JP2018095579A - Pest control agent composition and method for use thereof - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a new technique for efficiently controlling those pests that are difficult or impossible to control by the conventional art.SOLUTION: A pest control agent composition contains at least one compound selected from active ingredients A, and at least one compound selected from active ingredients B, as active ingredients. The active ingredients A are 1-[3-{4-(4-chlorophenyloxy)-2-trifluoromethyl}-2-alkyl-2-hydroxy]-1,2,4-triazole compounds, and the active ingredients B are tiadinil, fulvene diamide, basic copper sulfate and the like.SELECTED DRAWING: None

Description

The present invention relates to an active ingredient A represented by the following chemical formula,
Alternatively, one or two or more compounds selected from salts thereof and active ingredient B having other pest control activity or one or more compounds selected from salts thereof are contained as active ingredients. The present invention relates to a pest control composition and a method of using the same. Furthermore, the present invention also relates to a method for controlling pests using the synergistic effect of the compound combination.

The compounds (I) and (II) used as the active ingredient A of the pesticidal composition of the present invention are known compounds and are known to have bactericidal activity (for example, Patent Documents 1 to 6). See).
Other compounds having pest control activity used as the active ingredient B of the pesticidal composition of the present invention include isoprothiolane, basic copper sulfate, fluoroimide, and flutolanil. ), Phenoxanil, tiadinil, buprofezin, isoprocarb (MIPC), fenobucarb, fenpyroximate, tebufenpyrad, belfenpyrad, tolfenpyrad, tolfenpyrad, tolfenpyrad, tolfenpyrad, tolfenpyrad Metaflumizone, pyrifluquinazon, chlorphthalim, pyraflufen-ethyl, indanofan, isouron, orthosulfamuron, pyripro Pyriprole, pyflubumide, pyraziflumid, 5- (1,3-dioxan-2-yl) -4- [4- (trifluoromethyl)] benzyloxypyrimidine, and copper hydroxyquinoline ( copper-8-quinolinolate). These are all known compounds and are commercially available as pest control agents and the like (see, for example, Patent Documents 7 to 10 or Non-patent Document 1), and pest control compositions using them and methods of using them are known. It has been. However, it has one or more compounds selected from Compound (I) and Compound (II) or a salt thereof used as active ingredient A, and the other pest control activity used as active ingredient B. A pest control composition combining one or more compounds selected from a compound or a salt thereof is not known, and a composition combining these is more synergistic than using each compound alone. It is also not known to have a pest control effect.

International Publication No. 2013/007767 Pamphlet International Publication No. 2014/095994 Pamphlet International Publication No. 2015/003908 Pamphlet International Publication No. 2016/008740 Pamphlet International Publication No. 2016/078995 Pamphlet International Publication No. 2016/079043 Pamphlet International Publication No. 2007/020986 Pamphlet International Publication No. 2007/072999 Pamphlet International Publication No. 2013/115391 Pamphlet International Publication No. 92/12970 Pamphlet

The Pesticide Manual 17th Edition (British Crop Production Council, 2015)

  In agricultural production, pest control work is a particularly heavy burden. Pests include various pests and weeds, and these damages are still significant, and it is necessary to treat pesticides (ie, insecticides, fungicides, herbicides, etc.) to control them. . Also, in the production of crops, reducing the processing work of pesticides is strongly demanded from the viewpoint of occupational health, which reduces the labor burden on farmers, and from the economical aspect, which reduces crop production costs. Various pest control agents have been developed. However, with the conventional technology, effective control may not be possible depending on the type of organism to be controlled, habitat characteristics, development of drug resistance, etc., and it is necessary to efficiently control pests that are difficult or impossible to control. Development of new technology was desired.

As a result of intensive studies to solve the above-mentioned problems, the present inventors have found that the active ingredient A represented by the following chemical formula, which is known as a pest control agent, is shown below.
Alternatively, one or more compounds selected from salts thereof, and isoprothiolane, basic copper sulfate, fluoroimide, flutolanil, phenoxanyl (isoprothiolane) shown as the active ingredient B fenoxanil, thiadinil, buprofezin, isoprocarb (isoprocarb: MIPC), fenobucarb, fenpyroximate, tebufenpyrad, tolfenpyrad, flubendiamide (fluben), flubendiamide (fluben) , Pyrifluquinazon, chlorphthalim, pyraflufen-ethyl, indanofan, isouron, orthosulfamuron, pyrip Pyriprole, pyflubumide, pyraziflumid, 5- (1,3-dioxan-2-yl) -4- [4- (trifluoromethyl)] benzyloxypyrimidine, and copper hydroxyquinoline ( copper-8-quinolinolate), or a salt thereof, combined with one or more compounds selected from the above, a remarkable synergistic effect compared to the case where each compound is used alone, The inventors have found that the present invention has effects such as expansion, reduction in the amount of drug used, and reduction in the number of drug treatments, thereby completing the present invention.

That is, the present invention
[1] Active ingredient A represented by the following chemical formula,
Or at least one or two or more compounds selected from salts thereof;
The following active ingredient B,
Isoprothiolane, basic copper sulfate, fluoroimide, flutolanil, phenoxanil, tiadinil, buprofezin, isoprocarb (MIPC), fenobucarb ), Fenpyroximate, tebufenpyrad, tolfenpyrad, flubendiamide, flubendiamide, metaflumizone, pyrifluquinazon, chlorphthalim, chlorphthalim, pyraflufen-ethyl, pyraflufen-ethyl, pyraflufen-ethyl indanofan), isouron, orthosulfamuron, pyriprole, piflubumide, pyraziflumid, 5- (1, One or more compounds selected from 3-dioxan-2-yl) -4- [4- (trifluoromethyl)] benzyloxypyrimidine and hydroxyquinoline copper or a salt thereof; A pest control composition containing as an active ingredient,
[2] The pesticidal composition according to [1], containing 0.01 to 5000 parts by mass of the active ingredient B with respect to 1 part by mass of the active ingredient A,
[3] A pest control composition characterized by applying an effective amount of the pest control composition according to [1] or [2] to a target crop, seeds of the target crop, soil, or a cultivation carrier. how to use,
[4] A method for controlling pests, which comprises applying an effective amount of the pest control composition according to [1] or [2] to a target crop, seeds, soil, and cultivation carrier of the target crop,
[5] Active ingredient A represented by the following chemical formula,
Or at least one or two or more compounds selected from salts thereof;
The following active ingredient B,
Isoprothiolane, basic copper sulfate, fluoroimide, flutolanil, phenoxanil, tiadinil, buprofezin, isoprocarb (MIPC), fenobucarb ), Fenpyroximate, tebufenpyrad, tolfenpyrad, flubendiamide, flubendiamide, metaflumizone, pyrifluquinazon, chlorphthalim, chlorphthalim, pyraflufen-ethyl, pyraflufen-ethyl, pyraflufen-ethyl indanofan), isouron, orthosulfamuron, pyriprole, piflubumide, pyraziflumid, 5- (1, One or more compounds selected from 3-dioxan-2-yl) -4- [4- (trifluoromethyl)] benzyloxypyrimidine and hydroxyquinoline copper or a salt thereof; Pest control method, characterized by applying to the target crop, the seed of the target crop, the soil, the cultivation carrier at the same time,
About.

  The pest control composition of the present invention has a remarkable synergistic effect, expansion of target pest species, reduction in the amount of drug used, reduction in the number of drug treatments, and usefulness compared to the case where each compound is used alone. It has the effect of reducing the impact on plants and the environment, and provides new technology for efficiently controlling pests such as pests and weeds that are difficult or impossible to control with conventional technology. is there.

In the present invention, pests represent weeds and pests in the field of agriculture and horticulture. The compound selected from the active ingredient A which is the active ingredient of the present invention is a compound represented by the following chemical formula (I) or (II), and includes a salt acceptable as a pest control agent.

  The salt of the compounds (I) and (II) is not particularly limited as long as it is acceptable as a pest control agent. From the chemical structure, hydrochloride, sulfate, nitrate, formate, acetate, trifluoroacetate, Inorganic acids or organic acids such as methanesulfonate sulfonate, trifluoromethanesulfonate, and p-toluenesulfonate are preferred. In addition, the said active ingredient A is a well-known compound, and can be manufactured with the manufacturing method disclosed by the said patent document 1 (International publication 2013/007767).

  The compound selected from the active ingredient B which is the active ingredient of the present invention is (B-1) isoprothiolane, (B-2) basic copper sulfate, (B-3) fluoroimide. ), (B-4) flutolanil, (B-5) phenoxanil, (B-6) thiadinyl, (B-7) buprofezin, (B-8) isoprocarb : MIPC), (B-9) fenobucarb, (B-10) fenpyroximate, (B-11) tebufenpyrad, (B-12) tolfenpyrad, (B-13) fulvene Flubendiamide, (B-14) metaflumizone, (B-15) pyrifluquinazon, (B-16) chlor Chlorphthalim, (B-17) pyraflufen-ethyl, (B-18) indanofan, (B-19) isouron, (B-20) orthosulfamron (B-20) orthosulfamuron), (B-21) pyriprole, (B-22) piflubumide, (B-23) pyraziflumid, (B-24) 5- (1,3-dioxan-2-yl) ) -4- [4- (trifluoromethyl)] benzyloxypyrimidine and (B-25) hydroxy-8-quinolinolate, including acceptable salts as pest control agents. The salt of active ingredient B is not particularly limited as long as it is acceptable as a pest control agent, but an acid salt or a basic salt can be appropriately selected according to the chemical structure. Acid salts include inorganic acids or organic acids such as hydrochloride, sulfate, nitrate, formate, acetate, trifluoroacetate, methanesulfonate, trifluoromethanesulfonate, p-toluenesulfonate, and the like. Examples of the basic salt include ammonium salt, amine salt, isopropylamine salt, potassium salt, calcium salt, sodium salt and the like.

Active ingredient B can be obtained by purchasing a commercially available agent or can be produced by a known production method. Pyriprole, which is a relatively new active ingredient, is disclosed in WO2002 / 010153, and pifluvide is disclosed in WO2007 / 020986. In addition, pyradiflumide is disclosed in International Publication No. 2007/072999, and 5- (1,3-dioxan-2-yl) -4- [4- (trifluoromethyl)] benzyloxypyrimidine is in International Publication No. 2013/115391. It can be manufactured by the manufacturing method disclosed in the pamphlet.

  Specific combinations of the pesticidal composition of the present invention include compound (I) + (B-1), compound (I) + (B-2), compound (I) + (B-3), Compound (I) + (B-4), Compound (I) + (B-5), Compound (I) + (B-6), Compound (I) + (B-7), Compound (I) + ( B-8), Compound (I) + (B-9), Compound (I) + (B-10), Compound (I) + (B-11), Compound (I) + (B-12), Compound (I) + (B-13), Compound (I) + (B-14), Compound (I) + (B-15), Compound (I) + (B-16), Compound (I) + (B -17), compound (I) + (B-18), compound (I) + (B-19), compound (I) + (B-20), compound (I) + (B-21), compound ( I) + (B-22), compound (I + (B-23), compound (I) + (B-24), compound (I) + (B-25),

  Compound (II) + (B-1), Compound (II) + (B-2), Compound (II) + (B-3), Compound (II) + (B-4), Compound (II) + ( B-5), Compound (II) + (B-6), Compound (II) + (B-7), Compound (II) + (B-8), Compound (II) + (B-9), Compound (II) + (B-10), Compound (II) + (B-11), Compound (II) + (B-12), Compound (II) + (B-13), Compound (II) + (B -14), compound (II) + (B-15), compound (II) + (B-16), compound (II) + (B-17), compound (II) + (B-18), compound ( II) + (B-19), compound (II) + (B-20), compound (II) + (B-21), compound (II) + (B-22), compound (II) + (B− 2 ), The compound (II) + (B-24), compound (II) + (B-25),

Compound (I) + (B-1) + (B-2), Compound (I) + (B-1) + (B-3), Compound (I) + (B-1) + (B-4) Compound (I) + (B-1) + (B-5), Compound (I) + (B-1) + (B-6), Compound (I) + (B-1) + (B-7) ), Compound (I) + (B-1) + (B-8), Compound (I) + (B-1) + (B-9), Compound (I) + (B-1) + (B- 10), compound (I) + (B-1) + (B-11), compound (I) + (B-1) + (B-12), compound (I) + (B-1) + (B -13), compound (I) + (B-1) + (B-14), compound (I) + (B-1) + (B-15), compound (I) + (B-1) + ( B-16), compound (I) + (B-1) + (B-17), compound (I) + (B-1) + (B-18), Compound (I) + (B-1) + (B-19), Compound (I) + (B-1) + (B-20), Compound (I) + (B-1) + (B-21) Compound (I) + (B-1) + (B-22), Compound (I) + (B-1) + (B-23), Compound (I) + (B-1) + (B-24) ), Compound (I) + (B-1) + (B-25),

Compound (I) + (B-2) + (B-3), Compound (I) + (B-2) + (B-4), Compound (I) + (B-2) + (B-5) , Compound (I) + (B-2) + (B-6), compound (I) + (B-2) + (B-7), compound (I) + (B-2) + (B-8) ), Compound (I) + (B-2) + (B-9), Compound (I) + (B-2) + (B-10), Compound (I) + (B-2) + (B− 11), Compound (I) + (B-2) + (B-12), Compound (I) + (B-2) + (B-13), Compound (I) + (B-2) + (B -14), compound (I) + (B-2) + (B-15), compound (I) + (B-2) + (B-16), compound (I) + (B-2) + ( B-17), compound (I) + (B-2) + (B-18), compound (I) + (B-2) + (B-19), Compound (I) + (B-2) + (B-20), Compound (I) + (B-2) + (B-21), Compound (I) + (B-2) + (B-22) ), Compound (I) + (B-2) + (B-23), Compound (I) + (B-2) + (B-24), Compound (I) + (B-2) + (B− 25),

Compound (I) + (B-3) + (B-4), Compound (I) + (B-3) + (B-5), Compound (I) + (B-3) + (B-6) , Compound (I) + (B-3) + (B-7), compound (I) + (B-3) + (B-8), compound (I) + (B-3) + (B-9) ), Compound (I) + (B-3) + (B-10), Compound (I) + (B-3) + (B-11), Compound (I) + (B-3) + (B− 12), Compound (I) + (B-3) + (B-13), Compound (I) + (B-3) + (B-14), Compound (I) + (B-3) + (B -15), compound (I) + (B-3) + (B-16), compound (I) + (B-3) + (B-17), compound (I) + (B-3) + ( B-18), compound (I) + (B-3) + (B-19), compound (I) + (B-3) + (B-20) Compound (I) + (B-3) + (B-21), Compound (I) + (B-3) + (B-22), Compound (I) + (B-3) + (B-23) Compound (I) + (B-3) + (B-24), Compound (I) + (B-3) + (B-25),

Compound (I) + (B-4) + (B-5), Compound (I) + (B-4) + (B-6), Compound (I) + (B-4) + (B-7) Compound (I) + (B-4) + (B-8), Compound (I) + (B-4) + (B-9), Compound (I) + (B-4) + (B-10) ), Compound (I) + (B-4) + (B-11), Compound (I) + (B-4) + (B-12), Compound (I) + (B-4) + (B− 13), Compound (I) + (B-4) + (B-14), Compound (I) + (B-4) + (B-15), Compound (I) + (B-4) + (B -16), compound (I) + (B-4) + (B-17), compound (I) + (B-4) + (B-18), compound (I) + (B-4) + ( B-19), compound (I) + (B-4) + (B-20), compound (I) + (B-4) + (B-21) Compound (I) + (B-4) + (B-22), Compound (I) + (B-4) + (B-23), Compound (I) + (B-4) + (B-24) ), Compound (I) + (B-4) + (B-25),

Compound (I) + (B-5) + (B-6), Compound (I) + (B-5) + (B-7), Compound (I) + (B-5) + (B-8) Compound (I) + (B-5) + (B-9), Compound (I) + (B-5) + (B-10), Compound (I) + (B-5) + (B-11) ), Compound (I) + (B-5) + (B-12), Compound (I) + (B-5) + (B-13), Compound (I) + (B-5) + (B− 14), Compound (I) + (B-5) + (B-15), Compound (I) + (B-5) + (B-16), Compound (I) + (B-5) + (B -17), compound (I) + (B-5) + (B-18), compound (I) + (B-5) + (B-19), compound (I) + (B-5) + ( B-20), compound (I) + (B-5) + (B-21), compound (I) + (B-5) + (B-2) ), Compound (I) + (B-5) + (B-23), Compound (I) + (B-5) + (B-24), Compound (I) + (B-5) + (B− 25),

