WO2023209415A1 - Heating method of a semi-finished metal products - Google Patents
Heating method of a semi-finished metal products Download PDFInfo
- Publication number
- WO2023209415A1 WO2023209415A1 PCT/IB2022/053816 IB2022053816W WO2023209415A1 WO 2023209415 A1 WO2023209415 A1 WO 2023209415A1 IB 2022053816 W IB2022053816 W IB 2022053816W WO 2023209415 A1 WO2023209415 A1 WO 2023209415A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- semi
- metal product
- temperature
- fluidized bed
- finished metal
- Prior art date
Links
- 239000002184 metal Substances 0.000 title claims abstract description 97
- 238000000034 method Methods 0.000 title claims abstract description 36
- 238000010438 heat treatment Methods 0.000 title claims abstract description 10
- 239000002245 particle Substances 0.000 claims abstract description 20
- 239000007787 solid Substances 0.000 claims abstract description 15
- 238000012546 transfer Methods 0.000 claims abstract description 10
- 229910000831 Steel Inorganic materials 0.000 claims description 18
- 239000010959 steel Substances 0.000 claims description 18
- 238000003303 reheating Methods 0.000 claims description 3
- 239000000047 product Substances 0.000 description 76
- 239000007789 gas Substances 0.000 description 17
- 239000005431 greenhouse gas Substances 0.000 description 4
- 238000004088 simulation Methods 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- 238000005098 hot rolling Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002918 waste heat Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910003465 moissanite Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052609 olivine Inorganic materials 0.000 description 1
- 239000010450 olivine Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/56—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
- C21D1/613—Gases; Liquefied or solidified normally gaseous material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/12—Accessories for subsequent treating or working cast stock in situ
- B22D11/1213—Accessories for subsequent treating or working cast stock in situ for heating or insulating strands
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/34—Methods of heating
- C21D1/53—Heating in fluidised beds
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0056—Furnaces through which the charge is moved in a horizontal straight path
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0062—Heat-treating apparatus with a cooling or quenching zone
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0081—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for slabs; for billets
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D13/00—Heat-exchange apparatus using a fluidised bed
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2251/00—Treating composite or clad material
- C21D2251/02—Clad material
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
- C21D9/567—Continuous furnaces for strip or wire with heating in fluidised beds
Definitions
- the invention relates to a method for heating a semi-finished metal product to be further laminated.
- the present invention relates to a method for heating at least one semi-finished metal product to be further laminated, by means of a heat exchanging device comprising a chamber containing solid particles, supporting means able to support said semi-finished metal product and a gas injector, comprising the steps of: i. injecting a gas into said chamber so as to form a fluidized bed, ii. inserting at least one hot metal product, having a temperature from THMIN to THMAX, into said fluidized bed, wherein THMIN is greater than the temperature of the fluidised bed such that said at least one hot metal product is able to transfer heat to said fluidized bed, iii.
- the heat exchanging device 1 comprises a chamber 2 containing solid particles 3, a support able to support at least one semi-finished steel product 4 and a gas injector 5.
- the chamber is preferentially able to receive more than two semi-finished metal products simultaneously.
- the supporting means 6 is preferentially able to receive more than two semi-finished metal products and at least one metal product.
- the supporting means can be a mesh basket.
- the supporting means can be composed of several parts not necessarily connected one to another.
- the supporting means can comprise several mesh baskets.
- the support means can be pillars/ stumps with guides inside the bed
- the chamber may be a closed chamber with a closable opening through which a semifinished metal product may be conveyed, but it could also have an open roof or any configuration suitable for semi-finished steel products conveying.
- a gas 6 is injected into said chamber 2 so as to form a fluidized bed 7 as illustrated in Figure 1.
- the chamber 2 comprises solid particles 3 but in Figure IB, a gas 6 is injected, by means of the gas injector 5, forming a fluidized bed 7.
- the solid particles have a direction of circulation.
- said solid particles of said fluidized bed are in a bubbling regime.
