WO2023213987A1 - Alliage maître d'alsimgx et utilisation de l'alliage maître dans la production d'un alliage d'aluminium - Google Patents

Alliage maître d'alsimgx et utilisation de l'alliage maître dans la production d'un alliage d'aluminium Download PDF

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WO2023213987A1
WO2023213987A1 PCT/EP2023/061884 EP2023061884W WO2023213987A1 WO 2023213987 A1 WO2023213987 A1 WO 2023213987A1 EP 2023061884 W EP2023061884 W EP 2023061884W WO 2023213987 A1 WO2023213987 A1 WO 2023213987A1
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alloy
aisimgx
master alloy
master
content
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PCT/EP2023/061884
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English (en)
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Leonhard Heusler
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Norsk Hydro Asa
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • C22C21/02—Alloys based on aluminium with silicon as the next major constituent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D21/00—Casting non-ferrous metals or metallic compounds so far as their metallurgical properties are of importance for the casting procedure; Selection of compositions therefor
    • B22D21/02—Casting exceedingly oxidisable non-ferrous metals, e.g. in inert atmosphere
    • B22D21/04—Casting aluminium or magnesium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/02—Making non-ferrous alloys by melting
    • C22C1/026—Alloys based on aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/02—Making non-ferrous alloys by melting
    • C22C1/03—Making non-ferrous alloys by melting using master alloys
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • C22C21/02—Alloys based on aluminium with silicon as the next major constituent
    • C22C21/04—Modified aluminium-silicon alloys

Definitions

  • the invention relates to a master alloy for increasing the Magnesium content of aluminium alloy melts, especially aluminium foundry alloy melts.
  • the invention also relates to a process for preparing a target aluminium alloy by increasing the Mg content of aluminium foundry alloys, and the use of the master alloy for increasing the Mg content of aluminium foundry alloys.
  • the aluminium foundry alloys used for shape-casting are based on Si and Mg as major alloying elements.
  • Si gives an alloy good castability, and together with Mg it enables precipitation hardening.
  • the AISi7Mg-type of alloys listed e.g. as EN AC-AISi7Mg0.3 in the European Standard EN1706 with a Mg-range of 0.25-0.45 wt%, is by far the most used primary foundry alloys worldwide, while variants with higher Mg content (up to 0.7 wt%) or with some copper addition (up to 1 wt%) are also commonly used.
  • AISiMnMg alloys with a Si content from 7 to 10 wt% and a Mg-content up to 0.6 wt% have become very popular.
  • the present invention provides a solution that alleviates at least some or all of the problems associated with the traditional methods for increasing the Mg content in aluminium alloys.
  • the present invention solves, or at least alleviates the problems associated with the traditional methods for increasing the Mg content in aluminium alloys, by providing an AISiMgX master alloy for use in preparing aluminium-silicon based foundry alloys comprising Mg.
  • the present invention also provides a method for preparing an aluminium target alloy by use of said AISiMgX master alloy.
  • base alloy means an initial aluminium-based alloy prepared according to common methods in a melting furnace after melting of input material such as ingots, pre-alloyed ingots, master alloys, alloying elements, process scrap, feeders, chips etc.
  • the term “master alloy” means an aluminium alloy rich in certain alloying elements to be added to a base alloy in order to achieve/prepare a target aluminium alloy composition.
  • the AISiMgX master alloy is rich in Mg, while the other alloying elements essentially corresponds with the aluminium base alloy, and hence the aluminium target alloy.
  • target alloy means an aluminium alloy achieved after adding the alloying elements, e.g. by using a master alloy, to the base aluminium alloy to achieve a target composition of the aluminium alloy.
  • target aluminium alloy should be understood to denote an aluminium base alloy to which the AISiMgX master alloy has been added resulting in an increase of the Mg concentration in the target aluminium alloy, compared with the aluminium base alloy
  • the term "alloying element” means any purposeful addition of an element to a base metal, in this disclosure aluminium, for the purpose of improving its processability or modifying the mechanical, corrosion, electrical or thermal characteristics through modification of the metallurgical structure of the base metal.
