WO2023098385A1 - Refrigerator and drawer assembly thereof - Google Patents

Refrigerator and drawer assembly thereof Download PDF

Info

Publication number
WO2023098385A1
WO2023098385A1 PCT/CN2022/129567 CN2022129567W WO2023098385A1 WO 2023098385 A1 WO2023098385 A1 WO 2023098385A1 CN 2022129567 W CN2022129567 W CN 2022129567W WO 2023098385 A1 WO2023098385 A1 WO 2023098385A1
Authority
WO
WIPO (PCT)
Prior art keywords
drawer
cathode membrane
cover plate
assembly
drawer assembly
Prior art date
Application number
PCT/CN2022/129567
Other languages
French (fr)
Chinese (zh)
Inventor
黄璐璐
费斌
苗建林
Original Assignee
青岛海尔电冰箱有限公司
海尔智家股份有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 青岛海尔电冰箱有限公司, 海尔智家股份有限公司 filed Critical 青岛海尔电冰箱有限公司
Publication of WO2023098385A1 publication Critical patent/WO2023098385A1/en

Links

Images

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D25/00Charging, supporting, and discharging the articles to be cooled
    • F25D25/02Charging, supporting, and discharging the articles to be cooled by shelves
    • F25D25/024Slidable shelves
    • F25D25/025Drawers
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/03Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
    • C25B11/031Porous electrodes
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • C25B9/23Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms comprising ion-exchange membranes in or on which electrode material is embedded
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D11/00Self-contained movable devices, e.g. domestic refrigerators
    • F25D11/02Self-contained movable devices, e.g. domestic refrigerators with cooling compartments at different temperatures
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D23/00General constructional features
    • F25D23/12Arrangements of compartments additional to cooling compartments; Combinations of refrigerators with other equipment, e.g. stove
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D25/00Charging, supporting, and discharging the articles to be cooled
    • F25D25/02Charging, supporting, and discharging the articles to be cooled by shelves
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Definitions