- the gas velocity to be applied to get a bubbling regime depends on several parameters like the kind of gas used, the size and density of the particles or the size of the chamber which are easily managed by a person skilled in the art.
- step ii. at least one hot metal product is inserted inside the fluidized bed.
- Said at least one hot metal product at the time of its insertion, has a temperature from THMIN to THM X-
- the minimum temperature at which said hot metal product is inserted, THMIN is greater than the temperature of said fluidised bed. It permits that said at least one hot metal product transfers heat to the fluidized bed, i.e. the particles composing the fluidized bed. Due to the heat transfer, the temperature of the hot metal product will decrease.
- said hot metal product is a semi-finished metal product.
- said at least one hot metal product can be a slab or bloom that has been casted and has thus a temperature from 400°C to 1000°C.
- Figure 2 embodies a chamber 2 comprising a fluidized bed 7 and three hot metal products 8 inserted inside said fluidized bed.
- step iii. at least one semi-finished metal product to be further laminated is inserted inside the fluidized bed.
- said at least one semi-finished metal product to be further laminated has a temperature from TCMIN to TCMAX-
- the maximum temperature at which a hot semi-finished metal product is inserted, CMA is smaller than the temperature of the fluidised bed. It permits that said at least one hot metal product can thus transfer heat to the fluidized bed, i.e. the particles composing the fluidized bed.
- the semi-finished metal product to be further laminated can, for example, be retrieved from a stock or a pile.
- Figure 3 embodies a chamber comprising a fluidized bed, three hot metal products 8 inserted inside said fluidized bed and four semi-finished metal products to be further laminated 9 inside said fluidized bed.
- At least one semi-finished metal product to be further laminated can be inserted inside the fluidized bed before inserting at least one hot metal product.
- hot metal products and semi-finished metal products to be rolled can be inserted alternatively inside said fluidized bed.
- step iv. at least one semi-finished metal product to be further laminated, that has previously been inserted inside said fluidized bed, is taken out of said fluidized bed when its temperature is less than 100°C below the temperature of said fluidised bed. For example, if the temperature of the fluidised bed is 350°C, then at least one semi-finished metal product to be further laminated, that has previously been inserted inside said fluidized bed, is taken out of said fluidized bed when its temperature is from 251°C to 350°C.
- the metal product, hot or to be further laminated may be conveyed inside and/ or outside the chamber by a rolling conveyor or may be placed inside the chamber by pick up means, such as cranes or any suitable pick up mean.
- pick up means such as cranes or any suitable pick up mean.
- the system disclosed in WO 2021 064 451 can be used to as pick up means.
- the method according to the invention permits to use the hot metal products heat to heat the semi-finished metal product to be further laminated.
- Such a method permits to reduce the amount of greenhouse gas emission required to heat a semi-finished metal product before rolling.
- said metal products are made of steel.
- said metal products can be of different steel grade.
- said metal products are a slab and/ or a bloom and/ or a billet and/ or a blank and/ or an ingot.
- said semi-finished metal products are slabs being from 150 to 250 mm thick, being from 600 to 1800 mm wide and being from 5000 to 15000 mm long.
- said semifinished metal products are slabs weighing from 3.5 tons to 50 tons.
- said metal products, hot or to be further laminated comprise a broad face.
- said broad face is parallel to the direction of circulation of the solid particles of the fluidized bed.
- said gas injected in said chamber is heated.
- said gas injected in said chamber has a temperature greater than TCMAX, even more preferably greater than then temperature of the fluidised bed and even more preferably greater than HMIN-
- said gas is at least partly heated by a renewable energy source and/ or by recovered waste heat.
- the recovered waste heat can for example come from reused fumes.
- said gas injected in said chamber is air.
- the gas injected by the gas injector is preferably an inert gas, such as argon or helium, or nitrogen or a mix of gases.
- the gas is injected at a velocity from 1 to 30 cm.s 4 .
