WO2023026135A1 - Système électrochromique utilisant une transmission de puissance sans fil - Google Patents

Système électrochromique utilisant une transmission de puissance sans fil Download PDF

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Publication number
WO2023026135A1
WO2023026135A1 PCT/IB2022/057677 IB2022057677W WO2023026135A1 WO 2023026135 A1 WO2023026135 A1 WO 2023026135A1 IB 2022057677 W IB2022057677 W IB 2022057677W WO 2023026135 A1 WO2023026135 A1 WO 2023026135A1
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WO
WIPO (PCT)
Prior art keywords
wireless power
window
smart
smart windows
charging element
Prior art date
Application number
PCT/IB2022/057677
Other languages
English (en)
Inventor
Guillermo Garcia
Thomas Schumann
David England
Timothy SKELTON
Original Assignee
Hivisq Technologies, S.L.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hivisq Technologies, S.L. filed Critical Hivisq Technologies, S.L.
Publication of WO2023026135A1 publication Critical patent/WO2023026135A1/fr

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Classifications

    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/163Operation of electrochromic cells, e.g. electrodeposition cells; Circuit arrangements therefor
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B9/00Screening or protective devices for wall or similar openings, with or without operating or securing mechanisms; Closures of similar construction
    • E06B9/24Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blinds
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02JCIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
    • H02J50/00Circuit arrangements or systems for wireless supply or distribution of electric power
    • H02J50/005Mechanical details of housing or structure aiming to accommodate the power transfer means, e.g. mechanical integration of coils, antennas or transducers into emitting or receiving devices
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02JCIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
    • H02J50/00Circuit arrangements or systems for wireless supply or distribution of electric power
    • H02J50/10Circuit arrangements or systems for wireless supply or distribution of electric power using inductive coupling
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04BTRANSMISSION
    • H04B5/00Near-field transmission systems, e.g. inductive or capacitive transmission systems
    • H04B5/70Near-field transmission systems, e.g. inductive or capacitive transmission systems specially adapted for specific purposes
    • H04B5/79Near-field transmission systems, e.g. inductive or capacitive transmission systems specially adapted for specific purposes for data transfer in combination with power transfer
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B9/00Screening or protective devices for wall or similar openings, with or without operating or securing mechanisms; Closures of similar construction
    • E06B9/24Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blinds
    • E06B2009/2464Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blinds featuring transparency control by applying voltage, e.g. LCD, electrochromic panels
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02JCIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
    • H02J50/00Circuit arrangements or systems for wireless supply or distribution of electric power
    • H02J50/40Circuit arrangements or systems for wireless supply or distribution of electric power using two or more transmitting or receiving devices

Definitions

  • the present invention is generally directed to electrochromic systems, and more particularly to electrochromic systems including wireless power transmission systems.
  • BACKGROUND OF THE INVENTION [0002]
  • Residential and commercial buildings represent a prime opportunity to improve energy efficiency and sustainability in the United States. The buildings sector alone accounts for 40% of the United States' yearly energy consumption (40 quadrillion BTUs, or “quads”, out of 100 total), and 8% of the world's energy use. Lighting and thermal management each represent about 30% of the energy used within a typical building, which corresponds to around twelve quads each of yearly energy consumption in the US.
  • Windows cover an estimated area of about 2,500 square kilometers (km 2 ) in the US and are a critical component of building energy efficiency as they strongly affect the amount of natural light and solar gain that enters a building.
  • Recent progress has been made toward improving window energy efficiency through the use of inexpensive static coatings that either retain heat in cold climates (low emissive films) or reject solar heat gain in warm climates (near-infrared rejection films).
  • static window coatings can be manufactured at relatively low cost.
  • These window coatings are static and not well suited for locations with varying climates.
  • An electrochromic (EC) window coating overcomes these limitations by enhancing the window performance in all climates. Electrochromic window coatings undergo a reversible change in optical properties when driven by an applied potential.
  • a system may include: one or more smart windows, each of the one or more smart windows including: an electrochromic (EC) device having a bright optical state and a dark optical state; a charging element configured to store electrical energy; a wireless power receiver configured to generate electrical energy from wireless power transmissions; and power driving electronics electrically connecting at least the EC device to the charging element and the charging element to the wireless power receiver, wherein the power driving electronics are configured to provide at least a portion of the generated electrical energy to the charging element.
  • EC electrochromic
  • a method of operating an electrochromic (EC) device includes storing electrical energy generated from wireless power transmissions received by a wireless power receiver; and controlling an optical state of the EC device using the stored electrical energy.
  • FIG. 1A is a schematic representation of an electrochromic (EC) window system according to various embodiments of the present disclosure.
  • FIG. 1B is a schematic representation of an EC window system according to various embodiments of the present disclosure.
  • FIG. 2 is a schematic representation of an EC device according to various embodiments of the present disclosure.
  • FIG. 3A is a schematic representation of a smart window according to various embodiments of the present disclosure.
  • FIG. 3B is a schematic representation of a smart window according to various embodiments of the present disclosure.
  • FIG. 4 is a cut-away schematic representation of a portion of a smart window according to various embodiments of the present disclosure.
  • FIG. 5A is a schematic representation of a smart window according to various embodiments of the present disclosure.
  • FIG. 5B is a schematic representation of a smart window according to various embodiments of the present disclosure.
  • FIG. 6A is a schematic representation of a smart window according to various embodiments of the present disclosure.
  • FIG. 6B is a schematic representation of a smart window according to various embodiments of the present disclosure.
  • FIG. 6B is a schematic representation of a smart window according to various embodiments of the present disclosure.
  • FIG. 7A is a schematic representation of a window adjustment unit according to various embodiments of the present disclosure.
  • FIG. 7B is a schematic representation of a window adjustment unit according to various embodiments of the present disclosure.