  • the invention relates to the field of refrigeration and freezing, in particular to a refrigerator and a drawer assembly thereof.
  • the deoxygenating module capable of deoxygenating the refrigerating drawer of the refrigerator.
  • the deoxygenating module is generally installed on the back of the refrigerating drawer, so that the items stored in the refrigerating drawer will inevitably be separated from the deoxidizer. Oxygen modules come into contact, affecting the deoxygenation effect, resulting in reduced work efficiency and a greatly reduced freshness preservation effect.
  • An object of the present invention is to overcome at least one defect in the prior art, and provide a refrigerator and a drawer assembly thereof.
  • a further object of the present invention is to improve the freshness preservation effect of the drawer assembly, and improve the reliability and stability of the electrolytic deoxidizer.
  • Another further object of the present invention is to ensure the smooth exchange of air and cathode membrane components, and improve the electrolysis efficiency of the electrolytic deoxygenation device.
  • the present invention provides a drawer assembly for a refrigerator, comprising: a cover plate; a drawer body with an upwardly open storage space, and the drawer body is pullably arranged under the cover plate so that when it When it is in the closed position, the cover plate covers the storage space; the electrolytic deoxygenation device is arranged on the cover plate and is configured to consume oxygen in the air in the storage space when the drawer body is in the closed position.
  • the cover plate is provided with an installation port; and the electrolytic deoxygenation device includes: a housing, fixed at the installation port, with an accommodating cavity inside; a cathode membrane assembly, arranged in the accommodating cavity, to accommodate The cavity separates the liquid storage chamber for containing the electrolyte and the ventilation chamber located below the liquid storage chamber.
  • the ventilation chamber communicates with the storage space through the air intake hole. Oxygen in the air entering the ventilation chamber; the anode plate is arranged in the liquid storage chamber at intervals from the cathode membrane assembly, and is configured to provide reactants to the cathode membrane assembly through an electrochemical reaction and generate electrolytic products.
  • the housing includes an upper shell portion and a lower shell portion, the upper shell portion and the lower shell portion are fastened together to define an accommodating cavity; and an overlapping portion is formed on the outer periphery of the lower shell portion, the overlapping portion On the edge of the installation opening, so that the bottom wall and part of the surrounding wall of the lower shell are below the cover plate, and the air intake hole is opened on the surrounding wall of the lower shell below the cover plate, so that the air in the storage space can enter the ventilation cavity.
  • a through hole is opened on the top of the upper shell; and the drawer assembly also includes: a cover body, which is arranged on the through hole, and the cover body has a liquid replenishment port for replenishing liquid to the liquid storage chamber and is used to generate the anode plate The exhaust port for the exit of the reactants.
  • the bottom wall of the lower shell is in an inclined state, and the lower shell is provided with a liquid discharge port downstream of the inclination of the bottom wall, so as to discharge the liquid in the ventilation cavity. Effusion.
  • the cathode membrane assembly includes: a fixed frame, which is horizontally fixed in the accommodating cavity, and the inside of the fixed frame is provided with an installation groove along the circumference; the cathode membrane group, and the periphery of the cathode membrane group is fixed in the installation groove, to It is fixedly arranged in the center of the fixed frame.
  • the cathode membrane group includes a catalytic layer, a first waterproof and breathable layer, a conductive layer and a second waterproof and breathable layer arranged in sequence from top to bottom;
  • the cathode tab is electrically connected to provide power to the cathode membrane stack.
  • the upper surface of the fixed frame is provided with a plurality of stepped positioning posts
  • the anode plate has a plurality of positioning holes
  • the positioning holes and the stepped positioning posts are matched one by one to fix the anode plate to the cathode membrane assembly at intervals.
  • the drawer assembly also includes: a cylinder body, which has a drawer space opened forward, and the drawer body can be pulled out or retracted into the drawer space; wherein the drawer assembly is also configured such that its cover plate serves as a roof.
  • the present invention also provides a refrigerator, which may include any one of the above-mentioned drawer assemblies.
  • the drawer body is arranged under the cover plate, and the electrolytic deoxygenation device is arranged on the cover plate, when the drawer body is in the closed position, the electrolytic deoxygenation device can consume the oxygen in the air in the storage space, reducing the drawer
  • the probability of interference between the items in the storage space of the main body and the electrolytic deoxygenation device increases the contact degree between the air in the storage space and the electrolytic deoxygenation device, and improves the freshness preservation effect.
  • placing the electrolytic deoxygenation device on the static cover can also reduce the influence of the movement of the drawer body on the assembly structure of the electrolytic deoxygenation device, and improve the reliability and reliability of the electrolytic deoxygenation device. stability.
  • the cathode membrane assembly is arranged in the housing cavity to separate the housing cavity into a liquid storage cavity and a ventilation cavity distributed up and down, the air in the storage space first passes through The air intake hole enters the ventilation cavity and contacts the cathode membrane assembly, so that the distance between the cathode membrane assembly and the object will not be too close, which can not only prevent the object from piercing the cathode membrane assembly, reduce the risk of electrolyte leakage, but also leave the cathode membrane
  • the air intake space under the components ensures smooth air exchange and improves electrolysis efficiency.
  • FIG. 1 is a schematic diagram of a refrigerator according to an embodiment of the present invention
  • FIG. 2 is a schematic diagram of a drawer assembly in a refrigerator according to an embodiment of the present invention.
  • FIG. 3 is an exploded view of a drawer assembly in a refrigerator according to one embodiment of the present invention.
  • FIG. 4 is a longitudinal sectional view of a drawer assembly in a refrigerator according to one embodiment of the present invention.
  • Fig. 5 is an exploded view of a housing and a cover in a drawer assembly according to an embodiment of the present invention
  • FIG. 6 is an exploded view of the cathode membrane assembly and the anode plate in the drawer assembly according to one embodiment of the present invention
  • Fig. 7 is an enlarged view of part A in Fig. 6;
  • FIG. 8 is an exploded view of a drawer assembly in a refrigerator according to another embodiment of the present invention.
  • FIG. 1 is a schematic diagram of a refrigerator 1 according to an embodiment of the present invention.
  • the present invention provides a refrigerator 1 , which generally includes a box body 10 and a door body 20 .
  • the box body 10 may include an outer shell and a plurality of liners, and the outer shell is located on the outermost side of the overall refrigerator 1 to protect the entire refrigerator 1 .
  • a plurality of inner tanks are wrapped by the outer shell, and the space between them and the outer shell is filled with thermal insulation material (forming a foam layer), so as to reduce the outward heat dissipation of the inner tanks.
  • Each liner can define a storage compartment that is open forward, and the storage compartment can be configured as a refrigerator, freezer, temperature-changing room, etc. The number and functions of the specific storage compartments can be based on prior needs to configure.
  • the door body 20 is movably arranged in front of the inner tank to open and close the storage compartment of the inner tank.
  • the door body 20 can be set on one side of the front of the box body 10 in a hinged manner, and can be opened and closed by pivoting. Storage room.
  • the refrigerator 1 may further include a drawer assembly 30 , which may be disposed in the box body 10 , and the user may open and close the drawer assembly 30 by pulling to get food therein.
  • a drawer assembly 30 which may be disposed in the box body 10 , and the user may open and close the drawer assembly 30 by pulling to get food therein.
  • FIG. 2 is a schematic diagram of the drawer assembly 30 in the refrigerator 1 according to an embodiment of the present invention
  • FIG. 3 is an exploded view of the drawer assembly 30 in the refrigerator 1 according to an embodiment of the present invention
  • the drawer assembly 30 may also include a cover plate 100, a drawer body 200, and an electro-deoxidizer 300.
  • the drawer body 200 has an upwardly open storage space 210, and the drawer body 200 is arranged under the cover plate 100 in a pullable manner, so as to When it is in the closed position, the cover plate 100 covers the storage space 210, and the electrolytic deoxygenation device 300 is arranged on the cover plate 100, and consumes the oxygen in the air in the storage space 210 when the drawer body 200 is in the closed position.
  • the cover plate 100 can be arranged in the box body 10, the drawer body 200 is located under the cover plate 100, and the drawer body 200 is operable to move between the pull-out position and the closed position.
  • the drawer body 200 is in the closed position In the above position, the storage space 210 is directly below the cover plate 100, so that the cover plate 100 can be used to cover the storage space 210 to prevent cold air from leaking out.
  • the electrolytic deoxygenation device 300 is arranged on the cover plate 100.
  • the air in the storage space 210 of the drawer body 200 can be in contact with the electrolytic deoxygenation device 300, so that the electrolytic deoxygenation device 300 can pass through
  • the electrochemical reaction separates oxygen from the air flowing through the storage space 210 , and leaves nitrogen in the storage space 210 of the drawer body 200 , so as to realize fresh-keeping storage of food.
  • the drawer body 200 of this embodiment adopts an electrolytic deoxidizer 300 arranged on the cover plate 100 used to cover the storage space 210, which can reduce the distance between the items in the storage space 210 and the The probability of interference from the electrolytic deoxygenation device 300 increases the degree of contact between the air in the storage space 210 and the electrolytic deoxygenation device 300 , improving the freshness preservation effect.
  • the electrolytic deoxygenation device 300 is set at The static cover plate 100 can also reduce the influence of the movement of the drawer body 200 on the assembly structure of the electrolytic deoxygenation device 300 and improve the reliability and stability of the electrolytic deoxygenation device 300 .
  • FIG. 4 is a longitudinal sectional view of the drawer assembly 30 in the refrigerator 1 according to one embodiment of the present invention
  • FIG. 5 is an exploded view of the housing and the cover 340 in the drawer assembly 30 according to one embodiment of the present invention. picture.
  • the cover plate 100 is provided with an installation opening 110
  • the electrolytic oxygen removal device 300 may further include a housing, a cathode membrane assembly 320 and an anode plate 330
  • the housing is fixed at the installation opening 110
  • the housing has a
  • the cathode membrane assembly 320 is arranged in the accommodating cavity, so as to separate the accommodating cavity into a liquid storage cavity 312 for containing electrolyte and a ventilation cavity 314 located below the liquid storage cavity 312, and the ventilation cavity 314 passes through the
  • the air hole 319 communicates with the storage space 210
  • the cathode membrane assembly 320 consumes oxygen in the air entering the ventilation chamber 314 from the air inlet 319 through an electrochemical reaction
  • the anode plate 330 and the cathode membrane assembly 320 are arranged in the liquid storage chamber at intervals Within 312, the anode plate 330 provides reactants (eg, electrons) to the cathode membrane assembly 320 through an electrochemical reaction and generates electrolysis products.
  • the cathode membrane assembly 320 can be horizontally fixed in the accommodation cavity of the casing, so that the accommodation cavity can be separated into a liquid storage chamber 312 distributed up and down and a ventilation chamber 314, and the ventilation chamber 314 is located below It can be close to the storage space 210 of the drawer body 200, so that the air in the storage space 210 can enter the ventilation cavity 314 through the air inlet hole 319, and finally contact with the cathode membrane assembly 320, and perform an electrochemical reaction.
  • the cathode membrane assembly 320 can define the liquid storage chamber 312 with the upper part of the casing, and the cathode membrane assembly 320 can be used as the lower wall of the liquid storage chamber 312, so that the air entering the ventilation chamber 314 can pass through the cathode membrane assembly 320 (cathode membrane assembly 320 has waterproof and breathable function) enters the liquid storage chamber 312, the cathode membrane assembly 320 can be loaded with the negative electrode of the external power supply, and the oxygen in the air can undergo a reduction reaction at the cathode membrane assembly 320 to generate negative ions, namely: O 2 +2H 2 O+ 4e ⁇ ⁇ 4OH ⁇ .
  • the anode plate 330 can be horizontally arranged in the liquid storage chamber 312 to be spaced from the cathode membrane assembly 320, and the anode plate 330 can be loaded with the positive pole of an external power supply. , which can be adjusted according to actual needs), the negative ions generated at the cathode membrane assembly 320 flow to the anode plate 330 under the action of the electric field, and an oxidation reaction occurs on the anode plate 330 to generate oxygen, namely: 4OH - ⁇ O 2 +2H 2 O+4e - .
  • the cathode membrane assembly 320 is arranged in the accommodation cavity of the casing, and separates the accommodation cavity into the liquid storage chamber 312 and the ventilation chamber 314 distributed up and down, the air in the storage space 210 first passes through The air inlet hole 319 enters the ventilation cavity 314 and contacts the cathode membrane assembly 320, so that the distance between the cathode membrane assembly 320 and the article will not be too close, which can not only prevent the article from piercing the cathode membrane assembly 320, reduce the risk of electrolyte leakage, and The air intake space under the cathode membrane assembly 320 can be reserved to ensure smooth air exchange and improve electrolysis efficiency.
  • the housing further includes an upper shell portion 316 and a lower shell portion 318, the upper shell portion 316 and the lower shell portion 318 are snapped together to define an accommodating cavity, and the lower shell portion
  • the outer periphery of 318 is formed with overlapping portion 318a, and overlapping portion 318a overlaps the edge of installation port 110, so that the bottom wall and part of the surrounding wall of lower shell portion 318 are below the cover plate 100, and the air inlet 319 is opened in the cover plate 100.
  • the surrounding wall of the lower shell portion 318 below the board 100 allows the air in the storage space 210 to enter the ventilation cavity 314 .
  • the upper shell portion 316 can be provided with a plurality of buckles 316b on its peripheral wall, and a plurality of snap grooves 318b are provided on the peripheral wall of the lower shell portion 318. It can extend into the lower shell part 318, and make a plurality of buckles 316b and a plurality of slots 318b match one by one, so as to fix the upper shell part 316 and the lower shell part 318, and define an accommodating cavity.
  • An overlapping portion 318a is formed on the outer periphery of the lower shell portion 318, and the overlapping portion 318a is overlapped on the edge of the installation opening 110 of the cover plate 100, so that the housing as a whole can be fixed at the installation opening 110, and the bottom of the lower housing portion 318
  • the wall and part of the surrounding wall sink into the bottom of the cover plate 100 from the installation port 110, and the number of air inlets 319 can be multiple, and they are distributed on the surrounding wall of the lower shell part 318 below the cover plate 100, which can facilitate the air intake holes 319. Being closer to the storage space 210 of the drawer body 200 facilitates the air in the storage space 210 to enter the ventilation cavity 314 .
  • a through hole 316a is opened on the top of the upper shell portion 316
  • the drawer assembly 30 may further include a cover 340, the cover 340 is disposed on the through hole 316a, and the cover 340 has a liquid supply port 342 for supplying liquid to the liquid storage chamber 312 and an exhaust port 344 for discharging reactants (oxygen) generated by the anode plate 330 .
  • There may also be a connection port at the through hole 316a, and the cover body 340 may be connected with the connection port through a sealing ring 346 so as to seal the through hole 316a.
  • the cathode membrane assembly 320 is horizontally fixed in the housing cavity to separate the liquid storage chamber 312 in the housing cavity, and the anode plate 330 is arranged in the liquid storage chamber 312.
  • the cathode membrane assembly 320 reduces the oxygen in the storage space 210 to negative ions, and the negative ions are oxidized to oxygen at the anode plate 330 (it can also be understood that the electrolytic deoxygenation device 300 can transfer the oxygen in the cathode membrane assembly 320 to the anode plate 330)
  • the top of the upper case 316 is provided with a through hole 316a, and the cover 340 is disposed in the through hole 316a.
  • the cover 340 has an exhaust port 344, that is, the exhaust port 344 is close to the anode plate 330, which can reduce or avoid electrolyte leakage. Leakage is also conducive to shortening the exhaust path, so that the oxygen generated by the anode plate 330 can be discharged in time, which is beneficial to the positive progress of the electrochemical reaction.
  • a liquid replenishment pipe and an oxygen discharge pipe can also be provided on the cover 340, and the oxygen discharge pipe can also extend into the liquid storage chamber 312, and its end is above the liquid level of the electrolyte, so that the oxygen discharge pipe is closer to the anode plate 330, so that the oxygen generated on the anode plate 330 overflows from the electrolyte and enters the oxygen exhaust pipe.
  • the overlapping portion 318a overlaps the edge of the installation opening 110, the bottom wall of the lower shell portion 318 is in an inclined state, and the lower shell portion 318 is provided with a The liquid discharge port 319a is used to discharge the accumulated liquid in the ventilation cavity 314 .
  • the cathode membrane assembly 320 can be used as the lower wall of the liquid storage chamber 312, and the ventilation chamber 314 can protect the cathode membrane assembly 320, and once the cathode membrane assembly 320 is damaged and ruptured, the ventilation chamber 314 can also collect the liquid that flows out of the liquid storage chamber 312.
  • the electrolytic solution further improves the safety and reliability of the electrolytic deoxygenation device 300.
  • the bottom wall of the lower shell portion 318 is in an inclined state, so that after the cathode membrane assembly 320 is damaged and ruptured, the electrolyte flows into the ventilation cavity 314 , and is guided to one side by the inclined bottom wall to facilitate discharge from the drain port 319a.
  • the drain port 319a is provided with a drain pipe 319b so as to be guided to the outside for collection.
  • FIG. 6 is an exploded view of the cathode membrane assembly 320 and the anode plate 330 in the drawer assembly 30 according to an embodiment of the present invention
  • FIG. 7 is an enlarged view of part A in FIG. 6
  • the cathode membrane assembly 320 may further include a fixed frame 322 and a cathode membrane group 324, the fixed frame 322 is horizontally fixed in the accommodating cavity, and the inner side of the fixed frame 322 is provided with a mounting groove 326 along the circumference, the cathode The peripheral edge of the membrane group 324 is fixed in the installation groove 326 so that it is fixedly disposed in the center of the fixing frame 322 .
  • the outer periphery of the fixed frame 322 can be fixed with the inner wall of the accommodating cavity, specifically, it can be fixed inside the upper shell portion 316.
  • the inner side of the fixed frame 322 is provided with an installation groove 326 along the circumference, and the periphery of the cathode membrane group 324 is fixed in the installation groove. 326, so that the cathode membrane group 324 can be tightened in the center of the fixed frame 322 to provide a bottom wall for the liquid storage chamber 312 stably.
  • the cathode membrane group 324 also includes a catalytic layer, a first waterproof and breathable layer, a conductive layer 328 and a second waterproof and breathable layer arranged in sequence from top to bottom.
  • the catalyst layer can use noble metal or rare metal catalyst, such as metal platinum, metal gold, metal silver, metal manganese or metal rubidium and so on.
  • the first waterproof and gas-permeable layer and the second waterproof and gas-permeable layer can be waterproof and gas-permeable membranes, so that the electrolyte cannot seep out from the liquid storage chamber 312, and air can enter the liquid storage chamber through the first waterproof and gas-permeable layer and the second waterproof and gas-permeable layer 312.
  • the conductive layer 328 can be made into a corrosion-resistant metal current collector, such as metal nickel, metal titanium, etc., so that it not only has better conductivity, corrosion resistance and supporting strength.
  • the conductive layer 328 also has an extension portion 328 a , and the extension portion 328 a passes through the installation slot 326 and is electrically connected to the cathode contact sheet 352 to provide electricity to the cathode film group 324 .
  • the fixed frame 322 can also be provided with a protruding portion 322a on one side, and the extension portion 328a of the conductive layer 328 passes through the installation groove 326 and enters the inside of the protruding portion 322a of the fixed frame 322, and the inside of the protruding portion 322a can also be provided with Cathode connecting piece 352, a part of cathode connecting piece 352 is pressed on the extension 328a of the conductive layer 328, and the other part protrudes outward from the protrusion 322a of the fixed frame 322, so as to be connected to the negative pole of the external power supply.
  • the anode plate 330 can be made of materials with strong corrosion resistance and reducibility, such as metal foam nickel, nickel mesh, etc., and one side of the anode plate 330 can also be connected to the anode electrode 354, and the anode electrode 354 can extend out of the shell. Body, in order to facilitate the positive connection of the external power supply.
  • the upper surface of the fixed frame 322 is provided with a plurality of stepped positioning columns 329, and the anode plate 330 has a plurality of positioning holes 332, and the positioning holes 332 are matched with the stepped positioning columns 329 one by one,
  • the anode plate 330 is fixed above the cathode membrane assembly 320 at intervals.
  • Each step positioning column 329 can have a support portion 329a and a fixed portion 329b, the support portion 329a is coaxially arranged with the fixed portion 329b, and the diameter of the support portion 329a is larger than the fixed portion 329b, and the diameter of the fixed portion 329b matches the positioning hole 332, so that
  • the positioning hole 332 is matched with the fixed portion 329b of the step positioning column 329, the anode plate 330 is lapped on the support portion 329a of the step positioning column 329, which not only realizes fixing the anode plate 330, but also enables the connection between the anode plate 330 and the cathode membrane assembly 320 Keep a certain distance between them to prevent short circuit.
  • a distance of 5mm to 10mm can be maintained between the anode plate 330 and the cathode membrane assembly 320, which can avoid the gap between the anode plate 330 and the cathode membrane assembly 320 If the distance is too large, the reaction efficiency will be low, and the oxygen generated by the anode plate 330 cannot be discharged in time due to the small distance, which will affect the reaction process.
  • FIG. 8 is an exploded view of a drawer assembly 30 in a refrigerator 1 according to another embodiment of the present invention.
  • the drawer assembly 30 may also include a barrel body 360, the barrel body 360 has a drawing space open forward, the drawer body 200 can be pulled out or retracted into the drawer space, and the drawer assembly 30 is also configured so that Its cover plate 100 serves as the top plate of the drawing space.
  • the cover plate 100 can not only be used independently to cover the storage space 210 of the drawer body 200, but also can be used as the top plate of the drawer space, so that the drawer body 200 as a whole can be pulled out or retracted into the drawer space,
  • the drawer body 200 When in the closed position, the drawer body 200 can be placed in the cylinder body 360 as a whole, and the top plate of the cylinder body 360 (ie, the cover plate 100 ) covers the storage space 210, and the electrolytic deoxygenation device arranged on the cylinder body 360 top plate 300 consumes oxygen in the air in storage space 210 .