Compound (I) + (B-6) + (B-7), Compound (I) + (B-6) + (B-8), Compound (I) + (B-6) + (B-9) Compound (I) + (B-6) + (B-10), Compound (I) + (B-6) + (B-11), Compound (I) + (B-6) + (B-12) ), Compound (I) + (B-6) + (B-13), Compound (I) + (B-6) + (B-14), Compound (I) + (B-6) + (B− 15), Compound (I) + (B-6) + (B-16), Compound (I) + (B-6) + (B-17), Compound (I) + (B-6) + (B −18), compound (I) + (B−6) + (B−19), compound (I) + (B−6) + (B−20), compound (I) + (B−6) + ( B-21), compound (I) + (B-6) + (B-22), compound (I) + (B-6) + (B− 3), the compound (I) + (B-6) + (B-24), compound (I) + (B-6) + (B-25),

Compound (I) + (B-7) + (B-8), Compound (I) + (B-7) + (B-9), Compound (I) + (B-7) + (B-10) Compound (I) + (B-7) + (B-11), Compound (I) + (B-7) + (B-12), Compound (I) + (B-7) + (B-13) ), Compound (I) + (B-7) + (B-14), Compound (I) + (B-7) + (B-15), Compound (I) + (B-7) + (B− 16), Compound (I) + (B-7) + (B-17), Compound (I) + (B-7) + (B-18), Compound (I) + (B-7) + (B -19), compound (I) + (B-7) + (B-20), compound (I) + (B-7) + (B-21), compound (I) + (B-7) + ( B-22), compound (I) + (B-7) + (B-23), compound (I) + (B-7) + (B 24), compound (I) + (B-7) + (B-25),

Compound (I) + (B-8) + (B-9), Compound (I) + (B-8) + (B-10), Compound (I) + (B-8) + (B-11) Compound (I) + (B-8) + (B-12), Compound (I) + (B-8) + (B-13), Compound (I) + (B-8) + (B-14) ), Compound (I) + (B-8) + (B-15), Compound (I) + (B-8) + (B-16), Compound (I) + (B-8) + (B- 17), Compound (I) + (B-8) + (B-18), Compound (I) + (B-8) + (B-19), Compound (I) + (B-8) + (B -20), compound (I) + (B-8) + (B-21), compound (I) + (B-8) + (B-22), compound (I) + (B-8) + ( B-23), compound (I) + (B-8) + (B-24), compound (I) + (B-8) + ( -25),

Compound (I) + (B-9) + (B-10), Compound (I) + (B-9) + (B-11), Compound (I) + (B-9) + (B-12) Compound (I) + (B-9) + (B-13), Compound (I) + (B-9) + (B-14), Compound (I) + (B-9) + (B-15) ), Compound (I) + (B-9) + (B-16), Compound (I) + (B-9) + (B-17), Compound (I) + (B-9) + (B− 18), Compound (I) + (B-9) + (B-19), Compound (I) + (B-9) + (B-20), Compound (I) + (B-9) + (B -21), compound (I) + (B-9) + (B-22), compound (I) + (B-9) + (B-23), compound (I) + (B-9) + ( B-24), compound (I) + (B-9) + (B-25),

Compound (I) + (B-10) + (B-11), Compound (I) + (B-10) + (B-12), Compound (I) + (B-10) + (B-13) Compound (I) + (B-10) + (B-14), Compound (I) + (B-10) + (B-15), Compound (I) + (B-10) + (B-16) ), Compound (I) + (B-10) + (B-17), Compound (I) + (B-10) + (B-18), Compound (I) + (B-10) + (B- 19), Compound (I) + (B-10) + (B-20), Compound (I) + (B-10) + (B-21), Compound (I) + (B-10) + (B −22), compound (I) + (B−10) + (B−23), compound (I) + (B−10) + (B−24), compound (I) + (B−10) + ( B-25),

Compound (I) + (B-11) + (B-12), Compound (I) + (B-11) + (B-13), Compound (I) + (B-11) + (B-14) Compound (I) + (B-11) + (B-15), Compound (I) + (B-11) + (B-16), Compound (I) + (B-11) + (B-17) ), Compound (I) + (B-11) + (B-18), compound (I) + (B-11) + (B-19), compound (I) + (B-11) + (B− 20), Compound (I) + (B-11) + (B-21), Compound (I) + (B-11) + (B-22), Compound (I) + (B-11) + (B -23), compound (I) + (B-11) + (B-24), compound (I) + (B-11) + (B-25),

Compound (I) + (B-12) + (B-13), Compound (I) + (B-12) + (B-14), Compound (I) + (B-12) + (B-15) Compound (I) + (B-12) + (B-16), Compound (I) + (B-12) + (B-17), Compound (I) + (B-12) + (B-18) ), Compound (I) + (B-12) + (B-19), Compound (I) + (B-12) + (B-20), Compound (I) + (B-12) + (B− 21), compound (I) + (B-12) + (B-22), compound (I) + (B-12) + (B-23), compound (I) + (B-12) + (B -24), compound (I) + (B-12) + (B-25),

Compound (I) + (B-13) + (B-14), Compound (I) + (B-13) + (B-15), Compound (I) + (B-13) + (B-16) Compound (I) + (B-13) + (B-17), Compound (I) + (B-13) + (B-18), Compound (I) + (B-13) + (B-19) ), Compound (I) + (B-13) + (B-20), Compound (I) + (B-13) + (B-21), Compound (I) + (B-13) + (B− 22), Compound (I) + (B-13) + (B-23), Compound (I) + (B-13) + (B-24), Compound (I) + (B-13) + (B -25),

Compound (I) + (B-14) + (B-15), Compound (I) + (B-14) + (B-16), Compound (I) + (B-14) + (B-17) Compound (I) + (B-14) + (B-18), Compound (I) + (B-14) + (B-19), Compound (I) + (B-14) + (B-20) ), Compound (I) + (B-14) + (B-21), Compound (I) + (B-14) + (B-22), Compound (I) + (B-14) + (B− 23), compound (I) + (B-14) + (B-24), compound (I) + (B-14) + (B-25),

Compound (I) + (B-15) + (B-16), Compound (I) + (B-15) + (B-17), Compound (I) + (B-15) + (B-18) Compound (I) + (B-15) + (B-19), Compound (I) + (B-15) + (B-20), Compound (I) + (B-15) + (B-21) ), Compound (I) + (B-15) + (B-22), compound (I) + (B-15) + (B-23), compound (I) + (B-15) + (B- 24), Compound (I) + (B-15) + (B-25),

Compound (I) + (B-16) + (B-17), Compound (I) + (B-16) + (B-18), Compound (I) + (B-16) + (B-19) Compound (I) + (B-16) + (B-20), Compound (I) + (B-16) + (B-21), Compound (I) + (B-16) + (B-22) ), Compound (I) + (B-16) + (B-23), Compound (I) + (B-16) + (B-24), Compound (I) + (B-16) + (B- 25),

Compound (I) + (B-17) + (B-18), Compound (I) + (B-17) + (B-19), Compound (I) + (B-17) + (B-20) Compound (I) + (B-17) + (B-21), Compound (I) + (B-17) + (B-22), Compound (I) + (B-17) + (B-23) ), Compound (I) + (B-17) + (B-24), compound (I) + (B-17) + (B-25),

Compound (I) + (B-18) + (B-19), Compound (I) + (B-18) + (B-20), Compound (I) + (B-18) + (B-21) Compound (I) + (B-18) + (B-22), Compound (I) + (B-18) + (B-23), Compound (I) + (B-18) + (B-24) ), Compound (I) + (B-18) + (B-25),

Compound (I) + (B-19) + (B-20), Compound (I) + (B-19) + (B-21), Compound (I) + (B-19) + (B-22) Compound (I) + (B-19) + (B-23), Compound (I) + (B-19) + (B-24), Compound (I) + (B-19) + (B-25) ),

Compound (I) + (B-20) + (B-21), Compound (I) + (B-20) + (B-22), Compound (I) + (B-20) + (B-23) Compound (I) + (B-20) + (B-24), Compound (I) + (B-20) + (B-25),

Compound (I) + (B-21) + (B-22), Compound (I) + (B-21) + (B-23), Compound (I) + (B-21) + (B-24) Compound (I) + (B-21) + (B-25), Compound (I) + (B-22) + (B-23), Compound (I) + (B-22) + (B-24) ), Compound (I) + (B-22) + (B-25), Compound (I) + (B-23) + (B-24), Compound (I) + (B-23) + (B− 25), compound (I) + (B-24) + (B-25),

Compound (II) + (B-1) + (B-2), Compound (II) + (B-1) + (B-3), Compound (II) + (B-1) + (B-4) , Compound (II) + (B-1) + (B-5), compound (II) + (B-1) + (B-6), compound (II) + (B-1) + (B-7) ), Compound (II) + (B-1) + (B-8), Compound (II) + (B-1) + (B-9), Compound (II) + (B-1) + (B- 10), Compound (II) + (B-1) + (B-11), Compound (II) + (B-1) + (B-12), Compound (II) + (B-1) + (B -13), compound (II) + (B-1) + (B-14), compound (II) + (B-1) + (B-15), compound (II) + (B-1) + ( B-16), compound (II) + (B-1) + (B-17), compound (I ) + (B-1) + (B-18), Compound (II) + (B-1) + (B-19), Compound (II) + (B-1) + (B-20), Compound ( II) + (B-1) + (B-21), compound (II) + (B-1) + (B-22), compound (II) + (B-1) + (B-23), compound (II) + (B-1) + (B-24), compound (II) + (B-1) + (B-25),

Compound (II) + (B-2) + (B-3), Compound (II) + (B-2) + (B-4), Compound (II) + (B-2) + (B-5) , Compound (II) + (B-2) + (B-6), Compound (II) + (B-2) + (B-7), Compound (II) + (B-2) + (B-8) ), Compound (II) + (B-2) + (B-9), Compound (II) + (B-2) + (B-10), Compound (II) + (B-2) + (B− 11), Compound (II) + (B-2) + (B-12), Compound (II) + (B-2) + (B-13), Compound (II) + (B-2) + (B -14), compound (II) + (B-2) + (B-15), compound (II) + (B-2) + (B-16), compound (II) + (B-2) + ( B-17), compound (II) + (B-2) + (B-18), compound ( I) + (B-2) + (B-19), compound (II) + (B-2) + (B-20), compound (II) + (B-2) + (B-21), compound (II) + (B-2) + (B-22), compound (II) + (B-2) + (B-23), compound (II) + (B-2) + (B-24), Compound (II) + (B-2) + (B-25),

Compound (II) + (B-3) + (B-4), Compound (II) + (B-3) + (B-5), Compound (II) + (B-3) + (B-6) Compound (II) + (B-3) + (B-7), Compound (II) + (B-3) + (B-8), Compound (II) + (B-3) + (B-9) ), Compound (II) + (B-3) + (B-10), Compound (II) + (B-3) + (B-11), Compound (II) + (B-3) + (B− 12), Compound (II) + (B-3) + (B-13), Compound (II) + (B-3) + (B-14), Compound (II) + (B-3) + (B -15), compound (II) + (B-3) + (B-16), compound (II) + (B-3) + (B-17), compound (II) + (B-3) + ( B-18), compound (II) + (B-3) + (B-19), compound II) + (B-3) + (B-20), compound (II) + (B-3) + (B-21), compound (II) + (B-3) + (B-22), compound (II) + (B-3) + (B-23), compound (II) + (B-3) + (B-24), compound (II) + (B-3) + (B-25),

Compound (II) + (B-4) + (B-5), Compound (II) + (B-4) + (B-6), Compound (II) + (B-4) + (B-7) Compound (II) + (B-4) + (B-8), Compound (II) + (B-4) + (B-9), Compound (II) + (B-4) + (B-10) ), Compound (II) + (B-4) + (B-11), Compound (II) + (B-4) + (B-12), Compound (II) + (B-4) + (B− 13), Compound (II) + (B-4) + (B-14), Compound (II) + (B-4) + (B-15), Compound (II) + (B-4) + (B -16), compound (II) + (B-4) + (B-17), compound (II) + (B-4) + (B-18), compound (II) + (B-4) + ( B-19), compound (II) + (B-4) + (B-20), compound (II) + (B-4) + (B-21), compound (II) + (B-4) + (B-22), compound (II) + (B-4) + (B-23), Compound (II) + (B-4) + (B-24), Compound (II) + (B-4) + (B-25),

Compound (II) + (B-5) + (B-6), Compound (II) + (B-5) + (B-7), Compound (II) + (B-5) + (B-8) Compound (II) + (B-5) + (B-9), Compound (II) + (B-5) + (B-10), Compound (II) + (B-5) + (B-11) ), Compound (II) + (B-5) + (B-12), Compound (II) + (B-5) + (B-13), Compound (II) + (B-5) + (B− 14), Compound (II) + (B-5) + (B-15), Compound (II) + (B-5) + (B-16), Compound (II) + (B-5) + (B -17), compound (II) + (B-5) + (B-18), compound (II) + (B-5) + (B-19), compound (II) + (B-5) + ( B-20), compound (II) + (B-5) + (B-21), Compound (II) + (B-5) + (B-22), Compound (II) + (B-5) + (B-23), Compound (II) + (B-5) + (B-24) Compound (II) + (B-5) + (B-25),

Compound (II) + (B-6) + (B-7), Compound (II) + (B-6) + (B-8), Compound (II) + (B-6) + (B-9) Compound (II) + (B-6) + (B-10), Compound (II) + (B-6) + (B-11), Compound (II) + (B-6) + (B-12) ), Compound (II) + (B-6) + (B-13), Compound (II) + (B-6) + (B-14), Compound (II) + (B-6) + (B− 15), Compound (II) + (B-6) + (B-16), Compound (II) + (B-6) + (B-17), Compound (II) + (B-6) + (B −18), compound (II) + (B−6) + (B−19), compound (II) + (B−6) + (B−20), compound (II) + (B−6) + ( B-21), compound (II) + (B-6) + (B-22), Compound (II) + (B-6) + (B-23), Compound (II) + (B-6) + (B-24), Compound (II) + (B-6) + (B-25) ),

Compound (II) + (B-7) + (B-8), Compound (II) + (B-7) + (B-9), Compound (II) + (B-7) + (B-10) Compound (II) + (B-7) + (B-11), Compound (II) + (B-7) + (B-12), Compound (II) + (B-7) + (B-13) ), Compound (II) + (B-7) + (B-14), Compound (II) + (B-7) + (B-15), Compound (II) + (B-7) + (B− 16), Compound (II) + (B-7) + (B-17), Compound (II) + (B-7) + (B-18), Compound (II) + (B-7) + (B -19), compound (II) + (B-7) + (B-20), compound (II) + (B-7) + (B-21), compound (II) + (B-7) + ( B-22), compound (II) + (B-7) + (B-23) Compound (II) + (B-7) + (B-24), compound (II) + (B-7) + (B-25),

Compound (II) + (B-8) + (B-9), Compound (II) + (B-8) + (B-10), Compound (II) + (B-8) + (B-11) Compound (II) + (B-8) + (B-12), Compound (II) + (B-8) + (B-13), Compound (II) + (B-8) + (B-14) ), Compound (II) + (B-8) + (B-15), Compound (II) + (B-8) + (B-16), Compound (II) + (B-8) + (B- 17), Compound (II) + (B-8) + (B-18), Compound (II) + (B-8) + (B-19), Compound (II) + (B-8) + (B -20), compound (II) + (B-8) + (B-21), compound (II) + (B-8) + (B-22), compound (II) + (B-8) + ( B-23), compound (II) + (B-8) + (B-24) Compound (II) + (B-8) + (B-25),

