WO2022239902A1 - Apparatus for producing oil with waste synthetic resin - Google Patents

Apparatus for producing oil with waste synthetic resin Download PDF

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Publication number
WO2022239902A1
WO2022239902A1 PCT/KR2021/007048 KR2021007048W WO2022239902A1 WO 2022239902 A1 WO2022239902 A1 WO 2022239902A1 KR 2021007048 W KR2021007048 W KR 2021007048W WO 2022239902 A1 WO2022239902 A1 WO 2022239902A1
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Prior art keywords
synthetic resin
waste synthetic
main body
temperature
resin melt
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PCT/KR2021/007048
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French (fr)
Korean (ko)
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이병삼
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이병삼
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Publication of WO2022239902A1 publication Critical patent/WO2022239902A1/en

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00Recovery or working-up of waste materials
    • C08J11/04Recovery or working-up of waste materials of polymers
    • C08J11/10Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/18Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G19/00Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
    • C10G19/02Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment with aqueous alkaline solutions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G31/00Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
    • C10G31/06Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by heating, cooling, or pressure treatment
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G31/00Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
    • C10G31/09Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by filtration
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G5/00Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas
    • C10G5/06Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas by cooling or compressing
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G70/00Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/14Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils in pipes or coils with or without auxiliary means, e.g. digesters, soaking drums, expansion means
    • C10G9/18Apparatus
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/40Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by indirect contact with preheated fluid other than hot combustion gases
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Definitions

  • the present invention relates to an emulsification device that produces renewable energy by thermally decomposing waste synthetic resin and converting it into oil and combustible gas, and more particularly, by impregnating solid waste synthetic resin in high-temperature oil and stirring it to form a melt of waste synthetic resin, The chlorine component and foreign substances contained in it are removed, and the melt is quickly raised in temperature using a water tube heat exchanger, and then put into a thermal decomposition furnace to convert the melt into oil and gas components. It relates to an emulsification device for waste synthetic resin that can minimize the energy required for thermal decomposition by recirculating the furnace.
  • waste synthetic resin which is generated a lot in household waste or industrial waste, is treated by incineration or landfill.
  • high-temperature heat of about 500°C is applied, the high-carbon molecular ring is broken and converted into oil or combustible gas with a low-carbon molecular ring. It is being studied a lot.
  • a fluidized bed of sand is formed at the bottom of the vertical cylinder pyrolysis furnace, and high-temperature inert gas (mainly nitrogen gas is used a lot) of 400 ° C to 500 ° C is blown at high pressure at the bottom of the fluidized bed to raise the temperature and flow the fluidized sand to a high temperature to form a fluidized bed.
  • high-temperature inert gas mainly nitrogen gas is used a lot
  • waste synthetic resin pulverized into a size of 4 cm or less is continuously injected into the formed fluidized bed to quickly pyrolyze and continuously convert it into oil and combustible gas.
  • the cylindrical pyrolysis method is a method in which a cylindrical pyrolysis furnace is filled with waste synthetic resin, sealed, and then heat is applied from the outside or inside to pyrolyze the waste synthetic resin inside the pyrolysis furnace. It takes about 30 to 40 minutes to reach it, especially in the temperature rising section where the temperature rises to 250 ° C to 350 ° C, the high carbon molecular ring of about C 800 to C 2000 in some waste synthetic resins contains C 30 to C 50 molecules of the oil component It is not thermally decomposed into a ring and a combustible gas component, C 3 to C 8 molecular ring, but thermally decomposed into wax or grease, which is a C 200 to C 400 molecular ring.
  • the fluidized bed pyrolysis furnace method has the advantage of continuously inputting waste synthetic resin and continuously pyrolyzing it, but requires a pretreatment facility to grind the waste synthetic resin to 4 cm or less, and when the fluidized sand collides with each other, it is pulverized and atomized. Dust is discharged along with the recovered oil, clogging the piping of the oil recovery cooling condenser, and the recovered oil contains dust, making it difficult to produce good quality oil. It is difficult to process, and the efficiency of reusing fluidized sand is low.
  • the melt pyrolysis method is an excellent pyrolysis method for waste synthetic resin that enables continuous operation, no wax generation, and can recover high-quality oil.
  • a device for removing unmelted foreign substances such as aluminum foil contained in the melted waste synthetic resin, and the melt must be able to reach the pyrolysis temperature in a short time.
  • the present invention is to solve and supplement various problems caused by the prior art as described above, and an object of the present invention is to impregnate and stir the waste synthetic resin in high-temperature oil when melting the solid waste synthetic resin and melt it, An object of the present invention is to provide an apparatus for emulsifying waste synthetic resin capable of reducing energy consumption costs by using a melted waste synthetic resin melt.
  • Another object of the present invention is to provide a foreign matter removal facility equipped with a three-stage gravity settling plate, on the one hand, in order to remove foreign substances contained in the waste synthetic resin melt, and on the other hand, through the foreign matter removal facility, the foreign matter contained in the waste synthetic resin
  • An object of the present invention is to provide an apparatus for emulsifying waste synthetic resin capable of recovering high-quality oil by performing desalination to remove chlorine gas.
  • Another object of the present invention is to raise the temperature of the waste synthetic resin melt in a quick time using a water-tube heat exchange heating method from the outside of the pyrolysis furnace, and then pyrolyze the waste synthetic resin melt in the pyrolysis furnace to suppress the generation of wax generated in the low temperature section. It is to provide an emulsification device for synthetic resin.
  • Another object of the present invention is to neutralize chlorine gas generated during desalination in a foreign matter removal facility with an alkali chemical in a liquid cleaning device, and convert the melted waste synthetic resin into oil vapor and combustible gas in a pyrolysis furnace, and then use an oil recovery cooling condenser to
  • An object of the present invention is to provide an apparatus for emulsifying waste synthetic resin that can reduce the use of thermal energy by recovering oil vapor and using combustible gas as combustion fuel for a hot stove.
  • the waste synthetic resin emulsification apparatus includes a melting furnace for receiving solid waste synthetic resin and high-temperature oil and impregnating the solid waste synthetic resin into the high-temperature oil to melt the solid waste synthetic resin;
  • Heat exchange occurs between a heater including a water-tube heat exchanger in which heat is exchanged while the molten waste synthetic resin supplied from the melting furnace passes, and the molten waste synthetic resin passing through the water-tube heat exchanger by supplying high-temperature hot air to the heater.
  • a heating facility including a hot air stove for raising the temperature of the waste synthetic resin melt to a temperature suitable for thermal decomposition;
  • thermo decomposition furnace for converting the waste synthetic resin melt supplied from the heating facility into oil vapor and combustible gas components by thermally decomposing the waste synthetic resin melt heated to a temperature suitable for thermal decomposition.
  • energy saving can be achieved by transferring a part of the waste synthetic resin melt existing in the pyrolysis furnace as high-temperature oil to the melting furnace for use.
  • the melting furnace further includes an agitator, which promotes melting of the solid waste synthetic resin by stirring the high-temperature oil and the solid waste synthetic resin supplied to the melting furnace.
  • a foreign matter removal facility is further formed, which includes a box-shaped body, a hopper integrally formed in the body, an inlet pipe for introducing the waste synthetic resin melt from the melting furnace, and a waste synthetic resin It includes a foreign matter conveying means for removing foreign matter contained in the melt and deposited on the bottom surface of the hopper.
  • first, second, and third settling plates are disposed in the main body in order in a horizontal direction from left to right, and the settling plates are disposed until the waste synthetic resin melt introduced through the inlet pipe is discharged while flowing inside the main body.
  • the foreign matter removal facility further includes an outer wall for forming a double jacket structure in the main body by entirely surrounding the outside of the main body, and supplying high-temperature exhaust gas discharged from the heating facility to the double jacket.
  • the chlorine gas contained in the waste synthetic resin melt can be desalinated by raising the temperature of the waste synthetic resin melt flowing through the main body.
  • the water tube heat exchanger of the heater includes a pair of headers, and a plurality of pipes disposed spaced apart from each other so that both ends are connected and communicated between the pair of headers. Therefore, the molten waste synthetic resin supplied from the melting furnace undergoes heat exchange between the pair of headers of the water tube heat exchanger and the high-temperature hot air supplied from the hot air furnace while passing through the inside of the pipes. The temperature of the waste synthetic resin melt is rapidly raised to a temperature suitable for extracting the oil component from the synthetic resin melt.
  • the heater including the water-tube heat exchanger is configured separately from the pyrolysis furnace, and the waste synthetic resin melt is rapidly raised to a temperature suitable for pyrolysis through the water-tube heat exchanger and then introduced into the pyrolysis furnace Since thermal decomposition proceeds, it is possible to obtain oil vapor or combustible gas for conversion to oil by stable thermal decomposition.
  • the melt of waste synthetic resin obtained by continuously inputting solid waste synthetic resin into a melting furnace and impregnating it in high-temperature oil can be converted into oil and combustible gas by thermal decomposition, enabling continuous operation.
  • Costs and heat energy required for producing high-temperature oil can be reduced by reusing some of the heated (ie, high-temperature) waste synthetic resin melt instead of high-temperature oil used to quickly and easily melt solid waste synthetic resin in a melting furnace.
  • the waste synthetic resin melt which is primarily melted in the melting furnace, passes through the three-stage sedimentation plate provided in the main body of the foreign matter removal facility, removing foreign substances (heavy or light metallic and fine floating foreign substances).
  • a demineralization process that volatilizes the components can be performed in parallel, so that high-quality oil can be recovered.
  • the waste synthetic resin melt from which foreign substances and chlorine components have been removed is rapidly raised to the pyrolysis temperature through a water-tube heat exchanger installed separately from the pyrolysis furnace and thermally decomposed, thereby minimizing the generation of wax generated during low-temperature pyrolysis.
  • FIG. 1 is an overall configuration diagram schematically illustrating an apparatus for emulsifying waste synthetic resin according to an embodiment of the present invention.
  • Figure 2 is a view showing the structure of the melting facility in the emulsification device of Figure 1 in more detail.
  • FIG. 3 is a partial cross-sectional view intensively showing a foreign matter removal facility in the emulsification device of FIG. 1;
  • FIG. 4 is a view showing a heating facility, a thermal decomposition facility, and a circulation facility, in particular, in the emulsification device of FIG. 1.
  • FIG. 1 is an overall configuration diagram schematically illustrating an apparatus for emulsifying waste synthetic resin according to an embodiment of the present invention.
  • the waste synthetic resin emulsification device includes a melting facility 100, a foreign matter removal facility 200, a heating facility 300, a pyrolysis facility 400, and a circulation facility ( 500) are included.
  • the emulsification device additionally includes a chemical liquid cleaning device 600 for treating exhaust gas as needed, an oil recovery cooling condenser 700 for recovering oil by gas-liquid separation of pyrolyzed oil vapor and combustible gas, and an oil storage tank 701 may further include.
  • FIG. 2 is a view showing the structure of the melting facility in the emulsification device of Figure 1 in more detail.
  • the cylindrical melting furnace 101 constituting the melting facility 100 is formed at an upper point and has an inlet 102 for introducing pulverized solid waste synthetic resin into the melting furnace 101, and formed at another upper point. It includes a transfer pipe 103 for injecting the high-temperature melted waste synthetic resin transferred from the pyrolysis furnace 401 (see FIG. 4). And, a discharge valve 104 capable of discharging the waste synthetic resin melt is attached to the lower part of the melting furnace 101.
  • the melting facility 100 is provided with an agitator 105 extending into the melting furnace 101 through a point at the top of the melting furnace 101 and installed. This is to rapidly obtain a desired melt of waste synthetic resin by accelerating the melting of the solid waste synthetic resin by mixing and stirring the waste synthetic resin and the liquid high-temperature oil or high-temperature waste synthetic resin melt.
  • the melting temperature required to impregnate and melt the waste synthetic resin using high-temperature oil is about 170°C to 200°C.
  • the agitator 105 includes a motor 106 and a reducer 107 installed exposed to the outside of the melting furnace 101, and a shaft disposed inside the melting furnace 101 ( 108) and stirring blades 109.
  • the stirring blades 109 are installed at the end of a shaft 108 extending and disposed inside the melting furnace 101, and a cap 111 with a plurality of holes 110 is wrapped around the stirring blades 109 as a whole. while being fixed to the shaft 108.
  • the rotation of the motor 106 is transmitted to the shaft 108 and the stirring blades 109 to cause rotation, and by this rotation, the waste synthetic resin (solid waste synthetic resin and liquid high-temperature oil or high-temperature waste synthetic resin melt)
  • the waste synthetic resin solid waste synthetic resin and liquid high-temperature oil or high-temperature waste synthetic resin melt
  • the cap 111 surrounds the stirring blades 109, the solid waste synthetic resin that has entered the cap 111 is cut while the stirring blades 109 rotate as if brushing the surface of the cap 111.
  • the cap 111 prevents the solid waste synthetic resin from being wrapped around the stirring blades 109 and forming lumps.
  • the agitator 105 it is preferable to install the agitator 105 at an angle, which means that when the agitator blades 109 are installed horizontally, when the waste synthetic resin is melted, a lump of waste synthetic resin that is in a solid state or has not yet been properly melted is wound around the agitator blades 109 or This is to prevent sticking.
  • FIG. 3 is a partial cross-sectional view intensively showing a foreign matter removal facility in the emulsification device of FIG. 1; It should be understood that foreign matter removal herein includes both physical and chemical matters.