  • the term does not include incidental impurities, unless expressively stated differently.
  • the present invention provides, according to a first aspect, an AISiMgX master alloy for increasing the content of Mg in an aluminium base alloy in the preparation of a target aluminium alloy (the term “content of Mg” may also be referred to as “concentration of Mg” herein).
  • the aluminium base alloy may be an AISiMg alloy.
  • the aluminium base alloy is an AISiMg alloy having a composition essentially corresponding to the AISiMgX master alloy, except for the Mg concentration which is generally lower in the aluminium base alloy compared with the AISiMgX master alloy.
  • the target aluminium alloy may be an AISiMg alloy. It is preferred that the aluminium target alloy is an AISiMg alloy having a composition essentially corresponding to the AISiMgX master alloy and the aluminium base alloy, except for the Mg concentration which is generally lower compared with the AISiMgX master alloy but higher compared with the aluminium base alloy.
  • the AISiMgX master alloy has the following composition: Mg 1 .3-6.5 wt%, Si 6.5-11.5 wt%, Cu 0-1 .0 wt%, Mn 0-1 .0 wt%, Fe ⁇ 0.40 wt%, Ti ⁇ 0.18 wt%, Sr ⁇ 0.10 wt%, and the rest being Al and incidental impurities.
  • the respective concentrations of the alloying elements selected from the group comprising Si, Cu, Mn, Fe, Ti and Sr in the AISiMgX master alloy should correspond to the concentrations of the same alloying elements in the aluminium base alloy to which the AISiMgX master alloy is to be added, while the Mg content in the AISiMgX master alloy can be significantly higher than the said aluminium base alloy.
  • the present AISiMgX master alloy gives a predictable yield in the aluminium target alloy prepared by usage of the AISiMgX master alloy, it does not deteriorate the melt quality, and it does not change the overall chemical composition by diluting effects. Any burn-off of Mg can be adjusted in a reliable and consistent way by addition of an appropriate amount of an AISiMgX master alloy having an appropriate base composition.
  • the content of Mg in the AISiMgX master alloy is from 1 .3 to 6.5 wt%.
  • the content of Mg in the AISiMgX master alloy may suitably be from 1 .3 to 5.5 wt%; such as from 1 .3 to 2.5 wt%; 1 .5 to 2.5 wt%; 1 .5 to 2.0 wt%; 2.0 to 3.0 wt%; 2.5 to 3.5 wt%; 3.4 to 4.0 wt%; 4.0 to 5.5 wt%; 4.5 to 5.5 wt%, or from 4.0 to 4.6 wt%.
  • the alternative concentration ranges of Mg in the AISiMgX master alloy allows preparation of different AISiMgX master alloy compositions which may be tailored for desired increase of Mg content in different target aluminium alloys, compared with the base aluminium alloy.
  • the content of Si in the AISiMgX master alloy is between 6.5 and 11 .5 wt%.
  • the content of Si in the AISiMgX master alloy may be from 6.5 to 7.5 wt%, or from 9 to 11 .5 wt%.
  • the said Si ranges are used in many aluminium foundry alloys based on Si and Mg as major alloying elements. Therefore, AISiMgX master alloys comprising Si in the said ranges are especially suitable for adjusting the Mg content of such AISiMg foundry alloys.
  • the content of Si in the AISiMgX master alloy is from 6.5 to 11 .5 wt%
  • the content of Mn is from 0.4 to 0.8 wt%.
  • the content of Si in the AISiMgX master alloy is from 6.5 to 8.5 wt%, and the content of Mn is from 0.4 to 0.8 wt%. In a further example, the content of Si in the AISiMgX master alloy is from 9.0 to 11 .5 wt%, and the content of Mn is from 0.4 to 0.8 wt%.
