multiple companies can divide "product" varieties, or/and segment "manufacturing" processes to collaboratively implement commercial operations;
例11-3.可用自营或外发代工的商业模式实施“产品”或/和“制法”的商业运营; Example 11-3. The business model of self-operated or outsourced manufacturing can be used to implement the commercial operation of "products" or/and "manufacturing methods";
例10-4.所述的商业运营,其中使用包括固/液态有机土壤改良剂在内的涉农产品,与农户或农耕经营者易货包括粮棉油大田之秸秆在内的能源草。Example 10-4. The commercial operation described in Example 10-4 uses agricultural products including solid/liquid organic soil conditioners, and barters energy grasses including straw from grain, cotton and oil fields with farmers or farming operators.
本发明的积极意义至少在于:The positive significance of the present invention is at least:
本发明提供一种以能源草为原料的清洁化产品集合及制法,其中的核心创新至少有两:其一是,提出了一个清洁化产品集合,所述“产品集合”由主产品A,或主产品A再与副产品B、C的任一或两种产品的组合所构成,或主产品A或和副产品B/C,再与辅助产品D、E、F、G、H、I的任一或多种产品的组合所构成;其二是,提供了所提出的“产品集合”的制法。The present invention provides a collection of cleaning products and a manufacturing method using energy grass as raw materials. There are at least two core innovations therein: first, a collection of cleaning products is proposed. The "product collection" consists of main product A, Or the main product A is combined with any one or two of the by-products B and C, or the main product A is combined with the by-product B/C, and then is combined with any of the auxiliary products D, E, F, G, H, and I. It consists of a combination of one or more products; secondly, it provides a method for making the proposed "product set".
本发明的主产品A所蕴含的积极意义至少在于:将一些粮、棉、油等会产生巨量秸秆或枝条的农作物也归类入能源草这一上位代称,然后皆以能源草为上位代称名,介绍以前述“能源草,或能源草和牛粪”经锯/碾/切/锤的任一或多种组合碎化再过筛处理,获得其中的“过3目至不过28目筛范围的任一目数的分级或混合粒径的细长状纤维束”碎化物,清洁化制备主产品A--亲水疏解纤维。制备过程中所排出棕/黑液的重量份W棕/黑液,与所获主产品A中含水不超15%的绝干纤维之重量份WA的比例在W棕/黑液/WA=90~100~300/100范围,且“棕/黑液”中所含Na+或/和K+或/和Mg2+的克摩尔与其所含水的升体积之比为≤0.034mol/L,其pH值皆不超出5.0~9.4范围,既各指标都未踏入盐碱地特征值范围;使用的助剂中,所含苛性碱、氨、铵盐、过氧化物、生物酶的任一或多种的总含量为0。这为每吨主产品A所携的至多不超3吨的无溶盐既无害植被的“棕/黑液”资源的绿色化利用,导通了此行业“棕/黑液”资源化利用的淤塞瓶颈。The positive meaning contained in the main product A of the present invention is at least that: some grain, cotton, oil and other crops that produce huge amounts of straw or branches are also classified into the upper code name of energy grass, and then all use energy grass as the upper code name. Name, the introduction is based on the aforementioned "energy grass, or energy grass and cow dung", which are crushed by any or more combinations of sawing/milling/cutting/hammering and then sieved to obtain the range of "passing 3 mesh to not passing 28 mesh" The slender fiber bundles of any mesh size are classified or mixed with particle sizes, and the main product A-hydrophilic decomposable fiber is prepared through cleaning. The ratio of the weight part W brown / black liquor of the brown / black liquor discharged during the preparation process to the weight part W A of the absolute dry fiber containing no more than 15% water in the main product A is W brown / black liquor / W A =90~100~300/100 range, and the ratio of the gram moles of Na + or/and K + or/and Mg 2+ contained in the "brown/black liquor" to the liter volume of the water contained in it is ≤0.034 mol/ L, its pH value does not exceed the range of 5.0 to 9.4, and all indicators do not enter the range of characteristic values of saline-alkali soil; the additives used include caustic alkali, ammonia, ammonium salts, peroxides, and biological enzymes. The total content of one or more species is 0. This is the green utilization of “brown/black liquor” resources that contain no more than 3 tons of dissolved salt and are harmless to vegetation per ton of main product A, and leads to the green utilization of “brown/black liquor” resources in this industry. siltation bottleneck.
本发明所提供的“产品集合”,其中围绕着主产品A--亲水疏解纤维,设置了副产品B、C,或/和辅助产品D、E、F、G、H、I之两道应变组合墙。这种“应变组合墙”设置的积极意义在于:在核心主产品A的外围,设置了两道针对制备A过程中所排出的各种“废物”的消纳防线,并能连带地将生产主产品A实施地周边的杂废塑料或/和畜禽粪便也抓来协同地被资源绿色化再利用。The "product set" provided by the present invention surrounds the main product A - hydrophilic decomposable fiber, and sets two strains of by-products B, C, or/and auxiliary products D, E, F, G, H, and I. Combination walls. The positive significance of this "strain combination wall" is that around the core main product A, two lines of defense are set up to absorb various "waste" discharged in the process of preparing A, and can jointly integrate the main production Miscellaneous plastic waste and/or livestock and poultry manure surrounding the implementation site of Product A are also captured and collaboratively used for green resource utilization.
本发明的主产品A,因其制法中所排出的“棕/黑液”之量少且无害植被,这为本发明的产业化实施地可选在近大田地域,带来了可能;由于可在近大田地域做实施,则又为获得低运输成本的包括粮、棉、油大田秸秆在内的能源草物料带来了可能,这其中还包含着用辅助产品D--固态有机土壤改良剂,或/和辅助产品E--液态有机土壤改良剂,也能低成本地就近与大田农户以易货的商业交换模式获得秸秆等能源草材料提供了方便。所述的“‘棕/黑液’之量少且无害植被”、“用辅助产品D,或/和辅助产品E”、“就近与大田农户以易货的商业交换模式获得秸秆等能源草材料”,这连串化的实施,实可意味着突破了我国大田农户因嫌有机肥价高但显效慢于无机肥,而不能赔本地施用有机肥于大田的价格阻碍,也就是实现了大田秸秆在离田后被社会化应用了一圈后,再化作液/固态有机土壤改良剂,这其中还包括了消纳畜禽粪便等皆被无阻碍地回入大田,这可是将空气中二氧化碳被粮、棉、油作物固碳入秸秆,秸秆被制成A、B、C、D、E、F、G、H、I产品集合,最后又被无阻碍地再埋入大田中,这可是解决大田因长年仅施无机肥而逐年扳结的好路径。此法若是配套于在盐碱地里种植海水稻、巨人稻,则能使严重缺乏有机质的盐碱地会更快地熟化而变成良田。The main product A of the present invention has a small amount of “brown/black liquor” discharged during the production process and is harmless to vegetation, which makes it possible for the industrial implementation of the present invention to be carried out in areas near fields; Since it can be implemented near field areas, it also brings the possibility of obtaining energy grass materials with low transportation costs, including grain, cotton, and oil field straw. This also includes the use of auxiliary products D-solid organic soil improvement. The agent, or/and the auxiliary product E-liquid organic soil conditioner, can also be used to obtain energy grass materials such as straw and other energy grass materials through barter with farmers nearby at low cost. The described "'Brown/Black Liquor' amount is small and harmless to vegetation", "Use auxiliary product D, or/and auxiliary product E", "Obtain straw and other energy grasses through barter commercial exchange model with farmers in nearby fields. "Materials", this serial implementation can actually mean a breakthrough in the price barrier of farmers in our country's field fields being unable to compensate for the high price of organic fertilizers but slower effectiveness than inorganic fertilizers. After leaving the field, the straw is used in a circle and then turned into a liquid/solid organic soil conditioner, which also includes the consumption of livestock and poultry manure, etc., and is returned to the field without hindrance, which removes the air from the soil. Carbon dioxide is fixed into the straw by grain, cotton, and oil crops, and the straw is made into a collection of products A, B, C, D, E, F, G, H, and I, and finally is buried in the field without hindrance. But it is a good way to solve the problem of field failure year after year due to only applying organic fertilizer for many years. If this method is used to plant sea rice and giant rice in saline-alkali land, the saline-alkali land that is seriously lacking in organic matter will mature faster and become fertile land.
如实施例5所述的“‘主产品A--亲水疏解纤维产品’和‘副产品C--木素/树脂混合物产品’的联产制法””,从创新角度看,本实施例所获的副产品C-1,较公知的如用巨菌草茎秆榨汁制饮料等方案,是属a-1型的技术创新,所获副产品C-1是属包括制饮料在内的多种应用的原料产品;从实用性角度讲,其能省却下游种种用途企业各家都自要从原料开 始做产品的种种麻烦。As described in Example 5 of the "Co-production method of 'main product A--hydrophilic decomposable fiber product' and 'by-product C--lignin/resin mixture product'", from an innovative perspective, the method used in this example The by-product C-1 obtained is a type a-1 technological innovation, which is a type of technological innovation such as the use of Juicyrus gigantea stalks to squeeze juice into beverages. raw material products for application; from a practical point of view, it can save the downstream enterprises of various uses from having to develop raw materials. All the troubles of starting a product.
当产品集合中引入了“副产品B--木塑复合再生质粗粒”,如实施例1、6所介绍。其创新点在于:在木塑复合制品的原料领域,引入了此行业并不公知的“粗粒”这一新原料产品的剂型及其新制法。其实用性在于:先低能耗地将泡货状的“木”和“塑”处理成粗粒,此粗粒既可直接投用于下游木塑复合制品所用高扭矩低转速的螺杆挤出机,也能更方便地进料于CN202010141136.X实施例所述碾磨再生的工艺装置,脱除本实施例中由“塑”组份所可能带入铝屑等杂质后,获得木塑复合制品所需均匀化质量的木塑颗粒,由此绕开泡货状的“木”和“塑”难于直接进塑料造粒所用的螺杆挤出机之工艺障碍;所提粗料含“木”或“塑”上下限两料的变量化搀兑施用,调和了上游的简单化生产与下游的含量多变要求间的矛盾。使用来源于能源草中的“木”,因其粉碎用机械能总会较从大块的杂废木料粉碎要来的低,故此种“木”具有节能的市场竞争优势。When "by-product B - wood-plastic composite regenerated coarse particles" is introduced into the product collection, as introduced in Examples 1 and 6. Its innovation lies in the fact that in the field of raw materials for wood-plastic composite products, it has introduced a new raw material product dosage form of "coarse grain" that is not well known in this industry and its new preparation method. Its practicality lies in: first processing the foamed "wood" and "plastic" into coarse particles with low energy consumption. This coarse particles can be directly used in high-torque and low-speed screw extruders used in downstream wood-plastic composite products. , it can also be more conveniently fed into the grinding and regeneration process device described in the CN202010141136. The required homogenized quality of wood-plastic pellets is required, thereby bypassing the technological obstacle of the difficulty in directly feeding the foam-like "wood" and "plastic" into the screw extruder used for plastic granulation; the proposed coarse material contains "wood" or "plastic" The variable blending and application of the upper and lower limits of "plastic" reconciles the contradiction between the simplified production of the upstream and the variable content requirements of the downstream. Using "wood" from energy grass, the mechanical energy required for crushing is always lower than crushing from large pieces of waste wood, so this kind of "wood" has an energy-saving competitive advantage.
还值一提的是,至少是在上述实施例1、5、7、8中提及了牛粪被使用,和至少是在上述实施例1、3、6、7、8中提及了废塑料被使用,既在具体实施方式层面再度地阐述了本发明构思的实现,既:“所述‘清洁化制法’,不但要自扫门前雪,对能源草综合利用过程中所产废液等要悉数资源绿色化利用;也要顺手带走别家的瓦上霜,既对实施地周边的牛粪或田间的废弃农用地膜等废物也被消纳后作资源绿色化利用等”。It is also worth mentioning that at least in the above-mentioned embodiments 1, 5, 7, and 8, it is mentioned that cow dung is used, and at least in the above-mentioned embodiments 1, 3, 6, 7, and 8, it is mentioned that waste Plastics are used, which once again elaborates on the realization of the concept of the invention at the level of specific implementation, that is: "The 'clean production method' not only requires self-cleaning of the snow in front of the door, but also the waste generated during the comprehensive utilization of energy grass. All resources such as liquids and liquids must be used for green utilization; the frost on other people’s tiles must also be taken away, and wastes such as cow dung around the implementation site or discarded agricultural mulch films in the fields must also be absorbed and used for green utilization.”
再可一提的是,当将牛等爱吃的巨菌草等具有速生性和高大植株且能耐肥耗水的能源草下位品种植物为原料,再将实施例5中的例5-5里提及的技术方案等作实施:“对牛粪所做淘/洗处理后排出的淘/洗液”,“则可作耐肥耗水的巨菌草等的直接浇灌用水等”;其积极意义是建立起了一个环保性的循环链:巨菌草由“巨菌草种植地块”出,……巨菌草源类牛粪的“淘/洗液”,再回此“巨菌草种植地块”的循环链;这一循环链不但可使被种植在本可能是选种在贫瘠土地上的巨菌草会变得更茂盛,且使土地快速由贫瘠变肥沃,更是在巨菌草种植业所携的养牛业基础上,又被绿色化地叠加了更多的巨菌草之后续的利用和加工业及其效益;这会使我国诸多贫瘠的荒地,在种植巨菌草后更迅速地变成效益倍出的沃土。It can be mentioned again that when the low-level plants of energy grasses, which are fast-growing, tall plants and can tolerate fertilizer and water consumption, such as giant mushroom grass that cattle and others like to eat, are used as raw materials, then the Examples 5-5 in Example 5 are used. The technical solutions mentioned are implemented: "The washing/washing liquid discharged after the washing/washing of cow dung" "can be used as direct irrigation water for fertilizer-resistant and water-consuming giant fungus grass, etc."; its positive The meaning is to establish an environmentally friendly cycle chain: Giant Juncao comes from the "Giant Juncao planting plot"... Giant Juncao is derived from the "washing liquid" of cow dung, and then returns to this "Giant Juncao" The circular chain of "planting plots"; this circular chain not only makes the giant fungus planted on barren land become more lush, but also makes the land quickly turn from barren to fertile. On the basis of the cattle raising industry brought about by the Juncao planting industry, more subsequent utilization and processing industries of Juncao and their benefits have been added in a green way; this will make many barren wastelands in our country less likely to grow giant Juncao. The grass quickly becomes fertile soil with multiple benefits.
当然,本领域技术人员也会对本发明实施例再给出许多的修饰和改进,但这些未有突破本发明构思、技术方案大框架的实施例的等效变化及修饰,最后获得本发明实施例所述“以能源草为原料的清洁化产品集合及制法”的,皆应属于本发明的保护范畴。Of course, those skilled in the art will also make many modifications and improvements to the embodiments of the present invention, but these do not break through the equivalent changes and modifications of the embodiments of the concept of the present invention and the broad framework of the technical solution. Finally, the embodiments of the present invention are obtained. The above-mentioned "cleaning product collection and preparation method using energy grass as raw material" should all fall within the protection scope of the present invention.
加注:在本说明书等文件中所用选择性连词或符号的含义说明:Note: Explanation of the meaning of optional conjunctions or symbols used in this manual and other documents:
第1种,既“或”,使用句型通式:甲或乙,含义是:从二种--甲、乙中,任选一种。The first type, that is, "or", uses the general sentence pattern: A or B, which means: choose one of the two types - A or B.
第2种,既“或/和”,使用句型通式:甲或/和乙,含义皆是:从三种--甲、乙、甲和乙中,任选一种。The second type, namely "or/and", uses the general sentence pattern: A or/and B, which means: choose any one from three types - A, B, A and B.
第3种,既“/”,其含义有三:其一是,表示两数量间的比例关系,如,A/B=3/5=3:5,既A比B;其二是“/”等同于“÷”;其三则是与前述第2种的含义相同。The third type, "/", has three meanings: one is to express the proportional relationship between two quantities, such as A/B=3/5=3:5, which means A is better than B; the other is "/" It is equivalent to "÷"; the third one has the same meaning as the second one mentioned above.
第4种,既“或和”,使用句型通式:甲或和乙,含义是:从二种--甲、甲和乙中,任选一种;其也等同于“甲或再和乙”或“甲,或再和乙”。The fourth type, "or and", uses the general sentence pattern: A or and B, which means: choose any one from the two types - A, A and B; it is also equivalent to "A or then and B" B" or "A, or again and B".
第5种,既“或再”,这等同于“或和”、“或和再”、“或再和”的任一种表述。 The fifth type is "or again", which is equivalent to any expression of "or and", "or and again", "or again and".