  • the foreign matter removal facility 200 includes a main body 201 including a hopper 203 formed at the bottom of a box-shaped container, and a cover on the upper opening of the main body 201. It includes an upper plate 202 installed in the form, and a foreign matter conveying facility 204 formed across the bottom surface of the hopper 203, and the main body 201 is made of a closed structure to the extent that gas does not leak as a whole.
  • the foreign matter transfer facility 204 is composed of foreign material transfer means including a conveyor, a collection box, and the like.
  • a first settling plate 205 is provided inside the main body 201 at a predetermined distance from the wall of the main body 201 facing the opposite side. wide surface) along the wall surface of the main body 201 facing the body 201 and is disposed to extend horizontally.
  • the extension length may be extended by a certain length so as to contact the other two wall surfaces of the main body 201 or not to touch the other two walls of the main body 201 .
  • the horizontal extension length of the first settling plate 205 is also applied to the horizontal extension length of each of the second and third settling plates 206 and 207 described later.
  • each of the first, second, and third settling plates 205, 206, and 207 may have different horizontal extension lengths.
  • the lower surface (lower part) of the first sedimentation plate 205 is fixed to the bottom surface of the hopper 203, and the free end (upper part or upper surface) of the first sedimentation plate 205, which is not fixed, is an inlet pipe 208 to be described later. And bent at a right angle as a whole toward the wall of the body 201 close to it, so the cross-sectional shape is generally L-shaped. Of course, the free end portion may be bent while maintaining a gentle curved shape. In this way, the upper surface (free end) of the first settling plate 205 is spaced apart from the upper plate 202 of the main body 201.
  • the second settling plate 206 is disposed at a predetermined distance from the first settling plate 205, and the upper surface of the second settling plate 206 is fixed to the upper plate 202 of the main body 201 and is free from being fixed.
  • the end (bottom surface) is spaced apart from the bottom surface of the hopper 203 by a certain distance without a folded (bent) portion. Accordingly, the second settling plate 206 has a flat plate shape as a whole and takes on the shape of the letter “1”.
  • the third settler plate 207 is disposed at a predetermined distance from the second settler plate 206, and its shape and arrangement are generally the same as those of the first settler plate 205. In this way, in one embodiment of the present invention, the foreign matter removal facility 200 is configured with a three-stage sedimentation plate structure.
  • the body 201 of the foreign matter removal facility 200 is provided with an inlet pipe 208 for receiving the melted waste synthetic resin from the melting furnace 101, and the inlet pipe 208 is the horizontal surface of the first settling plate 205. It is disposed between the wall surface of the main body 201 and the first settling plate 205 facing each other.
  • the inlet pipe 208 penetrates the upper plate 202 of the main body 201 and is disposed to extend a certain length downward along the wall surface of the main body 201, preferably a discharge point (discharge port) of the inlet pipe 208. It is preferable to install it so that it comes down to the entrance of the silver hopper 203. That is, it is preferable to extend the length of the inlet pipe 208 so that discharge of the inlet pipe 208 occurs at the inlet of the hopper 203 .
  • the foreign matter removal facility 200 is provided with sedimentation plates 205, 206, and 207.
  • the molten waste synthetic resin melt supplied from the melting furnace 101 is introduced into the main body 201 through the inlet pipe 208, and discharge from the inlet pipe 208 occurs near the inlet of the hopper 203.
  • the melted waste synthetic resin discharged from the inlet pipe 208 is pushed down to the bottom of the hopper 203 of the main body 201 due to the discharge pressure and then rises.
  • the waste synthetic resin melt that overflows after primarily heavy or coarse foreign substances are removed collides with the second settling plate 206 and descends to the bottom (bottom surface) of the hopper 203.
  • Inorganic substances such as calcium and magnesium, which are the main components of the filler used as auxiliary raw materials, collide with the second settling plate 206 in inertia and are separated from the waste synthetic resin melt.
  • the remaining waste synthetic resin melt separated from inorganic materials flows through the free space under the second settling plate 206 together with the separated inorganic materials, the inorganic materials settle on the bottom surface of the hopper 203, and then the foreign matter conveying equipment 204 It is removed from the foreign matter removal facility 200 by.
  • the melted waste synthetic resin that has passed through the second settling plate 206 meets the third settling plate 207 again, and at this time, fine floating foreign substances contained in the melted waste synthetic resin that have not yet been removed are separated from the first settling plate 205 and the second settling plate 205. According to the same removal principle, it is finally separated while flowing through the third sedimentation plate 207.
  • the main body 201 is designed to be airtight so as not to leak gas as a whole. Furthermore, the main body 201 further includes an outer wall for forming a double jacket 209 structure by entirely surrounding the outside of the main body 201 .
  • the high-temperature exhaust gas discharged from the heater 307 is supplied to the double jacket 209 thus formed to raise the temperature of the waste synthetic resin melt flowing inside the main body 201.
  • desalination of chlorine gas is performed. It is operated from 230°C to 280°C, which is the temperature required for
  • the desalinated chlorine gas is an air pollutant, it is neutralized and treated using an alkali chemical solution in the chemical liquid cleaning device 600.
  • the high-temperature exhaust gas introduced to raise the temperature of the waste synthetic resin melt flowing inside the main body 201 in the double jacket 209 structure ie, for desalination
  • the discharged low-temperature exhaust gas in the chemical liquid cleaning device 600 like demineralized chlorine gas.
  • a discharge port is formed at the lower right side of the foreign matter removal facility 200 to discharge the melted waste synthetic resin that has passed through the main body 201 to the heating facility 300, which is the next step, and a transfer pump 210 for transferring the melted waste synthetic resin may further include.
  • FIG. 4 is a view showing a heating facility, a thermal decomposition facility, and a circulation facility, in particular, in the emulsification device of FIG. 1.
  • the heating facility 300 and the thermal decomposition facility 400 are installed separately, and in the heating facility 300, the waste synthetic resin melt is quickly heated and raised to a higher temperature, and then the thermal decomposition facility 400 stably causes thermal decomposition to occur.
  • the waste synthetic resin melt is converted into oil or combustible gas to be obtained.
  • the reason why the heating facility 300 and the pyrolysis facility 400 are installed separately is that when the entire waste plastic (waste synthetic resin) melt is put into the pyrolysis furnace 401 constituting the pyrolysis facility 400 and heated, the waste synthetic resin melt This is because the wax problem generated when the whole is gradually raised in temperature and thermally decomposed cannot be solved.
  • the heating facility 300 is composed of a heater 307 and a hot stove 308.
  • the heater 307 includes a first water and tube heat exchanger 304 , a second water and tube heat exchanger 305 , and a casing 306 .
  • Each of the first and second heat exchangers 304 and 305 has both ends between a pair of headers (ie, upper header 301 and lower header 302) and a pair of headers 301 and 302. includes a plurality of pipes 303 arranged to be connected, and the pipes 303 are spaced apart from each other at equal intervals and are connected to communicate with the headers 301 and 302, respectively.
  • the first water and tube heat exchanger 304 and the second water and tube heat exchanger 305 are disposed in series with each other, and the first and second heat exchangers 304 and 305 respectively and 750 ° C to 850 ° C supplied from the outside.
  • the casing 306 is arranged so that heat exchange is performed with the high-temperature hot air.
  • the hot air stove 308 is a device for generating and supplying high-temperature hot air to the heater 307, and the fuel used to create the high-temperature hot air is a combustible gas that is a gaseous gas separated from gas in the oil recovery cooling condenser 700 will be able to use
  • the waste synthetic resin melt discharged from the foreign matter removal facility 200 is supplied to the first water and tube heat exchanger 304 by the transfer pump 210 and flows therein. At this time, the first water and tube heat exchanger 304 and the hot stove 308 ), the waste synthetic resin melt is rapidly raised to about 380° C. to 430° C. by heat exchange between high-temperature hot air supplied from, and then introduced into the pyrolysis facility 400.
  • the waste synthetic resin melt heated to a high temperature suitable for thermal decomposition while passing through the first water-tube heat exchanger 304 of the heater 307 is supplied to the thermal decomposition furnace 401, and the waste synthetic resin melt is stably thermally decomposed in the thermal decomposition furnace 401.
  • the process progresses, it is converted into oil vapor with oil components and pyrolysis gas with combustible gas components.
  • the converted oil vapor and pyrolysis gas are condensed and recovered as oil in the oil recovery cooling condenser 700 and stored in the oil storage tank 701, while the uncondensed combustible gas can be used as fuel for the hot stove 308 There will be.
  • the melted waste synthetic resin whose temperature has dropped is precipitated to the lower part of the pyrolysis furnace 401. 2 It is transported to the water-tube heat exchanger 305, heated again in the same way as described above, and then reintroduced into the pyrolysis furnace 401 to be converted into oil through a pyrolysis process. Meanwhile, some of the waste synthetic resin melt precipitated at the bottom of the pyrolysis furnace 401 is transported by the pumping means 501 to the transfer pipe 103 installed in the melting furnace 101 (see FIG. 1) and impregnated with the solid waste synthetic resin. It can also be reused as a hot oil that can be melted.
  • the high-temperature exhaust gas of 750 ° C to 850 ° C generated by burning combustible gas in the hot stove 308 is in a high temperature state of 350 ° C to 450 ° C even after performing heat exchange in the heater 307 to raise the temperature of the waste synthetic resin melt. Discharged from the heater 307, this exhaust gas is supplied to the double jacket 209 configured outside the main body 201 of the foreign matter removal facility 200 to increase the temperature of the waste synthetic resin melt flowing inside the foreign matter removal facility 200. It may also be used to achieve demineralization at elevated levels. This has been explained in the previous section.
  • melting facility 101 melting furnace
  • inlet pipe 209 double jacket
  • pipe 304 first water tube heat exchanger
  • Second water tube heat exchanger 306 casing
  • circulation facility 501 circulation pump

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Abstract

An apparatus for producing oil with waste synthetic resin according to the present invention comprises: a melting furnace for melting solid waste synthetic resin by impregnating same in a high-temperature oil; and a foreign substance removal facility for removing foreign substances such as metals from the waste synthetic resin melt supplied from the melting furnace. A main body constituting the foreign substance removal facility is provided with three stages of sedimentation plates, and foreign substances are removed from the waste synthetic resin melt by disposing the three stages of sedimentation plates in such a manner that the waste synthetic resin melt flows while overflowing and colliding between the three stages of sedimentation plates. The waste synthetic resin melt from which foreign substances are removed passes through a water pipe type heat exchanger constituting a heater for heat exchange. The heat required for heat exchange is supplied from a hot stove. The waste synthetic resin melt is heated up to a temperature suitable for thermal decomposition while passing through the water pipe type heat exchanger, and is then put into a pyrolysis furnace to be subjected to pyrolytic decomposition. Combustible gas components and oil vapor containing oil components are obtained by conducting the pyrolytic decomposition of the waste synthetic resin melt, and are sent to a cooler and cooled to obtain a desired oil.

Description

폐합성수지의 유화장치Waste synthetic resin emulsification device
본 발명은 폐합성수지를 열분해하여 오일과 가연성 가스로 전환시켜 재생에너지를 생산하는 유화장치에 관한 것으로, 상세하게는 고상의 폐합성수지를 고온의 오일에 함침시켜 교반하여 폐합성수지 용융액으로 만들고, 용융액에 함유된 염소성분 및 이물질을 제거하고, 수관식 열교환기를 이용하여 용융액을 빠르게 승온 시킨 후 열분해로에 투입하여 용융액을 오일과 가스성분으로 전환시키는 한편 열분해로에서 일부 용융액을 폐합성수지 용융에 필요한 고온 오일로 재순환 사용하여 열분해에 소요되는 에너지를 최소화 할 수 있도록 한 폐합성수지의 유화장치에 관한 것이다.The present invention relates to an emulsification device that produces renewable energy by thermally decomposing waste synthetic resin and converting it into oil and combustible gas, and more particularly, by impregnating solid waste synthetic resin in high-temperature oil and stirring it to form a melt of waste synthetic resin, The chlorine component and foreign substances contained in it are removed, and the melt is quickly raised in temperature using a water tube heat exchanger, and then put into a thermal decomposition furnace to convert the melt into oil and gas components. It relates to an emulsification device for waste synthetic resin that can minimize the energy required for thermal decomposition by recirculating the furnace.
일반적으로 생활폐기물이나 산업폐기물에서 많이 발생되는 폐합성수지는 소각이나 매립방법으로 많이 처리하고 있지만, 최근 폐합성수지를 탄소(C)분자량이 매우 큰 고체 오일로 보고 폐합성수지에 무 산소상태에서 300℃에서 500℃ 정도의 고온의 열을 가하면 고 탄소분자 고리가 끊어져서 저 탄소분자 고리를 가진 오일이나 가연성 가스로 전환되는데, 이 전환된 것을 포집하여 재생에너지로 사용하는 유화(油化)장치 및 유화방법이 많이 연구되어지고 있다.In general, waste synthetic resin, which is generated a lot in household waste or industrial waste, is treated by incineration or landfill. When high-temperature heat of about 500℃ is applied, the high-carbon molecular ring is broken and converted into oil or combustible gas with a low-carbon molecular ring. It is being studied a lot.
