JP2021020878A - Pest control agent composition and process for use thereof - Google Patents

Abstract

To provide a new pest control agent composition for efficiently controlling pests that are difficult or impossible to control in the conventional art.SOLUTION: A pest control agent composition comprises a first active ingredient such as 2-(3-ethoxysulfonyl-2-pyridyl-5-(2,2,3,3,3-pentafluoropropyloxy) pyrazine, and a second active ingredient such as isoprothiolane, basic copper sulfate, fluoroimide, flutolanil, fenoxanil, tiadinil, buprofezin, isoprocarb, fenobucarb.SELECTED DRAWING: None

Description

The present invention is selected from compounds (A-1) and (A-5) or salts thereof as the first active ingredient, and compounds having pest control activity or salts thereof as the second active ingredient1 The present invention relates to a pest control agent composition containing a species or two or more compounds and a method for using the same. Furthermore, it also relates to a method for controlling pests utilizing the synergistic effect of the compound combination.

The compounds (A-1) and (A-5) used as the first active ingredient of the pest control agent composition of the present invention are known compounds and are known to have insecticidal activity or herbicidal activity. (See, for example, Patent Documents 1 and 17). The compounds used as the second active ingredient in the pest control composition of the present invention are isoprothiolane, basic copper sulfate, fluoroimide, flutolanil, fenoxanil. , Tiadinil, buprofezin, isoprocarb (MIPC), fenobucarb, fenpyroximate, tebufenpyrad, tolfenpyrad, tolfenpyrad, flubendiamide, flubendiamide, flubendiamide, flubendiamide (pyrifluquinazon), chlorphthalim, pyraflufen-ethyl, indanofan, isouron, orthosulfamuron, pyriprole, pyflubumide, pyraziflumid ), Benzpyrimoxan, and hydroxyquinolin copper (copper-8-quinolinolate). All of these are known compounds and are commercially available as pest control agents (see, for example, Non-Patent Document 1), and pest control agent compositions using them and methods for using them are known. However, compound (A-1), Otoshi (A-5) or a salt thereof is combined with one or more compounds selected from the other compounds having pest control activity or salts thereof. No pest control agent composition is known, nor is it known that a composition combining these has a synergistic pest control effect compared to the use of each compound alone.

International Publication No. 2017/065228 Pamphlet International Publication No. 2019/111869 Pamphlet International Publication No. 2012/20296 Pamphlet International Publication No. 2018/11934 Pamphlet International Publication No. 2017/178582 Pamphlet International Publication No. 2019/076930 Pamphlet International Publication No. 2019/076934 Pamphlet International Publication No. 2013/092350 Pamphlet International Publication No. 2019/07647 Pamphlet International Publication No. 2019/076750 Pamphlet International Publication No. 2019/076751 Pamphlet International Publication No. 2019/076752 Pamphlet International Publication No. 2019/076754 Pamphlet International Publication No. 2014/151005 Pamphlet International Publication No. 2019/0466666 Pamphlet International Publication No. 2019/046666 Pamphlet International Publication No. 2019/060366 Pamphlet

The Pesticide Manual 18th Edition (British Crop Production Council, 2018)

In the production of agricultural products, pest control work is a particularly heavy burden. Pests include various pests and weeds, and their damage is still large, and it is necessary to treat pest control agents (that is, pesticides, fungicides, herbicides, etc.) for their control. .. In addition, in the production of agricultural products, reducing the treatment work of pest control agents is strongly required from the viewpoint of occupational hygiene, which reduces the labor burden of agricultural workers, and from the economical viewpoint of reducing the cost of producing agricultural products. Various pest control agents have been developed. However, with the prior art, effective control may not be possible due to the type of organism to be controlled, habitat characteristics, development of drug resistance, etc., and in order to efficiently control pests that are difficult or impossible to control. The development of new technology was desired.

As a result of diligent research to solve the above problems, the present inventor has made compounds (A-1) and (A-5) or salts thereof, isoprothiolane, basic copper sulfate, and fluorimide. (Fluorimide), flutolanil, fenoxanil, tiadinil, buprofezin, isoprocarb (MIPC), fenobucarb, fenpyroximate, tebufenpyrad, tebufenpyrad, tebufenpyrad , Flubendiamide, metaflumizone, pyrifluquinazon, chlorphthalim, pyraflufen-ethyl, indanofan, isouron, orthosulfamuron, orthosulfamuron, One or more selected from pyriprole, pyflubumide, pyraziflumid, benzpyrimoxan, and hydroxyquinoline copper (copper-8-quinolinolate), or salts thereof. By combining with compounds (hereinafter, these may be referred to as active ingredient B), a remarkable synergistic effect, expansion of target pest species, and reduction of drug amount used as compared with the case where each compound is used alone. , And found that it has effects such as reduction of the number of chemical treatments, and completed the present invention.

That is, the present invention
[1] It is a combination
As the first active ingredient, one or more compounds selected from the following group of compounds (A) or salts thereof,
As the second active ingredient, the following group of compounds (B),
Isoprothiolane (B-1), basic copper sulfate (B-2), fluoroimide (B-3), flutolanil (B-4), fenoxanil (fenoxanil) ( B-5), tiadinil (B-6), buprofezin (B-7), isoprocarb (MIPC) (B-8), fenobucarb (B-9), fenpyroximate ) (B-10), tebufenpyrad (B-11), tolfenpyrad (B-12), flubendiamide (B-13), metaflumizone (B-14), pyrifluquinazone ( pyrifluquinazon (B-15), chlorphthalim (B-16), pyraflufen-ethyl (B-17), indanofan (B-18), isouron (B-) 19), orthosulfamuron (B-20), pyriprole (B-21), pyflubumide (B-22), pyraziflumid (B-23), benzpyrimoxane Pest control agent composition containing (benzpyrimoxan) (B-24) and one or more compounds selected from hydroxyquinolin copper (copper-8-quinolinolate) (B-25) or salts thereof. Stuff,
[2] The pest control agent composition according to [1], which contains the second active ingredient in a ratio of 0.01 to 5000 parts by mass with respect to 1 part by mass of the first active ingredient.
[3] A pest control agent composition, which comprises applying an effective amount of the pest control agent composition according to [1] or [2] to a target crop, seeds of the target crop, soil, and a cultivation carrier. how to use,
[4] A method for controlling pests, which comprises applying an effective amount of the pest control agent composition according to [1] or [2] to a target crop, seeds of the target crop, soil, and a cultivation carrier.
[5] As the first active ingredient, one or more compounds selected from the following group of compounds (A) or salts thereof,
As the second active ingredient, the following group of compounds (B),
Isoprothiolane (B-1), basic copper sulfate (B-2), fluoroimide (B-3), flutolanil (B-4), fenoxanil (fenoxanil) ( B-5), tiadinil (B-6), buprofezin (B-7), isoprocarb (MIPC) (B-8), fenobucarb (B-9), fenpyroximate ) (B-10), tebufenpyrad (B-11), tolfenpyrad (B-12), flubendiamide (B-13), metaflumizone (B-14), pyrifluquinazone ( pyrifluquinazon (B-15), chlorphthalim (B-16), pyraflufen-ethyl (B-17), indanofan (B-18), isouron (B-) 19), orthosulfamuron (B-20), pyriprole (B-21), pyflubumide (B-22), pyraziflumid (B-23), benzpyrimoxane (benzpyrimoxan) (B-24), and hydroxyquinoline copper (copper-8-quinolinolate) (B-25), or one or more compounds selected from salts thereof, were used in the target crops at the same time. , A method for controlling pests, which is characterized by being applied to the seeds, soil, and cultivation carrier of the target crop.
Regarding.

The pest control agent composition of the present invention has a remarkable synergistic effect as compared with the case where each compound is used alone, the number of target pest species is expanded, the amount of drug used is reduced, the number of drug treatments is reduced, and the usefulness thereof It has the effect of reducing the impact on plants and the environment, and provides new technology for efficiently controlling pests, weeds, and other pests that are difficult or impossible to control with conventional technology. Is.

In the present invention, the pest refers to weeds and pests in the field of agriculture and horticulture. Compounds (A-1) and (A-5), which are the first active ingredients of the present invention, are compounds represented by the following chemical formulas, and contain salts that are acceptable as pest control agents thereof.

The salt of the compound (A-1) and the salt (A-5) is not particularly limited as long as it is acceptable as a pest control agent, but due to its chemical structure, a hydrochloride, a sulfate, a nitrate, a formate, an acetate, and a bird. Inorganic or organic acids such as fluoroacetates, methanesulfonates, trifluoromethanesulfonates, p-toluenesulfonates are preferred. The compounds (A-1) and (A-5) are known compounds and can be produced by the production methods disclosed in Patent Documents 1 and 17.

The compound which is the second active ingredient of the present invention is isoprothiolane (B-1), basic copper sulfate (B-2), fluoroimide (B-3), flutranyl ( flutolanil (B-4), fenoxanil (B-5), tiadinil (B-6), buprofezin (B-7), isoprocarb (MIPC) (B-8), Fenobucarb (B-9), fenpyroximate (B-10), tebufenpyrad (B-11), tolfenpyrad (B-12), flubendiamide (B-13) , Metaflumizone (B-14), pyrifluquinazon (B-15), chlorphthalim (B-16), pyraflufen-ethyl (B-17), indanofan (B-18), isouron (B-19), orthosulfamuron (B-20), pyriprole (B-21), pyflubumide (B-22), pyraziflumid (Pyraziflumid) (B-23), benzpyrimoxan (B-24), and hydroxyquinolin copper (copper-8-quinolinolate) (B-25), which are acceptable as pest control agents. Contains salt. The salt of the second active ingredient is not particularly limited as long as it is acceptable as a pest control agent, but an acidic salt or a basic salt can be appropriately selected depending on its chemical structure. Acidic salts include inorganic or organic acids such as hydrochlorides, sulfates, nitrates, formates, acetates, trifluoroacetates, methanesulfonic acid salts, trifluoromethanesulfonates, p-toluenesulfonates. Examples of the basic salt include ammonium salt, amine salt, isopropylamine salt, potassium salt, calcium salt, sodium salt and the like.

These second active ingredients can be produced by purchasing commercially available agents or by known manufacturing methods. The relatively new active ingredient, pyriprol, is published in International Publication No. 2002/010153, and Piflubumid is published in International Publication No. 2007 /. Pyraziflumid can be produced in Pamphlet 020986, pyraziflumid can be produced in Pamphlet 2007/07299, and benzpyrimoxane can be produced by the method disclosed in Pamphlet 2013/115391.

Specific combinations of the pest control agent composition of the present invention include (A-1) + (B-1), (A-1) + (B-2), (A-1) + (B-). 3), (A-1) + (B-4), (A-1) + (B-5), (A-1) + (B-6), (A-1) + (B-7) , (A-1) + (B-8), (A-1) + (B-9), (A-1) + (B-10), (A-1) + (B-11), ( A-1) + (B-12), (A-1) + (B-13), (A-1) + (B-14), (A-1) + (B-15), (A- 1) + (B-16), (A-1) + (B-17), (A-1) + (B-18), (A-1) + (B-19), (A-1) ＋ (B-20), (A-1) ＋ (B-21), (A-1) ＋ (B-22), (A-1) ＋ (B-23), (A-1) ＋ ( B-24), (A-1) + (B-25),

(A-1) + (B-1) + (B-2), (A-1) + (B-1) + (B-3), (A-1) + (B-1) + (B) -4), (A-1) + (B-1) + (B-5), (A-1) + (B-1) + (B-6), (A-1) + (B-1) ) ＋ (B-7), (A-1) ＋ (B-1) ＋ (B-8), (A-1) ＋ (B-1) ＋ (B-9), (A-1) ＋ (B-1) + (B-10), (A-1) + (B-1) + (B-11), (A-1) + (B-1) + (B-12), (A -1) + (B-1) + (B-13), (A-1) + (B-1) + (B-14), (A-1) + (B-1) + (B-15) ), (A-1) + (B-1) + (B-16), (A-1) + (B-1) + (B-17), (A-1) + (B-1) + (B-18), (A-1) + (B-1) + (B-19), (A-1) + (B-1) + (B-20), (A-1) + (B) -1) + (B-21), (A-1) + (B-1) + (B-22), (A-1) + (B-1) + (B-23), (A-1) ) ＋ (B-1) ＋ (B-24), (A-1) ＋ (B-1) ＋ (B-25),

(A-1) + (B-2) + (B-3), (A-1) + (B-2) + (B-4), (A-1) + (B-2) + (B) -5), (A-1) + (B-2) + (B-6), (A-1) + (B-2) + (B-7), (A-1) + (B-2) ) ＋ (B-8), (A-1) ＋ (B-2) ＋ (B-9), (A-1) ＋ (B-2) ＋ (B-10), (A-1) ＋ (B-2) + (B-11), (A-1) + (B-2) + (B-12), (A-1) + (B-2) + (B-13), (A -1) + (B-2) + (B-14), (A-1) + (B-2) + (B-15), (A-1) + (B-2) + (B-16) ), (A-1) + (B-2) + (B-17), (A-1) + (B-2) + (B-18), (A-1) + (B-2) + (B-19), (A-1) + (B-2) + (B-20), (A-1) + (B-2) + (B-21), (A-1) + (B) -2) + (B-22), (A-1) + (B-2) + (B-23), (A-1) + (B-2) + (B-24), (A-1) ) ＋ (B-2) ＋ (B-25),

(A-1) ＋ (B-3) ＋ (B-4), (A-1) ＋ (B-3) ＋ (B-5), (A-1) ＋ (B-3) ＋ (B) -6), (A-1) + (B-3) + (B-7), (A-1) + (B-3) + (B-8), (A-1) + (B-3) ) ＋ (B-9), (A-1) ＋ (B-3) ＋ (B-10), (A-1) ＋ (B-3) ＋ (B-11), (A-1) ＋ (B-3) + (B-12), (A-1) + (B-3) + (B-13), (A-1) + (B-3) + (B-14), (A -1) ＋ (B-3) ＋ (B-15), (A-1) ＋ (B-3) ＋ (B-16), (A-1) ＋ (B-3) ＋ (B-17) ), (A-1) + (B-3) + (B-18), (A-1) + (B-3) + (B-19), (A-1) + (B-3) + (B-20), (A-1) + (B-3) + (B-21), (A-1) + (B-3) + (B-22), (A-1) + (B) -3) + (B-23), (A-1) + (B-3) + (B-24), (A-1) + (B-3) + (B-25),

(A-1) + (B-4) + (B-5), (A-1) + (B-4) + (B-6), (A-1) + (B-4) + (B) -7), (A-1) + (B-4) + (B-8), (A-1) + (B-4) + (B-9), (A-1) + (B-4) ) ＋ (B-10), (A-1) ＋ (B-4) ＋ (B-11), (A-1) ＋ (B-4) ＋ (B-12), (A-1) ＋ (B-4) + (B-13), (A-1) + (B-4) + (B-14), (A-1) + (B-4) + (B-15), (A -1) ＋ (B-4) ＋ (B-16), (A-1) ＋ (B-4) ＋ (B-17), (A-1) ＋ (B-4) ＋ (B-18) ), (A-1) + (B-4) + (B-19), (A-1) + (B-4) + (B-20), (A-1) + (B-4) + (B-21), (A-1) + (B-4) + (B-22), (A-1) + (B-4) + (B-23), (A-1) + (B) -4) + (B-24), (A-1) + (B-4) + (B-25),

(A-1) + (B-5) + (B-6), (A-1) + (B-5) + (B-7), (A-1) + (B-5) + (B) -8), (A-1) + (B-5) + (B-9), (A-1) + (B-5) + (B-10), (A-1) + (B-5) ) ＋ (B-11), (A-1) ＋ (B-5) ＋ (B-12), (A-1) ＋ (B-5) ＋ (B-13), (A-1) ＋ (B-5) + (B-14), (A-1) + (B-5) + (B-15), (A-1) + (B-5) + (B-16), (A -1) ＋ (B-5) ＋ (B-17), (A-1) ＋ (B-5) ＋ (B-18), (A-1) ＋ (B-5) ＋ (B-19) ), (A-1) + (B-5) + (B-20), (A-1) + (B-5) + (B-21), (A-1) + (B-5) + (B-22), (A-1) + (B-5) + (B-23), (A-1) + (B-5) + (B-24), (A-1) + (B) -5) + (B-25),

(A-1) ＋ (B-6) ＋ (B-7), (A-1) ＋ (B-6) ＋ (B-8), (A-1) ＋ (B-6) ＋ (B) -9), (A-1) + (B-6) + (B-10), (A-1) + (B-6) + (B-11), (A-1) + (B-6) ) ＋ (B-12), (A-1) ＋ (B-6) ＋ (B-13), (A-1) ＋ (B-6) ＋ (B-14), (A-1) ＋ (B-6) + (B-15), (A-1) + (B-6) + (B-16), (A-1) + (B-6) + (B-17), (A -1) ＋ (B-6) ＋ (B-18), (A-1) ＋ (B-6) ＋ (B-19), (A-1) ＋ (B-6) ＋ (B-20) ), (A-1) + (B-6) + (B-21), (A-1) + (B-6) + (B-22), (A-1) + (B-6) + (B-23), (A-1) + (B-6) + (B-24), (A-1) + (B-6) + (B-25),

(A-1) ＋ (B-7) ＋ (B-8), (A-1) ＋ (B-7) ＋ (B-9), (A-1) ＋ (B-7) ＋ (B) -10), (A-1) + (B-7) + (B-11), (A-1) + (B-7) + (B-12), (A-1) + (B-7) ) ＋ (B-13), (A-1) ＋ (B-7) ＋ (B-14), (A-1) ＋ (B-7) ＋ (B-15), (A-1) ＋ (B-7) + (B-16), (A-1) + (B-7) + (B-17), (A-1) + (B-7) + (B-18), (A -1) ＋ (B-7) ＋ (B-19), (A-1) ＋ (B-7) ＋ (B-20), (A-1) ＋ (B-7) ＋ (B-21) ), (A-1) ＋ (B-7) ＋ (B-22), (A-1) ＋ (B-7) ＋ (B-23), (A-1) ＋ (B-7) ＋ (B-24), (A-1) + (B-7) + (B-25),

(A-1) ＋ (B-8) ＋ (B-9), (A-1) ＋ (B-8) ＋ (B-10), (A-1) ＋ (B-8) ＋ (B) -11), (A-1) + (B-8) + (B-12), (A-1) + (B-8) + (B-13), (A-1) + (B-8) ) ＋ (B-14), (A-1) ＋ (B-8) ＋ (B-15), (A-1) ＋ (B-8) ＋ (B-16), (A-1) ＋ (B-8) + (B-17), (A-1) + (B-8) + (B-18), (A-1) + (B-8) + (B-19), (A -1) + (B-8) + (B-20), (A-1) + (B-8) + (B-21), (A-1) + (B-8) + (B-22) ), (A-1) + (B-8) + (B-23), (A-1) + (B-8) + (B-24), (A-1) + (B-8) + (B-25),

(A-1) ＋ (B-9) ＋ (B-10), (A-1) ＋ (B-9) ＋ (B-11), (A-1) ＋ (B-9) ＋ (B) -12), (A-1) + (B-9) + (B-13), (A-1) + (B-9) + (B-14), (A-1) + (B-9) ) ＋ (B-15), (A-1) ＋ (B-9) ＋ (B-16), (A-1) ＋ (B-9) ＋ (B-17), (A-1) ＋ (B-9) + (B-18), (A-1) + (B-9) + (B-19), (A-1) + (B-9) + (B-20), (A -1) ＋ (B-9) ＋ (B-21), (A-1) ＋ (B-9) ＋ (B-22), (A-1) ＋ (B-9) ＋ (B-23) ), (A-1) + (B-9) + (B-24), (A-1) + (B-9) + (B-25),

(A-1) + (B-10) + (B-11), (A-1) + (B-10) + (B-12), (A-1) + (B-10) + (B -13), (A-1) + (B-10) + (B-14), (A-1) + (B-10) + (B-15), (A-1) + (B-10) ) + (B-16), (A-1) + (B-10) + (B-17), (A-1) + (B-10) + (B-18), (A-1) + (B-10) + (B-19), (A-1) + (B-10) + (B-20), (A-1) + (B-10) + (B-21), (A -1) + (B-10) + (B-22), (A-1) + (B-10) + (B-23), (A-1) + (B-10) + (B-24) ), (A-1) ＋ (B-10) ＋ (B-25),

(A-1) + (B-11) + (B-12), (A-1) + (B-11) + (B-13), (A-1) + (B-11) + (B) -14), (A-1) + (B-11) + (B-15), (A-1) + (B-11) + (B-16), (A-1) + (B-11) ) + (B-17), (A-1) + (B-11) + (B-18), (A-1) + (B-11) + (B-19), (A-1) + (B-11) + (B-20), (A-1) + (B-11) + (B-21), (A-1) + (B-11) + (B-22), (A -1) + (B-11) + (B-23), (A-1) + (B-11) + (B-24), (A-1) + (B-11) + (B-25) ),

(A-1) + (B-12) + (B-13), (A-1) + (B-12) + (B-14), (A-1) + (B-12) + (B -15), (A-1) + (B-12) + (B-16), (A-1) + (B-12) + (B-17), (A-1) + (B-12) ) + (B-18), (A-1) + (B-12) + (B-19), (A-1) + (B-12) + (B-20), (A-1) + (B-12) + (B-21), (A-1) + (B-12) + (B-22), (A-1) + (B-12) + (B-23), (A -1) + (B-12) + (B-24), (A-1) + (B-12) + (B-25),

(A-1) + (B-13) + (B-14), (A-1) + (B-13) + (B-15), (A-1) + (B-13) + (B) -16), (A-1) + (B-13) + (B-17), (A-1) + (B-13) + (B-18), (A-1) + (B-13) ) + (B-19), (A-1) + (B-13) + (B-20), (A-1) + (B-13) + (B-21), (A-1) + (B-13) + (B-22), (A-1) + (B-13) + (B-23), (A-1) + (B-13) + (B-24), (A -1) + (B-13) + (B-25),

(A-1) + (B-14) + (B-15), (A-1) + (B-14) + (B-16), (A-1) + (B-14) + (B) -17), (A-1) + (B-14) + (B-18), (A-1) + (B-14) + (B-19), (A-1) + (B-14) ) + (B-20), (A-1) + (B-14) + (B-21), (A-1) + (B-14) + (B-22), (A-1) + (B-14) + (B-23), (A-1) + (B-14) + (B-24), (A-1) + (B-14) + (B-25),

(A-1) + (B-15) + (B-16), (A-1) + (B-15) + (B-17), (A-1) + (B-15) + (B) -18), (A-1) + (B-15) + (B-19), (A-1) + (B-15) + (B-20), (A-1) + (B-15) ) + (B-21), (A-1) + (B-15) + (B-22), (A-1) + (B-15) + (B-23), (A-1) + (B-15) + (B-24), (A-1) + (B-15) + (B-25),

(A-1) + (B-16) + (B-17), (A-1) + (B-16) + (B-18), (A-1) + (B-16) + (B -19), (A-1) + (B-16) + (B-20), (A-1) + (B-16) + (B-21), (A-1) + (B-16) ) + (B-22), (A-1) + (B-16) + (B-23), (A-1) + (B-16) + (B-24), (A-1) + (B-16) + (B-25),

(A-1) + (B-17) + (B-18), (A-1) + (B-17) + (B-19), (A-1) + (B-17) + (B) -20), (A-1) + (B-17) + (B-21), (A-1) + (B-17) + (B-22), (A-1) + (B-17) ) + (B-23), (A-1) + (B-17) + (B-24), (A-1) + (B-17) + (B-25),

(A-1) + (B-18) + (B-19), (A-1) + (B-18) + (B-20), (A-1) + (B-18) + (B -21), (A-1) + (B-18) + (B-22), (A-1) + (B-18) + (B-23), (A-1) + (B-18) ) + (B-24), (A-1) + (B-18) + (B-25),

(A-1) + (B-19) + (B-20), (A-1) + (B-19) + (B-21), (A-1) + (B-19) + (B) -22), (A-1) + (B-19) + (B-23), (A-1) + (B-19) + (B-24), (A-1) + (B-19) ) + (B-25),

(A-1) + (B-20) + (B-21), (A-1) + (B-20) + (B-22), (A-1) + (B-20) + (B) -23), (A-1) + (B-20) + (B-24), (A-1) + (B-20) + (B-25),

(A-1) + (B-21) + (B-22), (A-1) + (B-21) + (B-23), (A-1) + (B-21) + (B) -24), (A-1) + (B-21) + (B-25), (A-1) + (B-22) + (B-23), (A-1) + (B-22) ) + (B-24), (A-1) + (B-22) + (B-25), (A-1) + (B-23) + (B-24), (A-1) + (B-23) + (B-25), (A-1) + (B-24) + (B-25),

(A-2) + (B-1), (A-2) + (B-2), (A-2) + (B-3), (A-2) + (B-4), (A -2) + (B-5), (A-2) + (B-6), (A-2) + (B-7), (A-2) + (B-8), (A-2) ) ＋ (B-9), (A-2) ＋ (B-10), (A-2) ＋ (B-11), (A-2) ＋ (B-12), (A-2) ＋ (B-13), (A-2) + (B-14), (A-2) + (B-15), (A-2) + (B-16), (A-2) + (B) -17), (A-2) + (B-18), (A-2) + (B-19), (A-2) + (B-20), (A-2) + (B-21) ), (A-2) + (B-22), (A-2) + (B-23), (A-2) + (B-24), (A-2) + (B-25),

(A-2) + (B-1) + (B-2), (A-2) + (B-1) + (B-3), (A-2) + (B-1) + (B) -4), (A-2) + (B-1) + (B-5), (A-2) + (B-1) + (B-6), (A-2) + (B-1) ) ＋ (B-7), (A-2) ＋ (B-1) ＋ (B-8), (A-2) ＋ (B-1) ＋ (B-9), (A-2) ＋ (B-1) + (B-10), (A-2) + (B-1) + (B-11), (A-2) + (B-1) + (B-12), (A -2) ＋ (B-1) ＋ (B-13), (A-2) ＋ (B-1) ＋ (B-14), (A-2) ＋ (B-1) ＋ (B-15) ), (A-2) + (B-1) + (B-16), (A-2) + (B-1) + (B-17), (A-2) + (B-1) + (B-18), (A-2) + (B-1) + (B-19), (A-2) + (B-1) + (B-20), (A-2) + (B) -1) + (B-21), (A-2) + (B-1) + (B-22), (A-2) + (B-1) + (B-23), (A-2) ) ＋ (B-1) ＋ (B-24), (A-2) ＋ (B-1) ＋ (B-25),

(A-2) + (B-2) + (B-3), (A-2) + (B-2) + (B-4), (A-2) + (B-2) + (B) -5), (A-2) + (B-2) + (B-6), (A-2) + (B-2) + (B-7), (A-2) + (B-2) ) ＋ (B-8), (A-2) ＋ (B-2) ＋ (B-9), (A-2) ＋ (B-2) ＋ (B-10), (A-2) ＋ (B-2) + (B-11), (A-2) + (B-2) + (B-12), (A-2) + (B-2) + (B-13), (A -2) + (B-2) + (B-14), (A-2) + (B-2) + (B-15), (A-2) + (B-2) + (B-16) ), (A-2) + (B-2) + (B-17), (A-2) + (B-2) + (B-18), (A-2) + (B-2) + (B-19), (A-2) + (B-2) + (B-20), (A-2) + (B-2) + (B-21), (A-2) + (B) -2) + (B-22), (A-2) + (B-2) + (B-23), (A-2) + (B-2) + (B-24), (A-2) ) ＋ (B-2) ＋ (B-25),

(A-2) ＋ (B-3) ＋ (B-4), (A-2) ＋ (B-3) ＋ (B-5), (A-2) ＋ (B-3) ＋ (B) -6), (A-2) + (B-3) + (B-7), (A-2) + (B-3) + (B-8), (A-2) + (B-3) ) ＋ (B-9), (A-2) ＋ (B-3) ＋ (B-10), (A-2) ＋ (B-3) ＋ (B-11), (A-2) ＋ (B-3) + (B-12), (A-2) + (B-3) + (B-13), (A-2) + (B-3) + (B-14), (A -2) ＋ (B-3) ＋ (B-15), (A-2) ＋ (B-3) ＋ (B-16), (A-2) ＋ (B-3) ＋ (B-17) ), (A-2) + (B-3) + (B-18), (A-2) + (B-3) + (B-19), (A-2) + (B-3) + (B-20), (A-2) + (B-3) + (B-21), (A-2) + (B-3) + (B-22), (A-2) + (B) -3) + (B-23), (A-2) + (B-3) + (B-24), (A-2) + (B-3) + (B-25),

(A-2) ＋ (B-4) ＋ (B-5), (A-2) ＋ (B-4) ＋ (B-6), (A-2) ＋ (B-4) ＋ (B) -7), (A-2) + (B-4) + (B-8), (A-2) + (B-4) + (B-9), (A-2) + (B-4) ) ＋ (B-10), (A-2) ＋ (B-4) ＋ (B-11), (A-2) ＋ (B-4) ＋ (B-12), (A-2) ＋ (B-4) + (B-13), (A-2) + (B-4) + (B-14), (A-2) + (B-4) + (B-15), (A -2) ＋ (B-4) ＋ (B-16), (A-2) ＋ (B-4) ＋ (B-17), (A-2) ＋ (B-4) ＋ (B-18) ), (A-2) + (B-4) + (B-19), (A-2) + (B-4) + (B-20), (A-2) + (B-4) + (B-21), (A-2) + (B-4) + (B-22), (A-2) + (B-4) + (B-23), (A-2) + (B) -4) + (B-24), (A-2) + (B-4) + (B-25),

(A-2) + (B-5) + (B-6), (A-2) + (B-5) + (B-7), (A-2) + (B-5) + (B) -8), (A-2) + (B-5) + (B-9), (A-2) + (B-5) + (B-10), (A-2) + (B-5) ) ＋ (B-11), (A-2) ＋ (B-5) ＋ (B-12), (A-2) ＋ (B-5) ＋ (B-13), (A-2) ＋ (B-5) + (B-14), (A-2) + (B-5) + (B-15), (A-2) + (B-5) + (B-16), (A -2) ＋ (B-5) ＋ (B-17), (A-2) ＋ (B-5) ＋ (B-18), (A-2) ＋ (B-5) ＋ (B-19) ), (A-2) + (B-5) + (B-20), (A-2) + (B-5) + (B-21), (A-2) + (B-5) + (B-22), (A-2) + (B-5) + (B-23), (A-2) + (B-5) + (B-24), (A-2) + (B) -5) + (B-25),

(A-2) ＋ (B-6) ＋ (B-7), (A-2) ＋ (B-6) ＋ (B-8), (A-2) ＋ (B-6) ＋ (B) -9), (A-2) + (B-6) + (B-10), (A-2) + (B-6) + (B-11), (A-2) + (B-6) ) ＋ (B-12), (A-2) ＋ (B-6) ＋ (B-13), (A-2) ＋ (B-6) ＋ (B-14), (A-2) ＋ (B-6) ＋ (B-15), (A-2) ＋ (B-6) ＋ (B-16), (A-2) ＋ (B-6) ＋ (B-17), (A -2) + (B-6) + (B-18), (A-2) + (B-6) + (B-19), (A-2) + (B-6) + (B-20) ), (A-2) ＋ (B-6) ＋ (B-21), (A-2) ＋ (B-6) ＋ (B-22), (A-2) ＋ (B-6) ＋ (B-23), (A-2) + (B-6) + (B-24), (A-2) + (B-6) + (B-25),

