WO2022224765A1 - Insecticide composition for agricultural or horticultural use and use method therefor - Google Patents
Insecticide composition for agricultural or horticultural use and use method therefor Download PDFInfo
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- WO2022224765A1 WO2022224765A1 PCT/JP2022/015814 JP2022015814W WO2022224765A1 WO 2022224765 A1 WO2022224765 A1 WO 2022224765A1 JP 2022015814 W JP2022015814 W JP 2022015814W WO 2022224765 A1 WO2022224765 A1 WO 2022224765A1
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- IHNSIFFSNUQGQN-UHFFFAOYSA-N tioxazafen Chemical compound C1=CSC(C=2ON=C(N=2)C=2C=CC=CC=2)=C1 IHNSIFFSNUQGQN-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- OBZIQQJJIKNWNO-UHFFFAOYSA-N tolclofos-methyl Chemical group COP(=S)(OC)OC1=C(Cl)C=C(C)C=C1Cl OBZIQQJJIKNWNO-UHFFFAOYSA-N 0.000 description 1
- WPALTCMYPARVNV-UHFFFAOYSA-N tolfenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(OC=3C=CC(C)=CC=3)=CC=2)=C1Cl WPALTCMYPARVNV-UHFFFAOYSA-N 0.000 description 1
- RSOBJVBYZCMJOS-CYBMUJFWSA-N tolprocarb Chemical compound FC(F)(F)COC(=O)N[C@@H](C(C)C)CNC(=O)C1=CC=C(C)C=C1 RSOBJVBYZCMJOS-CYBMUJFWSA-N 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical class CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- HYVWIQDYBVKITD-UHFFFAOYSA-N tolylfluanid Chemical compound CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)C1=CC=C(C)C=C1 HYVWIQDYBVKITD-UHFFFAOYSA-N 0.000 description 1
- XNFIRYXKTXAHAC-UHFFFAOYSA-N tralopyril Chemical compound BrC1=C(C(F)(F)F)NC(C=2C=CC(Cl)=CC=2)=C1C#N XNFIRYXKTXAHAC-UHFFFAOYSA-N 0.000 description 1
- XMLSXPIVAXONDL-UHFFFAOYSA-N trans-jasmone Natural products CCC=CCC1=C(C)CCC1=O XMLSXPIVAXONDL-UHFFFAOYSA-N 0.000 description 1
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 1
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 description 1
- AMFGTOFWMRQMEM-UHFFFAOYSA-N triazophos Chemical compound N1=C(OP(=S)(OCC)OCC)N=CN1C1=CC=CC=C1 AMFGTOFWMRQMEM-UHFFFAOYSA-N 0.000 description 1
- IQGKIPDJXCAMSM-UHFFFAOYSA-N triazoxide Chemical compound N=1C2=CC=C(Cl)C=C2[N+]([O-])=NC=1N1C=CN=C1 IQGKIPDJXCAMSM-UHFFFAOYSA-N 0.000 description 1
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 1
- QFNFRZHOXWNWAQ-UHFFFAOYSA-N triclopyricarb Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NC(Cl)=C(Cl)C=C1Cl QFNFRZHOXWNWAQ-UHFFFAOYSA-N 0.000 description 1
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 description 1
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 description 1
- HSMVPDGQOIQYSR-KGENOOAVSA-N triflumizole Chemical compound C1=CN=CN1C(/COCCC)=N/C1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-KGENOOAVSA-N 0.000 description 1
- XAIPTRIXGHTTNT-UHFFFAOYSA-N triflumuron Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl XAIPTRIXGHTTNT-UHFFFAOYSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- RROQIUMZODEXOR-UHFFFAOYSA-N triforine Chemical compound O=CNC(C(Cl)(Cl)Cl)N1CCN(C(NC=O)C(Cl)(Cl)Cl)CC1 RROQIUMZODEXOR-UHFFFAOYSA-N 0.000 description 1
- YNWVFADWVLCOPU-MAUPQMMJSA-N uniconazole P Chemical compound C1=NC=NN1/C([C@@H](O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MAUPQMMJSA-N 0.000 description 1
- 241000701447 unidentified baculovirus Species 0.000 description 1
- JARYYMUOCXVXNK-IMTORBKUSA-N validamycin Chemical compound N([C@H]1C[C@@H]([C@H]([C@H](O)[C@H]1O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)CO)[C@H]1C=C(CO)[C@H](O)[C@H](O)[C@H]1O JARYYMUOCXVXNK-IMTORBKUSA-N 0.000 description 1
- DBXFMOWZRXXBRN-LWKPJOBUSA-N valifenalate Chemical compound CC(C)OC(=O)N[C@@H](C(C)C)C(=O)NC(CC(=O)OC)C1=CC=C(Cl)C=C1 DBXFMOWZRXXBRN-LWKPJOBUSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 230000003612 virological effect Effects 0.000 description 1
- 239000000664 voltage gated sodium channel blocking agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
- FJBGIXKIXPUXBY-UHFFFAOYSA-N {2-[3-(4-chlorophenyl)propyl]-2,4,4-trimethyl-1,3-oxazolidin-3-yl}(imidazol-1-yl)methanone Chemical compound C1=CN=CN1C(=O)N1C(C)(C)COC1(C)CCCC1=CC=C(Cl)C=C1 FJBGIXKIXPUXBY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P7/00—Arthropodicides
- A01P7/04—Insecticides
Definitions
- the present invention relates to an agricultural and horticultural insecticide composition characterized by containing Nitenpyram (hereinafter referred to as compound (II)) as an active ingredient, and a method for using the same.
- compound (II) Nitenpyram
- the present invention also relates to a method for controlling agricultural and horticultural pests by using the above two compounds in combination.
- Compound (I) used as an active ingredient in the agricultural and horticultural insecticide composition of the present invention is a known compound (see Patent Document 1), and is useful as a pest control agent in combination with other agricultural chemical active ingredients. have been reported (see Patent Document 2).
- Compound (II) is also a known compound, and its insecticidal activity has been reported (see Non-Patent Document 1). Compound (II) is also known to exhibit control activity against planthoppers in combination with other agents (see Patent Document 3).
- Patent Document 3 none of the prior art documents describes or suggests the agricultural and horticultural insecticide composition of the present invention relating to the combination of compound (I) and compound (II).
- An object of the present invention is to provide an insecticide composition having an excellent control effect against agricultural and horticultural pests such as various pests and mites. That is, the problem to be solved by the present invention is that, in the treatment of compound (I) or compound (II) alone, the difference in effect due to the type, growth stage, habitat characteristics, etc. of target pests, etc., and resistance Effective control may not be possible due to reasons such as development, usage amount, and restrictions on the number of times of control. Therefore, new means and methods for efficiently controlling agricultural and horticultural pests such as various pests and mites that are impossible or difficult to control by single treatment with compound (I) or compound (II). is required.
- compound (I) and compound (II) can be used in combination to efficiently control various agricultural and horticultural pests. and completed the present invention.
- At least the present invention relates to each of the following inventions.
- an effective amount of the agricultural and horticultural insecticide composition according to [1] or [2] is applied to target pests, target useful plants, and target useful plants.
- a method of using an agricultural and horticultural insecticide composition characterized in that it is applied to seeds, soil or cultivation carriers, [4] 5-(1,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine and (1E)-N1-[(6-chloropyridin-3-yl)methyl ] -N1-ethyl-N'1-methyl-2-nitrovinylidene-1,1-diamine separately applied to plants or cultivation carriers at the same time, A method for controlling agricultural and horticultural pests, [5] 5-(1,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine and (1E)-N1-[(
- the agricultural and horticultural insecticide composition of the present invention By using the agricultural and horticultural insecticide composition of the present invention, it is possible to expand the range of insect pests to be controlled and to reduce the dosage of each active ingredient compound, and each alone can provide sufficient effects. Significant effects can be obtained even at dosages that were not recommended. Therefore, the agricultural and horticultural insecticide composition of the present invention is effective against various agricultural and horticultural pests that could not be controlled by the above active ingredients alone, and agricultural and horticultural pests such as insect pests and mites that exhibit chemical resistance. However, it has a remarkable control effect. In addition, the agricultural and horticultural insecticide composition of the present invention is excellent in residual effect, and can improve the efficiency of agricultural work by reducing the frequency of spraying. Furthermore, it is also possible to prevent the development of resistance to agricultural and horticultural pests.
- composition of the present invention has the following formula [I]:
- Compound (II) represented by (agricultural chemical generic name: nitenpyram, chemical name: (1E)-N1-[(6-chloropyridin-3-yl)methyl]-N1-ethyl-N'1-methyl-2-nitro It contains vinylidene-1,1-diamine, CAS registration number: 150824-47-8) as an active ingredient.
- the compound (I) contained as an active ingredient in the composition of the present invention can be produced by the production method disclosed in the aforementioned Patent Document 1.
- Compound (II) contained as the other active ingredient in the composition of the present invention can be used as is as a commercially available product (for example, best guard (registered trademark) water solvent).
- the compound (II) can be purchased from an agricultural chemical technical substance supplier and formulated.
- Salts of these compounds, which are equivalents of compound (I) or compound (II) include inorganic acid salts such as hydrochlorides, sulfates, nitrates, phosphates, acetates, fumarates, and maleic acid. Salts, organic acid salts such as oxalates, methanesulfonates, benzenesulfonates, p-toluenesulfonates, etc. can be mentioned, and such salts can also be produced according to methods known per se.
- the content of the active ingredient in 100 parts by mass of the composition is usually 0.01 part by mass to 80 parts by mass, preferably It is 0.1 to 50 parts by mass, more preferably 0.5 to 20 parts by mass.
- the content ratio of compound (I) and compound (II) in the active ingredient is usually 0.01 to 2000 parts by mass of compound (II) per 1 part by mass of compound (I). , preferably 0.05 to 100 parts by mass, more preferably 0.1 to 30 parts by mass.
- the amount of compound (II) is 0.1 to 10 parts by mass per 1 part by mass of compound (I).
- composition of the present invention When the composition of the present invention is used, it is generally used as a formulation in a dosage form convenient for use in accordance with conventional methods for agricultural chemical formulations. That is, compound (I) and compound (II) used in the composition of the present invention are blended in a suitable inert carrier, optionally together with an adjuvant, in an appropriate proportion, dissolved, dispersed, or suspended. , mixed, or impregnated, adsorbed or attached to an appropriate dosage form such as suspension, emulsion suspension, emulsion, liquid, wettable powder, wettable granules, granules, powders, tablets, packs It may be used after being formulated into a drug or the like. Where appropriate, other dosage forms may be combined, incorporated and mixed.
- kneaded granules and impregnated granules may be mixed, wettable powders and wettable granules may be mixed and solidified as tablets, suspensions and liquids may be combined to form packs and the like.
- kneaded granules and impregnated granules may be mixed, wettable powders and wettable granules may be mixed and solidified as tablets, suspensions and liquids may be combined to form packs and the like.
- the inert carrier examples include solid carriers and liquid carriers.
- Solid carriers include, for example, kaolinite (kaolin), sericite, clay minerals such as talc, bentonite, acid clay, clay such as attapulgite.
- Minerals such as quartz, pyrophyllite, zeolite, diatomaceous earth; inorganic salts such as calcium carbonate, ammonium sulfate, sodium sulfate, potassium chloride; synthetic silicic acid and synthetic silicates such as precipitated silica, fumed silica, calcium silicate; starch , cellulose, vegetable powder (e.g., sawdust, coconut shell, corn cob, tobacco stalk, etc.); plastic resin carriers such as polyethylene, polypropylene, polystyrene, polyvinylidene chloride, polyethylene terephthalate; urea-aldehyde resins, etc. thermosetting resins; porous granular carriers such as perlite and vermiculite; plastic hollow bodies; These may
- liquid carriers examples include monohydric alcohols such as methanol, ethanol, propanol, isopropanol and butanol, and polyhydric alcohols such as ethylene glycol, diethylene glycol, propylene glycol, hexylene glycol, polyethylene glycol, polypropylene glycol and glycerin.
- monohydric alcohols such as methanol, ethanol, propanol, isopropanol and butanol
- polyhydric alcohols such as ethylene glycol, diethylene glycol, propylene glycol, hexylene glycol, polyethylene glycol, polypropylene glycol and glycerin.
- polyhydric alcohol derivatives such as propylene glycol ether; ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, and cyclohexanone; ethers such as ethyl ether, dioxane, ethylene glycol monoethyl ether, dipropyl ether, and tetrahydrofuran Aliphatic hydrocarbons such as normal paraffin, naphthene, isoparaffin, kerosene and mineral oil; Aromatic hydrocarbons such as benzene, toluene, xylene, solvent naphtha and alkylnaphthalene; Halogenation such as dichloromethane, chloroform and carbon tetrachloride Hydrocarbons; esters such as ethyl acetate, diisopropyl phthalate, dibutyl phthalate, dioctyl phthalate, dimethyl a
- Auxiliaries include dispersants, wetting agents, spreaders, spreading agents, binders, tackifiers, thickeners, colorants, stabilizers, disintegrants, anti-drift agents, and the like.
- plant pieces or the like may be used as additive components. These additive components may be used alone or in combination of two or more.
- polyhydric alcohols such as glycerin, polyethylene glycol, and sorbitol
- water-soluble polymers such as sodium polyacrylate
- nonionic surfactants etc.
- extenders include silicone-based surfactants, cellulose powder, dextrin, modified starch, polyaminocarboxylic acid chelate compounds, and half esters of polyhydric alcohol polymers and dicarboxylic acid anhydrides.
- spreading agents include various surfactants, terpenes, polyamide resins, higher fatty acid esters of polyoxyethylene-polyoxypropylene glycol, polyacrylates, waxes, and polyvinyl alkyl ethers.
- surfactants used as dispersing agents, wetting agents, spreading agents, and spreading agents include sorbitan fatty acid esters, polyoxyethylene sorbitan fatty acid esters, sucrose fatty acid esters, polyoxyethylene fatty acid esters, poly Oxyethylene resin acid esters, polyoxyethylene fatty acid diesters, polyoxyethylene alkyl ethers, polyoxyethylene alkylaryl ethers such as polyoxyethylene alkylphenyl ethers, polyoxyethylene dialkylphenyl ethers, polyoxyethylene alkylphenyl ether formalin condensates, Polyoxyethylene polyoxypropylene block copolymer, polystyrene polyoxyethylene block polymer, alkyl polyoxyethylene polypropylene block copolymer ether, polyoxyethylene alkylamine, polyoxyethylene fatty acid amide, polyoxyethylene fatty acid bisphenyl ether, polyoxyalkylene benzylphenyl Silicone surfactants such as ether, polyoxyalkylene styryl
- Alkyl sulfates polyoxyethylene alkyl ether sulfates, polyoxyethylene alkylphenyl ether sulfates, polyoxyethylene styrylphenyl ether sulfates, alkylbenzenesulfonates, alkylarylsulfonates, ligninsulfonates, alkyl sulfosuccinates , naphthalenesulfonates, alkylnaphthalenesulfonates, salts of formalin condensates of naphthalenesulfonic acid, salts of formalin condensates of alkylnaphthalenesulfonic acids, fatty acid salts, polycarboxylates, polyacrylates, N-methyl- anionic surfactants such as fatty acid sarcosinates, resinates, polyoxyethylene alkyl ether phosphates, polyoxyethylene alkylphenyl ether phosphates;
- Cationic surfactants such as alkylamine salts such as laurylamine hydrochloride, stearylamine hydrochloride, oleylamine hydrochloride, stearylamine acetate, stearylaminopropylamine acetate, alkyltrimethylammonium chloride, alkyldimethylbenzalkonium chloride; and amphoteric surfactants such as betaine-type or betaine-type surfactants. These surfactants may be used alone or in combination of two or more.
- binders or tackifiers include sugars such as sucrose; polysaccharides such as dextrin, water-soluble starch, modified starch, gum arabic, xanthan gum and guar gum; cellulose and derivatives such as cellulose powder, carboxymethylcellulose and salts thereof.
- Phospholipids such as cephalin and lecithin; Polyvinyl alcohol, polyvinyl alkyl ether, polyvinyl acetate, polyvinylpyrrolidone, crosslinked polyvinylpyrrolidone, polyacrylates such as sodium polyacrylate, polyethylene glycol having an average molecular weight of 6,000 to 20,000, and an average molecular weight of 100,000 -5 million polyethylene glycol, polyaminocarboxylic acid chelate compound, copolymer of maleic acid and styrenes, (meth)acrylic acid copolymer, half ester of polyhydric alcohol polymer and dicarboxylic anhydride, Water-soluble salts of polystyrene sulfonic acid, polyamide resins, alkylphenol-formalin condensates, polymers such as synthetic resin emulsions; paraffins, terpenes, waxes, and the like.
- thickeners examples include polysaccharides such as xanthan gum, guar gum, diyutan gum, and starch derivatives; water-soluble polymers such as carboxymethyl cellulose, polyvinylpyrrolidone, carboxyvinyl polymer, and acrylic polymers; fumed silica, white carbon) and other inorganic fine powders.
- coloring agents include inorganic pigments such as iron oxide, titanium oxide, and Prussian blue; organic pigments such as alizarin dyes, azo dyes, and metal phthalocyanine dyes.
- stabilizers include preservatives such as sodium benzoate, potassium sorbate, p-hydroxybenzoic acid ester, 1,2-benzothiazolin-3-one, and formalin solutions; Anti-caking agents such as starch, alginic acid, mannose, galactose, polyvinylpyrrolidone, fumed silica (white carbon), ester gum, petroleum resin; zeolite, quicklime, Decomposition of drying agents such as magnesium oxide, antioxidants such as phenol antioxidants, amine antioxidants, sulfur antioxidants, phosphoric acid antioxidants, and UV absorbers such as benzophenone UV absorbers. inhibitors and the like.
- Anti-caking agents such as starch, alginic acid, mannose, galactose, polyvinylpyrrolidone, fumed silica (white carbon), ester gum, petroleum resin
- zeolite, quicklime Decomposition of drying agents such as magnesium oxide, antioxidants such as phenol antioxidants, amine antioxidants, sulfur antioxidants
- Disintegrants include sodium tripolyphosphate, sodium hexametaphosphate, metal stearate, cellulose powder, dextrin, methacrylic acid ester copolymer, polyvinylpyrrolidone, polyaminocarboxylic acid chelate compound, sulfonated styrene/isobutylene/maleic anhydride copolymer. coalescence, starch-polyacrylonitrile graft copolymer, and the like.
- water-soluble polymers such as methyl cellulose, polyvinyl alcohol, and starch are used for emulsions, and polyisobutylene is used for oils.
- wettable powders polyethylene glycol, polypropylene glycol, glycerin, etc. are used, and as powders, petroleum resins, polystyrene, polyvinyl acetate, epoxy resins, etc. are used.
- activity enhancers such as metabolic degradation inhibitors such as piperonyl butoxide can also be used as necessary.
- composition of the present invention can also be used by mixing with insecticides, acaricides, fungicides, herbicides, plant growth regulators, fertilizers, etc. other than compound (I) and compound (II).
- Agents that can be mixed and used include compounds described in The Pesticide Manual (published by The British Crop Protection Council, 17th edition). More specifically, if it has insecticidal activity, fungicidal activity or herbicidal activity and is effective as an agricultural and horticultural insecticide, an agricultural and horticultural fungicide, an agricultural and horticultural biopesticide, or an agricultural and horticultural herbicide , can be used without particular limitation, for example, a. organophosphorus compounds, b. carbamate compounds, c.
- pyrethroid compounds d. phenylpyrazole compounds, e. nicotine and neonicotinoid compounds, f. tetronic acid and tetramic acid derivatives, g. diamide compounds, h. diacyl-hydrazine compounds, i. macrolide compounds, j. nereistoxin analogues, k. spinosyn compounds, l. semicarbazone compounds, m. compounds with insect growth regulating activity, n. Ingredients such as insecticidal proteins produced by microorganisms can be mentioned.
- organic phosphorous compounds compounds that act as acetylcholinesterase (AChE) inhibitors are preferably used.
- AChE acetylcholinesterase
- carbamate compounds compounds that act as acetylcholinesterase (AChE) inhibitors are preferably used.
- MIPC Isoprocarb
- Methiocarb Methiocarb
- Methomyl Metolcarb
- MTMC Metolcarb
- Oxamyl Pirimicarb
- PHC Propoxur
- Thiodicarb Thiophanox
- Triazamate Trimetacarb
- XMC 3,5-d
- pyrethroid compounds compounds that act as sodium channel modulators are preferably used. permethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, deltamethrin, etofenprox, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau-fluvalinate, halfenprox, permethrin, silafluofen, tefluthrin, tralomethrin, protrifenbute and the like.
- a compound that acts as a GABAergic chloride ion channel blocker is preferably used.
- Neonicotinoid compounds include, for example, imidacloprid, clothianidin, thiamethoxam, dinotefuran, acetamiprid, thiacloprid and the like.
- neonicotinoid compounds include sulphylimine S-oxide compounds such as sulfoxaflor that function as competitive nicotinic acetylcholine receptor (nAChR) modulators, butenolide compounds such as flupyradifuron, triflumesopyrim, and dichloromesotiaz. and other mesoionic compounds are also included.
- sulphylimine S-oxide compounds such as sulfoxaflor that function as competitive nicotinic acetylcholine receptor (nAChR) modulators
- butenolide compounds such as flupyradifuron, triflumesopyrim, and dichloromesotiaz.
- mesoionic compounds are also included.
- nicotine-based compounds include nicotine sulfate and the like.
- tetronic acid and tetramic acid derivatives compounds that act as acetyl-CoA carboxylase inhibitors are preferably used, and examples thereof include spirodiclofen, spiromesifen, and spirotetramato.
- a compound acting as a ryanodine receptor modulator is preferably used, and examples thereof include flubendiamide, chlorantraniliprole, cyantraniliprole, cyclaniliprole, cyhalodiamide, and tetraniliprole.
- diacyl-hydrazine compounds compounds that act as molting hormone (ecdysone) receptor agonists are preferably used.
- molting hormone ecdysone
- '-benzoyl-N-tert-butylbenzohydrazide tebufenozide and the like.
- GluCl glutamatergic chloride channel
- macrolide compounds compounds that act as glutamatergic chloride channel (GluCl) allosteric modulators are preferably used, and include abamectin, ivermectin, eprinomectin, emamectin, emamectin benzoate, selamectin, milbemectin, moxidectin, doramectin, lepimectin, and the like. is mentioned.
- nAChR nicotinic acetylcholine receptor
- spinosyn compounds compounds that act as nicotinic acetylcholine receptor (nAChR) allosteric modulators are preferably used, and examples thereof include spinetoram, spinosad and the like.
- nAChR nicotinic acetylcholine receptor
- semicarbazone compounds compounds that act as voltage-gated sodium channel blockers are preferably used, and examples thereof include indoxacarb and metaflumizone.
- Examples of compounds having an insect growth-regulating action include benzoyl urea compounds such as bistriflurone and chlorfluazurone, thiadiazinon compounds such as buprofezin, compounds acting as chordotonal modulators such as pymetrozine, flonicamid, and aphidopyropene, and pyrifluquinazone. be done.
- insecticidal proteins produced by microorganisms include Bacillus thuringiensis, for example, Bacillus thuringiensis aizawai, Bacillus thuringiensis israelensis, Bacillus thuringiensis ⁇ Crystalline protein toxins (Bt toxin insecticidal compounds) produced by Bacillus thuringienses japonensis, Bacillus thuringienses kurstaki, Bacillus thuringienses tenebrionis, etc. .
- Bacillus thuringiensis for example, Bacillus thuringiensis aizawai, Bacillus thuringiensis israelensis, Bacillus thuringiensis ⁇ Crystalline protein toxins (Bt toxin insecticidal compounds) produced by Bacillus thuringienses japonensis, Bacillus thuringienses kurstaki, Bacillus thuringienses tenebrionis, etc. .
- Active ingredient group A includes (A1) agricultural and horticultural insecticide group; 3,5-xylyl methylcarbamate (XMC), Bacillus thuringiensis: for example, Bacillus thuringiensis Bacillus thuringienses aizawai, Bacillus thuringienses israelensis, Bacillus thuringienses japonensis, Bacillus thuringienses kurstaki, Bacillus thuringiensis crystalline protein toxin (Bt toxin insecticidal compound) produced by Bacillus thuringienses tenebrionis, etc.), Methylcarbamic acid 2-sec-butylphenyl ester (BPMC), chlorfenson (CPCBS), Dichlorodiisopropyl ether (DCIP), 1,3-Dichloroprop
- A2 Fungicide group for agricultural and horticultural use aureofungin, azaconazole, azithiram, acypetacs, acibenzolar, acibenzolar S-methyl, azoxyst azoxystrobin, anilazine, amisulbrom, ampropylfos, ametoctradin, allyl alcohol, aldimorph, amobam, isotianil, isovarezione (isovaledione), isopyrazam, isofetamide, isoprothiolane, ipconazole, iprodione, iprovalicarb, iprobenfos, imazalil, iminoctadine, metam (metam), iminoctadine-triacetate, imibenconazole, uniconazole, uniconazole P, eclomezole, edifenphos, etaconazole, ethaboxam ), ethiri
- biopesticides In addition to the above agricultural and horticultural insecticides and agricultural and horticultural fungicides, further biopesticides can be used or utilized. Specific examples include Agrobacterium radiobacter strain K84 (e.g., "Galltrol-A (registered trademark)” manufactured by “AgBioChem, CA”), Agrobacterium radiobacter strain K1026 (e.g., “Nogall (registered trademark)” manufactured by “Becker Underwood, US”), Agrobacterium radiobacter strain 84 (e.g., "Nippon Nohyaku Co., Ltd.” "Bacteroses ( Agrobacterium spp., such as “Agrobacterium spp.”; genera (Ampelomyces sp.); Aspergillus flavus (e.g.
- Bacillus amylo request facilitation B Bacillus amyloliquefaciens strain D747 (e.g. "Bacstar®” from “Etec Crop Solutions, NZ"), Bacillus amyloliquefaciens strain DB101 (e.g. from “Dagutat Biolab, ZA”). "Shelter®”), Bacillus amyloliquefaciens strain DB102 (e.g. "Artemis®” from “Dagutat Biolab, ZA”), Bacillus amyloliquefaciens amyloliquefaciens strain FZB42 (e.g.
- BioNeem® from “AgoGreen”
- Bacillus laterosporus e.g. "Bio-Tode®” from “Agro-Organics, SA
- Bacillus licheniformis strain SB3086 e.g. "EcoGuard Biofungicide®” from “Novozymes”
- Bacillus maroccanus e.g. from “Micro Flo Company
- Bacillus - Bacillus megaterium strain YFM3.25 e.g. "Bioarc®” from “BioArc”
- Bacillus metiens from “Micro Flo Company”
- Bacillus mycoides Isolate J. e.g.
- Bacillus popilliae e.g. "Cronox®” from “Bio-Crop, CO
- Bacillus pumilus strain BU F-33 e.g. "Integral F-33®” from “Becker Underwood, US”
- Bacillus pumilus strain GB34 e.g.
- Bacillus pumilus strain QST2808 e.g., "Sonata” from Bayer CropScience LP, US
- Bacillus simplex ( Bacillus simplex) strain CGF2856 (“Momihope wettable powder (registered trademark)” manufactured by “Arista Life Sciences Co., Ltd.”
- Bacillus sphaericus especially serotype H5a5b strain 2362 (for example, “Valent BioSciences, "VectoLex (registered trademark)” manufactured by US”), Bacillus subtilis (for example, “Botkiller Wettable Powder (registered trademark)” manufactured by "Idemitsu Agri Co., Ltd.”), Bacillus subtilis var.
- Bacillus subtilis var. "SERENADE MAX®” manufactured by U.S.A. Bacillus subtilis strain AQ30002 (e.g., "Serenade-DPZ (registered trademark)"), Bacillus subtilis strain D747 (e.g., "Eco Shot (registered trademark)” manufactured by "Kumiai Chemical Industry Co., Ltd.”), Bacillus subtilis ( Bacillus subtilis) strain HAI-0404 (for example, “Agrocare Wettable Powder (registered trademark)” manufactured by "Nisso Green Co., Ltd.”), Bacillus subtilis strain MBI600 (for example, “Idemitsu Kosan Co., Ltd.") "Botopika wettable powder (registered trademark)” manufactured by Bacillus subtilis strain Y1336 (for example, “Batister wettable powder (registered trademark)” manufactured by Arista Life Sciences Co., Ltd.), Bacillus subtilis strain Y1336 Bacillus thuringiensis strain AM
- Novodor FC® from “BioFa DE”
- Bacillus thuringiensis var. 7216 e.g. " Amactic” and “Pethian”
- Bacillus thuringiensis var. T36 e.g., "Cahat”
- Bacillus thuringiensis var. Colmeri e.g., "Changzhou Jianghai Chemical "TianBaoBTc®” made by “Factory”
- Bacillus thuringiensis var. san diego e.g., "M-One®” made by "Bacillus thuringiensis var. san diego"
- Bacillus spp. such as Bacillus spp.
- Beauveria bassiana strains e.g. “Naturalis®” from “Intrachem Bio Italia”
- Beauveria bassiana strain CG716 e.g. “BoveMax®” from “Novozymes”
- Beauveria bassiana strain F-263 e.g., “Biolisa Madara (registered trademark)” manufactured by “Idemitsu Kosan Co., Ltd.”
- Beauveria bassiana strain GHA e.g., “ Beauveria such as "Botaniguard Wettable Powder” from “ARYSTA”
- Beauveria brongniartii e.g.
- Lactobacillus acidophilus e.g. "Inagrosa-Industrias" Agrobiologicas, S.A.'s “Fruitsan®”
- Lactobacillus plantarum strain BY e.g., "Meiji Seika Pharma Co., Ltd.'s “Lactogard wettable powder”
- Lactobacillus (Lactobacillus sp.) e.g., "Lactoplant (registered trademark)” manufactured by “LactoPAFI”
- Lactobacillus acidophilus e.g. "Inagrosa-Industrias”
- Agrobiologicas S.A.'s “Fruitsan®
- Lactobacillus plantarum strain BY e.g., "Meiji Seika Pharma Co., Ltd.'s “Lactogard wettable powder”
- Lactobacillus (Lactobacillus sp.) e.g., "Lactoplant (register
- Metschnikowia fructicola e.g. "Shemer®” from “Bayer CropScience”
- Microdochium dimerum “ANTIBOT®” from “Agrauxine, France”
- Microsphaeropsis ochracea e.g. "Microx®” from “Prophyta”
- Monaclosporium fimatopa gum Monacrosporium phymatopagum
- Mucor haemelis e.g. “BioAvard®” from “Indore Biotech Inputs & Research”
- Myrothecium verrucaria strain AARC-0255 e.g.
- DiaTera TM from “Valent Biosciences”
- Ophios Ophiostoma piliferum strain D97 e.g. "Sylvanex”
- Paecilomyces fumosoroseus strain apopka 97 e.g. "PreFeRal® WG” from “Biobest”
- Paecilomyces fumosoroseus strain FE 9901 e.g., "No Fly (registered trademark)” manufactured by "Natural Industries Inc.
- Paecilomyces fumosoroseus e.g., "Tokai Bussan Co., Ltd.” preferred wettable powder
- Paecilomyces lilacinus strain 251 e.g., "BioAct WG®” from “Prophyta”
- compositions containing Paecilomyces lilacinus e.g., "MELOCON (registered trademark)
- Paecilomyces tenuipes strain T1 for example, "Gottsu A (registered trademark)” manufactured by "Idemitsu Kosan Co., Ltd.”
- Pasteuria penetrans e.g., "Nemaquim®” from “Quimia, MX”
- Paenibacillus polymyxa strain AC-1 from “Green Biotech Company Ltd.”
- Paenibacillus spp. such as “Topseed®”
- Paenibacillus poppiliae e.g., "Milky spore disease®” from “St. Gabriel Laboratories”
- (Pasteuria nishizawa) (“Clariva®”) Pasteuria nishizawae (e.g. “oyacystLF/S” from “Pasteuria Bioscience”)
- Pasteuria spp. such as Pasteuria penetrans (e.g.
- Pectobacterium carotovorum for example, “Biokeeper (registered trademark)” manufactured by “Nissan Chemical Co., Ltd.”
- Pectobacterium carotovorum CGE234M403 strain for example, “Ecomate (registered trademark)” manufactured by “Kumiai Chemical Industry Co., Ltd.”
- Pectobacterium spp. such as "Pectobacterium spp.”
- Penicillium bilaii strains e.g., "Jump Start®” from “Novozymes”
- Phlebiopsis gigantea Strain FOC PG B22/SP1190/3.2 e.g. "ROTSOP®” from “Verdera, Finland”
- Phoma macrostroma strain 94-44B e.g. "Scotts, US"
- Phoma H registered trademark
- Pochonia chlamydosporia var. catenulata e.g. "The National Center of Animal and Plant Health (CENSA); "KlamiC®” by CU); Pseudomonas aureofaciens Strain TX-1 (e.g., "Spot-Less Biofungicide®” from “Eco Soils Systems, CA”), Pseudomonas chlororaphis strain 63-28 (e.g., " ATEze®”), Pseudomonas chlororaphis strain MA 342 (e.g.
- Biosave® from EcoScience, US
- Pseudomonas syringae syringae) strain 742RS for example, "Frost Technology Corp (registered trademark)” manufactured by “Frostban C”
- Pseudomonas rhodesiae HAI-0804 strain Masterpiece Hydration” manufactured by "Nippon Soda Co., Ltd.
- Agent registered trademark
- Pseudomonas sp. Strain CAB-02 e.g., "Nissan Chemical Co., Ltd.” Momigenki wettable powder
- Pseudomonas spp. Pseudomonas spp.; Pseudozyma aphidis (for example, “Yissum Research Development Company of the Hebrew University of Jerusalem”), Pseudozyma flocculosa strain PF-A22 UL (for example, "Plant Products Co. Ltd, CA”) Pseudozyma sp., such as Sporodex L®); Pythium oligandrum strain DV74 or M1 (e.g., Polyversum® from Bioprepraty, CZ); Reynoutria sachlinensis (e.g. "REGALIA®” from “Marrone BioInnovations, US”); Rhizopogon amylopogon (e.g.
- Myco-Sol® from “Helena Chemical Company”
- Rhizopogon fulvigleba e.g. "Myco-Sol®” from “Helena Chemical Company”
- Saccharomyces cerevisiae Saccharomyces cerevisiae strains (e.g. from “Lesaffre et Compagnie, FR”
- Sclerotinia minor e.g. "Sarritor” from "Agrium Advanced Technologies”
- Serratia entomophila e.g. "Invade®” from “Wrightson Seeds”
- Sporothrix insectorum e.g.
- Streptomyces candidus strain Y21007-2 e.g., “BioBac®” from “Biontech, TW”
- Streptomyces galbus strain K61 e.g., "" Mycostop® from Verdera
- Streptomyces lydicus strain WYEC108 e.g., ACTINOVATE® from Natural Industries, US
- Streptomyces Streptomyces spp. such as saraceticus (e.g. "Clanda®” from "A & A Group (Agro Chemical Corp.)”);
- Talaromyces flavus strain B-422 e.g., "Momikeeper (registered trademark)” manufactured by “Central Glass Co., Ltd.”
- Talaromyces flavus strain SAY-Y-94-01 e.g., "Tough Block (registered trademark)” manufactured by "Idemitsu Kosan Co., Ltd.”
- Talaromyces flavus strain V117b for example, "PROTUS (registered trademark) WG” manufactured by "Prophyta, DE", etc.
- Trichoderma asperellum strain ICC 012 manufactured by “Isagro”
- Trichoderma asperellum strain T34 e.g. "T34 Biocontrol (registered trademark)” manufactured by “Bioncontrol Technologies, ES” Trademark)
- Trichoderma asperellum strain SKT-1 e.g., "ECO-HOPE (registered trademark)” manufactured by "Kumiai Chemical Industry Co., Ltd.”
- Trichoderma atroviride strain e.g. , "Esquive® WP" from “Agrauxine, FR”
- Trichoderma atroviride strain LC52 e.g.
- Trichoderma Trichoderma atroviride strain SKT-1 e.g., "Ecohope DJ (registered trademark)” manufactured by "Kumiai Chemical Industry Co., Ltd.”
- Trichoderma gamsii strain ICC 080 e.g., "Bayer Crop Science LP ⁇ BIO-TAMTM (registered trademark)'' manufactured by ⁇ US'', Trichoderma harzianum m) strain DB 103 (e.g. "T-Gro 7456®” from “Dagutat Biolab”)
- Trichoderma harzianum strain ITEM 908 e.g.
- Trichoderma harzianum strain KD e.g. “Trichoplus®” from “Biological Control Products, SA”
- Trichoderma harzianum strain TH-35 e.g. “Mycontrol Ltd.
- Trichoderma harzianum rifai strain T-22 KRL-AG2
- PANTSHIELD T- 22G registered trademark
- Trichoderma harzianum rifai strain T-39 e.g.
- Trichoderma lignorum strain TL-0601 for example, “Mycotric (registered trademark)” manufactured by “Futureco Bioscience, ES”
- Trichoderma polysporum strain for example, “Binab TF WP (for example, “BINAB Bio-Innovation AB, Sweden”) registered trademark)
- Trichoderma stromaticum e.g. "TRICOVAB®” from “Ceplac; Brazil”
- Trichoderma virens ("Gliocladium virens ) strain GL-21 (e.g.
- Trichoderma viride strain ICC080 e.g. "Isagro Ricerca, ITALIA”
- REMEDIE R® WP Trichoderma viride strain TV1 (e.g. “Trianum-P®” from “Koppert”); (Tsukamurella paurometabola) strain C-924 (e.g. "HeberNem®”); Ulocladium oudemansii strain HRU3 (e.g.
- Verticillium alboatrum strain WCS850 e.g. "Dutch Trig®” from “Tree Care Innovations”
- Verticillium lecanii strain IMI 179172 e.g. "Arysta Life Science “Vertalec (registered trademark)” manufactured by “Co., Ltd.”
- Verticillium lecanii strain IMI 263817 for example, “Mycotal (registered trademark)” manufactured by “Arista Life Sciences Co., Ltd.”
- Verticillium spp.; Xanthomonas campestris (Campelico Liquid (registered trademark) available from Taki Kagaku) and the like can also be used in combination.
- IPM integrated pest management
- insect pheromones such as communication disruptors for tomatopods and armyworms
- natural enemy insects etc.
- the agent of the present invention can be used in combination with these technologies. , or systematized.
- red-clawed thrips isaea thrips, thrips thrips, thrips thrips, gifu aphid, cucumeris cucumeris, mulberry wasp, coleman thrips, desert thrips, leopard fly, swirski phytoseiid mite, tyric himehana Stink bug, mediterranean wasp, Chilean genus Chilean stinkbug, Chabara physiognomy cucumber, Tsuyako wasp, Degeneran phytoseiid tick, Trichograma (bee), Nami ladybug, Namihime stink bug, Leaf beetle, Leaf grim green wasp, Lesser stink bug, Lesser stink bug, Miyako phytoseiid mite, Collembola such as F.candida and A.flavescens, which feed on Rhizoctonia spp. and Rhizocens, which feed on Rhizoctonia
- Heterorhabditis baujardi Heterorhabditis heliothidis (e.g. " Heterorhabditis spp. such as Heterorhabditis indica, Heterorhabditis marelatus, Heterorhabditis megidis, Heterorhabditis zealandica );Hexamermis spp.;Hydromermis spp.;Isomermis spp.
- Nemasys® products known as “Biotopia”
- Steinernema glaseri for example, “Biotopia” manufactured by “Arista Life Sciences” and products known as “Biotopia”
- Steinernema glaseri Steinernema kraussei
- Steinernema kushidai e.g. "Shibaichi Nema” manufactured by “Kubota Corporation”
- Steinernema riobrave e.g. the product known as "Biovector”
- Steinernema scapterisci e.g.
- Steinernema spp. such as Steinernema scarabaei, Steinernema siamkayai, etc.; Strelkovimermis peterseni); Subulura spp.; Sulphuretylenchus elongatus; Tetrameres spp.
- Adoxophyes orana granulosis virus e.g. the product known as "BIOFA-Capex®”
- Adoxophyes orana granulosis virus MAFF632001
- MAFF632002 a mixture of Chahamaki granulosis virus
- MAFF632002 Agrotis segetum nuclear polyhedrosis virus
- NPV Agrotis segetum nuclear polyhedrosis virus
- Anticarsia gemmatalis (Woolly pyrol moth) mNPV (e.g.
- mNPV e.g. "VPN80 (Registered Trademark)”; Source: Agricola El Sol), tea looper (Biston suppressaria) NPV, Bombyx mori NPV, Cryptophlebia leucotreta (false codling moth) GV (e.g. the product known as "Cryptex®”), Cydia pomonella spp. such as Cydia pomonella granulosis, viruses, Cydia pomonella ) granulosis virus (CpGV) (e.g.
- Neodiprion lecontei red-headed pinesawfly
- NPV for example, the product known as “Lecontvirus®”
- Neodiprion sertifer NPV for example, the product known as "Neocheck-S®”
- Orgyia pseudotsugata Douglas-fir tussock moth
- NPV for example, the product known as "Virtuss®”
- tobacco leaf miner Phthorimaea operculella
- GV e.g. the product known as "Matapol®
- Pieris rapae GV Pieris rapae GV
- Plutella xylostella GV e.g.
- mNPV Spodoptera albula (gray-streaked armyworm moth) mNPV (e.g. product known as “VPN 82®”), African armyworm (true armyworm) (Spodoptera exempta) mNPV (e.g. products known as "Spodec®”), sugarbeet armyworm (Spodoptera exigua) mNPV (e.g. known as "Spexit®”) products; source: Andermatt Biocontrol), fall armyworm (Spodoptera frugiperda) mNPV (e.g.
- Bactivirus VPN® Egyptian armyworm (tobacco cutworm) ( Spodoptera lit toralis) NPV (product known as "Spodoptrin®”; source: NPP Calliope France), oriental leafworm moth (Spodoptera litura) NPV (Littovir®), oriental leafworm moth ) Nuclear polyhedrosis virus Fu-1 strain embedded body ("Hasmon natural enemy” manufactured by "Nippon Kayaku Co., Ltd.”), oriental leafworm moth nuclear polyhedrosis virus clone A9 strain and clone C3 strain embedded body (for example, "Hasmon Killer” manufactured by "Ibigawa Kogyo Co., Ltd.”), zucchini yellow mosaic virus attenuated strain ZY-02 (for example, “Kyoto Biken” Cubio ZY manufactured by "Microbial Chemical Laboratory Co., Ltd.” -02 (registered trademark)”), zucchini yellow mosaic virus attenuated strain ZY-95 (for example, “Kyoto Biken” Cubio ZY
- the compounds or ingredients contained in the above active ingredient group A are sold in Japan and overseas, or are compounds or ingredients known in the literature.
- the insecticide composition of the present invention which contains compound (I) and compound (II) as active ingredients, damages agricultural crops such as paddy rice, fruit trees, vegetables and other crops, and useful plants such as garden plants such as ornamental plants. It is suitable for controlling pests such as various agricultural pests that grow on rice and stored grains such as wheat flour.
