WO2023173902A1 - Waste-heat recovery system matching hismelt smelting reduction ironmaking system - Google Patents

Waste-heat recovery system matching hismelt smelting reduction ironmaking system Download PDF

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WO2023173902A1
WO2023173902A1 PCT/CN2022/143823 CN2022143823W WO2023173902A1 WO 2023173902 A1 WO2023173902 A1 WO 2023173902A1 CN 2022143823 W CN2022143823 W CN 2022143823W WO 2023173902 A1 WO2023173902 A1 WO 2023173902A1
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flue
cooling
section
steam
flue gas
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PCT/CN2022/143823
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French (fr)
Chinese (zh)
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钱飞舟
朱泓
魏兆强
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苏州海陆重工股份有限公司
苏州海陆节能环保技术研究所有限公司
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Publication of WO2023173902A1 publication Critical patent/WO2023173902A1/en

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/004Systems for reclaiming waste heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/008Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases cleaning gases

Definitions

  • the invention relates to a waste heat recovery system, in particular to a waste heat recovery system matched to the HISMELT smelting reduction ironmaking system.
  • HISMELT is translated into Haismet according to the Chinese pronunciation.
  • HISMELT smelting reduction ironmaking technology is a short-process ironmaking technology that uses non-coking coal and iron ore powder to produce liquid iron by injection. Because it does not require the original coke process and pellet process of ironmaking, and directly uses coal powder and iron ore powder to make iron, it has the advantages of strong raw material adaptability, low environmental pollution, and high product quality. The factory construction is relatively simple. It has extremely high social, economic and environmental value.
  • Smelting reduction ironmaking technology is a technological improvement in blast furnace ironmaking technology, in which the waste heat recovery system is a key part of the entire system.
  • the HISMELT reactor in the HISMELT smelting reduction ironmaking system also known as the reduction furnace, produces high-temperature flue gas with a pressure close to 1.0 bar and a temperature of about 1450°C.
  • the high-temperature flue gas contains combustible gases such as CO and H 2 , and also contains a large amount of Bonded dust in a molten state.
  • the waste heat recovery system in the HISMELT smelting reduction ironmaking system converts the heat energy in the high-temperature flue gas into steam to generate electricity.
  • the current waste heat recovery system in the HISMELT smelting reduction ironmaking system The specific structure can be found in Chinese patent application CN103773912A. It mainly includes: a flue connected to the reduction furnace.
  • the flue includes an ascending section and a descending section.
  • the ascending section flue and the descending section The upper ends of the flue sections are connected by a transition flue, and the lower end of the descending flue section is provided with a connecting flue.
  • the connecting flue is connected to the high-temperature cyclone separator, and the flue gas outlet of the high-temperature cyclone separator is connected to the waste heat boiler. .
  • the high-temperature flue gas generated by the reduction furnace releases heat sequentially through the ascending flue, the transition flue, and the descending flue, and then enters the high-temperature cyclone separator through the connecting flue.
  • the high-temperature cyclone separator removes large particles in the high-temperature flue gas. After removal, the high-temperature flue gas with large particles removed enters the waste heat boiler for heat transfer.
  • the above-mentioned waste heat recovery system in the HISMELT smelting reduction ironmaking system has the following technical problems during operation: the high-temperature flue gas after removing large particles through the high-temperature cyclone separator still contains a large number of high-temperature bonded dust with smaller particle diameters.
  • the characteristic of this kind of high-temperature bonded dust particles is that their surface temperature is relatively low, but their internal core temperature is still very high, that is, the small-sized bonded dust remaining in the high-temperature gas has not been completely cooled.
  • Such high-temperature bonded dust particles is very easy to adhere to the wall of the heat exchange tube in the waste heat boiler, thus forming slagging on the wall of the heat exchange tube, and more and more accumulated dust can easily lead to large pieces falling off and clogging. As time goes by, the heat exchange effect of waste heat boilers continues to decrease, and safety hazards become more and more serious.
  • the purpose of this invention is to provide a waste heat recovery system that is matched to the Hesmet smelting reduction ironmaking system.
  • the waste heat recovery system can solve the technical problem of slagging on the walls of heat exchange tubes caused by particulate matter in high-temperature flue gases. , and further greatly improve the heat recovery efficiency.
  • a waste heat recovery system matched to the Hesmet smelting reduction ironmaking system including: a cooling flue with a membrane water-cooled wall structure, and a smoke duct with a membrane water-cooled wall cooling the flue.
  • the water-cooled wall rising pipe and the flue water-cooled wall descending pipe are connected to the flue drum.
  • the outlet end of the cooling flue is provided with a connecting flue.
  • the outlet of the connecting flue is connected to a separator for separating solid particles in the gas.
  • the cooling The flue includes an entrance section cooling flue.
  • the entrance section cooling flue is connected to the reactor.
  • the entrance section cooling flue is gradually tilted upward from the reactor.
  • the angle between the entrance section cooling flue and the horizontal direction is greater than or equal to 45 degrees and less than or equal to 60 degrees, the molten slag in the high-temperature flue gas in the entrance section cooling flue can flow back to the reaction furnace along the entrance section cooling flue.
  • the temperature of the flue gas at the outlet end of the cooling flue is controlled between 750°C and 1000°C.
  • the cooling medium is introduced into the flue to cool the flue gas entering the connecting flue to 600°C ⁇ 700°C; the flue gas outlet of the separator is connected to the steam superheater, and the superheater flue gas outlet of the steam superheater is connected to the fire tube boiler.
  • the boiler riser and boiler downcomers of the fire tube boiler are connected to the boiler drum.
  • the fire tube boiler is connected to the fire tube economizer through the transition smoke chamber.
  • the bottom of the fire tube economizer is provided with a flue gas outlet.
  • the discharge cylinder, the fire tube economizer is provided with an economizer water inlet pipe and an economizer water outlet pipe.
  • the economizer outlet pipe is connected to the fire tube boiler drum water supply pipe and the flue drum water supply pipe.
  • the fire tube boiler steam drum The package water supply pipe is connected to the fire tube boiler steam drum, the flue steam drum water supply pipe is connected to the flue steam drum, the flue steam drum is provided with a flue steam drum steam output pipe, and the fire tube boiler steam drum is provided with a saturated steam output pipe.
  • the flue drum steam output pipe and the saturated steam output pipe are convergently connected to the superheater steam input end of the steam superheater, and a superheated steam output pipe is provided on the steam superheater.
  • the cooling medium uses cooling water, or the flue gas output from the flue gas outlet of the flue gas discharge cylinder is desulfurized. And used as cooling medium after dust removal and purification.
  • the cooling medium in the connecting flue is injected through nozzles, and the nozzles are arranged at the top, bottom and both sides of the connecting flue.
  • the nozzles on the inner wall of the connecting flue, the top, the bottom and both sides of the connecting flue are all arranged at intervals along the length of the connecting flue.
  • the cooling flue also includes a roundabout section cooling section flue, and the roundabout section cooling flue includes vertical and The ascending section cooling flue and the descending section cooling flue are arranged in parallel intervals.
  • the upper ends of the ascending section cooling flue and the descending section cooling flue are connected by the transition section cooling flue.
  • the lower end of the ascending section cooling flue is connected with the inlet section cooling flue.
  • the upper end of the channel is connected, and the bottom of the descending section cooling flue is connected to the descending section smoke exhaust barrel.
  • a cooling flue ash outlet is set on the bottom of the descending section smoke exhaust barrel, and the connecting flue is connected to the descending section smoke exhaust barrel.
  • the transition section cooling flue includes: a mirror-image set of first-stage cooling flue and a second-stage cooling flue, and a first-stage cooling flue.
  • the cooling flue of the second section curves upward from the top of the cooling flue in the ascending section and towards the cooling flue in the descending section.
  • the cooling flue in the second section curves upward from the top of the cooling flue in the descending section and bends in the direction of the cooling flue in the ascending section.
  • the cooling flue in the turning section The cooling flue is connected to the second section of the cooling flue at the top.
  • two flue gas explosion-proof valves are provided at the top of the transition section cooling flue, and the two flue gas explosion-proof valves are respectively located in the cooling section of the corner.
  • the flue and the second cooling section of the turning flue are respectively located in the cooling section of the corner.
  • the heating tube in the steam superheater adopts a serpentine heating tube.
  • both the fire tube boiler and the fire tube economizer are vertical structures.
  • the advantages of the present invention are: 1.
  • the inlet section cooling flue is gradually tilted upward from one end of the reaction furnace, and the angle between the inlet section cooling flue and the horizontal direction is greater than or equal to 45 degrees and less than or equal to 60 degrees, which can make high-temperature smoke
  • the molten slag in the gas flows back into the reactor along the inlet cooling flue, thereby effectively reducing the amount of molten particulate matter in the high-temperature flue gas at the source of the waste heat recovery system, and effectively avoiding slagging in the waste heat recovery system equipment.
  • the waste heat recovery system uses a steam superheater.
  • the setting of the steam superheater greatly improves the heat recovery efficiency and reduces the temperature of the outlet flue gas. That is, the temperature of the final exhaust flue gas is effectively reduced. After the temperature is lowered, The flue gas can be directly purified by dry dust removal, such as direct bag dust removal, which effectively saves the cost of exhaust gas purification. 4.