(A-2) ＋ (B-7) ＋ (B-8), (A-2) ＋ (B-7) ＋ (B-9), (A-2) ＋ (B-7) ＋ (B) -10), (A-2) + (B-7) + (B-11), (A-2) + (B-7) + (B-12), (A-2) + (B-7) ) ＋ (B-13), (A-2) ＋ (B-7) ＋ (B-14), (A-2) ＋ (B-7) ＋ (B-15), (A-2) ＋ (B-7) + (B-16), (A-2) + (B-7) + (B-17), (A-2) + (B-7) + (B-18), (A -2) + (B-7) + (B-19), (A-2) + (B-7) + (B-20), (A-2) + (B-7) + (B-21) ), (A-2) + (B-7) + (B-22), (A-2) + (B-7) + (B-23), (A-2) + (B-7) + (B-24), (A-2) + (B-7) + (B-25),

(A-2) ＋ (B-8) ＋ (B-9), (A-2) ＋ (B-8) ＋ (B-10), (A-2) ＋ (B-8) ＋ (B) -11), (A-2) + (B-8) + (B-12), (A-2) + (B-8) + (B-13), (A-2) + (B-8) ) ＋ (B-14), (A-2) ＋ (B-8) ＋ (B-15), (A-2) ＋ (B-8) ＋ (B-16), (A-2) ＋ (B-8) + (B-17), (A-2) + (B-8) + (B-18), (A-2) + (B-8) + (B-19), (A -2) + (B-8) + (B-20), (A-2) + (B-8) + (B-21), (A-2) + (B-8) + (B-22) ), (A-2) + (B-8) + (B-23), (A-2) + (B-8) + (B-24), (A-2) + (B-8) + (B-25),

(A-2) ＋ (B-9) ＋ (B-10), (A-2) ＋ (B-9) ＋ (B-11), (A-2) ＋ (B-9) ＋ (B) -12), (A-2) + (B-9) + (B-13), (A-2) + (B-9) + (B-14), (A-2) + (B-9) ) ＋ (B-15), (A-2) ＋ (B-9) ＋ (B-16), (A-2) ＋ (B-9) ＋ (B-17), (A-2) ＋ (B-9) + (B-18), (A-2) + (B-9) + (B-19), (A-2) + (B-9) + (B-20), (A -2) ＋ (B-9) ＋ (B-21), (A-2) ＋ (B-9) ＋ (B-22), (A-2) ＋ (B-9) ＋ (B-23) ), (A-2) + (B-9) + (B-24), (A-2) + (B-9) + (B-25),

(A-2) + (B-10) + (B-11), (A-2) + (B-10) + (B-12), (A-2) + (B-10) + (B) -13), (A-2) + (B-10) + (B-14), (A-2) + (B-10) + (B-15), (A-2) + (B-10) ) + (B-16), (A-2) + (B-10) + (B-17), (A-2) + (B-10) + (B-18), (A-2) + (B-10) + (B-19), (A-2) + (B-10) + (B-20), (A-2) + (B-10) + (B-21), (A -2) + (B-10) + (B-22), (A-2) + (B-10) + (B-23), (A-2) + (B-10) + (B-24) ), (A-2) ＋ (B-10) ＋ (B-25),

(A-2) + (B-11) + (B-12), (A-2) + (B-11) + (B-13), (A-2) + (B-11) + (B) -14), (A-2) + (B-11) + (B-15), (A-2) + (B-11) + (B-16), (A-2) + (B-11) ) + (B-17), (A-2) + (B-11) + (B-18), (A-2) + (B-11) + (B-19), (A-2) + (B-11) + (B-20), (A-2) + (B-11) + (B-21), (A-2) + (B-11) + (B-22), (A -2) + (B-11) + (B-23), (A-2) + (B-11) + (B-24), (A-2) + (B-11) + (B-25) ),

(A-2) + (B-12) + (B-13), (A-2) + (B-12) + (B-14), (A-2) + (B-12) + (B) -15), (A-2) + (B-12) + (B-16), (A-2) + (B-12) + (B-17), (A-2) + (B-12) ) + (B-18), (A-2) + (B-12) + (B-19), (A-2) + (B-12) + (B-20), (A-2) + (B-12) + (B-21), (A-2) + (B-12) + (B-22), (A-2) + (B-12) + (B-23), (A -2) + (B-12) + (B-24), (A-2) + (B-12) + (B-25),

(A-2) + (B-13) + (B-14), (A-2) + (B-13) + (B-15), (A-2) + (B-13) + (B) -16), (A-2) + (B-13) + (B-17), (A-2) + (B-13) + (B-18), (A-2) + (B-13) ) + (B-19), (A-2) + (B-13) + (B-20), (A-2) + (B-13) + (B-21), (A-2) + (B-13) + (B-22), (A-2) + (B-13) + (B-23), (A-2) + (B-13) + (B-24), (A -2) + (B-13) + (B-25),

(A-2) + (B-14) + (B-15), (A-2) + (B-14) + (B-16), (A-2) + (B-14) + (B) -17), (A-2) + (B-14) + (B-18), (A-2) + (B-14) + (B-19), (A-2) + (B-14) ) + (B-20), (A-2) + (B-14) + (B-21), (A-2) + (B-14) + (B-22), (A-2) + (B-14) + (B-23), (A-2) + (B-14) + (B-24), (A-2) + (B-14) + (B-25),

(A-2) + (B-15) + (B-16), (A-2) + (B-15) + (B-17), (A-2) + (B-15) + (B) -18), (A-2) + (B-15) + (B-19), (A-2) + (B-15) + (B-20), (A-2) + (B-15) ) + (B-21), (A-2) + (B-15) + (B-22), (A-2) + (B-15) + (B-23), (A-2) + (B-15) + (B-24), (A-2) + (B-15) + (B-25),

(A-2) + (B-16) + (B-17), (A-2) + (B-16) + (B-18), (A-2) + (B-16) + (B) -19), (A-2) + (B-16) + (B-20), (A-2) + (B-16) + (B-21), (A-2) + (B-16) ) + (B-22), (A-2) + (B-16) + (B-23), (A-2) + (B-16) + (B-24), (A-2) + (B-16) + (B-25),

(A-2) + (B-17) + (B-18), (A-2) + (B-17) + (B-19), (A-2) + (B-17) + (B) -20), (A-2) + (B-17) + (B-21), (A-2) + (B-17) + (B-22), (A-2) + (B-17) ) + (B-23), (A-2) + (B-17) + (B-24), (A-2) + (B-17) + (B-25),

(A-2) + (B-18) + (B-19), (A-2) + (B-18) + (B-20), (A-2) + (B-18) + (B) -21), (A-2) + (B-18) + (B-22), (A-2) + (B-18) + (B-23), (A-2) + (B-18) ) + (B-24), (A-2) + (B-18) + (B-25),

(A-2) + (B-19) + (B-20), (A-2) + (B-19) + (B-21), (A-2) + (B-19) + (B) -22), (A-2) + (B-19) + (B-23), (A-2) + (B-19) + (B-24), (A-2) + (B-19) ) + (B-25),

(A-2) + (B-20) + (B-21), (A-2) + (B-20) + (B-22), (A-2) + (B-20) + (B) -23), (A-2) + (B-20) + (B-24), (A-2) + (B-20) + (B-25),

(A-2) + (B-21) + (B-22), (A-2) + (B-21) + (B-23), (A-2) + (B-21) + (B) -24), (A-2) + (B-21) + (B-25), (A-2) + (B-22) + (B-23), (A-2) + (B-22) ) + (B-24), (A-2) + (B-22) + (B-25), (A-2) + (B-23) + (B-24), (A-2) + (B-23) + (B-25), (A-2) + (B-24) + (B-25),

(A-3) + (B-1), (A-3) + (B-2), (A-3) + (B-3), (A-3) + (B-4), (A -3) + (B-5), (A-3) + (B-6), (A-3) + (B-7), (A-3) + (B-8), (A-3) ) ＋ (B-9), (A-3) ＋ (B-10), (A-3) ＋ (B-11), (A-3) ＋ (B-12), (A-3) ＋ (B-13), (A-3) + (B-14), (A-3) + (B-15), (A-3) + (B-16), (A-3) + (B) -17), (A-3) + (B-18), (A-3) + (B-19), (A-3) + (B-20), (A-3) + (B-21) ), (A-3) + (B-22), (A-3) + (B-23), (A-3) + (B-24), (A-3) + (B-25),

(A-3) + (B-1) + (B-2), (A-3) + (B-1) + (B-3), (A-3) + (B-1) + (B) -4), (A-3) + (B-1) + (B-5), (A-3) + (B-1) + (B-6), (A-3) + (B-1) ) ＋ (B-7), (A-3) ＋ (B-1) ＋ (B-8), (A-3) ＋ (B-1) ＋ (B-9), (A-3) ＋ (B-1) + (B-10), (A-3) + (B-1) + (B-11), (A-3) + (B-1) + (B-12), (A -3) + (B-1) + (B-13), (A-3) + (B-1) + (B-14), (A-3) + (B-1) + (B-15) ), (A-3) + (B-1) + (B-16), (A-3) + (B-1) + (B-17), (A-3) + (B-1) + (B-18), (A-3) + (B-1) + (B-19), (A-3) + (B-1) + (B-20), (A-3) + (B) -1) + (B-21), (A-3) + (B-1) + (B-22), (A-3) + (B-1) + (B-23), (A-3) ) ＋ (B-1) ＋ (B-24), (A-3) ＋ (B-1) ＋ (B-25),

(A-3) + (B-2) + (B-3), (A-3) + (B-2) + (B-4), (A-3) + (B-2) + (B) -5), (A-3) + (B-2) + (B-6), (A-3) + (B-2) + (B-7), (A-3) + (B-2) ) ＋ (B-8), (A-3) ＋ (B-2) ＋ (B-9), (A-3) ＋ (B-2) ＋ (B-10), (A-3) ＋ (B-2) + (B-11), (A-3) + (B-2) + (B-12), (A-3) + (B-2) + (B-13), (A -3) ＋ (B-2) ＋ (B-14), (A-3) ＋ (B-2) ＋ (B-15), (A-3) ＋ (B-2) ＋ (B-16) ), (A-3) + (B-2) + (B-17), (A-3) + (B-2) + (B-18), (A-3) + (B-2) + (B-19), (A-3) + (B-2) + (B-20), (A-3) + (B-2) + (B-21), (A-3) + (B) -2) + (B-22), (A-3) + (B-2) + (B-23), (A-3) + (B-2) + (B-24), (A-3) ) ＋ (B-2) ＋ (B-25),

(A-3) ＋ (B-3) ＋ (B-4), (A-3) ＋ (B-3) ＋ (B-5), (A-3) ＋ (B-3) ＋ (B) -6), (A-3) + (B-3) + (B-7), (A-3) + (B-3) + (B-8), (A-3) + (B-3) ) ＋ (B-9), (A-3) ＋ (B-3) ＋ (B-10), (A-3) ＋ (B-3) ＋ (B-11), (A-3) ＋ (B-3) + (B-12), (A-3) + (B-3) + (B-13), (A-3) + (B-3) + (B-14), (A -3) ＋ (B-3) ＋ (B-15), (A-3) ＋ (B-3) ＋ (B-16), (A-3) ＋ (B-3) ＋ (B-17) ), (A-3) + (B-3) + (B-18), (A-3) + (B-3) + (B-19), (A-3) + (B-3) + (B-20), (A-3) + (B-3) + (B-21), (A-3) + (B-3) + (B-22), (A-3) + (B) -3) + (B-23), (A-3) + (B-3) + (B-24), (A-3) + (B-3) + (B-25),

(A-3) ＋ (B-4) ＋ (B-5), (A-3) ＋ (B-4) ＋ (B-6), (A-3) ＋ (B-4) ＋ (B) -7), (A-3) + (B-4) + (B-8), (A-3) + (B-4) + (B-9), (A-3) + (B-4) ) ＋ (B-10), (A-3) ＋ (B-4) ＋ (B-11), (A-3) ＋ (B-4) ＋ (B-12), (A-3) ＋ (B-4) + (B-13), (A-3) + (B-4) + (B-14), (A-3) + (B-4) + (B-15), (A -3) ＋ (B-4) ＋ (B-16), (A-3) ＋ (B-4) ＋ (B-17), (A-3) ＋ (B-4) ＋ (B-18) ), (A-3) + (B-4) + (B-19), (A-3) + (B-4) + (B-20), (A-3) + (B-4) + (B-21), (A-3) + (B-4) + (B-22), (A-3) + (B-4) + (B-23), (A-3) + (B) -4) + (B-24), (A-3) + (B-4) + (B-25),

(A-3) ＋ (B-5) ＋ (B-6), (A-3) ＋ (B-5) ＋ (B-7), (A-3) ＋ (B-5) ＋ (B) -8), (A-3) + (B-5) + (B-9), (A-3) + (B-5) + (B-10), (A-3) + (B-5) ) ＋ (B-11), (A-3) ＋ (B-5) ＋ (B-12), (A-3) ＋ (B-5) ＋ (B-13), (A-3) ＋ (B-5) + (B-14), (A-3) + (B-5) + (B-15), (A-3) + (B-5) + (B-16), (A -3) ＋ (B-5) ＋ (B-17), (A-3) ＋ (B-5) ＋ (B-18), (A-3) ＋ (B-5) ＋ (B-19) ), (A-3) + (B-5) + (B-20), (A-3) + (B-5) + (B-21), (A-3) + (B-5) + (B-22), (A-3) + (B-5) + (B-23), (A-3) + (B-5) + (B-24), (A-3) + (B) -5) + (B-25),

(A-3) ＋ (B-6) ＋ (B-7), (A-3) ＋ (B-6) ＋ (B-8), (A-3) ＋ (B-6) ＋ (B) -9), (A-3) + (B-6) + (B-10), (A-3) + (B-6) + (B-11), (A-3) + (B-6) ) ＋ (B-12), (A-3) ＋ (B-6) ＋ (B-13), (A-3) ＋ (B-6) ＋ (B-14), (A-3) ＋ (B-6) + (B-15), (A-3) + (B-6) + (B-16), (A-3) + (B-6) + (B-17), (A -3) ＋ (B-6) ＋ (B-18), (A-3) ＋ (B-6) ＋ (B-19), (A-3) ＋ (B-6) ＋ (B-20) ), (A-3) + (B-6) + (B-21), (A-3) + (B-6) + (B-22), (A-3) + (B-6) + (B-23), (A-3) + (B-6) + (B-24), (A-3) + (B-6) + (B-25),

(A-3) ＋ (B-7) ＋ (B-8), (A-3) ＋ (B-7) ＋ (B-9), (A-3) ＋ (B-7) ＋ (B) -10), (A-3) + (B-7) + (B-11), (A-3) + (B-7) + (B-12), (A-3) + (B-7) ) ＋ (B-13), (A-3) ＋ (B-7) ＋ (B-14), (A-3) ＋ (B-7) ＋ (B-15), (A-3) ＋ (B-7) + (B-16), (A-3) + (B-7) + (B-17), (A-3) + (B-7) + (B-18), (A -3) ＋ (B-7) ＋ (B-19), (A-3) ＋ (B-7) ＋ (B-20), (A-3) ＋ (B-7) ＋ (B-21) ), (A-3) + (B-7) + (B-22), (A-3) + (B-7) + (B-23), (A-3) + (B-7) + (B-24), (A-3) + (B-7) + (B-25),

(A-3) ＋ (B-8) ＋ (B-9), (A-3) ＋ (B-8) ＋ (B-10), (A-3) ＋ (B-8) ＋ (B) -11), (A-3) + (B-8) + (B-12), (A-3) + (B-8) + (B-13), (A-3) + (B-8) ) ＋ (B-14), (A-3) ＋ (B-8) ＋ (B-15), (A-3) ＋ (B-8) ＋ (B-16), (A-3) ＋ (B-8) + (B-17), (A-3) + (B-8) + (B-18), (A-3) + (B-8) + (B-19), (A -3) ＋ (B-8) ＋ (B-20), (A-3) ＋ (B-8) ＋ (B-21), (A-3) ＋ (B-8) ＋ (B-22) ), (A-3) + (B-8) + (B-23), (A-3) + (B-8) + (B-24), (A-3) + (B-8) + (B-25),

(A-3) + (B-9) + (B-10), (A-3) + (B-9) + (B-11), (A-3) + (B-9) + (B) -12), (A-3) + (B-9) + (B-13), (A-3) + (B-9) + (B-14), (A-3) + (B-9) ) ＋ (B-15), (A-3) ＋ (B-9) ＋ (B-16), (A-3) ＋ (B-9) ＋ (B-17), (A-3) ＋ (B-9) + (B-18), (A-3) + (B-9) + (B-19), (A-3) + (B-9) + (B-20), (A -3) ＋ (B-9) ＋ (B-21), (A-3) ＋ (B-9) ＋ (B-22), (A-3) ＋ (B-9) ＋ (B-23) ), (A-3) + (B-9) + (B-24), (A-3) + (B-9) + (B-25),

(A-3) + (B-10) + (B-11), (A-3) + (B-10) + (B-12), (A-3) + (B-10) + (B -13), (A-3) + (B-10) + (B-14), (A-3) + (B-10) + (B-15), (A-3) + (B-10) ) + (B-16), (A-3) + (B-10) + (B-17), (A-3) + (B-10) + (B-18), (A-3) + (B-10) + (B-19), (A-3) + (B-10) + (B-20), (A-3) + (B-10) + (B-21), (A -3) + (B-10) + (B-22), (A-3) + (B-10) + (B-23), (A-3) + (B-10) + (B-24) ), (A-3) ＋ (B-10) ＋ (B-25),

(A-3) + (B-11) + (B-12), (A-3) + (B-11) + (B-13), (A-3) + (B-11) + (B) -14), (A-3) + (B-11) + (B-15), (A-3) + (B-11) + (B-16), (A-3) + (B-11) ) + (B-17), (A-3) + (B-11) + (B-18), (A-3) + (B-11) + (B-19), (A-3) + (B-11) + (B-20), (A-3) + (B-11) + (B-21), (A-3) + (B-11) + (B-22), (A -3) + (B-11) + (B-23), (A-3) + (B-11) + (B-24), (A-3) + (B-11) + (B-25) ),

(A-3) + (B-12) + (B-13), (A-3) + (B-12) + (B-14), (A-3) + (B-12) + (B) -15), (A-3) + (B-12) + (B-16), (A-3) + (B-12) + (B-17), (A-3) + (B-12) ) + (B-18), (A-3) + (B-12) + (B-19), (A-3) + (B-12) + (B-20), (A-3) + (B-12) + (B-21), (A-3) + (B-12) + (B-22), (A-3) + (B-12) + (B-23), (A -3) + (B-12) + (B-24), (A-3) + (B-12) + (B-25),

(A-3) + (B-13) + (B-14), (A-3) + (B-13) + (B-15), (A-3) + (B-13) + (B) -16), (A-3) + (B-13) + (B-17), (A-3) + (B-13) + (B-18), (A-3) + (B-13) ) + (B-19), (A-3) + (B-13) + (B-20), (A-3) + (B-13) + (B-21), (A-3) + (B-13) + (B-22), (A-3) + (B-13) + (B-23), (A-3) + (B-13) + (B-24), (A -3) + (B-13) + (B-25),

(A-3) + (B-14) + (B-15), (A-3) + (B-14) + (B-16), (A-3) + (B-14) + (B) -17), (A-3) + (B-14) + (B-18), (A-3) + (B-14) + (B-19), (A-3) + (B-14) ) + (B-20), (A-3) + (B-14) + (B-21), (A-3) + (B-14) + (B-22), (A-3) + (B-14) + (B-23), (A-3) + (B-14) + (B-24), (A-3) + (B-14) + (B-25),

(A-3) + (B-15) + (B-16), (A-3) + (B-15) + (B-17), (A-3) + (B-15) + (B) -18), (A-3) + (B-15) + (B-19), (A-3) + (B-15) + (B-20), (A-3) + (B-15) ) + (B-21), (A-3) + (B-15) + (B-22), (A-3) + (B-15) + (B-23), (A-3) + (B-15) + (B-24), (A-3) + (B-15) + (B-25),

(A-3) + (B-16) + (B-17), (A-3) + (B-16) + (B-18), (A-3) + (B-16) + (B) -19), (A-3) + (B-16) + (B-20), (A-3) + (B-16) + (B-21), (A-3) + (B-16) ) + (B-22), (A-3) + (B-16) + (B-23), (A-3) + (B-16) + (B-24), (A-3) + (B-16) + (B-25),

(A-3) + (B-17) + (B-18), (A-3) + (B-17) + (B-19), (A-3) + (B-17) + (B) -20), (A-3) + (B-17) + (B-21), (A-3) + (B-17) + (B-22), (A-3) + (B-17) ) + (B-23), (A-3) + (B-17) + (B-24), (A-3) + (B-17) + (B-25),

(A-3) + (B-18) + (B-19), (A-3) + (B-18) + (B-20), (A-3) + (B-18) + (B) -21), (A-3) + (B-18) + (B-22), (A-3) + (B-18) + (B-23), (A-3) + (B-18) ) + (B-24), (A-3) + (B-18) + (B-25),

(A-3) + (B-19) + (B-20), (A-3) + (B-19) + (B-21), (A-3) + (B-19) + (B) -22), (A-3) + (B-19) + (B-23), (A-3) + (B-19) + (B-24), (A-3) + (B-19) ) + (B-25),

(A-3) + (B-20) + (B-21), (A-3) + (B-20) + (B-22), (A-3) + (B-20) + (B) -23), (A-3) + (B-20) + (B-24), (A-3) + (B-20) + (B-25),

(A-3) + (B-21) + (B-22), (A-3) + (B-21) + (B-23), (A-3) + (B-21) + (B) -24), (A-3) + (B-21) + (B-25), (A-3) + (B-22) + (B-23), (A-3) + (B-22) ) + (B-24), (A-3) + (B-22) + (B-25), (A-3) + (B-23) + (B-24), (A-3) + (B-23) + (B-25), (A-3) + (B-24) + (B-25),

(A-4) + (B-1), (A-4) + (B-2), (A-4) + (B-3), (A-4) + (B-4), (A -4) ＋ (B-5), (A-4) ＋ (B-6), (A-4) ＋ (B-7), (A-4) ＋ (B-8), (A-4) ) ＋ (B-9), (A-4) ＋ (B-10), (A-4) ＋ (B-11), (A-4) ＋ (B-12), (A-4) ＋ (B-13), (A-4) + (B-14), (A-4) + (B-15), (A-4) + (B-16), (A-4) + (B) -17), (A-4) + (B-18), (A-4) + (B-19), (A-4) + (B-20), (A-4) + (B-21) ), (A-4) + (B-22), (A-4) + (B-23), (A-4) + (B-24), (A-4) + (B-25),

(A-4) + (B-1) + (B-2), (A-4) + (B-1) + (B-3), (A-4) + (B-1) + (B) -4), (A-4) + (B-1) + (B-5), (A-4) + (B-1) + (B-6), (A-4) + (B-1) ) ＋ (B-7), (A-4) ＋ (B-1) ＋ (B-8), (A-4) ＋ (B-1) ＋ (B-9), (A-4) ＋ (B-1) + (B-10), (A-4) + (B-1) + (B-11), (A-4) + (B-1) + (B-12), (A -4) ＋ (B-1) ＋ (B-13), (A-4) ＋ (B-1) ＋ (B-14), (A-4) ＋ (B-1) ＋ (B-15) ), (A-4) + (B-1) + (B-16), (A-4) + (B-1) + (B-17), (A-4) + (B-1) + (B-18), (A-4) + (B-1) + (B-19), (A-4) + (B-1) + (B-20), (A-4) + (B) -1) + (B-21), (A-4) + (B-1) + (B-22), (A-4) + (B-1) + (B-23), (A-4) ) ＋ (B-1) ＋ (B-24), (A-4) ＋ (B-1) ＋ (B-25),

(A-4) + (B-2) + (B-3), (A-4) + (B-2) + (B-4), (A-4) + (B-2) + (B) -5), (A-4) + (B-2) + (B-6), (A-4) + (B-2) + (B-7), (A-4) + (B-2) ) ＋ (B-8), (A-4) ＋ (B-2) ＋ (B-9), (A-4) ＋ (B-2) ＋ (B-10), (A-4) ＋ (B-2) + (B-11), (A-4) + (B-2) + (B-12), (A-4) + (B-2) + (B-13), (A -4) ＋ (B-2) ＋ (B-14), (A-4) ＋ (B-2) ＋ (B-15), (A-4) ＋ (B-2) ＋ (B-16) ), (A-4) + (B-2) + (B-17), (A-4) + (B-2) + (B-18), (A-4) + (B-2) + (B-19), (A-4) + (B-2) + (B-20), (A-4) + (B-2) + (B-21), (A-4) + (B) -2) + (B-22), (A-4) + (B-2) + (B-23), (A-4) + (B-2) + (B-24), (A-4) ) ＋ (B-2) ＋ (B-25),

(A-4) ＋ (B-3) ＋ (B-4), (A-4) ＋ (B-3) ＋ (B-5), (A-4) ＋ (B-3) ＋ (B) -6), (A-4) + (B-3) + (B-7), (A-4) + (B-3) + (B-8), (A-4) + (B-3) ) ＋ (B-9), (A-4) ＋ (B-3) ＋ (B-10), (A-4) ＋ (B-3) ＋ (B-11), (A-4) ＋ (B-3) + (B-12), (A-4) + (B-3) + (B-13), (A-4) + (B-3) + (B-14), (A -4) ＋ (B-3) ＋ (B-15), (A-4) ＋ (B-3) ＋ (B-16), (A-4) ＋ (B-3) ＋ (B-17) ), (A-4) ＋ (B-3) ＋ (B-18), (A-4) ＋ (B-3) ＋ (B-19), (A-4) ＋ (B-3) ＋ (B-20), (A-4) + (B-3) + (B-21), (A-4) + (B-3) + (B-22), (A-4) + (B) -3) ＋ (B-23), (A-4) ＋ (B-3) ＋ (B-24), (A-4) ＋ (B-3) ＋ (B-25),

(A-4) ＋ (B-4) ＋ (B-5), (A-4) ＋ (B-4) ＋ (B-6), (A-4) ＋ (B-4) ＋ (B) -7), (A-4) + (B-4) + (B-8), (A-4) + (B-4) + (B-9), (A-4) + (B-4) ) ＋ (B-10), (A-4) ＋ (B-4) ＋ (B-11), (A-4) ＋ (B-4) ＋ (B-12), (A-4) ＋ (B-4) + (B-13), (A-4) + (B-4) + (B-14), (A-4) + (B-4) + (B-15), (A -4) ＋ (B-4) ＋ (B-16), (A-4) ＋ (B-4) ＋ (B-17), (A-4) ＋ (B-4) ＋ (B-18) ), (A-4) ＋ (B-4) ＋ (B-19), (A-4) ＋ (B-4) ＋ (B-20), (A-4) ＋ (B-4) ＋ (B-21), (A-4) + (B-4) + (B-22), (A-4) + (B-4) + (B-23), (A-4) + (B) -4) + (B-24), (A-4) + (B-4) + (B-25),

(A-4) ＋ (B-5) ＋ (B-6), (A-4) ＋ (B-5) ＋ (B-7), (A-4) ＋ (B-5) ＋ (B) -8), (A-4) + (B-5) + (B-9), (A-4) + (B-5) + (B-10), (A-4) + (B-5) ) ＋ (B-11), (A-4) ＋ (B-5) ＋ (B-12), (A-4) ＋ (B-5) ＋ (B-13), (A-4) ＋ (B-5) ＋ (B-14), (A-4) ＋ (B-5) ＋ (B-15), (A-4) ＋ (B-5) ＋ (B-16), (A -4) ＋ (B-5) ＋ (B-17), (A-4) ＋ (B-5) ＋ (B-18), (A-4) ＋ (B-5) ＋ (B-19) ), (A-4) + (B-5) + (B-20), (A-4) + (B-5) + (B-21), (A-4) + (B-5) + (B-22), (A-4) + (B-5) + (B-23), (A-4) + (B-5) + (B-24), (A-4) + (B) -5) + (B-25),

(A-4) ＋ (B-6) ＋ (B-7), (A-4) ＋ (B-6) ＋ (B-8), (A-4) ＋ (B-6) ＋ (B) -9), (A-4) ＋ (B-6) ＋ (B-10), (A-4) ＋ (B-6) ＋ (B-11), (A-4) ＋ (B-6) ) ＋ (B-12), (A-4) ＋ (B-6) ＋ (B-13), (A-4) ＋ (B-6) ＋ (B-14), (A-4) ＋ (B-6) + (B-15), (A-4) + (B-6) + (B-16), (A-4) + (B-6) + (B-17), (A -4) ＋ (B-6) ＋ (B-18), (A-4) ＋ (B-6) ＋ (B-19), (A-4) ＋ (B-6) ＋ (B-20) ), (A-4) ＋ (B-6) ＋ (B-21), (A-4) ＋ (B-6) ＋ (B-22), (A-4) ＋ (B-6) ＋ (B-23), (A-4) + (B-6) + (B-24), (A-4) + (B-6) + (B-25),

(A-4) ＋ (B-7) ＋ (B-8), (A-4) ＋ (B-7) ＋ (B-9), (A-4) ＋ (B-7) ＋ (B) -10), (A-4) + (B-7) + (B-11), (A-4) + (B-7) + (B-12), (A-4) + (B-7) ) ＋ (B-13), (A-4) ＋ (B-7) ＋ (B-14), (A-4) ＋ (B-7) ＋ (B-15), (A-4) ＋ (B-7) + (B-16), (A-4) + (B-7) + (B-17), (A-4) + (B-7) + (B-18), (A -4) ＋ (B-7) ＋ (B-19), (A-4) ＋ (B-7) ＋ (B-20), (A-4) ＋ (B-7) ＋ (B-21) ), (A-4) ＋ (B-7) ＋ (B-22), (A-4) ＋ (B-7) ＋ (B-23), (A-4) ＋ (B-7) ＋ (B-24), (A-4) + (B-7) + (B-25),

(A-4) ＋ (B-8) ＋ (B-9), (A-4) ＋ (B-8) ＋ (B-10), (A-4) ＋ (B-8) ＋ (B) -11), (A-4) + (B-8) + (B-12), (A-4) + (B-8) + (B-13), (A-4) + (B-8) ) ＋ (B-14), (A-4) ＋ (B-8) ＋ (B-15), (A-4) ＋ (B-8) ＋ (B-16), (A-4) ＋ (B-8) + (B-17), (A-4) + (B-8) + (B-18), (A-4) + (B-8) + (B-19), (A -4) ＋ (B-8) ＋ (B-20), (A-4) ＋ (B-8) ＋ (B-21), (A-4) ＋ (B-8) ＋ (B-22) ), (A-4) + (B-8) + (B-23), (A-4) + (B-8) + (B-24), (A-4) + (B-8) + (B-25),

(A-4) ＋ (B-9) ＋ (B-10), (A-4) ＋ (B-9) ＋ (B-11), (A-4) ＋ (B-9) ＋ (B) -12), (A-4) + (B-9) + (B-13), (A-4) + (B-9) + (B-14), (A-4) + (B-9) ) ＋ (B-15), (A-4) ＋ (B-9) ＋ (B-16), (A-4) ＋ (B-9) ＋ (B-17), (A-4) ＋ (B-9) ＋ (B-18), (A-4) ＋ (B-9) ＋ (B-19), (A-4) ＋ (B-9) ＋ (B-20), (A -4) ＋ (B-9) ＋ (B-21), (A-4) ＋ (B-9) ＋ (B-22), (A-4) ＋ (B-9) ＋ (B-23) ), (A-4) + (B-9) + (B-24), (A-4) + (B-9) + (B-25),