- Pests for which the insecticidal composition of the present invention is effective include, for example, Lepidoptera (Lepidoptera), such as Parasa consocia, Anomis mesogona, Papilio xuthus, Matsumuraeses azukivora, and Azuki no Meiga (Ostrinia scapulalis), Spodoptera exempta, Hyphantria cunea, Ostrinia furnacalis, Pseudaletia separata, Tinea translucens, Bactra furfurana, Parnara gutta ), Marasmia exigua, Sesamia inferens, Brachmia triannulella, Monema flavescens, Trichoplusia ni, Pleuroptya ruralis, Cystidia couaggaria Lampides boeticus, Cephonodes hylas, Helicoverpa armigera, Phalerodonta manleyi
- Agrotis isilon, Euproctis pseudoconspersa, Adoxophyes orana, Caloptilia theivora, Homona magnanima, Ephestia elutella, Eumeta minuscula (Clostera anachoreta), Heliothis maritima, Sparganothis pilleriana, Busseola fusca, Euproctis subflava, Biston robustum, Heliothis zea, Aedia leucomelas), Narosoideus flavidorsalis, Viminia rumicis, Bucculatrix pyrivorella, Grapholita molesta, Spulerina astaurota, Ectomyelois pyrivorella, Chilo suppressalis, Acrolepiphysis sapporensis), Plodia interpunctella, Hellula undalis, Sitotroga ceralella, Spodoptera litura, Eucosma aporema, Acleris comarian
- Fall army worm (Spodoptera frugiperda), coltsfoot moth (Ostrinia zaguliaevi), Naranga aenescens, Andraca bipunctata, Grape sparrow (Paranthrene regalis), Grape sparrow (Acosmeryx castanea), Grape leaf moth (Phyllocnistis toparcha), Endopiza viteana, Eupoecillia ambiguella, Velvet bean caterpillar (Anticarsia gemmatalis), Cnephasia cinereipalpana, Lymantria dispar, Dendrolimus spectabilis, Legumivora glycinivorella, Bean moth (Maruca testulalis), Mitsumuraeses phaseoli, Caloptilia soyella, Phyllocnistis citrella, Hadylepta indicata, Archips fuscocupreanus Acanthoplusia agnata), minnow (Bambalina sp.), peach moth (Carpos
- Peach moth (Synanthedon sp.), Lyonetia clerkella, Papilio helenus, Colias erate poliographus, Phalera flavescens, Pieris rapae crucivora (subspecies), Cabbage butterfly ( Pieris rapae), Pieridae, Euproctis similis, Acrolepiopsis suzukiella, Ostrinia nubilalis, Mamestra brassicae, Ascotis selenaria, Mugwort Phtheochroides clandestina), Hoshinoa adumbratana, Odonestis pruni japonensis, Triaena intermedia, Adoxophyes orana fasciata, Grapholita inopinata, Spilonota ocellana), Spilonota lechriaspis, Illiberis pruni, Argyresthia conjugella, Caloptilia zachrysa, Archips
- Hemiptera Hemiptera (Stink bugs), for example, Nezara antennata, Stenotus rubrovittatus, Graphosoma rubrolineatum, Trigonotylus coelestialium, etc., Aeschynteles maculatus), Creontiades pallidifer, Dysdercus cingulatus, Chrysomphalus ficus, Aonidiella aurantii, Graptopsaltria nigrofuscata, Blissus leucopterus, Iselia Scale insect (Icerya purchasi), Japanese stink bug (Piezodorus hybneri), Rice stink bug (Lagynotomus elongatus), Rice leafhopper (Thaia subrufa), Rice black stink bug (Scotinophara lurida), Thorny aphid (Sitobion ibarae), Stink bug (Stariodes iwasakii) , Aspidiotus
- Grape leaf hopper (Erythroneura comess), Black-footed stink bug (Paromius exguus), Black-footed scale bug (Duplaspidiotus claviger), Leafhopper (Nephotettix nigropictus), Black-footed turtle (Halticiellus insularis), Black-footed planthopper (Perkinsiella saccharicida), Psylla malivorella, Anomeura mori, Pseudococcus longispinis, Pseudaulacaspis pentagona, Pulvinaria kuwacola, Apolygus lucorum, Long-tailed stink bug (Togo hemipterus), Toxoptera aurantii, Saccharicoccus sacchari, Geoica lucifuga, Numata muiri, Comstockaspis perniciosa, Citrus Snowscale ( Unaspis citri), potato aphid (Aulacorthum solani), white stink bug
- Nilaparvata lugens Psylla tobirae, Eurydema rugosum, Schizaphis piricola, Psylla pyricola, Parlatoreopsis pyri, Stephanitis sashi, Psylla pyricola Dysmicoccus wistariae), pear scale insect (Lepholeucaspis japonica), pear aphid (Sappaphis piri), radish aphid (Lipaphis erysimi), onion aphid (Neotoxoptera formosana), husquilla aphid (Rhopalosophum nymphaeae), leafhopper (Edwardsiana rosae) ), Pinnaspis aspidistrae, Psylla alni, Speusotettix subfusculus, Alnetoidia alneti, Sogatella panicicola, Adelphocoris lineolatus, and Rhinoceros stink
- Macrosteles fascifrons Dolycoris baccarum, Adelphocoris triannulatus, Viteus vitifolii, Acanthocoris sordidus, Leptocorisa acuta Macropes obnubilus, Cletus punctiger, Riptortus clavatus, Paratrioza cockerelli, Aphrophora costalis, Lygus disponsi, Lygus saundersi, Crisicoccus pini, Crisicoccus matsumotoi, Aphis craccivora, Megacopta punctatatissimum, Eysarcoris guttiger, Lepidosaphes beckii, Diaphorina triaphorina ), citrus black aphid (Toxoptera citricidus), citrus mealybug (Planococcus citri),
- Coleoptera (Coleoptera), such as Xystrocera globosa, Paederus fuscipes, Eucetonia roelofsi, Callosobruchus chinensis, Cylas formicarius, Alfalfa weevil ( Hypera postica, Echinocnemus squameus, Oulema oryzae, Donacia provosti, Lissorhoptrus oryzophilus, Colasposoma dauricum, Euscepes postfasciatus, Epilachna varives (Acanthoscelides obtectus), Western corn rootworm (Diabrotica virgifera virgifera), Plum weevil (Involvulus cupreus), Cucumber beetle (Aulacophora femoralis), Pea weevil (Bruchus pisorum), Epilachna vigintioctomaculata (Carpophilus dimidiatus), Cassi
- Diptera e.g., Pegomya hyoscyami, Liriomyza huidobrensis, Chlorops oryzae, Hydrellia sasakii, Agromyza oryzae, rice Flea flies such as Hydrellia griseola, Ophiomyia phaseoli, Dacus cucurbitae, Drosophila suzukii, Rhacochlaena japonica, and Megaselia spiralis (Phoridae), Clogmia albipunctata,
- Radish fly (Hylemya brassicae), soybean fly (Asphondylia sp.), seed fly (Delia platura), onion fly (Delia antiqua), cherry fruit fly (Rhagoletis cerasi), Mediterranean fruit fly (Ceratitis capitata), Bradysia agrestis, sugar beet Pegomya cunicularia, Liriomyza sativae, Liriomyza bryoniae, Chromatomyia horticola, Liriomyza chinensis, Liriomyza trifolii, Dacus dorsalis, Citrus fruit fly Dacus tsuneonis), Sitodiplosis mosellana, Meromuza nigriventris, Mexican fruit fly (Anastrepha ludens), Phagoletis pomonella,
- Hymenoptera e.g., Pristomyrmex ponnets, Bethylidae, Monomorium pharaosis, Pheidole noda, Athalia rosae, Dryocosmus kuriphilus, etc., Formica fusca japonica), Vespinae, Athalia infumata, Arge pagana, Athalia japonica, Leaf-cutting ant (Acromyrmex spp.), Fire ant (Solenopsis spp.), Apple sawfly ( Argemali), Ruriari (Ochetellusglaber),
- Orthoptera such as Homorocoryphus lineosus, Gryllotalpa sp., Oxya hyla intricata, Oxya yezoensis, Locusta migratoria, Oxya japonica, Homorocoryphus jezoensis), emma cricket (Teleogryllus emma),
- Thrips for example, Selenothrips rubrocinctus, Stenchaetothrips biformis, Haplothrips aculeatus, Ponticulothrips diospyrosi, etc., Thrips flavus, Anascurthrips obscurthrips , Liothrips floridensis, Gladiolus simplex, Thrips nigropilosus, Heliothrips haemorrhoidalis, Pseudodendrothrips mori, Microcephalothrips abdominalis Leeuwenia pasanii), Litotetothrips pasaniae, Scirtothrips citri, Haplothrips chinensis, Mycterothrips glycines, Thrips setosus, Scirtothrips dali ), Dendrothrips minowai, Haplothrips niger, Thrips tabaci, Thrips alliorum, Thrips hawaiiens
- Acarina e.g. Tetranychus ludeni, Tetranychus truncatus, Tetranychus viennensis, Tetranychus kanzawai, Acaphylla theavagrans, Polyphagotarsonemus latus, Tomato rust mite Aculesciops ), Tetranychus urticae, Eriophyes chibaensis, Tyrophagus similis, Panonychus citri, Brevipalpus phoenicis, Phyllocoptruta citri, Aculus Mattendali), apple spider mite (Panonychus ulmi),
- Termites such as Reticulitermes miyatakei, Incisitermes minor, Coptotermes forsanus, Hodotermopsis japonica, Reticulitermes sp., Reticulitermes flaviceps amamianus, Glyptotermes kushimensis, Coptotermes guangzhoensis, Neotermes koshunensis, Glyptotermes kodamai, Glyptotermes satsumensis, Cryptotermes domesticus, Odontotermes, Formosanustermes Glyptotermes nakajimai, Pericapritermes nitobei, Reticulitermes speratus,
- Araneae e.g. Latrodectus hasseltii
- Nematodes such as Nothotylenchus acris, Aphelenchoides besseyi, Pratylenchus penetrans, Meloidogyne hapla, Meloidogyne incognita, Globodera rostochiensis), Java root nematode (Meloidogyne javanica), Soybean cyst nematode (Heterodera glycines), Minaminegusare nematode (Pratylenchus coffeae), Muginegusare nematode (Pratylenchus neglectus), Tangerine nematode (Tylenchus semipenetrans),
- the composition of the present invention is preferably used against pests of the order Hemiptera (order Stinkbugs). Among them, it is particularly preferably used for various planthoppers such as black planthopper, brown planthopper, brown planthopper, and brown planthopper.
- Useful plants to which the composition of the present invention can be applied are not particularly limited. , kidney beans, peanuts, etc.), fruit trees and fruits (apples, citrus fruits, pears, grapes, peaches, plums, cherry blossoms, chestnuts, almonds, bananas, etc.), leafy and fruit vegetables (cabbage, tomatoes, spinach, broccoli, lettuce, onions) , green onions, green peppers, eggplants, strawberries, peppers, okra, etc.), root vegetables (carrots, potatoes, sweet potatoes, taro, radishes, turnips, lotus roots, burdocks, garlic, etc.), processed crops (cotton, hemp, beets, hops, Sugar cane, sugar beets, olives, gum, coffee, tobacco, tea, etc.), gourds (pumpkin, cucumber, watermelon, Japanese melon, melon, etc.), grasses (orchard grass, sorghum, timothy, clover, alfalfa, etc.), lawn
- the composition of the present invention is added in an amount effective for controlling various agricultural and horticultural pests as it is, or in the form of being diluted or suspended with water or the like. is used for plants for which For example, for various pests and mites that occur in fruit trees, cereals, vegetables, etc., it is sprayed on foliage.
- it can be used for seed treatment, soil or cultivation carrier treatment, addition to paddy fields, addition to nutrient solution in hydroponics, smoking, trunk injection, application to building materials, etc., and also as a bait. can be used.
- the present invention provides an agricultural and horticultural insecticide that treats target pests, target useful plants, soil or cultivation carriers with an effective amount of the composition of the present invention in order to protect useful plants from various agricultural and horticultural pests.
- a method of using the agent composition (hereinafter also referred to herein as the "method of the invention") is also provided.
- target pests include various pests such as agricultural pests, grain storage pests, livestock pests, sanitary pests, and the like.
- Useful plants to be protected from agricultural and horticultural pests include the above-mentioned cereals, beans, fruit trees/fruits, leaves/fruit vegetables, root vegetables, processing crops, pasture grasses, lawns. , plants for fragrances and spices, flowers, garden trees, timbers, and the like.
- the composition of the present invention in the form of a liquid formulation such as an emulsion, a flowable formulation, a wettable powder, or a solid formulation such as a wettable granule is mixed with water or the like as appropriate.
- Examples of the method for treating the seeds of the target useful plants include, for example, a method of soaking the seeds in the form of a solution or suspension in which the composition of the present invention in a liquid or solid formulation is diluted or not diluted, a solid formulation or a liquid formulation.
- the "seed" to be subjected to the seed treatment means a plant body in the early stage of cultivation used for plant propagation. Plants for propagation can be mentioned.
- the "soil” or “cultivation carrier” treated with the composition of the present invention indicates a support for cultivating the target useful plant, especially a support for growing roots.
- the material is not particularly limited, but any material that allows the plant to grow may be used, such as so-called soil, seedling mat, water, etc. Specific materials include, for example, sand, pumice, vermiculite, diatomaceous earth, It may be agar, gel-like substance, polymeric substance, rock wool, glass wool, wood chips, bark, or the like.
- soil or “cultivation carrier” includes seedling boxes for paddy rice, paddy fields, cultivation carriers used for upland crops, and nutrient solution in hydroponics.
- a method for treating soil or a cultivation carrier for example, a method of applying the composition of the present invention in the form of a liquid formulation to the stock of a target useful plant or a nursery bed for raising seedlings, with or without diluting it with water.
- a method of spraying the composition of the present invention in the form of granules at the base of a plant body or a nursery bed for raising seedlings A method of irrigating or spraying the composition of the present invention in the form of a powder, wettable powder, wettable granules, granules, etc. on a nursery bed for raising seedlings, or mixing with the entire soil or cultivation carrier in the vicinity of the transplant site, before sowing
- the dosage form that can be selected for formulation may differ depending on the treatment time such as sowing, greening, and transplanting. It may be treated as a dosage form such as a blend, granules, or the like. It can also be treated by mixing with potting soil, and mixing potting soil with the composition of the present invention in the form of powder, wettable granules, granules, etc., for example, mixing with bed soil, mixing with covering soil, mixing with the whole potting soil, etc. or may simply be applied in alternating layers of potting soil and the compositions of the invention in various formulations.
- the composition of the present invention in the form of solid formulations such as jumbo formulations, pack formulations, granules and wettable granules, and liquid formulations such as flowable formulations and emulsions, is usually treated in flooded paddy fields. disperse to In addition, at the time of rice planting, an appropriate formulation can be sprayed or injected into the soil as it is or mixed with fertilizer or the like. In addition, by using the composition of the present invention in the form of an emulsion, a flowable agent, or the like, at the inlet of water to a paddy field such as a water outlet or an irrigation system, labor-saving treatment can be achieved along with the supply of water.
- a paddy field such as a water outlet or an irrigation system
- the seeds or cultivation carriers that are close to the plant during the period from sowing to raising seedlings.
- the agent for plants that are directly sown in a field, it is preferable to apply the agent directly to the seeds as well as to the base of the plant under cultivation.
- the spraying treatment can be carried out with the composition of the invention in granule form, or the irrigation treatment can be carried out with the composition of the invention in liquid form, diluted with water or undiluted. It is also a preferred treatment to mix the composition of the invention in granules with a pre-sowing cultivation carrier and then sowing.
- compound (I) and compound (II), which are active ingredients of the agricultural and horticultural insecticide of the present invention, can be used alone (separately) at the same time to produce an agricultural and horticultural It is possible to exert the effect of broadening the bactericidal spectrum similar to that of the bactericidal agent composition for food, and the synergistic effect of the combined use of compound (I) and compound (II). That is, compound (I) or compound (II) may be formulated separately or its dilution may be mixed and applied at the time of treatment at the site of use, or they may be used separately at the same time. Plant foliage, seeds, cultivation carriers and the like may also be treated.
- compound (I) or compound (II) When compound (I) or compound (II) is separately formulated and applied separately, they may be applied at the same time or may be applied at intervals of about 7 days (time difference). It is preferable to apply the other active ingredient when one of the active ingredients remains in the plant or cultivation carrier.
- the term "simultaneous period” is a concept that includes at least a portion of the period in which both active ingredients are processed due to the residual effects of the active ingredients, as described above. It can also be rephrased as the period when the previously used active ingredient remains in the plant or cultivation carrier, and does not necessarily mean that the application operations are performed at the same time.
- the period during which the previously used active ingredient remains in the plant or cultivation carrier differs between compound (I) and compound (II), but is usually within 6 months from the date or time when one of the active ingredients is used. , may be within 3 months, may be within 1 month, may be within 10 days, may be within 7 days, may be within 3 days, may be within 24 hours It may be within 12 hours, or within 6 hours.
- the present invention also encompasses a method for controlling plant diseases in which effective amounts of compound (I) and compound (II) are applied separately, simultaneously, or with a time delay to a plant or cultivation carrier.
- the effective amount of compound (I) or compound (II) is the same as the effective amount in the agricultural and horticultural insecticide composition described above.
- composition of the present invention is formulated into dosage forms commonly employed in the art, such as emulsions, wettable powders, wettable granules, flowables, liquids, granules, powders, and smokes.
- the amount used is determined by the mixing ratio of the active ingredients compound (I) and compound (II), weather conditions, dosage form, timing of use, method of use, place of use, type of target pests, target Although it varies depending on the type of useful plant, etc., the amount of active ingredient (total amount of compound (I) and compound (II)) per 1 are may be appropriately selected from the range of 0.1 g to 1000 g, preferably 1 g. ⁇ 500 g.
- the amount of active ingredient in the range of 0.01% to 50% by weight based on the weight of the seed, and it is possible to use it in the range of 0.1% to 10% by weight. preferable.
- the concentration used is 0.00001% by weight to 0.1% by weight in terms of the concentration of the active ingredient.
- seeds are treated as a liquid agent or the like, it is usually used as it is without dilution.
- DYNO MILL registered trademark of DYNO
- xanthan gum 1 weight of xanthan gum that had been separately mixed and dissolved in advance was added.
- % aqueous solution is added and uniformly mixed to obtain an aqueous suspension (flowable preparation) containing 7% by weight of active ingredients (compound (I) and compound (II)).
- Test Example 1 Control effect on brown planthopper (Nilaparvata lugens) (test method 1) (1) Preparation of sample A composition of the present invention containing compound (I) and compound (II) as active ingredients was prepared according to the formulation example, and dispersed in water so as to have the concentration shown in Table 1. , respectively. In addition, each concentration of compound (I) and compound (II) is independently dispersed in water to prepare a sample. (2) Evaluation of pest control effect About 40 mL of each sample is sprayed on potted rice (variety: Kinnanfu) with a spray gun and air-dried.
- control rate calculated from the evaluation results obtained by treatment with the composition of the present invention containing compound (I) and compound (II) contains each of the active ingredients contained in the composition of the present invention alone. If the expected value (E) calculated from the control rate obtained when treated with the sample is exceeded, it can be said that the composition of the present invention exhibits a synergistic effect.
- Control rate (%) (1-number of surviving insects/number of surviving insects in control section) x 100
- Test method 2 Control effect on brown planthopper (Nilaparvata lugens) (test method 2) (1) Preparation of Sample Compound (I) and Compound (II) were dispersed in water at concentrations shown in Table 1 to prepare test compositions. In addition, each concentration of compound (I) and compound (II) were individually dispersed in water to prepare samples. (2) Evaluation of control effect Rice leaf sheaths (variety: Kinnanpu) were immersed in the above sample solution for 30 seconds, air-dried, placed in glass test tubes, and inoculated with 10 5th instar brown planthoppers (Nilaparvata lugens) each.
- composition of the present invention containing compound (I) and compound (II) both showed good control effect, and when treated with the composition of the present invention, the expected value A higher mortality than (E') was obtained.
- composition of the present invention synergistically improves the control effect compared to the case where each agricultural or horticultural agent is used alone.
- the present invention provides an agricultural and horticultural insecticide composition that synergistically improves the control effect against various agricultural and horticultural pests and can efficiently control a plurality of pests. can do.
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Abstract
The present invention relates: to an insecticide composition for agricultural or horticultural use characterized by containing 5-(1,3-dioxane-2-yl)-4-[4-(trifluoromethyl) benzyloxy] pyrimidine and nitenpyram as active ingredients; and a use method therefor. According to the present invention, an insecticide composition for agricultural or horticultural use can be provided, wherein combined use of both of the active ingredients can efficiently control various pest insects that are difficult to control by treatment using a single one of the active ingredients.
Description
本発明は、下記式[I]:
The present invention uses the following formula [I]:
で示される5-(1,3-ジオキサン-2-イル)-4-[4-(トリフルオロメチル)ベンジルオキシ]ピリミジン(化学名)(農薬一般名:ベンズピリモキサン;以下、これを化合物(I)と称する)、及び下記式[II]:
5-(1,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine (chemical name) (pesticide general name: benzpyrimoxane; hereinafter, this compound (I)), and the following formula [II]:
で示される(1E)-N1-[(6-クロロピリジン-3-イル)メチル]-N1-エチル-N’1-メチル-2-ニトロビニリデン-1,1-ジアミン(化学名)(農薬一般名:ニテンピラム;以下、これを化合物(II)と称する)を有効成分として含有することを特徴とする、農園芸用殺虫剤組成物及びその使用方法に関する。また、本発明は、上記2化合物を組み合わせて使用することによる農園芸害虫類の防除方法にも関する。
(1E)-N1-[(6-chloropyridin-3-yl)methyl]-N1-ethyl-N'1-methyl-2-nitrovinylidene-1,1-diamine (chemical name) (pesticides in general The present invention relates to an agricultural and horticultural insecticide composition characterized by containing Nitenpyram (hereinafter referred to as compound (II)) as an active ingredient, and a method for using the same. The present invention also relates to a method for controlling agricultural and horticultural pests by using the above two compounds in combination.
本発明の農園芸用殺虫剤組成物において有効成分として用いられる化合物(I)は公知化合物であり(特許文献1参照)、他の農薬有効成分との組み合わせにより有害生物防除剤として有用なことが報告されている(特許文献2参照)。
Compound (I) used as an active ingredient in the agricultural and horticultural insecticide composition of the present invention is a known compound (see Patent Document 1), and is useful as a pest control agent in combination with other agricultural chemical active ingredients. have been reported (see Patent Document 2).
化合物(II)も公知化合物であり、その殺虫活性等について報告されている(非特許文献1参照)。また、化合物(II)は、他剤との組み合わせによりウンカ類の防除活性を示すことも知られている(特許文献3参照)。しかし、いずれの先行技術文献にも、化合物(I)及び化合物(II)の組み合わせに係る本発明の農園芸用殺虫剤組成物については何ら記載も示唆もされていない。
Compound (II) is also a known compound, and its insecticidal activity has been reported (see Non-Patent Document 1). Compound (II) is also known to exhibit control activity against planthoppers in combination with other agents (see Patent Document 3). However, none of the prior art documents describes or suggests the agricultural and horticultural insecticide composition of the present invention relating to the combination of compound (I) and compound (II).
農作物の栽培においては各種殺虫剤が用いられている。本発明は、各種害虫・ダニ類等の農園芸害虫類に対する優れた防除効力を有する殺虫剤組成物を提供することを課題とする。
即ち、本発明が解決しようとする課題は、化合物(I)又は化合物(II)の各々単独での処理では、対象害虫類等の種類、生育ステージ、生息特性等による効果の差、抵抗性の発達、使用量や防除回数の制限等の理由で有効な防除ができない場合があることである。
それ故、化合物(I)又は化合物(II)の単独の処理では防除が不可能な、又は困難な各種害虫・ダニ類等の農園芸害虫類を効率的に防除するための新たな手段及び方法が求められている。 Various insecticides are used in the cultivation of crops. An object of the present invention is to provide an insecticide composition having an excellent control effect against agricultural and horticultural pests such as various pests and mites.
That is, the problem to be solved by the present invention is that, in the treatment of compound (I) or compound (II) alone, the difference in effect due to the type, growth stage, habitat characteristics, etc. of target pests, etc., and resistance Effective control may not be possible due to reasons such as development, usage amount, and restrictions on the number of times of control.
Therefore, new means and methods for efficiently controlling agricultural and horticultural pests such as various pests and mites that are impossible or difficult to control by single treatment with compound (I) or compound (II). is required.
即ち、本発明が解決しようとする課題は、化合物(I)又は化合物(II)の各々単独での処理では、対象害虫類等の種類、生育ステージ、生息特性等による効果の差、抵抗性の発達、使用量や防除回数の制限等の理由で有効な防除ができない場合があることである。
それ故、化合物(I)又は化合物(II)の単独の処理では防除が不可能な、又は困難な各種害虫・ダニ類等の農園芸害虫類を効率的に防除するための新たな手段及び方法が求められている。 Various insecticides are used in the cultivation of crops. An object of the present invention is to provide an insecticide composition having an excellent control effect against agricultural and horticultural pests such as various pests and mites.
That is, the problem to be solved by the present invention is that, in the treatment of compound (I) or compound (II) alone, the difference in effect due to the type, growth stage, habitat characteristics, etc. of target pests, etc., and resistance Effective control may not be possible due to reasons such as development, usage amount, and restrictions on the number of times of control.
Therefore, new means and methods for efficiently controlling agricultural and horticultural pests such as various pests and mites that are impossible or difficult to control by single treatment with compound (I) or compound (II). is required.
本発明者は、上記課題を解決すべく鋭意研究を重ねた結果、化合物(I)と、化合物(II)とを併用することにより、種々の農園芸害虫類を効率的に防除することができることを見出し、本発明を完成させたものである。
As a result of intensive studies aimed at solving the above problems, the present inventors have found that compound (I) and compound (II) can be used in combination to efficiently control various agricultural and horticultural pests. and completed the present invention.
即ち、少なくとも本発明は以下の各発明に関する。
That is, at least the present invention relates to each of the following inventions.
[1]化合物(I)として5-(1,3-ジオキサン-2-イル)-4-[4-(トリフルオロメチル)ベンジルオキシ]ピリミジン、及び化合物(II)として(1E)-N1-[(6-クロロピリジン-3-イル)メチル]-N1-エチル-N’1-メチル-2-ニトロビニリデン-1,1-ジアミンを含有する農園芸用殺虫剤組成物、
[2]化合物(I)の1質量部に対して、化合物(II)を0.01~2000質量部の割合で含有する、[1]に記載の農園芸用殺虫剤組成物、
[3]農園芸害虫類から有用植物を保護するために、有効量の[1]又は[2]に記載の農園芸用殺虫剤組成物を、対象害虫類、対象有用植物、対象有用植物の種子、土壌又は栽培担体に施用することを特徴とする、農園芸用殺虫剤組成物の使用方法、
[4]5-(1,3-ジオキサン-2-イル)-4-[4-(トリフルオロメチル)ベンジルオキシ]ピリミジン及び(1E)-N1-[(6-クロロピリジン-3-イル)メチル]-N1-エチル-N’1-メチル-2-ニトロビニリデン-1,1-ジアミンを、別個に、同時期に植物又は栽培担体に施用することを特徴とする農園芸害虫類の防除方法、
[5]5-(1,3-ジオキサン-2-イル)-4-[4-(トリフルオロメチル)ベンジルオキシ]ピリミジン及び(1E)-N1-[(6-クロロピリジン-3-イル)メチル]-N1-エチル-N’1-メチル-2-ニトロビニリデン-1,1-ジアミンを、別個に、同時に植物又は栽培担体に施用することを特徴とする農園芸害虫類の防除方法、
[6]5-(1,3-ジオキサン-2-イル)-4-[4-(トリフルオロメチル)ベンジルオキシ]ピリミジン及び(1E)-N1-[(6-クロロピリジン-3-イル)メチル]-N1-エチル-N’1-メチル-2-ニトロビニリデン-1,1-ジアミンを、別個に、時間差をおいて植物又は栽培担体に施用することを特徴とする農園芸害虫類の防除方法、
[7]5-(1,3-ジオキサン-2-イル)-4-[4-(トリフルオロメチル)ベンジルオキシ]ピリミジン及び(1E)-N1-[(6-クロロピリジン-3-イル)メチル]-N1-エチル-N’1-メチル-2-ニトロビニリデン-1,1-ジアミンを含有する殺虫剤組成物、及び
[8](1E)-N1-[(6-クロロピリジン-3-イル)メチル]-N1-エチル-N’1-メチル-2-ニトロビニリデン-1,1-ジアミンと併用するための、5-(1,3-ジオキサン-2-イル)-4-[4-(トリフルオロメチル)ベンジルオキシ]ピリミジンを含有する殺虫剤組成物、
に関する。 [1] 5-(1,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine as compound (I), and (1E)-N1-[ as compound (II) (6-chloropyridin-3-yl)methyl]-N1-ethyl-N'1-methyl-2-nitrovinylidene-1,1-diamine-containing agricultural and horticultural insecticide composition,
[2] The agricultural and horticultural insecticide composition according to [1], which contains 0.01 to 2000 parts by mass of compound (II) per 1 part by mass of compound (I).
[3] In order to protect useful plants from agricultural and horticultural pests, an effective amount of the agricultural and horticultural insecticide composition according to [1] or [2] is applied to target pests, target useful plants, and target useful plants. A method of using an agricultural and horticultural insecticide composition, characterized in that it is applied to seeds, soil or cultivation carriers,
[4] 5-(1,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine and (1E)-N1-[(6-chloropyridin-3-yl)methyl ] -N1-ethyl-N'1-methyl-2-nitrovinylidene-1,1-diamine separately applied to plants or cultivation carriers at the same time, A method for controlling agricultural and horticultural pests,
[5] 5-(1,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine and (1E)-N1-[(6-chloropyridin-3-yl)methyl ] -N1-ethyl-N'1-methyl-2-nitrovinylidene-1,1-diamine separately and simultaneously applied to plants or cultivation carriers, A method for controlling agricultural and horticultural pests,
[6] 5-(1,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine and (1E)-N1-[(6-chloropyridin-3-yl)methyl ] -N1-ethyl-N'1-methyl-2-nitrovinylidene-1,1-diamine is separately applied to a plant or a cultivation carrier with a time lag. ,
[7] 5-(1,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine and (1E)-N1-[(6-chloropyridin-3-yl)methyl ]-N1-ethyl-N'1-methyl-2-nitrovinylidene-1,1-diamine, and [8](1E)-N1-[(6-chloropyridin-3-yl ) 5-(1,3-dioxan-2-yl)-4-[4-( An insecticidal composition containing trifluoromethyl)benzyloxy]pyrimidine,
Regarding.
[2]化合物(I)の1質量部に対して、化合物(II)を0.01~2000質量部の割合で含有する、[1]に記載の農園芸用殺虫剤組成物、
[3]農園芸害虫類から有用植物を保護するために、有効量の[1]又は[2]に記載の農園芸用殺虫剤組成物を、対象害虫類、対象有用植物、対象有用植物の種子、土壌又は栽培担体に施用することを特徴とする、農園芸用殺虫剤組成物の使用方法、
[4]5-(1,3-ジオキサン-2-イル)-4-[4-(トリフルオロメチル)ベンジルオキシ]ピリミジン及び(1E)-N1-[(6-クロロピリジン-3-イル)メチル]-N1-エチル-N’1-メチル-2-ニトロビニリデン-1,1-ジアミンを、別個に、同時期に植物又は栽培担体に施用することを特徴とする農園芸害虫類の防除方法、
[5]5-(1,3-ジオキサン-2-イル)-4-[4-(トリフルオロメチル)ベンジルオキシ]ピリミジン及び(1E)-N1-[(6-クロロピリジン-3-イル)メチル]-N1-エチル-N’1-メチル-2-ニトロビニリデン-1,1-ジアミンを、別個に、同時に植物又は栽培担体に施用することを特徴とする農園芸害虫類の防除方法、
[6]5-(1,3-ジオキサン-2-イル)-4-[4-(トリフルオロメチル)ベンジルオキシ]ピリミジン及び(1E)-N1-[(6-クロロピリジン-3-イル)メチル]-N1-エチル-N’1-メチル-2-ニトロビニリデン-1,1-ジアミンを、別個に、時間差をおいて植物又は栽培担体に施用することを特徴とする農園芸害虫類の防除方法、
[7]5-(1,3-ジオキサン-2-イル)-4-[4-(トリフルオロメチル)ベンジルオキシ]ピリミジン及び(1E)-N1-[(6-クロロピリジン-3-イル)メチル]-N1-エチル-N’1-メチル-2-ニトロビニリデン-1,1-ジアミンを含有する殺虫剤組成物、及び
[8](1E)-N1-[(6-クロロピリジン-3-イル)メチル]-N1-エチル-N’1-メチル-2-ニトロビニリデン-1,1-ジアミンと併用するための、5-(1,3-ジオキサン-2-イル)-4-[4-(トリフルオロメチル)ベンジルオキシ]ピリミジンを含有する殺虫剤組成物、
に関する。 [1] 5-(1,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine as compound (I), and (1E)-N1-[ as compound (II) (6-chloropyridin-3-yl)methyl]-N1-ethyl-N'1-methyl-2-nitrovinylidene-1,1-diamine-containing agricultural and horticultural insecticide composition,
[2] The agricultural and horticultural insecticide composition according to [1], which contains 0.01 to 2000 parts by mass of compound (II) per 1 part by mass of compound (I).
[3] In order to protect useful plants from agricultural and horticultural pests, an effective amount of the agricultural and horticultural insecticide composition according to [1] or [2] is applied to target pests, target useful plants, and target useful plants. A method of using an agricultural and horticultural insecticide composition, characterized in that it is applied to seeds, soil or cultivation carriers,
[4] 5-(1,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine and (1E)-N1-[(6-chloropyridin-3-yl)methyl ] -N1-ethyl-N'1-methyl-2-nitrovinylidene-1,1-diamine separately applied to plants or cultivation carriers at the same time, A method for controlling agricultural and horticultural pests,
[5] 5-(1,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine and (1E)-N1-[(6-chloropyridin-3-yl)methyl ] -N1-ethyl-N'1-methyl-2-nitrovinylidene-1,1-diamine separately and simultaneously applied to plants or cultivation carriers, A method for controlling agricultural and horticultural pests,
[6] 5-(1,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine and (1E)-N1-[(6-chloropyridin-3-yl)methyl ] -N1-ethyl-N'1-methyl-2-nitrovinylidene-1,1-diamine is separately applied to a plant or a cultivation carrier with a time lag. ,
[7] 5-(1,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine and (1E)-N1-[(6-chloropyridin-3-yl)methyl ]-N1-ethyl-N'1-methyl-2-nitrovinylidene-1,1-diamine, and [8](1E)-N1-[(6-chloropyridin-3-yl ) 5-(1,3-dioxan-2-yl)-4-[4-( An insecticidal composition containing trifluoromethyl)benzyloxy]pyrimidine,
Regarding.
本発明の農園芸用殺虫剤組成物の使用により、防除対象となる害虫の範囲を拡大させるとともに、個々の有効成分化合物の使用薬量を低減することができ、各々単独では十分な効果が得られなかった薬量でも顕著な効果が得られる。それ故、本発明の農園芸用殺虫剤組成物は、上記各有効成分単独では防除できなかった各種農園芸害虫類、及び薬剤抵抗性等を示す害虫・ダニ類等の農園芸害虫類に対しても、顕著な防除効果を有するものである。また、本発明の農園芸用殺虫剤組成物は、残効にも優れ、散布回数の低減等により農作業を効率化することができる。さらに、農園芸害虫類の抵抗性の発達を防止することも可能である。
By using the agricultural and horticultural insecticide composition of the present invention, it is possible to expand the range of insect pests to be controlled and to reduce the dosage of each active ingredient compound, and each alone can provide sufficient effects. Significant effects can be obtained even at dosages that were not recommended. Therefore, the agricultural and horticultural insecticide composition of the present invention is effective against various agricultural and horticultural pests that could not be controlled by the above active ingredients alone, and agricultural and horticultural pests such as insect pests and mites that exhibit chemical resistance. However, it has a remarkable control effect. In addition, the agricultural and horticultural insecticide composition of the present invention is excellent in residual effect, and can improve the efficiency of agricultural work by reducing the frequency of spraying. Furthermore, it is also possible to prevent the development of resistance to agricultural and horticultural pests.
本発明の農園芸用殺虫剤組成物(以下、本明細書において「本発明の組成物」ということがある)は、下記式[I]:
The agricultural and horticultural insecticide composition of the present invention (hereinafter sometimes referred to as the "composition of the present invention") has the following formula [I]:
で示される化合物(I)(農薬一般名:ベンズピリモキサン、化学名:5-(1,3-ジオキサン-2-イル)-4-[4-(トリフルオロメチル)ベンジルオキシ]ピリミジン、CAS登録番号:1449021-97-9)、及び
下記式[II]: Compound (I) (agricultural chemical generic name: benzpyrimoxane, chemical name: 5-(1,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine, CAS Registration number: 1449021-97-9), and the following formula [II]:
下記式[II]: Compound (I) (agricultural chemical generic name: benzpyrimoxane, chemical name: 5-(1,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine, CAS Registration number: 1449021-97-9), and the following formula [II]:
で示される化合物(II)(農薬一般名:ニテンピラム、化学名:(1E)-N1-[(6-クロロピリジン-3-イル)メチル]-N1-エチル-N’1-メチル-2-ニトロビニリデン-1,1-ジアミン、CAS登録番号:150824-47-8)を有効成分として含有する。
Compound (II) represented by (agricultural chemical generic name: nitenpyram, chemical name: (1E)-N1-[(6-chloropyridin-3-yl)methyl]-N1-ethyl-N'1-methyl-2-nitro It contains vinylidene-1,1-diamine, CAS registration number: 150824-47-8) as an active ingredient.
本発明の組成物中に、有効成分として含まれる化合物(I)は、前述の特許文献1に開示された製造方法で製造することができる。
The compound (I) contained as an active ingredient in the composition of the present invention can be produced by the production method disclosed in the aforementioned Patent Document 1.
本発明の組成物中のもう一方の有効成分として含まれる化合物(II)は、市販品(例えば、ベストガード(登録商標)水溶剤として市販されている。)をそのまま使用することができ、また、農薬原体供給業者から化合物(II)を購入して製剤化することもできる。
上記化合物(I)又は化合物(II)の等価物である、これら化合物の塩としては、例えば、塩酸塩、硫酸塩、硝酸塩、燐酸塩等の無機酸塩類、酢酸塩、フマル酸塩、マレイン酸塩、シュウ酸塩、メタンスルホン酸塩、ベンゼンスルホン酸塩、パラトルエンスルホン酸塩等の有機酸塩類等が挙げられ、かかる塩も、自体公知の方法に従って製造することができる。 Compound (II) contained as the other active ingredient in the composition of the present invention can be used as is as a commercially available product (for example, best guard (registered trademark) water solvent). , the compound (II) can be purchased from an agricultural chemical technical substance supplier and formulated.
Salts of these compounds, which are equivalents of compound (I) or compound (II), include inorganic acid salts such as hydrochlorides, sulfates, nitrates, phosphates, acetates, fumarates, and maleic acid. Salts, organic acid salts such as oxalates, methanesulfonates, benzenesulfonates, p-toluenesulfonates, etc. can be mentioned, and such salts can also be produced according to methods known per se.
上記化合物(I)又は化合物(II)の等価物である、これら化合物の塩としては、例えば、塩酸塩、硫酸塩、硝酸塩、燐酸塩等の無機酸塩類、酢酸塩、フマル酸塩、マレイン酸塩、シュウ酸塩、メタンスルホン酸塩、ベンゼンスルホン酸塩、パラトルエンスルホン酸塩等の有機酸塩類等が挙げられ、かかる塩も、自体公知の方法に従って製造することができる。 Compound (II) contained as the other active ingredient in the composition of the present invention can be used as is as a commercially available product (for example, best guard (registered trademark) water solvent). , the compound (II) can be purchased from an agricultural chemical technical substance supplier and formulated.
Salts of these compounds, which are equivalents of compound (I) or compound (II), include inorganic acid salts such as hydrochlorides, sulfates, nitrates, phosphates, acetates, fumarates, and maleic acid. Salts, organic acid salts such as oxalates, methanesulfonates, benzenesulfonates, p-toluenesulfonates, etc. can be mentioned, and such salts can also be produced according to methods known per se.
化合物(I)と、化合物(II)を含有する本発明の組成物において、当該組成物100質量部中の有効成分の含有量は、通常0.01質量部~80質量部であり、好ましくは0.1質量部~50質量部であり、より好ましくは0.5質量部~20質量部である。また、有効成分中の化合物(I)と、化合物(II)との含有量比は、化合物(I)が1質量部に対して、化合物(II)が通常0.01質量部~2000質量部であり、好ましくは0.05質量部~100質量部であり、より好ましくは0.1質量部~30質量部である。特に好ましくは、化合物(I)が1質量部に対して、化合物(II)が0.1質量部~10質量部である。
In the composition of the present invention containing compound (I) and compound (II), the content of the active ingredient in 100 parts by mass of the composition is usually 0.01 part by mass to 80 parts by mass, preferably It is 0.1 to 50 parts by mass, more preferably 0.5 to 20 parts by mass. In addition, the content ratio of compound (I) and compound (II) in the active ingredient is usually 0.01 to 2000 parts by mass of compound (II) per 1 part by mass of compound (I). , preferably 0.05 to 100 parts by mass, more preferably 0.1 to 30 parts by mass. Particularly preferably, the amount of compound (II) is 0.1 to 10 parts by mass per 1 part by mass of compound (I).
本発明の組成物を使用する場合、農薬製剤上の常法に従い、使用上都合のよい剤形の製剤として使用するのが一般的である。
即ち、本発明の組成物に用いられる化合物(I)、及び化合物(II)を適当な不活性担体に、必要に応じて補助剤と一緒に適当な割合に配合して溶解、分散、懸濁、混合し、又は含浸、吸着若しくは付着させて、適宜の剤形、例えば、懸濁剤、乳懸濁剤、乳剤、液剤、水和剤、顆粒水和剤、粒剤、粉剤、錠剤、パック剤等に製剤化して使用すればよい。適当な場合には、別の剤形を組み合わせ、組み込み、混合してもよい。例えば、練り込み粒剤と含浸粒剤とを混合してもよく、水和剤と顆粒水和剤とを混合して錠剤として固形化してもよく、懸濁剤と液剤を組み合わせてパック剤等とすることもできる。 When the composition of the present invention is used, it is generally used as a formulation in a dosage form convenient for use in accordance with conventional methods for agricultural chemical formulations.
That is, compound (I) and compound (II) used in the composition of the present invention are blended in a suitable inert carrier, optionally together with an adjuvant, in an appropriate proportion, dissolved, dispersed, or suspended. , mixed, or impregnated, adsorbed or attached to an appropriate dosage form such as suspension, emulsion suspension, emulsion, liquid, wettable powder, wettable granules, granules, powders, tablets, packs It may be used after being formulated into a drug or the like. Where appropriate, other dosage forms may be combined, incorporated and mixed. For example, kneaded granules and impregnated granules may be mixed, wettable powders and wettable granules may be mixed and solidified as tablets, suspensions and liquids may be combined to form packs and the like. can also be
即ち、本発明の組成物に用いられる化合物(I)、及び化合物(II)を適当な不活性担体に、必要に応じて補助剤と一緒に適当な割合に配合して溶解、分散、懸濁、混合し、又は含浸、吸着若しくは付着させて、適宜の剤形、例えば、懸濁剤、乳懸濁剤、乳剤、液剤、水和剤、顆粒水和剤、粒剤、粉剤、錠剤、パック剤等に製剤化して使用すればよい。適当な場合には、別の剤形を組み合わせ、組み込み、混合してもよい。例えば、練り込み粒剤と含浸粒剤とを混合してもよく、水和剤と顆粒水和剤とを混合して錠剤として固形化してもよく、懸濁剤と液剤を組み合わせてパック剤等とすることもできる。 When the composition of the present invention is used, it is generally used as a formulation in a dosage form convenient for use in accordance with conventional methods for agricultural chemical formulations.
That is, compound (I) and compound (II) used in the composition of the present invention are blended in a suitable inert carrier, optionally together with an adjuvant, in an appropriate proportion, dissolved, dispersed, or suspended. , mixed, or impregnated, adsorbed or attached to an appropriate dosage form such as suspension, emulsion suspension, emulsion, liquid, wettable powder, wettable granules, granules, powders, tablets, packs It may be used after being formulated into a drug or the like. Where appropriate, other dosage forms may be combined, incorporated and mixed. For example, kneaded granules and impregnated granules may be mixed, wettable powders and wettable granules may be mixed and solidified as tablets, suspensions and liquids may be combined to form packs and the like. can also be
上記不活性担体としては、固体担体及び液体担体が挙げられ、固体担体としては、例えば、カオリナイト(カオリン)、セリサイト、タルク等の粘土鉱物、ベントナイト、酸性白土、アタパルジャイト等の粘土(クレー)、石英、ピロフィライト、ゼオライト、珪藻土等の鉱物;炭酸カルシウム、硫酸アンモニウム、硫酸ナトリウム、塩化カリウム等の無機塩;沈降法シリカ、ヒュームドシリカ、ケイ酸カルシウム等の合成ケイ酸及び合成ケイ酸塩;デンプン、セルロース、植物粉末(例えば、おがくず、ヤシガラ、トウモロコシ穂軸、タバコ茎等)等の植物性担体;ポリエチレン、ポリプロピレン、ポリスチレン、ポリ塩化ビニリデン、ポリエチレンテレフタレート等のプラスチック樹脂担体;尿素-アルデヒド樹脂等の熱硬化性樹脂;パーライト、バーミキュライト等の多孔質粒状担体;プラスチック中空体等が挙げられる。これらは単独で用いてもよいし、また、2種以上を組み合わせて用いてもよい。
Examples of the inert carrier include solid carriers and liquid carriers. Solid carriers include, for example, kaolinite (kaolin), sericite, clay minerals such as talc, bentonite, acid clay, clay such as attapulgite. Minerals such as quartz, pyrophyllite, zeolite, diatomaceous earth; inorganic salts such as calcium carbonate, ammonium sulfate, sodium sulfate, potassium chloride; synthetic silicic acid and synthetic silicates such as precipitated silica, fumed silica, calcium silicate; starch , cellulose, vegetable powder (e.g., sawdust, coconut shell, corn cob, tobacco stalk, etc.); plastic resin carriers such as polyethylene, polypropylene, polystyrene, polyvinylidene chloride, polyethylene terephthalate; urea-aldehyde resins, etc. thermosetting resins; porous granular carriers such as perlite and vermiculite; plastic hollow bodies; These may be used alone or in combination of two or more.
液体担体としては、例えば、メタノール、エタノール、プロパノール、イソプロパノール、ブタノール等の一価アルコール類、及びエチレングリコール、ジエチレングリコール、プロピレングリコール、ヘキシレングリコール、ポリエチレングリコール、ポリプロピレングリコール、グリセリン等の多価アルコール類等のアルコール類;プロピレングリコールエーテル等の多価アルコール誘導体;アセトン、メチルエチルケトン、メチルイソブチルケトン、ジイソブチルケトン、シクロヘキサノン等のケトン類;エチルエーテル、ジオキサン、エチレングリコールモノエチルエーテル、ジプロピルエーテル、テトラヒドロフラン等のエーテル類;ノルマルパラフィン、ナフテン、イソパラフィン、ケロシン、鉱油等の脂肪族炭化水素類;ベンゼン、トルエン、キシレン、ソルベントナフサ、アルキルナフタレン等の芳香族炭化水素類;ジクロロメタン、クロロホルム、四塩化炭素等のハロゲン化炭化水素類;酢酸エチル、ジイソプロピルフタレート、ジブチルフタレート、ジオクチルフタレート、アジピン酸ジメチル等のエステル類;γ-ブチロラクトン等のラクトン類;ジメチルホルムアミド、ジエチルホルムアミド、ジメチルアセトアミド、N-アルキルピロリドン(N-メチルピロリドン等)等のアミド類;アセトニトリル等のニトリル類;ジメチルスルホキシド等の硫黄化合物類;大豆油、ナタネ油、綿実油、ヒマシ油等の植物油;及び水等を挙げることができる。これらは単独で用いてもよいし、また、2種以上を組み合わせて用いてもよい。
Examples of liquid carriers include monohydric alcohols such as methanol, ethanol, propanol, isopropanol and butanol, and polyhydric alcohols such as ethylene glycol, diethylene glycol, propylene glycol, hexylene glycol, polyethylene glycol, polypropylene glycol and glycerin. polyhydric alcohol derivatives such as propylene glycol ether; ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, and cyclohexanone; ethers such as ethyl ether, dioxane, ethylene glycol monoethyl ether, dipropyl ether, and tetrahydrofuran Aliphatic hydrocarbons such as normal paraffin, naphthene, isoparaffin, kerosene and mineral oil; Aromatic hydrocarbons such as benzene, toluene, xylene, solvent naphtha and alkylnaphthalene; Halogenation such as dichloromethane, chloroform and carbon tetrachloride Hydrocarbons; esters such as ethyl acetate, diisopropyl phthalate, dibutyl phthalate, dioctyl phthalate, dimethyl adipate; lactones such as γ-butyrolactone; dimethylformamide, diethylformamide, dimethylacetamide, N-alkylpyrrolidone (N-methylpyrrolidone etc.); nitriles such as acetonitrile; sulfur compounds such as dimethyl sulfoxide; vegetable oils such as soybean oil, rapeseed oil, cottonseed oil and castor oil; These may be used alone or in combination of two or more.
補助剤としては、分散剤、湿潤剤、拡展剤、展着剤、結合剤、粘着付与剤、増粘剤、着色剤、安定化剤、崩壊剤、及びドリフト防止剤等が挙げられる。その他必要に応じ、植物片等を添加成分に用いてもよい。これらの添加成分は単独で用いてもよいし、また、2種以上を組み合わせて用いてもよい。
Auxiliaries include dispersants, wetting agents, spreaders, spreading agents, binders, tackifiers, thickeners, colorants, stabilizers, disintegrants, anti-drift agents, and the like. In addition, if necessary, plant pieces or the like may be used as additive components. These additive components may be used alone or in combination of two or more.
分散剤としては、各種の界面活性剤が用いられる。
Various surfactants are used as dispersants.
湿潤剤としては、グリセリン、ポリエチレングリコール、ソルビトール等の多価アルコール類;ポリアクリル酸ナトリウム等の水溶性高分子;非イオン性界面活性剤等が用いられる。
As wetting agents, polyhydric alcohols such as glycerin, polyethylene glycol, and sorbitol; water-soluble polymers such as sodium polyacrylate; nonionic surfactants, etc. are used.