  • the AISiMgX master alloys comprising Si and Mn are especially suitable for adjusting the Mg content of AISiMnMg foundry alloys.
  • the content of Si is from 6.5 to 7.5 wt% and the content of Cu is from 0.2 to 0.7 wt%.
  • the AISiMgX master alloys comprising Si and Cu are especially suitable for adjusting the Mg content of AISiCuMg foundry alloys.
  • the content of Fe in the AISiMgX master alloy is up to 0.40 wt%. In an alternative embodiment, the amount of Fe in the AISiMgX master alloy may be 0.15 wt% or less. The content of Ti in the AISiMgX master alloy is up to 0.18 wt%, In an alternative embodiment, the amount of Ti in the AISiMgX master alloy may be from 0.05 to 0.15 wt%. The content of Sr in the AISiMgX master alloy is up to 0.10 wt%. In an alternative embodiment, the amount of Sr in the AISiMgX master alloy may be from 0.02 to 0.04 wt%.
  • the AISiMgX master alloy may be based on 3xx alloys (according to the nomenclature of the Aluminium Association designation system), EN AC-42xxx alloys (AISi7Mg), EN AC-43500 alloys (AISi MnMg), or EN AC-45500 alloys (AISi7CuO.5Mg) (according to European Standard EN1706 and/or EN 1676), wherein the AISiMgX master alloy has a higher Mg concentration compared to the said standard alloys, the Mg content being within 1 .3 to 6.5 wt%, such as 1 .3 to 5.5 wt%, or 1 .3 to 2.5 wt%, or 1 .5 to 2.5 wt%, or 1 .5 to 2.0 wt%, or 2.0 to 3.0 wt%, or 2.5 to 3.5 wt%, or 3.4 to 4.0 wt%, or 4.0 to 5.5 wt%, or 4.5 to 5.5 wt%, or 4.0 to
  • the said standard casting alloys represent common foundry alloys.
  • AISiMgX master alloys based on such standard casting alloys but having an increased amount of Mg compared with the standard composition, can be tailormade for the standard foundry alloys and for specific increase of the concentration of Mg without changing the overall chemistry of the alloy.
  • the AISiMgX master alloy may be in the form of an ingot, rod, wire, pellet, briquet, foil, waffle, button, rod, powder or splatter.
  • the AISiMgX master alloy is in the form of an ingot.
  • An AISiMgX master alloy ingot may have a weight of 6.5, 7.5 or 9.2 kg, or other standard ingot weight used in the aluminium smelting industry.
  • the present disclosure provides a method for adjusting the concentration of Mg in an aluminium base alloy in the preparation of an aluminium target alloy, the method comprises
  • the concentration of any other alloying elements chosen from the group comprising Si, Cu, Mn, Fe, Ti, Sr in the aluminium target alloy are essentially unchanged compared with the aluminium base alloy after addition of the AISiMgX master alloy.
  • the term “essentially” should in this context and in the present disclosure be understood as the concentration of the said alloying elements are not changed in an amount that would alter the characteristics of the aluminium target alloy, as the modification of the aluminium target alloy is based on the adjustment of the Mg concentration.
  • the AISiMgX master alloy may be added to a melting furnace, prior to, during, or after melting the aluminium base alloy.
  • the AISiMgX master alloy may be added to a transport crucible, prior to, during, or after being filled with molten aluminium base alloy.
  • the AISiMgX master alloy may be added to a holding or casting furnace, prior to, during, or after pouring in aluminium base alloy.
  • the AISiMgX master alloy may be added to a continuously melting furnace, wherein the AISiMgX master alloy may be periodically fed to the furnace to compensate for Mg-loss.
  • the AISiMgX master alloy may be added in the form of an ingot, rod, wire, pellet, briquet, foil, waffle, button, rod, powder or splatter.