(A-4) + (B-10) + (B-11), (A-4) + (B-10) + (B-12), (A-4) + (B-10) + (B -13), (A-4) + (B-10) + (B-14), (A-4) + (B-10) + (B-15), (A-4) + (B-10) ) + (B-16), (A-4) + (B-10) + (B-17), (A-4) + (B-10) + (B-18), (A-4) + (B-10) + (B-19), (A-4) + (B-10) + (B-20), (A-4) + (B-10) + (B-21), (A -4) + (B-10) + (B-22), (A-4) + (B-10) + (B-23), (A-4) + (B-10) + (B-24) ), (A-4) ＋ (B-10) ＋ (B-25),

(A-4) + (B-11) + (B-12), (A-4) + (B-11) + (B-13), (A-4) + (B-11) + (B) -14), (A-4) + (B-11) + (B-15), (A-4) + (B-11) + (B-16), (A-4) + (B-11) ) + (B-17), (A-4) + (B-11) + (B-18), (A-4) + (B-11) + (B-19), (A-4) + (B-11) + (B-20), (A-4) + (B-11) + (B-21), (A-4) + (B-11) + (B-22), (A -4) + (B-11) + (B-23), (A-4) + (B-11) + (B-24), (A-4) + (B-11) + (B-25) ),

(A-4) + (B-12) + (B-13), (A-4) + (B-12) + (B-14), (A-4) + (B-12) + (B) -15), (A-4) + (B-12) + (B-16), (A-4) + (B-12) + (B-17), (A-4) + (B-12) ) + (B-18), (A-4) + (B-12) + (B-19), (A-4) + (B-12) + (B-20), (A-4) + (B-12) + (B-21), (A-4) + (B-12) + (B-22), (A-4) + (B-12) + (B-23), (A -4) + (B-12) + (B-24), (A-4) + (B-12) + (B-25),

(A-4) + (B-13) + (B-14), (A-4) + (B-13) + (B-15), (A-4) + (B-13) + (B) -16), (A-4) + (B-13) + (B-17), (A-4) + (B-13) + (B-18), (A-4) + (B-13) ) + (B-19), (A-4) + (B-13) + (B-20), (A-4) + (B-13) + (B-21), (A-4) + (B-13) + (B-22), (A-4) + (B-13) + (B-23), (A-4) + (B-13) + (B-24), (A -4) + (B-13) + (B-25),

(A-4) + (B-14) + (B-15), (A-4) + (B-14) + (B-16), (A-4) + (B-14) + (B) -17), (A-4) + (B-14) + (B-18), (A-4) + (B-14) + (B-19), (A-4) + (B-14) ) + (B-20), (A-4) + (B-14) + (B-21), (A-4) + (B-14) + (B-22), (A-4) + (B-14) + (B-23), (A-4) + (B-14) + (B-24), (A-4) + (B-14) + (B-25),

(A-4) + (B-15) + (B-16), (A-4) + (B-15) + (B-17), (A-4) + (B-15) + (B) -18), (A-4) + (B-15) + (B-19), (A-4) + (B-15) + (B-20), (A-4) + (B-15) ) + (B-21), (A-4) + (B-15) + (B-22), (A-4) + (B-15) + (B-23), (A-4) + (B-15) + (B-24), (A-4) + (B-15) + (B-25),

(A-4) + (B-16) + (B-17), (A-4) + (B-16) + (B-18), (A-4) + (B-16) + (B) -19), (A-4) + (B-16) + (B-20), (A-4) + (B-16) + (B-21), (A-4) + (B-16) ) + (B-22), (A-4) + (B-16) + (B-23), (A-4) + (B-16) + (B-24), (A-4) + (B-16) + (B-25),

(A-4) + (B-17) + (B-18), (A-4) + (B-17) + (B-19), (A-4) + (B-17) + (B) -20), (A-4) + (B-17) + (B-21), (A-4) + (B-17) + (B-22), (A-4) + (B-17) ) + (B-23), (A-4) + (B-17) + (B-24), (A-4) + (B-17) + (B-25),

(A-4) + (B-18) + (B-19), (A-4) + (B-18) + (B-20), (A-4) + (B-18) + (B) -21), (A-4) + (B-18) + (B-22), (A-4) + (B-18) + (B-23), (A-4) + (B-18) ) + (B-24), (A-4) + (B-18) + (B-25),

(A-4) + (B-19) + (B-20), (A-4) + (B-19) + (B-21), (A-4) + (B-19) + (B) -22), (A-4) + (B-19) + (B-23), (A-4) + (B-19) + (B-24), (A-4) + (B-19) ) + (B-25),

(A-4) + (B-20) + (B-21), (A-4) + (B-20) + (B-22), (A-4) + (B-20) + (B) -23), (A-4) + (B-20) + (B-24), (A-4) + (B-20) + (B-25),

(A-4) + (B-21) + (B-22), (A-4) + (B-21) + (B-23), (A-4) + (B-21) + (B) -24), (A-4) + (B-21) + (B-25), (A-4) + (B-22) + (B-23), (A-4) + (B-22) ) + (B-24), (A-4) + (B-22) + (B-25), (A-4) + (B-23) + (B-24), (A-4) + (B-23) + (B-25), (A-4) + (B-24) + (B-25),

(A-5) + (B-1), (A-5) + (B-2), (A-5) + (B-3), (A-5) + (B-4), (A -5) ＋ (B-5), (A-5) ＋ (B-6), (A-5) ＋ (B-7), (A-5) ＋ (B-8), (A-5) ) ＋ (B-9), (A-5) ＋ (B-10), (A-5) ＋ (B-11), (A-5) ＋ (B-12), (A-5) ＋ (B-13), (A-5) + (B-14), (A-5) + (B-15), (A-5) + (B-16), (A-5) + (B) -17), (A-5) + (B-18), (A-5) + (B-19), (A-5) + (B-20), (A-5) + (B-21) ), (A-5) + (B-22), (A-5) + (B-23), (A-5) + (B-24), (A-5) + (B-25),

(A-5) ＋ (B-1) ＋ (B-2), (A-5) ＋ (B-1) ＋ (B-3), (A-5) ＋ (B-1) ＋ (B) -4), (A-5) + (B-1) + (B-5), (A-5) + (B-1) + (B-6), (A-5) + (B-1) ) ＋ (B-7), (A-5) ＋ (B-1) ＋ (B-8), (A-5) ＋ (B-1) ＋ (B-9), (A-5) ＋ (B-1) + (B-10), (A-5) + (B-1) + (B-11), (A-5) + (B-1) + (B-12), (A -5) ＋ (B-1) ＋ (B-13), (A-5) ＋ (B-1) ＋ (B-14), (A-5) ＋ (B-1) ＋ (B-15) ), (A-5) + (B-1) + (B-16), (A-5) + (B-1) + (B-17), (A-5) + (B-1) + (B-18), (A-5) + (B-1) + (B-19), (A-5) + (B-1) + (B-20), (A-5) + (B) -1) + (B-21), (A-5) + (B-1) + (B-22), (A-5) + (B-1) + (B-23), (A-5) ) ＋ (B-1) ＋ (B-24), (A-5) ＋ (B-1) ＋ (B-25),

(A-5) + (B-2) + (B-3), (A-5) + (B-2) + (B-4), (A-5) + (B-2) + (B) -5), (A-5) + (B-2) + (B-6), (A-5) + (B-2) + (B-7), (A-5) + (B-2) ) ＋ (B-8), (A-5) ＋ (B-2) ＋ (B-9), (A-5) ＋ (B-2) ＋ (B-10), (A-5) ＋ (B-2) + (B-11), (A-5) + (B-2) + (B-12), (A-5) + (B-2) + (B-13), (A -5) ＋ (B-2) ＋ (B-14), (A-5) ＋ (B-2) ＋ (B-15), (A-5) ＋ (B-2) ＋ (B-16) ), (A-5) ＋ (B-2) ＋ (B-17), (A-5) ＋ (B-2) ＋ (B-18), (A-5) ＋ (B-2) ＋ (B-19), (A-5) + (B-2) + (B-20), (A-5) + (B-2) + (B-21), (A-5) + (B) -2) + (B-22), (A-5) + (B-2) + (B-23), (A-5) + (B-2) + (B-24), (A-5) ) ＋ (B-2) ＋ (B-25),

(A-5) ＋ (B-3) ＋ (B-4), (A-5) ＋ (B-3) ＋ (B-5), (A-5) ＋ (B-3) ＋ (B) -6), (A-5) + (B-3) + (B-7), (A-5) + (B-3) + (B-8), (A-5) + (B-3) ) ＋ (B-9), (A-5) ＋ (B-3) ＋ (B-10), (A-5) ＋ (B-3) ＋ (B-11), (A-5) ＋ (B-3) + (B-12), (A-5) + (B-3) + (B-13), (A-5) + (B-3) + (B-14), (A -5) ＋ (B-3) ＋ (B-15), (A-5) ＋ (B-3) ＋ (B-16), (A-5) ＋ (B-3) ＋ (B-17) ), (A-5) + (B-3) + (B-18), (A-5) + (B-3) + (B-19), (A-5) + (B-3) + (B-20), (A-5) + (B-3) + (B-21), (A-5) + (B-3) + (B-22), (A-5) + (B) -3) + (B-23), (A-5) + (B-3) + (B-24), (A-5) + (B-3) + (B-25),

(A-5) ＋ (B-4) ＋ (B-5), (A-5) ＋ (B-4) ＋ (B-6), (A-5) ＋ (B-4) ＋ (B) -7), (A-5) ＋ (B-4) ＋ (B-8), (A-5) ＋ (B-4) ＋ (B-9), (A-5) ＋ (B-4) ) ＋ (B-10), (A-5) ＋ (B-4) ＋ (B-11), (A-5) ＋ (B-4) ＋ (B-12), (A-5) ＋ (B-4) + (B-13), (A-5) + (B-4) + (B-14), (A-5) + (B-4) + (B-15), (A -5) ＋ (B-4) ＋ (B-16), (A-5) ＋ (B-4) ＋ (B-17), (A-5) ＋ (B-4) ＋ (B-18) ), (A-5) ＋ (B-4) ＋ (B-19), (A-5) ＋ (B-4) ＋ (B-20), (A-5) ＋ (B-4) ＋ (B-21), (A-5) + (B-4) + (B-22), (A-5) + (B-4) + (B-23), (A-5) + (B) -4) + (B-24), (A-5) + (B-4) + (B-25),

(A-5) ＋ (B-5) ＋ (B-6), (A-5) ＋ (B-5) ＋ (B-7), (A-5) ＋ (B-5) ＋ (B) -8), (A-5) + (B-5) + (B-9), (A-5) + (B-5) + (B-10), (A-5) + (B-5) ) ＋ (B-11), (A-5) ＋ (B-5) ＋ (B-12), (A-5) ＋ (B-5) ＋ (B-13), (A-5) ＋ (B-5) ＋ (B-14), (A-5) ＋ (B-5) ＋ (B-15), (A-5) ＋ (B-5) ＋ (B-16), (A -5) ＋ (B-5) ＋ (B-17), (A-5) ＋ (B-5) ＋ (B-18), (A-5) ＋ (B-5) ＋ (B-19) ), (A-5) ＋ (B-5) ＋ (B-20), (A-5) ＋ (B-5) ＋ (B-21), (A-5) ＋ (B-5) ＋ (B-22), (A-5) + (B-5) + (B-23), (A-5) + (B-5) + (B-24), (A-5) + (B) -5) + (B-25),

(A-5) ＋ (B-6) ＋ (B-7), (A-5) ＋ (B-6) ＋ (B-8), (A-5) ＋ (B-6) ＋ (B) -9), (A-5) ＋ (B-6) ＋ (B-10), (A-5) ＋ (B-6) ＋ (B-11), (A-5) ＋ (B-6) ) ＋ (B-12), (A-5) ＋ (B-6) ＋ (B-13), (A-5) ＋ (B-6) ＋ (B-14), (A-5) ＋ (B-6) + (B-15), (A-5) + (B-6) + (B-16), (A-5) + (B-6) + (B-17), (A -5) ＋ (B-6) ＋ (B-18), (A-5) ＋ (B-6) ＋ (B-19), (A-5) ＋ (B-6) ＋ (B-20) ), (A-5) + (B-6) + (B-21), (A-5) + (B-6) + (B-22), (A-5) + (B-6) + (B-23), (A-5) + (B-6) + (B-24), (A-5) + (B-6) + (B-25),

(A-5) ＋ (B-7) ＋ (B-8), (A-5) ＋ (B-7) ＋ (B-9), (A-5) ＋ (B-7) ＋ (B) -10), (A-5) + (B-7) + (B-11), (A-5) + (B-7) + (B-12), (A-5) + (B-7) ) ＋ (B-13), (A-5) ＋ (B-7) ＋ (B-14), (A-5) ＋ (B-7) ＋ (B-15), (A-5) ＋ (B-7) ＋ (B-16), (A-5) ＋ (B-7) ＋ (B-17), (A-5) ＋ (B-7) ＋ (B-18), (A -5) ＋ (B-7) ＋ (B-19), (A-5) ＋ (B-7) ＋ (B-20), (A-5) ＋ (B-7) ＋ (B-21) ), (A-5) ＋ (B-7) ＋ (B-22), (A-5) ＋ (B-7) ＋ (B-23), (A-5) ＋ (B-7) ＋ (B-24), (A-5) + (B-7) + (B-25),

(A-5) ＋ (B-8) ＋ (B-9), (A-5) ＋ (B-8) ＋ (B-10), (A-5) ＋ (B-8) ＋ (B) -11), (A-5) + (B-8) + (B-12), (A-5) + (B-8) + (B-13), (A-5) + (B-8) ) ＋ (B-14), (A-5) ＋ (B-8) ＋ (B-15), (A-5) ＋ (B-8) ＋ (B-16), (A-5) ＋ (B-8) + (B-17), (A-5) + (B-8) + (B-18), (A-5) + (B-8) + (B-19), (A -5) ＋ (B-8) ＋ (B-20), (A-5) ＋ (B-8) ＋ (B-21), (A-5) ＋ (B-8) ＋ (B-22) ), (A-5) ＋ (B-8) ＋ (B-23), (A-5) ＋ (B-8) ＋ (B-24), (A-5) ＋ (B-8) ＋ (B-25),

(A-5) ＋ (B-9) ＋ (B-10), (A-5) ＋ (B-9) ＋ (B-11), (A-5) ＋ (B-9) ＋ (B) -12), (A-5) + (B-9) + (B-13), (A-5) + (B-9) + (B-14), (A-5) + (B-9) ) ＋ (B-15), (A-5) ＋ (B-9) ＋ (B-16), (A-5) ＋ (B-9) ＋ (B-17), (A-5) ＋ (B-9) + (B-18), (A-5) + (B-9) + (B-19), (A-5) + (B-9) + (B-20), (A -5) ＋ (B-9) ＋ (B-21), (A-5) ＋ (B-9) ＋ (B-22), (A-5) ＋ (B-9) ＋ (B-23) ), (A-5) ＋ (B-9) ＋ (B-24), (A-5) ＋ (B-9) ＋ (B-25),

(A-5) ＋ (B-10) ＋ (B-11), (A-5) ＋ (B-10) ＋ (B-12), (A-5) ＋ (B-10) ＋ (B) -13), (A-5) + (B-10) + (B-14), (A-5) + (B-10) + (B-15), (A-5) + (B-10) ) + (B-16), (A-5) + (B-10) + (B-17), (A-5) + (B-10) + (B-18), (A-5) + (B-10) + (B-19), (A-5) + (B-10) + (B-20), (A-5) + (B-10) + (B-21), (A -5) ＋ (B-10) ＋ (B-22), (A-5) ＋ (B-10) ＋ (B-23), (A-5) ＋ (B-10) ＋ (B-24) ), (A-5) ＋ (B-10) ＋ (B-25),

(A-5) + (B-11) + (B-12), (A-5) + (B-11) + (B-13), (A-5) + (B-11) + (B) -14), (A-5) + (B-11) + (B-15), (A-5) + (B-11) + (B-16), (A-5) + (B-11) ) + (B-17), (A-5) + (B-11) + (B-18), (A-5) + (B-11) + (B-19), (A-5) + (B-11) + (B-20), (A-5) + (B-11) + (B-21), (A-5) + (B-11) + (B-22), (A -5) ＋ (B-11) ＋ (B-23), (A-5) ＋ (B-11) ＋ (B-24), (A-5) ＋ (B-11) ＋ (B-25) ),

(A-5) + (B-12) + (B-13), (A-5) + (B-12) + (B-14), (A-5) + (B-12) + (B) -15), (A-5) + (B-12) + (B-16), (A-5) + (B-12) + (B-17), (A-5) + (B-12) ) + (B-18), (A-5) + (B-12) + (B-19), (A-5) + (B-12) + (B-20), (A-5) + (B-12) + (B-21), (A-5) + (B-12) + (B-22), (A-5) + (B-12) + (B-23), (A -5) + (B-12) + (B-24), (A-5) + (B-12) + (B-25),

(A-5) + (B-13) + (B-14), (A-5) + (B-13) + (B-15), (A-5) + (B-13) + (B) -16), (A-5) + (B-13) + (B-17), (A-5) + (B-13) + (B-18), (A-5) + (B-13) ) + (B-19), (A-5) + (B-13) + (B-20), (A-5) + (B-13) + (B-21), (A-5) + (B-13) + (B-22), (A-5) + (B-13) + (B-23), (A-5) + (B-13) + (B-24), (A -5) + (B-13) + (B-25),

(A-5) + (B-14) + (B-15), (A-5) + (B-14) + (B-16), (A-5) + (B-14) + (B) -17), (A-5) + (B-14) + (B-18), (A-5) + (B-14) + (B-19), (A-5) + (B-14) ) + (B-20), (A-5) + (B-14) + (B-21), (A-5) + (B-14) + (B-22), (A-5) + (B-14) + (B-23), (A-5) + (B-14) + (B-24), (A-5) + (B-14) + (B-25),

(A-5) + (B-15) + (B-16), (A-5) + (B-15) + (B-17), (A-5) + (B-15) + (B) -18), (A-5) + (B-15) + (B-19), (A-5) + (B-15) + (B-20), (A-5) + (B-15) ) + (B-21), (A-5) + (B-15) + (B-22), (A-5) + (B-15) + (B-23), (A-5) + (B-15) + (B-24), (A-5) + (B-15) + (B-25),

(A-5) + (B-16) + (B-17), (A-5) + (B-16) + (B-18), (A-5) + (B-16) + (B) -19), (A-5) + (B-16) + (B-20), (A-5) + (B-16) + (B-21), (A-5) + (B-16) ) + (B-22), (A-5) + (B-16) + (B-23), (A-5) + (B-16) + (B-24), (A-5) + (B-16) + (B-25),

(A-5) + (B-17) + (B-18), (A-5) + (B-17) + (B-19), (A-5) + (B-17) + (B) -20), (A-5) + (B-17) + (B-21), (A-5) + (B-17) + (B-22), (A-5) + (B-17) ) + (B-23), (A-5) + (B-17) + (B-24), (A-5) + (B-17) + (B-25),

(A-5) + (B-18) + (B-19), (A-5) + (B-18) + (B-20), (A-5) + (B-18) + (B) -21), (A-5) + (B-18) + (B-22), (A-5) + (B-18) + (B-23), (A-5) + (B-18) ) + (B-24), (A-5) + (B-18) + (B-25),

(A-5) + (B-19) + (B-20), (A-5) + (B-19) + (B-21), (A-5) + (B-19) + (B) -22), (A-5) + (B-19) + (B-23), (A-5) + (B-19) + (B-24), (A-5) + (B-19) ) + (B-25),

(A-5) + (B-20) + (B-21), (A-5) + (B-20) + (B-22), (A-5) + (B-20) + (B) -23), (A-5) + (B-20) + (B-24), (A-5) + (B-20) + (B-25),

(A-5) + (B-21) + (B-22), (A-5) + (B-21) + (B-23), (A-5) + (B-21) + (B) -24), (A-5) + (B-21) + (B-25), (A-5) + (B-22) + (B-23), (A-5) + (B-22) ) + (B-24), (A-5) + (B-22) + (B-25), (A-5) + (B-23) + (B-24), (A-5) + (B-23) + (B-25), (A-5) + (B-24) + (B-25),
Can be mentioned.

The preferred weight ratio of the first active ingredient A and the second active ingredient B that can be used in accordance with the present invention can be any suitable ratio between 10000: 1 〜 1: 10000. Preferably 5000: 1 〜 1: 5000, more preferably 200-1000: 1 〜 1: 200-1000, 100: 1 〜 1: 100, 10: 1 〜 1:10, in particular. The preferred ratio is 1: 5 〜 5: 1.

As each of these active ingredients, a commercially available preparation may be used as it is, or the active ingredients may be formulated individually or together. At the time of formulation, the active ingredient is appropriately blended in an appropriate inert carrier or, if necessary, in an appropriate ratio together with an auxiliary agent to dissolve, separate, suspend, mix, impregnate, adsorb or adhere. Dosage forms, such as suspensions (flowables), oily suspensions (ODs), milk suspensions (EWs), emulsions, liquids, wettable powders, granule wettable powders, granules, powders, It may be formulated in microcapsules, capsules, tablets, jumbo agents or packs. If appropriate, different dosage forms may be combined, incorporated and mixed. For example, the kneaded granules and the impregnated granules may be mixed, or the wettable powder and the granule wettable powder may be mixed and solidified into tablets to form a pack.

In the case of formulation, the blending ratio of the active ingredient to the entire pest control agent composition of the present invention can be adjusted as necessary and is not particularly limited, but the total amount of the active ingredient is usually 0.01 to 90% by mass. It is about 0.1 to 30 parts by mass in the case of powder or granules, and 0.1 to 60 parts by mass in the case of emulsions, wettable powders, flowable agents or granule wettable powders. Degree is preferred.

Auxiliary agents include surfactants used as dispersants, wetting agents, spreading agents, spreading agents, etc., binders, tackifiers, thickeners, colorants, freeze-restoring agents, anticaking agents, disintegrants. , Degradation inhibitor, pH adjuster, light stabilizer and the like. In addition, if necessary, preservatives, plant pieces and the like may be used as additive components. These additive components may be used alone or in combination of two or more.

The surfactant suitable for use in the present invention can be any of those known in the art. Examples of the surfactant used as a dispersant / wetting agent / spreading agent / spreading agent include a vegetable oil type nonionic surfactant, an alcohol type nonionic surfactant, and a polyoxyethylene / polyoxypropylene block. Polymer-type nonionic surfactant, alkylphenol-type nonionic surfactant, sugar ester-type nonionic surfactant, fatty acid ester-type nonionic surfactant, bisphenol-type nonionic surfactant, polyaromatic ring Examples thereof include type nonionic surfactants, silicon type nonionic surfactants, and fluorine type nonionic surfactants. Examples of vegetable oil-type nonionic surfactants include hardened castor oil, polyoxyalkylene castor oil (for example, polyoxyethylene castor oil), and polyoxyalkylene hardened castor oil (for example, polyoxyethylene hardened castor oil). Be done. Examples of the alcohol-type nonionic surfactant include polyoxyethylene alkyl ether, polyoxyethylene alkylaryl ether, acetylene diol, and polyoxyalkylene-added acetylene diol. Examples of the polyoxyethylene / polyoxypropylene block polymer type nonionic surfactant include polyoxyethylene / polyoxypropylene block polymer, polystyrene polyoxyethylene block polymer, alkyl polyoxyethylene / polyoxypropylene block polymer ether, and the like. Examples thereof include polyoxyethylene alkylamine, alkylphenyl polyoxyethylene / polyoxypropylene block polymer ether and the like. Examples of the alkylphenol type nonionic surfactant include polyoxyethylene alkyl phenyl ether, polyoxyethylene dialkyl phenyl ether, polyoxyalkylene benzyl phenyl ether, polyoxyalkylene styryl phenyl ether, and polyoxyethylene alkyl phenyl ether / formalin condensation. Things etc. can be mentioned. Examples of the sugar ester type nonionic surfactant include polyoxyethylene sorbitan fatty acid ester, polyoxyalkylene sorbitol fatty acid ester (for example, polyoxyethylene sorbitol fatty acid ester, etc.), glycerin fatty acid ester, polyoxyethylene fatty acid amide, and sucrose. Examples include fatty acid esters. Examples of the fatty acid ester type nonionic surfactant include sorbitan fatty acid ester, polyoxyethylene fatty acid ester, polyoxyethylene resin acid ester, polyoxyethylene fatty acid diester and the like. Examples of the bisphenol type nonionic surfactant include polyoxybisphenyl ether and polyoxyethylene fatty acid bisphenyl ether. Examples of the polyaromatic ring-type nonionic surfactant include polyoxyalkylene benzyl phenyl ether and polyoxyalkylene styryl phenyl ether. Examples of the silicon-type nonionic surfactant include a polyoxyethylene ether-type silicon-based surfactant and a polyoxyethylene ester-type silicon-based surfactant.

Examples of the anionic surfactant include a sulfate-type anionic surfactant, a sulfonate-type anionic surfactant, a phosphate-type anionic surfactant, and a carboxylic acid-type anionic surfactant. Examples of sulfate-type anionic surfactants include alkyl sulfates, polyoxyethylene alkyl ether sulfates, polyoxyethylene alkylphenyl ether sulfates, polyoxyethylene styrylphenyl ether sulfates, alkylbenzene sulfonates, and alkylaryl sulfates. Examples thereof include acid salt, lignin sulfonate, alkyl sulfosuccinate, naphthalene sulfonate, alkyl naphthalene sulfonate, formalin condensate salt of naphthalene sulfonic acid, polyoxyethylene / polyoxypropylene block polymer sulfate and the like. Examples of the sulphonate-type anionic surfactant include paraffin sulphonate, dialkyl sulfosuccinate, alkylbenzene sulphonate, monoalkylnaphthalene sulphonate, dialkylnaphthalens sulphonate, and formalin condensate salt of alkylnaphthalene sulfonic acid. Alkyldiphenyl ether disulfonate, phosphate type anionic surfactants include, for example, polyoxyethylene alkyl ether phosphate, polyoxyethylene alkylphenyl ether phosphate, polyoxyethylene dialkylphenyl ether phosphate, polyoxyethylene styrylphenyl. Examples thereof include ether phosphate, polyoxyethylene / polyoxypropylene block polymer phosphate, and alkyl phosphate. Examples of the carboxylic acid type anionic surfactant include fatty acid salts such as sodium fatty acid, potassium fatty acid, and ammonium fatty acid, polycarboxylic acid salt, polyacrylic acid salt, N-methyl-fatty acid sarcosinate, sodium resinate, and potassium resinate. And the like, and the like.

Examples of the cationic surfactant include alkylamine salts, ammonium-type cationic surfactants, benzalkonium-type cationic surfactants, and the like. Examples of the alkylamine salt include laurylamine hydrochloride, stearylamine hydrochloride, oleylamine hydrochloride, stearylamine acetate, stearylaminopropylamine acetate, alkyltrimethylammonium chloride, alkyldimethylbenzalconium chloride and the like. Examples of the ammonium-type cationic surfactant include methylpolyoxyethylene alkylammonium chloride, alkyl N-methylpyridinium bromide, mono- or dialkylmethylated ammonium chloride, alkylpentamethylpropylenediamine chloride and the like. Examples of the benzalkonium-type cationic surfactant include alkyldimethylbenzalkonium chloride, benzethonium chloride, octylphenoxyethoxyethyldimethylbenzylammonium chloride and the like.

Examples of the amphoteric tenside agent include an amino acid type or betaine type amphoteric tenside agent. Examples of the betaine-type amphoteric surfactant include dialkyldiaminoethyl betaine, alkyldimethylbenzyl betaine, alkyldimethylaminoacetic acid betaine, coconut oil fatty acid amide propyl betaine, and octanoate amide propyl betaine.
Examples of the amino acid type include alkyldimethylamine oxide and the like. These surfactants may be used alone or in combination of two or more.

Examples of the inert carrier include solid carriers and liquid carriers, and examples of the solid carrier include natural carriers such as quartz, clay, kaolinite, pyrophyllite, cericite, talc, bentonite, acidic white clay, attapulsite, zeolite, and diatomaceous earth. Minerals, inorganic salts such as calcium carbonate, ammonium sulfate, sodium sulfate, potassium chloride, organic silicic acid, synthetic silicates, starch, cellulose, plant powders (eg, shavings, coconut husks, corn spikes, tobacco stems, etc.) Examples thereof include solid carriers, plastic carriers such as polyethylene, polypropylene and polyvinylidene chloride, urea, inorganic hollow bodies, plastic hollow bodies, fumed silica (white carbon) and the like. These may be used alone or in combination of two or more.

Examples of the liquid carrier include monohydric alcohols such as methanol, ethanol, propanol, isopropanol and butanol, and polyhydric alcohols such as ethylene glycol, diethylene glycol, propylene glycol, hexylene glycol, polyethylene glycol, polypropylene glycol and glycerin. Such alcohols, polyhydric alcohol compounds such as propylene glycol ether, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, cyclohexanone, ethyl ether, dioxane, ethylene glycol monoethyl ether, dipropyl ether, tetrahydrofuran and the like. Ethers, normal paraffins, naphthenes, isoparaffins, kerosines, aliphatic hydrocarbons such as mineral oils, aromatic hydrocarbons such as benzene, toluene, xylene, solventnaphtha, alkylnaphthalene, dichloromethane, chloroform, carbon tetrachloride, etc. Halogenated hydrocarbons, ethyl acetate, diisopropylphthalate, dibutylphthalate, dioctylphthalate, esters such as dimethyl adipate, lactones such as γ-butyrolactone, dimethylformamide, diethylformamide, dimethylacetamide, amides such as N-alkylpyrrolidinone. Examples include nitriles such as acetonitrile, sulfur compounds such as dimethyl sulfoxide, vegetable oils such as soybean oil, rapeseed oil, cotton seed oil, and castor oil, and water. These may be used alone or in combination of two or more.

In the composition of the present invention, the following can also be used as an oil-based dispersion medium. Among the oily dispersion media that can be used, examples of animal oil include whale oil, cod liver oil, musk oil, mink oil and the like. Vegetable oils that can be used include, for example, soybean oil, rapeseed oil, corn oil, corn oil, sunflower oil, cottonseed oil, flaxseed oil, coconut oil, palm oil, thistle oil, walnut oil, arakis oil, olive oil, papaya oil, camellia oil. , Palm oil, sesame oil, rice bran oil, peanut oil, flaxseed oil, cutting oil, sunflower oil, sunflower oil, tea tree oil, lactic acid ester and other esters. Vegetable oils also include their ester metastases, including, for example, methyl oleate, methyl rapeseed oil, or ethyl rapeseed oil. These may be used alone or in combination of two or more.

Examples of the binder and tackifier include carboxymethyl cellulose and its salts, dextrin, water-soluble starch, xanthan gum, guar gum, sucrose, polyvinylpyrrolidone, gum arabic, polyvinyl alcohol, polyvinyl acetate, sodium polyacrylate, and an average molecular weight of 6000 to Of 20000 polyethylene glycols, polyethylene oxides with an average molecular weight of 100,000 to 5 million, phospholipids (eg cephalin, lecithin, etc.), cellulose powder, dextrin, processed starch, polyaminocarboxylic acid chelate compounds, crosslinked polyvinylpyrrolidone, maleic acid and styrenes. Copolymer, (meth) acrylic acid-based copolymer, half ester of polymer composed of polyhydric alcohol and dicarboxylic acid anhydride, water-soluble salt of polystyrene sulfonic acid, paraffin, terpene, polyamide resin, polyacrylate, Examples thereof include polyoxyethylene, wax, polyvinyl alkyl ether, alkylphenol formalin condensate, and synthetic resin emulsion. These may be used alone or in combination of two or more.