拡展剤としては、シリコーン系界面活性剤、セルロース粉末、デキストリン、加工デンプン、ポリアミノカルボン酸のキレート化合物、多価アルコールのポリマーとジカルボン酸無水物とのハーフエステル等が挙げられる。
Examples of extenders include silicone-based surfactants, cellulose powder, dextrin, modified starch, polyaminocarboxylic acid chelate compounds, and half esters of polyhydric alcohol polymers and dicarboxylic acid anhydrides.
展着剤としては、種々の界面活性剤、テルペン、ポリアミド樹脂、ポリオキシエチレンポリオキシプロピレングリコールの高級脂肪酸エステル、ポリアクリル酸塩、ワックス、ポリビニルアルキルエーテル等が挙げられる。
Examples of spreading agents include various surfactants, terpenes, polyamide resins, higher fatty acid esters of polyoxyethylene-polyoxypropylene glycol, polyacrylates, waxes, and polyvinyl alkyl ethers.
上記の分散剤、湿潤剤、拡展剤、展着剤等として用いられる界面活性剤としては、例えば、ソルビタン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ショ糖脂肪酸エステル、ポリオキシエチレン脂肪酸エステル、ポリオキシエチレン樹脂酸エステル、ポリオキシエチレン脂肪酸ジエステル、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンアルキルフェニルエーテル等のポリオキシエチレンアルキルアリールエーテル、ポリオキシエチレンジアルキルフェニルエーテル、ポリオキシエチレンアルキルフェニルエーテルホルマリン縮合物、ポリオキシエチレンポリオキシプロピレンブロックコポリマー、ポリスチレンポリオキシエチレンブロックポリマー、アルキルポリオキシエチレンポリプロピレンブロックコポリマーエーテル、ポリオキシエチレンアルキルアミン、ポリオキシエチレン脂肪酸アミド、ポリオキシエチレン脂肪酸ビスフェニルエーテル、ポリオキシアルキレンベンジルフェニルエーテル、ポリオキシアルキレンスチリルフェニルエーテル、アセチレンジオール、ポリオキシアルキレン付加アセチレンジオール、ポリオキシエチレンエーテル型シリコーン、エステル型シリコーン等のシリコーン系界面活性剤、フッ素系界面活性剤、ポリオキシエチレンひまし油、ポリオキシエチレン硬化ひまし油等の非イオン界面活性剤;
Examples of surfactants used as dispersing agents, wetting agents, spreading agents, and spreading agents include sorbitan fatty acid esters, polyoxyethylene sorbitan fatty acid esters, sucrose fatty acid esters, polyoxyethylene fatty acid esters, poly Oxyethylene resin acid esters, polyoxyethylene fatty acid diesters, polyoxyethylene alkyl ethers, polyoxyethylene alkylaryl ethers such as polyoxyethylene alkylphenyl ethers, polyoxyethylene dialkylphenyl ethers, polyoxyethylene alkylphenyl ether formalin condensates, Polyoxyethylene polyoxypropylene block copolymer, polystyrene polyoxyethylene block polymer, alkyl polyoxyethylene polypropylene block copolymer ether, polyoxyethylene alkylamine, polyoxyethylene fatty acid amide, polyoxyethylene fatty acid bisphenyl ether, polyoxyalkylene benzylphenyl Silicone surfactants such as ether, polyoxyalkylene styrylphenyl ether, acetylene diol, polyoxyalkylene-added acetylene diol, polyoxyethylene ether-type silicone, ester-type silicone, fluorine-based surfactant, polyoxyethylene castor oil, polyoxy nonionic surfactants such as ethylene hydrogenated castor oil;
アルキル硫酸塩、ポリオキシエチレンアルキルエーテル硫酸塩、ポリオキシエチレンアルキルフェニルエーテル硫酸塩、ポリオキシエチレンスチリルフェニルエーテル硫酸塩、アルキルベンゼンスルホン酸塩、アルキルアリールスルホン酸塩、リグニンスルホン酸塩、アルキルスルホコハク酸塩、ナフタレンスルホン酸塩、アルキルナフタレンスルホン酸塩、ナフタレンスルホン酸のホルマリン縮合物の塩、アルキルナフタレンスルホン酸のホルマリン縮合物の塩、脂肪酸塩、ポリカルボン酸塩、ポリアクリル酸塩、N-メチル-脂肪酸サルコシネート、樹脂酸塩、ポリオキシエチレンアルキルエーテルリン酸塩、ポリオキシエチレンアルキルフェニルエーテルリン酸塩等のアニオン界面活性剤;
Alkyl sulfates, polyoxyethylene alkyl ether sulfates, polyoxyethylene alkylphenyl ether sulfates, polyoxyethylene styrylphenyl ether sulfates, alkylbenzenesulfonates, alkylarylsulfonates, ligninsulfonates, alkyl sulfosuccinates , naphthalenesulfonates, alkylnaphthalenesulfonates, salts of formalin condensates of naphthalenesulfonic acid, salts of formalin condensates of alkylnaphthalenesulfonic acids, fatty acid salts, polycarboxylates, polyacrylates, N-methyl- anionic surfactants such as fatty acid sarcosinates, resinates, polyoxyethylene alkyl ether phosphates, polyoxyethylene alkylphenyl ether phosphates;
ラウリルアミン塩酸塩、ステアリルアミン塩酸塩、オレイルアミン塩酸塩、ステアリルアミン酢酸塩、ステアリルアミノプロピルアミン酢酸塩、アルキルトリメチルアンモニウムクロライド、アルキルジメチルベンザルコニウムクロライド等のアルキルアミン塩等のカチオン界面活性剤;アミノ酸型又はベタイン型等の両性界面活性剤等が挙げられる。これらの界面活性剤は単独で用いてもよいし、また、2種以上を組み合わせて用いてもよい。
Cationic surfactants such as alkylamine salts such as laurylamine hydrochloride, stearylamine hydrochloride, oleylamine hydrochloride, stearylamine acetate, stearylaminopropylamine acetate, alkyltrimethylammonium chloride, alkyldimethylbenzalkonium chloride; and amphoteric surfactants such as betaine-type or betaine-type surfactants. These surfactants may be used alone or in combination of two or more.
結合剤又は粘着付与剤としては、例えば、蔗糖等の糖類;デキストリン、水溶性デンプン、加工デンプン、アラビアゴム、キサンタンガム、グアーガム等の多糖類;セルロース粉末、カルボキシメチルセルロース及びその塩等のセルロース及びその誘導体;セファリン、レシチン等のリン脂質;ポリビニルアルコール、ポリビニルアルキルエーテル、ポリビニルアセテート、ポリビニルピロリドン、架橋ポリビニルピロリドン、ポリアクリル酸ナトリウム等のポリアクリル酸塩、平均分子量6000~20000のポリエチレングリコール、平均分子量10万~500万のポリエチレングリコール、ポリアミノカルボン酸キレート化合物、マレイン酸とスチレン類との共重合体、(メタ)アクリル酸系共重合体、多価アルコールからなるポリマーとジカルボン酸無水物とのハーフエステル、ポリスチレンスルホン酸の水溶性塩、ポリアミド樹脂、アルキルフェノールホルマリン縮合物、合成樹脂エマルション等のポリマー;パラフィン、テルペン、ワックス等が挙げられる。
Examples of binders or tackifiers include sugars such as sucrose; polysaccharides such as dextrin, water-soluble starch, modified starch, gum arabic, xanthan gum and guar gum; cellulose and derivatives such as cellulose powder, carboxymethylcellulose and salts thereof. Phospholipids such as cephalin and lecithin; Polyvinyl alcohol, polyvinyl alkyl ether, polyvinyl acetate, polyvinylpyrrolidone, crosslinked polyvinylpyrrolidone, polyacrylates such as sodium polyacrylate, polyethylene glycol having an average molecular weight of 6,000 to 20,000, and an average molecular weight of 100,000 -5 million polyethylene glycol, polyaminocarboxylic acid chelate compound, copolymer of maleic acid and styrenes, (meth)acrylic acid copolymer, half ester of polyhydric alcohol polymer and dicarboxylic anhydride, Water-soluble salts of polystyrene sulfonic acid, polyamide resins, alkylphenol-formalin condensates, polymers such as synthetic resin emulsions; paraffins, terpenes, waxes, and the like.
増粘剤としては、例えば、キサンタンガム、グアーガム、ダイユウタンガム、デンプン誘導体等の多糖類;カルボキシメチルセルロース、ポリビニルピロリドン、カルボキシビニルポリマー、アクリル系ポリマー等の水溶性高分子;高純度ベントナイト、フュームド シリカ(fumed silica, ホワイトカーボン)等の無機微粉末等が挙げられる。
Examples of thickeners include polysaccharides such as xanthan gum, guar gum, diyutan gum, and starch derivatives; water-soluble polymers such as carboxymethyl cellulose, polyvinylpyrrolidone, carboxyvinyl polymer, and acrylic polymers; fumed silica, white carbon) and other inorganic fine powders.
着色剤としては、例えば、酸化鉄、酸化チタン、プルシアンブルー等の無機顔料;アリザリン染料、アゾ染料、金属フタロシアニン染料のような有機顔料等が挙げられる。
Examples of coloring agents include inorganic pigments such as iron oxide, titanium oxide, and Prussian blue; organic pigments such as alizarin dyes, azo dyes, and metal phthalocyanine dyes.
安定化剤としては、安息香酸ナトリウム、ソルビン酸カリウム、パラヒドロキシ安息香酸エステル、1,2-ベンゾチアゾリン-3-オン、ホルマリン溶液等の防腐剤;エチレングリコール、ジエチレングリコール、プロピレングリコール、グリセリン等の多価アルコール類等の凍結復元剤;デンプン、アルギン酸、マンノース、ガラクトース等の糖類、ポリビニルピロリドン、フュームドシリカ(fumed silica, ホワイトカーボン)、エステルガム、石油樹脂等の固結防止剤;ゼオライト、生石灰、酸化マグネシウム等の乾燥剤、フェノール系酸化防止剤、アミン系酸化防止剤、イオウ系酸化防止剤、リン酸系酸化防止剤等の酸化防止剤、ベンゾフェノン系紫外線吸収剤等の紫外線吸収剤等の分解防止剤等が挙げられる。
Examples of stabilizers include preservatives such as sodium benzoate, potassium sorbate, p-hydroxybenzoic acid ester, 1,2-benzothiazolin-3-one, and formalin solutions; Anti-caking agents such as starch, alginic acid, mannose, galactose, polyvinylpyrrolidone, fumed silica (white carbon), ester gum, petroleum resin; zeolite, quicklime, Decomposition of drying agents such as magnesium oxide, antioxidants such as phenol antioxidants, amine antioxidants, sulfur antioxidants, phosphoric acid antioxidants, and UV absorbers such as benzophenone UV absorbers. inhibitors and the like.
崩壊剤としては、トリポリリン酸ナトリウム、ヘキサメタリン酸ナトリウム、ステアリン酸金属塩、セルロース粉末、デキストリン、メタクリル酸エステル共重合体、ポリビニルピロリドン、ポリアミノカルボン酸キレート化合物、スルホン化スチレン・イソブチレン・無水マレイン酸共重合体、デンプン・ポリアクリロニトリルグラフト共重合体等が挙げられる。
Disintegrants include sodium tripolyphosphate, sodium hexametaphosphate, metal stearate, cellulose powder, dextrin, methacrylic acid ester copolymer, polyvinylpyrrolidone, polyaminocarboxylic acid chelate compound, sulfonated styrene/isobutylene/maleic anhydride copolymer. coalescence, starch-polyacrylonitrile graft copolymer, and the like.
ドリフト防止剤としては、乳剤の場合、メチルセルロース、ポリビニルアルコール、デンプン等の水溶性高分子が用いられ、油剤にはポリイソブチレンが用いられる。水和剤では、ポリエチレングリコール、ポリプロピレングリコール、グリセリン等が用いられ、粉剤には、石油樹脂、ポリスチレン、ポリ酢酸ビニル、エポキシ樹脂等が用いられる。
As anti-drift agents, water-soluble polymers such as methyl cellulose, polyvinyl alcohol, and starch are used for emulsions, and polyisobutylene is used for oils. As wettable powders, polyethylene glycol, polypropylene glycol, glycerin, etc. are used, and as powders, petroleum resins, polystyrene, polyvinyl acetate, epoxy resins, etc. are used.
更に必要に応じてピペロニルブトキサイド等の代謝分解阻害剤等の活性増強剤も使用することができる。
Furthermore, activity enhancers such as metabolic degradation inhibitors such as piperonyl butoxide can also be used as necessary.
本発明の組成物は、化合物(I)及び化合物(II)以外の他の殺虫剤、殺ダニ剤、殺菌剤、除草剤、植物成長調節剤、肥料等と混合して用いることもできる。混合して用いることができる薬剤としては、ペスティサイドマニュアル(第17版 The British Crop Protection Council 発行)に記載の化合物が挙げられる。より具体的には、殺虫活性、殺菌活性又は除草活性を有し、農園芸用殺虫剤、農園芸用殺菌剤若しくは農園芸用生物農薬類、又は農園芸用除草剤として有効な薬剤であれば、特に制限されることなく用いることができ、例えば、a.有機リン系化合物、b.カーバメート系化合物、c.ピレスロイド系化合物、d.フェニルピラゾール系化合物、e.ニコチン及びネオニコチノイド系化合物、f.テトロン酸及びテトラミン酸誘導体、g.ジアミド系化合物、h.ジアシル-ヒドラジン系化合物、i.マクロライド系化合物、j.ネライストキシン類縁化合物、k.スピノシン系化合物、l.セミカルバゾン化合物、m.昆虫成長調節作用を有する化合物、n.微生物が生成する殺虫タンパク質等の成分が挙げられる。
The composition of the present invention can also be used by mixing with insecticides, acaricides, fungicides, herbicides, plant growth regulators, fertilizers, etc. other than compound (I) and compound (II). Agents that can be mixed and used include compounds described in The Pesticide Manual (published by The British Crop Protection Council, 17th edition). More specifically, if it has insecticidal activity, fungicidal activity or herbicidal activity and is effective as an agricultural and horticultural insecticide, an agricultural and horticultural fungicide, an agricultural and horticultural biopesticide, or an agricultural and horticultural herbicide , can be used without particular limitation, for example, a. organophosphorus compounds, b. carbamate compounds, c. pyrethroid compounds, d. phenylpyrazole compounds, e. nicotine and neonicotinoid compounds, f. tetronic acid and tetramic acid derivatives, g. diamide compounds, h. diacyl-hydrazine compounds, i. macrolide compounds, j. nereistoxin analogues, k. spinosyn compounds, l. semicarbazone compounds, m. compounds with insect growth regulating activity, n. Ingredients such as insecticidal proteins produced by microorganisms can be mentioned.
a.有機リン系化合物としては、アセチルコリンエステラーゼ(AChE)阻害剤として作用する化合物が好ましく用いられ、例えば、アザメチホス、アジンホスエチル、アジンホスメチル、カズサホス、クロレトキシホス、クロルフェンビンホス(CVP)、クロルメホス、クマホス、シアノホス(CYAP)、ジメトン-S-メチル、ダイアジノン、ジクロルボス(DDVP)、ジクロトホス、ジメトエート、ジメチルビンホス、エチルチオメトン(ジスルホトン)、O-エチル-O-4-ニトロフェニルフェニルフォスフォノチオエート(EPN)、エチオン、エトプロホス、ファムフル、フェナミホス、フェニトロチオン(MEP)、フェンチオン(MPP)、ホスチアゼート、ヘプテノホス、イミシアホス、イソフェンホス、イソプロピルO-(メトキシアミノチオホスホリル)サリチラート、イソキサチオン、マラソン(マラチオン)、メカルバム、メタミドホス、メチダチオン(DMTP)、メビンホス、モノクロトホス、ナレッド(BRP)、オメトエート、オキシジメトンメチル、パラチオン、メチルパラチオン(パラチオンメチル)、フェントエート(PAP)、ホレート、ホサロン、ホスメット(PMP)、ホスファミドン、ホキシム、ピリミホスメチル、プロフェノホス、プロペタムホス、プロチオホス、ピラクロホス、ピリダフェンチオン、キナルホス、スルホテップ、テブピリムホス、テメホス、テルブホス、テトラクロルビンホス(CVMP)、チオメトン、トリアゾホス、トリクロルホン(DEP)、バミドチオン、クロルピリホス、クロルピリホスメチル、アセフェート等が挙げられる。
a. As organic phosphorous compounds, compounds that act as acetylcholinesterase (AChE) inhibitors are preferably used. ), dimethone-S-methyl, diazinon, dichlorvos (DDVP), dicrotophos, dimethoate, dimethylvinphos, ethyl thiomethone (disulfotone), O-ethyl-O-4-nitrophenylphenylphosphonothioate (EPN), ethione, ethprophos , famflu, fenamiphos, fenitrothion (MEP), fenthion (MPP), fosthiazate, heptenophos, imiciaphos, isofenphos, isopropyl O-(methoxyaminothiophosphoryl) salicylate, isoxathion, marathon (malathion), mecarbam, methamidophos, methidathion (DMTP), mevinphos, monocrotophos, nared (BRP), omethoate, oxydimetone methyl, parathion, methyl parathion (parathion methyl), phenthoate (PAP), folate, fosarone, phosmet (PMP), phosphamidone, phoxime, pirimiphos methyl, profenophos, propetamphos, prothiophos, pyraclophos, pyridafenthion, quinalphos, sulfotep, tebupyrimphos, temefos, terbufos, tetrachlorbinphos (CVMP), thiometone, triazophos, trichlorofone (DEP), vamidothion, chlorpyrifos, chlorpyrifos-methyl, acephate and the like.
b.カーバメート系化合物としては、アセチルコリンエステラーゼ(AChE)阻害剤として作用する化合物が好ましく用いられ、例えば、アラニカルブ、アルジカルブ、ベンダイオカルブ、ベンフラカルブ、ブトカルボキシム、ブトキシカルボキシム、カルバリル(NAC)、カルボフラン、カルボスルファン、エチオフェンカルブ、ホルメタネート、フラチオカルブ、イソプロカルブ(MIPC)、メチオカルブ、メソミル、メトルカルブ(MTMC)、オキサミル、ピリミカーブ、プロポキスル(PHC)、チオジカルブ、チオファノックス、トリアザメート、トリメタカルブ、メチルカルバミン酸3,5-ジメチルフェニル(XMC)、キシリルカルブ(MPMC)、フェノブカルブ(BPMC)等が挙げられる。
b. As carbamate compounds, compounds that act as acetylcholinesterase (AChE) inhibitors are preferably used. Sulfan, Ethiophenecarb, Formetanate, Furatiocarb, Isoprocarb (MIPC), Methiocarb, Methomyl, Metolcarb (MTMC), Oxamyl, Pirimicarb, Propoxur (PHC), Thiodicarb, Thiophanox, Triazamate, Trimetacarb, 3,5-dimethylphenyl methylcarbamate (XMC), xylylcarb (MPMC), fenocarb (BPMC) and the like.
c.ピレスロイド系化合物としては、ナトリウムチャネルモジュレーターとして作用する化合物が好ましく用いられ、例えば、アクリナトリン、ビフェントリン、シクロプロトリン、シフルトリン、ベータ-シフルトリン、シハロトリン、ラムダ-シハロトリン、ガンマ-シハロトリン、シペルメトリン、アルファ-シペルメトリン、ベータ-シペルメトリン、シータ-シペルメトリン、ゼータ-シペルメトリン、デルタメトリン、エトフェンプロックス、フェンプロパトリン、フェンバレレート、エスフェンバレレート、フルシトリネート、フルバリネート、タウ-フルバリネート、ハルフェンプロックス、ペルメトリン、シラフルオフェン、テフルトリン、トラロメトリン、プロトリフェンビュート等が挙げられる。
c. As pyrethroid compounds, compounds that act as sodium channel modulators are preferably used. permethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, deltamethrin, etofenprox, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau-fluvalinate, halfenprox, permethrin, silafluofen, tefluthrin, tralomethrin, protrifenbute and the like.
d.フェニルピラゾール系化合物としては、GABA作動性塩素イオンチャネルブロッカーとして作用する化合物が好ましく用いられ、例えば、エチプロール、フィプロニル、アセトプロール、バニリプロール、ピリプロール、ピラフルプロール等が挙げられる。
d. As the phenylpyrazole compound, a compound that acts as a GABAergic chloride ion channel blocker is preferably used.
e.ニコチン及びネオニコチノイド系化合物としては、ニコチン性アセチルコリン受容体(nAChR)競合的モジュレーターとして作用する化合物が好ましく用いられる。
ネオニコチノイド系化合物としては、例えば、イミダクロプリド、クロチアニジン、チアメトキサム、ジノテフラン、アセタミプリド、チアクロプリド等が挙げられる。
また、ネオニコチノイド系化合物には、ニコチン性アセチルコリン受容体(nAChR)競合的モジュレーターとして機能するスルホキサフロル等のスルフィルイミンS-オキシド化合物、フルピラジフロン等のブテノライド系化合物、トリフルメゾピリム、ジクロロメゾチアズ等のメソイオン系化合物も含まれる。
ニコチン系化合物としては、硫酸ニコチン等が挙げられる。 e. Compounds that act as nicotinic acetylcholine receptor (nAChR) competitive modulators are preferably used as nicotine and neonicotinoid compounds.
Neonicotinoid compounds include, for example, imidacloprid, clothianidin, thiamethoxam, dinotefuran, acetamiprid, thiacloprid and the like.
In addition, neonicotinoid compounds include sulphylimine S-oxide compounds such as sulfoxaflor that function as competitive nicotinic acetylcholine receptor (nAChR) modulators, butenolide compounds such as flupyradifuron, triflumesopyrim, and dichloromesotiaz. and other mesoionic compounds are also included.
Examples of nicotine-based compounds include nicotine sulfate and the like.
ネオニコチノイド系化合物としては、例えば、イミダクロプリド、クロチアニジン、チアメトキサム、ジノテフラン、アセタミプリド、チアクロプリド等が挙げられる。
また、ネオニコチノイド系化合物には、ニコチン性アセチルコリン受容体(nAChR)競合的モジュレーターとして機能するスルホキサフロル等のスルフィルイミンS-オキシド化合物、フルピラジフロン等のブテノライド系化合物、トリフルメゾピリム、ジクロロメゾチアズ等のメソイオン系化合物も含まれる。
ニコチン系化合物としては、硫酸ニコチン等が挙げられる。 e. Compounds that act as nicotinic acetylcholine receptor (nAChR) competitive modulators are preferably used as nicotine and neonicotinoid compounds.
Neonicotinoid compounds include, for example, imidacloprid, clothianidin, thiamethoxam, dinotefuran, acetamiprid, thiacloprid and the like.
In addition, neonicotinoid compounds include sulphylimine S-oxide compounds such as sulfoxaflor that function as competitive nicotinic acetylcholine receptor (nAChR) modulators, butenolide compounds such as flupyradifuron, triflumesopyrim, and dichloromesotiaz. and other mesoionic compounds are also included.
Examples of nicotine-based compounds include nicotine sulfate and the like.
f.テトロン酸及びテトラミン酸誘導体としては、アセチルCoAカルボキシラーゼ阻害剤として作用する化合物が好ましく用いられ、例えば、スピロジクロフェン、スピロメシフェン、スピロテトラマト等が挙げられる。
f. As tetronic acid and tetramic acid derivatives, compounds that act as acetyl-CoA carboxylase inhibitors are preferably used, and examples thereof include spirodiclofen, spiromesifen, and spirotetramato.
g.ジアミド系化合物としては、リアノジン受容体モジュレーターとして作用する化合物が好ましく用いられ、例えば、フルベンジアミド、クロラントラニリプロール、シアントラニリプロール、シクラニリプロール、シハロジアミド、テトラニリプロール等が挙げられる。
g. As the diamide compound, a compound acting as a ryanodine receptor modulator is preferably used, and examples thereof include flubendiamide, chlorantraniliprole, cyantraniliprole, cyclaniliprole, cyhalodiamide, and tetraniliprole.
h.ジアシル-ヒドラジン系化合物としては、脱皮ホルモン(エクダイソン)受容体アゴニストとして作用する化合物が好ましく用いられ、例えば、クロマフェノジド、ハロフェノジド、メトキシフェノジド、フランテブフェノジド、N’-ベンゾイル-N-t-ブチルベンゾヒドラジド(N'-benzoyl-N-tert-butylbenzohydrazide)、テブフェノジド等が挙げられる。
h. As diacyl-hydrazine compounds, compounds that act as molting hormone (ecdysone) receptor agonists are preferably used. '-benzoyl-N-tert-butylbenzohydrazide), tebufenozide and the like.
i.マクロライド系化合物としては、グルタミン酸作動性塩素イオンチャネル(GluCl)アロステリックモジュレーターとして作用する化合物が好ましく用いられ、アバメクチン、イベルメクチン、エプリノメクチン、エマメクチン、エマメクチン安息香酸塩、セラメクチン、ミルベメクチン、モキシデクチン、ドラメクチン、レピメクチン等が挙げられる。
i. As macrolide compounds, compounds that act as glutamatergic chloride channel (GluCl) allosteric modulators are preferably used, and include abamectin, ivermectin, eprinomectin, emamectin, emamectin benzoate, selamectin, milbemectin, moxidectin, doramectin, lepimectin, and the like. is mentioned.
j.ネライストキシン類縁化合物としては、ニコチン性アセチルコリン受容体(nAChR)チャネルブロッカーとして作用する化合物が好ましく用いられ、例えば、ベンスルタップ、カルタップ塩酸塩、ポリチアラン、チオシクラム、チオスルタップナトリウム塩等が挙げられる。
j. As the nereistoxin-related compound, a compound that acts as a nicotinic acetylcholine receptor (nAChR) channel blocker is preferably used.
k.スピノシン系化合物としては、ニコチン性アセチルコリン受容体(nAChR)アロステリックモジュレーターとして作用する化合物が好ましく用いられ、例えば、スピネトラム、スピノサド等が挙げられる。
k. As spinosyn compounds, compounds that act as nicotinic acetylcholine receptor (nAChR) allosteric modulators are preferably used, and examples thereof include spinetoram, spinosad and the like.
l.セミカルバゾン化合物としては、電位依存性ナトリウムチャネルブロッカーとして作用する化合物が好ましく用いられ、例えば、インドキサカルブ、メタフルミゾン等が挙げられる。
l. As semicarbazone compounds, compounds that act as voltage-gated sodium channel blockers are preferably used, and examples thereof include indoxacarb and metaflumizone.
m.昆虫成長調節作用を有する化合物として、ビストリフルロン、クロルフルアズロン等のベンゾイル尿素系化合物、ブプロフェジン等のチアジアジノン系化合物、ピメトロジン、フロニカミド、アフィドピロペン等の弦音器官モジュレーターとして作用する化合物、ピリフルキナゾン等が挙げられる。
m. Examples of compounds having an insect growth-regulating action include benzoyl urea compounds such as bistriflurone and chlorfluazurone, thiadiazinon compounds such as buprofezin, compounds acting as chordotonal modulators such as pymetrozine, flonicamid, and aphidopyropene, and pyrifluquinazone. be done.
n.微生物が生成する殺虫タンパク質としては、バチルス・チューリンゲンシス(Bacillus thuringienses)、例えば、バチルス・チューリンゲンシス・アイザワイ(Bacillus thuringienses aizawai)、バチルス・チューリンゲンシス・イスラエレンシス(Bacillus thuringienses israelensis)、バチルス・チューリンゲンシス・ジャポネンシス(Bacillus thuringienses japonensis)、バチルス・チューリンゲンシス・クルスターキ(Bacillus thuringienses kurstaki)、バチルス・チューリンゲンシス・テネブリオニス(Bacillus thuringienses tenebrionis)等が生成する結晶タンパク毒素(Btトキシン系殺虫性化合物)等が挙げられる。
n. Examples of insecticidal proteins produced by microorganisms include Bacillus thuringiensis, for example, Bacillus thuringiensis aizawai, Bacillus thuringiensis israelensis, Bacillus thuringiensis・Crystalline protein toxins (Bt toxin insecticidal compounds) produced by Bacillus thuringienses japonensis, Bacillus thuringienses kurstaki, Bacillus thuringienses tenebrionis, etc. .
本発明の組成物に加える場合には、上記したa.群~o.群の化合物又は成分は、1種を選択して用いてもよく、2種以上を選択し、組み合わせて用いてもよい。
When added to the composition of the present invention, the above a. Group-o. One of the compounds or components of the group may be selected and used, or two or more may be selected and used in combination.
また、本発明の組成物に他の薬剤として混合して用いることができる薬剤として、下記の有効成分群Aから1種又は2種以上を選択して用いてもよい。
有効成分群Aは、(A1)農園芸用殺虫剤群;3,5-キシリルメチルカルバメイト(3,5-xylyl methylcarbamate)(XMC)、バチルス・チューリンゲンシス(Bacillus thuringienses:例えば、バチルス・チューリンゲンシス・アイザワイ(Bacillus thuringienses aizawai)、バチルス・チューリンゲンシス・イスラエレンシス(Bacillus thuringienses israelensis)、バチルス・チューリンゲンシス・ジャポネンシス(Bacillus thuringienses japonensis)、バチルス・チューリンゲンシス・クルスターキ(Bacillus thuringienses kurstaki)、バチルス・チューリンゲンシス・テネブリオニス(Bacillus thuringienses tenebrionis)等)が生成する結晶タンパク毒素(Btトキシン系殺虫性化合物)、フェノブカルブ(Methylcarbamic acid 2-sec-butylphenyl ester )(BPMC)、クロルフェンソン(chlorfenson)(CPCBS)、ジクロロジイソプロピルエーテル(dichlorodiisopropyl ether)(DCIP)、1,3-ジクロロプロペン(1, 3-Dichloropropene)(D-D)、ジクロロジフェニルトリクロロエタン(Dichlorodiphenyltrichloroethane)(DDT)、カルバリル(1-Naphthyl N-methylcarbamate)(NAC)、O-4-ジメチルスルファモイルフェニル O,O-ジエチルフォスフォロチオエート (O-4-dimethylsulfamoylphenyl O,O-diethyl phosphorothioate)(DSP)、O-エチル-O-4-ニトロフェニルフェニルフォスフォノチオエート(O-ethyl O-4-nitrophenyl phenylphosphonothioate)(EPN)、トリプロピルイソシアヌレート(tripropylisocyanurate)(TPIC)、アクリナトリン(acrinathrin)、アザディラクチン(azadirachtin)、アジンホスメチル(azinphosmethyl)、アセキノシル(acequinocyl)、アセタミプリド(acetamiprid)、アセトプロール(acetoprole)、アセフェート(acephate)、アバメクチン(abamectin)、アフィドピロペン(afidopyropen)、アベルメクチン(avermectin)、アミドフルメット(amidoflumet)、アミトラズ(amitraz)、アラニカルブ(alanycarb)、アルジカルブ(aldicarb)、アルドキシカルブ(aldoxycarb)、アルドリン(aldrin)、アルファ-エンドスルファン(alpha-endosulfan)、アルファ-シペルメトリン(alpha-cypermethrin)、アルベンダゾール(albendazole)、アレスリン(allethrin)、イサゾホス(isazofos)、イサミドホス(isamidofos)、イソキサチオン(isoxathion)、イソフェンホス(isofenphos)、イソプロカルブ(isoprocarb)(MIPC)、イベルメクチン(ivermectin)、イミシアホス(imicyafos)、イミダクロプリド(imidacloprid)、イミプロトリン(imiprothrin)、インドキサカルブ(indoxacarb)、エスフェンバレレート(esfenvalerate)、エチオフェンカルブ(ethiofencarb)、エチオン(ethion)、エチプロール(ethiprole)、エトキサゾール(etoxazole)、エトフェンプロックス(ethofenprox)、エトプロホス(ethoprophos)、エトリムホス(etrimfos)、エマメクチン(emamectin)、エマメクチンベンゾエート(emamectin benzoate)、エンドスルファン(endosulfan)、エンペントリン(empenthrin)、オキサミル(oxamyl)、オキシジメトンメチル(oxydemeton methyl)、オキシデプロホス(oxydeprofos: ESP)、オキシベンダゾール(oxibendazole)、オクスフェンダゾール(oxfendazole)、オレイン酸カリウム(Potassium oleate)、オレイン酸ナトリウム(sodium oleate)、カズサホス(cadusafos)、カルタップ(cartap)、カルバリル(carbaryl)、カルボスルファン(carbosulfan)、カルボフラン(carbofuran)、ガンマ-シハロトリン(gamma-cyhalothrin)、キシリルカルブ(xylylcarb)、キナルホス(quinalphos)、キノプレン(kinoprene)、キノメチオネート(chinomethionat)、クロエトカルブ(cloethocarb)、クロチアニジン(clothianidin)、クロフェンテジン(clofentezine)、クロマフェノジド(chromafenozide)、クロラントラニリプロール(chlorantraniliprole)、クロルエトキシホス(chlorethoxyfos)、クロルジメホルム(chlordimeform)、クロルデン(chlordane)、クロルピリホス(chlorpyrifos)、クロルピリホスメチル(chlorpyrifos-methyl)、クロルフェナピル(chlorphenapyr)、クロルフェンソン(chlorfenson)、クロルフェンビンホス(chlorfenvinphos)、クロルフルアズロン(chlorfluazuron)、クロルベンジレート(chlorobenzilate)、クロロベンゾエート(chlorobenzoate)、ケルセン(ジコホル)(dicofol)、サリチオン(salithion)、シアノホス(cyanophos)(CYAP)、ジアフェンチウロン(diafenthiuron)、ジアミダホス(diamidafos)、シアントラニリプロール(cyantraniliprole)、シータ-シペルメトリン(theta-cypermethrin)、ジエノクロル(dienochlor)、シエノピラフェン(cyenopyrafen)、ジオキサベンゾホス(dioxabenzofos)、ジオフェノラン(diofenolan)、シグマ-シペルメトリン(sigma-cypermethrin)、シクラニリプロール(cyclaniliprole)、ジクロフェンチオン(dichlofenthion)(ECP)、シクロプロトリン(cycloprothrin)、ジクロルボス(dichlorvos)(DDVP)、ジスルホトン(disulfoton)、ジノテフラン(dinotefuran)、シハロトリン(cyhalothrin)、シフェノトリン(cyphenothrin)、シフルトリン(cyfluthrin)、ジフルベンズロン(diflubenzuron)、シフルメトフェン(cyflumetofen)、ジフロビダジン(diflovidazin)、水酸化トリシクロヘキシルスズ(シヘキサチン)(cyhexatin)、シペルメトリン(cypermethrin)、ジメチルビンホス(dimethylvinphos)、ジメトエート(dimethoate)、ジメフルスリン(dimefluthrin)、シラフルオフェン(silafluofen)、シロマジン(cyromazine)、スピネトラム(spinetoram)、スピノサド(spinosad)、スピロジクロフェン(spirodiclofen)、スピロテトラマト(spirotetramat)、スピロメシフェン(spiromesifen)、スルフルラミド(sulfluramid)、スルプロホス(sulprofos)、スルホキサフロル(sulfoxaflor)、ゼータ-シペルメトリン(zeta-cypermethrin)、ダイアジノン(diazinon)、タウ-フルバリネート(tau-fluvalinate)、ダゾメット(dazomet)、チアクロプリド(thiacloprid)、チアメトキサム(thiamethoxam)、チオキサザフェン(tioxazafen)、チオジカルブ(thiodicarb)、チオシクラム(thiocyclam)、チオスルタップ(thiosultap)、チオスルタップナトリウム(thiosultap-sodium)、チオナジン(thionazin)、チオメトン(thiometon)、ディート(deet)、ディルドリン(dieldrin)、テトラクロルビンホス(tetrachlorvinphos)、テトラジホン(tetradifon)、テトラニリプロール(tetraniliprole)、テトラメチルフルトリン(tetramethylfluthrin)、テトラメトリン(tetramethrin)、テブピリムホス(tebupirimfos)、テブフェノジド(tebufenozide)、テブフェンピラド(tebufenpyrad)、テフルトリン(tefluthrin)、テフルベンズロン(teflubenzuron)、デメトン-S-メチル(demeton-S-methyl)、テメホス(temephos)、デルタメトリン(deltamethrin)、テルブホス(terbufos)、トラロピリル(tralopyril)、トラロメトリン(tralomethrin)、トランスフルトリン(transfluthrin)、トリアザメート(triazamate)、トリアズロン(triazuron)、トリクラミド(trichlamide)、トリクロルホン(trichlorphon)(DEP)、トリフルムロン(triflumuron)、トリフルメゾピリム(triflumezopyrim)、トルフェンピラド(tolfenpyrad)、ナレッド(naled)(BRP)、ニチアジン(nithiazine)、ノバルロン(novaluron)、ノビフルムロン(noviflumuron)、ハイドロプレン(hydroprene)、バニリプロール(vaniliprole)、バミドチオン(vamidothion)、パラチオン(parathion)、パラチオン-メチル(parathion-methyl)、ハルフェンプロックス(halfenprox)、ハロフェノジド(halofenozide)、ビストリフルロン(bistrifluron)、ビスルタップ(bisultap)、ヒドラメチルノン(hydramethylnon)、ヒドロキシプロピルデンプン(hydroxy propyl starch)、ビナパクリル(binapacryl)、ビフェナゼート(bifenazate)、ビフェントリン(bifenthrin)、ピフルブミド(pyflubumide)、ピメトロジン(pymetrozine)、ピラクロホス(pyraclorfos)、ピラフルプロール(pyrafluprole)、ピリダフェンチオン(pyridafenthion)、ピリダベン(pyridaben)、ピリダリル(pyridalyl)、ピリフルキナゾン(pyrifluquinazon)、ピリプロール(pyriprole)、ピリプロキシフェン(pyriproxyfen)、ピリミカーブ(pirimicarb)、ピリミジフェン(pyrimidifen)、ピリミホスメチル(pirimiphos methyl)、ピレトリン(pyrethrin)、フィプロニル(fipronil)、フェナザキン(fenazaquin)、フェナミホス(fenamiphos)、フェニソブロモレート(phenisobromolate)、フェニトロチオン(fenitrothion)(MEP)、フェノキシカルブ(fenoxycarb)、フェノチオカルブ(fenothiocarb)、フェノトリン(phenothrin)、フェンスルフォチオン(fensulfothion)、フェンチオン(fenthion)(MPP)、フェントエート(phenthoate)(PAP)、フェンバレレート(fenvalerate)、フェンピロキシメート(fenpyroximate)、フェンプロパトリン(fenpropathrin)、フェンベンダゾール(fenbendazole)、ブタチオホス(butathiofos)、ブプロフェジン(buprofezin)、フラチオカルブ(furathiocarb)、プラレトリン(prallethrin)、フルアクリピリム(fluacrypyrim)、フルアジナム(fluazinam)、フルアズロン(fluazuron)、フルエンスルホン(fluensulfone)、フルシクロクスロン(flucycloxuron)、フルシトリネート(flucythrinate)、フルバリネート(fluvalinate)、フルピラジフロン(flupyradifurone)、フルピラゾホス(flupyrazofos)、フルフィプロール(flufiprole)、フルフェネリム(flufenerim)、フルフェノクスロン(flufenoxuron)、フルフェンジン(flufenzine)、フルフェンプロックス(flufenprox)、フルプロキシフェン(fluproxyfen)、フルブロシスリネート(flubrocythrinate)、フルヘキサホン(fluhexafon)、フルベンジアミド(flubendiamide)、フルメトリン(flumethrin)、フルリムフェン(flurimfen)、プロチオホス(prothiofos)、プロトリフェンブト(protrifenbute)、フロニカミド(flonicamid)、プロパホス(propaphos)、プロパルギット(propargite)(BPPS)、プロフェノホス(profenofos)、プロフルスリン(profluthrin)、プロポキスル(propoxur)(PHC)、フロメトキン(flometoquin)、ブロモプロピレート(bromopropylate)、ベータ-シフルトリン(beta-cyfluthrin)、ヘキサフルムロン(hexaflumuron)、ヘキシチアゾクス(hexythiazox)、ヘプタフルスリン(heptafluthrin)、ヘプテノホス(heptenophos)、ペルメトリン(permethrin)、ベンクロチアズ(benclothiaz)、ベンジオカルブ(bendiocarb)、ベンスルタップ(bensultap)、ベンゾキシメート(benzoximate)、ベンフラカルブ(benfuracarb)、ホキシム(phoxim)、ホサロン(phosalone)、ホスチアゼート(fosthiazate)、ホスチエタン(fosthietan)、ホスファミドン(phosphamidon)、ホスホカルブ(phosphocarb)、ホスメット(phosmet)(PMP)、ポリナクチン複合体(polynactins)、ホルメタネート(formetanate)、ホルモチオン(formothion)、ホレート(phorate)、マシン油(machine oil)、マラチオン(malathion)、ミルベマイシン(milbemycin)、ミルベマイシンA(milbemycin A)、ミルベメクチン(milbemectin)、メカルバム(mecarbam)、メスルフェンホス(mesulfenfos)、メソミル(methomyl)、メタアルデヒド(metaldehyde)、メタフルミゾン(metaflumizone)、メタミドホス(methamidophos)、メタムアンモニウム(metam-ammonium)、メタムナトリウム(metam-sodium)、メチオカルブ(methiocarb)、メチダチオン(methidathion)(DMTP)、メチルイソチオシアネート(methylisothiocyanate)、メチルネオデカナミド(methylneodecanamide)、メチルパラチオン(methylparathion)、メトキサジアゾン(metoxadiazone)、メトキシクロル(methoxychlor)、メトキシフェノジド(methoxyfenozide)、メトフルトリン(metofluthrin)、メトプレン(methoprene)、メトルカルブ(metolcarb)、メパルフルスリン(meperfluthrin)、メビンホス(mevinphos)、モノクロトホス(monocrotophos)、モノスルタップ(monosultap)、モムフルオロスリン(momfluorothrin)、ラムダ-シハロトリン(lambda-cyhalothrin)、リアノジン(ryanodine)、ルフェヌロン(lufenuron)、レスカルール(rescalure)、レスメトリン(resmethrin)、レピメクチン(lepimectin)、ロテノン(rotenone)、塩酸レバミゾール(lev
amisol hydrochloride)、酸化フェンブタスズ(fenbutatin oxide)、酒石酸モランテル(morantel tartarate)、臭化メチル(methyl bromide)、石灰窒素(calcium cyanamide)、石灰硫黄合剤(calcium polysulfide)、硫黄(sulfur)、硫酸ニコチン(nicotine sulfate)、 In addition, as a drug that can be used by mixing with the composition of the present invention as another drug, one or more selected from the following active ingredient group A may be used.
