WO2022250464A3 - 기계적인 힘에 선택적으로 감응하는 아지리딘 고분자 - Google Patents

기계적인 힘에 선택적으로 감응하는 아지리딘 고분자 Download PDF

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Publication number
WO2022250464A3
WO2022250464A3 PCT/KR2022/007464 KR2022007464W WO2022250464A3 WO 2022250464 A3 WO2022250464 A3 WO 2022250464A3 KR 2022007464 W KR2022007464 W KR 2022007464W WO 2022250464 A3 WO2022250464 A3 WO 2022250464A3
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WIPO (PCT)
Prior art keywords
mechanical force
aziridine
selectively responsive
mechanophore
polymer
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PCT/KR2022/007464
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English (en)
French (fr)
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WO2022250464A2 (ko
Inventor
윤효재
정상민
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고려대학교 산학협력단
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Priority claimed from KR1020220063950A external-priority patent/KR102695640B1/ko
Application filed by 고려대학교 산학협력단 filed Critical 고려대학교 산학협력단
Priority to US18/564,467 priority Critical patent/US20240317932A1/en
Publication of WO2022250464A2 publication Critical patent/WO2022250464A2/ko
Publication of WO2022250464A3 publication Critical patent/WO2022250464A3/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/14—Side-groups
    • C08G2261/143—Side-chains containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/14—Side-groups
    • C08G2261/148—Side-chains having aromatic units
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
    • C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3322—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from cyclooctene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40—Polymerisation processes
    • C08G2261/41—Organometallic coupling reactions
    • C08G2261/418—Ring opening metathesis polymerisation [ROMP]

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

본 발명은 기계적 힘에 선택적으로 감응하는 아지리딘 유도체의 메카노포어 구조체 및 이를 포함하는 고분자에 관한 것으로서, 아지리딘 유도체 화합물을 메카노포어로 사용하여 기계적인 힘과 열 자극에 각각 반응을 진행할 경우, 기계적인 힘에 선택적으로 아지리딘의 공유 결합이 끊어짐으로써, 기계적인 힘에만 선택적으로 감응할 수 있는 아지리딘이 존재하는 것을 밝힌 바, 본 발명에 따르면, 기계적인 힘에만 선택적으로 감응하는 메카노포어를 내포한 고분자를 제조할 수 있는바, 신소재 분야 등 다양한 산업 분야에서 널리 활용될 수 있다.
PCT/KR2022/007464 2021-05-27 2022-05-26 기계적인 힘에 선택적으로 감응하는 아지리딘 고분자 WO2022250464A2 (ko)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US18/564,467 US20240317932A1 (en) 2021-05-27 2022-05-26 Mechanical force selectively responsive aziridine polymer

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR20210068357 2021-05-27
KR10-2021-0068357 2021-05-27
KR10-2022-0063950 2022-05-25
KR1020220063950A KR102695640B1 (ko) 2021-05-27 2022-05-25 기계적인 힘에 선택적으로 감응하는 아지리딘 고분자

Publications (2)

Publication Number Publication Date
WO2022250464A2 WO2022250464A2 (ko) 2022-12-01
WO2022250464A3 true WO2022250464A3 (ko) 2023-01-19

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PCT/KR2022/007464 WO2022250464A2 (ko) 2021-05-27 2022-05-26 기계적인 힘에 선택적으로 감응하는 아지리딘 고분자

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US (1) US20240317932A1 (ko)
WO (1) WO2022250464A2 (ko)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160065833A (ko) * 2013-09-30 2016-06-09 다우 글로벌 테크놀로지스 엘엘씨 폴리올레핀 반응성 텔레켈릭 예비중합체를 제조하는 방법, 폴리올레핀 반응성 텔레켈릭 예비중합체 및 가교 엘라스토머 및 고분자량 엘라스토머

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160065833A (ko) * 2013-09-30 2016-06-09 다우 글로벌 테크놀로지스 엘엘씨 폴리올레핀 반응성 텔레켈릭 예비중합체를 제조하는 방법, 폴리올레핀 반응성 텔레켈릭 예비중합체 및 가교 엘라스토머 및 고분자량 엘라스토머

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
JUNG SANGMIN, YOON HYO JAE: "Mechanical Force for the Transformation of Aziridine into Imine", ANGEWANDTE CHEMIE INTERNATIONAL EDITION, VERLAG CHEMIE, vol. 60, no. 44, 25 October 2021 (2021-10-25), pages 23564 - 23568, XP093024568, ISSN: 1433-7851, DOI: 10.1002/anie.202109358 *
JUNG SANGMIN, YOON HYO JAE: "Mechanical Force Induces Ylide‐Free Cycloaddition of Nonscissible Aziridines", ANGEWANDTE CHEMIE INTERNATIONAL EDITION, VERLAG CHEMIE, vol. 59, no. 12, 16 March 2020 (2020-03-16), pages 4883 - 4887, XP093024565, ISSN: 1433-7851, DOI: 10.1002/anie.201915438 *
KLEIN ISABEL M., HUSIC COREY C., KOVÁCS DÁVID P., CHOQUETTE NICOLAS J., ROBB MAXWELL J.: "Validation of the CoGEF Method as a Predictive Tool for Polymer Mechanochemistry", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMERICAN CHEMICAL SOCIETY, vol. 142, no. 38, 23 September 2020 (2020-09-23), pages 16364 - 16381, XP093024566, ISSN: 0002-7863, DOI: 10.1021/jacs.0c06868 *
KUZNETSOV M. A., VORONIN V. V.: "Thermal transformations of alk-1-enyl-N-phthalimidoaziridines", RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, M A I K NAUKA - INTERPERIODICA, RU, vol. 49, no. 1, 1 January 2013 (2013-01-01), RU , pages 83 - 94, XP093024567, ISSN: 1070-4280, DOI: 10.1134/S1070428013010156 *

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US20240317932A1 (en) 2024-09-26
WO2022250464A2 (ko) 2022-12-01

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