WO2023000632A1 - Laser-assisted in-situ mass transfer method and system - Google Patents

Laser-assisted in-situ mass transfer method and system Download PDF

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WO2023000632A1
WO2023000632A1 PCT/CN2022/072563 CN2022072563W WO2023000632A1 WO 2023000632 A1 WO2023000632 A1 WO 2023000632A1 CN 2022072563 W CN2022072563 W CN 2022072563W WO 2023000632 A1 WO2023000632 A1 WO 2023000632A1
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laser
micro
substrate
led chip
transfer structure
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PCT/CN2022/072563
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French (fr)
Chinese (zh)
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张震
杨伟
刘义杰
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清华大学
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/02Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
    • B23K26/06Shaping the laser beam, e.g. by masks or multi-focusing
    • B23K26/064Shaping the laser beam, e.g. by masks or multi-focusing by means of optical elements, e.g. lenses, mirrors or prisms
    • B23K26/0643Shaping the laser beam, e.g. by masks or multi-focusing by means of optical elements, e.g. lenses, mirrors or prisms comprising mirrors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/02Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
    • B23K26/06Shaping the laser beam, e.g. by masks or multi-focusing
    • B23K26/062Shaping the laser beam, e.g. by masks or multi-focusing by direct control of the laser beam
    • B23K26/0622Shaping the laser beam, e.g. by masks or multi-focusing by direct control of the laser beam by shaping pulses
    • B23K26/0624Shaping the laser beam, e.g. by masks or multi-focusing by direct control of the laser beam by shaping pulses using ultrashort pulses, i.e. pulses of 1ns or less
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/08Devices involving relative movement between laser beam and workpiece
    • B23K26/082Scanning systems, i.e. devices involving movement of the laser beam relative to the laser head
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/70Auxiliary operations or equipment
    • B23K26/702Auxiliary equipment

Definitions

  • the application belongs to the field of semiconductor optoelectronic technology, and in particular relates to a laser-assisted in-situ mass transfer method and system.
  • Micro-LED is a micro-light-emitting diode, which refers to a high-density integrated LED array, in which the distance between LED pixels in the array is on the order of 10 ⁇ m, and each LED pixel can emit light by itself.
  • Micro-LED has become a recognized next-generation display technology in the industry due to its high resolution, low power consumption, high brightness, high color saturation, fast response, thin thickness, and long life.
  • the Micro-LED manufacturing process mainly includes four key technologies, namely epitaxy and chip technology, mass transfer technology, bonding technology, and colorization scheme.
  • the mass transfer technology mainly refers to the technology of quickly and accurately transferring the Micro-LED array grown on the epitaxial substrate to the driving circuit substrate, and forming a good electrical connection and mechanical fixation with the driving circuit.
  • the traditional transfer solution has the problems of long time consumption and insufficient accuracy. Therefore, a time-efficient and high-accuracy method is required Mass transfer method.
  • the existing mass transfer methods mainly include elastic stamp method, laser-assisted transfer method, electrostatic transfer method, electromagnetic transfer method and fluid self-assembly method.
  • the transfer yield of the elastic impression method can reach 99.99% at present, but because the transfer amount per hour can only reach 1.0 to 2.5 ⁇ 10 4 units, the transfer area is small and transfer errors are prone to occur due to the deformation of the stamp.
  • the electrostatic transfer method is easy to cause damage to the LED chip due to its high voltage, and the electromagnetic transfer method requires an additional ferromagnetic layer
  • the laser-assisted transfer method can transfer up to 1 ⁇ 10 8 per hour under a small transfer error unit body, but its transfer yield can only reach 90%.
  • the present application provides a laser-assisted in-situ mass transfer method and system.
  • the present application provides a laser-assisted in-situ mass transfer method, which comprises the following steps:
  • the temporary transfer structure includes a transparent substrate, a heat-sensitive layer, and an adhesive layer;
  • the pulsed laser beam passes through the laser galvanometer system, it directly acts on the position of the Micro-LED chip to be transferred on the temporary transfer structure, and adopts a point-by-point laser scanning method, that is, on the temporary transfer structure
  • Each position of the Micro-LED chip to be transferred uses the pulsed laser to continuously apply multiple pulses, and uses the principle of laser energy accumulation to make the laser energy act on the interface between the transparent substrate and the thermal layer, so that the Micro-LED chip can be selected positively fall onto the target substrate.
  • step S1 the heat-sensitive layer material in the temporary transfer structure is polyimide.
  • step S2 the substrate bonded with the temporary transfer structure is placed directly under the laser galvanometer system, and the Micro-LED chip surface in the temporary transfer structure is located in the laser galvanometer system
  • the laser scans the back side of the surface so that the scanning range of the laser galvanometer system can act on the GaN/sapphire interface of the substrate to the maximum extent.
  • step S3 the distance between the temporary transfer structure on which the Micro-LED chip is bonded and the target substrate is d ⁇ 1.2h, where h is the maximum thickness of the placed Micro-LED chip.
  • step S4 according to the size of the Micro-LED, use To determine the focal length required by the applied laser galvanometer system; where r is the maximum distance from the center of the Micro-LED chip to the edge, ⁇ is the laser wavelength, and f is the focal length of the laser galvanometer.
  • step S4 the laser vibrating mirror system stays at one Micro-LED chip transfer position for several pulses and then directly transfers to the next Micro-LED chip transfer position, during which the laser light does not need to be switched on and off.
  • the present application provides a laser-assisted in-situ mass transfer method, which comprises the following steps:
  • Adopt a point-by-point scanning laser scanning method that is, use a pulsed laser to continuously act on multiple pulses at each position of the Micro-LED chip to be transferred on the temporary transfer structure, and use the principle of laser energy accumulation to make the laser act on the transparent substrate At the interface with the heat-sensitive layer, the Micro-LED chips are selectively dropped onto the target substrate.
  • the present application also provides a laser-assisted in-situ mass transfer system, which is characterized in that it includes an infrared laser, an ultrashort pulse laser, an optical gate, a half-mirror system, a laser beam expander, a laser galvanometer system, a temporary Transfer structure, target substrate, motion stage;
  • the ultrashort pulse laser emits laser with a pulse width less than or equal to 10 ps.
  • the temporary transfer structure includes a transparent substrate, a heat-sensitive layer and an adhesive layer; grooves for receiving Micro-LED chips are provided on the target substrate.
  • the motion table is an xyz three-dimensional precision motion table.
  • the moving table is used to adjust the relative positional relationship between the target substrate and the temporary transfer structure, so that the micro-LED chip groove to be transferred on the target substrate is aligned with the micro-LED chip to be transferred.
  • the half mirror system includes two light inlets and two light outlets perpendicular to each other, and the two light inlets are aligned with the infrared laser and the ultrashort pulse laser, so that the emitted laser light can be directly transmitted to the half-mirror system; optical gates are respectively arranged between the two light inlets of the half-mirror system and the infrared laser and the ultrashort pulse laser; one of the light-out of the half-mirror system The mouth is aligned with the laser galvanometer, so that the laser beam is applied to the mass transfer of Micro-LED chips, and a beam expander is installed at the other light outlet to expand the beam of the generated beam splitting laser so that its energy density reduce, prevent danger, and ensure the application safety of the device; the temporary transfer structure is installed above the target substrate, and the target substrate is installed on the moving platform.
  • this application uses parallel processing of infrared lasers and ultrashort pulse lasers at the same time, wherein the use of long-wavelength infrared lasers can expand the laser spot scanning area while ensuring the efficiency of laser energy transmission, effectively improving Separation efficiency of Micro-LED chips; positioning transfer of Micro-LED chips by using ultra-short pulse laser, in which, the "cold processing" effect of ultra-short pulse laser processing can effectively protect the unprocessed area of the temporary transfer structure and greatly avoid Contamination of Micro-LED chips; positioning transfer of Micro-LED chips using ultra-short pulse lasers, in which the Micro-LED chips are selectively transferred to the target by using the energy accumulation effect of multi-pulse processing of ultra-short pulse laser processing Since the pulse width of the ultrashort pulse laser is only on the order of picoseconds or even femtoseconds, and the number of laser pulses required for the accumulation of multi-pulse laser action energy is small, this method is used to process the huge amount of Micro-LED chips
  • the transfer can greatly increase the transfer efficiency on the basis of effectively improving the processing yield; using the laser galvanometer system to position and move the laser beam can better meet the required processing accuracy and the required laser beam moving speed, and better Realize high-efficiency mass transfer of Micro-LED chips;
  • the half-mirror system is used to convert the two laser beams, which can satisfy the use of the same laser processing optical path for the use of dual beams, and avoid The optical path adjustment is difficult due to the change of the optical path; for the extra laser component generated in the dual-laser coaxial processing system, the laser beam expansion system is added to keep its energy density at a low level and ensure the processing process. Safety.