  • the present disclosure provides a method for preparing the AISiMgX master alloy according to the present disclosure, the method comprising: providing an aluminium base alloy in solid or molten state; if necessary determining the concentration, in weight percent, of each alloying element in the aluminium base alloy; estimating and adding an appropriate amount of Mg into the aluminium base alloy to obtain a desired concentration of Mg in the AISiMgX master alloy, and casting the molten AISiMgX master alloy.
  • the aluminium base alloy, on which the AISiMgX master alloy is based may be chosen from a 3xx alloy (according to the nomenclature of the Aluminium Association designation system), EN AC-42xxx, EN AC-43500 (AISi MnMg) or EN AC-45500 (AISi7CuO.5Mg) alloy (according to European Standard EN1706 and/or EN 1676).
  • the method for preparing the AISiMgX master alloy may comprise adjusting the amount of any other alloying elements selected from the group consisting of Si, Cu, Fe, Mn, Ti and Sr by adding an appropriate amount of the alloying element(s) to the aluminium base alloy to obtain the desired composition of the AISiMgX master alloy.
  • the method comprises casting the AISiMgX master alloy into an ingot, rod, wire, pellet, or briquet.
  • the cast AISiMgX master alloy may be further processed to be in the form of a foil, waffle, button, rod, wire, powder or splatter.
  • the present disclosure further provides the use of the AISiMgX master alloy according to the present disclosure, wherein the AISiMgX master alloy is added to an aluminium base alloy to increase the content of Mg in the aluminium base alloy while keeping the concentration of any other alloying elements in the aluminium base alloy essentially unchanged.
  • Fig. 1 illustrates the mechanical properties of AISi7 in T6 temper as a function of the Mg-content.
  • the present disclosure relates to an AISiMgX master alloy especially suitable for increasing the Mg content of aluminium foundry alloy melts.
  • the AISiMgX master alloys according to the present disclosure is therefore especially suitable for usage in a process for preparing target aluminium alloys.
  • the AISiMgX master alloy contains overall the same alloying elements and essentially in the same concentrations that are desired in the target aluminium alloy, except for a higher content of Mg.
  • the AISiMgX master alloy according to the present disclosure comprises:
  • the AISiMgX master alloy is used in a process for preparing a target aluminium alloy by addition of an appropriate amount of the above AISiMgX master alloy to an aluminium base alloy.
  • any particular AISiMgX master alloy according to the present disclosure depends upon the composition of the desired target aluminium alloy, which also corresponds with the composition of the base aluminium alloy. Except for the concentration of Mg, the AISiMgX master alloy shall have essentially the same concentrations of alloying elements (alloying elements selected from the group consisting of Si, Cu, Fe, Mn, Ti and Sr) as the target alloy.
  • alloying elements alloying elements selected from the group consisting of Si, Cu, Fe, Mn, Ti and Sr
  • AISiMgX master alloy By “essentially the same concentrations” is meant that the concentrations of the said alloying elements (except Mg) in the AISiMgX master alloy corresponds with the target aluminium alloy, such that the resulting concentration of the said alloying elements in the target aluminium alloy, after addition of the AISiMgX master alloy to a base aluminium alloy, have generally corresponding concentration except the concentration of Mg which is increased in the target aluminium alloy compared to the base alloy.
  • an AISiMgX master alloy of the invention can be prepared. It should be appreciated that the weight percent concentration of each alloying element in the base alloy can be identified by techniques, generally known in the art.
  • the AISiMgX master alloy may be used in a process for preparing a target aluminium alloy by addition of the AISiMgX master alloy to an aluminium base alloy.
  • a preferred aluminium base alloy may be selected from the 3xx series, as designated by the Aluminium Association or from other European or national foundry alloys.
  • the aluminium base alloy may be an EN AC-42xxx, EN AC-43500 (AISil OMnMg) or EN AC-45500 (AISi7CuO.5Mg) alloy, according to European Standard EN1706 and/or EN1676.
  • the base alloy, to which the AISiMgX master alloy is added determines the alloying elements and their concentration in the AISiMgX master alloy.