Examples of the thickener include water-soluble polymers such as xanthan gum, guar gum, daiyutan gum, carboxymethyl cellulose, polyvinylpyrrolidone, carboxyvinyl polymer, acrylic polymer, starch derivative and polysaccharide; high-purity bentnite and fumed silica (fumed). silica, white carbon), inorganic fine powder such as alumina fine particles; cellulose fiber, cellulose nanofiber, chitosan fiber, hemicellulose, papermaking pulp, cotton pulp such as cotton linter and cotton lint, chemical pulp, semi-chemical pulp, mechanical pulp, Examples thereof include non-wood pulp, deinked pulp made from used paper, and fibrous materials such as non-wood pulp such as hemp, straw, and bagas. These may be used alone or in combination of two or more.

Examples of the colorant include inorganic pigments such as iron oxide, titanium oxide and Prussian blue, alizarin dyes, azo dyes, organic dyes such as metallic phthalocyanine dyes, and organic pigments such as phthalocyanine blue and permanent red. Be done.

Examples of the antifreeze / restoration agent include polyhydric alcohols such as ethylene glycol, diethylene glycol, propylene glycol, and glycerin.

Auxiliary agents for preventing caking and promoting disintegration include, for example, polysaccharides such as starch, alginic acid, mannose, and galactose, polyvinylpyrrolidone, fumed silica (white carbon), ester gum, petroleum resin, sodium tripolyphosphate, and the like. Sodium hexametaphosphate, metal stearate, cellulose powder, dextrin, methacrylic acid ester copolymer, polyvinylpyrrolidone, polyaminocarboxylic acid chelate compound, sulfonated styrene / isobutylene / maleic anhydride copolymer, starch / polyacrylonitrile graft Examples include polymers.

Examples of the decomposition inhibitor include desiccants such as zeolite, quicklime and magnesium oxide, antioxidants such as phenol compounds, amine compounds, sulfur compounds and phosphoric acid compounds, and ultraviolet absorbers such as salicylate compounds and benzophenone compounds. Be done.

Examples of the defoaming agent include silicone oil and the like. Examples of the preservative include potassium sorbate, 1,2-benzoisothiazolin-3-one and the like.

Examples of the pH adjusting agent include a method of adding various inorganic acids and organic acids such as hydrochloric acid, sulfuric acid, phosphoric acid, sulfonic acid and carboxylic acid, and salts and esters thereof in a predetermined amount to the composition of the present invention. Specific examples of the organic acid include acidic phosphoric acid ester, citric acid, maleic acid, sorbic acid, lactic acid and tartaric acid. In addition, various buffer solutions such as sodium hydrogen phosphate-citrate aqueous solution, sodium acetate-hydrochloric acid aqueous solution, formate-sodium formate aqueous solution, lactic acid-sodium lactate aqueous solution, tartrate acid-sodium citrate aqueous solution and sodium citrate-hydrochloric acid aqueous solution are provided. The pH can be controlled by adding a fixed amount.

Examples of the light stabilizer include titanium oxide, iron yellow oxide, yellow iron sesquioxide, brown iron oxide, iron sesquioxide and the like.

Further, if necessary, a functional spreading agent, an activity enhancer such as a metabolic decomposition inhibitor such as piperonyl butoxide, an antioxidant such as BHT, and other auxiliary agents such as an ultraviolet absorber can also be used.

The "useful crops" to which the pest control agent composition of the present invention can be used are not particularly limited, but for example, grains (for example, rice, melon, wheat, limewood, oat wheat, sorghum (koulyan), corn, sorghum). ); Beans (eg soybeans, azuki, sorghum, sorghum, green beans, sorghum, etc.); Fruit trees / fruits (eg, apples, oranges, oranges, lemons, limes, grapefruits, karin, sorghum, pears, sorghum, etc.) Japanese pear, grapes, blueberries, cranberries, blackberries, raspberries, strawberries, peaches, sorghum, nectarins, melons, sorghum, sorghum, apricots, prunes, walnuts, hashibami, greens, almonds, pistachios, cashew nuts, macadamia nuts, bananas, oysters, Olives, biwa, nut palms, coconut palms, abra palms, etc.; vegetables (eg cabbage, tomatoes, spinach, broccoli, lettuce, onions, onions, peppers, eggplant, sorghum, hakusai, komatsuna, karashina, broccoli, cauliflower, shungiku, artichoke , Lettuce, asparagus, parsley, sorghum, sorghum, sorghum, pepper, okla, nira, etc.; root vegetables (eg carrots, gobos, potatoes, potatoes, sweet potatoes, sorghum, sweet potatoes, radishes, lentils, cubs, gobos) , Garlic, sorghum, etc.); Processing crops (eg cotton, sorghum, sorghum, sorghum, rapeseed, oil palm, broccoli, buckwheat, beet, hop, sugar cane, sorghum, olive, rubber, coffee, tobacco, sorghum, etc. Cha, sunflower, etc.); Cucumbers (eg, pumpkin, cucumber, zucchini, watermelon, macwauri, melon, etc.); Grasses (eg, orchardgrass, sorghum, timothy, clover, alfalfa, etc.);

Lawns (for example, Shiva such as Noshiba and Kouraishiba, Bermudagrass such as Gyogishiba, Bentgrass such as Konukagusa, Agrostis stolonifera, and Itokonukkagusa, Bluegrass such as Nagahagusa and Oosuzumenokatabira, Fescue, rat, ryegrass such as perennial ryegrass, Dactylis, tall fescue, etc.; Fragrance and other crops (eg, lavender, rosemary, thyme, parsley, pepper, spruce, wasabi, ginger, garlic, perilla, mint, basil Flowers (eg roses, carnations, kiku, fescue, dactylis, sunflower, gerbera, marigold, salvia, petunia, barbena, tulip, aster, lindow, lily, pansy, cyclamen, orchid, tin orchid, lavender, stock , Habutton, Primula, Poinsetia, Gradiolas, Cattleya, Daisy, Verbena, Symbidium, Begonia, etc.; Trees (eg, Aoki, Sakura, Toneriko, Kabanoki, Hanamizuki, Eucalyptus, Ginkgo, Lilac, Mokuren, Kaede, Kashi, Poplar , Hanazuou, Fu, Platanas, Keyaki, Kurobe, Mominoki, Tsuga, Nezu, Matsu, Todomatsu, Ezomatsu, Tohi, Ichii, Nire, Tochinoki, Coral, Inumaki, Sugi, Hinoki, Hiba, Kuroton, Masaki, Kanamechi, etc. ) And so on.

In addition, the above-mentioned "useful crops" include genetically modified crops (herbicide-resistant crops, pest-resistant crops incorporating insecticidal protein-producing genes) that have been given useful traits due to classical breeding methods and recent advances in genetically modified technology. It also includes crops, disease-resistant crops incorporating disease-resistant inducer-producing genes, taste-enhancing crops, conservation-improving crops, yield-improving crops, etc.).

The above-mentioned "useful plants" include HPPD inhibitors such as isoxaflutol, ALS inhibitors such as imazetapill and thifensulfuronmethyl, EPSP synthase inhibitors such as glyphosate, glutamine synthase inhibitors such as gluhosinate, and setoxydim. Tolerance to acetyl CoA carboxylase inhibitors, PPO inhibitors such as flumioxadin, and herbicides such as bromoxinyl, dicamba, 2,4-D by classical breeding methods, gene recombination technology, or gene editing technology Granted plants are also included, and the compositions of the present invention can be used for these plants as well.

Examples of "useful plants" that have been endowed with resistance by classical breeding methods include rapeseed, wheat, sunflower, and rice that are resistant to imidazolinone-based ALS-inhibiting herbicides such as imazetapill, and are Clearfield® products. Already sold under the name. Similarly, there are soybeans resistant to sulfonylurea ALS-inhibiting herbicides such as thifensulfuron-methyl by classical breeding methods, which are already sold under the trade name of STS soybeans. Similarly, SR corn and the like are known as examples of plants to which resistance to acetyl-CoA carboxylase inhibitors such as trionoxime-based and aryloxyphenoxypropionic acid-based herbicides has been imparted, and other proceedings of the -It is described in the National Academy of Sciences of the United States of America (Proc. Natl. Acad. Sci. USA), Vol. 87, pp. 7175-7179 (1990).

An example of a plant resistant to a 4-hydroxyphenylpyrvate dioxygenase inhibitor (“HPPD inhibitor”) is the soybean strain (eg WO2012 / 082548A). This is the avhppd-03 gene, which is a mutant HPPD gene derived from the genus Oat (Avena), and S. cerevisiae. Described is a transgenic soybean plant having a phosphinotricine acetyltransferase gene (“SYHT0H2 event”) from S. viridochromogenes.

As an example of a plant resistant to a protoporphyrinogen oxidase inhibitor (“PPO inhibitor” or “Protox inhibitor”), the soybean described in US2016 / 0194654, US-2016 / 0194655, or WO2017 / 039969A1). The strain can be mentioned. They use gene recombination technology to introduce mutant PPO genes that are less sensitive to PPO inhibitors, to overexpress PPO genes, to introduce detoxification metabolism genes such as P450, or to apply those technologies at the same time. By doing so, it is described that a plant resistant to the PPO inhibitor can be produced.

In addition, the fatty acid residue composition of phosphatidyl glycerol, which is a plant having various environmental stress tolerances, for example, the thylakoid membrane of plastide, is involved in the substrate specificity of the fatty acid residues taken up in the biosynthesis system of phosphatidylglycerol. Enzymes involved: acyl- (acyl-carrier protein): Plants (N. Murata, O. Ishizaki-Nis) that have been imparted sensitivity and resistance to low temperature stress by modifying glycerol-3-phosphatidyltransphase (GPAT). Higashi, H. Hayashi, Y. Tasaka & I. Nishida (23 April 1992) Nature 356: 710 – 713, "Genetically engineered engine emission from fatty acid engine, fatty acid emission from fatty acid engine" To overproduce OsSDIR1, which is an E3 ubiquitin fatty acid involved in protein ubiquitination, in plants subjected to osmotic stress (salt stress) using Na ⁺ / H ⁺ antiporter, etc. Rice (Gao T, Wu Y, Zhang Y, Liu L, Ning Y, Wang D, Tong H, Chen S, Chu C, Xie Q., 2011 May; Plant Mol Bio, which was imparted with drought stress resistance. 76 (1-2): 145-156. "OsSDIR1 overexppression protein drivees drewt fatty acid solution."), And other plants subjected to freezing stress, high temperature stress, strong light stress, submergence stress, etc. are also "useful crops". include.

Examples of "useful plants" that have been endowed with resistance by gene recombination technology include glyphosate-tolerant maize, soybean, cotton, rapeseed, and tensai varieties, Roundup Ready <registered trademark>, Agrisure GT <registered. It is already sold under a trade name such as Trademark>. Similarly, there are glufosinate-tolerant corn, soybean, cotton, and rapeseed varieties produced by genetic recombination technology, which are already sold under trade names such as Liberty Link (registered trademark). Similarly, bromoxynil-resistant cotton produced by genetic recombination technology is already sold under the trade name of BXN.

Crop resistant to acetyl-CoA carboxylase inhibitors is the Proceedings of the National Academy of Sciences of the United States of America (Proc. Natl. Acad. Sci. USA) 87 volumes, pp. 7175-7179 (1990) and the like. In addition, mutant acetyl-CoA carboxylase resistant to acetyl-CoA carboxylase inhibitors has been reported in Weed Science, Vol. 53, pp. 728-746 (2005), and such mutant acetyl-CoA carboxylase genes have been genetically modified. A crop resistant to an acetyl-CoA carboxylase inhibitor can be produced by introducing the gene into the crop or by introducing a mutation related to imparting resistance into the crop acetyl-CoA carboxylase. Furthermore, a base substitution mutation-introducing nucleic acid represented by Chimera Plasty Technology (Gura T. 1999. Repairing the Genome's Spelling Mistakes. Science 285: 316-318.) Is introduced into a crop cell to produce a crop {acetyl CoA carboxylase. } By inducing a site-specific amino acid substitution mutation in the gene, crops resistant to {acetyl CoA carboxylase inhibitor} can be produced, and the composition of the present invention can be used for these plants as well.

In addition, the above-mentioned "useful crops" also include genetically modified crops capable of synthesizing insecticidal toxins and the like using gene recombination technology. Examples of the insecticidal toxin expressed in such a recombinant plant include insecticidal proteins derived from Bacillus cereus and Bacillus popilliae; Cry1Ab derived from Bacillus thuringiensis. , Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1 or Cry9C and other δ-endotoxins, VIP1, VIP2, VIP3 or VIP3A and other insecticidal proteins; Bacillus ceretoxin, spider toxin Toxins produced by animals such as insect-specific neurotoxins; Streptococcal toxins; Plant lectins; Agglutinin; Prototype inhibitors such as trypsin inhibitors, Bacillus protease inhibitors, Patatin, cystatin, papain inhibitors; Lycin, corn- Ribosome-inactivating proteins (RIPs) such as RIP, abrin, saporin, briozin; steroid-metabolizing enzymes such as 3-hydroxysteroid oxidase, exdisteroid-UDP-glucosyltransferase, cholesterol oxidase; ecdison inhibitors; HMG-CoA reductase; Ion channel inhibitors such as sodium channel inhibitors and calcium channel inhibitors; immature hormone esterases; diuretic hormone receptors; stillben synthase; bibenzyl synthase; chitinase; glucanase and the like. Examples of these toxins and recombinant crops capable of synthesizing these toxins include, for example, EP-A-0374753, WO93 / 07278, WO95 / 34656, EP-A-0427529, EP-A-451878, WO03 / 052073 and the like. Have been described. The toxins contained in these recombinant crops are particularly suitable for controlling Coleoptera pests, Diptera pests, and Lepidopteran pests, and impart resistance to these pests to the crops.

Genetically modified crops expressing one or more of these insecticidal toxins are already known and some are commercially available. Examples of these recombinant crops include corn varieties expressing Cry1Ab toxin, such as Yield Gard <registered trademark>, and corn varieties expressing Cry3Bb1 toxin, such as Yield Garden <registered. Phosphinotricin N-acetyltransferase (PAT) for conferring resistance to Cry1Fa2 toxin and gluhosinate, such as corn varieties expressing Cry1Ab and Cry3Bb1 toxins, such as <Trademark>, for example Yield Gard Plus <registered trademark>. ), Such as Herculex I <registered trademark>, Cry1Ac toxin-expressing cotton varieties, such as NuCOTN33B <registered trademark>, Bollgard I <registered trademark>, etc. And Cry2Ab toxin-expressing cotton varieties, such as Bollgard II <registered trademark>, VIP toxin-expressing cotton varieties, such as VIPCOT <registered trademark>, Cry3A toxin-expressing potato varieties, such as New Leaf ( New Leaf) <registered trademark>, etc. GA21 glyphosate resistant trait Nature Guard Agrisure GT Advantage <registered trademark>, etc. Bt11 corn borer (CB) trait, eg Agrisure CBage Examples include <registered trademark> and protector (Protecta) <registered trademark>.

Furthermore, those imparted with a trait that produces an anti-pathogenic substance having a selective action by using a gene recombination technique are also included. Known antipathogenic substances include, for example, PR proteins (PRPs, described in EP-A-0392225); sodium channel inhibitors, calcium channel inhibitors (KP1, KP4, KP6 toxins produced by viruses, etc.). Ion channel inhibitors such as); stillben synthase; bibenzyl synthase; chitinase; glucanase; peptide antibiotics, antibiotics with heterocycles, protein factors involved in plant disease resistance (called plant disease resistance genes) , WO 03/000906) and the like produced by microorganisms. Such antipathogenic substances and the genetically modified crops that produce them are described in EP-A-0392225, WO95 / 33818, EP-A-0353191 and the like.

Furthermore, crops to which useful traits such as oil component modification and amino acid content enhancing traits have been imparted using gene recombination technology are also included. Examples include VISTIVE <registered trademark> (low linolenic soybean with reduced linolenic content) or high-lysine (or high-oil) corn (corn with increased lysine or oil content).

In addition, crops produced by using the Oligonucleotide directed mutagenesis method are also included as useful crops to which herbicide resistance has been imparted by gene editing technology. As an example, there is a rapeseed variety resistant to a sulfonylurea ALS inhibitor such as trivenurone, which is already sold under a trade name such as SU Canola (registered trademark). Further, as an example of imparting herbicide resistance to crops by gene editing technology, a method using Zinc finger Nuclease is reported in Nature 459, 437-441 (2009). Another example of imparting herbicide resistance to crops by gene editing technology is the method using the CRISPR locus and Cas9 nuclease, called the CRISPR / Cas9 method, Nature Biotechnology, Vol. 31, pp. 688-691 ( It was reported in 2013).

In addition, a plurality of useful traits such as the above-mentioned classical herbicide traits or herbicide resistance genes, insecticidal pest resistance genes, antipathogenic substance production genes, oil component modification and amino acid content enhancing traits are described. Combined stack varieties are also included. When the pest control composition of the present invention is used on a herbicide-tolerant crop, the herbicide to which the crop is resistant (eg, glyphosate or its salt, gluhosinate or its salt, dicamba or its salt). , Imazetapill or a salt thereof, isoxaflutol, etc.) and systematic treatment and / or mixed treatment of the pest control agent composition of the present invention can comprehensively control weeds and pests.

In order to control various pests, the agricultural and horticultural pest control agent composition of the present invention has various harmful substances in the form of the above-mentioned preparation containing each active ingredient as it is, or appropriately diluted or suspended with water or the like. An amount effective for biological control may be applied directly to the target crop in which the occurrence of the pest is predicted, or to the soil for sowing the seeds, or the cultivation carrier, etc., for example, fruit trees, For pests that occur in grains, vegetables, etc., in addition to spraying on the foliage
Immersion of seeds in chemicals, seed powder coating, seed disinfection, seed treatment such as calper treatment, soil full-thickness mixing, cropping application, bed soil mixing, cell seedling treatment, planting hole treatment, plant root treatment, top dress, rice Seedling box treatment, irrigation treatment, soil mixing treatment, water surface application, cleanup treatment (Plant Burndown) before sowing of treated crops on soil, etc. can also be used by absorbing from the roots. As a soil treatment, it is also useful for a cleanup treatment (Plant Burndown) before sowing crops. In addition, it can be applied to nutrient solution in hydroponic cultivation, smoked or injected into a tree trunk. Further, for example, in addition to spraying on stored grain pests, house pests, sanitary pests, forest pests and the like, it can also be used as application to house building materials, smoke, bait and the like. As a method of seed treatment, for example, a method of immersing seeds in a liquid state without diluting or diluting a liquid or solid preparation to allow the drug to permeate, mixing a solid preparation or a liquid preparation with seeds, and powder coating. Examples thereof include a method of treating and adhering to the surface of seeds, a method of mixing with an adhesive carrier such as a resin or a polymer and coating the seeds, and a method of spraying around the seeds at the same time as planting. The "seed" that performs the seed treatment means a plant body in the early stage of cultivation used for breeding of plants, for example, in addition to seeds, bulbs, tubers, seed potatoes, plant buds, propagules, scales or nutrients for cuttings. Plants for reproduction can be mentioned.

The "soil" or "cultivation carrier" of a plant when the method of using the agricultural and horticultural pest control agent composition of the present invention is carried out refers to a support for cultivating a crop, particularly a support for growing roots. The material is not particularly limited, but may be any material that allows plants to grow, so-called soil, seedling mat, water, etc. Specific materials include, for example, sand, pebble, and vermiculite. , Diatomaceous earth, agar, gel-like substance, polymer substance, rock wool, glass wool, wood chips, bark and the like.

As a method of spraying the agricultural and horticultural pest control agent composition of the present invention on crop foliage or stored grain pests, house pests, sanitary pests, forest pests, etc., emulsions, flowable agents, oil suspension agents (OD preparations) Examples thereof include a method of appropriately diluting a liquid preparation such as a liquid preparation such as a wettable powder or a solid preparation such as a granular wettable powder with water and spraying the liquid preparation, a method of spraying a powder preparation, smoke and the like. Examples of the method of application to soil include a method of applying a liquid preparation or a solid preparation to the plant root, the vicinity of the installation site, a nursery for raising seedlings, etc. without diluting or diluting with water, and the granules of the plant. Method of spraying on the root of the plant, near the installation site, nursery for raising seedlings, etc., method of spraying powder, wettable powder, granular wettable powder, granules, etc. before sowing or transplanting, and mixing with the whole soil, Examples thereof include a method of spraying a powder, a wettable powder, a granule wettable powder, a granule, etc. on a planting hole, a crop, etc. before sowing or planting a plant.

The treatment amount of the pest control agent composition of the present invention is such that the composition is suspended (flowable), emulsion, oily suspending agent (OD preparation), liquid, wettable powder, granule wettable powder, granule, When processed and used in preparations such as powders and smoke agents, the application rate depends on various factors such as purpose, pests to be controlled, target crops and growth conditions of crops, weather, environmental conditions, formulation form, etc. It depends on the method of application, the place of application, the time of application, the mixing ratio of the active ingredient, the weather conditions, etc. It may be appropriately selected from the range of 2000 g and applied, preferably in the range of 0.1 g to 500 g. In the case of soil or irrigation treatment, the active ingredient may be sprayed or irrigated in the range of 1 g to 1000 g on the surrounding soil in which the target crop is growing. In the treatment of seeds, it is possible to use the active ingredient in the range of 0.01% to 50%, preferably in the range of 0.1% to 10%, as compared with the seed weight. When an emulsion, wettable powder, etc. is diluted with water or the like and applied, the application concentration is 0.00001 to 0.1%, and a liquid agent or the like when treating granules, powders or seeds is usually diluted. You can apply it as it is without any problems.

For field crops such as potatoes, sweet potatoes, and soybeans, it is preferable to treat the seeds or a cultivation carrier close to the plant from the sowing to the seedling raising period. For plants that are sown directly in the field, it is preferable to treat the seeds directly as well as the roots of the plants being cultivated. Granules can be used for spraying or liquid irrigation with a drug that is diluted or not diluted in water. It is also a preferable treatment to mix the granules with the cultivation carrier before sowing and then sow. Further, as the sowing of the cultivated plant to be transplanted and the treatment during the seedling raising period, in addition to the direct treatment on the seeds, the seedbed for raising seedlings is preferably irrigated with a liquid chemical or sprayed with granules. It is also preferable to treat the granules in the planting holes at the time of planting or to mix them with a cultivation carrier near the transplanting site.

When the pest control agent composition for agriculture and horticulture of the present invention is applied to rice, it may be applied to rice seeds, a seedling raising medium, or a paddy field or a dry field. The rice seeds referred to here mean rice seeds in a state before sowing in soil such as paddy fields. Examples of the paddy field include paddy fields that are flooded or in a flooded state. Paddy fields that are in a flooded state are paddy fields that have been cultivated, filled with water, puddled, etc. Paddy field. In addition, the paddy field in a flooded state means a paddy field in which the water content is maintained at the same level as the flooded state and the soil surface is exposed by performing a waterfall treatment from the flooded state.

Rice seeds to which this composition is applied can be cultivated by directly sowing in dry fields, wet fields, and paddy fields, or may be sown and cultivated in a seedling raising medium such as a nursery box. The sprouting of rice seeds may be carried out by immersing the rice seeds in water or by keeping the rice seeds in a moist state after immersing them in water. The wet state means a state in which a part or all of the surface of the rice seed after being immersed in water can be in contact with the outside air and can retain the water content of the rice seed, for example, after being immersed in water. Rice seeds are covered with a breathable material such as rice straw or cloth, and water is sprinkled over the coated material as needed, or the reticulated or bag-like body used when immersing the rice seeds in water. This is achieved by storing rice seeds as they are in the material. The seedling raising medium is not particularly limited as long as it is a soil for raising rice seedlings, and a seedling raising mat seedling raising box other than the soil, a seedling raising tray for paddy rice or a nursery bed may be used, or the seedlings may be cultivated by pool raising.

When applied to a seedling raising box of paddy rice, the dosage form may differ depending on the application time such as application at the time of sowing, application during the greening period, application at the time of transplantation, etc. For example, this composition is applied to powder, granule wettable powder, granule It may be applied by a method suitable for the time with a dosage form such as. It can also be applied by mixing with hilling soil, and can be mixed with hilling soil and powder, granule wettable powder, granules, etc., for example, bed soil mixing, soil covering mixing, mixing with the entire hilling soil, and the like. You may simply apply the soil and various preparations in layers alternately. The time of application at the time of sowing may be before, at the same time, after sowing, or after soil covering. In the field of paddy rice, water surface application such as granules to paddy fields is often used. The time of application is not particularly limited as long as it is the period from the time of sowing to the time of transplantation. Examples include bed soil mixing treatment, soil covering treatment at the time of sowing, greening period treatment, transplantation day treatment, and transplantation simultaneous treatment. It may be applied from 7 days before transplantation to the day before transplantation, and can be applied at any time during the period from seeding to transplantation. The period from sowing to transplantation varies depending on the seedlings (seedlings around 2.5 leaf stage), medium seedlings (seedlings around 3.5 leaf stage) or adult seedlings (seedlings around 4.5 leaf stage). The seedling raising period varies depending on the weather conditions, but it can be applied in any case. Further, the kneaded granules or sand-coated granules of the present composition may be sprayed on the nursery box, or a diluted solution of the preparation of the present composition may be irrigated on the nursery box. The formulation of this composition can also be applied by mixing with bed soil, hilling, and hilling, and mixing of hilling with powder, granule wettable powder, granules, etc., for example, hilling mixing, hilling mixing, whole hilling. It can be mixed with the soil, and the soil and various preparations may be alternately layered and applied.

As a method of applying the pest control agent composition for agriculture and horticulture of the present invention to paddy fields, a method of applying it to rice stalks or leaves as it is or by formulating it, or a method of applying it to paddy soil during direct sowing cultivation. , And a method of applying to the water surface of a flooded paddy field. When applied to the leaves of rice stalks, the time may be any time from the seedling raising period to the harvest. The method of application to paddy fields is not particularly limited, but preparations, flowable agents, dry flowable agents, wettable powders, jumbo agents, pack agents, granules, granules, etc., which are applied as they are, such as powders and fine granules. A method of diluting and spraying a solid preparation such as a wettable powder, an SE agent, a water solvent, a granular water solvent, a liquid agent, a microemulsion agent, an EW agent, an oil agent, a surf agent, or a liquid preparation such as an emulsion emulsion is diluted and sprayed. , Usually sprayed on flooded paddy fields. In addition, at the time of rice planting, an appropriate preparation can be sprayed or injected into the soil as it is or mixed with fertilizer or the like. Further, by treating a chemical such as an emulsion, a flowable, or a jumbo agent at the inflow source of water into a paddy field such as a water outlet or an irrigation device, it can be applied labor-savingly with the supply of water. When a spraying device is used, any device that is normally used may be used, and a hand-cranked spreader, a power spreader, a punkle sprayer, a radio-controlled helicopter, a manned helicopter, a radio-controlled boat, or the like can be used. As another method, in irrigation around useful plants using an irrigation device such as a sprinkler, a drip tube, or a drip valve, the composition of the present invention is mixed with the irrigation water and sprayed to save labor or resources. It is also possible to apply it as a target.
Alternatively, it may be sprayed by hand without using a device.

As a method of applying the pest control agent composition for agriculture and horticulture of the present invention to paddy soil, a method of treating the entire surface of the paddy soil (full surface treatment) and a method of treating the groove provided when rice is sown (sowing groove). Treatment), a method of treating directly above (0 to 10 cm) or directly below (0 to 10 cm) of rice seeds, a method of treating rice strains or seeds in a streak or dot shape (side-row treatment), etc. Be done. When applied to paddy soil, it can be mixed with agricultural materials such as paste fertilizer and granular fertilizer, or applied at the same time. The time to apply this composition may be before sowing or transplanting of rice, at the same time as sowing or transplanting, or immediately after sowing or immediately after transplanting. When it is applied at the same time as sowing or transplanting, it may be applied using an attachment attached to a seeding machine or a transplanting machine, or may be applied by another method. Further, in the case of full-scale treatment, the period from sowing or transplantation to water injection, the mid-drying period, or the intermittent irrigation period may be used. When this composition is used, the soil surface of the paddy field may be dry, or the soil surface may be moist but not flooded (water depth 0 cm). When applied to the surface of a flooded paddy field, it may be applied at any time from sowing or transplanting to harvesting, as long as the water depth is maintained by normal rice management.

When the agricultural and horticultural pest control agent composition of the present invention is applied to paddy fields and used for direct sowing rice, or when rice seeds to which this composition is applied are used for direct sowing cultivation, rice seeds Supply iron powder (iron oxide powder, reduced iron powder, atomized iron powder, electrolytic iron powder, etc.), calcium peroxide, oxoanion, molybdenum compounds (molybdenum alone, molybdenum oxide, molybdic acid and its salts, molybdrine) The surface treatment can be applied with a coating material such as an acid and a salt thereof, and molybdosilicic acid and a salt thereof. Examples of the salt of molybdic acid include calcium molybdate, magnesium molybdate, ammonium molybdate, and sodium molybdate. And potassium molybdate. Examples of molybdated phosphate include ammonium molybdated phosphate, sodium molybdated phosphate, potassium molybdated phosphate and the like. In addition, tungsten-containing substances, chromium-containing substances, selenium-containing substances, and selenium-containing substances. Coating materials such as tellurium-containing substances may be applied to the surface treatment. These coating materials may be used alone or mixed in any ratio, and if necessary, the amount may be increased or rice seeds may be used. Auxiliary agents such as mineral powders such as roasted gypsum and montmorillonite can be added for the purpose of improving adhesion to, etc. A mixture of calcium peroxide, roasted gypsum and mineral powder is available as a commercial product, for example, Calper. Powder granule 16 (manufactured by Hodoya UPL Co., Ltd.) can be mentioned. The preparation of this composition can be applied by coating rice seeds with powder, but the rice seeds before sprouting are immersed in a solution containing this composition. Alternatively, after sprouting, a solution containing the present compound may be sprayed for treatment.

When the agricultural and horticultural pest control agent composition of the present invention is used for herbicidal treatment, it can be treated on and / or in the vicinity where the target crop is cultivated. Therefore, the composition of the present invention may be applied, for example, to a region where useful plants grow, and may be applied by a commonly used method such as foliage application, soil application, or the like. The application time is not particularly limited as long as it does not interfere with the effects of the present invention, and may be from before the emergence of useful plants to the growing season, before the emergence of weeds, the germination stage, the growing season and the like. For spraying on the soil (soil application), spray on the soil surface before the emergence of useful plants and before the emergence of weeds, and spray on the soil surface from above after the emergence of useful plants and before the emergence of weeds. Specific examples thereof include spraying on the soil surface between furrows or between strains after germination and before weeds, or spraying on the soil surface from above after germination of useful plants and after weeds emerge. In addition, when the composition of the present invention is sprayed on the plants of weeds to be controlled (application of foliage), it is sprayed on the foliage of weeds from above before the emergence of useful plants and after the emergence of weeds, or the emergence of useful plants. Specific examples thereof include spraying the weeds on the foliage of the weeds from above after the weeds have grown.

A desired pest control effect can be exhibited even if a preparation containing each active ingredient is mixed in the field and treated by the above treatment method. Further, even if each of the individual preparations is treated by the above-mentioned treatment method at the same time, a desired pest control effect can be exhibited. Here, the same period does not only mean that the processes are performed at exactly the same time, but can be regarded as the same period within a period of about one week, and different processing methods can be adopted for each. Furthermore, the desired pest control effect can also be exhibited by treating each of the individual preparations at intervals by the above-mentioned treatment method. The treatment interval at this time is not particularly limited as long as the effects of the present invention can be exhibited, but in general, it is preferably within 3 months from the treatment of each individual preparation, and particularly preferably within 2 months. .. At this time, either active ingredient may be treated first, or different treatment methods may be adopted for each.

The pest control agent composition of the present invention can also be used as a pest control agent other than farmland, for example, cutting marks, fallow fields, ridges, farm roads, waterways, pastures, graveyards, parks. , Roads, athletic fields, vacant lots around buildings, cleared land, railroad ends, or for controlling general weeds such as forests, or for controlling undergrowth of fruit trees such as grapes and olives, or for controlling flies. Can be done. In this case, it is economically most effective to treat the weeds by the beginning of the outbreak, but the present invention is not limited to this, and weeds and the like in the growing season can also be controlled.

