WO2023201671A1 - 检测组件及其制造方法、检测装置和检测系统 - Google Patents

检测组件及其制造方法、检测装置和检测系统 Download PDF

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Publication number
WO2023201671A1
WO2023201671A1 PCT/CN2022/088340 CN2022088340W WO2023201671A1 WO 2023201671 A1 WO2023201671 A1 WO 2023201671A1 CN 2022088340 W CN2022088340 W CN 2022088340W WO 2023201671 A1 WO2023201671 A1 WO 2023201671A1
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Prior art keywords
layer
sub
detected
detection
housing
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PCT/CN2022/088340
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English (en)
French (fr)
Inventor
裴宝有
瞿飞
何佳宁
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宁德时代新能源科技股份有限公司
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Application filed by 宁德时代新能源科技股份有限公司 filed Critical 宁德时代新能源科技股份有限公司
Priority to CN202280030694.6A priority Critical patent/CN117280199A/zh
Priority to PCT/CN2022/088340 priority patent/WO2023201671A1/zh
Publication of WO2023201671A1 publication Critical patent/WO2023201671A1/zh

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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/75Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
    • G01N21/77Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
    • G01N21/78Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator producing a change of colour

Definitions

  • the present application relates to the technical field of detection analysis, and more specifically, to a detection component and its manufacturing method, detection device and detection system.
  • This application provides a detection component and its manufacturing method, detection device and detection system, which can shorten the detection time and make the detection process simple.
  • a detection component including a base layer and a reaction layer.
  • the base layer includes a first part and a second part connected to each other, and the first part is configured to contact the object to be detected, so that the object to be detected diffuses from the first part to the direction of the second part.
  • the reaction layer is disposed on the surface of the first part in the direction from the first part to the second part.
  • the reaction layer includes a plurality of sub-layers arranged at intervals. Each sub-layer is configured to react with the substance to be detected in sequence and generate a reactant, so that The reactants diffuse into the second part so that the color of the second part changes.
  • the object to be detected can diffuse from the first part to the second part.
  • the object to be detected is in advance separated from the second part of the plurality of sub-layers.
  • a chemical reaction occurs in a part of the sub-layer, and the substance to be detected diffuses in the direction of the second part after the chemical reaction, and finally diffuses to a sub-layer in the plurality of sub-layers close to the second part and undergoes a chemical reaction to generate a reactant.
  • Having a color different from the second part can cause the color of the second part to change, so that the content of the preset component in the object to be detected can be determined based on the color of the second part.
  • the embodiment of the present application uses a chemical reaction between the object to be detected and the sub-layer to detect the content of the preset component in the object to be detected.
  • the detection process is simple; and since the chemical reaction can be completed during the diffusion process of the object to be detected, it can Reduce detection time.
  • the base layer includes a cotton fiber layer and/or a fiberglass layer.
  • the fiber layer of the embodiment of the present application has a good diffusion ability, which is conducive to the diffusion of the substance to be detected; and is conducive to the formation of the reactant on the base layer.
  • At least part of the surface of the first portion is a planar surface.
  • the reaction layer of the embodiment of the present application is disposed on a flat surface, and the overall space occupied by the detection component is smaller.
  • the diffusion path of the substance to be detected on a flat surface is shorter, which is conducive to the rapid diffusion of the substance to be detected, and is suitable for substances to be detected with high activity and rapid reaction.
  • At least part of the surface of the first part has a plurality of depressions and a plurality of protrusions protruding relative to the depressions, and a protrusion is provided between two adjacent depressions, wherein the reaction layer Provided on multiple recessed parts and multiple protruding parts.
  • the reaction layer of the embodiment of the present application is disposed on an uneven surface, the diffusion path of the substance to be detected is longer, which is beneficial to prolonging the reaction time of the substance to be detected, thereby increasing the reaction time between the substance to be detected and the reaction layer. , to ensure that the chemical reaction between the substance to be detected and the reaction layer fully occurs, thereby improving the accuracy of content detection of the preset component in the substance to be detected.
  • the bonding force between the reaction layer and the surface of the first part is stronger, and the reaction layer is not easily peeled off from the first part.
  • the first portion includes a first connection portion and a second connection portion.
  • a reaction layer is provided on the surface of the first connection part.
  • the second connection part is connected to a side of the first connection part away from the second part, and the second connection part is configured to contact the object to be detected, so that the object to be detected diffuses from the second connection part to the first connection part.
  • the embodiment of the present application provides a second connection part, and the second connection part can be directly placed in the device containing the object to be detected, which is beneficial to the detection operation and helps to expand the applicable scope of the detection component.
  • the spacing between two adjacent sub-layers is 5 mm to 10 mm; optionally, 5 mm to 8 mm.
  • the spacing between two adjacent sub-layers in the embodiment of the present application meets the above range, the risk of interference when chemical reactions occur between adjacent sub-layers can be reduced, and the interaction between compounds between adjacent sub-layers can also be reduced.
  • the possibility of doping can give each sub-layer sufficient space to react, thereby improving detection accuracy.
  • the substance to be detected includes a polyol compound; in the direction from the first part to the second part, the plurality of sub-layers include a first sub-layer and a second sub-layer arranged at intervals; the first sub-layer includes a polyol compound.
  • the first sub-layer in the embodiment of the present application can impart acidity to the substance to be detected, preparing for subsequent reactions.
  • the second sub-layer continues to react to generate a reactant.
  • the reactant has a different initial color from the second sub-layer, thereby changing the color of the second sub-layer, and continues Diffuse it to the second part and change the color of the second part.
  • the mass of the first sub-layer is 0.11 mg/n to 0.2 mg/n, where n represents the number of hydroxyl groups in the polyol compound.
  • the first sub-layer has a thickness of 80 ⁇ m to 100 ⁇ m.
  • the area of the first sub-layer ranges from 90mm 2 to 120mm 2 , optionally from 110mm 2 to 120mm 2 .
  • embodiments of the present application can regulate the parameters of the first sub-layer to ensure that the first sub-layer and the substance to be detected fully undergo a chemical reaction.
  • the mass of the second sub-layer is 0.3-0.4 mg/n, where n represents the number of hydroxyl groups in the polyol compound.
  • the second sub-layer has a thickness of 80 ⁇ m to 100 ⁇ m.
  • the area of the second sub-layer is 90 mm 2 to 120 mm 2 .
  • embodiments of the present application can regulate the parameters of the second sub-layer to ensure that the second sub-layer and the substance to be detected are fully chemically reacted.
  • embodiments of the present application provide a detection device, including a housing component and a detection component.
  • the detection component is at least partially disposed in the housing component.
  • the detection component adopts the detection component of any embodiment of the first aspect of this application.
  • the detection process of the embodiment of the present application is simple; and since the chemical reaction can be completed during the diffusion process of the substance to be detected, the detection time can be shortened.
  • the housing assembly includes a first housing portion and a second housing portion.
  • the second housing part is connected to and opposite to the first housing part, and an installation space with an opening is formed between the second housing part and the first housing part.
  • the installation space is used to install the detection component, wherein at least the first part
  • the partial through opening protrudes from at least one of the first housing part and the second housing part; and/or a first through hole is provided on at least one of the first housing part and the second housing part.
  • At least part of the first part of the embodiment of the present application protrudes from the housing assembly, which facilitates contact between the first part and the object to be detected, so that the object to be detected can diffuse from the first part to the second part.
  • the housing assembly of the embodiment of the present application may include a first through hole, and the first through hole is arranged opposite to at least part of the second part, so as to facilitate observing the color change of the second part through the first through hole during operation. Partially conduct colorimetry to determine the content of the preset component in the substance to be detected.
  • the first housing part includes a housing body and two extension parts protruding from the housing body.
  • the two extension parts are arranged oppositely, wherein at least part of the first part protrudes from the housing body and is located on two between extensions.
  • the extension part of the embodiment of the present application can protect the edge of the first part protruding from the shell body, so as to reduce the risk of damage to the first part.
  • At least part of the recess at the connection between the first housing part and the second housing part forms an engaging portion.
  • the engaging portion of the embodiment of the present application can easily form an engaging connection with an external component such as the engaging portion, which facilitates assembly.
  • embodiments of the present application provide a detection system, including the detection component of any embodiment of the first aspect of the application or the detection device of any embodiment of the second aspect of the application; and a storage component for accommodating the to-be-done object. Detection object.
  • the storage assembly includes a storage body and a cover.
  • the storage body includes a receiving cavity for accommodating the object to be detected; and the cover portion is closed on the storage body, and the cover portion includes a second through hole arranged opposite to the detection component, wherein at least one of the storage body and the cover portion One includes a packaging part to seal the accommodation cavity, and the detection component can pass through the packaging part through the second through hole and extend into the accommodation cavity.
  • the packaging part of the embodiment of the present application seals the accommodating cavity into a sealed structure, so that the object to be detected contained in the accommodating cavity is not easy to leak, and is not easy to have side reactions with oxygen and/or water vapor in the external environment. , which is conducive to ensuring the accuracy of detection of the object to be detected.
  • the encapsulation part is an aluminum-plastic layer, a polyethylene layer or a polypropylene layer.
  • the sealing effect of the packaging part of the embodiment of the present application is better, and it is easier for the detection component to destroy the packaging part, so that the first part of the detection component extends into the containing cavity and comes into contact with the object to be detected.
  • the cover portion includes a cover body and a snap portion protruding toward the geometric center of the second through hole
  • the detection device includes a housing component
  • the housing component includes a snap portion
  • the snap portion is used for connection.
  • the clamping part is arranged opposite to the clamping part.
  • the engaging portion and the engaging portion of the embodiment of the present application cooperate with each other, and their shapes match.
  • the detection component extends into the accommodation cavity through the second through hole, the engaging part and the snap-in part are connected.
  • the detection component and the storage component are not easy to loosen, and the structure is relatively stable, which is conducive to ensuring the smooth progress of the detection.
  • embodiments of the present application provide a detection method for detecting the content of a preset component in a substance to be detected.
  • the method includes: providing a substance to be detected, configuring the substance to be detected as a solution to be detected; providing a detection method component, the detection component includes a base layer and a reaction layer, the base layer includes a first part and a second part connected to each other, the reaction layer is arranged on the surface of the first part, pointing from the first part to the direction of the second part, the reaction layer includes a plurality of sub-substrates arranged at intervals.
  • the first part is brought into contact with the solution to be detected, so that the substance to be detected in the solution to be detected diffuses from the first part to the second part, and reacts with multiple sub-layers in sequence to generate reactants, and the reactants diffuse to the second part.
  • part to change the color of the second part compare the color of the second part with a preset color set to determine the content of the preset component.
  • Figure 1 is a schematic structural diagram of a detection component provided by some embodiments of the present application.
  • Figure 2 is a schematic structural diagram of a detection component provided by other embodiments of the present application.
  • Figure 3 is a schematic structural diagram of the detection component shown in Figure 2 from another angle;
  • Figure 4 is a schematic structural diagram of a detection component provided by other embodiments of the present application.
  • Figure 5 is a schematic structural diagram of the detection component shown in Figure 4 from another angle;
  • Figure 6 is a schematic structural diagram of a detection component provided by other embodiments of the present application.