Claims (10)

  1. 以能源草为原料的清洁化产品集合,其特征在于:以能源草,或能源草和牛粪为起始主原料,经加工子路径的串并联集成清洁生产之工艺及组合设备或装置阵,最后制得清洁化产品集合,所述“产品集合”具体由如下所述的主产品A,或主产品A再与副产品B、C的任一或两种产品的组合所构成;或主产品A或和副产品B/C,再与辅助产品D、E、F、G、H、I的任一或多种产品的组合所构成:A collection of clean products using energy grass as raw material, which is characterized by: using energy grass, or energy grass and cow dung as the starting main raw materials, through the series and parallel connection of processing sub-paths, the clean production process and combined equipment or device array are integrated, and finally A collection of cleaning products is prepared, and the "product collection" is specifically composed of main product A as described below, or a combination of main product A and any one or two of by-products B and C; or main product A or and by-product B/C, and then combined with any one or more of the auxiliary products D, E, F, G, H, and I:
    主产品A——亲水疏解纤维,特征是:以前述“能源草,或能源草和牛粪”经锯/碾/切/锤的任一或多种组合碎化再过筛处理,获得其中的“过3目至不过28目筛范围的任一目数的分级或混合粒径的细长状纤维束”碎化物,以其为原料;制备过程中会排出棕/黑液,所述“棕/黑液”的重量份W棕/黑液,与所获主产品A中含水不超15%的绝干纤维之重量份WA的比例在W棕/黑液/WA=90~100~300/100范围;且“棕/黑液”中所含Na+或/和K+或/和Mg2+的克摩尔与其所含水的升体积之比为≤0.034mol/L,其pH值在5.0~9.4范围;使用的助剂中,所含苛性碱、氨、铵盐、过氧化物、生物酶的任一或多种的总含量为0;或和制备中使用水不溶或难溶性物质做晶须助剂,对纤维表面实施低灰分的晶须接枝/包覆,所述“晶须助剂”,对主产品A中绝干纤维100重量份的添加量,为≤1~3~5~9重量份,既≤1重量份或≤3重量份或≤5重量份或≤9重量份;所述主产品α——亲水疏解纤维产品,其入水或再经搅拌后能不浮水面;The main product A - hydrophilic decomposable fiber, characterized by: using the aforementioned "energy grass, or energy grass and cow dung", crushed by any or more combinations of sawing/milling/cutting/hammering and then sieving to obtain the "Elongated fiber bundles of any mesh size that pass through a sieve ranging from 3 mesh to no more than 28 mesh" are used as raw materials; the brown/black liquor will be discharged during the preparation process, and the "brown/black liquor" will be discharged. The ratio of the weight part W brown/black liquor of "black liquor" to the weight part W A of the absolute dry fiber containing no more than 15% water in the main product A is W brown/black liquor /W A = 90~100~300 /100 range; and the ratio of the gram moles of Na + or/and K + or/and Mg 2+ contained in the "brown/black liquor" to the liter volume of the water contained is ≤0.034mol/L, and its pH value is within 5.0~9.4 range; the total content of any one or more of caustic alkali, ammonia, ammonium salts, peroxides, and biological enzymes in the additives used is 0; or the water-insoluble or poorly soluble substances used in the preparation To make a whisker additive, implement low-ash whisker grafting/coating on the fiber surface. The "whisker additive" added to 100 parts by weight of the absolutely dry fiber in the main product A is ≤ 1 to 3 ~5~9 parts by weight, either ≤1 part by weight or ≤3 parts by weight or ≤5 parts by weight or ≤9 parts by weight; the main product α - a hydrophilic decomposable fiber product, which cannot be removed after being put into water or stirred again floating surface;
    所述主产品A,其又可被细分有主产品A-1——被控制为低亲水之打浆度<16°SR的亲水疏解纤维,和主产品A-2——被控制呈高亲水之打浆度≥16°SR的亲水疏解纤维;The main product A can be subdivided into the main product A-1 - a hydrophilic decomposable fiber controlled to have a low hydrophilic beating degree of <16°SR, and the main product A-2 - controlled to be Hydrophilic and decomposable fiber with high hydrophilic beating degree ≥16°SR;
    副产品B——木塑复合再生质粗粒;特征是:至少以前述“能源草”经锯/碾/切/锤的任一或多种组合碎化,再经筛分处理后所获其中的另一部分:“过28目筛的细屑料或/和粉碎物,或和过3目筛的粗细混合的碎化物”,再取其与“废塑料”为原料,或和再与A中所述“棕/黑液”存在传质联系,使用生物质燃料颗粒机制粒;By-product B - wood-plastic composite regenerated coarse particles; characterized by: at least the above-mentioned "energy grass" is crushed by any one or more combinations of sawing/milling/cutting/hammering, and then screened. The other part: "Fine materials or/and crushed materials that pass through a 28-mesh sieve, or crushed materials that are mixed with coarse and fine materials that pass through a 3-mesh sieve", and then use them with "waste plastics" as raw materials, or mix them with those in A The above-mentioned "brown/black liquor" has a mass transfer connection and is pelletized using a biomass fuel pellet machine;
    副产品C——木素/树脂混合物,特征是:以A中所述“棕/黑液”为原料所制获,在室温下呈红茶色的亲水性液体,或呈面酱状棕褐或近黑色胶体,或呈咖啡或近黑色粉体或颗粒,或呈松香状固体;所述副产品C,其中又可被细分有副产品C-1——食用或医用级的木素/树脂混合物,副产品C-2——饲用或工业级的木素/树脂混合物;By-product C - lignin/resin mixture, characterized by: It is produced using the "brown/black liquor" mentioned in A as raw material. It is a hydrophilic liquid in the color of black brown at room temperature, or in the form of a paste-like brown or Nearly black colloid, or in the form of coffee or nearly black powder or granules, or in the form of rosin-like solid; the by-product C, which can be subdivided into by-product C-1 - edible or medical grade lignin/resin mixture, By-product C-2 - feed or industrial grade lignin/resin mixture;
    辅助产品D——固态有机土壤改良剂,特征是:在提取了“能源草,或能源草和牛粪”中不过28目筛孔料制主产品A后的余料,既过28目筛孔的能源草之粉料或和细牛粪沉渣,作为固态有机土壤改良剂中的配料之一;Auxiliary product D - solid organic soil conditioner, characterized by: the remaining material after extracting "energy grass, or energy grass and cow dung" that does not pass the 28-mesh sieve to make the main product A. Energy grass powder or fine cow dung sediment is used as one of the ingredients in the solid organic soil conditioner;
    辅助产品E——液态有机土壤改良剂,特征是:利用在制备亲水疏解纤维主产品A的过程中会排出棕/黑液,或/和利用因提质主产品A和副产品C而排出的压榨液或/和洗涤液或/和淘洗液,按所被施农作物和田块的土质需要所搀兑出的产品;所述“排出的压榨液或/和洗涤液或/和淘洗液”或“棕/黑液”,其pH值在5.0~9.4范围,和其中所含Na+或/和K+或/和Mg2+的克摩尔与其所含水的升体积之比为≤0.034mol/L,或其中所含的可溶性钠盐、钾盐、镁盐的wt%总浓度≤0.20%(wt%),或其中所含的可溶性钠盐、钾盐、镁盐的总浓度与生产实施地所取水源中的可溶性钠盐、钾盐、镁盐的总浓度之差≤0.01%(wt%);辅助产品E与主产品A的重量之比被控制在WE/WA≤500/100或≤或2000/100≤或3000/100范围;Auxiliary product E - liquid organic soil conditioner, characterized by: utilizing the brown/black liquor discharged during the preparation of the hydrophilic decomposable fiber main product A, or/and utilizing the discharged liquid due to upgrading the main product A and by-product C Pressed liquid or/and washing liquid or/and elutriated liquid, products blended according to the soil requirements of the crops and fields to be applied; the "discharged pressed liquid or/and washing liquid or/and elutriated liquid" Or "brown/black liquor", with a pH value in the range of 5.0 to 9.4, and the ratio of the gram moles of Na + or/and K + or/and Mg 2+ contained in it to the liter volume of the water contained therein is ≤0.034 mol /L, or the total wt% concentration of the soluble sodium salt, potassium salt, and magnesium salt contained therein is ≤ 0.20% (wt%), or the total concentration of the soluble sodium salt, potassium salt, and magnesium salt contained therein is consistent with the production implementation The difference in the total concentration of soluble sodium salts, potassium salts, and magnesium salts in the water source taken from the local area is ≤0.01% (wt%); the weight ratio of auxiliary product E and main product A is controlled at W E /W A ≤500/ 100 or ≤ or 2000/100 ≤ or 3000/100 range;
    辅助产品F——发酵饲料,特征是:在产品里掺入了主产品A制备过程中所排出的“棕/黑液”;Auxiliary product F - fermented feed, characterized by: the product is mixed with the "brown/black liquor" discharged during the preparation process of main product A;
    辅助产品G——颗粒饲料,特征是:用能源草干料仅经破碎过筛所获的过28目筛细粉,或/和过28至不过150目筛范围的含土量微的粒径居中的能源草纤维粉屑,用其作为颗粒饲 料的配料组份之一;Auxiliary product G - pellet feed, characterized by: the energy grass dry material is only crushed and sieved to obtain a fine powder that passes through a 28 mesh sieve, or/and a particle size with a small soil content that passes through a 28 to less than 150 mesh sieve. Centered energy grass fiber crumbs for use as pellet feed One of the ingredients of the material;
    辅助产品H——生物质颗粒燃料,特征是:以能源草被破碎、过筛脱除了未过28目筛之粗纤维后的细粉料,或是全组份的能源草粉碎物,为配料组份;或再配加了废塑料;所述“废塑料”,至少包括废农用塑膜、废泡沫塑料、废化纤织物或/和化纤棉絮的任一或多种的组合,所述的“配加”占辅助产品H之总重量的5%以下,或至高不超22%;Auxiliary product H - biomass pellet fuel, characterized by: the fine powder obtained by crushing and sieving the energy grass to remove crude fibers that have not passed the 28 mesh sieve, or the full-component crushed energy grass as ingredients. components; or waste plastics are added; the "waste plastics" include at least any one or combination of waste agricultural plastic films, waste foam plastics, waste chemical fiber fabrics or/and chemical fiber cotton batting, and the "waste plastics" "Additional" accounts for less than 5% of the total weight of auxiliary product H, or does not exceed 22%;
    辅助产品I——食用菌种植棒/块,特征是:在提取了“能源草,或能源草和牛粪”中之不过28目筛孔料制主产品A后的余料,既过28目筛孔的能源草之粉料或和细牛粪沉渣,作为食用菌种植棒/块中的配料组份之一。Auxiliary product I - Edible fungus planting stick/block, characterized by: the remaining material after extracting the main product A from "energy grass, or energy grass and cow dung" with a mesh size of no more than 28 mesh, and passing through a 28 mesh sieve. The energy grass powder or fine cow dung sediment of the hole is used as one of the ingredients in the edible fungus planting sticks/blocks.
  2. 权利要求1所述的“主产品A——亲水疏解纤维”,其特征至少还包括如下ⅰ至ⅵ,或再与ⅶ的组合:The characteristics of the "main product A - hydrophilic and decomposable fiber" according to claim 1 include at least the following ⅰ to ⅵ, or a combination with ⅶ:
    ⅰ.所用原料:包括芒萁、里白、香茅、芦竹、芦苇、类芦、斑茅、象草、王草、皇竹草、巨菌草、五节芒、大米草、紫象草、矮象草、红象草、甜象草、牧草笋、牧草蔗、拟高粱、甜高粱、彼特草、苏丹草、台湾甜草、交狼尾草、互花米草杂、美洲狼尾草、杂交狼尾草的任一种或多种组合的能源草,产生大量秸秆的粮、棉、油农作物——稻、麦、玉米、棉花、油菜、大豆、油牡丹、油芍药、向日葵、蓖麻的任一种或多种秸秆组合的能源草,或由人工矮化种植且常年要修剪上部枝条的柳树、竹柳、杨树、桑树、枸树的任一种或多种组合的能源草;经锯/碾/切/锤的任一或多种组合碎化再过筛处理,获得其中的一部分:过3目至不过28目筛范围的任一目数的分级或混合粒径的细长状纤维束碎化物;ⅰ. Raw materials used: including Echinacea, Liba, lemongrass, Arundodis, reeds, reeds, zebra grass, elephant grass, king grass, king bamboo grass, giant fungus grass, five-jointed miscanthus, rice grass, purple elephant grass , dwarf elephant grass, red elephant grass, sweet elephant grass, grass shoots, grass sugarcane, pseudosorghum, sweet sorghum, Peter grass, Sudan grass, Taiwan sweet grass, Pennisetum alterniflora, Spartina alterniflora hybrid, American wolftail Energy grasses of any one or more combinations of grasses and hybrid pennisetum, grain, cotton, and oil crops that produce a large amount of straw - rice, wheat, corn, cotton, rape, soybeans, oil peony, oil peony, sunflower, Energy grass of any one or more combinations of castor straws, or any one or more combinations of willows, bamboo willows, poplars, mulberry trees, and wolfberry trees that are artificially planted in dwarfs and whose upper branches need to be pruned all year round. Grass; crushed by any one or more combinations of sawing/grinding/cutting/hammering and then sieved, a part of it is obtained: fine particles with any mesh size ranging from 3 mesh to no more than 28 mesh sieve or mixed particle size Fragments of long fiber bundles;
    ⅱ.副产物料:副产物料1:热水脱木素/树脂工序所排棕/黑液,在制所述的“A”时,会在用干料在热水脱木素/树脂工序,经压/挤排出棕/黑液;所述的“棕/黑液”,其重量份W棕/黑液,与所获主产品A中含水不超15%的绝干纤维之重量份WA的比例在W棕/黑液/WA=90~100~300/100范围;所述“棕/黑液”中所含Na+或/和K+或/和Mg2+的克摩尔与其升体积之比为≤0.034mol/L,或/和所含的可溶性无机钠盐、钾盐、镁盐的wt%总浓度≤0.20%(wt%),或水中所含的可溶性无机盐、钾盐、镁盐的wt%总浓度与生产实施地所取水源中的总浓度之差≤0.01%(wt%),“棕/黑液”之pH值在5.0~9.4范围;ⅱ. By-product materials: By-product material 1: Brown/black liquor discharged from the hot water delignification/resin process. When making the "A" mentioned above, dry materials will be used in the hot water delignification/resin process. , the brown/black liquor is discharged by pressing/squeezing; the "brown/black liquor" has a weight part W of the brown/black liquor and a weight part W of the absolute dry fiber containing no more than 15% water in the main product A obtained The ratio of A is in the range of W brown/black liquor /W A =90~100~300/100; the gram moles of Na + or/and K + or/and Mg 2+ contained in the "brown/black liquor" are equal to The volume ratio per liter is ≤0.034mol/L, or/and the total wt% concentration of the soluble inorganic sodium salts, potassium salts, and magnesium salts contained in the water is ≤0.20% (wt%), or the soluble inorganic salts and potassium salts contained in the water The difference between the total wt% concentration of salt and magnesium salt and the total concentration in the water source taken from the production site is ≤0.01% (wt%), and the pH value of the "brown/black liquor" is in the range of 5.0 to 9.4;
    或副产物料2:用鲜能源草或先用水洗净后的鲜能源草再经压榨所获的鲜汁液;或干能源草经水洗净后再水煮、压榨所获的汁液;Or by-product material 2: fresh juice obtained from fresh energy grass or fresh energy grass washed with water and then squeezed; or juice obtained from dried energy grass washed with water and then boiled and squeezed;
    或和副产物料3:以牛粪为起始原料,对牛粪做淘/洗后所排出的淘/洗液;Or and by-product material 3: using cow dung as the starting material, the washing/washing liquid discharged after washing/washing the cow dung;
    或和副产物料4:使用活性炭和酸性白土,对前述“棕/黑液”做吸附脱色杂,制净化循环用水后,所获的脱色吸附渣泥;或对前述“棕/黑液”,滴加硫酸酸化至pH值不超出7.0条件下,使用活性炭或活性炭和酸性白土制净化循环用水后所获的脱色吸附渣泥;Or and by-product material 4: use activated carbon and acidic clay to adsorb and decolorize impurities in the aforementioned "brown/black liquor", and purify circulating water to obtain the decolorized adsorption sludge; or use the aforementioned "brown/black liquor", The decolorized adsorption sludge is obtained by adding sulfuric acid dropwise to acidify until the pH value does not exceed 7.0, and using activated carbon or activated carbon and acid clay to purify circulating water;
    或和副产物料5:使用化学或生化法,对前述“棕/黑液”或/和“淘/洗液”做沉淀净化处理所获得的脱色沉淀渣泥;Or and by-product material 5: decolorized precipitated sludge obtained by precipitation and purification of the aforementioned "brown/black liquor" or/and "washing liquor" using chemical or biochemical methods;