The pest control agent composition of the present invention includes various agricultural and forestry, gardening, forest and wood pests, livestock pests, lepidoptera pests, sanitary pests, nematodes, etc. that harm paddy rice, fruit trees, vegetables, other crops and flowers. Suitable for controlling pests of Lepidoptera, for example, Aoiraga (Parasa consocia), Akakiriba (Anomis mesogona), Ageha (Papilio xuthus), Azukisayamusiga (Matsumuraeses azukivora), Azukinomeiga (Ostrinia scap) African yoto (Spodoptera exempta), Fall webworm (Hyphantria cunea), Awanomeiga (Ostrinia furnacalis), Awayoto (Pseudaletia separata), Iga (Tinea translucens), Igusa shinmusiga (Bactra furfurana), Ichimonji seri (Bactra furfurana), Parnara gutta (Bactra furfurana) Parnara guttata, Sesamia inferens, Brachmia triannulella, Monema flavescens, Trichoplusia ni, Pleuroptya ruralis, Umeeda dia cousi, pea blue moth (Pleuroptya ruralis), pea blue moth (Pleuroptya ruralis), pea blue moth (Pleuroptya ruralis) ), Cephonodes hylas, Helicoverpa armigera, Phalerodonta manleyi, Eumeta japonica, Pieris brassicae, Obikareha (Malacosoma neustria testacea), Monema flavescens (Malacosoma neustria testacea) (Cuphodes diospyrosella), Kakumonhamaki (Archips xylosteanus), Kabrayaga (Agrotis segetum), Kanshoshinuihamaki (Tetramoera schistaceana), Kiageha (Papilio) machaon hippocrates, endoclyta sinensis, Lyonetia prunifoliella, Phyllonorycter ringoneella, Cydia kurokoi, Eucoenogenes aestuosa, gray flour moth (Latoia sinica), Kurofutamon Madarameiga (Euzophera batangensis), Kwaihosohamaki (Phalonidia mesotypa), Kuwagomadara Hitori (Spilosoma imparilis), Kwanomeiga (Glyphodes pyloalis), Kuwahimehamaki (Olethreutes mori), Kuwahimehamaki (Olethreutes) ), Kokuga (Nemapogon granellus), Kosuka Shiba (Synanthedon hector), Codling Moth (Cydia pomonella), Konaga (Plutella xylostella), Kobunomeiga (Cnaphalo crocis medinalis), Southern Pink Borer (Sesamia calamistis), Sanka Meiga (Sesamia calamistis), Sanka Meiga (Scidia) ), Potato moth (Phthorimaea operculella), Shachihokoga (Stauropus fagi persimilis), Beet armyworm (Etiella zinckenella), Beet armyworm (Spodoptera exigua), White bat (Palpifer sexnotata), White bat (Palpifer sexnotata), White bat (Palpifer sexnotata) innotata, Setaceous Hebrew (Xestia c-nigrum), Spodoptera de pravata, Mediterranean Flour Moth (Ephestia kuehniella), Angerona prunaria, Closter a anastomosis), soybean looper (Pseudoplusia includens), soybean scabbard (Matsumuraeses falcana), tobacco moth (Helicoverpa assulta), tamanagin uwaba (Autographa nigrisigna), tamanayaga (Agrotis ipsilon), chadokuga (Agrotis ipsilon), chadokuga (Euproctis pseudos) Caloptilia theivora, Homona magnanima, Ephestia elutella, Eumeta minuscula, Clostera anachoreta, Heliothis maritima, Sparghamaki (Sparganothis), Spodoptera frugiperda (Heliothis maritima), Spodoptera frugiperda (Heliothis maritima) fusca), Dokuga (Euproctis subflava), Tobimon Oedashaku (Biston robustum), Tomato fruit worm (Heliothis zea), Nakajiroshitaba (Aedia leucomelas), Nashiiraga (Narosoideus flavidorsalis), Nashikenmon (Viminia rumicis), Nashikenmon (Viminia rumicis) Oriental fruit moth (Grapholita molesta), Nashihosoga (Spulerina astaurota), Nashimadarameiga (Ectomyelois pyrivorella), Nikameiga (Chilo suppressalis), Negikoga (Acrolepiopsis sapporensis), Noshimemadarameiga (Plodia interpunctella), Noshimemadarameiga (Plodia interpunctella) Sitotroga ceralella), Spodoptera litura, Eucosma aporema, Acleris comariana, Scopelodes contracus, Orgyia thyell ina), Fall Army Worm (Spodoptera frugiperda), Fukinomeiga (Ostrinia zaguliaevi), Futaobikoyaga (Naranga aenescens), Futatenkagibamodoki (Andraca bipunctata), Grape gypsy moth (Paranthrene regalis), Grape gypsy moth (Acosmeryx castanea) toparcha, grape himehamaki (Endopiza viteana), grape hosohamaki (Eupoecillia ambiguella), velvet bean caterpillar (Anticarsia gemmatalis), hosobahaiirohamaki (Cnephasia cinereipalpana), gypsy moth (Lymantria dispar), gypsy moth (Lymantria dispar), gypsy moth (Lymantria dispar) Gypsy vorella), Gypsy moth (Maruca testulalis), Gypsy moth (Matsumuraeses phaseoli), Gypsy moth (Caloptilia soyella), Gypsy moth (Phyllocnistis citrella), Gypsy moth (Hadylepta indicata), Cabbage white moth (Hadylepta indicata) Cabbage white moth (Acanthoplusia agnata), Minoga (Bambalina sp.), Peach gypsy moth (Carposina niponensis), Gypsy moth (Conogethes punctiferalis), Peach gypsy moth (Synanthedon sp.), Cabbage white moth (Lyonetia apia clerkella) White butterflies such as the cabbage white butterfly (Colias erate poliographus), the cabbage white butterfly (Phalera flavescens), the cabbage white butterfly (Pieris rapae crucivora), the cabbage white butterfly (Pieris rapae), the yellow-tail moth (Euproctis similis), and the gypsy moth (Acrolepi). ukiella), European cornballer (Ostrinia nubilalis), Spodoptera frugiperda (Mamestra brassicae), Spodoptera frugiperda (Ascotis selenaria), Spodoptera frugiperda (Phtheochroides clandestina), Apple fruit moth (Hoshinoa adumbratana), Apple fruit moth (Hoshinoa adumbratana) Triaena intermedia), apple fruit moth (Adoxophyes orana fasciata), apple fruit moth (Grapholita inopinata), apple fruit moth (Spilonota ocellana), apple fruit leafminer (Spilonota lechriaspis), apple fruit moth (Illiberis pruni) Sinkui (Argyresthia conjugella), apple fruit moth (Caloptilia zachrysa), apple fruit moth (Archips breviplicanus), cotton leafminer (Anomis flava), cotton leafminer (Pectinophora gossypiella), cotton leafminer (Notarcha derogata), cotton leafminer (Notarcha derogata), cotton leafminer (Notarcha derogata) Heliothis virescens), Watalinga (Earias cupreoviridis), and Tomato leafminer (tentative name, Tuta absoluta, English name Tomato leaf miner), etc.

Examples of the stink bugs include the stink bug (Nezara antennata), the stink bug (Stenotus rubrovittatus), the stink bug (Graphosoma rubrolineatum), the stink bug (Trigonotylus coelestialium), and the stink bug (Trigonotylus coelestialium). Aeschynteles maculatus), red stink bug (Creontiades pallidifer), stink bug (Dysdercus cingulatus), stink bug (Chrysomphalus ficus), stink bug (Aonidiella aurantii), stink bug (Aonidiella aurantii), stink bug (Aonidiella aurantii), stink bug (Graptopsalt) Kaigaramushi (Icerya purchasi), Ichimonjikamemushi (Piezodorus hybneri), Inekamemushi (Lagynotomus elongatus), Inekiirohimeyokobai (Thaia subrufa), Inekurokamemushi (Scotinophara lurida), Ibarahigenagai , Aspidiotus destructor, Taylorilygus pallidulus, Myzusmumecola, Pseudaulacaspis prunicola, Pseudaulacaspis prunicola, Acyrthosiphon stink bug, Acyrthosiphon pisum , Ectometopterus micantulus, Eysarcoris lewisi, Molipteryx fulginosa, Cicadella viridis, Rhopalosophium ru ia oleae), Onsitsukonajirami (Trialeurodes vaporariorum), Kashihimeyokobai (Aguriahana quercus), Kasumi turtles (Lygus sp.), Kabawatafukimadara aphids (Euceraphis punctipennis), Kankitsukaigaramushi (Andaspis koshi) ), Cavelerius saccharivorus, Galetas spinifrons, Macrosiphoniella sanborni, Aonidiella citrina, Kusagi scale insects (Halyomorpha mista), Halyomorpha mista, scale insects, scale insects, scale insects, scale insects, scale insects, scale insects, scale insects, scale insects, scale insects, scale insects, scale insects, scale insects, scale insects, scale insects. camphorae, spider helicopter (Leptocorisa chinensis), triosa quercicola, walnut ganbai (Uhlerites latius), grape leaf hopper (Erythroneura comes), black-spotted scale insect (Paromius exguus), black-tailed scale insect (Paromius exguus) ), Cross-dwelling tuna (Nephotettix nigropictus), Kurotobikasumikame (Halticiellus insularis), Kurofutsunounka (Perkinsiella saccharicida), Kuroringo-kijirami (Psylla malivorella), Kuwaki-jirami (Anomomeura mori), Kuwaki-jirami (Anomomeura mori) Scale insect (Pseudaula caspis pentagona), Kuwata scale insect (Pulvinaria kuwacola), Koaokasumi turtle (Apolygus lucorum), Kobane leopard scale insect (Togo hemipterus), Komikan aphid (Toxoptera aurantii), Satoukibiko coccus sacchari), Satoukibinewatamushi (Geoica lucifuga), Satonousuirouunka (Numata muiri), Sanhose scale insect (Comstockaspis perniciosa), Citrus snow scale (Unaspis citri), Potato beetle aphid (Aulacorthum solani) ), Silver leaf aphid (Bemisia argentifolii), white-spotted aphid (Cicadella spectra), white-spotted aphid (Aspidiotus hederae), squirrel aphid (Liorhyssus hyalinus), seguro-himeki-jirami (Calophya nigridorsalis), Seguro-himeki-jirami (Calophya nigridorsalis) Aphid (Megoura crassicauda), Daikon aphid (Brevicoryne brassicae), Soybean aphid (Aphis glycines), Tiwan spider aphid (Leptocorisa oratorius), Tiwan tsumaguro yokobai (Nephotettix virescens), Tiwan higenaga aphid (Uroeucon) , Tobacco aphid (Bemisia tabaci), Chanokatakaigaramushi (Lecanium persicae), Chanokurohoshikaigaramushi (Parlatoria theae), Chanomarukaigaramushi (Pseudaonidia paeoniae), Chanomidorihimeyokobai (Empoasca onukii), Chabanea st. Tulip aphid (Dysaphis tulipae), Tulip aphid (Macrosiphum euphorbiae), Tsutsujigunbai (Stephanitis pyrioides), Tsunoroumushi (Ceroplastes ceriferus), Tsubakikurohoshikaigaramushi (Parlatoria camelliae), Tsumaguro Aokasumi Scale insects (Nephotettix cincticeps), scale insects (Glaucias subpunctatus), scale insects (Orthotylus flavosparsus), corn aphids (Rhopalosiphum maidis), corn scale insects (Peregrinus maidis), corn scale insects (Peregrinus maidis), scale insects (Peregrinus maidis), scale insects (Peregrinus maidis) abieti, Nila parvata lugens, Psylla tobirae, Eurydema rugosum, Schizaphis piricola, Psylla pyricola, Psylla pyricola, Nacyclohoshi scale insect (Parlatoreopsi) Scale insects (Dysmicoccus wistariae), scale insects (Lepholeucaspis japonica), pear aphids (Sappaphis piri), fake aphids (Lipaphis erysimi), Negia aphids (Neotoxoptera formosana), Haskubi aphids (Neotoxoptera formosana) (Edwardsianarosae), Harannaga scale insect (Pinnaspisaspidistrae), Hannokijirami (Psylla alni), Hannonagayokobai (Speusotettix subfusculus), Hannohimeyokobai (Alnetoidia alneti), Himeunka (Sogatella panicicola), Hiemega (Sogatella panicicola) (Dysdercus poecilus), scale insect (Parlatoria ziziphi), Himegunbai (Uhlerites debile), Himetobiunka (Laodelphax striatellus), Himenagame (Eurydema pulchrum), Himeharikamemushi (Cletus trigonu) s), Himeftatenagaawafuki (Clovia punctata), Himeyokobai (Empoasca sp.), Hirata scale insect (Coccus hesperidum), Hirata scale insect (Pachybrachius luridus), Fujikonakaigaramushi (Planococcus kra) Stenotus binotatus, Arboridia apicaris, Macrosteles fascifrons, Dolycoris baccarum, Adelphocoris triannulatus, Viteus vitifolii, scale insects, scale insects, scale insects, scale insects, scale insects, scale insects, scale insects, scale insects, scale insects, scale insects, scale insects, scale insects sordidus), scale insect (Leptocorisa acuta), scale insect (Macropes obnubilus), scale insect (Cletus punctiger), scale insect (Riptortus clavatus), potato scale insect (Paratrioza cockerelli), potato scale insect (Paratrioza cockerelli) Kasumi turtle (Lygus disponsi), Madara Kasumi turtle (Lygus saundersi), Matsuko scale insect (Crisicoccus pini), Matsuhime Yokobai (Empoasca abietis), Matsumoto scale insect (Crisicoccus matsumotoi), Mame abramushi (Aphi) , Marushirahoshikamemushi (Eysarcoris guttiger), Mikankakikaigaramushi (Lepidosaphes beckii), Mikankijirami (Diaphorina citri), Mikankuroabramushi (Toxoptera citricidus), Mikankonakaigaramushi (Planococcus citri), Mikankonajira (Planococcus citri) Aleurocanthus spiniferus), Pseud scale insect ococcus citriculus, Zyginella citri, Pulvinaria citricola, Coccus discrepans, Pseudaonidia duplex, Pseudaonidia duplex, Pulvinaria aphid, Pulvinaria aphid, aphid, aphid, aphid, aphid, aphid, aphid, aphid, aphid, aphid, aphid corni), Minamia aphid (Nezara viridula), Wheat turtle (Stenodema calcaratum), Wheat aphid (Rhopalosiphum padi), Wheat aphid (Sitobion akebiae), Wheat aphid (Schizaphis graminum), Mugimidria aphid (Schizaphis graminum) Aphids (Brachycaudus helichrysi), purple aphids (Carpocoris purpureipennis), Momoka aphids (Myzus persicae), Momokofuki aphids (Hyalopterus pruni), Yanagia aphids (Aphis farinose yanagicola), Aphis farinose yanagicola, Yanagigunbai ), Yamaasakijirami (Mesohomotoma camphorae), Yukiyanagi aphid (Aphis spiraecola), apple aphid (Aphis pomi), apple aphid (Lepidosaphes ulmi), apple aphid (Psylla mali), apple aphid (Psylla mali), apple aphid (Heterocordylu) malisuctus), apple aphid (Aphidonuguis mali), apple aphid (Orientus ishidai), apple aphid (Ovatus malicolens), apple aphid (Eriosoma lanigerum), ruby aphid (Ceroplastes rubens), cotton aphid (Aphis gossyp) ,

Examples of Coleoptera (Coleoptera) include Cylas formicarius (Xystrocera globosa), Cylas formicarius (Paederus fuscipes), Eucetonia roelofsi, Cylas formicarius (Callosobruchus chinensis), Cylas formicarius (Callosobruchus chinensis), Cylas formicarius (Callosobruchus chinensis) Weevil (Hypera postica), Weevil (Echinocnemus squameus), Cylas formicarius (Oulema oryzae), Cylas formicarius (Donacia provosti), Cylas formicarius (Lissorhoptrus oryzophilus), Weevil weevil (Colasposoma dauricum), Weevil weevil (Colasposoma dauricum) Cylas formicarius (Acanthoscelides obtectus), Western corn root worm (Diabrotica virgifera virgifera), Cylas formicarius (Involvulus cupreus), Cylas formicarius (Aulacophora femoralis), Cylas formicarius (Bruchus pisorum), Cylas formicarius (Bruchus pisorum), Cylas formicarius (Bruchus pisorum) Deokisui (Carpophilus dimidiatus), turtle weevil (Cassida nebulosa), weevil (Luperomorpha tunebrosa), weevil weevil (Phyllotreta striolata), weevil (Psacothea hilaris), weevil (Psacothea hilaris), weevil (Psacothea hilaris), weevil Carpophilus hemipterus, Oxycetonia jucunda, corn root worms (Diabrotica sp.), Mimela splendens, weevil (Sitophilus zeamais), Cylas formicarius (Triboliu) m castaneum, red flour beetle (Sitophilus oryzae), red flour beetle (Palorus subdepressus), red flour beetle (Melolontha japonica), sesame seedling (Anoplophora malasiaca), sesame leaf beetle (Neatus picipes), leaf beetle (Neatus picipes), leaf beetle (Neatus picipes), leaf beetle (Neatus picipes) undecimpunctata howardi, Sphenophorus venatus, Crioceris quatuordecimpunctata, Conotrachelus nenuphar, Ceutorhynchidius albosuturalis, Ceutorhynchidius albosuturalis , Sitona japonicus, Adoretus tenuimaculatus, Tenebrio molitor, Basilepta balyi, Hypera nigrirostris, Hypera nigrirostris, Hypera nigrirostris, Red Flour Beetle, Red Flour Beetle, Red Flour Beetle, Red Flour Beetle, Red Flour Beetle, Red Flour Beetle, Red Flour Beetle, Red Flour Beetle, Red Flour Beetle, Red Flour Beetle (Anomala cuprea), Nagachakogane (Heptophylla picea), Nijuyahoshitentou (Epilachna vigintioctopunctata), Northern corn root worm (Diabrotica longicornis), Hanamuri (Eucetonia pilifera), Leaf beetle (Agriotes spp.), Leaf beetle (Agriotes spp.) , Himekibanesaruhamushi (Pagria signata), Himekogane (Anomala rufocuprea), Himekokunusutomodoki (Palorus ratzeburgii), Himegomushidamashi (Alphitobius laevigatus) s verbasci), Confused flour beetle (Lyctus brunneus), Confused flour beetle (Tribolium confusum), Medythia nigrobilineata, Grape tiger kamikiri (Xylotrechus pyrrhoderus), Potato free beetle (Epitrix cucume) , Matsunomadarakamikiri (Monochamus alternatus), Mamekogane (Popillia japonica), Mamehanmyo (Epicauta gorhami), Maze Weevil (Sitophilus zeamais), Peach weevil (Rhynchites heros), Yasaizoumushi (Listroderes) maculatus), apple weevil (Phyllobius armatus), apple weevil (Anthonomus pomorum), Lurihamushi (Linaeidea aenea), cotton weevil (Anthonomus grandis), etc.

Diptera (Flies) include, for example, Agromyzidae (Culex pipiens pallens), Agromyzidae (Pegomya hyoscyami), Agromyzidae (Liriomyza huidobrensis), Housefly (Musca domestica), Rice leafminer (Chlorops oryzidae). Agromyzidae (Hydrellia sasakii), Agromyzidae (Agromyza oryzae), Agromyzidae (Hydrellia griseola), Agromyzidae (Hydrellia griseola), Agromyzidae (Ophiomyia phaseoli), Agromyzidae (Ophiomyia phaseoli), Agromyzidae (Dacus cucurbitae) Agromyzidae (Rhacochlaena japonica), Oye fly (Muscina stabulans), Okimon flies (Megaselia spiracularis) and other flies, Ocho fly (Clogmia albipunctata), Kiriujigagambo (Tipula aino), Kiriujigagambo (Tipula aino) ), Agromyzidae (Anopheles sinensis), Agromyzidae (Hylemya brassicae), Soybean leafminer (Asphondylia sp.), Agromyzidae (Delia platura), Onion fly (Delia antiqua), Cherry fruit fly (Rhagoletis cerasi), Chikaieka (Culex pisk) , Chichukai mibae (Ceratitis capitata), Chibikurobane mushroom fly (Bradysia agrestis), Tensaimogurihana fly (Pegomya cunicularia), Tomato leafminer (Liriomyza sativae), Nashamoguribae (Liriomyza bryoniae), Agromyzidae (Liriomyza bryoniae), Agromyzidae , Nettai Yeka (Culex quinquefa) sciatus), Aedes aegypti, Aedes albopictus, Liriomyza trifolii, Dacus dorsalis, Dacus tsuneonis, Dacus tsuneonis, Mugi tsuneonis, Mugi tsuneonis, Sitodiplosis (Anastrepha ludens), Aedes albopictus (Phagoletis pomonella), etc.

Examples of Hymenoptera (Hymenoptera) include Pristomyrmex pungens, Arigata bees, Monomorium pharaosis, Pheidole noda, Athalia rosae, Dryocosmus kuriphilus, and Dryocosmus kuriphilus. ), Spider bees (Vespidae spp.), Seguro kabra bees (Athalia infumata infumata), Churange bees (Arge pagana), Japanese bees (Athalia japonica), Hakiriari (Acromyrmex spp.), Fire ants (Solenopsis spp.) (Arge mali), Luriari (Ochetellus glaber), etc.

Examples of Orthoptera (Orthoptera) include Kusakiri (Homorocory phus lineosus), Mole cricket (Gryllotalpa sp.), Oxya hyla intricata, Oxya yezoensis, Migratory locust (Locusta migratoria), Oxya japonica (Locusta migratoria), and Oxya japonica. Himekusakiri (Homorocory phus jezoensis), Emma locust (Teleogryllus emma), etc.

Thrips include, for example, Thrips thrips (Selenothrips rubrocinctus), Thrips palmi Karny (Stenchaetothrips biformis), Thrips palmi Karny (Haplothrips aculeatus), Thrips palmi Karny (Ponticulothrips diospyrosi) Thrips palmi Karny ), Thrips thrips (Liothrips floridensis), Thrips simplex, Thrips nigropilosus, Thrips nigropilosus, Thrips haemorrhoidalis, Thrips haemorrhoidalis, Thrips thrips (Pseudodendrothrips) Thrips thrips (Leeuwenia pasanii), Thrips thrips (Litotetothrips pasaniae), Thrips citrus (Scirtothrips citri), Thrips chinensis (Haplothrips chinensis) dorsalis), Chanokuro thrips (Dendrothrips minowai), Thrips thrips (Haplothrips niger), Thrips tabaci, Thrips alliorum, Thrips alliorum, Thrips hawaiiensis Thrips thrips (Chirothrips manicatus), Thrips palmi Karny (Frankliniella intonsa), Thrips coloratus, Thrips palmi Karny (Franklinella occidentalis), Thrips palmi Karny (Thrips palm) Ma (Frankliniella lilivora), Thrips palmi Karny (Liothrips vaneeckei), etc.

Examples of ticks include house dust mites (Leptotrombidium akamushi), house dust mites (Tetranychus ludeni), American dock ticks (Dermacentor variabilis), house dust mites (Tetranychus truncatus), house dust mites (Ornithonyssus bacoti), house dust mites (Ornithonyssus bacoti), and house dust mites (Ornithonyssus bacoti). (Tetranychus viennensis), Kanzawa spider mite (Tetranychus kanzawai), mite such as Kuriirokoitamadani (Rhipicephalus sanguineus), Kwagatatsumedani (Cheyletus malaccensis), Kenagakonadani (Tyrophagus putrescentiae), Tyrophagus putrescentiae Dermacentor taiwanicus, Acaphylla theavagrans, Polyphagotarsonemus latus, Aculops lycopersici, Ornithonyssus sylvairum, Ornithonyssus sylvairum, Tyrophagus putrescentiae (Tetranychus) Sacroptes scabiei, Haemaphysalis longicornis, Black legd tick (Ixodes scapularis), Tyrophagus similis, Cheyletus eruditus, Mikan spider mite (Panonychus citri), Mikan spider mite (Panonychus citri), Mikan spider mite (Panonychus citri) phoenicis), Mimihizen mite (Octodectes cynotis), Yake leopard mite (Dermatophagoides ptrenyssnus), Yamato chimite (Haemaphysalis flava), Yamato mite (Ixodes ov) Atus), Ryukyu mikan sabi mite (Phyllocoptruta citri), apple sabi mite (Aculus schlechtendali), apple spider mite (Panonychus ulmi), Lone star tick (Amblyomma americanum), red mites (Dermanyssus gallinae), etc.

Examples of termites include termites (Reticulitermes miyatakei), Incisitermes minor (Incisitermes minor), Formosan subterranean termites (Coptotermes formosanus), Hodotermopsis japonica, Kanmon termites (Reticulitermes sp.), And termites (Reticulitermes sp.) ), Glyptotermes kushimensis, Coptotermes guangzhoensis, Neotermes koshunensis, Glyptotermes kodamai, Glyptotermes kodamai, Satsumashiro ant (Glyptotermes kodamai) ), Nakajima termites (Glyptotermes nakajimai), Nitobe termites (Pericapritermes nitobei), Yamato termites (Reticulitermes speratus), etc.

Examples of cockroaches include the Smokybrown cockroach (Periplaneta fuliginosa), the German cockroach (Blattella germanica), the German cockroach (Blatta orientalis), the brown cockroach (Periplaneta brunnea), the German cockroach (Blattella lituricollis), and the Japanese cockroach (Blattella lituricollis). (Periplaneta Americana) etc.

Examples of fleas include human fleas (Pulex irritans), cat fleas (Ctenocephalides felis), chicken fleas (Ceratophyllus gallinae), and the like.

Examples of nematodes include strawberry mesenchu (Nothotylenchus acris), rice root-knot nematode (Aphelenchoides besseyi), Kitanegusare nematode (Pratylenchus penetrans), Kitanekobu nematode (Meloidogyne hapla), sweet potato nematode co. Globodera rostochiensis), Javanese root-knot nematode (Meloidogyne javanica), Soybean cyst nematode (Heterodera glycines), Minaminegusare nematode (Pratylenchus coffeae), Wheat Negusare nematode (Pratylenchus neglectus), Mikannesenchu (Tench)

Mollusks include, for example, apple snails (Pomacea canaliculata), giant african snails (Achatina fulica), slugs (Meghimatium bilineatum), threeband gardenslugs (Lehmannina valentiana), slugs (Limacus flavus), and acusta despecta (Acusta despecta). Other examples include agricultural and horticultural pests such as Tuta absoluta.

The pest control agent composition of the present invention has an excellent control effect on various plant diseases, and is particularly suitable for controlling plant diseases of paddy rice, fruit trees, vegetables, other crops and flowers. Plant diseases belong to a wide variety of filamentous fungi, such as Phycomycetes, Ascomycetes, Ascomycetes, Deuteromycetes, and Basidiomycetes. Not only has an excellent bactericidal effect against fungi, but also has an excellent effect against phytopathogenic bacteria and phytoviruses.

Rice diseases include, for example: yellowing dwarf disease (S.macrospora), seedling blight (R.chinensis, T.viride), bakanae disease (G.fujikuroi), blast disease (M.grisea, P. oryzae), browning disease (Erwinia ananas), blight (R.solani), sesame leaf blight (C.miyabeanus), browning ear (A.padwiki), red rice (E.nigrum), rice koji Disease (C.virens), Rice blight (P.glumae), Leaf sheath browning disease (P.fuscovaginae), Brown streak (P.avenae), Seedling blight (P.plantarii), White leaf blight (P.plantarii) X.oryzae) etc .;

Examples of corn diseases include: sesame leaf blight (B.maydis, C.heterostrophus), soot spot disease (E.turcicum), spot disease (P.maydis), smut disease (U.maydis), etc.

Tobacco diseases include, for example: plague (P.nicotianae / parasitica), downy mildew (P.tabacina), powdery mildew (E.cichoracearum), anthrax (C.tabacum), gymnosporangium (A.longipes,) A.alternata), powdery mildew (C.salicinum), yellowing disease (O.brassicae), etc .;

Cha diseases include, for example: red granuloma disease (N.cinnabarina), white spot disease (E.leucospila), anthrax (C.theae-sinensis), ring spot disease (P.longiseta, P.theae). , Net blast (E.reticulatum), blast (E.vexans), red anthrax (P.syringae pv.theae), etc.;

Food crop diseases include, for example: sweet potato black spot disease (C.fimbriata), sweet potato blue mold disease (P.expansum), sweet potato root rot (T.basicora), embuck coronary rust (P.coronata), Bacterial disease (S.mori), oil palm ganoderma disease (G.boninense), nut palm eye spot disease (S.palmivora), etc.;

Examples of cruciferous diseases include: cruciferous root-knot disease (P.brassicae), cruciferous Chinese cabbage (A.macrospora), cruciferous cabbage (P.brassicae), cruciferous cabbage (S.sclerotiorum). ), Cabbage root decay (P.lingam), cabbage strain rot (T.cucumeris), rapeseed white spot (C.brassicicola), Chinese cabbage white spot (C.brassicicola), Chinese cabbage soft rot (Erwinia carotovora subsp. Carotovora) , Brassicaceae black spot disease (A.brassicae), cabbage black rot (X.campestris pv.campestris), etc.;

Examples of strawberry diseases include epidemics (P.cactorum, P.nicotianae), powdery mildew (S.macularis), anthrax (G.cingulata), black spot disease (A.alternata), and Janome disease (M.fragariae). )Such;

Examples of tomato diseases include: plague (P.infestans), anthrax (C.phomoides), leaf mold (C.fulvum), spot disease (S.lycopersici), ring pattern disease (A.solani), ulcer. Disease (C.michiganensis), etc .;

Examples of Solanaceae diseases include: Mycorrhizal disease (S.sclerotiorum), Udonko disease (S.furiginea), Brown rot of potato (P.vexans), Susukab disease (M.nattrassii), Bell pepper spot disease (S. .lycopersici), solanaceous spot disease (S.lycopersici), Solanaceae bacterial wilt (P.solanacearum), Solanaceae bacterial wilt (P.solanacearum), etc.;

Examples of Cucurbitaceae diseases include: Cucumber epidemic (P.melonis), Cucumber beetle disease (P.cubensis), Cucumber udonko disease (S.furiginea), Cucumber vine blight (M.melonis, D.bryoniae). ), Watermelon vine blight (M.melonis, D.bryoniae), Cucumber fungus nucleus disease (S.sclerotiorum),
Cucumber charcoal disease (C.lagenarium), cucumber brown spot disease (C.cassiicora), cucumber scab (C.cucumerinum), cucumber panama disease (F.oxysporum f.sp.cucumerinum, F.oxysporum f.sp.) meronis), cucumber spot bacterial disease (P.syringae pv. Lachrymans), etc.;

Examples of onion and onion diseases include: Negibeto disease (P.destructor), Negi soft rot (E.carotovora subsp.carotovora, E.chrysanthemi, E.rhapontici), Negi rust (P.allii), Negi. Black spot disease (A.porri), onion dwarf disease (Shallot yellow stripe virus), onion wilt disease (Fusarium oxysporum f.sp.cepae), onion seedling blight (Rhizoctonia solani), onion yellow stripe disease (Phytoplasma), onion Epidemic (Phytophthora nicotianae), onion yellow spot (Heterosporium allii), onion black rot (Sclerotium cepivorum), onion black astringent (Mycosphaerella allicina), onion black panicle (Urocystis cepulae Frost), onion small fungus nuclear rot ( Botrytis squamosa), onion white silk disease (Sclerotium rolfsii), onion white epidemic (Phytophthora porri), onion spot virus (Iris yellow spot virus), onion gray mold (Botrytis spp.), Onion leaf blight (Pleospora herbarum) , Onion red root rot (Pyrenochaeta terrestris), onion leaf blight (P. herbarum), onion fungal nucleus disease (S.sclerotiorum), onion gray rot (B.alli), onion white spot blight (B. byssoidea) , B. squamosa), onion dry rot (F.oxysporum f.sp.cepae), onion soft rot (E. carotovora subsp.), Onion black spot (A. porri), onion beetle (P. destructor) ), Onion gray mold (B. cinerea), Onion yellow dwarf virus, Onion leaf blight (Pleospora herbarum), Onion white plague (Phytophthora porri Foister), etc.;

Examples of root vegetable diseases include: carrot black leaf blight (A.dauci), radish black spot disease (A.brassicicola), etc.