  • Figure 7 is a schematic structural diagram of a detection device provided by some embodiments of the present application.
  • Figure 8 is a schematic structural diagram of a detection device provided by other embodiments of the present application.
  • Figure 9 is a cross-sectional view of the detection device shown in Figure 8 taken along line A-A;
  • Figure 10 is a schematic structural diagram of a detection system provided by some embodiments of the present application.
  • Figure 11 is an exploded schematic diagram of a detection system provided by other embodiments of the present application.
  • Figure 12 is an exploded schematic diagram of the storage component of the detection system shown in Figure 11;
  • Figure 13 is a cross-sectional view of the storage assembly shown in Figure 12 taken along line B-B;
  • Figure 14 is a schematic flowchart of a detection method provided by some embodiments of the present application.
  • Base layer 11. First part; 11a, recessed part; 11b, protruding part; 111. first connecting part; 112. second connecting part; 12. second part;
  • Reaction layer 20. Sub-layer; 21. First sub-layer; 22. Second sub-layer;
  • Shell assembly 210. First shell part; 211. First through hole; 212. Shell body; 213. Extension part; 220. Second shell part; 230. Engagement part; 240. Opening;
  • Storage component 310. Storage body; 311. Accommodation cavity; 320. Covering part; 321. Covering body; 322. Snapping part; 330. Second through hole; 340. Packaging part;
  • an embodiment means that a particular feature, structure or characteristic described in connection with the embodiment may be included in at least one embodiment of the application.
  • the appearances of this phrase in various places in the specification are not necessarily all referring to the same embodiment, nor are separate or alternative embodiments mutually exclusive of other embodiments.
  • connection should be understood in a broad sense.
  • connection can be a fixed connection, It can also be detachably connected or integrally connected; it can be directly connected or indirectly connected through an intermediate medium; it can be internal communication between two components.
  • connection can be a fixed connection
  • connection can also be detachably connected or integrally connected; it can be directly connected or indirectly connected through an intermediate medium; it can be internal communication between two components.
  • connection can also be detachably connected or integrally connected; it can be directly connected or indirectly connected through an intermediate medium; it can be internal communication between two components.
  • “Plural” appearing in this application means two or more (including two).
  • the battery cell includes a positive electrode piece and a negative electrode piece.
  • the positive electrode piece includes a positive current collector and a positive active material layer disposed on at least one surface of the positive current collector.
  • the negative electrode sheet includes a negative electrode current collector and a negative electrode active material layer disposed on at least one surface of the negative electrode current collector.
  • the positive active material layer includes positive active materials and functional additives such as polyols. Polyols can increase the plasticity of the positive active material layer and improve the binding force between the positive active material layer and the positive current collector.
  • the content of polyols is too low, it cannot play a good plastic role; if the content of polyols is too high, the proportion of positive active materials will decrease, thereby reducing the electrochemical performance of the secondary battery; and it will increase the number of positive electrodes.
  • the water absorption property of the active material layer may cause the positive active material layer to peel off from the positive electrode current collector, or even cause problems such as lithium precipitation. Therefore, it is usually necessary to detect the content of polyols to ensure the performance of battery cells.
  • gas chromatography is mainly used to detect polyol substances in related technologies. This method usually requires the preparation and analysis of samples. The detection time is long and the detection process is complicated, which seriously affects the quality of battery cells. Continuous production.
  • the inventor designed a detection component for detecting the content of a preset component in the object to be detected. By detecting the color reaction of the component, the content of the preset component can be obtained through comparison.
  • This detection component is not only suitable for product testing in the battery field, but also suitable for other areas of chemical production such as water quality testing.
  • an embodiment of the present application provides a detection component.
  • the detection component 100 includes a base layer 1 and a reaction layer 2 .
  • the base layer 1 includes a first part 11 and a second part 12 connected to each other.
  • the first part 11 is configured to be in contact with the object to be detected, so that the object to be detected diffuses from the first part 11 to the direction of the second part 12 .
  • the reaction layer 2 is disposed on the surface of the first part 11 in the direction from the first part 11 to the second part 12.
  • the reaction layer 2 includes a plurality of sub-layers 20 arranged at intervals, and the plurality of sub-layers 20 are configured to react with the substance to be detected in sequence. And generate reactants, and cause the reactants to diffuse to the second part 12, so that the color of the second part 12 changes.
  • the X direction in FIG. 1 refers to the direction from the first part 11 to the second part 12 .
  • the object to be detected is a mixed system composed of multiple components.
  • the detection component 100 of the embodiment of the present application can be used to detect the content of a preset component in the mixed system.
  • the preset component can be one of the mixed systems or Several components, for example, a preset component may be a component in the mixed system that affects the performance of the mixed system to a greater extent.
  • the content of the preset component in the embodiments of the present application may refer to the mass of the preset component, or may refer to the mass ratio of the preset component to the substance to be detected.
  • the substance to be detected can be in various forms.
  • the substance to be detected may be in liquid or solid state.
  • a quantitative amount of the substance to be detected can be directly dropped into the first part 11 of the detection component 100 for detection; or the adsorption characteristics of the detection component 100 can be used to absorb a quantitative amount of the substance to be detected for detection.
  • the object to be detected is in a solid state, the object to be detected can be dissolved into a liquid state, and then the liquid object to be detected is placed in the first part 11 of the detection component 100 for detection.
  • the object to be detected is positive electrode slurry or positive electrode sheet.
  • the positive electrode piece is placed in a solvent to dissolve the positive active material layer.
  • the positive active material layer is configured as a solution to be detected, and then the solution to be detected is placed in the detection component 100 Perform testing.
  • the base layer 1 is a component with liquid absorption and diffusion functions, for example, a component containing fibers, which is conducive to the rapid diffusion of liquid and basically does not chemically react with the object to be detected, so as to reduce its interference with the accuracy of the detection of the object to be detected.
  • the base layer 1 includes a first part 11 and a second part 12 connected to each other.
  • the first part 11 and the second part 12 may be formed in various ways.
  • the first part 11 and the second part 12 may be of an integrated structure, that is, the first part 11 and the second part 12 may be formed in one piece. There is no clear boundary between the two parts 12.
  • the first part 11 and the second part 12 are provided independently, and the base layer 1 is formed by connecting the independently provided first part 11 and the second part 12 .
  • the base layer 1 includes two surfaces opposite to each other along its own thickness direction.
  • the reaction layer 2 may be disposed on at least one surface of the base layer 1 .
  • the reaction layer 2 is provided on one surface of the base layer 1; or the reaction layer 2 is provided on both surfaces of the base layer 1.
  • the reaction layer 2 can be formed on the surface of the base layer 1 through a coating process, an imprinting process, or the like.
  • the reaction layer 2 contains substances that can chemically react with preset components in the substance to be detected.
  • the reaction layer 2 in order to improve the accuracy of detecting the preset components in the object to be detected, the reaction layer 2 is configured to include a plurality of sub-layers 20 arranged at intervals. Each sub-layer 20 may contain different chemistries.
  • the object to be detected can react chemically with the sub-layers 20 in sequence, and multiple chemical reactions occur in the detection component 100.
  • the object to be detected gradually undergoes chemical reactions, and finally reacts with the sub-layer 20 of the plurality of sub-layers 20 that is close to the second part 12.
  • a color reaction occurs to ensure the accuracy of detection of preset component content.
  • the sub-layer 20 close to the second part 12 can undergo a color reaction with the substance to be detected to produce a reactant.
  • the reactant can change the color of the base layer 1 .
  • After the reactant diffuses to the second part 12 it can change the color of the second part 12 .
  • the color of the part 12 can be compared with the preset color set to determine the content of the preset component in the substance to be detected.
  • the color reaction refers to the color change after the second sub-layer 22 undergoes a chemical reaction.
  • the second sub-layer 22 before the reaction is colorless
  • the reactant is red
  • the red reactant diffuses to the second sub-layer 22 . part 12, causing the second part 12 to turn red.
  • the preset color set may be a preset color card, and the preset color set includes the corresponding relationship between the color and the content of the preset component. Therefore, by comparing the color of the second part 12 with the preset color set, the content of the preset component can be determined.
  • the plurality of sub-layers 20 may include two sub-layers 20 , for example, the plurality of sub-layers 20 include a first sub-layer 21 and a second sub-layer 22 , and the second sub-layer 22 is close to the second sub-layer 20 .
  • the portion 12 is arranged with the first sub-layer 21 located on a side of the second sub-layer 22 facing away from the second portion 12 .
  • the detection component 100 absorbs the object to be detected, and the object to be detected diffuses from the first part 11 to the direction of the second part 12, and first diffuses to the area of the first part 11 corresponding to the first sub-layer 21, and then the object to be detected can be connected with the second part 12.
  • a sub-layer 21 undergoes a chemical reaction to produce primary products.
  • the primary product continues to diffuse to the region of the first part 11 corresponding to the second sub-layer 22, and then the primary product can chemically react with the second sub-layer 22 to generate a reactant, which has a different property than the initial second part. 12 colors.
  • the reactant continues to diffuse to the second part 12, and the second part 12 displays the color of the reactant.
  • the color displayed by the second part 12 determines the content of the preset component.
  • An example in which the plurality of sub-layers 20 includes a first sub-layer 21 and a second sub-layer 22 is shown in FIG. 2 .
  • the plurality of sub-layers 20 may include three sub-layers 20 .
  • the plurality of sub-layers 20 point from the first part 11 to the direction of the second part 12.
  • the plurality of sub-layers 20 include a first sub-layer 21, a third sub-layer and a second sub-layer 22 arranged at intervals.
  • the second sub-layer 22 is close to the first sub-layer 21 and the second sub-layer 22.
  • Two parts 12 are arranged, the first sub-layer 21 is located on the side of the second sub-layer 22 away from the second part 12 , and the third sub-layer is located between the first sub-layer 21 and the second sub-layer 22 .
  • the detection component 100 absorbs the object to be detected, and the object to be detected diffuses from the first part 11 to the direction of the second part 12, and first diffuses to the area of the first part 11 corresponding to the first sub-layer 21, and then the object to be detected can be connected with the second part 12.
  • a sub-layer 21 undergoes a chemical reaction to produce primary products.
  • the primary product continues to diffuse to the region of the first part 11 corresponding to the third sub-layer, and then the primary product can chemically react with the third sub-layer to generate a secondary product.
  • the secondary product continues to diffuse to the region of the first part 11 corresponding to the second sub-layer 22, and then the secondary product can chemically react with the second sub-layer 22 to generate a reactant, which has a different property than the initial second part. 12 colors.
  • the reactants continue to diffuse to the second part 12, and the color of the second part 12 changes.
  • the content of the preset component is determined by the color displayed by the second part 12.
  • the multiple sub-layers 20 may also include four sub-layers 20, five sub-layers 20, etc.
  • the number of sub-layers 20 is not limited here, and the number of sub-layers 20 can be flexibly selected according to production requirements.
  • the object to be detected can diffuse from the first part 11 to the second part 12 .
  • the object to be detected is preliminarily combined with the components in the multiple sub-layers 20
  • the sub-layer 20 facing away from the second part 12 undergoes a chemical reaction.