    ⅲ.残留色度:主产品A入清水,以产品绝干料与清水按重量比=1:6所加热至70℃泡化5至10分钟后所挤获未蒸发失重清液料,以比色管直观或比色仪检测色度不浓于ⅱ项所述“棕/黑液”被清水稀释16倍的色度,或仪器检测其COD或BOD值不高于ⅱ项所述“棕/黑液”被清水体积稀释16倍的COD或BOD值,或用容量滴定法测其高锰酸钾退色消耗量值不高于ⅱ项所述“棕/黑液”被清水体积稀释16倍的高锰酸钾退色消耗量值;ⅲ. Residual color: Add the main product A into clean water, heat the product to 70°C and bubble it for 5 to 10 minutes, then squeeze out the clear liquid material that has not evaporated and lost weight. The color of the color tube intuitively or the colorimeter detects is not thicker than the color of the "brown/black liquid" mentioned in item ⅱ diluted 16 times with clean water, or the instrument detects that its COD or BOD value is not higher than the "brown/black liquor" mentioned in item ⅱ The COD or BOD value of the "black liquor" diluted 16 times by the volume of clean water, or the discoloration consumption value of potassium permanganate measured by volumetric titration is not higher than the value of the "brown/black liquor" diluted 16 times by the volume of clean water as described in item ⅱ Potassium permanganate fading consumption value;
    ⅳ.产品剂型:主产品A的剂型可为含水不多于75%呈松散肉松状潮料、含水不多于75%呈潮纸状料、含水不多于20%的肉松状干料、含水不多于20%的纸状干料、含水不多于20%的呈压实砖状干料、含水不多于20%的呈压实颗粒状干料的任一种; ⅳ. Product dosage form: The dosage form of the main product A can be a loose meat floss-like moist material with a water content of not more than 75%, a wet paper-like material with a water content of not more than 75%, a dry meat floss-like material with a water content of not more than 20%, and a water-based material. Any of paper-like dry materials containing no more than 20% water, compacted brick-shaped dry materials containing no more than 20% water, and compacted granular dry materials containing no more than 20% water;
    ⅴ.物性特征:被控制为低亲水之打浆度<16°SR的主产品A-1,或A-1与控制呈高亲水之打浆度≥16°SR的主产品A-2,A-1与A-2呈可被方便任意掺配的两组料;在与标样团料——天牛幼虫或木蠹蛾幼虫蛀食柳树杆的粪便所制标样,做团料对团料的对掐测试中,A-1或A-2的硬度≤标样的硬度;或和在与标样团料,做团料对团料的对搓至少10次测试中,以裸眼看或用天平秤重比较,A-1或A-2的散落屑量不多于标样散落屑量的5倍;ⅴ. Physical properties: Main product A-1 controlled to have a low hydrophilicity with a beating degree of <16°SR, or A-1 and main product A-2, A controlled to have a high hydrophilicity with a beating degree of ≥16°SR. -1 and A-2 are two sets of materials that can be blended easily and arbitrarily; they are compared with the standard sample pellets - the excrement of beetle larvae or wood moth larvae eating willow stems. In the pinch test of the material, the hardness of A-1 or A-2 ≤ the hardness of the standard sample; or in the test of rubbing the dough with the standard sample for at least 10 times, it can be seen with the naked eye or Use a balance to weigh and compare, the amount of scattered chips of A-1 or A-2 is not more than 5 times the amount of scattered chips of the standard sample;
    ⅵ.产程特征:生产过程里,所涉水中,所含Na+或/和K+或/和Mg2+的克摩尔与“水”的升体积之比为≤0.034mol/L;和采用不低于70℃的水至少2次浸渍纤维物料,以脱除纤维中的木素/树脂;所述的“水”流中之逐级渐浓的棕/黑液流向与纤维物料在生产过程中的流向呈逆流;或和添加水不溶或难溶性物质做晶须助剂,其添加量对主产品A或其中间产物里绝干纤维100重量份,为≤1~3~5~9重量份,既≤1重量份或≤3重量份或≤5重量份或≤9重量份,对纤维表面实施低灰分的晶须接枝/包覆;使用的助剂中,所含苛性碱、氨、铵盐、过氧化物、生物酶的任一或多种的总含量为0;ⅵ. Production process characteristics: During the production process, the ratio of the gram moles of Na + or/and K + or/and Mg 2+ contained in the water involved to the liter volume of "water" is ≤0.034 mol/L; and adopt Impregnate the fiber material with water of not less than 70°C at least twice to remove the lignin/resin in the fiber; the flow direction of the gradually thickening brown/black liquor in the "water" flow is consistent with the flow direction of the fiber material in the production process The flow direction in the product is countercurrent; or water-insoluble or poorly soluble substances are added as whisker additives, and the amount added is ≤1~3~5~9 parts by weight for 100 parts by weight of absolute dry fiber in the main product A or its intermediate product parts by weight, either ≤1 part by weight or ≤3 parts by weight or ≤5 parts by weight or ≤9 parts by weight, implement low-ash whisker grafting/coating on the fiber surface; among the additives used, caustic alkali, ammonia The total content of any one or more of ammonium salts, peroxides, and biological enzymes is 0;
    ⅶ.较佳参数:或ⅱ项所述的“其排出的重量份W棕/黑液,与含水不超15%的绝干主产品A的总获重量份WA的比例在W棕/黑液/WA=100~120~150/100范围;或和ⅵ项所述的“添加水不溶或难溶性物质做晶须助剂,其添加量对主产品A或其中间产物里绝干纤维100重量份”“为≤1~3~5重量份”,“既≤1重量份或≤3重量份或≤5重量份”;所述的“晶须助剂”至少是氢氧化钙饱和水溶液、硅溶胶的任一种,或/和在水相中新生成的氢氧化钙、氢氧化铝、水合硅酸、硅酸钙、硅酸镁、硅酸铝、碳酸钙、二水合硫酸钙、氢氧化铁的任一或多种的组合,或/和经超细粉碎至在水中不能在半小时里自然沉淀至表层水清的高岭土、粘土、粉煤灰、硅灰石的任一或多种的组合,或和粉碎至过320目的高岭土、粘土、粉煤灰、硅灰石的任一或多种的组合。ⅶ. Preferable parameters: or "The ratio of the discharged weight part W brown/black liquor and the total obtained weight part W A of the absolutely dry main product A with a water content not exceeding 15% as described in item ⅱ is W brown/black Liquid /W A = 100~120~150/100 range; or "adding water-insoluble or poorly soluble substances as whisker additives as described in item ⅵ, the amount added is equivalent to the absolute dry fiber in the main product A or its intermediate product "100 parts by weight""is ≤1~3~5 parts by weight", "either ≤1 part by weight or ≤3 parts by weight or ≤5 parts by weight"; the "whisker additive" is at least a saturated aqueous solution of calcium hydroxide , any kind of silica sol, or/and newly generated calcium hydroxide, aluminum hydroxide, hydrated silicic acid, calcium silicate, magnesium silicate, aluminum silicate, calcium carbonate, calcium sulfate dihydrate, Any one or more combinations of ferric hydroxide, or/and any one or more of kaolin, clay, fly ash, wollastonite that has been ultrafinely pulverized to the point where it cannot naturally precipitate to clear surface water within half an hour in water. A combination of these, or a combination of any one or more of kaolin, clay, fly ash, and wollastonite crushed to over 320 mesh.
  3. 权利要求1所述“副产品B——木塑复合再生质粗粒”,其更多特征在于:其中“木”之特征为如下3-1或3-1与3-2的组合,其中“塑”之特征为如下3-3或3-3与3-4的组合,其产品剂型特征为如下3-5至3-8:The "by-product B - wood-plastic composite regenerated coarse particles" described in claim 1 is more characterized in that: the characteristics of "wood" are as follows 3-1 or the combination of 3-1 and 3-2, wherein "plastic "The characteristics are the following 3-3 or the combination of 3-3 and 3-4, and the product dosage form characteristics are the following 3-5 to 3-8:
    3-1.其中的“木”,含来源于能源草之中的一部分:过28目筛的细屑料或/和粉碎物,或和过3目筛的粗细混合的碎化物;3-1. The “wood” includes part of the energy grass: fine materials or/and crushed materials that pass through a 28-mesh sieve, or crushed materials mixed with coarse and fine materials that pass through a 3-mesh sieve;
    3-2.由如上3-1所述的“一部分”,为所述“木”在空气中自然干燥后含15%平衡水量之干基重,在副产品B的总重量中占比5%至78%(wt%)之间;3-2. The "part" as described in 3-1 above is the dry basis weight of the "wood" containing 15% of equilibrium water after natural drying in the air, accounting for 5% to 5% of the total weight of by-product B. Between 78% (wt%);
    3-3.其中的“塑”之原料,皆选材于废塑料;3-3. The raw materials for "plastic" are all selected from waste plastics;
    3-4.如上3-3所述“废塑料”,至少包括如后所述的任一或多种的组合:废纸再生所弃的杂废塑膜渣,包括所述“杂废塑膜渣”经水浮选所获浮水含塑物或/和沉水含塑物;商品的塑膜质废包装袋、塑膜包装袋生产中的切/冲边料、废复合塑膜材、商标标贴生产/使用中所弃的塑膜复合离型纸/膜、废铝塑复合膜、废农用塑膜;由废旧轮胎经破碎分离出的含杂聚合物纤维,从汽车中拆除出的废化纤绒布,废化纤地毯、废化纤织物、废化纤熔喷布、废化纤过滤纸;废电线塑料皮、废塑料包装带、废塑料编织袋、废土工布、废/旧塑料鞋、废塑料铺地制品、废塑料玩具、废塑料桶、废塑料瓶、废塑料土工布、废/旧塑料草坪、废杂塑料建材、废塑料管、废塑料板、废塑料文具、废塑料箱/包、废塑料杂件;废PVC人造革、废PU人造革;废泡沫塑料;3-4. "Waste plastics" as described in 3-3 above, at least include any one or a combination of more as described below: Miscellaneous waste plastic film residue discarded from waste paper recycling, including the "miscellaneous waste plastic film" "Residue" obtained by water flotation, floating plastics or/and submerged plastics; plastic film waste packaging bags for commodities, cut/punch edges from the production of plastic film packaging bags, waste composite plastic film materials, trademarks Plastic film composite release paper/film, waste aluminum-plastic composite film, and waste agricultural plastic film discarded during label production/use; impurity-containing polymer fibers separated from waste tires after crushing, waste removed from cars Chemical fiber flannel, waste chemical fiber carpet, waste chemical fiber fabric, waste chemical fiber meltblown cloth, waste chemical fiber filter paper; waste wire plastic skin, waste plastic packaging tape, waste plastic woven bag, waste geotextile, waste/old plastic shoes, waste plastic shop Ground products, waste plastic toys, waste plastic barrels, waste plastic bottles, waste plastic geotextiles, waste/old plastic lawns, waste plastic building materials, waste plastic pipes, waste plastic boards, waste plastic stationery, waste plastic boxes/bags, waste Miscellaneous plastic parts; waste PVC artificial leather, waste PU artificial leather; waste foam plastic;
    3-5.副产品B的剂型至少可被设置呈甲、乙、丙、丁之第一组,或/和戊、己、更、辛之第二组,或/和壬、癸之第三组,即可在第一至第三组中的甲至癸中任取一或多种以任意比的作搀兑联用,就能方便地使木塑复合再生质粗粒的下游之塑料粒子或制品中的“木”或 携“杂质”的“木”总重量投料占比为5%至78%范围;前述“携‘杂质’的‘木’”中的两者重量之比为W杂质/W=0~10/100,所述的“木”,为含水量不高于15%的绝干料,所述的“杂质”为如权利要求2中ⅱ里所述“副产物料4”或/和“副产物料5”;“塑”和软化剂总重量投料占比为22%至95%范围,前述“‘塑’和软化剂”中的两者重量之比,即W废塑料/W软化剂=100/0~100:3-5. The dosage form of by-product B can be at least set into the first group of A, B, C, and D, or/and the second group of E, Ji, Geng, and Xin, or/and the third group of Ren and Gui. , that is, any one or more of A to Gui in the first to third groups can be blended and combined in any ratio to easily make the downstream plastic particles or coarse particles of wood-plastic composite regeneration. "Wood" in products or The proportion of the total weight of "wood" carrying "impurities" ranges from 5% to 78%; the weight ratio of the two in the aforementioned "'wood' carrying 'impurities'" is W impurities /W wood = 0~10/ 100. The "wood" is absolutely dry material with a moisture content of no more than 15%, and the "impurities" are "by-product materials 4" or/and "by-products" as described in claim 2, ii. Material 5"; the total weight of "plastic" and softener is in the range of 22% to 95%. The weight ratio of the two in the aforementioned "'plastic' and softener" is W waste plastic /W softener = 100 /0~100:
    第一组:First group:
    甲中包括“木”总重量投料占比为76%,废塑料和软化剂总重量投料占比为24%;The total weight input of "wood" in A includes 76%, and the total weight input of waste plastics and softeners accounts for 24%;
    乙中包括“木”总重量投料占比为35%,废塑料和软化剂总重量投料占比为65%;The total weight input of "wood" in B is 35%, and the total weight input of waste plastics and softeners is 65%;
    丙中包括“木”总重量投料占比为25%,废塑料和软化剂总重量投料占比为75%;The total weight input of "wood" in C is 25%, and the total weight input of waste plastics and softeners is 75%;
    丁中包括“木”总重量投料占比为5,废塑料和软化剂总重量投料占比为95%;The total weight input of "wood" in D is 5, and the total weight input of waste plastics and softeners is 95%;
    第二组:Second Group:
    戊中包括“木”总重量投料占比为77%,废塑料和软化剂总重量投料占比为23%;The total weight input of "wood" in E includes 77%, and the total weight input of waste plastics and softeners accounts for 23%;
    己中包括“木”总重量投料占比为38%,废塑料和软化剂总重量投料占比为62%;The total weight input of "wood" accounts for 38%, and the total weight input of waste plastics and softeners accounts for 62%;
    更中包括“木”总重量投料占比为23%,废塑料和软化剂总重量投料占比为77%;The update includes that the total weight input of "wood" accounts for 23%, and the total weight input of waste plastics and softeners accounts for 77%;
    辛中包括“木”总重量投料占比为10,废塑料和软化剂总重量投料占比为90%;The total weight input of "wood" in Xin is 10, and the total weight input of waste plastics and softeners is 90%;
    第三组:The third group:
    壬中包括“木”总重量投料占比为78%,废塑料和软化剂总重量投料占比为22%;The total weight input of "wood" in Renzhong accounts for 78%, and the total weight input of waste plastics and softeners accounts for 22%;
    癸中包括“木”总重量投料占比为15%,废塑料和软化剂总重量投料占比为85%;The total weight input of "wood" in Guizhong accounts for 15%, and the total weight input of waste plastics and softeners accounts for 85%;
    3-6.或在3-5项所述的“在第一至第三组中的甲至癸中任取一或多种搀兑联用,控制了在木塑复合再生质粗粒的下游塑料粒子或制品中的“木”总重量投料占比为5%至78%范围,“塑”和软化剂总重量投料占比为22%至95%范围”内,3-5项所述的“第一组”、“第二组”、“第三组”中的甲至癸的各投料组合中的“木”总重量投料占比,与“塑”和软化剂总重量投料占比,皆可按市场客户的定制来定;3-6. Or as described in item 3-5, "select one or more of the A to Gui in the first to third groups and use them in combination to control the downstream coarse particles of the wood-plastic composite regenerated material. The total weight of "wood" in plastic particles or products is in the range of 5% to 78%, and the total weight of "plastic" and softener is in the range of 22% to 95%", items 3-5 The proportion of the total weight of "wood" in each feeding combination from A to Gui in the "first group", "second group" and "third group", and the proportion of the total weight of "plastic" and softener, All can be customized according to market customers;
    3-7.所述的“木塑复合再生质粗粒”,其组成的物料按3-5项前述的“第一组”或/和“第二组”或/和“第三组”中的甲至癸各分组合配料投料,经粗粒造粒机处理后,得质地呈可被人手指/掌直接拉/扳/捏/撕/抓得碎的低强度粗粒,所述“低强度”,至少是抗拉强度≤3PMa的塑料之标样试片;3-7. The "wood-plastic composite recycled coarse particles" are composed of materials according to the "first group" or/and the "second group" or/and the "third group" mentioned in item 3-5. The ingredients from A to Gui are combined and fed. After being processed by a coarse granulator, the resulting texture is low-strength coarse granules that can be directly pulled/pulled/pinched/teared/grabbed with fingers/palms. The "low-strength coarse granules" "Strength", at least the standard sample specimen of plastic with tensile strength ≤3PMa;
    3-8.如上3-7项所述“粗粒造粒机”,具体是指具有连续式进/出料功能的饲料颗粒机、有机肥造粒机、生物质燃料颗粒机的任一种,或再在前述“颗粒机”/“造粒机”之后再串联螺旋切粒中碎机。3-8. The "coarse granulator" mentioned in item 3-7 above specifically refers to any feed pellet machine, organic fertilizer granulator, or biomass fuel pellet machine with continuous feeding/discharging function. , or a spiral granulator and intermediate crusher can be connected in series after the aforementioned "granulator"/"granulator".