- a velocity range requires a low ventilation power and thus a reduced energy consumption
- said chamber does not comprise a heat exchanger in contact with the fluidized bed.
- a heat exchanger is to be understood as a device wherein a transfer medium is circulated.
- Such a chamber is advantageous because the heating method does not require the use of energy, outside of the energy brought by the hot semi-finished steel product and the gas, to heat the fluidised bed and thus the semi-finished steel product to be further laminated. It permits to reduce even more the amount of greenhouse gas emission required to heat a semi-finished metal product before rolling
- the solid particles have a size from 40 to 500 pm.
- the solid particles have a heat capacity comprised from 500 to 2000 J.kg'bK 1 .
- the bulk density of the solid particles is from 1400 to 4000 kg.rn ⁇
- the solid particles are ceramic particles.
- the solid particles are made of glass or any other solid materials chemically stable up to 1000°C.
- the solid particles can be made of SiC, Olivine, steel slag or alumina.
- the solid particles are inert. It avoids any reaction with the metallic product.
- THMIN is to 400°C. Even more preferably, THMIN is to 600°C. Even more preferably, THMIN is to 800°C.
- HMAX is to 1000°C. Even more preferably, HMAX is to 800°C.
- said at least one hot metal product is taken out of said fluidized bed when the temperature of said hot metal product is from the temperature of the fluidised bed to 100°C higher than the temperature of the fluidised bed. Even more preferably, said at least one hot metal product is taken out of said fluidized bed when the temperature of said hot metal product is from the temperature of the fluidised bed to 50°C higher than the temperature of the fluidised bed. For example, if the temperature of the fluidised bed is 315°C, then said at least one hot metal product is taken out of said fluidized bed when the temperature of said hot metal product is from 265°C to 315°C.
- At least a second hot metal product having a temperature from HMIN to THMAX, is inserted into said fluidized bed.
- Said at least second hot metal product is inserted between the steps ii and iii and/or between the steps iii and iv and/ or after the step iv.
- TCMIN is equal to -20°C.
- TCMAX is equal to 200°C. Even more preferably, TCMAX is equal to 100°C.
- said at least one semi-finished metal product to be further laminated is taken out of said fluidized bed when the temperature of said semi-finished metal product to be further laminated is less than 50°C below the temperature of said fluidized bed.
- At least a second semi-finished metal product to be further laminated having a temperature from TCMIN to CMAX, is inserted into said fluidized bed.
- Said at least second hot semi-finished metal product is inserted between the steps iii and iv and/ or after the step iv.
- Removing the semi-finished metal product to be further laminated having underwent a temperature increase permits to replace them by other semi-finished metal product needing to be heated.
- the product temperature may be measured using contact thermocouples placed on the slab support and/ or using pyrometer when entering/ exiting of slab and/ or during performance tests, using embedded thermocouples on the slab similar to tests performed for reheating furnace thermal profiles.
- said fluidized bed is kept at a temperature from 100°C to 700°C. Even more preferably, said fluidized bed is kept at a temperature from 250°C to 600°C.
- the fluidized bed temperature may be measured using thermocouples placed at different points inside the fluidised bed with a small filter on the tip to avoid particles entrapment and/ or the air exiting the fluidized may also be measured to give an order of magnitude.
- said method comprises a step v., after the step iv. wherein said semi-finished metal product to be further laminated that has been heated in the fluidized bed is then heated in a reheating furnace to a temperature from 1100°C to 1400°C.
- said method comprises a step vi., after the step v. wherein said semifinished metal product to be further laminated is hot rolled.
- the method can use at least two heat exchanging devices, so as to have a cascade of heat exchanging device where hot semi-finished metal product goes in one way and the semi-finished metal product to be further laminated goes in the opposite direction.
- a simulation has been performed to illustrate an embodiment of the claimed method.
- the modelled fluidised bed has an average specific heat capacity of 0.6 kJ.kgTl-C 1 and a mass of 200 000 kg.