Compound (II) + (B-9) + (B-10), Compound (II) + (B-9) + (B-11), Compound (II) + (B-9) + (B-12) Compound (II) + (B-9) + (B-13), Compound (II) + (B-9) + (B-14), Compound (II) + (B-9) + (B-15) ), Compound (II) + (B-9) + (B-16), Compound (II) + (B-9) + (B-17), Compound (II) + (B-9) + (B− 18), Compound (II) + (B-9) + (B-19), Compound (II) + (B-9) + (B-20), Compound (II) + (B-9) + (B -21), compound (II) + (B-9) + (B-22), compound (II) + (B-9) + (B-23), compound (II) + (B-9) + ( B-24), compound (II) + (B-9) + (B-2 ),

Compound (II) + (B-10) + (B-11), Compound (II) + (B-10) + (B-12), Compound (II) + (B-10) + (B-13) , Compound (II) + (B-10) + (B-14), compound (II) + (B-10) + (B-15), compound (II) + (B-10) + (B-16) ), Compound (II) + (B-10) + (B-17), compound (II) + (B-10) + (B-18), compound (II) + (B-10) + (B− 19), Compound (II) + (B-10) + (B-20), Compound (II) + (B-10) + (B-21), Compound (II) + (B-10) + (B −22), compound (II) + (B−10) + (B−23), compound (II) + (B−10) + (B−24), compound (II) + (B−10) + ( B-25),

Compound (II) + (B-11) + (B-12), Compound (II) + (B-11) + (B-13), Compound (II) + (B-11) + (B-14) Compound (II) + (B-11) + (B-15), Compound (II) + (B-11) + (B-16), Compound (II) + (B-11) + (B-17) ), Compound (II) + (B-11) + (B-18), Compound (II) + (B-11) + (B-19), Compound (II) + (B-11) + (B− 20), Compound (II) + (B-11) + (B-21), Compound (II) + (B-11) + (B-22), Compound (II) + (B-11) + (B −23), compound (II) + (B-11) + (B-24), compound (II) + (B-11) + (B-25),

Compound (II) + (B-12) + (B-13), Compound (II) + (B-12) + (B-14), Compound (II) + (B-12) + (B-15) Compound (II) + (B-12) + (B-16), Compound (II) + (B-12) + (B-17), Compound (II) + (B-12) + (B-18) ), Compound (II) + (B-12) + (B-19), Compound (II) + (B-12) + (B-20), Compound (II) + (B-12) + (B− 21), compound (II) + (B-12) + (B-22), compound (II) + (B-12) + (B-23), compound (II) + (B-12) + (B -24), compound (II) + (B-12) + (B-25),

Compound (II) + (B-13) + (B-14), Compound (II) + (B-13) + (B-15), Compound (II) + (B-13) + (B-16) Compound (II) + (B-13) + (B-17), Compound (II) + (B-13) + (B-18), Compound (II) + (B-13) + (B-19) ), Compound (II) + (B-13) + (B-20), Compound (II) + (B-13) + (B-21), Compound (II) + (B-13) + (B− 22), Compound (II) + (B-13) + (B-23), Compound (II) + (B-13) + (B-24), Compound (II) + (B-13) + (B -25),

Compound (II) + (B-14) + (B-15), Compound (II) + (B-14) + (B-16), Compound (II) + (B-14) + (B-17) Compound (II) + (B-14) + (B-18), Compound (II) + (B-14) + (B-19), Compound (II) + (B-14) + (B-20) ), Compound (II) + (B-14) + (B-21), Compound (II) + (B-14) + (B-22), Compound (II) + (B-14) + (B− 23), compound (II) + (B-14) + (B-24), compound (II) + (B-14) + (B-25),

Compound (II) + (B-15) + (B-16), Compound (II) + (B-15) + (B-17), Compound (II) + (B-15) + (B-18) Compound (II) + (B-15) + (B-19), Compound (II) + (B-15) + (B-20), Compound (II) + (B-15) + (B-21) ), Compound (II) + (B-15) + (B-22), Compound (II) + (B-15) + (B-23), Compound (II) + (B-15) + (B− 24), compound (II) + (B-15) + (B-25),

Compound (II) + (B-16) + (B-17), Compound (II) + (B-16) + (B-18), Compound (II) + (B-16) + (B-19) Compound (II) + (B-16) + (B-20), Compound (II) + (B-16) + (B-21), Compound (II) + (B-16) + (B-22) ), Compound (II) + (B-16) + (B-23), Compound (II) + (B-16) + (B-24), Compound (II) + (B-16) + (B− 25),

Compound (II) + (B-17) + (B-18), Compound (II) + (B-17) + (B-19), Compound (II) + (B-17) + (B-20) Compound (II) + (B-17) + (B-21), Compound (II) + (B-17) + (B-22), Compound (II) + (B-17) + (B-23) ), Compound (II) + (B-17) + (B-24), compound (II) + (B-17) + (B-25),

Compound (II) + (B-18) + (B-19), Compound (II) + (B-18) + (B-20), Compound (II) + (B-18) + (B-21) Compound (II) + (B-18) + (B-22), Compound (II) + (B-18) + (B-23), Compound (II) + (B-18) + (B-24) ), Compound (II) + (B-18) + (B-25),

Compound (II) + (B-19) + (B-20), Compound (II) + (B-19) + (B-21), Compound (II) + (B-19) + (B-22) Compound (II) + (B-19) + (B-23), Compound (II) + (B-19) + (B-24), Compound (II) + (B-19) + (B-25) ),

Compound (II) + (B-20) + (B-21), Compound (II) + (B-20) + (B-22), Compound (II) + (B-20) + (B-23) Compound (II) + (B-20) + (B-24), Compound (II) + (B-20) + (B-25),

Compound (II) + (B-21) + (B-22), Compound (II) + (B-21) + (B-23), Compound (II) + (B-21) + (B-24) Compound (II) + (B-21) + (B-25), Compound (II) + (B-22) + (B-23), Compound (II) + (B-22) + (B-24) ), Compound (II) + (B-22) + (B-25), Compound (II) + (B-23) + (B-24), Compound (II) + (B-23) + (B− 25), compound (II) + (B-24) + (B-25),
Is mentioned.

The preferred weight ratio of active ingredient A and active ingredient B that can be used according to the present invention can be any suitable ratio between 10000: 1 〜 1: 10000, preferably 5000: 1 &#.12316; 1: 5000, more preferably 200-1000: 1 〜 1: 200-1000, 100: 1 〜 1: 100, 10: 1 〜 1: 10, particularly preferred ratio is 1: 5 〜 5: 1.

  Each of these active ingredients may be a commercially available preparation as it is, and the active ingredients can be used alone or in combination. When formulating, the active ingredient is mixed in an appropriate inert carrier, or if necessary, together with an auxiliary agent in an appropriate ratio and dissolved, separated, suspended, mixed, impregnated, adsorbed or adhered as appropriate. Dosage forms such as suspensions (flowables), milk suspensions, emulsions, solutions, wettable powders, wettable granules, granules, powders, microcapsules, capsules, tablets, jumbos or packs What is necessary is just to formulate in an agent.

In the case of formulating, the proportion of the active ingredient relative to the whole pest control composition of the present invention can be adjusted as necessary, and is not particularly limited, but is generally 0.01 to 90 mass as the total amount of the active ingredient For example, in the case of a powder or granule, it is preferably about 0.1 to 30 parts by mass, and in the case of an emulsion, wettable powder, flowable powder or granular wettable powder, 0.1 to 60 parts by mass The degree is preferred.

  Examples of the inert carrier include a solid carrier and a liquid carrier. Examples of the solid carrier include natural materials such as quartz, clay, kaolinite, pyrophyllite, sericite, talc, bentonite, acid clay, attapulgite, zeolite, and diatomaceous earth. Minerals, inorganic salts such as calcium carbonate, ammonium sulfate, sodium sulfate, potassium chloride, organics such as synthetic silicic acid, synthetic silicate, starch, cellulose, plant powder (eg sawdust, coconut shell, corn cob, tobacco stem) Examples thereof include solid carriers, plastic carriers such as polyethylene, polypropylene, and polyvinylidene chloride, urea, inorganic hollow bodies, plastic hollow bodies, fumed silica (white carbon), and the like. These may be used alone or in combination of two or more.

  Examples of the liquid carrier include monohydric alcohols such as methanol, ethanol, propanol, isopropanol, and butanol, and polyhydric alcohols such as ethylene glycol, diethylene glycol, propylene glycol, hexylene glycol, polyethylene glycol, polypropylene glycol, and glycerin. Alcohols, polyhydric alcohol compounds such as propylene glycol ether, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, cyclohexanone, ethyl ether, dioxane, ethylene glycol monoethyl ether, dipropyl ether, tetrahydrofuran, etc. Ethers, normal paraffins, naphthenes, isoparaffins, kerosene, mineral oils and other aliphatics Hydrogen fluorides, aromatic hydrocarbons such as benzene, toluene, xylene, solvent naphtha, alkylnaphthalene, halogenated hydrocarbons such as dichloromethane, chloroform, carbon tetrachloride, ethyl acetate, diisopropyl phthalate, dibutyl phthalate, dioctyl phthalate, Esters such as dimethyl adipate, lactones such as γ-butyrolactone, amides such as dimethylformamide, diethylformamide, dimethylacetamide, N-alkylpyrrolidinone, nitriles such as acetonitrile, sulfur compounds such as dimethylsulfoxide, soybean oil And vegetable oils such as rapeseed oil, cottonseed oil and castor oil, and water. These may be used alone or in combination of two or more.

  As auxiliary agents, surfactants, binders, tackifiers, thickeners, colorants, freeze-restoring agents, anti-caking agents, disintegrating agents used as dispersing agents, wetting agents, spreading agents, spreading agents, etc. And decomposition inhibitors. In addition, you may use a preservative, a plant piece, etc. as an additional component as needed. These additive components may be used alone or in combination of two or more.

  Surfactants used as dispersants, wetting agents, spreading agents, spreading agents, etc. include, for example, sorbitan fatty acid esters, polyoxyethylene sorbitan fatty acid esters, sucrose fatty acid esters, polyoxyethylene fatty acid esters, polyoxyethylene resin acids Esters, polyoxyethylene fatty acid diesters, polyoxyethylene alkyl ethers, polyoxyethylene alkyl aryl ethers, polyoxyethylene alkyl phenyl ethers, polyoxyethylene dialkyl phenyl ethers, polyoxyethylene alkyl phenyl ether formalin condensates, polyoxyethylene polyoxy Propylene block copolymer, polystyrene polyoxyethylene block polymer, alkyl polyoxyethylene polypropylene block copolymer , Polyoxyethylene alkylamine, polyoxyethylene fatty acid amide, polyoxyethylene fatty acid bisphenyl ether, polyalkylene benzyl phenyl ether, polyoxyalkylene styryl phenyl ether, acetylene diol, polyoxyalkylene-added acetylene diol, polyoxyethylene ether type Nonionic surfactants such as silicone, ester type silicone, fluorosurfactant, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil,

Alkyl sulfate, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl phenyl ether sulfate, polyoxyethylene styryl phenyl ether sulfate, alkyl benzene sulfonate, alkyl aryl sulfonate, lignin sulfonate, alkyl sulfo succinate , Naphthalene sulfonate, alkyl naphthalene sulfonate, salt of formalin condensate of naphthalene sulfonic acid, salt of formalin condensate of alkyl naphthalene sulfonic acid, fatty acid salt, polycarboxylate, polyacrylate, N-methyl- Anionic surfactants such as fatty acid sarcosinate, resinate, polyoxyethylene alkyl ether phosphate, polyoxyethylene alkyl phenyl ether phosphate,

Cationic surfactants such as alkylamine salts such as laurylamine hydrochloride, stearylamine hydrochloride, oleylamine hydrochloride, stearylamine acetate, stearylaminopropylamine acetate, alkyltrimethylammonium chloride, alkyldimethylbenzalkonium chloride, amino acids And amphoteric surfactants such as molds or betaines. These surfactants may be used alone or in combination of two or more.

  Examples of binders and tackifiers include carboxymethyl cellulose and salts thereof, dextrin, water-soluble starch, xanthan gum, guar gum, sucrose, polyvinyl pyrrolidone, gum arabic, polyvinyl alcohol, polyvinyl acetate, sodium polyacrylate, and an average molecular weight of 6000 to 600. 20,000 polyethylene glycol, polyethylene oxide having an average molecular weight of 100,000 to 5,000,000, phospholipid (for example, cephalin, lecithin, etc.), cellulose powder, dextrin, modified starch, polyaminocarboxylic acid chelate compound, crosslinked polyvinylpyrrolidone, maleic acid and styrenes Copolymer, (meth) acrylic acid copolymer, half ester of polycarboxylic alcohol and dicarboxylic anhydride, water soluble salt of polystyrene sulfonic acid Paraffin, terpene, polyamide resins, polyacrylate, polyoxyethylene, wax, polyvinyl alkyl ethers, alkylphenol-formalin condensates, synthetic resin emulsions and the like.

  Examples of the thickener include xanthan gum, guar gum, diyutane gum, carboxymethylcellulose, polyvinylpyrrolidone, carboxyvinyl polymer, acrylic polymer, starch derivative, water-soluble polymer such as polysaccharide, high-purity bentonite, fumed silica (fumed Inorganic fine powder such as silica (white carbon).

  Examples of the colorant include inorganic pigments such as iron oxide, titanium oxide, and Prussian blue, organic pigments such as phthalocyanine blue and permanent red, alizarin dyes, azo dyes, and organic dyes such as metal phthalocyanine dyes. It is done.

  Examples of the freeze restoring agent include polyhydric alcohols such as ethylene glycol, diethylene glycol, propylene glycol, and glycerin.

  Adjuvants for preventing caking and promoting disintegration include, for example, polysaccharides such as starch, alginic acid, mannose and galactose, polyvinylpyrrolidone, fumed silica (white carbon), ester gum, petroleum resin, sodium tripolyphosphate, Sodium hexametaphosphate, stearic acid metal salt, cellulose powder, dextrin, methacrylate copolymer, polyvinylpyrrolidone, polyaminocarboxylic acid chelate compound, sulfonated styrene / isobutylene / maleic anhydride copolymer, starch / polyacrylonitrile graft copolymer A polymer etc. are mentioned.

  Examples of the decomposition inhibitor include desiccants such as zeolite, quicklime and magnesium oxide, antioxidants such as phenolic compounds, amine compounds, sulfur compounds and phosphoric acid compounds, and ultraviolet absorbers such as salicylic acid compounds and benzophenone compounds. It is done. Examples of the preservative include potassium sorbate and 1,2-benzisothiazolin-3-one.

  Further, if necessary, activity enhancers such as functional spreading agents, metabolic degradation inhibitors such as piperonyl butoxide, antioxidants such as BHT, and other auxiliary agents such as ultraviolet absorbers can be used.

  The “crop” in which the pest control composition of the present invention can be used is not particularly limited. Beans (eg, soybeans, red beans, empty beans, peas, peanuts, etc.); fruit trees and fruits (eg, apples, mandarin oranges, lemons, limes, grapefruits, quince, quince, pears, pears, Japanese pears, grapes, blueberries , Cranberry, blackberry, raspberry, strawberry, peach, plum, nectarine, plum, sweet potato, apricot, prune, walnut, hazel, almond, pistachio, cashew nut, macadamia nut, banana, oyster, olive, loquat, date palm, coconut palm, oil palm Etc.); Vegetables (eg Cabbage, tomato, spinach, broccoli, lettuce, onion, leek, bell pepper, eggplant, kohlrabi, Chinese cabbage, cabbage, komatsuna, mustard, broccoli, cauliflower, shungiku, artichoke, lettuce, leek, onion, asparagus, carrot, parsley Root vegetables (eg carrot, burdock, potato, sweet potato, yam, taro, radish, lotus root, turnip, etc.); crops for processing (eg cotton, chrysanthemum, mulberry, mitsumata, etc.) Oilseed rape, oil palm, oilseed crab, buckwheat, beet, hop, sugarcane, sugar beet, olive, rubber, coffee, tobacco, mulberry, tea, etc .; moss (pumpkin, cucumber, zucchini, watermelon, melon, etc.); Class (e.g., orchardgrass, sorghum, timothy, clover, alfalfa, etc.);

Turf (for example, buckwheat such as prickly pear and red moth, bermudagrass such as leopard moth, bentgrass such as prunus, hykonukagusa, damselfly, bluegrass such as nagahagusa, osuzumenokatabira; Fescue, ryegrass such as rat wheat, barley, etc .; camouflage, blue whale, etc .; crops such as fragrances (eg, lavender, rosemary, thyme, parsley, pepper, pepper, horseradish, ginger, garlic, perilla, mint, basil) Florals (eg, roses, carnations, chrysanthemum, eustoma, gypsophila, sunflower, gerbera, marigold, salvia, petunia, verbena, tulips, asters, gentian, Lily, pansy, cyclamen, orchid, lily of the valley, lavender, stock, habutton, primula, poinsettia, gladiolus, cattleya, daisy, verbena, cymbidium, begonia, etc .; trees (eg ash, birch, dogwood, eucalyptus, ginkgo, lilac) , Magnolia, maple, oak, poplar, redwood, fu, sycamore, Japanese zelkova, black bean, Japanese apricot, tsutsuga, rat, pine, spruce, yew, elm, shinoki, coral jug, Japanese cypress, cedar, cypress, croton, masaki, kanamochi) Etc.