Active ingredient group A includes (A1) agricultural and horticultural insecticide group; 3,5-xylyl methylcarbamate (XMC), Bacillus thuringiensis: for example, Bacillus thuringiensis Bacillus thuringienses aizawai, Bacillus thuringienses israelensis, Bacillus thuringienses japonensis, Bacillus thuringienses kurstaki, Bacillus thuringiensis crystalline protein toxin (Bt toxin insecticidal compound) produced by Bacillus thuringienses tenebrionis, etc.), Methylcarbamic acid 2-sec-butylphenyl ester (BPMC), chlorfenson (CPCBS), Dichlorodiisopropyl ether (DCIP), 1,3-Dichloropropene (DD), Dichlorodiphenyltrichloroethane (DDT), 1-Naphthyl N-methylcarbamate (NAC) , O-4-dimethylsulfamoylphenyl O, O-diethyl phosphorothioate (DSP), O-ethyl-O-4-nitrophenylphenylphosphonothioate O-ethyl O-4-nitrophenyl phenylphosphonothioate (EPN), tripropylisocyanurate (TPIC), acrinathrin, azadirachtin, azinphosmet hyl), acequinocyl, acetamiprid, acetoprole, acephate, abamectin, aphidopyropen, avermectin, amidoflumet, amitraz, alanycarb, aldicarb, aldoxycarb, aldrin, alpha-endosulfan, alpha-cypermethrin, albendazole, allethrin ), isazofos, isamidofos, isoxathion, isofenphos, isoprocarb (MIPC), ivermectin, imicyafos, imidacloprid, imiprothrin, indoxacarb, esfenvalerate, ethiofencarb, ethion, ethiprole, etoxazole, ethofenprox, ethoprophos, etrimfos , emamectin, emamectin benzoate, endosulfan, empenthrin, oxamyl, oxydemeton methyl, oxydeprofos (ESP), oxibendazole ), oxfendazole, potassium oleate, sodium oleate, cadusafos ), cartap, carbaryl, carbosulfan, carbofuran, gamma-cyhalothrin, xylylcarb, quinalphos, kinoprene, quinomethionate ( chinomethionat, cloethocarb, clothianidin, clofentezine, chromafenozide, chlorantraniliprole, chlorethoxyfos, chlordimeform, chlordane , chlorpyrifos, chlorpyrifos-methyl, chlorphenapyr, chlorfenson, chlorfenvinphos, chlorfluazuron, chlorobenzilate, chloro chlorobenzoate, dicofol, salition, cyanophos (CYAP), diafenthiuron, diamidafos, cyantraniliprole, theta Permethrin (theta-cypermethrin), dienochlor, cyenopyrafen, dioxabenzofos, diofenolan, sigma-cypermethrin, cyclaniliprole, diclofenthion ( dichlofenthion (ECP), cycloprothrin, dichlorvos (DDVP), disulfoton, dinotefuran (di notefuran, cyhalothrin, cyphenothrin, cyfluthrin, diflubenzuron, cyflumetofen, diflovidazin, tricyclohexyltin hydroxide (cyhexatin), cypermethrin ), dimethylvinphos, dimethoate, dimefluthrin, silafluofen, cyromazine, spinetoram, spinosad, spirodiclofen, spirotetramat ( spirotetramat, spiromesifen, sulfluramid, sulprofos, sulfoxaflor, zeta-cypermethrin, diazinon, tau-fluvalinate, dazomet, thiacloprid, thiamethoxam, tioxazafen, thiodicarb, thiocyclam, thiosultap, thiosultap-sodium, thionazin, thiometon, deet, dieldrin, tetrachlorvinphos, tetradifon, tetraniliprole, tetramethylfluthrin, tetramethrin, tebpilimphos ( tebupirimfos), tebufenozide, tebufenpyrad, tefluthrin, teflubene teflubenzuron, demeton-S-methyl, temphos, deltamethrin, terbufos, tralopyril, tralomethrin, transfluthrin, triazamate, triazuron, trichlamide, trichlorphon (DEP), triflumuron, triflumezopyrim, tolfenpyrad, naled (BRP), nithiazine ( nithiazine, novaluron, noviflumuron, hydroprene, vaniliprole, vamidothion, parathion, parathion-methyl, halfenprox, Halofenozide, bistrifluron, bisultap, hydramethylnon, hydroxy propyl starch, binapacryl, bifenazate, bifenthrin, piflubumide ( pyflubumide, pymetrozine, pyraclofos, pyrafluprole, pyridafenthion, pyridaben, pyridalyl, pyrifluquinazon, pyriprole, pyriproxyfen ), pirimicarb, pyrimidifen, pirimiphos methyl, pyrethrin in), fipronil, fenazaquin, fenamiphos, phenisobromolate, fenitrothion (MEP), fenoxycarb, fenothiocarb, phenothrin, fensulfothion, fenthion (MPP), phenthoate (PAP), fenvalerate, fenpyroximate, fenpropathrin, fenbendazole, butathiophos ( butathiofos, buprofezin, furathiocarb, prallethrin, fluacrypyrim, fluazinam, fluazuron, fluensulfone, flucycloxuron, flucitrinate flucythrinate, fluvalinate, flupyradifurone, flupyrazofos, flufiprole, flufenerim, flufenoxuron, flufenzine, flufenprox , fluproxyfen, flubrocythrinate, fluhexafon, flubendiamide, flumethrin, flurimfen, prothiofos, protrifenbute ), flonicamid, propaphos, propargite (BPPS), profenofos, profluthrin, propoxur (PHC), flometoquin, bromopropylate, beta-cyfluthrin, hexaflumuron, hexythiazox, heptafluthrin ( heptafluthrin, heptenophos, permethrin, benclothiaz, bendiocarb, bensultap, benzoximate, benfuracarb, phoxim, phosalone, fosthiazate, fosthietan, phosphamidon, phosphocarb, phosmet (PMP), polynactins, formetanate, formothion, folate, machine oil, malathion, milbemycin, milbemycin A, milbemectin, mecarbam, mesulfenfos, methomyl, metaldehyde, metaflumizone, methamidophos, metam-ammonium, metam-sodium, methiocarb, methidathion (DMTP), methylisothiocyanate, methylneo decanamide, methylparathion, metoxadiazone, methoxychlor, methoxyfenozide hoxyfenozide), metofluthrin, metoprene, metolcarb, meperfluthrin, mevinphos, monocrotophos, monosultap, momfluorothrin, lambda-cyhalothrin ( lambda-cyhalothrin), ryanodine, lufenuron, rescalure, resmethrin, lepimectin, rotenone, levamisole hydrochloride
amisol hydrochloride, fenbutatin oxide, morantel tartrate, methyl bromide, calcium cyanamide, calcium polysulfide, sulfur, nicotine sulfate ( nicotine sulfate),
有効成分群Aは、(A1)農園芸用殺虫剤群;3,5-キシリルメチルカルバメイト(3,5-xylyl methylcarbamate)(XMC)、バチルス・チューリンゲンシス(Bacillus thuringienses:例えば、バチルス・チューリンゲンシス・アイザワイ(Bacillus thuringienses aizawai)、バチルス・チューリンゲンシス・イスラエレンシス(Bacillus thuringienses israelensis)、バチルス・チューリンゲンシス・ジャポネンシス(Bacillus thuringienses japonensis)、バチルス・チューリンゲンシス・クルスターキ(Bacillus thuringienses kurstaki)、バチルス・チューリンゲンシス・テネブリオニス(Bacillus thuringienses tenebrionis)等)が生成する結晶タンパク毒素(Btトキシン系殺虫性化合物)、フェノブカルブ(Methylcarbamic acid 2-sec-butylphenyl ester )(BPMC)、クロルフェンソン(chlorfenson)(CPCBS)、ジクロロジイソプロピルエーテル(dichlorodiisopropyl ether)(DCIP)、1,3-ジクロロプロペン(1, 3-Dichloropropene)(D-D)、ジクロロジフェニルトリクロロエタン(Dichlorodiphenyltrichloroethane)(DDT)、カルバリル(1-Naphthyl N-methylcarbamate)(NAC)、O-4-ジメチルスルファモイルフェニル O,O-ジエチルフォスフォロチオエート (O-4-dimethylsulfamoylphenyl O,O-diethyl phosphorothioate)(DSP)、O-エチル-O-4-ニトロフェニルフェニルフォスフォノチオエート(O-ethyl O-4-nitrophenyl phenylphosphonothioate)(EPN)、トリプロピルイソシアヌレート(tripropylisocyanurate)(TPIC)、アクリナトリン(acrinathrin)、アザディラクチン(azadirachtin)、アジンホスメチル(azinphosmethyl)、アセキノシル(acequinocyl)、アセタミプリド(acetamiprid)、アセトプロール(acetoprole)、アセフェート(acephate)、アバメクチン(abamectin)、アフィドピロペン(afidopyropen)、アベルメクチン(avermectin)、アミドフルメット(amidoflumet)、アミトラズ(amitraz)、アラニカルブ(alanycarb)、アルジカルブ(aldicarb)、アルドキシカルブ(aldoxycarb)、アルドリン(aldrin)、アルファ-エンドスルファン(alpha-endosulfan)、アルファ-シペルメトリン(alpha-cypermethrin)、アルベンダゾール(albendazole)、アレスリン(allethrin)、イサゾホス(isazofos)、イサミドホス(isamidofos)、イソキサチオン(isoxathion)、イソフェンホス(isofenphos)、イソプロカルブ(isoprocarb)(MIPC)、イベルメクチン(ivermectin)、イミシアホス(imicyafos)、イミダクロプリド(imidacloprid)、イミプロトリン(imiprothrin)、インドキサカルブ(indoxacarb)、エスフェンバレレート(esfenvalerate)、エチオフェンカルブ(ethiofencarb)、エチオン(ethion)、エチプロール(ethiprole)、エトキサゾール(etoxazole)、エトフェンプロックス(ethofenprox)、エトプロホス(ethoprophos)、エトリムホス(etrimfos)、エマメクチン(emamectin)、エマメクチンベンゾエート(emamectin benzoate)、エンドスルファン(endosulfan)、エンペントリン(empenthrin)、オキサミル(oxamyl)、オキシジメトンメチル(oxydemeton methyl)、オキシデプロホス(oxydeprofos: ESP)、オキシベンダゾール(oxibendazole)、オクスフェンダゾール(oxfendazole)、オレイン酸カリウム(Potassium oleate)、オレイン酸ナトリウム(sodium oleate)、カズサホス(cadusafos)、カルタップ(cartap)、カルバリル(carbaryl)、カルボスルファン(carbosulfan)、カルボフラン(carbofuran)、ガンマ-シハロトリン(gamma-cyhalothrin)、キシリルカルブ(xylylcarb)、キナルホス(quinalphos)、キノプレン(kinoprene)、キノメチオネート(chinomethionat)、クロエトカルブ(cloethocarb)、クロチアニジン(clothianidin)、クロフェンテジン(clofentezine)、クロマフェノジド(chromafenozide)、クロラントラニリプロール(chlorantraniliprole)、クロルエトキシホス(chlorethoxyfos)、クロルジメホルム(chlordimeform)、クロルデン(chlordane)、クロルピリホス(chlorpyrifos)、クロルピリホスメチル(chlorpyrifos-methyl)、クロルフェナピル(chlorphenapyr)、クロルフェンソン(chlorfenson)、クロルフェンビンホス(chlorfenvinphos)、クロルフルアズロン(chlorfluazuron)、クロルベンジレート(chlorobenzilate)、クロロベンゾエート(chlorobenzoate)、ケルセン(ジコホル)(dicofol)、サリチオン(salithion)、シアノホス(cyanophos)(CYAP)、ジアフェンチウロン(diafenthiuron)、ジアミダホス(diamidafos)、シアントラニリプロール(cyantraniliprole)、シータ-シペルメトリン(theta-cypermethrin)、ジエノクロル(dienochlor)、シエノピラフェン(cyenopyrafen)、ジオキサベンゾホス(dioxabenzofos)、ジオフェノラン(diofenolan)、シグマ-シペルメトリン(sigma-cypermethrin)、シクラニリプロール(cyclaniliprole)、ジクロフェンチオン(dichlofenthion)(ECP)、シクロプロトリン(cycloprothrin)、ジクロルボス(dichlorvos)(DDVP)、ジスルホトン(disulfoton)、ジノテフラン(dinotefuran)、シハロトリン(cyhalothrin)、シフェノトリン(cyphenothrin)、シフルトリン(cyfluthrin)、ジフルベンズロン(diflubenzuron)、シフルメトフェン(cyflumetofen)、ジフロビダジン(diflovidazin)、水酸化トリシクロヘキシルスズ(シヘキサチン)(cyhexatin)、シペルメトリン(cypermethrin)、ジメチルビンホス(dimethylvinphos)、ジメトエート(dimethoate)、ジメフルスリン(dimefluthrin)、シラフルオフェン(silafluofen)、シロマジン(cyromazine)、スピネトラム(spinetoram)、スピノサド(spinosad)、スピロジクロフェン(spirodiclofen)、スピロテトラマト(spirotetramat)、スピロメシフェン(spiromesifen)、スルフルラミド(sulfluramid)、スルプロホス(sulprofos)、スルホキサフロル(sulfoxaflor)、ゼータ-シペルメトリン(zeta-cypermethrin)、ダイアジノン(diazinon)、タウ-フルバリネート(tau-fluvalinate)、ダゾメット(dazomet)、チアクロプリド(thiacloprid)、チアメトキサム(thiamethoxam)、チオキサザフェン(tioxazafen)、チオジカルブ(thiodicarb)、チオシクラム(thiocyclam)、チオスルタップ(thiosultap)、チオスルタップナトリウム(thiosultap-sodium)、チオナジン(thionazin)、チオメトン(thiometon)、ディート(deet)、ディルドリン(dieldrin)、テトラクロルビンホス(tetrachlorvinphos)、テトラジホン(tetradifon)、テトラニリプロール(tetraniliprole)、テトラメチルフルトリン(tetramethylfluthrin)、テトラメトリン(tetramethrin)、テブピリムホス(tebupirimfos)、テブフェノジド(tebufenozide)、テブフェンピラド(tebufenpyrad)、テフルトリン(tefluthrin)、テフルベンズロン(teflubenzuron)、デメトン-S-メチル(demeton-S-methyl)、テメホス(temephos)、デルタメトリン(deltamethrin)、テルブホス(terbufos)、トラロピリル(tralopyril)、トラロメトリン(tralomethrin)、トランスフルトリン(transfluthrin)、トリアザメート(triazamate)、トリアズロン(triazuron)、トリクラミド(trichlamide)、トリクロルホン(trichlorphon)(DEP)、トリフルムロン(triflumuron)、トリフルメゾピリム(triflumezopyrim)、トルフェンピラド(tolfenpyrad)、ナレッド(naled)(BRP)、ニチアジン(nithiazine)、ノバルロン(novaluron)、ノビフルムロン(noviflumuron)、ハイドロプレン(hydroprene)、バニリプロール(vaniliprole)、バミドチオン(vamidothion)、パラチオン(parathion)、パラチオン-メチル(parathion-methyl)、ハルフェンプロックス(halfenprox)、ハロフェノジド(halofenozide)、ビストリフルロン(bistrifluron)、ビスルタップ(bisultap)、ヒドラメチルノン(hydramethylnon)、ヒドロキシプロピルデンプン(hydroxy propyl starch)、ビナパクリル(binapacryl)、ビフェナゼート(bifenazate)、ビフェントリン(bifenthrin)、ピフルブミド(pyflubumide)、ピメトロジン(pymetrozine)、ピラクロホス(pyraclorfos)、ピラフルプロール(pyrafluprole)、ピリダフェンチオン(pyridafenthion)、ピリダベン(pyridaben)、ピリダリル(pyridalyl)、ピリフルキナゾン(pyrifluquinazon)、ピリプロール(pyriprole)、ピリプロキシフェン(pyriproxyfen)、ピリミカーブ(pirimicarb)、ピリミジフェン(pyrimidifen)、ピリミホスメチル(pirimiphos methyl)、ピレトリン(pyrethrin)、フィプロニル(fipronil)、フェナザキン(fenazaquin)、フェナミホス(fenamiphos)、フェニソブロモレート(phenisobromolate)、フェニトロチオン(fenitrothion)(MEP)、フェノキシカルブ(fenoxycarb)、フェノチオカルブ(fenothiocarb)、フェノトリン(phenothrin)、フェンスルフォチオン(fensulfothion)、フェンチオン(fenthion)(MPP)、フェントエート(phenthoate)(PAP)、フェンバレレート(fenvalerate)、フェンピロキシメート(fenpyroximate)、フェンプロパトリン(fenpropathrin)、フェンベンダゾール(fenbendazole)、ブタチオホス(butathiofos)、ブプロフェジン(buprofezin)、フラチオカルブ(furathiocarb)、プラレトリン(prallethrin)、フルアクリピリム(fluacrypyrim)、フルアジナム(fluazinam)、フルアズロン(fluazuron)、フルエンスルホン(fluensulfone)、フルシクロクスロン(flucycloxuron)、フルシトリネート(flucythrinate)、フルバリネート(fluvalinate)、フルピラジフロン(flupyradifurone)、フルピラゾホス(flupyrazofos)、フルフィプロール(flufiprole)、フルフェネリム(flufenerim)、フルフェノクスロン(flufenoxuron)、フルフェンジン(flufenzine)、フルフェンプロックス(flufenprox)、フルプロキシフェン(fluproxyfen)、フルブロシスリネート(flubrocythrinate)、フルヘキサホン(fluhexafon)、フルベンジアミド(flubendiamide)、フルメトリン(flumethrin)、フルリムフェン(flurimfen)、プロチオホス(prothiofos)、プロトリフェンブト(protrifenbute)、フロニカミド(flonicamid)、プロパホス(propaphos)、プロパルギット(propargite)(BPPS)、プロフェノホス(profenofos)、プロフルスリン(profluthrin)、プロポキスル(propoxur)(PHC)、フロメトキン(flometoquin)、ブロモプロピレート(bromopropylate)、ベータ-シフルトリン(beta-cyfluthrin)、ヘキサフルムロン(hexaflumuron)、ヘキシチアゾクス(hexythiazox)、ヘプタフルスリン(heptafluthrin)、ヘプテノホス(heptenophos)、ペルメトリン(permethrin)、ベンクロチアズ(benclothiaz)、ベンジオカルブ(bendiocarb)、ベンスルタップ(bensultap)、ベンゾキシメート(benzoximate)、ベンフラカルブ(benfuracarb)、ホキシム(phoxim)、ホサロン(phosalone)、ホスチアゼート(fosthiazate)、ホスチエタン(fosthietan)、ホスファミドン(phosphamidon)、ホスホカルブ(phosphocarb)、ホスメット(phosmet)(PMP)、ポリナクチン複合体(polynactins)、ホルメタネート(formetanate)、ホルモチオン(formothion)、ホレート(phorate)、マシン油(machine oil)、マラチオン(malathion)、ミルベマイシン(milbemycin)、ミルベマイシンA(milbemycin A)、ミルベメクチン(milbemectin)、メカルバム(mecarbam)、メスルフェンホス(mesulfenfos)、メソミル(methomyl)、メタアルデヒド(metaldehyde)、メタフルミゾン(metaflumizone)、メタミドホス(methamidophos)、メタムアンモニウム(metam-ammonium)、メタムナトリウム(metam-sodium)、メチオカルブ(methiocarb)、メチダチオン(methidathion)(DMTP)、メチルイソチオシアネート(methylisothiocyanate)、メチルネオデカナミド(methylneodecanamide)、メチルパラチオン(methylparathion)、メトキサジアゾン(metoxadiazone)、メトキシクロル(methoxychlor)、メトキシフェノジド(methoxyfenozide)、メトフルトリン(metofluthrin)、メトプレン(methoprene)、メトルカルブ(metolcarb)、メパルフルスリン(meperfluthrin)、メビンホス(mevinphos)、モノクロトホス(monocrotophos)、モノスルタップ(monosultap)、モムフルオロスリン(momfluorothrin)、ラムダ-シハロトリン(lambda-cyhalothrin)、リアノジン(ryanodine)、ルフェヌロン(lufenuron)、レスカルール(rescalure)、レスメトリン(resmethrin)、レピメクチン(lepimectin)、ロテノン(rotenone)、塩酸レバミゾール(lev
amisol hydrochloride)、酸化フェンブタスズ(fenbutatin oxide)、酒石酸モランテル(morantel tartarate)、臭化メチル(methyl bromide)、石灰窒素(calcium cyanamide)、石灰硫黄合剤(calcium polysulfide)、硫黄(sulfur)、硫酸ニコチン(nicotine sulfate)、 In addition, as a drug that can be used by mixing with the composition of the present invention as another drug, one or more selected from the following active ingredient group A may be used.
Active ingredient group A includes (A1) agricultural and horticultural insecticide group; 3,5-xylyl methylcarbamate (XMC), Bacillus thuringiensis: for example, Bacillus thuringiensis Bacillus thuringienses aizawai, Bacillus thuringienses israelensis, Bacillus thuringienses japonensis, Bacillus thuringienses kurstaki, Bacillus thuringiensis crystalline protein toxin (Bt toxin insecticidal compound) produced by Bacillus thuringienses tenebrionis, etc.), Methylcarbamic acid 2-sec-butylphenyl ester (BPMC), chlorfenson (CPCBS), Dichlorodiisopropyl ether (DCIP), 1,3-Dichloropropene (DD), Dichlorodiphenyltrichloroethane (DDT), 1-Naphthyl N-methylcarbamate (NAC) , O-4-dimethylsulfamoylphenyl O, O-diethyl phosphorothioate (DSP), O-ethyl-O-4-nitrophenylphenylphosphonothioate O-ethyl O-4-nitrophenyl phenylphosphonothioate (EPN), tripropylisocyanurate (TPIC), acrinathrin, azadirachtin, azinphosmet hyl), acequinocyl, acetamiprid, acetoprole, acephate, abamectin, aphidopyropen, avermectin, amidoflumet, amitraz, alanycarb, aldicarb, aldoxycarb, aldrin, alpha-endosulfan, alpha-cypermethrin, albendazole, allethrin ), isazofos, isamidofos, isoxathion, isofenphos, isoprocarb (MIPC), ivermectin, imicyafos, imidacloprid, imiprothrin, indoxacarb, esfenvalerate, ethiofencarb, ethion, ethiprole, etoxazole, ethofenprox, ethoprophos, etrimfos , emamectin, emamectin benzoate, endosulfan, empenthrin, oxamyl, oxydemeton methyl, oxydeprofos (ESP), oxibendazole ), oxfendazole, potassium oleate, sodium oleate, cadusafos ), cartap, carbaryl, carbosulfan, carbofuran, gamma-cyhalothrin, xylylcarb, quinalphos, kinoprene, quinomethionate ( chinomethionat, cloethocarb, clothianidin, clofentezine, chromafenozide, chlorantraniliprole, chlorethoxyfos, chlordimeform, chlordane , chlorpyrifos, chlorpyrifos-methyl, chlorphenapyr, chlorfenson, chlorfenvinphos, chlorfluazuron, chlorobenzilate, chloro chlorobenzoate, dicofol, salition, cyanophos (CYAP), diafenthiuron, diamidafos, cyantraniliprole, theta Permethrin (theta-cypermethrin), dienochlor, cyenopyrafen, dioxabenzofos, diofenolan, sigma-cypermethrin, cyclaniliprole, diclofenthion ( dichlofenthion (ECP), cycloprothrin, dichlorvos (DDVP), disulfoton, dinotefuran (di notefuran, cyhalothrin, cyphenothrin, cyfluthrin, diflubenzuron, cyflumetofen, diflovidazin, tricyclohexyltin hydroxide (cyhexatin), cypermethrin ), dimethylvinphos, dimethoate, dimefluthrin, silafluofen, cyromazine, spinetoram, spinosad, spirodiclofen, spirotetramat ( spirotetramat, spiromesifen, sulfluramid, sulprofos, sulfoxaflor, zeta-cypermethrin, diazinon, tau-fluvalinate, dazomet, thiacloprid, thiamethoxam, tioxazafen, thiodicarb, thiocyclam, thiosultap, thiosultap-sodium, thionazin, thiometon, deet, dieldrin, tetrachlorvinphos, tetradifon, tetraniliprole, tetramethylfluthrin, tetramethrin, tebpilimphos ( tebupirimfos), tebufenozide, tebufenpyrad, tefluthrin, teflubene teflubenzuron, demeton-S-methyl, temphos, deltamethrin, terbufos, tralopyril, tralomethrin, transfluthrin, triazamate, triazuron, trichlamide, trichlorphon (DEP), triflumuron, triflumezopyrim, tolfenpyrad, naled (BRP), nithiazine ( nithiazine, novaluron, noviflumuron, hydroprene, vaniliprole, vamidothion, parathion, parathion-methyl, halfenprox, Halofenozide, bistrifluron, bisultap, hydramethylnon, hydroxy propyl starch, binapacryl, bifenazate, bifenthrin, piflubumide ( pyflubumide, pymetrozine, pyraclofos, pyrafluprole, pyridafenthion, pyridaben, pyridalyl, pyrifluquinazon, pyriprole, pyriproxyfen ), pirimicarb, pyrimidifen, pirimiphos methyl, pyrethrin in), fipronil, fenazaquin, fenamiphos, phenisobromolate, fenitrothion (MEP), fenoxycarb, fenothiocarb, phenothrin, fensulfothion, fenthion (MPP), phenthoate (PAP), fenvalerate, fenpyroximate, fenpropathrin, fenbendazole, butathiophos ( butathiofos, buprofezin, furathiocarb, prallethrin, fluacrypyrim, fluazinam, fluazuron, fluensulfone, flucycloxuron, flucitrinate flucythrinate, fluvalinate, flupyradifurone, flupyrazofos, flufiprole, flufenerim, flufenoxuron, flufenzine, flufenprox , fluproxyfen, flubrocythrinate, fluhexafon, flubendiamide, flumethrin, flurimfen, prothiofos, protrifenbute ), flonicamid, propaphos, propargite (BPPS), profenofos, profluthrin, propoxur (PHC), flometoquin, bromopropylate, beta-cyfluthrin, hexaflumuron, hexythiazox, heptafluthrin ( heptafluthrin, heptenophos, permethrin, benclothiaz, bendiocarb, bensultap, benzoximate, benfuracarb, phoxim, phosalone, fosthiazate, fosthietan, phosphamidon, phosphocarb, phosmet (PMP), polynactins, formetanate, formothion, folate, machine oil, malathion, milbemycin, milbemycin A, milbemectin, mecarbam, mesulfenfos, methomyl, metaldehyde, metaflumizone, methamidophos, metam-ammonium, metam-sodium, methiocarb, methidathion (DMTP), methylisothiocyanate, methylneo decanamide, methylparathion, metoxadiazone, methoxychlor, methoxyfenozide hoxyfenozide), metofluthrin, metoprene, metolcarb, meperfluthrin, mevinphos, monocrotophos, monosultap, momfluorothrin, lambda-cyhalothrin ( lambda-cyhalothrin), ryanodine, lufenuron, rescalure, resmethrin, lepimectin, rotenone, levamisole hydrochloride
amisol hydrochloride, fenbutatin oxide, morantel tartrate, methyl bromide, calcium cyanamide, calcium polysulfide, sulfur, nicotine sulfate ( nicotine sulfate),
(A2)農園芸用殺菌剤群;アウレオフンギン(aureofungin)、アザコナゾール(azaconazole)、アジチラム(azithiram)、アシペタックス(acypetacs)、アシベンゾラル(acibenzolar)、アシベンゾラルSメチル(acibenzolar S-methyl)、アゾキシストロビン(azoxystrobin)、アニラジン(anilazine)、アミスルブロム(amisulbrom)、アムプロピルホス(ampropylfos)、アメトクトラジン(ametoctradin)、アリルアルコール(allyl alcohol)、アルジモルフ(aldimorph)、アンバム(amobam)、イソチアニル(isotianil)、イソバレジオン(isovaledione)、イソピラザム(isopyrazam)、イソフェタミド(isofetamid)、イソプロチオラン(isoprothiolane )、イプコナゾール(ipconazole)、イプロジオン(iprodione)、イプロバリカルブ(iprovalicarb)、イプロベンホス(iprobenfos)、イマザリル(imazalil)、イミノクタジン(iminoctadine)、メタム(metam)、イミノクタジン酢酸塩(iminoctadine-triacetate)、イミベンコナゾール(imibenconazole)、ウニコナゾール(uniconazole)、ウニコナゾールP(uniconazole P)、エクロメゾール(echlomezole)、エジフェンホス(edifenphos)、エタコナゾール(etaconazole)、エタボキサム(ethaboxam)、エチリモール(ethirimol)、エテム(etem)、エトキシキン(ethoxyquin)、エトリジアゾール(etridiazole)、エネストロブリン(enestroburin)、エポキシコナゾール(epoxiconazole)、オキサジキシル(oxadixyl)、オキシカルボキシン(oxycarboxin)、オキシテトラサイクリン(oxytetracycline)、オキシン銅(copper oxinate)、オキスポコナゾール(oxpoconazole)、オキスポコナゾールフマル酸塩(oxpoconazole fumarate)、オキソリニック酸(oxolinic acid)、オクチリノン(octhilinone)、オフラセ(ofurace)、オリサストロビン(orysastrobin)、メタムナトリウム(metam-sodium)、カスガマイシン(kasugamycin)、カルバモルフ(carbamorph)、カルプロパミド(carpropamid)、カルベンダジム(carbendazim)、カルボキシン(carboxin)、カルボン(carvone)、キナザミド(quinazamid)、キナセトール(quinacetol)、キノキシフェン(quinoxyfen)、キノメチオネート(chinomethionat)、キャプタホール(captafol)、キャプタン(captan)、キララキシル(kiralaxyl)、キンコナゾール(quinconazole)、キントゼン(quintozene)、グアザチン(guazatine)、クフラネブ(cufraneb)、クプロバム(cuprobam)、グリオジン(glyodin)、グリセオフルビン(griseofulvin)、クリムバゾール(climbazole)、クレゾール(cresol)、クレソキシムメチル(kresoxim-methyl)、クロゾリネート(chlozolinate)、クロトリマゾール(clotrimazole)、クロベンチアゾン(chlobenthiazone)、クロラニホルメタン(chloraniformethan)、クロラニル(chloranil)、クロルキノックス(chlorquinox)、クロルピクリン(chloropicrin )、クロルフェナゾール(chlorfenazole)、クロロジニトロナフタレン(chlorodinitronaphthalene)、クロロタロニル(chlorothalonil)、クロロネブ(chloroneb)、サリチルアニリド(salicylanilide)、ザリラミド(zarilamid)、シアゾファミド(cyazofamid)、ジエチルピロカーボナート(diethyl pyrocarbonate )、ジエトフェンカルブ(diethofencarb)、シクラフラミド(cyclafuramid)、ジクロシメット(diclocymet)、ジクロゾリン(dichlozoline)、ジクロブトラゾール(diclobutrazol)、ジクロフルアニド(dichlofluanid)、シクロヘキシミド(cycloheximide)、ジクロメジン(diclomezine)、ジクロラン(dicloran)、ジクロロフェン(dichlorophen)、ジクロン(dichlone)、ジスルフィラム(disulfiram)、ジタリムホス(ditalimfos)、メタラキシル(metalaxyl)、ジチアノン(dithianon)、ジニコナゾール(diniconazole)、ジニコナゾールM(diniconazole-M)、ジネブ(zineb)、ジノカップ(dinocap)、ジノクトン(dinocton)、ジノスルホン(dinosulfon)、ジノテルボン(dinoterbon)、ジノブトン(dinobuton)、ジノペントン(dinopenton)、ジピリチオン(dipyrithione)、ジフェニルアミン(diphenylamine)、ジフェノコナゾール(difenoconazole)、シフルフェナミド(cyflufenamid)、ジフルメトリム(diflumetorim)、シプロコナゾール(cyproconazole)、シプロジニル(cyprodinil)、シプロフラム(cyprofuram)、シペンダゾール(cypendazole)、シメコナゾール(simeconazole)、ジメチリモール(dimethirimol)、ジメトモルフ(dimethomorph)、シモキサニル(cymoxanil)、ジモキシストロビン(dimoxystrobin)、臭化メチル(methyl bromide)、ジラム(ziram)、シルチオファム(silthiofam)、ストレプトマイシン(streptomycin)、スピロキサミン(spiroxamine)、スルトロペン(sultropen)、セダキサン(sedaxane)、ゾキサミド(zoxamide)、メチラム(metiram)、ダゾメット(dazomet)、チアジアジン(thiadiazin)、チアジニル(tiadinil)、チアジフルオル(thiadifluor)、チアベンダゾール(thiabendazole)、チオキシミド(tioxymid)、チオキノックス(thioquinox)、チオクロルフェンフィム(thiochlorfenphim)、チオファネート(thiophanate)、チオファネートメチル(thiophanate methyl)、メチルイソチオシアナート(methyl isothiocyanate)、チシオフェン(thicyofen)、チフルザミド(thifluzamide)、チラム(thiram)、デカフェンチン(decafentin)、テクナゼン(tecnazene)、テクロフタラム(tecloftalam)、テコラム(tecoram)、テトラコナゾール(tetraconazole)、デバカルブ(debacarb)、デヒドロ酢酸(dehydroacetic acid )、テブコナゾール(tebuconazole)、テブフロキン(tebufloquin)、ドジシン(dodicin)、ドジン(dodine)、ドデシルベンゼンスルホン酸ビスエチレンジアミン銅(II)錯塩(DBEDC)、ドデモルフ(dodemorph)、ドラゾキソロン(drazoxolon)、トリアジメノール(triadimenol)、トリアジメホン(triadimefon)、メタラキシルM(metalaxyl M)、トリアズブチル(triazbutil)、トリアゾキシド(triazoxide)、トリアミホス(triamiphos)、トリアリモール(triarimol)、トリクラミド(trichlamide)、トリシクラゾール(tricyclazole) 、トリチコナゾール(triticonazole)、トリデモルフ(tridemorph)、トリブチルチンオキシド(tributyltin oxide)、トリフルミゾール(triflumizole)、トリフロキシストロビン(trifloxystrobin)、トリホリン(triforine)、トリルフルアニド(tolylfluanid)、トルクロホスメチル(tolclofos methyl)、トルプロカルブ(tolprocarb)、ナタマイシン(natamycin)、ナバム(nabam)、ニトロスチレン(nitrostyrene)、ニトロタールイソプロピル(nitrothal-isopropyl)、ヌアリモール(nuarimol)、ノニルフェノールスルホン酸銅(copper nonylphenol sulfonate)、ハラクリネート(halacrinate)、バリダマイシン(validamycin)、バリフェナラート(valifenalate)、ハルピンタンパク(harpin protein)、ビキサフェン(bixafen)、ピコキシストロビン(picoxystrobin)、ピコベンザミド(picobenzamide)、ビチオノール(bithionol)、ビテルタノール(bitertanol)、ヒドロキシイソキサゾール(hydroxyisoxazole)、ヒドロキシイソキサゾールカリウム(hydroxyisoxazole-potassium)、ビナパクリル(binapacryl)、ビフェニル(biphenyl)、ピペラリン(piperalin )、ヒメキサゾール(hymexazol)、ピラオキシストロビン(pyraoxystrobin)、ピラカルボリド(pyracarbolid)、ピラクロストロビン(pyraclostrobin)、ピラゾホス(pyrazophos)、ピラメトストロビン(pyrametostrobin)、ピリオフェノン(pyriofenone)、ピリジニトリル(pyridinitril)、ピリフェノックス(pyrifenox)、ピリベンカルブ(pyribencarb)、ピリメタニル(pyrimethanil)、ピロキシクロル(pyroxychlor)、ピロキシフル(pyroxyfur)、ピロキロン(pyroquilon)、ビンクロゾリン(vinclozolin)、ファーバム(ferbam)、ファモキサドン(famoxadone)、フェナパニル(fenapanil)、フェナミドン(fenamidone)、フェナミノスルフ(fenaminosulf)、フェナリモール(fenarimol)、フェニトロパン(fenitropan)、フェノキサニル(fenoxanil)、フェリムゾン(ferimzone)、フェンチン(fentin)、フェンピクロニル(fenpiclonil)、フェンピラザミン(fenpyrazamine)、フェンブコナゾール(fenbuconazole)、フェンフラム(fenfuram)、フェンプロピジン(fenpropidin)、フェンプロピモルフ(fenpropimorph)、フェンヘキサミド(fenhexamid)、フタリド(phthalide)、ブチオベート(buthiobate)、ブチルアミン(butylamine)、メチルジノカップ(meptyldinocap)、ブピリメート(bupirimate)、フベリダゾール(fuberidazole)、ブラストサイジンS(blasticidin S)、フラメトピル(furametpyr)、フララキシル(furalaxyl)、フルアクリピリム(fluacrypyrim)、フルアジナム(fluazinam)、フルオキサストロビン(fluoxastrobin)、フルオトリマゾール(fluotrimazole)、フルオピコリド(fluopicolide)、フルオピラム(fluopyram)、フルオロイミド(fluoroimide)、フルカルバニル(furcarbanil)、フルキサピロキサド(fluxapyroxad)、フルキンコナゾール(fluquinconazole)、フルコナゾール(furconazole)、イミノクタジンアルベシル酸塩(iminoctadine albesilate)、フルコナゾールシス(furconazole-cis)、フルジオキソニル(fludioxonil)、フルシラゾール(flusilazole)、フルスルファミド(flusulfamide)、フルチアニル(flutianil)、フルトラニル(flutolanil)、フルトリアホール(flutriafol)、フルフラール(furfural)、フルメシクロックス(furmecyclox)、フルメットバー(flumetover)、フルモルフ(flumorph)、プロキナジド(proquinazid)、プロクロラズ(prochloraz)、プロシミドン(procymidone)、プロチオカルブ(prothiocarb)、プロチオコナゾール(prothioconazole)、プロパモカルブ(propamocarb)、プロピコナゾール(propiconazole)、プロピネブ(propineb)、フロファネート(furophanate)、プロベナゾール(probenazole)、ブロムコナゾール(bromuconazole)、ヘキサクロロブタジエン(hexachlorobutadiene)、ヘキサコナゾール(hexaconazole)、ヘキシルチオホス(hexylthiofos)、ベトキサジン(bethoxazin)、ベナラキシル(benalaxyl)、ベナラキシルM(benalaxyl M)、ベノダニル(benodanil)、ベノミル(benomyl)、ペフラゾエート(pefurazoate)、ベンキノックス(benquinox)、ペンコナゾール(penconazole)、ベンザモルフ(benzamorf)、ペンシクロン(pencycuron) 、ベンゾヒドロキサム酸(benzohydroxamic acid)、ベンタルロン(bentaluron) 、ベンチアゾール(benthiazole)、ベンチアバリカルブ(benthiavalicarb)、ベンチアバリカルブイソプロピル(benthiavalicarb isopropyl)、ペンチオピラド(penthiopyrad)、ペンフルフェン(penflufen)、ボスカリド(boscalid)、ホスジフェン(phosdiphen)、ホセチル(fosetyl)、ホセチルアルミニウム(fosetylalminium)、ポリオキシン(polyoxins)、ポリオキソリム(polyoxorim)、ポリカーバメート(polycarbamate)、メタゾキソロン(metazoxolon)、ホルペット(folpet)、ホルムアルデヒド(formaldehyde)、マシン油(machine oil)、マネブ(maneb)、マンコゼブ(mancozeb)、マンジプロパミド(mandipropamid)、ミクロゾリン(myclozolin)、ミクロブタニル(myclobutanil)、ミルディオマイシン(mildiomycin)、ミルネブ(milneb)、メカルビンジド(mecarbinzid)、メタスルホカルブ(methasulfocarb)、エノキサストロビン(enoxastrobin)、オキサチアピプロリン(oxathiapiprolin)、クモキシストロビン(coumoxystrobin)、トリクロピリカルブ(triclopyricarb)、ピカルブトラゾックス(picarbutrazox)、ピリソキサゾール(pyrisoxazole)、ピリミノストロビン(pyriminostrobin)、フェナミンストロビン(fenaminstrobin)、フルフェノキシストロビン(flufenoxystrobin)、マンデストロビン
(mandestrobin)、メトコナゾール(metconazole)、メトスルホバックス(metsulfovax)、メトフロキサム(methfuroxam)、メトミノストロビン(metominostrobin)、メトラフェノン(metrafenone)、メパニピリム(mepanipyrim)、メフェノキサム(mefenoxam)、メプチルジノカップ(meptyldinocap)、メプロニル(mepronil)、メベニル(mebenil)、ヨウ化メチル(iodomethane)、ラベンザゾール(rabenzazole)、塩化ベンザルコニウム(benzalkonium chloride)、塩基性塩化銅(basic copper chloride)、塩基性硫酸銅(basic copper sulfate)、金属銀(silver)等の無機殺菌剤、次亜塩素酸ナトリウム(sodium hypochlorite)、水酸化第二銅(cupric hydroxide)、水和硫黄剤(wettable sulfur)、石灰硫黄合剤(calcium polysulfide)、炭酸水素カリウム(potassium hydrogen carbonate)、炭酸水素ナトリウム(sodium hydrogen carbonate)、無機硫黄(sulfur)、無水硫酸銅(copper sulfate anhydride)、有機ニッケル(nickel dimethyldithiocarbamate)、硫酸亜鉛(zinc sulfate)、硫酸銅五水塩(copper sulfate)、 (A2) Fungicide group for agricultural and horticultural use; aureofungin, azaconazole, azithiram, acypetacs, acibenzolar, acibenzolar S-methyl, azoxyst azoxystrobin, anilazine, amisulbrom, ampropylfos, ametoctradin, allyl alcohol, aldimorph, amobam, isotianil, isovarezione (isovaledione), isopyrazam, isofetamide, isoprothiolane, ipconazole, iprodione, iprovalicarb, iprobenfos, imazalil, iminoctadine, metam (metam), iminoctadine-triacetate, imibenconazole, uniconazole, uniconazole P, eclomezole, edifenphos, etaconazole, ethaboxam ), ethirimol, etem, ethoxyquin, etridiazole, enestroburin, epoxiconazole, oxadixyl, oxycarbboxin, oxytetracycline (oxytetracycline), copper oxinate, oxpoconazole, oxpoconazole fumarate , oxolinic acid, octhilinone, ofurace, orysastrobin, metam-sodium, kasugamycin, carbamorph, carpropamid, carbendazim ( carbendazim, carboxin, carvone, quinazamid, quinacetol, quinoxyfen, chinomethionat, captafol, captan, kiralaxyl , quinconazole, quintozene, guazatine, cufraneb, cuprobam, glyodin, griseofulvin, climbazole, cresol, kresoxim -methyl), clozolinate, clotrimazole, clobenthiazone, chloraniformethan, chloranil, chlorquinox, chloropicrin, chlorfe chlorfenazole, chlorodinitronaphthalene, chlorothalonil, chloroneb, salicylanilide, zarilamid, cyazofamid, diethyl pyrocarbonate, diethofencarb ), cyclafuramid, diclocymet, dichlozoline, diclobutrazoline diclobutrazol, dichlofluanid, cycloheximide, diclomezine, dicloran, dichlorophen, dichlone, disulfiram, ditalimfos, metalaxyl ( metalaxyl), dithianon, diniconazole, diniconazole-M, zineb, dinocap, dinocton, dinosulfon, dinoterbon, dinobuton , dinopenton, dipyrithione, diphenylamine, difenoconazole, cyflufenamid, diflumetorim, cyproconazole, cyprodinil, cyprofuram, cypendazole ( cypendazole, simeconazole, dimethirimol, dimethomorph, cymoxanil, dimoxystrobin, methyl bromide, ziram, silthiofam, streptomycin streptomycin, spiroxamine, sultropen, sedaxane, zoxamide, metiram, dazomet, thiadiazin, tiadinil, thiadifluor, thiabendazole (thiabendazole), tioxymid, thioquinox, thiochlorfen phim), thiophanate, thiophanate methyl, methyl isothiocyanate, thicyofen, thifluzamide, thiram, decafentin, tecnazene, tecoftaram tecloftalam, tecoram, tetraconazole, debacarb, dehydroacetic acid, tebuconazole, tebufloquin, dodicin, dodine, dodecylbenzene Bisethylenediamine copper(II) sulfonate (DBEDC), dodemorph, drazoxolone, triadimenol, triadimefon, metalaxyl M, triazbutil, triazoxide ), triamiphos, triarimol, trichlamide, tricyclazole, triticonazole, tridemorph, tributyltin oxide, triflumizole , trifloxystrobin, triforine, tolylfluanid, tolclofos methyl, tolprocarb, natamycin, nabam, nitrostyrene, nitro Nitrothal-isopropyl, nuarimol, copper nonylphenol sulfonate, halacrinate, Validama validamycin, valifenalate, harpin protein, bixafen, picoxystrobin, picobenzamide, bithionol, bitertanol, hydroxyisoxafen hydroxyisoxazole, hydroxyisoxazole-potassium, binapacryl, biphenyl, piperalin, hymexazol, pyraoxystrobin, pyracarbolid, pyracarbolid clostrobin, pyrazophos, pyrametostrobin, pyriofenone, pyridinitril, pyrifenox, pyribencarb, pyrimethanil, pyroxychlor, pyroxyfur, pyroquilon, vinclozolin, ferbam, famoxadone, fenapanil, fenamidone, fenaminosulf, fenarimol, fenitropan , fenoxanil, ferimzone, fentin, fenpiclonil, fenpyrazamine, fenbuconazole, fenfuram, fenpropidin, fenpropimorph ), fenhexamid, phthalide, buthiobate, butylamine ( butylamine, meptyldinocap, bupirimate, fuberidazole, blasticidin S, furametpyr, furalaxyl, fluacrypyrim, fluazinam, flu oxastrobin, fluotrimazole, fluopicolide, fluopyram, fluoroimide, furcarbanil, fluxapyroxad, fluquinconazole, fluconazole, iminoctadine albesilate, furconazole-cis, fludioxonil, flusilazole, flusulfamide, flutianil, flutolanil, flutria flutriafol, furfural, furmecyclox, flumetover, flumorph, proquinazid, prochloraz, procymidone, prothiocarb, prothiocona prothioconazole, propamocarb, propiconazole, propineb, furophanate, probenazole, bromuconazole, hexachlorobutadiene, hexaconazole ), hexylthiofos, bethoxazin, benalaxyl ), benalaxyl M, benodanil, benomyl, pefurazoate, benquinox, penconazole, benzamorph, pencycuron, benzohydroxamic acid), bentaluron, benthiazole, benthiavalicarb, benthiavalicarb isopropyl, penthiopyrad, penflufen, boscalid, phosdiphen ), fosetyl, fosetyl aluminum, polyoxins, polyoxorim, polycarbamate, metazoxolon, folpet, formaldehyde, machine oil , maneb, mancozeb, mandipropamid, myclozolin, myclobutanil, mildiomycin, milneb, mecarbinzid, methasulfocarb, enoxastrobin, oxathiapiprolin, coumoxystrobin, triclopyricarb, picarbutrazox, pyrisoxazole, pyriminostrobin , fenaminstrobin, flufenoxystrobin, mandestrobin, metconazole (metc onazole, metsulfovax, methfuroxam, metominostrobin, metrafenone, mepanipyrim, mefenoxam, meptyldinocap, mepronil, mebenil, iodomethane, rabenzazole, benzalkonium chloride, basic copper chloride, basic copper sulfate, metallic silver ), sodium hypochlorite, cupric hydroxide, wettable sulfur, calcium polysulfide, potassium hydrogen carbonate hydrogen carbonate, sodium hydrogen carbonate, inorganic sulfur, copper sulfate anhydride, nickel dimethyldithiocarbamate, zinc sulfate, copper sulfate pentahydrate ),
(mandestrobin)、メトコナゾール(metconazole)、メトスルホバックス(metsulfovax)、メトフロキサム(methfuroxam)、メトミノストロビン(metominostrobin)、メトラフェノン(metrafenone)、メパニピリム(mepanipyrim)、メフェノキサム(mefenoxam)、メプチルジノカップ(meptyldinocap)、メプロニル(mepronil)、メベニル(mebenil)、ヨウ化メチル(iodomethane)、ラベンザゾール(rabenzazole)、塩化ベンザルコニウム(benzalkonium chloride)、塩基性塩化銅(basic copper chloride)、塩基性硫酸銅(basic copper sulfate)、金属銀(silver)等の無機殺菌剤、次亜塩素酸ナトリウム(sodium hypochlorite)、水酸化第二銅(cupric hydroxide)、水和硫黄剤(wettable sulfur)、石灰硫黄合剤(calcium polysulfide)、炭酸水素カリウム(potassium hydrogen carbonate)、炭酸水素ナトリウム(sodium hydrogen carbonate)、無機硫黄(sulfur)、無水硫酸銅(copper sulfate anhydride)、有機ニッケル(nickel dimethyldithiocarbamate)、硫酸亜鉛(zinc sulfate)、硫酸銅五水塩(copper sulfate)、 (A2) Fungicide group for agricultural and horticultural use; aureofungin, azaconazole, azithiram, acypetacs, acibenzolar, acibenzolar S-methyl, azoxyst azoxystrobin, anilazine, amisulbrom, ampropylfos, ametoctradin, allyl alcohol, aldimorph, amobam, isotianil, isovarezione (isovaledione), isopyrazam, isofetamide, isoprothiolane, ipconazole, iprodione, iprovalicarb, iprobenfos, imazalil, iminoctadine, metam (metam), iminoctadine-triacetate, imibenconazole, uniconazole, uniconazole P, eclomezole, edifenphos, etaconazole, ethaboxam ), ethirimol, etem, ethoxyquin, etridiazole, enestroburin, epoxiconazole, oxadixyl, oxycarbboxin, oxytetracycline (oxytetracycline), copper oxinate, oxpoconazole, oxpoconazole fumarate , oxolinic acid, octhilinone, ofurace, orysastrobin, metam-sodium, kasugamycin, carbamorph, carpropamid, carbendazim ( carbendazim, carboxin, carvone, quinazamid, quinacetol, quinoxyfen, chinomethionat, captafol, captan, kiralaxyl , quinconazole, quintozene, guazatine, cufraneb, cuprobam, glyodin, griseofulvin, climbazole, cresol, kresoxim -methyl), clozolinate, clotrimazole, clobenthiazone, chloraniformethan, chloranil, chlorquinox, chloropicrin, chlorfe chlorfenazole, chlorodinitronaphthalene, chlorothalonil, chloroneb, salicylanilide, zarilamid, cyazofamid, diethyl pyrocarbonate, diethofencarb ), cyclafuramid, diclocymet, dichlozoline, diclobutrazoline diclobutrazol, dichlofluanid, cycloheximide, diclomezine, dicloran, dichlorophen, dichlone, disulfiram, ditalimfos, metalaxyl ( metalaxyl), dithianon, diniconazole, diniconazole-M, zineb, dinocap, dinocton, dinosulfon, dinoterbon, dinobuton , dinopenton, dipyrithione, diphenylamine, difenoconazole, cyflufenamid, diflumetorim, cyproconazole, cyprodinil, cyprofuram, cypendazole ( cypendazole, simeconazole, dimethirimol, dimethomorph, cymoxanil, dimoxystrobin, methyl bromide, ziram, silthiofam, streptomycin streptomycin, spiroxamine, sultropen, sedaxane, zoxamide, metiram, dazomet, thiadiazin, tiadinil, thiadifluor, thiabendazole (thiabendazole), tioxymid, thioquinox, thiochlorfen phim), thiophanate, thiophanate methyl, methyl isothiocyanate, thicyofen, thifluzamide, thiram, decafentin, tecnazene, tecoftaram tecloftalam, tecoram, tetraconazole, debacarb, dehydroacetic acid, tebuconazole, tebufloquin, dodicin, dodine, dodecylbenzene Bisethylenediamine copper(II) sulfonate (DBEDC), dodemorph, drazoxolone, triadimenol, triadimefon, metalaxyl M, triazbutil, triazoxide ), triamiphos, triarimol, trichlamide, tricyclazole, triticonazole, tridemorph, tributyltin oxide, triflumizole , trifloxystrobin, triforine, tolylfluanid, tolclofos methyl, tolprocarb, natamycin, nabam, nitrostyrene, nitro Nitrothal-isopropyl, nuarimol, copper nonylphenol sulfonate, halacrinate, Validama validamycin, valifenalate, harpin protein, bixafen, picoxystrobin, picobenzamide, bithionol, bitertanol, hydroxyisoxafen hydroxyisoxazole, hydroxyisoxazole-potassium, binapacryl, biphenyl, piperalin, hymexazol, pyraoxystrobin, pyracarbolid, pyracarbolid clostrobin, pyrazophos, pyrametostrobin, pyriofenone, pyridinitril, pyrifenox, pyribencarb, pyrimethanil, pyroxychlor, pyroxyfur, pyroquilon, vinclozolin, ferbam, famoxadone, fenapanil, fenamidone, fenaminosulf, fenarimol, fenitropan , fenoxanil, ferimzone, fentin, fenpiclonil, fenpyrazamine, fenbuconazole, fenfuram, fenpropidin, fenpropimorph ), fenhexamid, phthalide, buthiobate, butylamine ( butylamine, meptyldinocap, bupirimate, fuberidazole, blasticidin S, furametpyr, furalaxyl, fluacrypyrim, fluazinam, flu oxastrobin, fluotrimazole, fluopicolide, fluopyram, fluoroimide, furcarbanil, fluxapyroxad, fluquinconazole, fluconazole, iminoctadine albesilate, furconazole-cis, fludioxonil, flusilazole, flusulfamide, flutianil, flutolanil, flutria flutriafol, furfural, furmecyclox, flumetover, flumorph, proquinazid, prochloraz, procymidone, prothiocarb, prothiocona prothioconazole, propamocarb, propiconazole, propineb, furophanate, probenazole, bromuconazole, hexachlorobutadiene, hexaconazole ), hexylthiofos, bethoxazin, benalaxyl ), benalaxyl M, benodanil, benomyl, pefurazoate, benquinox, penconazole, benzamorph, pencycuron, benzohydroxamic acid), bentaluron, benthiazole, benthiavalicarb, benthiavalicarb isopropyl, penthiopyrad, penflufen, boscalid, phosdiphen ), fosetyl, fosetyl aluminum, polyoxins, polyoxorim, polycarbamate, metazoxolon, folpet, formaldehyde, machine oil , maneb, mancozeb, mandipropamid, myclozolin, myclobutanil, mildiomycin, milneb, mecarbinzid, methasulfocarb, enoxastrobin, oxathiapiprolin, coumoxystrobin, triclopyricarb, picarbutrazox, pyrisoxazole, pyriminostrobin , fenaminstrobin, flufenoxystrobin, mandestrobin, metconazole (metc onazole, metsulfovax, methfuroxam, metominostrobin, metrafenone, mepanipyrim, mefenoxam, meptyldinocap, mepronil, mebenil, iodomethane, rabenzazole, benzalkonium chloride, basic copper chloride, basic copper sulfate, metallic silver ), sodium hypochlorite, cupric hydroxide, wettable sulfur, calcium polysulfide, potassium hydrogen carbonate hydrogen carbonate, sodium hydrogen carbonate, inorganic sulfur, copper sulfate anhydride, nickel dimethyldithiocarbamate, zinc sulfate, copper sulfate pentahydrate ),