  • Fire tube boilers and fire tube economizers are both vertical structures, adopt longitudinal flushing, and have good self-cleaning effect, which can effectively improve the heat exchange effect of heat exchange equipment and extend the service life of the equipment.
  • Figure 1 is a schematic structural diagram of the waste heat recovery system matched to the Hesmet smelting reduction ironmaking system according to the present invention.
  • FIG. 2 is a schematic structural diagram of the cooling flue in Figure 1.
  • the waste heat recovery system supporting the Hesmet smelting reduction ironmaking system includes: cooling flue 1 with a membrane water-cooled wall structure, and water-cooled flue with a membrane water-cooled wall for cooling flue 1
  • the wall rising pipe 21 and the flue water-cooled wall descending pipe 22 are connected to the flue drum 2 .
  • the cooling flue 1 includes an entrance section cooling flue 11.
  • the entrance section cooling flue 11 is connected to the reaction furnace 3.
  • the entrance section cooling flue 11 is gradually inclined upward from the reaction furnace 3.
  • the entrance section cooling flue 11 is oriented horizontally.
  • the angle ⁇ is greater than or equal to 45 degrees and less than or equal to 60 degrees.
  • the molten slag in the high-temperature flue gas in the inlet section cooling flue 11 can flow back to the reaction furnace 3 along the inlet section cooling flue 11.
  • the temperature of the flue gas at the outlet end of the cooling flue 1 is controlled to 750°C to 1000°C.
  • the cooling flue 1 also includes a circuitous section cooling section flue 12.
  • the circuitous section cooling flue 12 includes an ascending section cooling flue 121 and a descending section cooling flue 122 arranged vertically and in parallel.
  • the upper ends of the ascending section cooling flue 121 and the descending section cooling flue 122 are connected by the transition section cooling flue.
  • the lower end of the ascending section cooling flue 121 is connected with the upper end of the entrance section cooling flue 11.
  • the descending section cooling flue 122 A descending section smoke exhaust cylinder 123 is connected to the bottom, and a cooling flue ash outlet 124 is provided on the bottom of the descending section smoke exhaust cylinder 123 .
  • the descending section smoke exhaust cylinder 123 is connected to the connecting flue 4.
  • the transition section cooling flue includes: a first-stage cooling flue 125 and a second-stage cooling flue 126 arranged in mirror symmetry.
  • the first-stage cooling flue 125 and the second-stage cooling flue 126 are arranged in mirror symmetry for the purpose of : Easy to install and maintain, reducing manufacturing and production costs.
  • the cooling flue 125 of the first turning section goes upward from the top of the cooling flue 121 of the ascending section and bends in the direction of the cooling flue 122 of the descending section.
  • the cooling flue 126 of the second section of the turning starts from the top of the cooling flue 122 of the descending section and bends upward towards the cooling section of the ascending section.
  • the direction of the flue 121 is curved, and the first cooling flue 125 and the second cooling flue 126 are connected at the top.
  • Two smoke explosion-proof valves 127 are provided at the top of the transition section cooling flue. The two smoke explosion-proof valves 127 are respectively located on the cooling flue 125 of the first turning section and the cooling flue 126 of the second turning section.
  • the cooling medium is introduced into the connecting flue 4 to cool the flue gas entering the connecting flue 4 to 600°C to 700°C. At this temperature, the particles in the high-temperature flue gas can be completely cooled, that is, the particles are no longer molten from the core to the outer surface.
  • the cooling medium in the connecting flue 4 is sprayed by nozzles 41.
  • the nozzles 41 are arranged on the top, bottom and inner walls of the connecting flue on both sides of the connecting flue 4.
  • the top of the connecting flue 4 is The nozzles 41 on the inner wall of the connecting flue 4 at the bottom and both sides are spaced along the length direction of the connecting flue 4.
  • the cooling medium needs to ensure that the introduction of the cooling medium will not cause explosion, combustion or other safety issues in the connecting flue 4 .
  • the outlet of the connecting flue 4 is connected to a separator 5 for separating solid particles in the gas.
  • a separator ash hopper 51 is provided at the bottom of the separator 5 .
  • the separator 5 adopts a high temperature cyclone separator. The high-temperature cyclone separator can effectively remove particles and prevent them from scouring and abrading the waste heat recovery system.
  • the flue gas outlet of the separator 5 is connected to the steam superheater 6, and the superheater flue gas outlet of the steam superheater 6 is connected to the fire tube boiler 7.
  • a boiler rising pipe 711 is provided between the fire tube boiler 7 and the fire tube boiler drum 71. and the boiler downcomer 712.
  • the fire tube boiler 7 is connected to the fire tube economizer 9 through the transition section smoke chamber 8.
  • the bottom of the fire tube economizer 9 is provided with a flue gas discharge cylinder 91 with a flue gas discharge port 911, and the bottom of the flue gas discharge cylinder 91 is provided with a discharge cylinder ash hopper 912.
  • both the fire tube boiler 7 and the fire tube economizer 9 adopt a vertical structure.
  • the fire tube economizer 9 is provided with an economizer water inlet pipe 92 and an economizer water outlet pipe 93.
  • the economizer water outlet pipe 93 is connected to the fire tube boiler water supply pipe 713 and the flue drum water supply pipe 201.
  • the fire tube boiler water supply pipe 713 is connected to the fire tube boiler steam drum 71
  • the flue steam drum water supply pipe 201 is connected to the flue steam drum 2 .
  • the flue drum steam output pipe 23 is provided on the flue drum 2
  • the saturated steam output pipe 714 is provided on the fire tube boiler drum 71.
  • the flue drum steam output pipe 23 and the saturated steam output pipe 714 are collectively connected to the superheater steam input end 61 of the steam superheater 6 , and a superheated steam output pipe 62 is provided on the steam superheater 6 .
  • the cooling medium is cooling water, or the flue gas output from the flue gas discharge port 911 of the flue gas discharge cylinder 91 is used as the cooling medium after being purified by desulfurization and dust removal, and the flue gas discharged from the flue gas discharge port 911 is used as the cooling medium.
  • the cooling medium can effectively reduce the cost of waste heat recovery.
  • Flue range The high-temperature flue gas generated by the reactor 3 enters the cooling flue 1 through the entrance section cooling flue 11. Since the entrance section cooling flue 11 is tilted, the inclination angle ⁇ is greater than or equal to 45 degrees and less than or equal to 60 Therefore, the molten slag in the cooling flue 11 at the entrance section can flow back to the reaction furnace 3 very well. That is to say, the amount of molten ash entering the waste heat recovery system is greatly reduced at the entrance of the waste heat recovery system, thereby effectively reducing the risk of slagging in the waste heat recovery system.
  • the high-temperature flue gas enters the roundabout section cooling flue 12 through the inlet section cooling flue 11.
  • the high-temperature flue gas passes through the ascending section cooling flue 121, the first turning cooling flue 125, and the second turning section cooling in the roundabout section cooling flue 12.
  • the flue 126 and the descending section cooling flue 122 continuously release heat and then cool to 750°C to 1000°C, and then enter the descending section smoke exhaust barrel 123.
  • the ash in the descending section smoke exhaust cylinder 123 is discharged from the cooling flue ash outlet 124.
  • the high-temperature flue gas in the descending section smoke exhaust cylinder 123 enters the connecting flue 4.
  • the nozzle 41 in the connection flue 4 sprays cooling medium to further cool the high-temperature flue gas.
  • the cooling medium is cooling water or the flue gas output from the flue gas discharge port 911 of the flue gas discharge cylinder 91. Both of them can be used to cool down the high-temperature flue gas. High temperature flue gas is effectively cooled. Another advantage of using the exhaust gas output from the flue gas outlet 911 of the flue gas exhaust cylinder 91 for cooling is that it utilizes the exhaust gas and reduces the cost of waste heat recovery.
  • the high-temperature flue gas is further cooled to 600°C to 700°C in the connecting flue 4. At this temperature, the ash remaining in the high-temperature flue gas is further cooled until its core is no longer molten.
  • the high-temperature flue gas further cooled in the connecting flue 4 enters the separator 5 for solid particle separation.
  • the separator 5 separates the larger particle size particles from the high-temperature flue gas. Since the high-temperature flue gas is cooled for a second time in the connecting flue 4, the particles that still remain in the high-temperature flue gas after separation by the separator 5 are Since the core temperature of the particles has been further reduced, the particles are no longer molten from the outside to the core, which greatly reduces the possibility of the particles forming slagging in the waste heat recovery system.
  • the high-temperature flue gas separated by the separator 5 enters the steam superheater 6 through the flue gas outlet of the separator 5.
  • the steam superheater 6 adopts a serpentine heat exchange tube. Although the serpentine heat exchange tube bundle in the steam superheater 6 is densely packed, the particulate matter in the high-temperature flue gas output from the separator 5 has been completely cooled to the core and is no longer molten, that is, the particulate matter has been fully cooled. Such high-temperature flue gas enters The steam superheater 6 with a dense heat exchange tube bundle will not produce slagging on the heat exchange tube bundle of the steam superheater 6. This is the key to using the steam superheater 6 in this waste heat recovery system.