  In addition, the above "crop" includes genetically modified crops (herbicide-tolerant crops, pest-tolerant crops that incorporate insecticidal protein-producing genes) that have been given useful traits through classical breeding methods and recent advances in genetic engineering techniques. , Disease resistant crops, crop enhancing crops, preservative crops, yield improving crops, etc.) that incorporate genes that induce resistance to disease.

  Examples of “crop” imparted with herbicide tolerance by classical breeding methods include rapeseed, wheat, sunflower, rice and corn that are resistant to imidazolinone-based ALS-inhibiting herbicides such as imazetapil. Is already sold under the brand name. Similarly, there are soybeans that are resistant to sulfonylurea ALS-inhibiting herbicides such as Thifensulfuron methyl by classical breeding methods, and are already sold under the trade name STS soybeans. Similarly, SR corn and the like are examples of crops to which tolerance has been imparted to acetyl CoA carboxylase inhibitors such as trione oxime and aryloxyphenoxypropionic acid herbicides.

  Examples of crops that have been rendered tolerant by genetic recombination technology include glyphosate-resistant corn, soybean, cotton, rapeseed and sugar beet varieties, such as Roundup Ready (registered trademark) and AgriureGT (registered trademark). Already sold by name. Similarly, there are corn, soybean, cotton and rapeseed varieties resistant to glufosinate by genetic recombination technology, and these are already sold under trade names such as Liberty Link (registered trademark). Similarly, bromoxynyl-resistant cotton by gene recombination technology is already sold under the trade name BXN.

  Crops that have been rendered tolerant to acetyl CoA carboxylase inhibitors are Proceedings of the National Academy of Sciences of the United States of America (Proc. Natl. Acad. Sci. USA) 87, 7175-7179 (1990). A mutant acetyl CoA carboxylase resistant to an acetyl CoA carboxylase inhibitor has been reported in Weed Science 53, 728-746 (2005). By introducing a mutation into the crop acetyl-CoA carboxylase or introducing a mutation associated with imparting resistance into the crop, a crop resistant to the acetyl-CoA carboxylase inhibitor can be produced. Further, a nucleic acid introduced with a base substitution mutation represented by chimera plastic technology (Gura T. 1999. Repairing the Genome's Spelling Mistakes. Science 285: 316-318.) Is introduced into a crop cell (acetyl CoA carboxylase). } Generating site-specific amino acid substitution mutations in the gene can produce crops that are resistant to {acetyl CoA carboxylase inhibitors}.

  Also included are genetically modified crops that have been able to synthesize insecticidal toxins using genetic engineering techniques. Examples of insecticidal toxins expressed in such transgenic plants include insecticidal proteins derived from Bacillus cereus and Bacillus popilliae; Cry1 Ab derived from Bacillus thuringiensis , Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1 or Cry9C or other insecticidal proteins such as VIP1, VIP2, VIP3 or VIP3A; nematode-derived insecticidal proteins; Toxins produced by animals such as insect-specific neurotoxins; filamentous fungi toxins; plant lectins; agglutinins; trypsin inhibitors, serine protease inhibitors, patatin, cystatins, papain inhibitors and other protease inhibitors Ribosome inactivating protein (RIP) such as ricin, corn-RIP, abrin, saporin, bryodin; steroid metabolic enzymes such as 3-hydroxysteroid oxidase, ecdysteroid-UDP-glucosyltransferase, cholesterol oxidase; ecdysone inhibitor; HMG-CoA reductase; ion channel inhibitors such as sodium channel inhibitor and calcium channel inhibitor; juvenile hormone esterase; diuretic hormone receptor; stilbene synthase; bibenzyl synthase; chitinase; Examples of these toxins and recombinant crops capable of synthesizing these toxins are disclosed in, for example, EP-A-0374753, WO93 / 07278, WO95 / 34656, EP-A-0427529, EP-A-451878, WO03 / 052073, etc. Have been described. The toxins contained in these recombinant crops are particularly suitable for controlling Coleoptera pests, Diptera pests, and Lepidoptera pests, and impart resistance traits to these pests.

  Of these insecticidal toxins, genetically modified crops expressing one or more toxins are already known and some are commercially available. Examples of these genetically modified crops include corn varieties expressing Cry1Bb toxin, such as corn varieties expressing Cry1Ab toxin, such as Yield Gard <registered trademark>, such as Yield Gard Rootworm <registered trademark>. Corn varieties that express Cry1Ab and Cry3Bb1 toxins, such as Yield Gard Plus®, such as phosphinothricin N-acetyltransferase (PAT) to confer resistance to Cry1Fa2 toxin and glufosinate. ) That expresses Cry1Ac toxin, such as a corn variety that expresses Cry1Ac toxin, such as Herculex I®. Cotton varieties that express Cry1Ac and Cry2Ab toxins, such as Bollgard II, such as Bollgard I <registered trademark>, such as cotton varieties that express VIP toxins, such as VIPCOT < Potato varieties expressing Cry3A toxin, such as New Leaf <registered trademark>, such as GA21 glyphosate resistant trait Natureguard, Aguresure GT Advantage <registered trademark>, Bt11 Corn borer (CB) traits, such as Agurisure CB Advantage (registered trademark), Protector (registered trademark), etc. It is.

  Furthermore, those given a trait for producing an anti-pathogenic substance having a selective action using a gene recombination technique are also included. Examples of anti-pathogenic substances include PR proteins (described in PRPs, EP-A-0392225); sodium channel inhibitors, calcium channel inhibitors (virus-produced KP1, KP4, KP6 toxins, etc.) Stilbene synthase; bibenzyl synthase; chitinase; glucanase; peptide antibiotics, heterocyclic antibiotics, protein factors involved in plant disease resistance (called plant disease resistance genes) , Described in WO 03/000906) and the like. Such anti-pathogenic substances and genetically modified crops that produce them are described in EP-A-0392225, WO95 / 33818, EP-A-0353191, and the like.

  Furthermore, crops to which useful traits such as oil component modification and amino acid content enhancing traits have been imparted using genetic recombination techniques are also included. Examples include VISTIVE <(R)> (low linolenic soybean with reduced linolenic content) or high-lysine (or high-oil) corn (corn with increased lysine or oil content).

  In addition, the above-mentioned classic herbicide traits or herbicide resistance genes, insecticidal pest resistance genes, anti-pathogenic substance production genes, oil traits modification, amino acid content enhancement traits, etc. Combined stack varieties are also included. When the pesticide composition of the present invention is used for a crop that has become herbicide-tolerant, the herbicide to which the crop is tolerated (for example, glyphosate or a salt thereof, glufosinate or a salt thereof, dicamba or a salt thereof) , Imazetapyr or a salt thereof, isoxaflutol and the like) and the pest control composition of the present invention can be comprehensively controlled for weeds and pests.

  In the use of the pesticidal composition of the present invention for pests in the field of agriculture and horticulture, various pests in which the preparation containing each active ingredient is diluted in advance or diluted appropriately with water or the like in advance. An amount effective for control may be directly applied to a pest, a target crop in which the occurrence of the pest is predicted, or soil for sowing seeds or a cultivation carrier. Treatment methods include, for example, spraying on foliage, rice seedling box treatment, seed treatment such as seed dressing, seed soaking, and seed disinfection, planting treatment, plant base treatment, crop treatment, irrigation treatment, soil mixing The processing method, such as a process, is mentioned, You may process to the hydroponic liquid in hydroponics.

  In the use of the pesticidal composition of the present invention for weeds in the field of agriculture and horticulture, weed control in the form of the above-mentioned preparation containing each active ingredient as it is, or appropriately diluted with water or suspended. In addition to spraying an effective amount directly on the foliage of the weeds, seed treatment such as soaking in seeds, seed dressing, calper treatment, soil entire layer mixing, crop application, floor soil mixing, cell seedling It can also be used by treating it with soil, such as treatment, planting hole treatment, plant root treatment, top dress, rice box treatment, and water surface application.

  As a seed treatment method, for example, according to a usual method, for example, a liquid or solid preparation is diluted or undiluted and the seed is immersed in a liquid state to infiltrate the drug, and the solid preparation or liquid preparation is seeded. Method of adhering to the surface of the seed by mixing with powder, dressing treatment, etc., mixing with a highly adhesive carrier such as resin or polymer, coating the seed in a single layer or multiple layers, spraying around the seed simultaneously with planting And the like. The “seed” for performing the seed treatment is broadly synonymous with the “reproduction plant body” in the present invention. In addition to so-called seeds, bulbs, tubers, seeds, bulbs, stems for cutting plant cultivation, etc. Includes plants for vegetative propagation.

  The “soil” or “cultivation carrier” of the crop when the method of use of the present invention is carried out indicates a support for cultivating the crop, particularly a support for growing roots, and the material is not particularly limited. However, any material that can grow crops may be used, and so-called soil, seedling mats, water, etc. may be used. Specific materials include, for example, sand, pumice, cotton, paper, vermiculite, diatomaceous earth, agar, and gel. It may be a state substance, a polymer substance, rock wool, glass wool, wood chip, bark and the like.

  Examples of the application method to the soil include, for example, a method in which a liquid or solid preparation is diluted or not diluted with water and applied to the vicinity of a plant installation place or a nursery bed for raising seedlings, and a granule is installed to a plant body. The method of spraying to the vicinity or the nursery, the method of spraying powder, wettable powder, granule wettable powder, granule etc. before sowing or transplanting and mixing with the whole soil, the hole before sowing or planting the plant body, Examples include a method of spraying powder, wettable powder, wettable powder, granule, etc. on the strip.

  As a method for applying paddy rice to a seedling box, the dosage form may vary depending on the time of application such as application at seeding, application at greening period, application at transplanting, etc., but agents such as powder, granule wettable powder, granule Apply with a mold. It can also be applied by mixing with soil, and it can be mixed with soil and powder, granulated wettable powder or granules, for example, mixed with ground soil, mixed with soil covering, mixed with the entire soil. Simply, the soil and various preparations may be applied alternately in layers. The time of application at the time of sowing may be before sowing, at the same time, after sowing, or after covering. Also, in the paddy rice field, water surface application such as granules to paddy fields is often used.

  In field crops such as potato, sweet potato, soybean, and the like, it is preferable to treat the seeds or a cultivation carrier close to the plant body from sowing to raising seedling. In plants that are sown directly in a field, in addition to direct treatment on seeds, treatment on a cultivation carrier adjacent to the plant being cultivated is suitable. For example, a spray treatment using a granule or an irrigation treatment in a liquid of a drug diluted or not diluted in water can be performed.

  As the seeding of the cultivated plant to be transplanted and the treatment of the seedling raising period, in addition to the direct treatment to the seed, the irrigation treatment of the liquid drug or the granule spraying treatment to the seedling nursery can be performed. Moreover, a granule can be processed into a planting hole at the time of planting, or can be mixed with a cultivation carrier in the vicinity of the transplanting site.

  Even if a formulation containing each single active ingredient is mixed on site and treated by the above treatment method, a desired pest control effect can be exhibited. Moreover, even if each single preparation is treated by the above treatment method at the same time, a desired pest control effect can be exhibited. Here, “simultaneous period” does not only mean that the processing is performed at the same time, but can be regarded as the simultaneous period within a period of about one week, and different processing methods can be adopted. Furthermore, the desired pest control effect can also be expressed by treating each single preparation by the above-mentioned treatment method at intervals. The treatment interval at this time is not particularly limited as long as the effect of the present invention can be exerted, but generally it is preferably within 3 months, particularly preferably within 2 months, from the treatment of each single preparation. . At this time, either active ingredient may be processed first, or different processing methods may be employed.

  In addition, in recent years, IPM (Integrated Pest Management) technology using insect pheromones (such as toads and moths), natural enemy insects, etc. have advanced, and the agent of the present invention has been Can be used in combination or systematized.

  The treatment amount of the pesticidal composition of the present invention varies depending on various factors such as purpose, target pests, crop growth, weather, environmental conditions, dosage form, application method, application location, application time, etc. However, in the case of spraying treatment as an active ingredient compound, the active ingredient A may be appropriately treated in the range of 0.01 g to 200 g and the active ingredient B in the range of 0.01 g to 2000 g per hectare. In the case of the treatment, the active ingredient A may be sprayed or irrigated on the surrounding soil where the target crop is growing in the range of 1 g to 100 g and the active ingredient B in the range of 20 g to 1000 g.

The pest control composition of the present invention can also be used as a pest control agent other than farmland, for example, cuts, fallow fields, ridges, farm roads, waterways, grassland, cemeteries, parks , Roads, playgrounds, vacant lots around buildings, clearing terrain, railroad ends or forest pest control, or undergrowth of fruit trees such as grapes and olives I can do it.

The pest control composition of the present invention is suitable for controlling various types of agricultural forests such as rice, vegetables, fruit trees, and other flowers, horticultural storage pests, sanitary pests, and nematodes.
Lepidoptera (Lepidoptera) include, for example, Paraiso consocia, Redwood (Anomis mesogona), Swallowtail (Papilio xuthus), Azukiyamamushiga (Matsumuraeses azukivora), Azukinogaiga (Ostrinia scapulalis), African exoto (Spodera) (Hyphantria cunea), Awanoiga (Ostrinia furnacalis), Ayayoto (Pseudaletia separata), iga (Tinea translucens), rush saint moth (Bactra furfurana), Ichinomosei (Parnara guttata), Inaitei inferens), Brachmia triannulella, Monema flavescens, Iraqusinu Waiba (Trichoplusia ni), Pleuroptya ruralis, Cystidia couaggaria, Lampides boeticus, Males flamingo (Helicoverpa armigera) Killer whale pike (Phalerodonta manleyi), Oominoga (Eumeta japonica), giant cabbage butterfly (Pieris brassicae), lackey moth (Malacosoma neustria testacea),

Stathmopoda masinissa, Japanese oyster (Cuphodes diospyrosella), Japanese oyster (Archips xylosteanus), Japanese oyster (Agrotis segetum), Japanese sweet squirrel (Tetramoera schistaceana), Japanese pheasant (Papilio machaon hippoocula) Clawed moth (Lyonetia prunifoliella), Golden horned soga (Phyllonorycter ringoneella), Crimea (Cydia kurokoi), Crimidrisinigaiga (Eucoenogenes aestuosa), Grapeberry moss (Lobesia botrana), Black-tailed moth (Latoia sinica), Black moth Phalonidia mesotypa, Spilosoma imparilis, Glyphodes pyloalis, Olethreutes mori, Tineola bisselliella, bat moth (Endoclyta excres)

Kokuga (Nemapogon granellus), Cosca Shiba (Synanthedon hector), Codlinga (Cydia pomonella), Plutella xylostella, Cnaphalocrocis medinalis, Southern Pink Borer (Sesamia calamistis), Sanka Peldia (Scirpophaga incert) Potato moth (Phthorimaea operculella), killer whale (Stauropus fagi persimilis), Etiella zinckenella, Spodoptera exigua, white bat (Palpifer sexnotata), Sia , Xestia c-nigrum, Spodoptera depravata, Ephestia kuehniella, Angerona prunaria, Clostera anastomosis, mura, plus soy bean looper eses falcana, Tobacco moth (Helicoverpa assulta), Tamanaginuwawa (Autographa nigrisigna), Tamanayaga (Agrotis ipsilon), Euproctis pseudoconspersa, Adoxophyes orana, nanhochamagaki