- the modelled hot metal products are hot steel slabs of 25 tons having an average specific heat capacity of 0.8085 kJ.kg bK 1 .
- the modelled semi-finished metal products to be further laminated are steel slabs to be laminated of 25 tons having an average specific heat capacity of 0.519 kJ.kg bK 1 .
- the simulation as illustrated in Figure 4, embodies a running process wherein the fluidised bed has a temperature of 310°C when a hot steel slab, having a temperature of 800°C, is inserted inside the fluidised bed. This corresponds to the step ii. of the claimed method.
- the temperature of the fluidised bed is represented by a continuous line while the temperature of the hot steel slab is represented by a dash line.
- a first steel slabs to be laminated having a temperature of 25°C
- a second steel slabs to be laminated having a temperature of 20°C
- the temperature of the steel slabs to be laminated are represented by a dash-dot line and a dash-dot-dot line.
- the first steel slab to be laminated is taken out of the fluidised bed when its temperature around 15°C lower than that of the bath. This corresponds to the step iv. of the claimed method.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Crucibles And Fluidized-Bed Furnaces (AREA)
Abstract
The invention relates to a method for heating at least one semi-finished metal products to be further laminated, by means of a heat exchanging device comprising a chamber containing solid particles, supporting means able to support semi-finished metal product and a gas injector, comprising the steps of: i. injecting a gas into said chamber so as to form a fluidized bed, ii. inserting at least one hot semi-finished metal product such that said at least one hot semi-finished metal product is able to transfer heat to said fluidized bed, iii. inserting said at least one semi-finished metal product to be further laminated such that said fluidized bed is able to transfer heat to said at least one semi-finished metal product to be further laminated, iv. taking out said at least one semi-finished metal product to be further laminated of said fluidized bed when the temperature of said at least one semi-finished metal product to be further laminated is less than 100°C below the temperature of said fluidized bed.
Description
HEATING METHOD OF A SEMI-FINISHED METAL PRODUCTS
The invention relates to a method for heating a semi-finished metal product to be further laminated.
In the metal production, but more specifically in steel production, semi-finished products need to be heated before undergoing further forming process. This is for example the case of steel slab before hot rolling which are heated, in a furnace, to temperatures above 1000°C prior to the hot rolling.
However, such a heating consumes a great amount of energy leading to emission of greenhouse gas. It is thus desirable to develop heating methods of semi-finished metal products reducing greenhouse gas emission.
It is a subject of this invention to provide such a heating method.
This is achieved by providing a method according to any one of the claims 1 to 13.
Other characteristics and advantages will become apparent from the following description of the invention.
The present invention relates to a method for heating at least one semi-finished metal product to be further laminated, by means of a heat exchanging device comprising a chamber containing solid particles, supporting means able to support said semi-finished metal product and a gas injector, comprising the steps of: i. injecting a gas into said chamber so as to form a fluidized bed, ii. inserting at least one hot metal product, having a temperature from THMIN to THMAX, into said fluidized bed, wherein THMIN is greater than the temperature of the fluidised bed such that said at least one hot metal product is able to transfer heat to said fluidized bed, iii. inserting said at least one semi-finished metal product to be further laminated, having a temperature from TCMIN to TCMAX into said fluidized bed, wherein TCMAX is smaller than the temperature of said fluidised bath such that said fluidized bed is able to transfer heat to said at least one semi-finished metal product to be further laminated, iv. taking out said at least one semi-finished metal product to be further laminated of said fluidized bed when the temperature of said at least one semi-finished metal product to be further laminated is less than 100°C below the temperature of said fluidised bed..
As illustrated in Figure 1, the heat exchanging device 1 comprises a chamber 2 containing solid particles 3, a support able to support at least one semi-finished steel product 4 and a gas injector 5. The chamber is preferentially able to receive more than two semi-finished metal products simultaneously.