  4. 权利要求1所述产品集合中的“主产品A——亲水疏解纤维产品”的制法,其特征可包括如下步骤一至十:The manufacturing method of "main product A - hydrophilic decomposable fiber product" in the product set described in claim 1 can be characterized by including the following steps one to ten:
    步骤一——预处理备料:Step 1 - Preprocessing and preparation:
    对能源草干料先做品种归类,或再对已归类料中所含金属或/和砖石块或/和树皮杂质作进一步的脱杂处理,然后再对已归类、脱杂的能源草实施锯/碾/切/锤的任一或多种组合碎化再过筛处理处理;排出另作利用的过28目筛的能源草碎化物;Classify the energy grass dry materials first, or further remove impurities from metals or/and masonry blocks or/and bark impurities contained in the classified materials, and then classify and remove impurities. The energy grass is crushed by any one or more combinations of sawing/grinding/cutting/hammering and then screened; the crushed energy grass that passes through a 28-mesh sieve is discharged for further use;
    筛取能源草碎化物料中的过3目至不过28目筛范围的任一目数的分级或混和粒径的细长状纤维束;Sieve out the elongated fiber bundles with classified or mixed particle sizes in any mesh range from 3 mesh to 28 mesh in the energy grass crushed material;
    或对已获脱杂净化的细长状纤维束能源草碎化物,再施机械膨化处理;Or the slender fiber bundle energy grass crumbs that have been removed and purified are subjected to mechanical expansion processing;
    由此获得备做步骤二处理的备用能源草碎化物,此“备用能源草碎化物”料以其在空气中自然吸附的平衡水量15%(wt)计的,被称之为自然绝干料; Thus, the backup energy grass crumbs prepared for step 2 are obtained. This "backup energy grass crumbs" material is called natural absolutely dry material based on its naturally adsorbed equilibrium water content in the air of 15% (wt). ;
    步骤二——第一次配料:Step 2 - First Ingredients:
    取经步骤一所获的“备用能源草碎化物”料之自然绝干料:100重量份,拌入后续步骤七所述“第二次固液分离”所获的挤出水,所述“拌入”“挤出水”,在测知后续步骤四所述“第一次固液分离”所获固相中之自然绝干料100重量份所携的游离水为x重量份,则“拌入”的“挤出水”为不少于:2x重量份;或再拌入前述“挤出水”“2x重量份”的0.1~0.3%重量份之表面活性剂:丁基萘磺酸钠、十二烷基苯磺酸钠、十二烷基硫酸钠的任一种或多种的组合,或/和椰子油脂肪酸二乙醇酰胺、脂肪醇聚氧乙烯醚的任一或多种的组合;所述的“2x”对应能源草碎化物料之自然绝干料100重量份:在25~50~300重量份范围;Take 100 parts by weight of the natural dry material of the "Standby Energy Grass Crushed Material" material obtained in step 1, and mix in the extruded water obtained from the "second solid-liquid separation" described in the subsequent step 7. "Put in" and "squeeze out water", and after measuring that the free water carried by 100 parts by weight of the natural absolutely dry material in the solid phase obtained in the "first solid-liquid separation" described in the subsequent step 4 is x parts by weight, then "mix "Put in" "extruded water" is no less than: 2x parts by weight; or mix in 0.1 to 0.3% by weight of the surfactant: sodium butyl naphthalene sulfonate of the "2x parts by weight" of the aforementioned "extruded water" , any one or more combinations of sodium dodecyl benzene sulfonate, sodium lauryl sulfate, or/and any one or more combinations of coconut oil fatty acid diethanolamide, fatty alcohol polyoxyethylene ether ; The "2x" corresponds to 100 parts by weight of the natural dry material of crushed energy grass materials: in the range of 25 to 50 to 300 parts by weight;
    步骤三——加热溶出:Step three - heating and dissolution:
    将前述“‘备用能源草碎化物’料之自然绝干料100重量份”、“后续步骤七所述‘第二次固液分离’所获的挤出水”:“2x重量份”,或和“‘挤出水’‘2x重量份’的0.1~0.3%重量份之‘表面活性剂’”,将这些物料置于一可被搅拌混合和加热且保温的罐中,对物料实施均匀搅拌和加热至70℃以上,并保温滞留至少5分钟,或被取样分析,当不见有挤出液的颜色更变深色时,即可停止此加热、保温操作;Add the aforementioned "100 parts by weight of the natural dry material of 'Standby Energy Grass Crushed Material'" and "the squeezed water obtained from the 'second solid-liquid separation' described in the subsequent step seven": "2x parts by weight", or and "'Extruded water'" 2x parts by weight" and 0.1 to 0.3% by weight of 'surfactant'", place these materials in a tank that can be stirred, mixed, heated and insulated, and stir the materials evenly and heat to above 70°C, and keep it warm for at least 5 minutes, or take samples for analysis. When the color of the extruded liquid no longer changes to a darker color, you can stop this heating and heat preservation operation;
    步骤四——第一次固液分离:Step 4 - First solid-liquid separation:
    将上述“加热、保温操作”后的物料,导入螺杆或扎辊式挤浆机,对物料的纤维束作碾挤的机械揉化处理,然后再将物料导入固液分离机作固/液分离;或直接将上述加热、保温操作后的物料导入固液分离机作固/液分离;由此得到如权利要求1所述的“压/挤出棕/黑液”,和初脱除纤维中水溶质的待处理亲水疏解纤维中间产物甲的潮料;The material after the above "heating and heat preservation operation" is introduced into a screw or roller extruder, and the fiber bundles of the material are mechanically kneaded by crushing and extrusion, and then the material is introduced into a solid-liquid separator for solid/liquid separation. ; Or directly introduce the material after the above-mentioned heating and heat preservation operations into a solid-liquid separator for solid/liquid separation; thereby obtaining the "pressed/extruded brown/black liquor" as claimed in claim 1, and the initial fiber removal The moisture material of the hydrophilic decomposable fiber intermediate product A to be treated with water solute;
    本“第一次固液分离”,所获的“压/挤出棕/黑液”,其排出的重量份W压/挤出棕/黑液,与亲水疏解纤维中间产物甲之自然绝干料重量份W亲水疏解纤维中间产物甲的比例,可使用常规的固液分离机械,被控制在W压/挤出棕/黑液/W亲水疏解纤维中间产物甲=25~100~300/100范围,既本“第一次固液分离”,所获潮料中“亲水疏解纤维中间产物甲”之自然绝干料重量百分含量,能被控制在80%~50%~25%范围;In this "first solid-liquid separation", the "pressed/extruded brown/black liquor" obtained is naturally separated from the hydrophilic decomposable fiber intermediate product A by the weight portion of the discharged brown/black liquor. The proportion of dry material weight part W hydrophilic decomposable fiber intermediate product A can be controlled by using conventional solid-liquid separation machinery at W pressing/extrusion brown/black liquor /W hydrophilic decomposable fiber intermediate product A =25~100~ In the range of 300/100, in this "first solid-liquid separation", the weight percentage of the natural absolute dry material of the "hydrophilic and decomposable fiber intermediate product A" in the obtained moisture material can be controlled between 80% and 50%. 25% range;
    步骤五——第二次配料:Step 5 - Second batching:
    在测知步骤四所述“待处理亲水疏解纤维中间产物甲的潮料”固相中之自然绝干料100重量份所携的游离水为x重量份后,取“待处理亲水疏解纤维中间产物甲的潮料”所含之自然绝干料100重量份和所携的游离水x重量份,再拌入后续步骤十所述“第三次固液分离”所获的挤出水不少于:x重量份;或和再按权利要求1中项所述“A-1”与“A-2”的差异性要求,有差别化地再配加晶须助剂,所述“晶须助剂”至少是氢氧化钙饱和水溶液、硅溶胶的任一种,或/和在水相中新生成的氢氧化钙、氢氧化铝、水合硅酸、硅酸钙、硅酸镁、硅酸铝、碳酸钙、二水合硫酸钙、氢氧化铁的任一或多种的组合,或/和经超细粉碎至在水中不能在半小时里自然沉淀至表层水清的高岭土、粘土、粉煤灰、硅灰石的任一或多种的组合,或和粉碎至过320目的高岭土、粘土、粉煤灰、硅灰石的任一或多种的组合;所述“晶须助剂”,对“亲水疏解纤维中间产物甲的潮料”中之绝干纤维100重量份的添加量,为≤1~3~5~9重量份,既添加量≤1重量份或≤3重量份或≤5重量份或≤9重量份;After measuring that the free water carried by 100 parts by weight of the natural dry material in the solid phase of the "moist material of the hydrophilic decomposable fiber intermediate product A to be treated" described in step 4 is "Moist material of fiber intermediate product A" contains 100 parts by weight of natural absolutely dry material and x parts by weight of free water, and then mix in the extruded water obtained in the "third solid-liquid separation" described in the subsequent step ten. Not less than: "Whisker additive" is at least any one of calcium hydroxide saturated aqueous solution, silica sol, or/and newly generated calcium hydroxide, aluminum hydroxide, hydrated silicic acid, calcium silicate, magnesium silicate, Any one or combination of aluminum silicate, calcium carbonate, calcium sulfate dihydrate, ferric hydroxide, or/and kaolin, clay, etc. that have been ultrafinely crushed to the point where they cannot naturally precipitate to a clear surface within half an hour in water. Any one or more combinations of fly ash and wollastonite, or any one or more combinations of kaolin, clay, fly ash, and wollastonite crushed to over 320 mesh; the "whisker additive" ”, the added amount of 100 parts by weight of absolute dry fiber in the “moist material of hydrophilic decomposable fiber intermediate product A” is ≤1~3~5~9 parts by weight, that is, the added amount is ≤1 part by weight or ≤3 parts by weight parts or ≤5 parts by weight or ≤9 parts by weight;
    将本步骤五所述的第二次配料,先在搅拌槽中混匀,即成待入高浓磨处理的物料;Mix the second batching ingredients described in step 5 in the mixing tank first to form the materials to be processed by high-concentration grinding;
    步骤六——碾磨消潜:Step 6 - Grind to eliminate potential:
    将步骤五所得的“待入高浓磨处理的物料”,导入高浓磨处理;或再将出高浓磨的发热物料,乘热导入带保温设置的消潜罐中保温或和加热,以不低于70℃之温静置,以松弛经高浓磨处理过程中产生的对纤维的扭结、卷曲,和对纤维中的憎水性脂类的溶出; Introduce the "materials to be fed into the high-concentration grinding process" obtained in step 5 into the high-concentration grinding process; or then introduce the heat-generating materials from the high-concentration grinding into a latent elimination tank with a heat preservation setting for insulation or heating. Let it stand at a temperature of not less than 70°C to relax the kinks and curls in the fibers produced during the high-concentration grinding process, and to dissolve the hydrophobic lipids in the fibers;
    由此步骤六处理后,获得又待固液分离之碾磨或和消遣操作后的物料;After processing in step 6, the material after grinding or processing is obtained and is subject to solid-liquid separation;
    步骤七——第二次固液分离:Step 7 - Second solid-liquid separation:
    将上述“碾磨或和消遣操作后的物料”导入螺杆或扎辊式挤浆机,对物料的纤维束再作碾挤的机械揉化处理,然后再将物料导入固液分离机作固/液分离;或省去机械柔化,就将上述“碾磨或和消遣操作后的物料”直接导入固液分离机作固/液分离;由此得到如前“步骤二”中所述的“‘第二次固液分离’所获的挤出水”,和尚待最后再作新水洗涤之待处理亲水疏解纤维中间产物乙的潮料;The above-mentioned "material after grinding or processing" is introduced into a screw or roller extruder, and the fiber bundles of the material are mechanically kneaded by crushing and extrusion, and then the material is introduced into a solid-liquid separator for solid/liquid separator. Liquid separation; or omitting mechanical softening, the above-mentioned "materials after grinding or processing" are directly introduced into the solid-liquid separator for solid/liquid separation; thereby obtaining the "materials after grinding or processing" as described in the previous "Step 2" "The extruded water obtained from the 'second solid-liquid separation'" and the wet material of the hydrophilic and decomposable fiber intermediate product B are to be finally washed with new water;
    步骤八——第三次配料:Step 8 - The third ingredient:
    在测知步骤七所述“待处理亲水疏解纤维中间产物乙的潮料”固相中之自然绝干料100重量份所携的游离水为x重量份后,取“待处理亲水疏解纤维中间产物乙的潮料”所含之自然绝干料100重量份和所携的游离水x重量份,或和再配加晶须助剂,所述“晶须助剂”至少是包括氢氧化钙饱和水溶液、硅溶胶的任一种,或/和在水相中新生成的氢氧化钙、氢氧化铝、硅溶胶的任一种,或/和在水相中新生成的氢氧化钙、氢氧化铝、水合硅酸、硅酸钙、硅酸镁、硅酸铝、碳酸钙、二水合硫酸钙、氢氧化铁的任一或多种的组合,或和经超细粉碎至在水中难以在半小时里自然沉淀至表层水清的高岭土、粘土、粉煤灰、硅灰石的任一或多种的组合,或和粉碎至过320目的高岭土、粘土、粉煤灰、硅灰石的任一或多种的组合;所述“晶须助剂”,对“中间产物乙的潮料”中之绝干纤维100重量份的添加量,为≤1~3~5~9重量份,既添加量≤1重量份或≤3重量份或≤5重量份或≤9重量份;After measuring that the free water carried by 100 parts by weight of the natural dry material in the solid phase of the "moist material of the hydrophilic decomposable fiber intermediate product B to be treated" described in step seven is The "moist material of fiber intermediate product B" contains 100 parts by weight of natural absolutely dry material and x parts by weight of free water, or may be combined with a whisker auxiliary, and the "whisker auxiliary" at least includes hydrogen Any one of calcium oxide saturated aqueous solution, silica sol, or/and any one of newly generated calcium hydroxide, aluminum hydroxide, and silica sol in the aqueous phase, or/and newly generated calcium hydroxide in the aqueous phase , aluminum hydroxide, hydrated silicic acid, calcium silicate, magnesium silicate, aluminum silicate, calcium carbonate, calcium sulfate dihydrate, iron hydroxide, any one or a combination thereof, or ultrafinely crushed into water Any one or combination of kaolin, clay, fly ash, and wollastonite that is difficult to naturally precipitate to a clear surface within half an hour, or kaolin, clay, fly ash, and wollastonite crushed to a mesh size of 320 Any one or a combination of more; the "whisker additive" added to 100 parts by weight of absolutely dry fiber in the "moist material of intermediate product B" is ≤1~3~5~9 parts by weight , that is, the addition amount is ≤1 part by weight or ≤3 parts by weight or ≤5 parts by weight or ≤9 parts by weight;
    由此步骤八的计量加水和晶须助剂,获待送步骤九处理的第三次配料;From the metered addition of water and whisker additives in step eight, the third ingredient to be sent to step nine is obtained;
    步骤九——搅拌洗涤:Step 9 - Stir and wash:
    将上述步骤八的“第三次配料”导入螺杆或扎辊式挤浆机,对物料的纤维束再作碾挤的机械揉化处理,然后再将物料导入待最后挤干的物料暂储槽;或将上述“第三次配料”直接导入搅拌机作搅拌,使新水,或和晶须助剂与亲水疏解纤维中间产物乙的潮料固相纤维中本来所含的旧水物料,实现充分的混合,然后再将物料导入待最后挤干的物料暂储槽;Introduce the "third batching" of the above step 8 into the screw or roller squeezer, perform mechanical kneading treatment on the fiber bundles of the material, and then introduce the material into the temporary storage tank of the material to be finally squeezed dry. ; Or the above-mentioned "third batching" can be directly introduced into the mixer for stirring, so that new water, or the old water material originally contained in the moisture solid phase fiber of the whisker additive and the hydrophilic decomposable fiber intermediate product B can be achieved. Mix thoroughly, and then introduce the material into the temporary storage tank for the final squeezed dry material;
    由此步骤九的处理,获得待送步骤十处理的待最后挤干的物料;From the processing in step nine, the material to be finally squeezed out and sent to step ten is obtained;
    步骤十——第三次固液分离或和最后修饰:Step 10 - The third solid-liquid separation or final modification:
    将上述步骤九的“待最后挤干的物料”导入固液分离机作固/液分离;由此得到如前“步骤五”中所述的“‘第三次固液分离’所获的挤出水”,和最后产品——包括A-1或/和A-2之亲水疏解纤维A产品;或和再对最后产品添加掩蔽铁/锰离子的助剂:草酸、草酸钠、草酸钾、草酸铵、乙二胺四乙酸、乙二胺四乙酸钠、四乙酰乙二胺、柠檬酸、柠檬酸钠、酒石酸、酒石酸钠、葡萄糖酸、二亚乙基三胺五乙酸、二亚乙基三胺五亚甲基膦酸、二乙烯三胺五乙酸五钠、次氨基三乙酸钠的任一或以上种的组合物料,所述组合物料,其可被配成掩蔽助剂水溶液:组合物料的总摩尔加入量在0.1~1.2mol/L范围,添加掩蔽助剂水溶液的量可控制在绝干亲水疏解纤维A 100重量份,加掩蔽助剂水溶液1至2重量份;或和再对最后产品添加常规量的普通防霉助剂。Introduce the "material to be finally squeezed dry" in the above step nine into the solid-liquid separator for solid/liquid separation; thereby obtaining the extruded material obtained by the "'third solid-liquid separation'" as described in the previous "step five". "Water out", and the final product - including the hydrophilic decomposable fiber A product of A-1 or/and A-2; or adding additives that mask iron/manganese ions to the final product: oxalic acid, sodium oxalate, potassium oxalate , ammonium oxalate, ethylenediaminetetraacetic acid, sodium ethylenediaminetetraacetate, tetraacetylethylenediamine, citric acid, sodium citrate, tartaric acid, sodium tartrate, gluconic acid, diethylenetriaminepentaacetic acid, diethyleneethylene A combination material of any one or more of triamine pentamethylene phosphonic acid, pentasodium diethylene triamine pentaacetate, and sodium nitrilotriacetate. The combination material can be formulated into an aqueous masking aid solution: Combination The total molar amount of materials added is in the range of 0.1~1.2mol/L. The amount of masking additive aqueous solution can be controlled at 100 parts by weight of absolutely dry hydrophilic decomposable fiber A, and 1 to 2 parts by weight of masking additive aqueous solution; or and then Add conventional amounts of common antifungal additives to the final product.