Chamellar Eiga Edashak (Biston robustum), Tomato fruit worm (Heliothis zea), Nakajirositaba (Aedia leucomelas), Nashiiraga (Narosoideus flavidorsalis), Nashikenmon (Viminia rumicis), Nashichigaiga (Bucculatrix pyrivorella), Nashihimosata (ota) Ectomyelois pyrivorella, Chilo suppressalis, Acropepiopsis sapporensis, Plodia interpunctella, Hellula undalis, Spodtroga ceralella, ura, Kind ( Eucosma aporema, Acleris comariana, Scopelodes contracus, Orgyia thyellina, Fall army worm (Spodoptera frugiperda), Ostrinia zaguliaevi, Andracidae cenracandene bipunctata), grape squirrel (Paranthrene regalis), grape sparrow (Acosmeryx castanea),

Grape Anemone (Phyllocnistis toparcha), Grape Tomatochamaki (Endopiza viteana), Grape Hosohakimaki (Eupoecillia ambiguella), Velvet Bean Caterpillar (Anticarsia gemmatalis), Hosobahaiiromaki (Cnephasia cinereipalpana), Myria parm , Leguminivora glycinivorella, Maruca testulalis, Matsumuraeses phaseoli, Caloptilia soyella, Phyllocnistis citrella, Ardylco ), Acanthoplusia agnata, Bambalina sp., Carposina niponensis, Conogethes punctiferalis, Synanthedon sp., Lyonetia rk

White butterflies (Papilio helenus), Monk butterfly (Colias erate poliographus), Monarch butterfly (Phalera flavescens), white butterfly (Pieris rapae crucivora), white butterfly (Pieris rapae) and other white butterflies, , European corn borer (Ostrinia nubilalis), Mamestra brassicae, Ascitis selenaria, Phtheochroides clandestina, Apple tomato (Hoshinoa adumbratana), Apple uni ), Apple wolfberry (Adoxophyes orana fasciata), apple wolfberry (Grapholita inopinata), apple tiger beetle (Spilonota ocellana), apple tiger beetle (Spilonota lechriaspis), apple kingfisher (Illiberis pruni) (Argyrest hia conjugella, appleopter zebra (Caloptilia zachrysa), apple chipworm (Archips breviplicanus), cotton killer whale (Anomis flava), cotton beetle (Pectinophora gossypiella), cotton moth (Notarcha derogata), cotton helicopter moth (dia) And wateringa (Earias cupreoviridis)

Examples of the Hemiptera (Hymenoptera) include the red beetle (Nezara antennata), the red beetle (Stenotus rubrovittatus), the red beetle (Graphosoma rubrolineatum), the red beetle (Trigonotylus coelestialium), Aeschynteles maculatus), red beetle (Creontiades pallidifer), red beetle (Dysdercus cingulatus), red beetle (Chrysomphalus ficus), red beetle (Aonidiella aurantii), bulazesemis Scale insects (Icerya purchasi), green beetle (Piezodorus hybneri), blue beetle (Lagynotomus elongatus), blue beetle (Thaia subrufa), blue beetle (Scotinophara lurida), ibari beetle Ito Memushi (Stariodes iwasakii), Aspidiotus destructor, Usylorilygus turtle (Taylorilygus pallidulus), Myzusmumecola, Pseudaulacaspis prunicola, Pyuda sumi tho si phon Stink bug (Anacanthocoris striicornis), giant beetle turtle (Ectometopterus micantulus), giant beetle bug (Eysarcoris lewisi),

Molipteryx fulginosa, Cicadella viridis, Rhapalosophum rufiabdominalis, Olive scale (Saissetia oleae), Trialeurodes vaporariorum, cus A, cus L sp.), Euceraphis punctipennis, Andaspis kashicola, Coccus pseudomagnoliarum, Cavelerius saccharivorus, Galeatus ), Aonidiella citrina, Halyomorpha mista, Stephanitis fasciicarina, Trioza camphorae, Leptocorisa chinensis Kritari lice (Trioza quercicola), walnuts (Uhlerites latius), grape leaf hoppers (Erythroneura comes), black-footed beetle (Paromius exguus), black-footed beetle (Duplaspidiotus claviger), crocodile tuss Tobika turtle (Halticiellus insularis), Black planthopper (Perkinsiella saccharicida), Black apple lice (Psylla malivorella),

Anomeura mori, Pseudococcus longispinis, Swan scale (Pseudaulacaspis pentagona), Pulvinaria kuwacola, Apolygus lucorum, Tossa (Toxoptera aurantii), sugar cane scale insect (Saccharicoccus sacchari), sugar beetle beetle (Geoica lucifuga), sugar beetle (Numata muiri), sanjo scale insect (Comstockaspis perniciosa), citrus snow scale (Unaspis citriforma) Aulacorthum solani, Eysarcoris ventralis, Silver leaf whitefly (Bemisia argentifolii), White-footed beetle (Cicadella spectra), White-footed bug (Aspidiotus hederae), Liorhyssus h yalinus), Sophia nigridorsalis, Sogatella furcifera, Broad bean aphid (Megoura crassicauda), Daikon aphid (Bevicoryne brassicae), Soybean aphid (Aphis glycius), L (Nephotettix virescens), Thai aphids (Uroeucon formosanum), Tobacco turtle (Cyrtopeltis tennuis), Tobacco whitefly (Bemisia tabaci), Chanochaeta scales (Lecanium persicae), Chanokurohushi scale insect (Parlatoria thee dia) ),

Empoasca onukii, Plautia stali, Dysaphis tulipae, Macrosiphum euphorbiae, Stephanitis pyrioides, Cero cera (Parlatoria camelliae), Apolygus spinola turtle, Nephotettix cincticeps, Glaucias subpunctatus, sugar beet turtle (Orthotylus flavosparsus), corn aphid (Rhopalosiphum maidis) Eysarcoris parvus), Japanese lice (Cimex lectularius), Japanese lice (Psylla abieti), Japanese brown planthopper (Nilaparvata lugens), Japanese larva (Psylla tobirae), Japanese sea turtle (Eurydema rugosum), Nassiabra Bugs (Schizaphis piricola), psylla pyricola, psylla pyricola, parlatoreopsis pyri, pears (Stephanitis sashi), pears (Dysmicoccus wistariae), pears (Lepholeucaspis japula) ), Flounder erysimi, Neotoxoptera formosana, Rhopalosophum nymphaeae,

Bark beetle (Edwardsianarosae), Bark beetle (Pinnaspisaspidistrae), White horned beetle (Psylla alni), White-nosed leafhopper (Speusotettix subfusculus), Hanno-no-meki (Alnetoidia alneti), Delaco Japanese red beetle (Dysdercus poecilus), Japanese scale beetle (Parlatoria ziziphi), Japanese white-spotted beetle (Uhlerites debile), Japanese yellow-spotted plant (Laodelphax striatellus), Japanese green turtle (Eurydema pulchrum), Japanese white-spotted beetle (C) punctata, Empoasca sp., Coccus hesperidum, Pachybrachius luridus, Planococcus kraunhiae, Planococcus kraunhiae, Stenotus binotatus Bark beetle (Arboridia apicaris), butterfly leaf beetle (Macrosteles fascifrons), spotted beetle (Dolycoris baccarum), spotted beetle beetle (Adelphocoris triannulatus), grape beetle (Viteus vitifolii), sock beetle thoris beetle (Leptocorisa acuta),

White-headed bug (Macropes obnubilus), White-headed bug (Cletus punctiger), White-headed beetle (Riptortus clavatus), Potatopisilido (Paratrioza cockerelli), Maekiawafuki (Aphrophora costalis), Makibakasumi pon (Lygus) , Pine Criscus pini, Empoasca abietis, Cristicoccus matsumotoi, Bean Aphid (Aphis craccivora), Megacopta punctatissimum, Ori (Lepidosaphes beckii), citrus leaf pea (Diaphorina citri), citrus black aphid (Toxoptera citricidus), citrus scale insect (Planococcus citri), citrus white lice (Dialeurodes citri), citrus white lice (Aleurocanthus spiniferus) Pseudodococcus citriculus, Zyginella citri, Pulvinaria citricola, Coccus discrepans, Pseudaonidia duplex, Pteridaoni aria Scale insects (Lecanium corni), Nezara viridula, Stenodema calcaratum, Rhopalosiphum padi, Sitobion akebiae,

Barley beetle (Schizaphis graminum), Bark beetle (Sorhoanus tritici), Brachycaudus helichrysi, Spotted beetle (Carpocoris purpureipeny), Momoka peri yanagicola), willow beetle (Metasalis populi), willow beetle (Unaspis yanonensis), porcupine (Mesohomotoma camphorae), snowy beetle (Aphis spiraecola), apple aphid (Aphis pomi), apple oyster scale phe mali), apple crocus turtle (Heterocordylus flavipes), apple aphid (Myzus malisuctus), apple aphid (Aphidonuguis mali), apple madara leafhopper (Orientus ishidai), apple midori aramushi (Ovatus m alicolens), apple rotifer (Eriosoma lanigerum), ruby weevil (Ceroplastes rubens), cotton aphid (Aphis gossypii), etc.

As the Coleoptera (Coleoptera), for example, Xystrocera globosa, Aedagari (Paederus fuscipes), Eucetonia roelofsi, Azuki weevil (Callosobruchus chinensis), Arimodokisarifu (Hypera postica), weevil (Echinocnemus squameus), rice beetle (Oulema oryzae), rice beetle (Oulema oryzae), rice beetle (Donacia provosti), rice weevil (Lissorhoptrus oryzophilus), mosos euphorus (Epilachna varivestis), bean weevil (Acanthoscelides obtectus), western corn rootworm (Diabrotica virgifera virgifera), beetle weevil (Involvulus cupreus), weevil (Aulacophora femoralis), pea weevil ( Bruchus pisorum), Epilachna vigintioctomaculata, Carpophilus dimidiatus, Cassida nebulosa, Luperomorpha tunebrosa, Phyllotreais tribala Beetle (Aeolesthes chrysothrix),

Curculio sikkimensis, Carpophilus hemipterus, Oxycetonia jucunda, Cornroot worms (Diabrotica sp.), Mimela splendens, Sitophilus Taneribost , Sweeophilus oryzae, Palorus subdepressus, Melonlontha japonica, Anoplophora malasiaca, Neatus picipes, Decemtarsa decinotarsa , Sphenophorus venatus, Crichoris quatuordecimpunctata, weevil (Conotrachelus nenuphar), radish weevil (Ceuthorhynchidius albosuturalis), radish beetle (Phaedon brasse) White beetle (Lasioderma serricorne), Citkovian weevil (Sitona japonicus), White-horned beetle (Adoretus tenuimaculatus), White-footed beetle (Tenebrio molitor), White-footed beetle (Basilepta balyi), Trichosium gris Chaetocnema concinna), Anomala cuprea, Heptophylla picea, Epilachna vigintioctopunctata, Northern corn rootworm (Diabrotica longicornis), Eucetonia pilifera, sp

Crested beetle (Attagenus unicolor japonicus), Crested beetle (Pagria signata), Crested beetle (Anomala rufocuprea), Crested beetle (Palorus ratzeburgii), Crested beetle (Alphitobius laevigatus), Crested beetle L brunneus), Tribolium confusum, Medythia nigrobilineata, Xylotrechus pyrrhoderus, potato-free beetle (Epitrix cucumeris), pine beetle (Tomicus piniperda), Tomicus piniperda (Tomicus piniperda) , Poppy japonica, Epicauta gorhami, Sitophilus zeamais, Rhynchites heros, Listroderes costirostris, Callosobruchus macula, Callosobruchus macaque Bugs (Phyllobius armatus), Apple beetle (Anthonomus pomorum), Luri potato beetle (Linaeidea aenea), Cotton weevil (Anthonomus grandis), etc.

Examples of the Diptera (Flyidae) include Culex pipiens pallens, Pegomya hyoscyami, Liriomyza huidobrensis, Musca domestica, Chlorops oryzae and Chlorops oryzae. Flies (Hydrellia sasakii), rice leafhopper (Agromyza oryzae), rice brown leaf fly (Hydrellia griseola), rice leaf fly (Hydrellia griseola), common beetle (Ophiomyia phaseoli), leaflet (Dacus cucurbitae) Fruit flies such as fruit flies (Rhacochlaena japonica), Muscina stabulans, and fruit fly (Megaselia spiracularis); , Sinaha Daraka (Anopheles sinensis), Daikonbae (Hylemya brassicae),

Soybean fly (Asphondylia sp.), Seed fly (Delia platura), Onion fly (Delia antiqua), Cherry fruit fly (Rhagoletis cerasi), Chikaieka (Culex pipiens molestus Forskal), Ceratitis capitata, sia agrebanes tis , Sugar beetle (Pegomya cunicularia), tomato leaffly (Liriomyza sativae), eggplant leaffly (Liriomyza bryoniae), leafworm (Chromatomyia horticola), leafhopper (Liriomyza chinensis), netti questi (Aedes albopictus), beetle (Liriomyza trifolii), citrus fruit fly (Dacus dorsalis), citrus fly (Dacus tsuneonis), bark fly (Sitodiplosis mosellana), bark beetle (Meromuza nigriventden) ), Ring fly (Phagoletis pomonella), etc.

Examples of the order Hymenoptera (Hymenoptera) include, for example, red ants (Pristomyrmex pungens), antwing bees, Monomorium pharaosis, Pheidole noda, Athalia rosae, cricket (Dryocosmus kuriphilus), ica ), Hornets, sedge bee (Athalia infumata infumata), horned bee (Arge pagana), Japanese bee (Athalia japonica), hachiriari (Acromyrmex spp.), Fire ant (Solenopsis spp.), Apple bee (Arge mali) Rugliari (Ochetellus glaber)

Examples of the order of Diptera (Homoptera) include, for example, Homorocoryphus lineosus, Gryllotalpa sp. (Homorocoryphus jezoensis), Emmacrickets (Teleogryllus emma), etc.

Examples of the thrips include Selenothrips rubrocinctus, Rice thrips (Stenchaetothrips biformis), Thrips thrips (Haplothrips aculeatus), flavus thrips (Ponticulothrips diospyrosi), Thrips ), Thoths simplex, Thrips nigropilosus, Helothothripus microcephalus, Pseudodendrothrips (Leeuwenia pasanii), Shiimaruda thrips (Litotetothrips pasaniae), Citrus srips (Scirtothrips citri), Hawkins thrips (Haplothrips chinensis), Soybean thrips (Mycterothrips glycines),

Soybean thrips (Thrips setosus), Chano thrips dorsalis, Dendrothrips minowai, Thripsrips niger, Thrips tabaci, Thrips tabaci, Thrips tabaci Thrips hawaiiensis, Haplothrips kurdjumovi, Chirothrips manicatus, Frankliniella intonsa, Thrips coloratus, Thrips coloratus , Lily thrips (Frankliniella lilivora), lily thrips (Liothrips vaneeckei), etc.

For example, mite (Leptotrombidium akamushi), Asanowa tick (Tetranychus ludeni), American dock tic (Dermacentor variabilis), Ichinami spider mite (Tetranychus truncatus), house dust mite (Ornithonyssus bacoti), mite mite Tetranychus viennensis), tick such as Tetranychus kanzawai, Rhipicephalus sanguineus Tick (Dermacentor taiwanicus), Chinese cabbage mite (Acaphylla theavagrans), Chinese cabbage mite (Polyphagotarsonemus latus), Tomato mite (Aculops lycopersici), Tricarid mite (Ornithonyssus sylvairum), Nami spider mite (Tetranychus urticae) Mite (Eriophyes chibaensis), Mite (Sacroptes scabiei), Mite (Haemaphysalis longicornis), Black-legged tick (Ixodes scapularis), Spinach mite (Tyrophagus similis), Mite (Cheyletus eruditu) moorei), southern spider mite (Brevipuspus tick) ), Apple tick (Panonychus ulmi), lone star tic (Amblyomma americanum), duck spider (Dermanyssus gallinae), etc.