  • the use of the steam superheater 6 is effective
  • the heat recovery efficiency of the entire waste heat recovery system is improved, and the temperature of the flue gas discharged from the flue gas outlet 911 is greatly reduced.
  • the flue gas output by the steam superheater 6 enters the fire tube boiler 7, and the flue gas further releases heat in the fire tube boiler 7.
  • the flue gas output by the fire tube boiler 7 enters the fire tube economizer 9 through the transition section smoke chamber 8.
  • the flue gas after releasing heat in the tube economizer 9 is discharged outward from the flue gas discharge port 911 on the flue gas discharge cylinder 91.
  • a part of the flue gas discharged from the flue gas discharge port 911 can be used as a cooling medium in the connecting flue 4 .
  • the ash in the flue gas discharge cylinder 91 is discharged from the discharge cylinder ash hopper 912 .
  • the external water supply enters the fire tube economizer 9 through the fire tube economizer water inlet pipe 92, and the water that has absorbed heat in the fire tube economizer 9 enters through the economizer outlet pipe 93 and the fire tube boiler water supply pipe 713. It reaches the fire tube boiler drum 71 and enters the flue drum 2 through the economizer outlet pipe 93 and the flue drum water supply pipe 201.
  • the hot water in the fire tube boiler drum 71 enters the fire tube boiler 7 through the boiler downcomer 712.
  • the steam-water mixture formed after absorbing the heat of the flue gas in the fire tube boiler 7 enters the fire tube boiler drum 71 through the boiler riser tube 711. , the saturated steam generated by the fire tube boiler drum 71 is output from the saturated steam output pipe 714.
  • the hot water in the flue drum 2 enters the membrane water-cooling wall of the cooling flue 1 through the downcomer 22 of the flue water-cooling wall.
  • the hot water in the membrane water-cooling wall absorbs the heat of the high-temperature flue gas and forms steam through the flue gas.
  • the water-cooled wall rising pipe 21 enters the flue drum 2, and the saturated steam generated by the flue drum 2 is output through the flue drum steam output pipe 23.
  • the saturated steam output by the flue drum steam output pipe 23 and the saturated steam output by the fire tube boiler drum 71 through the saturated steam output pipe 714 converge and enter the steam superheater 6.
  • the saturated steam absorbs high-temperature smoke in the steam superheater 6.
  • the heat of the gas is then formed into superheated saturated steam that can be used to generate electricity, and is output through the hot steam output pipe 62.
  • the advantages of the present invention are: 1.
  • the inlet section cooling flue 11 is gradually tilted upward from one end of the reaction furnace 3, and the angle between the inlet section cooling flue 11 and the horizontal direction is greater than or equal to 45 degrees and less than or equal to 60 degrees, so that The molten slag in the high-temperature flue gas is allowed to flow back into the reaction furnace 3 along the inlet section cooling flue, thereby effectively reducing the amount of molten particulate matter in the high-temperature flue gas at the source of the waste heat recovery system, and thus effectively avoiding slagging on the waste heat recovery system equipment.
  • the phenomenon 2.
  • the waste heat recovery system uses a steam superheater.
  • the setting of the steam superheater greatly improves the heat recovery efficiency and reduces the temperature of the outlet flue gas, that is, the temperature of the flue gas discharged from the final flue gas outlet 911 is effectively
  • the flue gas can be directly purified by dry dust removal, such as direct bag dust removal, which effectively saves the cost of exhaust gas purification.
  • Fire tube boilers and fire tube economizers are both vertical structures, adopt longitudinal flushing, and have good self-cleaning effect, which can effectively improve the heat exchange effect of heat exchange equipment and extend the service life of the equipment.

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)

Abstract

Disclosed in the present invention is a waste-heat recovery system matching a HIsmelt smelting reduction ironmaking system, the waste-heat recovery system comprising: a cooling flue and a flue steam drum, wherein an outlet end of the cooling flue is provided with a connection flue, an outlet of the connection flue is connected to a separator, an inlet section of the cooling flue is connected to a reaction furnace, and a cooling medium is introduced into the connection flue to cool flue gas; and a flue gas outlet of the separator is connected to a steam superheater, a superheater flue gas outlet of the steam superheater is connected to a fire-tube boiler, a boiler ascending tube and a boiler descending tube of the fire-tube boiler are connected to a boiler steam drum, the fire-tube boiler is connected to a fire-tube economizer, a flue gas discharge cylinder body is arranged at the bottom of the fire-tube economizer, an economizer water output tube on the fire-tube economizer supplies water to the fire-tube boiler steam drum and the flue steam drum, and steam output by the flue steam drum and the fire-tube boiler steam drum is conveyed to the steam superheater, and the steam superheater is provided with a superheated steam output tube. The present invention can effectively prevent a slagging phenomenon and significantly improve thermal efficiency.

Description

配套于海斯梅特熔融还原炼铁体系的余热回收系统Waste heat recovery system supporting Hesmet smelting reduction ironmaking system 技术领域Technical field
本发明涉及余热回收系统,具体涉及配套于HISMELT熔融还原炼铁体系的余热回收系统。The invention relates to a waste heat recovery system, in particular to a waste heat recovery system matched to the HISMELT smelting reduction ironmaking system.
背景技术Background technique
HISMELT根据中文读音译成海斯梅特。HISMELT熔融还原炼铁技术是一种利用非焦煤及铁矿粉采取喷射方式生产液态铁的短流程炼铁技术。由于其不需要原有炼铁的焦炭流程、球团流程,直接采用煤粉、铁矿粉炼铁,因此具有原料适应性强、环境污染小,产品质量高的优点,工厂建设相对比较简单,有着极高的社会、经济价值、环境价值。熔融还原炼铁技术是在高炉炼铁技术上的一次技术提升,其中的余热回收系统是整个系统的关键部分。HISMELT is translated into Haismet according to the Chinese pronunciation. HISMELT smelting reduction ironmaking technology is a short-process ironmaking technology that uses non-coking coal and iron ore powder to produce liquid iron by injection. Because it does not require the original coke process and pellet process of ironmaking, and directly uses coal powder and iron ore powder to make iron, it has the advantages of strong raw material adaptability, low environmental pollution, and high product quality. The factory construction is relatively simple. It has extremely high social, economic and environmental value. Smelting reduction ironmaking technology is a technological improvement in blast furnace ironmaking technology, in which the waste heat recovery system is a key part of the entire system.
HISMELT熔融还原炼铁体系中的HISMELT反应炉、也称还原炉,产生压力接近1.0bar、温度在1450℃左右的高温烟气,高温烟气中含有CO、H 2等可燃气体,并且还含有大量熔融状态的粘结粉尘。HISMELT熔融还原炼铁系统中的余热回收系统将高温烟气中的热能转化成为蒸汽后进行发电。 The HISMELT reactor in the HISMELT smelting reduction ironmaking system, also known as the reduction furnace, produces high-temperature flue gas with a pressure close to 1.0 bar and a temperature of about 1450°C. The high-temperature flue gas contains combustible gases such as CO and H 2 , and also contains a large amount of Bonded dust in a molten state. The waste heat recovery system in the HISMELT smelting reduction ironmaking system converts the heat energy in the high-temperature flue gas into steam to generate electricity.
目前的HISMELT熔融还原炼铁系统中的余热回收系统,具体结构可参见中国专利申CN103773912A,主要包括:与还原炉相连接的烟道,烟道包括上升段和下降段,上升段烟道与下降段烟道的上端部之间通过过渡烟道连接,下降段烟道的下端部设置有连接烟道,连接烟道与高温旋风分离器相连接,高温旋风分离器的烟气出口与余热锅炉连接。还原炉产生的高温烟气依次通过上升段烟道、过渡段烟道、下降段烟道释放热量,然后经连接烟道进入高温旋风分离器中,高温旋风分离器将高温烟气中的大颗粒物脱除,脱除了大颗粒物的高温烟气再进入余热锅炉内进行热传递。The current waste heat recovery system in the HISMELT smelting reduction ironmaking system. The specific structure can be found in Chinese patent application CN103773912A. It mainly includes: a flue connected to the reduction furnace. The flue includes an ascending section and a descending section. The ascending section flue and the descending section The upper ends of the flue sections are connected by a transition flue, and the lower end of the descending flue section is provided with a connecting flue. The connecting flue is connected to the high-temperature cyclone separator, and the flue gas outlet of the high-temperature cyclone separator is connected to the waste heat boiler. . The high-temperature flue gas generated by the reduction furnace releases heat sequentially through the ascending flue, the transition flue, and the descending flue, and then enters the high-temperature cyclone separator through the connecting flue. The high-temperature cyclone separator removes large particles in the high-temperature flue gas. After removal, the high-temperature flue gas with large particles removed enters the waste heat boiler for heat transfer.