따라서 상기 폐합성수지를 유화하는 방법 또는 장치로는 수평의 원통형 열분해로 내부에 폐합성수지를 가득 채워놓고 밀폐시킨 후에 열분해로 외부에서 직접 화염 열을 가하거나 열분해로 내부에서 전기히터 또는 발열세라믹을 이용하여 발생한 열을 가하여 열분해로 내의 폐합성수지를 열분해 시켜 오일과 가연성 가스로 전환시키는 고정 원통형 열분해방법이 있고, 원통형 열분해로를 회전시켜 열분해로 내부에 가득 채워져 있는 폐합성수지에 고르게 열을 전달하여 빠른 열분해를 유도하는 로타리 킬른형 열분해 방법이 있다.Therefore, as a method or device for emulsifying the waste synthetic resin, after filling the inside of the horizontal cylindrical pyrolysis furnace with the waste synthetic resin and sealing it, direct flame heat is applied from the outside of the pyrolysis furnace or inside the pyrolysis furnace by using an electric heater or a heat-generating ceramic. There is a fixed cylindrical pyrolysis method in which the generated heat is applied to pyrolyze the waste synthetic resin in the pyrolysis furnace and convert it into oil and combustible gas. There is a rotary kiln-type pyrolysis method that induces
또한 수직 원통 열분해로 하부에 모래로 유동층을 형성시키고 유동층 하부에서 400℃ 내지 500℃의 고온 불활성가스(주로 질소가스를 많이 사용)를 고압으로 불어넣어 유동 모래를 고온으로 승온 및 유동시켜 유동층을 형성하고, 형성된 유동층 내부로 4cm이하 크기로 분쇄한 폐합성수지를 연속적으로 투입하여 빠르게 열분해 시켜 오일과 가연성가스로 연속 전환시키는 유동상 열분해 방법이 있다.In addition, a fluidized bed of sand is formed at the bottom of the vertical cylinder pyrolysis furnace, and high-temperature inert gas (mainly nitrogen gas is used a lot) of 400 ° C to 500 ° C is blown at high pressure at the bottom of the fluidized bed to raise the temperature and flow the fluidized sand to a high temperature to form a fluidized bed. Then, there is a fluidized bed pyrolysis method in which waste synthetic resin pulverized into a size of 4 cm or less is continuously injected into the formed fluidized bed to quickly pyrolyze and continuously convert it into oil and combustible gas.
한편 분쇄된 고상의 폐합성수지를 고온의 오일 속에 연속적으로 함침시키면서 교반 용융하여 용융액으로 만든 후 용융액을 열분해로에서 연속적으로 열분해 시켜 오일과 가연성 가스로 연속 전환하는 용융 열분해 방법이 있다.On the other hand, there is a melting pyrolysis method in which pulverized solid waste synthetic resin is continuously impregnated in high-temperature oil while stirring and melted to form a molten liquid, and then the molten liquid is continuously pyrolyzed in a pyrolysis furnace to continuously convert into oil and combustible gas.
먼저 원통형 열분해 방법은 원통형 열분해로에 폐합성수지를 가득 채워 놓고 밀폐시킨 후에 외부나 내부에서 열을 가해서 열분해를 하는 방법으로 초기에 열분해로 내부에 있는 폐합성수지가 적정 열분해 온도인 350℃내지 450℃에 도달할 때 까지 약 30 내지 40분 정도가 걸리는데 특히 250℃ 내지 350℃ 까지 온도가 올라가는 승온 구간에서 일부 폐합성수지 내의 C800 내지 C2000정도의 고 탄소분자 고리가 오일 성분인 C30내지 C50분자 고리와 가연성 가스 성분인 C3내지 C8분자 고리로 열분해 되지 않고 C200 내지 C400 분자 고리인 왁스나 구리스로 열분해 되어 오일회수 냉각응축기의 배관을 막아서 운전 유지보수 비용이 증대되고, 열분해가 완료된 후 원통형 열분해로가 식은 후에 열분해 되지 않은 재를 꺼내고 다시 폐합성수지를 채워 고온으로 승온 작업하여 열분해 운전을 해야 하기 때문에 연속운전이 안 되는 단점이 있다.First, the cylindrical pyrolysis method is a method in which a cylindrical pyrolysis furnace is filled with waste synthetic resin, sealed, and then heat is applied from the outside or inside to pyrolyze the waste synthetic resin inside the pyrolysis furnace. It takes about 30 to 40 minutes to reach it, especially in the temperature rising section where the temperature rises to 250 ° C to 350 ° C, the high carbon molecular ring of about C 800 to C 2000 in some waste synthetic resins contains C 30 to C 50 molecules of the oil component It is not thermally decomposed into a ring and a combustible gas component, C 3 to C 8 molecular ring, but thermally decomposed into wax or grease, which is a C 200 to C 400 molecular ring. After the post-cylindrical pyrolysis furnace cools down, the ash that has not been pyrolyzed is taken out, and the waste synthetic resin is filled again to raise the temperature to a high temperature to operate the pyrolysis operation, so there is a disadvantage that continuous operation is not possible.
또한 유동상 열분해로 방법은 연속적으로 폐합성수지를 투입하고 연속적으로 열분해하는 장점은 있지만, 폐합성수지를 4cm 이하로 분쇄하는 전처리설비가 필요하고, 유동모래가 유동할 때 모래끼리 충돌하면서 분쇄되어 미립화 된 먼지가 회수된 오일과 함께 배출되어 오일회수 냉각응축기의 배관이 막히고, 회수된 오일에 먼지가 함유되어 양질의 오일 생산이 어려우며, 금속성분이 포함된 재가 유동 모래와 같이 배출되면서 재와 모래의 분리가 어려워 유동모래 재사용 효율이 떨어지는 단점이 있다.In addition, the fluidized bed pyrolysis furnace method has the advantage of continuously inputting waste synthetic resin and continuously pyrolyzing it, but requires a pretreatment facility to grind the waste synthetic resin to 4 cm or less, and when the fluidized sand collides with each other, it is pulverized and atomized. Dust is discharged along with the recovered oil, clogging the piping of the oil recovery cooling condenser, and the recovered oil contains dust, making it difficult to produce good quality oil. It is difficult to process, and the efficiency of reusing fluidized sand is low.
이들에 비해. 용융 열분해 방법은 연속운전이 가능하고, 왁스 발생이 없고, 양질의 오일을 회수할 수 있는 우수한 폐합성수지 열분해 방법이지만, 폐합성수지를 열분해가 일어나지 않고 용융만 되는 200℃이하의 저온에서 오랜 시간 녹여야하고, 녹은 폐합성수지 내에 함유된 알루미늄 호일등과 같은 녹지 않은 이물질을 제거하는 장치가 있어야하며, 용융액이 빠른 시간에 열분해 온도까지 도달할 수 있어야 하는 등의 기술적으로 해결하여야 할 문제점이 많다.compared to these. The melt pyrolysis method is an excellent pyrolysis method for waste synthetic resin that enables continuous operation, no wax generation, and can recover high-quality oil. However, there are many technical problems to be solved, such as a device for removing unmelted foreign substances such as aluminum foil contained in the melted waste synthetic resin, and the melt must be able to reach the pyrolysis temperature in a short time.
본 발명은 전술한 바와 같은 종래 기술에서 기인되는 제반 문제점을 해결 보완하기 위한 것으로, 본 발명의 목적은 고상의 폐합성수지를 용융할 때 고온의 오일에 폐합성수지를 함침 및 교반하여 용융시키고, 고온의 오일로는 용융된 폐합성수지 용융액을 사용함으로써 에너지 사용비용을 절감할 수 있는 폐합성수지의 유화장치를 제공하는 데 있다.The present invention is to solve and supplement various problems caused by the prior art as described above, and an object of the present invention is to impregnate and stir the waste synthetic resin in high-temperature oil when melting the solid waste synthetic resin and melt it, An object of the present invention is to provide an apparatus for emulsifying waste synthetic resin capable of reducing energy consumption costs by using a melted waste synthetic resin melt.
본 발명의 다른 목적은 폐합성수지 용융액에 포함된 이물질을 제거하기 위하여 한편으로는, 3단의 중력 침강판이 구비된 이물질 제거설비를 제공하고, 다른 한편으로는 이물질 제거설비를 통해 폐합성수지에 함유된 염소가스를 제거하는 탈염을 수행함으로써 양질의 오일을 회수할 수 있는 폐합성수지의 유화장치를 제공하는 데 있다.Another object of the present invention is to provide a foreign matter removal facility equipped with a three-stage gravity settling plate, on the one hand, in order to remove foreign substances contained in the waste synthetic resin melt, and on the other hand, through the foreign matter removal facility, the foreign matter contained in the waste synthetic resin An object of the present invention is to provide an apparatus for emulsifying waste synthetic resin capable of recovering high-quality oil by performing desalination to remove chlorine gas.
본 발명의 또 다른 목적은 폐합성수지 용융액을 열분해로 외부에서 수관식 열교환 가열 방식으로 빠른 시간에 승온시킨 다음 열분해로에서 폐합성수지 용융액을 열분해함으로써 저온 구간에서 발생하게 되는 왁스 생성을 억제시킬 수 있는 폐합성수지의 유화장치를 제공하는 데 있다.Another object of the present invention is to raise the temperature of the waste synthetic resin melt in a quick time using a water-tube heat exchange heating method from the outside of the pyrolysis furnace, and then pyrolyze the waste synthetic resin melt in the pyrolysis furnace to suppress the generation of wax generated in the low temperature section. It is to provide an emulsification device for synthetic resin.
본 발명의 또 다른 목적은 이물질 제거설비에서 탈염시 발생하는 염소가스는 약액세정장치에서 알칼리 약품으로 중화처리하고, 폐합성수지 용융액은 열분해로에서 유증기와 가연성 가스로 전환된 후 오일회수 냉각응축기에 의해 유증기는 오일로 회수되고 가연성 가스는 열풍로의 연소연료로 사용함으로써 열에너지 사용을 저감시킬 수 있는 폐합성수지의 유화장치를 제공하는 데 있다.Another object of the present invention is to neutralize chlorine gas generated during desalination in a foreign matter removal facility with an alkali chemical in a liquid cleaning device, and convert the melted waste synthetic resin into oil vapor and combustible gas in a pyrolysis furnace, and then use an oil recovery cooling condenser to An object of the present invention is to provide an apparatus for emulsifying waste synthetic resin that can reduce the use of thermal energy by recovering oil vapor and using combustible gas as combustion fuel for a hot stove.
본 발명에 따른 폐합성수지 유화장치는, 고체상의 폐합성수지 및 고온의 오일을 공급받아 상기 고체상의 폐합성수지를 상기 고온의 오일에 함침시켜 상기 고체상의 폐합성수지를 용융하기 위한 용융로;The waste synthetic resin emulsification apparatus according to the present invention includes a melting furnace for receiving solid waste synthetic resin and high-temperature oil and impregnating the solid waste synthetic resin into the high-temperature oil to melt the solid waste synthetic resin;
상기 용융로로부터 공급되는 상기 폐합성수지 용융액이 통과되면서 열교환이 이루어지는 수관식 열교환기를 포함하는 가열기, 및 고온의 열풍을 상기 가열기에 공급하여 상기 수관식 열교환기를 통과하는 상기 폐합성수지 용융액과의 사이에 열교환이 발생하도록 함으로써 상기 폐합성수지 용융액을 열분해시키기 적합한 온도로 승온시키기 위한 열풍로를 포함하는 가열설비; 및Heat exchange occurs between a heater including a water-tube heat exchanger in which heat is exchanged while the molten waste synthetic resin supplied from the melting furnace passes, and the molten waste synthetic resin passing through the water-tube heat exchanger by supplying high-temperature hot air to the heater. a heating facility including a hot air stove for raising the temperature of the waste synthetic resin melt to a temperature suitable for thermal decomposition; and
상기 가열설비로부터 공급받은 열분해에 적합한 온도로 승온된 상기 폐합성수지 용융액을 열분해함으로써 오일 성분을 함유한 유증기와 가연성 가스 성분으로 전환시키기 위한 열분해로;를 포함한다.and a thermal decomposition furnace for converting the waste synthetic resin melt supplied from the heating facility into oil vapor and combustible gas components by thermally decomposing the waste synthetic resin melt heated to a temperature suitable for thermal decomposition.
본 발명 폐합성수지 유화장치의 한 특징에 따르면, 고온의 오일로서 열분해로 내에 존재하는 폐합성수지 용융액 중 일부를 상기 용융로로 이송시켜 이용함으로써 에너지 절감을 달성할 수 있게 된다.According to one feature of the waste synthetic resin emulsification apparatus of the present invention, energy saving can be achieved by transferring a part of the waste synthetic resin melt existing in the pyrolysis furnace as high-temperature oil to the melting furnace for use.
본 발명의 또 다른 특징에 따르면, 용융로는 교반기를 더 포함하는데, 교반기는 용융로에 제공된 고체상의 폐합성수지와 고온의 오일을 교반시켜 고체상의 폐합성수지의 용융을 촉진시키게 된다.According to another feature of the present invention, the melting furnace further includes an agitator, which promotes melting of the solid waste synthetic resin by stirring the high-temperature oil and the solid waste synthetic resin supplied to the melting furnace.