  • the substance to be detected diffuses in the direction of the second part 12 and diffuses to the sub-layer 20 close to the second part 12 among the plurality of sub-layers 20 and undergoes chemical reaction.
  • the reaction generates a reactant, which has a color different from that of the second part 12, so that the color of the second part 12 can be changed, so that the color of the preset component in the substance to be detected can be determined based on the color of the second part 12. content.
  • the embodiment of the present application uses a chemical reaction between the object to be detected and the sub-layer 20 to detect the content of the preset component in the object to be detected. The detection process is simple; and since the chemical reaction can be completed during the diffusion process of the object to be detected, therefore Detection time can be shortened.
  • the base layer 1 may include a cotton fiber layer and/or a glass fiber layer. This type of fiber layer has good diffusion ability, which is conducive to the diffusion of the substance to be detected; and is conducive to the formation of reactants on the base layer 1 .
  • the base layer 1 can be provided in a single-layer or multi-layer structure.
  • the base layer 1 may include a cotton fiber layer; or the base layer 1 may include a glass fiber layer; or the base layer 1 may include a cotton fiber layer and a glass fiber layer, and the cotton fiber layer and the glass fiber layer may be stacked along the thickness direction of the base layer 1 .
  • the base layer 1 in the embodiment of the present application includes a variety of structural forms. By selecting the structural form of the base layer 1, the detection time of the object to be detected can be adjusted.
  • At least part of the surface of the first portion 11 is a flat surface.
  • part of the surface of the first part 11 is a flat surface, or the entire surface of the first part 11 is a flat surface.
  • the plurality of sub-layers 20 of the reaction layer 2 are disposed on a flat surface, and the overall space occupied by the detection component 100 is smaller.
  • the diffusion path of the substance to be detected on a flat surface is shorter, which is conducive to the rapid diffusion of the substance to be detected. It is suitable for substances to be detected with high activity and rapid reaction.
  • At least part of the surface of the first part 11 may be an uneven surface. At least part of the surface of the first part 11 has a plurality of recessed portions 11a and a plurality of protruding portions 11b protruding relative to the recessed portions 11a, and a protruding portion 11b is provided between two adjacent recessed portions 11a, wherein the reaction layer
  • the plurality of sub-layers 20 are disposed on the plurality of recessed portions 11a and the plurality of protruding portions 11b.
  • the entire surface of the first portion 11 is an uneven surface.
  • part of the surface of the first part 11 is a flat surface, and another part of the surface is an uneven surface.
  • the diffusion path of the substance to be detected is longer, which is conducive to prolonging the reaction time of the substance to be detected, thereby increasing the reaction time between the substance to be detected and the reaction layer to ensure that the substance to be detected and the reaction A chemical reaction occurs fully between them, thereby improving the accuracy of detecting the content of the preset component in the object to be detected.
  • the reaction layer is disposed on an uneven surface, the bonding force between the plurality of sub-layers 20 of the reaction layer and the surface of the first part 11 is stronger, and the reaction layer is not easily peeled off from the first part 11 .
  • the first portion 11 includes a first connecting portion 111 and a second connecting portion 112 .
  • the reaction layer 2 is provided on the surface of the first connection part 111 .
  • the second connection part 112 is connected to the side of the first connection part 111 away from the second part 12 .
  • the second connection part 112 is configured to detect the object to be detected, so that the object to be detected moves from the second connection part 112 to the first part.
  • the connection portion 111 is diffused.
  • the reaction layer 2 is not provided on the second connection part 112, which is mainly used for diffusion to diffuse the substance to be detected to the first connection part 111, so that the reaction layer 2 corresponding to the first connection part 111 reacts.
  • the embodiment of the present application provides the second connection part 112, and the second connection part 112 can be directly placed in the device containing the object to be detected, which is beneficial to the detection operation and helps to expand the applicable scope of the detection component 100.
  • the surface of the second connecting part 112 may be configured as a flat surface
  • the surface of the first connecting part 111 may be configured as an uneven surface. Since the surface of the second connecting part 112 is a flat surface and its diffusion path is short, the substance to be detected can quickly diffuse to the first connecting part 111 through the second connecting part 112 , and the amount of the substance to be detected on the second connecting part 112 can be reduced. amount of loss.
  • the surface of the first connecting part 111 is set as an uneven surface.
  • the diffusion path of the object to be detected is relatively long. The object to be detected can fully react with each sub-layer 20 in the reaction layer 2 , thereby improving the preset concentration of the object to be detected. Accuracy of component detection.
  • the surfaces of the second connecting part 112 and the first connecting part 111 are both set as flat surfaces; alternatively, the surface of the second connecting part 112 can be set as an uneven surface, and the surface of the first connecting part 111 can be set as a flat surface. .
  • the first connection part 111 and the second connection part 112 in the embodiment of the present application can be an integrated structure.
  • the first connection part 111 and the second connection part 112 are integrally formed. There is no obvious boundary between them, which can reduce the need for detection. The object is lost at the connection between the two, thereby improving detection accuracy.
  • the first connecting part 111 and the second connecting part 112 can be provided independently, and then the first connecting part 111 and the second connecting part 112 are connected.
  • the reaction layer 2 includes a plurality of sub-layers 20 arranged at intervals. In other words, there is a spacing between the plurality of sub-layers 20 . d shown in FIG. 6 represents the spacing between two adjacent sub-layers 20 .
  • the distance between two adjacent sub-layers 20 is 5 mm to 10 mm.
  • the distance between two adjacent sub-layers 20 is 5 mm to 10 mm. Further, the distance between two adjacent sub-layers 20 may be 5 mm to 8 mm. For example, the spacing between two adjacent sub-layers 20 may be 5mm, 5.5mm, 6mm, 6.5mm, 7mm, 7.5mm, 8mm, 8.5mm, 9mm, 9.5mm or 10mm, or any two of the above. A combination of values.
  • the plurality of sub-layers 20 include first sub-layers 21 and second sub-layers 22 that are spaced apart.
  • the second sub-layer 22 is disposed close to the second part 12
  • the first sub-layer 21 is located on a side of the second sub-layer 22 away from the second part 12 .
  • the object to be detected includes polyol compounds.
  • the first sub-layer 21 includes sodium p-toluenesulfonate, a citric acid substance or solid oxalic acid.
  • Sodium p-toluenesulfonate and the like can react chemically with polyols to make the polyols acidic.
  • the first sub-layer 21 can impart acidity to the substance to be detected to prepare for subsequent reactions.
  • the second sub-layer 22 includes potassium dichromate or potassium permanganate. Substances such as potassium dichromate can undergo oxidation-reduction reactions with acidic polyols, causing the color of potassium dichromate to change. In other words, the second sub-layer 22 continues to react on the basis of the reaction between the first layer and the substance to be detected to generate a reactant. The reactant has a different initial color from the second sub-layer 22, thus changing the color of the second sub-layer 22. color, and continues to spread to the second part 12, and changes the color of the second part 12.
  • the parameters of the first sub-layer 21 can be adjusted to ensure that the first sub-layer 21 and the substance to be detected fully undergo a chemical reaction.
  • the parameter of the first sub-layer 21 may be at least one of the mass, thickness, and area of the first sub-layer 21 .
  • the parameter of the first sub-layer 21 may also be the width or length of the first sub-layer 21, etc.
  • the mass of the first sub-layer 21 is 0.11 mg/n to 0.2 mg/n, optionally 0.2 mg/n, where n represents the number of hydroxyl groups in the polyol compound.
  • the thickness of the first sub-layer 21 is 80 ⁇ m ⁇ 100 ⁇ m, optionally 100 ⁇ m.
  • the area of the first sub-layer 21 is 90mm 2 to 120mm 2 , optionally 110mm 2 .
  • the parameters of the second sub-layer 22 can be adjusted to ensure that the second sub-layer 22 and the substance to be detected are fully chemically reacted.
  • the parameter of the second sub-layer 22 may be at least one of the mass, thickness, and area of the second sub-layer 22 .
  • the parameter of the second sub-layer 22 may also be the width or length of the second sub-layer 22, etc.
  • the mass of the second sub-layer 22 is 0.3 mg/n to 0.4 mg/n, optionally 0.35 mg/n, where n represents the number of hydroxyl groups in the polyol compound.
  • the thickness of the second sub-layer 22 is 80 ⁇ m ⁇ 100 ⁇ m, optionally 90 ⁇ m.
  • the area of the second sub-layer 22 is 90mm 2 to 120mm 2 , optionally 120mm 2 .
  • embodiments of the present application also provide a detection device.
  • the detection device 1000 includes a housing component 200 and a detection component 100 . At least part of the detection component 100 is disposed in the housing component 200 .
  • the detection component 100 can adopt the detection component 100 of any embodiment of the first aspect of this application.
  • the housing component 200 is disposed outside the detection component 100, which can provide protection to the detection component 100 and facilitate detection operations.
  • the shape of the housing component 200 can be flexibly selected according to the structure of the detection component 100.
  • the detection component 100 is a long layered structure, and the housing component 200 can be a rectangular parallelepiped structure with an installation space; or the detection component 100 can be a cylindrical structure,
  • the housing assembly 200 may be a cylindrical structure with an installation space.
  • the object to be detected can diffuse from the first part 11 to the second part 12.
  • the object to be detected interacts with each component of the detection component 100 respectively.
  • the layer undergoes a chemical reaction and generates a reactant, which has a color different from that of the second part 12, so that the color of the second part 12 can change, so that the predetermined content in the substance to be detected can be determined by the color of the second part 12.
  • the detection process is simple; and since the chemical reaction can be completed during the diffusion process of the substance to be detected, the detection time can be shortened.
  • the detection assembly 100 includes a first part 11 , at least part of the first part 11 protrudes from the housing assembly 200 , which facilitates the first part 11 to contact the object to be detected, so that The substance to be detected can diffuse from the first part 11 to the second part 12 .
  • the first part 11 is located within the housing assembly 200 .
  • the housing assembly 200 has an opening 240 , which is connected to the first part 11 The ends facing away from the second part 12 are arranged oppositely.
  • the opening 240 is provided so that the object to be detected can contact the first part 11 through the opening 240 , so that the object to be detected further diffuses from the first part 11 to the second part 12 .
  • the housing component 200 may include a first through hole 211 , and the first through hole 211 is connected to the second part 12 . At least part of the part 12 is arranged relative to each other, so as to observe the color change of the second part 12 through the first through hole 211 during operation, and perform color comparison on the second part 12 to determine the content of the preset component in the object to be detected. .
  • At least part of the second part 12 can protrude from the housing assembly 200, and the color of the second part 12 can be directly measured through the color change of the second part 12 located outside the housing assembly 200. To determine the content of the preset component in the substance to be detected.
  • the housing assembly 200 includes a first housing portion 210 and a second housing portion 220 .
  • the second housing part 220 is connected to and opposite to the first housing part 210 .
  • An installation space with an opening 240 is formed between the second housing part 220 and the first housing part 210 .
  • the installation space is used to install the detection component 100 .
  • At least part of the first part 11 protrudes through the opening 240 from at least one of the first housing part 210 and the second housing part 220; and/or at least part of the first housing part 210 and the second housing part 220
  • a first through hole 211 is provided on one.