Examples of the termites are: the termite termite (Reticulitermes miyatakei), the American ant termite (Incisitermes minor), the termite (Coptotermes formosanus), the termite (Hodotermopsis japonica), the camper termite (Reticulitermes sp.), , Glyptotermes kushimensis, Coptotermes guangzhoensis, Neotermes koshunensis, Glyptotermes kodamai, Glyptotermes satsumen , Glyptotermes nakajimai, Pericapritermes nitobei, Yamato termite (Reticulitermes speratus), etc.

Examples of cockroaches include Periplaneta fuliginosa, German cockroach (Blattella germanica), Great cockroach (Blatta orientalis), Greater cockroach (Periplaneta brunnea), Greater cockroach (Blattella lituricollis), Greater cockroach (Peri) Periplaneta Americana)

Examples of fleas include human fleas (Pulex irritans), cat fleas (Ctenocephalides felis), chicken fleas (Ceratophyllus gallinae), etc.

As nematodes, for example, strawberry nematode (Nothotylenchus acris), rice scallop nematode (Aphelenchoides besseyi), red larvae nematode (Pratylenchus penetrans), red-footed nematode (Meloidogyne hapla), rostochiensis), Javaloid nematode (Meloidogyne javanica), Soybean cyst nematode (Heterodera glycines), Southern nematode nematode (Pratylenchus coffeae), Barley nematode (Pratylenchus neglectus), Citrus nematode (Tylenchus semipene, etc.)

Examples of molluscs include Pomacea canaliculata, Achatina fulica, slug (Meghimatium bilineatum), Lehmannina valentiana, Limacus flavus, and Acusta despecta si Other examples include agricultural and horticultural pests such as Tuta absoluta.

  The pest control composition of the present invention has an excellent control effect against various plant diseases, and is particularly suitable for controlling plant diseases of rice, fruit trees, vegetables, other crops and flowers.

Plant diseases belong to a wide variety of filamentous fungi such as Oomycetes, Ascomycetes, Ascomycetes, Deuteromycetes, and Basidiomycetes Not only has an excellent bactericidal effect against bacteria, but also has an excellent effect against phytopathogenic bacteria and plant viruses.

Examples of rice diseases include: yellow dwarf disease (S. macrospora), seedling blight (R. chinensis, T. viride), idiot seedling disease (G. fujikuroi), rice blast disease (M. grisea, P. oryzae), coat blight (R. solani), sesame leaf blight (C. miyabeanus), brown ear (A.padwiki), red rice (E. nigrum), rice koji (C. virens), blight Bacterial disease (P.glumae), leaf sheath browning disease (P.fuscovaginae), brown stripe disease (P.avenae), seedling bacterial disease (P.plantarii), white leaf blight (X.oryzae), etc .;
Examples of corn diseases include: sesame leaf blight (B.maydis, C.heterostrophus), soot spot (E.turcicum), spot disease (P.maydis), smut (U.maydis), etc .; tobacco diseases Examples include: plague (P. nicotianae / parasitica), downy mildew (P. tabacina), powdery mildew (E. cichoracearum), anthrax (C. tabacum), red scab (A. longipes, A. longipes) alternata), soot disease (C. salicinum), yellow spot disease (O. brassicae), etc .;

Examples of tea diseases include: erythema carcinoma (N. cinnabarina), leprosy (E. leucospila), anthrax (C. theae-sinensis), ring spot (P. longiseta, P. theae) , Net blast (E. reticulatum), blast (E. vexans), red burning (P. syringae pv. Theae), etc .; food crop diseases include, for example: sweet potato black spot (C. fimbriata), Sweet potato blue mold (P.expansum), sweet potato root rot (T.basicora), oat crown rust (P.coronata), mulberry and blight (S.mori), oil palm ganoderma disease (G.boninense), date palm Eye spot disease (S.palmivora), etc .; Examples of Brassicaceae diseases include: Brassicaceae clubroot (P. brassicae), Brassicaceae white rust (A.macrospora), Brassicaceae downy mildew (P.brassicae) , Brassicaceae nuclear disease (S. sclerotiorum), cabbage root rot (P. lingam), cabbage strain rot (T. cucumeris), rape vitiligo (C. brassicico) la), cabbage white spot disease (C.brassicicola), cabbage soft rot (Erwinia carotovora subsp.carotovora), cruciferous black spot disease (A.brassicae), cabbage black rot (X.campestris pv.campestris), etc .;

Strawberry diseases include, for example, plague (P. cactorum, P. nicotianae), powdery mildew (S. macularis), anthrax (G. cingulata), black spot (A. alternata), snake eye disease (M. fragariae) Examples of tomato diseases include: plague (P. infestans), anthrax (C. phomoides), leaf mold (C. fulvum), spot disease (S. lycopersici), ring rot (A. solani) ), Ulcer disease (C. michiganensis), etc .; Examples of solanaceous diseases include: S. sclerotiorum, powdery mildew (S. furiginea), brown leaf disease (P. vexans), subtilis disease (M. nattrassii), sweet pepper spot disease (S. lycopersici), red pepper spot disease (S. lycopersici), solanaceous bacterial wilt (P. solanacearum), solanaceous bacterial wilt (P. solanacearum), etc .;

Examples of cucurbitaceae diseases include: cucumber blight (P. melonis), cucumber downy mildew (P. cubensis), cucumber powdery mildew (S. furiginea), cucumber vine blight (M. melonis, D. bryoniae) ), Watermelon vine blight (M.melonis, D.bryoniae), cucumber sclerotia (S.sclerotiorum),
Cucumber anthracnose (C. lagenarium), cucumber brown spot (C. cassiicora), cucumber black spot (C. cucumerinum), cucumber vine split (F. oxysporum f.sp. cucumerinum, F. oxysporum f.sp. meronis), cucumber spotted bacterial disease (P. syringae pv. Lachrymans), etc. Examples of onion and onion diseases include: leek downy mildew (P. destructor), leek soft rot (E. carotovora subsp. carotovora, E. chrysanthemi, E.rhapontici), onion leaf blight (P.herbarum), onion sclerotia (S.sclerotiorum), onion gray rot (B.alli), onion vitiligo leaf blight (B. byssoidea, B. squamosa) ), Onion black spot (A.porri), onion dry rot (F.oxysporum f.sp.cepae), leek rust (P.allii), etc .;

Examples of root vegetables diseases include: carrot black leaf blight (A. dauci), radish black spot disease (A. brassicicola), etc .; examples of flower diseases include: rose blight (P. megasperma), rose noodles Disease (S. pannosa), rose rust (K. rosae / japonica), rose black spot (D. rosae), chrysanthemum brown (S. chrysanthemi-indici), chrysanthemum (C. chrysanthemi), chrysanthemum white Rust disease ((P.horiana), Chisha downy mildew (B.lactucae), Astor downy mildew (B.lactucae), root cancer (A.tumefaciens), etc .;

Examples of turf / grass diseases include: turf red burn (P.apahanidermatum), turf summer patch (M.poae), turf hermint sporium leaf blight (D.poae), turf dollar spot (S.homoeocarpa) ), Lawn anthracnose (C.graminicora), carraria leaf blight (C.geniculata), turf large patch (R.solani), brown patch (R.solani), snow rot (Pythium sp., S.borealis, M.nivalis, F.nivale, T.ishikariensis, T.incarnata), pasture black sesame disease (P.graminis), alfalfa leaf spot (P.medicaginis), clover leaf spot (P.trifolii), grass Ear disease (E.typhina), alfalfa macular disease (P.medicaginis), alfalfa stem blight (P.medicaginis), etc .;

Examples of wheat diseases include: Snow rot (Pythium sp., M.nivalis, S. borealis, F.nivale), snow rot (T.ishikariensis, T.incarnata), red mold (G.zeae, F.avenaceum, F.graminearum, F. culmorum, M.nivale), ergot disease (C.purpurea), blight (G.graminis), strain rot (C.gramineum), sharp eyespot (C.cereale) , Powdery mildew (B.graminis fsp. Tritici), blight (L. nodorum, S.nodorum), red rust (P.recondita), black rust (P. graminis), yellow rust (P.striiformis) ), Eye spot disease (P.herpotrichoides), leaf blight (S.tritici), macular disease (P.tritici-repentis), streak disease (C.gramineum), naked smut (U.nuda), kurokuroho Disease (T.caries), smut (U.agropyri), etc .;

Examples of barley diseases include: Snow rot (Pythium sp., S. borealis, M. nivalis, F. nivale, T.ishikariensis, T. incarnata), Red mold (G.zeae, M. nivale, F) .avenaceum, F.graminearum, F. culmorum), ergot disease (C. purpurea), blight (G.graminis, O.graminis), streak disease (C.gramineum), powdery mildew (B.graminis fsp) Hordei), net blotch disease (P. teres), leaf spot disease (P. graminea), spot disease (B. sorokiniana, C. sativus), leaf burning (C. herbarm), cloud disease (R. secaris) , Black rust (P. graminis), yellow rust (P. striiformis), scab (P. hordei), black smut (U. hordei), etc .;

Potato diseases include, for example: powdery scab (S. subterranea), scab (S. scabies), plague (P. infestans), summer plague (A. solani), black bruise (R. solani) ), Ring rot (C. michiganensis), ring lot disease (C. michiganensis), etc .; sugar beet diseases include, for example: black root disease (A. sochlioides), leaf rot (T. cucumeris), root rot ( T.cucumeris), snake eye disease (P.betae), brown spot disease (C.beticora), spot disease (R.beticora), rust fungus (U.betae), etc .;

Examples of the diseases of legumes include: S. sclerotiorum, soybean rust (P. pachyrhizi), soybean downy mildew (P. manshurica), soybean purpura (C. kikuchii), soybean black spot ( D.phaseolorum var. Sojae), soybean black rot (E. glycines), soybean charcoal (M.phaseolina), soybean black root rot (C. crotalariae), groundnut black root rot (C. crotalariae), groundnut black Astringent disease (M.personatum), groundnut scab (S.arachidis), groundnut black mold (A.niger), groundnut brown spot (C.arachidicola), kidney bean disease (C.arachidicola), bean anthrax Disease (C.indemthianum), kidney bean root rot (F.solani f.sp.phaseoli), kidney bean bacterial disease (C.flaccumfasiens), azuki bean disease (P.griseola), pea downy mildew (P.pisi) ), Pea powdery mildew (E.pisi), broad bean plague (P.nicotianae), broad bean mildew (P.viciae), broad bean brown spot A.fabae) and the like;

Examples of apple diseases include: powdery mildew (P. leucotricha), rot (V. ceratosperma), white coat (R. necatrix), purple coat (H. mompa), and black spot (V. inaequaris), spotted leaf disease (A.mali), moniliosis (M.mali), anthrax (G.cingulata), ring rot (Botryosphaeria sp,), blacklot disease (B.obtusa, X.campestris pv. campestris), sunspot disease (M.pomi), brown spot disease (D.mali), red star disease (G.yamadae), cedar-apple rust (G.Juniperi-virginianae), Suehirotake disease (S.commune), silver Leaf disease (C. purpurreum), root cancer disease (A. tumefaciens), burn disease (E. amylovora), etc .;

Pear diseases include, for example: white coat disease (R. necatrix), black spot disease (V. nashicola), black spot disease (A. kikuchiana), red star disease (G. asiaticum), powdery mildew (P. pyri) ), Ring rot (P.piricora), blight (P.fukushii), heart rot (L. sulphureus), root cancer (A.tumefaciens), burn (E.amylovora), etc .; Examples of grape diseases include: white rot (R. necatrix), gray mold (B. cinerea), downy mildew (P. viticola), powdery mildew (U. necator), late rot (G .cingulata), black scab (E.ampelina), brown spot (P.vitis), rust (P.ampelopsidis), blacklot (G.bidwellii, X.campestris pv.campestris)), Pestarocia vine withering Disease (P. menezesiana), California disease (X.fastidiosa), root cancer disease (A.vitis), etc .;

The peach diseases include, for example: T. deformans, M. fructicola, C. carpophilum, Phomopsis sp., Mildew disease (A. niger) ), Spot disease (C. beyerinckii), root cancer disease (A. tumefaciens), perforated bacterial disease (X. campestris pv. Pruni), etc .; necatrix), gray mold disease (B.cinerea), sunspot disease (D.citri), scab disease (E.fawcettii), black spot disease (G.citricarpa), round star disease (P.beltranii), anthrax disease ( C. gloeosporioides), green mold disease (P. digitatum), blue mold disease (P. italicum), mushroom disease (G. applanatum), soot disease (C. salicinum), ulcer disease (X. campestris pv.citri) ), Stubborn disease (S. citri), Greening disease (C. Liberibacter), etc .; Kiwi diseases include, for example: Kiwi fruit scab (P. syringae pv. Actinidiaea, A. delicio) sa, A.chinensis, A. arguta) etc.

Examples of tree / flower disease include: Akebono powdery mildew (M.akebiae), alder powdery mildew (M. penicillata), or elder disease such as Dutch elm disease (O.ulmi), chestnut Blight (E.parasitica), apricot blight (L..persoonii), elm spot (G.ulmi), cherry black knot (A.morbosa), pine leaf sieve needle cast (L pinastri), pine soot leaf needle blight (R. kalkhoffii), pine species Diplodia blight (S.sapinea), cherry rust (T.asiatica / prumi-spinosae), willow leaf rust (M. arctica), poplar leaf rust (M.medusae), button rust (C.flaccidum), oak stem sorghum (S.hirsutum), cypress root rot (H.annosum), pine root Rot (G.lucidum), bamboo shoot (A.mellea), bamboo shoot (T.versicolor), pine knot (C.quercum), pine leaf rust (C.asterum), walnut stem heart Rot (P.igniarius), red pine leaf blight (D.septosporum), black pine leaf blight (D.septosporum), cherry stem heart rot (F.pinicora), etc .;

Other fruit tree diseases include, for example: white coat rot (R. necatrix), ume powdery mildew (P. tridactyla), ume black scab (C. carpophilum), oyster circle deciduous (M. nawae), oyster Anthracnose (G.kaki), Oyster leaf blight (P.diospyri), Oyster horn spot leaf disease (C.kaki), Oyster black spot disease (F. levieri), Biwa anthracnose (C.acutatum), Banana shigatoka M.fijiensis / musicola, banana panama disease (F.oxysporum f.sp.cubense), root cancer disease (A.tumefaciens), mango anthracnose (C.gloeosporioides), etc .;

Examples of polycytic diseases include: various seedling blight (P.ultimum, P.apahanidermatum), various root rots (P.cinnamomi), white coat rot (R.necatrix), rot (V. ceratosperma), half body wilt disease (V. dahliae, V. albo-atrum), gray mold disease (B. cinerea), mycorrhizal disease (S. sclerotiorum), silkworm disease (S. rolfsii), vegetable wilt disease (R. solani), purple crest (H. mompa), soft rot (E. carotovora, E. aroideae), root cancer (A. tumefaciens), etc .;

Moreover, this fungicide has an excellent bactericidal effect against resistant bacteria. Resistant bacteria include Botrytis cinerea, Cercospora beticola, Venturia inaequalis, and pear scab that are resistant to benzimidazole fungicides such as thiophanate methyl, benomyl, and carbendazim. (Venturia nashicola); Gray mold fungus (Botrytis cinerea) which shows resistance to dicarboximide fungicides (for example, vinclozoline, procymidone, iprodione) and the like.