上述的HISMELT熔融还原炼铁体系中的余热回收系统在运行过程中存在以下技术问题:经高温旋风分离器脱除大颗粒物后的高温烟气中仍然含有较多颗粒直径较小的高温粘结粉尘,这种高温粘结粉尘颗粒的特点在于其表面温度相对较低、但其内部核心温度仍然很高,即残留在高温气体内的小粒径的粘结粉尘并没有完全冷却,这样的高温粘结粉尘十分容易粘结在余热锅炉内的换热管的管壁上,从而在换热管的管壁上形成结渣,且越积越多,容易导致大块脱落和堵塞。随着时间推移,余热锅炉的换热效果不断降低,安全隐患也越来越严重。The above-mentioned waste heat recovery system in the HISMELT smelting reduction ironmaking system has the following technical problems during operation: the high-temperature flue gas after removing large particles through the high-temperature cyclone separator still contains a large number of high-temperature bonded dust with smaller particle diameters. , the characteristic of this kind of high-temperature bonded dust particles is that their surface temperature is relatively low, but their internal core temperature is still very high, that is, the small-sized bonded dust remaining in the high-temperature gas has not been completely cooled. Such high-temperature bonded dust particles The agglomerated dust is very easy to adhere to the wall of the heat exchange tube in the waste heat boiler, thus forming slagging on the wall of the heat exchange tube, and more and more accumulated dust can easily lead to large pieces falling off and clogging. As time goes by, the heat exchange effect of waste heat boilers continues to decrease, and safety hazards become more and more serious.
发明内容Contents of the invention
本发明的目的是:提供一种配套于海斯梅特熔融还原炼铁体系的余热回收系统,该余热回收系统能解决高温烟气中的颗粒物在换热管的管壁上产生结渣的技术问题,并进一步大大提高热回收效率。The purpose of this invention is to provide a waste heat recovery system that is matched to the Hesmet smelting reduction ironmaking system. The waste heat recovery system can solve the technical problem of slagging on the walls of heat exchange tubes caused by particulate matter in high-temperature flue gases. , and further greatly improve the heat recovery efficiency.
为实现上述目的,本发明采用的技术方案是:配套于海斯梅特熔融还原炼铁体系的余热回收系统,包括:膜式水冷壁结构的冷却烟道,冷却烟道的膜式水冷壁的烟道水冷壁上升管与烟道水冷壁下降管连接至烟道汽包,冷却烟道的出口端设置有连接烟道,连接烟道的出口连接至用于分离气体中固体颗粒的分离器,冷却烟道包括入口段冷却烟道,入口段冷却烟道连接至反应炉,入口段冷却烟道由反应炉逐步倾斜向上设置,入口段冷却烟道与水平方向呈的角度大于等于45度且小于等于60度,入口段冷却烟道中高温烟气中熔融状态的炉渣能沿着入口段冷却烟道回流至反应炉中,冷却烟道的出口端的烟气的温度控制在750℃~1000℃,在连接烟道内通入冷却介质使得进入连接烟道内的烟气降温至600℃~700℃;分离器的烟气出口与蒸汽过热器相连接,蒸汽过热器的过热器烟气出口与火管锅炉连接,火管锅炉的锅炉上升管和锅炉下降管连接至锅炉汽包,火管锅炉通过过渡段烟室与火管省煤器连接,火管省煤器的底部设置有带烟气排出口的烟气排出筒体,火管省煤器上设置有省煤器进水管和省煤器出水管,省煤器出水管与火管锅炉汽包供水管以及烟道汽包供水管连接,火管锅炉汽包供水管连接至火管锅炉汽包,烟道汽包供水管连接至烟道汽包,烟道汽包上设置烟道汽包蒸汽输出管,火管锅炉汽包上设置有饱和蒸汽输出管,烟道汽包蒸汽输出管、饱和蒸汽输出管汇聚连接至蒸汽过热器的过热器蒸汽输入端,蒸汽过热器上设置过热蒸汽输出管。In order to achieve the above purpose, the technical solution adopted by the present invention is: a waste heat recovery system matched to the Hesmet smelting reduction ironmaking system, including: a cooling flue with a membrane water-cooled wall structure, and a smoke duct with a membrane water-cooled wall cooling the flue. The water-cooled wall rising pipe and the flue water-cooled wall descending pipe are connected to the flue drum. The outlet end of the cooling flue is provided with a connecting flue. The outlet of the connecting flue is connected to a separator for separating solid particles in the gas. The cooling The flue includes an entrance section cooling flue. The entrance section cooling flue is connected to the reactor. The entrance section cooling flue is gradually tilted upward from the reactor. The angle between the entrance section cooling flue and the horizontal direction is greater than or equal to 45 degrees and less than or equal to 60 degrees, the molten slag in the high-temperature flue gas in the entrance section cooling flue can flow back to the reaction furnace along the entrance section cooling flue. The temperature of the flue gas at the outlet end of the cooling flue is controlled between 750°C and 1000°C. The cooling medium is introduced into the flue to cool the flue gas entering the connecting flue to 600℃~700℃; the flue gas outlet of the separator is connected to the steam superheater, and the superheater flue gas outlet of the steam superheater is connected to the fire tube boiler. The boiler riser and boiler downcomers of the fire tube boiler are connected to the boiler drum. The fire tube boiler is connected to the fire tube economizer through the transition smoke chamber. The bottom of the fire tube economizer is provided with a flue gas outlet. The discharge cylinder, the fire tube economizer is provided with an economizer water inlet pipe and an economizer water outlet pipe. The economizer outlet pipe is connected to the fire tube boiler drum water supply pipe and the flue drum water supply pipe. The fire tube boiler steam drum The package water supply pipe is connected to the fire tube boiler steam drum, the flue steam drum water supply pipe is connected to the flue steam drum, the flue steam drum is provided with a flue steam drum steam output pipe, and the fire tube boiler steam drum is provided with a saturated steam output pipe. , the flue drum steam output pipe and the saturated steam output pipe are convergently connected to the superheater steam input end of the steam superheater, and a superheated steam output pipe is provided on the steam superheater.
进一步地,前述的配套于海斯梅特熔融还原炼铁体系的余热回收系统,其中,所述的冷却介质采用冷却水,或者将从烟气排出筒体的烟气排出口输出的烟气经脱硫和除尘净化后作为冷却介质。Further, in the aforementioned waste heat recovery system matched to the Hesmet smelting reduction ironmaking system, the cooling medium uses cooling water, or the flue gas output from the flue gas outlet of the flue gas discharge cylinder is desulfurized. And used as cooling medium after dust removal and purification.
进一步地,前述的配套于海斯梅特熔融还原炼铁体系的余热回收系统,其中,连接烟道内的冷却介质通过喷嘴喷射引入,所述的喷嘴设置在连接烟道内的顶部、底部以及两侧的连接烟道内壁上,连接烟道内的顶部、底部以及两侧的连接烟道内壁上的喷嘴都顺着连接烟道的长度方向间隔设置。Further, in the aforementioned waste heat recovery system matched to the Hesmet smelting reduction ironmaking system, the cooling medium in the connecting flue is injected through nozzles, and the nozzles are arranged at the top, bottom and both sides of the connecting flue. The nozzles on the inner wall of the connecting flue, the top, the bottom and both sides of the connecting flue are all arranged at intervals along the length of the connecting flue.
更进一步地,前述的配套于海斯梅特熔融还原炼铁体系的余热回收系统,其中,所述的冷却烟道还包括迂回段冷却段烟道,所述的迂回段冷却烟道包括竖直且平行间隔设置的上升段冷却烟道和下降段冷却烟道,上升段冷却烟道和下降段冷却烟道的上端部由过渡段冷却烟道连通,上升段冷却烟道的下端与入口段冷却烟道的上端连通,下降段冷却烟道的底部连接有下降段排烟筒体,下降段排烟筒体的底部上设置冷却烟道出灰斗,连接烟道与下降段 排烟筒体连接。Furthermore, in the aforementioned waste heat recovery system supporting the Hesmet smelting reduction ironmaking system, the cooling flue also includes a roundabout section cooling section flue, and the roundabout section cooling flue includes vertical and The ascending section cooling flue and the descending section cooling flue are arranged in parallel intervals. The upper ends of the ascending section cooling flue and the descending section cooling flue are connected by the transition section cooling flue. The lower end of the ascending section cooling flue is connected with the inlet section cooling flue. The upper end of the channel is connected, and the bottom of the descending section cooling flue is connected to the descending section smoke exhaust barrel. A cooling flue ash outlet is set on the bottom of the descending section smoke exhaust barrel, and the connecting flue is connected to the descending section smoke exhaust barrel.
更进一步地,前述的配套于海斯梅特熔融还原炼铁体系的余热回收系统,其中,过渡段冷却烟道包括:镜像设置的转弯一段冷却烟道和转弯二段冷却烟道,转弯一段冷却烟道由上升段冷却烟道的顶端向上、并向下降段冷却烟道方向弯曲,转弯二段冷却烟道由下降段冷却烟道的顶端向上并向上升段冷却烟道方向弯曲,转弯一段冷却烟道与转弯二段冷却烟道在顶部相连通。Furthermore, the aforementioned waste heat recovery system supporting the Hesmet smelting reduction ironmaking system, in which the transition section cooling flue includes: a mirror-image set of first-stage cooling flue and a second-stage cooling flue, and a first-stage cooling flue. The cooling flue of the second section curves upward from the top of the cooling flue in the ascending section and towards the cooling flue in the descending section. The cooling flue in the second section curves upward from the top of the cooling flue in the descending section and bends in the direction of the cooling flue in the ascending section. The cooling flue in the turning section The cooling flue is connected to the second section of the cooling flue at the top.