  • the first housing part 210 and the second housing part 220 may be fixedly connected, and the overall stability of the housing assembly 200 is relatively high; for example, the first housing part 210 and the second housing part 220 are an integral structure.
  • the first housing part 210 and the second housing part 220 may be detachably connected to facilitate replacement of the detection assembly 100 .
  • the first housing part 210 and the second housing part 220 jointly protect the detection component 100 to improve the protection capability of the detection component 100 .
  • At least part of the first part 11 protrudes from the first housing part 210 through the opening 240, and at least part of the first part 11 is exposed to the external environment to facilitate contact with the object to be detected.
  • at least part of the first part 11 protrudes from the second housing part 220 through the opening 240, and at least part of the first part 11 is exposed to the external environment to facilitate contact with the object to be detected.
  • at least part of the first portion 11 can pass through the opening 240 and protrude out of the first housing portion 210 and the second housing portion 220 at the same time.
  • the first through hole 211 may be provided in the first housing part 210 , that is, the first through hole 211 penetrates the first housing part 210 along the thickness direction of the first housing part 210 , and the second part can be observed through the first through hole 211 12 colors.
  • the first through hole 211 may be provided in the second housing part 220 , that is, the first through hole 211 penetrates the second housing part 220 along the thickness direction of the second housing part 220 , and the second housing part 220 can be observed through the first through hole 211 .
  • Part 2 12 colors can be provided on both the first housing part 210 and the second housing part 220, which is more convenient for the operator to observe the color of the second part 12.
  • the first housing part 210 includes a housing body 212 and two extension parts 213 protruding from the housing body 212 .
  • the two extension parts 213 are arranged oppositely, wherein the At least part of the part 11 protrudes from the housing body 212 and is located between the two extension parts 213 .
  • the two extension parts 213 are arranged opposite each other along the Y direction.
  • the two extension parts 213 can protect the edge of the first part 11 protruding from the shell body 212 to reduce the risk of the first part 11 being damaged.
  • the Y direction is perpendicular to the X direction.
  • the second housing part 220 may have the same structure as the first housing part 210 , or may have different structures.
  • the second housing portion 220 may include a housing body 212 .
  • At least part of the recess at the connection between the first housing part 210 and the second housing part 220 forms the engaging part 230 .
  • the engaging portion 230 facilitates the engagement with external components such as the engaging portion, thereby facilitating assembly.
  • embodiments of the present application also provide a detection system.
  • the detection system 2000 includes a storage component 300 .
  • the storage component 300 is used to accommodate the object to be detected.
  • the detection system 2000 may also include the detection component 100 of any embodiment of the first aspect of the application, or the detection device 1000 of any embodiment of the second aspect of the application.
  • the storage component 300 can be a component with a holding function, such as a reagent bottle or a reagent box, and its structural form is not limited.
  • the object to be detected is contained in the storage component 300, and the detection component 100 or the first part of the detection device 1000 can absorb the object to be detected, and enable the object to be detected to diffuse from the first part to the second part.
  • the substance to be detected chemically reacts with each sub-layer respectively and generates a reactant.
  • the reactant has a color different from that of the second part, thereby enabling the color of the second part to occur. change, so that the content of the preset component in the object to be detected can be determined from the color of the second part, and the detection process is simple; and because the chemical reaction can be completed during the diffusion process of the object to be detected, the detection time can be shortened.
  • the storage assembly 300 may include a storage body 310 and a cover portion 320 .
  • the storage body 310 includes an accommodation cavity 311 for accommodating the object to be detected.
  • the cover portion 320 covers the storage body 310, and the cover portion 320 includes a second through hole 330 opposite to the detection component 100, wherein at least one of the storage body 310 and the cover portion 320 includes a packaging portion 340,
  • the accommodating cavity 311 is sealed, and the detection component 100 can pass through the packaging part 340 through the second through hole 330 and extend into the accommodating cavity 311 .
  • the packaging part 340 may be provided on the storage body 310 or the cover part 320 , or the packaging part may be provided on both the storage body 310 and the cover part 320 .
  • the packaging part 340 seals the accommodating cavity 311 into a sealed structure, so that the object to be detected contained in the accommodating cavity 311 is not easy to leak, and is not easy to have side reactions with oxygen and/or water vapor in the external environment, which is conducive to ensuring that the object to be detected is not easily leaked. Accuracy of test object detection.
  • the encapsulation part 340 may be an aluminum-plastic layer, a polyethylene layer, or a polypropylene layer.
  • the sealing effect of the above-mentioned packaging part 340 is good, and it is convenient for the detection component 100 to destroy the packaging part 340, so that the first part 11 of the detection component 100 extends into the containing cavity 311 and contacts the object to be detected.
  • the covering portion 320 includes a covering body 321 and a snap portion 322 protruding toward the geometric center of the second through hole 330 .
  • the detection device 1000 includes a housing assembly 200.
  • the housing assembly 200 includes an engaging portion 230.
  • the engaging portion 230 is used to connect the engaging portion 322 and is arranged opposite to the engaging portion 322.
  • the engaging portion 230 cooperates with the engaging portion 322, and their shapes match.
  • embodiments of the present application also provide a detection method, which is used to detect the content of a preset component in a substance to be detected. As shown in Figure 14, the method includes:
  • S100 Provide a substance to be detected, and configure the substance to be detected as a solution to be detected.
  • the detection component includes a base layer and a reaction layer.
  • the base layer includes a first part and a second part connected to each other.
  • the reaction layer is arranged on the surface of the first part in the direction from the first part to the second part.
  • the reaction layer includes intervals. Multiple sub-layers of settings.
  • S300 contact the first part with the solution to be detected, so that the substance to be detected in the solution to be detected diffuses from the first part to the second part, and reacts with multiple sub-layers in sequence to generate reactants, and the reactants diffuse to the second part. section to change the color of the second section.
  • S400 Compare the color of the second part with the preset color set to determine the content of the preset component.
  • the substance to be detected When the substance to be detected is in a liquid state, the substance to be detected can be directly used as the solution to be detected. When the substance to be detected is in a solid state, the substance to be detected can be dissolved in a solvent to form a solution to be detected.
  • the method adopted in the embodiment of the present application has a simple detection process; and since the chemical reaction can be completed during the diffusion process of the substance to be detected, the detection time can be shortened.
  • the detection device 1000 includes a storage component 300 , a housing component 200 and a detection component 100 . At least part of the detection component 100 is disposed in the housing component 200 .
  • the storage component 300 is used to accommodate the object to be detected.
  • the storage assembly 300 may include a storage body 310 and a cover portion 320 .
  • the storage body 310 includes an accommodation cavity 311 for accommodating the object to be detected.
  • the cover part 320 is closed on the storage body 310, and the cover part 320 includes a second through hole 330 that is opposite to the detection component 100.
  • the cover part 320 includes a packaging part 340 to seal the accommodation cavity 311, and the detection component 100 can pass through the packaging part 340 through the second through hole 330 and extend into the containing cavity 311 .
  • the detection component 100 includes a base layer 1 and a reaction layer 2 .
  • the base layer 1 includes a first part 11 and a second part 12 connected to each other.
  • the first part 11 includes a first connecting part 111 and a second connecting part 112 .
  • the reaction layer 2 is provided on the surface of the first connection part 111 .
  • the second connection part 112 is connected to the side of the first connection part 111 away from the second part 12 .
  • the second connection part 112 is configured to detect the object to be detected, so that the object to be detected moves from the second connection part 112 to the first part.
  • the connection portion 111 is diffused.
  • the reaction layer 2 includes a first sub-layer 21 and a second sub-layer 22 .
  • the first sub-layer 21 is located on the side of the second sub-layer 22 facing away from the second portion 12 .
  • a portion of the second connecting portion 112 protrudes from the housing assembly 200 .
  • the detection process is explained by taking the positive electrode piece as the object to be detected as an example.
  • a preset weight of positive electrode pieces is provided, and the positive electrode pieces are placed in the containing cavity 311 to be dissolved.
  • a sodium citrate solution can be placed in the accommodation cavity 311 in advance, and the sodium citrate solution can activate the polyol.
  • the positive electrode slurry in the positive electrode piece is dissolved in the sodium citrate solution, shaken well, and left to stand to become the positive electrode slurry to be detected. It should be noted that the positive electrode current collector in the positive electrode piece will basically not dissolve.
  • the positive electrode slurry coated on the positive electrode piece will dissolve to form the positive electrode slurry to be detected, and the content of polyol substances in the positive electrode slurry to be detected will be detected.
  • the second connecting part 112 of the detection component 100 is inserted into the cover part 320 of the storage component 310, passes through the packaging part 340 and extends into the containing cavity 311, and comes into contact with the positive electrode slurry to be detected.
  • the cathode slurry to be detected diffuses from the second connection part 112 to the first connection part 111. When it diffuses to the area of the base layer 1 corresponding to the first sub-layer 21, the polyol in the cathode slurry to be detected and the first sub-layer 21 A chemical reaction occurred.
  • the first sub-layer 21 may be sodium p-toluene sulfonate, and sodium p-toluene sulfonate imparts acidity to the polyol in the positive electrode slurry to be detected. Then, the positive electrode slurry to be detected continues to diffuse to the area of the base layer 1 corresponding to the second sub-layer 22 , and the polyol endowed with acidity reacts chemically with the second sub-layer 22 .
  • the second sub-layer 22 may be potassium dichromate.
  • the polyol and potassium dichromate undergo a redox reaction to generate a reactant, and the color changes. Since the color change has a certain hysteresis, the reactant continues to diffuse to the second part 12. When it diffuses to the second part 12, it can pass through the second part.
  • the color of Part 12 is compared to a preset color set to determine the polyol content.
  • the accommodation chamber 311 contains 20 ppm sodium citrate solution, and the height of the sodium citrate solution in the accommodation chamber 311 is 30 ml. After the second connecting part 112 is inserted, the height of the solution in the accommodation chamber 311 rises, so that it is connected with the second connecting part 112
  • the volume of sodium citrate solution in contact is the standard 7.0ml.