  5. 权利要求1所述产品集合中的“主产品A——亲水疏解纤维产品”和“副产品C——木素/树脂混合物产品”的联产制法,其特征至少包括:制A与C-1联产,可先经如下5-1或/和5-2步骤;或制A与C-2联产,可先经如下5-3或/和5-4或/和5-5步骤;最后都走5-6步骤而获实现:The co-production method of "main product A - hydrophilic decomposable fiber product" and "by-product C - lignin/resin mixture product" in the product set as claimed in claim 1, has at least the following features: making A and C- 1 co-production, you can first go through the following steps 5-1 or/and 5-2; or make A and C-2 co-production, you can go through the following steps 5-3 or/and 5-4 or/and 5-5 first; In the end, it was achieved by taking 5-6 steps:
    5-1.用新鲜的能源草之去根带叶的整株或剥除叶片的茎秆部料,用清水洗净,脱水、晾干,然后进榨汁机压榨,较佳的是控制压榨后的出渣含水量在20%(wt%)以下,压榨出之液体 既为权利要求2中ⅱ项所述的副产物料2——“先用水洗净后的鲜能源草再经压榨所获的鲜汁液”;或再将此“鲜汁液”加热至100~105℃保持3~5分钟,冷却、装罐即成液体状红茶色之食用或医用级的木素/树脂混合物产品C-1;若在加热的同时,再对“鲜汁液”施以蒸发提浓操作,则在控制蒸出水多少的操控工艺参数条件下,可使“鲜汁液”的被蒸浓料再在冷至室温时,可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的食用或医用级木素/树脂混合物产品C-1;5-1. Use fresh energy grass to remove the whole plant with roots and leaves or peel off the stem parts of the leaves, wash it with clean water, dehydrate and dry it, and then press it into a juicer. It is better to control the pressing. The moisture content of the final slag is below 20% (wt%), and the liquid squeezed out It is the by-product material 2 described in item ii of claim 2 - "fresh juice obtained from fresh energy grass washed with water and then squeezed"; or this "fresh juice" is heated to 100-105 Keep at ℃ for 3 to 5 minutes, cool and can the liquid black brown edible or medical grade lignin/resin mixture product C-1; if it is heated at the same time, the "fresh juice" is evaporated and concentrated. Operation, under the control of process parameters that control the amount of steamed water, the steamed concentrated material of "fresh juice" can be in the form of a tan paste-like colloid, or a coffee-colored powder or granules when cooled to room temperature. Or edible or medical grade lignin/resin mixture product C-1 in the form of rosin-like solid blocks;
    5-2.用经晒干或自然晾干或烘干的能源草之去根带叶的整株或剥除叶片的茎秆部,或是用能源草干料经破碎过筛脱除过28目筛细粉后的粗料,用清水洗净,可再加入干料重量的0.7至5.7倍范围的清水,加热到70℃乃至煮沸,然后进榨汁机压榨,较佳的是控制压榨后的出渣含水量在20%(wt%)以下,压榨出之液体既为权利要求2中ⅱ项所述的副产物料2——“干能源草经水洗净后再水煮、压榨所获的汁液”;或再将此“汁液”加热至100~105℃保持3~5分钟,冷却、装罐即成液体状红茶色之食用或医用级的木素/树脂混合物产品C-1;若在加热的同时,再对“汁液”施以蒸发提浓操作,则在控制蒸出水多少的操控工艺参数条件下,可使“汁液”被蒸浓料再在冷至室温时,可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的食用或医用级木素/树脂混合物产品C-1;5-2. Use the energy grass that has been sun-dried or naturally dried or oven-dried to remove the whole plant with roots and leaves or remove the stem part of the leaves, or use the dry energy grass material to remove 28% by crushing and screening After sieving the coarse material into fine powder, wash it with clean water. You can add water ranging from 0.7 to 5.7 times the weight of the dry material, heat it to 70°C or even boil it, and then press it into a juicer. It is better to control the amount of water after squeezing. The moisture content of the residue is below 20% (wt%), and the liquid squeezed out is the by-product material 2 described in item ii of claim 2 - "dry energy grass washed with water and then boiled and pressed." "Obtained juice"; or heat this "juice" to 100-105°C for 3-5 minutes, cool it, and can it into a liquid black brown edible or medical grade lignin/resin mixture product C-1; If the "juice" is subjected to an evaporation and concentration operation while heating, then under the control of process parameters that control the amount of steamed water, the "juice" can be evaporated and concentrated, and then when cooled to room temperature, it can be presented as noodles. Edible or medical grade lignin/resin mixture product C-1 in the form of paste-like brown colloid, or coffee-colored powder or granules, or rosin-like solid block;
    5-3.用新鲜的能源草湿料的去根带叶的整株或剥除叶片的茎秆部料,然后进榨汁机压榨,较佳的是控制压榨后的出渣含水量在20%(wt%)以下,压榨出之液体既为权利要求2中ⅱ项所述的副产物料2——“用鲜能源草”“经压榨所获的鲜汁液”;或再将“鲜汁液”加热至100~105℃保持3~5分钟,冷却、装罐即成液体状红茶色之饲用或工业级的木素/树脂混合物产品C-2;若在加热的同时,再对“鲜汁液”施以蒸发提浓操作,则在控制蒸出水多少的操控工艺参数条件下,可使“鲜汁液”的被蒸浓料再在冷至室温时,可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的饲用或工业级的木素/树脂混合物产品C-2;5-3. Use fresh energy grass wet material to remove the roots and leaves of the whole plant or remove the stem parts of the leaves, and then squeeze it into a juicer. It is better to control the moisture content of the residue after pressing to be 20 % (wt%) or less, the liquid squeezed out is the by-product material 2 described in item ii of claim 2 - "fresh energy grass" and "fresh juice obtained by pressing"; or the "fresh juice" "Heat to 100~105℃ and hold for 3~5 minutes, cool and can the liquid black brown feed or industrial grade lignin/resin mixture product C-2; if it is heated at the same time, then "fresh" "Juice" is subjected to an evaporation and concentration operation, and under the control of process parameters that control the amount of steamed water, the steamed and concentrated material of "fresh juice" can be in the form of a brown colloid like a pasta sauce when it is cooled to room temperature, or Feed or industrial grade lignin/resin mixture product C-2 in the form of brown powder or granules, or rosin-like solid blocks;
    5-4.用经晒干或自然晾干或烘干的能源草之去根带叶的整株或剥除叶片的茎秆部料,或是用能源草干料仅经破碎过筛脱除过28目筛细粉后的粗料,可加入干料重量的0.7至5.7倍的清水,加热到70℃乃至煮沸,然后进榨汁机压榨,较佳的是控制压榨后的出渣含水量在20%(wt%)以下,压榨出之液体既为权利要求2中ⅱ项所述的副产物料1——热水脱木素/树脂工序所排棕/黑液;或再将“棕/黑液”加热至100~105℃保持3~5分钟,冷却、装罐即成液体状红茶色之饲用或工业级的木素/树脂混合物产品C-2;若在加热的同时,再对“棕/黑液”施以蒸发提浓操作,则在控制蒸出水多少的操控工艺参数条件下,可使“棕/黑液”被蒸浓料再在冷至室温时,可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的饲用或工业级的木素/树脂混合物产品C-2;5-4. Use the whole plant with roots and leaves removed from the energy grass that has been sun-dried or naturally dried or oven-dried, or use the stem material with the leaves peeled off, or use the dry energy grass material only after crushing and screening. After passing through a 28-mesh sieve, the coarse material can be added with 0.7 to 5.7 times the weight of the dry material in water, heated to 70°C or even boiled, and then pressed in a juicer. It is better to control the moisture content of the residue after pressing. Below 20% (wt%), the liquid squeezed out is either the by-product material 1 described in item ii of claim 2 - brown/black liquor discharged from the hot water delignification/resin process; or the "brown liquor" /Black liquor" is heated to 100~105℃ for 3~5 minutes, cooled and canned to obtain a liquid black brown feed or industrial grade lignin/resin mixture product C-2; if it is heated at the same time, then The "brown/black liquor" is subjected to an evaporation and concentration operation, and under the control of process parameters that control the amount of steamed water, the "brown/black liquor" can be evaporated and concentrated, and then when cooled to room temperature, it can be turned into a pasta sauce The feed or industrial grade lignin/resin mixture product C-2 is in the form of brown colloid, or coffee-colored powder or granules, or rosin-like solid block;
    5-5.收集前述5-1或/和5-2项中所述“清水洗净”后脱除水,用此种水对牛粪作洗选,脱除过28目筛的杂质,撩获由水淘洗过筛后未过28筛的粗纤维,对其作煮沸处理,杀灭其中的纤维素分解酶,再对其做进榨汁机压榨,较佳的是控制压榨后的出渣含水量在20%(wt%)以下,压榨出之液体既为权利要求2中ⅱ项所述的副产物料1——热水脱木素/树脂工序所排棕/黑液;或再将“棕/黑液”加热至100~105℃保持3~5分钟,冷却、装罐即成液体状红茶色之饲用或工业级的木素/树脂混合物产品C-2;若在加热的同时,再对“棕/黑液”施以蒸发提浓操作,则在控制蒸出水多少的操控工艺参数条件下,可使“棕/黑液”被蒸浓料再在冷至室温时,可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的饲用或工业级的木素/树脂混合物产品C-2;对牛粪所做淘/洗处理后排出的淘/洗液,则至少可作耐肥耗水的巨菌草种植所用的直接浇灌用水; 5-5. Collect and remove the water after "washing with clean water" mentioned in item 5-1 or/and 5-2 above, use this water to wash the cow dung, remove impurities that pass through a 28-mesh sieve, and remove Obtain the crude fiber that has not passed 28 sieves after being washed with water, boil it to kill the cellulolytic enzymes in it, and then put it into a juicer for squeezing. It is better to control the output after squeezing. The moisture content of the slag is below 20% (wt%), and the liquid squeezed out is the by-product material 1 described in item ii of claim 2 - brown/black liquor discharged from the hot water delignification/resin process; or Heat the "brown/black liquor" to 100-105°C for 3-5 minutes, cool it, and can it to form a liquid black brown feed or industrial grade lignin/resin mixture product C-2; if it is heated At the same time, the "brown/black liquor" is subjected to an evaporation and concentration operation. Under the control process parameters of controlling the amount of steamed water, the "brown/black liquor" can be evaporated and concentrated and then cooled to room temperature. Feed or industrial grade lignin/resin mixture product C-2 in the form of a paste-like brown colloid, or coffee-colored powder or granules, or rosin-like solid block; it is discharged after washing/washing of cow dung If the washing/washing liquid is used, it can at least be used as direct irrigation water for planting the fertilizer-resistant and water-consuming giant Juniper grass;
    5-6.将前述5-1至5-5所述的“较佳的是控制压榨后的出渣含水量在20%(wt%)以下”之渣,可再用水泡化成含固25%的呈松散肉松状物料,筛取其中大小在过3目至不过28目筛孔范围的粒度分级或混合的细长状纤维束,既可获如权利要求4中步骤四所述的“初脱除纤维中水溶质的待处理亲水疏解纤维中间产物甲的潮料”,后续可再走权利要求4中第五至第十步骤的操作,最后就能获亲水疏解纤维产品A-1或A-2;对前述5-5中所述的“对牛粪作洗选”“由水淘洗过筛”所产生的含牛粪之水,既为权利要求2中ⅱ项所述的“副产物料3:淘/洗牛粪所产生的淘/洗液”,可被导送做权利要求1所述“辅助产品E——液态有机土壤改良剂”的配料之一。5-6. The slag mentioned in the above 5-1 to 5-5 "It is better to control the moisture content of the slag after pressing to be below 20% (wt%)" can be soaked into a solid content of 25%. The loose floss-like material is sifted out and the elongated fiber bundles with particle size classification or mixing ranging from 3 mesh to no more than 28 mesh can be obtained. "The moisture material of the hydrophilic decomposable fiber intermediate product A to be treated to remove the water solute in the fiber" can be followed by the fifth to tenth steps in claim 4, and finally the hydrophilic decomposable fiber product A-1 or A-2; The water containing cow dung produced by "washing cow dung" and "washing and sieving with water" described in the aforementioned 5-5 is the "water containing cow dung" described in item ii of claim 2 By-product material 3: "washing liquid produced by washing cow dung" can be directed to be one of the ingredients of the "auxiliary product E - liquid organic soil conditioner" described in claim 1.