본 발명의 또 다른 특징에 따르면, 이물질 제거설비가 더 형성되는데, 이물질 제거설비는 상자 형태의 본체, 이 본체에 일체로 형성되는 호퍼, 용융로로부터 폐합성수지 용융액을 유입시키기 위한 유입파이프, 및 폐합성수지 용융액에 함유되어 있던 것으로서 호퍼의 바닥면에 침강된 이물질을 제거하기 위한 이물질 이송수단을 포함한다. 그리고, 본체에는 왼쪽으로부터 오른쪽으로 수평방향으로 순서대로 배열되는 제1, 제2, 및 제3 침강판이 배치되는데, 침강판들은 유입파이프를 통해 유입된 폐합성수지 용융액이 본체 내부에서 흐르면서 토출되기까지 폐합성수지 용융액이 3단의 침강판들 사이를 월류 및 충돌하면서 흐르도록 배치함으로써 금속과 같은 무거운 이물질이나 알루미늄 호일과 같은 가벼우나 거친 이물질, 및/또는 미세한 부유물질 등을 제거할 수 있게 된다.According to another feature of the present invention, a foreign matter removal facility is further formed, which includes a box-shaped body, a hopper integrally formed in the body, an inlet pipe for introducing the waste synthetic resin melt from the melting furnace, and a waste synthetic resin It includes a foreign matter conveying means for removing foreign matter contained in the melt and deposited on the bottom surface of the hopper. In addition, first, second, and third settling plates are disposed in the main body in order in a horizontal direction from left to right, and the settling plates are disposed until the waste synthetic resin melt introduced through the inlet pipe is discharged while flowing inside the main body. By arranging the synthetic resin melt to flow while overflowing and colliding between the three-stage settling plates, it is possible to remove heavy foreign substances such as metal, light but rough foreign substances such as aluminum foil, and/or fine floating substances.
본 발명의 또 다른 특징에 따르면, 이물질 제거설비가 본체의 외부를 전체적으로 둘러쌈으로써 본체에 이중 자켓 구조를 형성하기 위한 외벽을 더 포함하며, 가열설비로부터 배출되는 고온의 배기가스를 이중 자켓에 공급하여 본체 내부를 흐르는 폐합성수지 용융액의 온도를 승온시킴으로써 폐합성수지 용융액에 함유된 염소 가스를 탈염시킬 수 있게 된다.According to another feature of the present invention, the foreign matter removal facility further includes an outer wall for forming a double jacket structure in the main body by entirely surrounding the outside of the main body, and supplying high-temperature exhaust gas discharged from the heating facility to the double jacket. The chlorine gas contained in the waste synthetic resin melt can be desalinated by raising the temperature of the waste synthetic resin melt flowing through the main body.
본 발명의 또 다른 특징에 따르면, 가열기의 수관식 열교환기는, 한 쌍의 헤더, 및 한 쌍의 헤더 사이에 각각의 양끝단부가 연결되어 연통되도록 서로 이격되어 배치되는 복수의 파이프들을 포함한다. 따라서, 용융로로부터 공급된 폐합성수지 용융액은, 수관식 열교환기의 한 쌍의 헤더와 파이프들 내부를 통과하는 동안 열풍로로부터 공급되는 고온의 열풍과의 사이에서 열교환을 얻게 되며, 이 열교환을 통해 폐합성수지 용융액으로부터 오일 성분을 추출하기 적합한 온도로 폐합성수지 용융액을 신속하게 승온시키게 된다.According to another feature of the present invention, the water tube heat exchanger of the heater includes a pair of headers, and a plurality of pipes disposed spaced apart from each other so that both ends are connected and communicated between the pair of headers. Therefore, the molten waste synthetic resin supplied from the melting furnace undergoes heat exchange between the pair of headers of the water tube heat exchanger and the high-temperature hot air supplied from the hot air furnace while passing through the inside of the pipes. The temperature of the waste synthetic resin melt is rapidly raised to a temperature suitable for extracting the oil component from the synthetic resin melt.
본 발명의 또 다른 특징에 따르면, 수관식 열교환기를 포함하는 가열기를 열분해로와 별개로 분리하여 구성하고, 폐합성수지 용융액은 수관식 열교환기를 통해 열분해에 적절한 온도로 신속히 승온된 다음 열분해로에 투입되어 열분해가 진행되기 때문에 안정적인 열분해에 의해 오일로 전환하기 위한 유증기나 가연성 가스를 얻을 수 있게 된다.According to another feature of the present invention, the heater including the water-tube heat exchanger is configured separately from the pyrolysis furnace, and the waste synthetic resin melt is rapidly raised to a temperature suitable for pyrolysis through the water-tube heat exchanger and then introduced into the pyrolysis furnace Since thermal decomposition proceeds, it is possible to obtain oil vapor or combustible gas for conversion to oil by stable thermal decomposition.
첫째. 용융로에 연속적으로 고상의 폐합성수지를 투입하여 고온의 오일에 함침시켜 얻은 폐합성수지 용융액을 열분해하여 오일 및 가연성 가스로 전환시킬 수 있어서 연속운전이 가능하다.first. The melt of waste synthetic resin obtained by continuously inputting solid waste synthetic resin into a melting furnace and impregnating it in high-temperature oil can be converted into oil and combustible gas by thermal decomposition, enabling continuous operation.
둘째. 용융로에서 고체상의 폐합성수지를 빠르고 쉽게 용융하기 위해 사용하는 고온의 오일 대신에 가열된(즉, 고온 상태의) 폐합성수지 용융액 일부를 재사용함으로써 고온의 오일 제조에 필요한 비용 및 열에너지를 절감할 수 있다.second. Costs and heat energy required for producing high-temperature oil can be reduced by reusing some of the heated (ie, high-temperature) waste synthetic resin melt instead of high-temperature oil used to quickly and easily melt solid waste synthetic resin in a melting furnace.
셋째. 용융로에서 일차적으로 용융된 폐합성수지 용융액은 이물질 제거설비의 본체에 마련된 3단의 침강판을 통과하면서 이물질(무겁거나 가벼운 금속성 및 미세한 부유 이물질)이 제거되며, 또 한편 승온 및 체류시간을 길게 하여 염소성분을 휘발시키는 탈염 공정이 병행 진행됨으로써 양질의 오일을 회수할 수가 있다.third. The waste synthetic resin melt, which is primarily melted in the melting furnace, passes through the three-stage sedimentation plate provided in the main body of the foreign matter removal facility, removing foreign substances (heavy or light metallic and fine floating foreign substances). A demineralization process that volatilizes the components can be performed in parallel, so that high-quality oil can be recovered.
넷째. 이물질 및 염소성분이 제거된 폐합성수지 용융액을 열분해로와는 별개로 분리하여 설치된 수관식 열교환기를 통하여 빠른 시간에 열분해 온도까지 승온시켜 열분해함으로써 저온 열분해시 발생하게 되는 왁스 생성을 최소화 시킬 수 있다.fourth. The waste synthetic resin melt from which foreign substances and chlorine components have been removed is rapidly raised to the pyrolysis temperature through a water-tube heat exchanger installed separately from the pyrolysis furnace and thermally decomposed, thereby minimizing the generation of wax generated during low-temperature pyrolysis.
도 1은 본 발명의 일 실시예에 따른 폐합성수지의 유화장치를 간략하게 나타낸 전체 구성도이다. 1 is an overall configuration diagram schematically illustrating an apparatus for emulsifying waste synthetic resin according to an embodiment of the present invention.
도 2는 도1의 유화장치에서 용융설비 구조를 보다 상세히 보여주는 도면이다.Figure 2 is a view showing the structure of the melting facility in the emulsification device of Figure 1 in more detail.
도 3은 도1의 유화장치에서 이물질 제거설비를 집중적으로 보여주는 부분 단면도이다.3 is a partial cross-sectional view intensively showing a foreign matter removal facility in the emulsification device of FIG. 1;
도 4는 도1의 유화장치에서 특히 가열설비와 열분해설비 및 순환설비를 나타낸 도면이다.4 is a view showing a heating facility, a thermal decomposition facility, and a circulation facility, in particular, in the emulsification device of FIG. 1.
이하 도면을 참조하여 본 발명에 대해 상세히 설명한다. The present invention will be described in detail with reference to the drawings below.
도 1은 본 발명의 일 실시예에 따른 폐합성수지의 유화장치를 간략하게 나타내는 전체 구성도이다. 1 is an overall configuration diagram schematically illustrating an apparatus for emulsifying waste synthetic resin according to an embodiment of the present invention.
도 1을 참조하면, 본 발명의 일 실시예에 따른 폐합성수지의 유화장치는 크게 용융설비(100), 이물질 제거설비(200), 가열설비(300), 열분해설비(400), 및 순환설비(500)를 포함한다.Referring to FIG. 1, the waste synthetic resin emulsification device according to an embodiment of the present invention includes a melting facility 100, a foreign matter removal facility 200, a heating facility 300, a pyrolysis facility 400, and a circulation facility ( 500) are included.
유화장치는 추가로 필요에 따라 배기가스를 처리하는 약액세정장치(600), 열분해 된 유증기와 가연성 가스를 기액 분리하여 오일을 회수하기 위한 오일회수 냉각응축기(700), 및 오일 저장탱크(701)를 더 포함할 수도 있다. The emulsification device additionally includes a chemical liquid cleaning device 600 for treating exhaust gas as needed, an oil recovery cooling condenser 700 for recovering oil by gas-liquid separation of pyrolyzed oil vapor and combustible gas, and an oil storage tank 701 may further include.
도 2는 도1의 유화장치에서 용융설비 구조를 보다 상세히 보여주는 도면이다. 용융설비(100)를 구성하고 있는 원통형의 용융로(101)는 상부 일 지점에 형성되어 분쇄된 고체상의 폐합성수지를 용융로(101)에 투입하기 위한 투입구(102), 및 상부 다른 일 지점에 형성되어 열분해로(401)(도4참고)로부터 이송되는 고온의 폐합성수지 용융액을 투입하기 위한 이송관(103)을 포함한다. 그리고, 용융로(101) 하부에는 폐합성수지 용융액을 배출할 수 있는 배출밸브(104)가 부착된다.Figure 2 is a view showing the structure of the melting facility in the emulsification device of Figure 1 in more detail. The cylindrical melting furnace 101 constituting the melting facility 100 is formed at an upper point and has an inlet 102 for introducing pulverized solid waste synthetic resin into the melting furnace 101, and formed at another upper point. It includes a transfer pipe 103 for injecting the high-temperature melted waste synthetic resin transferred from the pyrolysis furnace 401 (see FIG. 4). And, a discharge valve 104 capable of discharging the waste synthetic resin melt is attached to the lower part of the melting furnace 101.
한편, 용융설비(100)에는 용융로(101) 상부 일 지점을 통해 용융로(101) 내부로 연장되어 설치되는 교반기(105)가 제공되는데, 교반기(105)는 용융로(101) 내에 투입되는 고체상의 상온 폐합성수지와 액체상의 고온의 오일 내지는 고온의 폐합성수지 용융액을 혼합 교반시킴으로써 고체상의 폐합성수지의 용융을 촉진시켜 신속하게 원하는 폐합성수지 용융액을 얻기 위한 것이다. 일반적으로 고온의 오일을 이용하여 폐합성수지를 함침시켜 용융하는데 필요한 용융온도는 170℃에서 200℃ 정도인 것으로 알려져 있다.On the other hand, the melting facility 100 is provided with an agitator 105 extending into the melting furnace 101 through a point at the top of the melting furnace 101 and installed. This is to rapidly obtain a desired melt of waste synthetic resin by accelerating the melting of the solid waste synthetic resin by mixing and stirring the waste synthetic resin and the liquid high-temperature oil or high-temperature waste synthetic resin melt. In general, it is known that the melting temperature required to impregnate and melt the waste synthetic resin using high-temperature oil is about 170°C to 200°C.
도2의 우측에 별도로 분리하여 도시한 것과 같이, 상기 교반기(105)는 용융로(101) 외부에 노출되어 설치되는 모터(106)와 감속기(107), 및 용융로(101) 내부에 배치되는 축(108)과 교반 날개(109)를 포함한다. 교반 날개(109)는 용융로(101) 내부에 일정 길이 연장되어 배치되는 축(108)의 끝단부에 설치되며, 다수의 구멍(110)이 뚫린 캡(111)이 교반 날개(109)를 전체적으로 감싸면서 축(108)에 고정된다. 모터(106)의 회전은 축(108)과 교반 날개(109)에 전달이 되어 회전을 일으키게 되고, 이 회전에 의해 폐합성수지(고체상의 폐합성수지와 액체상의 고온의 오일 내지 고온의 폐합성수지 용융액)를 교반하게 되는데, 이때 캡(111)이 교반 날개(109)를 감싸고 있기 때문에 캡(111) 내에 들어온 고체상의 폐합성수지를 교반날개(109)가 캡(111)면을 스치듯이 회전하면서 절단하게 된다. 또한 캡(111)에 의해 고체상의 폐합성수지가 교반 날개(109)에 감겨서 덩어리지는 것이 방지된다.As shown separately on the right side of FIG. 2, the agitator 105 includes a motor 106 and a reducer 107 installed exposed to the outside of the melting furnace 101, and a shaft disposed inside the melting furnace 101 ( 108) and stirring blades 109. The stirring blades 109 are installed at the end of a shaft 108 extending and disposed inside the melting furnace 101, and a cap 111 with a plurality of holes 110 is wrapped around the stirring blades 109 as a whole. while being fixed to the shaft 108. The rotation of the motor 106 is transmitted to the shaft 108 and the stirring blades 109 to cause rotation, and by this rotation, the waste synthetic resin (solid waste synthetic resin and liquid high-temperature oil or high-temperature waste synthetic resin melt) At this time, since the cap 111 surrounds the stirring blades 109, the solid waste synthetic resin that has entered the cap 111 is cut while the stirring blades 109 rotate as if brushing the surface of the cap 111. . In addition, the cap 111 prevents the solid waste synthetic resin from being wrapped around the stirring blades 109 and forming lumps.