更进一步地,前述的配套于海斯梅特熔融还原炼铁体系的余热回收系统,其中,过渡段冷却烟道的顶部设置有两个烟气防爆阀,两个烟气防爆阀分别位于转弯一段冷却烟道与转弯二段冷却烟道上。Furthermore, in the aforementioned waste heat recovery system supporting the Hesmet smelting reduction ironmaking system, two flue gas explosion-proof valves are provided at the top of the transition section cooling flue, and the two flue gas explosion-proof valves are respectively located in the cooling section of the corner. The flue and the second cooling section of the turning flue.
进一步地,前述的配套于海斯梅特熔融还原炼铁体系的余热回收系统,其中,蒸汽过热器内的受热管采用蛇形受热管。Further, in the aforementioned waste heat recovery system matched to the Hesmet smelting reduction ironmaking system, the heating tube in the steam superheater adopts a serpentine heating tube.
更进一步地,前述的配套于海斯梅特熔融还原炼铁体系的余热回收系统,其中,火管锅炉与火管省煤器均为立式结构。Furthermore, in the aforementioned waste heat recovery system supporting the Hesmet smelting reduction ironmaking system, both the fire tube boiler and the fire tube economizer are vertical structures.
本发明的优点是:一、入口段冷却烟道由反应炉一端向上逐步倾斜向上设置,并且入口段冷却烟道与水平方向呈的角度大于等于45度且小于等于60度,这样能使得高温烟气中熔融状的炉渣沿入口段冷却烟道回流至反应炉中,从而在余热回收系统源头有效减少高温烟气中熔融状颗粒物的量,也就有效避免余热回收系统设备结渣的现象。二、将冷却烟道输出的高温烟气的温度控制在750℃~1000℃,并在连接烟道中喷入冷却介质对高温烟气进一部降温至600℃~700℃,这使得高温烟气中的颗粒物彻底冷却,即高温烟气中的颗粒物的内核也不再呈熔融状,这就能避免高温烟气进入换热设备后颗粒物粘附在换热管的管壁上而产生结渣现象,从而有效提高换热效果,并延长余热回收系统的使用寿命。三、基于前两点,余热回收系统采用蒸汽过热器,蒸汽过热器的设置大大提高了热回收效率,降低了出口烟气的温度,即使得最终排出的烟气的温度有效降低,温度降低后的烟气可以直接采用干法除尘的净化处理,如直接布袋除尘,这有效节约了废气的净化处理成本。四、火管锅炉、火管省煤器均为立式结构,采用纵向冲刷,自清灰效果好,这能有效提高换热设备的换热效果同时延长设备的使用寿命。The advantages of the present invention are: 1. The inlet section cooling flue is gradually tilted upward from one end of the reaction furnace, and the angle between the inlet section cooling flue and the horizontal direction is greater than or equal to 45 degrees and less than or equal to 60 degrees, which can make high-temperature smoke The molten slag in the gas flows back into the reactor along the inlet cooling flue, thereby effectively reducing the amount of molten particulate matter in the high-temperature flue gas at the source of the waste heat recovery system, and effectively avoiding slagging in the waste heat recovery system equipment. 2. Control the temperature of the high-temperature flue gas output from the cooling flue at 750°C to 1000°C, and spray cooling medium into the connecting flue to further cool the high-temperature flue gas to 600°C to 700°C, which makes the high-temperature flue gas The particles in the high-temperature flue gas are completely cooled, that is, the core of the particles in the high-temperature flue gas is no longer molten. This can prevent the particles from adhering to the wall of the heat exchange tube and causing slagging after the high-temperature flue gas enters the heat exchange equipment. , thereby effectively improving the heat exchange effect and extending the service life of the waste heat recovery system. 3. Based on the first two points, the waste heat recovery system uses a steam superheater. The setting of the steam superheater greatly improves the heat recovery efficiency and reduces the temperature of the outlet flue gas. That is, the temperature of the final exhaust flue gas is effectively reduced. After the temperature is lowered, The flue gas can be directly purified by dry dust removal, such as direct bag dust removal, which effectively saves the cost of exhaust gas purification. 4. Fire tube boilers and fire tube economizers are both vertical structures, adopt longitudinal flushing, and have good self-cleaning effect, which can effectively improve the heat exchange effect of heat exchange equipment and extend the service life of the equipment.
附图说明Description of the drawings
图1是本发明所述的配套于海斯梅特熔融还原炼铁体系的余热回收系统的结构示意图。Figure 1 is a schematic structural diagram of the waste heat recovery system matched to the Hesmet smelting reduction ironmaking system according to the present invention.
图2是图1中冷却烟道的结构示意图。Figure 2 is a schematic structural diagram of the cooling flue in Figure 1.
具体实施方式Detailed ways
下面结合附图和优选实施例对本发明作进一步的详细说明。The present invention will be further described in detail below with reference to the accompanying drawings and preferred embodiments.
如图1、图2所示,配套于海斯梅特熔融还原炼铁体系的余热回收系统,包括:膜式水冷壁结构的冷却烟道1,冷却烟道1的膜式水冷壁的烟道水冷壁上升管21与烟道水冷壁下降管22连接至烟道汽包2。冷却烟道1包括入口段冷却烟道11,入口段冷却烟道11与反应炉3相连接,入口段冷却烟道11由反应炉3逐步倾斜向上设置,入口段冷却烟道11与水平方向呈的角度θ大于等于45度且小于等于60度,入口段冷却烟道11中高温烟气中熔融状态的炉渣能沿着入口段冷却烟道11回流至反应炉3中。冷却烟道1的出口端的烟气的温度控制在至750℃~1000℃。As shown in Figure 1 and Figure 2, the waste heat recovery system supporting the Hesmet smelting reduction ironmaking system includes: cooling flue 1 with a membrane water-cooled wall structure, and water-cooled flue with a membrane water-cooled wall for cooling flue 1 The wall rising pipe 21 and the flue water-cooled wall descending pipe 22 are connected to the flue drum 2 . The cooling flue 1 includes an entrance section cooling flue 11. The entrance section cooling flue 11 is connected to the reaction furnace 3. The entrance section cooling flue 11 is gradually inclined upward from the reaction furnace 3. The entrance section cooling flue 11 is oriented horizontally. The angle θ is greater than or equal to 45 degrees and less than or equal to 60 degrees. The molten slag in the high-temperature flue gas in the inlet section cooling flue 11 can flow back to the reaction furnace 3 along the inlet section cooling flue 11. The temperature of the flue gas at the outlet end of the cooling flue 1 is controlled to 750°C to 1000°C.
本实施例中,冷却烟道1还包括迂回段冷却段烟道12,所述的迂回段冷却烟道12包括竖直且平行间隔设置的上升段冷却烟道121和下降段冷却烟道122,上升段冷却烟道121和下降段冷却烟道122的上端部由过渡段冷却烟道连通,上升段冷却烟道121的下端与入口段冷却烟道11的上端连通,下降段冷却烟道122的底部连接有下降段排烟筒体123,下降段排烟筒体123的底部上设置冷却烟道出灰斗124。下降段排烟筒体123与连接烟道4连接。In this embodiment, the cooling flue 1 also includes a circuitous section cooling section flue 12. The circuitous section cooling flue 12 includes an ascending section cooling flue 121 and a descending section cooling flue 122 arranged vertically and in parallel. The upper ends of the ascending section cooling flue 121 and the descending section cooling flue 122 are connected by the transition section cooling flue. The lower end of the ascending section cooling flue 121 is connected with the upper end of the entrance section cooling flue 11. The descending section cooling flue 122 A descending section smoke exhaust cylinder 123 is connected to the bottom, and a cooling flue ash outlet 124 is provided on the bottom of the descending section smoke exhaust cylinder 123 . The descending section smoke exhaust cylinder 123 is connected to the connecting flue 4.
本实施例中过渡段冷却烟道包括:镜像对称设置的转弯一段冷却烟道125和转弯二段冷却烟道126,转弯一段冷却烟道125和转弯二段冷却烟道126镜像对称设置其目的在于:便于安装和维修,降低制造生产成本。转弯一段冷却烟道125由上升段冷却烟道121的顶端向上、并向下降段冷却烟道122方向弯曲,转弯二段冷却烟道126由下降段冷却烟道122的顶端向上并向上升段冷却烟道121方向弯曲,转弯一段冷却烟道125与转弯二段冷却烟道126在顶部相连通。过渡段冷却烟道的顶部设置有两个烟气防爆阀127,两个烟气防爆阀127分别位于转弯一段冷却烟道125与转弯二段冷却烟道126上。In this embodiment, the transition section cooling flue includes: a first-stage cooling flue 125 and a second-stage cooling flue 126 arranged in mirror symmetry. The first-stage cooling flue 125 and the second-stage cooling flue 126 are arranged in mirror symmetry for the purpose of : Easy to install and maintain, reducing manufacturing and production costs. The cooling flue 125 of the first turning section goes upward from the top of the cooling flue 121 of the ascending section and bends in the direction of the cooling flue 122 of the descending section. The cooling flue 126 of the second section of the turning starts from the top of the cooling flue 122 of the descending section and bends upward towards the cooling section of the ascending section. The direction of the flue 121 is curved, and the first cooling flue 125 and the second cooling flue 126 are connected at the top. Two smoke explosion-proof valves 127 are provided at the top of the transition section cooling flue. The two smoke explosion-proof valves 127 are respectively located on the cooling flue 125 of the first turning section and the cooling flue 126 of the second turning section.