  • DETAILED DESCRIPTION OF THE EMBODIMENTS [0019] The invention is described more fully hereinafter with reference to the accompanying drawings, in which exemplary embodiments of the invention are shown. This invention may, however, be embodied in many different forms and should not be construed as limited to the exemplary embodiments set forth herein. Rather, these exemplary embodiments are provided so that this disclosure is thorough, and will fully convey the scope of the invention to those skilled in the art. In the drawings, the size and relative sizes of layers and regions may be exaggerated for clarity.
  • Electrochromic devices may be incorporated into, for example, windows for commercial and/or residential buildings. Such electrochromic windows may be operated independently, or as part of an integrated building management system. In various embodiments, a building or other facility may have at least one window that contains one or more electrochromic device.
  • the optical state of an electrochromic device within a building window may be controlled by a system that receives voltage generated by one or more wireless power systems that is integrated in or attached to the electrochromic window.
  • the wireless power systems e.g., wireless power transmitters, wireless power receivers, combinations of wireless power transmitters and wireless power receivers operating together, etc.
  • the wireless power systems may be any type wireless power systems configured to operate in any manner to transmit and/or receive wireless power.
  • the wireless power systems of the various embodiments may be near field wireless power systems (also sometimes referred to as inductive wireless power systems) in which a wireless power transmitter and a wireless power receiver may be in relatively close proximity to one another such that electromagnetic field coupling may provide the wireless power transmission between the wireless power transmitter and the wireless power receiver.
  • the wireless power systems of the various embodiments may be across room wireless power systems in which a wireless power transmitter and a wireless power receiver may be located across a room from one another such that radio frequency (RF) transmissions from the wireless power transmitter may provide the wireless power transfer to the wireless power receiver.
  • RF radio frequency
  • the terms “smart window,” “electrochromic window,” and “EC window” are used interchangeably herein to refer to a window unit that contains at least one glass pane, such as two or more glass panes, and one or more electrochromic device.
  • the electrochromic device(s) may include one or more layers deposited on a transparent substrate, such as a glass pane.
  • the current or voltage may be produced in response to external conditions.
  • the term “smart window system” refers to one or more smart window and associated components (e.g., a controller, wiring/connectors, a frame, etc.). Electrochromic windows are discussed herein in relation to various example applications and/or installations, such as in buildings, in vehicles, etc.
  • Wireless power for electrochromic window systems may remove barriers to commercial adoption of electrochromic window systems.
  • Wireless power for electrochromic window systems may support the use of electrochromic window systems in window retrofits (e.g., replacing a window that did not previously require power to operate with an electrochromic window, etc.) as wireless power may enable the electrochromic window systems to be installed without needing new electrical wires to be run to the electrochromic windows being installed.
  • Wireless power for electrochromic window systems may support the use of electrochromic window systems in new window installations (e.g., windows installed in new building construction, etc.) as wireless power may enable the electrochromic window systems to be installed without concern as to running electrical wires to the electrochromic windows being installed.
  • a wireless power transmitter may wireless transmit power to an electrochromic window system to thereby provide power to a charging element (e.g., one or more capacitor, one or more battery, a combination of one or more capacitor and one or more battery, etc.) of the electrochromic window system.
  • a charging element e.g., one or more capacitor, one or more battery, a combination of one or more capacitor and one or more battery, etc.
  • the charging element e.g., one or more capacitor, one or more battery, a combination of one or more capacitor and one or more battery, etc.
  • power driving electronics e.g., a widow driver, a controller, a switch, etc.
  • the power driving electronics e.g., the window driver, the controller, the switch, etc.
  • an electrochromic device e.g., an electrochromic window, etc.
  • transmission state i.e., transparency state or optical state, such as bright and dark states.
  • the power driving electronics may be controlled to apply electrical energy to an electrochromic device (e.g., an electrochromic window, etc.) from the charging element (e.g., the one or more capacitor, the one or more battery, the combination of one or more capacitor and one or more battery, etc.) to control a transmission state (or transparency state or optical state) of the electrochromic device (e.g., the electrochromic window, etc.).
  • an electrochromic device e.g., an electrochromic window, etc.
  • the charging element e.g., the one or more capacitor, the one or more battery, the combination of one or more capacitor and one or more battery, etc.
  • a transmission state or transparency state or optical state
  • the power driving electronics may be controlled to remove electrical energy from the electrochromic device (e.g., the electrochromic window, etc.) to control a transmission state (or transparency state or optical state) of the electrochromic device (e.g., the electrochromic window, etc.).
  • the power driving electronics may be controlled to transfer electrical energy from the electrochromic device (e.g., the electrochromic window, etc.) to the charging element (e.g., the one or more capacitor, the one or more battery, the combination of one or more capacitor and one or more battery, etc.) to control a transmission state (or transparency state or optical state) of the electrochromic device (e.g., the electrochromic window, etc.).
  • the wireless power transmitter may provide continuous or near-continuous charging for the charging element (e.g., the one or more capacitor, the one or more battery, the combination of one or more capacitor and one or more battery, etc.) of the electrochromic window system.
  • a user may communicate commands to the power driving electronics (e.g., the window driver, the controller, the switch, etc.) of the electrochromic window system to cause the power electronics (e.g., the window driver, the controller, etc.) to execute operations to control a transmission state (or transparency state or optical state) of the electrochromic device (e.g., the electrochromic window, etc.).
  • the commands from the user may be communicated as part of the wireless power transmissions themselves received by the wireless power receiver.
  • the commands from the user may be communicated as part of separate wireless communications received by a wireless communication receiver of the electrochromic window system.
  • the EC window system 100 may include at least one smart window 108 (also referred to as EC window) and at least one wireless power transmitter 104.
  • the at least one smart window 108 and at least one wireless power transmitter 104 may be installed in an enclosure 102, such as a building (e.g., a room of a residential home, a room of a commercial building, etc.), a vehicle (e.g., a plane, a car, a boat, etc.), etc.
  • the wireless power transmitter 104 may be configured to transmit wireless power transmissions 110 to the at least one smart window 108.
  • the at least one smart window 108 may include one or more antennas 111 connected to a wireless power receiver 106.