또한 교반기(105)는 경사지게 설치하는 것이 바람직한데, 이는 교반 날개(109)를 수평으로 설치할 경우 폐합성수지가 용융될 때 고체 상태이거나 아직 제대로 용융되지 않은 폐합성수지 덩어리가 교반 날개(109)에 감기거나 들러붙는 것을 방지하기 위한 것이다. In addition, it is preferable to install the agitator 105 at an angle, which means that when the agitator blades 109 are installed horizontally, when the waste synthetic resin is melted, a lump of waste synthetic resin that is in a solid state or has not yet been properly melted is wound around the agitator blades 109 or This is to prevent sticking.
도 3은 도1의 유화장치에서 이물질 제거설비를 집중적으로 보여주는 부분 단면도이다. 여기서의 이물질 제거는 물리적인 것과 화학적인 것 둘 다를 포함하는 것으로 이해하여야 한다. 3 is a partial cross-sectional view intensively showing a foreign matter removal facility in the emulsification device of FIG. 1; It should be understood that foreign matter removal herein includes both physical and chemical matters.
먼저, 물리적인 측면 즉 구조적인 측면을 살펴보면, 이물질 제거설비(200)는 상자(box) 형태의 용기 하부에 형성된 호퍼(203)를 포함하는 본체(201), 본체(201)의 상부 개구부에 덮개 형태로 설치되는 상부판(202), 및 호퍼(203) 저면을 가로질러 형성되는 이물질 이송설비(204)를 포함하며, 본체(201)는 전체적으로 가스가 새지 않는 정도의 밀폐구조로 제작된다. 이물질 이송설비(204)는 컨베이어, 수거함 등을 포함하는 이물질 이송수단으로 구성된다.First, looking at the physical aspect, that is, the structural aspect, the foreign matter removal facility 200 includes a main body 201 including a hopper 203 formed at the bottom of a box-shaped container, and a cover on the upper opening of the main body 201. It includes an upper plate 202 installed in the form, and a foreign matter conveying facility 204 formed across the bottom surface of the hopper 203, and the main body 201 is made of a closed structure to the extent that gas does not leak as a whole. The foreign matter transfer facility 204 is composed of foreign material transfer means including a conveyor, a collection box, and the like.
한편, 본체(201) 내부에는 대향하는 본체(201) 벽으로부터 일정 간격 이격되어 제1 침강판(205)이 제공되는데, 제1 침강판(205)은 침강판(205)의 면(가로면 또는 넓은 면)과 대향하는 본체(201)의 벽면을 따라 가로로 연장되어 배치되며, 이때 연장 길이는 본체(201)의 나머지 두 벽면과 닿도록 연장되거나 또는 닿지 않도록 일정 길이만큼 연장될 수도 있다. 이와 같은 제1 침강판(205)의 가로면 연장 길이는 후술하는 제2 및 제3 침강판(206, 207) 각각의 가로면 연장 길이에도 적용된다. 그리고, 제1, 제2, 및 제3 침강판(205, 206, 207) 각각의 가로면 연장 길이는 서로 다를 수 있다.On the other hand, a first settling plate 205 is provided inside the main body 201 at a predetermined distance from the wall of the main body 201 facing the opposite side. wide surface) along the wall surface of the main body 201 facing the body 201 and is disposed to extend horizontally. In this case, the extension length may be extended by a certain length so as to contact the other two wall surfaces of the main body 201 or not to touch the other two walls of the main body 201 . The horizontal extension length of the first settling plate 205 is also applied to the horizontal extension length of each of the second and third settling plates 206 and 207 described later. In addition, each of the first, second, and third settling plates 205, 206, and 207 may have different horizontal extension lengths.
제1 침강판(205)의 밑면(하단부)은 호퍼(203)의 바닥면에 고정되며, 고정되지 않는 제1 침강판(205)의 자유단부(상단부 즉 윗면)는 후술하는 유입파이프(208) 및 이와 가까운 본체(201)의 벽 쪽으로 전체적으로 직각으로 굽은, 그래서 일반적으로 단면 형상이 ㄱ자 형태를 띠게 된다. 물론 자유단부는 완만한 곡선 형태를 유지하면서 휘어질 수도 있다. 이와 같이 제1 침강판(205)의 윗면(자유단부)은 본체(201)의 상부판(202)으로부터 이격되어 배치된다.The lower surface (lower part) of the first sedimentation plate 205 is fixed to the bottom surface of the hopper 203, and the free end (upper part or upper surface) of the first sedimentation plate 205, which is not fixed, is an inlet pipe 208 to be described later. And bent at a right angle as a whole toward the wall of the body 201 close to it, so the cross-sectional shape is generally L-shaped. Of course, the free end portion may be bent while maintaining a gentle curved shape. In this way, the upper surface (free end) of the first settling plate 205 is spaced apart from the upper plate 202 of the main body 201.
제2 침강판(206)은 제1 침강판(205)과 일정 거리 이격되어 배치되며, 제2 침강판(206)의 윗면은 본체(201)의 상부판(202)에 고정되며 고정되지 않는 자유단부(밑면)는 접은(굽은) 부분이 없이 호퍼(203)의 바닥면으로부터 일정 거리 이격되어 배치된다. 따라서, 제2 침강판(206)은 전체적으로 평판 형태로서 "1(일)"자 형태를 띠게 된다. The second settling plate 206 is disposed at a predetermined distance from the first settling plate 205, and the upper surface of the second settling plate 206 is fixed to the upper plate 202 of the main body 201 and is free from being fixed. The end (bottom surface) is spaced apart from the bottom surface of the hopper 203 by a certain distance without a folded (bent) portion. Accordingly, the second settling plate 206 has a flat plate shape as a whole and takes on the shape of the letter “1”.
제3침강판(207)은 제2 침강판(206)으로부터 일정 거리 이격되어 배치되는데, 그 형태 및 배치 방법은 제1침강판(205)의 그것들과 일반적으로 같다. 이와 같이 하여 본 발명의 일 구현 예에서는 3단의 침강판 구조로 이물질 제거설비(200)를 구성하였다.The third settler plate 207 is disposed at a predetermined distance from the second settler plate 206, and its shape and arrangement are generally the same as those of the first settler plate 205. In this way, in one embodiment of the present invention, the foreign matter removal facility 200 is configured with a three-stage sedimentation plate structure.
또한 이물질 제거설비(200)의 본체(201)에는 용융로(101)로부터 폐합성수지 용융액을 공급받기 위한 유입 파이프(208)가 제공되는데, 유입 파이프(208)는 제1 침강판(205)의 가로면과 대향하는 본체(201)의 벽면과 제1 침강판(205) 사이에 배치된다. 유입 파이프(208)는 본체(201)의 상부판(202)를 관통하여 본체(201)의 벽면을 따라 하방으로 일정 길이 연장되도록 배치되는데, 바람직하게는 유입 파이프(208)의 토출지점(토출구)은 호퍼(203) 입구까지 내려오도록 설치하는 것이 바람직하다. 즉, 유입 파이프(208)의 토출이 호퍼(203) 입구에서 발생하도록 유입 파이프(208)의 길이를 연장하여 배치하는 것이 좋다.In addition, the body 201 of the foreign matter removal facility 200 is provided with an inlet pipe 208 for receiving the melted waste synthetic resin from the melting furnace 101, and the inlet pipe 208 is the horizontal surface of the first settling plate 205. It is disposed between the wall surface of the main body 201 and the first settling plate 205 facing each other. The inlet pipe 208 penetrates the upper plate 202 of the main body 201 and is disposed to extend a certain length downward along the wall surface of the main body 201, preferably a discharge point (discharge port) of the inlet pipe 208. It is preferable to install it so that it comes down to the entrance of the silver hopper 203. That is, it is preferable to extend the length of the inlet pipe 208 so that discharge of the inlet pipe 208 occurs at the inlet of the hopper 203 .
이물질 제거설비(200)의 작동원리를 살펴본다. 일반적으로 용융로(101)로부터 이물질 제거설비(200)에 투입된 폐합성수지 용융액에 함유되어 있던 이물질은 자중이나 거칠기 등으로 인해 본체(201)에 일체로 형성된 호퍼(203)의 바닥면에 침강하게 된다. 그러나 이러한 자중이나 거칠기와 같은 이물질 자체가 가지는 물리적인 특성에만 의존하여 폐합성수지 용융액에 함유되어 있던 이물질을 제거하는 데에는 분명한 한계가 있다. The operating principle of the foreign matter removal facility 200 will be looked at. In general, foreign substances contained in the waste synthetic resin melt introduced from the melting furnace 101 to the foreign matter removal equipment 200 settle on the bottom surface of the hopper 203 integrally formed in the main body 201 due to its own weight or roughness. However, there is a clear limit to removing foreign substances contained in the waste synthetic resin melt by relying only on the physical properties of the foreign substances themselves, such as dead weight or roughness.
이러한 한계를 극복하기 위해 본 발명의 일 구현에 따른 이물질 제거설비(200)는 침강판들(205, 206, 207)이 제공된다. 용융로(101)로부터 공급되는 용융된 폐합성수지 용융액은 유입 파이프(208)를 통해 본체(201)에 투입되는데, 이때 유입 파이프(208)에서의 토출은 호퍼(203) 입구 부근에서 발생하게 된다. 유입파이프(208)로부터 토출되는 폐합성수지 용융액은 토출 압력으로 인해 본체(201)의 호퍼(203) 하부로까지 밀려내려 갔다가 상승하게 되는데, 이때 폐합성수지 용융액에 포함되어 있던 철, 구리 등과 같은 금속성분의 무거운 물질은 호퍼(203) 바닥면으로 침강하게 되며, 반면 알루미늄 호일, 나무 조각 같은 가볍지만 거친 이물질은 폐합성수지 용융액과 함께 상승하여 제1 침강판(205)을 월류하여 흐르려고 한다. 이렇게 월류가 발생할 때, 제1 침강판(205)의 자유단부(상단부)가 굽어있기 때문에 가볍지만 거친 이물질은 굽어있는 부분, 즉 일반적으로 ㄱ자형태의 침강판(205) 중에서 수평판에 걸려서 월류되지 못하고 수직판을 타고 호퍼(203)의 바닥면으로 침강하게 된다. In order to overcome these limitations, the foreign matter removal facility 200 according to one embodiment of the present invention is provided with sedimentation plates 205, 206, and 207. The molten waste synthetic resin melt supplied from the melting furnace 101 is introduced into the main body 201 through the inlet pipe 208, and discharge from the inlet pipe 208 occurs near the inlet of the hopper 203. The melted waste synthetic resin discharged from the inlet pipe 208 is pushed down to the bottom of the hopper 203 of the main body 201 due to the discharge pressure and then rises. At this time, metal components such as iron and copper contained in the melted waste synthetic resin The heavy materials of are settled to the bottom surface of the hopper 203, while light but rough foreign materials such as aluminum foil and wood chips rise together with the waste synthetic resin melt and try to flow over the first settling plate 205. When overflow occurs in this way, since the free end (upper end) of the first settling plate 205 is bent, light but rough foreign substances are caught on the horizontal plate among the curved parts, that is, generally L-shaped settling plate 205, and do not overflow , and sinks to the bottom surface of the hopper 203 on the vertical plate.
이와 같이 일차적으로 무겁거나 거친 이물질이 제거되어 월류된 폐합성수지 용융액은 제2 침강판(206)과 충돌하면서 호퍼(203) 하부(바닥면)로 하강하게 되는데, 이때 플라스틱 제조시 강도 유지를 위해서 흔히 보조 원료로 사용하는 필러의 주성분인 칼슘, 마그내슘과 같은 무기물이 제2 침강판(206)과 관성 충돌하면서 폐합성수지 용융액과 분리된다. 이렇게 무기물과 분리된 나머지 폐합성수지 용융액이 분리된 무기물과 함께 제2 침강판(206) 하부의 자유 공간을 통과하여 흐를 때, 무기물은 호퍼(203) 바닥면에 침강되고 이어서 이물질 이송설비(204)에 의해 이물질 제거설비(200)로부터 제거된다.In this way, the waste synthetic resin melt that overflows after primarily heavy or coarse foreign substances are removed collides with the second settling plate 206 and descends to the bottom (bottom surface) of the hopper 203. At this time, in order to maintain strength during plastic manufacturing, Inorganic substances such as calcium and magnesium, which are the main components of the filler used as auxiliary raw materials, collide with the second settling plate 206 in inertia and are separated from the waste synthetic resin melt. When the remaining waste synthetic resin melt separated from inorganic materials flows through the free space under the second settling plate 206 together with the separated inorganic materials, the inorganic materials settle on the bottom surface of the hopper 203, and then the foreign matter conveying equipment 204 It is removed from the foreign matter removal facility 200 by.
제2 침강판(206)을 통과한 폐합성수지 용융액은 다시 제3 침강판(207)과 만나게 되고, 이때 폐합성수지 용융액에 함유된 아직 제거되지 않은 미세 부유 이물질은, 제1 침강판(205)과 같은 제거 원리에 따라, 제3 침강판(207)을 월류하면서 최종 분리된다.The melted waste synthetic resin that has passed through the second settling plate 206 meets the third settling plate 207 again, and at this time, fine floating foreign substances contained in the melted waste synthetic resin that have not yet been removed are separated from the first settling plate 205 and the second settling plate 205. According to the same removal principle, it is finally separated while flowing through the third sedimentation plate 207.