在连接烟道4内通入冷却介质使得进入连接烟道4内的烟气降温至600℃~700℃。该温度下高温烟气中的颗粒物能彻底冷却,即颗粒物从内核至外表面都不再呈熔融状。本实施例中连接烟道4内的冷却介质由喷嘴41喷射,所述的喷嘴41设置在连接烟道4内的顶部、底部以及两侧的连接烟道内壁上,连接烟道4内的顶部、底部以及两侧的连接烟道内壁上的喷嘴41都顺着连接烟道4的长度方向间隔设置。所述的冷却介质需要确保冷却介质的引入不会造成连接烟道4内发生爆炸、燃烧等安全问题。The cooling medium is introduced into the connecting flue 4 to cool the flue gas entering the connecting flue 4 to 600°C to 700°C. At this temperature, the particles in the high-temperature flue gas can be completely cooled, that is, the particles are no longer molten from the core to the outer surface. In this embodiment, the cooling medium in the connecting flue 4 is sprayed by nozzles 41. The nozzles 41 are arranged on the top, bottom and inner walls of the connecting flue on both sides of the connecting flue 4. The top of the connecting flue 4 is The nozzles 41 on the inner wall of the connecting flue 4 at the bottom and both sides are spaced along the length direction of the connecting flue 4. The cooling medium needs to ensure that the introduction of the cooling medium will not cause explosion, combustion or other safety issues in the connecting flue 4 .
连接烟道4的出口连接至用于分离气体中固体颗粒的分离器5。分离器5的底部设置有分离器灰斗51。所述的分离器5采用高温旋风分离器。高温旋风分离器能有效去除颗粒 物,避免颗粒物对余热回收系统产生冲刷和磨损。The outlet of the connecting flue 4 is connected to a separator 5 for separating solid particles in the gas. A separator ash hopper 51 is provided at the bottom of the separator 5 . The separator 5 adopts a high temperature cyclone separator. The high-temperature cyclone separator can effectively remove particles and prevent them from scouring and abrading the waste heat recovery system.
分离器5的烟气出口与蒸汽过热器6相连接,蒸汽过热器6的过热器烟气出口与火管锅炉7连接,火管锅炉7与火管锅炉汽包71之间设置锅炉上升管711和锅炉下降管712,火管锅炉7通过过渡段烟室8与火管省煤器9连接。火管省煤器9的底部设置有带烟气排出口911的烟气排出筒体91,烟气排出筒体91的底部设置排出筒体灰斗912。本实施例中,火管锅炉7与火管省煤器9都采用立式结构。火管省煤器9上设置有省煤器进水管92和省煤器出水管93,省煤器出水管93与火管锅炉供水管713以及烟道汽包供水管201连接。火管锅炉供水管713连接至火管锅炉汽包71,烟道汽包供水管201连接至烟道汽包2。烟道汽包2上设置烟道汽包蒸汽输出管23,火管锅炉汽包71上设置有饱和蒸汽输出管714。本实施例中烟道汽包蒸汽输出管23、饱和蒸汽输出管714汇聚连接至蒸汽过热器6的过热器蒸汽输入端61,蒸汽过热器6上设置过热蒸汽输出管62。所述的冷却介质为冷却水,或者将从烟气排出筒体91的烟气排出口911输出的烟气经脱硫和除尘净化后作为冷却介质,采用烟气排出口911中排出的烟气作为冷却介质能有效降低余热回收成本。The flue gas outlet of the separator 5 is connected to the steam superheater 6, and the superheater flue gas outlet of the steam superheater 6 is connected to the fire tube boiler 7. A boiler rising pipe 711 is provided between the fire tube boiler 7 and the fire tube boiler drum 71. and the boiler downcomer 712. The fire tube boiler 7 is connected to the fire tube economizer 9 through the transition section smoke chamber 8. The bottom of the fire tube economizer 9 is provided with a flue gas discharge cylinder 91 with a flue gas discharge port 911, and the bottom of the flue gas discharge cylinder 91 is provided with a discharge cylinder ash hopper 912. In this embodiment, both the fire tube boiler 7 and the fire tube economizer 9 adopt a vertical structure. The fire tube economizer 9 is provided with an economizer water inlet pipe 92 and an economizer water outlet pipe 93. The economizer water outlet pipe 93 is connected to the fire tube boiler water supply pipe 713 and the flue drum water supply pipe 201. The fire tube boiler water supply pipe 713 is connected to the fire tube boiler steam drum 71 , and the flue steam drum water supply pipe 201 is connected to the flue steam drum 2 . The flue drum steam output pipe 23 is provided on the flue drum 2, and the saturated steam output pipe 714 is provided on the fire tube boiler drum 71. In this embodiment, the flue drum steam output pipe 23 and the saturated steam output pipe 714 are collectively connected to the superheater steam input end 61 of the steam superheater 6 , and a superheated steam output pipe 62 is provided on the steam superheater 6 . The cooling medium is cooling water, or the flue gas output from the flue gas discharge port 911 of the flue gas discharge cylinder 91 is used as the cooling medium after being purified by desulfurization and dust removal, and the flue gas discharged from the flue gas discharge port 911 is used as the cooling medium. The cooling medium can effectively reduce the cost of waste heat recovery.
工作原理:烟程:反应炉3产生的高温烟气经入口段冷却烟道11进入至经冷却烟道1中,由于入口段冷却烟道11倾斜设置,倾角θ大于等于45度且小于等于60度,因此入口段冷却烟道11中的熔融状的炉渣能很好的回流至反应炉3中。也即在余热回收系统的入口处先大大减少进入余热回收系统中的熔融状灰渣的量,从而有效降低余热回收系统结渣的风险。Working principle: Flue range: The high-temperature flue gas generated by the reactor 3 enters the cooling flue 1 through the entrance section cooling flue 11. Since the entrance section cooling flue 11 is tilted, the inclination angle θ is greater than or equal to 45 degrees and less than or equal to 60 Therefore, the molten slag in the cooling flue 11 at the entrance section can flow back to the reaction furnace 3 very well. That is to say, the amount of molten ash entering the waste heat recovery system is greatly reduced at the entrance of the waste heat recovery system, thereby effectively reducing the risk of slagging in the waste heat recovery system.
高温烟气经入口段冷却烟道11进入迂回段冷却烟道12中,高温烟气在迂回段冷却烟道12中依次通过上升段冷却烟道121、转弯一段冷却烟道125、转弯二段冷却烟道126、下降段冷却烟道122,不断释放热量后降温至750℃~1000℃,然后进入下降段排烟筒体123。下降段排烟筒体123中的灰渣从冷却烟道出灰斗124中排出。下降段排烟筒体123中的高温烟气进入连接烟道4。The high-temperature flue gas enters the roundabout section cooling flue 12 through the inlet section cooling flue 11. The high-temperature flue gas passes through the ascending section cooling flue 121, the first turning cooling flue 125, and the second turning section cooling in the roundabout section cooling flue 12. The flue 126 and the descending section cooling flue 122 continuously release heat and then cool to 750°C to 1000°C, and then enter the descending section smoke exhaust barrel 123. The ash in the descending section smoke exhaust cylinder 123 is discharged from the cooling flue ash outlet 124. The high-temperature flue gas in the descending section smoke exhaust cylinder 123 enters the connecting flue 4.
连接烟道4中的喷嘴41喷出冷却介质对高温烟气进一步冷却,冷却介质采用冷却水或由烟气排出筒体91的烟气排出口911输出的烟气,这两者采都能将高温烟气有效降温。采用烟气排出筒体91的烟气排出口911输出的废气进行降温,还有一个好处则是:废气利用,降低余热回收成本。高温烟气在连接烟道4中进一步降温至600℃~700℃,该温度下高温烟气中残留的灰渣进一步冷却至其内核也不呈熔融状。The nozzle 41 in the connection flue 4 sprays cooling medium to further cool the high-temperature flue gas. The cooling medium is cooling water or the flue gas output from the flue gas discharge port 911 of the flue gas discharge cylinder 91. Both of them can be used to cool down the high-temperature flue gas. High temperature flue gas is effectively cooled. Another advantage of using the exhaust gas output from the flue gas outlet 911 of the flue gas exhaust cylinder 91 for cooling is that it utilizes the exhaust gas and reduces the cost of waste heat recovery. The high-temperature flue gas is further cooled to 600°C to 700°C in the connecting flue 4. At this temperature, the ash remaining in the high-temperature flue gas is further cooled until its core is no longer molten.