Abstract

Provided are a refrigerator (1) and a drawer assembly (30) thereof. The drawer assembly (30) comprises a cover plate (100), a drawer body (200) and an electrolytic oxygen removal device (300), wherein the drawer body (200) is provided with a storage space (210) opened upwards, and the drawer body (200) is arranged below the cover plate (100) in a drawable manner, so that when the drawer body (200) is in a closed position, the cover plate (100) covers the storage space (210); and the electrolytic oxygen removal device (300) is arranged on the cover plate (100) and is configured to consume oxygen in the air in the storage space (210) when the drawer body (200) is in the closed position. By means of the drawer assembly (30), the electrolytic oxygen removal device (300) is arranged on the cover plate (100), so that the probability of interference between objects and the electrolytic oxygen removal device (300) is reduced, the degree of contact between the air in the storage space (210) and the electrolytic oxygen removal device (300) is increased, and a freshness-preservation effect is improved.

Description

冰箱及其抽屉组件Refrigerator and its drawer assembly 技术领域technical field
本发明涉及冷藏冷冻领域,特别是涉及一种冰箱及其抽屉组件。The invention relates to the field of refrigeration and freezing, in particular to a refrigerator and a drawer assembly thereof.
背景技术Background technique
现有技术中出现了能够对冰箱的制冷抽屉进行除氧的除氧模块,为了不影响制冷抽屉抽拉,除氧模块一般设置在制冷抽屉的背部,这样制冷抽屉内存储的物品难免会与除氧模块发生接触,影响除氧效果,导致工作效率降低,保鲜效果也大打折扣。In the prior art, there is a deoxygenation module capable of deoxygenating the refrigerating drawer of the refrigerator. In order not to affect the drawing of the refrigerating drawer, the deoxygenating module is generally installed on the back of the refrigerating drawer, so that the items stored in the refrigerating drawer will inevitably be separated from the deoxidizer. Oxygen modules come into contact, affecting the deoxygenation effect, resulting in reduced work efficiency and a greatly reduced freshness preservation effect.
发明内容Contents of the invention
本发明的一个目的旨在克服现有技术中的至少一个缺陷,提供一种冰箱及其抽屉组件。An object of the present invention is to overcome at least one defect in the prior art, and provide a refrigerator and a drawer assembly thereof.
本发明一个进一步的目的是要提升抽屉组件的保鲜效果,并提高电解除氧装置的可靠性和稳定性。A further object of the present invention is to improve the freshness preservation effect of the drawer assembly, and improve the reliability and stability of the electrolytic deoxidizer.
本发明另一个进一步的目的是要保证空气与阴极膜组件交换畅通,提高电解除氧装置的电解效率。Another further object of the present invention is to ensure the smooth exchange of air and cathode membrane components, and improve the electrolysis efficiency of the electrolytic deoxygenation device.
特别地,本发明提供了一种用于冰箱的抽屉组件,包括:盖板;抽屉本体,其具有向上敞开的储物空间,抽屉本体可抽拉地设置于盖板的下方,以使当其处于关闭位置时,盖板封盖储物空间;电解除氧装置,设置于盖板,配置成当抽屉本体处于关闭位置时消耗储物空间内空气中的氧气。In particular, the present invention provides a drawer assembly for a refrigerator, comprising: a cover plate; a drawer body with an upwardly open storage space, and the drawer body is pullably arranged under the cover plate so that when it When it is in the closed position, the cover plate covers the storage space; the electrolytic deoxygenation device is arranged on the cover plate and is configured to consume oxygen in the air in the storage space when the drawer body is in the closed position.
可选地,盖板开设有安装口;且电解除氧装置包括:壳体,固定于安装口处,其内具有容置空腔;阴极膜组件,设置于容置空腔,以将容置空腔分隔出用于盛装电解液的储液腔和位于储液腔下方的通风腔,通风腔通过进气孔与储物空间相连通,阴极膜组件配置成通过电化学反应消耗从进气孔进入通风腔的空气中的氧气;阳极板,与阴极膜组件间隔地设置于储液腔内,配置成通过电化学反应向阴极膜组件提供反应物且生成电解产物。Optionally, the cover plate is provided with an installation port; and the electrolytic deoxygenation device includes: a housing, fixed at the installation port, with an accommodating cavity inside; a cathode membrane assembly, arranged in the accommodating cavity, to accommodate The cavity separates the liquid storage chamber for containing the electrolyte and the ventilation chamber located below the liquid storage chamber. The ventilation chamber communicates with the storage space through the air intake hole. Oxygen in the air entering the ventilation chamber; the anode plate is arranged in the liquid storage chamber at intervals from the cathode membrane assembly, and is configured to provide reactants to the cathode membrane assembly through an electrochemical reaction and generate electrolytic products.
可选地,壳体包括上壳部和下壳部,上壳部与下壳部相扣合以限定出容置空腔;且下壳部的外周形成有搭接部,搭接部搭接于安装口的边缘,以使下壳部的底壁以及部分周壁处于盖板的下方,进气孔开设于处于盖板下方的下壳部周壁,以便储物空间内的空气进入通风腔。Optionally, the housing includes an upper shell portion and a lower shell portion, the upper shell portion and the lower shell portion are fastened together to define an accommodating cavity; and an overlapping portion is formed on the outer periphery of the lower shell portion, the overlapping portion On the edge of the installation opening, so that the bottom wall and part of the surrounding wall of the lower shell are below the cover plate, and the air intake hole is opened on the surrounding wall of the lower shell below the cover plate, so that the air in the storage space can enter the ventilation cavity.
可选地,上壳部的顶部开设有通孔;且抽屉组件还包括:盖体,设置于通孔上,并且盖体具有用于向储液腔补液的补液口以及用于将阳极板产生的反应物排出的排气口。Optionally, a through hole is opened on the top of the upper shell; and the drawer assembly also includes: a cover body, which is arranged on the through hole, and the cover body has a liquid replenishment port for replenishing liquid to the liquid storage chamber and is used to generate the anode plate The exhaust port for the exit of the reactants.
可选地,当搭接部搭接于安装口的边缘时,下壳部的底壁处于倾斜状态,并且下壳部在其底壁倾斜下游处设置有排液口,以便排出通风腔内的积液。Optionally, when the overlapping portion overlaps the edge of the installation opening, the bottom wall of the lower shell is in an inclined state, and the lower shell is provided with a liquid discharge port downstream of the inclination of the bottom wall, so as to discharge the liquid in the ventilation cavity. Effusion.
可选地,阴极膜组件包括:固定框架,水平地固定于容置空腔内,固定框架的内侧沿周向开设有安装槽;阴极膜组,阴极膜组的周缘固定于安装槽内,以使其固定设置于固定框架的中央。Optionally, the cathode membrane assembly includes: a fixed frame, which is horizontally fixed in the accommodating cavity, and the inside of the fixed frame is provided with an installation groove along the circumference; the cathode membrane group, and the periphery of the cathode membrane group is fixed in the installation groove, to It is fixedly arranged in the center of the fixed frame.
可选地,阴极膜组包括自上而下依次设置的催化层、第一防水透气层、导电层和第二防水透气层;且导电层具有延伸部,延伸部向外穿过安装槽并与阴极接电片电连接,以为阴极膜组供电。Optionally, the cathode membrane group includes a catalytic layer, a first waterproof and breathable layer, a conductive layer and a second waterproof and breathable layer arranged in sequence from top to bottom; The cathode tab is electrically connected to provide power to the cathode membrane stack.
可选地,固定框架的上表面设置有多个台阶定位柱,阳极板上具有多个定位孔,定位孔与台阶定位柱一一对应地配合,以将阳极板间隔地固定于阴极膜组件的上方。Optionally, the upper surface of the fixed frame is provided with a plurality of stepped positioning posts, and the anode plate has a plurality of positioning holes, and the positioning holes and the stepped positioning posts are matched one by one to fix the anode plate to the cathode membrane assembly at intervals. above.
可选地,抽屉组件还包括:筒体,其具有向前敞开的抽拉空间,抽屉本体可拉出或缩进于抽拉空间;其中抽屉组件还配置成使其盖板作为抽拉空间的顶板。Optionally, the drawer assembly also includes: a cylinder body, which has a drawer space opened forward, and the drawer body can be pulled out or retracted into the drawer space; wherein the drawer assembly is also configured such that its cover plate serves as a roof.
特别地,本发明还提供了一种冰箱,该冰箱可包括上述任一项的抽屉组件。In particular, the present invention also provides a refrigerator, which may include any one of the above-mentioned drawer assemblies.
本发明的抽屉组件,由于抽屉本体设置于盖板的下方,电解除氧装置设置于盖板,因此当抽屉本体处于关闭位置时电解除氧装置能够消耗储物空间内空气中的氧气,降低抽屉本体的储物空间内物品与电解除氧装置产生干涉的概率,提升储物空间内的空气与电解除氧装置的接触度,提升保鲜效果。此外,由于抽屉本体属于频繁运动部件,因此将电解除氧装置设置在处于静态的盖板也可以降低由于抽屉本体运动对电解除氧装置的装配结构的影响,提高电解除氧装置的可靠性和稳定性。In the drawer assembly of the present invention, since the drawer body is arranged under the cover plate, and the electrolytic deoxygenation device is arranged on the cover plate, when the drawer body is in the closed position, the electrolytic deoxygenation device can consume the oxygen in the air in the storage space, reducing the drawer The probability of interference between the items in the storage space of the main body and the electrolytic deoxygenation device increases the contact degree between the air in the storage space and the electrolytic deoxygenation device, and improves the freshness preservation effect. In addition, since the drawer body is a frequently moving part, placing the electrolytic deoxygenation device on the static cover can also reduce the influence of the movement of the drawer body on the assembly structure of the electrolytic deoxygenation device, and improve the reliability and reliability of the electrolytic deoxygenation device. stability.
进一步地,本发明的抽屉组件,由于阴极膜组件设置在壳体的容置空腔内,以将容置空腔分隔出上下分布的储液腔和通风腔,储物空间内的空气先通过进气孔进入通风腔中与阴极膜组件相接触,这样可使阴极膜组件与物品距离不会过近,不仅能够防止物品刺破阴极膜组件,降低电解液泄漏风险,而且可以留出阴极膜组件下方的进气空间,保证空气交换畅通,提高电解效 率。Further, in the drawer assembly of the present invention, since the cathode membrane assembly is arranged in the housing cavity to separate the housing cavity into a liquid storage cavity and a ventilation cavity distributed up and down, the air in the storage space first passes through The air intake hole enters the ventilation cavity and contacts the cathode membrane assembly, so that the distance between the cathode membrane assembly and the object will not be too close, which can not only prevent the object from piercing the cathode membrane assembly, reduce the risk of electrolyte leakage, but also leave the cathode membrane The air intake space under the components ensures smooth air exchange and improves electrolysis efficiency.