(A3)農園芸用生物農薬類;上記記載の農園芸用殺虫剤、農園芸用殺菌剤以外に、更なる生物農薬を使用又は利用することができる。その具体例としては、例えば、アグロバクテリウム・ラジオバクテル(Agrobacterium radiobacter)株K84(例えば、「AgBioChem,CA」製の「Galltrol-A(登録商標)」)、アグロバクテリウム・ラジオバクテル(Agrobacterium radiobacter)株K1026(例えば、「Becker Underwood,US」製の「Nogall(登録商標)」)、アグロバクテリウム・ラジオバクテル株84(Agrobacterium radiobacter strain 84)(例えば、「日本農薬(株)」製の「バクテローズ(登録商標)」等のアグロバクテリウム属(Agrobacterium spp.);アンペロマイセス・キスカリス(Ampelomyces quisqualis) 株AQ10(例えば、「IntrachemBio Italia & Co.KG」製の「AQ 10(登録商標)」)等のアンペロマイセス属(Ampelomyces sp.);アスペルギルス・フラブス(Aspergillus flavus)(例えば、「Syngenta」製の「Afla-Guard(登録商標)」)、アスペルギルス・フラブス(Aspergillus flavus)株AF36(例えば、「Arizona Cotton Research and Protection Council,US」製の「AF36(登録商標)」)等のアスペルギルス属(Aspergillus spp.);アウレオバシジウム・プルランス(Aureobasidium pullulans)株DSM14940の出芽胞子と、株DSM14941の出芽胞子の混合物(例えば、「bio-ferm,GmbH」製の「Botector(登録商標)」)等のアウレオバシジウム属(Aureobasidium spp.);バチルス・アミロリクエファシエンス(Bacillus amyloliquefaciens)株AT-332(例えば、「出光アグリ(株)」製の「インプレッションクリア(登録商標)」)、バチルス・アミロリクエファシエンス(Bacillus amyloliquefaciens)株B246(例えば、「University of Pretoria」製の「Avogreen(登録商標)」)、バチルス・アミロリクエファシエンス(Bacillus amyloliquefaciens)株D747(例えば、「Etec Crop Solutions,NZ」製の「Bacstar(登録商標)」)、バチルス・アミロリクエファシエンス(Bacillus amyloliquefaciens)株DB101(例えば、「Dagutat Bio lab, ZA」製の「Shelter(登録商標)」)、バチルス・アミロリクエファシエンス(Bacillus amyloliquefaciens)株DB102(例えば、「Dagutat Bio lab,ZA」製の「Artemis(登録商標)」)、バチルス・アミロリクエファシエンス(Bacillus amyloliquefaciens)株FZB42(例えば、「ABiTEP,DE」製の「RhizoVital(登録商標)」)、バチルス・アミロリクエファシエンス(Bacillus amyloliquefaciens)株GB03(例えば、「Bayer Crop Science AG, DE」製の「Kodiak(登録商標)」)、バチルス・アミロリクエファシエンス(Bacillus amyloliquefaciens)株MBI600(例えば、「Becker Underwood,US」製の「Subtilex(登録商標)」)、バチルス・セパシア(Bacillus cepacia)(例えば、「Microbial Products」製の「Deny Stine(登録商標)」)、バチルス・セレウス(Bacillus cereus)株BP01(例えば、「Arysta, US」製の「Mepichlor(登録商標)」)、バチルス・ファーマス(Bacillus firmus)株I-1582(例えば、「AgoGreen製)の「BioNeem(登録商標)」)、バチルス・ラテロスポルス(Bacillus laterosporus)(例えば、「Agro-Organics,SA」製の「Bio-Tode(登録商標)」)、バチルス・リケニホルミス(Bacillus licheniformis)株SB3086(例えば、「Novozymes」製の「EcoGuard Biofungicide(登録商標)」)、バチルス・マロカヌス(Bacillus maroccanus)(例えば、「Micro Flo Company」製)、バチルス・メガテリウム(Bacillus megaterium)株YFM3.25(例えば、「BioArc」製の「Bioarc(登録商標)」)、バチルス・メチエンス(Bacillus metiens)(「Micro Flo Company」製)、バチルス・ミコイデス(Bacillus mycoides)分離株J.(例えば、「Certis USA」製の「BmJ(登録商標)」)、バチルス・ポピリアエ(Bacillus popilliae)(例えば、「Bio-Crop,CO」製の「Cronox(登録商標)」)、バチルス・プミラス(Bacillus pumilus)株BU F-33(例えば、「Becker Underwood,US」製の「Integral F-33(登録商標)」)、バチルス・プミラス(Bacillus pumilus)株GB34(例えば、「Bayer CropScience AG,DE」製の「Yield Shield(登録商標)」)、バチルス・プミラス(Bacillus pumilus)株QST2808(例えば、「Bayer CropScience LP,US」製の「Sonata(登録商標)」)、バチルス・シンプレクス(Bacillus simplex)株CGF2856(「アリスタライフサイエンス(株)」製の「モミホープ水和剤(登録商標)」)、バチルス・スファエリクス(Bacillus sphaericus)、特に、抗原型H5a5b株2362(例えば、「Valent BioSciences,US」製の「VectoLex(登録商標)」)、バチルス・サブチリス(Bacillus subtilis)(例えば「出光アグリ(株)」製の「ボトキラー水和剤(登録商標)」)、バチルス・サブチリス var.アミロリクエファシエンス(Bacillus subtilis var. amyloliquefaciens)株FZB24(例えば、「Novozyme Biologicals,Inc.US」製の「Taegro(登録商標)」)、バチルス・サブチリス(Bacillus subtilis)株QST713/AQ713(例えば、「Bayer CropScienceLP,US」製の「SERENADE MAX(登録商標)」)、バチルス・サブチリス(Bacillus subtilis)株AQ30002(例えば、「Serenade-DPZ(登録商標)」)、バチルス・サブチルス(Bacillus subtilis)株D747(例えば、「クミアイ化学工業(株)」製の「エコショット(登録商標)」)、バチルス・サブチリス(Bacillus subtilis)株HAI-0404(例えば、「(株)ニッソーグリーン」製の「アグロケア水和剤(登録商標)」)、バチルス・サブチリス(Bacillus subtilis)株MBI600(例えば、「出光興産(株)」製の「ボトピカ水和剤(登録商標)」)、バチルス・サブチリス(Bacillus subtilis)株Y1336(例えば、「アリスタライフサイエンス(株)」製の「バチスター水和剤(登録商標)」)、バチルス・チューリンゲンシス(Bacillus thuringiensis)株AM65-52(例えば、「Valent BioSciences,US」製の「VectoBac(登録商標)」)、バチルス・チューリンゲンシス・イスラエレンシス(Bacillus thuringiensis israelensis)株BMP144(例えば、「Becker Microbial Products IL」製の「Aquabac(登録商標)」)、バチルス・チューリンギエンシス・クルスタキー(Bacillus thuringiensis subspec.Kurstaki)株BMP 123(「Becker Microbial Products,IL」製)、バチルス・チューリンギエンシス・クルスタキー(Bacillus thuringiensis Kurstaki)株HD-1(例えば、「Valent BioSciences,US」製の「Dipel ES(登録商標)」)、バチルス・チューリンゲンシス亜種アイザワイ(Bacillus thuringiensis subsp.aizawai) 株ABTS-1857(SD-1372、例えば、「Bayer Crop Science AG, DE」製の「XenTari(登録商標)」)、バチルス・チューリンゲンシス亜種アイザワイ(Bacillus thuringiensis subsp.aizawai)抗原型H-7(例えば、「Valent BioSciences,US」製の「Florbac WG(登録商標)」)、バチルス・チューリンゲンシス亜種アイザワイ(Bacillus thuringiensis subsp.aizawai)株GC-91、バチルス・チューリンゲンシス 亜種 アエギプチ(Bacillus thuringiensis subspecies.Aegypti)(例えば、「Agerin(登録商標)」)、バチルス・チューリンゲンシス亜種テネブリオニス(Bacillus thuringiensis subsp.tenebrionis)株NB 176(SD-5428、例えば、「BioFa DE」製の「Novodor FC(登録商標)」)、バチルス・チューリンギエンシス変種7216(Bacillus thuringiensis var.7216)(例えば、「Amactic」及び「Pethian」)、バチルス・チューリンギエンシス変種T36(Bacillus thuringiensis var.T36)(例えば、「Cahat」)、バチルス・チューリンゲンシス変種コルメリ(Bacillus thuringiensis var.Colmeri)(例えば、「Changzhou Jianghai Chemical Factory」製の「TianBaoBTc(登録商標)」)、バチルス・チューリンゲンシス変種サンジエゴ(Bacillus thuringiensis var. san diego)(例えば、「Bacillus thuringiensis var. san diego」」製の「M-One(登録商標)」)等のバチルス属(Bacillus spp.);
(A3) Agricultural and horticultural biopesticides: In addition to the above agricultural and horticultural insecticides and agricultural and horticultural fungicides, further biopesticides can be used or utilized. Specific examples include Agrobacterium radiobacter strain K84 (e.g., "Galltrol-A (registered trademark)" manufactured by "AgBioChem, CA"), Agrobacterium radiobacter strain K1026 (e.g., "Nogall (registered trademark)" manufactured by "Becker Underwood, US"), Agrobacterium radiobacter strain 84 (e.g., "Nippon Nohyaku Co., Ltd." "Bacteroses ( Agrobacterium spp., such as “Agrobacterium spp.”; genera (Ampelomyces sp.); Aspergillus flavus (e.g. "Afla-Guard®" from "Syngenta"), Aspergillus flavus strain AF36 (e.g. "Arizona Cotton Research and Aspergillus spp., such as "AF36®" manufactured by the Protection Council, US; a mixture of budding spores of Aureobasidium pullulans strain DSM14940 and budding spores of strain DSM14941 (e.g. Aureobasidium spp. such as "Botector®" from "bio-ferm, GmbH"); Bacillus amyloliquefaciens strain AT-332 (e.g. Ltd.), Bacillus amyloliquefaciens strain B246 (e.g. "Avogreen®" from the University of Pretoria), Bacillus amylo request facilitation (B Bacillus amyloliquefaciens strain D747 (e.g. "Bacstar®" from "Etec Crop Solutions, NZ"), Bacillus amyloliquefaciens strain DB101 (e.g. from "Dagutat Biolab, ZA"). "Shelter®"), Bacillus amyloliquefaciens strain DB102 (e.g. "Artemis®" from "Dagutat Biolab, ZA"), Bacillus amyloliquefaciens amyloliquefaciens strain FZB42 (e.g. "RhizoVital®" from "ABiTEP, DE"), Bacillus amyloliquefaciens strain GB03 (e.g. "Kodiak" from "Bayer Crop Science AG, DE") (registered trademark)”), Bacillus amyloliquefaciens strain MBI600 (e.g. “Subtilex®” from “Becker Underwood, US”), Bacillus cepacia (e.g. “ Microbial Products" Deny Stine"), Bacillus cereus strain BP01 (e.g. "Mepichlor" from Arysta, US), Bacillus firmus Strain I-1582 (e.g. "BioNeem®" from "AgoGreen"), Bacillus laterosporus (e.g. "Bio-Tode®" from "Agro-Organics, SA") , Bacillus licheniformis strain SB3086 (e.g. "EcoGuard Biofungicide®" from "Novozymes"), Bacillus maroccanus (e.g. from "Micro Flo Company"), Bacillus - Bacillus megaterium strain YFM3.25 (e.g. "Bioarc®" from "BioArc"), Bacillus metiens (from "Micro Flo Company"), Bacillus mycoides Isolate J. (e.g. "BmJ®" from "Certis USA"), Bacillus popilliae (e.g. "Cronox®" from "Bio-Crop, CO"), Bacillus pumilus strain BU F-33 (e.g. "Integral F-33®" from "Becker Underwood, US"), Bacillus pumilus strain GB34 (e.g. "Bayer CropScience AG, DE"), Bacillus pumilus strain QST2808 (e.g., "Sonata" from Bayer CropScience LP, US), Bacillus simplex ( Bacillus simplex) strain CGF2856 (“Momihope wettable powder (registered trademark)” manufactured by “Arista Life Sciences Co., Ltd.”), Bacillus sphaericus, especially serotype H5a5b strain 2362 (for example, “Valent BioSciences, "VectoLex (registered trademark)" manufactured by US"), Bacillus subtilis (for example, "Botkiller Wettable Powder (registered trademark)" manufactured by "Idemitsu Agri Co., Ltd."), Bacillus subtilis var. Bacillus subtilis var. "SERENADE MAX®" manufactured by U.S.A., Bacillus subtilis strain AQ30002 (e.g., "Serenade-DPZ (registered trademark)"), Bacillus subtilis strain D747 (e.g., "Eco Shot (registered trademark)" manufactured by "Kumiai Chemical Industry Co., Ltd."), Bacillus subtilis ( Bacillus subtilis) strain HAI-0404 (for example, "Agrocare Wettable Powder (registered trademark)" manufactured by "Nisso Green Co., Ltd."), Bacillus subtilis strain MBI600 (for example, "Idemitsu Kosan Co., Ltd.") "Botopika wettable powder (registered trademark)" manufactured by Bacillus subtilis strain Y1336 (for example, "Batister wettable powder (registered trademark)" manufactured by Arista Life Sciences Co., Ltd.), Bacillus subtilis strain Y1336 Bacillus thuringiensis strain AM65-52 (e.g. "VectoBac®" from "Valent BioSciences, US"), Bacillus thuringiensis israelensis strain BMP144 (e.g. "Becker "Aquabac®" from "Microbial Products IL"), Bacillus thuringiensis subspec. Kurstaki strain BMP 123 (from "Becker Microbial Products, IL"), Bacillus thuringiensis kurstaki (Bacillus thuringiensis Kurstaki) strain HD-1 (e.g. "Dipel ES®" from "Valent BioSciences, US"), Bacillus thuringiensis subsp. aizawai strain ABTS-1857 (SD -1372, e.g. "XenTari®" from "Bayer Crop Science AG, DE"), Bacillus thuringiensis subsp. aizawai serotype H-7 (e.g. "Valent BioSciences, US" Florbac WG (registered trademark)), Bacillus thuringiensis Bacillus thuringiensis subsp. aizawai strain GC-91, Bacillus thuringiensis subsp. Aegypti (e.g. "Agerin®"), Bacillus thuringiensis subsp. Bacillus thuringiensis subsp.tenebrionis strain NB 176 (SD-5428, e.g. "Novodor FC®" from "BioFa DE"), Bacillus thuringiensis var. 7216 (e.g. " Amactic" and "Pethian"), Bacillus thuringiensis var. T36 (e.g., "Cahat"), Bacillus thuringiensis var. Colmeri (e.g., "Changzhou Jianghai Chemical "TianBaoBTc®" made by "Factory"), Bacillus thuringiensis var. san diego (e.g., "M-One®" made by "Bacillus thuringiensis var. san diego") ) such as Bacillus spp.;
ベアウベリア・バシアナ(Beauveria bassiana)株(例えば、「Intrachem Bio Italia」製の「Naturalis(登録商標)」)、ベアウベリア・バシアナ(Beauveria bassiana)株CG716(例えば、「Novozymes」製の「BoveMax(登録商標)」)、ベアウベリア・バシアナ(Beauveria bassiana)株F-263(例えば、「出光興産(株)」製の「バイオリサ・マダラ(登録商標)」)、ベアウベリア・バシアナ(Beauveria bassiana)株GHA(例えば、「ARYSTA」製の「ボタニガード水和剤(登録商標)」)、ベアウベリア・ブロングニアルチイ(Beauveria brongniartii)(例えば、「Andermatt Biocontrol AG」製の「Beaupro(登録商標)」)等のベアウベリア属(Beauveria spp.);ブラディリゾビウム・ジャポニクム(Bradyrhizobium japonicum) (例えば、「Novozymes」製の「Optimize(登録商標)」);バークホルデリア(Burkholderia spp.)株A396(例えば、「Marrone Bio Innovations」製の「MBI-206 TGAI(登録商標)」);カンジダ・オレオフィラ(Candida oleophila)株I-82(例えば、「Ecogen Inc.,US」製の「Aspire(登録商標)」)、カンジダ・オレオフィラ(Candida oleophila)O株(例えば、「BioNext」製の「Nexy(登録商標)」)、カンジダ・サイトアナ(Candida saitoana)(例えば、「Biotechnology Research And Development Corporation」製)、カンジダ・サイトアナ(Candida saitoana)(例えば、「Micro Flo Company、US(BASF SE)」製の「BIOCURE(登録商標)」)等のカンジダ属(Candida spp.);カエトミウム・クプレウム(Chaetomium cupreum)(例えば、「AgriLife」製の「BIOKUPRUM TM(登録商標)」)、カエトミウム・グロボスム(Chaetomium globosum)(例えば、「Rivale」製の「Rivadiom(登録商標)」)等のカエトミウム属(Chaetomium sp.);クロモバクテリウム・サブツガエ(Chromobacterium subtsugae)株PRAA4-1T(MBI-203、例えば、「Marrone Bio Innovations」製の「Grandevo(登録商標)」)等のクロモバクテリウム属(Chromo-bacterium sp.);クラドスポリウム・クラドスポリオイデス(Cladosporium cladosporioides)(例えば、「Cladosporium cladosporioides」製);クロノスタキス・ロゼア・カテヌラータ(Clonostachys rosea f. catenulate)株J1446 (例えば、「Verdera,Finland」製の「PRESTOP(登録商標)」);コレトトリクム・グロエオスポリオイデス(Colletotrichum gloeosporioides)(例えば、「Agriultural Research Initiatives」製の「Collego(登録商標)」);コニオチリウム・ミニタンス(Coniothyrium minitans)株CON/M/91-08 (例えば、「Encore Technologies,LLC」製の「Contans(登録商標)」)等のコニオチリウム属(Coniothyrium spp.);クリプトコックス・アルビドゥス(Cryptococcus albidus)(例えば、「Anchor Bio-Technologies,ZA」製の「YieldPlus(登録商標)」);デルフチア・アシドボランス(Delftia acidovorans)株RAY209(例えば、「Brett Young Seeds」製の「BioBoost(登録商標)」);ジロホスホラ・アロペクリ(Dilophosphora alopecuri)(例えば、「Twist Fungus(登録商標)」);ドレクスレラ・モノセラス(Drechsrela monoceras)株MTB-951(例えば、「三井化学アグロ(株)」製の「タスマート除草剤(登録商標)」)等のドレックスレラ属(Drechsrela sp.);エントモフトラ・ビルレンタ(Entomophthora virulenta)(例えば、「Ecomic」製の「Vektor(登録商標)」);フザリウム・オキシスポラム(Fusarium oxysporum)株101-2(例えば、「エーザイ生科研社」製の「マルカライト」)、フザリウム・オキシスポラム(Fusarium oxysporum)株Fo47(例えば、「Natural Plant Protection」製の「Fusaclean(登録商標)」)等のフザリウム属(Fusarium spp.);グリオクラジウム・カテヌラツム(Gliocladium catenulatum)株J1446(例えば、「AgBio Inc.」製の「Prestop(登録商標)」)、グリオクラジウム・ロセウム(Gliocladium roseum)株321U(「W.F.Stoneman Company LLC」製)等のグリオクラジウム属(Gliocladium sp.);ヒルステラ・トムプソニイ(Hirsutella thompsonii)(例えば、「Agro Bio-tech Research Centre, IN」製の「Mycohit(登録商標)」及び「ABTEC(登録商標)」);ラクトバチルス・アシドフィルス(Lactobacillus acidophilus)(例えば、「Inagrosa-Industrias Agrobiologicas, S.A」製の「Fruitsan(登録商標)」)、ラクトバチルス・プランタラム(Lactobacillus plantarum)株BY(例えば、「Meiji Seika ファルマ(株)」製の「ラクトガード水和剤」)、ラクトバチルス(Lactobacillus sp.)(例えば、「LactoPAFI」製の「Lactoplant(登録商標)」)等のラクトバチルス属(Lactobacillus sp.);
Beauveria bassiana strains (e.g. "Naturalis®" from "Intrachem Bio Italia"), Beauveria bassiana strain CG716 (e.g. "BoveMax®" from "Novozymes") ”), Beauveria bassiana strain F-263 (e.g., “Biolisa Madara (registered trademark)” manufactured by “Idemitsu Kosan Co., Ltd.”), Beauveria bassiana strain GHA (e.g., “ Beauveria such as "Botaniguard Wettable Powder" from "ARYSTA"), Beauveria brongniartii (e.g. "Beaupro" from "Andermatt Biocontrol AG") spp.); Bradyrhizobium japonicum (e.g. "Optimize®" from "Novozymes"); Burkholderia spp. strain A396 (e.g. from "Marrone Bio Innovations" Candida oleophila strain I-82 (e.g., "Aspire®" from Ecogen Inc., US), Candida oleophila oleophila) strain O (e.g., "Nexy®" from "BioNext"), Candida saitoana (e.g., from "Biotechnology Research And Development Corporation"), Candida saitoana Candida spp. such as (e.g., "BIOCURE®" from "Micro Flo Company, US (BASF SE)"); Chaetomium cupreum (e.g., "" from "AgriLife") BIOKUPRUM TM®”), Chaetomium globo sum) (e.g. "Rivadiom®" from "Rivale"); Chromobacterium subtsugae strain PRAA4-1T (MBI-203, e.g. "Marrone Chromo-bacterium sp., such as "Grandevo®" from Bio Innovations; Cladosporium cladosporioides (for example, from "Cladosporium cladosporioides"); Chronos Clonostachys rosea f. catenulate strain J1446 (e.g. "PRESTOP®" from "Verdera, Finland"); Colletotrichum gloeosporioides (e.g. "Agriultural Research Initiatives") "Collego®" from "Encore Technologies, LLC"); (Coniothyrium spp.); Cryptococcus albidus (e.g. "YieldPlus®" from "Anchor Bio-Technologies, ZA"); Delftia acidovorans strain RAY209 (e.g. "Brett Dilophosphora alopecuri (e.g. Twist Fungus®); Drechsrela monoceras strain MTB-951 (e.g. Mitsui Drechsrela sp. such as "Tasmart herbicide (registered trademark)" manufactured by Kagaku Agro Co., Ltd.; Entomophthora virulenta) (e.g. "Vektor®" from "Ecomic"); Fusarium oxysporum strain 101-2 (e.g. "Marcalite" from "Eisai Seikaken"), Fusarium oxysporum (Fusarium oxysporum) strain Fo47 (e.g. "Fusaclean®" from "Natural Plant Protection"); Gliocladium catenulatum strain J1446 (e.g. "AgBio Gliocladium sp. such as "Prestop®" from "W.F. Stoneman Company LLC"), Gliocladium roseum strain 321U (from "W.F. Stoneman Company LLC"); Hirsutella thompsonii) (e.g. "Mycohit®" and "ABTEC®" from "Agro Bio-tech Research Center, IN"); Lactobacillus acidophilus (e.g. "Inagrosa-Industrias") Agrobiologicas, S.A.'s "Fruitsan®"), Lactobacillus plantarum strain BY (e.g., "Meiji Seika Pharma Co., Ltd.'s "Lactogard wettable powder"), Lactobacillus (Lactobacillus sp.) (e.g., "Lactoplant (registered trademark)" manufactured by "LactoPAFI");
レカニシリウム・レカニイ(Lecanicillium lecanii)株KV01の分生子(例えば、「Koppert/Arysta」製の「Mycotal(登録商標)」);メタリジウム・アニソプリアエ(Metarhizium anisopliae)株F52(例えば、「Bayer CropScience」製の「BIO 1020(登録商標)」)、メタリジウム・アニソプリアエ(Metarhizium anisopliae)株SMZ-2000(「アリスタライフサイエンス(株)」製の「パイレーツ粒剤(登録商標)」)、メタリジウム・アニソプリアエ変種アクリジウム(Metarhizium anisopliae var. acridum)(例えば、「Biological Control Products」製の「Green Muscle(登録商標)」)、メタリジウム・アニソプリアエ変種アクリズム(Metarhizium anisopliae var. acridum)(例えば、「Becker Underwood,US」製の「GreenGuard(登録商標)」)等のメタリジウム属(Metarhizium spp.);メトスクニコウィア・フラクチコーラ(Metschnikowia fructicola) (例えば、「Bayer CropScience」製の「Shemer(登録商標)」);ミクロドキウム・ジメルム(Microdochium dimerum)(例えば、「Agrauxine、France」製の「ANTIBOT(登録商標)」);ミクロスファエロプシス・オクラセア(Microsphaeropsis ochracea)(例えば、「Prophyta」製の「Microx(登録商標)」);モナクロスポリウム・フィマトパガム(Monacrosporium phymatopagum)(「トモエ化学工業(株)」製の「ネマヒトン(登録商標)」);ムコル・ハエメリス(Mucor haemelis)(例えば、「Indore Biotech Inputs & Research」製の「BioAvard(登録商標)」);ミロテシウム・ベルカリア(Myrothecium verrucaria)株AARC-0255(例えば、「Valent Biosciences」製の「DiTera TM(登録商標)」);オフィオストマ・ピリフェルム(Ophiostoma piliferum)株D97(例えば、「Sylvanex」);パエシロマイセス・フモソロセウス(Paecilomyces fumosoroseus)株apopka 97(例えば、「Biobest」製の「PreFeRal(登録商標)WG」)、パエシロマイセス・フモソロセウス(Paecilomyces fumosoroseus)株FE 9901(例えば、「Natural Industries Inc.(Novozymes company)」製の「No Fly(登録商標)」)、パエシロマイセス・フモソロセウス(Paecilomyces fumosoroseus)(例えば、「東海物産(株)」製の「プリファード水和剤」)、パエシロマイセス・リラシヌス(Paecilomyces lilacinus) 株251 (例えば、「Prophyta」製の「BioAct WG(登録商標)」)、パエシロマイセス・リラシヌス(Paecilomyces lilacinus)を含んでいる組成物(例えば、「MELOCON(登録商標)」)、パエシロマイセス・テヌイペス(Pacilimyces tenuipes)株T1(例えば、「出光興産(株)」製の「ゴッツA(登録商標)」)、パエシロマイセス・バリオチイ(Paecilomyces variotii)株Q-09(例えば、「Quimia,MX」製の「Nemaquim(登録商標)」)等のパエシロマイセス属(Paecilomyces spp.);パエニバチルス・ポリミキサ(Paenibacillus polymyxa)株AC-1(「Green Biotech Company Ltd.」製の「Topseed(登録商標)」)、パエニバチルス・ポピリアエ(Paenibacillus poppiliae) (例えば、「St.Gabriel Laboratories」製の「Milky spore disease(登録商標)」)等のパエニバチルス属(Paenibacillus spp.);パスツリア・ニシザワ(Pasteuria nishizawa)(「Clariva(登録商標)」)、パスツリア・ニシザワエ(Pasteuria nishizawae)(例えば、「Pasteuria Bioscience」製の「oyacystLF/ST(登録商標)」)、パスツリア・ペネトランス(Pasteuria penetrans)(例えば、「Pasteuria Bioscience」製の「Pasteuria(登録商標)」)等のパスツリア属(Pasteuria spp.);ペクトバクテリウム・カロトボルム(Pectobacterium carotovorum)(例えば、「日産化学(株)」製の「バイオキーパー(登録商標)」)、ペクトバクテリウム・カロトボルム(Pectobacterium carotovorum)CGE234M403株(例えば、「クミアイ化学工業(株)」製の「エコメイト(登録商標)」)等のペクトバクテリウム属(Pectobacterium spp.);ペニシリウム・ビライイ(Penicillium bilaii)株(例えば、「Novozymes」製の「Jump Start(登録商標)」);フレビオプシス・ギガンテア(Phlebiopsis gigantea)株FOC PG B22/SP1190/3.2 (例えば、「Verdera、Finland」製の「ROTSOP(登録商標)」);ホマ・マクロストロマ(Phoma macrostroma)株94-44B(例えば、「Scotts, US」製の「Phoma H(登録商標)」);
Conidia of Lecanicillium lecanii strain KV01 (e.g. "Mycotal®" from "Koppert/Arysta"); Metarhizium anisopliae strain F52 (e.g. "Bayer CropScience"); BIO 1020 (registered trademark)"), Metarhizium anisopliae strain SMZ-2000 ("Pirate Granules (registered trademark)" manufactured by "Arista Life Sciences Inc."), Metarhizium anisopliae var. acridium (Metarhizium anisopliae) acridum (e.g. "Green Muscle®" from "Biological Control Products"), Metarhizium anisopliae var. Metschnikowia fructicola (e.g. "Shemer®" from "Bayer CropScience"); Microdochium dimerum ( "ANTIBOT®" from "Agrauxine, France"); Microsphaeropsis ochracea (e.g. "Microx®" from "Prophyta"); Monaclosporium fimatopa gum (Monacrosporium phymatopagum) (“Nemahithon®” from “Tomoe Chemical Industry Co., Ltd.”); Mucor haemelis (e.g. “BioAvard®” from “Indore Biotech Inputs & Research”) ); Myrothecium verrucaria strain AARC-0255 (e.g. "DiTera TM" from "Valent Biosciences"); Ophios Ophiostoma piliferum strain D97 (e.g. "Sylvanex"); Paecilomyces fumosoroseus strain apopka 97 (e.g. "PreFeRal® WG" from "Biobest"), Paecilomyces fumosoroseus) strain FE 9901 (e.g., "No Fly (registered trademark)" manufactured by "Natural Industries Inc. (Novozymes company)"), Paecilomyces fumosoroseus (e.g., "Tokai Bussan Co., Ltd." preferred wettable powder"), Paecilomyces lilacinus strain 251 (e.g., "BioAct WG®" from "Prophyta"), compositions containing Paecilomyces lilacinus (e.g., "MELOCON (registered trademark)"), Paecilomyces tenuipes strain T1 (for example, "Gottsu A (registered trademark)" manufactured by "Idemitsu Kosan Co., Ltd."), Paecilomyces variotii strain Q- Paecilomyces spp. such as 09 (e.g., "Nemaquim®" from "Quimia, MX"); Paenibacillus polymyxa strain AC-1 (from "Green Biotech Company Ltd."); Paenibacillus spp., such as "Topseed®"), Paenibacillus poppiliae (e.g., "Milky spore disease®" from "St. Gabriel Laboratories"); (Pasteuria nishizawa) (“Clariva®”), Pasteuria nishizawae (e.g. “oyacystLF/S” from “Pasteuria Bioscience”) Pasteuria spp. such as Pasteuria penetrans (e.g. "Pasteuria®" from "Pasteuria Bioscience"); Pectobacterium carotovorum ) (for example, “Biokeeper (registered trademark)” manufactured by “Nissan Chemical Co., Ltd.”), Pectobacterium carotovorum CGE234M403 strain (for example, “Ecomate (registered trademark)” manufactured by “Kumiai Chemical Industry Co., Ltd.”) Pectobacterium spp., such as "Pectobacterium spp."); Penicillium bilaii strains (e.g., "Jump Start®" from "Novozymes"); Phlebiopsis gigantea Strain FOC PG B22/SP1190/3.2 (e.g. "ROTSOP®" from "Verdera, Finland"); Phoma macrostroma strain 94-44B (e.g. "Scotts, US") Phoma H (registered trademark)");
ポコニア・クラミドスポリア 変種カテヌラタ(Pochonia chlamydosporia var. catenulata)(例えば、「The National Center of Animal and Plant Health(CENSA);CU」製の「KlamiC(登録商標)」);シュードモナス・アウレオファシエンス(Pseudomonas aureofaciens)株TX-1(例えば、「Eco Soils Systems, CA」製の「Spot-Less Biofungicide(登録商標)」)、シュードモナス・クロロラフィス(Pseudomonas chlororaphis)株63-28(例えば、「EcoSoil Systems」製の「ATEze(登録商標)」)、シュードモナス・クロロラフィス(Pseudomonas chlororaphis)株MA 342(例えば、「Bioagri,S」製の「Cedomon(登録商標)」)、シュードモナス・フルオレセンス(Pseudomonas fluorescens)株1629RS(例えば、「Frost Technology Corp」製の「Frostban D(登録商標)」)、シュードモナス・フルオレセンス(Pseudomonas fluorescens)株A506(例えば、「Blightban」」製の「Blightban(登録商標)」)、シュードモナス・フルオレセンス(Pseudomonas fluorescens)株FPT-9601(「多木化学(株)」製の「小苗ふく土(登録商標)」)、シュードモナス・フルオレセンス(Pseudomonas fluorescens)株FPT-9601と株FPH-9601の混合品(「多木化学(株)」製の「セル苗元気(登録商標)」)、シュードモナス・フルオレセンス(Pseudomonas fluorescens)株G7090(例えば、「アリスタライフサイエンス(株)」製の「ベジキーパー(登録商標)」)、シュードモナス・プロラジキス(Pseudomonas proradix)(例えば、「Sourcon Padena」製の[Proradix(登録商標)])、シュードモナス・レシノボランス(Pseudomonas resinovorans)(例えば、「Agricultural Research Council,SA」製の「Solanacure(登録商標)」)、シュードモナス・シリンガエ(Pseudomonas syringae)株MA-4(例えば、「EcoScience,US」製の「Biosave(登録商標)」)、シュードモナス・シリンガエ(Pseudomonas syringae)株742RS(例えば、「Frostban C」製の「Frost Technology Corp(登録商標)」)、シュードモナス・ロデシア(Pseudomonas rhodesiae) HAI-0804株(「日本曹達(株)」製の「マスタピース水和剤(登録商標)」)、シュードモナス(Pseudomonas sp.) 株CAB-02(例えば、「日産化学工業(株)」製の「モミゲンキ水和剤」)等のシュードモナス属(Pseudomonas spp.);シュードジマ・アフィジス(Pseudozyma aphidis)(例えば、「Yissum Research Development Company of the Hebrew University of Jerusalem」製)、シュードジマ・フロキュローザ(Pseudozyma flocculosa) 株PF-A22 UL(例えば、「Plant Products Co.Ltd,CA」製の「Sporodex L(登録商標)」)等のシュードジマ属(Pseudozyma sp.);ピシウム・オリガンドルム(Pythium oligandrum)株DV74又はM1(例えば、「Bioprepraty,CZ」製の「Polyversum(登録商標)」);レイノウトリア・サクリネンシス(Reynoutria sachlinensis)(例えば、「Marrone BioInnovations,US」製の「REGALIA(登録商標)」);リゾポゴン・アミロポゴン(Rhizopogon amylopogon)(例えば、「Helena Chemical Company」製の「Myco-Sol(登録商標)」)、リゾポゴン・フルビグレバ(Rhizopogon fulvigleba)(例えば、「Helena Chemical Company」製の「Myco-Sol(登録商標)」)等のリゾポゴン属(Rhizopogon spp.);サッカロマイセス・セレビシエ(Saccharomyces cerevisiae)株 (例えば、「Lesaffre et Compagnie, FR」製);スクレロチニア・ミノル(Sclerotinia minor)(例えば、「Agrium Advanced Technologies」製の「Sarritor(登録商標)」);セラチア・エントモフィラ(Serratia entomophila)(例えば、「Wrightson Seeds」製の「Invade(登録商標)」);スポロトリキス・インセクトルム(Sporothrix insectorum)(例えば、「Biocerto;BR」製の「Sporothrix Es(登録商標)」);スタゴノスポラ・ファセオリ(Stagonospora phaseoli)(例えば、「Syngenta」から市販されている);ストレプトマイセス・アシジスカビエス(Streptomyces acidiscabies)株RL-110T(例えば、「Marrone Bioinnovations, CA」製の「MBI-005EP(登録商標)」)、ストレプトマイセス・カンジズス(Streptomyces candidus)株Y21007-2(例えば、「Biontech,TW」製の「BioBac(登録商標)」)、ストレプトマイセス・ガルバス(Streptomyces galbus)株K61(例えば、「「Verdera」製のMycostop(登録商標)」)、ストレプトマイセス・リジクス(Streptomyces lydicus)株WYEC108(例えば、「Natural Industries,US」製の「ACTINOVATE(登録商標)」)、ストレプトマイセス・サラセチクス(Streptomyces saraceticus)(例えば、「A & A Group(Agro Chemical Corp.)」製の「Clanda(登録商標)」)等のストレプトマイセス属(Streptomyces spp.);
Pochonia chlamydosporia var. catenulata (e.g. "The National Center of Animal and Plant Health (CENSA); "KlamiC®" by CU); Pseudomonas aureofaciens Strain TX-1 (e.g., "Spot-Less Biofungicide®" from "Eco Soils Systems, CA"), Pseudomonas chlororaphis strain 63-28 (e.g., " ATEze®”), Pseudomonas chlororaphis strain MA 342 (e.g. “Cedomon®” from “Bioagri, S”), Pseudomonas fluorescens strain 1629RS ( For example, "Frostban D®" from "Frost Technology Corp"), Pseudomonas fluorescens strain A506 (e.g. "Blightban®" from "Blightban"), Pseudomonas Fluorescens (Pseudomonas fluorescens) strain FPT-9601 (“Konae Fukudo (registered trademark)” manufactured by “Taki Kagaku Co., Ltd.”), Pseudomonas fluorescens strain FPT-9601 and strain FPH- 9601 mixture ("Cell Seedling Genki (registered trademark)" manufactured by "Taki Chemical Co., Ltd."), Pseudomonas fluorescens strain G7090 (for example, manufactured by "Arysta Life Science Co., Ltd." “Vegkeeper®”), Pseudomonas proradix (e.g. [Proradix®] from “Sourcon Padena”), Pseudomonas resinovorans (e.g. “Agricultural Research “Solanacure®” from EcoScience, SA), Pseudomonas syringae strain MA-4 (e.g. “Biosave®” from EcoScience, US), Pseudomonas syringae syringae) strain 742RS (for example, "Frost Technology Corp (registered trademark)" manufactured by "Frostban C"), Pseudomonas rhodesiae HAI-0804 strain ("Masterpiece Hydration" manufactured by "Nippon Soda Co., Ltd.") Agent (registered trademark)"), Pseudomonas sp. Strain CAB-02 (e.g., "Nissan Chemical Co., Ltd." Momigenki wettable powder), etc. Pseudomonas spp.; Pseudozyma aphidis (for example, "Yissum Research Development Company of the Hebrew University of Jerusalem"), Pseudozyma flocculosa strain PF-A22 UL (for example, "Plant Products Co. Ltd, CA") Pseudozyma sp., such as Sporodex L®); Pythium oligandrum strain DV74 or M1 (e.g., Polyversum® from Bioprepraty, CZ); Reynoutria sachlinensis (e.g. "REGALIA®" from "Marrone BioInnovations, US"); Rhizopogon amylopogon (e.g. "Myco-Sol®" from "Helena Chemical Company") ), Rhizopogon fulvigleba (e.g. "Myco-Sol®" from "Helena Chemical Company"); Saccharomyces cerevisiae (Sacc Haromyces cerevisiae strains (e.g. from "Lesaffre et Compagnie, FR"); Sclerotinia minor (e.g. "Sarritor" from "Agrium Advanced Technologies"); Serratia entomophila ) (e.g. "Invade®" from "Wrightson Seeds"); Sporothrix insectorum (e.g. "Sporothrix Es®" from "Biocerto; BR"); (Stagonospora phaseoli) (commercially available, e.g. from "Syngenta"); Streptomyces acidiscabies strain RL-110T (e.g. "MBI-005EP®" from "Marrone Bioinnovations, CA"); ), Streptomyces candidus strain Y21007-2 (e.g., "BioBac®" from "Biontech, TW"), Streptomyces galbus strain K61 (e.g., "" Mycostop® from Verdera), Streptomyces lydicus strain WYEC108 (e.g., ACTINOVATE® from Natural Industries, US), Streptomyces Streptomyces spp. such as saraceticus (e.g. "Clanda®" from "A & A Group (Agro Chemical Corp.)");
タラロマイセス・フラバス(Talaromyces flavus) 株B-422(例えば、「セントラル硝子(株)」製の「モミキーパー(登録商標)」)、タラロマイセス・フラバス(Talaromyces flavus)株SAY-Y-94-01(例えば、「出光興産(株)」製の「タフブロック(登録商標)」)、タラロマイセス・フラバス(Talaromyces flavus) 株V117b(例えば、「Prophyta,DE」製の「PROTUS(登録商標) WG」)等のタラロマイセス属(Talaromyces spp.);チオバチルス属(Thiobacillus sp.)(例えば、「Cropaid Ltd,UK」製の「Cropaid(登録商標)」);トリコデルマ・アルブム(Trichoderma album)(例えば、「Bio-Zeid」として知られている製品)、トリコデルマ・アスペレラム(Trichoderma asperellum)株ICC 012(「Isagro」製)、トリコデルマ・アスペレラム(Trichoderma asperellum)株T34(例えば、「Bioncontrol Technologies,ES」製の「T34 Biocontrol(登録商標)」)、トリコデルマ・アスペレラム(Trichoderma asperellum) 株SKT-1(例えば、「クミアイ化学工業(株)」製の「ECO-HOPE(登録商標)」)、トリコデルマ・アトロビリデ(Trichoderma atroviride) 株(例えば、「Agrauxine,FR」製の「Esquive(登録商標) WP」)、トリコデルマ・アトロビリデ(Trichoderma atroviride) 株LC52(例えば、「Agrimm Technologies Ltd,NZ」製の「Tenet(登録商標)」)、トリコデルマ・アトロビリデ(Trichoderma atroviride) 株SKT-1(例えば、「クミアイ化学工業(株)」製の「エコホープ DJ (登録商標)」)、トリコデルマ・ガムシイ(Trichoderma gamsii)株ICC 080(例えば、「Bayer Crop Science LP,US」製の「BIO-TAMTM(登録商標)」)、トリコデルマ・ハルジアヌム(Trichoderma harzianum)株DB 103(例えば、「Dagutat Biolab」製の「T-Gro 7456(登録商標)」)、トリコデルマ・ハルジアヌム(Trichoderma harzianum) 株ITEM908(例えば、「Koppert」製の「Trianum-P(登録商標)」)、トリコデルマ・ハルジアヌム(Trichoderma harzianum)株KD(例えば、「Biological Control Products,SA」製の「Trichoplus(登録商標)」)、トリコデルマ・ハルジアヌム(Trichoderma harzianum) 株TH-35(例えば、「Mycontrol Ltd.」製の「ROOT PRO (登録商標)」)、トリコデルマ・ハルジアヌム・リファイ(Trichoderma harzianum rifai)株T-22(KRL-AG2) (例えば、「Firma BioWorks Inc.US」製の「PLANTSHIELD T-22G(登録商標)」)、トリコデルマ・ハルジアヌム・リファイ(Trichoderma harzianum rifai)株T-39(例えば、「Makhteshim Ltd,US」製の「TRICHODEX(登録商標)」)、トリコデルマ・リグノルム(Trichoderma lignorum)株TL-0601(例えば、「Futureco Bioscience,ES」製の「Mycotric(登録商標)」)、トリコデルマ・ポリスポラム(Trichoderma polysporum)株(例えば、「BINAB Bio-Innovation AB,Sweden」製の「Binab TF WP(登録商標)」)、トリコデルマ・ストロマチカム(Trichoderma stromaticum)(例えば、「Ceplac;Brazil」製の「TRICOVAB(登録商標)」)、トリコデルマ・ビレンス(Trichoderma virens) (「グリオクラジウム・ビレンス(Gliocladium virens)」としても知られている)株GL-21(例えば、「Certis LLC,US」製の「SOILGARD(登録商標)」)、トリコデルマ・ビリデ(Trichoderma viride) 株ICC080(例えば、「Isagro Ricerca,ITALIA」製の「REMEDIER(登録商標) WP」)、トリコデルマ・ビリデ(Trichoderma viride) 株TV1(例えば、「Koppert」製の「Trianum-P(登録商標)」)等のトリコデルマ属(Trichoderma spp.); ツカムレラ・パウロメタボラ(Tsukamurella paurometabola)株C-924(例えば、「HeberNem(登録商標)」);ウロクラジウム・ウデマンシー(Ulocladium oudemansii)株HRU3(例えば、「Botry-Zen Ltd,NZ」製の「Botry-Zen(登録商標)」);バリオボラックス・パラドクス(Variovorax paradoxus)株CGF4526(例えば、「セントラル硝子」製の「フィールドキーパー水和剤(登録商標)」);VA (Vesicular-Arbuscular Mycorrhiza)菌根菌(「出光アグリ(株)」製の「Drキンコン(登録商標)」);
Talaromyces flavus strain B-422 (e.g., "Momikeeper (registered trademark)" manufactured by "Central Glass Co., Ltd."), Talaromyces flavus strain SAY-Y-94-01 (e.g., , "Tough Block (registered trademark)" manufactured by "Idemitsu Kosan Co., Ltd."), Talaromyces flavus strain V117b (for example, "PROTUS (registered trademark) WG" manufactured by "Prophyta, DE"), etc. Talaromyces spp.; Thiobacillus sp. (e.g. "Cropaid®" from "Cropaid Ltd, UK"); Trichoderma album (e.g. "Bio-Zeid" ), Trichoderma asperellum strain ICC 012 (manufactured by "Isagro"), Trichoderma asperellum strain T34 (e.g. "T34 Biocontrol (registered trademark)" manufactured by "Bioncontrol Technologies, ES" Trademark)"), Trichoderma asperellum strain SKT-1 (e.g., "ECO-HOPE (registered trademark)" manufactured by "Kumiai Chemical Industry Co., Ltd."), Trichoderma atroviride strain (e.g. , "Esquive® WP" from "Agrauxine, FR"), Trichoderma atroviride strain LC52 (e.g. "Tenet®" from "Agrimm Technologies Ltd, NZ"), Trichoderma Trichoderma atroviride strain SKT-1 (e.g., "Ecohope DJ (registered trademark)" manufactured by "Kumiai Chemical Industry Co., Ltd."), Trichoderma gamsii strain ICC 080 (e.g., "Bayer Crop Science LP ``BIO-TAMTM (registered trademark)'' manufactured by ``US'', Trichoderma harzianum m) strain DB 103 (e.g. "T-Gro 7456®" from "Dagutat Biolab"), Trichoderma harzianum strain ITEM 908 (e.g. "Trianum-P®" from "Koppert") )”), Trichoderma harzianum strain KD (e.g. “Trichoplus®” from “Biological Control Products, SA”), Trichoderma harzianum strain TH-35 (e.g. “Mycontrol Ltd.), Trichoderma harzianum rifai strain T-22 (KRL-AG2) (e.g., "PLANTSHIELD T- 22G (registered trademark)"), Trichoderma harzianum rifai strain T-39 (e.g. "TRICHODEX (registered trademark)" from "Makhteshim Ltd, US"), Trichoderma lignorum strain TL-0601 (for example, "Mycotric (registered trademark)" manufactured by "Futureco Bioscience, ES"), Trichoderma polysporum strain (for example, "Binab TF WP (for example, "BINAB Bio-Innovation AB, Sweden") registered trademark)"), Trichoderma stromaticum (e.g. "TRICOVAB®" from "Ceplac; Brazil"), Trichoderma virens ("Gliocladium virens ) strain GL-21 (e.g. "SOILGARD®" from "Certis LLC, US"), Trichoderma viride strain ICC080 (e.g. "Isagro Ricerca, ITALIA"). Made by REMEDIE R® WP”), Trichoderma viride strain TV1 (e.g. “Trianum-P®” from “Koppert”); (Tsukamurella paurometabola) strain C-924 (e.g. "HeberNem®"); Ulocladium oudemansii strain HRU3 (e.g. "Botry-Zen®" from "Botry-Zen Ltd, NZ"); ); Variovorax paradoxus strain CGF4526 (for example, "Field Keeper Wettable Powder (registered trademark)" manufactured by "Central Glass"); VA (Vesicular-Arbuscular Mycorrhiza) mycorrhizal fungi ("Idemitsu Aguri "Dr Kinkon (registered trademark)" manufactured by Co., Ltd.);
バーティシリウム・アルボアトルム(Verticillium alboatrum)株WCS850(例えば、「Tree Care Innovations」製の「Dutch Trig(登録商標)」)、バーティシリウム・レカニ(Verticillium lecanii)株IMI 179172(例えば、「アリスタライフサイエンス(株)」製の「バータレック(登録商標)」)、バーティシリウム・レカニ(Verticillium lecanii)株IMI 263817(例えば、「アリスタライフサイエンス(株)」製の「マイコタール(登録商標)」)等のバーティシリウム属(Verticillium spp.);キサントモナス・カムペストリス(Xanthomonas campestris)(キャンペリコ液剤(登録商標) 多木化学より入手可能)等を併用することも可能である。
Verticillium alboatrum strain WCS850 (e.g. "Dutch Trig®" from "Tree Care Innovations"), Verticillium lecanii strain IMI 179172 (e.g. "Arysta Life Science "Vertalec (registered trademark)" manufactured by "Co., Ltd."), Verticillium lecanii strain IMI 263817 (for example, "Mycotal (registered trademark)" manufactured by "Arista Life Sciences Co., Ltd."), etc. Verticillium spp.; Xanthomonas campestris (Campelico Liquid (registered trademark) available from Taki Kagaku) and the like can also be used in combination.