  • FIG. 1 is a schematic structural diagram of an embodiment of a laser-assisted in-situ mass transfer system of the present application
  • Figures 2 to 3 are schematic diagrams of the process of transferring the Micro-LED chip on the substrate to the temporary transfer structure by using infrared laser;
  • 4 to 6 are schematic diagrams of the process of transferring a Micro-LED chip to a target substrate by using an ultrashort pulse laser.
  • a laser-assisted in-situ mass transfer method includes the following steps:
  • the temporary transfer structure 8 includes a transparent substrate 801, heat sensitive layer 802 and adhesive layer 803;
  • the pulsed laser beam passes through the laser galvanometer system 7, it directly acts on the position of the Micro-LED chip 1103 to be transferred on the temporary transfer structure 8, and adopts a point-by-point scanning laser scanning method, that is, in the temporary
  • a point-by-point scanning laser scanning method that is, in the temporary
  • Each position of the Micro-LED chip to be transferred on the transfer structure uses a pulsed laser to continuously act on multiple pulses, and uses the principle of laser energy accumulation to make the laser act on the interface between the transparent substrate 801 and the heat-sensitive layer 802, so that the Micro-LED Chips 1103 are selectively dropped onto the target substrate 9 .
  • the material of the heat-sensitive layer 802 in the temporary transfer structure 8 is polyimide.
  • step S2 the substrate 11 bonded with the temporary transfer structure 8 is placed directly under the laser galvanometer system 7, and the The surface of the Micro-LED chip 1103 in the temporary transfer structure 8 is located on the back of the laser scanning surface in the laser galvanometer system 7, so that the scanning range of the laser galvanometer system can maximize the GaN/sapphire on the substrate interface.
  • the infrared laser beam rapidly acts on the substrate 11 of the in-situ grown Micro-LED chip through the laser galvanometer system 7, so that the GaN near the interface in the GaN layer 1102 absorbs
  • the thermal energy generated by the laser light is decomposed by heat, so that the Micro-LED chip 1103 is quickly separated from the sapphire substrate 11 , and the Micro-LED chip 1103 is adhered to the temporary transfer structure 8 through the adhesive layer 801 .
  • step S3 in step S3, the distance d ⁇ 1.2h between the temporary transfer structure 8 with the Micro-LED chips 1103 bonded thereto and the target substrate 9, wherein h is the maximum thickness of the placed Micro-LED chip 1103 .
  • step S4 according to the size of the Micro-LED chip 1103, use To determine the focal length required by the laser galvanometer system 7 applied; where, r is the maximum distance from the center position of the Micro-LED chip 1103 to the edge, ⁇ is the laser wavelength, and f is the laser galvanometer system 7 focal length.
  • step S4 the laser galvanometer system 7 stays in a Micro-LED chip transfer position for multiple pulses and then directly transfers to the next Micro-LED The position of the chip is transferred without changing the on-off of the laser.
  • the ultrashort pulse laser emitted by the ultrashort pulse laser 2 passes through the laser galvanometer system 7 and then focuses on the interface between the transparent substrate 801 and the heat-sensitive layer 802 of the temporary transfer structure 8 to be transferred.
  • the ultrashort pulse laser is continuously applied to multiple pulses at this position.
  • the energy of the laser pulses used is low, only when multiple laser pulses act together
  • the thermal effect generated by the energy accumulation effect generated at this position causes air bubbles to be generated between the heat-sensitive layer 802 and the transparent substrate 803 in the temporary transfer structure 8, and the Micro-LED chip 1103 is transferred to the target position in the target substrate 9;
  • the action position of the ultrashort pulse laser beam starts to move to the next Micro-LED chip by controlling the laser galvanometer system.
  • the LED chip is to be transferred, during the movement of the laser beam, due to the interaction between a single laser beam and the thermal layer 802, and the low energy of the set ultrafast laser beam, it is not enough to make it react on the thermal layer 802 Bubbles are produced between the transparent substrate 803, thus ensuring the yield rate during the Micro-LED chip transfer process; when transferring to the next Micro-LED chip to be transferred, the laser vibrating mirror system 7 is used to make the ultrashort pulse laser Multiple pulses are applied continuously here, and the micro-LED chip transfer at this position is completed by using the aforementioned energy accumulation principle.
  • the present application also provides a laser-assisted in-situ mass transfer system, as shown in Figure 1, including an infrared laser 1; an ultrashort pulse laser 2; optical gates 3 and 4; a half-mirror system 5; mirror 6; laser galvanometer system 7; temporary transfer structure 8; target substrate 9;
  • the short-pulse laser light is transmitted through the shutter 4 to the half-mirror system 5 .
  • the ultrashort pulse laser emits laser with a pulse width less than or equal to 10 ps.
  • the temporary transfer structure 8 includes a transparent substrate 801, a heat-sensitive layer 802 and an adhesive layer 803; groove.
  • the motion table 10 is an xyz three-dimensional precision motion table.
  • the moving table 10 is used to adjust the relative positional relationship between the target substrate 9 and the temporary transfer structure 8, so that the The groove of the micro-LED chip to be transferred is aligned with the micro-LED chip 1103 to be transferred.
  • the half mirror system 5 includes two light inlets and two light outlets perpendicular to each other, and the two light inlets are aligned with the infrared laser 1 and the ultrashort pulse laser 2, so that the emitted laser light can be directly transmitted to the half mirror system 5 after passing through the respective optical gates 3 and 4; one of the light outlets is aligned with the laser galvanometer system 7, so that the laser beam Applied to the mass transfer of Micro-LED chips 1103, a laser beam expander 6 is installed at the other light outlet, and the beam splitting laser generated is expanded by using the principle of expanding the laser beam diameter and reducing its laser energy density, so that Its energy density is reduced, which prevents danger and ensures the application safety of the device.
  • This application adopts the parallel processing method of using infrared laser and ultrashort pulse laser at the same time, in which the use of long-wavelength infrared laser can expand the scanning area of laser spot while ensuring the efficiency of laser energy transmission, and effectively improve the separation of Micro-LED chips efficiency;
  • ultrashort pulse laser for positioning transfer of Micro-LED chips.
  • the "cold processing" effect of ultrashort pulse laser processing can effectively protect the unprocessed area of the temporary transfer structure and greatly avoid damage to the Micro-LED chip. pollute;
  • ultrashort pulse laser for positioning transfer of Micro-LED chips, in which, the energy accumulation effect of multi-pulse processing of ultrashort pulse laser is used to selectively transfer Micro-LED chips to the target substrate, due to the ultrashort pulse
  • the pulse width of the laser is only on the order of picoseconds or even femtoseconds, and the number of laser pulses required for the accumulation of multi-pulse laser energy is small. Therefore, using this method to transfer a large amount of Micro-LED chips can effectively improve the processing On the basis of yield rate, the transfer efficiency is greatly increased;
  • the half-mirror system is used to convert the two laser beams, which can satisfy the use of the same laser processing optical path for the use of dual beams, and avoid the difficulty of optical path adjustment caused by the change of the optical path;
  • the laser beam expansion system is added to keep its energy density at a low level and ensure the safety during processing.
  • connection should be understood in a broad sense, for example, it can be a fixed connection or a detachable connection. Connected, or integrally connected; it can be mechanically connected or electrically connected; it can be directly connected or indirectly connected through an intermediary, and it can be the internal communication of two components. Those of ordinary skill in the art can understand the specific meanings of the above terms in this application in specific situations. In addition, in the description of the present application, unless otherwise specified, "plurality" means two or more.