根据下文结合附图对本发明具体实施例的详细描述,本领域技术人员将会更加明了本发明的上述以及其他目的、优点和特征。Those skilled in the art will be more aware of the above and other objects, advantages and features of the present invention according to the following detailed description of specific embodiments of the present invention in conjunction with the accompanying drawings.
附图说明Description of drawings
后文将参照附图以示例性而非限制性的方式详细描述本发明的一些具体实施例。附图中相同的附图标记标示了相同或类似的部件或部分。本领域技术人员应该理解,这些附图未必是按比例绘制的。附图中:Hereinafter, some specific embodiments of the present invention will be described in detail by way of illustration and not limitation with reference to the accompanying drawings. The same reference numerals in the drawings designate the same or similar parts or parts. Those skilled in the art will appreciate that the drawings are not necessarily drawn to scale. In the attached picture:
图1是根据本发明一个实施例的冰箱的示意图;FIG. 1 is a schematic diagram of a refrigerator according to an embodiment of the present invention;
图2是根据本发明一个实施例的冰箱中抽屉组件的示意图;2 is a schematic diagram of a drawer assembly in a refrigerator according to an embodiment of the present invention;
图3是根据本发明一个实施例的冰箱中抽屉组件的分解图;3 is an exploded view of a drawer assembly in a refrigerator according to one embodiment of the present invention;
图4是根据本发明一个实施例的冰箱中抽屉组件的纵向截面图;4 is a longitudinal sectional view of a drawer assembly in a refrigerator according to one embodiment of the present invention;
图5是根据本发明一个实施例的抽屉组件中壳体与盖体的分解图;Fig. 5 is an exploded view of a housing and a cover in a drawer assembly according to an embodiment of the present invention;
图6是根据本发明一个实施例的抽屉组件中阴极膜组件与阳极板的分解图;6 is an exploded view of the cathode membrane assembly and the anode plate in the drawer assembly according to one embodiment of the present invention;
图7是图6中A部放大图;Fig. 7 is an enlarged view of part A in Fig. 6;
图8是根据本发明另一个实施例的冰箱中抽屉组件的分解图。FIG. 8 is an exploded view of a drawer assembly in a refrigerator according to another embodiment of the present invention.
具体实施方式Detailed ways
下面将参照附图更详细地描述本公开的示例性实施例。虽然附图中显示了本公开的示例性实施例,然而应当理解,可以以各种形式实现本公开而不应被这里阐述的实施例所限制。相反,提供这些实施例是为了能够更透彻地理解本公开,并且能够将本公开的范围完整的传达给本领域的技术人员。Exemplary embodiments of the present disclosure will be described in more detail below with reference to the accompanying drawings. Although exemplary embodiments of the present disclosure are shown in the drawings, it should be understood that the present disclosure may be embodied in various forms and should not be limited by the embodiments set forth herein. Rather, these embodiments are provided for more thorough understanding of the present disclosure and to fully convey the scope of the present disclosure to those skilled in the art.
请参见图1,图1是根据本发明一个实施例的冰箱1的示意图。本发明提供一种冰箱1,其一般性地可包括箱体10和门体20。Please refer to FIG. 1 , which is a schematic diagram of a refrigerator 1 according to an embodiment of the present invention. The present invention provides a refrigerator 1 , which generally includes a box body 10 and a door body 20 .
箱体10可以包括外壳和多个内胆,外壳位于整体冰箱1的最外侧,以保护整个冰箱1。多个内胆被外壳包裹,并且与外壳之间的空间中填充有保温材料(形成发泡层),以降低内胆向外散热。每个内胆可以限定出向前敞开的储物间室,并且储物间室可以被配置成冷藏室、冷冻室、变温室等等,具体的储物间室的数量和功能可以根据预先的需求进行配置。The box body 10 may include an outer shell and a plurality of liners, and the outer shell is located on the outermost side of the overall refrigerator 1 to protect the entire refrigerator 1 . A plurality of inner tanks are wrapped by the outer shell, and the space between them and the outer shell is filled with thermal insulation material (forming a foam layer), so as to reduce the outward heat dissipation of the inner tanks. Each liner can define a storage compartment that is open forward, and the storage compartment can be configured as a refrigerator, freezer, temperature-changing room, etc. The number and functions of the specific storage compartments can be based on prior needs to configure.
门体20可动地设置于内胆的前方,以开闭内胆的储物间室,例如门体20可以通过铰接的方式设置箱体10前部的一侧,通过枢转的方式开闭储物 间室。The door body 20 is movably arranged in front of the inner tank to open and close the storage compartment of the inner tank. For example, the door body 20 can be set on one side of the front of the box body 10 in a hinged manner, and can be opened and closed by pivoting. Storage room.
在一些实施例中,该冰箱1还可包括抽屉组件30,抽屉组件30可以设置于箱体10内,用户可以通过抽拉的方式开闭抽屉组件30,以拿取其内的食物。In some embodiments, the refrigerator 1 may further include a drawer assembly 30 , which may be disposed in the box body 10 , and the user may open and close the drawer assembly 30 by pulling to get food therein.
参见图2和图3,图2是根据本发明一个实施例的冰箱1中抽屉组件30的示意图,图3是根据本发明一个实施例的冰箱1中抽屉组件30的分解图。该抽屉组件30还可包括盖板100、抽屉本体200和电解除氧装置300,抽屉本体200具有向上敞开的储物空间210,并且抽屉本体200可抽拉地设置于盖板100的下方,以使当其处于关闭位置时,盖板100封盖储物空间210,电解除氧装置300设置于盖板100,当抽屉本体200处于关闭位置时消耗储物空间210内空气中的氧气。2 and 3, FIG. 2 is a schematic diagram of the drawer assembly 30 in the refrigerator 1 according to an embodiment of the present invention, and FIG. 3 is an exploded view of the drawer assembly 30 in the refrigerator 1 according to an embodiment of the present invention. The drawer assembly 30 may also include a cover plate 100, a drawer body 200, and an electro-deoxidizer 300. The drawer body 200 has an upwardly open storage space 210, and the drawer body 200 is arranged under the cover plate 100 in a pullable manner, so as to When it is in the closed position, the cover plate 100 covers the storage space 210, and the electrolytic deoxygenation device 300 is arranged on the cover plate 100, and consumes the oxygen in the air in the storage space 210 when the drawer body 200 is in the closed position.
在本实施例中,盖板100可设置于箱体10内,抽屉本体200位于盖板100的下方,抽屉本体200可操作地在拉出位置和关闭位置之间运动,当抽屉本体200处于关闭位置时,其储物空间210处于盖板100的正下方,以便利用盖板100封盖储物空间210,防止冷气外泄。In this embodiment, the cover plate 100 can be arranged in the box body 10, the drawer body 200 is located under the cover plate 100, and the drawer body 200 is operable to move between the pull-out position and the closed position. When the drawer body 200 is in the closed position In the above position, the storage space 210 is directly below the cover plate 100, so that the cover plate 100 can be used to cover the storage space 210 to prevent cold air from leaking out.
电解除氧装置300设置在盖板100上,当抽屉本体200处于关闭位置时,抽屉本体200的储物空间210内的空气可以与电解除氧装置300相接触,这样电解除氧装置300可通过电化学反应分离出来自储物空间210且流经其上的空气中的氧气,并将氮气留在抽屉本体200的储物空间210内,实现对食物的保鲜储存。The electrolytic deoxygenation device 300 is arranged on the cover plate 100. When the drawer body 200 is in the closed position, the air in the storage space 210 of the drawer body 200 can be in contact with the electrolytic deoxygenation device 300, so that the electrolytic deoxygenation device 300 can pass through The electrochemical reaction separates oxygen from the air flowing through the storage space 210 , and leaves nitrogen in the storage space 210 of the drawer body 200 , so as to realize fresh-keeping storage of food.
如背景技术部分所述,现有技术中出现了能够对冰箱的制冷抽屉进行除氧的除氧模块,为了不用影响制冷抽屉抽拉,除氧模块一般设置在制冷抽屉的背部,这样制冷抽屉内存储的物品难免会与除氧模块发生接触,影响除氧效果。As mentioned in the background technology section, in the prior art, a deoxygenation module that can deoxygenate the refrigeration drawer of the refrigerator has appeared. In order not to affect the drawing of the refrigeration drawer, the deoxygenation module is generally installed Stored items will inevitably come into contact with the oxygen removal module, affecting the oxygen removal effect.
为了克服上述现有技术的缺陷,本实施例的抽屉本体200采用将电解除氧装置300设置在用于封盖储物空间210的盖板100上,这样能够降低储物空间210内的物品与电解除氧装置300产生干涉的概率,提升储物空间210内的空气与电解除氧装置300的接触度,提升保鲜效果。In order to overcome the defects of the above-mentioned prior art, the drawer body 200 of this embodiment adopts an electrolytic deoxidizer 300 arranged on the cover plate 100 used to cover the storage space 210, which can reduce the distance between the items in the storage space 210 and the The probability of interference from the electrolytic deoxygenation device 300 increases the degree of contact between the air in the storage space 210 and the electrolytic deoxygenation device 300 , improving the freshness preservation effect.
此外,由于抽屉本体200属于频繁运动部件,而电解除氧装置300可能具有相对复杂的装配结构(例如补液管路、排气管路、电源线束等),因此将电解除氧装置300设置在处于静态的盖板100也可以降低由于抽屉本体 200运动对电解除氧装置300的装配结构的影响,提高电解除氧装置300的可靠性和稳定性。In addition, since the drawer body 200 is a frequently moving part, and the electrolytic deoxygenation device 300 may have a relatively complicated assembly structure (such as a liquid replenishment pipeline, an exhaust pipeline, a power harness, etc.), the electrolytic deoxygenation device 300 is set at The static cover plate 100 can also reduce the influence of the movement of the drawer body 200 on the assembly structure of the electrolytic deoxygenation device 300 and improve the reliability and stability of the electrolytic deoxygenation device 300 .
参见图3至图5,图4是根据本发明一个实施例的冰箱1中抽屉组件30的纵向截面图,图5是根据本发明一个实施例的抽屉组件30中壳体与盖体340的分解图。3 to 5, FIG. 4 is a longitudinal sectional view of the drawer assembly 30 in the refrigerator 1 according to one embodiment of the present invention, and FIG. 5 is an exploded view of the housing and the cover 340 in the drawer assembly 30 according to one embodiment of the present invention. picture.