  6. 权利要求1所述产品集合中的“B——木塑复合再生质粗粒产品”之制法,其特征在于如下6-1至6-6:The preparation method of "B - wood-plastic composite recycled coarse-grained product" in the product set of claim 1 is characterized by the following 6-1 to 6-6:
    6-1.备料:对权利要求5中5-1至5-5里的任一所述的“较佳的是控制压榨后的出渣含水量在20%(wt%)以下”之渣,做“木塑复合再生质粗粒”中的“木”备料;6-1. Material preparation: For the slag described in any one of 5-1 to 5-5 in claim 5, "It is better to control the moisture content of the slag after pressing to be below 20% (wt%)", Prepare the "wood" material in "Wood Plastic Composite Regenerated Coarse Grains";
    或/和用未经压榨处理的干能源草,仅经一次的破碎或切段粉碎后之风选或/和筛分,选出养分较少的物料做“木塑复合再生质粗粒”中的“木”备料,和剩余出的养分较多物料另做有机肥或/和饲料的备料;所述“养分较少的物料”,计量地讲,是将在经一次的破碎或切段粉碎后,能经受住机械破碎力而未被更细碎化的过3至不过28目筛范围的能源草粗纤维,和过150目筛的之能源草粉碎物中含土量较多的精细能源草纤维粉;所述“养分较多的物料”,计量地讲,就是在仅经一次的破碎或切段粉碎后,不能经受住机械破碎力而被更细碎化的过28至不过150目筛范围的含土量微的粒径居中的能源草纤维粉屑;Or/and use dry energy grass that has not been pressed, and only crush or cut into sections once, then winnow or/and screen, and select materials with less nutrients to make "Wood-Plastic Composite Regenerated Coarse Grain" The "wood" is prepared, and the remaining materials with more nutrients are used as organic fertilizer or/and feed materials; the "materials with less nutrients", in terms of measurement, are the materials that have been crushed or cut into pieces after one Finally, the crude energy grass fiber that can withstand the mechanical crushing force without being more finely divided and passes through a sieve ranging from 3 to 28 mesh, and the fine energy grass that has a higher soil content in the crushed energy grass that passes through a 150 mesh sieve. Fiber powder; the "materials with more nutrients", in terms of measurement, are materials that cannot withstand the mechanical crushing force and are more finely crushed after being crushed or cut into pieces once, and pass through a sieve ranging from 28 to no more than 150 mesh. Energy grass fiber powder with small soil content and medium particle size;
    对购入或/和免费收集来的废塑料原料,对其呈压缩打包态或/和其中杂有大块金属、砖块类固体的原料,则须先经破碎、风选,以开松物料和脱除其中的金属、砖块类硬质固体;将脱除了杂质的蓬松废塑料作为“木塑复合再生质粗粒”中的“塑”备料;Waste plastic raw materials purchased or/and collected for free, which are in a compressed and packaged state or/and which contain large pieces of metal or brick-like solids, must first be crushed and winnowed to loosen the materials. and remove hard solids such as metal and bricks; use the fluffy waste plastic with impurities removed as the "plastic" material in "wood-plastic composite recycled coarse particles";
    6-2.配料:按权利要求3中3-4或3-5所述“木塑复合再生质粗粒”的组成中“木”与“塑”和软化剂在产品总重量中的投料占比,秤重配料;6-2. Ingredients: According to the proportion of "wood", "plastic" and softener in the total weight of the product in the composition of the "wood-plastic composite regenerated coarse particles" described in 3-4 or 3-5 of claim 3. Ratio, weigh ingredients;
    6-3.造粒:将秤配好的料,经混合集料仓,再由机械输送,投于权利要求3中之3-7、3-8所述“粗粒造粒机”中成粒;所述“粗粒造粒机”所使用的机械是:具有连续式进/出料功能的饲料颗粒机、有机肥造粒机、生物质燃料颗粒机的任一种,或再在前述“颗粒机”/“造粒机”之后再串联螺旋切粒中碎机;前述的“颗粒机”/“造粒机”,出机物料呈过孔模所形成的段条粒状,如将前述“段条粒状”“物料”再经串联的螺旋切粒中碎机处理,则再出机物料就呈不规则颗粒;成粒时的物料被机械挤压/摩擦所发热升温,可用向物料或/和机械中的夹层中加水方式,来操控其出机物料不超过110℃;此操作所造成的“木塑复合再生质粗粒”,其质地呈可被人手指/掌直接拉/扳/捏/撕得碎的低强度;其成粒形状至少包括呈过孔模所形成的段条粒状或呈不规则颗粒;所述“孔模”的孔形,至少包括等边或不等边长的3至12边形的任一种,或圆形;所述“粒”的大小,在过25mm至不过2.0mm筛孔范围的任一孔径的分级或混合;6-3. Granulation: The materials prepared by the scale are passed through the mixing and collecting bin, then transported by machinery, and put into the "coarse granulator" described in claim 3-7 and 3-8. Granules; the machinery used in the "coarse granulator" is: any of the feed pellet machine, organic fertilizer granulator, biomass fuel pellet machine with continuous inlet/output function, or any of the above-mentioned The "granulator"/"granulator" is then connected in series with a spiral granulator and intermediate crusher; the aforementioned "granulator"/"granulator" discharges the material in the form of segmented granules formed by the through-hole die. For example, the aforementioned "granulator"/"granulator" The "segmented granular" "materials" are then processed by the spiral granulator in series, and then the materials come out of the machine as irregular particles; the materials during granulation are heated by mechanical extrusion/friction, and can be used to feed the materials or /The water is added to the interlayer in the machine to control the outgoing material to not exceed 110°C; the "coarse wood-plastic composite recycled material" produced by this operation has a texture that can be directly pulled/pulled by human fingers/palms/ Low strength when kneaded/torn into pieces; its granulated shape at least includes segmented granules or irregular particles formed by a through-hole mold; the hole shape of the "hole mold" includes at least equilateral or unequal side lengths Any one of 3 to 12 sides, or round; the size of the "grain" is classified or mixed in any aperture ranging from 25mm to less than 2.0mm mesh;
    6-4.均化混粒:若6-3项所获的“木塑复合再生质粗粒”在后续包装后有明显的包包不同质的质量瑕疵,则可在称重包装前加施混粒均化处理,所述的处理,既是用机械滚筒将5-3项所获的“木塑复合再生质粗粒”导入,滚翻混合匀即可;6-4. Homogenization and mixing: If the "wood-plastic composite recycled coarse particles" obtained in item 6-3 have obvious quality defects such as inhomogeneous packaging after subsequent packaging, they can be added before weighing and packaging. Mixing and homogenizing treatment, the above-mentioned treatment is to use a mechanical roller to introduce the "wood-plastic composite recycled coarse particles" obtained in item 5-3, and tumble and mix evenly;
    6-5.称重包装:将符合质量要求的6-3或/和6-4项所获的“木塑复合再生质粗粒”经称重后导入市场客户认可规格的包装袋中;6-5. Weighing and packaging: The "wood-plastic composite recycled coarse particles" obtained in items 6-3 or/and 6-4 that meet the quality requirements are weighed and introduced into packaging bags with specifications approved by market customers;
    6-6.入库质检:将包装好的产品按序入库,并按市场客户所需知的指标项,给出各批次 入库产品的质检报告作存档。6-6. Warehousing quality inspection: Put the packaged products into the warehouse in order, and give each batch according to the indicators that market customers need to know. Quality inspection reports of incoming products are archived.
  7. 权利要求1所述产品集合中的“辅助产品”D至I的制法,其特征在于7-1至7-6所述:The preparation method of "auxiliary products" D to I in the product set of claim 1 is characterized by the following: 7-1 to 7-6:
    7-1.权利要求1所述“辅助产品D——固态有机土壤改良剂产品”的制法,其特征至少在于:以能源草,或能源草和牛粪为起始主原料时,使用提取了制主产品A用原料后的余料,既过28目筛孔的能源草之粉料或和细牛粪沉渣,作为“辅助产品D”中的配料之一;7-1. The preparation method of "auxiliary product D - solid organic soil conditioner product" according to claim 1, which is at least characterized in that: when using energy grass, or energy grass and cow dung as the starting main raw materials, use extracted The remaining materials after making the main product A, including energy grass powder or fine cow dung sediment that has passed through a 28-mesh sieve, are used as one of the ingredients in "auxiliary product D";
    7-2.权利要求1所述“辅助产品E——液态有机土壤改良剂产品”的制法,,其特征至少在于:由能源草,或能源草和牛粪为起始主原料,在制备“主产品A——亲水疏解纤维产品”和“副产品C——木素/树脂混合物产品”时,由因提质产品A和C所排出的压榨液或/和洗涤液或/和淘洗液;再将“压榨液或/和洗涤液或/和淘洗液”按所被施农作物和地块的土质改良所需,经搀兑处理所获的液态有机土壤改良剂产品;所述“排出的压榨液或/和洗涤液或/和淘洗液”,其pH值皆不超出5.0~9.4范围,和其中所含Na+或/和K+或/和Mg2+的克摩尔与其所含水的升体积之比为≤0.034mol/L,或其中所含的可溶性钠盐、钾盐、镁盐的wt%总浓度≤0.20%(wt%),或其中所含的可溶性钠盐、钾盐、镁盐的总浓度与生产实施地所取水源中的可溶性钠盐、钾盐、镁盐的总浓度之差≤0.01%(wt%);辅助产品E与主产品A的重量之比被控制在产品E/产品A≤100/100~300/100范围,既≤100/100或≤300/100范围;7-2. The preparation method of "auxiliary product E - liquid organic soil conditioner product" according to claim 1, which is at least characterized in that: energy grass, or energy grass and cow dung are used as the starting main raw materials, and in the preparation of " When the main product A - hydrophilic decomposable fiber product" and "by-product C - lignin/resin mixture product", the pressing liquid or/and washing liquid or/and elutriation liquid discharged from the upgraded products A and C ; Then the liquid organic soil conditioner product obtained by blending the "pressed liquid or/and washing liquid or/and elutriation liquid" according to the soil improvement requirements of the crops and plots being applied; the "discharge" The press liquid or/and washing liquid or/and elutriation liquid”, the pH value does not exceed the range of 5.0 to 9.4, and the gram moles of Na + or/and K + or/and Mg 2+ contained therein are equal to those of the The liter volume ratio of water is ≤0.034mol/L, or the total wt% concentration of soluble sodium salts, potassium salts, and magnesium salts contained therein is ≤0.20% (wt%), or the soluble sodium salts, potassium salts contained therein are The difference between the total concentration of salt and magnesium salt and the total concentration of soluble sodium salt, potassium salt and magnesium salt in the water source taken from the production site is ≤0.01% (wt%); the weight ratio of auxiliary product E to main product A is Control within the range of product E/product A ≤ 100/100 ~ 300/100, that is, ≤ 100/100 or ≤ 300/100;
    7-3.权利要求1所述“辅助产品F——发酵饲料产品”的制法,其特征至少在于:将权利要求2中ⅱ项所述“副产物料1:热水脱木素/树脂工序所排棕/黑液”或/和“或副产物料2:压榨鲜能源草所获的鲜汁液会”掺于仅经破/粉碎的能源草后,再经发酵,既可获得辅助产品F;7-3. The preparation method of "auxiliary product F - fermented feed product" according to claim 1, which is at least characterized in that: the "by-product material 1: hot water delignification/resin" described in item ii in claim 2 The brown/black liquor discharged from the process" or/and" or by-product material 2: The fresh juice obtained by squeezing the fresh energy grass will be mixed with the energy grass that has only been broken/crushed, and then fermented to obtain auxiliary products F;
    7-4.权利要求1所述“辅助产品G——颗粒饲料产品”的制法,其特征至少在于:在以未经压榨处理的干能源草为起始主原料时,用筛取了主产品A用原料后的余料,既“过28目筛细粉”,或/和“过28至不过150目筛范围的含土量微的粒径居中的能源草纤维粉屑”,作为颗粒饲料产品中的配料组份;7-4. The preparation method of "auxiliary product G - pellet feed product" according to claim 1, which is at least characterized in that: when dry energy grass without pressing treatment is used as the starting main raw material, the main raw material is screened out. The remaining materials after using the raw materials for Product A are "fine powder passed through a 28 mesh sieve", or/and "energy grass fiber powder with a small soil content and a medium particle size passed through a 28 mesh to no more than 150 mesh sieve", as particles. Ingredients in feed products;
    7-5.权利要求1所述“辅助产品H——生物质颗粒燃料产品”的制法,其特征至少在于:以能源草被破碎、过筛脱除了未过28目筛之粗纤维的细粉料,或是全组份的能源草粉碎物,为配料组份,或再配加了废塑料的生物质颗粒燃料产品;所述“废塑料”,至少包括废农用塑膜、废泡沫塑料、废化纤织物或/和化纤棉絮的任一或多种的组合,所述的“配加”占辅助产品H之总重量的5%以下,或至可高不超22%;7-5. The preparation method of "auxiliary product H - biomass pellet fuel product" according to claim 1, which is at least characterized in that: the energy grass is crushed and sieved to remove fine fibers that have not passed the 28-mesh sieve. Powder, or a full-component energy grass crushing material, as an ingredient component, or a biomass pellet fuel product with waste plastics added; the "waste plastics" include at least waste agricultural plastic films and waste foam plastics , any one or more combinations of waste chemical fiber fabrics or/and chemical fiber wadding, the "addition" accounting for less than 5% of the total weight of the auxiliary product H, or up to no more than 22%;
    7-6.权利要求1所述“辅助产品I——食用菌种植棒/块产品”的制法,其特征至少在于:在以能源草,或能源草和牛粪为起始主原料时,用筛取了主产品A用原料后的余料,既过28目筛孔的能源草之粉料或和细牛粪沉渣,作为食用菌种植棒/块产品中的配料组份。7-6. The preparation method of "auxiliary product I - edible fungus planting stick/block product" according to claim 1, which is at least characterized in that: when using energy grass, or energy grass and cow dung as the starting main raw materials, use The remaining materials after sifting out the raw materials for the main product A, namely energy grass powder or fine cow manure sediment that has passed through a 28-mesh sieve, are used as ingredients in the edible fungus planting stick/block product.
  8. 权利要求4至7所述“制法”所用及的设备,其特征还在于如下8-1至8-4或和8-5所述:The equipment used in the "preparation method" described in claims 4 to 7 is also characterized by the following 8-1 to 8-4 or 8-5:
    8-1.实施权利要求4所述“步骤一”至“步骤十”,涉及设置组合机械Ⅰ至Ⅹ:8-1. Implementing "step one" to "step ten" described in claim 4 involves setting up combined machines I to X:
    对实施权利要求4所述“步骤一”的“预处理备料”用组合机械Ⅰ,其中至少包括:The combined machine I for implementing the "pretreatment and material preparation" of "Step 1" described in claim 4 at least includes:
    设置破碎机械1、锯/碾/切/锤的任一或多种组合碎化机2、风选机械3、机械筛4,以对能源草干捆扎料在经破碎机,锯/碾/切/锤的任一或多种组合碎化机处理,再经风选、筛分后,筛取出能源草碎化物料中的过3目至不过28目筛范围的任一目数的分级或混和粒径的细长状纤维束;或在机械筛4之后再设置膨化机械5,实现对已获脱杂净化和筛分后的细长状纤维束能源草碎化物,再施机械膨化处理;由此1、2、3、4、5的机械设置,实现对权 利要求4中步骤一的“预处理备料”之实现——获得可入步骤二再做加工的备用能源草碎化物;备用能源草碎化物Set up any or multiple combinations of crushing machinery 1, sawing/grinding/cutting/hammer crusher 2, air separation machinery 3, and mechanical screen 4 to crush the energy straw bundles and saw/grind/cut them. /hammer, and then through air selection and screening, screen out the classified or mixed particles of any mesh size from 3 mesh to 28 mesh in the energy grass crushed material. The elongated fiber bundles with a diameter of 100 mm or more; or a puffing machine 5 is installed after the mechanical screen 4 to realize the mechanical puffing treatment of the elongated fiber bundle energy grass crumbs that have been removed, purified and screened; thus Mechanical settings of 1, 2, 3, 4, and 5 to achieve right alignment Implementation of the "pre-treatment preparation" in step 1 of requirement 4 - obtaining backup energy grass crumbs that can be processed in step 2; backup energy grass crumbs
    对实施权利要求4所述“步骤二”的“第一次配料”用组合机械Ⅱ,其中至少包括:The combined machine II for implementing the "first batching" of "step two" in claim 4 at least includes:
    设置放置“备用能源草碎化物”的配料仓6,盛载后续步骤七所述“第二次固液分离”所获的挤出水之液槽7,或和设置存放“表面活性剂”的料仓8,设置称重计量衡器9,设置对“第一次配料”后的混合搅拌器10;由此6、7、8、9、10的机械设置,实现对权利要求4中步骤二的“第一次配料”之实现;Set up a batching warehouse 6 for placing "backup energy grass crumbs", a liquid tank 7 for holding the extruded water obtained from the "second solid-liquid separation" described in the subsequent step seven, or a tank for storing "surfactant" The silo 8 is equipped with a weighing scale 9 and a mixing agitator 10 after the "first batching"; thus, the mechanical settings of 6, 7, 8, 9, and 10 realize the second step in claim 4. The realization of “first batching”;
    对实施权利要求4所述“步骤三”的“加热溶出”用组合机械Ⅲ,其中至少包括:The combined machine III for implementing the "heating dissolution" of "step three" in claim 4 at least includes:
    设置设置搅拌混合和加热且保温的罐11;以此11的机械设置,实现对权利要求3中步骤三所述“‘备用能源草碎化物’料之自然绝干料:100重量份”、“后续步骤七所述‘第二次固液分离’所获的挤出水”:“2x重量份”,或和“‘挤出水’‘2x重量份’的0.1~0.3%重量份之‘表面活性剂’”,将这些物料置于一可被搅拌混合和加热且保温的罐11中,对物料实施均匀搅拌和加热至70℃以上,并保温滞留的操作;Set up a tank 11 for stirring, mixing, heating and insulation; with this mechanical arrangement of 11, the "natural dry material of 'standby energy grass crushed material' material: 100 parts by weight" and " The "extruded water obtained from the second solid-liquid separation" described in the subsequent step seven: "2x parts by weight", or the surface of 0.1 to 0.3% of the "extruded water" 2x parts by weight Active agent'", place these materials in a tank 11 that can be stirred, mixed, heated and insulated, and perform the operations of evenly stirring and heating the materials to above 70°C, and retaining them;
    对实施权利要求4所述“步骤四”的“第一次固液分离”用组合机械Ⅳ,其中至少包括:A combined machine IV is used to implement the "first solid-liquid separation" of "step four" in claim 4, which at least includes:
    设置输送机械12、螺杆或扎辊式挤浆机13,固液分离机14,存放“第一次固液分离”所获的“压/挤出棕/黑液”的储槽15;由此12、13、14、15的机械设置,实现将权利要求4中步骤四所述将“加热、保温操作后的物料导入螺杆或扎辊式挤浆机,对物料的纤维束作碾挤的机械揉化处理,然后再将物料导入固液分离机作固/液分离”,“或直接将上述加热、保温操作后的物料导入固液分离机作固/液分离”;Set up a conveying machine 12, a screw or roller squeezer 13, a solid-liquid separator 14, and a storage tank 15 to store the "pressed/extruded brown/black liquor" obtained from the "first solid-liquid separation"; thus The mechanical settings of 12, 13, 14, and 15 realize the introduction of the material after the heating and heat preservation operations described in step 4 of claim 4 into a screw or roller extruder, and crush the fiber bundles of the material. kneading treatment, and then introduce the material into the solid-liquid separator for solid/liquid separation", "or directly introduce the material after the above heating and heat preservation operations into the solid-liquid separator for solid/liquid separation";
    对实施权利要求4所述“步骤五”的“第二次配料”用组合机械Ⅴ,其中至少包括:The combined machine V for implementing the "second batching" of "step five" in claim 4 at least includes:
    设置放置“待处理亲水疏解纤维中间产物甲的潮料”的存料仓16,盛载后续步骤十所述“第三次固液分离”所获的挤出水之液槽17,或和设置存放“晶须助剂”的料仓18,设置称重计量衡器19,设置对“第二次配料”后的混合搅拌器20;由此16、17、18、19、20的机械设置实现对权利要求4中“步骤五”的机械化操作;Set up a storage bin 16 for placing the "moist material of the hydrophilic decomposable fiber intermediate product A to be processed", a liquid tank 17 containing the extruded water obtained from the "third solid-liquid separation" described in the subsequent step ten, or Set up a silo 18 for storing "whisker additives", set up a weighing scale 19, and set up a mixing agitator 20 for "second batching"; thus the mechanical settings of 16, 17, 18, 19, 20 are implemented The mechanized operation of "step five" in claim 4;
    对实施权利要求4所述“步骤六”的“碾磨消潜”用组合机械Ⅵ,其中至少包括:The combined machine VI for "grinding and eliminating latent" in "Step 6" described in claim 4 at least includes:
    设置高浓磨浆机21,在高浓磨浆机21的进料口之前设置待处理物料的储料仓22,在储料仓22与高浓磨浆机21之间,设置输送机构或输送机械23;在高浓磨浆机21的出料口之后,设置带保温或和加热功能的消潜罐24,在高浓磨浆机21的出料口与消潜罐24的进料口之间,设置输送机构或输送机械25;由此21、22、23、24、25的机械设置实现对权利要求4中“步骤六”的机械化操作;A high-consistency refiner 21 is provided. A storage bin 22 for materials to be processed is provided in front of the feed port of the high-consistency refiner 21. A conveyor mechanism or conveyor is provided between the storage bin 22 and the high-consistency refiner 21. Machinery 23; after the discharge port of the high-consistency refiner 21, a submersible tank 24 with a heat preservation or heating function is provided, between the discharge port of the high-consistency refiner 21 and the feed port of the submersible tank 24. time, a conveying mechanism or conveying machine 25 is provided; thus the mechanical arrangements of 21, 22, 23, 24, and 25 realize the mechanized operation of "step six" in claim 4;
    对实施权利要求4所述“步骤七”的“第二次固液分离”用组合机械Ⅶ,其中至少包括:The combined machine VII for implementing the "second solid-liquid separation" of "step seven" in claim 4 at least includes:
    设置输送机械26、螺杆或扎辊式挤浆机27,固液分离机28,存放权利要求3中步骤七所述“‘第二次固液分离’所获的挤出水”之储槽19;由此26、27、28的机械设置实现对权利要求4中“步骤七”的机械化操作;Conveying machinery 26, a screw or roller squeezer 27, a solid-liquid separator 28, and a storage tank 19 for storing the "extruded water obtained from the 'second solid-liquid separation'" described in step seven of claim 3 are provided. ;Thus, the mechanical settings of 26, 27, and 28 realize the mechanized operation of "step seven" in claim 4;
    对实施权利要求4所述对“步骤八”的“第三次配料”用组合机械Ⅷ,其中至少包括:The combined machine VIII for implementing the "third batching" of "Step 8" described in claim 4 at least includes:
    设置存放权利要求4中步骤七所述“待处理亲水疏解纤维中间产物乙的潮料”之储料仓29,计量存放新水和循环净化水的储槽30,存放晶须助剂的料仓31,称量衡器32,搅拌混合槽33;由此29、30、31、32、33的机械设置实现对权利要求4中“步骤八”的机械化操作;A storage bin 29 is provided for storing the "tidal material of the hydrophilic decomposable fiber intermediate product B to be processed" described in step seven of claim 4, a storage tank 30 for metering and storing new water and circulating purified water, and a material for storing whisker additives. Chamber 31, weighing scale 32, stirring and mixing tank 33; thus the mechanical arrangement of 29, 30, 31, 32, 33 realizes the mechanized operation of "step eight" in claim 4;
    对实施权利要求4所述对“步骤九”的“搅拌洗涤”用组合机械Ⅸ,其中至少包括: The combined machine IX for implementing the "stirring and washing" of "step nine" in claim 4 at least includes:
    在前述的“搅拌混合槽33”后设置输送机构或输送机械34、螺杆或扎辊式挤浆机35,物料暂储槽36;由此34、35、36的机械设置,实现权利要求4中步骤九所述工艺目的:将“‘第三次配料’导入螺杆或扎辊式挤浆机,对物料的纤维束再作碾挤的机械揉化处理,然后再将物料导入待最后挤干的物料暂储槽;或将上述‘第三次配料’直接导入搅拌机作搅拌,使新水与亲水疏解纤维中间产物乙的潮料固相纤维中本来所含的旧水,实现充分的混合,然后再将物料导入待最后挤干的物料暂储槽”;After the aforementioned "stirring and mixing tank 33", a conveying mechanism or conveying machine 34, a screw or roller squeezer 35, and a temporary material storage tank 36 are provided; thus, the mechanical arrangement of 34, 35, and 36 realizes the claim 4 The purpose of the process described in step 9: Introduce the "'third batching'" into the screw or roller squeezer, perform a mechanical kneading treatment on the fiber bundles of the material, and then introduce the material into the final drying process. Temporary material storage tank; or directly introduce the above 'third batching' into the mixer for stirring, so that the new water and the old water originally contained in the moisture solid phase fiber of the hydrophilic decomposable fiber intermediate product B can be fully mixed. Then the material is introduced into the temporary storage tank for the material to be finally squeezed dry";
    对实施权利要求4所述“步骤十”的“第三次固液分离或和最后修饰”用组合机械Ⅹ,其中至少包括:A combined machine X is used to implement the "third solid-liquid separation or final modification" of "step ten" in claim 4, which at least includes:
    设置输送机构或输送机械37、固液分离机38,设置存放掩蔽铁/锰离子助剂的料槽39、存放防霉助剂的料槽40;由此37、38、39、40的机械设置,实现权利要求3中步骤十所述工艺目的:得到如权利要求4中步骤五中所述的“‘第三次固液分离’所获的挤出水”,和最后产品——包括A-1或/和A-2之亲水疏解纤维A主产品;或和再做最后修饰,既减少产品的变色和被霉;Set up a conveying mechanism or conveying machinery 37, a solid-liquid separator 38, a trough 39 for storing iron/manganese ion masking additives, and a trough 40 for storing anti-mildew additives; thus the mechanical settings of 37, 38, 39, and 40 , to achieve the purpose of the process described in step ten in claim 3: to obtain the "extruded water obtained from the 'third solid-liquid separation'" as described in step five in claim 4, and the final product - including A- 1 or/and A-2 hydrophilic and decomposable fiber A as the main product; or and then make final modifications to reduce product discoloration and mildew;
    8-2.实施权利要求5所述“联产制法”所用及的设备,涉及设置组合机械Ⅺ至Ⅹ Ⅲ:8-2. Equipment used to implement the "joint production method" described in claim 5, involving the installation of combined machinery XI to XIII:
    对实施权利要求5中5-1、5-2所述“制A与C-1联产”所用组合机械Ⅺ,其中至少包括:The combined machinery XI used to implement the "co-production of A and C-1" described in 5-1 and 5-2 of claim 5 at least includes:
    针对权利要求5中5-1所述的具体制法,设置对新鲜的能源草作去根、剥除叶片的操作机械41,设置再对新鲜能源草做清水洗净、脱水、晾干用清洗机械42,设置做“水洗净后的鲜能源草”压榨取汁的压榨机43,设置储存压榨能源草鲜汁液的储料槽44,或再设置对鲜汁液做加热至沸或蒸发提浓的蒸馏釜45,设置冷却、装罐机械46;经此设置的41、42、43、44、45、46,实现从鲜能源草,经去根、除叶、水洗、脱水、压榨取汁,再加热灭菌、蒸发提浓、冷却、灌装,或直至加热蒸发至干的机械处理,获得可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的食用或医用级木素/树脂混合物副产品C-1;In view of the specific production method described in 5-1 of claim 5, an operating machine 41 is provided for removing the roots and leaves of the fresh energy grass, and a cleaning machine 41 is provided for washing, dehydrating and drying the fresh energy grass. The machine 42 is equipped with a press 43 for squeezing and extracting juice from "fresh energy grass washed with water", a storage tank 44 for storing the fresh juice of the squeezed energy grass, or a press 43 for heating the fresh juice to boiling or evaporation to thicken it. The distillation kettle 45 is equipped with cooling and canning machinery 46; through the 41, 42, 43, 44, 45, 46 set up here, it is possible to extract juice from fresh energy grass through root removal, leaf removal, water washing, dehydration, and squeezing. Reheating and sterilizing, evaporation and concentration, cooling, filling, or mechanical processing until heating and evaporation to dryness, to obtain edible food that can be in the form of a tan colloid in the form of pasta, or in the form of coffee-colored powder or granules, or in the form of rosin-like solid blocks. or medical grade lignin/resin mixture by-product C-1;
    和针对权利要求5中5-2所述的具体制法,设置对干能源草作去根、剥除叶片的操作机械47,或是设置对能源草干料做破碎、过筛的组合机械48,设置再对干能源草做清水洗净、脱水之清洗机械49,设置可再加水、加热至沸,然后做榨汁取榨的组合机械50,设置储存压榨能源草汁液的储料槽51,所述“能源草汁液”也既为实施例2中ⅱ项所述的副产物料2——“干能源草经水洗净后再水煮、压榨所获的汁液”;或再设置对“能源草汁液”做加热至沸或蒸发提浓的蒸馏釜52,设置冷却、装罐机械53;经此设置的47、48、49、50、51、52、53,实现从干能源草,经去根、除叶、破碎、过筛、水洗、脱水、热水浸渍、压榨取汁,再加热灭菌、蒸发提浓、冷却、灌装,或直至加热蒸发至干的机械处理,获得可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的食用或医用级木素/树脂混合物副产品C-1;And for the specific production method described in 5-2 of claim 5, an operating machine 47 is provided for removing roots and leaves of the dry energy grass, or a combined machine 48 is provided for crushing and screening the dry energy grass material. , set up a cleaning machine 49 for washing and dehydrating the dried energy grass, a combined machine 50 that can add water, heat it to boiling, and then extract the juice, and a storage tank 51 for storing the squeezed energy grass juice, The "energy grass juice" is also the by-product material 2 described in item ii of Example 2 - "the juice obtained by washing the dried energy grass with water and then boiling and pressing it"; or another set of "juice" "Energy Grass Juice" is used to make a distillation kettle 52 that is heated to boiling or evaporated to concentrate, and a cooling and canning machine 53 is set up; through the 47, 48, 49, 50, 51, 52, 53 set up here, the dry energy grass is realized. Root removal, leaf removal, crushing, sieving, washing, dehydration, hot water soaking, pressing to extract juice, then heat sterilization, evaporation and concentration, cooling, filling, or mechanical processing until it is heated and evaporated to dryness to obtain a form that can be presented. Edible or medical grade lignin/resin mixture by-product C-1 in the form of paste-like brown colloid, or coffee-colored powder or granules, or rosin-like solid block;
    对实施权利要求5中5-3至5-5所述“制A与C-2联产”所用组合机械Ⅻ,其中至少包括:The combined machinery XII used to implement the "co-production of A and C-2" described in 5-3 to 5-5 of claim 5, at least includes:
    针对权利要求5中5-3所述的具体制法,设置对新鲜的能源草作去根、剥除叶片的操作机械54,设置做新鲜能源草压榨取汁的压榨机55,设置储存压榨能源草鲜汁液的储料槽56,或再设置对鲜汁液做加热至沸或蒸发提浓的蒸馏釜57,设置冷却、装罐机械58;经此设置的54、55、56、57、58,实现从鲜能源草,经去根、除叶、压榨取汁,再加热灭菌、蒸发提浓、冷却、灌装,或直至加热蒸发至干的机械处理,获得可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的饲用或工业级的木素/树脂混合物产品C-2; In view of the specific production method described in 5-3 of claim 5, an operating machine 54 is provided for removing roots and leaves of fresh energy grass, a press 55 is provided for pressing and extracting juice from fresh energy grass, and a press energy storage device is provided. A storage tank 56 for the fresh juice is provided, or a distillation kettle 57 for heating the fresh juice to boiling or evaporation and concentration is provided, and a cooling and canning machine 58 is provided; through the 54, 55, 56, 57, 58 set up, Realize the mechanical treatment from fresh energy grass, through root removal, leaf removal, squeezing and juice extraction, then heat sterilization, evaporation and concentration, cooling, filling, or until heat and evaporation to dryness, to obtain a tan colloid that can be in the form of a paste. , or feed or industrial grade lignin/resin mixture product C-2 in the form of brown powder or granules, or rosin-like solid blocks;
    针对权利要求5中5-4所述的具体制法,设置对干能源草作去根、剥除叶片的操作机械59,或是设置对能源草干料做破碎、过筛的组合机械60,设置可再加水、加热至沸,然后做榨汁取榨的组合机械61,设置储存压榨能源草汁液的储料槽62,所述“能源草汁液”也既为权利要求2中ⅱ项所述的副产物料1——热水脱木素/树脂工序所排棕/黑液;或再设置对“能源草汁液”做加热至沸或蒸发提浓的蒸馏釜63,设置冷却、装罐机械64;经此设置的59、60、61、62、63、64,实现从干能源草,经去根、除叶、破碎、过筛、热水浸渍、压榨取汁,再加热灭菌、蒸发提浓、冷却、灌装,或直至加热蒸发至干的机械处理,获得可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的食用或医用级木素/树脂混合物副产品C-2;For the specific preparation method described in 5-4 of claim 5, an operating machine 59 for removing roots and blades of dry energy grass is provided, or a combined machine 60 for crushing and screening the dry energy grass material is provided. A combined machine 61 that can add water, heat it to boiling, and then extract juice is provided, and a storage tank 62 is provided that stores the squeezed energy grass juice. The "energy grass juice" is also described in item ii of claim 2. By-product material 1 - brown/black liquor discharged from the hot water delignification/resin process; or a distillation kettle 63 for heating the "energy grass juice" to boiling or evaporation and concentration, and cooling and canning machinery are installed. 64; Through the settings 59, 60, 61, 62, 63, and 64, it is possible to extract juice from dry energy grass by removing roots, removing leaves, crushing, sifting, soaking in hot water, pressing, and then heating, sterilizing, and evaporating Concentrate, cool, fill, or mechanically process until it is heated and evaporated to dryness to obtain edible or medical grade lignin that can be in the form of a paste-like brown colloid, or a coffee-colored powder or granule, or a rosin-like solid block/ Resin mixture by-product C-2;