Examples of plant pathogenic bacterial diseases include: cucumber spotted bacterial disease (P. syringae pv. Lachrymans), rice brown stripe disease (P. avenae), rice seedling bacterial disease (P. plantarii), rice wilt bacterial disease (P.glumae), rice leaf sheath browning disease (P.fuscovaginae), solanaceae bacterial wilt (P.solanacearum), tea scab (P.syringae pv.theae), citrus ulcer disease (X.campestris pv.citri) ), Cabbage black rot (X.campestris pv.campestris), peach perforated bacterial disease (X.campestris pv.pruni), rice leaf blight (X.oryzae), grape blacklot disease (X.campestris pv.campestris) , Apple blacklot disease (X.campestris pv.campestris), apple burn disease (E.amylovora), pear burn disease (E.amylovora), soft rot disease (E.aroideae, E.carotovora), bean wilt bacterial disease (C .flaccumfasiens), root cancer disease (A.tumefaciens), grape root cancer disease (A.vitis), potato scab (S.scabies), citrus Bone disease (S. citri), tomato ulcer disease (C. michiganensis), potato ring rot (C. michiganensis), ring lot disease (C. michiganensis), citrus greening disease (C. Liberibacter), etc .;

Diseases caused by plant viruses include, for example: tomato mosaic disease (tobacco mosaic virus), cucumber green spot mosaic disease (cucumber green spot mosaic virus), tobacco stem rot (tobacco stem virus), wheat Dwarf disease (wheat dwarf virus), barley spotted mosaic disease (wheat spotted mosaic virus), potato tuber brown ring spot disease (potato mop top virus), sugar beet root disease (beat beetle leaf yellowing virus), Tomato mosaic disease (potato virus X), apple high contact disease (apple stem grooving virus), apple high contact disease (apple chlorotic tie spot virus), tomato mosaic disease (potato virus Y), umewahanbyo (umemehan virus), Cucumber Mosaic Byou (Zucchini hammozai) Virus), radish mosaic disease (turnip mosaic virus), soybean mosaic disease (soybean mosaic virus), barley stripe dwarf disease (barley stripe dwarf virus), barley yellow dwarf disease (barley yellow dwarf virus), soybean dwarf disease (soybean dwarf disease) Virus), strawberry virus disease (strawberry mild yellow edge virus), potato leaf curl disease (potato leaf curl virus), rice dwarf disease (rice dwarf virus), cucumber mosaic disease (cucumber mosaic virus), alfalfa mosaic disease (alfalfamo) Cycvirus), Northland Mosaic Disease (Wheat Northland Mosaic Disease), Rice Stripe Disease (Rice Stripe Virus), Tomato Yellow Scab (Tomato Yellow Shrimp Virus), Rice Dwarf Disease (Rice Atrophy) Virus), rice black stripe dwarf disease (rice black stripe dwarf virus) Can be mentioned.

  As the genus of dicotyledonous weeds, the weeds that can be controlled by the harmful control composition of the present invention include morning glory (Ipomoea), azena (Lindernia), American horned moth (Sesbania), ichibi (Abutilon), dog chamomile (Matricaria), dog garage ( Rorippa), nettle (Urtica), nettle (Lamium), red fir tree (Xanthium), mustard (Sinapis), red stag beetle (Rotala) stag beetle (Veronica), poppy (Papaver), white crab (Chenopodium), white clover ), Surihiyu Matsuba button (Portulaca), Violet pansy (Viola), Aruba morning glory (Pharbitis), Chishima Odro (Galeopsis), Datura, Eggplant potato (Solanum), Nazuna (Capsella), Nozami fujiami ( Cirsium, Sonchus, Haginamega (Galinsoga), Hakobe (Stella) ria), Syencho, Senecio, Amaranthus, Ambrosia, Kochia, Hotokenoza (Lamium), Leipidium, Polygonum, Yaemu Galium), cornflower (Centaurea), mugwort (Artemisia) and the like.

Examples of monocotyledonous weeds include Azegaya (Leptochloa), Akagaeri Timothy (Phleum), Strawberry Swallow Suzume Katavilla (Poa), Ushikokesa Toboshigara (Festuca), Enokoro Awa (Setaria), Ohishiba Shikokubie (Eleus) Omodaka Kwai (Sagittaria), Duckweed (Agropyron), Platypus (Ischaemum), Cyperus Papyrus schitoui hamasuge (Cyperus), Oats, Oat (Avena), Vineyards (Bromu), Bromu Cynodon, Monochoria, Alopecurus, Paspalum, Commelina, Fimbristylis, Lolium, Brachiaria, charisto, Agrostis ), Echinochlona, Ho Louis Ukiyagura-thick (Scirpus), crabgrass (Digitaria), and the like sorghum (Sorghum).

Specific examples of other weeds include Amaranthus retroflexus, Amaranthus viridis, Aquinocologosa (Setaria faberi), Azegaya (Leptochloa chinensis), Azetogarashi (Lindernia angustifolia), Abena (Lindernia) ), American Azena (Lindernia dubia), American King Deer (Sida spinosa), American Sanaetade (Polygonum pensylvanicum), American horned foxtail (Sesbania exaltata), American staghorn (Geranium carolinense), Arechinogiku (Conyza bonariensis), margarus well (A) , Polygonum cuspidatum, Abutilon theophrasti, Matricaria perforata, Polygonum longisetum, Echinochloa crus-galli, Amaranthus lividus, Swan rum , Musva sylvestris, Horsetail (Bromus tectorum), Surittaria pygmaea Miq, Rumex obtusifolius, Enocorosa (Setaria viridis), Cassia obtusifolia (Cassia obtusifolia) Veronica persica, Xanthium canadens, Paccum dichotomiflorum, Asclepias syriaca, Euphorbia maculata, Anthony palm, Planto asiatica, Oth strumarium), Venus sterilis, Eleusine indica, Ogitaka (Sagittaria trifolia), Eurodium cic utarium,
Dutch Gregia (Cerastium glomeratum), Ortricia matricarioides, Camellia (Matricaria chamomilla), Vicia angustifolia, Vilas angustifolia, Bromus secalinus, Avena fatua, ala carousa ), Ripex japonicus, Cyperus esculentus, Setaria glauca, Pueraria lobata, Eleocharis kuroguwai Ohwi, Ambrosia trifida, Cornumgold seum, Chrysantum seum iria), oak (Monochoria vaginalis), kochimebie (Echinochloa colona), Sasiomodaka (Alisma plantago-aquatica), weed rice (Oryza sativa), Sanaetade (Polygonum lapathifolium),

Shibamugi (Agropyron repens), Shater cane (Sorghum vulgare), Silky bentgrass (Apera spica-venti), Shiroza (Chenopodium album), White clover (Trifolium repens), White butterfly (Datura stramonium), Sugina (Equisetum arv) Poa annua), Bromus japonicus, Alopecurus aequalis, Portulaca oleracea, Solidago altissima, Sorghum halepena, jun jun , Convolvulus arvensis, Malva neglecta, Oenanthe javanica, Buckwheat (Polygonum convolvulus), Echinochloa oryzicola Vasing, Ischaemum rugosum, Tachiinu Veronica arvensis, Cyperus difformis L., Amaranthus rudis, Ludwigia prostrata Roxburgh, Commelina communis, Panicum texanum, E Nagameshigishi (Rumex crispus), Japanese red tuna (Capsella bursa-pastoris), Japanese persimmon (Euphorbia pseudochamaesyce), Japanese persimmon (Brachiaria plantaginea), Japanese barley (Lolium multiflorum), Japanese horned moth (Alopecurus myosuroides) , Steller's media, Cyperus rotundus, Amaranthus spinosus, Polygonum persicaria, Papaver rhoeas, Sunflower (Helianthus annuus), Lamin purpureum (Lamium purpureum) a), Ammannia multiflora, Erigeron canadensis, Potamogeton distinctus A. Benn, Amaranthus tuberculatus, Viola arvensis, Ambrosia artemisae , Blackgrass (Alopecurus myosuroides), Florida begerweed (Desmodium tortuosum), leafhopper (Plantago lanceolata), leafhopper (Alisma canaliculatum A. Br.et Bouche), barbet (Kochia scoparia), bark (Lolium rigidum), barbet (Lolium rigidum) Ammannia coccinea), barley (Lolium perenne), firefly (Scirpus juncoides Roxburgh), red beetle (Lamium amplexicaule), red-tailed hawk (Amaranthus hybridus), pine beetle (Eleocharis acicularis L.), bean moth (Ipomoea lac) Ipomoea pu rpurea, Marpa American morning glory (Ipomoea hederacea var integriuscula), Marbatus duckweed (Commelina bengharensis), Monchoria korsakowii, Cyperus serotinus Rottboel, Digitari digit (Elatine triandrak) sanguinalis), sorghum (Sorghum bicolor), yamgra (Galium aparine), mugwort (Artemisia princeps), wild pansy (Viola tricolor), wild radish (Raphanus raphanistrum), forget-me-not (Myosotis arvensis), hera moda flaccidus).

Other weeds that can be controlled are Inubibies (Gramineae 1st grade, paddy weeds), Azena (Lepidoptera 1st grade grass, paddy weeds), Japanese oaks (1st graded grass, paddy weeds), Mizuaoi (Apiaceae annual, weed of paddy field), Himemisohagi (Misohagi annual, weed of paddy field), Tamagayatsuri (Cyperaceae annual, paddy weed), Matsubai (Cyperaceae perennial, wetland, waterway, paddy field) Perennial weeds of paddy fields), Omodaka (Omodakaceae, paddy fields, wetlands, perennial weeds that grow in trenches), Urikawa (Omodakaceae, paddy fields, wetlands, perennial weeds that grow in trenches), fireflies (Perennial weeds perennials), Paddy field, wetland, ditch), Krogwei (Cyperaceae perennial grass, paddy field, damp ground, ditch), sparrow gill Tasakusaku, occurring in low-wetlands), oats (occurring in the perennial grass, flatland, wasteland, upland), mugwort (occurring in the perennial grass, Yamano, upland), barbet (annual grass, field, Arboretum weeds), Gigigishi (Tadeiaceae perennial grass, field and roadside), Kogomegatsutsu (Cyperaceae 1st year grass, upland weed), Aubiyu (Amaranthus 1st grade, vacant land, roadside, and field), Onamomi (Asteraceae annual grass, upland weed), Ichibi (Aoiaceae annual grass, upland weed), White-faced dwarf morning glory (Oldaceae 1-year grass, upland weed), Giant pufferfish , Field weeds) or yamgra (Rubiaceae perennial, field, orchard weeds), etc., are first-year, perennial or perennial weeds.

  The pesticidal composition of the present invention may be used for other agro-horticultural insecticides, acaricides, and line killers, depending on the situation of use, for the purpose of controlling the organisms to be controlled, the appropriate control period, or for the purpose of reducing the dose. It can also be used as a mixture with insecticides, fungicides, biological pesticides, herbicides, plant growth regulators, safeners (also called safeners), soil conditioners, fertilizers and the like. Although the typical compound is illustrated below, it is not limited to these.

Other herbicides used for such purposes include, for example, 1-naphthylacetamide, 2,4-PA, 2,3,6-TBA, 2,4,5-T, 2,4,5-TB, 2,4 -D, 2,4-DB, 2,4-DEB, 2,4-DEP, 3,4-DA, 3,4-DB, 3,4-DP, 4-CPA, 4-CPB, 4-CPP , MCP, MCPA, MCPA thioethyl, MCPB, ioxynil, acronifen, azafenidin, acifluorfen, aziprotryne, azimsulfuron, aslam, acelam Acetochlor, atrazine, atraton, anisuron, anilofos, abiglycine, abscisic acid, amicarbazone, amidosulfuron, amitrol (Amitrole), aminocyclopyrachlor, aminopyralide (a minopyralid, amibuzin, amiprophos-methyl, ametridione, ametrin, alachlor, arichlor (allidochlor), alloxydim, alorac, i Offensesulfuron, isouron, isocarbamide, isoxachlortole, isoxapyrifop, isoxaflutole, isoxaflutole, isoxaben, isosyl , Isonoruron, isoproturon, isopropalin, isopolinate, isomethiozin, inabenfide, ipazine, ipfencarbazone, ipryam ), Imazaquin, imazapic, imazapyr, imazamethapyr, imazamethabenz, imazamethabenz-methyl, imazamox, imazathapyr, imazethapyr imazosulfuron, indaziflam, indanofan, indolebutyric acid, uniconazole-P (uniconazole-P), eglinazine, esprocarb, ethametsulfuron, etametosulfuron (ethametsulfuron-methyl), ethalluralin, etiolate, ethichlozate ethyl, etidimuron, etinofen, ethephon, ethoxysulfur on, ethoxyfen, etnipromid, etofumesate, etobenzanid, epronaz, erbon, endothal, oxadiazon, oxadiargyl, Oxaziclomefone, oxasulfuron, oxapyrazon, oxyfluorfen, oryzalin, orthosulfamuron, orbencarb, caffenstrole, cambendichlor cambendichlor, carbasulam, carfentrazone, carfentrazone-ethyl, karbutilate, carbetamide, carboxazole carboxazole), quizalofop, quizalofop-P, quizalofop-ethyl, xylachlor, quinoclamine, quinonamid, quinclorac, quinclorac (Quinmerac), cumyluron, cliodinate, glyphosate, glufosinate, glufosinate-P, credazine, clethodim, cloxyfonac, Clodinahop, clodinafop-propargyl, clotoluron, clopyralid, cloproxydim, cloprop, clobromuron, clofop, clomazone ), Lomethoxynil, chlomethoxyfen, clomeprop, chlorazifop, chlorazine, chlorazine, chloranocryl, chloramben, chloramslam-methyl , Chloridazon, chlorimuron, chlorimuron-ethyl, chlorsulfuron, chlorthal, chlorthiamid, chlortoluron, chlornitrofen, chlorfenac (Chlorfenac), chlorfenprop, chlorbufam, chlorflurazole, chlorflurenol, chlorprocarb, chlorprocarb Chlorpropham, chlormequat, chloreturon, chloroxynil, chloroxuron, chloropon, saflufenacil, cyanazine, cyanatryn, dialate ), Diuron, diethamquat, dicamba, cycluron, cycloate, cyclooxydim, diclosulam, cyclosulfamuron, cyclopyrimoleate ( cyclopyrimorate, dichlorprop, dichlorprop-P, diclolobenil, diclofop, diclofop-methyl, dichlormate, dichloralure a), diquat, cisanilide, disul, siduron, dithiopyr, dinitramine, cinidon-ethyl, dinosam, cinosulfuron, Dinoceb (dinoseb), dinoterb (dinoterb), dinofenate (dinofenate), dinoprop (dinoprop), cyhalofop-butyl, diphenamid (diphenamid), diphenoxuron (difenoxten), difenopenten (difenopenten), difenzot di ), Sibutrin, cyprazine, cyprazole, diflufenican, diflufenzopyr, dipropetryn, cypromid, cyperquat, berellin, b Simazine, dimexano, dimethachlor, dimedazon, dimethametryn, dimethenamid, simethrin, simeton, dimepiperatedi, dimeperon, dimefronate Cinmethylin, swep, sulglycapin, sulcotrione, sulfallate, sulfentrazone, sulfosulfuron, sulfometuron, sulfometuron methyl (sulfometuron-methyl), secbumeton, sethoxydim, sebuthylazine, terbacil, daimuron, dazomet, dalapon, thiazafluron Thiazopyr, tiafenacil, thiencarbazone, thiencarbazone-methyl, thiocarbazyl, tioclorim, thiobencarb, thiobencarb, thidiazimin, idiron Thifensulfuron, thifensulfuron-methyl, desmedipham, desmetryn, tetrafluron, tenenylchlor, tebutam, tebuthiuron, tebuthiuron (Terbumeton), tepraloxydim, tefuryltrione, tembotrione, delachlor, terbacil, terbucarb, terb Terbuchlor, terbuthylazine, terbutryn, topramezone, tralkoxydim, triaziflam, triasulfuron, triafamone, tri-allate, tri-allate, tri-allate (Trietazine), tricamba, triclopyr, tridiphane, tritac, tritosulfuron, trifludimoxazin, triflusulfuron, triflusulfuron methyl (triflusulfuron-methyl), trifluralin, trifloxysulfuron, tripropindan, tribenuron-methyl, tribenuron, trifop, Rifopsime, trimeturon, tolpyralate, naptalam, naproanilide, napropamide, nicosulfuron, nitralin, nitrofen, nitroflufen (Nitrofluorfen), nipyraclofen, neburon, norflurazon, noruron, barban, paclobutrazol, paraquat, parafluron, haloxydine ), Haloxyifen, Haloxyfop, Haloxyfop-P, Haloxyfop-methyl, Halofafen, Halofuron, Halofururon, Halofurfonmethyl uron-methyl, picloram, picolinafen, bicyclopyrone, bispyribac, bispyribac-sodium, pydanon, pinoxaden, bifenox , Piperophos, hymexazol, pyraclonil, pyrasulfotole, pyrazoxifene, pyrazosulfuron, pyrazosulfuron-ethyl, pyrazolate, birazolate, pyrazolate bilanafos), pyraflufen-ethyl, pyriclor, pyridafol, pyrithiobac, pyrithiobac-sodium, pyridate, pyriftalide Pyributicarb, pyribenzoxim, pyrimisulfan, pyrimisulfuron, pyriminobac-methyl, pyroxasulfone, pyroxsulam, fenasulam , Phenisopham, fenuron, fenoxasulfone,
Fenoxaprop, fenoxaprop-P, fenoxaprop-ethyl, phenoxathiol, phenothiop, fenopropuron, phenobenzuron, fenquinotrione (Fenquinotrione), fenthiaprop, fenteracol, fentrazamide, phenmedipham, phenmedipham-ethyl, butachlor, butafenacil, butamifos (Butamifos), buthiuron, buthidazole, butyrate, buturon, butenachlor, butenaxy, butroxydim, butralin, flazasulfuron, flamprop ), Furyloxyfen, prynachlor, primisulfuron-methyl, fluazifop, fluazifop-P, fluazifop-butyl, fluazolate (Fluazolate), fluroxypyr, fluothiuron, fluometuron, fluoroglycofen, flurochloridone, fluorodifen, fluoronitrofen, fluoromidine ), Flucarbazone, flucarbazone-sodium, fluchloralin, flucetosulfuron, fluthiaset, fluthiaset-methyl, flupyrsulfuron ( flupyrsulfuron, flufenacet, flufenican, flufenpyr, flupropacil, flupropanate, flupoxam, flumioxazin, flumicoxazin, flumiclorac, Flumiclorac-pentyl, flumipropyn, flumezin, fluometuron, flumetsulam, fluridone, flurtamone, fluroxypyr, pre-chloracrol Proxan, proglinazine, procyazine, prodiamine, prosulfalin, prosulfuron, prosulfocarb, prosulfocarb Kizahop (propaquizafop), propachlor, propazine, propanil, propyzamide, propisochlor, prohydrojasmon, propyrisulfuron, propham ), Profluazol, profluralin, prohexadione-calcium, propoxycarbazone, propoxycarbazone-sodium, propoxycarbazone-sodium, prooxydim, bromacil , Brompyrazon, prometryn, prometon, bromoxynil, bromofenoxim, bromobutide, bromobonil, florasulam (fl) orasulam), florpyrauxifen, hexachloroacetone, hexazinone, petoxamide, benazolin, penoxsulam, pebulate, beflubutamid, benobutrate vernolate, perfluidone, bencarbazone, benzadox, benzzipram, benzylaminopurine, benzthiazuron, benzfendizone, bensulide, benz Bensulfuron-methyl, benzoylprop, benzobicyclon, benzofenap, benzofluor, benzofluor, bentazone, pentano Pentanochlor, benthiocarb, pendimethalin, pentoxazone, benfluralin, benfuresate, fosamine, fomesafen, foramsulfuron, hol Chlorfenuron (maleic hydrazide), mecoprop (mecoprop), mecoprop-P (mecoprop-P), mezinoterb, mesosulfuron, mesosulfuron-methyl, mesotriuron-methyl (Mesotrione), mesoprazine, mesoprotryne, metazachlor, methazole, metazosulfuron, methabenzthiazuron, metamitron, metamitron Hop (metamifop), metam (methalpropalin), methiuron (methiuron), methiozoline (methiozolin), methiobencarb (methiobencarb), methyldymron (methyldymron), methoxuron (metoxuron), methosulon (methosulon) (Metsulfuron), metsulfuron methyl (metsu1furon-methy1), methotrazon (metflurazon), metrobromuron (metobenzuron), metometron (methometon), metolachlor (metolachlor), metribuzin (metribuzin) -chloride), mefenacet, mefluidide, monalide, monisouron, monuron, monochloroacetic acid, monolinuron, molinate , Morfamquat, iodosulfuron, iodosulfuron-methyl-sodium, iodobonil, iodomethane, lactofen, lancotrione, linuron (Linuron), rimsulfuron, lenacil, rhodethanil, calcium peroxide, methyl bromide and the like.