在一些实施例中,盖板100开设有安装口110,并且该电解除氧装置300还可包括壳体、阴极膜组件320和阳极板330,壳体固定于安装口110处,壳体内具有容置空腔,阴极膜组件320设置于容置空腔,以将容置空腔分隔出用于盛装电解液的储液腔312和位于储液腔312下方的通风腔314,通风腔314通过进气孔319与储物空间210相连通,阴极膜组件320通过电化学反应消耗从进气孔319进入通风腔314的空气中的氧气,阳极板330与阴极膜组件320间隔地设置于储液腔312内,阳极板330通过电化学反应向阴极膜组件320提供反应物(例如电子)且生成电解产物。In some embodiments, the cover plate 100 is provided with an installation opening 110, and the electrolytic oxygen removal device 300 may further include a housing, a cathode membrane assembly 320 and an anode plate 330, the housing is fixed at the installation opening 110, and the housing has a The cathode membrane assembly 320 is arranged in the accommodating cavity, so as to separate the accommodating cavity into a liquid storage cavity 312 for containing electrolyte and a ventilation cavity 314 located below the liquid storage cavity 312, and the ventilation cavity 314 passes through the The air hole 319 communicates with the storage space 210, the cathode membrane assembly 320 consumes oxygen in the air entering the ventilation chamber 314 from the air inlet 319 through an electrochemical reaction, and the anode plate 330 and the cathode membrane assembly 320 are arranged in the liquid storage chamber at intervals Within 312, the anode plate 330 provides reactants (eg, electrons) to the cathode membrane assembly 320 through an electrochemical reaction and generates electrolysis products.
在本实施例中,阴极膜组件320可水平地固定在壳体的容置空腔内,这样可将容置空腔分隔出上下分布的储液腔312和通风腔314,通风腔314位于下方可靠近抽屉本体200的储物空间210,这样便于储物空间210内的空气可通过进气孔319进入通风腔314,最终与阴极膜组件320相接触,并进行电化学反应。In this embodiment, the cathode membrane assembly 320 can be horizontally fixed in the accommodation cavity of the casing, so that the accommodation cavity can be separated into a liquid storage chamber 312 distributed up and down and a ventilation chamber 314, and the ventilation chamber 314 is located below It can be close to the storage space 210 of the drawer body 200, so that the air in the storage space 210 can enter the ventilation cavity 314 through the air inlet hole 319, and finally contact with the cathode membrane assembly 320, and perform an electrochemical reaction.
阴极膜组件320可与壳体的上部限定出储液腔312,且阴极膜组件320可作为储液腔312的下壁面,这样进入通风腔314的空气可透过阴极膜组件320(阴极膜组件320具有防水透气功能)进入储液腔312,阴极膜组件320可加载外部电源的负极,空气中的氧气可在阴极膜组件320处发生还原反应,生成负离子,即:O 2+2H 2O+4e -→4OH -The cathode membrane assembly 320 can define the liquid storage chamber 312 with the upper part of the casing, and the cathode membrane assembly 320 can be used as the lower wall of the liquid storage chamber 312, so that the air entering the ventilation chamber 314 can pass through the cathode membrane assembly 320 (cathode membrane assembly 320 has waterproof and breathable function) enters the liquid storage chamber 312, the cathode membrane assembly 320 can be loaded with the negative electrode of the external power supply, and the oxygen in the air can undergo a reduction reaction at the cathode membrane assembly 320 to generate negative ions, namely: O 2 +2H 2 O+ 4e → 4OH .
阳极板330可水平设置在储液腔312中,以与阴极膜组件320相间隔,阳极板330可加载外部电源的正极,由于储液腔312盛装有电解液(例如0.1~8mol/L的NaOH,具体可根据实际需要调整),在阴极膜组件320处生成的负离子在电场的作用下流向阳极板330,并在阳极板330上发生氧化反应,生成氧气,即:4OH -→O 2+2H 2O+4e -The anode plate 330 can be horizontally arranged in the liquid storage chamber 312 to be spaced from the cathode membrane assembly 320, and the anode plate 330 can be loaded with the positive pole of an external power supply. , which can be adjusted according to actual needs), the negative ions generated at the cathode membrane assembly 320 flow to the anode plate 330 under the action of the electric field, and an oxidation reaction occurs on the anode plate 330 to generate oxygen, namely: 4OH - → O 2 +2H 2 O+4e - .
在本实施例中,由于阴极膜组件320设置于壳体的容置空腔,并将容置空腔分隔出上下分布的储液腔312和通风腔314,储物空间210内的空气先通过进气孔319进入通风腔314中与阴极膜组件320相接触,这样可使阴极 膜组件320与物品距离不会过近,不仅能够防止物品刺破阴极膜组件320,降低电解液泄漏风险,而且可以留出阴极膜组件320下方的进气空间,保证空气交换畅通,提高电解效率。In this embodiment, since the cathode membrane assembly 320 is arranged in the accommodation cavity of the casing, and separates the accommodation cavity into the liquid storage chamber 312 and the ventilation chamber 314 distributed up and down, the air in the storage space 210 first passes through The air inlet hole 319 enters the ventilation cavity 314 and contacts the cathode membrane assembly 320, so that the distance between the cathode membrane assembly 320 and the article will not be too close, which can not only prevent the article from piercing the cathode membrane assembly 320, reduce the risk of electrolyte leakage, and The air intake space under the cathode membrane assembly 320 can be reserved to ensure smooth air exchange and improve electrolysis efficiency.
参见图3至图5,在一些实施例中,壳体还包括上壳部316和下壳部318,上壳部316与下壳部318相扣合以限定出容置空腔,下壳部318的外周形成有搭接部318a,搭接部318a搭接于安装口110的边缘,以使下壳部318的底壁以及部分周壁处于盖板100的下方,进气孔319开设于处于盖板100下方的下壳部318周壁,以便储物空间210内的空气进入通风腔314。3 to 5, in some embodiments, the housing further includes an upper shell portion 316 and a lower shell portion 318, the upper shell portion 316 and the lower shell portion 318 are snapped together to define an accommodating cavity, and the lower shell portion The outer periphery of 318 is formed with overlapping portion 318a, and overlapping portion 318a overlaps the edge of installation port 110, so that the bottom wall and part of the surrounding wall of lower shell portion 318 are below the cover plate 100, and the air inlet 319 is opened in the cover plate 100. The surrounding wall of the lower shell portion 318 below the board 100 allows the air in the storage space 210 to enter the ventilation cavity 314 .
上壳部316在其周壁上可设置多个卡扣316b,下壳部318的周壁上设置有多个卡槽318b,上壳部316和下壳部318扣合时,上壳部316的周壁可伸入下壳部318内,并使多个卡扣316b和多个卡槽318b一一对应地相配合,以便固定上壳部316和下壳部318,并限定出容置空腔。The upper shell portion 316 can be provided with a plurality of buckles 316b on its peripheral wall, and a plurality of snap grooves 318b are provided on the peripheral wall of the lower shell portion 318. It can extend into the lower shell part 318, and make a plurality of buckles 316b and a plurality of slots 318b match one by one, so as to fix the upper shell part 316 and the lower shell part 318, and define an accommodating cavity.
下壳部318外周形成有搭接部318a,搭接部318a搭接于盖板100的安装口110的边缘,这样可将壳体整体固定在安装口110处,并使下壳部318的底壁以及部分周壁从安装口110处陷入盖板100的下方,进气孔319的数量可以为多个,并分布在处于盖板100下方的下壳部318周壁,这样能够有利于进气孔319更加靠近抽屉本体200的储物空间210,进而有利于储物空间210的空气进入通风腔314。An overlapping portion 318a is formed on the outer periphery of the lower shell portion 318, and the overlapping portion 318a is overlapped on the edge of the installation opening 110 of the cover plate 100, so that the housing as a whole can be fixed at the installation opening 110, and the bottom of the lower housing portion 318 The wall and part of the surrounding wall sink into the bottom of the cover plate 100 from the installation port 110, and the number of air inlets 319 can be multiple, and they are distributed on the surrounding wall of the lower shell part 318 below the cover plate 100, which can facilitate the air intake holes 319. Being closer to the storage space 210 of the drawer body 200 facilitates the air in the storage space 210 to enter the ventilation cavity 314 .
参见图3至图5,在一些实施例中,上壳部316的顶部开设有通孔316a,并且该抽屉组件30还可包括盖体340,盖体340设置于通孔316a上,并且盖体340具有用于向储液腔312补液的补液口342以及用于将阳极板330产生的反应物(氧气)排出的排气口344。通孔316a处还可具有连接口,盖体340可通过密封圈346与连接口相连接,以便密封通孔316a。3 to 5, in some embodiments, a through hole 316a is opened on the top of the upper shell portion 316, and the drawer assembly 30 may further include a cover 340, the cover 340 is disposed on the through hole 316a, and the cover 340 has a liquid supply port 342 for supplying liquid to the liquid storage chamber 312 and an exhaust port 344 for discharging reactants (oxygen) generated by the anode plate 330 . There may also be a connection port at the through hole 316a, and the cover body 340 may be connected with the connection port through a sealing ring 346 so as to seal the through hole 316a.
阴极膜组件320水平地固定在壳体的容置空腔内,以在容置空腔内分隔出储液腔312,阳极板330设置在储液腔312内,在电解除氧装置300工作时,阴极膜组件320将储物空间210的氧气还原成负离子,负离子在阳极板330处氧化成氧气(也可理解成电解除氧装置300可将阴极膜组件320的氧气转移至阳极板330),上壳部316的顶部开设通孔316a,盖体340设置于通孔316a,盖体340具有排气口344,也即,排气口344靠近于阳极板330,这样既能减少或避免电解液泄露,又有利于缩短排气路径,以使阳极板330生成的氧气及时排出,有利于电化学反应正向进行。The cathode membrane assembly 320 is horizontally fixed in the housing cavity to separate the liquid storage chamber 312 in the housing cavity, and the anode plate 330 is arranged in the liquid storage chamber 312. When the electrolytic deoxygenation device 300 is working , the cathode membrane assembly 320 reduces the oxygen in the storage space 210 to negative ions, and the negative ions are oxidized to oxygen at the anode plate 330 (it can also be understood that the electrolytic deoxygenation device 300 can transfer the oxygen in the cathode membrane assembly 320 to the anode plate 330), The top of the upper case 316 is provided with a through hole 316a, and the cover 340 is disposed in the through hole 316a. The cover 340 has an exhaust port 344, that is, the exhaust port 344 is close to the anode plate 330, which can reduce or avoid electrolyte leakage. Leakage is also conducive to shortening the exhaust path, so that the oxygen generated by the anode plate 330 can be discharged in time, which is beneficial to the positive progress of the electrochemical reaction.
进一步地,盖体340上还可设置补液管和排氧管,排氧管还可伸入储液腔312内,其端部处于电解液的液位上方,这样使得排氧管更加靠近阳极板330,以便阳极板330上产生的氧气从电解液溢出后进入排氧管。Further, a liquid replenishment pipe and an oxygen discharge pipe can also be provided on the cover 340, and the oxygen discharge pipe can also extend into the liquid storage chamber 312, and its end is above the liquid level of the electrolyte, so that the oxygen discharge pipe is closer to the anode plate 330, so that the oxygen generated on the anode plate 330 overflows from the electrolyte and enters the oxygen exhaust pipe.
参见图4,在一些实施例中,当搭接部318a搭接于安装口110的边缘时,下壳部318的底壁处于倾斜状态,并且下壳部318在其底壁倾斜下游处设置有排液口319a,以便排出通风腔314内的积液。4, in some embodiments, when the overlapping portion 318a overlaps the edge of the installation opening 110, the bottom wall of the lower shell portion 318 is in an inclined state, and the lower shell portion 318 is provided with a The liquid discharge port 319a is used to discharge the accumulated liquid in the ventilation cavity 314 .