连接烟道4中进一步冷却后的高温烟气进入分离器5中进行固体颗粒分离。分离器5将较大粒径的颗粒物分离出高温烟气,由于在连接烟道4中高温烟气得到了第二次冷却,因 此经分离器5分离后仍然残存在高温烟气中的颗粒物,由于颗粒物的内核温度已经进一步降低,颗粒物的外表至内核都不再呈熔融状,这就大大降低了颗粒物在余热回收系统中形成结渣的可能性。The high-temperature flue gas further cooled in the connecting flue 4 enters the separator 5 for solid particle separation. The separator 5 separates the larger particle size particles from the high-temperature flue gas. Since the high-temperature flue gas is cooled for a second time in the connecting flue 4, the particles that still remain in the high-temperature flue gas after separation by the separator 5 are Since the core temperature of the particles has been further reduced, the particles are no longer molten from the outside to the core, which greatly reduces the possibility of the particles forming slagging in the waste heat recovery system.
经分离器5分离后的高温烟气经分离器5的烟气出口进入蒸汽过热器6,蒸汽过热器6采用蛇形换热管。虽然蒸汽过热器6中的蛇形换热管束密集,但分离器5输出的高温烟气中颗粒物已经完全冷却至内核也不再呈熔融状,也即颗粒物都充分冷却,这样的高温烟气进入换热管束密集的蒸汽过热器6,不会在蒸汽过热器6的换热管束上产生结渣,这正是本余热回收系统中能够采用蒸汽过热器6的关键所在,采用蒸汽过热器6有效提高了整个余热回收系统的热回收效率,并大大降低烟气排出口911排出的烟气的温度。蒸汽过热器6输出的烟气进入火管锅炉7,烟气在火管锅炉7中进一步释放热量,火管锅炉7输出的烟气经过渡段烟室8进入火管省煤器9,在火管省煤器9中释放热量后的烟气从烟气排出筒体91上的烟气排出口911向外排出,烟气排出口911排出的烟气一部分可作为连接烟道4内的冷却介质。烟气排出筒体91中的灰渣从排出筒体灰斗912中排出。The high-temperature flue gas separated by the separator 5 enters the steam superheater 6 through the flue gas outlet of the separator 5. The steam superheater 6 adopts a serpentine heat exchange tube. Although the serpentine heat exchange tube bundle in the steam superheater 6 is densely packed, the particulate matter in the high-temperature flue gas output from the separator 5 has been completely cooled to the core and is no longer molten, that is, the particulate matter has been fully cooled. Such high-temperature flue gas enters The steam superheater 6 with a dense heat exchange tube bundle will not produce slagging on the heat exchange tube bundle of the steam superheater 6. This is the key to using the steam superheater 6 in this waste heat recovery system. The use of the steam superheater 6 is effective The heat recovery efficiency of the entire waste heat recovery system is improved, and the temperature of the flue gas discharged from the flue gas outlet 911 is greatly reduced. The flue gas output by the steam superheater 6 enters the fire tube boiler 7, and the flue gas further releases heat in the fire tube boiler 7. The flue gas output by the fire tube boiler 7 enters the fire tube economizer 9 through the transition section smoke chamber 8. The flue gas after releasing heat in the tube economizer 9 is discharged outward from the flue gas discharge port 911 on the flue gas discharge cylinder 91. A part of the flue gas discharged from the flue gas discharge port 911 can be used as a cooling medium in the connecting flue 4 . The ash in the flue gas discharge cylinder 91 is discharged from the discharge cylinder ash hopper 912 .
水程:外部给水经火管省煤器进水管92进入火管省煤器9,在火管省煤器9中吸收了热量的水经省煤器出水管93、火管锅炉供水管713进入至火管锅炉汽包71中,经省煤器出水管93、烟道汽包供水管201进入烟道汽包2中。火管锅炉汽包71中的热水经锅炉下降管712进入火管锅炉7中,火管锅炉7中吸收了烟气热量后形成的汽水混合物经锅炉上升管711进入火管锅炉汽包71中,火管锅炉汽包71产生的饱和蒸汽从饱和蒸汽输出管714输出。Water process: The external water supply enters the fire tube economizer 9 through the fire tube economizer water inlet pipe 92, and the water that has absorbed heat in the fire tube economizer 9 enters through the economizer outlet pipe 93 and the fire tube boiler water supply pipe 713. It reaches the fire tube boiler drum 71 and enters the flue drum 2 through the economizer outlet pipe 93 and the flue drum water supply pipe 201. The hot water in the fire tube boiler drum 71 enters the fire tube boiler 7 through the boiler downcomer 712. The steam-water mixture formed after absorbing the heat of the flue gas in the fire tube boiler 7 enters the fire tube boiler drum 71 through the boiler riser tube 711. , the saturated steam generated by the fire tube boiler drum 71 is output from the saturated steam output pipe 714.
烟道汽包2内的热水经以及烟道水冷壁下降管22进入冷却烟道1的膜式水冷壁内,膜式水冷壁中的热水吸收了高温烟气的热量后形成蒸汽经烟道水冷壁上升管21进入烟道汽包2中,烟道汽包2产生饱和蒸汽经烟道汽包蒸汽输出管23输出。The hot water in the flue drum 2 enters the membrane water-cooling wall of the cooling flue 1 through the downcomer 22 of the flue water-cooling wall. The hot water in the membrane water-cooling wall absorbs the heat of the high-temperature flue gas and forms steam through the flue gas. The water-cooled wall rising pipe 21 enters the flue drum 2, and the saturated steam generated by the flue drum 2 is output through the flue drum steam output pipe 23.
烟道汽包蒸汽输出管23输出的饱和蒸汽、以及火管锅炉汽包71经饱和蒸汽输出管714输出的饱和蒸汽汇聚进入蒸汽过热器6中,饱和蒸汽在蒸汽过热器6中吸收了高温烟气的热量后形成能用于发电的过热饱和蒸汽、并经过热蒸汽输出管62输出。The saturated steam output by the flue drum steam output pipe 23 and the saturated steam output by the fire tube boiler drum 71 through the saturated steam output pipe 714 converge and enter the steam superheater 6. The saturated steam absorbs high-temperature smoke in the steam superheater 6. The heat of the gas is then formed into superheated saturated steam that can be used to generate electricity, and is output through the hot steam output pipe 62.
本发明的优点在于:一、入口段冷却烟道11由反应炉3一端向上逐步倾斜向上设置,并且入口段冷却烟道11与水平方向呈的角度大于等于45度且小于等于60度,这样能使得高温烟气中熔融状的炉渣沿入口段冷却烟道回流至反应炉3中,从而在余热回收系统源头有效减少高温烟气中熔融状颗粒物的量,也就有效避免余热回收系统设备结渣的现象。二、将冷却烟道输出的高温烟气的温度控制在750℃~1000℃,并在连接烟道4中喷入冷却 介质对高温烟气进一部降温至600℃~700℃,这使得高温烟气中的颗粒物彻底冷却,即高温烟气中的颗粒物的内核也不再呈熔融状,这就能避免高温烟气进入换热设备后颗粒物粘附在换热管的管壁上而产生结渣现象,从而有效提高换热效果,并延长余热回收系统的使用寿命。三、基于前两点,余热回收系统采用蒸汽过热器,蒸汽过热器的设置大大提高了热回收效率,降低了出口烟气的温度,即使得最终烟气排出口911排出的烟气的温度有效降低,温度降低后的烟气可以直接采用干法除尘的净化处理,如直接布袋除尘,这有效节约了废气的净化处理成本。四、火管锅炉、火管省煤器均为立式结构,采用纵向冲刷,自清灰效果好,这能有效提高换热设备的换热效果同时延长设备的使用寿命。The advantages of the present invention are: 1. The inlet section cooling flue 11 is gradually tilted upward from one end of the reaction furnace 3, and the angle between the inlet section cooling flue 11 and the horizontal direction is greater than or equal to 45 degrees and less than or equal to 60 degrees, so that The molten slag in the high-temperature flue gas is allowed to flow back into the reaction furnace 3 along the inlet section cooling flue, thereby effectively reducing the amount of molten particulate matter in the high-temperature flue gas at the source of the waste heat recovery system, and thus effectively avoiding slagging on the waste heat recovery system equipment. The phenomenon. 2. Control the temperature of the high-temperature flue gas output from the cooling flue at 750°C to 1000°C, and spray cooling medium into the connecting flue 4 to further cool the high-temperature flue gas to 600°C to 700°C, which makes the high-temperature flue gas The particulate matter in the flue gas is completely cooled, that is, the core of the particulate matter in the high-temperature flue gas is no longer molten. This can prevent the particles from adhering to the wall of the heat exchange tube after the high-temperature flue gas enters the heat exchange equipment and causing formation of condensation. slag phenomenon, thereby effectively improving the heat exchange effect and extending the service life of the waste heat recovery system. 3. Based on the first two points, the waste heat recovery system uses a steam superheater. The setting of the steam superheater greatly improves the heat recovery efficiency and reduces the temperature of the outlet flue gas, that is, the temperature of the flue gas discharged from the final flue gas outlet 911 is effectively After the temperature is lowered, the flue gas can be directly purified by dry dust removal, such as direct bag dust removal, which effectively saves the cost of exhaust gas purification. 4. Fire tube boilers and fire tube economizers are both vertical structures, adopt longitudinal flushing, and have good self-cleaning effect, which can effectively improve the heat exchange effect of heat exchange equipment and extend the service life of the equipment.