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  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
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Abstract

The present application discloses a laser-assisted in-situ mass transfer method and system, mainly comprising the following content: using the characteristics of a long infrared laser wavelength and a large laser light spot radius while ensuring the laser energy density to scan, by means of a laser galvanometer, a GaN/sapphire substrate on which Micro-LED chips are grown, and lifting off the Micro-LED chips from the substrate and transferring the Micro-LED chips to a temporary transfer structure; using the "cold processing" effect of an ultrashort pulse laser and the energy accumulation principle of the multi-pulse effect to perform point-by-point fast scanning on the temporary transfer structure by using the laser galvanometer to achieve the high-speed fixed-point mass transfer of the Micro-LED chips to a target substrate; and using a semi-transparent mirror to introduce two laser lights into a same laser processing light path, and providing a laser beam expanding device at an unused laser light outlet. In the present application, the mass transfer of Micro-LED chips is performed by using dual-laser beam scanning and pulse laser point-by-point scanning, so that the transfer rate is high and the yield rate is guaranteed.

Description

一种激光辅助原位巨量转移方法及系统A laser-assisted in-situ mass transfer method and system 技术领域technical field
本申请属于半导体光电技术领域,尤其涉及一种激光辅助原位巨量转移方法及系统。The application belongs to the field of semiconductor optoelectronic technology, and in particular relates to a laser-assisted in-situ mass transfer method and system.
背景技术Background technique
Micro-LED即微型发光二极管,是指高密度集成的LED阵列,其中阵列中的LED像素点距离在10μm量级,且每个LED像素都能自发光。相比LCD和OLED技术,Micro-LED凭借其高解析度、低功耗、高亮度、高色彩饱和度、反应速度快、厚度薄、寿命长等特性成为业界公认的下一代显示技术。Micro-LED is a micro-light-emitting diode, which refers to a high-density integrated LED array, in which the distance between LED pixels in the array is on the order of 10 μm, and each LED pixel can emit light by itself. Compared with LCD and OLED technologies, Micro-LED has become a recognized next-generation display technology in the industry due to its high resolution, low power consumption, high brightness, high color saturation, fast response, thin thickness, and long life.
Micro-LED制程主要包含四大关键技术,即磊晶与芯片技术、巨量转移技术、键结技术、彩色化方案。其中巨量转移技术主要是指将生长在外延衬底上的Micro-LED阵列快速精准地转移到驱动电路基板上,并与驱动电路之间形成良好的电气连接和机械固定的技术。然而由于所需转移的Micro-LED芯片数量庞大,且需要快速且准确的转移,因此采用传统的转移方案存在耗时过长且准确度不足的问题,因此需要一种高时效且准确度高的巨量转移方法。The Micro-LED manufacturing process mainly includes four key technologies, namely epitaxy and chip technology, mass transfer technology, bonding technology, and colorization scheme. Among them, the mass transfer technology mainly refers to the technology of quickly and accurately transferring the Micro-LED array grown on the epitaxial substrate to the driving circuit substrate, and forming a good electrical connection and mechanical fixation with the driving circuit. However, due to the large number of Micro-LED chips that need to be transferred, and the need for fast and accurate transfer, the traditional transfer solution has the problems of long time consumption and insufficient accuracy. Therefore, a time-efficient and high-accuracy method is required Mass transfer method.
现有的巨量转移方法主要有弹性印章法、激光辅助转移法、静电转移法、电磁转移法及流体自组装法等。其中,弹性印模法的转移良率目前可达99.99%,但由于其每小时转移量仅能达到1.0至2.5×10 4个单元体,转移面积较小且由于存在印章变形而容易产生转移误差; 静电转移法由于其电压过高容易导致LED芯片被损坏,并且电磁转移法需要额外的铁磁层;激光辅助转移法在较小的转移误差下,其每小时转移量可达1×10 8个单元体,但其转移良率仅能到达90%。 The existing mass transfer methods mainly include elastic stamp method, laser-assisted transfer method, electrostatic transfer method, electromagnetic transfer method and fluid self-assembly method. Among them, the transfer yield of the elastic impression method can reach 99.99% at present, but because the transfer amount per hour can only reach 1.0 to 2.5×10 4 units, the transfer area is small and transfer errors are prone to occur due to the deformation of the stamp. ; The electrostatic transfer method is easy to cause damage to the LED chip due to its high voltage, and the electromagnetic transfer method requires an additional ferromagnetic layer; the laser-assisted transfer method can transfer up to 1×10 8 per hour under a small transfer error unit body, but its transfer yield can only reach 90%.
因此,如何提供一种解决上述技术问题的方案是本领域技术人员需要解决的问题。Therefore, how to provide a solution to the above technical problems is a problem that those skilled in the art need to solve.
发明内容Contents of the invention
为解决现有巨量转移环节中存在的良率、效率的问题,本申请提供一种激光辅助原位巨量转移方法及系统。In order to solve the problems of yield and efficiency in the existing mass transfer link, the present application provides a laser-assisted in-situ mass transfer method and system.
本申请提供一种激光辅助原位巨量转移方法,该巨量转移方法包括以下步骤:The present application provides a laser-assisted in-situ mass transfer method, which comprises the following steps:
S1、准备原位生长有Micro-LED芯片的衬底、临时转移结构、目标基板、激光振镜系统、激光器及运动台,所述临时转移结构包括透明基板、热敏层及粘结层;S1. Prepare a substrate with Micro-LED chips grown in situ, a temporary transfer structure, a target substrate, a laser galvanometer system, a laser, and a motion table. The temporary transfer structure includes a transparent substrate, a heat-sensitive layer, and an adhesive layer;
S2、将原位生长在所述衬底上的Micro-LED芯片粘接在所述临时转移结构的粘接层上,通过使用所述激光振镜系统采用连续扫描的方式将红外激光作用于所述衬底的GaN/蓝宝石界面上,使得靠近界面处的GaN吸收激光能量被分解,从而使得Micro-LED芯片从所述衬底上剥离;S2. Bond the Micro-LED chip grown on the substrate in situ on the adhesive layer of the temporary transfer structure, and use the laser galvanometer system to act on the infrared laser in a continuous scanning manner. on the GaN/sapphire interface of the substrate, so that the GaN near the interface absorbs laser energy and is decomposed, so that the Micro-LED chip is peeled off from the substrate;
S3、将粘接有Micro-LED芯片的所述临时转移结构放置于所述目标基板正上方,利用所述运动台保证所述目标基板上所需放置Micro-LED芯片的位置与所述临时转移结构上的待转移Micro-LED芯片位置对准;S3. Place the temporary transfer structure with the Micro-LED chip bonded directly above the target substrate, and use the motion table to ensure that the position where the Micro-LED chip needs to be placed on the target substrate is consistent with the temporary transfer Structural alignment of Micro-LED chips to be transferred;
S4、将脉冲激光束通过所述激光振镜系统后直接作用于所述临时转移结构上的待转移Micro-LED芯片位置处,采用逐点扫描的激光扫描方式,即在所述临时转移结构上每个待转移Micro-LED芯片位置使用所述脉冲激光连续作用多个脉冲,利用激光能量累计原理使得激光能量作用于所述透明基板与所述热敏层的界面处,使得Micro-LED芯片选择性的落入所述目标基板上。S4. After the pulsed laser beam passes through the laser galvanometer system, it directly acts on the position of the Micro-LED chip to be transferred on the temporary transfer structure, and adopts a point-by-point laser scanning method, that is, on the temporary transfer structure Each position of the Micro-LED chip to be transferred uses the pulsed laser to continuously apply multiple pulses, and uses the principle of laser energy accumulation to make the laser energy act on the interface between the transparent substrate and the thermal layer, so that the Micro-LED chip can be selected positively fall onto the target substrate.
进一步地,在步骤S1中,所述临时转移结构中的所述热敏层材料为聚酰亚胺。Further, in step S1, the heat-sensitive layer material in the temporary transfer structure is polyimide.
进一步地,在步骤S2中,将粘接有所述临时转移结构的衬底放置于所述激光振镜系统正下方,所述临时转移结构中Micro-LED芯片面位于所述激光振镜系统中激光扫描面的背面,使得所述激光振镜系统的扫描范围可以最大限度的作用于所述衬底的GaN/蓝宝石界面。Further, in step S2, the substrate bonded with the temporary transfer structure is placed directly under the laser galvanometer system, and the Micro-LED chip surface in the temporary transfer structure is located in the laser galvanometer system The laser scans the back side of the surface so that the scanning range of the laser galvanometer system can act on the GaN/sapphire interface of the substrate to the maximum extent.