阴极膜组件320可作为储液腔312的下壁,通风腔314可起到保护阴极膜组件320的作用,并且一旦阴极膜组件320受损破裂,通风腔314还可收集从储液腔312流出的电解液,进一步提高了电解除氧装置300的安全性和可靠性。The cathode membrane assembly 320 can be used as the lower wall of the liquid storage chamber 312, and the ventilation chamber 314 can protect the cathode membrane assembly 320, and once the cathode membrane assembly 320 is damaged and ruptured, the ventilation chamber 314 can also collect the liquid that flows out of the liquid storage chamber 312. The electrolytic solution further improves the safety and reliability of the electrolytic deoxygenation device 300.
参见图4,进一步地,当搭接部318a搭接于安装口110的边缘时,下壳部318的底壁处于倾斜状态,这样阴极膜组件320受损破裂后,电解液流进通风腔314,并由倾斜的底壁引导至一侧,便于从排液口319a排出,排液口319a出设置有排液管319b,以便引导至外部进行收集。Referring to Fig. 4, further, when the overlapping portion 318a overlaps the edge of the installation port 110, the bottom wall of the lower shell portion 318 is in an inclined state, so that after the cathode membrane assembly 320 is damaged and ruptured, the electrolyte flows into the ventilation cavity 314 , and is guided to one side by the inclined bottom wall to facilitate discharge from the drain port 319a. The drain port 319a is provided with a drain pipe 319b so as to be guided to the outside for collection.
参见图6和图7,图6是根据本发明一个实施例的抽屉组件30中阴极膜组件320与阳极板330的分解图,图7是图6中A部放大图。在一些实施例中,阴极膜组件320还可包括固定框架322和阴极膜组324,固定框架322水平地固定于容置空腔内,固定框架322的内侧沿周向开设有安装槽326,阴极膜组324的周缘固定于安装槽326内,以使其固定设置于固定框架322的中央。6 and 7, FIG. 6 is an exploded view of the cathode membrane assembly 320 and the anode plate 330 in the drawer assembly 30 according to an embodiment of the present invention, and FIG. 7 is an enlarged view of part A in FIG. 6 . In some embodiments, the cathode membrane assembly 320 may further include a fixed frame 322 and a cathode membrane group 324, the fixed frame 322 is horizontally fixed in the accommodating cavity, and the inner side of the fixed frame 322 is provided with a mounting groove 326 along the circumference, the cathode The peripheral edge of the membrane group 324 is fixed in the installation groove 326 so that it is fixedly disposed in the center of the fixing frame 322 .
固定框架322的外周可与容置空腔内壁相固定,具体地可固定在上壳部316的内部,固定框架322的内侧沿周向开设安装槽326,阴极膜组324的周缘固定于安装槽326内,这样阴极膜组324可绷紧于固定框架322的中央,以稳固地为储液腔312提供底壁。The outer periphery of the fixed frame 322 can be fixed with the inner wall of the accommodating cavity, specifically, it can be fixed inside the upper shell portion 316. The inner side of the fixed frame 322 is provided with an installation groove 326 along the circumference, and the periphery of the cathode membrane group 324 is fixed in the installation groove. 326, so that the cathode membrane group 324 can be tightened in the center of the fixed frame 322 to provide a bottom wall for the liquid storage chamber 312 stably.
进一步地,阴极膜组324还包括自上而下依次设置的催化层、第一防水透气层、导电层328和第二防水透气层。催化层可以采用贵金属或稀有金属催化剂,例如金属铂、金属金、金属银、金属锰或金属铷等。第一防水透气层和第二防水透气层可以为防水透气膜,以使得电解液无法从储液腔312渗出,而空气可以透过第一防水透气层和第二防水透气层进入储液腔312。导电层328可以制作成耐腐金属集流网,例如金属镍、金属钛等,以使其不仅具备较佳的导电性、防腐性和支撑强度。Further, the cathode membrane group 324 also includes a catalytic layer, a first waterproof and breathable layer, a conductive layer 328 and a second waterproof and breathable layer arranged in sequence from top to bottom. The catalyst layer can use noble metal or rare metal catalyst, such as metal platinum, metal gold, metal silver, metal manganese or metal rubidium and so on. The first waterproof and gas-permeable layer and the second waterproof and gas-permeable layer can be waterproof and gas-permeable membranes, so that the electrolyte cannot seep out from the liquid storage chamber 312, and air can enter the liquid storage chamber through the first waterproof and gas-permeable layer and the second waterproof and gas-permeable layer 312. The conductive layer 328 can be made into a corrosion-resistant metal current collector, such as metal nickel, metal titanium, etc., so that it not only has better conductivity, corrosion resistance and supporting strength.
参见图6,导电层328还具有延伸部328a,延伸部328a向外穿过安装槽326并与阴极接电片352电连接,以为阴极膜组324通电。固定框架322在一侧还可设置有凸出部322a,导电层328的延伸部328a向外穿过安装槽326后进入固定框架322的凸出部322a内部,凸出部322a的内部还可设置阴极接电片352,阴极接电片352的一部分压紧在导电层328的延伸部328a上,另一部分向外伸出固定框架322的凸出部322a,以便于外部电源的负极相连。Referring to FIG. 6 , the conductive layer 328 also has an extension portion 328 a , and the extension portion 328 a passes through the installation slot 326 and is electrically connected to the cathode contact sheet 352 to provide electricity to the cathode film group 324 . The fixed frame 322 can also be provided with a protruding portion 322a on one side, and the extension portion 328a of the conductive layer 328 passes through the installation groove 326 and enters the inside of the protruding portion 322a of the fixed frame 322, and the inside of the protruding portion 322a can also be provided with Cathode connecting piece 352, a part of cathode connecting piece 352 is pressed on the extension 328a of the conductive layer 328, and the other part protrudes outward from the protrusion 322a of the fixed frame 322, so as to be connected to the negative pole of the external power supply.
阳极板330可采用耐蚀性和还原性强的材料制成,例如金属泡沫镍、镍网等,阳极板330的一侧还可连接阳极接电片354,阳极接电片354可伸出壳体,以便于外部电源的正极相连。The anode plate 330 can be made of materials with strong corrosion resistance and reducibility, such as metal foam nickel, nickel mesh, etc., and one side of the anode plate 330 can also be connected to the anode electrode 354, and the anode electrode 354 can extend out of the shell. Body, in order to facilitate the positive connection of the external power supply.
参见图6和图7,进一步地,固定框架322的上表面设置有多个台阶定位柱329,阳极板330上具有多个定位孔332,定位孔332与台阶定位柱329一一对应地配合,以将阳极板330间隔地固定于阴极膜组件320的上方。Referring to Fig. 6 and Fig. 7, further, the upper surface of the fixed frame 322 is provided with a plurality of stepped positioning columns 329, and the anode plate 330 has a plurality of positioning holes 332, and the positioning holes 332 are matched with the stepped positioning columns 329 one by one, The anode plate 330 is fixed above the cathode membrane assembly 320 at intervals.
每个台阶定位柱329可具有支撑部分329a和固定部分329b,支撑部分329a与固定部分329b同轴设置,且支撑部分329a直径大于固定部分329b,固定部分329b的直径与定位孔332相匹配,这样当定位孔332与台阶定位柱329的固定部分329b配合时阳极板330搭接在台阶定位柱329的支撑部分329a上,不仅实现固定阳极板330,而且可使阳极板330与阴极膜组件320之间保持一定的距离,防止短路。Each step positioning column 329 can have a support portion 329a and a fixed portion 329b, the support portion 329a is coaxially arranged with the fixed portion 329b, and the diameter of the support portion 329a is larger than the fixed portion 329b, and the diameter of the fixed portion 329b matches the positioning hole 332, so that When the positioning hole 332 is matched with the fixed portion 329b of the step positioning column 329, the anode plate 330 is lapped on the support portion 329a of the step positioning column 329, which not only realizes fixing the anode plate 330, but also enables the connection between the anode plate 330 and the cathode membrane assembly 320 Keep a certain distance between them to prevent short circuit.
在一些具体的实施例中,阳极板330和阴极膜组件320之间还可保持5mm至10mm(例如5mm、7mm或者10mm等)的间距,既能够避免因阳极板330与阴极膜组件320的间距过大而导致反应效率低,又能够避免因间距过小而导致阳极板330产生的氧气无法及时排出,影响反应进程。In some specific embodiments, a distance of 5mm to 10mm (such as 5mm, 7mm or 10mm, etc.) can be maintained between the anode plate 330 and the cathode membrane assembly 320, which can avoid the gap between the anode plate 330 and the cathode membrane assembly 320 If the distance is too large, the reaction efficiency will be low, and the oxygen generated by the anode plate 330 cannot be discharged in time due to the small distance, which will affect the reaction process.
参见图8,图8是根据本发明另一个实施例的冰箱1中抽屉组件30的分解图。在一些实施例中,该抽屉组件30还可包括筒体360,筒体360具有向前敞开的抽拉空间,抽屉本体200可拉出或缩进于抽拉空间,抽屉组件30还配置成使其盖板100作为抽拉空间的顶板。Referring to FIG. 8 , FIG. 8 is an exploded view of a drawer assembly 30 in a refrigerator 1 according to another embodiment of the present invention. In some embodiments, the drawer assembly 30 may also include a barrel body 360, the barrel body 360 has a drawing space open forward, the drawer body 200 can be pulled out or retracted into the drawer space, and the drawer assembly 30 is also configured so that Its cover plate 100 serves as the top plate of the drawing space.
也即,盖板100不仅可独立使用,以封盖抽屉本体200的储物空间210,而且可作为抽拉空间的顶板,以使抽屉本体200整体可在拉出或缩进于抽拉空间,当处于关闭位置时,抽屉本体200可整体处于筒体360内,并且筒体360的顶板(即盖板100)封盖其储物空间210,并利用设置在筒体360顶板 的电解除氧装置300消耗储物空间210内空气中的氧气。That is, the cover plate 100 can not only be used independently to cover the storage space 210 of the drawer body 200, but also can be used as the top plate of the drawer space, so that the drawer body 200 as a whole can be pulled out or retracted into the drawer space, When in the closed position, the drawer body 200 can be placed in the cylinder body 360 as a whole, and the top plate of the cylinder body 360 (ie, the cover plate 100 ) covers the storage space 210, and the electrolytic deoxygenation device arranged on the cylinder body 360 top plate 300 consumes oxygen in the air in storage space 210 .
至此,本领域技术人员应认识到,虽然本文已详尽示出和描述了本发明的多个示例性实施例,但是,在不脱离本发明精神和范围的情况下,仍可根据本发明公开的内容直接确定或推导出符合本发明原理的许多其他变型或修改。因此,本发明的范围应被理解和认定为覆盖了所有这些其他变型或修改。So far, those skilled in the art should appreciate that, although a number of exemplary embodiments of the present invention have been shown and described in detail herein, without departing from the spirit and scope of the present invention, the disclosed embodiments of the present invention can still be used. Many other variations or modifications consistent with the principles of the invention are directly identified or derived from the content. Accordingly, the scope of the present invention should be understood and deemed to cover all such other variations or modifications.