  • the one or more antennas 111 may be configured to receive the wireless power transmissions 110 and the wireless power receiver 106 may be configured to generate electrical energy from the wireless power transmissions 110 received by the one or more antennas 111.
  • the electrical energy generated by the wireless power receiver 106 may be used by a window control unit 105 of the smart window 108.
  • the window control unit 105 of the smart window 108 may utilize the generated electrical energy to change an optical state of the smart window 108.
  • the transmission of wireless power from the wireless power transmitter 104 to the smart window 108 may enable the smart window 108 to be installed without any wires physically connecting the smart window 108 to an external power source located outside the smart window 108.
  • the ability to provide power to the smart window 108 wirelessly may support the smart window 108 being used as a window retrofit or as a new window installation without the need to provide electrical wires to the installed smart window 108.
  • the at least one smart window 108 may be installed in a charged state such that an EC device of the at least one smart window 108 is charged at installation. The charging may be conducted during manufacture of the smart window 108 prior to delivery of the smart window to the installation site.
  • the at least one smart window 108 may be charged at the installation site such that an EC device of the at least one smart window 108 is charged before, during or after installation by applying a temporary external power source, such as a charging battery, charging generator, power from the electrical grid, etc., to the at least one smart window 108 after installation but prior to normal operation of the smart window 108.
  • the pre-charging and/or post install charging may provide initial power to the smart window 108 to enable operation without waiting for wireless power transmission to full charge the smart window 108.
  • Such pre-charging and/or post install charging may be optional as wireless power transmission may enable charging of the smart window 108.
  • the wireless power transmitter 104 may be any type wireless power transmitter configured to enable wireless power transmission in which electrical energy is transferred to the wireless power receiver 106 from the wireless power transmitter 104 via the wireless power transmissions 110.
  • the wireless power transmissions 110 may be radio frequency (RF) transmissions sent from the wireless power transmitter 104.
  • the wireless power transmissions 110 may be a few milliwatt (mW) or lower power RF transmissions.
  • the wireless power transmissions 110 may be an electromagnetic field generated by the wireless power transmitter 104.
  • the wireless power transmitter 104 may be connected to one or more antennas 118 configured to output the wireless power transmissions 110.
  • the one or more antennas 118 may be dipole antennas, antenna arrays, inductive coils, etc. In some embodiments, the one or more antennas 118 may be one or more directional antennas configured to output the wireless power transmissions 110 along a selected transmission path. The wireless power transmissions 110 emanating from the wireless power transmitter 104 and its radiating one or more antennas 118 may beam power to the one or more smart windows 108.
  • the wireless power receiver 106 may be any type wireless power receiver configured to enable wireless power transmission in which electrical energy is received from the wireless power transmitter 104 via the wireless power transmissions 110.
  • the one or more antennas 111 connected to the wireless power receiver 106 may be configured to receive the wireless power transmissions 110.
  • the one or more antennas 111 may be dipole antennas, antenna arrays, inductive coils, etc.
  • the one or more antennas 111 may be one or more inductive coil configured to support near field wireless power reception when the wireless power transmissions are an electromagnetic field generated by the wireless power transmitter 104.
  • the one or more antennas 111 may be RF antennas configured to support RF wireless power reception when the wireless power transmissions are RF transmissions generated by the wireless power transmitter 104.
  • the one or more antennas 118 of the wireless power transmitter 104 may be one or more directional antennas configured to receive the wireless power transmissions 110 along a selected reception direction.
  • the one or more antennas 118 and the one or more antennas 111 may be aligned with one another when the smart window 108 and wireless power transmitter 104 are installed such that a transmission path of the one or more antennas 118 aligns with a reception direction of the one or more antennas 111.
  • the wireless power transmitter 104 and one or more antennas 118 may be components of a window adjustment unit 103, such as a control panel, control switch, master control unit, building control unit, vehicle control system, etc., that may enable a user to control the one or more smart windows 108.
  • the window adjustment unit 103 may include a user interface configured to enable a user to interact with the window adjustment unit 103 to control an optical state of a smart window 108, such as to brighten, darken, etc. the smart window 108.
  • the commands from the user may be communicated as part of the wireless power transmissions 110 themselves sent from the wireless power transmitter 104 to the wireless power receiver 106.
  • the commands may be encoded into the wireless power transmissions 110 to support wireless communication between the window adjustment unit 103 and the window control unit 105.
  • the wireless power transmissions 110 may be multi- channel transmissions with power transmitted in a first subset of one or more RF channels and communications transmitted in a second subset of one or more RF channels.
  • the window adjustment unit 103 may communicate with the window control unit 105 to send commands to the window control unit to control an optical state of a smart window 108.
  • a window adjustment unit 103 may be optional in various embodiments, as in some scenarios the smart window 108 may be controlled without a window adjustment unit 103. While FIG. 1A illustrates the wireless power transmitter 104 as part of the optional window adjustment unit 103, the window adjustment unit 103 and wireless power transmitter 104 may be separate devices.
  • the EC window system 100 may include at least one wireless power transmitter 104 and at least one smart window 108.
  • multiple smart windows 108 and/or multiple wireless power transmitters 104 may be present in the EC system 100, such as more than one smart window 108 and more than one wireless power transmitter 104 (and optionally more than one multiple window adjustment unit 103) in the enclosure 102.
  • FIG.1A illustrates at least two smart windows 108, one smart window 108 may be present in the EC window system 100, two smart windows 108 may be present in the EC window system 100, or more than two (e.g., three, four, five, or more) smart windows 108 may be present in the EC window system 100. While FIG.
  • FIG. 1A illustrates a single wireless power transmitter 104 (and a single optional window adjustment unit 103) more than one (e.g., two, three, four, five, or more) wireless power transmitters 104 (and optional window adjustment units 103) may be present in the EC window system 100.
  • FIG. 1B is a schematic representation of an EC window system 150 according to various embodiments. With reference to FIGS.1A and 1B, the EC window system 150 of FIG.1B is similar to the EC window system of FIG.