进一步地,在步骤S3中,粘接有Micro-LED芯片的所述临时转移结构与目标基板之间的距离d≈1.2h,其中h为所放置所述Micro-LED芯片的最大厚度。Further, in step S3, the distance between the temporary transfer structure on which the Micro-LED chip is bonded and the target substrate is d≈1.2h, where h is the maximum thickness of the placed Micro-LED chip.
进一步地,在步骤S4中,需根据Micro-LED的尺寸,利用
Figure PCTCN2022072563-appb-000001
来确定所应用所述激光振镜系统所需要的焦距;其中,r为所述Micro-LED芯片中心位置至边缘的最大距离,λ为所述激光波长,f为激光振镜的焦距。
Further, in step S4, according to the size of the Micro-LED, use
Figure PCTCN2022072563-appb-000001
To determine the focal length required by the applied laser galvanometer system; where r is the maximum distance from the center of the Micro-LED chip to the edge, λ is the laser wavelength, and f is the focal length of the laser galvanometer.
进一步地,在步骤S4中,所述激光振镜系统在一个Micro-LED芯片转移位置停留多个脉冲过后直接转移到下一个Micro-LED芯片转移位置,期间不需要改变激光的通断。Further, in step S4, the laser vibrating mirror system stays at one Micro-LED chip transfer position for several pulses and then directly transfers to the next Micro-LED chip transfer position, during which the laser light does not need to be switched on and off.
本申请提供一种激光辅助原位巨量转移方法,该巨量转移方法包括以下步骤:The present application provides a laser-assisted in-situ mass transfer method, which comprises the following steps:
S1、准备原位生长有Micro-LED芯片的衬底、临时转移结构、目标基板,所述临时转移结构包括基板、热敏层及粘结层;S1. Prepare a substrate with Micro-LED chips grown in situ, a temporary transfer structure, and a target substrate, where the temporary transfer structure includes a substrate, a heat-sensitive layer, and an adhesive layer;
S2、将原位生长在所述衬底上的Micro-LED芯片粘接在所述临时转移结构的粘接层上,采用连续扫描的方式将激光作用于所述衬底的界面上,从而使得Micro-LED芯片从所述衬底上剥离;S2. Bond the Micro-LED chip grown on the substrate in situ to the adhesive layer of the temporary transfer structure, and apply laser light to the interface of the substrate in a continuous scanning manner, so that The Micro-LED chip is peeled off from the substrate;
S3、将粘接有Micro-LED芯片的所述临时转移结构放置于所述目标基板正上方,保证所述目标基板上所需放置Micro-LED芯片的位置与所述临时转移结构上的待转移Micro-LED芯片位置对准;S3. Place the temporary transfer structure with the Micro-LED chip bonded directly above the target substrate, ensuring that the position where the Micro-LED chip needs to be placed on the target substrate is consistent with the position to be transferred on the temporary transfer structure Micro-LED chip position alignment;
S4、采用逐点扫描的激光扫描方式,即在所述临时转移结构上每个待转移Micro-LED芯片位置使用脉冲激光连续作用多个脉冲,利用激光能量累计原理使得激光作用于所述透明基板与所述热敏层的界面处,使得Micro-LED芯片选择性的落入所述目标基板上。S4. Adopt a point-by-point scanning laser scanning method, that is, use a pulsed laser to continuously act on multiple pulses at each position of the Micro-LED chip to be transferred on the temporary transfer structure, and use the principle of laser energy accumulation to make the laser act on the transparent substrate At the interface with the heat-sensitive layer, the Micro-LED chips are selectively dropped onto the target substrate.
相应的,本申请还提供一种激光辅助原位巨量转移系统,其特征在于,包括红外激光器、超短脉冲激光器、光闸、半反射镜系统、激光扩束镜、激光振镜系统、临时转移结构、目标基板、运动台;Correspondingly, the present application also provides a laser-assisted in-situ mass transfer system, which is characterized in that it includes an infrared laser, an ultrashort pulse laser, an optical gate, a half-mirror system, a laser beam expander, a laser galvanometer system, a temporary Transfer structure, target substrate, motion stage;
进一步地,所述超短脉冲激光器出射激光脉宽小于等于10ps。Further, the ultrashort pulse laser emits laser with a pulse width less than or equal to 10 ps.
进一步地,所述临时转移结构包括透明基板、热敏层及粘结层;所述目标基板上设有用于接收Micro-LED芯片的凹槽。Further, the temporary transfer structure includes a transparent substrate, a heat-sensitive layer and an adhesive layer; grooves for receiving Micro-LED chips are provided on the target substrate.
进一步地,所述运动台为xyz三维精密运动台。Further, the motion table is an xyz three-dimensional precision motion table.
进一步地,所述运动台用于调整目标基板与临时转移结构之间的 相对位置关系,使所述目标基板上的待转移Micro-LED芯片凹槽对准待转移Micro-LED芯片。Further, the moving table is used to adjust the relative positional relationship between the target substrate and the temporary transfer structure, so that the micro-LED chip groove to be transferred on the target substrate is aligned with the micro-LED chip to be transferred.
进一步地,所述半反射镜系统包括互相垂直的两个进光口以及两个出光口,两个进光口对准于所述红外激光器和所述超短脉冲激光器,使得其所出射激光可以直接传输至所述半反射镜系统;所述半反射镜系统的两个进光口与所述红外激光器和超短脉冲激光器之间分别设置有光闸;所述半反射镜系统的其中一个出光口对准于激光振镜,使其激光光束应用于Micro-LED芯片的巨量转移中,另一出光口处设置一扩束镜,对所产生的分束激光进行扩束从而使得其能量密度降低,防止产生危险,保证该装置的应用安全;所述临时转移结构装置于所述目标基板上方,且所述目标基板装置于所述运动台上。Further, the half mirror system includes two light inlets and two light outlets perpendicular to each other, and the two light inlets are aligned with the infrared laser and the ultrashort pulse laser, so that the emitted laser light can be directly transmitted to the half-mirror system; optical gates are respectively arranged between the two light inlets of the half-mirror system and the infrared laser and the ultrashort pulse laser; one of the light-out of the half-mirror system The mouth is aligned with the laser galvanometer, so that the laser beam is applied to the mass transfer of Micro-LED chips, and a beam expander is installed at the other light outlet to expand the beam of the generated beam splitting laser so that its energy density reduce, prevent danger, and ensure the application safety of the device; the temporary transfer structure is installed above the target substrate, and the target substrate is installed on the moving platform.
本申请产生的有益效果是:本申请通过同时使用红外激光器和超短脉冲激光器并行加工的加工方式,其中利用长波长的红外激光可以在保证激光能量传输效率的同时扩大激光光斑扫描面积,有效提高Micro-LED芯片的分离效率;利用超短脉冲激光器进行Micro-LED芯片的定位转移,其中,利用超短脉冲激光加工的“冷加工”效应可以有效保护临时转移结构的未加工区域以及极大地避免了对Micro-LED芯片产生污染;利用超短脉冲激光器进行Micro-LED芯片的定位转移,其中,利用超短脉冲激光加工的多脉冲作用时的能量累积效应将Micro-LED芯片选择性地转移至目标基板,由于超短脉冲激光的脉冲宽度仅为皮秒量级甚至飞秒量级,且其多脉冲激光作用能量累计所需激光脉冲数较小,因此利用该方式进行Micro-LED芯 片的巨量转移可以在有效提升加工良率的基础上极大的增加转移效率;利用激光振镜系统来进行激光束的定位与运动可以更好地满足所需加工精度及所需激光束移动速度,更好地实现高效率的Micro-LED芯片巨量转移;对于双激光同轴加工系统采用半反射镜系统进行两种激光束的转换,可以满足利用同一激光加工光路进行双光束的使用的基础上,避免因光路的改变而造成的光路调解困难;对于双激光同轴加工系统中所产生的额外激光分量加持了激光扩束系统,以此来使其能量密度保持在较低水准,保证加工过程中的安全。The beneficial effects of this application are: this application uses parallel processing of infrared lasers and ultrashort pulse lasers at the same time, wherein the use of long-wavelength infrared lasers can expand the laser spot scanning area while ensuring the efficiency of laser energy transmission, effectively improving Separation efficiency of Micro-LED chips; positioning transfer of Micro-LED chips by using ultra-short pulse laser, in which, the "cold processing" effect of ultra-short pulse laser processing can effectively protect the unprocessed area of the temporary transfer structure and greatly avoid Contamination of Micro-LED chips; positioning transfer of Micro-LED chips using ultra-short pulse lasers, in which the Micro-LED chips are selectively transferred to the target by using the energy accumulation effect of multi-pulse processing of ultra-short pulse laser processing Since the pulse width of the ultrashort pulse laser is only on the order of picoseconds or even femtoseconds, and the number of laser pulses required for the accumulation of multi-pulse laser action energy is small, this method is used to process the huge amount of Micro-LED chips. The transfer can greatly increase the transfer efficiency on the basis of effectively improving the processing yield; using the laser galvanometer system to position and move the laser beam can better meet the required processing accuracy and the required laser beam moving speed, and better Realize high-efficiency mass transfer of Micro-LED chips; For the dual-laser coaxial processing system, the half-mirror system is used to convert the two laser beams, which can satisfy the use of the same laser processing optical path for the use of dual beams, and avoid The optical path adjustment is difficult due to the change of the optical path; for the extra laser component generated in the dual-laser coaxial processing system, the laser beam expansion system is added to keep its energy density at a low level and ensure the processing process. Safety.