The supporting means 6 is preferentially able to receive more than two semi-finished metal products and at least one metal product. The supporting means can be a mesh basket. The supporting means can be composed of several parts not necessarily connected one to another. For example, the supporting means can comprise several mesh baskets. Alternatively, the support means can be pillars/ stumps with guides inside the bed
The chamber may be a closed chamber with a closable opening through which a semifinished metal product may be conveyed, but it could also have an open roof or any configuration suitable for semi-finished steel products conveying.
In step i. of the method, a gas 6 is injected into said chamber 2 so as to form a fluidized bed 7 as illustrated in Figure 1. In both Figures 1A and IB, the chamber 2 comprises solid particles 3 but in Figure IB, a gas 6 is injected, by means of the gas injector 5, forming a fluidized bed 7. The solid particles have a direction of circulation.
Preferably, said solid particles of said fluidized bed are in a bubbling regime. The gas velocity to be applied to get a bubbling regime depends on several parameters like the kind of gas used, the size and density of the particles or the size of the chamber which are easily managed by a person skilled in the art.
In step ii., at least one hot metal product is inserted inside the fluidized bed. Said at least one hot metal product, at the time of its insertion, has a temperature from THMIN to THM X- The minimum temperature at which said hot metal product is inserted, THMIN, is greater than the temperature of said fluidised bed. It permits that said at least one hot metal product transfers heat to the fluidized bed, i.e. the particles composing the fluidized bed. Due to the heat transfer, the temperature of the hot metal product will decrease.
Preferably, said hot metal product is a semi-finished metal product. For example, said at least one hot metal product can be a slab or bloom that has been casted and has thus a temperature from 400°C to 1000°C.
Figure 2 embodies a chamber 2 comprising a fluidized bed 7 and three hot metal products 8 inserted inside said fluidized bed.
In step iii., at least one semi-finished metal product to be further laminated is inserted inside the fluidized bed. When inserted inside said fluidized bed, said at least one semi-finished metal product to be further laminated has a temperature from TCMIN to TCMAX-
The maximum temperature at which a hot semi-finished metal product is inserted, CMA , is smaller than the temperature of the fluidised bed. It permits that said at least one hot metal product can thus transfer heat to the fluidized bed, i.e. the particles composing the fluidized bed.
The semi-finished metal product to be further laminated can, for example, be retrieved from a stock or a pile.
Figure 3 embodies a chamber comprising a fluidized bed, three hot metal products 8 inserted inside said fluidized bed and four semi-finished metal products to be further laminated 9 inside said fluidized bed.
Alternatively, at least one semi-finished metal product to be further laminated can be inserted inside the fluidized bed before inserting at least one hot metal product. Alternatively, hot metal products and semi-finished metal products to be rolled can be inserted alternatively inside said fluidized bed.
In step iv., at least one semi-finished metal product to be further laminated, that has previously been inserted inside said fluidized bed, is taken out of said fluidized bed when its temperature is less than 100°C below the temperature of said fluidised bed. For example, if the temperature of the fluidised bed is 350°C, then at least one semi-finished metal product to be further laminated, that has previously been inserted inside said fluidized bed, is taken out of said fluidized bed when its temperature is from 251°C to 350°C.
In the steps ii, iii. and iv., the metal product, hot or to be further laminated, may be conveyed inside and/ or outside the chamber by a rolling conveyor or may be placed inside the chamber by pick up means, such as cranes or any suitable pick up mean. For example, the system disclosed in WO 2021 064 451 can be used to as pick up means.
The method according to the invention permits to use the hot metal products heat to heat the semi-finished metal product to be further laminated.
Such a method permits to reduce the amount of greenhouse gas emission required to heat a semi-finished metal product before rolling.
Preferably, said metal products are made of steel. Preferably, said metal products can be of different steel grade.
Preferably, said metal products are a slab and/ or a bloom and/ or a billet and/ or a blank and/ or an ingot.
Preferably, said semi-finished metal products are slabs being from 150 to 250 mm thick, being from 600 to 1800 mm wide and being from 5000 to 15000 mm long. Preferably, said semifinished metal products are slabs weighing from 3.5 tons to 50 tons.