  • the window control unit 105 of the smart window 108 may include a separate wireless communication receiver 156 and one or more antennas 158.
  • the window adjustment unit 103 may include a separate wireless communication transmitter 154 and one or more antennas 159.
  • the wireless communication transmitter 154 and one or more antennas 159 may output wireless communication transmissions 160 to the one or more antennas 158 and wireless communication receiver 156 of the window control unit 105 of the smart window 108.
  • the wireless communication transmissions 160 may include commands indicated by a user to control an optical state of a smart window 108, such as to brighten, darken, etc. the smart window 108.
  • the window adjustment unit 103 may communicate with the window control unit 105 to send commands to the window control unit to control an optical state of a smart window 108.
  • FIG. 1B illustrates the wireless power transmitter 104 and wireless communication transmitter 154 as part of the optional window adjustment unit 103, in other configurations the window adjustment unit 103 and the wireless communication transmitter 154 may be components of one device and the wireless power transmitter 104 may be a separate device. While FIG. 1B illustrates a wireless communication transmitter 154 and wireless communication receiver 156, alternatively the wireless communication transmitter 154 and wireless communication receiver 156 may not be dedicated transmit and receiver devices, but may be transceivers.
  • a window control unit 105 may receive output signals from one or more window adjustment unit 103, and determine an amount of voltage or current to apply across one or more electrochromic device using a predetermined relationship between the received output signals and the desired optical properties of the smart window.
  • FIGS. 1A and 1B illustrate the wireless power transmitter 104 and wireless power receiver 106 a relative distance from one another, that relative distance is not intended to be limiting and the wireless power transmitter 104 may vary in distance from the wireless power receiver 106 in the various embodiments.
  • the effective range of the wireless power transmissions 110 based on the type of wireless power system may govern a maximum distance between the wireless power transmitter 104 and wireless power receiver 106.
  • the wireless power transmitter 104 may be close to the wireless power receiver 106, such as in the window frame supporting an EC device.
  • the wireless power transmitter 104 and wireless power receiver 106 may be located across a room from one another (e.g., on opposite sides of the room, on different walls of the room, etc.).
  • FIG. 2 illustrates an exemplary electrochromic device.
  • an exemplary electrochromic device 200 may include a first transparent conductor layer 202a, a working electrode 204, a solid state electrolyte 206, a counter electrode 208, and a second transparent conductor layer 202b.
  • electrochromic devices may also include first and second light transmissive substrates 210a, 210b respectively positioned in front of the first transparent conductor layer 202a and/or positioned behind the second transparent conductor layer 202b.
  • the first and second substrates 210a, 210b may be formed of a transparent material such as glass or plastic.
  • the first and second transparent conductor layers 202a, 202b may be formed from transparent conducting films fabricated using inorganic and/or organic materials.
  • the transparent conductor layers 202a, 202b may include inorganic films of transparent conducting oxide (TCO) materials, such as indium tin oxide (ITO) or fluorine doped tin oxide (FTO).
  • TCO transparent conducting oxide
  • ITO indium tin oxide
  • FTO fluorine doped tin oxide
  • organic films in transparent conductor layers 202a, 202b may include graphene and/or various polymers.
  • the working electrode 204 may include a nanostructured electrochemically-active material, such as nanostructures 212 of a doped or undoped transition metal oxide bronze, as well as optional nanostructures 213 of a transparent conducting oxide (TCO) composition shown schematically as circles and hexagons for illustration purposes only.
  • TCO transparent conducting oxide
  • nanostructures 212, 213 may be embedded in an optically transparent matrix material or provided as a packed or loose layer of nanostructures exposed to the electrolyte.
  • the doped transition metal oxide bronze of nanostructures 212 may be a ternary composition of the type AxMzOy, where M represents a transition metal ion species in at least one transition metal oxide, and A represents at least one dopant.
  • Transition metal oxides that may be used in the various embodiments include, but are not limited to any transition metal oxide which can be reduced and has multiple oxidation states, such as niobium oxide, tungsten oxide, molybdenum oxide, vanadium oxide, titanium oxide and mixtures of two or more thereof.
  • the nanostructured transition metal oxide bronze may include a plurality of tungsten oxide (WO3–x) nanoparticles, where 0 ⁇ x ⁇ 1, such as 0 ⁇ x ⁇ 0.8, or lithium tungsten oxide nanoparticles.
  • nanostructures 213 may optionally be mixed with the doped transition metal oxide bronze nanostructures 212 in the working electrode 204.
  • the nanostructures 213 may include at least one TCO composition, which prevents UV radiation from reaching the electrolyte and generating electrons.
  • the nanostructures 213 may include an indium tin oxide (ITO) composition, which may be a solid solution of around 60– 95 wt% (e.g., 85–90 wt%) indium(III) oxide (In2O3) and around 5–40 wt% (e.g., 10– 15 wt%) tin(IV) oxide (SnO 2 ).
  • the nanostructures 213 may include an aluminum-doped zinc oxide (AZO) composition, which may be a solid solution of around 99 wt% zinc oxide (ZnO) and around 2 wt% aluminum(III) oxide (Al2O3).
  • Additional or alternative TCO compositions that may be used to form nanostructures 213 in the various embodiments include, but are not limited to, indium oxide, zinc oxide and other doped zinc oxides such as gallium-doped zinc oxide and indium-doped zinc oxide.
  • the nanostructures 212 and optional nanostructure 213 of the working electrode may modulate transmittance of visible radiation as a function of applied voltage and/or current by operating in two different modes.
  • a first mode may be a highly solar transparent (“bright”) mode in which the working electrode 204 is transparent to NIR radiation and visible light radiation.
  • a second mode may be a visible blocking (“dark”) mode in which the working electrode 204 absorbs radiation in the visible spectral region and at least a portion of the NIR spectral region.
  • application of a first voltage having a negative bias may cause the electrochromic device to operate in the dark mode, blocking transmittance of visible and NIR radiation at wavelengths of around 780–2500 nm.