Examples of flower diseases include: rose epidemic (P.megasperma), rose downy mildew (S.pannosa), downy mildew (K.rosae / japonica), rose scab (D.rosae), and brown spot disease. (S.chrysanthemi-indici), Kiku spot disease (C.chrysanthemi), Kiku white rust ((P.horiana), Chisha downy mildew (B.lactucae), Astor downy mildew (B.lactucae), root Cancer disease (A. tumefaciens), etc .;

Examples of turf / grass diseases include: turf red burning disease (P.apahanidermatum), turf summer patch (M.poae), turf hermint sporium leaf blight (D.poae), turf dollar spot (S.homoeocarpa). ), Clover scab (C.graminicora), Curvularia leaf blight (C.geniculata), Sturf large patch (R.solani), Brown patch (R.solani), Snow rot (Pythium sp., S.borealis, M.nivalis, F.nivale, T.ishikariensis, T.incarnata), grass black sesame disease (P.graminis), alfalfa leaf spot (P.medicaginis), clover leaf spot (P.trifolii), grass sesame Ear disease (E.typhina), alfalfa yellow spot disease (P.medicaginis), alfalfa stalk blight (P.medicaginis), etc.;

Examples of wheat diseases include: snow rot (Pythium sp., M.nivalis, S.borealis, F.nivale), snow rot (T.ishikariensis, T.incarnata), Fusarium head blight (G.zeae,) F.avenaceum, F.graminearum, F. culmorum, M.nivale), ergot disease (C.purpurea), wilt disease (G.graminis), strain rot (C.gramineum), sharp eyespot (C.cereale) , Udonko disease (B. graminis fsp. Tritici), Blight (L. nodorum, S. nodorum), Fusarium head blight (P. recondita), Black rust (P. graminis), Yellow rust (P. striiformis) ), Eye print disease (P.herpotrichoides), Leaf blight (S.tritici), Yellow spot disease (P.tritici-repentis), Streak disease (C.gramineum), Naked ergot disease (U.nuda), Wheat black ear Diseases (T.caries), to ergot disease (U.agropyri), etc .;

Examples of barley diseases include: snow rot (Pythium sp., S.borealis, M.nivalis, F.nivale, T.ishikariensis, T.incarnata), Fusarium head blight (G.zeae, M.nivale, F). .avenaceum, F.graminearum, F. culmorum), ergot disease (C.purpurea), wilt disease (G.graminis, O.graminis), streak disease (C.gramineum), udonko disease (B.graminis fsp) Hordei), net spot disease (P.teres), leaf spot disease (P.graminea), spot disease (B.sorokiniana, C.sativus), leaf burning disease (C.herbarm), cloud disease (R.secaris) , Black rust (P. graminis), Yellow rust (P. striiformis), Small rust (P. hordei), Hard ergot (U. hordei), etc.;

Potato diseases include, for example: powdery scab (S.subterranea), scab (S.scabies), plague (P.infestans), summer plague (A.solani), black bruise (R.solani). ), Ring rot (C.michiganensis), Ringlot's disease (C.michiganensis), etc .;

Examples of sugar beet diseases include: black root disease (A.sochlioides), leaf rot (T.cucumeris), root rot (T.cucumeris), Janome disease (P.betae), brown spot disease (C.beticora). , Spot disease (R.beticora), rust fungus (U.betae), etc.;

Diseases of soybeans include, for example: Azuki leaf disease (Phialophora gregata), Azuki stem epidemic (Phytophthora vignae), Azuki fungus nucleus disease (Sclerotinia sclerotiorum), Azuki gray mold (Botrytis cinerea), Azuki charcoal hum , Azuki brown spot bacterial disease (Pseudomonas syringae), Azuki stem rot bacterial disease (Pseudomonas sp), Soybean fungus nucleus disease (S.sclerotiorum), Soybean rust (P.pachyrhizi), Soybean bean disease (P.manshurica), Soybean purpura (C.kikuchii), soybean black spot disease (D.phaseolorum var. Sojae), soybean black sputum (E.glycines), soybean charcoal rot (M.phaseolina), soybean black root rot (C.crotalariae) , Lakkasei black root rot (C.crotalariae), Lakkasei black astringent disease (M.personatum), Lakkasei scab (S.arachidis), Lakkasei black mold (A.niger), Lakkasei brown spot disease (C.arachidicola) , Green bean brown spot disease (C.arachidicola), green bean charcoal disease (C.indemthianum), green bean root rot (F.solani f.sp.phaseoli), green bean wilt bacterial disease (C.flaccumfasiens), Azuki horn spot disease ( P.griseola), pea bean disease (P.pisi), pea udonko disease (E.pisi), soybean epidemic (P.nicotianae), soybean bean disease (P.viciae), soybean brown spot disease (A. fabae) etc .;

Examples of apple diseases include: Udonko disease (P.leucotricha), rotting disease (V.ceratosperma), white scab (R.necatrix), purple scab (H.mompa), scab (V. inaequaris), spot foliar disease (A.mali), monilia disease (M.mali), charcoal scab (G.cingulata), ring pattern disease (Botryosphaeria sp,), Blacklot disease (B.obtusa, X.campestris pv.) campestris), black spot disease (M.pomi), brown spot disease (D.mali), red spot disease (G.yamadae), cedar-apple rust (G.Juniperi-virginianae), Suehirotake disease (S.commune), silver Leaf disease (C. purpurreum), root cancer disease (A. tumefaciens), burn disease (E. amylovora), etc .;

Pear diseases include, for example: white spot feather disease (R.necatrix), scab (V.nashicola), scab (A.kikuchiana), gymnosporangium (G.asiaticum), udonko disease (P.pyri). ), Ring stain disease (P.piricora), Blight disease (P.fukushii), Heart rot (L.sulphureus), Radical cancer disease (A.tumefaciens), Erwinia amylovora (E.amylovora), etc.;

Grape diseases include, for example: white spot feather disease (R.necatrix), gray mold disease (B.cinerea), sticky disease (P. viticola), udonko disease (U.necator), late rot (G). .cingulata), black pox (E.ampelina), brown spot (P.vitis), rust (P.ampelopsidis), blacklot disease (G.bidwellii, X.campestris pv.campestris)), pestarocia vine withering Diseases (P.menezesiana), California disease (X.fastidiosa), root cancer disease (A.vitis), etc .;

Peach diseases include, for example: leaf mold (T.deformans), monilinia fructicola (M.fructicola), scab (C.carpophilum), phomopsis sp., And scab (A.niger). ), Spot disease (C.beyerinckii), root cancer disease (A.tumefaciens), perforated bacterial disease (X.campestris pv.pruni), etc.;

Examples of citrus diseases include: white spot feather disease (R.necatrix), gray mold disease (B.cinerea), black spot disease (D.citri), scab disease (E.fawcettii), black spot disease (G. citricarpa), round star disease (P.beltranii), charcoal scab (C.gloeosporioides), green mold (P.digitatum), blue mold (P. italicum), scab (G.applanatum), soot disease (C.salicinum), ulcer disease (X.campestris pv.citri), staborn disease (S.citri), greening disease (C.Liberibacter), etc.

Examples of kiwi diseases include: Kiwifruit scab (P.syringae pv.Actinidiaea, A.deliciosa, A.chinensis, A.arguta), etc.

Examples of tree / flower tree diseases include: Akebii udonko disease (M.akebiae), Hannoki udonko disease (M.penicillata), Orendanire and other niles wilt disease Dutch elm disease (O.ulmi), chestnut Bacterial blight (E.parasitica), Apricot blight (L..persoonii), Nile scab (G.ulmi), Sakura black knot (A.morbosa), Pine leaf sieving needle cast (L) .pinastri), pine soot leaf blight needle blight (R.kalkhoffii), pine Diplodia blight (S.sapinea), cherry rust (T.asiatica / prumi-spinosae), eel leaf rust (M. arctica), poplar leaf rust (M.medusae), button rust (C.flaccidum), oak trunk sapwood rot (S.hirsutum), hinoki root heart rot (H.annosum), pine root heart Rot (G.lucidum), scab (A.mellea), scab (T.versicolor), pine hump (C.quercum), pine leaf rust (C.asterum), walnut trunk Heart rot (P.igniarius), red pine red spot blight (D.septosporum), black pine red spot blight (D.septosporum), cherry trunk heart rot (F.pinicora), etc.;

Other fruit tree diseases include, for example: white crest disease (R.necatrix), Ume Udonko disease (P.tridactyla), Ume scab (C.carpophilum), oyster round star foliage disease (M.nawae), oyster Charcoal scab (G.kaki), oyster leaf blight (P.diospyri), oyster horn spot foliage disease (C.kaki), oyster scab (F.levieri), biwa charcoal scab (C.acutatum), banana stag beetle disease ( M.fijiensis / musicola), banana panama disease (F.oxysporum f.sp.cubense), root cancer disease (A.tumefaciens); mango charcoal disease (C.gloeosporioides), etc.;

The multi-criminal diseases include, for example: various seedling blight (P.ultimum, P.apahanidermatum), various root rot (P.cinnamomi), white crest disease (R.necatrix), rotting disease (V. ceratosperma), half-body wilt (V.dahliae, V.albo-atrum), gray mold (B.cinerea), mycorrhizal disease (S.sclerotiorum), white silk disease (S.rolfsii), vegetable wilt (R.solani), purple crest disease (H.mompa), soft rot (E.carotovora, E.aroideae), root cancer tumor disease (A.tumefaciens), etc.;

In addition, the bactericidal agent of the present invention has an excellent bactericidal effect against resistant bacteria. Resistant bacteria include Botrytis cinerea, Cercospora beticola, apple scab (Venturia inaequalis), and pear scab, which are resistant to benzimidazole fungicides such as thiophanatemethyl, benomyl, and carvendazim. (Venturia nashicola); Botrytis cinerea, which is resistant to dicarboxyimide-based fungicides (eg, benzimidazole, prosimidon, iprodion) and the like.

Examples of phytopathogenic bacterial diseases include: cucumber spot bacterial disease (P.syringae pv. Lachrymans), rice brown streak disease (P.avenae), rice seedling blight bacterial disease (P.plantarii), rice paddy bacterial disease. (P.glumae), Rice leaf sheath browning disease (P.fuscovaginae), Pseudomonas chinensis (P.solanacearum), Cha red burning disease (P.syringae pv.theae), Cucumber ulcer disease (X.campestris pv.citri) ), Cucumber black rot (X.campestris pv.campestris), Pseudomonas peach bacterial disease (X.campestris pv.pruni), Rice leaf blight (X.oryzae), Grape black lot disease (X.campestris pv.campestris) , Apple black lot disease (X.campestris pv.campestris), apple burn disease (E.amylovora), pear burn disease (E.amylovora), soft rot (E.aroideae, E.carotovora), Ingen wilt bacterial disease (C) .flaccumfasiens), root cancer disease (A.tumefaciens), grape root cancer disease (A.vitis), potato scabies (S.scabies), citrus stubborn disease (S.citri), tomatoes Cucumber disease (C.michiganensis), potato ring rot (C.michiganensis), Ringlot's disease (C.michiganensis), citrus greening disease (C.Liberibacter), etc.;

Diseases caused by plant viruses include, for example: tomato mosaic disease (tobacco mosaic virus), cucumber green spot mosaic disease (cucumber green spot mosaic virus), tobacco stem disease (tobacco stem virus), wheat species. Atrophy disease (wheat atrophy virus), wheat mottled leaf mosaic disease (wheat mottled leaf mosaic virus), potato mass stalk brown ring spot disease (potato mop top virus), tensai sore root disease (beetle leaf vein yellow virus), Tobacco mosaic disease (potatovirus X), apple high contact disease (apple stem grooving virus), apple high contact disease (apple chloroticif spot virus), tomato mosaic disease (potatovirus Y), Umewahan disease (Umewahan virus) , Cucumber mosaic disease (Zucchiniohan mosaic virus), Daikon mosaic disease (Cub mosaic virus), Soybean mosaic disease (Soybean mosaic virus), Omugi stripe dwarf disease (Omugi stripe atrophy virus), Omugi yellow wilt disease (Omugi yellow wilt virus) ), Soybean dwarf disease (soybean dwarf virus), Strawberry virus disease (Strawberry mild yellow edge virus), Potato leaf curl disease (potato leaf curl virus), Rice dwarf disease (rice dwarf virus), Cucumber mosaic disease (cucumber mosaic) Virus), alfalfa mosaic disease (alfalfa mosaic virus), northern mosaic disease (wheat northern mosaic disease), rice stripe blight (rice stripe blight virus), tomato yellow mosaic disease (tomato yellow mosaic disease) Virus), rice atrophy disease (rice atrophy virus), rice black streak atrophy disease (rice black streak atrophy virus), and the like.

The weeds that can be controlled by the harmful control composition of the present invention include dicotyledonous weeds such as Ipomoea, Lindernia, Sesbania, Conyza, Abutilon, and Inukamitsure (Abutilon). Matricaria, Rorippa, Urtica, Dead-nettles (Lamium), Onamomi (Xanthium), Karashi (Sinapis), Kikasigusa (Rotala), Kuwagatasou Inunofuguri (Veronica), Keshi (Papaver), Shiroza Aritasou Chenopodium, Trifolium, Portulaca, Viola, Pharmabitis, Galeopsis, Datura, Solanum, Capsella Noazami Fujiazami (Cirsium), Nogeshi (Sonchus), Hakidamegiku (Galinsoga), Hakobe (Stellaria), Hangosou Noborogiku Kion (Senecio), Hiyu Hagateus (Amaranthus), Butakusa (Ambrosia) Lamium), Mamegunbainazuna (Leipidium), Michiyanagi (Polygonum), Yaemgra Kinutasou (Galium), Yagurumagiku (Centaurea), Yomogi (Artemisia), etc.

The genus of monocotyledonous weeds is Azegaya (Leptochloa), Awagaeri Timothy (Phleum), Strawberry Tsunagi Suzumenokatabira (Poa), Fescues, Toboshigara (Festuca), Enokoro Awa (Setaria), Goosegrass Shikokubie (Eleus)・ Kwai (Sagittaria), Kamojigusa (Agropyron), Kamonohashi (Ischaemum), Kayatsurigusa, Papilus, Shichitoui, Hamasuge (Cyperus), Karasumugi, Otomugi (Embaku) (Avena), Kitsunegaya, Inumugi (Bromus), Kibi (Bromus) (Cynodon), Konagi (Monochoria), Suzumenoteppo (Alopecurus), Suzumenohie (Paspalum), Tsuyukusa (Commelina), Tentsuki (Fimbristylis), Ryegrass (Lolium), Nikukibi (Brachiaria), Nukabo (Agrostis), Hari , Echinochlona, Hotarui Ukiyagra Futoi (Scirpus), Mehishiba (Digitaria), Morokoshi (Sorghum), etc.

Specific examples of other weeds include Amaranthus retroflexus, Amaranthus viridis, Setaria faberi, Leersia japonica, Leersia japonica, Leptochloa chinensis, Leptochloa chinensis, Leptochloa chinensis, Amaranthus retroflexus, Amaranthus viridis, Amaranthus viridis Azena (Lindernia procumbens), Abnome (Dopatrium junceum), American Asagao (Ipomoea hederacea), American Azena (Lindernia dubia), American King deer (Sida spinosa), American Sana Etade (Polygonum pensylvanicum), American Tsunoxanem (Sesbania ex) Furo (Geranium carolinense), Erigeron bonariensis (Conyza bonariensis), Amaranthus powellii, Itadori (Polygonum cuspidatum), Ichibi (Abutilon theophrasti), Inukamitsure (Matricaria perforata), Inutade (Polygonum longisetum), Inutade (Polygonum longisetum) Amaranthus lividus, Solanum nigrum, Schoenoplectus juncoides (Roxb.) Palla, Murdannia keisak, Malva parviflora, Malva parviflora, Malva parviflora, Malva sylris Sagittaria pygmaea Miq), Ezonogishigishi (Rumex obtusifolius), Ezonosanukagusa (Leersia oryzoides (L.) Sw.), Enokorogusa (Setaria viridis), Ebisugusa (Cassia obtusifolia), Ooakabana (Epilobium hirsut) trensis, oat (Veronica persica), goosegrass (Spirodela polyrhiza), cocklebur (Xanthium canadens), oat (Coreopsis lanceolata), oat (Panicum dichotomiflorum), goosegrass (Panicum dichotomiflorum), goosegrass ), Amaranthus palmeri (Amaranthus palmeri), Cocklebur (Xanthium strumarium), Oat sterilis, Goosegrass (Eleusine indica), Goosegrass (Eleusine indica), Omodaka (Sagittaria trifolia), Netherlands , Dutch cocklebur (Cerastium glomeratum), goosegrass (Matricaria matricarioides), cocklebur (Matricaria chamomilla), crow no pea (Vicia angustifolia), oat (Bromus secalinus), oat (Avena fatua), oat (Avena fatua), oat (Avena fatua), oat (Avena fatua) Koehne, Rumex japonicus, Paspalum distichum, Cyperus esculentus, Setaria glauca, Pueraria lobata, Eleocharis kuroguwai Ohwi, Eleocharis kuroguwai Ohwi verticillata), goosegrass (Bolboschoenus maritimus (L.) Palla), corn marigold (Chrysanthemum segetum), kogomegayatsuri (Cyperus iria), kosendangusa (Bidens pilosa), oat (Monochoria vag) inalis, Echinochloa colona, Alisma plantago-aquatica, Oryza sativa, Polygonum lapathifolium, Agropyron repens, Sorghum vulgare, Sorghum vulgare, Sorghum vulgare ), Silky bentgrass (Apera spica-venti), Shiroza (Chenopodium album), Shirotsumekusa (Trifolium repens), Shirobana chosen asagao (Datura stramonium), Sugina (Equisetum arvense), Suzumenokatabira (Poa annua), Suzumenochahiki (Brom) , Alopecurus aequalis, Portulaca oleracea, Solidago altissima, Sorghum halepense, Brassica juncea, Brassica juncea, Taraxacium officin (Convolvulus arvensis), Dwarf mallow (Malva neglecta), Seri (Oenanthe javanica), Couch couch (Polygonum convolvulus), Echinochloa oryzicola Vasing, Taiwan Aiashi (Ischaemum rugosum), Corn speedwell (Ischaemum rugosum), Corn speedwell (Veronica) , Tarihonoaogaito (Amaranthus rudis), Choujitade (Ludwigia prostrata Roxburgh), Tsuyukusa (Commelina communis), Texas Panicum (Panicum texanum), Todaigusa (Euphorbia helioscopia), Nagabagishigishi (Rumex cris) astoris), Nishikisou (Euphorbia pseudochamaesyce), Nikkibi (Brachiaria plantaginea), Festuca perennial (Lolium multiflorum), Nosuzumenotepo (Alopecurus myosuroides), Noharagarashi (Sinapis arvensis), Noharagarashi (Sinapis arvensis), Hakidamegiku (Galinsoga) ), Amaranthus spinosus, Redshank (Polygonum persicaria), Papaver rhoeas, Helianthus annuus, Lamium purpureum, Kyllinga gracillima, Kyllinga gracillima, Horseweed (Kyllinga gracillima), Horseweed (Amaranthus spinosus) Hilmushiro (Potamogeton distinctus A. Benn), Red Deadnettle (Amaranthus tuberculatus), Field Pansy (Viola arvensis), Butakusa (Ambrosia artemisiifolia), Frasabasou (Veronica hederaefolia), Blackgrass (Alopecurus myosuroides), Florida Begerweed , Heraoobaco (Plantago lanceolata), Heraomodaka (Alisma canaliculatum A. Br.et Bouche), Houkigi (Kochia scoparia), Boumugi (Lolium rigidum), Hosobahimemisohagi (Ammannia coccinea), Hosomugi (Lolium perennea) ), Hotokenoza (Lamium amplexicaule), Hossmo (Najas graminea), Amaranthus hybridus, Matsubai (Eleocharis acicularis L.), Mameasagao (Ipomoea lacunosa), Marubaasagao (Ipomoea purpurea), Malva American Asagao (Ipomoea hederacea var integriuscula), Marubatsuyukusa (Commelina bengharensis), Mizuaoi (Monochoria korsakowii), Mizugayatsuri (Cyperus serotinus Rottboel), Digitaria ciliaris (Cyperus serotinus Rottboel), Elatine triandra (Digitaria sanguinalis), Morokoshi (Sorghum bicolor), Yaemgra (Galium aparine), Yomogi (Artemisia princeps), Wild Pansy (Viola tricolor), Wild Radish (Raphanus raphanistrum), Wasurenagusa (Myosotis arvensis), Heraomodaka (Alisma canalicum) (Cyperus flaccidus) and the like.

Other weeds that can be controlled are Inubie (annual rice family, weeds in paddy fields), Azena (annual sesame family, weeds in paddy fields), Konagi (annual plants of Mizuaoi family, weeds in paddy fields), Mizuaoi. (Mizuaoi family annuals, paddy field weeds), Himemisohagi (Misohagi family annuals, paddy field weeds), Tamagayatsuri (Kayatsurigusa annuals, paddy field weeds), Matsubai (Kayatsurigusa annuals, wetlands, waterways, paddy fields) Occurrences in paddy fields), Omodaka (Omodaka family, paddy fields, marshes, perennial weeds that occur in ditches), Urikawa (Omodaka family, paddy fields, marshes, perennial weeds that occur in ditches), Inuhotarui (Occurs in paddy fields, marshes, ditches), Kuroguwai (occurs in paddy fields, marshes, ditches), Suzumenoteppo (occurs in rice family annuals, paddy field backs, lowlands), crow wheat (rice family annuals, (Occurs in flatlands, wastelands, and upland fields), Yomogi (occurs in Kiku family annuals, mountains, and upland fields), Mehishiba (annual rice plants, fields, orchard weeds), Gishigishi (occurs in Tade family annuals, upland fields, roadsides) Outbreak), Kogomegayatsuri (annual Kayatsurigusa, annual weeds in the field), Aobiyu (annual Hiyu, vacant lots, roadsides, upland), Onamomi (annual Kiku, weeds in the field), Ichibi (Aoi) Annuals (annuals, upland weeds), Shirobanayoushuchosenasagao (annuals of the eggplant family, upland weeds), Oinunofuguri (annual grasses of the Gomanohagusa family, weeds of upland fields) or Yaemgra (annual weeds of the Akane family, upland fields, trees) It is an annual, perennial or perennial weed that occurs in paddy fields, fields, orchards, or marshes such as weeds in gardens.

The pest control agent composition of the present invention is used for other agricultural and horticultural insecticides, acaricides, and line killing agents depending on the usage situation for the purpose of expanding the control target organism, the optimum control period, or reducing the amount of the drug. It can also be used in combination with insecticides, bactericides, biopesticides, herbicides, plant growth regulators, pesticides (also called safeners), soil conditioners, fertilizers, etc. Representative compounds are exemplified below, but the compounds are not limited thereto.

Other agricultural and horticultural insecticides, acaricides and nematode pesticides used for this purpose include, for example, 3,5-xylyl methylcarbamate (XMC), Bacillus thuringiensis aizawai, Bacillus thuringiensis israelensis, Bacillus thuringiensis japonensis, Bacillus thuringiensis kurstaki, Bacillus. thuringiensis tenebrionis, crystal protein toxin produced by Bacillus thuringiensis, BPMC, Bt toxin insecticidal compound, CPCBS (chlorfenson), DCIP (dichlorodiisopropyl ether), DD (1, 3-Dichloropropene), DDT, NAC, O-4-dimethylsulfamoylphenyl O, O-diethyl phosphorothioate (DSP), O-ethyl O-4-nitrophenyl phenylphosphonothioate (EPN), tripropylisocyanurate (TPIC), acrinathrin, acinonapyr, azadirachtin, azinphos -methyl, acequinocyl, acetamiprid, acetoprole, acephate, abamectin, afidopyropen, avelmectin-B, amidoflumet, amitrazu amitraz, alanycarb, aldicarb, aldoxycarb, aldrin, alpha-endosulfan, alpha-cypermethrin, albendazole, Allethrin, isazofos, isamidofos, isoamidephos (i) soamidofos, isoxathion, isocycloseram, isofenphos, isoprocarb (MIPC), epsilon-metofluthrin, epsilon-monfluthrin (epsilon-momfluorothrin), ibermethrin Imiciafos, imidac1oprid, imiprothrin, indoxacarb, esfenvalerate, ethiofencarb, ethion, ethiprole, ethiprole, ethoxole Etofenprox, ethoprophos, etrimfos, emamectin, emamectin-benzoate, endosulfan, empentrin, oxazosulfyl, oxazosulfyl, oxamil Oxamyl, oxydemeton-methyl, oxydeprofos (ESP), oxibendazole, oxfendazole, Potassium oleate, sodium oleate ), Cadusafos, kappa-bifenthrin, cartap, carbary1, carbosulfan, carbofuryl, gamma-cyhalothrin, xylylcarb. ), Quinalphos, kinoprene, chinamethionat, cloethocarb, clothianidin, black Clofentezine, chromafenozide, chlorantraniliprole, chlorethoxyfos, chlordimeform, chlordane, chlorpyrifos, chlorpyrifos, chlorpyrifos-methyl. Chlorphenapyr, chlorfenson, ch1orfenvinphos, chlorfluazuron, chlorobenzilate, chlorobenzoate, chloroprallethrin, kersen (chlorphenapyr), chlorfenapyr (chlorfenson), chlorfenvinphos (ch1orfenvinphos) Dicofol: dicofol, salithion, cyhalodiamide, cyanophos (CYAP), diafenthiuron, diamidaphos, cyantraniliprole, theta-cypermethrin (theta- cypermethrin, dienochlor, cyenopyrafen, dioxabenzofos, diofenolan, sigma-cypermethrin, cyclaniliprole, dichlorphenthion, dichlofenthion Cycloprothrin, dichlorvos (DDVP), dichlorromezotiaz, disulfoton, dinotefuran, cyhalodiamide, cyhalothrin, cyphenothrin, cyphenothrin, cyhalothrin, dichlorvos (DDVP), dichlorvos (DDVP), dicloromezotiaz, disulfoton, dinotefuran, cyhalodiamide, cyhalothrin cyfluthrin), diflubenzuron, cyflumetofen, diflumetofen Diflovidazin, cyhexatin, cypermethrin, dimpropyridaz, dimethylvinphos, dimethoate, dimefluthrin, dimefluthrin, silafluofen, silafluofen, silafluofen spinetoram, spinosad, spirodiclofen, spiropidion, spirotetramat, spiromesifen, sulfluramid, sulprofos, sulfoxaflor , Zeta-cypermethrin, diazinon, tau-fluvalinate, dazomet, thiacloprid, thiamethoxam, tioxazafen, tioxazafen, thiodicarb Thiocyclam, thiosultap, thiosultap-sodium, thionazin, thiometon, tyclopyrazoflor, deet, dieldrin, tetramethrin Tranylliprole, tetrachlorantraniliprole, tetrach1orvinphos, tetradifon, tetraniliprole, tetramethylfluthrin, tetramethrin, tebupirimfos, tebupirimfos, tebupirimfos Tebufenpyrad, tefluthrin, teflubenzuron, deme Ton-S-methyl (demeton-S-methyl), temephos, deltamethrin, terbufos, doramectin, tralopyril, tralomethrin, transfluthrin, Triazamate, triazuron, trichlamide, trichlorphon (DEP), triflumezopyrim, triflumuron, tolfenpyrad, naled (BRP), nithiazine , Nitenpyram, novaluron, noviflumuron, hydroprene, vaniliprole, vamidothion, parathion, parathion-methyl, halphenprox (parathion-methyl), parathion (parathion), parathion (parathion), parathion (parathion), parathion (parathion), parathion (parathion) halfenprox), halofenozide, bistrifluron, bisultap, hydramethylnon, hydroxy propyl starch, binapacryl, pyflubumide, bifenazate , Bifenthrin, pymetrozine, pyraclorfos, pyrafluprole, pyridafenthion, pyridaben, pyridalyl, pyridalyl, pyrifluquinazon, pyrifluquinazon, pyrifluquinazon Fen (pyriproxyfen), pyrimicarb (pirimicarb), pyrimidifen (pyrimidifen), pyriminostrobi n), pyrimiphos-methy1, pyrethrins, fiproni1, fenazaquin, fenamiphos, phenisobromolate (bromopropylate), fenitrothion (MEP), phenoxycarb , Fenothiocarb, phenothrin, fenobucarb, fensulfothion, fenthion (MPP), phenthoate (PAP), fenvalerate, fenpyroximate, fenpyroximate Fenpropathrin, fenbendazole, fosthiazate, formetanate, butathiofos, buprofezin, furathiocarb, prallethrin, fluacrypyrim Zindrindolizine, flupyrimin, fluazinam, fluazuron, fluensulfone, fluxametamide, flucycloxuron, flucythrinate, fluvalinate (fluvalinate), flufiprole, flupyradifurone, flupyrazofos, flufenerim, flufenoxystrobin, flufenoxuron, flufenzine, flufenzine flufenoprox), fluproxyfen, flubrocythrina te), fluhexafon, flubendiamide, flumethrin, flurimfen, prothiofos, protrifenbute, flonicamid, propaphos, propargit (te), fluhexafon, flubendiamide, flumethrin, flurimfen, prothiofos. propargite: BPPS, profenofos, broflanilide, profluthrin, propoxur (PHC), fromometoquin, alpha-bromadiolone, bromopropylate, Beta-cyfluthrin, hexaflumuron, hexythiazox, heptafluthrin, heptenophos, permethrin, benclothiaz, bendiocarb Moxane (benzpyrimoxan), bensu1tap, benzoximate, benfuracarb, hoxim, phosalone, fosthiazate, fosthietan, phosphamidon, phosphocarb phosphocarb, phosmet (PMP), polynactins, formethanate, formothion, phorate, machine oil, malathion, milbemycin, milbemycin -A (milbemycin-A), milbemectin, mecarbam, mesulfenfos, methomyl, metaaldehyde, Metaflumizone, methamidophos, metam-ammonium, metam-sodium, metiocarb, methidathion (DMTP), methylisothiocyanate, methyl neothiocyanate Namide (methyl neodecanamide), methyl parathion, metoxadiazone, methoxychlor, methoxyfenozide, metoflutrin, metoprene, metolcarb, meperfluthrin, meperfluthrin, meperfluthrin. , Monocrotophos, monosultap, momfluorothrin, lambda-cyhalothrin (lamb)
da-cyhalothrin, ryanodine, lufenuron, rescalure, resmethrin, lepimectin, rotenone, levamisol hydrochloride, fenbutatin oxide, tartrate acid Morantel tartarate, methyl bromide, cyhexatin hydroxide, calcium cyanamide, lime sulfur, sulfur, and nicotine- Sulfur) and the like can be exemplified.