Preferably, said metal products, hot or to be further laminated, comprise a broad face. Even more preferably, said broad face is parallel to the direction of circulation of the solid particles of the fluidized bed.
Preferably, said gas injected in said chamber is heated. Preferably, said gas injected in said chamber has a temperature greater than TCMAX, even more preferably greater than then temperature of the fluidised bed and even more preferably greater than HMIN-
Even preferably, said gas is at least partly heated by a renewable energy source and/ or by recovered waste heat. The recovered waste heat can for example come from reused fumes.
Preferably, said gas injected in said chamber is air. Alternatively, the gas injected by the gas injector is preferably an inert gas, such as argon or helium, or nitrogen or a mix of gases.
Preferably, the gas is injected at a velocity from 1 to 30 cm.s4. Such a velocity range requires a low ventilation power and thus a reduced energy consumption
Advantageously, said chamber does not comprise a heat exchanger in contact with the fluidized bed. Here a heat exchanger is to be understood as a device wherein a transfer medium is circulated. Such a chamber is advantageous because the heating method does not require the use
of energy, outside of the energy brought by the hot semi-finished steel product and the gas, to heat the fluidised bed and thus the semi-finished steel product to be further laminated. It permits to reduce even more the amount of greenhouse gas emission required to heat a semi-finished metal product before rolling
Preferably, the solid particles have a size from 40 to 500 pm.
Preferably, the solid particles have a heat capacity comprised from 500 to 2000 J.kg'bK 1.
Preferably, the bulk density of the solid particles is from 1400 to 4000 kg.rn \
Preferably, the solid particles are ceramic particles. Preferably, the solid particles are made of glass or any other solid materials chemically stable up to 1000°C. For example, the solid particles can be made of SiC, Olivine, steel slag or alumina.
Preferably, the solid particles are inert. It avoids any reaction with the metallic product.
Preferably, THMIN is to 400°C. Even more preferably, THMIN is to 600°C. Even more preferably, THMIN is to 800°C.
Preferably, HMAX is to 1000°C. Even more preferably, HMAX is to 800°C.
Preferably, said at least one hot metal product is taken out of said fluidized bed when the temperature of said hot metal product is from the temperature of the fluidised bed to 100°C higher than the temperature of the fluidised bed. Even more preferably, said at least one hot metal product is taken out of said fluidized bed when the temperature of said hot metal product is from the temperature of the fluidised bed to 50°C higher than the temperature of the fluidised bed. For example, if the temperature of the fluidised bed is 315°C, then said at least one hot metal product is taken out of said fluidized bed when the temperature of said hot metal product is from 265°C to 315°C.
Preferably, at least a second hot metal product, having a temperature from HMIN to THMAX, is inserted into said fluidized bed.
Said at least second hot metal product is inserted between the steps ii and iii and/or between the steps iii and iv and/ or after the step iv.
Removing hot products having transferred heat to the fluidised bed permits to replace them with hotter semi-finished metal product so as to continuously have at least one source of heat inside the fluidized bed.
Preferably, TCMIN is equal to -20°C.
Preferably, TCMAX is equal to 200°C. Even more preferably, TCMAX is equal to 100°C.
Preferably, said at least one semi-finished metal product to be further laminated is taken out of said fluidized bed when the temperature of said semi-finished metal product to be further laminated is less than 50°C below the temperature of said fluidized bed.
Preferably, at least a second semi-finished metal product to be further laminated, having a temperature from TCMIN to CMAX, is inserted into said fluidized bed.
Said at least second hot semi-finished metal product is inserted between the steps iii and iv and/ or after the step iv.
Removing the semi-finished metal product to be further laminated having underwent a temperature increase permits to replace them by other semi-finished metal product needing to be heated.