  • application of a second voltage having a positive bias may cause the electrochromic device to operate in the bright mode, allowing transmittance of radiation in both the visible and NIR spectral regions.
  • the applied voltage may be between -2V and 2V.
  • the first voltage may be -2V
  • the second voltage may be 2V.
  • the nanostructures 212 and/or 213 may be embedded in a matrix and/or capped by a capping layer.
  • the capping layer may comprise a metal oxide material, such as niobium oxide or lithium niobate
  • the matrix may comprise an ionically conductive and electrically insulating lithium rich antiperovskite (LiRAP) material, as described in U.S. Patent Number 10,698,287 B2, incorporated herein by reference in its entirety.
  • the LiRAP material may have a formula Li 3 OX, where X is F, Cl, Br, I, or any combination thereof.
  • the LiRAP material may comprise Li 3 OI.
  • the solid state electrolyte 206 may include at least a polymer material and an optional plasticizer material.
  • the solid state electrolyte 206 may further include a salt containing, for example, an ion species selected from the group of lanthanides (e.g., cerium, lanthanum, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium), alkali metals (e.g., lithium, sodium, potassium, rubidium, and cesium), and alkali earth metals (e.g., beryllium, magnesium, calcium, strontium, and barium).
  • lanthanides e.g., cerium, lanthanum, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium
  • such salt in the solid state electrolyte 206 may contain a lithium and/or sodium ions.
  • Polymers that may be part of the electrolyte 206 may include, but are not limited to, poly(methyl methacrylate) (PMMA), poly(vinyl butyral-co-vinyl alcohol-co-vinyl acetate) (PVB), poly(ethylene oxide) (PEO), polyurethane acrylate, fluorinated co-polymers such as poly(vinylidene fluoride-co-hexafluoropropylene), poly(acrylonitrile) (PAN), poly(vinyl alcohol) (PVA), etc.
  • PMMA poly(methyl methacrylate)
  • PVB poly(vinyl butyral-co-vinyl alcohol-co-vinyl acetate)
  • PEO poly(ethylene oxide)
  • PEO polyurethane acrylate
  • fluorinated co-polymers such as poly(vinylidene fluoride-co-hex
  • Plasticizers that may be part of the polymer electrolyte formulation include, but are not limited to, glymes (tetraglyme, triglyme, diglyme etc.), propylene carbonate, ethylene carbonate, ionic liquids (1-ethyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium hexafluorophosphate, 1-butyl-3- methylimidazolium bis(trifluoromethane sulfonyl) imide, 1-butyl-1-methyl- pyrrolidinium bis(trifluoromethane sulfonyl)imide, etc.), N,N-dimethylacetamide, and mixtures thereof.
  • the counter electrode 208 of the various embodiments should be capable of storing enough charge to sufficiently balance the charge needed to cause visible tinting to the nanostructured transition metal oxide bronze in the working electrode 204.
  • the counter electrode 208 may be formed as a conventional, single component film, a nanostructured film, or a nanocomposite layer.
  • the counter electrode 208 may be formed from at least one passive material that is optically transparent to both visible and NIR radiation during the applied biases.
  • Examples of such passive counter electrode materials may include CeO 2 , CeVO 2 , TiO 2 , indium tin oxide, indium oxide, tin oxide, manganese or antimony doped tin oxide, aluminum doped zinc oxide, zinc oxide, gallium zinc oxide, indium gallium zinc oxide, molybdenum doped indium oxide, Fe 2 O 3 , and/or V 2 O 5.
  • the counter electrode 208 may be formed from at least one complementary material, which may be transparent to NIR radiation but which may be oxidized in response to application of a bias, thereby causing absorption of visible light radiation.
  • the counter electrode 208 may include nanostructures of one or more passive materials and/or one or more complementary materials described above embedded in a matrix and/or capped by a capping layer.
  • the capping layer may comprise a metal oxide material, such as niobium oxide or lithium niobate, and the matrix may comprise the LiRAP material.
  • the smart window 300 may be an example of the smart window 108.
  • the smart window 108 may include an electrochromic device 302, which may be similar to the electrochromic device 200 discussed above.
  • the smart window 300 may include a frame 319.
  • a frame 319 may provide support to components of the smart window 300, but may not be required and may therefore be optional.
  • the frame 319 may support the electrochromic device 302 and/or the window control unit 105.
  • the window control unit 105 may be partially and/or fully disposed within the frame 319.
  • the frame 319 may maintain the gap between the electrochromic device 302 and an inner pane (not shown).
  • the gap may be maintained at below atmospheric pressure, may be filled with air, or may be filled with an inert gas, such as argon.
  • the gap may include a portion of the window control unit 105 therein.
  • the window control unit 105 may be supported at least in part between a portion of the electrochromic device 302 and the frame 319.
  • the inner pane may be formed of glass or plastic and may be coated with a low-emissivity coating.
  • the inner pane may be disposed inside of an enclosure, such as enclosure 102102, in which the smart window 300 is mounted, with the electrochromic device 302 disposed toward the outside of the enclosure, such as enclosure 102.
  • a glass pane 316 may form the outermost layer of the smart window 300.
  • the glass pane 316 may be supported by the frame 319.
  • the glass substrate of the electrochromic device 302 may form the glass pane 316 (or part thereof).
  • the substrate may be a glass pane 316 that is sized for residential or commercial window applications.
  • the glass pane 316 may be an additional glass layer overlaying the glass substrate of the electrochromic device 302.
  • the glass pane 316 may be made of any of a number of suitable materials, for example, clear or tinted soda lime glass, including soda lime float glass. Such glass may be tempered or untempered. In some embodiments, the glass pane 316 may be made of architectural glass or a mirror material.
  • the window control unit 105 of the smart window 300 may be electrically connected to the electrochromic device 302 by one or more wires, such as a connector 330 (e.g., a pigtail connector, etc.). As an example, the connector 330 may connect the power driving electronics of the window control unit 105 to the electrochromic device 302.