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Abstract

提供一种检测组件(100)及其制造方法、检测装置(1000)和检测系统(2000)。检测组件(100),包括基层(1)和反应层(2)。基层(1)包括彼此连接的第一部分(11)和第二部分(12),第一部分(11)被配置为与待检测物接触,以使待检测物由第一部分(11)向第二部分(12)的方向扩散。反应层(2)设置于第一部分(11)的表面,由第一部分(11)指向第二部分(12)的方向上,反应层(2)包括间隔设置的多个子层(20),各子层(20)被配置为与待检测物依次发生反应并生成反应物,并使得反应物扩散至第二部分(12),以使第二部分(12)的颜色发生变化。检测组件(100)能够缩短检测时间,且检测过程简单。

Description

检测组件及其制造方法、检测装置和检测系统 技术领域
本申请涉及检测分析技术领域,并且更具体地,涉及一种检测组件及其制造方法、检测装置和检测系统。
背景技术
在化工生产领域,为了保证产品的性能,通常需要对产品中的其中一些组分进行含量检测,以调控产品的性能符合生产需求。
但是对产品的其中一些组分含量检测的检测时间较长,检测过程较为复杂。
发明内容
本申请提供了一种检测组件及其制造方法、检测装置和检测系统,能够缩短检测时间,且检测过程简单。
第一方面,本申请实施例提供了一种检测组件,包括基层和反应层。基层包括彼此连接的第一部分和第二部分,第一部分被配置为与待检测物接触,以使待检测物由第一部分向第二部分的方向扩散。反应层设置于第一部分的表面,由第一部分指向第二部分的方向上,反应层包括间隔设置的多个子层,各子层被配置为与待检测物依次发生反应并生成反应物,并使得反应物扩散至第二部分,以使第二部分的颜色发生变化。
由此,根据本申请实施例的检测组件,待检测物能够由第一部分向第二部分扩散,在第一部分向第二部分扩散的过程中,待检测物预先与多个子层中的背离第二部分的子层发生化学反应,发生化学反应后的待检测物向第二部分的方向扩散,并最终扩散至多个子层中的靠近第二部分的子层并发生化学反应生成反应物,该反应物具有不同于第二部分的颜色,从而能够使得第二部分的颜色发生变化,从而能够由第二部分的颜色确定待检测物中的预设组分的含量。本申请实施例通过待检测物与子层发生化学反应,以检测待检测物中预设组分的含量,检测过程简单;并且由于在待检测物扩散过程中即可完成化学反应,由此可以缩短检测时间。
在一些实施例中,基层包括棉纤维层和/或玻璃纤维层。
由此,本申请实施例的纤维层具有较好的扩散能力,有利于待检测物的扩散;且有利于反应物形成于基层上。
在一些实施例中,第一部分的至少部分表面为平坦表面。
由此,本申请实施例的反应层设置于平坦表面上,检测组件的整体占用空间较 小。待检测物在平坦表面上的扩散路径较短,有利于待检测物的快速扩散,适用于活性较高、反应迅速的待检测物。
在一些实施例中,第一部分的至少部分表面具有多个凹陷部和相对于凹陷部凸出的多个凸出部,相邻的两个凹陷部之间设置有凸出部,其中,反应层设置于多个凹陷部和多个凸出部上。
由此,本申请实施例的反应层设置于凹凸不平的表面时,待检测物的扩散路径较长,有利于延长待检测物的反应时间,从而能够使得待检测物和反应层的反应时间增加,以确保待检测物和反应层之间充分发生化学反应,进而提高对待检测物中的预设组分的含量检测的准确性。此外,反应层设置于凹凸不平的表面时,反应层和第一部分的表面的结合力更强,反应层不容易从第一部分上剥离。
在一些实施例中,第一部分包括第一连接部和第二连接部。第一连接部的表面设置有反应层。第二连接部连接于第一连接部的背离第二部分的一侧,第二连接部被配置为与待检测物接触,以使待检测物由第二连接部向第一连接部扩散。
由此,本申请实施例设置第二连接部,可以将第二连接部直接置于容纳有待检测物的设备中,有利于检测操作,有利于扩展检测组件的适用范围。
在一些实施例中,相邻两个子层之间的间距为5mm~10mm;可选地,5mm~8mm。
由此,本申请实施例的相邻两个子层之间的间距满足上述范围时,可以降低相邻子层之间分别发生化学反应时发生干扰的风险,也降低相邻子层间的化合物互相掺杂的可能性,能够给予每个子层充分反应的空间,从而提高检测准确性。
在一些实施例中,待检测物包含多元醇类化合物;由第一部分指向第二部分的方向上,多个子层包括间隔设置的第一子层和第二子层;第一子层包括对甲基苯磺酸钠、柠檬酸物质或固体草酸;和/或第二子层包括重铬酸钾或高锰酸钾。
由此,本申请实施例的第一子层能够赋予待检测物以酸性,为后续的反应作准备。第二子层在第一层和待检测物发生反应的基础上,继续进行反应生成反应物,该反应物和第二子层的初始颜色不同,从而改变了第二子层的颜色,并继续扩散至第二部分,并改变第二部分的颜色。
在一些实施例中,第一子层的质量为0.11mg/n~0.2mg/n,其中,n表示多元醇类化合物中的羟基数量。
在一些实施例中,第一子层的厚度为80μm~100μm。
在一些实施例中,第一子层的面积为90mm 2~120mm 2,可选为110mm 2~120mm 2
由此,本申请实施例可以通过对第一子层的参数进行调控,以确保第一子层和待检测物充分发生化学反应。
在一些实施例中,第二子层的质量为0.3~0.4mg/n,其中,n表示多元醇类化合物中的羟基数量。
在一些实施例中,第二子层的厚度为80μm~100μm。
在一些实施例中,第二子层的面积为90mm 2~120mm 2
由此,本申请实施例可以通过对第二子层的参数进行调控,以确保第二子层和待检测物充分发生化学反应。
第二方面,本申请实施例提供了一种检测装置,包括壳体组件和检测组件,检测组件,其至少部分设置于壳体组件内。检测组件采用本申请第一方面任一实施例的检测组件。
由此,本申请实施例检测过程简单;并且由于在待检测物扩散过程中即可完成化学反应,由此可以缩短检测时间。
在一些实施例中,壳体组件包括第一壳体部和第二壳体部。第二壳体部与第一壳体部连接且相对设置,第二壳体部和第一壳体部之间形成具有开口的安装空间,安装空间用于设置检测组件,其中,第一部分的至少部分穿过开口凸出于第一壳体部和第二壳体部中的至少一者;和/或第一壳体部和第二壳体部的至少一者上设置有第一通孔。
由此,本申请实施例的第一部分的至少部分凸出于壳体组件,有利于第一部分与待检测物接触,从而使得待检测物可以由第一部分向第二部分扩散。
本申请实施例的壳体组件可以包括第一通孔,第一通孔与第二部分的至少部分相对设置,以便于在操作时通过第一通孔观察第二部分的颜色变化,对第二部分进行比色,以确定待检测物中的预设组分的含量。
在一些实施例中,第一壳体部包括壳本体和凸出于壳本体的两个延伸部,两个延伸部相对设置,其中,第一部分的至少部分凸出于壳本体,并位于两个延伸部之间。
由此,本申请实施例的延伸部可以对凸出于壳本体的第一部分的边缘进行防护,以降低第一部分被损坏的风险。
在一些实施例中,第一壳体部和第二壳体部的连接处的至少部分凹陷形成卡合部。
由此,本申请实施例的卡合部便于与外部的构件例如卡接部形成卡接,有利于装配。
第三方面,本申请实施例提供了一种检测系统,包括本申请第一方面任一实施例的检测组件或本申请第二面任一实施例的检测装置;以及置物组件,用于容纳待检测物。
在一些实施例中,置物组件包括置物本体和盖合部。置物本体包括用于容纳待检测物的容纳腔;以及盖合部盖合于置物本体,且盖合部包括与检测组件相对设置的第二通孔,其中,置物本体和盖合部中的至少一者包括封装部,以密封容纳腔,且检测组件能够通过第二通孔穿过封装部并延伸至容纳腔内。
由此,本申请实施例的封装部将容纳腔密封为密封结构,以使容纳于容纳腔内的待检测物不容易泄露,且不容易与外部环境中的氧气和/或水汽等发生副反应,有利于保证待检测物检测的准确性。
在一些实施例中,封装部为铝塑层、聚乙烯层或聚丙烯层。
由此,本申请实施例的封装部的密封效果较好,且便于检测组件破坏封装部,以使检测组件的第一部分伸入容纳腔内,并与待检测物接触。
在一些实施例中,盖合部包括盖合本体和朝向第二通孔的几何中心凸出的卡接部,检测装置包括壳体组件,壳体组件包括卡合部,卡合部用于连接卡接部且与卡接部相对设置。
由此,本申请实施例的卡合部与卡接部相配合,其外形相匹配。在检测组件通过第二通孔伸入容纳腔内时,卡合部和卡接部连接,检测组件和置物组件之间不容易松动,结构相对稳定,有利于保证检测的顺利进行。
第四方面,本申请实施例提供了一种检测方法,用于检测待检测物中的预设组分的含量,方法包括:提供待检测物,将待检测物配置为待检测溶液;提供检测组件,检测组件包括基层和反应层,基层包括彼此连接的第一部分和第二部分,反应层设置于第一部分的表面,由第一部分指向第二部分的方向上,反应层包括间隔设置的多个子层;将第一部分与待检测溶液接触,以使待检测溶液中的待检测物由第一部分向第二部分的方向扩散,并依次与多个子层发生反应生成反应物,反应物扩散至第二部分以改变第二部分的颜色;将第二部分的颜色与预设颜色集合进行比对,以确定预设组分的含量。
附图说明
为了更清楚地说明本申请实施例的技术方案,下面将对本申请实施例中所需要使用的附图作简单地介绍,显而易见地,下面所描述的附图仅仅是本申请的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据附图获得其他的附图。
图1为本申请一些实施例提供的检测组件的结构示意图;
图2为本申请另一些实施例提供的检测组件的结构示意图;
图3为图2所示的检测组件在另一角度下的结构示意图;
图4为本申请另一些实施例提供的检测组件的结构示意图;
图5为图4所示的检测组件在另一角度下的结构示意图;
图6为本申请另一些实施例提供的检测组件的结构示意图;
图7为本申请一些实施例提供的检测装置的结构示意图;
图8为本申请另一些实施例提供的检测装置的结构示意图;
图9为图8所示的检测装置沿A-A线作出的剖视图;
图10为本申请一些实施例提供的检测系统的结构示意图;
图11为本申请另一些实施例提供的检测系统的分解示意图
图12为图11所示的检测系统的置物组件的分解示意图;
图13为图12所示的置物组件沿B-B线作出的剖视图;
图14为本申请一些实施例提供的检测方法的流程示意图。
附图并未按照实际的比例绘制。
附图标记如下:
100、检测组件;
1、基层;11、第一部分;11a、凹陷部;11b、凸出部;111、第一连接部;112、第二连接部;12、第二部分;
2、反应层;20、子层;21、第一子层;22、第二子层;
200、壳体组件;210、第一壳体部;211、第一通孔;212、壳本体;213、延伸部;220、第二壳体部;230、卡合部;240、开口;
1000、检测装置;
300、置物组件;310、置物本体;311、容纳腔;320、盖合部;321、盖合本体;322、卡接部;330、第二通孔;340、封装部;
2000、检测系统。
具体实施方式
为使本申请实施例的目的、技术方案和优点更加清楚,下面将结合本申请实施例中的附图,对本申请实施例中的技术方案进行清楚地描述,显然,所描述的实施例是本申请一部分实施例,而不是全部的实施例。基于本申请中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本申请保护的范围。