  • the Mg concentration in the AISiMgX master alloy is from 1 .3 to 6.5 wt%. In some applications, the Mg concentration in the AISiMgX master alloy may range from 1 .3 to 5.5 wt%, or 1 .3 to 4.5, or 1 .3 to 2.5 wt%, or 1 .5 to 2.5 wt%, or 1 .5 to 2.0 wt%, or 2.0 to 3.0 wt%, or 2.5 to 3.5 wt%, or 3.4 to 4.0 wt%, or 4.0 to 5.5 wt%, or 4.5 to 5.5 wt%, or 4.0 to 4.6 wt%.
  • the concentration of Mg in the AISiMgX master alloy generally depends on the desired increase of Mg in the target aluminium alloy, compared with the base aluminium alloy.
  • the Si concentration in the AISiMgX master alloy is from 6.5 to 11 .5 wt%. In some examples, the Si concentration in the AISiMgX master alloy may range from 6.5 to 7.5 wt%. Some gravity and low-pressure aluminium casting alloys are of the AISi7Mg-type, hence AISiMgX master alloys having between 6.5-7.5 wt% Si are especially suited for such AISi7Mg-type alloys. In another example, the Si concentration in the AISiMgX master alloy may range from 9 to 11 .5 wt% which are particularly suitable for addition to AISi10Mg-type alloys.
  • An AISiMgX master alloy comprising from 6.5 to 11 .5 wt% Si, e.g. from 6.5 to 8.5 wt% Si, or from 9.0 to 11 .5 wt% Si, together with 0.4 to 0.8 wt% Mn are especially suitable for additions to AISiMnMg-type alloys, such as AISi7MnMg-type and AISi1 OMnMg-type alloys. Furthermore, an AISiMgX master alloy comprising from 6.5 to 7.5 wt% Si and 0.2 to 0.7 wt% Cu are especially suitable for addition to AISi7MgCu0.5 type alloys.
  • the Fe concentration in the AISiMgX master alloy should be 0.40 wt% or less, such as 0.15 wt% or less.
  • the Ti concentration in the AISiMgX master alloy should be 0.18 wt% or less, such as between 0.05 and 0.15 wt%.
  • the Sr concentration in the AISiMgX master alloy should be 0.10 wt% or less, such as between 0.02-0.04 wt%.
  • composition of the AISiMgX master alloy may be varied by combining the exemplified ranges of the alloying elements, and within the generally defined composition according to the appended claims.
  • the AISiMgX master alloys of the present disclosure are prepared according to generally known techniques of production of foundry alloys. Commercially pure aluminium, scrap aluminium alloy, including recycled aluminium metal, or a combination thereof, as well as the alloying elements of the respective base alloy can be used as the starting material.
  • the AISiMgX master alloy is preferably based on a 3xx series alloy (according to the nomenclature of the Aluminium Association designation system), EN AC-42xxx, EN AC-43500 (AISi MnMg) or EN AC- 45500 (AISi7CuO.5Mg) alloy (according to European Standard EN1706 and/or EN 1676), having an increased Mg concentration compared with the said standard base alloys.
  • a sufficient amount of magnesium is used to provide the calculated final concentration of magnesium in the AISiMgX master alloy. After the final element has been added, it is desirable to immediately adjust the temperature so as to provide fluidity for casting and, depending on furnace stirring characteristics, provide a product that, when cast, is of consistent chemistry from the beginning to the end of the charge so as to remove concerns about segregation.
  • the casted AISiMgX master alloy may be further processed or the final step in its preparation may be modified so as to produce the AISiMgX master alloy in any desirable form.
  • Such forms include foil, waffle, ingot, button, rod, wire, pellet, powder, briquet, and splatter.
  • the preferred form of the AISiMgX master alloy is an ingot.
  • the ingot can be in a corresponding shape and/or size of the ingots used for the base alloy ingots.