    针对权利要求5中5-5所述的具体制法,设置储存来源于组合机械Ⅺ中对能源草的“清水洗净”后的脱除水之用的储存槽65,设置用储存槽65的流出水对牛粪作淘洗、筛选的组合机械66,设置可再加水、加热至沸,然后做榨汁取榨的组合机械67,设置储存压榨能源草汁液的储料槽68,所述“能源草汁液”也既为权利要求2中ⅱ项所述的副产物料1——热水脱木素/树脂工序所排棕/黑液;或再设置对“能源草汁液”做加热至沸或蒸发提浓的蒸馏釜69,设置冷却、装罐机械70;经此设置的65、66、67、68、69、70,实现对牛粪作淘洗、筛选、热水浸渍、压榨取汁,再加热灭菌、蒸发提浓、冷却、灌装,或直至加热蒸发至干的机械处理,获得可呈面酱状棕褐色胶体,或呈咖啡色粉体或颗粒,或松香状固体块状的食用或医用级木素/树脂混合物副产品C-2;For the specific preparation method described in 5-5 in claim 5, a storage tank 65 is provided for storing the dewatered water after "cleaning" the energy grass in the combined machine XI, and a storage tank 65 is provided. A combined machine 66 for washing and screening cow dung with outflow water, a combined machine 67 for adding water, heating to boiling, and then squeezing the juice, and a storage tank 68 for storing the squeezed energy grass juice, as described in " The "energy grass juice" is also the by-product material 1 described in claim 2 item ii - brown/black liquor discharged from the hot water delignification/resin process; or it is further configured to heat the "energy grass juice" to boiling Or the distillation kettle 69 for evaporation and concentration is equipped with cooling and canning machinery 70; through the 65, 66, 67, 68, 69, 70 set up here, the cow dung can be washed, screened, soaked in hot water, and squeezed to extract juice. , then heat and sterilize, evaporate and concentrate, cool, fill, or mechanically process until it is heated and evaporated to dryness to obtain a paste-like brown colloid, or a coffee-colored powder or granule, or a rosin-like solid block. Edible or medical grade lignin/resin mixture by-product C-2;
    对实施权利要求5中的5-6所述“后续可再走”、“后续可被导”细节所用组合机械Ⅹ Ⅲ,其中至少包括:The combined machinery XIII used to implement the details of "can be moved later" and "can be guided subsequently" described in 5-6 of claim 5, at least includes:
    设置分类收集仓71,分别收集由组合机械Ⅺ、Ⅻ导出的能源草或和牛粪经“压榨后的出渣”;设置将前述“压榨后的出渣”用水泡化成含固25%的呈松散肉松状物料之搅拌、加热的组合机械72;设置机械筛73,以筛取泡化料中大小在过3目至不过28目筛孔范围的粒度分级或混合的细长状纤维束;设置收集“过3目至不过28目筛孔范围的粒度分级或混合的细长状纤维束”的收集仓74;设置将收集仓74中的物料导送前述“组合机械Ⅴ”的“存料仓16”的输送机械75,以使物料以权利要求4中步骤四所述的“初脱除纤维中水溶质的待处理亲水疏解纤维中间产物甲的潮料”的归类,后续可再走权利要求4中第五至第十步骤的操作,最后就能获亲水疏解纤维产品A-1或A-2;设置收集槽76,收集权利要求5中5-5里所述的“对牛粪作洗选”“由水淘洗过筛”所产生的含牛粪之水,既为权利要求2中ⅱ项所述的“副产物料3:淘/洗牛粪所产生的淘/洗液”,后续可被导送做权利要求1所述“辅助产品E——液态有机土壤改良剂”的配料之一;Set up a classification collection bin 71 to collect the "pressed dregs" of energy grass or cow dung exported by the combined machines XI and A combined machine 72 for stirring and heating floss-like materials; a mechanical sieve 73 is set up to screen the elongated fiber bundles with particle size classification or mixing ranging from 3 mesh to no more than 28 mesh sieve holes in the foamed material; and is set up to collect A collection bin 74 for "elongated fiber bundles with particle sizes ranging from 3 mesh to no more than 28 mesh sieves or mixed"; a "storage bin 16" that guides the materials in the collection bin 74 to the aforementioned "combined machine V" is provided "Conveyor machinery 75, so that the material is classified into the "moist material from which the water solute in the fiber has been initially removed and the hydrophilic decomposed fiber intermediate product A to be treated" described in step 4 of claim 4, and can be followed by the right Through the operations of the fifth to tenth steps in claim 4, the hydrophilic decomposable fiber product A-1 or A-2 can finally be obtained; a collection tank 76 is provided to collect the "cow dung" described in 5-5 in claim 5. The water containing cow dung produced by "washing and sifting with water" is the "by-product material 3: washing/washing liquid produced by washing/washing cow dung" described in claim 2 item ii ”, which can subsequently be directed to be one of the ingredients of the “auxiliary product E—liquid organic soil conditioner” described in claim 1;
    8-3.执行权利要求6所述“B”之“制法”所用及的设备,涉及设置子组合机械Ⅹ Ⅳ至Ⅹ Ⅶ,其中包括:8-3. The equipment used to implement the "preparation method" of "B" described in claim 6 involves setting up sub-assembly machines XIV to XVII, including:
    设置权利要求6中6-1的“备料”子组合装置Ⅹ Ⅳ,其中又包括:机械筛77,或再加破碎机械78、风选机械79;Set up the "material preparation" sub-assembly device XIV of 6-1 in claim 6, which further includes: a mechanical screen 77, or a crushing machine 78 and a winnowing machine 79;
    设置实施权利要求6中6-2的“配料”子组合装置Ⅹ Ⅴ,其中又包括:称重衡器80、分别存放所述“木塑复合再生质粗粒”组成中“木”与“塑”和软化剂的储料仓81,和计量配料后的混合槽82;Set up and implement the "ingredients" sub-assembly device ⅩⅤ of 6-2 in claim 6, which further includes: a weighing scale 80, respectively storing "wood" and "plastic" in the composition of the "wood-plastic composite recycled material coarse particles" And the storage bin 81 of the softener, and the mixing tank 82 after metering and batching;
    设置实施权利要求6中6-3的“造粒”子组合装置Ⅹ Ⅵ,其中又包括:输送机械83、粗粒造粒机84;Set up and implement the "granulation" sub-combination device XVI of 6-3 in claim 6, which further includes: a conveying machine 83 and a coarse granulator 84;
    设置实施权利要求6中6-4至6-5的“均化混粒”、“称重包装”子组合装置Ⅹ Ⅶ其中 又包括:均化混粒机85、称重包装机械86;Set up and implement the "homogenizing mixing" and "weighing packaging" sub-assembly device Ⅹ Ⅶ of 6-4 to 6-5 in claim 6, wherein Also includes: homogenizing mixer 85, weighing and packaging machinery 86;
    8-4.执行权利要求7所述“辅助产品”之“制法”所用及的设备,涉及设置子组合机械Ⅹ Ⅷ至Ⅱ Ⅲ,其中包括:8-4. The equipment used to implement the "manufacturing method" of the "auxiliary product" described in claim 7 involves setting up sub-assembly machines XVIII to IIIII, including:
    设置实施权利要求7中7-1“辅助产品D——固态有机土壤改良剂”制法所用子组合装置Ⅹ Ⅷ,其特征在于:包含一套制备固态有机土壤改良剂的组合装置87;以实现将“能源草,或能源草和牛粪”为起始主原料时,在使用提取了制主产品A用原料后的余料,既过28目筛孔的能源草之粉料或和细牛粪沉渣,作为“辅助产品D”中的配料之工艺目的;Set up and implement the sub-assembly device XVIII used in the preparation method of 7-1 "auxiliary product D - solid organic soil conditioner" in claim 7, which is characterized in that: it includes a set of assembly devices 87 for preparing solid organic soil conditioner; to realize When "energy grass, or energy grass and cow dung" is used as the starting main raw material, the remaining material after extracting the raw materials for making the main product A is used, that is, energy grass powder or fine cow dung that has passed through a 28-mesh sieve. Sediment, used as an ingredient in "auxiliary product D" for process purposes;
    设置实施权利要求7中7-2“辅助产品E——液态有机土壤改良剂”制法所用子组合装置Ⅹ Ⅸ,其特征在于:包含一套制备液态有机土壤改良剂产品的组合装置88;以实现将权利要求2中ⅱ项所述“副产物料1”或/和“副产物料3”,作为“辅助产品E”中的配料之工艺目的;Set up and implement the sub-assembly device XIX used in the preparation method of 7-2 "auxiliary product E - liquid organic soil conditioner" in claim 7, which is characterized in that: it includes a set of assembly devices 88 for preparing liquid organic soil conditioner products; To achieve the technological purpose of using "by-product material 1" or/and "by-product material 3" described in item ii of claim 2 as ingredients in "auxiliary product E";
    设置实施权利要求7中7-3“辅助产品F——发酵饲料”制法所用子组合装置Ⅱ Ⅹ,其特征在于:包含一套制备发酵饲料产品的组合装置89;以实现将权利要求2中ⅱ项所述“副产物料1”或/和“或副产物料2”,掺于仅经破/粉碎的能源草中再经发酵制获辅助产品F的工艺目的;Set up and implement the sub-assembly device Ⅱ The purpose of the process of adding "by-product material 1" or/and "or by-product material 2" mentioned in item ii to energy grass that has only been broken/pulverized and then fermenting it to obtain auxiliary product F;
    设置实施权利要求7中7-4“辅助产品G——颗粒饲料”制法所用子组合装置Ⅱ Ⅰ,其特征在于:包含一套制备颗粒饲料产品的组合装置90;以实现将用筛取了主产品A用原料后的余料,既“过28目筛细粉”,或/和“过28至不过150目筛范围的含土量微的粒径居中的能源草纤维粉屑”,作为颗粒饲料产品中的配料组份之工艺目的;Set up and implement the sub-assembly device Ⅱ Ⅰ used in the preparation method of 7-4 "auxiliary product G - pellet feed" in claim 7, which is characterized in that: it includes a set of assembly devices 90 for preparing pellet feed products; to achieve the purpose of screening out the pellet feed products The remaining materials after using the raw materials for the main product A are "fine powder passed through a 28 mesh sieve", or/and "energy grass fiber powder with a small soil content and a medium particle size passed through a 28 to less than 150 mesh sieve", as The technological purpose of the ingredients in pellet feed products;
    设置实施权利要求7中7-5“辅助产品H——生物质颗粒燃料”制法所用子组合装置Ⅱ Ⅱ,其特征在于:包含一套制备生物质颗粒燃料产品的组合装置91;以实现将“以能源草被破碎、过筛脱除了未过28目筛之粗纤维的细粉料,或是全组份的能源草粉碎物,为配料组份,或再配加了废塑料”制生物质颗粒燃料产品的工艺目的;Set up the sub-assembly device II II used to implement the 7-5 "auxiliary product H - biomass pellet fuel" preparation method in claim 7, which is characterized in that: it includes a set of assembly devices 91 for preparing biomass pellet fuel products; to realize the "The energy grass is crushed and sieved to remove the fine powder that has not passed the 28-mesh sieve, or the full-component energy grass crushing material is used as the ingredient, or waste plastic is added." The technological purpose of the material pellet fuel product;
    设置实施权利要求7中7-6“辅助产品I——食用菌种植棒/块”制法所用子组合装置Ⅱ Ⅲ,其特征在于:包含一套制备食用菌种植棒/块产品的组合装置92;以实现将“以能源草,或能源草和牛粪为起始主原料时,用筛取了主产品A用原料后的余料,既过28目筛孔的能源草之粉料或和细牛粪沉渣,作为食用菌种植棒/块产品中的配料组份”的工艺目的;Set up and implement the sub-assembly device II III used in the preparation method of 7-6 "auxiliary product I - edible fungus planting stick/block" in claim 7, which is characterized in that: it includes a set of assembly devices 92 for preparing edible fungus planting stick/block products ; In order to realize "using energy grass, or energy grass and cow dung as the starting main raw materials, the remaining material after sifting out the raw materials for the main product A, that is, the powder or fine energy grass that has passed through a 28-mesh sieve. The purpose of the process is to use cow dung sediment as an ingredient in edible fungus planting sticks/block products;
    8-5.或和可将如前8-1至8-4中所述1至88的各单元机械,规整设置入标准集装箱中。8-5. Alternatively, each unit of machinery from 1 to 88 as described in 8-1 to 8-4 above can be arranged neatly into a standard container.
  9. 权利要求1至8所述“产品”或/和“制法”或/和“设备”的用途,至少包括如下所述的任一或多种的组合:The uses of the "product" or/and "preparation method" or/and "equipment" described in claims 1 to 8 at least include any one or a combination of more of the following:
    9-1.权利要求1、2所述“主产品A——亲水疏解纤维”,其用途至少可被用作制备育秧纸、瓦楞纸、纸板,或/和包括蛋托、方便餐盘/碗、纸质育苗盆/钵在内的纸模塑制品中作部分或全部地替代废纸再生纸浆的一种替代材料;也可作为做进一步深加工,如制漂白纸浆的新起始原料;或是作为制备纤维素醚的原料;9-1. "Main product A - hydrophilic decomposable fiber" described in claims 1 and 2, its use can be used at least to prepare rice seedling paper, corrugated paper, cardboard, or/and include egg trays, convenient dinner plates/bowls It can be used as an alternative material to partially or completely replace waste paper recycled pulp in paper molded products including paper seedling pots/bowls; it can also be used as a new starting material for further processing, such as making bleached pulp; or As a raw material for preparing cellulose ether;
    9-2.权利要求1、3所述“副产品B——木塑复合再生质粗粒”,其用途至少可被用作热挤出木塑制品用木塑颗粒的待改性或/和精制的原料,或是直接用作热挤出木塑制品的一种新剂型原料,也可作为一种供热用的颗粒质燃料;9-2. The "by-product B - wood-plastic composite recycled coarse particles" described in claims 1 and 3 can be used at least as wood plastic particles to be modified or/and refined for hot extrusion of wood-plastic products. raw material, or directly used as a new formulation raw material for hot extrusion wood plastic products, or as a granular fuel for heating;
    9-3.权利要求1所述“副产品C-1——食用或医用级的木素/树脂混合物”,其用途至少可被用作制备饮料或/和中药制剂的原料;9-3. The "by-product C-1 - edible or medical grade lignin/resin mixture" described in claim 1 can be used at least as a raw material for preparing beverages or/and traditional Chinese medicine preparations;
    9-4.权利要求1所述“副产品C-2——饲用或工业级的木素/树脂混合物”,其用途至少可被用作制备饲料原料,或/和混凝土的减水剂、橡胶/塑料中的软化剂的任一种; 9-4. The "by-product C-2 - feed or industrial grade lignin/resin mixture" described in claim 1 can be used at least as a feed raw material, or/and as a water-reducing agent for concrete and rubber. /Any kind of softener in plastics;
    9-5.权利要求1至8所述“产品”、“制法”、“设备”,至少可被用于对包括巨菌草等在内的权利要求2中ⅰ项里所述“原料”的加工;或被扩展地应用于对竹子、甘蔗皮、棕榈油果串枝杈的加工;9-5. The "products", "preparation methods" and "equipment" described in claims 1 to 8 can be used at least for the "raw materials" described in item i of claim 2, including Giant Juncao, etc. Processing; or be expanded to the processing of bamboo, sugar cane bark, palm oil fruit bunch branches;
    9-6.权利要求1至8所述“产品”、“制法”、“设备”,皆可成为独立的商品。9-6. The "products", "production methods" and "equipment" described in claims 1 to 8 can all become independent commodities.
  10. 权利要求1至9的任一或多项所述的“产品”或/和“制法”的商业运作模式,至少包括如下所述的任一或多种的组合:The business operation model of the “product” or/and “process” described in any one or more of claims 1 to 9 at least includes any one or a combination of the following:
    10-1.可由一家企业独立地实施“产品”或/和“制法”的商业运营;10-1. One enterprise can independently implement the commercial operation of "products" or/and "manufacturing methods";
    10-2.可由多家企业分割“产品”品种,或/和分段“制法”过程来协同地实施商业运营;10-2. Multiple companies can divide "product" varieties, or/and segment "manufacturing" processes to collaboratively implement commercial operations;
    10-3.可用自营或外发代工的商业模式实施“产品”或/和“制法”的商业运营;10-3. The business model of self-operated or outsourced manufacturing can be used to implement the commercial operation of "products" or/and "manufacturing methods";
    10-4.所述的商业运营,其中使用包括固/液态有机土壤改良剂在内的涉农产品,与农户或农耕经营者易货包括粮棉油大田之秸秆在内的能源草。 10-4. The described commercial operations, which use agricultural products including solid/liquid organic soil conditioners, and barter with farmers or farming operators for energy grass including straw from grain, cotton and oil fields.
PCT/CN2023/097506 2021-06-04 2023-05-31 Clean product set prepared by using energy grass as raw material, and preparation method therefor WO2023232087A1 (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101532260A (en) * 2009-04-17 2009-09-16 华南理工大学 Method for pulping by cooking solid base in plant fiber
CN103523945A (en) * 2012-07-04 2014-01-22 上海橡本永拓环保科技发展有限公司 Clean production method of plant fiber product
CN109418006A (en) * 2017-08-30 2019-03-05 陈汇宏 The stalk that easily collection coarse crushing just shunts again as many as deep system advantage comprehensively utilizes mode
CN115431432A (en) * 2021-06-04 2022-12-06 唐禹豪 Clean product collection using energy grass as raw material and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101532260A (en) * 2009-04-17 2009-09-16 华南理工大学 Method for pulping by cooking solid base in plant fiber
CN103523945A (en) * 2012-07-04 2014-01-22 上海橡本永拓环保科技发展有限公司 Clean production method of plant fiber product
CN109418006A (en) * 2017-08-30 2019-03-05 陈汇宏 The stalk that easily collection coarse crushing just shunts again as many as deep system advantage comprehensively utilizes mode
CN115431432A (en) * 2021-06-04 2022-12-06 唐禹豪 Clean product collection using energy grass as raw material and preparation method thereof

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