이와 같이, 이물질 제거설비(200)의 본체(201)에 설치된 3개의 침강판들(205, 206, 207)에 의해 폐합성수지 용융액에 함유되어 있다가 분리된 각종 이물질들은 호퍼(203)의 바닥면에 모이게 되고, 이렇게 모인 이물질들은 이물질 이송설비(204)에 의해 이물질 제거설비(200)로부터 배출된다.In this way, various foreign substances contained in the waste synthetic resin melt and separated by the three settling plates 205, 206, and 207 installed on the main body 201 of the foreign matter removal facility 200 are separated from the bottom surface of the hopper 203. It is collected in, and the foreign substances collected in this way are discharged from the foreign matter removal facility 200 by the foreign matter transport facility 204.
이제, 이물질 제거설비(200)의 화학적 측면에 대해서 살펴보면, 위에서 설명한 것과 같이 본체(201)는 전체적으로 가스가 새지 않도록 밀페되게 설계된다. 나아가, 본체(201)는 본체(201)의 외부를 전체적으로 둘러쌈으로써 2중 자켓(209) 구조를 형성하기 위한 외벽을 더 포함한다. 이렇게 형성된 이중 자켓(209)에는 가열기(307)에서 배출되는 고온의 배기가스가 공급되어 본체(201) 내부를 흐르는 폐합성수지 용융액의 온도를 승온시키게 되는데, 본 발명의 일 구현에서는 염소가스의 탈염을 위해 필요한 온도인 230℃에서 280℃가 되도록 운영한다.Now, looking at the chemical aspect of the foreign matter removal facility 200, as described above, the main body 201 is designed to be airtight so as not to leak gas as a whole. Furthermore, the main body 201 further includes an outer wall for forming a double jacket 209 structure by entirely surrounding the outside of the main body 201 . The high-temperature exhaust gas discharged from the heater 307 is supplied to the double jacket 209 thus formed to raise the temperature of the waste synthetic resin melt flowing inside the main body 201. In one embodiment of the present invention, desalination of chlorine gas is performed. It is operated from 230℃ to 280℃, which is the temperature required for
탈염된 염소 가스는 대기오염 물질이므로 약액세정장치(600)에서 알칼리 약액을 사용하여 중화시켜 처리한다. 아울러, 2중 자켓(209) 구조에서 본체(201) 내부를 유동하는 폐합성수지 용융액의 온도를 승온시키기 위하여 (즉, 탈염을 위해) 유입된 상기 고온의 배기가스는 열교환되어 온도가 낮아진 상태에서 배출되는데, 배출되는 저온 배기가스는 탈염된 염소가스와 같이 약액세정장치(600)에서 처리하는 것이 바람직하다.Since the desalinated chlorine gas is an air pollutant, it is neutralized and treated using an alkali chemical solution in the chemical liquid cleaning device 600. In addition, the high-temperature exhaust gas introduced to raise the temperature of the waste synthetic resin melt flowing inside the main body 201 in the double jacket 209 structure (ie, for desalination) is heat exchanged and discharged in a state where the temperature is lowered. However, it is preferable to treat the discharged low-temperature exhaust gas in the chemical liquid cleaning device 600 like demineralized chlorine gas.
본체(201)를 통과하면서 제거된 이물질은 일부 폐합성수지 용융액과 혼합된 상태로 이물질 이송설비(204)를 통해 배출되는데, 일부 폐합성수지 용융물이 혼합되어 있어서 발열량이 높으므로 성형화시켜 고형연료로 제조하여(pellet화) 사용할 수도 있을 것이다.Foreign substances removed while passing through the main body 201 are mixed with some of the waste synthetic resin melt and discharged through the foreign substance transfer facility 204. Since some of the waste synthetic resin melt is mixed and has a high calorific value, it is molded and manufactured as solid fuel. (pelletization) may be used.
이물질 제거설비(200)의 우측 하단부에는 본체(201)를 통과한 폐합성수지 용융액을 다음 단계인 가열설비(300)로 토출시키기 위한 토출구가 형성되며, 폐합성수지 용융액을 이송시키기 위한 이송 펌프(210)를 더 포함할 수 있다. A discharge port is formed at the lower right side of the foreign matter removal facility 200 to discharge the melted waste synthetic resin that has passed through the main body 201 to the heating facility 300, which is the next step, and a transfer pump 210 for transferring the melted waste synthetic resin may further include.
도 4는 도1의 유화장치에서 특히 가열설비와 열분해설비 및 순환설비를 나타낸 도면이다. 가열설비(300)와 열분해설비(400)는 분리되어 설치되며, 가열설비(300)에서 폐합성수지 용융액을 빠르게 더 높은 고온으로 가열·승온시킨 다음 열분해설비(400)에서 안정되게 열분해가 발생되게 함으로써 폐합성수지 용융액을 얻고자 하는 오일이나 가연성 가스로 전환시키게 된다.4 is a view showing a heating facility, a thermal decomposition facility, and a circulation facility, in particular, in the emulsification device of FIG. 1. The heating facility 300 and the thermal decomposition facility 400 are installed separately, and in the heating facility 300, the waste synthetic resin melt is quickly heated and raised to a higher temperature, and then the thermal decomposition facility 400 stably causes thermal decomposition to occur. The waste synthetic resin melt is converted into oil or combustible gas to be obtained.
가열설비(300)와 열분해설비(400)를 분리 설치하는 이유는 열분해설비(400)를 구성하고 있는 열분해로(401)에 폐플라스틱(폐합성수지) 용융액 전체를 투입 후 가열을 하게 되면 폐합성수지 용융액 전체가 서서히 승온되어 열분해 할 때 발생되는 왁스 문제를 해결할 수 없기 때문이다.The reason why the heating facility 300 and the pyrolysis facility 400 are installed separately is that when the entire waste plastic (waste synthetic resin) melt is put into the pyrolysis furnace 401 constituting the pyrolysis facility 400 and heated, the waste synthetic resin melt This is because the wax problem generated when the whole is gradually raised in temperature and thermally decomposed cannot be solved.
가열설비(300)는 가열기(307)와 열풍로(308)로 구성된다. 가열기(307)는 제1 수관식 열교환기(304), 제2 수관식 열교환기(305), 및 케이싱(306)을 포함한다. 제1 및 제2 열교환기(304, 305) 각각은 한 쌍의 헤더(즉, 상부 헤더(301) 및 하부 헤더(302)), 및 한 쌍의 헤더(301, 302) 사이에 각각의 양끝단부가 연결되도록 배열되는 다수의 파이프들(303)을 포함하는데, 파이프들(303)은 서로 등간격 이격되어 헤더들(301, 302)과 서로 각각 연통되도록 연결된다. 제1 수관식 열교환기(304)와 제2 수관식 열교환기(305)는 서로 직렬로 배치되며, 제1 및 제2 열교환기(304, 305) 각각과 외부에서 공급되는 750℃∼850℃ 의 고온 열풍과의 사이에 열교환이 이루어지도록 케이싱(306)이 배치된다. The heating facility 300 is composed of a heater 307 and a hot stove 308. The heater 307 includes a first water and tube heat exchanger 304 , a second water and tube heat exchanger 305 , and a casing 306 . Each of the first and second heat exchangers 304 and 305 has both ends between a pair of headers (ie, upper header 301 and lower header 302) and a pair of headers 301 and 302. includes a plurality of pipes 303 arranged to be connected, and the pipes 303 are spaced apart from each other at equal intervals and are connected to communicate with the headers 301 and 302, respectively. The first water and tube heat exchanger 304 and the second water and tube heat exchanger 305 are disposed in series with each other, and the first and second heat exchangers 304 and 305 respectively and 750 ° C to 850 ° C supplied from the outside. The casing 306 is arranged so that heat exchange is performed with the high-temperature hot air.
한편, 열풍로(308)는 가열기(307)에 고온의 열풍을 만들어서 공급하는 장치이며, 고온의 열풍을 만들기 위해 사용되는 연료로는 오일회수 냉각응축기(700)에서 기액 분리된 기체가스인 가연성 가스가 사용될 수 있을 것이다.On the other hand, the hot air stove 308 is a device for generating and supplying high-temperature hot air to the heater 307, and the fuel used to create the high-temperature hot air is a combustible gas that is a gaseous gas separated from gas in the oil recovery cooling condenser 700 will be able to use
이물질 제거설비(200)로부터 배출되는 폐합성수지 용융액은 이송펌프(210)에 의해 제1 수관식 열교환기(304)로 공급되어 흐르게 되는데, 이때 제1 수관식 열교환기(304)와 열풍로(308)로부터 공급되는 고온의 열풍 사이의 열교환에 의해 폐합성수지 용융액은 약 380℃ ∼ 430℃ 상으로 빠르게 승온된 후 열분해설비(400)로 투입된다. The waste synthetic resin melt discharged from the foreign matter removal facility 200 is supplied to the first water and tube heat exchanger 304 by the transfer pump 210 and flows therein. At this time, the first water and tube heat exchanger 304 and the hot stove 308 ), the waste synthetic resin melt is rapidly raised to about 380° C. to 430° C. by heat exchange between high-temperature hot air supplied from, and then introduced into the pyrolysis facility 400.
가열기(307)의 제1 수관식 열교환기(304)를 통과하면서 열분해에 적합한 고온으로 승온된 폐합성수지 용융액은 열분해로(401)로 공급되고, 열분해로(401)에서 폐합성수지 용융액은 안정적으로 열분해가 진행되면서 오일 성분이 있는 유증기와 가연성 가스 성분인 열분해 가스로 전환된다. 전환된 유증기와 열분해 가스는 오일회수 냉각응축기(700)에서 오일로 응축 회수되어 오일 저장탱크(701)에 저장되고, 한편 응축되지 않은 가연성 가스는 상기 열풍로(308)의 연료로 사용되어 질 수 있을 것이다.The waste synthetic resin melt heated to a high temperature suitable for thermal decomposition while passing through the first water-tube heat exchanger 304 of the heater 307 is supplied to the thermal decomposition furnace 401, and the waste synthetic resin melt is stably thermally decomposed in the thermal decomposition furnace 401. As the process progresses, it is converted into oil vapor with oil components and pyrolysis gas with combustible gas components. The converted oil vapor and pyrolysis gas are condensed and recovered as oil in the oil recovery cooling condenser 700 and stored in the oil storage tank 701, while the uncondensed combustible gas can be used as fuel for the hot stove 308 There will be.
한편, 열분해로(401)에서 열분해가 진행되면서 온도가 떨어진 폐합성수지 용융액은 열분해로(401) 하부로 침전되는데, 침전된 폐합성수지 용융액은 순환설비(500)인 순환펌프(501)를 이용하여 제2 수관식 열교환기(305)로 이송되어, 위에서 설명한 것과 같은 방법으로, 다시 승온된 후 열분해로(401)로 재투입되어 열분해 과정을 거쳐 오일로 전환된다. 한편, 열분해로(401) 하부로 침전된 폐합성수지 용융액 중 일부는 펌핑 수단(501)에 의해 용융로(101)에 설치된 이송관(103)으로 이송시켜(도1 참고) 고상의 폐합성수지를 함침시켜 용융시킬 수 있는 고온의 오일로 재사용할 수도 있다. On the other hand, as thermal decomposition progresses in the pyrolysis furnace 401, the melted waste synthetic resin whose temperature has dropped is precipitated to the lower part of the pyrolysis furnace 401. 2 It is transported to the water-tube heat exchanger 305, heated again in the same way as described above, and then reintroduced into the pyrolysis furnace 401 to be converted into oil through a pyrolysis process. Meanwhile, some of the waste synthetic resin melt precipitated at the bottom of the pyrolysis furnace 401 is transported by the pumping means 501 to the transfer pipe 103 installed in the melting furnace 101 (see FIG. 1) and impregnated with the solid waste synthetic resin. It can also be reused as a hot oil that can be melted.
한편, 열풍로(308)에서 가연성 가스를 연소시켜 발생한 750℃∼ 850℃ 의 고온의 배기가스는 가열기(307)에서 폐합성수지 용융액을 승온시키는 열교환을 수행하고도 350℃ ∼ 450℃ 의 고온 상태로 가열기(307)에서 배출되는데, 이 배기가스는 이물질 제거설비(200)의 본체(201) 외부에 구성된 2중 자켓(209)으로 공급되어 이물질 제거설비(200) 내부를 흐르는 폐합성수지 용융액의 온도를 높여서 탈염이 이루어지도록 이용될 수도 있을 것이다. 이에 대해서는 앞서 해당 부분에서 설명하였다.On the other hand, the high-temperature exhaust gas of 750 ° C to 850 ° C generated by burning combustible gas in the hot stove 308 is in a high temperature state of 350 ° C to 450 ° C even after performing heat exchange in the heater 307 to raise the temperature of the waste synthetic resin melt. Discharged from the heater 307, this exhaust gas is supplied to the double jacket 209 configured outside the main body 201 of the foreign matter removal facility 200 to increase the temperature of the waste synthetic resin melt flowing inside the foreign matter removal facility 200. It may also be used to achieve demineralization at elevated levels. This has been explained in the previous section.