  • Another preferred form of the AISiMgX master alloy is a continuous cast (direct chill) ingot, where the developing Mg- containing phases are small in size and well distributed due to the high solidification rate.
  • An AISiMgX master alloy ingot wherein the Mg-containing phases are small in size and well distributed facilitates a rapid dissolution of the master alloy when added to a molten aluminium base alloy.
  • the AISiMgX master alloy according to the invention is used in the preparation of final target aluminium alloys.
  • the AISiMgX master alloy can be added to a melting furnace (prior to, during, or after melting), to the melt in a transport crucible or in a holding or casting furnace.
  • the base aluminium alloy is often prepared by using pre-alloyed foundry aluminium alloy ingots.
  • the base aluminium alloy may be prepared, using commercially pure aluminium, scrap aluminium alloy, including recycled aluminium metal, or a combination thereof as well as the required alloying elements.
  • Sufficient material is added until the basic charge weight is achieved, except for the amount of the AISiMgX master alloy which may be added subsequently.
  • the temperature is raised to above the melting point, typically between 700 and 800 °C.
  • an appropriate amount of AISiMgX master alloy material may be added to achieve the desired final chemistry of the target alloy.
  • the surface of the molten aluminium base alloy is skimmed clean of any oxides before the AISiMgX master alloy addition.
  • an appropriate amount of AISiMgX master alloy can also be added to the input material prior to melting in order to directly achieve the desired Mg-content after complete melting of the input and the AISiMgX master alloy materials.
  • the AISiMgX master alloys according to the present disclosure can be added to continuously melting furnaces such as shaft furnaces or chip-melting furnaces, where the normal expected Mg-loss due to burn-off during melting is usually quite well known. Depending on the hourly melting capacity and the necessary compensation of the Mg-loss or desired increase of the Mg-content, AISiMgX master alloy ingots can be fed into the melt, e.g. in regular periods.
  • the AISiMgX master alloys according to the present disclosure can be added to the base aluminium alloy in a holding or casting furnace as the base alloy metal is being poured in. This provides a stirring action and minimizes the time and temperature for making alloying additions, thereby minimizing oxidation of some alloying elements, especially Mg.
  • the AISiMgX master alloys according to the present disclosure can be added outside of the melting furnace, such as in a transport crucible, so that the base alloy melt composition in the melting furnace is not affected.
  • the addition of the AISiMgX master alloy takes place into the empty transport crucible before it is being filled or to the melt in a transport crucible prior to an eventual rotor degassing process. Again, this provides stirring action and minimizes the time and temperature for making alloying additions, thereby minimizing oxidation of some alloying elements.
  • the AISiMgX master alloy is in the form of ingots having a size and a Mg-concentration that results in a stepwise and/or fixed increase of the Mg concentration when one or more AISiMgX master alloy ingots are added to a certain amount of base aluminium alloy.
  • the AISiMgX master alloy ingots may have a weight of 6.5 kg, 7.5 kg or 9.2 kg, which sizes corresponds to commonly used base aluminium ingots. Addition of one AISiMgX master alloy ingot to a certain amount of the base aluminium alloy may increase the Mg concentration in the target aluminium alloy by e.g. 0.1 wt% (percentage point).
  • Table 1 shows examples of AISiMgX master alloy ingots sizes and Mg ranges resulting in a fixed Mg increase (in wt%) in target aluminium alloys by addition of one ingot to 1000 kg base alloy. Using such “standardized” AISiMgX master alloy ingot system facilitates and simplifies the production of target aluminium alloys. It should be noted that Table 1 only illustrates example alloys for better understanding the invention. The examples illustrated in Table 1 should therefore not be construed as limiting for the present invention since there are a variety of possible master alloy compositions within the defined claim scope in the appended claims.
  • the first illustrating example concerns a 3xx base alloy containing nominally 7 wt% Si, 0.12 wt% Fe, 0.12 wt% Ti 0.02 wt% Sr, and 0.28 wt% magnesium, balance Al.