  • the power driving electronics 318 of the window control unit 105 may be various devices and/or circuitry configured to electrically connect the wireless power receiver 106 to a charging element 321.
  • the power driving electronics 318 of the window control unit 105 may be various devices and/or circuitry configured to electrically connect the charging element 321 to the electrochromic device 302 via the connector 330.
  • the power driving electronics 318 may include various devices and/or circuitry, such as one or more controllers, switches, resistors, inductors, wires, drivers, etc., singularly or in various combinations.
  • the power driving electronics 318 may include a controller 325 (e.g., a microcontroller, etc.), a switch 322 (e.g., a three-position switch, etc.), and a window driver (e.g., a direct current (DC) to DC converter, etc.).
  • the controller 325 may be configured with various algorithms, conditions, and/or settings to control the operation of the switch 322 and/or window driver 326.
  • the controller 325 may be connected to the wireless power receiver 106, switch 322, window driver 326, and/or other components of the window control unit 105 by various wires or other type connections to thereby exchange information and/or control signals with the wireless power receiver 106, switch 322, window driver 326, and/or other components of the window control unit 105.
  • the charging element 321 may one or more capacitor (e.g., an ultracapacitor, etc.), one or more battery, a combination of one or more capacitor and one or more battery, or any other type electrical storage device configured to store an electrical charge and dissipate an electrical charge.
  • the power driving electronics 318 may be configured to receive electrical energy from the wireless power receiver 106 and output the electrical energy to the charging element 321.
  • the controller 325 may be configured with various algorithms, conditions, and/or settings to control the switch 322 to provide electrical energy from the window driver 326 to the charging element 321 to thereby charge the charging element 312.
  • the power driving electronics 318 may be configured to provide electrical energy from the charging element 321 to the electrochromic device 302.
  • the controller 325 may be configured with various algorithms, conditions, and/or settings to control the switch 322 to provide electrical energy from the charging element 321 to the window driver 326 to thereby cause the window driver 326 to apply a bias voltage to the electrochromic device 302.
  • the power driving electronics 318 may be configured to provide electrical energy from the electrochromic device 302 to the charging element 321.
  • the controller 325 may be configured with various algorithms, conditions, and/or settings to control the switch 322 dissipate a charge from the electrochromic device 302 through the window driver 326 to the charging element 312 to thereby charge the charging element 312.
  • commands from a user may be communicated as part of the wireless power transmissions 110 themselves sent to the wireless power receiver 106.
  • the wireless communication receiver 156 may be included in the window control unit 105 and connected to the wireless power receiver 106 and/or one or more antennas 111.
  • Wiring 330 may include various components (e.g., leads, bus bars, etc.) that connect the TCO layers 309a, 309b to provide the electric potential and a circuit across the electrochromic device 302, to affect changes in the transmissivity of the smart window 300. Specifically, wiring 330 may connect the electrochromic device 302 to the window driver 326, which allows for the polarity of the charge across the electrochromic device 302 to be reversed as part of the change in optical state.
  • the controller 325 may be configured with various algorithms, conditions, and/or settings to direct the switch 322 and the window driver 326.
  • the controller 328 may calculate a magnitude and polarity of a bias voltage that should be applied to achieve a desired optical state. Based on comparing the magnitude of the bias voltage and/or other information (e.g., state charging element 321, etc.), the controller 325 may send control signals controlling the switch 322 to change the optical state of the electrochromic device 302.
  • the controller 325 may control the switch 322 and/or window driver 326, and if applicable, an amount of power drawn from the charging element 321.
  • the bias voltage may drive a transition of the electrochromic device 302 from one optical state to another.
  • the controller 325 may control the electrochromic device 302 to make the smart window 300 more or less transmissive to light, thereby dynamically changing the amount of light that passes into the enclosure, such as enclosure 102, from outside.
  • power e.g., a bias voltage
  • a bias voltage may be supplied the EC device 302 to change the optical state thereof. For example, energy by be applied to charge the EC device 302, such that the EC device 302 is switched from a thermodynamically low energy state to a thermodynamically high energy state, as measured by the open circuit voltage of the EC device 302.
  • the high energy state corresponds to a dark (i.e., substantially opaque) optical state
  • the low energy state corresponds to a bright optical state (e.g., a bleached or substantially transparent optical state).
  • Thermodynamically, there is driving force to equalize the electrochemical potentials of the working electrode 308 (Eworking_electrode) and the counter electrode 304 (Ecounter_electrode), such that (Eworking_electrode Ecounter_electrode).
  • the open circuit voltage (Eoc) of the EC device 302 may be equal to Eworking_electrode - Ecounter_electrode.
  • the power driving electronics 318 may be configured to store energy released from the EC device 302, when the EC device 302 changes optical state.
  • the power driving electronics 318 may be configured to store energy released from the EC device 302 in the charging element 321.
  • the EC device 302 may experience photochromic darkening, due to photochromic charge (e.g., photoelectrochemically generated charge) accumulation in the EC device 302.
  • photochromic charge e.g., photoelectrochemically generated charge
  • exposure to UV light from the Sun may result in photochromic charge accumulation in the working electrode 308.
  • the EC device 302 may experience unwanted darkening and reduction of light and unintentional onset of the dark optical state.
  • the smart window 300 may also be configured to store the photochromic charge accumulated in the working electrode 308.
  • window driver 326 and switch 322 may be configured to discharge the photochromic charge from the EC device 302 and store the same in the charging element 321, as disclosed above.
  • energy from the EC device 302 may be provided for storage in the charging element 321 when the EC device 302 is intentionally switched from one state to another (e.g., from the dark optical state to the bright optical state) and/or to remove photogenerated charge that accumulates in the EC device due to photochromic darkening.
  • the controller 325 may determine if the EC device 302 has been intentionally set into the dark or the bright state.
  • controller 325 may release the excess charge to the charging element 321 to brighten the EC device 302.