更に、近年では昆虫性フェロモン(ハマキガ類、ヨトウガ類の交信攪乱剤等)、天敵昆虫等を用いたIPM(総合的害虫管理)技術が進歩しており、本発明の剤はそれらの技術と併用、又は体系化して用いることができる。例えば、アカメガシワクダアザミウマ、アリガタシマアザミウマ、イサエアヒメコバチ、オンシツツチヤコバチ、キイカブリダニ、ギフアブラバチ、ククメリスカブリダニ、クワコナコバチ、コレマンアブラバチ、サバクツヤコバチ、ショクガタマバエ、スワルスキーカブリダニ、タイリクヒメハナカメムシ、チチュウカイツヤコバチ、チリカブリダニ、チャバラアブラコバチ、ツヤコバチ、デジェネランスカブリダニ、トリコグラマ(蜂)、ナミテントウ、ナミヒメハナカメムシ、ハモグリコマユバチ、ハモグリミドリヒメコバチ、ヒメカメノコテントウ、ヒメハナカメムシ、ミヤコカブリダニ、リュウキュウツヤテントウ、リゾクトニア属(Rhizoctonia spp.)を食する、F. candidaやA. flavescens等のトビムシ(「トビムシと伝染性植物病原菌 (Rhizoctonia属)」化学と生物 Vol.51,No.4,2013 p267-269に記載)、ルビーアカヤドリコバチ、ヤマトクサカゲロウ、ヨーロッパトビチビアメバチ、リモニカスカブリダニ等の天敵生物、
Furthermore, in recent years, IPM (integrated pest management) technology using insect pheromones (such as communication disruptors for tomatopods and armyworms), natural enemy insects, etc. has progressed, and the agent of the present invention can be used in combination with these technologies. , or systematized. For example, red-clawed thrips, alligator thrips, isaea thrips, thrips thrips, thrips thrips, gifu aphid, cucumeris cucumeris, mulberry wasp, coleman thrips, desert thrips, leopard fly, swirski phytoseiid mite, tyric himehana Stink bug, mediterranean wasp, Chilean genus Chilean stinkbug, Chabara physiognomy cucumber, Tsuyako wasp, Degeneran phytoseiid tick, Trichograma (bee), Nami ladybug, Namihime stink bug, Leaf beetle, Leaf grim green wasp, Lesser stink bug, Lesser stink bug, Miyako phytoseiid mite, Collembola such as F.candida and A.flavescens, which feed on Rhizoctonia spp. and Rhizoctonia spp. 2013 pp267-269), natural enemy organisms such as ruby red wasps, mountain lacewings, European blackeye wasps, and phytoseiid Limonica
アブレビアタ・カウカシカ(Abbreviata caucasica);アクアリア属種(Acuaria spp.);アガメルミス・デカウダタ(Agamermis decaudata);アラントネマ属種(Allantonema spp.);アムフィメルミス属種(Amphimermis spp.);ベッジンギア・シリジコラ(Beddingia siridicola);ボビエネマ属種(Bovienema spp.);カメロニア属種(Cameronia spp.);キトウォオジエラ・オボフィラメンタ(Chitwoodiella ovofilamenta);コントルチレンクス属種(Contortylenchus spp.);クリシメルミス属種(Culicimermis spp.);ジプロトリアエナ属種(Diplotriaena spp.);エムピドメルミス属種(Empidomermis spp.);フィリプジェビメルミス・レイプサンドラ(Filipjevimermis leipsandra);ガストロメルミス属種(Gastromermis spp.);ゴンギロネマ属種(Gongylonema spp.);ギノポエシリア・プセウドビパラ(Gynopoecilia pseudovipara);ヘテロラブジチス・バクテリオホラ(Heterorhabditis bacteriophora)(例えば、「B-Green」として知られている製品)、ヘテロラブジチス・バウジャルジ(Heterorhabditis baujardi)、ヘテロラブジチス・ヘリオチジス(Heterorhabditis heliothidis)(例えば、「Nematon」として知られている製品)、ヘテロラブジチス・インジカ(Heterorhabditis indica)、ヘテロラブジチス・マレラツス(Heterorhabditis marelatus)、ヘテロラブジチス・メギジス(Heterorhabditis megidis)、ヘテロラブジチス・ゼアランジカ(Heterorhabditis zealandica)等のヘテロラブジチス属種(Heterorhabditis spp.);ヘキサメルミス属種(Hexamermis spp.);ヒドロメルミス属種(Hydromermis spp.);イソメルミス属種(Isomermis spp.);リムノメルミス属種(Limnomermis spp.);マウパシナ・ウェイシ(Maupasina weissi);メルミス・ニグレセンス(Mermis nigrescens);メソメルミス属種(Mesomermis spp.);ネオメソメルミス属種(Neomesomermis spp.);ネオパラシチレンクス・ルグロシ(Neoparasitylenchus rugulosi);オクトミオメルミス属種(Octomyomermis spp.);パラシタフェレンクス属種(Parasitaphelenchus spp.);パラシトラブジチス属種(Parasitorhabditis spp.);パラシチレンクス属種(Parasitylenchus spp.);ペルチリメルミス・クリシス(Perutilimermis culicis);ファスマラブジチス・ヘルマフロジタ(Phasmarhabditis hermaphrodita);フィサロプテラ属種(Physaloptera spp.);プロトレラツス属種(Protrellatus spp.);プテリゴデルマチテス属種(Pterygodermatites spp.);ロマノメルミス属種(Romanomermis spp.);セウラツム・カダラケンセ(Seuratum cadarachense);スファエルラリオプシス属種(Sphaerulariopsis spp.);スピルラ・グイアネンシス(Spirura guianensis);スタイナーネマ・カルポカプサエ(Steinernema carpocapsae)(例えば、「Biocontrol」として知られている製品や、「SDSバイオテック(株)」製の「バイオセーフ(登録商標)」)、スタイナーネマ・フェルチアエ(Steinernema feltiae)(例えば、「Nemasys(登録商標)」として知られている製品)、スタイナーネマ・グラセライ(Steinernema glaseri)( 例えば、「アリスタライフサイエンス(株)」製の「バイオトピア(登録商標)」や、「Biotopia」として知られている製品)、スタイナーネマ・クラウッセイ(Steinernema kraussei)(例えば、「Larvesure」として知られている製品)、スタイナーネマ・クシダイ(Steinernema kushidai)(例えば、「(株)クボタ」製の「芝市ネマ」)、スタイナーネマ・リオブラベ(Steinernema riobrave)(例えば、「Biovector」として知られている製品)、スタイナーネマ・スカプテリシ(Steinernema scapterisci)(例えば、「Nematac S」として知られている製品)、スタイナーネマ・スカラバエイ(Steinernema scarabaei)、スタイナーネマ・シアムカヤイ(Steinernema siamkayai)、等のスタイナーネマ属種(Steinernema spp.); ストレルコビメルミス・ペテリセニ(Strelkovimermis peterseni);スブルラ属種(Subulura spp.);スルフレチレンクス・エロンガツス(Sulphuretylenchus elongatus);テトラメレス属種(Tetrameres spp.)等の天敵線虫、
Abbreviata caucasica; Acuaria spp.; Agamermis decaudata; Allantonema spp.; Amphimermis spp.; Beddingia siridicola Bovienema spp.; Cameronia spp.; Chitwoodiella ovofilamenta; Contortylenchus spp.; Genus species (Diplotriaena spp.); Empidomermis spp.; Filipjevimermis leipsandra; Gastromermis spp.; Gongylonema spp.; Gynopoecilia pseudovipara; Heterorhabditis bacteriophora (e.g. the product known as "B-Green"), Heterorhabditis baujardi, Heterorhabditis heliothidis (e.g. " Heterorhabditis spp. such as Heterorhabditis indica, Heterorhabditis marelatus, Heterorhabditis megidis, Heterorhabditis zealandica );Hexamermis spp.;Hydromermis spp.;Isomermis spp. Limnomermis spp.; Maupasina weissi; Mermis nigrescens; Mesomermis spp.; Neoparasitylenchus rugulosi; Octomyomermis spp.; Parasitaphelenchus spp.; Parasitorhabditis spp.; Parasitylenchus spp.); Perutilimermis culicis; Phasmarhabditis hermaphrodita; Physaloptera spp.; Protrellatus spp.; Romanomermis spp.; Seuratum cadarachense; Sphaerulariopsis spp.; Spirura guianensis; Products known as "Biocontrol" and "Biosafe®" manufactured by "SDS Biotech Ltd."), Steinernema feltiae (e.g. known as "Nemasys®"). products known as "Biotopia"), Steinernema glaseri (for example, "Biotopia" manufactured by "Arista Life Sciences" and products known as "Biotopia"), Steinernema glaseri (Steinernema kraussei) (e.g. the product known as "Larvesure"), Steinernema kraussei Steinernema kushidai (e.g. "Shibaichi Nema" manufactured by "Kubota Corporation"), Steinernema riobrave (e.g. the product known as "Biovector"), Steinernema scapterisci ) (e.g. products known as "Nematac S"), Steinernema spp. such as Steinernema scarabaei, Steinernema siamkayai, etc.; Strelkovimermis peterseni); Subulura spp.; Sulphuretylenchus elongatus; Tetrameres spp.
タバコモザイクウイルス、リンゴコカクモンハマキ(Adoxophyes orana)グラニュローシスウイルス(GV)(例えば、「BIOFA-Capex(登録商標)」として知られている製品)、リンゴコカクモンハマキ(Adoxophyes orana)顆粒病ウイルス(MAFF632001)とチャハマキ顆粒病ウイルス(MAFF632002)の混合物(例えば、「アリスタライフサイセンス(株)」製の「ハマキ天敵(登録商標)」)、カブラヤガ(Agrotis segetum)核多角体病ウイルス(NPV)、アンチカルシア・ゲムマタリス(Anticarsia gemmatalis)(Woolly pyrol moth)mNPV(例えば、「Polygen(登録商標)」として知られている製品)、アウトグラファ・カリホルニカ(Autographacalifornica)(Alfalfa Looper)mNPV(例えば、「VPN80(登録商標)」として知られている製品;供給元:Agricola El Sol)、チャシャクトリムシ(tea looper)(Biston suppressaria)NPV、カイコ(Bombyx mori)NPV、クリプトフレビア・レウコトレタ(Cryptophlebia leucotreta)(false codling moth)GV(例えば、「Cryptex(登録商標)」として知られている製品)、シディア・ポモネラ・グラヌロシス(Cydia pomonella granulosis)等のシディア・ポモネラ(Cydia pomonella spp.)、ウイルス、コドリンガ(Cydia pomonella)顆粒病ウイルス(CpGV)(例えば、「Madex Plus(登録商標)」として知られている製品)、マッソンマツカレハ(Dendrolimus punctatus)CPV(例えば、「中外製薬」製のDVC水和剤「マツケミン」)、ヘリコベルパ・アルミゲラ(Helicoverpa armigera)NPV(例えば、「AgBiTech-ViVUS Max(登録商標)」として知られている製品)、オオタバコガ(Helicoverpa zea)(以前は、Heliothis zea)NPV(例えば、「Elcar(登録商標)」として知られている製品)、 ヤナギドクガ(Leucoma salicis)NPV、マイマイガ(Lymantria dispar)NPV(例えば、「Gypcheck(登録商標)」として知られている製品)、バルサムモミハバチ(balsam-fir sawfly)(Neodiprion abietis)NPV(例えば、「Abietiv(登録商標)」として知られている製品)、ネオジプリオン・レコンテイ(Neodiprion lecontei)(red-headed pinesawfly)NPV(例えば、「Lecontvirus(登録商標)」として知られている製品)、マツノキハバチ(Neodiprion sertifer)NPV(例えば、「Neocheck-S(登録商標)」として知られている製品)、オルギア・プセウドツガタ(Orgyia pseudotsugata)(Douglas-fir tussock moth)NPV(例えば、「Virtuss(登録商標)」として知られている製品)、ジャガイモガ(tobacco leaf miner)(Phthorimaea operculella)GV(例えば、「Matapol(登録商標)」として知られている製品)、モンシロチョウ(Pieris rapae)GV、コナガ(Plutella xylostella)GV(例えば、「Plutec(登録商標)」として知られている製品)、スポドプテラ・アルブラ(Spodoptera albula)(gray-streaked armyworm moth)mNPV(例えば、「VPN 82(登録商標)」として知られている製品)、アフリカシロナヨトウ(true armyworm)(Spodoptera exempta)mNPV(例えば、「Spodec(登録商標)」として知られている製品)、シロイチモジヨトウ(sugarbeet armyworm)(Spodoptera exigua)mNPV(例えば、「Spexit(登録商標)」として知られている製品;供給元:Andermatt Biocontrol)、ツマジロクサヨトウ(fall armyworm)(Spodoptera frugiperda)mNPV(例えば、「Baculovirus VPN(登録商標)」として知られている製品)、エジプトヨトウ(tobacco cutworm)(Spodoptera littoralis)NPV(「Spodoptrin(登録商標)」として知られている製品;供給元:NPP Calliope France)、ハスモンヨトウ(oriental leafworm moth)(Spodoptera litura)NPV(Littovir(登録商標))、ハスモンヨトウ(oriental leafworm moth)核多角体病ウイルスFu-1株包埋体(「日本化薬(株)」製の「ハスモン天敵」)、ハスモンヨトウ(oriental leafworm moth)核多角体病ウイルス クローンA9株及びクローンC3株包埋体(例えば、「揖斐川工業(株)」製の「ハスモンキラー」)、ズッキーニ黄斑モザイクウイルス弱毒株ZY-02 (例えば、「(株)微生物化学研究所」製の「“京都微研”キュービオ ZY-02(登録商標)」)、ズッキーニ黄斑モザイクウイルス弱毒株ZY-95 (例えば、「(株)微生物化学研究所」製の「“京都微研”キュービオ ZY(登録商標)」)、トウガラシマイルドモットルウイルス弱毒株 AVP08(例えば、「(株)微生物化学研究所」製の「グリーンペパー PM(登録商標)」)等のウイルス剤、
Tobacco mosaic virus, Adoxophyes orana granulosis virus (GV) (e.g. the product known as "BIOFA-Capex®"), Adoxophyes orana granulosis virus (MAFF632001) and a mixture of Chahamaki granulosis virus (MAFF632002) (e.g., "Hamaki Tenteki (registered trademark)" manufactured by "Arista Lifesciences Co., Ltd."), Agrotis segetum nuclear polyhedrosis virus (NPV) , Anticarsia gemmatalis (Woolly pyrol moth) mNPV (e.g. the product known as "Polygen®"), Autographa californica (Alfalfa Looper) mNPV (e.g. "VPN80 (Registered Trademark)"; Source: Agricola El Sol), tea looper (Biston suppressaria) NPV, Bombyx mori NPV, Cryptophlebia leucotreta (false codling moth) GV (e.g. the product known as "Cryptex®"), Cydia pomonella spp. such as Cydia pomonella granulosis, viruses, Cydia pomonella ) granulosis virus (CpGV) (e.g. the product known as "Madex Plus®"), Dendrolimus punctatus CPV (e.g. "Matsuchemin" DVC wettable powder manufactured by "Chugai Pharmaceutical") , Helicoverpa armigera NPV (e.g. the product known as "AgBiTech-ViVUS Max®"), Helicoverpa zea (formerly Heliothis zea) NPV (e.g. "Elcar® trademark)”), Willow Duckweed (Leucoma salicis) NPV, Lymantria dispar NPV (e.g. the product known as "Gypcheck®"), balsam-fir sawfly (Neodiprion abietis) NPV (e.g. "Abietiv® )”), Neodiprion lecontei (red-headed pinesawfly) NPV (for example, the product known as “Lecontvirus®”), Neodiprion sertifer NPV ( For example, the product known as "Neocheck-S®"), Orgyia pseudotsugata (Douglas-fir tussock moth) NPV (for example, the product known as "Virtuss®") ), tobacco leaf miner (Phthorimaea operculella) GV (e.g. the product known as "Matapol®"), Pieris rapae GV, Plutella xylostella GV (e.g. "Plutec (registered trademark)”, Spodoptera albula (gray-streaked armyworm moth) mNPV (e.g. product known as “VPN 82®”), African armyworm (true armyworm) (Spodoptera exempta) mNPV (e.g. products known as "Spodec®"), sugarbeet armyworm (Spodoptera exigua) mNPV (e.g. known as "Spexit®") products; source: Andermatt Biocontrol), fall armyworm (Spodoptera frugiperda) mNPV (e.g. the product known as "Baculovirus VPN®"), Egyptian armyworm (tobacco cutworm) ( Spodoptera lit toralis) NPV (product known as "Spodoptrin®"; source: NPP Calliope France), oriental leafworm moth (Spodoptera litura) NPV (Littovir®), oriental leafworm moth ) Nuclear polyhedrosis virus Fu-1 strain embedded body ("Hasmon natural enemy" manufactured by "Nippon Kayaku Co., Ltd."), oriental leafworm moth nuclear polyhedrosis virus clone A9 strain and clone C3 strain embedded body (for example, "Hasmon Killer" manufactured by "Ibigawa Kogyo Co., Ltd."), zucchini yellow mosaic virus attenuated strain ZY-02 (for example, "Kyoto Biken" Cubio ZY manufactured by "Microbial Chemical Laboratory Co., Ltd." -02 (registered trademark)”), zucchini yellow mosaic virus attenuated strain ZY-95 (for example, “Kyoto Biken” Cubio ZY (registered trademark) manufactured by “Microbial Chemistry Laboratory Co., Ltd.”), hot pepper mild mot Viral agents such as attenuated virus strain AVP08 (for example, "Green Pepper PM (registered trademark)" manufactured by "Microbial Chemistry Laboratory Co., Ltd."),
アルミゲルア・ウワバルア・ダイアモルア・ビートアーミルア・リトルア剤(「協友アグリ(株)」製の「コンフーザーV(登録商標)」)、キュウルア液剤(例えば、「サンケイ化学(株)」製の「キュウルア(登録商標)」)、メチルオイゲノール剤(例えば、「サンケイ化学(株)」製の「サンケイメチルオイゲノール(登録商標)」)、シナンセルア剤(「信越化学工業(株)」製の「スカシバコン L(登録商標)」)、コッシンルア剤(「信越化学工業(株)」製の「ボクトウコン-H(登録商標)」)、トートリルア剤(「信越化学工業(株)」製の「ハマキコン-N(登録商標)」)、オリフルア・トートリルア・ピーチフルア剤(「協友アグリ(株)」製の「コンフューザー R(登録商標)」)、オリフルア・トートリルア・ピーチフルア剤剤(「信越化学工業(株)」製の「コンフーザー N(登録商標)」)、オリフルア・トートリルア・ピーチフルア・ピリマルア剤(「信越化学工業(株)」製の「コンフーザー MM(登録商標)」)、アリマルア・オリフルア・トートリルア・ピーチフルア剤(「信越化学工業(株)」製の「コンフーザー AA(登録商標)」)、マシニッサルア剤(「信越化学工業(株)」製の「ヘタムシコン(登録商標)」)、フォールウェブルア剤(「出光興産(株)」製の「ニトルアー<アメシロ>(登録商標)」)、ケルキボルア剤(「サンケイ化学(株)」製のカシナガコール(登録商標)」)、ブルウェア・ロウカリア剤(例えば、「信越化学工業(株)」製の「コンフーザー G(登録商標)」)、MEP・スウィートビルア粒剤(「サンケイ化学(株)」製の「アリモドキコール粒剤(登録商標)」)、インフェルア剤(「信越化学工業(株)」製の「ヨトウコン-1(登録商標)」)、オキメラノルア剤(例えば、「サンケイ化学(株)」製の「サンケイオキメラノコール(登録商標)」)、サキネラノルア剤(「サンケイ化学(株)」製の「サキメラノコール(登録商標)」)、ビートアーミルア剤(例えば、「信越化学工業(株)」製の「ヨトウコン-S(登録商標)」)、リトルア剤(例えば、「住友化学(株)」製の「フェロディン SL(登録商標)」)、ダイアモルア剤(例えば、「サンケイ化学(株)」製の「コナガコン(登録商標)」)等のフェロモン剤、
Armigelua, Uwabarua, Diamorua, Beet Armilla, Littleua agents (“Confuzer V (registered trademark)” manufactured by “Kyoyu Agri Co., Ltd.”), cure liquid agents (e.g., “Sankei Chemical Co., Ltd.” manufactured by “Kyulua ( (registered trademark)”), methyl eugenol agent (for example, “Sankei Methyl Eugenol (registered trademark)” manufactured by “Sankei Chemical Co., Ltd.”), cinanecera agent (“Sukashibakon L (registered trademark)” manufactured by “Shin-Etsu Chemical Co., Ltd.” Trademark)”), Kossin lure agent (“Bokutoukon-H (registered trademark)” manufactured by “Shin-Etsu Chemical Co., Ltd.”), Toothuria agent (“Hamakikon-N (registered trademark)” manufactured by “Shin-Etsu Chemical Co., Ltd.” ”), Oriflua, Tautrillua, and Peachflur agents (“Confuser R (registered trademark)” manufactured by “Kyoyu Agri Co., Ltd.”), Oriflua, Tautrillua, and Peachflua agents (“Confuzer” manufactured by “Shin-Etsu Chemical Co., Ltd.”) N (registered trademark)"), Oriflua-Thortrilua-Peachflua-Pirimarua agent ("Confuser MM (registered trademark)" manufactured by "Shin-Etsu Chemical Co., Ltd."), Alimarua-Oliflua-Thortrilua-Peachflua agent ("Shin-Etsu Chemical Co., Ltd. "Confuzer AA (registered trademark)" manufactured by "Shin-Etsu Chemical Co., Ltd." "Nitrure <Ameshiro> (registered trademark)" manufactured by Sankei Chemical Co., Ltd.), Kelkibolua agent (Kashinagakoru (registered trademark) manufactured by "Sankei Chemical Co., Ltd."), Bulware Roucaria agent (for example, "Shin-Etsu Chemical Co., Ltd." "Confuzer G (registered trademark)" manufactured by Sankei Chemical Co., Ltd.), MEP Sweet Billua granules ("Arimodokicol granules (registered trademark)" manufactured by Sankei Chemical Co., Ltd.), Infera agent ("Shin-Etsu Chemical Co., Ltd. "Yotokon-1 (registered trademark)"), Ochimeranolu agent (for example, Sankei Chemical Co., Ltd. "Sankei Ochimeranocol (registered trademark)"), Sakinella noru agent ("Sankei Chemical ( "Sakimelanocol (registered trademark)" manufactured by "Shin-Etsu Chemical Co., Ltd." Pheromone agents such as "Ferrodin SL (registered trademark)" manufactured by Sumitomo Chemical Co., Ltd.), diamolure agents (for example, "Konagakon (registered trademark)" manufactured by "Sankei Chemical Co., Ltd."),
アカシアネグラ抽出物(Acacia negra extract)、アブシジン酸(Abscisic acid)、アリタソウ(Chenopodium ambrosiodae)抽出物、アルギニン(Arginine)、アルギン酸オリゴ糖(Alginate oligosaccharide)、イヌハッカ油(Nepitella oil)、オイゲノール(Eugenol)、L-カルボン(L-carvone)、ギ酸エチル(Ethyl formate)、キチン(chitin)、キトサン(Chitosan) (例えば、「BotriZen Ltd.,NZ」製の「ARMOUR-ZEN」)、キラヤエキス抽出物(Quillay Extract)、ギンコライド A(Ginkgolide A)、ギンコライド B(Ginkgolide B)、ギンコライド C(Ginkgolide C)、ギンコライド J(Ginkgolide J)及びギンコライド M(Ginkgolide M)からなる群から選択されるイチョウの成分、グレープフルーツ種子及び果肉抽出物、ケイ酸カリウム(potassium silicate)、サイトカイニン(cytokinin)、サンギナリン(タケニグサ由来物)( sanguinarine)、シスジャスモン(cis-Jasmone)、シトラール(Citral)、ジベレリン誘導体(gibberellin derivative)、シッカニン(Siccanin)(糸状菌であるライグラス斑点病菌(Helminthosporium siccans)が生産する物質)、シトロネラ油(Citronella Oil)、シトロネロール(Citronellol)、ジャスモン酸(Jasmonic acid)、ジャスモン酸メチル(Methyl Jasmonate)、ソルビトールオクタノエート(Sorbitol actanoate)、ニームツリー(neem tree;extracts from seeds of the neem tree)、ニーム油(Neem Oil)、チモール(Thymol)、テルピノレン(Terpinolene)、合成的に製造された、ケノポディウム・アンブロシオイデス・near・アンブロシオイデス(Chenopodium ambrosioides near ambrosioides)の抽出物のテルペン成分(terpenes)〔これは、殺有害生物活性成分として、3種類のテルペン(terpene)、即ち、α-テルピネン(α-terpinene)、p-シメン(p-cymene)及びリモネン(limonene)の混合物を含んでいる〕(例えば、「Requiem(登録商標)」として知られている製品;供給元:Bayer CropScienceLP,US)、ビロバライド(Bilobalide)、褐炭粘土(Lignite clay)の形態から抽出されるフミン酸(Humic Acid)及びフルボ酸(fulvic acid)、ペンタテルマノン(pentatermanone)、マリーゴールド油(Marigold Oil)、ミリスチン酸イソプロピル(Isopropyl Myristate)、メチルオイゲノール(Methyl eugenol)、メチルジャスモネート(methyl jasmonate)、ハーピン・タンパク(Harpin protein)、酪酸ヘプチル(Heptyl butyrate)、ラバンズリルセネシオエート(lavanulyl senecioate)、レオナルダイト(leonardite)として知られる褐炭(lignite coal)等のフメート類(Humates)、レシチン(Lecithin)、(E,Z)-7,9-ドデカジエン-1-イルアセテート、(E,Z)-2,4-エチルデカジエノエート(ナシエステル)、(Z,Z,E)-7,11,13-ヘキサデカトリエナール、2-メチル-1-ブタノール、(E,Z)-2,13-オクタデカジエン-1-オール、(E,Z)-2,13-オクタデカジエン-1-オールアセテート、(E,Z)-3,13-オクタデカジエン-1-オール、R-1-オクテン-3-オール、(E,Z,Z)-3,8,11-テトラデカトリエニルアセテート、(Z,E)-9,12-テトラデカジエン-1-イルアセテート、Z-7-テトラデセン-2-オン、Z-9-テトラデセン-1-イルアセテート、Z-11-テトラデセナール、Z-11-テトラデセン-1-オール、ポンガミア(Pongamia)属、ロトロピス(Calotropis)属、プルンバゴ(Plumbago)属、メイチヌス(Maytenus)属、バッカリス(Baccharis)属、ルビア(Rubia)属、カロフィルム(Calophyllum)属、アーティカ(Urtica)属、コブレシア(Kobresia)属、カエサルピニア(Caesalpinia)属からの植物抽出エキス成分であるプルンバギン(plumbagin)、ロードシュードモナス・スペロイデス(Rhodo-pseudomonas speroides) 、特に、株IFO-12203から産出されるブラシノステロイド(brassinosteroid)等の生物からの抽出物;ハーピン(エルウィニア・アミロボラ(Erwinia amylovora)によって単離されるもの(ハルピン(Harpin)タンパク質);例えば、「Harp-N-Tek (登録商標)」、「Messenger(登録商標)」、「Employ (登録商標)」、「ProAct (登録商標)」として知られている製品)等と併用することも可能である。
Acacia negra extract, Abscisic acid, Chenopodium ambrosiodae extract, Arginine, Alginate oligosaccharide, Nepitella oil, Eugenol, L-carvone, Ethyl formate, chitin, Chitosan (for example, "ARMOUR-ZEN" manufactured by "BotriZen Ltd., NZ"), Quillay Extract ), ginkgolide A, ginkgolide B, ginkgolide C, ginkgolide J and ginkgolide M selected from the group consisting of ginkgo biloba, grapefruit seeds and Fruit extract, potassium silicate, cytokinin, sanguinarine, cis-Jasmone, citral, gibberellin derivative, siccanin ) (substances produced by the filamentous fungus Helminthosporium siccans), Citronella Oil, Citronellol, Jasmonic Acid, Methyl Jasmonate, Sorbitol Octanoate (Sorbitol actanoate), neem tree; extracts from seeds of the neem tree, Neem Oil, Thymol, Terpinolene, synthetically produced Cenopodium ambrosioides Te of extracts of near ambrosioides (Chenopodium ambrosioides near ambrosioides) terpenes, which, as pesticidal active ingredients, are a mixture of three terpenes, namely α-terpinene, p-cymene and limonene; (for example, products known as "Requiem®"; source: Bayer CropScience LP, US), Bilobalide, humic acid extracted from the form of lignite clay Humic Acid and Fulvic Acid, Pentatermanone, Marigold Oil, Isopropyl Myristate, Methyl Eugenol, Methyl Jasmonate Humates such as , Harpin protein, Heptyl butyrate, Lavanulyl senecioate, lignite coal known as leonardite, Lecithin, (E,Z)-7,9-dodecadien-1-yl acetate, (E,Z)-2,4-ethyldecadienoate (nacieester), (Z,Z,E)-7,11,13 -hexadecatrienal, 2-methyl-1-butanol, (E,Z)-2,13-octadecadien-1-ol, (E,Z)-2,13-octadecadien-1-ol acetate , (E,Z)-3,13-octadecadien-1-ol, R-1-octen-3-ol, (E,Z,Z)-3,8,11-tetradecatrienyl acetate, ( Z,E)-9,12-tetradecadien-1-yl acetate, Z-7-tetradecen-2-one, Z-9-tetradecen-1-yl acetate, Z-11-tetradecenal, Z-11-tetradecene -1-ol, genus Pongamia, genus Calotropis, genus Plumbago, genus Maytenus, genus Baccharis, genus Rubia, genus Calophyll Plumbagin, Rhodo-pseudomonas speroides, which is a plant extract extract component from the genus Urtica, Kobresia, Caesalpinia, the genus Pseudomonas speroides, in particular the strain IFO extracts from organisms such as brassinosteroids produced from -12203; Harpin (isolated by Erwinia amylovora (Harpin protein); e.g., Harp-N-Tek (registered trademark)”, “Messenger (registered trademark)”, “Employ (registered trademark)”, products known as “ProAct (registered trademark)”), etc.
上記有効成分群Aに含まれる化合物又は成分は、国内外で販売されているか、又は文献公知の化合物又は成分である。
The compounds or ingredients contained in the above active ingredient group A are sold in Japan and overseas, or are compounds or ingredients known in the literature.
化合物(I)及び化合物(II)を有効成分として含有する、本発明の殺虫剤組成物は、水稲、果樹、野菜、その他の作物等の農作物、花卉類等の園芸植物等の有用植物を加害する各種農業害虫、米、小麦粉等の貯蔵されている穀物に対する貯穀害虫等の害虫の防除に適する。
The insecticide composition of the present invention, which contains compound (I) and compound (II) as active ingredients, damages agricultural crops such as paddy rice, fruit trees, vegetables and other crops, and useful plants such as garden plants such as ornamental plants. It is suitable for controlling pests such as various agricultural pests that grow on rice and stored grains such as wheat flour.