  • the Mg concentration shall be increased to 0.29 wt%.
  • the addition of two ingots would nominally increase the Mg-content by 0.02 wt%.
  • a calculated nominal loss in melt temperature of approx. 7.5 degrees per added ingot to a 1000-kg-melt has to be taken into consideration.
  • the time for melting and complete dissolution of the AISiMgX master alloy ingot can be expected to be within 2-3 minutes. Pouring the liquid base alloy onto the master alloy ingot or stirring (e.g. by a rotor degassing treatment) would further decrease the melting and dissolution time.
  • the second illustrating example concerns a 3xx base alloy containing nominally 7 wt% Si, 0.12 wt% Fe, 0.12 wt% Ti, 0.02 wt% Sr, and 0.28 wt% magnesium, balance Al.
  • the Mg concentration shall be increased to 0.32 wt%.
  • the AISiMgX master alloys of the present invention provide several advantages over conventional methods of adding Mg to aluminium alloys.
  • the AISiMgX master alloys provide a concentrated amount of Mg in the proper proportion that is required to produce the specific target alloy, thereby allowing the desired composition to be reached with the addition of only one master alloy. Due to finely distributed Mg-phases the AISiMgX master alloys provide high solution rates, thereby reducing furnace cycle time or process time.
  • the AISiMgX master alloys reduce losses, e.g. caused by burn-off, and furthermore, they reduce melt treatment time, both due to faster dissolution and easier handling compared with the traditional methods.
  • the AISiMgX master alloys also provide, in certain instances, more consistent chemistry control due to more reliable yield compared to addition of pure Mg or binary AIMg alloys.
  • An AISiMgX master alloy according to the invention was added to the 233.1 kg melt.
  • the composition of the AISiMgX master alloy is given in table 2.
  • the Mg concentration of the master alloy was 1 .37 wt%.
  • An amount of master alloy (5.009 kg) representing a theoretical increment in Mg concentration of 0.0223 wt%. was added to the melt. After dissolution of the master alloy the Mg concentration increased by 0.0249 wt%, giving an estimated yield of 111 .5 %.
  • OES chemical analyses
  • a transport crucible was filled with 891 kg of an AISi7Mg melt from a melting furnace. The weight of the melt was determined by weighing the crucible before and after filling.
  • the composition of the alloy analyzed with Optical Emission Spectroscopy (OES) is given in table 4.
  • the Mg concentration was 0,3021%.
  • An AISiMgX master alloy according to the invention was added to the 981 kg melt.
  • the composition of the AISiMgX master alloy is given in table 4.
  • the Mg concentration of the master alloy was 1 ,37 wt%.
  • composition of the target alloy has essentially the same composition of the alloying elements as the base alloys, except the amount of Mg which is increased to the desired concentration.

Abstract

L'invention concerne un alliage maître d'AlSiMgX, particulièrement approprié pour augmenter la concentration en magnésium de matières fondues d'alliage de fonderie d'aluminium. L'invention concerne également un procédé pour augmenter la teneur en Mg d'alliages de fonderie d'aluminium par utilisation de l'alliage maître d'AlSiMgX dans la préparation d'un alliage d'aluminium cible. L'alliage maître d'AlSiMgX comprend : Mg 1,3 à 6,5 % en poids, Si 6,5 à 11,5 % en poids, Cu 0 à 1 % en poids, Mn 0 à 1,0 % en poids, Fe ≤ 0,40 % en poids, Ti ≤ 0,18 % en poids, Sr ≤ 0,10 % en poids, l'Al d'équilibrage et les impuretés inévitables.
PCT/EP2023/061884 2022-05-05 2023-05-05 Alliage maître d'alsimgx et utilisation de l'alliage maître dans la production d'un alliage d'aluminium WO2023213987A1 (fr)

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Citations (3)

* Cited by examiner, † Cited by third party
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