附图说明Description of drawings
下面将结合附图及实施例对本申请作进一步说明,附图中:The application will be further described below in conjunction with the accompanying drawings and embodiments, in the accompanying drawings:
图1为本申请一种激光辅助原位巨量转移系统实施例的结构示意图;FIG. 1 is a schematic structural diagram of an embodiment of a laser-assisted in-situ mass transfer system of the present application;
图2至图3为利用红外激光将衬底上的Micro-LED芯片转移到临时转移结构上的过程示意图;Figures 2 to 3 are schematic diagrams of the process of transferring the Micro-LED chip on the substrate to the temporary transfer structure by using infrared laser;
图4至图6为利用超短脉冲激光将Micro-LED芯片转移到目标基板的过程示意图。4 to 6 are schematic diagrams of the process of transferring a Micro-LED chip to a target substrate by using an ultrashort pulse laser.
图中:1-红外激光器;2-超短脉冲激光器;3、4-光闸;5-半反射镜系统;6-激光扩束镜;7-激光振镜系统;8-临时转移结构;9-目标基板;10-微调整运动台;11-原位生长有Micro-LED芯片的衬底;801-粘结层;802-热敏层;803-透明基板;1101-蓝宝石基底;1102-GaN层;1103-Micro-LED芯片。In the figure: 1-infrared laser; 2-ultrashort pulse laser; 3, 4-optical gate; 5-half mirror system; 6-laser beam expander; 7-laser galvanometer system; 8-temporary transfer structure; 9 -target substrate; 10-micro-adjustment motion table; 11-substrate with in-situ growth of Micro-LED chip; 801-adhesive layer; 802-thermal layer; 803-transparent substrate; 1101-sapphire substrate; 1102-GaN layer; 1103 - Micro-LED chips.
具体实施方式detailed description
为使本申请实施例的目的、技术方案和优点更加清楚,下面将结 合本申请实施例中的附图,对本申请实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例是本申请的一部分实施例,而不是全部的实施例。应当理解,此处所描述的具体实施例仅用以解释本申请,并不用于限定本申请。基于本申请中的实施例,本领域普通技术人员在没有做出创造性劳动的前提下所获得的所有其他实施例,都属于本申请保护的范围。In order to make the purposes, technical solutions and advantages of the embodiments of the present application clearer, the technical solutions in the embodiments of the present application will be clearly and completely described below in conjunction with the drawings in the embodiments of the present application. Obviously, the described embodiments It is a part of the embodiments of this application, but not all of them. It should be understood that the specific embodiments described here are only used to explain the present application, not to limit the present application. Based on the embodiments in the present application, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present application.
如图1-图6所示,一种激光辅助原位巨量转移方法,包括以下步骤:As shown in Figures 1-6, a laser-assisted in-situ mass transfer method includes the following steps:
S1、准备原位生长有Micro-LED芯片1103的衬底11、临时转移结构8、目标基板9、激光振镜系统7、激光器1、2及运动台10,所述临时转移结构8包括透明基板801、热敏层802及粘结层803;S1. Prepare the substrate 11 on which the Micro-LED chip 1103 is grown in situ, the temporary transfer structure 8, the target substrate 9, the laser galvanometer system 7, the lasers 1, 2 and the moving table 10, the temporary transfer structure 8 includes a transparent substrate 801, heat sensitive layer 802 and adhesive layer 803;
S2、将原位生长在所述衬底11上的Micro-LED芯片1103粘接在所述临时转移结构8的所述粘接层803上,通过使用所述激光振镜系统7采用连续扫描的方式将红外激光作用于所述衬底的GaN/蓝宝石界面上,使得靠近界面处的GaN吸收激光能量被分解,从而使得Micro-LED芯片1103从所述衬底11上剥离;S2. Bond the Micro-LED chip 1103 grown in-situ on the substrate 11 on the adhesive layer 803 of the temporary transfer structure 8, by using the laser vibrating mirror system 7 to adopt continuous scanning In this way, the infrared laser is applied to the GaN/sapphire interface of the substrate, so that the GaN near the interface absorbs the laser energy and is decomposed, so that the Micro-LED chip 1103 is peeled off from the substrate 11;
S3、将粘接有Micro-LED芯片1103的所述临时转移结构8放置于所述目标基板9正上方,利用所述运动台10保证所述目标基板9上所需放置Micro-LED芯片1103的位置与所述临时转移结构8上的待转移Micro-LED芯片1103位置对准;S3. Place the temporary transfer structure 8 bonded with the Micro-LED chip 1103 directly above the target substrate 9, and use the moving table 10 to ensure that the Micro-LED chip 1103 needs to be placed on the target substrate 9. The position is aligned with the Micro-LED chip 1103 to be transferred on the temporary transfer structure 8;
S4、将脉冲激光束通过所述激光振镜系统7后直接作用于所述临时转移结构8上的待转移Micro-LED芯片1103位置处,采用逐点扫 描的激光扫描方式,即在所述临时转移结构上每个待转移Micro-LED芯片位置使用脉冲激光连续作用多个脉冲,利用激光能量累计原理使得激光作用于所述透明基板801与所述热敏层802的界面处,使得Micro-LED芯片1103选择性的落入所述目标基板9上。S4. After the pulsed laser beam passes through the laser galvanometer system 7, it directly acts on the position of the Micro-LED chip 1103 to be transferred on the temporary transfer structure 8, and adopts a point-by-point scanning laser scanning method, that is, in the temporary Each position of the Micro-LED chip to be transferred on the transfer structure uses a pulsed laser to continuously act on multiple pulses, and uses the principle of laser energy accumulation to make the laser act on the interface between the transparent substrate 801 and the heat-sensitive layer 802, so that the Micro-LED Chips 1103 are selectively dropped onto the target substrate 9 .
在本申请的优选实施例中,如图2和图3所示,步骤S1中,所述临时转移结构8中的所述热敏层802材料为聚酰亚胺。In a preferred embodiment of the present application, as shown in FIG. 2 and FIG. 3 , in step S1 , the material of the heat-sensitive layer 802 in the temporary transfer structure 8 is polyimide.
在本申请的优选实施例中,如图2和图3所示,步骤S2中,将粘接有所述临时转移结构8的衬底11放置于所述激光振镜系统7正下方,所述临时转移结构8中Micro-LED芯片1103面位于所述激光振镜系统7中激光扫描面的背面,使得所述激光振镜系统的扫描范围可以最大限度的作用于所述衬底的GaN/蓝宝石界面。In a preferred embodiment of the present application, as shown in FIG. 2 and FIG. 3, in step S2, the substrate 11 bonded with the temporary transfer structure 8 is placed directly under the laser galvanometer system 7, and the The surface of the Micro-LED chip 1103 in the temporary transfer structure 8 is located on the back of the laser scanning surface in the laser galvanometer system 7, so that the scanning range of the laser galvanometer system can maximize the GaN/sapphire on the substrate interface.
