WO2023013665A1 - Procédé de prétraitement de minerai d'or et procédé de récupération d'or - Google Patents

Procédé de prétraitement de minerai d'or et procédé de récupération d'or Download PDF

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Publication number
WO2023013665A1
WO2023013665A1 PCT/JP2022/029744 JP2022029744W WO2023013665A1 WO 2023013665 A1 WO2023013665 A1 WO 2023013665A1 JP 2022029744 W JP2022029744 W JP 2022029744W WO 2023013665 A1 WO2023013665 A1 WO 2023013665A1
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WO
WIPO (PCT)
Prior art keywords
gold
ore
gold ore
leaching
pretreatment
Prior art date
Application number
PCT/JP2022/029744
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English (en)
Japanese (ja)
Inventor
圭子 笹木
コジョ トワム コナドゥ
フローレス ディエゴ モイセス メンドーサ
諒太郎 境
郁美 須山
剛 平島
悠二 青木
菜奈 村瀬
Original Assignee
国立大学法人九州大学
住友金属鉱山株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2022080943A external-priority patent/JP2023024269A/ja
Application filed by 国立大学法人九州大学, 住友金属鉱山株式会社 filed Critical 国立大学法人九州大学
Priority to AU2022322227A priority Critical patent/AU2022322227A1/en
Priority to CA3227387A priority patent/CA3227387A1/fr
Publication of WO2023013665A1 publication Critical patent/WO2023013665A1/fr

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00Obtaining noble metals
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/18Extraction of metal compounds from ores or concentrates by wet processes with the aid of microorganisms or enzymes, e.g. bacteria or algae
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/22Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
    • C22B3/24Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition by adsorption on solid substances, e.g. by extraction with solid resins
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Definitions

  • Patent Document 1 discloses a CIP (Carbon In Pulp) method as a method for recovering gold from gold ore.
  • Gold recovery by the CIP method is performed in the following procedure.
  • a dilute cyanide solution of an alkali metal or an alkaline earth metal and an alkali are added to finely ground gold ore to elute gold in the gold ore as a gold cyanide ion complex (Au(CN) 2 ⁇ ).
  • Au(CN) 2 ⁇ gold cyanide ion complex
  • the slurry containing the ore and the gold complex and the activated carbon are brought into contact with each other in a countercurrent flow to adsorb the gold complex to the activated carbon.
  • a hot cyanide solution is allowed to act on the activated carbon separated from the slurry to desorb the gold complex from the activated carbon.
  • the gold is then recovered by subjecting the cyanide solution in which the gold complex is concentrated to electrowinning.
  • electrolytic gold can be recovered by performing electrowinning using a gold solution. It is preferable to reactivate the activated carbon after gold has been eluted and use it repeatedly.
  • the mineral ratio of the gold ore before and after washing was analyzed with an MLA device (manufactured by FEI, model number: MLA650F). Table 1 shows the results.
  • FIG. 3 shows the results of measuring samples 1 to 5 with a TG-DTA device (2000-SA, manufactured by Bruker). Focusing on the endothermic reaction peak of sulfides around 450° C., it can be seen that the endothermic peak of sample 3 is smaller than the endothermic peak of sample 2. This means that sample 3 has less sulfide than sample 2. Pyrite (FeS 2 ) corresponds to sulfide in the composition of the gold ore used in this example. It is considered that pyrite was removed by washing with sulfuric acid.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • Biochemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)