Claims (8)

  1. 配套于海斯梅特熔融还原炼铁体系的余热回收系统,包括:膜式水冷壁结构的冷却烟道,冷却烟道的膜式水冷壁的烟道水冷壁上升管与烟道水冷壁下降管连接至烟道汽包,冷却烟道的出口端设置有连接烟道,连接烟道的出口连接至用于分离气体中固体颗粒的分离器,其特征在于:冷却烟道包括入口段冷却烟道,入口段冷却烟道连接至反应炉,入口段冷却烟道由反应炉逐步倾斜向上设置,入口段冷却烟道与水平方向呈的角度大于等于45度且小于等于60度,入口段冷却烟道中高温烟气中熔融状态的炉渣能沿着入口段冷却烟道回流至反应炉中,冷却烟道的出口端的烟气的温度控制在750℃~1000℃,在连接烟道内通入冷却介质使得进入连接烟道内的烟气降温至600℃~700℃;分离器的烟气出口与蒸汽过热器相连接,蒸汽过热器的过热器烟气出口与火管锅炉连接,火管锅炉的锅炉上升管和锅炉下降管连接至锅炉汽包,火管锅炉通过过渡段烟室与火管省煤器连接,火管省煤器的底部设置有带烟气排出口的烟气排出筒体,火管省煤器上设置有省煤器进水管和省煤器出水管,省煤器出水管与火管锅炉汽包供水管以及烟道汽包供水管连接,火管锅炉汽包供水管连接至火管锅炉汽包,烟道汽包供水管连接至烟道汽包,烟道汽包上设置烟道汽包蒸汽输出管,火管锅炉汽包上设置有饱和蒸汽输出管,烟道汽包蒸汽输出管、饱和蒸汽输出管汇聚连接至蒸汽过热器的过热器蒸汽输入端,蒸汽过热器上设置过热蒸汽输出管。The waste heat recovery system supporting the Hesmet smelting reduction ironmaking system includes: a cooling flue with a membrane water-cooled wall structure, a flue water-cooled wall rising pipe connected to the flue water-cooled wall descending pipe of the membrane water-cooled cooling wall To the flue steam drum, the outlet end of the cooling flue is provided with a connecting flue, and the outlet of the connecting flue is connected to a separator for separating solid particles in the gas. It is characterized in that: the cooling flue includes an inlet section cooling flue, The cooling flue in the entrance section is connected to the reactor. The cooling flue in the entrance section is gradually tilted upward from the reactor. The angle between the cooling flue in the entrance section and the horizontal direction is greater than or equal to 45 degrees and less than or equal to 60 degrees. The high temperature in the cooling flue in the entrance section is The molten slag in the flue gas can flow back to the reaction furnace along the inlet cooling flue. The temperature of the flue gas at the outlet end of the cooling flue is controlled at 750°C ~ 1000°C. The cooling medium is introduced into the connecting flue to make it enter the connection. The flue gas in the flue is cooled to 600℃~700℃; the flue gas outlet of the separator is connected to the steam superheater, the superheater flue gas outlet of the steam superheater is connected to the fire tube boiler, and the boiler riser of the fire tube boiler is connected to the boiler The downcomer is connected to the boiler drum, and the fire tube boiler is connected to the fire tube economizer through the transition section smoke chamber. The bottom of the fire tube economizer is equipped with a flue gas discharge cylinder with a flue gas outlet. The fire tube economizer There is an economizer water inlet pipe and an economizer water outlet pipe. The economizer outlet pipe is connected to the fire tube boiler steam drum water supply pipe and the flue steam drum water supply pipe. The fire tube boiler steam drum water supply pipe is connected to the fire tube boiler steam drum water supply pipe. package, the flue drum water supply pipe is connected to the flue drum, the flue drum steam output pipe is provided on the flue drum, the fire tube boiler drum is provided with a saturated steam output pipe, the flue drum steam output pipe, The saturated steam output pipes are collectively connected to the superheater steam input end of the steam superheater, and a superheated steam output pipe is provided on the steam superheater.
  2. 根据权利要求1所述的配套于海斯梅特熔融还原炼铁体系的余热回收系统,其特征在于:所述的冷却介质采用冷却水,或者将从烟气排出筒体的烟气排出口输出的烟气经脱硫和除尘净化后作为冷却介质。The waste heat recovery system matched to the Hesmet smelting reduction ironmaking system according to claim 1, characterized in that: the cooling medium adopts cooling water, or is output from the flue gas outlet of the flue gas discharge cylinder. The flue gas is used as cooling medium after desulfurization and dust removal.
  3. 根据权利要求2所述配套于海斯梅特熔融还原炼铁体系的余热回收系统,其特征在于:连接烟道内的冷却介质通过喷嘴喷射引入,所述的喷嘴设置在连接烟道内的顶部、底部以及两侧的连接烟道内壁上,连接烟道内的顶部、底部以及两侧的连接烟道内壁上的喷嘴都顺着连接烟道的长度方向间隔设置。The waste heat recovery system matched to the Hesmet smelting reduction ironmaking system according to claim 2, characterized in that: the cooling medium in the connecting flue is injected through nozzles, and the nozzles are arranged at the top, bottom and bottom of the connecting flue. The nozzles on the inner walls of the connecting flue on both sides, the top and bottom of the connecting flue, and the inner walls of the connecting flue on both sides are spaced apart along the length of the connecting flue.
  4. 根据权利要求2或3所述的配套于海斯梅特熔融还原炼铁体系的余热回收系统,其特征在于:所述的冷却烟道还包括迂回段冷却段烟道,所述的迂回段冷却烟道包括竖直且平行间隔设置的上升段冷却烟道和下降段冷却烟道,上升段冷却烟道和下降段冷却烟道的上端部由过渡段冷却烟道连通,上升段冷却烟道的下端与入口段冷却烟道的上端连通,下降段冷却烟道的底部连接有下降段排烟筒体,下降段排烟筒体的底部上设置冷却烟道出灰斗,连接烟道与下降段排烟筒体连接。The waste heat recovery system matched to the Hesmet smelting reduction ironmaking system according to claim 2 or 3, characterized in that: the cooling flue further includes a roundabout section cooling section flue, and the roundabout section cooling flue The duct includes an ascending section cooling flue and a descending section cooling flue arranged vertically and parallelly. The upper ends of the ascending section cooling flue and the descending section cooling flue are connected by the transition section cooling flue. The lower end of the ascending section cooling flue It is connected with the upper end of the inlet section cooling flue. The bottom of the descending section cooling flue is connected to the descending section smoke exhaust barrel. The cooling flue ash outlet is set on the bottom of the descending section smoke exhaust barrel to connect the flue and the descending section smoke exhaust barrel. connect.
  5. 根据权利要求4所述的配套于海斯梅特熔融还原炼铁体系的余热回收系统,其特征在于:过渡段冷却烟道包括:镜像设置的转弯一段冷却烟道和转弯二段冷却烟道,转弯一段冷 却烟道由上升段冷却烟道的顶端向上、并向下降段冷却烟道方向弯曲,转弯二段冷却烟道由下降段冷却烟道的顶端向上并向上升段冷却烟道方向弯曲,转弯一段冷却烟道与转弯二段冷却烟道在顶部相连通。The waste heat recovery system supporting the Hesmet smelting reduction ironmaking system according to claim 4, characterized in that: the transition section cooling flue includes: a first-stage turning cooling flue and a second-stage turning cooling flue arranged in mirror images. One section of the cooling flue starts from the top of the ascending cooling flue and bends toward the direction of the descending cooling flue. The second cooling flue curves upward from the top of the descending cooling flue toward the ascending cooling flue. It turns. One section of the cooling flue is connected to the second section of the cooling flue at the top.
  6. 根据权利要求5所述的配套于海斯梅特熔融还原炼铁体系的余热回收系统,其特征在于:过渡段冷却烟道的顶部设置有两个烟气防爆阀,两个烟气防爆阀分别位于转弯一段冷却烟道与转弯二段冷却烟道上。The waste heat recovery system matched to the Hesmet smelting reduction ironmaking system according to claim 5, characterized in that: two flue gas explosion-proof valves are provided at the top of the transition section cooling flue, and the two flue gas explosion-proof valves are respectively located at On the first section of the cooling flue and the second section of the cooling flue.
  7. 根据权利要求1所述的配套于海斯梅特熔融还原炼铁体系的余热回收系统,其特征在于:蒸汽过热器内的受热管采用蛇形受热管。The waste heat recovery system matched to the Hesmet smelting reduction ironmaking system according to claim 1, characterized in that: the heating tube in the steam superheater adopts a serpentine heating tube.
  8. 根据权利要求1所述的配套于海斯梅特熔融还原炼铁体系的余热回收系统,其特征在于:火管锅炉与火管省煤器均为立式结构。The waste heat recovery system matched to the Hesmet smelting reduction ironmaking system according to claim 1, characterized in that: both the fire tube boiler and the fire tube economizer are vertical structures.
PCT/CN2022/143823 2022-03-14 2022-12-30 Waste-heat recovery system matching hismelt smelting reduction ironmaking system WO2023173902A1 (en)

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