具体的,如图2和图3所示,红外激光束通过所述激光振镜系统7快速作用于原位生长Micro-LED芯片的衬底11上,使得GaN层1102中靠近界面处的GaN吸收激光光能产生热能受热分解,从而使Micro-LED芯片1103快速从蓝宝石衬底11上分离,并使Micro-LED芯片1103通过粘接层801粘附在临时转移结构8上。Specifically, as shown in FIG. 2 and FIG. 3, the infrared laser beam rapidly acts on the substrate 11 of the in-situ grown Micro-LED chip through the laser galvanometer system 7, so that the GaN near the interface in the GaN layer 1102 absorbs The thermal energy generated by the laser light is decomposed by heat, so that the Micro-LED chip 1103 is quickly separated from the sapphire substrate 11 , and the Micro-LED chip 1103 is adhered to the temporary transfer structure 8 through the adhesive layer 801 .
在本申请的优选实施例中,如图4所示,步骤S3中,粘接有Micro-LED芯片1103的所述临时转移结构8与所述目标基板9之间的距离d≈1.2h,其中h为所放置Micro-LED芯片1103的最大厚度。In a preferred embodiment of the present application, as shown in FIG. 4, in step S3, the distance d≈1.2h between the temporary transfer structure 8 with the Micro-LED chips 1103 bonded thereto and the target substrate 9, wherein h is the maximum thickness of the placed Micro-LED chip 1103 .
在本申请的优选实施例中,如图4至图6所示,步骤S4中,需根据Micro-LED芯片1103的尺寸,利用
Figure PCTCN2022072563-appb-000002
来确定所应用所述激光振镜系统7所需要的焦距;其中,r为所述Micro-LED芯片1103 中心位置至边缘的最大距离,λ为所述激光波长,f为激光振镜系统7的焦距。
In the preferred embodiment of the present application, as shown in Figure 4 to Figure 6, in step S4, according to the size of the Micro-LED chip 1103, use
Figure PCTCN2022072563-appb-000002
To determine the focal length required by the laser galvanometer system 7 applied; where, r is the maximum distance from the center position of the Micro-LED chip 1103 to the edge, λ is the laser wavelength, and f is the laser galvanometer system 7 focal length.
在本申请的优选实施例中,如图4至图6所示,步骤S4中,所述激光振镜系统7在一个Micro-LED芯片转移位置停留多个脉冲过后直接转移到下一个Micro-LED芯片转移位置,期间不需要改变激光的通断。In a preferred embodiment of the present application, as shown in Fig. 4 to Fig. 6, in step S4, the laser galvanometer system 7 stays in a Micro-LED chip transfer position for multiple pulses and then directly transfers to the next Micro-LED The position of the chip is transferred without changing the on-off of the laser.
具体的,如图4至图6所示,超短脉冲激光器2所出射的超短脉冲激光经过激光振镜系统7后聚焦于临时转移结构8透明基板801与热敏层802的界面中待转移Micro-LED芯片1103位置处,通过激光振镜系统7的控制保持超短脉冲激光在该位置处连续作用多个脉冲,由于所采用的激光脉冲能量较低,因此只有当多个激光脉冲共同作用于该位置时所产生的能量累计效应从而产生的热效应使得临时转移结构8中热敏层802与透明基板803之间生产气泡,将Micro-LED芯片1103转移至目标基板9中目标位置处;当多个激光脉冲连续作用使得Micro-LED芯片1103完成从临时转移结构8至目标基板9之间的转移时,通过控制激光振镜系统使超短脉冲激光束的作用位置开始运动向下一个Micro-LED芯片待转移位置点,在激光束运动过程中,由于为单个激光束与热敏层802相互作用,且由于所设置超快激光束能量较低,不足以使其发生反应在热敏层802与透明基板803之间生产气泡,因此保证了Micro-LED芯片转移过程中的良率;待转移到下一个Micro-LED芯片待转移位置点时,再次通过激光振镜系统7使得超短脉冲激光在此连续作用多个脉冲,利用前述能量累计原 理完成该位置处的Micro-LED芯片转移。Specifically, as shown in FIGS. 4 to 6, the ultrashort pulse laser emitted by the ultrashort pulse laser 2 passes through the laser galvanometer system 7 and then focuses on the interface between the transparent substrate 801 and the heat-sensitive layer 802 of the temporary transfer structure 8 to be transferred. At the position of Micro-LED chip 1103, through the control of the laser galvanometer system 7, the ultrashort pulse laser is continuously applied to multiple pulses at this position. Since the energy of the laser pulses used is low, only when multiple laser pulses act together The thermal effect generated by the energy accumulation effect generated at this position causes air bubbles to be generated between the heat-sensitive layer 802 and the transparent substrate 803 in the temporary transfer structure 8, and the Micro-LED chip 1103 is transferred to the target position in the target substrate 9; When multiple laser pulses act continuously so that the Micro-LED chip 1103 completes the transfer from the temporary transfer structure 8 to the target substrate 9, the action position of the ultrashort pulse laser beam starts to move to the next Micro-LED chip by controlling the laser galvanometer system. At the point where the LED chip is to be transferred, during the movement of the laser beam, due to the interaction between a single laser beam and the thermal layer 802, and the low energy of the set ultrafast laser beam, it is not enough to make it react on the thermal layer 802 Bubbles are produced between the transparent substrate 803, thus ensuring the yield rate during the Micro-LED chip transfer process; when transferring to the next Micro-LED chip to be transferred, the laser vibrating mirror system 7 is used to make the ultrashort pulse laser Multiple pulses are applied continuously here, and the micro-LED chip transfer at this position is completed by using the aforementioned energy accumulation principle.
相应的,本申请还提供一种激光辅助原位巨量转移系统,如图1所示,包括红外激光器1;超短脉冲激光器2;光闸3、4;半反射镜系统5;激光扩束镜6;激光振镜系统7;临时转移结构8;目标基板9;微运动台10;其中,红外激光器1发射红外激光通过光闸3传输至半反射镜系统5;超短脉冲激光器2发射超短脉冲激光通过光闸4传输至半反射镜系统5。Correspondingly, the present application also provides a laser-assisted in-situ mass transfer system, as shown in Figure 1, including an infrared laser 1; an ultrashort pulse laser 2; optical gates 3 and 4; a half-mirror system 5; mirror 6; laser galvanometer system 7; temporary transfer structure 8; target substrate 9; The short-pulse laser light is transmitted through the shutter 4 to the half-mirror system 5 .
在本申请的优选实施例中,所述超短脉冲激光器出射激光脉宽小于等于10ps。In a preferred embodiment of the present application, the ultrashort pulse laser emits laser with a pulse width less than or equal to 10 ps.
在本申请的优选实施例中,如图1所示,所述临时转移结构8包括透明基板801、热敏层802及粘结层803;所述目标基板9上设有用于接收Micro-LED芯片的凹槽。In a preferred embodiment of the present application, as shown in FIG. 1 , the temporary transfer structure 8 includes a transparent substrate 801, a heat-sensitive layer 802 and an adhesive layer 803; groove.
在本申请的优选实施例中,如图1所示,所述运动台10为xyz三维精密运动台。In a preferred embodiment of the present application, as shown in FIG. 1 , the motion table 10 is an xyz three-dimensional precision motion table.
在本申请的优选实施例中,如图1所示,所述运动台10用于调整所述目标基板9与所述临时转移结构8之间的相对位置关系,使所述目标基板9上的待转移Micro-LED芯片凹槽对准待转移Micro-LED芯片1103。In a preferred embodiment of the present application, as shown in FIG. 1, the moving table 10 is used to adjust the relative positional relationship between the target substrate 9 and the temporary transfer structure 8, so that the The groove of the micro-LED chip to be transferred is aligned with the micro-LED chip 1103 to be transferred.
在本申请的优选实施例中,如图1所示,所述半反射镜系统5包括互相垂直的两个进光口以及两个出光口,两个进光口对准于所述红外激光器1和超短脉冲激光器2,使得其所出射激光经过各自的光闸3、4后可以直接传输至所述半反射镜系统5;其中一个出光口对准于 激光振镜系统7,使其激光光束应用于Micro-LED芯片1103的巨量转移中,另一出光口处设置一激光扩束镜6,利用扩大激光束直径降低其激光能量密度的原理对所产生的分束激光进行扩束从而使得其能量密度降低,防止产生危险,保证该装置的应用安全。In a preferred embodiment of the present application, as shown in FIG. 1 , the half mirror system 5 includes two light inlets and two light outlets perpendicular to each other, and the two light inlets are aligned with the infrared laser 1 and the ultrashort pulse laser 2, so that the emitted laser light can be directly transmitted to the half mirror system 5 after passing through the respective optical gates 3 and 4; one of the light outlets is aligned with the laser galvanometer system 7, so that the laser beam Applied to the mass transfer of Micro-LED chips 1103, a laser beam expander 6 is installed at the other light outlet, and the beam splitting laser generated is expanded by using the principle of expanding the laser beam diameter and reducing its laser energy density, so that Its energy density is reduced, which prevents danger and ensures the application safety of the device.