[부호의 설명][Description of code]
100: 용융설비 101: 용융로100: melting facility 101: melting furnace
102: 투입구 103: 이송관102: inlet 103: transfer pipe
104: 배출밸브 105: 교반기104: discharge valve 105: agitator
106: 모터 107: 감속기106: motor 107: reducer
108: 축 109 : 교반날개108: shaft 109: stirring blade
110: 구멍 111: 캡110: hole 111: cap
200: 이물질 제거설비 201: 본체200: foreign matter removal facility 201: main body
202: 상부판 203: 호퍼202: top plate 203: hopper
204: 이물질 이송설비 205: 제1 침강판204: foreign matter transfer facility 205: first settling plate
206: 제2 침강판 207: 제3 침강판206: second settler plate 207: third settler plate
208: 유입파이프 209: 2중 자켓208: inlet pipe 209: double jacket
210: 이송펌프 300: 가열설비210: transfer pump 300: heating facility
301: 상부 헤더 302: 하부 헤더301: upper header 302: lower header
303: 파이프 304: 제1 수관식 열교환기303: pipe 304: first water tube heat exchanger
305; 제2 수관식 열교환기 306: 케이싱305; Second water tube heat exchanger 306: casing
307: 가열기 308: 열풍로307: heater 308: hot air furnace
400: 열분해설비 401: 열분해로400: pyrolysis facility 401: pyrolysis furnace
500: 순환설비 501: 순환펌프500: circulation facility 501: circulation pump
600: 약액세정장치 700: 오일회수 냉각응축기600: liquid chemical cleaning device 700: oil recovery cooling condenser
701: 오일 저장탱크701: oil storage tank

Claims (17)

  1. 고체상의 폐합성수지 및 고온의 오일을 공급받아 상기 고체상의 폐합성수지를 상기 고온의 오일에 함침시켜 상기 고체상의 폐합성수지를 용융하기 위한 용융로;a melting furnace receiving solid waste synthetic resin and high-temperature oil and impregnating the solid waste synthetic resin into the high-temperature oil to melt the solid waste synthetic resin;
    상기 용융로로부터 공급되는 상기 폐합성수지 용융액이 통과되면서 열교환이 이루어지는 수관식 열교환기를 포함하는 가열기, 및 고온의 열풍을 상기 가열기에 공급하여 상기 수관식 열교환기를 통과하는 상기 폐합성수지 용융액과의 사이에 열교환이 발생하도록 함으로써 상기 폐합성수지 용융액을 열분해시키기 적합한 온도로 승온시키기 위한 열풍로를 포함하는 가열설비; 및Heat exchange occurs between a heater including a water-tube heat exchanger in which heat is exchanged while the molten waste synthetic resin supplied from the melting furnace passes, and the molten waste synthetic resin passing through the water-tube heat exchanger by supplying high-temperature hot air to the heater. a heating facility including a hot air stove for raising the temperature of the waste synthetic resin melt to a temperature suitable for thermal decomposition; and
    상기 가열설비로부터 공급받은 열분해에 적합한 온도로 승온된 상기 폐합성수지 용융액을 열분해함으로써 오일 성분을 함유한 유증기와 가연성 가스 성분으로 전환시키기 위한 열분해로;를 포함하는 A thermal decomposition furnace for converting the waste synthetic resin melt supplied from the heating facility into oil vapor and combustible gas components by thermally decomposing the waste synthetic resin melt heated to a temperature suitable for thermal decomposition;
    폐합성수지의 유화장치.Waste synthetic resin emulsification device.
  2. 제1항에 있어서, According to claim 1,
    상기 고온의 오일로서 상기 열분해로 내에 존재하는 상기 폐합성수지 용융액 중 일부를 상기 용융로로 이송시켜 이용하는, Some of the waste synthetic resin melt existing in the pyrolysis furnace as the high-temperature oil is transferred to the melting furnace and used.
    폐합성수지의 유화장치.Waste synthetic resin emulsification device.
  3. 제1항에 있어서, According to claim 1,
    상기 용융로는 교반기를 더 포함하며;The melting furnace further includes an agitator;
    상기 교반기는, 상기 용융로 내부로 연장되어 배치되며 동력 전달을 받아 회전하는 축, 상기 용융로 내부로 연장된 상기 축의 자유 단부에 회전 가능하게 연결되는 교반 날개, 및 상기 교반 날개를 감싸고 있으며 복수의 구멍을 갖는 캡을 포함하며;The stirrer includes a shaft extending into the melting furnace and rotating by receiving power, a stirring blade rotatably connected to a free end of the shaft extending into the melting furnace, and a plurality of holes surrounding the stirring blade. Includes a cap having;
    상기 교반기는 상기 용융로에 제공된 상기 고체상의 폐합성수지와 상기 고온의 오일을 교반시켜 상기 고체상의 폐합성수지의 용융을 촉진시키기 위한,The stirrer promotes melting of the solid waste synthetic resin by stirring the solid waste synthetic resin and the high-temperature oil provided in the melting furnace.
    폐합성수지의 유화장치.Waste synthetic resin emulsification device.
  4. 제1항에 있어서, According to claim 1,
    하부에 형성되는 호퍼를 포함하는 본체;A main body including a hopper formed at a lower portion;
    상기 용융로로부터 상기 폐합성수지 용융액을 유입시키기 위한 유입파이프로서, 상기 유입파이프는 상기 본체의 벽에 가까이 위치되어 상기 본체의 벽을 따라 상기 호퍼 입구 가까이 이르도록 연장되어 배치되며;an inlet pipe for introducing the molten waste synthetic resin from the melting furnace, the inlet pipe being positioned close to the wall of the main body and extending along the wall of the main body to reach close to the inlet of the hopper;
    상기 호퍼의 바닥면에 제공되며, 상기 폐합성수지 용융액에 함유되어 있던 것으로서 상기 호퍼의 바닥면에 침강된 이물질을 제거하기 위한 이물질 이송수단; 및foreign matter transfer means provided on the bottom surface of the hopper and for removing foreign matter contained in the waste synthetic resin melt and deposited on the bottom surface of the hopper; and
    이물질이 제거된 상기 폐합성수지 용융액을 상기 가열설비 쪽으로 보내기 위한 토출구;를 포함하는 이물질 제거설비를 더 포함하는,Further comprising a foreign matter removal facility including a discharge port for sending the melted waste synthetic resin from which foreign substances are removed toward the heating facility,
    폐합성수지의 유화장치.Waste synthetic resin emulsification device.
  5. 제4항에 있어서, According to claim 4,
    상기 이물질 제거설비는 상기 본체에 배치되는 복수의 침강판들을 더 포함하며, 상기 유입파이프를 통해 유입된 상기 폐합성수지 용융액이 상기 본체 내부에서 흐르면서 상기 토출구로 토출되기까지 상기 폐합성수지 용융액이 상기 복수의 침강판들 사이를 월류 및 충돌하면서 흐르도록 상기 복수의 침강판들을 상기 본체에 배치하는,The foreign matter removal device further includes a plurality of settling plates disposed in the main body, and the waste synthetic resin melt flowing in through the inlet pipe flows inside the main body and is discharged through the discharge port until the waste synthetic resin melt is discharged through the plurality of sedimentation plates. Arranging the plurality of sedimentation plates in the main body to flow while overflowing and colliding between the sedimentation plates,
    폐합성수지의 유화장치.Waste synthetic resin emulsification device.
  6. 제5항에 있어서, According to claim 5,
    상기 침강판들은 수평방향으로 순서대로 배열되는 제1, 제2, 및 제3 침강판을 포함하며;The settling plates include first, second, and third settling plates sequentially arranged in a horizontal direction;
    상기 제1 침강판 및 제3 침강판 각각은, 상기 본체의 상기 호퍼의 바닥면을 가로질러 고정되는 하단부와 상기 하단부로부터 상기 본체 상부 쪽으로 연장되는 가로면과 상기 본체에 고정되지 않은 상태로 상기 유입파이프 쪽으로 굽은 자유단부를 포함하며;Each of the first sinking plate and the third sinking plate has a lower end fixed across the bottom surface of the hopper of the main body and a transverse surface extending from the lower end toward the upper part of the main body, and the inlet in a state that is not fixed to the main body. a free end bent towards the pipe;
    상기 제2 침강판은 상기 본체의 상기 호퍼의 바닥면으로부터 이격되어 상기 본체에 고정되고, 또한 상기 제1 및 제3 침강판과 각각 이격되어 배치되며;the second sinking plate is spaced apart from the bottom surface of the hopper of the main body and fixed to the main body, and is also disposed separately from the first and third sinking plates;
    여기서, 상기 폐합성수지 용융액은 상기 제1 침강판을 월류하여 흐른 다음 상기 제2 침강판에 충돌한 후 상기 호퍼의 하부를 통해 흐른 다음 상기 제3 침강판을 따라 월류하여 흐르는,Here, the waste synthetic resin melt overflows the first settling plate, collides with the second settling plate, flows through the lower part of the hopper, and then flows along the third settling plate.
    폐합성수지의 유화장치.Waste synthetic resin emulsification device.
  7. 제4항에 있어서, According to claim 4,
    상기 이물질 제거설비가 상기 본체의 외부를 전체적으로 둘러쌈으로써 상기 본체에 이중 자켓 구조를 형성하기 위한 외벽을 더 포함하며,The foreign matter removal device further includes an outer wall for forming a double jacket structure in the main body by entirely surrounding the outside of the main body,
    상기 가열설비로부터 배출되는 고온의 배기가스를 상기 이중 자켓에 공급하여 상기 본체 내부를 흐르는 상기 폐합성수지 용융액의 온도를 승온시킴으로써 상기 폐합성수지 용융액에 함유된 염소 가스를 탈염시키는,Desalting chlorine gas contained in the waste synthetic resin melt by supplying high-temperature exhaust gas discharged from the heating facility to the double jacket to raise the temperature of the waste synthetic resin melt flowing inside the main body;
    폐합성수지의 유화장치.Waste synthetic resin emulsification device.
  8. 제5항에 있어서,According to claim 5,
    상기 이물질 제거설비가 상기 본체의 외부를 전체적으로 둘러쌈으로써 상기 본체에 이중 자켓 구조를 형성하기 위한 외벽을 더 포함하며,The foreign matter removal device further includes an outer wall for forming a double jacket structure in the main body by entirely surrounding the outside of the main body,
    상기 가열설비로부터 배출되는 고온의 배기가스를 상기 이중 자켓에 공급하여 상기 본체 내부를 흐르는 상기 폐합성수지 용융액의 온도를 승온시킴으로써 상기 폐합성수지 용융액에 함유된 염소 가스를 탈염시키는,Desalting chlorine gas contained in the waste synthetic resin melt by supplying high-temperature exhaust gas discharged from the heating facility to the double jacket to raise the temperature of the waste synthetic resin melt flowing inside the main body;
    폐합성수지의 유화장치.Waste synthetic resin emulsification device.
  9. 제1항에 있어서,According to claim 1,
    상기 가열기의 상기 수관식 열교환기는, 한 쌍의 헤더, 및 상기 한 쌍의 헤더 사이에 각각의 양끝단부가 연결되어 연통되도록 서로 이격되어 배치되는 복수의 파이프들을 포함하며;The water-tube heat exchanger of the heater includes a pair of headers and a plurality of pipes disposed spaced apart from each other so that both ends are connected and communicated between the pair of headers;
    여기서, 상기 용융로로부터 공급되는 상기 폐합성수지 용융액은, 상기 수관식 열교환기의 상기 한 쌍의 헤더와 상기 파이프들 내부를 통과하는 동안 상기 열풍로로부터 공급되는 고온의 열풍과의 사이에서 열교환을 얻게 되며, 상기 열교환을 통해 상기 폐합성수지 용융액으로부터 오일 성분을 추출하기 적합한 온도로 상기 폐합성수지 용융액을 승온시키는,Here, the waste synthetic resin melt supplied from the melting furnace obtains heat exchange between the pair of headers of the water tube heat exchanger and the high-temperature hot air supplied from the hot air furnace while passing through the inside of the pipes. raising the temperature of the waste synthetic resin melt to a temperature suitable for extracting an oil component from the waste synthetic resin melt through the heat exchange;
    폐합성수지의 유화장치.Waste synthetic resin emulsification device.
  10. 제9항에 있어서,According to claim 9,
    펌핑수단을 더 포함하며;further comprising a pumping means;
    상기 가열기의 상기 열교환기로부터 상기 열분해로에 투입된 상기 폐합성수지 용융액 중에서 상기 열분해로에서 열분해가 진행되면서 온도가 떨어져 침전된 폐합성수지 용융액을 상기 용융로에 상기 펌핑수단으로 펌핑시켜 공급함으로써 상기 용융로 내에 있는 상기 고체상의 폐합성수지를 함침시켜 용융시키는,Among the melted waste synthetic resins introduced into the pyrolysis furnace from the heat exchanger of the heater, as thermal decomposition progresses in the pyrolysis furnace, the molten waste synthetic resin precipitated is pumped and supplied to the melting furnace by the pumping means to supply the melted waste synthetic resin to the melting furnace. Impregnating and melting solid waste synthetic resin,
    폐합성수지의 유화장치.Waste synthetic resin emulsification device.