除非另有定义,本申请所使用的所有的技术和科学术语与属于本申请的技术领域的技术人员通常理解的含义相同;本申请中在申请的说明书中所使用的术语只是为了描述具体的实施例的目的,不是旨在于限制本申请;本申请的说明书和权利要求书及上述附图说明中的术语“包括”和“具有”以及它们的任何变形,意图在于覆盖不排他的包含。本申请的说明书和权利要求书或上述附图中的术语“第一”、“第二”等是用于区别不同对象,而不是用于描述特定顺序或主次关系。
在本申请中提及“实施例”意味着,结合实施例描述的特定特征、结构或特性可以包含在本申请的至少一个实施例中。在说明书中的各个位置出现该短语并不一定均是指相同的实施例,也不是与其它实施例互斥的独立的或备选的实施例。
在本申请的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”、“附接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本申请中的具体含义。
本申请中术语“和/或”,仅仅是一种描述关联对象的关联关系,表示可以存在三种关系,例如,A和/或B,可以表示:单独存在A,同时存在A和B,单独存在B这三种情况。另外,本申请中字符“/”,一般表示前后关联对象是一种“或”的关系。
在本申请的实施例中,相同的附图标记表示相同的部件,并且为了简洁,在不同实施例中,省略对相同部件的详细说明。应理解,附图示出的本申请实施例中的各种部件的厚度、长宽等尺寸,以及集成装置的整体厚度、长宽等尺寸仅为示例性说明,而不应对本申请构成任何限定。
本申请中出现的“多个”指的是两个以上(包括两个)。
在化工生产领域,为了保证产品的性能,通常需要对产品中的其中一些组分进行含量检测,以调控产品的性能符合生产需求。接下来以生产电池单体为例进行说明。
电池单体包括正极极片和负极极片,正极极片包括正极集流体和设置于正极集流体至少一个表面上的正极活性物质层。负极极片包括负极集流体和设置于负极集流体上至少一个表面上的负极活性物质层。正极活性物质层包括正极活性物质和功能助剂例如多元醇类物质,多元醇类物质能够增加正极活性物质层的塑性,提高正极活性物质层和正极集流体之间的结合力等。
多元醇类物质的含量过低,不能起到良好的塑性作用;而多元醇类物质的含量过高会导致正极活性物质的占比下降,从而降低二次电池的电化学性能;并且会增加正极活性物质层的吸水性能,由此可能会导致正极活性物质层从正极集流体上剥离,甚至出现析锂等问题。故,通常需要对多元醇类物质的含量进行检测,以确保电池单体的性能。
发明人发现,相关技术中主要采用气相色谱法对多元醇类物质的检测,该方法通常需要对制备样品并对样品进行分析,检测时间较长且检测过程较为复杂,严重影响了电池单体的连续化生产。
不仅是对多元醇类物质的检测存在上述问题,在化工生产领域中对一些产品的检测过程也存在检测时间较长且检测过程复杂的问题。
鉴于发明人发现的上述问题,发明人设计了一种检测组件,用于检测待检测物中的预设组分的含量。通过检测组件的显色反应,可以比对得出预设组分的含量。该检测组件不仅适用于电池领域的产品检测,也适用于化工生产的其他领域例如水质检测等。
接下来结合图1至图14对本申请实施例进行详细说明。
[检测组件]
第一方面,本申请实施例提供的一种检测组件。
如图1所示,该检测组件100包括基层1和反应层2。基层1包括彼此连接的第一部分11和第二部分12。第一部分11被配置为与待检测物接触,以使待检测物由第一部分11向第二部分12的方向扩散。反应层2设置于第一部分11的表面,由第一部分11指向第二部分12的方向上,反应层2包括间隔设置的多个子层20,多个子层20被配置为与待检测物依次发生反应并生成反应物,并使得反应物扩散至第二部分12,以使第二部分12的颜色发生变化。在本文中,图1中的X方向即表示由第一部分11指向第二部分12的方向。
待检测物为多种组分构成的混合体系,本申请实施例的检测组件100可以用于检测混合体系中的预设组分的含量,预设组分可以为混合体系中的其中一种或几种组分,例如,预设组分可以为混合体系中影响混合体系性能程度较大的组分。本申请实施例的预设组分的含量可以是指预设组分的质量,也可以指预设组分占据待检测物的质量比。
待检测物可以为多种形态。示例性地,待检测物可以为液态或固态。在待检测 物为液态时,可以直接将定量的待检测物滴加于检测组件100的第一部分11中进行检测;或者利用检测组件100的吸附特性以吸取定量的待检测物进行检测。在待检测物为固态时,可以将待检测物溶解为液态后,然后将液态的待检测物设置于检测组件100中的第一部分11进行检测。示例性地,待检测物为正极浆料或正极极片。以待检测物为正极极片为例进行说明,将正极极片置于溶剂中以溶解正极活性物质层,正极活性物质层被配置为待检测溶液,进而将待检测溶液置于检测组件100中进行检测。
基层1为具有吸液和扩散作用的构件,例如,包含纤维的构件,有利于液体的快速扩散,且基本不会与待检测物发生化学反应,以降低其干扰待检测物检测的准确性。
基层1包括彼此连接的第一部分11和第二部分12。第一部分11和第二部分12的成型方式包括多种,示例性地,第一部分11和第二部分12可以为一体式结构,即第一部分11和第二部分12一体成型,第一部分11和第二部分12之间并无明显的界限。或者,第一部分11和第二部分12独立设置,将独立设置的第一部分11和第二部分12连接后形成基层1。
基层1包括沿其自身厚度方向彼此相对的两个表面。反应层2可以设置于基层1的至少一个表面。示例性地,反应层2设置于基层1的一个表面;或者反应层2设置于基层1的两个表面。反应层2可以通过涂布工艺、压印工艺等形成于基层1的表面。
反应层2包含能够与待检测物中的预设组分发生化学反应的物质。本申请实施例为了提高待检测物中的预设组分检测的准确率,将反应层2设置为包括间隔设置的多个子层20。各子层20可以包含不同的化学物质。待检测物可以依次与子层20发生化学反应,在检测组件100中发生多个化学反应,待检测物逐步发生化学反应,并最终与多个子层20中的靠近第二部分12的子层20发生显色反应,从而保证预设组分含量检测的准确率。
多个子层20中的靠近第二部分12的子层20能够与待检测物发生显色反应产生反应物,反应物能够改变基层1的颜色,反应物扩散至第二部分12后可以改变第二部分12的颜色,可以将第二部分12的颜色和预设颜色集合进行比对,以确定待检测物中的预设组分的含量。在本文中,显色反应是指第二子层22发生化学反应后产生了颜色变化,例如未反应前的第二子层22为无色,反应物为红色,红色的反应物扩散至第二部分12,使得第二部分12变为红色。或者未反应前的第二子层22为黄色,反应物为红色,红色的反应物扩散至第二部分12,使得第二部分12变为红色。预设颜色集合可以为预先设置的色卡,预设颜色集合包含颜色和预设组分的含量的对应关系。因此,通过将第二部分12的颜色和预设颜色集合进行比对,可以确定预设组分的含量。
作为一些示例,如图1和图2所示,多个子层20可以包括两个子层20,例如多个子层20包括第一子层21和第二子层22,第二子层22靠近第二部分12设置,第一子层21位于第二子层22的背离第二部分12的一侧。检测组件100吸取待检测物,待检测物由第一部分11向第二部分12的方向扩散,并先扩散至与第一子层21对应的第一部分11的区域位置,然后待检测物能够与第一子层21发生化学反应从而生成初产物。该初产物继续扩散至与第二子层22对应的第一部分11的区域位置,然后该初产物 能够与第二子层22发生化学反应从而生成反应物,该反应物具有不同于初始第二部分12的颜色。该反应物继续扩散至第二部分12,第二部分12显示反应物的颜色,由第二部分12显示的颜色,确定预设组分的含量。图2中示出了多个子层20包括第一子层21和第二子层22的示例。
作为另一些示例,多个子层20可以包括三个子层20。例如多个子层20由第一部分11指向第二部分12的方向上,多个子层20包括间隔设置的第一子层21、第三子层和第二子层22,第二子层22靠近第二部分12设置,第一子层21位于第二子层22的背离第二部分12的一侧,第三子层位于第一子层21和第二子层22之间。检测组件100吸取待检测物,待检测物由第一部分11向第二部分12的方向扩散,并先扩散至与第一子层21对应的第一部分11的区域位置,然后待检测物能够与第一子层21发生化学反应从而生成初产物。该初产物继续扩散至与第三子层对应的第一部分11的区域位置,然后该初产物能够与第三子层发生化学反应从而生成次产物。该次产物继续扩散至与第二子层22对应的第一部分11的区域位置,然后该次产物能够与第二子层22发生化学反应从而生成反应物,该反应物具有不同于初始第二部分12的颜色。该反应物继续扩散至第二部分12,第二部分12发生颜色变化,由第二部分12显示的颜色,确定预设组分的含量。
作为再一些示例,多个子层20还可以包括四个子层20、五个子层20等等,在此并不对子层20的数量进行限定,子层20的数量可以根据生产需求灵活选用。
根据本申请实施例的检测组件100,待检测物能够由第一部分11向第二部分12扩散,在第一部分11向第二部分12扩散的过程中,待检测物预先与多个子层20中的背离第二部分12的子层20发生化学反应,发生化学反应后的待检测物向第二部分12的方向扩散,并扩散至多个子层20中的靠近第二部分12的子层20并发生化学反应生成反应物,该反应物具有不同于第二部分12的颜色,从而能够使得第二部分12的颜色发生变化,从而能够由第二部分12的颜色确定待检测物中的预设组分的含量。本申请实施例通过待检测物与子层20发生化学反应,以检测待检测物中预设组分的含量,检测过程简单;并且由于在待检测物扩散过程中即可完成化学反应,由此可以缩短检测时间。
在一些实施例中,基层1可以包括棉纤维层和/或玻璃纤维层。该类纤维层具有较好的扩散能力,有利于待检测物的扩散;且有利于反应物形成于基层1上。
在本申请实施例中,基层1可以设置为单层或多层结构形式。示例性地,基层1可以包括棉纤维层;或者基层1可以包括玻璃纤维层;再或者基层1包括棉纤维层和玻璃纤维层,棉纤维层和玻璃纤维层可以沿基层1的厚度方向层叠设置。
本申请实施例的基层1包括多种结构形式,通过对基层1结构形式的选取,可以调节待检测物的检测时长等。
在一些实施例中,如图2和图3所示,第一部分11的至少部分表面为平坦表面。示例性地,第一部分11的部分表面为平坦表面,或者第一部分11的全部表面为平坦表面。反应层2的多个子层20设置于平坦表面上,检测组件100的整体占用空间较小。待检测物在平坦表面上的扩散路径较短,有利于待检测物的快速扩散,适用于活 性较高、反应迅速的待检测物。
在另一些实施例中,如图4和图5所示,第一部分11的至少部分表面可以为凹凸不平的表面。第一部分11的至少部分表面具有多个凹陷部11a和相对于凹陷部11a凸出的多个凸出部11b,相邻的两个凹陷部11a之间设置有凸出部11b,其中,反应层的多个子层20设置于多个凹陷部11a和多个凸出部11b上。
示例性地,第一部分11的全部表面为凹凸不平的表面。或者,第一部分11的一部分表面为平坦表面,另一部分表面为凹凸不平的表面。