Abstract

L'invention concerne : un procédé de prétraitement de minerai d'or permettant de faciliter la récupération d'or même lorsqu'un minerai d'or contient un sulfure ou un composant carboné ; et un procédé de récupération d'or présentant un taux de récupération d'or élevé. Le procédé de prétraitement comprend une étape d'oxydation biologique dans laquelle un minerai d'or contenant un sulfure et des bactéries oxydant le fer sont mis en contact l'un avec l'autre et maintenus pendant un temps prescrit. Le procédé de récupération d'or comprend : une étape de prétraitement pour appliquer un prétraitement à un minerai d'or au moyen d'un procédé de prétraitement ; une étape de lixiviation pour lixivier l'or à partir du minerai d'or pour obtenir un lixiviat ; une étape d'adsorption pour permettre à du charbon actif d'adsorber l'or dans le lixiviat ; et une étape d'élution pour éluer l'or du charbon actif pour obtenir une solution d'or. Du fait que les particules d'or contenant du sulfure sont décomposées par oxydation par l'action des bactéries oxydant le fer, les particules d'or sont libérées, ce par quoi la récupération d'or est facilitée. Par conséquent, le taux de récupération d'or peut être augmenté.
PCT/JP2022/029744 2021-08-05 2022-08-03 Procédé de prétraitement de minerai d'or et procédé de récupération d'or WO2023013665A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU2022322227A AU2022322227A1 (en) 2021-08-05 2022-08-03 Gold ore pretreatment method and gold recovery method
CA3227387A CA3227387A1 (fr) 2021-08-05 2022-08-03 Procede de pretraitement de minerai d'or et procede de recuperation d'or

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2021-128703 2021-08-05
JP2021128703 2021-08-05
JP2022080943A JP2023024269A (ja) 2021-08-05 2022-05-17 金鉱石の前処理方法および金回収方法
JP2022-080943 2022-05-17

Publications (1)

Publication Number Publication Date
WO2023013665A1 true WO2023013665A1 (fr) 2023-02-09

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ID=85155713

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2022/029744 WO2023013665A1 (fr) 2021-08-05 2022-08-03 Procédé de prétraitement de minerai d'or et procédé de récupération d'or

Country Status (3)

Country Link
AU (1) AU2022322227A1 (fr)
CA (1) CA3227387A1 (fr)
WO (1) WO2023013665A1 (fr)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4729788A (en) * 1987-01-23 1988-03-08 Advanced Mineral Technologies, Inc. Thermophilic microbial treatment of precious metal ores
JP2008302356A (ja) * 1995-06-02 2008-12-18 Geobiotics Llc 非撹拌表面バイオリアクター中の固形物質のバイオ処理方法
US20090158893A1 (en) * 2007-11-28 2009-06-25 Barrick Gold Corporation Microbial pre-treatment of double refractory gold ores
JP2015214731A (ja) * 2014-05-12 2015-12-03 住友金属鉱山株式会社 金の回収方法
JP2016128602A (ja) * 2015-01-09 2016-07-14 ソシエダード プンタ デル コブレ エス.エー.Sociedad Punta Del Cobre S.A. 鉱物精鉱用の担体及び鉱物精鉱の浸出法
JP2018035413A (ja) * 2016-09-01 2018-03-08 Jx金属株式会社 貴金属の回収方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4729788A (en) * 1987-01-23 1988-03-08 Advanced Mineral Technologies, Inc. Thermophilic microbial treatment of precious metal ores
JP2008302356A (ja) * 1995-06-02 2008-12-18 Geobiotics Llc 非撹拌表面バイオリアクター中の固形物質のバイオ処理方法
US20090158893A1 (en) * 2007-11-28 2009-06-25 Barrick Gold Corporation Microbial pre-treatment of double refractory gold ores
JP2015214731A (ja) * 2014-05-12 2015-12-03 住友金属鉱山株式会社 金の回収方法
JP2016128602A (ja) * 2015-01-09 2016-07-14 ソシエダード プンタ デル コブレ エス.エー.Sociedad Punta Del Cobre S.A. 鉱物精鉱用の担体及び鉱物精鉱の浸出法
JP2018035413A (ja) * 2016-09-01 2018-03-08 Jx金属株式会社 貴金属の回収方法

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Publication number Publication date
CA3227387A1 (fr) 2023-02-09
AU2022322227A1 (en) 2024-02-15

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