Agribenzolar-S-methyl, for example, aureofungin, azaconazole, azithiram, acypetacs, acibenzolar, acibenzolar-S-methyl, as agricultural and horticultural fungicides used for the same purpose. ), Azoxystrobin, anilazine, amisulbrom, Isocycloseram, ampropylfos, ametoctradin, allyl alcohol, aldimorph , Ambam, isothianil, isovaledione, isopyrazam, isofetamid, isoflucypram, isoprothiolane, ipconazole, ipfentrifluconazole, ipfentrifluconazole, isoflucypram, isoprothiolane, ipconazole , Ipflufenoquin, iprodione, iprovalicarb, iprobenfos, imazalil, iminoctadine, metam, iminoctadine albesilate- Iminoctadine-triacetate, imibenconazole, impyrfluxam, uniconazole, uniconazole-P, echlomezole, edifenphos, etaconazole etaconazole, ethaboxam, ethirimol, etem, ethoxyquin, etridiazole, enestrobur in), enoxastrobin, epoxiconazole, oxadixyl, oxathiapiprolin, oxycarboxin, oxyquinolin copper (copper-8-quinolinolate), oxytetracycline (Oxytetracycline), copper-oxinate, oxpoconazole, oxpoconazole-fumarate, oxolinic acid, octhilinone, ofurace, Orysastrobin, carbam (carbam, metam-sodium), kasugamycin, carbamorph, carpropamid, carpropamid, carbenazim, carvone, carvone, quinazamid , Kinacetol, quinoxyfen, quinofumelin, quinomethionat, quinomethionate, captafol, captan, kiralaxyl, quinconazole, quintozen , Guazatine, cufraneb, cuprobam, coumoxystrobin, glyodin, griseofulvin, climbazole, cresol, cresoxim-methyl methyl, chlozolinate, clotrimazole, chlobenthiazone, chloraniformethan, chloranil, chlorquinox (c) hlorquinox, chloropicrin, chlorfenazole, chlorodinitronaphthalene, chlorothalonil, chloroneb, salicylanilide, zarilamid, siazofamid, cyazofamid Diethyl pyrocarbonate, diethofencarb, cyclafuramid, cyclafuramid, diclocymet, dichlozoline, diclobutrazol, dichlofluanid, cycloheximide, cycloheximide, cycloheximide Azox (dichlobentiazox), dichromezine (diclomezine), dichlorolan (dicloran), dichlorophen (dichlorophen), dichlone, disulfiram, ditalimfos, dithianon, diniconazole (diniconazole), diniconazole (Diniconazole-M), dineb, dinocap, dinocton, dinosulfon, dinoterbon, dinobuton, dinopenton, dipymetitrone, dipyritione di , Diphenylamine, diphenoconazole, cyflufenamid, diflumetorim, cyproconazole, cyprodinil, cyprofuram, cyprofuram, cypendazole, cypendazole, cypendazole, cypendazole, cypendazole dimethirimol), dimethorimol omorph, cymoxanil, dimoxystrobin, ziram, silthiofam, streptomycin, spiroxamine, sultropen, sedaxane, zoxamide , Dazomet, thiadiazin, tiadinil, thiadifluor, thiabendazole, tioxymid, thiochlorfenphim, thiophanate, thiophanate-methyl methyl, thiofluzamide, thicyofen, thioquinox, thiram, decafentin, tecnazene, tecloftalam, tecoram, tetraconazole , Debacarb, dehydroacetic acid, tebuconazole, tebufloquin, dodicin, dodine, bisethylenediamine copper complex salt (II) (DBEDC), dodemorph (dodemorph) dodemorph, drazoxolon, triadimenol, triadimefon, triazbutil, triazoxide, triamiphos, triarimol, trichlamide, triclopyricalbu (triclopyricarb), tricyclazole, triticonazole, tridemorph, tributyltin oxide, triflumizole (t) riflumizole, trifloxystrobin, triforine, tolylfluanid, tolclofos-methyl, tolprocarb, natamycin, nabam, nitrostyrene. ), Nitrothal-isopropyl, nuarimol, copper nonylphenol sulfonate, halacrinate, validamycin, valifenalate, harpin protein , Picarbutrazox, bixafen, picoxystrobin, picobenzamide, pydiflumetofen, bithionol, bitertanol, hydroxyisoxazole ( hydroxyisoxazole, hydroxyisoxazole-potassium, binapacryl, biphenyl, piperalin, hymexazol, pyraoxystrobin, pyracarbolid, pyracrolto Robin (pyraclostrobin), pyrapropoyne (pyrapropoyne), pyraziflumid (pyraziflumid), pyrazophos (pyrazophos), pyrametostrobin, pyriofenone (pyriofenone), pyridinitrile (pyridinitril), pyridiflumethofen (pydiflumetofen) Pyridachlometyl, pyrifenox, pyribencarb, pyriminostrobin (Pyriminostrobin), pyrimetanil, pyroxychlor, pyroxyfur, pyroxyfur, pyroquilon, vinclozolin, ferbam, famoxadone, famoxadone, fenapanil, fenadone, fenapanil (Fenaminosulf), fenaminstrobin, fenarimol, fenitropan, fenoxanil, ferimzone, ferbam, fentin, fenpiclonil, fenpicoxa Mido (fenpicoxamid), fenpyrazamine (fenpyrazamine), fenbuconazole (fenbuconazole), fenfuram (fenfuram), fenpropidin (fenpropidin), fenpropimorph (fenpropimorph), fenhexamid (fenhexamid), phthalide (phthalide) buthiobate, butylamine, bupirimate, fuberidazole, blasticidin-S, furametpyr, furalaxyl, fluacrypyrim, fluazinam, fluazinam, fluazinam fluindapyr), fluoxastrobin, fluoxapiprolin, fluotrimazole, fluopicolide, fluopimomide, fluopyram, fluoroimide, furcarbanil ), Fluxapyroxad, fluquinconazole, furconazole, fluconazo Lu-cis (furconazole-cis), fludioxonil, flusilazole, flusulfamide, flutianil, flutolanil, flutriafol, flufenoxystrobin, furfural (Furfural), furmecyclox, flumetover, flumorph, proquinazid, prochloraz, procymidone, prothiocarb, prothioconazole, pronitridine. (pronitridine), propamocarb, propiconazole, propineb, furofanate, probenazole, bromuconazole, florylpicoxamid, hexachlorobutadiene (pronitridine), propamocarb, propiconazole, propineb, furofanate, probenazole, bromuconazole, florylpicoxamid hexachlorobutadiene), hexaconazole, hexylthiofos, bethoxazin, benalaxyl, benaraxyl-M, benodanil, benomyl, benomyl, pefurazoate Knox (benquinox), penconazole (penconazole), benzamorf (benzamorf), pencyclon (pencycuron), benzohydroxamic acid, benzovindiflupyr, ventalulon (bentaluron), benchazole (benthiazole), bench avalier Calve (benthiavalicarb), Bench Avaricarb-isopropyl (benthiavalicarb-isopropyl), Penthiopyrad,
Penflufen, boscalid, phosdiphen, fosetyl, fosetyl-Al, polyoxins, polyoxorim, polycarbamate, folpet , Formaldehyde, machine oil, maneb, mancozeb, mandipropamid, mandestrobin, microzoline (myclobutanil), microbutanil (myclobutanil), mildiomycin (mildiomycin) ), Milneb, mecarbinzid, methasulfocarb, metazoxolon, metam, metam sodium salt (metam-sodium), metalaxyl, metalaxyl-M (metalaxyl-) M), metiram, methyl isothiocyanate, methyl dynocup, methyltetraprole, metconazole, metsulfovax, methfuroxam, methminost Robin (metominostrobin), metrafenone (metrafenone), mepanipyrim (mefenipyrim), mefenoxam (mefenoxam), mefentrifluconazole (mefentrifluconazole), meptyldinocap, mepronil (mepronil), mebenil (mebenil) iodomethane), rabenzazole, methyl bromide, benzalkonium chloride, basic copper chloride, basic copper sulfat e), inorganic bactericides such as metallic silver (silver), sodium hypochlorote hypochlorote, cupric hydroxide, wettable sulfur, calcium polysulfide ), Potassium hydrogen carbonate, sodium hydrogen carbonate, inorganic sulfur (sulfur), anhydrous copper sulfate (copper sulfate anhydride), nickel dimethyldithiocarbamate, 8-hydroxyquinolin copper Examples include copper-based compounds such as (oxine copper), zinc sulfate, copper sulfate pentahydrate and the like.

As agricultural and horticultural herbicides used for the same purpose, for example, 1-naphthylacetamide, 2,4-PA, 2,3,6-TBA, 2,4,5-T, 2,4,5-TB, 2 , 4-D, 2,4-DB, 2,4-DEB, 2,4-DEP, 3,4-DA, 3,4-DB, 3,4-DP, 4-CPA, 4-CPB, 4 -CPP, MCP, MCPA, MCPA thioethyl, MCPB, ioxynil, aclonifen, azafenidin, acifluorfen, aziprotryne, azimsulfuron, ashlam , Acetochlor, atrazine, atraton, anisuron, anilofos, aviglycine, abscisic acid, amicabazone, amidosulfuron , Amitrole, aminocyclopyrachlor, aminopyralid, amibuzin, amiprophos-methyl, ametridione, ametridione, alachlor, Allidochlor, alloxydim, alorac, iofensulfuron, isouron, isocarbamid, isoxachlortole, isoxapyrifop, iso Isoxaflutole, isoxaben, isoxaben, isocil, isonorroon, isoproturon, isopropalin, isopolinate, isomethiozin, inabenfide, inabenfide ipazine), i Pfencarbazone, ipfencarbazone, iprymidam, imazaquin, imazapic, imazapyr, imazamethapyr, imazamethabenz, imazamethabenz, imazamethabenz-methyl ), Imazethapyr, imazosulfuron, indaziflam, indanofan, indolebutyric acid, uniconazole-P, eglinazine, esprocarb (espro) Ethametsulfuron, ethametsulfuron-methyl, ethalfluralin, ethiolate, ethychlozate-ethyl, ethidimuron, etinofen, etinofen, etinofen, etinofen ), ethoxysulfuron, ethoxyfen, etnipromid, ethofumesate, etobenzanid, epronaz, erbon, endothal, oxadiazon , Oxadiargyl, oxaziclomefone, oxasulfuron, oxapyrazon, oxyfluorfen, oryzalin, orthosulfamuron, orbencarb, orbencarb ), Cambendichlor, carbasulam, carfentrazone, mosquito Lufentrazone-ethyl, karbutilate, carbetamide, carboxazole, quizalofop, quizalofop-P, quizalofop-ethyl, xyla Clor (xylachlor), quinoclamine, quinonamid, quinclorac, quinmerac, cumyluron, clacyfos, cliodinate, glyphosate, glufosinate ), Glufosinate-P, credazine, clethodim, cloxyfonac, cloxyfonac, clodinafop, clodinafop-propargyl, chlorotoluron, clopyralid ), Cloproxydim, cloprop, chlorbromuron, clofop, clomazone, chlomethoxyni1, chlomethoxyfen, clomeprop, chlorazifop ), Chlorazine, chloranocryl, chloramben, cloransulam, cloransulam-methyl, chloridazon, chlorimuron, chlorimuron-ethyl, Chlorsulfuron, chlorthal, chlorthiamid, chlortoluron, chlo rnitrofen), chlorfenac, chlorfenprop, chlorbufam, chlorphthalim, chlorflurazole, chlorflurenol, chlorprocarb, chlorprocarb Fam (chlorpropham), chlormequat (chlormequat), chloreturon (chloreturon), chloroxynil (chloroxynil), chloroxuron (chloroxuron), chlorotoluron (chlorotoluron), chloropon (chloropon), saflufenacil (saflufenacil), cyanazine (cyanazine), cyanatrin (cyana) Di-allate, diuron, diethamquat, dicamba, cycluron, cycloate, cycloxydim, dicrosulam, cyclosulfamuron, Cyclopyranil, cyclopyrimorate, dichlorprop, dichlorprop-P, dichlorpropenil, dichlobenil, dicloofop, diclohop-methyl, dichromate (Dichlormate), dichloralurea, diquat, cisanilide, disul, siduron, dithiopyr, dinitramine, cinidon-ethyl, dinosam , Cinosulfuron, dinoseb, dinoterb, dinofenate, dinoprop, cyhalofop-butyl, diphenami Diphenamid, difenoxuron, difenopenten, difenzoquat, cybutryne, simazine, cyprazole, diflufenican, diflufenican, diflufenzopill Dipropetryn, cypromid, cyperquat, gibberellin, simazine, dimexano, dimethachlor, dimedazon, dimethazon, dimethamethametryn, dimethametryn Simazine, simeton, dimepiperate, dimefuron, cinmethylin, swep, sulglycapin, sulcotrione, sulfallate, sulfallate, sulfallate, sulglycapin, sulglycapin, sulglycapin, sulglycapin, sulglycapin. (Sulfentrazone), sulfosulfuron, sulfometuron, sulfometuron-methyl, secbumeton, sethoxydim, sebuthylazine, terbacil, daimuron , Dazomet, dalapon, thiazafluron, thiazopyr, tiafenacil, thiencarbazone, thiencarbazone-methyl, thiencarbazone-methyl, thiocarbazil, thiocarbazil, thiocarbazil Thiobencarb, thidiazimin, thidiazuron, thifensulfuron , Thifensulfuron-methyl, desmedipham, desmetryn, tetflupyrolimet, tetrafluron, thenylchlor, tebutam, tebuthiuron ), Terbumeton, tepraloxydim, tefuryltrione, tembotrione, delachlor, terbacil, terbucarb, terbuchlor, terbutyl ), Terbutryn, topramezone, tralkoxydim, triaziflam, triasulfuron, triafamone, tri-allate, trietazine, tricamba , Triclopyr (triclopyr), tridiphane, tritac, tritosulfuron, trifludimoxazin, triflusulfuron, triflusulfuron-methyl, triflusulfuron-methyl, triflusulfuron-methyl, triflusulfuron-methyl (Trifluralin), trifloxysulfuron, tripropindan, tribenuron, tribenuron-methyl, trifop, trifopsime, trimeturon, torpyralate (Tolpyralate), naptalam, naproanilide, napropamide, nicosulfuron, nitralin , Nitrofen, nitrofluorfen, nipyraclofen, neburon, norflurazon, noruron, barban, paclobutrazol, paraquat , Parafluron, haloxydine, halauxifen, haloxyfop, haloxyfop-P, haloxyfop-methyl, halosafen, halosulfuron, Halosulfuron-methyl, bilanafos, bixlozone, picloram, picolinafen, bicyclopyrone, bispyribac, bispyribac-sodium, Pydanon, pinoxaden, bifenox, piperophos, hymexazol, pyraclonil, pyrasulfotole, pyrazoxyfen, pyrazosulfuron, pyrazosulfuron (Pyrazosulfuron-ethyl), pyrazolate (pyrazolate), bilanafos, pyraflufen, pyraflufen-ethyl, pyriclor, pyridafol, pyrithiobac, pyrithiobac -sodium, pyridate, pyriftalid, pyributicarb, pyribenzoxim, pyrimisurfan (pyr) imisulfan), primisulfuron, pyriminobac-methyl, pyroxasulfone, pyroxsulam, fenasulam, phenisopham, fenuron, phenoxasulfone (Fenoxasulfone), fenoxaprop, phenoxaprop-P (fenoxaprop-P), fenoxaprop-ethyl, phenothiol (phenothio1), phenoprop (fenoprop), phenobenzuron ), Fenquinotrione, fenthiaprop, fenteracol, fentrazamide, phenmedipham, phenmedipham-ethyl, butachlor, Butafenacil, butamifos, buthiuron, buthidazole, butylate, buturon, butenachlor, butroxydim, butralin, butroxydim Flazasulfuron, flamprop, furyloxyfen, prynachlor, primisulfuron-methyl, fluazifop, fluazifop-P, Fluazifop-butyl, fluazolate, fluroxypyr, fluothiuron, fluometuron, fluoroglycofen, flurochlorid one), fluorodifen, fluoronitrofen, fluoromidine, flucarbazone, flucarbazone-sodium, fluchloralin, flucetosulfuron, flucetosulfuron (Fluthiacet), fluthiacet-methyl, flupyrsulfuron, flufenacet, flufenican, flufenpyr, flupropacil, flupropanate, Flupoxam, flumioxazin, flumiclorac, flumiclorac-pentyl, flumipropyn, flumezin, fluometuron, flumetsulam, flumetsulam (Fluridone), flurtamone, fluroxypyr, pretilachlor, proxan, proglinazine, propazine, prodiamine, prosulfalin, prosulfalin (fluridone), flurtamone, prodiamine, prosulfalin, prosulfalin. prosulfuron, prosulfocarb, propaquizafop, propachlor, propazine, propanil, propyzamide, propisochlor, prohydrojasmon ), Propyrisulfuron, propham, profluazol, profluuralin, prohexadion-calciu Prohexadione-calcium, propoxycarbazone, propoxycarbazone-sodium, profoxydim, bromacil, brompyrazon, prometryn, prometon, prometon, prohexadione-calcium, propoxycarbazone, propoxycarbazone-sodium, profoxydim, bromacil, brompyrazon, prometryn Bromoxynil, bromofenoxim, bromobutide, bromobonil, florasumam, florpyrauxifen, hexachloroacetone, hexazinone, pethoxamid , Benazolin, penoxsulam, pebulate, beflubutamid, beflubutamid-M, vernolate, perfluidone, bencarbazone, benzadox ), Benzipram, benzylaminopurine, benzthiazuron, benzfendizone, bensulide, bensulfuron-methyl, benzoylprop, benzobicyclon (Benzobicyclon), benzofenap, benzofluor, bentazone, pentanochlor, benthiocarb, pendimethalin, pentoxazone, benfluralin ), Benfuresate, fosamine, fomesafen, foramsulfuron , Forchlorfenuron, maleic hydrazide, mecoprop, mecoprop-P, mecoprop-P, medinoterb, mesosulfuron, mesosulfuron-methyl , Mesotrione, mesoprazine, mesoprotryne, metazachlor, metazole, metazosulfuron, metazosulfuron, metabenzthiazuron, metamitron, metamihop , Metam, metalpropalin, methiuron, methiozolin, methiobencarb, methyldymron, metoxuron, metosulon, metosulfuron, metosulfuron. Methosulfuron-methyl (metsu1furon-methy1), Metoflurazon, Metobromuron, Metobenzuron, Metomethometon, Metrachlor, metribuzin, Mepicote chloride (mepicot chloride) Mefenacet, mefluidide, monalide, monisouron, monuron, monochloroacetic acid, monochloroacetic acid, monolinuron, molinate, morpham coat (morfamquat) Sulflon (iodosulfuron), iodosulfuron-methyl-sodium, iodobonil, iodomethane (iodome) thane, lactofen, lancotrione, linuron, rimsulfuron, lenacil, rhodethanil, calcium peroxide, methyl bromide Etc. can be exemplified.

In addition, as a phytotoxicity reducing agent (also called safener), for example, 1,8-naphthalic anhydride, isoxadifen-ethyl, furilazole, cyprosulfamide ( cyprosulfamide, cyometrinil, dichlormid, dimepiperate, thiencarbazone-methyl, fenchlorazole-ethyl, fenclorim, fluxofenim, fluxofenim, fluxofenim It is also possible to use (flurazole), benoxacor, metcamifen, mefenpyr-diethyl and the like in combination.

In addition to the above-mentioned pest control agents, additional biopesticides can be used or used. Specific examples thereof include, for example, Agrobacterium radiobacter strain K84 (for example, "Galltrol &#8722; A (registered trademark)" manufactured by "AgBioChem, CA"), Agrobacterium radiobacter. ) Strain K1026 (for example, "Nogall (registered trademark)" manufactured by "Becker Underwood, US"), Agrobacterium radiobacter strain 84 (for example, "Bacte" manufactured by "Nippon Agricultural Chemicals Co., Ltd." Agrobacterium spp. Such as "Rose (registered trademark)"; AQ10 (for example, "AQ 10 (registered trademark)" manufactured by "Intrachem Bio Italia & Co. KG") of Ampelomyces quisqualis strain, etc. Ampelomyces sp.; Aspergillus flavus (eg, Syngenta's Afla-Guard®), Aspergillus flavus strain AF36 (eg, Arizona Cotton) A mixture of sprouting spores of Aureobasidium pullulans strain DSM14940 and sprouting spores of strain DSM14941, such as "AF36 (registered trademark)" manufactured by "Research and Protection Council, US". (For example, "Botector (registered trademark)" manufactured by "bio-ferm, GmbH"), etc. Aureobasidium spp.; Bacillus amyloliquefaciens strain AT-332 (for example, "Impression Clear (registered trademark)" manufactured by "Idemitsu Agri Co., Ltd."), B246 (for example, "Avogreen (registered trademark)" manufactured by "University of Pretoria"), Bacillus amyloliquefaciens strain Bacillus amilolikue Bacillus amyloliquefaciens strain D747 (eg, "Bacstar®" from "Etec Crop Solutions, NZ"), Bacillus amyloliquefaciens strain DB101 (eg, "Dagutat Bio lab, ZA") "Shelter®"), Bacillus amyloliquefaciens strain DB102 (eg "Artemis®" from "Dagutat Bio lab, ZA"), Bacillus amyloliquefaciens (Bacillus amyloliquefaciens) FZB42 (eg, "RhizoVital®" from "ABiTEP, DE"), Bacillus amyloliquefaciens (eg, "Bayer Crop Science AG, DE") GB03 (eg, "Bayer Crop Science AG, DE") "Kodiak®"), Bacillus amyloliquefaciens strain MBI600 (eg, "Subtilex®" from "Becker Underwood, US"), Bacillus cepacia (eg, "Bacillus cepacia") , "Deny Stine®" from "Microbial Products"), Bacillus cereus strain BP01 (eg "Mepichlor®" from "Arysta, US"), Bacillus Pharma (Bacillus) firmus strain I-1582 (eg, "BioNeem®" from "AgoGreen"), Bacillus laterosporus (eg, "Bio-Tode®" from "Agro-Organics, SA") ”), Bacillus licheniformis strain SB3086 (eg,“ EcoGuard Biofungicide® ”manufactured by“ Novozymes ”), Bacillus maroccanus (eg,“ Micro Flo Company ”) ”), Bacillus megaterium strain YFM3.25 (eg,“ Bioarc® ”made by“ BioArc ”), Bacillus metiens (made by“ Micro Flo Company ”), Bacillus. Bacillus mycoides isolate J. (eg, "BmJ®" from "Certis USA"), Bacillus popilliae (eg, "Cronox" from "Bio-Crop, CO") Trademark) "), Bacillus pumilus strain BU F-33 (for example," Integral F-33® "manufactured by" Becker Underwood, US "), Bacillus pumilus strain GB34 (for example) For example, "Yield Shield®" from "Bayer CropScience AG, DE"), QST2808 from Bacillus pumilus (eg, "Sonata®" from "Bayer CropScience LP, US") , Bacillus simplex strain CGF2856 ("Momihope wettable powder (registered trademark)" manufactured by "Arista Life Sciences Co., Ltd."), Bacillus sphaericus, in particular, antigenic H5a5b strain 2362 (eg, , "Vecto Lex®" manufactured by "Valent BioSciences, US"), Bacillus subtilis (eg "Botkiller wettable powder (registered trademark)" manufactured by "Idemitsu Agri Co., Ltd."), Bacillus subtilis. Bacillus subtilis var. Amyloliquefaciens strain FZB24 (eg, "Taegro®" from "Novozyme Biologicals, Inc. US"), Bacillus subtilis strain QST713 / AQ713 ( For example, "SERENADE MAX (registered trademark)" made by "Bayer Crop Science LP, US"), Bacillus subtilis. Stock AQ30002 (eg, "Serenade-DPZ®"), Bacillus subtilis strain D747 (eg, "Ecoshot®" manufactured by "Kumiai Kagaku Co., Ltd."), Bacillus subtilis (Bacillus subtilis) strain HAI-0404 (for example, "Agrocare wettable powder (registered trademark)" manufactured by "Nisso Green Co., Ltd."), Bacillus subtilis strain MBI600 (for example, "Idemitsu Kosan Co., Ltd.""Bacillus subtilis (registered trademark)"), Bacillus subtilis strain Y1336 (for example, "Bacillus wettable powder (registered trademark)" manufactured by "Arista Life Science Co., Ltd."), Bacillus Bacillus thuringiensis strain AM65-52 (eg, "VectoBac®" from "Valent BioSciences, US"), Bacillus thuringiensis israelensis strain BMP144 (eg, ""Aquabac®" made by "Becker Microbial Products IL"), Bacillus thuringiensis subspec. Kurstaki strain BMP 123 (made by "Becker Microbial Products, IL"), Bacillus thuringiensis Bacillus thuringiensis Kurstaki strain HD-1 (for example, "Dipel ES (registered trademark)" manufactured by "Valent BioSciences, US"), Bacillus thuringiensis subsp.aizawai strain ABTS-1857 (for example) SD-1372, eg "XenTari®" from "Bayer Crop Science AG, DE"), Bacillus thuringiensis subsp.aizawai antigen type H-7 (eg, "Valent BioSciences") , US "" Florbac WG (registered trademark) "), Bacillus Bacillus thuringiensis subsp.aizawai strain GC-91, Bacillus thuringiensis subspecies. Aegypti (eg, "Agerin®"), Bacillus thuringiensis subspecies Bacillus thuringiensis subsp. Tenebrionis strain NB 176 (SD-5428, for example, "Novodor FC®" from "BioFa DE"), Bacillus thuringiensis variant 7216 (Bacillus thuringiensis var. 7216) (for example) , "Amactic" and "Pethian"), Bacillus thuringiensis variant T36 (Bacillus thuringiensis var. T36) (eg "Cahat"), Bacillus thuringiensis variant Colmeri (eg "Changzhou") "Tian Bao BTc (registered trademark)" manufactured by Jianghai Chemical Factory), "M-One (registered trademark)" manufactured by "Bacillus thuringiensis var. San diego" (for example, "Bacillus thuringiensis var. San diego") ) ”), Etc. Bacillus spp.; Beauveria bassiana strain (for example,“ Naturalis® ”manufactured by“ Intrachem Bio Italia ”), Beauveria bassiana strain CG716 ( For example, "BoveMax (registered trademark)" manufactured by "Novozymes"), F-263 (for example, "Biolisa Madara (registered trademark)" manufactured by "Idemitsu Kosan Co., Ltd."), Beauveria bassiana strain. Beauveria bassiana strain GHA (for example, "Botaniguard wettable powder (registered trademark)" made by "ARYSTA"), Beauveria br. ongniartii) (eg, "Beaupro®" from "Andermatt Biocontrol AG"), etc. Burkholderia spp.; Bradyrhizobium japonicum (eg, "Novozymes" from "Novozymes" Optimize (registered trademark) "); Burkholderia spp. Strain A396 (for example," MBI-206 TGAI® "manufactured by" Marrone Bio Innovations "); Candida oleophila strain I- 82 (eg, "Aspire®" from "Ecogen Inc., US"), Candida oleophila O strain (eg, "Nexy®" from "BioNext"), Candida. Candida saitoana (eg, "Biotechnology Research And Development Corporation"), Candida saitoana (eg, "Micro Flo Company, US (BASF SE)", "BIOCURE®" ) Etc. Candida spp.; Chaetomium cupreum (for example, "BIOKUPRUM TM (registered trademark)" made by "AgriLife"), Chaetomium globosum (for example, made by "Rivale") "Rivadiom®"), etc. Chaetomium sp.; Chromobacterium subtsugae strain PRAA4-1T (MBI-203, eg, "Grandevo" from "Marrone Bio Innovations""Chromo-bacteriumsp.",Etc.; Cladosporium cladosporioides (for example, "Cladosporium cladosporioides"); Clonostas rosea catenurata (Clonosta) chys rosea f. Catenulate strain J1446 (eg, "PRESTOP®" from "Verdera, Finland"); Colletotrichum gloeosporioides (eg, "Collego" from "Agriultural Research Initiatives") "Contans®"); Coniothyrium spp., Such as Coniothyrium minitans strain CON / M / 91-08 (eg, "Contans®" from "Encore Technologies, LLC"); Cryptococcus albidus (eg, "Yield Plus®" from "Anchor Bio &#8722; Technologies, ZA"); Delftia acidovorans strain RAY209 (eg, "Brett Young Seeds") "Bio Boost®"); Dilophosphora alopecuri (eg, "Twist Fungus®"); Drechsrela monoceras strain MTB-951 (eg, "Mitsui Kagaku Agro Co., Ltd." ) ”, Etc.,“ Drechsrela sp. ”); Entomophthora virulenta (eg,“ Ecomic ”,“ Vektor® ”); Fusarium oxysporum strain 101-2 (eg, "Marcarite" manufactured by Eisai Seikakukensha), Fusarium oxysporum strain Fo47 (eg, "Fusaclean" manufactured by "Natural Plant Protection") ) ”) Etc. Fusarium spp.; Gliocladium catenulatum strain J1446 (for example,“ Prestop® ”manufactured by“ AgBio Inc. ”), Gliocladium ro. Gliocladium roseum strain 321U (manufactured by "WF Stoneman Company LLC"), etc. Gliocladium sp.; Hirsutella thompsonii (eg, "Agro Bio &#8722; tech Research Center, IN""Mycohit®" and "ABTEC®"); Lactobacillus acidophilus (eg, "Fruitsan®" from "Inagrosa &#8722; Industrias Agrobiologicas, SA") , Lactobacillus plantarum strain BY (eg, "Lactobacillus wettable powder" manufactured by "Meiji Seika Pharma Co., Ltd."), Lactobacillus sp. (For example, "Lactobacillus sp."
Lactobacillus sp., Etc. "Lactoplant®" made by "Lacto PAFI"; metarhizium of KV01 of Lecanicillium lecanii strain (eg, "Mycotal (registered)" made by "Koppert / Arysta" Trademark) ”); Metarhizium anisopliae strain F52 (eg,“ BIO 1020® ”manufactured by“ Bayer Crop Science ”), Metarhizium anisopliae strain SMZ-2000 (“Arista Life Sciences (” "Pirates Granules (registered trademark)" (registered trademark), Metarhizium anisopliae var. Acridum (for example, "Green Muscle (registered trademark)" manufactured by "Biological Control Products"), Metarhizium. Metarhizium spp. Such as Metarhizium anisopliae var. Acridum (eg, "Green Guard®" from "Becker Underwood, US"); Metschnikowia fructicola (eg, Metschnikowia fructicola). , "Shemer®" from "Bayer Crop Science"); Microdochium dimerum (eg, "ANTIBOT®" from "Agrauxine, France"); Microsphaeropsis ochracea) (for example, "Microx®" manufactured by "Prophyta"); Monacrosporium phymatopagum ("Nemahiton®" manufactured by "Tomoe Chemical Industry Co., Ltd."); Mucor haemelis (eg, "BioAvard®" from "Indore Biotech Inputs &Research"); Myrothecium verrucaria ) Strain AARC-0255 (eg, "DiTera TM®" from "Valent Biosciences"); Ophiostoma piliferum strain D97 (eg, "Sylvanex"); Paecilomyces fumosoroseus strain apopka 97 (eg, "PreFeRal® WG" from "Biobest"), Paecilomyces fumosoroseus strain FE 9901 (eg, "No Fly®" from "Natural Industries Inc. (Novozymes company)" ) ”), Paecilomyces fumosoroseus (eg,“ Preferred wettable powder ”manufactured by Tokai Bussan Co., Ltd.), Paecilomyces lilacinus strain 251 (eg,“ BioAct ”made by“ Prophyta ”) WG®), composition containing Paecilomyces lilacinus (eg,“ MELOCON® ”), Paecilomyces tenuipes strain T1 (eg, Idemitsu Kosan Co., Ltd.) ) ”), Paecilomyces variotii strain Q-09 (eg,“ Nemaquim® ”made by“ Quimia, MX ”), etc. Paecilomyces spp.); Paenibacillus polymyxa strain AC-1 (“Topseed®” manufactured by “Green Biotech Company Ltd.”), Paenibacillus poppiliae (eg, “St. Gabriel Laboratories”) Manufactured by "Milky spore disease (registered trademark)"), etc. Paenibacillus spp.; Pasteuria nishizawa ("Clariva (registered trademark)"), Pasturia Nishizawa D (Pasteuria nishizawae) (eg, "oyacyst LF / ST®" from "Pasteuria Bioscience"), Pasturia penetrans (eg, "Pasteuria®" from "Pasteuria Bioscience"), Etc. (Pasteuria spp.); Pectobacterium carotovorum (for example, "Biokeeper (registered trademark)" manufactured by "Nissan Chemical Co., Ltd."), Pectobacterium carotovorum (Pectobacterium carotovorum) Pectobacterium spp. Such as CGE234M403 strain (eg, "Ecomate®" from "Kumiai Kagaku");"JumpStart" from Penicillium bilaii strain (eg, "Novozymes") (Registered Trademark) ”); Phlebiopsis gigantea strain FOC PG B22 / SP1190 / 3.2 (for example,“ ROTSOP® ”manufactured by“ Verdera, Finland ”); Homa macrostroma strain 94-44B (eg, "Phoma H®" from "Scotts, US"); Pochonia chlamydosporia var. Catenulata (eg, "The National Center of Animal and Plant Health (CENSA)") "KlamiC®" from CU "); Pseudomonas aureofaciens strain TX-1 (eg" Spot-Less Biofungicide® "from" Eco Soils Systems, CA ") , Pseudomonas chlororaphis strain 63-28 (eg, "ATEze®" from "EcoSoil Systems"), Pseudomonas chlororaphis strain MA 342 (eg, "Cedomon®" from "Bioagri, S"), Pseudomonas fluorescens strain 1629RS (eg, "Frostban D®" from "Frost Technology Corp") , Pseudomonas fluorescens strain A506 (for example, "Blightban®" manufactured by "Blightban"), Pseudomonas fluorescens strain FPT-9601 ("Taki Kagaku Co., Ltd." ) ”), A mixture of Pseudomonas fluorescens strain FPT-9601 and strain FPH-9601 (“Cell seedlings” manufactured by “Taki Kagaku Co., Ltd.” Genki (registered trademark) ”), Pseudomonas fluorescens strain G7090 (for example,“ Veggie Keeper® ”manufactured by“ Arista Life Sciences Co., Ltd. ”), Pseudomonas proradix (for example) , [Proradix®] from "Sourcon Padena"), Pseudomonas resinovorans (eg "Solanacure®" from "Agricultural Research Council, SA"), Pseudomonas syringae ) Strain MA-4 (eg, "Biosave®" from "EcoScience, US"), Pseudomonas syringae Strain 742RS (eg, "Frost Technology Corp®" from "Frostban C") ”), Pseudomonas rhodesiae HAI-0804 strain (“Masterpiece wettable powder (registered trademark)” manufactured by “Nippon Soda Co., Ltd.”), Pseudomonas sp. Strain CAB-02 (for example, Pseudomonas spp. (Pseudomonas spp.) Such as "Momigenki wettable powder" manufactured by "Nissan Chemical Industry Co., Ltd."; Pseudomonas aphis (Ps) eudozyma aphidis) (for example, "Yissum Research Development Company of the Hebrew University of Jerusalem"), Pseudozyma flocculosa strain PF-A22 UL (for example, "Sporodex L" made by "Plant Products Co. Ltd, CA") (Registered Trademark) ”), etc. Rhizopogon (Pseudozyma sp.); Pythium oligandrum strain DV74 or M1 (eg,“ Polyversum® ”manufactured by“ Bioprepraty, CZ ”); Reynoutria saclinensis (Reynoutria sachlinensis) (eg, "REGALIA®" from "Marrone Bio Innovations, US"); Rhizopogon amylopogon (eg, "Myco-Sol®" from "Helena Chemical Company") ), Rhizopogon fulvigleba (eg, "Myco-Sol®" from "Helena Chemical Company"), etc. Rhizopogon spp.; Saccharomyces cerevisiae strains (eg,) "Lesaffre et Compagnie, FR"); Sclerotinia minor (eg, "Sarritor®" from "Agrium Advanced Technologies"); Serratia entomophila (eg, "Wrightson Seeds") "Invade®"); Sporothrix insectorum (eg, "Biocerto;BR""SporothrixEs®"); Stagonospora phaseoli (eg, Stagonospora phaseoli) (Commercially available from "Syngenta"); Streptomyces acidis cabies (Stre) ptomyces acidiscabies) strain RL-110T (eg, "MBI-005EP®" from "Marrone Bioinnovations, CA"), Streptomyces candidus strain Y21007-2 (eg, "Biontech, TW") "BioBac®"), Streptomyces galbus strain K61 (eg, "Verdera" Mycostop®), Streptomyces lydicus strain WYEC108 (For example, "ACTINOVATE®" from "Natural Industries, US"), Streptomyces saraceticus (eg, "Clanda" from "A & A Group (Agro Chemical Corp.)" Streptomyces spp., Etc.; Talaromyces flavus strain B-422 (for example, "Momikeeper (registered trademark)" manufactured by "Central Glass Co., Ltd."), Talaromyces -Flavus (Talaromyces flavus) strain SAY-Y-94-01 (for example, "Tough block (registered trademark)" manufactured by "Idemitsu Kosan Co., Ltd."), Talaromyces flavus strain V117b (for example, "Prophyta") , DE ”“ PROTUS® WG ”), etc. Talaromyces spp.; Thiobacills sp. (For example,“ Cropaid Ltd, UK ”“ Cropaid® ”) Trichoderma album (for example, a product known as "Bio-Zeid"), Trichoderma asperellum strain ICC 012 (manufactured by "Isagro"), Trichoderma asperellum strain T34 (For example, "T34 Biocontrol®" manufactured by "Bioncontrol Technologies, ES" ), Trichoderma asperellum strain SKT-1 (eg, "ECO-HOPE®" manufactured by Kumiai Chemical Industry Co., Ltd.), Trichoderma atroviride strain (eg, "Agrauxine") , FR "" Esquive® WP "), Trichoderma atroviride strain LC52 (eg" Tenet® "manufactured by" Agrimm Technologies Ltd, NZ "), Trichoderma atroviride (Trichoderma) atroviride) SKT-1 (for example, "Ecohope DJ (registered trademark)" manufactured by "Kumiai Chemical Industry Co., Ltd."), Trichoderma gamsii stock ICC 080 (for example, "Bayer Crop Science LP, US") "BIO-TAMTM®"), Trichoderma harzianum strain DB 103 (eg, "T-Gro 7456®" from "Dagutat Biolab"), Trichoderma harzianum ITEM908 (eg, "Trianum-P®" from "Koppert"), Trichoderma harzianum strain KD (eg, "Trichoplus®" from "Biological Control Products, SA") , Trichoderma harzianum strain TH-35 (for example, "ROOT PRO®" manufactured by "Mycontrol Ltd."), Trichoderma harzianum rifai strain T-22 (KRL &# 8722) AG2) For example, "PLANT SHIELD T-22G (registered trademark)" manufactured by "Firma BioWorks Inc. US"), Trichoderma harzianum rifai strain T-39 (for example, manufactured by "Makhteshim Ltd, US") "TRICHODEX (registered trademark)") , Trichoderma lignorum strain TL-0601 (eg, "Mycotric®" from "Futureco Bioscience, ES"), Trichoderma polysporum strain (eg, "BINAB Bio-Innovation AB,""Binab TF WP®" from Sweden "), Trichoderma stromaticum (eg" TRICOVAB® "from"Ceplac; Brazil "), Trichoderma virens ("Trichoderma virens") GL-21 (eg, "SOILGARD®" from "Certis LLC, US"), Trichoderma viride (ICC080), also known as "Gliocladium virens") (For example, "REMEDIER® WP" made by "Isagro Ricerca, ITALIA"), Trichoderma viride strain TV1 (for example, "Trianum &#8722;P®" made by "Koppert") Etc. Trichoderma spp.; Tsukamurella paurometabola strain C-924 (eg, "HeberNem®"); Ulocladium oudemansii strain HRU3 (eg, "Botry-Zen""Botry-Zen®" manufactured by Ltd., NZ "; CGF4526, Variovorax paradoxus strain (eg," Fieldkeeper wettable powder (registered trademark) "manufactured by" Central Glass "); VA ((Vesicular-Arbuscular Mycorrhiza) Mycorrhiza (“Dr Kincon®” from “Idemitsu Agri”); Verticillium alboatrum strain WCS850 (eg, “Tree Care Innovations” Dutch Trig®) ”), Berticillium Lecani (Verticillium lecanii) IMI 179172 (for example, "Verticillium lecanii" manufactured by "Verticillium lecanii"), Verticillium lecanii (Verticillium lecanii) IMI 263817 (for example, "Arysta LifeScience" ) ”, Etc., Verticillium spp.; Xanthomonas campestris (available from Camperico Liquid (registered trademark) Taki Kagaku); etc. It is also possible to use them together.