反应层设置于凹凸不平的表面时,待检测物的扩散路径较长,有利于延长待检测物的反应时间,从而能够使得待检测物和反应层的反应时间增加,以确保待检测物和反应之间充分发生化学反应,进而提高对待检测物中的预设组分的含量检测的准确性。此外,反应层设置于凹凸不平的表面时,反应层的多个子层20和第一部分11的表面的结合力更强,反应层不容易从第一部分11上剥离。
在一些实施例中,如图6所示,第一部分11包括第一连接部111和第二连接部112。第一连接部111的表面设置有反应层2。第二连接部112连接于第一连接部111的背离第二部分12的一侧,第二连接部112被配置为与待检测物检测,以使待检测物由第二连接部112向第一连接部111扩散。
第二连接部112上并未设置反应层2,其主要用于扩散将待检测物扩散至第一连接部111,以使与第一连接部111相对应的反应层2进行反应。本申请实施例设置第二连接部112,可以将第二连接部112直接置于容纳有待检测物的设备中,有利于检测操作,有利于扩展检测组件100的适用范围。
进一步地,第二连接部112的表面可以设置为平坦表面,第一连接部111的表面可以设置为凹凸不平的表面。鉴于第二连接部112的表面为平坦表面,其扩散路径较短,待检测物可以经第二连接部112快速扩散至第一连接部111,且能够降低待检测物在第二连接部112上的损失量。第一连接部111的表面设置为凹凸不平的表面,待检测物的扩散路径较长,待检测物能够与反应层2中的各子层20充分反应,从而能够提高待检测物中的预设组分检测的准确性。
当然,第二连接部112和第一连接部111的表面均设置为平坦表面;或者,第二连接部112的表面可以设置为凹凸不平的表面,第一连接部111的表面可以设置为平坦表面。
本申请实施例的第一连接部111和第二连接部112可以为一体式结构,第一连接部111和第二连接部112一体成型,二者之间并没有明显的界限,能够降低待检测物在二者连接处的损失,从而提高检测准确性。当然,第一连接部111和第二连接部112可以为独立设置,然后将第一连接部111和第二连接部112连接。
在本申请实施例中,反应层2包括多个间隔设置的子层20,换言之,多个子层20之间具有间距。图6中示出的d表示相邻两个子层20之间的间距。
在一些实施例中,相邻两个子层20之间的间距为5mm~10mm。
相邻两个子层20之间的间距满足上述范围时,可以降低相邻子层20之间分别发生化学反应时发生干扰的风险,也降低相邻子层20间的化合物互相掺杂的可能性, 能够给予每个子层20充分反应的空间,从而提高检测准确性。相邻两个子层20之间的间距为5mm~10mm,进一步地,相邻两个子层20之间的间距可以为5mm~8mm。示例性地,相邻两个子层20之间的间距可以为5mm、5.5mm、6mm、6.5mm、7mm、7.5mm、8mm、8.5mm、9mm、9.5mm或10mm,也可以为上述任两个数值组成的组合。
在一些实施例中,请继续参阅图6,由第一部分11指向第二部分12的方向上,多个子层20包括间隔设置的第一子层21和第二子层22。第二子层22靠近第二部分12设置,第一子层21位于第二子层22的背离第二部分12的一侧。接下来以待检测物包含多元醇类化合物为例进行说明。
第一子层21包括对甲基苯磺酸钠、柠檬酸物质或固体草酸。对甲基苯磺酸钠等能够与多元醇类物质发生化学反应,以使多元醇类物质呈酸性。换言之,第一子层21能够赋予待检测物以酸性,为后续的反应作准备。
第二子层22包括重铬酸钾或高锰酸钾。重铬酸钾等物质能够与酸性的多元醇类物质发生氧化还原反应,并使得重铬酸钾的颜色发生变化。换言之,第二子层22在第一层和待检测物发生反应的基础上,继续进行反应生成反应物,该反应物和第二子层22的初始颜色不同,从而改变了第二子层22的颜色,并继续扩散至第二部分12,并改变第二部分12的颜色。
在一些实施例中,可以通过对第一子层21的参数进行调控,以确保第一子层21和待检测物充分发生化学反应。在本文中,第一子层21的参数可以是第一子层21的质量、厚度、和面积中的至少一者。第一子层21的参数还可以是第一子层21的宽度或长度等。
作为一些示例,第一子层21的质量为0.11mg/n~0.2mg/n,可选为0.2mg/n,其中,n表示多元醇类化合物中的羟基数量。
作为另一些示例,第一子层21的厚度为80μm~100μm,可选为100μm。
作为再一些示例,第一子层21的面积为90mm 2~120mm 2,可选为110mm 2
在一些实施例中,可以通过对第二子层22的参数进行调控,以确保第二子层22和待检测物充分发生化学反应。在本文中,第二子层22的参数可以是第二子层22的质量、厚度、和面积中的至少一者。第二子层22的参数还可以是第二子层22的宽度或长度等。
第二子层22的质量为0.3mg/n~0.4mg/n,可选为0.35mg/n,其中,n表示多元醇类化合物中的羟基数量。
第二子层22的厚度为80μm~100μm,可选为90μm。
第二子层22的面积为90mm 2~120mm 2,可选为120mm 2
[检测装置]
第二方面,本申请实施例还提供了一种检测装置。
如图7至图9所示,该检测装置1000包括壳体组件200和检测组件100,检测组件100的至少部分设置于壳体组件200内。该检测组件100可以采用本申请第一方面任一实施例的检测组件100。
壳体组件200设置于检测组件100外,可以给予检测组件100以防护作用,且 有利于检测操作。壳体组件200的形状可以根据检测组件100的结构灵活选用,例如检测组件100为长形层状结构体,壳体组件200可以为具有安装空间的长方体结构;或者检测组件100为圆柱状结构,壳体组件200可以为具有安装空间的圆柱状结构。
根据本申请实施例的检测装置1000,待检测物能够由第一部分11向第二部分12扩散,在第一部分11向第二部分12扩散的过程中,待检测物分别与检测组件100的各子层发生化学反应并生成反应物,该反应物具有不同于第二部分12的颜色,从而能够使得第二部分12的颜色发生变化,从而能够由第二部分12的颜色确定待检测物中的预设组分的含量,检测过程简单;并且由于在待检测物扩散过程中即可完成化学反应,由此可以缩短检测时间。
在一些实施例中,请继续参阅图7至图9,检测组件100包括第一部分11,第一部分11的至少部分凸出于壳体组件200,有利于第一部分11与待检测物接触,从而使得待检测物可以由第一部分11向第二部分12扩散。
在另一些实施例中,第一部分11位于壳体组件200内,换言之,第一部分11可以不凸出于壳体组件200,相应地,壳体组件200具有开口240,该开口240与第一部分11的背离第二部分12的端部相对设置。该开口240的设置可以使得待检测物能够从该开口240与第一部分11接触,以使待检测物进一步由第一部分11向第二部分12扩散。
在一些实施例中,请继续参阅图7至图9,为了便于观察检测组件100的第二部分12的颜色变化,壳体组件200可以包括第一通孔211,第一通孔211与第二部分12的至少部分相对设置,以便于在操作时通过第一通孔211观察第二部分12的颜色变化,对第二部分12进行比色,以确定待检测物中的预设组分的含量。
在另一些实施例中,第二部分12的至少部分可以凸出于壳体组件200,可以直接通过位于壳体组件200外的第二部分12的颜色变化,对第二部分12进行比色,以确定待检测物中的预设组分的含量。
在一些实施例中,请继续参阅图7至图9,壳体组件200包括第一壳体部210和第二壳体部220。第二壳体部220与第一壳体部210连接且相对设置,第二壳体部220和第一壳体部210之间形成具有开口240的安装空间,安装空间用于设置检测组件100。第一部分11的至少部分穿过开口240凸出于第一壳体部210和第二壳体部220中的至少一者;和/或第一壳体部210和第二壳体部220的至少一者上设置有第一通孔211。
第一壳体部210和第二壳体部220之间可以是固定连接,壳体组件200的整体稳定性较高;例如,第一壳体部210和第二壳体部220为一体结构。第一壳体部210和第二壳体部220之间可以是可拆卸连接,便于更换检测组件100。第一壳体部210和第二壳体部220共同对检测组件100进行防护,以提高对检测组件100的防护能力。
第一部分11的至少部分穿过开口240凸出于第一壳体部210,第一部分11的至少部分显露于外部环境,便于与待检测物接触。或者,第一部分11的至少部分穿过开口240凸出于第二壳体部220,第一部分11的至少部分显露于外部环境,便于与待检测物接触。当然,第一部分11的至少部分可以穿过开口240同时凸出于第一壳体部210和第二壳体部220。
第一通孔211可以设置于第一壳体部210,即第一通孔211沿第一壳体部210的厚度方向贯穿第一壳体部210,可以通过第一通孔211观察第二部分12的颜色。或者,第一通孔211可以设置于第二壳体部220,即第一通孔211沿第二壳体部220的厚度方向贯穿第二壳体部220,可以通过第一通孔211观察第二部分12的颜色。当然,第一壳体部210和第二壳体部220上均可以设置第一通孔211,更有利于操作者观察第二部分12的颜色。
在一些实施例中,请继续参阅图7至图9,第一壳体部210包括壳本体212和凸出于壳本体212的两个延伸部213,两个延伸部213相对设置,其中,第一部分11的至少部分凸出于壳本体212,并位于两个延伸部213之间。
两个延伸部213沿Y方向相对设置,两个延伸部213可以对凸出于壳本体212的第一部分11的边缘进行防护,以降低第一部分11被损坏的风险。在本文中,Y方向垂直于X方向。
在一些实施例中,第二壳体部220可以与第一壳体部210为相同的结构,当然也可以结构不同。例如,第二壳体部220可以包括壳本体212。
在一些实施例中,请继续参阅图7至图9,第一壳体部210和第二壳体部220的连接处的至少部分凹陷形成卡合部230。卡合部230便于与外部的构件例如卡接部形成卡接,有利于装配。
[检测系统]
第三方面,本申请实施例还提供了一种检测系统。
如图10所示,该检测系统2000包括置物组件300。置物组件300用于容纳待检测物。该检测系统2000还可以包括本申请第一方面任一实施例的检测组件100,或者本申请第二方面任一实施例的检测装置1000。
置物组件300可以为具有容纳功能的构件,例如试剂瓶或者试剂盒等,其结构形式不限。
根据本申请实施例的检测系统2000,待检测物容纳于置物组件300中,检测组件100或检测装置1000的第一部分能够吸取待检测物,并使得待检测物能够由第一部分向第二部分扩散,在第一部分向第二部分扩散的过程中,待检测物分别与各子层发生化学反应并生成反应物,该反应物具有不同于第二部分的颜色,从而能够使得第二部分的颜色发生变化,从而能够由第二部分的颜色确定待检测物中的预设组分的含量,检测过程简单;并且由于在待检测物扩散过程中即可完成化学反应,由此可以缩短检测时间。
在一些实施例中,请参阅图10至图13,置物组件300可以包括置物本体310和盖合部320。置物本体310包括用于容纳待检测物的容纳腔311。盖合部320盖合于置物本体310,且盖合部320包括与检测组件100相对设置的第二通孔330,其中,置物本体310和盖合部320中的至少一者包括封装部340,以密封容纳腔311,且检测组件100能够通过第二通孔330穿过封装部340并延伸至容纳腔311内。