本発明の殺虫剤組成物が有効な害虫としては、例えば、鱗翅目(チョウ目)、例えばアオイラガ(Parasa consocia)、アカキリバ(Anomis mesogona)、アゲハ(Papilio xuthus)、アズキサヤムシガ(Matsumuraeses azukivora)、アズキノメイガ(Ostrinia scapulalis)、アフリカヨトウ(Spodoptera exempta)、アメリカシロヒトリ(Hyphantria cunea)、アワノメイガ(Ostrinia furnacalis)、アワヨトウ(Pseudaletia separata)、イガ(Tinea translucens)、イグサシンムシガ(Bactra furfurana)、イネツトムシ(イチモンジセセリ)(Parnara guttata)、イネタテハマキ(Marasmia exigua)、イネヨトウ(Sesamia inferens)、イモキバガ(Brachmia triannulella)、イラガ(Monema flavescens)、イラクサギンウワバ(Trichoplusia ni)、ウコンノメイガ(Pleuroptya ruralis)、ウメエダシャク(Cystidia couaggaria)、ウラナミシジミ(Lampides boeticus)、オオスカシバ(Cephonodes hylas)、オオタバコガ(Helicoverpa armigera)、オオトビモンシャチホコ(Phalerodonta manleyi)、オオミノガ(Eumeta japonica)、オオモンシロチョウ(Pieris brassicae)、オビカレハ(Malacosoma Neustria testaceum)、カキノヘタムシガ(Stathmopoda masinissa)、カキホソガ(Cuphodes diospyrosella)、カクモンハマキ(Archips xylosteanus)、カブラヤガ(Agrotis segetum)、カンショシンクイハマキ(Tetramoera schistaceana)、キアゲハ(Papilio machaon hippocrates)、キマダラコウモリ(Endoclyta sinensis)、ギンモンハモグリガ(Lyonetia prunifoliella)、
Pests for which the insecticidal composition of the present invention is effective include, for example, Lepidoptera (Lepidoptera), such as Parasa consocia, Anomis mesogona, Papilio xuthus, Matsumuraeses azukivora, and Azuki no Meiga (Ostrinia scapulalis), Spodoptera exempta, Hyphantria cunea, Ostrinia furnacalis, Pseudaletia separata, Tinea translucens, Bactra furfurana, Parnara gutta ), Marasmia exigua, Sesamia inferens, Brachmia triannulella, Monema flavescens, Trichoplusia ni, Pleuroptya ruralis, Cystidia couaggaria Lampides boeticus, Cephonodes hylas, Helicoverpa armigera, Phalerodonta manleyi, Eumeta japonica, Pieris brassicae, Malacosoma Neustria masaceum, Stathmopoda , Cuphodes diospyrosella, Archips xylosteanus, Agrotis segetum, Tetramoera scistaceana, Papilio machaon hippocrates, Endoclyta sinensis, Lyonetia prunifoliella ,
キンモンホソガ(Phyllonorycter ringoneella)、クリミガ(Cydia kurokoi)、クリミドリシンクイガ(Eucoenogenes aestuosa)、グレープベリーモス(Lobesia botrana)、クロシタアオイラガ(Latoia sinica)、クロフタモンマダラメイガ(Euzophera batangensis)、クワイホソハマキ(Phalonidia mesotypa)、クワゴマダラヒトリ(Spilosoma imparilis)、クワノメイガ(Glyphodes pyloalis)、クワヒメハマキ(Olethreutes mori)、コイガ(Tineola bisselliella)、コウモリガ(Endoclyta excrescens)、コクガ(Nemapogon granellus)、コスカシバ(Synanthedon hector)、コドリンガ(Cydia pomonella)、コナガ(Plutella xylostella)、コブノメイガ(Cnaphalocrocis medinalis)、サザンピンクボーラー(Sesamia calamistis)、サンカメイガ(Scirpophaga incertulas)、シバツトガ(Pediasia teterrellus)、ジャガイモガ(Phthorimaea operculella)、シャチホコガ(Stauropus fagi persimilis)、シロイチモジマダラメイガ(Etiella zinckenella)、シロイチモジヨトウ(Spodoptera exigua)、シロテンコウモリ(Palpifer sexnotata)、シロナヨトウ(Spodoptera manuritia)、シロメイチュウ(Scirpophaga innotata)、シロモンヤガ(Xestia c-nigrum)、スジキリヨトウ(Spodoptera depravata)、スジコナマダラメイガ(Ephestia kuehniella)、スモモエダシャク(Angerona prunaria)、セグロシャチホコ(Clostera anastomosis)、ソイビーンルーパー(Pseudoplusia includens)、ダイズサヤムシガ(Matsumuraeses falcana)、タバコガ(Helicoverpa assulta)、タマナギンウワバ(Autographa nigrisigna)、
Phyllonorycter ringoneella, Cydia kurokoi, Eucoenogenes aestuosa, Lobesia botrana, Latoia sinica, Euzophera batangensis, Phalonidia mesotypa, Spilosoma imparilis, Glyphodes pyloalis, Olethreutes mori, Tineola bisselliella, Endoclyta excrescens, Nemapogon granellus, Synanthedon hector, Cydia pomonella, Plutella xylostella, Cnaphalocrocis medinalis, Southern pink borer (Sesamia calamistis), Scirpophaga incertulas, Pediasia teterrellus, Phthorimaea operculella, Stauropus fagi persimilis, Beet moth Etiella zinckenella, Spodoptera exigua, Palpifer sexnotata, Spodoptera manuritia, Scirpophaga innotata, Xestia c-nigrum, Spodoptera depravata, Striped butterfly Ephestia kuehniella, Angelona prunaria, Clostera anastomosis, Pseudoplusia includens, Matsumuraseses falcana, tobacco moth (Helicoverpa assulta), sagebrush (Autographa nigrisigna),
タマナヤガ(Agrotis ipsilon)、チャドクガ(Euproctis pseudoconspersa)、チャノコカクモンハマキ(Adoxophyes orana)、チャノホソガ(Caloptilia theivora)、チャハマキ(Homona magnanima)、チャマダラメイガ(Ephestia elutella)、チャミノガ(Eumeta minuscula)、ツマアカシャチホコ(Clostera anachoreta)、ツメクサガ(Heliothis maritima)、テングハマキ(Sparganothis pilleriana)、トウモロコシメイガ(Busseola fusca)、ドクガ(Euproctis subflava)、トビモンオオエダシャク(Biston robustum)、トマトフルーツワーム(Heliothis zea)、ナカジロシタバ(Aedia leucomelas)、ナシイラガ(Narosoideus flavidorsalis)、ナシケンモン(Viminia rumicis)、ナシチビガ(Bucculatrix pyrivorella)、ナシヒメシンクイ(Grapholita molesta)、ナシホソガ(Spulerina astaurota)、ナシマダラメイガ(Ectomyelois pyrivorella)、ニカメイガ(Chilo suppressalis)、ネギコガ(Acrolepiopsis sapporensis)、ノシメマダラメイガ(Plodia interpunctella)、ハイマダラノメイガ(Hellula undalis)、バクガ(Sitotroga ceralella)、ハスモンヨトウ(Spodoptera litura)、ハマキガの一種(Eucosma aporema)、バラハマキ(Acleris comariana)、ヒメクロイラガ(Scopelodes contracus)、ヒメシロモンドクガ(Orgyia thyellina)、
Agrotis isilon, Euproctis pseudoconspersa, Adoxophyes orana, Caloptilia theivora, Homona magnanima, Ephestia elutella, Eumeta minuscula (Clostera anachoreta), Heliothis maritima, Sparganothis pilleriana, Busseola fusca, Euproctis subflava, Biston robustum, Heliothis zea, Aedia leucomelas), Narosoideus flavidorsalis, Viminia rumicis, Bucculatrix pyrivorella, Grapholita molesta, Spulerina astaurota, Ectomyelois pyrivorella, Chilo suppressalis, Acrolepiphysis sapporensis), Plodia interpunctella, Hellula undalis, Sitotroga ceralella, Spodoptera litura, Eucosma aporema, Acleris comariana, Scopelodes contracus , Orgyia Thyellina,
フォールアーミーワーム(Spodoptera frugiperda)、フキノメイガ(Ostrinia zaguliaevi)、フタオビコヤガ(Naranga aenescens)、フタテンカギバモドキ(Andraca bipunctata)、ブドウスカシバ(Paranthrene regalis)、ブドウスズメ(Acosmeryx castanea)、ブドウハモグリガ(Phyllocnistis toparcha)、ブドウヒメハマキ(Endopiza viteana)、ブドウホソハマキ(Eupoecillia ambiguella)、ベルベットビーンキャタピラー(Anticarsia gemmatalis)、ホソバハイイロハマキ(Cnephasia cinereipalpana)、マイマイガ(Lymantria dispar)、マツカレハ(Dendrolimus spectabilis)、マメシンクイガ(Leguminivora glycinivorella)、マメノメイガ(Maruca testulalis)、マメヒメサヤムシガ(Matsumuraeses phaseoli)、マメホソガ(Caloptilia soyella)、ミカンハモグリガ(Phyllocnistis citrella)、ミスジノメイガ(Hadylepta indicata)、ミダレカクモンハマキ(Archips fuscocupreanus)、ミツモンキンウワバ(Acanthoplusia agnata)、ミノガ(Bambalina sp.)、モモシンクイガ(Carposina niponensis)、モモノゴマダラノメイガ(Conogethes punctiferalis)、
Fall army worm (Spodoptera frugiperda), coltsfoot moth (Ostrinia zaguliaevi), Naranga aenescens, Andraca bipunctata, Grape sparrow (Paranthrene regalis), Grape sparrow (Acosmeryx castanea), Grape leaf moth (Phyllocnistis toparcha), Endopiza viteana, Eupoecillia ambiguella, Velvet bean caterpillar (Anticarsia gemmatalis), Cnephasia cinereipalpana, Lymantria dispar, Dendrolimus spectabilis, Legumivora glycinivorella, Bean moth (Maruca testulalis), Mitsumuraeses phaseoli, Caloptilia soyella, Phyllocnistis citrella, Hadylepta indicata, Archips fuscocupreanus Acanthoplusia agnata), minnow (Bambalina sp.), peach moth (Carposina niponensis), peach moth (Conogethes punctiferalis),
モモのスカシバ類(Synanthedon sp.)、モモハモグリガ(Lyonetia clerkella)、モンキアゲハ(Papilio helenus)、モンキチョウ(Colias erate poliographus)、モンクロシャチホコ(Phalera flavescens)、モンシロチョウ(Pieris rapae crucivora)(亜種)、モンシロチョウ(Pieris rapae)等のシロチョウ類(Pieridae)、モンシロドクガ(Euproctis similis)、ヤマノイモコガ(Acrolepiopsis suzukiella)、ヨーロピアンコーンボーラー(Ostrinia nubilalis)、ヨトウガ(Mamestra brassicae)、ヨモギエダシャク(Ascotis selenaria)、ヨモギオオホソハマキ(Phtheochroides clandestina)、リンゴオオハマキ(Hoshinoa adumbratana)、リンゴカレハ(Odonestis pruni japonensis)、リンゴケンモン(Triaena intermedia)、リンゴコカクモンハマキ(Adoxophyes orana fasciata)、リンゴコシンクイ(Grapholita inopinata)、リンゴシロヒメハマキ(Spilonota ocellana)、リンゴハイイロハマキ(Spilonota lechriaspis)、リンゴハマキクロバ(Illiberis pruni)、リンゴヒメシンクイ(Argyresthia conjugella)、リンゴホソガ(Caloptilia zachrysa)、リンゴモンハマキ(Archips breviplicanus)、ワタアカキリバ(Anomis flava)、ワタアカミムシ(Pectinophora gossypiella)、ワタノメイガ(Notarcha derogata)、ワタヘリクロノメイガ(Diaphania indica)、ワタミムシ(Heliothis virescens)、ワタリンガ(Earias cupreoviridis)、トマトキバガ(仮称)(Tuta absoluta、英名:Tomato leaf miner)、
Peach moth (Synanthedon sp.), Lyonetia clerkella, Papilio helenus, Colias erate poliographus, Phalera flavescens, Pieris rapae crucivora (subspecies), Cabbage butterfly ( Pieris rapae), Pieridae, Euproctis similis, Acrolepiopsis suzukiella, Ostrinia nubilalis, Mamestra brassicae, Ascotis selenaria, Mugwort Phtheochroides clandestina), Hoshinoa adumbratana, Odonestis pruni japonensis, Triaena intermedia, Adoxophyes orana fasciata, Grapholita inopinata, Spilonota ocellana), Spilonota lechriaspis, Illiberis pruni, Argyresthia conjugella, Caloptilia zachrysa, Archips breviplicanus, Anomis flava, Cotton earwig ( Pectinophora gossypiella), Notarcha derogata, Diaphania indica, Heliothis virescens, Earias cupreoviridis, Tomato leaf moth (tentative name) (Tuta absoluta, English name: Tomato leaf miner),
半翅目(カメムシ目)、例えば、アオクサカメムシ(Nezara antennata)、アカスジカスミカメ(Stenotus rubrovittatus)、アカスジカメムシ(Graphosoma rubrolineatum)、アカヒゲホソミドリカスミカメ(Trigonotylus coelestialium)等、アカヒメヘリカメムシ(Aeschynteles maculatus)、アカホシカスミカメ(Creontiades pallidifer)、アカホシカメムシ(Dysdercus cingulatus)、アカホシマルカイアガラムシ(Chrysomphalus ficus)、アカマルカイガラムシ(Aonidiella aurantii)、アブラゼミ(Graptopsaltria nigrofuscata)、アメリカコバネナガカメムシ(Blissus leucopterus)、イセリヤカイガラムシ(Icerya purchasi)、イチモンジカメムシ(Piezodorus hybneri)、イネカメムシ(Lagynotomus elongatus)、イネキイロヒメヨコバイ(Thaia subrufa)、イネクロカメムシ(Scotinophara lurida)、イバラヒゲナガアブラムシ(Sitobion ibarae)、イワサキカメムシ(Stariodes iwasakii)、ウスイロマルカイガラムシ(Aspidiotus destructor)、ウスモンミドリカスミカメ(Taylorilygus pallidulus)、ウメコブアブラムシ(Myzus mumecola)、
Hemiptera (Stink bugs), for example, Nezara antennata, Stenotus rubrovittatus, Graphosoma rubrolineatum, Trigonotylus coelestialium, etc., Aeschynteles maculatus), Creontiades pallidifer, Dysdercus cingulatus, Chrysomphalus ficus, Aonidiella aurantii, Graptopsaltria nigrofuscata, Blissus leucopterus, Iselia Scale insect (Icerya purchasi), Japanese stink bug (Piezodorus hybneri), Rice stink bug (Lagynotomus elongatus), Rice leafhopper (Thaia subrufa), Rice black stink bug (Scotinophara lurida), Thorny aphid (Sitobion ibarae), Stink bug (Stariodes iwasakii) , Aspidiotus destructor, Taylorilygus pallidulus, Myzus mumecola,
ウメシロカイガラムシ(Pseudaulacaspis prunicola)、エンドウヒゲナガアブラムシ(Acyrthosiphon pisum)、オオクモヘリカメムシ(Anacanthocoris striicornis)、オオクロトビカスミカメ(Ectometopterus micantulus)、オオトゲシラホシカメムシ(Eysarcoris lewisi)、オオヘリカメムシ(Molipteryx fulginosa)、オオヨコバイ(Cicadella viridis)、オカボノアカアブラムシ(Rhopalosophum rufiabdominalis)、オリーブカタカイガラムシ(Saissetia oleae)、オンシツコナジラミ(Trialeurodes vaporariorum)、カシヒメヨコバイ(Aguriahana quercus)、カスミカメムシ類(Lygus sp.)、カバワタフキマダラアブラムシ(Euceraphis punctipennis)、カンキツカイガラムシ(Andaspis kashicola)、カンキツカタカイガラムシ(Coccus pseudomagnoliarum)、カンシャコバネナガカメムシ(Cavelerius saccharivorus)、キクグンバイ(Galeatus spinifrons)、キクヒメヒゲナガアブラムシ(Macrosiphoniella sanborni)、キマルカイガラムシ(Aonidiella citrina)、クサギカメムシ(Halyomorpha mista)、クスグンバイ(Stephanitis fasciicarina)、クストガリキジラミ(Trioza camphorae)、クモヘリカメムシ(Leptocorisa chinensis)、クリトガリキジラミ(Trioza quercicola)、クルミグンバイ(Uhlerites latius)、
Pseudaulacaspis prunicola, Acyrthosiphon pisum, Anacanthocoris striicornis, Ectometopterus micantulus, Eysarcoris lewisi, Molipteryx fulginosa , Cicadella viridis, Rhopalosophum rufiabdominalis, Saissetia oleae, Trialeurodes vaporariorum, Aguriahana quercus, Lygus sp. Spotted aphid (Euceraphis punctipennis), citrus scale beetle (Andaspis kashicola), citrus scale beetle (Coccus pseudomagnoliarum), long-tailed stinkbug (Cavelerius saccharivorus), chrysanthemum beetle (Galeatus spinifrons), aphid (Macrosiphoniella sanborni), Kimaru scale insect (Macrosiphoniella sanborni) ), Halyomorpha mista, Stephanitis fasciicarina, Trioza camphorae, Leptocorisa chinensis, Trioza quercicola, Uhlerites latius,
グレープリーフホッパー(Erythroneura comes)、クロアシホソナガカメムシ(Paromius exguus)、クロカタマルカイガラムシ(Duplaspidiotus claviger)、クロスジツマグロヨコバイ(Nephotettix nigropictus)、クロトビカスミカメ(Halticiellus insularis)、クロフツノウンカ(Perkinsiella saccharicida)、クロリンゴキジラミ(Psylla malivorella)、クワキジラミ(Anomomeura mori)、クワコナカイガラムシ(Pseudococcus longispinis)、クワシロカイガラムシ(Pseudaulacaspis pentagona)、クワワタカイガラムシ(Pulvinaria kuwacola)、コアオカスミカメ(Apolygus lucorum)、コバネヒョウタンナガカメムシ(Togo hemipterus)、コミカンアブラムシ(Toxoptera aurantii)、サトウキビコナカイガラムシ(Saccharicoccus sacchari)、サトウキビネワタムシ(Geoica lucifuga)、サトウノウスイロウンカ(Numata muiri)、サンホーゼカイガラムシ(Comstockaspis perniciosa)、シトラススノースケール(Unaspis citri)、ジャガイモヒゲナガアブラムシ(Aulacorthum solani)、シラホシカメムシ(Eysarcoris ventralis)、シルバーリーフコナジラミ(Bemisia argentifolii)、シロオオヨコバイ(Cicadella spectra)、シロマルカイガラムシ(Aspidiotus hederae)、スカシヒメヘリカメムシ(Liorhyssus hyalinus)、セグロヒメキジラミ(Calophya nigridorsalis)、セジロウンカ(Sogatella furcifera)、ソラマメヒゲナガアブラムシ(Megoura crassicauda)、ダイコンアブラムシ(Brevicoryne brassicae)、ダイズアブラムシ(Aphis glycines)、タイワンクモヘリカメムシ(Leptocorisa oratorius)、タイワンツマグロヨコバイ(Nephotettix virescens)、
Grape leaf hopper (Erythroneura comess), Black-footed stink bug (Paromius exguus), Black-footed scale bug (Duplaspidiotus claviger), Leafhopper (Nephotettix nigropictus), Black-footed turtle (Halticiellus insularis), Black-footed planthopper (Perkinsiella saccharicida), Psylla malivorella, Anomeura mori, Pseudococcus longispinis, Pseudaulacaspis pentagona, Pulvinaria kuwacola, Apolygus lucorum, Long-tailed stink bug (Togo hemipterus), Toxoptera aurantii, Saccharicoccus sacchari, Geoica lucifuga, Numata muiri, Comstockaspis perniciosa, Citrus Snowscale ( Unaspis citri), potato aphid (Aulacorthum solani), white stink bug (Eysarcoris ventralis), silverleaf whitefly (Bemisia argentifolii), white leafhopper (Cicadella spectra), white scale beetle (Aspidiotus hederae), keyhole stink bug (Liorhyssus hyalinus) , Calophya nigridorsalis, Sogatella furcifera, Megoura crassicauda, Brevicoryne brassicae, Brevicoryne brassicae, Aphis glycines, Leptocorisa oratorius, Green tuna leafhopper (Nephotettix virescens),
タイワンヒゲナガアブラムシ(Uroeucon formosanum)、タバコカスミカメ(Cyrtopeltis tenuis)、タバココナジラミ(Bemisia tabaci)、チャノカタカイガラムシ(Lecanium persicae)、チャノクロホシカイガラムシ(Parlatoria theae)、チャノマルカイガラムシ(Pseudaonidia paeoniae)、チャバネアオカメムシ(Plautia stali)、チューリップネアブラムシ(Dysaphis tulipae)、チューリップヒゲナガアブラムシ(Macrosiphum euphorbiae)、ツツジグンバイ(Stephanitis pyrioides)、ツノロウムシ(Ceroplastes ceriferus)、ツバキクロホシカイガラムシ(Parlatoria camelliae)、ツマグロアオカスミカメ(Apolygus spinolai)、ツマグロヨコバイ(Nephotettix cincticeps)、ツヤアオカメムシ(Glaucias subpunctatus)、テンサイカスミカメ(Orthotylus flavosparsus)、トウモロコシアブラムシ(Rhopalosiphum maidis)、トウモロコシウンカ(Peregrinus maidis)、トゲシラホシカメムシ(Eysarcoris parvus)、トコジラミ(Cimex lectularius)、トドキジラミ(Psylla abieti)、
Aphids Uroeucon formosanum, Cyrtopeltis tenuis, Bemisia tabaci, Lecanium persicae, Parlatoria theae, Pseudaonidia paeoniae, German stink bug (Plautia stali), Dysaphis tulipae, Macrosiphum euphorbiae, Stephanitis pyrioides, Ceroplastes ceriferus, Parlatoria camelliae, Apolygus spinolai , leafhopper (Nephotettix cincticeps), green stink bug (Glaucias subpunctatus), sugar beetle (Orthotylus flavosparsus), corn aphid (Rhopalosiphum maidis), corn planthopper (Peregrinus maidis), spiny stink bug (Eysarcoris parvus), bed bug (Cimex lectularius), Psylla abieti),
トビイロウンカ(Nilaparvata lugens)、トベラキジラミ(Psylla tobirae)、ナガメ(Eurydema rugosum)、ナシアブラムシ(Schizaphis piricola)、ナシキジラミ(Psylla pyricola)、ナシクロホシカイガラムシ(Parlatoreopsis pyri)、ナシグンバイ(Stephanitis sashi)、ナシコナカイガラムシ(Dysmicoccus wistariae)、ナシシロナガカイガラムシ(Lepholeucaspis japonica)、ナシマルアブラムシ(Sappaphis piri)、ニセダイコンアブラムシ(Lipaphis erysimi)、ネギアブラムシ(Neotoxoptera formosana)、ハスクビレアブラムシ(Rhopalosophum nymphaeae)、バラヒメヨコバイ(Edwardsiana rosae)、ハランナガカイガラムシ(Pinnaspis aspidistrae)、ハンノキジラミ(Psylla alni)、ハンノナガヨコバイ(Speusotettix subfusculus)、ハンノヒメヨコバイ(Alnetoidia alneti)、ヒエウンカ(Sogatella panicicola)、ヒゲナガカスミカメ(Adelphocoris lineolatus)、ヒメアカホシカメムシ(Dysdercus poecilus)、ヒメクロカイガラムシ(Parlatoria ziziphi)、ヒメグンバイ(Uhlerites debile)、ヒメトビウンカ(Laodelphax striatellus)、ヒメナガメ(Eurydema pulchrum)、ヒメハリカメムシ(Cletus trigonus)、ヒメフタテンナガアワフキ(Clovia punctata)、ヒメヨコバイ類(Empoasca sp.)(チャノミドリヒメヨコバイ(Empoasca onukii)、マツヒメヨコバイ(Empoasca abietis)等)、ヒラタカタカイガラムシ(Coccus hesperidum)、ヒラタヒョウタンナガカメムシ(Pachybrachius luridus)、フジコナカイガラムシ(Planococcus kraunhiae)、フタスジカスミカメ(Stenotus binotatus)、フタテンヒメヨコバイ(Arboridia apicaris)、
Nilaparvata lugens, Psylla tobirae, Eurydema rugosum, Schizaphis piricola, Psylla pyricola, Parlatoreopsis pyri, Stephanitis sashi, Psylla pyricola Dysmicoccus wistariae), pear scale insect (Lepholeucaspis japonica), pear aphid (Sappaphis piri), radish aphid (Lipaphis erysimi), onion aphid (Neotoxoptera formosana), husquilla aphid (Rhopalosophum nymphaeae), leafhopper (Edwardsiana rosae) ), Pinnaspis aspidistrae, Psylla alni, Speusotettix subfusculus, Alnetoidia alneti, Sogatella panicicola, Adelphocoris lineolatus, and Rhinoceros stink bug ( Dysdercus poecilus), Parlatoria ziphi, Uhlerites debile, Laodelphax striatellus, Eurydema pulchrum, Cletus trigonus, Clovia punctata, Green leafhopper (Empoasca sp.) (Empoasca onukii, Empoasca abietis, etc.), Coccus hesperidum, Pachybrachius luridus, Planococcus kraunhiae, Blue-eyed turtle (Stenotus bi notatus), leafhopper (Arboridia apicaris),
フタテンヨコバイ(Macrosteles fascifrons)、ブチヒゲカメムシ(Dolycoris baccarum)、ブチヒゲクロカスミカメ(Adelphocoris triannulatus)、ブドウネアブラムシ(Viteus vitifolii)、ホオズキカメムシ(Acanthocoris sordidus)、ホソクモヘリカメムシ(Leptocorisa acuta)、ホソコバネナガカメムシ(Macropes obnubilus)、ホソハリカメムシ(Cletus punctiger)、ホソヘリカメムシ(Riptortus clavatus)、ポテトピシリド(Paratrioza cockerelli)、マエキアワフキ(Aphrophora costalis)、マキバカスミカメ(Lygus disponsi)、マダラカスミカメ(Lygus saundersi)、マツコナカイガラムシ(Crisicoccus pini)、マツモトコナカイガラムシ(Crisicoccus matsumotoi)、マメアブラムシ(Aphis craccivora)、マルカメムシ(Megacopta punctatissimum)、マルシラホシカメムシ(Eysarcoris guttiger)、ミカンカキカイガラムシ(Lepidosaphes beckii)、ミカンキジラミ(Diaphorina citri)、ミカンクロアブラムシ(Toxoptera citricidus)、ミカンコナカイガラムシ(Planococcus citri)、
Macrosteles fascifrons, Dolycoris baccarum, Adelphocoris triannulatus, Viteus vitifolii, Acanthocoris sordidus, Leptocorisa acuta Macropes obnubilus, Cletus punctiger, Riptortus clavatus, Paratrioza cockerelli, Aphrophora costalis, Lygus disponsi, Lygus saundersi, Crisicoccus pini, Crisicoccus matsumotoi, Aphis craccivora, Megacopta punctatatissimum, Eysarcoris guttiger, Lepidosaphes beckii, Diaphorina triaphorina ), citrus black aphid (Toxoptera citricidus), citrus mealybug (Planococcus citri),
ミカンコナジラミ(Dialeurodes citri)、ミカントゲコナジラミ(Aleurocanthus spiniferus)、ミカンヒメコナカイガラムシ(Pseudococcus citriculus)、ミカンヒメヨコバイ(Zyginella citri)、ミカンヒメワタカイガラムシ(Pulvinaria citricola)、ミカンヒラタカイガラムシ(Coccus discrepans)、ミカンマルカイガラムシ(Pseudaonidia duplex)、ミカンワタカイガラムシ(Pulvinaria aurantii)、ミズキカタカイガラムシ(Lecanium corni)、ミナミアオカメムシ(Nezara viridula)、ムギカスミカメ(Stenodema calcaratum)、ムギクビレアブラムシ(Rhopalosiphum padi)、ムギヒゲナガアブラムシ(Sitobion akebiae)、ムギミドリアブラムシ(Schizaphis graminum)、ムギヨコバイ(Sorhoanus tritici)、ムギワラギクオマルアブラムシ(Brachycaudus helichrysi)、ムラサキカメムシ(Carpocoris purpureipennis)、モモアカアブラムシ(Myzus persicae)、モモコフキアブラムシ(Hyalopterus pruni)、ヤナギアブラムシ(Aphis farinose yanagicola)、ヤナギグンバイ(Metasalis populi)、ヤノネカイガラムシ(Unaspis yanonensis)、ヤマアサキジラミ(Mesohomotoma camphorae)、ユキヤナギアブラムシ(Aphis spiraecola)、リンゴアブラムシ(Aphis pomi)、リンゴカキカイガラムシ(Lepidosaphes ulmi)、リンゴキジラミ(Psylla mali)、リンゴクロカスミカメ(Heterocordylus flavipes)、リンゴコブアブラムシ(Myzus malisuctus)、リンゴネアブラムシ(Aphidonuguis mali)、リンゴマダラヨコバイ(Orientus ishidai)、リンゴミドリアブラムシ(Ovatus malicolens)、リンゴワタムシ(Eriosoma lanigerum)、ルビーロウムシ(Ceroplastes rubens)、ワタアブラムシ(Aphis gossypii)、
Mandarin orange whitefly (Dialeurodes citri), mandarin orange whitefly (Aleurocanthus spiniferus), mandarin orange mealybug (Pseudococcus citriculus), mandarin leafhopper (Zyginella citri), mandarin orange scale (Pulvinaria citricola), mandarin orange scale (Coccus discrepans), mandarin orange Pseudaonidia duplex, Pulvinaria aurantii, Lecanium corni, Nezara viridula, Stenodema calcaratum, Rhopalosiphum padi, Aphid Sitobion akebiae), wheat aphid (Schizaphis graminum), wheat leafhopper (Sorhoanus tritici), wheat wart aphid (Brachycaudus helichrysi), purple stink bug (Carpocoris purpureipennis), green peach aphid (Myzus persicae), peach aphid (Hyalopterus pruni), willow Aphis farinose yanagicola, Metasalis populi, Unaspis yanonensis, Mesohomotoma camphorae, Aphis spiraecola, Aphis pomi, Lepidosaphes ulmi, Apple Pheasant (Psylla mali), Apple Black Turtle (Heterocordylus flavipes), Apple Coconut Aphid (Myzus malisuctus), Apple Leaf Aphid (Aphidonuguis mali), Apple Spotted Leafhopper (Orientus ishidai), Apple Green Aphid (Ovatus malicolens), Apple Boll ( Eriosoma l anigerum), ruby beetle (Ceroplastes rubens), cotton aphid (Aphis gossypii),
鞘翅目(コウチュウ目)、例えば、アオスジカミキリ(Xystrocera globosa)、アオバアリガタハネカクシ(Paederus fuscipes)、アオハナムグリ(Eucetonia roelofsi)、アズキゾウムシ(Callosobruchus chinensis)、アリモドキゾウムシ(Cylas formicarius)、アルファルファタコゾウムシ(Hypera postica)、イネゾウムシ(Echinocnemus squameus)、イネドロオイムシ(Oulema oryzae)、イネネクイハムシ(Donacia provosti)、イネミズゾウムシ(Lissorhoptrus oryzophilus)、イモサルハムシ(Colasposoma dauricum)、イモゾウムシ(Euscepes postfasciatus)、インゲンテントウ(Epilachna varivestis)、インゲンマメゾウムシ(Acanthoscelides obtectus)、ウエスタンコーンルートワーム(Diabrotica virgifera virgifera)、ウメチョッキリゾウムシ(Involvulus cupreus)、ウリハムシ(Aulacophora femoralis)、エンドウゾウムシ(Bruchus pisorum)、オオニジュウヤホシテントウ(Epilachna vigintioctomaculata)、ガイマイデオキスイ(Carpophilus dimidiatus)、カメノコハムシ(Cassida nebulosa)、キアシノミハムシ(Luperomorpha tunebrosa)、キスジノミハムシ(Phyllotreta striolata)、
Coleoptera (Coleoptera), such as Xystrocera globosa, Paederus fuscipes, Eucetonia roelofsi, Callosobruchus chinensis, Cylas formicarius, Alfalfa weevil ( Hypera postica, Echinocnemus squameus, Oulema oryzae, Donacia provosti, Lissorhoptrus oryzophilus, Colasposoma dauricum, Euscepes postfasciatus, Epilachna varives (Acanthoscelides obtectus), Western corn rootworm (Diabrotica virgifera virgifera), Plum weevil (Involvulus cupreus), Cucumber beetle (Aulacophora femoralis), Pea weevil (Bruchus pisorum), Epilachna vigintioctomaculata (Carpophilus dimidiatus), Cassida nebulosa, Luperomorpha tunebrosa, Phyllotreta striolata,
キボシカミキリ(Psacothea hilaris)、キマダラカミキリ(Aeolesthes chrysothrix)、クリシギゾウムシ(Curculio sikkimensis)、クリヤケシキスイ(Carpophilus hemipterus)、コアオハナムグリ(Oxycetonia jucunda)、コーンルートワーム類(Diabrotica sp.)、コガネムシ(Mimela splendens)、コクゾウムシ(Sitophilus zeamais)、コクヌストモドキ(Tribolium castaneum)、ココクゾウムシ(Sitophilus oryzae)、コヒメコクヌストモドキ(Palorus subdepressus)、コフキコガネ(Melolontha japonica)、ゴマダラカミキリ(Anoplophora malasiaca)、ゴミムシダマシ(Neatus picipes)、コロラドハムシ(Leptinotarsa decemlineata)、サザンコーンルートワーム(Diabrotica undecimpunctata howardi)、シバオサゾウムシ(Sphenophorus venatus)、ジュウシホシクビナガハムシ(Crioceris quatuordecimpunctata)、スモモゾウムシ(Conotrachelus nenuphar)、ダイコンサルゾウムシ(Ceuthorhynchidius albosuturalis)、ダイコンハムシ(Phaedon brassicae)、タバコシバンムシ(Lasioderma serricorne)、チビコフキゾウムシ(Sitona japonicus)、
Psacothea hilaris, Aeolesthes chrysothrix, Curculio sikkimensis, Carpophilus hemipterus, Oxycetonia jucunda, Diabrotica sp., Mimela splendens), Sitophilus zeamais, Tribolium castaneum, Sitophilus oryzae, Palorus subdepressus, Melolontha japonica, Anoplophora malasiaca, Neatus picipes, Colorado beetle Leaf beetle (Leptinotarsa decemlineata), Southern corn rootworm (Diabrotica undecimpunctata howardi), Sphenophorus venatus, Crioceris quatuordecimpunctata, Plum weevil (Conotrachelus nenuphar), Radish weevil (Ceuthorhynchidius) albosutural Leaf beetle (Phaedon brassicae), Tobacco beetle (Lasioderma serricorne), Tiny beetle (Sitona japonicus),
チャイロコガネ(Adoretus tenuimaculatus)、チャイロコメノゴミムシダマシ(Tenebrio molitor)、チャイロサルハムシ(Basilepta balyi)、ツメクサタコゾウムシ(Hypera nigrirostris)、テンサイトビハムシ(Chaetocnema concinna)、ドウガネブイブイ(Anomala cuprea)、ナガチャコガネ(Heptophylla picea)、ニジュウヤホシテントウ(Epilachna vigintioctopunctata)、ノーザンコーンルートワーム(Diabrotica longicornis)、ハナムグリ(Eucetonia pilifera)、ハリガネムシ類(Agriotes spp.)、ヒメカツオブシムシ(Attagenus unicolor japonicus)、ヒメキバネサルハムシ(Pagria signata)、ヒメコガネ(Anomala rufocuprea)、ヒメコクヌストモドキ(Palorus ratzeburgii)、ヒメゴミムシダマシ(Alphitobius laevigatus)、ヒメマルカツオブシムシ(Anthrenus verbasci)、ヒラタキクイムシ(Lyctus brunneus)、ヒラタコクヌストモドキ(Tribolium confusum)、フタスジヒメハムシ(Medythia nigrobilineata)、ブドウトラカミキリ(Xylotrechus pyrrhoderus)、ポテトフリービートル(Epitrix cucumeris)、マツノキクイムシ(Tomicus piniperda)、
Adoretus tenuimaculatus, Tenebrio molitor, Basilepta balyi, Hypera nigrirostris, Chaetocnema concinna, Anomala cuprea, Heptophylla picea), Epilachna vigintioctopunctata, Northern corn rootworm (Diabrotica longicornis), Eucetonia pilifera, Agriotes spp., Attagenus unicolor japonicus, Pagria signata), Anomala rufocuprea, Palorus ratzeburgii, Alphitobius laevigatus, Anthrenus verbasci, Lyctus brunneus, Tribolium confusum, Tribolium confusum (Medythia nigrobilineata), grape tiger beetle (Xylotrechus pyrrhoderus), potato-free beetle (Epitrix cucumeris), pine bark beetle (Tomicus piniperda),
マツノマダラカミキリ(Monochamus alternatus)、マメコガネ(Popillia japonica)、マメハンミョウ(Epicauta gorhami)、メイズウィービル(Sitophilus zeamais)、モモチョッキリゾウムシ(Rhynchites heros)、ヤサイゾウムシ(Listroderes costirostris)、ヨツモンマメゾウムシ(Callosobruchus maculatus)、リンゴコフキゾウムシ(Phyllobius armatus)、リンゴハナゾウムシ(Anthonomus pomorum)、ルリハムシ(Linaeidea aenea)、ワタミゾウムシ(Anthonomus grandis)、
Monochamus alternatus, Popillia japonica, Epicauta gorhami, Sitophilus zeamais, Rhynchites heroes, Listroderes costirostris, Callosobruchus maculatus ), Phyllobius armatus, Anthonomus pomorum, Linaeidea aenea, Anthonomus grandis,
双翅目(ハエ目)、例えば、アカザモグリハナバエ(Pegomya hyoscyami)、アシグロハモグリバエ(Liriomyza huidobrensis)、イネキモグリバエ(Chlorops oryzae)、イネクキミギワバエ(Hydrellia sasakii)、イネハモグリバエ(Agromyza oryzae)、イネヒメハモグリバエ(イネミギワバエ)(Hydrellia griseola)、インゲンモグリバエ(Ophiomyia phaseoli)、ウリミバエ(Dacus cucurbitae)、オウトウショウジョウバエ(Drosophila suzukii)、オウトウハマダラミバエ(Rhacochlaena japonica)、オオキモンノミバエ(Megaselia spiracularis)等のノミバエ類(Phoridae)、オオチョウバエ(Clogmia albipunctata)、
Diptera (Diptera), e.g., Pegomya hyoscyami, Liriomyza huidobrensis, Chlorops oryzae, Hydrellia sasakii, Agromyza oryzae, rice Flea flies such as Hydrellia griseola, Ophiomyia phaseoli, Dacus cucurbitae, Drosophila suzukii, Rhacochlaena japonica, and Megaselia spiralis (Phoridae), Clogmia albipunctata,
ダイコンバエ(Hylemya brassicae)、ダイズサヤタマバエ(Asphondylia sp.)、タネバエ(Delia platura)、タマネギバエ(Delia antiqua)、チェリーフルーツフライ(Rhagoletis cerasi)、チチュウカイミバエ(Ceratitis capitata)、チビクロバネキノコバエ(Bradysia agrestis)、テンサイモグリハナバエ(Pegomya cunicularia)、トマトハモグリバエ(Liriomyza sativae)、ナスハモグリバエ(Liriomyza bryoniae)、ナモグリバエ(Chromatomyia horticola)、ネギハモグリバエ(Liriomyza chinensis)、マメハモグリバエ(Liriomyza trifolii)、ミカンコミバエ(Dacus dorsalis)、ミカンバエ(Dacus tsuneonis)、ムギアカタマバエ(Sitodiplosis mosellana)、ムギキモグリバエ(Meromuza nigriventris)、メキシコミバエ(Anastrepha ludens)、リンゴミバエ(Phagoletis pomonella)、
Radish fly (Hylemya brassicae), soybean fly (Asphondylia sp.), seed fly (Delia platura), onion fly (Delia antiqua), cherry fruit fly (Rhagoletis cerasi), Mediterranean fruit fly (Ceratitis capitata), Bradysia agrestis, sugar beet Pegomya cunicularia, Liriomyza sativae, Liriomyza bryoniae, Chromatomyia horticola, Liriomyza chinensis, Liriomyza trifolii, Dacus dorsalis, Citrus fruit fly Dacus tsuneonis), Sitodiplosis mosellana, Meromuza nigriventris, Mexican fruit fly (Anastrepha ludens), Phagoletis pomonella,
膜翅目(ハチ目)、例えば、アミメアリ(Pristomyrmex pungens)、アリガタバチ類(Bethylidae)、イエヒメアリ(Monomorium pharaosis)、オオズアリ(Pheidole noda)、カブラハバチ(Athalia rosae)、クリタマバチ(Dryocosmus kuriphilus)等、クロヤマアリ(Formica fusca japonica)、スズメバチ類(Vespinae)、セグロカブラハバチ(Athalia infumata)、チュウレンジハバチ(Arge pagana)、ニホンカブラバチ(Athalia japonica)、ハキリアリ(Acromyrmex spp. )、ファイヤーアント(Solenopsis spp. )、リンゴハバチ(Arge mali)、ルリアリ(Ochetellus glaber)、
Hymenoptera (Hymenoptera), e.g., Pristomyrmex pungens, Bethylidae, Monomorium pharaosis, Pheidole noda, Athalia rosae, Dryocosmus kuriphilus, etc., Formica fusca japonica), Vespinae, Athalia infumata, Arge pagana, Athalia japonica, Leaf-cutting ant (Acromyrmex spp.), Fire ant (Solenopsis spp.), Apple sawfly ( Argemali), Ruriari (Ochetellusglaber),
直翅目(バッタ目)、例えば、クサキリ(Homorocoryphus lineosus)、ケラ(Gryllotalpa sp.)、コイナゴ(Oxya hyla intricata)、コバネイナゴ(Oxya yezoensis)、トノサマバッタ(Locusta migratoria)、ハネナガイナゴ(Oxya japonica)、ヒメクサキリ(Homorocoryphus jezoensis)、エンマコオロギ(Teleogryllus emma)、
Orthoptera (Grasshoppers), such as Homorocoryphus lineosus, Gryllotalpa sp., Oxya hyla intricata, Oxya yezoensis, Locusta migratoria, Oxya japonica, Homorocoryphus jezoensis), emma cricket (Teleogryllus emma),
アザミウマ目、例えば、アカオビアザミウマ(Selenothrips rubrocinctus)、イネアザミウマ(Stenchaetothrips biformis)、イネクダアザミウマ(Haplothrips aculeatus)、カキクダアザミウマ(Ponticulothrips diospyrosi)等、キイロハナアザミウマ(Thrips flavus)、クサキイロアザミウマ(Anaphothrips obscurus)、クスクダアザミウマ(Liothrips floridensis) 、グラジオラスアザミウマ(Thrips simplex)、クロゲハナアザミウマ(Thrips nigropilosus)、クロトンアザミウマ(Heliothrips haemorrhoidalis)、クワアザミウマ(Pseudodendrothrips mori)、コスモスアザミウマ(Microcephalothrips abdominalis)、シイオナガクダアザミウマ(Leeuwenia pasanii)、シイマルクダアザミウマ(Litotetothrips pasaniae)、シトラススリップス(Scirtothrips citri)、シナクダアザミウマ(Haplothrips chinensis)、ダイズアザミウマ(Mycterothrips glycines)、ダイズウスイロアザミウマ(Thrips setosus)、チャノキイロアザミウマ(Scirtothrips dorsalis)、チャノクロアザミウマ(Dendrothrips minowai)、ツメクサクダアザミウマ(Haplothrips niger)、ネギアザミウマ(Thrips tabaci)、ネギクロアザミウマ(Thrips alliorum)、ハナアザミウマ(Thrips hawaiiensis)、ハナクダアザミウマ(Haplothrips kurdjumovi)、ヒゲブトアザミウマ(Chirothrips manicatus)、ヒラズハナアザミウマ(Frankliniella intonsa)、ビワハナアザミウマ(Thrips coloratus)、ミカンキイロアザミウマ(Franklinella occidentalis)、ミナミキイロアザミウマ(Thrips palmi)、ユリキイロアザミウマ(Frankliniella lilivora)、ユリノクダアザミウマ(Liothrips vaneeckei)、
Thrips, for example, Selenothrips rubrocinctus, Stenchaetothrips biformis, Haplothrips aculeatus, Ponticulothrips diospyrosi, etc., Thrips flavus, Anascurthrips obscurthrips , Liothrips floridensis, Gladiolus simplex, Thrips nigropilosus, Heliothrips haemorrhoidalis, Pseudodendrothrips mori, Microcephalothrips abdominalis Leeuwenia pasanii), Litotetothrips pasaniae, Scirtothrips citri, Haplothrips chinensis, Mycterothrips glycines, Thrips setosus, Scirtothrips dali ), Dendrothrips minowai, Haplothrips niger, Thrips tabaci, Thrips alliorum, Thrips hawaiiensis, Haplothrips kurdjumovi, Bearded thrips Thrips (Chirothrips manicatus), Black thrips (Frankliniella intonsa), Loquat thrips (Thrips coloratus), Western yellow thrips (Franklinella occidentalis), Southern yellow thrips (Thrips palmi), Yellow thrips (F) rankliniella lilivora), Lithrips vaneeckei (Liothrips vaneeckei),
ダニ目、例えば、アシノワハダニ(Tetranychus ludeni)、イシイナミハダニ(Tetranychus truncatus)、オウトウハダニ(Tetranychus viennensis)、カンザワハダニ(Tetranychus kanzawai)、チャノナガサビダニ(Acaphylla theavagrans)、チャノホコリダニ(Polyphagotarsonemus latus)、トマトサビダニ(Aculops lycopersici)、ナミハダニ(Tetranychus urticae)、ニセナシサビダニ(Eriophyes chibaensis)、ホウレンソウケナガコナダニ(Tyrophagus similis)、ミカンハダニ(Panonychus citri)、ミナミヒメハダニ(Brevipalpus phoenicis)、リュウキュウミカンサビダニ(Phyllocoptruta citri)、リンゴサビダニ(Aculus schlechtendali)、リンゴハダニ(Panonychus ulmi)、
Acarina e.g. Tetranychus ludeni, Tetranychus truncatus, Tetranychus viennensis, Tetranychus kanzawai, Acaphylla theavagrans, Polyphagotarsonemus latus, Tomato rust mite Aculesciops ), Tetranychus urticae, Eriophyes chibaensis, Tyrophagus similis, Panonychus citri, Brevipalpus phoenicis, Phyllocoptruta citri, Aculus schlechtendali), apple spider mite (Panonychus ulmi),
シロアリ目、例えば、アマミシロアリ(Reticulitermes miyatakei)、アメリカカンザイシロアリ(Incisitermes minor)、イエシロアリ(Coptotermes formosanus)、オオシロアリ(Hodotermopsis japonica)、カンモンシロアリ(Reticulitermes sp.)、キアシシロアリ(Reticulitermes flaviceps amamianus)、クシモトシロアリ(Glyptotermes kushimensis)、コウシュウイエシロアリ(Coptotermes guangzhoensis)、コウシュンシロアリ(Neotermes koshunensis)、コダマシロアリ(Glyptotermes kodamai)、サツマシロアリ(Glyptotermes satsumensis)、ダイコクシロアリ(Cryptotermes domesticus)、タイワンシロアリ(Odontotermes formosanus)、ナカジマシロアリ(Glyptotermes nakajimai)、ニトベシロアリ(Pericapritermes nitobei)、ヤマトシロアリ(Reticulitermes speratus)、
Termites, such as Reticulitermes miyatakei, Incisitermes minor, Coptotermes forsanus, Hodotermopsis japonica, Reticulitermes sp., Reticulitermes flaviceps amamianus, Glyptotermes kushimensis, Coptotermes guangzhoensis, Neotermes koshunensis, Glyptotermes kodamai, Glyptotermes satsumensis, Cryptotermes domesticus, Odontotermes, Formosanustermes Glyptotermes nakajimai, Pericapritermes nitobei, Reticulitermes speratus,
クモ目、例えば、セアカゴケグモ(Latrodectus hasseltii)、
Araneae, e.g. Latrodectus hasseltii,
線虫類、例えば、イチゴメセンチュウ(Nothotylenchus acris)、イネシンガレセンチュウ(Aphelenchoides besseyi)、キタネグサレセンチュウ(Pratylenchus penetrans)、キタネコブセンチュウ(Meloidogyne hapla)、サツマイモネコブセンチュウ(Meloidogyne incognita)、ジャガイモシストセンチュウ(Globodera rostochiensis)、ジャワネコブセンチュウ(Meloidogyne javanica)、ダイズシストセンチュウ(Heterodera glycines)、ミナミネグサレセンチュウ(Pratylenchus coffeae)、ムギネグサレセンチュウ(Pratylenchus neglectus)、ミカンネセンチュウ(Tylenchus semipenetrans)、
Nematodes such as Nothotylenchus acris, Aphelenchoides besseyi, Pratylenchus penetrans, Meloidogyne hapla, Meloidogyne incognita, Globodera rostochiensis), Java root nematode (Meloidogyne javanica), Soybean cyst nematode (Heterodera glycines), Minaminegusare nematode (Pratylenchus coffeae), Muginegusare nematode (Pratylenchus neglectus), Tangerine nematode (Tylenchus semipenetrans),
軟体動物類、例えば、スクミリンゴガイ(Pomacea canaliculata)、アフリカマイマイ(Achatina fulica)、ナメクジ(Meghimatium bilineatum)、チャコウラナメクジ(Lehmannina valentiana)、コウラナメクジ(Limacus flavus)、ウスカワマイマイ(Acusta despecta sieboldiana)等が挙げられる。
本発明の組成物は、上記の害虫のうち、半翅目(カメムシ目)害虫に対して好ましく用いられる。中でも、クロフツノウンカ、セジロウンカ、トビイロウンカ、ヒメトビウンカ等の各種ウンカ類に対して特に好ましく用いられる。 Mollusks such as Pomacea canaliculata, Achatina fulica, Meghimatium bilineatum, Lehmannina valentiana, Limacus flavus, Acusta despecta sieboldiana, etc. mentioned.
Among the pests described above, the composition of the present invention is preferably used against pests of the order Hemiptera (order Stinkbugs). Among them, it is particularly preferably used for various planthoppers such as black planthopper, brown planthopper, brown planthopper, and brown planthopper.
本発明の組成物は、上記の害虫のうち、半翅目(カメムシ目)害虫に対して好ましく用いられる。中でも、クロフツノウンカ、セジロウンカ、トビイロウンカ、ヒメトビウンカ等の各種ウンカ類に対して特に好ましく用いられる。 Mollusks such as Pomacea canaliculata, Achatina fulica, Meghimatium bilineatum, Lehmannina valentiana, Limacus flavus, Acusta despecta sieboldiana, etc. mentioned.
Among the pests described above, the composition of the present invention is preferably used against pests of the order Hemiptera (order Stinkbugs). Among them, it is particularly preferably used for various planthoppers such as black planthopper, brown planthopper, brown planthopper, and brown planthopper.
本発明の組成物を使用できる有用植物は特に限定されるものではないが、例えば、穀類(例えば、イネ、オオムギ、コムギ、ライムギ、オートムギ、トウモロコシ等)、豆類(ダイズ、アズキ、ソラマメ、エンドウマメ、インゲンマメ、落花生等)、果樹・果実類(リンゴ、柑橘類、ナシ、ブドウ、モモ、ウメ、オウトウ、クリ、アーモンド、バナナ等)、葉・果菜類(キャベツ、トマト、ほうれんそう、ブロッコリー、レタス、タマネギ、ネギ、ピーマン、ナス、イチゴ、ペッパー、オクラ等)、根菜類(ニンジン、バレイショ、サツマイモ、サトイモ、ダイコン、カブ、レンコン、ゴボウ、ニンニク等)、加工用作物(棉、麻、ビート、ホップ、サトウキビ、テンサイ、オリーブ、ゴム、コーヒー、タバコ、茶等)、ウリ類(カボチャ、キュウリ、スイカ、マクワウリ、メロン等)、牧草類(オーチャードグラス、ソルガム、チモシー、クローバー、アルファルファ等)、芝類(高麗芝、ベントグラス等)、香料・香辛料用植物(ラベンダー、ローズマリー、タイム、パセリ、コショウ、ショウガ等)、観賞用植物(アスパラガス、グリーンネックレス、ゴールドクレスト、テーブルヤシ、トクサ等)、花卉類(キク、バラ、カーネーション、ラン等)、庭木(イチョウ、サクラ類、アオキ等)、林木(トドマツ類、エゾマツ類、マツ類、ヒバ、スギ、ヒノキ等)等の植物を挙げることができる。
Useful plants to which the composition of the present invention can be applied are not particularly limited. , kidney beans, peanuts, etc.), fruit trees and fruits (apples, citrus fruits, pears, grapes, peaches, plums, cherry blossoms, chestnuts, almonds, bananas, etc.), leafy and fruit vegetables (cabbage, tomatoes, spinach, broccoli, lettuce, onions) , green onions, green peppers, eggplants, strawberries, peppers, okra, etc.), root vegetables (carrots, potatoes, sweet potatoes, taro, radishes, turnips, lotus roots, burdocks, garlic, etc.), processed crops (cotton, hemp, beets, hops, Sugar cane, sugar beets, olives, gum, coffee, tobacco, tea, etc.), gourds (pumpkin, cucumber, watermelon, Japanese melon, melon, etc.), grasses (orchard grass, sorghum, timothy, clover, alfalfa, etc.), lawns ( Korai grass, bentgrass, etc.), aromatic and spice plants (lavender, rosemary, thyme, parsley, pepper, ginger, etc.), ornamental plants (asparagus, green necklace, gold crest, table palm, horsetail, etc.), flowers (chrysanthemums, roses, carnations, orchids, etc.), garden trees (ginkgo biloba, cherry trees, Japanese aoki etc.), forest trees (Sakhalin firs, Ezo spruces, pines, hiba, cedar, cypress, etc.).
本発明の組成物は、各種病害虫を防除するためにそのまま、又は水等で適宜希釈し、若しくは懸濁させた形で、各種農園芸害虫類防除に有効な量を各種害虫・ダニ類の発生が予測される植物に対して使用される。例えば、果樹、穀類、野菜等において発生する各種害虫・ダニ類に対しては、茎葉部に散布される。また、種子処理、土壌又は栽培担体の処理、水田への添加、水耕栽培における養液への添加、燻煙、樹幹注入、家屋建材への塗布等により使用することができ、ベイト剤としても使用することができる。
To control various pests, the composition of the present invention is added in an amount effective for controlling various agricultural and horticultural pests as it is, or in the form of being diluted or suspended with water or the like. is used for plants for which For example, for various pests and mites that occur in fruit trees, cereals, vegetables, etc., it is sprayed on foliage. In addition, it can be used for seed treatment, soil or cultivation carrier treatment, addition to paddy fields, addition to nutrient solution in hydroponics, smoking, trunk injection, application to building materials, etc., and also as a bait. can be used.
従って、本発明は、各種農園芸害虫類から有用植物を保護するために、本発明の組成物の有効量により、対象害虫類、対象有用植物、土壌又は栽培担体を処理する、農園芸用殺虫剤組成物の使用方法(以下、本明細書において、「本発明の方法」ともいう)をも提供する。
Therefore, the present invention provides an agricultural and horticultural insecticide that treats target pests, target useful plants, soil or cultivation carriers with an effective amount of the composition of the present invention in order to protect useful plants from various agricultural and horticultural pests. A method of using the agent composition (hereinafter also referred to herein as the "method of the invention") is also provided.
本発明の方法において、対象害虫類としては、上記した農業害虫、貯穀害虫、家畜害虫、衛生害虫等の各種害虫等が挙げられる。また、かかる各種害虫・ダニ類等の農園芸害虫類から保護される有用植物としては、上記した穀類、豆類、果樹・果実類、葉・果菜類、根菜類、加工用作物、牧草類、芝類、香料・香辛料用植物、花卉類、庭木、材木等の植物が挙げられる。
In the method of the present invention, target pests include various pests such as agricultural pests, grain storage pests, livestock pests, sanitary pests, and the like. Useful plants to be protected from agricultural and horticultural pests such as various pests and mites include the above-mentioned cereals, beans, fruit trees/fruits, leaves/fruit vegetables, root vegetables, processing crops, pasture grasses, lawns. , plants for fragrances and spices, flowers, garden trees, timbers, and the like.
対象害虫類又は対象有用植物を処理する方法としては、乳剤、フロアブル剤等の液状製剤もしくは水和剤、又は顆粒水和剤等の固形状製剤とした本発明の組成物を、水等で適宜希釈し、有用植物の茎葉部や各種害虫に対して散布する方法、又は樹幹に注入する方法、或いは粉剤とした本発明の組成物を散布又は燻煙する方法、対象有用植物の種子を本発明の組成物で処理する方法等が挙げられる。
対象有用植物の種子の処理方法としては、例えば、液状又は固体状の製剤とした本発明の組成物を希釈し又は希釈せずに溶液又は懸濁液として種子を浸漬する方法、固形製剤又は液状製剤とした本発明の組成物を種子と混和し、粉衣処理して種子の表面に付着させる方法、本発明の組成物を樹脂、ポリマー等の付着性の担体と混和して種子にコーティングする方法、植え付けと同時に種子付近に本発明の組成物を散布する方法等が挙げられる。
当該種子処理を行う「種子」とは、植物の繁殖に用いられる栽培初期の植物体を意味し、例えば、種子の他、球根、塊茎、種芋、株芽、むかご、鱗茎又は挿し木栽培用の栄養繁殖用の植物体を挙げることができる。 As a method for treating target pests or target useful plants, the composition of the present invention in the form of a liquid formulation such as an emulsion, a flowable formulation, a wettable powder, or a solid formulation such as a wettable granule is mixed with water or the like as appropriate. A method of diluting and spraying the foliage of useful plants and various pests, a method of injecting into tree trunks, a method of spraying or smoking the composition of the present invention in powder form, and applying the seeds of the target useful plants of the present invention and a method of treating with a composition of
Examples of the method for treating the seeds of the target useful plants include, for example, a method of soaking the seeds in the form of a solution or suspension in which the composition of the present invention in a liquid or solid formulation is diluted or not diluted, a solid formulation or a liquid formulation. A method of mixing the composition of the present invention as a formulation with seeds and applying it to the surface of the seeds by dressing, and coating the seeds by mixing the composition of the present invention with an adhesive carrier such as a resin or polymer. method, and a method of spraying the composition of the present invention around seeds at the same time as planting.