  • the photogenerated charge accumulated in the EC device 302 due to photochromic darkening is removed for storage and the EC device 302 is brightened to the bright state.
  • the embodiment method has a two-fold benefit of mitigating UV degradation and capturing energy.
  • the EC device 302 may be installed in dark state (i.e., having accumulated charge), or similarly charged to a dark state by a temporary external power source applied to the EC device 302 upon installation (i.e., charged by the temporary power source), and then controller 325 may release the excess charge to the charging element 321 to brighten the EC device 302.
  • This installation in the charged stated, or post installation initial temporary charging, of the EC device 302 may reduce the amount of wireless power needing to be provided to the window control unit 105 as the charging element 321 may be charged initially by the EC device 302 itself as compared to having to wireless provide the same charge to the charging element 321.
  • This installation in the charged stated, or post installation initial temporary charging may also reduce the time required to provide wireless power transmission to the window control unit 105 to support full normal operation of the window 300.
  • energy generated by the EC device 302 during a change in optical state of the EC device 302 is stored in a charging element 321.
  • the change of optical state of the EC device 302 may comprise an intentional change from a dark optical state to a bright optical state of the EC device 302 and/or may comprise photochromic darkening which results in accumulation of photochromic charge in the EC device 302.
  • the method further includes removing the photochromic charge from the EC device 302 to brighten the EC device 302 and to provide a current to the charging element 321 to store the energy.
  • FIG. 3A illustrates an example configuration of the window control unit 105 in which the one or more antennas 111 may be disposed within the window control unit 105 itself.
  • FIG. 3B is a schematic representation of a smart window 350 according to various embodiments. With reference to FIGS. 1A-3B, the smart window 350 may be an example of the smart window 108. The smart window 350 may be similar to smart window 300 described with reference to FIG.
  • FIG. 3A illustrates an example configuration of the window control unit 105 in which the one or more antennas 158 may be disposed within the window control unit 105 itself.
  • FIG. 4 is a cut-away schematic representation of a portion of a smart window 400 according to various embodiments. With refence to FIGS.
  • the smart window 400 may be a specific example of a portion of the smart windows 108, 300, 350 described above.
  • the smart window 400 may include a frame 319 supporting the window control unit 105 and the EC device 302.
  • the window control unit 105 may be connected to the EC device 302 by the connector 330.
  • the window control unit 105 (and the one or more antennas 111, charging element 321, wireless power receiver 106, and/or power driving electronics 318 therein) may be disposed between the EC device 302 and the frame 319. In this manner, the window control unit 105 may be hidden from view when the smart window 400 is installed.
  • FIG. 5A is a schematic representation of a smart window 500 according to various embodiments.
  • the smart window 500 is similar to the smart window 300 described above, except that the one or more antennas 111 may extend outside the window control unit 105 and into the frame 319 of the smart window 500.
  • the one or more antennas 111 may be integrated with the smart window 500 by being attached to, or incorporated, in the window frame 319.
  • FIG. 5B is a schematic representation of a smart window 550 according to various embodiments. With reference to FIGS.
  • the smart window 550 is similar to the smart windows 350 and 500 described above, except that in addition to the one or more antennas 111 extending outside the window control unit 105 and into the frame 319 of the smart window 550, the one or more antennas 158 also extend outside the window control unit 105 and into the frame 319 of the smart window 550.
  • the one or more antennas 158 may be integrated with the smart window 550 by being attached to, or incorporated, in the window frame 319.
  • FIG. 6A is a schematic representation of a smart window 600 according to various embodiments. With reference to FIGS.
  • the smart window 600 is similar to the smart window 300 described above, except that the one or more antennas 111 may extend outside the window control unit 105 and be incorporated in, or positioned adjacent to, the glass pane 316. While shown as adjacent to the glass pane 316, such position is merely representative, as the one or more antennas 111 may be provided in a number of different locations in various embodiments. In various embodiments, the one or more antennas 111 may be coated on the glass pane 316 or embedded in the glass pane 316. [0072] In various embodiments, the one or more antennas 111 may be formed in a variety of configurations in order to avoid impeding the appearance and/or function of the smart window 600.
  • one or more antennas 111 may be a specialized coating layered (e.g., printed, deposited, etc.) on the glass pane 316.
  • the one or more antennas 111 may be printed on the glass plane 316 when the wireless power transmitter 104 and wireless power receiver 106 are part of a RF beaming wireless power system.
  • one or more antennas 111 may be one or more antennas 111 that are embedded in one or more layer of the glass pane 316.
  • the one or more antennas 111 may be positioned at the edge of the glass pane 316 as strips located at the intersection with the window frame 319 or on the edge of the glass pane 316. [0073] FIG.
  • FIGS. 1A-6B is a schematic representation of a smart window 650 according to various embodiments.
  • the smart window 650 is similar to the smart windows 350, 500, 550, and 600 described above, except that in addition to the one or more antennas 111 extending outside the window control unit 105 and being incorporated in, or positioned adjacent to, the glass pane 316, the one or more antennas 158 also may extend outside the window control unit 105 and be incorporated in, or positioned adjacent to, the glass pane 316. While shown as adjacent to the glass pane 316, such position is merely representative, as the one or more antennas 158 may be provided in a number of different locations in various embodiments.
  • the one or more antennas 158 may be coated on the glass pane 316 or embedded in the glass pane 316.
  • the one or more antennas 158 may be formed in a variety of configurations in order to avoid impeding the appearance and/or function of the smart window 650.
  • one or more antennas 158 may be a specialized coating layered (e.g., printed, deposited, etc.) on the glass pane 316.
  • one or more antennas 158 may be one or more antennas 158 that are embedded in one or more layer of the glass pane 316.
  • FIG. 7A is a schematic representation of a window adjustment unit 103 according to various embodiments.
  • the window adjustment unit 103 may include a user interface 704, such as one or more buttons, one or more toggle switches, one or more touch screen displays, etc., and a controller 706 connected to the user interface 704.
  • the controller 706 may be connected to the wireless power transmitter 104.