For example, the product temperature may be measured using contact thermocouples placed on the slab support and/ or using pyrometer when entering/ exiting of slab and/ or during performance tests, using embedded thermocouples on the slab similar to tests performed for reheating furnace thermal profiles.
Preferably, said fluidized bed is kept at a temperature from 100°C to 700°C. Even more preferably, said fluidized bed is kept at a temperature from 250°C to 600°C.
For example, the fluidized bed temperature may be measured using thermocouples placed at different points inside the fluidised bed with a small filter on the tip to avoid particles entrapment and/ or the air exiting the fluidized may also be measured to give an order of magnitude.
Preferably, said method comprises a step v., after the step iv. wherein said semi-finished metal product to be further laminated that has been heated in the fluidized bed is then heated in a reheating furnace to a temperature from 1100°C to 1400°C.
Even more preferably, said method comprises a step vi., after the step v. wherein said semifinished metal product to be further laminated is hot rolled.
Alternatively, the method can use at least two heat exchanging devices, so as to have a cascade of heat exchanging device where hot semi-finished metal product goes in one way and the semi-finished metal product to be further laminated goes in the opposite direction.
A simulation has been performed to illustrate an embodiment of the claimed method.
In the simulations, the modelled fluidised bed has an average specific heat capacity of 0.6 kJ.kgTl-C1 and a mass of 200 000 kg. Moreover, in the simulation, the modelled hot metal products are hot steel slabs of 25 tons having an average specific heat capacity of 0.8085 kJ.kg bK 1. The modelled semi-finished metal products to be further laminated are steel slabs to be laminated of 25 tons having an average specific heat capacity of 0.519 kJ.kg bK 1.
The simulation, as illustrated in Figure 4, embodies a running process wherein the fluidised bed has a temperature of 310°C when a hot steel slab, having a temperature of 800°C, is inserted inside the fluidised bed. This corresponds to the step ii. of the claimed method. On Figure 4, the temperature of the fluidised bed is represented by a continuous line while the temperature of the hot steel slab is represented by a dash line.
Then a first steel slabs to be laminated, having a temperature of 25°C, and a second steel slabs to be laminated, having a temperature of 20°C, are inserted inside the fluidised bed. This corresponds to the step iii. of the claimed method. On Figure 4, the temperature of the steel slabs to be laminated are represented by a dash-dot line and a dash-dot-dot line.
Then the first steel slab to be laminated is taken out of the fluidised bed when its temperature around 15°C lower than that of the bath. This corresponds to the step iv. of the claimed method.
Claims
1. A method for heating at least one semi-finished metal product to be further laminated, by means of a heat exchanging device comprising a chamber containing solid particles, supporting means able to support said semi-finished metal product and a gas injector, comprising the steps of: i. injecting a gas into said chamber so as to form a fluidized bed, ii. inserting at least one hot metal product, having a temperature from THMIN to THMAX, into said fluidized bed, wherein THMIN is greater than the temperature of said fluidised bed such that said at least one hot metal product is able to transfer heat to said fluidized bed, iii. inserting said at least one semi-finished metal product to be further laminated, having a temperature from CMIN to CMAX into said fluidized bed, wherein CMAX is smaller than the temperature of said fluidized bath such that said fluidized bed is able to transfer heat to said at least one semi-finished metal product to be further laminated, iv. taking out said at least one semi-finished metal product to be further laminated of said fluidized bed when the temperature of said at least one semi-finished metal product to be further laminated is less than 100°C below the temperature of said fluidized bed.
2. Method according to claim 1, wherein said metal products are made of steel.
3. Method according to claim 1 or 2, wherein said metal products are a slab and/or a bloom and/ or a billet and/ or a blank and/ or an ingot.
4. Method according to claim 1 to 3, wherein HMIN is equal to 400°C.
5. Method according to claim 1 to 4, wherein THMAX is equal to 1000°C.
6. Method according to claim 1 to 5, wherein said at least one hot metal product is taken out of said fluidized bed when the temperature of said hot metal product is from the temperature of the fluidised bed to 100°C higher than the temperature of the fluidised bed.