Furthermore, in recent years, IPM (Comprehensive Pest Management) technology using insect pheromones (communication disrupting agents for tortrix moths, Spodoptera frugiperda, etc.) and natural enemy insects has advanced, and the agent of the present invention is used in combination with these technologies. , Or can be systematically used. For example, Akamega Shiwakuda Thrips, Arigatashima Thrips, Isaea Himekobachi, Onshitsutsuchiyakobachi, Predatory Mite, Gifu Abrabachi, Kukumerisukaburidani, Kuwakonakobachi, Koreman Aburabachi, Sabakutsuyakobachi, Shokugatai Stink bug, Chichukai Tsuyakobachi, Predatory mite, Chabara Abracobachi, Tsuyakobachi, Degeneration Kaburidani, Tricogramma (bee), Namitentou, Namihimehanakamemushi, Hamogori Mayubachi, Hamogurimidorihimekobachi, Himekamenokotentou, Himekamenokotentou Stink bugs such as F. candida and A. flavescens that eat Rhizoctonia spp. ("Rhizoctonia sp."" Chemistry and organisms Vol.51, No.4, (See 2013 p267-269), Natural enemy creatures such as Ruby Thrips, Thrips palmi Karny, European Stink bug, Rhizoctonia stink bug, etc.

Abbreviata caucasica; Acuaria spp.; Agamermis decaudata; Allantonema spp.; Amphimermis spp.; Bezingia siridia siridia siridia siridia Bovienema spp.; Cameronia spp.; Chitwoodiella ovofilamenta; Contortylenchus spp.; Culicimermis spp. Genus species (Diplotriaena spp.); Empidomermis spp.; Filipjevimermis leipsandra; Gastromermis spp.; Gongylonema spp. Gynopoecilia pseudovipara; Heterorhabditis bacteriophora (for example, a product known as "B &#8722; Green"), Heterorhabditis baujardi, for example Heterorhabditis baujardi, Heterorhabditis heliojadi , "Nematon"), Heterorhabditis indica, Heterorhabditis marelatus, Heterorhabditis megidis, Heterorhabditis megidis, Heterorhabditis megidis Heterorhabditis spp.); Hexamermis spp.; Hydromermis spp.; Isomermis spp. Species (Isomermis spp.); Limnomermis spp.; Maupasina weissi; Mermis nigrescens; Mesomermis spp.; Neomesomermis spp.; Neoparasitylenchus rugulosi; Octomyomermis spp.; Parasitaphelenchus spp.; Parasitorhabditis spp.; Parasitorhabditis spp. (Parasitylenchus spp.); Perutilimermis culicis; Phasmarhabditis hermaphrodita; Physaloptera spp.; Protrellatus spp.; Protrellatus spp. Pterygodermatites spp.; Romanomermis spp.; Seuratum cadarachense; Sphaerulariopsis spp.; Spirura guianensis (Spirura guianensis); For example, products known as "Biocontrol", "Biosafe®" manufactured by "SDS Biotech Co., Ltd."), Steinernema feltiae (eg "Nemasys®"). (Product known as), Steinernema glaseri (for example, "Biotopia (registered trademark)" manufactured by "Arista Life Sciences Co., Ltd." or "Biotopia"), Steinernema · Steinernema kraussei (for example, a product known as "Larvesure"), styling Steinernema kushidai (for example, "Shibaichi Nema" manufactured by "Kubota Co., Ltd."), Steinernema riobrave (for example, a product known as "Biovector"), Steinernema scapterisi (for example) Steinernema scapterisci (for example, a product known as "Nematac S"), Steinernema scarabaei, Steinernema siamkayai, etc. Steinernema spp. Natural enemy nematodes such as Peteriseni (Strelkovimer mis peterseni); Subulura spp.; Sulphuretylenchus elongatus; Tetrameres spp.

Tobacco Mosaic Virus, Codling Moth (Adoxophyes orana) Granulosis Virus (GV) (for example, a product known as "BIOFA &#8722; Capex®"), Codling Moth (Adoxophyes orana) Granules A mixture of the disease virus (MAFF632001) and the codling moth virus (MAFF632002) (for example, "Hamaki natural enemy (registered trademark)" manufactured by "Arista Life Sciences Co., Ltd."), Codling moth (Agrotis segetum) nuclear polyhedrosis virus (for example) NPV), Anticarsia gemmatalis (Woolly pyrol moth) mNPV (eg, a product known as "Polygen®"), Autographacalifornica (Alfalfa Looper) mNPV (eg, for example) Product known as "VPN80®"; Source: Agricola El Sol, tea looper (Biston suppressaria) NPV, Bombyx mori NPV, Cryptophlebia leucotreta (false codling moth) GV (eg, a product known as "Cryptex®"), Cydia pomonella spp. Such as Cydia pomonella granulosis, viruses, codling moth ( Cydia pomonella) Granular disease virus (CpGV) (for example, a product known as "Madex Plus®"), Masson Matsukareha (Dendrolimus punctatus) CPV (for example, "Matsukemin", a DVC wettable powder manufactured by Chugai Pharmaceutical Co., Ltd. ”), Helicoverpa armigera NPV (eg, a product known as“ AgBiTech &#8722; ViVUS Max® ”), Helicoverpa zea (formerly Heliothis zea) NPV (eg, for example) A product known as "Elcar®"), Yana Leucoma salicis NPV, Lymantria dispar NPV (eg, a product known as "Gypcheck®"), Balsam &#8722; fir sawfly (Neodiprion abietis) NPV (eg) Products known as "Abietiv®"), Neodiprion lecontei (red &#8722; headed pinesawfly) NPV (eg, products known as "Lecontvirus®"), Neodiprion sertifer NPV (for example, a product known as "Neocheck &#8722; S®"), Orgyia pseudotsugata (Douglas &#8722; fir tussock moth) NPV (for example, "Virtuss" Products known as "(registered trademark)"), potato moga (tobacco leaf miner) (Phthorimaea operculella) GV (for example, product known as "Matapol (registered trademark)"), fall armyworm (Pieris rapae) GV, Konaga (Plutella xylostella) GV (eg, a product known as "Plutec®"), Spodoptera albula (gray &#8722; streaked armyworm moth) mNPV (eg, "VPN 82®" ) ”), African armyworm (true armyworm) (Spodoptera exempta) mNPV (eg, product known as“ Spodec® ”), Shiroichimojiyoto (sugar beet armyworm) (Spodoptera exigua) mNPV (For example, a product known as "Spexit®"; source: Andermatt Biocontrol), fall armyworm (Spodoptera frugiperda) mNPV (eg, known as "Baculovirus VPN®") Have been Product), Tobacco cutworm (Spodoptera littoralis) NPV (Product known as "Spodoptrin®"; Source: NPP Calliope France), Spodoptera litura NPV (Littovir) (Registered Trademark)), Spodoptera litura (oriental leafworm moth) Nuclear polyhedrosis virus Fu-1 strain embedding ("Hasmon natural enemy" manufactured by "Nippon Kayaku Co., Ltd."), Spodoptera litura (oriental leafworm moth) Disease virus Clone A9 strain and Clone C3 strain embedded body (for example, "Hasmon killer" manufactured by "Ibikawa Kogyo Co., Ltd."), Zucchini yellow spot mosaic virus attenuated strain ZY-02 (for example, "Microbial Chemistry Laboratory Co., Ltd." "Kyoto Microken" Cubio ZY-02 (registered trademark)), Zucchini yellow spot mosaic virus attenuated strain ZY-95 (for example, "Kyoto Microken" Cubio manufactured by "Microbial Chemistry Laboratory Co., Ltd." ZY (registered trademark) "), Spodoptera litura virus attenuated strain AVP08 (for example," Green Pepper PM (registered trademark) "manufactured by Microbial Chemistry Laboratory Co., Ltd.), etc.

Alumingerua Uwabarua Diamorua Beat Armirua Little A agent (“Confuser V (registered trademark)” manufactured by “Kyoyu Agri Co., Ltd.”), Cuurua liquid agent (for example, “Cuurua” manufactured by “Sankei Chemical Co., Ltd.” "Registered trademark"), methyl eugenol agent (for example, "Sankei methyl eugenol (registered trademark)" manufactured by "Sankei Chemical Co., Ltd."), Sinanselua agent ("Sukashibacon L (registered trademark)" manufactured by "Shinetsu Chemical Industry Co., Ltd." Trademark) ”), Kossinlua agent (“Bokutokon-H (registered trademark)” manufactured by “Shinetsu Chemical Industry Co., Ltd.”), Totrilua agent (“Hamakicon-N (registered trademark)” manufactured by “Shinetsu Chemical Industry Co., Ltd.” ”), Oriflua totrilua peachflua agent (“Confuser R (registered trademark)” manufactured by “Kyoyu Agri Co., Ltd.”), Oriflua totrilua peachflua agent (“Confuser” manufactured by “Shinetsu Chemical Industry Co., Ltd.” N (registered trademark) "), Oriflua totrilua peachflua pilimalua agent ("Confuser MM (registered trademark) "manufactured by" Shinetsu Chemical Industry Co., Ltd. "), Alimarua totrilua totrilua peachflua agent ("Shinetsu Chemical Industry Co., Ltd. " "Confuser AA (registered trademark)" manufactured by "Comfusor AA (registered trademark)"), Machinisalua agent ("Hetamushikon (registered trademark)" manufactured by "Shinetsu Chemical Industry Co., Ltd."), Fallweb lure agent ("Idemitsu Kosan Co., Ltd." "Nitorua <Ameshiro> (registered trademark)"), Kerkiborua agent (Kashinagacol (registered trademark) manufactured by "Sankei Chemical Co., Ltd."), Bullware Locaria agent (for example, "Shinetsu Chemical Industry Co., Ltd." "Confuser G (registered trademark)"), MEP / Sweet Birua granules ("Arimodokicol granules (registered trademark)" manufactured by "Sankei Chemical Co., Ltd."), Inferua ("Shinetsu Chemical Industry") "Yotokon-1 (registered trademark)" manufactured by "Sankei Chemical Co., Ltd."), Ochimera Norua agent (for example, "Sankei Ochimera Nocol (registered trademark)" manufactured by "Sankei Chemical Co., Ltd."), Sakinela Norua agent ("Sankei Chemical (" Sankei Chemical Co., Ltd. "Sachimera Nocor (registered trademark)" manufactured by "Sachimera Nocor (registered trademark)"), Beat Armirua agent (for example, "Yotokon-S (registered trademark)" manufactured by "Shinetsu Chemical Industry Co., Ltd."), Little A agent (for example, " "Ferrodin SL (registered trademark)" manufactured by Sumitomo Chemical Co., Ltd.), Diamolua agents (for example, "Konagacon (registered trademark)" manufactured by "Sankei Chemical Co., Ltd."), etc.

Acacia negra extract, Abscisic acid, Chenopodium ambrosiodae extract, Arginine, Alginate oligosaccharide, Nepitella oil, Eugenol, L-carvone, Ethyl formate, chitin, Chitosan (for example, "ARMOUR-ZEN" from "BotriZen Ltd., NZ"), Quiillay Extract ), Ginkgolide A, Ginkgolide B, Ginkgolide C, Ginkgolide J and Ginkgolide M, ginkgolide ingredients, grapefruit seeds and Fruit flesh extract, potassium silicate, cytokinin, sanguinarine, cis-Jasmone, citral, gibberellin derivative, siccanin ) (A substance produced by the filamentous fungus Helminthosporium siccans), Citronella Oil, Citronellol, Jasmonic acid, Methyl Jasmonate, sorbitol octanoate (Sorbitol actanoate), neem tree (extracts from seeds of the neem tree), neem oil (Neem Oil), Timor (Thymol), terpinolene (Terpinolene), synthetically produced Kenopodium ambrosioides Extract of near ambrosioides (Chenopodium ambrosioides near ambrosioides) Terpenes [This is a pesticidal active ingredient, three types of terpenes, namely α &#8722; terpine, p &#8722; p-cymene and limonene. Contains a mixture of (limonene)] (eg, a product known as "Requiem®"; source: Bayer CropScienceLP, US), from the form of Bilobalide, Lignite clay. Extracted Humic Acid and fulvic acid, pentatermanone, Marigold Oil, Isopropyl Myristate, Methyl eugenol, Methyl jasmo Humates such as methyl jasmonate, Harpin protein, heptyl butyrate, lavanulyl senecioate, lignite coal known as leonardite, Lecithin, (E, Z) -7,9-dodecadien-1-yl acetate, (E, Z) -2,4-ethyldecadienoate (pear ester), (Z, Z, E)- 7,11,13-Hexadecatorienal, 2-Methyl-1-butanol, (E, Z) -2,13-Octadecadien-1-ol, (E, Z) -2,13-Octadecadien -1-all acetate, (E, Z) -3,13-octadecadien-1-ol, R-1-octen-3-ol, (E, Z, Z) -3,8,11-tetradeca Trienyl acetate, (Z, E) -9,12-tetradecadien-1-yl acetate, Z-7-tetradecene-2-one, Z-9-tetradecene-1-yl acetate, Z-11-tetradeceneal, Z-11-Tetradecene-1-ol, Pongamia, Calotropis, Plumbago, Maytenus, Baccharis, Rubia, Plumbagin, a component of plant extracts from the genera Calophyllum, Urtica, Kobresia, Caesalpinia, Rhodo-pseudomonas speroides, in particular , Extracts from organisms such as brassinosteroids from the strain IFO-12203; those isolated by Harpin (Erwinia amylovora) (Harpin protein); for example, "Harp" -It can also be used in combination with "N-Tek (registered trademark)", "Messenger (registered trademark)", "Employ (registered trademark)", "ProAct (registered trademark)", etc.

Representative examples and test examples of the present invention are shown below, but the present invention is not limited thereto. In the examples, "part" means "part by mass".

Preparation example 1. Emulsion Compound (A-1) to Compound (A-5) 5 parts Thiadinyl 10 parts Xylene 63 parts N-methylpyrrolidone 12 parts Mixture of polyoxyethylene nonylphenyl ether and calcium alkylbenzene sulfonate 10 parts or more are uniformly mixed and dissolved. To make an emulsion.

Preparation example 2. Powders Compounds (A-1) to Compounds (A-5) 5 parts Piraflufenethyl 5 parts Clay powder 78 parts Diatomaceous earth powder 12 parts or more are uniformly mixed and pulverized to obtain a powder.

Preparation example 3. Granules Compound (A-1) to Compound (A-5) 4 parts Orthosulfamron 6 parts Bentonite and clay mixed powder 85 parts Calcium lignin sulfonate 5 parts or more are uniformly mixed and an appropriate amount of water is added. Knead, granulate, and dry to make granules.

Preparation example 4. Wettable compounds Compounds (A-1) to Compounds (A-5) 2 parts Indanophan 2 parts Kaolin and synthetic highly dispersed silicic acid 88 parts Mixture of polyoxyethylene nonylphenyl ether and calcium alkylbenzene sulfonate 8 parts or more are uniformly mixed. Crush to make wettable powder.

Preparation example 5. Wettable compounds Compounds (A-1) to Compounds (A-5) 3 parts Fluvendiamide 5 parts Kaolin and synthetic highly dispersed silicic acid 85 parts Mixture of polyoxyethylene nonylphenyl ether and calcium alkylbenzene sulfonate 7 parts or more uniformly Mix and grind to make wettable powder.

Preparation example 6. Flowable agent Compound (A-1) to Compound (A-5) 5 parts Indanophan 3 parts Solpol 3105 (manufactured by Toho Chemical Industry Co., Ltd.) 5 parts Propylene glycol 7 parts Rodpole 23 (manufactured by Solvay Nikka) 0.2 parts Water 79.8 The above parts are uniformly mixed and dispersed in water to obtain an aqueous suspending agent (flowable agent).

Test example 1. Anti-spraying effect test against rice blast In 6-leaf stage rice (variety: Kinnanfu) cultivated in a pot, compound (A-1) to compound (A-5) and thiazinyl prepared according to Formulation Example 1 The mixture and each single agent are diluted with water to a predetermined concentration and sprayed on the foliage. After spraying, the pots are cultivated in a greenhouse and 7 days after treatment, spray inoculated with a suspension of Pyricularia oryzae spores. After inoculation, the number of lesions is investigated after 7 days under a humid condition of 20 ° C., and the control effect is calculated according to the following formula. At the same time, E (expected value) is obtained by the following Colby's formula. (See Colby, S.R., Weeds 15: 20-22 (1967).).

(Number 1)
E (expected value) = X + Y- (X × Y / 100)

Here, E (expected value) is expected when compounds (A-1) to (A-5) are mixed with pg / ha and the second active ingredient (active ingredient B) is mixed with qg / ha. Control effect (weed control effect, bactericidal effect, insecticidal effect, etc.), X is the control effect when compounds (A-1) to compound (A-5) are treated with pg / ha, and Y is the second active ingredient (Y). The control effect when the active ingredient B) is treated with qg / ha is shown (p and q in the above indicate arbitrary numbers). If the control effect when the two kinds of pest control agents are actually mixed and treated exceeds this E (expected value), it can be said that the combination shows a synergistic effect.

Disease index criteria 0: No disease 1: Spot area rate 1 to 10%
2: Disease area ratio 11 to 20%
3: Spot area rate 21 to 30%
4: Disease area ratio 31-40%
5: Spot area rate 41 to 50%
6: Disease area ratio 51-60%
7: Disease area ratio 61-70%
8: Spot area rate 71-80%
9: Disease area rate 81-90%
10: Disease area rate 91-100%

(Number 2)

Control effect (%) = (onset index of untreated plot-onset index of treated plot) x 100 / onset index of untreated plot

The control effect of the composition in which the compounds (A-1) to (A-5) and thiazinyl are combined in the spray preventive effect test against rice blast can be obtained from the Colby's formula when each compound is used alone. It exceeds E (expected value) and a synergistic effect is recognized.

Test example 2. Control effect test against diamondback moth (Plutella xylostella) Kanran (variety: YR Harutoku) was planted in a glass greenhouse and inoculated with diamondback moth 3rd instar at the 12th to 15th leaf stage. The number of parasites before drug treatment per 3 strains was investigated, and a mixture of compound (A-1) to compound (A-5) and flubendiamide and each single agent were diluted to a predetermined concentration with water according to Formulation Example 5. Sprinkle the chemical solution on the canlan. The number of parasites is investigated 2 days and 6 days after spraying, and the control effect is calculated by the number 3. Further, E (expected value) is obtained by the Colby formula as in Test Example 1.

(Number 3)
Control effect (%) = 100-{(Ta × Cb) / (Tb × Ca)} × 100
Ta = Number of parasites after chemical treatment in the treated group Tb = Number of parasites before chemical treatment in the treated group Ca = Number of parasites after chemical treatment in the untreated group Cb = Number of parasites before chemical treatment in the untreated group

In the control effect test on diamondback moth, the control effect of the composition in which the compounds (A-1) to (A-5) and flubendiamide are combined is obtained from the formula of Colby when each compound is used alone. It exceeds the expected value), and a synergistic effect is recognized.

Test example 3. Test of foliage treatment effect on Pontederia vaginalis A resin bat with a treatment test area of 100 cm ² is filled with diluvial upland soil, and Pontederia vaginalis seeds are uniformly sown. After that, the compound (A-1) was prepared according to Formulation Example 6 when the growing leaf age of the test weed reached the 2.0-2.5 leaf stage after flooding to a depth of 5 cm and continuing cultivation management in a greenhouse. ~ The mixture of compound (A-5) and indanophan and each single agent are treated with a predetermined effective dosage. Then, it is grown in a greenhouse, and the control effect is judged 28 days after the treatment. The control effect is determined according to the 100-point method (0 (same as untreated) to 100 (complete death)) by visual judgment. Further, as in Test Example 1, the expected value due to mixed use is obtained from the Colby formula.

In the foliage treatment effect test on Pontederia vaginalis, the control effect of the composition combining compounds (A-1) to (A-5) and indanophan can be obtained from the Colby formula when each compound is used alone. Expected value), synergistic effect is recognized

The control effect of the composition obtained by combining the compounds (A-1) to (A-5) and the active ingredient B is E (expected value) obtained from Colby's formula when each compound is used alone. It exceeds and a synergistic effect is recognized.

The compound according to the present invention has an excellent control effect on a wide range of pests and is useful.

Claims (5)

It ’s a combination,
As the first active ingredient, one or more compounds selected from the following group of compounds (A) or salts thereof,
As the second active ingredient, the following group of compounds (B),
Isoprothiolane (B-1), basic copper sulfate (B-2), fluoroimide (B-3), flutolanil (B-4), fenoxanil (fenoxanil) ( B-5), tiadinil (B-6), buprofezin (B-7), isoprocarb (MIPC) (B-8), fenobucarb (B-9), fenpyroximate ) (B-10), tebufenpyrad (B-11), tolfenpyrad (B-12), flubendiamide (B-13), metaflumizone (B-14), pyrifluquinazone ( pyrifluquinazon (B-15), chlorphthalim (B-16), pyraflufen-ethyl (B-17), indanofan (B-18), isouron (B-) 19), orthosulfamuron (B-20), pyriprole (B-21), pyflubumide (B-22), pyraziflumid (B-23), benzpyrimoxane Pest control agent composition containing (benzpyrimoxan) (B-24) and one or more compounds selected from hydroxyquinolin copper (copper-8-quinolinolate) (B-25) or salts thereof. Stuff. The pest control agent composition according to claim 1, wherein the second active ingredient is contained in a ratio of 0.01 to 5000 parts by mass with respect to 1 part by mass of the first active ingredient. A method for using a pest control agent composition, which comprises applying an effective amount of the pest control agent composition according to claim 1 or 2 to a target crop, seeds of the target crop, soil, or a cultivation carrier. A method for controlling pests, which comprises applying an effective amount of the pest control agent composition according to claim 1 or 2 to a target crop, seeds of the target crop, soil, and a cultivation carrier. As the first active ingredient, one or more compounds selected from the following group of compounds (A) or salts thereof,
As the second active ingredient, the following group of compounds (B),
Isoprothiolane (B-1), basic copper sulfate (B-2), fluoroimide (B-3), flutolanil (B-4), fenoxanil (fenoxanil) ( B-5), tiadinil (B-6), buprofezin (B-7), isoprocarb (MIPC) (B-8), fenobucarb (B-9), fenpyroximate ) (B-10), tebufenpyrad (B-11), tolfenpyrad (B-12), flubendiamide (B-13), metaflumizone (B-14), pyrifluquinazone ( pyrifluquinazon (B-15), chlorphthalim (B-16), pyraflufen-ethyl (B-17), indanofan (B-18), isouron (B-) 19), orthosulfamuron (B-20), pyriprole (B-21), pyflubumide (B-22), pyraziflumid (B-23), benzpyrimoxane (benzpyrimoxan) (B-24), and hydroxyquinoline copper (copper-8-quinolinolate) (B-25), or one or more compounds selected from salts thereof, were used in the target crops at the same time. A method for controlling pests, which is characterized by being applied to the seeds, soil, and cultivation carrier of a target crop.