Claims (10)

  1. 一种用于冰箱的抽屉组件,包括:A drawer assembly for a refrigerator, comprising:
    盖板;cover;
    抽屉本体,其具有向上敞开的储物空间,所述抽屉本体可抽拉地设置于所述盖板的下方,以使当其处于关闭位置时,所述盖板封盖所述储物空间;The drawer body has an upwardly open storage space, and the drawer body is pullably arranged under the cover plate, so that when it is in the closed position, the cover plate covers the storage space;
    电解除氧装置,设置于所述盖板,配置成当所述抽屉本体处于所述关闭位置时消耗所述储物空间内空气中的氧气。The electrolytic deoxygenation device is arranged on the cover plate and is configured to consume oxygen in the air in the storage space when the drawer body is in the closed position.
  2. 根据权利要求1所述的抽屉组件,其中The drawer assembly of claim 1, wherein
    所述盖板开设有安装口;且所述电解除氧装置包括:The cover plate is provided with an installation port; and the electrolytic deoxidizer includes:
    壳体,固定于所述安装口处,其内具有容置空腔;The housing is fixed at the installation port, and has an accommodating cavity inside;
    阴极膜组件,设置于所述容置空腔,以将所述容置空腔分隔出用于盛装电解液的储液腔和位于所述储液腔下方的通风腔,所述通风腔通过进气孔与所述储物空间相连通,所述阴极膜组件配置成通过电化学反应消耗从所述进气孔进入所述通风腔的空气中的氧气;The cathode membrane assembly is arranged in the accommodating cavity, so as to separate the accommodating cavity into a liquid storage cavity for containing electrolyte and a ventilation cavity below the liquid storage cavity, and the ventilation cavity passes through the The air hole communicates with the storage space, and the cathode membrane assembly is configured to consume oxygen in the air entering the ventilation cavity from the air inlet hole through an electrochemical reaction;
    阳极板,与所述阴极膜组件间隔地设置于所述储液腔内,配置成通过电化学反应向所述阴极膜组件提供反应物且生成电解产物。The anode plate is arranged in the liquid storage cavity at a distance from the cathode membrane assembly, and is configured to provide reactants to the cathode membrane assembly through an electrochemical reaction and generate an electrolysis product.
  3. 根据权利要求2所述的抽屉组件,其中The drawer assembly of claim 2, wherein
    所述壳体包括上壳部和下壳部,所述上壳部与所述下壳部相扣合以限定出所述容置空腔;且The housing includes an upper shell part and a lower shell part, the upper shell part and the lower shell part are fastened to define the accommodating cavity; and
    所述下壳部的外周形成有搭接部,所述搭接部搭接于所述安装口的边缘,以使所述下壳部的底壁以及部分周壁处于所述盖板的下方,所述进气孔开设于处于所述盖板下方的所述下壳部周壁,以便所述储物空间内的空气进入所述通风腔。An overlapping portion is formed on the outer periphery of the lower shell portion, and the overlapping portion overlaps the edge of the installation opening, so that the bottom wall and part of the surrounding wall of the lower shell portion are below the cover plate, so that The air intake hole is opened on the peripheral wall of the lower shell portion below the cover plate, so that the air in the storage space can enter the ventilation cavity.
  4. 根据权利要求3所述的抽屉组件,其中The drawer assembly of claim 3, wherein
    所述上壳部的顶部开设有通孔;且所述抽屉组件还包括:The top of the upper shell is provided with a through hole; and the drawer assembly also includes:
    盖体,设置于所述通孔上,并且所述盖体具有用于向所述储液腔补液的补液口以及用于将所述阳极板产生的反应物排出的排气口。The cover body is arranged on the through hole, and the cover body has a liquid replenishment port for replenishing liquid to the liquid storage chamber and an exhaust port for discharging reactants generated by the anode plate.
  5. 根据权利要求3或4所述的抽屉组件,其中A drawer assembly according to claim 3 or 4, wherein
    当所述搭接部搭接于所述安装口的边缘时,所述下壳部的底壁处于倾斜状态,并且所述下壳部在其底壁倾斜下游处设置有排液口,以便排出所述通风腔内的积液。When the overlapping portion overlaps the edge of the installation port, the bottom wall of the lower shell is in an inclined state, and the lower shell is provided with a liquid discharge port downstream of the inclination of the bottom wall, so as to discharge Fluid accumulation in the ventilation cavity.
  6. 根据权利要求3或4所述的抽屉组件,其中所述阴极膜组件包括:The drawer assembly according to claim 3 or 4, wherein the cathode membrane assembly comprises:
    固定框架,水平地固定于所述容置空腔内,所述固定框架的内侧沿周向开设有安装槽;The fixed frame is horizontally fixed in the accommodating cavity, and the inner side of the fixed frame is provided with a mounting groove along the circumferential direction;
    阴极膜组,所述阴极膜组的周缘固定于所述安装槽内,以使其固定设置于所述固定框架的中央。The cathode membrane group, the periphery of the cathode membrane group is fixed in the installation groove, so that it is fixedly arranged in the center of the fixing frame.
  7. 根据权利要求6所述的抽屉组件,其中The drawer assembly of claim 6, wherein
    所述阴极膜组包括自上而下依次设置的催化层、第一防水透气层、导电层和第二防水透气层;且The cathode membrane group includes a catalytic layer, a first waterproof and breathable layer, a conductive layer and a second waterproof and breathable layer arranged in sequence from top to bottom; and
    所述导电层具有延伸部,所述延伸部向外穿过所述安装槽并与阴极接电片电连接,以为所述阴极膜组供电。The conductive layer has an extension, and the extension passes outward through the installation slot and is electrically connected to the cathode contact piece to provide power to the cathode film group.
  8. 根据权利要求6所述的抽屉组件,其中The drawer assembly of claim 6, wherein
    所述固定框架的上表面设置有多个台阶定位柱,所述阳极板上具有多个定位孔,所述定位孔与所述台阶定位柱一一对应地配合,以将所述阳极板间隔地固定于所述阴极膜组件的上方。The upper surface of the fixed frame is provided with a plurality of step positioning columns, and the anode plate has a plurality of positioning holes, and the positioning holes cooperate with the step positioning columns one by one, so as to space the anode plate fixed above the cathode membrane assembly.
  9. 根据权利要求1-4、7-8中任一项所述的抽屉组件,还包括:The drawer assembly according to any one of claims 1-4, 7-8, further comprising:
    筒体,其具有向前敞开的抽拉空间,所述抽屉本体可拉出或缩进于所述抽拉空间;其中The cylinder has a drawing space open forward, and the drawer body can be pulled out or retracted into the drawing space; wherein
    所述抽屉组件还配置成使其盖板作为所述抽拉空间的顶板。The drawer assembly is also configured such that its cover plate serves as the top plate of the drawing space.
  10. 一种冰箱,包括根据权利要求1至9任一项所述的抽屉组件。A refrigerator, comprising the drawer assembly according to any one of claims 1-9.
PCT/CN2022/129567 2021-12-03 2022-11-03 Refrigerator and drawer assembly thereof WO2023098385A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN202111475004.1A CN116222122A (en) 2021-12-03 2021-12-03 Refrigerator and drawer assembly thereof
CN202111475004.1 2021-12-03