  • the wireless power transmitter 104 may be connected by one or more wires 710 to a power source 702, such as a building power source, vehicle battery, vehicle alternator, generator, renewable energy source, power grid, etc.
  • a power source 702 such as a building power source, vehicle battery, vehicle alternator, generator, renewable energy source, power grid, etc.
  • the wires 710 may be wires in a wall or ceiling when an enclosure, such as the enclosure 102, in which a smart window (e.g., 108, 300, 350, 400, 500, 550, 600, and/or 650) is installed is a building.
  • a smart window e.g., 108, 300, 350, 400, 500, 550, 600, and/or 650
  • the power source 702 may provide electrical power to the wireless power transmitter 104.
  • the wireless transmitter 104 may output wireless power transmissions 110 to beam power to a smart window (e.g., 108, 300, 350, 400, 500, 550, 600, and/or 650).
  • the window adjustment unit 103 may include the wireless communication transmitter 154.
  • commands from a user may be communicated as part of the wireless power transmissions 110 themselves sent by the wireless power transmitter 104.
  • the wireless communication transmitter 154 may be included in the window adjustment unit 103 and connected to the wireless power transmitter 104, controller 706, and/or one or more antennas 118.
  • the wireless communication transmitter 154 may be controlled to output commands from a user received via the user interface 704 to a smart window (e.g., 108, 300, 350, 400, 500, 550, 600, and/or 650) communicated as part of the wireless power transmissions 110.
  • a smart window e.g., 108, 300, 350, 400, 500, 550, 600, and/or 650
  • the method of operation of an EC window system may include receiving user inputs selecting an optical state (e.g., bright state, dark state, etc.) for one or more smart windows (e.g., 108, 300, 350, 400, 500, 550, 600, and/or 650) via the user interface 704, and controlling the operations of the wireless power transmitter 104 and/or wireless communication transmitter 154 via the controller 706 to send commands corresponding to the user’s selected optical state as part of the wireless power transmissions 110 themselves sent by the wireless power transmitter 104 to power the one or more smart windows wireless.
  • FIG. 7B is a schematic representation of a window adjustment unit 103 according to various embodiments of the present disclosure.
  • the window adjustment unit 103 of FIG. 7B may differ from that of FIG.7A in that the wireless communication transmitter 154 may be connected to its own one or more antennas 159. In this manner, the wireless communication transmitter 154 may send its own wireless communication transmissions 160.
  • commands from a user may be communicated separately from the wireless power transmissions 110 as separate wireless communication transmissions 160.
  • the wireless communication transmitter 154 may be included in the window adjustment unit 103 and connected to the controller 706 and the one or more antennas 159.
  • the wireless communication transmitter 154 may be controlled to output commands from a user received via the user interface 704 to a smart window (e.g., 108, 300, 350, 400, 500, 550, 600, and/or 650) communicated as separate wireless communication transmissions 160 distinct from the wireless power transmissions 110.
  • a smart window e.g., 108, 300, 350, 400, 500, 550, 600, and/or 650
  • the method of operation of an EC window system may include receiving user inputs selecting an optical state (e.g., bright state, dark state, etc.) for one or more smart windows (e.g., 108, 300, 350, 400, 500, 550, 600, and/or 650) via the user interface 704, and controlling the operations of the wireless communication transmitter 154 via the controller 706 to send commands corresponding to the user’s selected optical state as part of the wireless communication transmissions 160.
  • the wireless communication transmissions 160 may be sent separate from the wireless power transmissions 110 sent by the wireless power transmitter 104 to power the one or more smart windows wireless.

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  • Engineering & Computer Science (AREA)
  • Computer Networks & Wireless Communication (AREA)
  • Physics & Mathematics (AREA)
  • Power Engineering (AREA)
  • Structural Engineering (AREA)
  • Nonlinear Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Signal Processing (AREA)
  • Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)

Abstract

L'invention concerne un procédé de fonctionnement d'un dispositif électrochromique (EC), par exemple une "fenêtre intelligente" (108), qui consiste à stocker de l'énergie électrique générée à partir de transmissions de puissance sans fil (110) reçue par un récepteur de puissance sans fil (106), et à commander un état optique du dispositif EC, par exemple entre sensiblement transparent et sensiblement opaque, à l'aide de l'énergie électrique stockée.
PCT/IB2022/057677 2021-08-24 2022-08-16 Système électrochromique utilisant une transmission de puissance sans fil WO2023026135A1 (fr)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017007841A1 (fr) * 2015-07-08 2017-01-12 View, Inc. Gestion d'énergie pour des réseaux de fenêtres électro-chromiques
WO2018063919A1 (fr) * 2016-09-30 2018-04-05 View, Inc. Fenêtres électrochromes d'alimentation et alimentées sans fil
WO2018128906A1 (fr) * 2017-01-03 2018-07-12 Polyceed Inc. Structures de dispositif électrochromique
US20190346733A1 (en) * 2018-05-10 2019-11-14 Heliotrope Technologies, Inc. Smart widow system including energy storage unit and methods of using same
US10698287B2 (en) 2017-06-15 2020-06-30 Heliotrope Technologies, Inc. Electrochromic device including lithium-rich anti-perovskite material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017007841A1 (fr) * 2015-07-08 2017-01-12 View, Inc. Gestion d'énergie pour des réseaux de fenêtres électro-chromiques
WO2018063919A1 (fr) * 2016-09-30 2018-04-05 View, Inc. Fenêtres électrochromes d'alimentation et alimentées sans fil
WO2018128906A1 (fr) * 2017-01-03 2018-07-12 Polyceed Inc. Structures de dispositif électrochromique
US10698287B2 (en) 2017-06-15 2020-06-30 Heliotrope Technologies, Inc. Electrochromic device including lithium-rich anti-perovskite material
US20190346733A1 (en) * 2018-05-10 2019-11-14 Heliotrope Technologies, Inc. Smart widow system including energy storage unit and methods of using same

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