7. Method according to claim 1 to 6, wherein at least a second hot metal product, having a temperature from THMIN to THMAX, is inserted into said fluidized bed between the steps ii and iii and/ or between the steps iii and iv and/ or after the step iv.
8. Method according to claim 1 to 7, wherein TCMIN is equal to -20°C.
9. Method according to claim 1 to 8, wherein TCM is equal to 200°C.
10. Method according to claim 1 to 9, wherein said at least one semi-finished metal product to be further laminated is taken out of said fluidized bed when the temperature of said semi-finished metal product to be further laminated is less than 50°C below the temperature of said fluidized bed.
11. Method according to claim 1 to 10, wherein at least a second semi-finished metal product to be further laminated, having a temperature from TCMIN to CM X, is inserted into said fluidized bed between the steps iii and iv and/ or after the step iv.
12. Method according to any one of the claims 1 to 11, wherein said method comprises a step v., after the step iv. wherein said semi-finished metal product to be further laminated taken out of said fluidized bed is heated in a reheating furnace to a temperature from 1100°C to 1400°C.
13. Method according to claim 12, wherein said method comprises a step vi., after the step v. wherein said semi-finished metal product to be further laminated is hot rolled.
Priority Applications (3)
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PCT/IB2022/053816 WO2023209415A1 (en) | 2022-04-25 | 2022-04-25 | Heating method of a semi-finished metal products |
PCT/IB2023/053787 WO2023209480A1 (en) | 2022-04-25 | 2023-04-13 | Heating method of a semi-finished metal products |
KR1020247029462A KR20240146033A (en) | 2022-04-25 | 2023-04-13 | Heating method for metal semi-finished products |
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PCT/IB2022/053816 WO2023209415A1 (en) | 2022-04-25 | 2022-04-25 | Heating method of a semi-finished metal products |
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PCT/IB2022/053816 WO2023209415A1 (en) | 2022-04-25 | 2022-04-25 | Heating method of a semi-finished metal products |
PCT/IB2023/053787 WO2023209480A1 (en) | 2022-04-25 | 2023-04-13 | Heating method of a semi-finished metal products |
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PCT/IB2023/053787 WO2023209480A1 (en) | 2022-04-25 | 2023-04-13 | Heating method of a semi-finished metal products |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1005056A (en) * | 1963-07-10 | 1965-09-22 | Ass Elect Ind | Improvements relating to apparatus for the thermal treatment of continuous material or discrete articles |
JPS5194415A (en) * | 1975-01-21 | 1976-08-19 | ||
CN112229228A (en) * | 2020-09-24 | 2021-01-15 | 东北大学 | Multi-level phase change recycling and storing device for heat in continuous casting and steel billet cooling processes |
WO2021064451A1 (en) | 2019-10-02 | 2021-04-08 | Arcelormittal | System and method for handling semi-finished metal products |
-
2022
- 2022-04-25 WO PCT/IB2022/053816 patent/WO2023209415A1/en unknown
-
2023
- 2023-04-13 KR KR1020247029462A patent/KR20240146033A/en unknown
- 2023-04-13 WO PCT/IB2023/053787 patent/WO2023209480A1/en active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1005056A (en) * | 1963-07-10 | 1965-09-22 | Ass Elect Ind | Improvements relating to apparatus for the thermal treatment of continuous material or discrete articles |
JPS5194415A (en) * | 1975-01-21 | 1976-08-19 | ||
WO2021064451A1 (en) | 2019-10-02 | 2021-04-08 | Arcelormittal | System and method for handling semi-finished metal products |
CN112229228A (en) * | 2020-09-24 | 2021-01-15 | 东北大学 | Multi-level phase change recycling and storing device for heat in continuous casting and steel billet cooling processes |
Also Published As
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KR20240146033A (en) | 2024-10-07 |
WO2023209480A1 (en) | 2023-11-02 |
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