The "seed" to be subjected to the seed treatment means a plant body in the early stage of cultivation used for plant propagation. Plants for propagation can be mentioned.
対象有用植物の種子の処理方法としては、例えば、液状又は固体状の製剤とした本発明の組成物を希釈し又は希釈せずに溶液又は懸濁液として種子を浸漬する方法、固形製剤又は液状製剤とした本発明の組成物を種子と混和し、粉衣処理して種子の表面に付着させる方法、本発明の組成物を樹脂、ポリマー等の付着性の担体と混和して種子にコーティングする方法、植え付けと同時に種子付近に本発明の組成物を散布する方法等が挙げられる。
当該種子処理を行う「種子」とは、植物の繁殖に用いられる栽培初期の植物体を意味し、例えば、種子の他、球根、塊茎、種芋、株芽、むかご、鱗茎又は挿し木栽培用の栄養繁殖用の植物体を挙げることができる。 As a method for treating target pests or target useful plants, the composition of the present invention in the form of a liquid formulation such as an emulsion, a flowable formulation, a wettable powder, or a solid formulation such as a wettable granule is mixed with water or the like as appropriate. A method of diluting and spraying the foliage of useful plants and various pests, a method of injecting into tree trunks, a method of spraying or smoking the composition of the present invention in powder form, and applying the seeds of the target useful plants of the present invention and a method of treating with a composition of
Examples of the method for treating the seeds of the target useful plants include, for example, a method of soaking the seeds in the form of a solution or suspension in which the composition of the present invention in a liquid or solid formulation is diluted or not diluted, a solid formulation or a liquid formulation. A method of mixing the composition of the present invention as a formulation with seeds and applying it to the surface of the seeds by dressing, and coating the seeds by mixing the composition of the present invention with an adhesive carrier such as a resin or polymer. method, and a method of spraying the composition of the present invention around seeds at the same time as planting.
The "seed" to be subjected to the seed treatment means a plant body in the early stage of cultivation used for plant propagation. Plants for propagation can be mentioned.
本発明の方法において、本発明の組成物により処理される「土壌」又は「栽培担体」とは、対象有用植物を栽培するための支持体、特に根を生えさせる支持体を示すものであり、材質は特に制限されないが、該植物が生育しうる材質であればよく、いわゆる土壌、育苗マット、水等であってもよく、具体的な素材としては、例えば、砂、軽石、バーミキュライト、珪藻土、寒天、ゲル状物質、高分子物質、ロックウール、グラスウール、木材チップ、バーク等であってもよい。
上記の「土壌」又は「栽培担体」には、水稲の育苗箱、水田、畑作物に用いる栽培担体、水耕栽培における養液等も含まれる。
土壌又は栽培担体の処理方法としては、例えば、液状製剤とした本発明の組成物を水に希釈し又は希釈せずに、対象有用植物の植物体の株元又は育苗用苗床等に施用する方法、粒剤とした本発明の組成物を植物体の株元又は育苗のための苗床等に散布する方法、播種前又は移植前に、液状剤とした本発明の組成物を、育苗用苗床に灌注し、又は粉剤、水和剤、顆粒水和剤、粒剤等とした本発明の組成物を育苗用苗床に散布し、又は移植場所近辺の土壌全体又は栽培担体と混和する方法、播種前又は植物体を植える前に植え穴、作条等に粉剤、水和剤、顆粒水和剤、粒剤等とした本発明の組成物を散布する方法等が挙げられる。 In the method of the present invention, the "soil" or "cultivation carrier" treated with the composition of the present invention indicates a support for cultivating the target useful plant, especially a support for growing roots. The material is not particularly limited, but any material that allows the plant to grow may be used, such as so-called soil, seedling mat, water, etc. Specific materials include, for example, sand, pumice, vermiculite, diatomaceous earth, It may be agar, gel-like substance, polymeric substance, rock wool, glass wool, wood chips, bark, or the like.
The above-mentioned "soil" or "cultivation carrier" includes seedling boxes for paddy rice, paddy fields, cultivation carriers used for upland crops, and nutrient solution in hydroponics.
As a method for treating soil or a cultivation carrier, for example, a method of applying the composition of the present invention in the form of a liquid formulation to the stock of a target useful plant or a nursery bed for raising seedlings, with or without diluting it with water. , a method of spraying the composition of the present invention in the form of granules at the base of a plant body or a nursery bed for raising seedlings; A method of irrigating or spraying the composition of the present invention in the form of a powder, wettable powder, wettable granules, granules, etc. on a nursery bed for raising seedlings, or mixing with the entire soil or cultivation carrier in the vicinity of the transplant site, before sowing Alternatively, a method of spraying the composition of the present invention in the form of a powder, wettable powder, wettable granules, granules, or the like to a planting hole, row or the like before planting a plant body.
上記の「土壌」又は「栽培担体」には、水稲の育苗箱、水田、畑作物に用いる栽培担体、水耕栽培における養液等も含まれる。
土壌又は栽培担体の処理方法としては、例えば、液状製剤とした本発明の組成物を水に希釈し又は希釈せずに、対象有用植物の植物体の株元又は育苗用苗床等に施用する方法、粒剤とした本発明の組成物を植物体の株元又は育苗のための苗床等に散布する方法、播種前又は移植前に、液状剤とした本発明の組成物を、育苗用苗床に灌注し、又は粉剤、水和剤、顆粒水和剤、粒剤等とした本発明の組成物を育苗用苗床に散布し、又は移植場所近辺の土壌全体又は栽培担体と混和する方法、播種前又は植物体を植える前に植え穴、作条等に粉剤、水和剤、顆粒水和剤、粒剤等とした本発明の組成物を散布する方法等が挙げられる。 In the method of the present invention, the "soil" or "cultivation carrier" treated with the composition of the present invention indicates a support for cultivating the target useful plant, especially a support for growing roots. The material is not particularly limited, but any material that allows the plant to grow may be used, such as so-called soil, seedling mat, water, etc. Specific materials include, for example, sand, pumice, vermiculite, diatomaceous earth, It may be agar, gel-like substance, polymeric substance, rock wool, glass wool, wood chips, bark, or the like.
The above-mentioned "soil" or "cultivation carrier" includes seedling boxes for paddy rice, paddy fields, cultivation carriers used for upland crops, and nutrient solution in hydroponics.
As a method for treating soil or a cultivation carrier, for example, a method of applying the composition of the present invention in the form of a liquid formulation to the stock of a target useful plant or a nursery bed for raising seedlings, with or without diluting it with water. , a method of spraying the composition of the present invention in the form of granules at the base of a plant body or a nursery bed for raising seedlings; A method of irrigating or spraying the composition of the present invention in the form of a powder, wettable powder, wettable granules, granules, etc. on a nursery bed for raising seedlings, or mixing with the entire soil or cultivation carrier in the vicinity of the transplant site, before sowing Alternatively, a method of spraying the composition of the present invention in the form of a powder, wettable powder, wettable granules, granules, or the like to a planting hole, row or the like before planting a plant body.
水稲の育苗箱に対する本発明の組成物による処理方法においては、製剤化に際し選択し得る剤形は、播種時、緑化期、移植時等処理時期により異なる場合もあるが、例えば、粉剤、顆粒水和剤、粒剤等の剤形として処理すればよい。培土との混和によっても処理することができ、培土と粉剤、顆粒水和剤又は粒剤等とした本発明の組成物との混和、例えば、床土混和、覆土混和、培土全体への混和等により処理することができ、単に、培土と各種製剤とした本発明の組成物を交互に層状にして施用してもよい。
In the method of treating paddy rice nursery boxes with the composition of the present invention, the dosage form that can be selected for formulation may differ depending on the treatment time such as sowing, greening, and transplanting. It may be treated as a dosage form such as a blend, granules, or the like. It can also be treated by mixing with potting soil, and mixing potting soil with the composition of the present invention in the form of powder, wettable granules, granules, etc., for example, mixing with bed soil, mixing with covering soil, mixing with the whole potting soil, etc. or may simply be applied in alternating layers of potting soil and the compositions of the invention in various formulations.
水田の処理方法としては、ジャンボ剤、パック剤、粒剤、顆粒水和剤等の固形製剤、フロアブル剤、乳剤等の液状製剤とした本発明の組成物を、通常は、湛水状態の水田に散布する。その他、田植え時には、適当な製剤をそのまま又は肥料等に混和して土壌に散布、注入することもできる。また、水口や灌漑装置等の水田への水の流入元に乳剤、フロアブル剤等とした本発明の組成物を使用することにより、水の供給に伴い省力的に処理することもできる。
As a method for treating paddy fields, the composition of the present invention in the form of solid formulations such as jumbo formulations, pack formulations, granules and wettable granules, and liquid formulations such as flowable formulations and emulsions, is usually treated in flooded paddy fields. disperse to In addition, at the time of rice planting, an appropriate formulation can be sprayed or injected into the soil as it is or mixed with fertilizer or the like. In addition, by using the composition of the present invention in the form of an emulsion, a flowable agent, or the like, at the inlet of water to a paddy field such as a water outlet or an irrigation system, labor-saving treatment can be achieved along with the supply of water.
畑作物においては、播種から育苗期において、種子又は植物体に近接する栽培担体等の処理を行うことができる。畑に直接播種する植物においては、種子への直接処理の他、栽培中の植物の株元への処理が好適である。粒剤とした本発明の組成物を用いて散布処理を行い、又は水に希釈し又は希釈しない液状の本発明の組成物にて潅注処理を行うことができる。粒剤とした本発明の組成物を播種前の栽培担体と混和させた後、播種するのも好ましい処理である。
For field crops, it is possible to treat the seeds or cultivation carriers that are close to the plant during the period from sowing to raising seedlings. For plants that are directly sown in a field, it is preferable to apply the agent directly to the seeds as well as to the base of the plant under cultivation. The spraying treatment can be carried out with the composition of the invention in granule form, or the irrigation treatment can be carried out with the composition of the invention in liquid form, diluted with water or undiluted. It is also a preferred treatment to mix the composition of the invention in granules with a pre-sowing cultivation carrier and then sowing.
また、本発明の農園芸用殺虫剤の有効成分である化合物(I)及び化合物(II)は、各々単独で(別個に)同時期に使用することにより、予め有効成分が混合された農園芸用殺菌剤組成物と同様の殺菌スペクトラムの拡大効果や、化合物(I)及び化合物(II)の併用による相乗効果を発揮させることができる。即ち、化合物(I)又は化合物(II)を各々単独で製剤化したものやその希釈液を、使用の現場において処理時に混合して施用してもよく、また、これらを別個に同時期に用いて植物の茎葉部、種子、栽培担体等を処理してもよい。なお、化合物(I)又は化合物(II)を各々単独で製剤化したものを別個に施用する場合、同時に施用してもよく、約7日程度の間隔(時間差)を設けてもよいが、いずれか一方の有効成分が植物又は栽培担体に残存している時期に他方の有効成分を施用することが好ましい。本明細書において「同時期」とは、前述のように有効成分の残効等により、両有効成分が処理されている時期の少なくとも一部が重複することを含む概念であり、いずれか一方の先に使用した有効成分が植物または栽培担体に残存している時期と言い換えることもでき、必ずしも同時に施用作業を行うことを意味するものではない。先に使用した有効成分が植物又は栽培担体に残存している時期は、化合物(I)と化合物(II)とで異なるが、一方の有効成分を使用した日又は時から通常6月以内であり、3月以内であってもよく、1月以内であってもよく、10日以内であってもよく、7日以内であってもよく、3日以内であってもよく、24時間以内であってもよく、12時間以内であってもよく、6時間以内であってもよい。化合物(I)及び化合物(II)の有効量を、別個に、同時に、又は時間差をおいて植物又は栽培担体に施用する植物病害の防除方法も、本発明に包含される。化合物(I)又は化合物(II)の有効量としては、上述した農園芸用殺虫剤組成物における有効量と同様である。
In addition, compound (I) and compound (II), which are active ingredients of the agricultural and horticultural insecticide of the present invention, can be used alone (separately) at the same time to produce an agricultural and horticultural It is possible to exert the effect of broadening the bactericidal spectrum similar to that of the bactericidal agent composition for food, and the synergistic effect of the combined use of compound (I) and compound (II). That is, compound (I) or compound (II) may be formulated separately or its dilution may be mixed and applied at the time of treatment at the site of use, or they may be used separately at the same time. Plant foliage, seeds, cultivation carriers and the like may also be treated. When compound (I) or compound (II) is separately formulated and applied separately, they may be applied at the same time or may be applied at intervals of about 7 days (time difference). It is preferable to apply the other active ingredient when one of the active ingredients remains in the plant or cultivation carrier. As used herein, the term "simultaneous period" is a concept that includes at least a portion of the period in which both active ingredients are processed due to the residual effects of the active ingredients, as described above. It can also be rephrased as the period when the previously used active ingredient remains in the plant or cultivation carrier, and does not necessarily mean that the application operations are performed at the same time. The period during which the previously used active ingredient remains in the plant or cultivation carrier differs between compound (I) and compound (II), but is usually within 6 months from the date or time when one of the active ingredients is used. , may be within 3 months, may be within 1 month, may be within 10 days, may be within 7 days, may be within 3 days, may be within 24 hours It may be within 12 hours, or within 6 hours. The present invention also encompasses a method for controlling plant diseases in which effective amounts of compound (I) and compound (II) are applied separately, simultaneously, or with a time delay to a plant or cultivation carrier. The effective amount of compound (I) or compound (II) is the same as the effective amount in the agricultural and horticultural insecticide composition described above.
本発明の組成物は、当分野において通常採用される剤形、例えば、乳剤、水和剤、顆粒水和剤、フロアブル剤、液剤、粒剤、粉剤、薫煙剤等の剤形に製剤化して使用すればよく、その使用量は、有効成分である化合物(I)及び化合物(II)の配合割合、気象条件、剤形、使用時期、使用方法、使用場所、対象害虫類の種類、対象有用植物の種類等により異なるが、通常1アール当たり有効成分量(化合物(I)及び化合物(II)の総量)として0.1g~1000gの範囲から適宜選択して使用すれば良く、好ましくは1g~500gの範囲である。
種子の処理においては、種子重量に対し有効成分量として0.01重量%~50重量%の範囲で使用することが可能であり、0.1重量%~10重量%の範囲で使用することが好ましい。
乳剤、水和剤等として水等で希釈して使用する場合、その使用濃度は有効成分の濃度にして0.00001重量%~0.1重量%であり、粒剤、粉剤として使用する場合、又は液剤等として種子を処理する場合は、通常希釈することなくそのまま使用すれば良い。 The composition of the present invention is formulated into dosage forms commonly employed in the art, such as emulsions, wettable powders, wettable granules, flowables, liquids, granules, powders, and smokes. The amount used is determined by the mixing ratio of the active ingredients compound (I) and compound (II), weather conditions, dosage form, timing of use, method of use, place of use, type of target pests, target Although it varies depending on the type of useful plant, etc., the amount of active ingredient (total amount of compound (I) and compound (II)) per 1 are may be appropriately selected from the range of 0.1 g to 1000 g, preferably 1 g. ~500 g.
In the treatment of seeds, it is possible to use the amount of active ingredient in the range of 0.01% to 50% by weight based on the weight of the seed, and it is possible to use it in the range of 0.1% to 10% by weight. preferable.
When diluted with water or the like as an emulsion, wettable powder, etc., the concentration used is 0.00001% by weight to 0.1% by weight in terms of the concentration of the active ingredient. Alternatively, when seeds are treated as a liquid agent or the like, it is usually used as it is without dilution.
種子の処理においては、種子重量に対し有効成分量として0.01重量%~50重量%の範囲で使用することが可能であり、0.1重量%~10重量%の範囲で使用することが好ましい。
乳剤、水和剤等として水等で希釈して使用する場合、その使用濃度は有効成分の濃度にして0.00001重量%~0.1重量%であり、粒剤、粉剤として使用する場合、又は液剤等として種子を処理する場合は、通常希釈することなくそのまま使用すれば良い。 The composition of the present invention is formulated into dosage forms commonly employed in the art, such as emulsions, wettable powders, wettable granules, flowables, liquids, granules, powders, and smokes. The amount used is determined by the mixing ratio of the active ingredients compound (I) and compound (II), weather conditions, dosage form, timing of use, method of use, place of use, type of target pests, target Although it varies depending on the type of useful plant, etc., the amount of active ingredient (total amount of compound (I) and compound (II)) per 1 are may be appropriately selected from the range of 0.1 g to 1000 g, preferably 1 g. ~500 g.
In the treatment of seeds, it is possible to use the amount of active ingredient in the range of 0.01% to 50% by weight based on the weight of the seed, and it is possible to use it in the range of 0.1% to 10% by weight. preferable.
When diluted with water or the like as an emulsion, wettable powder, etc., the concentration used is 0.00001% by weight to 0.1% by weight in terms of the concentration of the active ingredient. Alternatively, when seeds are treated as a liquid agent or the like, it is usually used as it is without dilution.
以下に本発明の代表的な実施例及び試験例を例示するが、本発明はこれらに限定されるものではない。なお、実施例中、「部」とあるのは質量部を示す。
Although representative examples and test examples of the present invention are illustrated below, the present invention is not limited to these. In the examples, "parts" means parts by mass.
[製剤例1]
化合物(I) 4部
化合物(II) 4部
含水珪酸 30部
ポリオキシエチレンスチレン化フェニルエーテル硫酸アンモニウム
(「ハイテノール(登録商標)N08」(第一工業製薬株式会社製))
5部
リグニンスルホン酸カルシウム 3部
水和剤クレー 54部
製法:化合物(I)及び化合物(II)を含水珪酸に含浸させた後、他の成分と均一に混合して水和剤とする。 [Formulation Example 1]
Compound (I) 4 parts Compound (II) 4 parts Hydrous silicic acid 30 parts Polyoxyethylene styrenated phenyl ether ammonium sulfate ("Hitenol (registered trademark) N08" (manufactured by Daiichi Kogyo Seiyaku Co., Ltd.))
5 parts Calcium lignosulfonate 3 parts Wettable powder clay 54 parts Production method: After impregnating compound (I) and compound (II) in hydrous silicic acid, the mixture is homogeneously mixed with other ingredients to form a wettable powder.
化合物(I) 4部
化合物(II) 4部
含水珪酸 30部
ポリオキシエチレンスチレン化フェニルエーテル硫酸アンモニウム
(「ハイテノール(登録商標)N08」(第一工業製薬株式会社製))
5部
リグニンスルホン酸カルシウム 3部
水和剤クレー 54部
製法:化合物(I)及び化合物(II)を含水珪酸に含浸させた後、他の成分と均一に混合して水和剤とする。 [Formulation Example 1]
Compound (I) 4 parts Compound (II) 4 parts Hydrous silicic acid 30 parts Polyoxyethylene styrenated phenyl ether ammonium sulfate ("Hitenol (registered trademark) N08" (manufactured by Daiichi Kogyo Seiyaku Co., Ltd.))
5 parts Calcium lignosulfonate 3 parts Wettable powder clay 54 parts Production method: After impregnating compound (I) and compound (II) in hydrous silicic acid, the mixture is homogeneously mixed with other ingredients to form a wettable powder.
[製剤例2]
化合物(I) 6部
化合物(II) 3部
非イオン性・陰イオン性界面活性剤混合物
(「ソルポール(登録商標)3105」(東邦化学工業株式会社製))
5部
プロピレングリコール 5部
2%キサンタンガム分散混合液
(「ロドポール(Rhodopol:登録商標)23」(ソルベイ日華株式会社製))
10部
水 71部
製法:水以外の成分を均一に混合し、水に分散させてフロアブル剤とする。 [Formulation Example 2]
Compound (I) 6 parts Compound (II) 3 parts Nonionic/anionic surfactant mixture (“Solpol (registered trademark) 3105” (manufactured by Toho Chemical Industry Co., Ltd.))
5 parts propylene glycol 5 parts 2% xanthan gum dispersion mixture ("Rhodopol: registered trademark 23" (manufactured by Solvay Nicca Co., Ltd.))
10 parts Water 71 parts Production method: Uniformly mix ingredients other than water and disperse in water to obtain a flowable agent.
化合物(I) 6部
化合物(II) 3部
非イオン性・陰イオン性界面活性剤混合物
(「ソルポール(登録商標)3105」(東邦化学工業株式会社製))
5部
プロピレングリコール 5部
2%キサンタンガム分散混合液
(「ロドポール(Rhodopol:登録商標)23」(ソルベイ日華株式会社製))
10部
水 71部
製法:水以外の成分を均一に混合し、水に分散させてフロアブル剤とする。 [Formulation Example 2]
Compound (I) 6 parts Compound (II) 3 parts Nonionic/anionic surfactant mixture (“Solpol (registered trademark) 3105” (manufactured by Toho Chemical Industry Co., Ltd.))
5 parts propylene glycol 5 parts 2% xanthan gum dispersion mixture ("Rhodopol: registered trademark 23" (manufactured by Solvay Nicca Co., Ltd.))
10 parts Water 71 parts Production method: Uniformly mix ingredients other than water and disperse in water to obtain a flowable agent.
[製剤例3]
化合物(I) 3部
化合物(II) 6部
非イオン性・陰イオン性界面活性剤混合物
(「ソルポール(登録商標)3105」(東邦化学工業株式会社製))
5部
プロピレングリコール 2部
キサンタンガム 1部
水 78部
製法:水以外の成分を均一に混合し、水に分散させてフロアブル剤とする。 [Formulation Example 3]
Compound (I) 3 parts Compound (II) 6 parts Nonionic/anionic surfactant mixture (“Solpol (registered trademark) 3105” (manufactured by Toho Chemical Industry Co., Ltd.))
5 parts Propylene glycol 2 parts Xanthan gum 1 part Water 78 parts Production method: Uniformly mix ingredients other than water and disperse in water to obtain a flowable agent.
化合物(I) 3部
化合物(II) 6部
非イオン性・陰イオン性界面活性剤混合物
(「ソルポール(登録商標)3105」(東邦化学工業株式会社製))
5部
プロピレングリコール 2部
キサンタンガム 1部
水 78部
製法:水以外の成分を均一に混合し、水に分散させてフロアブル剤とする。 [Formulation Example 3]
Compound (I) 3 parts Compound (II) 6 parts Nonionic/anionic surfactant mixture (“Solpol (registered trademark) 3105” (manufactured by Toho Chemical Industry Co., Ltd.))
5 parts Propylene glycol 2 parts Xanthan gum 1 part Water 78 parts Production method: Uniformly mix ingredients other than water and disperse in water to obtain a flowable agent.
[製剤例4]
化合物(I) 9部
化合物(II) 1部
ポリオキシエチレンノニルフェニルエーテルと
アルキルベンゼンスルホン酸カルシウムとの混合物 15部
キシレン 45部
N-メチルピロリドン 30部
製法:上記成分を均一に混合融解して乳剤とする。 [Formulation Example 4]
Compound (I) 9 parts Compound (II) 1 part Mixture of polyoxyethylene nonylphenyl ether and calcium alkylbenzenesulfonate 15 parts Xylene 45 parts N-methylpyrrolidone 30 parts Production method: The above components are uniformly mixed and melted to form an emulsion. do.
化合物(I) 9部
化合物(II) 1部
ポリオキシエチレンノニルフェニルエーテルと
アルキルベンゼンスルホン酸カルシウムとの混合物 15部
キシレン 45部
N-メチルピロリドン 30部
製法:上記成分を均一に混合融解して乳剤とする。 [Formulation Example 4]
Compound (I) 9 parts Compound (II) 1 part Mixture of polyoxyethylene nonylphenyl ether and calcium alkylbenzenesulfonate 15 parts Xylene 45 parts N-methylpyrrolidone 30 parts Production method: The above components are uniformly mixed and melted to form an emulsion. do.
[製剤例5]
化合物(I) 0.5部
化合物(II) 2.5部
クレー粉末 82部
珪藻土粉末 15部
製法:上記成分を均一に混合粉砕して粉剤とする。 [Formulation Example 5]
Compound (I) 0.5 parts Compound (II) 2.5 parts Clay powder 82 parts Diatomaceous earth powder 15 parts Production method: Uniformly mix and pulverize the above components to obtain powders.
化合物(I) 0.5部
化合物(II) 2.5部
クレー粉末 82部
珪藻土粉末 15部
製法:上記成分を均一に混合粉砕して粉剤とする。 [Formulation Example 5]
Compound (I) 0.5 parts Compound (II) 2.5 parts Clay powder 82 parts Diatomaceous earth powder 15 parts Production method: Uniformly mix and pulverize the above components to obtain powders.
[製剤例6]
化合物(I) 3部
化合物(II) 3部
ベントナイトとクレーの混合粉末 89部
リグニンスルホン酸カルシウム 5部
製法:上記成分を均一に混合し、適量の水を加えて混錬し、造粒、乾燥して粒剤とする。 [Formulation Example 6]
Compound (I) 3 parts Compound (II) 3 parts Mixed powder of bentonite and clay 89 parts Calcium lignosulfonate 5 parts Production method: The above components are uniformly mixed, an appropriate amount of water is added, kneaded, granulated, and dried. and granules.
化合物(I) 3部
化合物(II) 3部
ベントナイトとクレーの混合粉末 89部
リグニンスルホン酸カルシウム 5部
製法:上記成分を均一に混合し、適量の水を加えて混錬し、造粒、乾燥して粒剤とする。 [Formulation Example 6]
Compound (I) 3 parts Compound (II) 3 parts Mixed powder of bentonite and clay 89 parts Calcium lignosulfonate 5 parts Production method: The above components are uniformly mixed, an appropriate amount of water is added, kneaded, granulated, and dried. and granules.
[製剤例7]
化合物(I) 2部
化合物(II) 5部
ナフタレンスルホネート・ホルマリン縮合物
(「ルノックス(登録商標)1000C」(東邦化学工業株式会社製))
5部
含水非晶質二酸化ケイ素(「カープレックス(登録商標)#80D」
(エボニック ジャパン株式会社製)) 3部
プロピレングリコール 8部
水 57部
製法:化合物(I)、化合物(II)、ナフタレンスルホネート・ホルマリン縮合物、含水非晶質二酸化ケイ素及びプロピレングリコールを水に混合分散させ、得られたスラリー状混合物を、横型ビーズミル(「ダイノーミル(DYNO呼称ダイノは登録商標)」、ウィリー・エ・バッコーフェン社製)で湿式粉砕した後、別にあらかじめ混合溶解しておいたキサンタンガム1重量%水溶液20部を加えて均一に混合し、有効成分(化合物(I)及び化合物(II))7重量%を含有する水性懸濁剤(フロアブル剤)とする。 [Formulation Example 7]
Compound (I) 2 parts Compound (II) 5 parts Naphthalene sulfonate formalin condensate (“Lunox (registered trademark) 1000C” (manufactured by Toho Chemical Industry Co., Ltd.))
5 parts hydrous amorphous silicon dioxide (“Carplex® #80D”
(manufactured by Evonik Japan Ltd.)) 3 parts propylene glycol 8 parts water 57 parts Production method: compound (I), compound (II), naphthalene sulfonate/formalin condensate, hydrous amorphous silicon dioxide and propylene glycol are mixed and dispersed in water. The resulting slurry-like mixture was wet-ground with a horizontal bead mill (“DYNO MILL (registered trademark of DYNO)” manufactured by Willie & Bakkofen), and then 1 weight of xanthan gum that had been separately mixed and dissolved in advance was added. % aqueous solution is added and uniformly mixed to obtain an aqueous suspension (flowable preparation) containing 7% by weight of active ingredients (compound (I) and compound (II)).
化合物(I) 2部
化合物(II) 5部
ナフタレンスルホネート・ホルマリン縮合物
(「ルノックス(登録商標)1000C」(東邦化学工業株式会社製))
5部
含水非晶質二酸化ケイ素(「カープレックス(登録商標)#80D」
(エボニック ジャパン株式会社製)) 3部
プロピレングリコール 8部
水 57部
製法:化合物(I)、化合物(II)、ナフタレンスルホネート・ホルマリン縮合物、含水非晶質二酸化ケイ素及びプロピレングリコールを水に混合分散させ、得られたスラリー状混合物を、横型ビーズミル(「ダイノーミル(DYNO呼称ダイノは登録商標)」、ウィリー・エ・バッコーフェン社製)で湿式粉砕した後、別にあらかじめ混合溶解しておいたキサンタンガム1重量%水溶液20部を加えて均一に混合し、有効成分(化合物(I)及び化合物(II))7重量%を含有する水性懸濁剤(フロアブル剤)とする。 [Formulation Example 7]
Compound (I) 2 parts Compound (II) 5 parts Naphthalene sulfonate formalin condensate (“Lunox (registered trademark) 1000C” (manufactured by Toho Chemical Industry Co., Ltd.))
5 parts hydrous amorphous silicon dioxide (“Carplex® #80D”
(manufactured by Evonik Japan Ltd.)) 3 parts propylene glycol 8 parts water 57 parts Production method: compound (I), compound (II), naphthalene sulfonate/formalin condensate, hydrous amorphous silicon dioxide and propylene glycol are mixed and dispersed in water. The resulting slurry-like mixture was wet-ground with a horizontal bead mill (“DYNO MILL (registered trademark of DYNO)” manufactured by Willie & Bakkofen), and then 1 weight of xanthan gum that had been separately mixed and dissolved in advance was added. % aqueous solution is added and uniformly mixed to obtain an aqueous suspension (flowable preparation) containing 7% by weight of active ingredients (compound (I) and compound (II)).
[試験例1]トビイロウンカ(Nilaparvata lugens)に対する防除効果(試験法1)
(1)試料の調製
製剤例に準じての化合物(I)及び化合物(II)を有効成分とする本発明の組成物を調製し、第1表に示す濃度となるように水に分散させて、それぞれ試料とする。また、化合物(I)及び化合物(II)の各濃度のそれぞれを単独で水に分散させて、試料とする。
(2)防除効果の評価
ポット植えのイネ(品種:金南風)に、各試料をスプレーガンで40mL程度を散布し、風乾する。前記試料による処理の処理直後、14日後及び28日後に、供試虫(トビイロウンカ(Nilaparvata lugens))の成虫を放虫する(雌雄各6頭)。なお、対照区のイネでは試料の代わりに同量の水を散布し、同様に供試虫を放虫し、同様に処理する。前記処理の後、表記載の所定日に生存虫数を計測し、[式1]に従って防除率を算出する。また、[式2]に示すコルビーの式(Colby,S.R.,Weeds15:20-22(1967) を参照)から期待値(E)を求める。
化合物(I)及び化合物(II)を含有する本発明の組成物により処理をして得られる評価結果から算出する防除率が、本発明の組成物に含有される有効成分をそれぞれ単独で含有する試料により処理した際に得られる防除率から算出される前記期待値(E)を上回れば、本発明の組成物は相乗効果を示すといえる。 [Test Example 1] Control effect on brown planthopper (Nilaparvata lugens) (test method 1)
(1) Preparation of sample A composition of the present invention containing compound (I) and compound (II) as active ingredients was prepared according to the formulation example, and dispersed in water so as to have the concentration shown in Table 1. , respectively. In addition, each concentration of compound (I) and compound (II) is independently dispersed in water to prepare a sample.
(2) Evaluation of pest control effect About 40 mL of each sample is sprayed on potted rice (variety: Kinnanfu) with a spray gun and air-dried. Immediate, 14 and 28 days after treatment with the samples, adults of the test insects (Nilaparvata lugens) are released (6 males and 6 females). In the control rice plants, the same amount of water is sprayed instead of the sample, and the test insects are released in the same manner and treated in the same manner. After the treatment, the number of surviving insects is counted on the predetermined day shown in the table, and the control rate is calculated according to [Formula 1]. Also, the expected value (E) is obtained from Colby's formula (see Colby, SR, Weeds 15:20-22 (1967)) shown in [Formula 2].
The control rate calculated from the evaluation results obtained by treatment with the composition of the present invention containing compound (I) and compound (II) contains each of the active ingredients contained in the composition of the present invention alone. If the expected value (E) calculated from the control rate obtained when treated with the sample is exceeded, it can be said that the composition of the present invention exhibits a synergistic effect.
(1)試料の調製
製剤例に準じての化合物(I)及び化合物(II)を有効成分とする本発明の組成物を調製し、第1表に示す濃度となるように水に分散させて、それぞれ試料とする。また、化合物(I)及び化合物(II)の各濃度のそれぞれを単独で水に分散させて、試料とする。
(2)防除効果の評価
ポット植えのイネ(品種:金南風)に、各試料をスプレーガンで40mL程度を散布し、風乾する。前記試料による処理の処理直後、14日後及び28日後に、供試虫(トビイロウンカ(Nilaparvata lugens))の成虫を放虫する(雌雄各6頭)。なお、対照区のイネでは試料の代わりに同量の水を散布し、同様に供試虫を放虫し、同様に処理する。前記処理の後、表記載の所定日に生存虫数を計測し、[式1]に従って防除率を算出する。また、[式2]に示すコルビーの式(Colby,S.R.,Weeds15:20-22(1967) を参照)から期待値(E)を求める。
化合物(I)及び化合物(II)を含有する本発明の組成物により処理をして得られる評価結果から算出する防除率が、本発明の組成物に含有される有効成分をそれぞれ単独で含有する試料により処理した際に得られる防除率から算出される前記期待値(E)を上回れば、本発明の組成物は相乗効果を示すといえる。 [Test Example 1] Control effect on brown planthopper (Nilaparvata lugens) (test method 1)
(1) Preparation of sample A composition of the present invention containing compound (I) and compound (II) as active ingredients was prepared according to the formulation example, and dispersed in water so as to have the concentration shown in Table 1. , respectively. In addition, each concentration of compound (I) and compound (II) is independently dispersed in water to prepare a sample.
(2) Evaluation of pest control effect About 40 mL of each sample is sprayed on potted rice (variety: Kinnanfu) with a spray gun and air-dried. Immediate, 14 and 28 days after treatment with the samples, adults of the test insects (Nilaparvata lugens) are released (6 males and 6 females). In the control rice plants, the same amount of water is sprayed instead of the sample, and the test insects are released in the same manner and treated in the same manner. After the treatment, the number of surviving insects is counted on the predetermined day shown in the table, and the control rate is calculated according to [Formula 1]. Also, the expected value (E) is obtained from Colby's formula (see Colby, SR, Weeds 15:20-22 (1967)) shown in [Formula 2].
The control rate calculated from the evaluation results obtained by treatment with the composition of the present invention containing compound (I) and compound (II) contains each of the active ingredients contained in the composition of the present invention alone. If the expected value (E) calculated from the control rate obtained when treated with the sample is exceeded, it can be said that the composition of the present invention exhibits a synergistic effect.
[式1]
防除率(%)=(1-生存虫数/対照区生存虫数)×100 [Formula 1]
Control rate (%) = (1-number of surviving insects/number of surviving insects in control section) x 100
防除率(%)=(1-生存虫数/対照区生存虫数)×100 [Formula 1]
Control rate (%) = (1-number of surviving insects/number of surviving insects in control section) x 100
[式2]
期待値(E)=X+Y-(X×Y/100)
X=化合物(I)単独で処理した場合の防除率(%)
Y=化合物(II)単独で処理した場合の防除率(%) [Formula 2]
Expected value (E) = X + Y - (X x Y / 100)
X = control rate (%) when treated with compound (I) alone
Y = control rate (%) when treated with compound (II) alone
期待値(E)=X+Y-(X×Y/100)
X=化合物(I)単独で処理した場合の防除率(%)
Y=化合物(II)単独で処理した場合の防除率(%) [Formula 2]
Expected value (E) = X + Y - (X x Y / 100)
X = control rate (%) when treated with compound (I) alone
Y = control rate (%) when treated with compound (II) alone
[試験例2]トビイロウンカ(Nilaparvata lugens)に対する防除効果(試験法2)
(1)試料の調製
化合物(I)と化合物(II)を、それぞれ第1表に示す濃度で水に分散させて、試験用の組成物を調製した。また、各濃度の化合物(I)と、化合物(II)のそれぞれを単独で水に分散させて、試料とした。
(2)防除効果の評価
上記試料液にイネ葉鞘(品種:金南風)を30秒間浸漬し、風乾した後にガラス試験管に入れ、トビイロウンカ(Nilaparvata lugens)の5齢を各10頭づつ接種した後に綿栓をし、所定日数後(4、5又は6日後)に生存虫数及び死亡虫数を調査し、死虫率を算出した。また、[式3]に示すように、コルビーの式から期待値(E’)を求めた。
本試験においても、本発明の組成物について実測された死虫率が各期待値より高い場合には、防除効果の相乗効果が認められる。評価結果を第1表に示した。 [Test Example 2] Control effect on brown planthopper (Nilaparvata lugens) (test method 2)
(1) Preparation of Sample Compound (I) and Compound (II) were dispersed in water at concentrations shown in Table 1 to prepare test compositions. In addition, each concentration of compound (I) and compound (II) were individually dispersed in water to prepare samples.
(2) Evaluation of control effect Rice leaf sheaths (variety: Kinnanpu) were immersed in the above sample solution for 30 seconds, air-dried, placed in glass test tubes, and inoculated with 10 5th instar brown planthoppers (Nilaparvata lugens) each. A cotton plug was later applied, and after a predetermined number of days (4, 5 or 6 days), the number of living insects and the number of dead insects were investigated, and the mortality rate was calculated. Also, as shown in [Formula 3], the expected value (E') was obtained from Colby's formula.
Also in this test, when the mortality rate actually measured for the composition of the present invention is higher than each expected value, a synergistic effect of the control effect is recognized. The evaluation results are shown in Table 1.
(1)試料の調製
化合物(I)と化合物(II)を、それぞれ第1表に示す濃度で水に分散させて、試験用の組成物を調製した。また、各濃度の化合物(I)と、化合物(II)のそれぞれを単独で水に分散させて、試料とした。
(2)防除効果の評価
上記試料液にイネ葉鞘(品種:金南風)を30秒間浸漬し、風乾した後にガラス試験管に入れ、トビイロウンカ(Nilaparvata lugens)の5齢を各10頭づつ接種した後に綿栓をし、所定日数後(4、5又は6日後)に生存虫数及び死亡虫数を調査し、死虫率を算出した。また、[式3]に示すように、コルビーの式から期待値(E’)を求めた。
本試験においても、本発明の組成物について実測された死虫率が各期待値より高い場合には、防除効果の相乗効果が認められる。評価結果を第1表に示した。 [Test Example 2] Control effect on brown planthopper (Nilaparvata lugens) (test method 2)
(1) Preparation of Sample Compound (I) and Compound (II) were dispersed in water at concentrations shown in Table 1 to prepare test compositions. In addition, each concentration of compound (I) and compound (II) were individually dispersed in water to prepare samples.
(2) Evaluation of control effect Rice leaf sheaths (variety: Kinnanpu) were immersed in the above sample solution for 30 seconds, air-dried, placed in glass test tubes, and inoculated with 10 5th instar brown planthoppers (Nilaparvata lugens) each. A cotton plug was later applied, and after a predetermined number of days (4, 5 or 6 days), the number of living insects and the number of dead insects were investigated, and the mortality rate was calculated. Also, as shown in [Formula 3], the expected value (E') was obtained from Colby's formula.
Also in this test, when the mortality rate actually measured for the composition of the present invention is higher than each expected value, a synergistic effect of the control effect is recognized. The evaluation results are shown in Table 1.
[式3]
期待値(E’)=X’+Y’-(X’×Y’/100)
X’=各濃度の化合物(I)単独で処理した場合の死虫率(%)
Y’=各濃度の化合物(II)単独で処理した場合の死虫率(%) [Formula 3]
Expected value (E') = X' + Y' - (X' x Y'/100)
X' = Mortality rate (%) when treated with compound (I) alone at each concentration
Y' = Mortality (%) when treated with compound (II) alone at each concentration
期待値(E’)=X’+Y’-(X’×Y’/100)
X’=各濃度の化合物(I)単独で処理した場合の死虫率(%)
Y’=各濃度の化合物(II)単独で処理した場合の死虫率(%) [Formula 3]
Expected value (E') = X' + Y' - (X' x Y'/100)
X' = Mortality rate (%) when treated with compound (I) alone at each concentration
Y' = Mortality (%) when treated with compound (II) alone at each concentration
第1表に示される通り、化合物(I)と化合物(II)とを含有する本発明の組成物はいずれも良好な防除効果を示し、本発明の組成物により処理した場合には、期待値(E’)を上回る死虫率が得られた。
As shown in Table 1, the composition of the present invention containing compound (I) and compound (II) both showed good control effect, and when treated with the composition of the present invention, the expected value A higher mortality than (E') was obtained.
上記試験例の結果から、本発明の組成物では、各農園芸用薬剤を単独で用いる場合に比べて、防除効果が相乗的に向上することが確認された。
From the results of the above test examples, it was confirmed that the composition of the present invention synergistically improves the control effect compared to the case where each agricultural or horticultural agent is used alone.
以上詳述したように、本発明によれば、各種農園芸害虫類に対する防除効果が相乗的に向上し、複数の害虫を効率的に防除することのできる、農園芸用殺虫剤組成物を提供することができる。
INDUSTRIAL APPLICABILITY As described in detail above, the present invention provides an agricultural and horticultural insecticide composition that synergistically improves the control effect against various agricultural and horticultural pests and can efficiently control a plurality of pests. can do.
本出願は、日本国で2021年4月20日に出願された特願2021-071103を基礎としており、その内容は本明細書にすべて包含されるものである。
This application is based on Japanese Patent Application No. 2021-071103 filed on April 20, 2021 in Japan, the contents of which are all incorporated herein.
Claims (8)
- 化合物(I)として5-(1,3-ジオキサン-2-イル)-4-[4-(トリフルオロメチル)ベンジルオキシ]ピリミジン、及び化合物(II)として(1E)-N1-[(6-クロロピリジン-3-イル)メチル]-N1-エチル-N’1-メチル-2-ニトロビニリデン-1,1-ジアミンを含有する農園芸用殺虫剤組成物。 5-(1,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine as compound (I), and (1E)-N1-[(6- An agricultural and horticultural insecticide composition containing chloropyridin-3-yl)methyl]-N1-ethyl-N'1-methyl-2-nitrovinylidene-1,1-diamine.
- 化合物(I)1質量部に対して、化合物(II)を0.01~2000質量部の割合で含有する、請求項1に記載の農園芸用殺虫剤組成物。 The agricultural and horticultural insecticide composition according to claim 1, which contains 0.01 to 2000 parts by mass of compound (II) per 1 part by mass of compound (I).
- 農園芸害虫類から有用植物を保護するために、有効量の請求項1又は2に記載の農園芸用殺虫剤組成物を、対象害虫類、対象有用植物、対象有用植物の種子、土壌又は栽培担体に施用することを特徴とする、農園芸用殺虫剤組成物の使用方法。 In order to protect useful plants from agricultural and horticultural pests, an effective amount of the agricultural and horticultural insecticide composition according to claim 1 or 2 is applied to target pests, target useful plants, seeds of target useful plants, soil or cultivation. A method of using an agricultural and horticultural insecticide composition, characterized by applying it to a carrier.
- 5-(1,3-ジオキサン-2-イル)-4-[4-(トリフルオロメチル)ベンジルオキシ]ピリミジン及び(1E)-N1-[(6-クロロピリジン-3-イル)メチル]-N1-エチル-N’1-メチル-2-ニトロビニリデン-1,1-ジアミンを、別個に、同時期に植物又は栽培担体に施用することを特徴とする農園芸害虫類の防除方法。 5-(1,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine and (1E)-N1-[(6-chloropyridin-3-yl)methyl]-N1 - A method for controlling agricultural and horticultural pests, characterized in that ethyl-N'1-methyl-2-nitrovinylidene-1,1-diamine is applied separately and simultaneously to plants or cultivation carriers.
- 5-(1,3-ジオキサン-2-イル)-4-[4-(トリフルオロメチル)ベンジルオキシ]ピリミジン及び(1E)-N1-[(6-クロロピリジン-3-イル)メチル]-N1-エチル-N’1-メチル-2-ニトロビニリデン-1,1-ジアミンを、別個に、同時に植物又は栽培担体に施用することを特徴とする農園芸害虫類の防除方法。 5-(1,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine and (1E)-N1-[(6-chloropyridin-3-yl)methyl]-N1 - A method for controlling agricultural and horticultural pests, characterized in that ethyl-N'1-methyl-2-nitrovinylidene-1,1-diamine is applied separately and simultaneously to plants or cultivation carriers.
- 5-(1,3-ジオキサン-2-イル)-4-[4-(トリフルオロメチル)ベンジルオキシ]ピリミジン及び(1E)-N1-[(6-クロロピリジン-3-イル)メチル]-N1-エチル-N’1-メチル-2-ニトロビニリデン-1,1-ジアミンを、別個に、時間差をおいて植物又は栽培担体に施用することを特徴とする農園芸害虫類の防除方法。 5-(1,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine and (1E)-N1-[(6-chloropyridin-3-yl)methyl]-N1 - A method for controlling agricultural and horticultural pests, characterized in that ethyl-N'1-methyl-2-nitrovinylidene-1,1-diamine is separately applied to plants or cultivation carriers with a time lag.
- 5-(1,3-ジオキサン-2-イル)-4-[4-(トリフルオロメチル)ベンジルオキシ]ピリミジン及び(1E)-N1-[(6-クロロピリジン-3-イル)メチル]-N1-エチル-N’1-メチル-2-ニトロビニリデン-1,1-ジアミンを含有する殺虫剤組成物。 5-(1,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine and (1E)-N1-[(6-chloropyridin-3-yl)methyl]-N1 - an insecticidal composition containing ethyl-N'1-methyl-2-nitrovinylidene-1,1-diamine.
- (1E)-N1-[(6-クロロピリジン-3-イル)メチル]-N1-エチル-N’1-メチル-2-ニトロビニリデン-1,1-ジアミンと併用するための、5-(1,3-ジオキサン-2-イル)-4-[4-(トリフルオロメチル)ベンジルオキシ]ピリミジンを含有する殺虫剤組成物。 5-(1 ,3-dioxan-2-yl)-4-[4-(trifluoromethyl)benzyloxy]pyrimidine.
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