封装部340可以设置于置物本体310,也可以设置于盖合部320,或者在置物本体310和盖合部320上均设置封装部。
封装部340将容纳腔311密封为密封结构,以使容纳于容纳腔311内的待检测物不容易泄露,且不容易与外部环境中的氧气和/或水汽等发生副反应,有利于保证待检测物检测的准确性。
在一些实施例中,封装部340可以为铝塑层、聚乙烯层或聚丙烯层。上述封装部340的密封效果较好,且便于检测组件100破坏封装部340,以使检测组件100的第一部分11伸入容纳腔311内,并与待检测物接触。
在一些实施例中,盖合部320包括盖合本体321和朝向第二通孔330的几何中心凸出的卡接部322。相应地,检测装置1000包括壳体组件200,壳体组件200包括卡合部230,卡合部230用于连接卡接部322,且与卡接部322相对设置。卡合部230与卡接部322相配合,其外形相匹配。在检测组件100通过第二通孔330伸入容纳腔311内时,卡合部230和卡接部322连接,检测组件100和置物组件300之间不容易松动,结构相对稳定,有利于保证检测的顺利进行。
[检测方法]
第四方面,本申请实施例还提供了一种检测方法,该检测方法用于检测待检测物中的预设组分的含量。如图14所示,该方法包括:
S100,提供待检测物,将待检测物配置为待检测溶液。
S200,提供检测组件,检测组件包括基层和反应层,基层包括彼此连接的第一部分和第二部分,反应层设置于第一部分的表面,由第一部分指向第二部分的方向上,反应层包括间隔设置的多个子层。
S300,将第一部分与待检测溶液接触,以使待检测溶液中的待检测物由第一部分向第二部分的方向扩散,并依次与多个子层发生反应生成反应物,反应物扩散至第二部分以改变第二部分的颜色。
S400,将第二部分的颜色与预设颜色集合进行比对,以确定预设组分的含量。
在待检测物为液态时,待检测物可以直接作为待检测溶液。在待检测物为固态时,可以将待检测物溶解于溶剂中形成待检测溶液。
本申请实施例所采用的方法,检测过程简单;并且由于在待检测物扩散过程中即可完成化学反应,由此可以缩短检测时间。
如图6和图10,作为一具体实施例,检测装置1000包括置物组件300、壳体组件200和检测组件100,检测组件100的至少部分设置于壳体组件200内。
置物组件300用于容纳待检测物。置物组件300可以包括置物本体310和盖合部320。置物本体310包括用于容纳待检测物的容纳腔311。盖合部320盖合于置物本体310,且盖合部320包括与检测组件100相对设置的第二通孔330,其中,盖合部320包括封装部340,以密封容纳腔311,且检测组件100能够通过第二通孔330穿过封装部340并延伸至容纳腔311内。
检测组件100包括基层1和反应层2。基层1包括彼此连接的第一部分11和第二部分12。第一部分11包括第一连接部111和第二连接部112。第一连接部111的表面设置有反应层2。第二连接部112连接于第一连接部111的背离第二部分12的一侧,第二连接部112被配置为与待检测物检测,以使待检测物由第二连接部112向第一连接 部111扩散。反应层2包括第一子层21和第二子层22。第一子层21位于第二子层22的背离第二部分12的一侧。第二连接部112的部分凸出于壳体组件200。
以待检测物为正极极片为例进行检测过程的说明。
提供预设重量的正极极片,将正极极片置于容纳腔311中溶解。容纳腔311内可以预先放置柠檬酸钠溶液,柠檬酸钠溶液可以起到活化多元醇的作用。正极极片中的正极浆料在柠檬酸钠溶液中溶解后摇匀、静置为待检测正极浆料。需要说明的是,正极极片中的正极集流体基本不会溶解,正极极片上涂覆的正极浆料溶解形成待检测正极浆料,对待检测正极浆料中的多元醇类物质进行含量检测。
将检测组件100的第二连接部112插入置物组件310的盖合部320中,并穿过封装部340并延伸至容纳腔311内,与待检测正极浆料接触。待检测正极浆料由第二连接部112向第一连接部111扩散,当扩散至第一子层21所对应的基层1的区域时,待检测正极浆料中的多元醇和第一子层21发生化学反应。第一子层21可以为对甲基苯磺酸钠,对甲基本酸钠赋予待检测正极浆料中的多元醇以酸性。然后,待检测正极浆料继续扩散至第二子层22所对应的基层1的区域,被赋予酸性的多元醇和第二子层22发生化学反应。第二子层22可以采用重铬酸钾。多元醇和重铬酸钾发生氧化还原反应生成反应物,并发生颜色变化,由于颜色变化具有一定的滞后性,故反应物继续向第二部分12扩散,扩散至第二部分12时可以通过第二部分12的颜色和预设颜色集合进行比对,确定多元醇的含量。
示例性地,容纳腔311含有20ppm柠檬酸钠溶液,容纳腔311内柠檬酸钠溶液高度为30ml,插入第二连接部112后,容纳腔311内溶液高度升高,使得与第二连接部112接触的柠檬酸钠溶液体积为标准的7.0ml。通过上述步骤可以使得所测定的多元醇溶液的体积恒定,以此可以定量检测正极浆料中的多元醇的含量,并结合第二部分12的颜色可准确确定含量。
需要说明的是,在不冲突的情况下,本申请中的实施例及实施例中的特征可以相互组合。
最后应说明的是:以上实施例仅用以说明本申请的技术方案,而非对其限制;尽管参照前述实施例对本申请进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换,但这些修改或者替换,并不使相应技术方案的本质脱离本申请各实施例技术方案的精神和范围。

Claims (17)

  1. 一种检测组件,包括:
    基层,包括彼此连接的第一部分和第二部分,所述第一部分被配置为与待检测物接触,以使所述待检测物由所述第一部分向所述第二部分的方向扩散;以及
    反应层,设置于所述第一部分的表面,由所述第一部分指向所述第二部分的方向上,所述反应层包括间隔设置的多个子层,各所述子层被配置为与所述待检测物依次发生反应并生成反应物,并使得所述反应物扩散至所述第二部分,以使所述第二部分的颜色发生变化。
  2. 根据权利要求1所述的检测组件,其中,所述基层包括棉纤维层和/或玻璃纤维层。
  3. 根据权利要求1或2所述的检测组件,其中,
    所述第一部分的至少部分表面为平坦表面;或
    所述第一部分的至少部分表面具有多个凹陷部和相对于凹陷部凸出的多个凸出部,相邻的两个所述凹陷部之间设置有所述凸出部,
    其中,所述反应层设置于多个所述凹陷部和多个所述凸出部上。
  4. 根据权利要求1至3中任一项所述的检测组件,其中,所述第一部分包括:
    第一连接部,所述第一连接部的表面设置有所述反应层;以及
    连接于所述第一连接部的背离所述第二部分的一侧的第二连接部,所述第二连接部被配置为与所述待检测物接触,以使所述待检测物由所述第二连接部向所述第一连接部扩散。
  5. 根据权利要求1至4中任一项所述的检测组件,其中,相邻两个所述子层之间的间距为5mm~10mm;可选地,5mm~8mm。
  6. 根据权利要求1至5中任一项所述的检测组件,其中,
    所述待检测物包含多元醇类化合物;由所述第一部分指向所述第二部分的方向上,多个所述子层包括间隔设置的第一子层和第二子层;
    所述第一子层包括对甲基苯磺酸钠、柠檬酸物质或固体草酸;和/或
    所述第二子层包括重铬酸钾或高锰酸钾。
  7. 根据权利要求6所述的检测组件,其中,
    所述第一子层的质量为0.11mg/n~0.2mg/n,其中,n表示多元醇类化合物中的羟基数量;和/或
    所述第一子层的厚度为80μm~100μm;和/或
    所述第一子层的面积为90mm 2~120mm 2
  8. 根据权利要求6或7所述的检测组件,其中,
    所述第二子层的质量为0.3mg/n~0.4mg/n,其中,n表示多元醇类化合物中的羟基数量;和/或
    所述第二子层的厚度为80μm~100μm;和/或
    所述第二子层的面积为90mm 2~120mm 2
  9. 一种检测装置,包括:
    壳体组件;以及
    如权利要求1至8中任一项所述的检测组件,其至少部分设置于所述壳体组件内。
  10. 根据权利要求9所述的检测装置,其中,所述壳体组件包括:
    第一壳体部;
    与所述第一壳体部连接且相对设置的第二壳体部,所述第二壳体部和所述第一壳体部之间形成具有开口的安装空间,所述安装空间用于设置所述检测组件,
    其中,所述第一部分的至少部分穿过所述开口且凸出于所述第一壳体部和所述第二壳体部中的至少一者;和/或
    所述第一壳体部和所述第二壳体部中的至少一者上设置有第一通孔。
  11. 根据权利要求10所述的检测装置,其中,所述第一壳体部包括壳本体和凸出于所述壳本体的两个延伸部,两个所述延伸部相对设置,
    其中,所述第一部分的至少部分凸出于所述壳本体,并位于两个所述延伸部之间。
  12. 根据权利要求10或11所述的检测装置,其中,
    所述第一壳体部和所述第二壳体部的连接处的至少部分凹陷形成卡合部。
  13. 一种检测系统,包括:
    如权利要求1至8中任一项所述的检测组件或如权利要求9至12中任一项所述的检测装置;以及
    置物组件,用于容纳待检测物。
  14. 根据权利要求13所述的检测系统,其中,所述置物组件包括:
    置物本体,包括用于容纳所述待检测物的容纳腔;以及
    盖合部,盖合于所述置物本体,且所述盖合部包括与所述检测组件相对设置的第二通孔,
    其中,所述置物本体和所述盖合部中的至少一者包括封装部,以密封所述容纳腔, 且所述检测组件能够通过所述第二通孔穿过所述封装部并延伸至所述容纳腔内。
  15. 根据权利要求14所述的检测系统,其中,
    所述封装部为铝塑层、聚乙烯层或聚丙烯层。
  16. 根据权利要求14或15所述的检测系统,其中,
    所述盖合部包括盖合本体和朝向所述第二通孔的几何中心凸出的卡接部,
    所述检测装置包括壳体组件,所述壳体组件包括卡合部,所述卡合部用于连接所述卡接部且与所述卡接部相对设置。
  17. 一种检测方法,用于检测待检测物中的预设组分的含量,所述方法包括:
    提供待检测物,将所述待检测物配置为待检测溶液;
    提供检测组件,所述检测组件包括基层和反应层,所述基层包括彼此连接的第一部分和第二部分,所述反应层设置于所述第一部分的表面,由所述第一部分指向所述第二部分的方向上,所述反应层包括间隔设置的多个子层;
    将所述第一部分与所述待检测溶液接触,以使所述待检测溶液中的待检测物由所述第一部分向所述第二部分的方向扩散,并依次与多个所述子层发生反应生成反应物,所述反应物扩散至所述第二部分以改变所述第二部分的颜色;
    将所述第二部分的颜色与预设颜色集合进行比对,以确定所述预设组分的含量。
PCT/CN2022/088340 2022-04-22 2022-04-22 检测组件及其制造方法、检测装置和检测系统 WO2023201671A1 (zh)

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