本申请具有以下优点:This application has the following advantages:
1、本申请通过同时使用红外激光器和超短脉冲激光器并行加工的加工方式,其中利用长波长的红外激光可以在保证激光能量传输效率的同时扩大激光光斑扫描面积,有效提高Micro-LED芯片的分离效率;1. This application adopts the parallel processing method of using infrared laser and ultrashort pulse laser at the same time, in which the use of long-wavelength infrared laser can expand the scanning area of laser spot while ensuring the efficiency of laser energy transmission, and effectively improve the separation of Micro-LED chips efficiency;
2、利用超短脉冲激光器进行Micro-LED芯片的定位转移,其中,利用超短脉冲激光加工的“冷加工”效应可以有效保护临时转移结构的未加工区域以及极大地避免了对Micro-LED芯片产生污染;2. Utilize ultrashort pulse laser for positioning transfer of Micro-LED chips. Among them, the "cold processing" effect of ultrashort pulse laser processing can effectively protect the unprocessed area of the temporary transfer structure and greatly avoid damage to the Micro-LED chip. pollute;
3、利用超短脉冲激光器进行Micro-LED芯片的定位转移,其中,利用超短脉冲激光加工的多脉冲作用时的能量累积效应将Micro-LED芯片选择性地转移至目标基板,由于超短脉冲激光的脉冲宽度仅为皮秒量级甚至飞秒量级,且其多脉冲激光作用能量累计所需激光脉冲数较少,因此利用该方式进行Micro-LED芯片的巨量转移可以在有效提升加工良率的基础上极大的增加转移效率;3. Utilize ultrashort pulse laser for positioning transfer of Micro-LED chips, in which, the energy accumulation effect of multi-pulse processing of ultrashort pulse laser is used to selectively transfer Micro-LED chips to the target substrate, due to the ultrashort pulse The pulse width of the laser is only on the order of picoseconds or even femtoseconds, and the number of laser pulses required for the accumulation of multi-pulse laser energy is small. Therefore, using this method to transfer a large amount of Micro-LED chips can effectively improve the processing On the basis of yield rate, the transfer efficiency is greatly increased;
4、利用激光振镜系统来进行激光束的定位与运动可以更好地满足所需加工精度及所需激光束移动速度,更好地实现高效率的Micro-LED芯片巨量转移;4. Using the laser galvanometer system to position and move the laser beam can better meet the required processing accuracy and the required moving speed of the laser beam, and better realize the high-efficiency mass transfer of Micro-LED chips;
5、对于双激光同轴加工系统采用半反射镜系统进行两种激光束 的转换,可以满足利用同一激光加工光路进行双光束的使用的基础上,避免因光路的改变而造成的光路调解困难;5. For the dual-laser coaxial processing system, the half-mirror system is used to convert the two laser beams, which can satisfy the use of the same laser processing optical path for the use of dual beams, and avoid the difficulty of optical path adjustment caused by the change of the optical path;
6、对于双激光同轴加工系统中所产生的额外激光分量加持了激光扩束系统,以此来使其能量密度保持在较低水准,保证加工过程中的安全。6. For the extra laser component generated in the dual laser coaxial processing system, the laser beam expansion system is added to keep its energy density at a low level and ensure the safety during processing.
在本申请的描述中,需要说明的是,术语“中心”、“纵向”、“横向”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本申请和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本申请的限制。此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性。In the description of this application, it should be noted that the terms "center", "longitudinal", "transverse", "upper", "lower", "front", "rear", "left", "right", " The orientation or positional relationship indicated by "vertical", "horizontal", "top", "bottom", "inner", "outer", etc. is based on the orientation or positional relationship shown in the drawings, and is only for the convenience of describing the present application and The description is simplified, rather than indicating or implying that the device or element referred to must have a specific orientation, be constructed in a specific orientation, and operate, and thus should not be construed as limiting the application. In addition, the terms "first" and "second" are used for descriptive purposes only, and should not be understood as indicating or implying relative importance.
在本申请的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以具体情况理解上述术语在本申请中的具体含义。此外,在本申请的描述中,除非另有说明,“多个”的含义是两个或两个以上。In the description of this application, it should be noted that unless otherwise specified and limited, the terms "installation", "connection", and "connection" should be understood in a broad sense, for example, it can be a fixed connection or a detachable connection. Connected, or integrally connected; it can be mechanically connected or electrically connected; it can be directly connected or indirectly connected through an intermediary, and it can be the internal communication of two components. Those of ordinary skill in the art can understand the specific meanings of the above terms in this application in specific situations. In addition, in the description of the present application, unless otherwise specified, "plurality" means two or more.
应当理解的是,对本领域普通技术人员来说,可以根据上述说明加以改进或变换,而所有这些改进和变换都应属于本申请所附权利要求的保护范围。It should be understood that those skilled in the art may make improvements or transformations based on the above description, and all such improvements and transformations shall fall within the protection scope of the appended claims of the present application.

Claims (13)

  1. 一种激光辅助原位巨量转移方法,其特征在于,包括以下步骤:A laser-assisted in-situ mass transfer method, characterized in that it comprises the following steps:
    S1、准备原位生长有Micro-LED芯片的衬底、临时转移结构、目标基板、激光振镜系统、激光器及运动台,所述临时转移结构包括透明基板、热敏层及粘结层;S1. Prepare a substrate with Micro-LED chips grown in situ, a temporary transfer structure, a target substrate, a laser galvanometer system, a laser, and a motion table. The temporary transfer structure includes a transparent substrate, a heat-sensitive layer, and an adhesive layer;
    S2、将原位生长在所述衬底上的Micro-LED芯片粘接在所述临时转移结构的粘接层上,通过使用所述激光振镜系统采用连续扫描的方式将红外激光作用于所述衬底的GaN/蓝宝石界面上,使得靠近界面处的GaN吸收激光能量被分解,从而使得Micro-LED芯片从所述衬底上剥离;S2. Bond the Micro-LED chip grown on the substrate in situ on the adhesive layer of the temporary transfer structure, and use the laser galvanometer system to act on the infrared laser in a continuous scanning manner. on the GaN/sapphire interface of the substrate, so that the GaN near the interface absorbs laser energy and is decomposed, so that the Micro-LED chip is peeled off from the substrate;
    S3、将粘接有Micro-LED芯片的所述临时转移结构放置于所述目标基板正上方,利用所述运动台保证所述目标基板上所需放置Micro-LED芯片的位置与所述临时转移结构上的待转移Micro-LED芯片位置对准;S3. Place the temporary transfer structure with the Micro-LED chip bonded directly above the target substrate, and use the motion table to ensure that the position where the Micro-LED chip needs to be placed on the target substrate is consistent with the temporary transfer Structural alignment of Micro-LED chips to be transferred;
    S4、将脉冲激光束通过所述激光振镜系统后直接作用于所述临时转移结构上的待转移Micro-LED芯片位置处,采用逐点扫描的激光扫描方式,即在所述临时转移结构上每个待转移Micro-LED芯片位置使用脉冲激光连续作用多个脉冲,利用激光能量累计原理使得激光作用于所述透明基板与所述热敏层的界面处,使得Micro-LED芯片选择性的落入所述目标基板上。S4. After the pulsed laser beam passes through the laser galvanometer system, it directly acts on the position of the Micro-LED chip to be transferred on the temporary transfer structure, and adopts a point-by-point laser scanning method, that is, on the temporary transfer structure Each position of the Micro-LED chip to be transferred uses a pulsed laser to continuously act on multiple pulses, and uses the principle of laser energy accumulation to make the laser act on the interface between the transparent substrate and the heat-sensitive layer, so that the Micro-LED chip can be selectively placed. into the target substrate.
  2. 根据权利要求1所述的一种激光辅助原位巨量转移方法,其特征在于,步骤S1中,所述临时转移结构中的所述热敏层材料为聚酰亚 胺。A laser-assisted in-situ mass transfer method according to claim 1, characterized in that, in step S1, the heat-sensitive layer material in the temporary transfer structure is polyimide.