Publications (1)

Publication Number Publication Date
WO2023098385A1 true WO2023098385A1 (en) 2023-06-08

Family

ID=86568400

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2022/129567 WO2023098385A1 (en) 2021-12-03 2022-11-03 Refrigerator and drawer assembly thereof

Country Status (2)

Country Link
CN (1) CN116222122A (en)
WO (1) WO2023098385A1 (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1532495A (en) * 2003-03-25 2004-09-29 株式会社东芝 Refrigerator
JP2017015332A (en) * 2015-07-01 2017-01-19 東芝ライフスタイル株式会社 Oxygen reducing device and refrigerator
CN109855375A (en) * 2017-11-30 2019-06-07 青岛海尔股份有限公司 Refrigerating device and its remove oxygen control method
CN111912158A (en) * 2020-07-23 2020-11-10 珠海格力电器股份有限公司 Electrolysis device, control method and low-temperature storage equipment
CN112747549A (en) * 2019-10-31 2021-05-04 青岛海尔电冰箱有限公司 Storage device for refrigerator and refrigerator with storage device
CN112747535A (en) * 2019-10-31 2021-05-04 青岛海尔电冰箱有限公司 Refrigerator with a door
CN112747536A (en) * 2019-10-31 2021-05-04 青岛海尔电冰箱有限公司 Refrigerator with a door

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1532495A (en) * 2003-03-25 2004-09-29 株式会社东芝 Refrigerator
JP2017015332A (en) * 2015-07-01 2017-01-19 東芝ライフスタイル株式会社 Oxygen reducing device and refrigerator
CN109855375A (en) * 2017-11-30 2019-06-07 青岛海尔股份有限公司 Refrigerating device and its remove oxygen control method
CN112747549A (en) * 2019-10-31 2021-05-04 青岛海尔电冰箱有限公司 Storage device for refrigerator and refrigerator with storage device
CN112747535A (en) * 2019-10-31 2021-05-04 青岛海尔电冰箱有限公司 Refrigerator with a door
CN112747536A (en) * 2019-10-31 2021-05-04 青岛海尔电冰箱有限公司 Refrigerator with a door
CN111912158A (en) * 2020-07-23 2020-11-10 珠海格力电器股份有限公司 Electrolysis device, control method and low-temperature storage equipment

Also Published As

Publication number Publication date
CN116222122A (en) 2023-06-06

Similar Documents

Publication Publication Date Title
CN217844419U (en) Refrigerator and electrolytic oxygen removal device thereof
JP4074322B2 (en) Combustion gas generator using electrolysis and in-vehicle combustion gas generator
CN108332479B (en) Refrigerator with a door
WO2022016824A1 (en) Freshness preservation device and refrigerator having same
CN112747550B (en) Storage device for refrigerator and refrigerator with storage device
CN113975911B (en) Deoxidization module, fresh-keeping device and refrigerator
WO2021083433A1 (en) Refrigerator
CN216409396U (en) Refrigerator with a door
WO2023098385A1 (en) Refrigerator and drawer assembly thereof
WO2023155665A1 (en) Refrigerator and electrolytic deoxygenization apparatus thereof
CN103623673A (en) Deacidification matter system
CN109855340B (en) Refrigerating and freezing device and storage container thereof
CN109855375B (en) Refrigerating and freezing device and deoxygenation control method thereof
CN217465034U (en) Refrigerator with a door
WO2023155667A1 (en) Refrigerator and electrolytic oxygen removal device thereof
WO2023098414A1 (en) Refrigerator and electrolytic deoxygenation device thereof
CN216114844U (en) Refrigerator and electrolytic oxygen removal device thereof
CN220017835U (en) Refrigerating and freezing device and oxygen treatment device thereof
CN220017829U (en) Refrigerating and freezing device and oxygen treatment device thereof
CN220017834U (en) Refrigerating and freezing device and oxygen treatment device thereof
CN107768779B (en) Cylindrical liquid flow metal-air battery and battery pack
WO2022242240A1 (en) Refrigerator
CN217465007U (en) Refrigerator with a door
CN217465006U (en) Refrigerator with a door
WO2022242239A1 (en) Refrigerator and electrolytic oxygen removal device thereof

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 22900190

Country of ref document: EP

Kind code of ref document: A1