  11. 제1항에 있어서,According to claim 1,
    상기 가열설비의 상기 가열기는 제1 및 제2 수관식 열교환기를 더 포함하며;The heater of the heating equipment further includes first and second water-tube heat exchangers;
    상기 제1 및 제2 열교환기 각각은 한 쌍의 헤더, 및 상기 한 쌍의 헤더 사이에 각각의 양끝단부가 연결되어 연통되도록 서로 이격되어 배치되는 복수의 파이프들을 포함하며;Each of the first and second heat exchangers includes a pair of headers and a plurality of pipes disposed spaced apart from each other so that both ends are connected and communicated between the pair of headers;
    여기서, 상기 용융로로부터 공급되는 상기 폐합성수지 용융액은 상기 제1 열교환기로 공급되어 통과하는 동안 상기 열풍로로부터 공급되는 고온의 열풍과의 사이에서 열교환을 얻게 되며, 상기 열교환을 통해 상기 폐합성수지 용융액으로부터 오일 성분을 추출하기 적합한 온도로 상기 폐합성수지 용융액을 승온되어 상기 열분해로로 투입되며;Here, while the waste synthetic resin melt supplied from the melting furnace is supplied to and passed through the first heat exchanger, heat is exchanged with the high-temperature hot air supplied from the hot air furnace, and through the heat exchange, oil from the waste synthetic resin melt is exchanged. The temperature of the waste synthetic resin melt is raised to a temperature suitable for extracting components and introduced into the thermal decomposition furnace;
    여기서, 상기 제1 열교환기로부터 공급되는 상기 폐합성수지 용융액이 상기 열분해로에서 열분해되는 동안 온도가 떨어져 침전된 폐합성수지 용융액은 상기 제2 열교환기로 공급되어 승온된 다음 다시 상기 열분해로로 재투입되어 열분해가 진행되는,Here, while the molten waste synthetic resin supplied from the first heat exchanger is pyrolyzed in the pyrolysis furnace, the molten waste synthetic resin precipitated due to a drop in temperature is supplied to the second heat exchanger, raised in temperature, and then reintroduced into the pyrolysis furnace for thermal decomposition. is going on,
    폐합성수지의 유화장치.Waste synthetic resin emulsification device.
  12. 고체상의 폐합성수지 및 고온의 오일을 공급받아 상기 고체상의 폐합성수지를 상기 고온의 오일에 함침시켜 상기 고체상의 폐합성수지를 용융하기 위한 용융로;a melting furnace receiving solid waste synthetic resin and high-temperature oil and impregnating the solid waste synthetic resin into the high-temperature oil to melt the solid waste synthetic resin;
    하부에 형성되는 호퍼를 포함하는 본체, 상기 본체의 벽에 가까이 위치되어 상기 본체의 벽을 따라 상기 호퍼 입구 가까이 이르도록 연장되어 배치되며 상기 용융로로부터 상기 폐합성수지 용융액을 유입시키기 위한 유입파이프, 상기 호퍼의 바닥면에 제공되며, 상기 폐합성수지 용융액에 함유되어 있던 것으로서 상기 호퍼의 바닥면에 침강된 이물질을 제거하기 위한 이물질 이송수단, 및 이물질이 제거된 상기 폐합성수지 용융액을 상기 가열설비 쪽으로 보내기 위한 토출구를 포함하는 이물질 제거설비;A main body including a hopper formed at a lower portion thereof, an inlet pipe positioned close to a wall of the main body and extending along the wall of the main body to reach an inlet of the hopper and introducing the molten waste synthetic resin from the melting furnace, the hopper provided on the bottom surface of the waste synthetic resin melt, and a foreign material transfer means for removing foreign matter contained in the waste synthetic resin melt and settling on the bottom surface of the hopper, and a discharge port for sending the waste synthetic resin melt from which the foreign matter is removed toward the heating facility. Foreign matter removal equipment including;
    상기 이물질 제거설비로부터 공급되는 상기 폐합성수지 용융액이 통과되면서 열교환이 이루어지는 수관식 열교환기를 포함하는 가열기, 및 고온의 열풍을 상기 가열기에 공급하여 상기 수관식 열교환기를 통과하는 상기 폐합성수지 용융액과의 사이에 열교환이 발생하도록 함으로써 상기 폐합성수지 용융액을 열분해시키기 적합한 온도로 승온시키기 위한 열풍로를 포함하는 가열설비; 및Between a heater including a water tube heat exchanger in which heat is exchanged while passing the melt of waste synthetic resin supplied from the foreign matter removal facility, and the melt of waste synthetic resin passing through the water tube heat exchanger by supplying high-temperature hot air to the heater a heating facility including a hot stove for raising the temperature of the waste synthetic resin melt to a temperature suitable for thermal decomposition by causing heat exchange; and
    상기 가열설비로부터 공급받은 열분해에 적합한 온도로 승온된 상기 폐합성수지 용융액을 열분해함으로써 오일 성분을 함유한 유증기와 가연성 가스 성분으로 전환시키기 위한 열분해로;를 포함하는 A thermal decomposition furnace for converting the waste synthetic resin melt supplied from the heating facility into oil vapor and combustible gas components by thermally decomposing the waste synthetic resin melt heated to a temperature suitable for thermal decomposition;
    폐합성수지의 유화장치.Waste synthetic resin emulsification device.
  13. 제12항에 있어서,According to claim 12,
    상기 이물질 제거설비는 상기 본체에 배치되는 복수의 침강판들을 더 포함하며, 상기 유입파이프를 통해 유입된 상기 폐합성수지 용융액이 상기 본체 내부에서 흐르면서 상기 토출구로 토출되기까지 상기 폐합성수지 용융액이 상기 복수의 침강판들 사이를 월류 및 충돌하면서 흐르도록 상기 복수의 침강판들을 상기 본체에 배치하는,The foreign matter removal device further includes a plurality of settling plates disposed in the main body, and the waste synthetic resin melt flowing in through the inlet pipe flows inside the main body and is discharged through the discharge port until the waste synthetic resin melt is discharged through the plurality of sedimentation plates. Arranging the plurality of sedimentation plates in the main body to flow while overflowing and colliding between the sedimentation plates,
    폐합성수지의 유화장치.Waste synthetic resin emulsification device.
  14. 제13항에 있어서, According to claim 13,
    상기 침강판들은 수평방향으로 순서대로 배열되는 제1, 제2, 및 제3 침강판을 포함하며;The settling plates include first, second, and third settling plates sequentially arranged in a horizontal direction;
    상기 제1 침강판 및 제3 침강판 각각은, 상기 본체의 상기 호퍼의 바닥면을 가로질러 고정되는 하단부와 상기 하단부로부터 상기 본체 상부 쪽으로 연장되는 가로면과 상기 본체에 고정되지 않은 상태로 상기 유입파이프 쪽으로 굽은 자유단부를 포함하며;Each of the first sinking plate and the third sinking plate has a lower end fixed across the bottom surface of the hopper of the main body and a transverse surface extending from the lower end toward the upper part of the main body, and the inlet in a state that is not fixed to the main body. a free end bent towards the pipe;
    상기 제2 침강판은 상기 본체의 상기 호퍼의 바닥면으로부터 이격되어 상기 본체에 고정되고, 또한 상기 제1 및 제3 침강판과 각각 이격되어 배치되며;the second sinking plate is spaced apart from the bottom surface of the hopper of the main body and fixed to the main body, and is also disposed separately from the first and third sinking plates;
    여기서, 상기 폐합성수지 용융액은 상기 제1 침강판을 월류하여 흐른 다음 상기 제2 침강판에 충돌한 후 상기 호퍼의 하부를 통해 흐른 다음 상기 제3 침강판을 따라 월류하여 흐르는,Here, the waste synthetic resin melt overflows the first settling plate, collides with the second settling plate, flows through the lower part of the hopper, and then flows along the third settling plate.
    폐합성수지의 유화장치.Waste synthetic resin emulsification device.
  15. 제12항에 있어서, According to claim 12,
    상기 이물질 제거설비가 상기 본체의 외부를 전체적으로 둘러쌈으로써 상기 본체에 이중 자켓 구조를 형성하기 위한 외벽을 더 포함하며,The foreign matter removal device further includes an outer wall for forming a double jacket structure in the main body by entirely surrounding the outside of the main body,
    상기 가열설비로부터 배출되는 고온의 배기가스를 상기 이중 자켓에 공급하여 상기 본체 내부를 흐르는 상기 폐합성수지 용융액의 온도를 승온시킴으로써 상기 폐합성수지 용융액에 함유된 염소 가스를 탈염시키는,Desalting chlorine gas contained in the waste synthetic resin melt by supplying high-temperature exhaust gas discharged from the heating facility to the double jacket to raise the temperature of the waste synthetic resin melt flowing inside the main body;
    폐합성수지의 유화장치.Waste synthetic resin emulsification device.
  16. 제12항에 있어서,According to claim 12,
    상기 가열기의 상기 수관식 열교환기는, 한 쌍의 헤더, 및 상기 한 쌍의 헤더 사이에 각각의 양끝단부가 연결되어 연통되도록 서로 이격되어 배치되는 복수의 파이프들을 포함하며;The water-tube heat exchanger of the heater includes a pair of headers and a plurality of pipes disposed spaced apart from each other so that both ends are connected and communicated between the pair of headers;
    여기서, 상기 이물질 제거설비로부터 공급되는 상기 폐합성수지 용융액은, 상기 수관식 열교환기의 상기 한 쌍의 헤더와 상기 파이프들 내부를 통과하는 동안 상기 열풍로로부터 공급되는 고온의 열풍과의 사이에서 열교환을 얻게 되며, 상기 열교환을 통해 상기 폐합성수지 용융액으로부터 오일 성분을 추출하기 적합한 온도로 상기 폐합성수지 용융액을 승온시키는,Here, the waste synthetic resin molten liquid supplied from the foreign matter removal facility undergoes heat exchange between the pair of headers of the water-tube heat exchanger and the high-temperature hot air supplied from the hot stove while passing through the inside of the pipes. and raising the temperature of the waste synthetic resin melt to a temperature suitable for extracting an oil component from the waste synthetic resin melt through the heat exchange.
    폐합성수지의 유화장치.Waste synthetic resin emulsification device.
  17. 제12항에 있어서,According to claim 12,
    상기 가열설비의 상기 가열기는 제1 및 제2 수관식 열교환기를 더 포함하며;The heater of the heating equipment further includes first and second water-tube heat exchangers;
    상기 제1 및 제2 열교환기 각각은 한 쌍의 헤더, 및 상기 한 쌍의 헤더 사이에 각각의 양끝단부가 연결되어 연통되도록 서로 이격되어 배치되는 복수의 파이프들을 포함하며;Each of the first and second heat exchangers includes a pair of headers and a plurality of pipes disposed spaced apart from each other so that both ends are connected and communicated between the pair of headers;
    여기서, 상기 이물질 제거설비로부터 공급되는 상기 폐합성수지 용융액은 상기 제1 열교환기로 공급되어 통과하는 동안 상기 열풍로로부터 공급되는 고온의 열풍과의 사이에서 열교환을 얻게 되며, 상기 열교환을 통해 상기 폐합성수지 용융액으로부터 오일 성분을 추출하기 적합한 온도로 상기 폐합성수지 용융액을 승온되어 상기 열분해로로 투입되며;Here, while the waste synthetic resin melt supplied from the foreign matter removal facility is supplied to and passes through the first heat exchanger, heat is exchanged with the high-temperature hot air supplied from the hot air furnace, and the waste synthetic resin melt is supplied through the heat exchange. raising the temperature of the waste synthetic resin melt to a temperature suitable for extracting an oil component from the melt and introducing it into the pyrolysis furnace;
    여기서, 상기 제1 열교환기로부터 공급된 상기 폐합성수지 용융액이 상기 열분해로에서 열분해되는 동안 온도가 떨어져 침전된 폐합성수지 용융액은 상기 제2 열교환기로 공급되어 승온된 다음 다시 상기 열분해로로 재투입되어 열분해가 진행되는,Here, while the waste synthetic resin melt supplied from the first heat exchanger is pyrolyzed in the pyrolysis furnace, the waste synthetic resin molten solution precipitated due to a drop in temperature is supplied to the second heat exchanger, raised in temperature, and then reintroduced into the pyrolysis furnace for thermal decomposition. is going on,
    폐합성수지의 유화장치.Waste synthetic resin emulsification device.
PCT/KR2021/007048 2021-05-14 2021-06-04 Apparatus for producing oil with waste synthetic resin WO2022239902A1 (en)

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JP2622933B2 (en) * 1993-08-03 1997-06-25 日立造船株式会社 Liquefaction of oil vapor from waste plastic melt
KR20020095289A (en) * 2001-06-14 2002-12-26 (주)코엔텍 CRACKING PROCESS and EQUIPMENT for The Plastic WASTE
KR20050115383A (en) * 2004-06-03 2005-12-07 주식회사 삼신기계 Apparatus and method for emulsifying waste synthetic resin capable of increasing recovery rate by accelerated degradation process
JP3839709B2 (en) * 2001-09-07 2006-11-01 株式会社荏原製作所 Gas supply device, gas supply utilization system, gasification and melting system, and gas supply method
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JP2622933B2 (en) * 1993-08-03 1997-06-25 日立造船株式会社 Liquefaction of oil vapor from waste plastic melt
KR20020095289A (en) * 2001-06-14 2002-12-26 (주)코엔텍 CRACKING PROCESS and EQUIPMENT for The Plastic WASTE
JP3839709B2 (en) * 2001-09-07 2006-11-01 株式会社荏原製作所 Gas supply device, gas supply utilization system, gasification and melting system, and gas supply method
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