  3. 根据权利要求1所述的一种激光辅助原位巨量转移方法,其特征在于,步骤S2中,将粘接有所述临时转移结构的衬底放置于所述激光振镜系统正下方,所述临时转移结构中Micro-LED芯片面位于所述激光振镜系统中激光扫描面的背面,使得激光振镜的扫描范围可以最大限度的作用于所述衬底的GaN/蓝宝石界面。A laser-assisted in-situ mass transfer method according to claim 1, wherein in step S2, the substrate bonded with the temporary transfer structure is placed directly under the laser galvanometer system, so that The surface of the Micro-LED chip in the temporary transfer structure is located on the back of the laser scanning surface in the laser vibrating mirror system, so that the scanning range of the laser vibrating mirror can act on the GaN/sapphire interface of the substrate to the greatest extent.
  4. 根据权利要求1所述的一种激光辅助原位巨量转移方法,其特征在于,步骤S3中,粘接有Micro-LED芯片的所述临时转移结构与所述目标基板之间的距离d≈1.2h,其中h为所放置Micro-LED芯片的最大厚度。The laser-assisted in-situ mass transfer method according to claim 1, wherein in step S3, the distance d≈ 1.2h, where h is the maximum thickness of the placed Micro-LED chip.
  5. 根据权利要求1所述的一种激光辅助原位巨量转移方法,其特征在于,步骤S4中,需根据Micro-LED的尺寸,利用
    Figure PCTCN2022072563-appb-100001
    来确定所应用所述激光振镜系统所需要的焦距;其中,r为所述Micro-LED芯片中心位置至边缘的最大距离,λ为所述激光波长,f为激光振镜的焦距。
    A laser-assisted in-situ mass transfer method according to claim 1, characterized in that in step S4, according to the size of the Micro-LED, use
    Figure PCTCN2022072563-appb-100001
    To determine the focal length required by the applied laser galvanometer system; where r is the maximum distance from the center of the Micro-LED chip to the edge, λ is the laser wavelength, and f is the focal length of the laser galvanometer.
  6. 根据权利要求1所述的一种激光辅助原位巨量转移方法,其特征在于,步骤S4中,所述激光振镜系统在一个Micro-LED芯片转移位置停留多个脉冲过后直接转移到下一个Micro-LED芯片转移位置,期间不需要改变激光的通断。A laser-assisted in-situ mass transfer method according to claim 1, characterized in that in step S4, the laser vibrating mirror system stays in a Micro-LED chip transfer position for multiple pulses and then directly transfers to the next The position of the Micro-LED chip is transferred, and there is no need to change the laser on and off during the process.
  7. 一种激光辅助原位巨量转移方法,其特征在于,包括以下步骤:A laser-assisted in-situ mass transfer method, characterized in that it comprises the following steps:
    S1、准备原位生长有Micro-LED芯片的衬底、临时转移结构、目标基板,所述临时转移结构包括基板、热敏层及粘结层;S1. Prepare a substrate with Micro-LED chips grown in situ, a temporary transfer structure, and a target substrate, where the temporary transfer structure includes a substrate, a heat-sensitive layer, and an adhesive layer;
    S2、将原位生长在所述衬底上的Micro-LED芯片粘接在所述临时转移结构的粘接层上,采用连续扫描的方式将激光作用于所述衬底的界面上,从而使得Micro-LED芯片从所述衬底上剥离;S2. Bond the Micro-LED chip grown on the substrate in situ to the adhesive layer of the temporary transfer structure, and apply laser light to the interface of the substrate in a continuous scanning manner, so that The Micro-LED chip is peeled off from the substrate;
    S3、将粘接有Micro-LED芯片的所述临时转移结构放置于所述目标基板正上方,保证所述目标基板上所需放置Micro-LED芯片的位置与所述临时转移结构上的待转移Micro-LED芯片位置对准;S3. Place the temporary transfer structure with the Micro-LED chip bonded directly above the target substrate, ensuring that the position where the Micro-LED chip needs to be placed on the target substrate is consistent with the position to be transferred on the temporary transfer structure Micro-LED chip position alignment;
    S4、采用逐点扫描的激光扫描方式,即在所述临时转移结构上每个待转移Micro-LED芯片位置使用脉冲激光连续作用多个脉冲,利用激光能量累计原理使得激光作用于所述透明基板与所述热敏层的界面处,使得Micro-LED芯片选择性的落入所述目标基板上。S4. Adopt a point-by-point scanning laser scanning method, that is, use a pulsed laser to continuously act on multiple pulses at each position of the Micro-LED chip to be transferred on the temporary transfer structure, and use the principle of laser energy accumulation to make the laser act on the transparent substrate At the interface with the heat-sensitive layer, the Micro-LED chips are selectively dropped onto the target substrate.
  8. 一种激光辅助原位巨量转移系统,其特征在于,包括红外激光器、超短脉冲激光器、光闸、半反射镜系统、激光扩束镜、激光振镜系统、临时转移结构、目标基板、运动台。A laser-assisted in-situ mass transfer system, characterized in that it includes an infrared laser, an ultrashort pulse laser, an optical gate, a half-reflecting mirror system, a laser beam expander, a laser galvanometer system, a temporary transfer structure, a target substrate, and a moving tower.
  9. 根据权利要求8所述的一种激光辅助原位巨量转移系统,其特征在于,所述超短脉冲激光器出射激光脉宽小于等于10皮秒。The laser-assisted in-situ mass transfer system according to claim 8, characterized in that the ultrashort pulse laser emits laser with a pulse width less than or equal to 10 picoseconds.
  10. 根据权利要求8所述的一种激光辅助原位巨量转移系统,其特征在于,所述临时转移结构包括透明基板、热敏层及粘结层;所述目标基板上设有用于接收Micro-LED芯片的凹槽。A laser-assisted in-situ mass transfer system according to claim 8, wherein the temporary transfer structure includes a transparent substrate, a heat-sensitive layer and an adhesive layer; Grooves for LED chips.
  11. 根据权利要求8所述的一种激光辅助原位巨量转移系统,其特征在于,所述运动台用于调整所述目标基板与所述临时转移结构之间的相对位置关系,使所述目标基板上的待转移Micro-LED芯片凹槽对准待转移Micro-LED芯片。The laser-assisted in-situ mass transfer system according to claim 8, wherein the moving stage is used to adjust the relative positional relationship between the target substrate and the temporary transfer structure, so that the target The micro-LED chip groove to be transferred on the substrate is aligned with the micro-LED chip to be transferred.
  12. 根据权利要求8所述的一种激光辅助原位巨量转移系统,其特征在于,所述运动台为xyz三维精密运动台。The laser-assisted in-situ mass transfer system according to claim 8, characterized in that the motion table is an xyz three-dimensional precision motion table.
  13. 根据权利要求8所述的一种激光辅助原位巨量转移系统,其特征在于,所述半反射镜系统包括互相垂直的两个进光口以及两个出光口,两个进光口对准于所述红外激光器和超短脉冲激光器,使得其所出射激光可以直接传输至所述半反射镜系统;所述半反射镜系统的两个进光口与所述红外激光器和超短脉冲激光器之间分别设置有光闸;所述半反射镜系统的其中一个出光口对准于激光扫描振镜,使其激光光束应用于Micro-LED芯片的巨量转移中,另一出光口处设置一扩束镜,对所产生的分束激光进行扩束从而使得其能量密度降低,防止产生危险,保证该装置的应用安全;所述临时转移结构装置于所述目标基板上方,且所述目标基板装置于所述运动台上。A laser-assisted in-situ mass transfer system according to claim 8, wherein the half-mirror system includes two light inlets and two light outlets perpendicular to each other, and the two light inlets are aligned between the infrared laser and the ultrashort pulse laser, so that the emitted laser light can be directly transmitted to the half mirror system; the two light inlets of the half mirror system are connected to the infrared laser and the ultrashort pulse laser Optical shutters are respectively arranged between them; one of the light outlets of the half-mirror system is aligned with the laser scanning galvanometer, so that the laser beam is applied to the mass transfer of Micro-LED chips, and an expander is set at the other light outlet. The beam mirror expands the beam of the generated beam splitting laser so as to reduce its energy density, prevent danger, and ensure the application safety of the device; the temporary transfer structure is installed above the target substrate, and the target substrate is installed on the exercise platform.
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