Other agricultural and horticultural insecticides, acaricides, and nematicides used for similar purposes include:
3,5-xylyl methylcarbamate (XMC), Bacillus thuringiensis aizawai, Bacillus thuringiensis israelensis, Bacillus thuringiensis japonensis, Bacillus thuringiensis kurstaki, Bacillus thuringiensis tenebrionis, Bacillus thuringiensis produced crystalline protein toxin, BPMC, Bt toxin C chlorfenson), DCIP (dichlorodiisopropyl ether), DD (1, 3-dichloropropene), DDT, NAC, O-4-dimethylsulfamoylphenyl O, O-diethyl phosphorothioate (DSP), O-ethyl O-4-nitrophenyl phenylphosphonothioate (EPN), tripropylisocyanurate (TPIC), acrinathrin, azadirachtin, azinphos-methyl, acequinocyl, acetamiprid, acetoprole, acephate, actin ), Afidopyropen, avermectin (avermectin-B), amidoflumet, amitraz, alanikalb (a lanycarb), aldicarb, aldoxycarb, aldrin, alpha-endosulfan, alpha-cypermethrin, albendazole, allethrin, isazophos ( isazofos, isamidofos, isamidofos, isoxathion, isofenphos, isofenphos, isoplocarb (MIPC), epsilon-metofluthrin, epsilon-momfluorothrin, ivermectin (ivermectin), imifiaphos imidac1oprid), imiprothrin, indoxacarb, indoxacarb, esfenvalerate, ethiofencarb, ethion, ethiprole, etoxazole, etofenprox, etofenprox (ethopro phos), etrimfos, emamectin, emamectin-benzoate, endosulfan, empenthalin, oxamyl, oxydemeton-methyl, oxydemeton-methyl, oxydeprofos (ESP), oxibendazole, oxfendazole, potassium oleate, sodium oleate, kazusafos, kappa-bifenthrin, cartap, carbaryl (carbary1), carbosulfan, carbofuryl, gamma-cyhalothrin, xylylcarb, quinalphos, quinoprene, chinomethionat, cloethocarb , Clothianidin, clofentezine, Lomafenozide, chlorantraniliprole, chlorethoxyfos, chlordimeform, chlordane, chlorpyrifos, chlorpyrifos-methyl, chlorphenapyr Chlorfenson, Chlorfenvinphos, Chlorfluazuron, Chlorbenzilate, Chlorobenzoate, Chlorobenzolate, Chloropallethrin, Kelsen (dicofol), Salithion, cyhalodiamide, cyanophos: CYAP, diafenthiuron, diamidafos, cyantraniliprole, theta-cypermethrin, dienochlor, cyenopyrafen, cyenopyrafen The Dioxabenzofos, diofenolan, sigma-cypermethrin, cyclaniliprole, dichlofenthion (ECP), cycloprothrin, dichlorvos (DDVP), dichloromezozozo Disulfoton, dinotefuran, cyhalodiamide, cyhalothrin, cyphenothrin, cyfluthrin, diflubenzuron, cyflumetincy, dihexobidin, dihexavidin , Cypermethrin, dimethylvinphos, dimethoate, dimefluthrin, silafluofen, cyromazine, spintoram, spinosad, spinosad, spinosad, spinosad, spinosad, spinosad, spinosad, spinosad, spinosad Diclofen, spirotetramat, spiromesifen, sulfluramid, sulprofos, sulfoxaflor, zeta-cypermethrin, diazinon , Tau-fluvalinate, dazomet, thiacloprid, thiamethoxam, tioxazafen, thiodicarb, thiocyclam, thiosultap, sodium thiosultap-dium ), Thionazin, thiometon, deet, dieldrin, tetrach1orvinphos, tetradifon, tetraniliprole, tetramethylfluthrin, tetramethrin, Tebupirimfos, Tebufenozide, tebufenpyrad, tefluthrin, teflubenzuron, demeton-S-methyl, temephos, deltamethrin, terbufos, terbufos tralopyril), tralomethrin, transfluthrin, triazamate, triazaron, triazuron, trichlamide, trichlorphon: DEP, triflumezopyrim, triflumuron, tolfenpyrad, tolfenpyrad (naled: BRP), nithiazine, nitenpyram, novaluron, noviflumuron, hydroprene, vaniliprole, vamidomion, parathion, parathion-methyl (Parathion-methyl), Halfenprox, halofenozide, bistrifluron, bisultap, hydramethylnon, hydroxy propyl starch, binapacryl, pyflubumide, Bifenazate, bifenthrin, pymetrozine, pyraclorfos, pyrafluprole, pyridafenthion, pyridaben, pyridalyl, proriquinol, pyriquinapy ), Pyriproxyfen, Pirimicarb, Pyrimidifen, Pyriminostrobin, Pirimiphos-methy1, Pirethrins, Fipronil (fiproni1), Fenazaquin, Fenamiphos (fenamiphos) Phenopropyl bromopropylate, phenoxythion (MEP), phenoxycarb, phenoxycarb, phenothrin, fenobucarb, fensulfothion, fenthion (MPP), Phenthoate (PAP), fenvalerate, fenpyroximate, fenpropathrin, fenbendazole, fosthiazate, formetanate, butathiofos, buprofezin (buprofezin), furathiocarb, prallethrin, fluacrypyrim, fluazaindolizine, fluazinam, fluazuron, fluensulfone, fluxametamide, flucycloxuron, Flucythrinate, fluvalinate, flufiprole, flupyradifurone, flupyrazofos, flufenerim, flufenoxystrobin, flufenoxuron, flufenzurine, flufenprox, flufenprox Fluproxyfen, flubrocythrinate, fluhexafon, flubendiamide, flumethrin, flurimfen, prothiofos, protrifenbute, flonicamid , Propaphos, propargite: BPPS, profenofos, broflanilide, profluthrin, propoxur: PHC, flemotoquin, bromopropylate, beta-cyfluthrin (beta- cyfluthrin), hexaf Lumron (hexaflumuron), hexythiazox (hexythiazox), heptafluthrin, heptenophos (heptenophos), permethrin, bencrothiaz (benclothiaz), bendiocarb (bendiocarb), bensulfap (bensu1tap), benzximate (benzoximate), bencarb (phoxim), phosalone, fosthiazate, fosthietan, phosphamidon, phosphocarb, phosmet (PMP), polynactins, formetanate, formotenate formothion, phorate, machine oil, malathion, milbemycin, milbemycin-A, milbemectin, mecarbam, mesulfenfos, mesomil ( methomyl), metaldehyde (metaldehy) de), metaflumizone, methamidophos, metam-ammonium, metam-sodium, methiocarb, methidathion (DMTP), methylisothiocyanate, Methylneodecanamide, methylparathion, metoxadiazone, methoxychlor, methoxyfenozide, methoxifluzrin, methoprene, methoprene, metolcarb, melthrin, meperthrin, meperthrin (mevinphos), monocrotophos, monosultap, momfluorothrin, lambda-cyhalothrin, ryanodine, lufenuron, rescalure, resmethrin, lepimectin, rotemectin Nonen (rotenone), levamisol hydrochloride, fenbutatin oxide, morantel tartarate, methyl bromide, tricyclohexyltin hydroxide (cyhexatin), calcium cyanamide, Examples thereof include calcium polysulfide, sulfur, and nicotine-sulfate.

Examples of agricultural and horticultural fungicides used for similar purposes include aureofungin, azaconazole, azithiram, acipetacs, acibenzolar, acibenzolar-S-methyl. ), Azoxystrobin, anilazine, amisulbrom, ampropylfos, ametoctradin, allyl alcohol, aldimorph, amobam, isothianyl (Isotianil), isovaledione, isopyrazam, isofetamid, isoprothiolane, ipconazole, ipfentrifluconazole, iprodione, iprodione Iprovalicarb, iprobenfos, imazalil, iminoctadine, iminoctadine-albesilate, iminoctadine-triacetate, iminoctadine-triacetate, imibenconazole, imibenconazole ), Uniconazole-P, echlomezole, edifenphos, etaconazole, ethaboxam, etirimol, etem, ethoxyquin, ethidiazole, etridiazole Enestroburin, enoxastrobin, enoxastrobin, epoxiconazole, oxadixyl, oxathiapiprolin, oxathiapiprolin Lorin (oxathiapiprolin), oxycarboxin, copper-8-quinolinolate, oxytetracycline, copper-oxinate, oxpoconazole, oxpoconazole fumarate Soil fungicides such as oxpoconazole-fumarate, oxolinic acid, octhilinone, ofurace, orysastrobin, metam-sodium, kasugamycin, carbamorph ), Carpropamid, carbendazim, carboxin, carvone, carnone, quinazamid, quinacetol, quinoxyfen, quinofumelin, quinomethionate, chinomethionat (qu inomethionate, captafol, captan, kiralaxyl, quinconazole, quintozene, guazatine, cufraneb, cuprobam, cuboxystrobin (coumoxystrobin), glyodin, griseofulvin, climbazole, cresol, kresoxim-methyl, chlozolinate, clotrimazole, clobenthiazone, chlobenthiazone Chloraniformethan, chloranil, chlorquinox, chloropicrin, chlorfenazole, chlorodinitronaphthalene, chlorothalonil ), Chloroneb, salicylanilide, zarilamid, zarazomid, cyazofamid, diethyl pyrocarbonate, dietofencarb, cyclafuramid, cyclodicet, diclocymet, diclocymet dichlozoline, diclobutrazol, dichlofluanid, cycloheximide, diclobentiazox, diclomezine, dicloran, dichlorophen, dichlone ), Disulfiram, ditalimfos, dithianon, diniconazole, diniconazole-M, zineb, dinocap, dinocto Dinocton, dinosulfon, dinoterbon, dinobuton, dinopenton, dipymetitrone, dipymetitrone, dipyrithione, diphenylamine, diphenylamine, diphenylamine, diphenylamine Cyflufenamid, diflumetorim, cyproconazole, cyprodinil, cyprofuram, cypendazole, simeconazole, dimethirimol, dimethirimol, dimethirimol, dimethirimol ), Dimoxystrobin, ziram, silthiofam, streptomycin, spiroxamine, sultrope (Sultropen), sedaxane, zoxamide, dazomet, thiadiazin, thiadinil, thiadifluor, thiabendazole, thiooxymid, thiochlorfenphim ), Thiophanate, thiophanate-methyl, thiofluzamide, thicyofen, thioquinox, thiram, decafentin, tecnazene, tecloftalam, tecloftalam Tecoram, tetraconazole, debacarb, dehydroacetic acid, tebuconazole, tebufloquin, dodicin, dodine, dodoine Silbenzene sulfonic acid bisethylenediamine copper complex salt (II) (DBEDC), dodemorph, dorazoxolon, triadimenol, triadimefon, triazbutil, triazoxide, triamiphos (triamiphos) ), Triarimol, trichlamide, triclopyricarb, tricyclazole, triticonazole, tridemorph, tributyltin oxide, triflumizole ( triflumizole, trifloxystrobin, triforine, tolylfluanid, tolclofos-methyl, tolprocarb, natamycin, nabam bam), nitrostyrene, nitrothal-isopropyl, nuarimol, copper nonylphenol sulfonate, halacrinate, validamycin, valifenalate , Harpin protein, picarbutrazox, bixafen, picoxystrobin, picobenzamide, pydiflumetofen, bithionol, bitertanol ), Hydroxyisoxazole, hydroxyisoxazole-potassium, binapacryl, biphenyl, piperalin, hymexazol, pyroxystro Pyraoxystrobin, pyracarbolid, pyraclostrobin, pyraziflumid, pyrazophos, pyrametostrobin, pyriofenone, pyridiinitril, didiflumetofenpy ), Pyridiflumetofen, pyrisoxazole, pyrifenox, pyribencarb, pyrimemethanil, pyroxycyclyl, pyroxyfur, pyroxylon, zine ), Famoxadone, fenapanil, fenamidone, fenaminosulf, fenaminstrobin, fenarimol, fenitro Fenitropan, fenoxanil, ferimzone, ferbam, fentin, fenpiclonil, fenpicoxamid, fenpyrazamine, fenbuconazole, Fenfuram, fenpropidin, fenpropimorph, fenhexamid, phthalide, buthiobate, butylamine, bupirimate, fuberidazole , Blasticidin-S, furametpyr, furalaxyl, fluacrypyrim, fluazinam, fluazinam, fluoxastrobin, fluotrimazole , Fluopicolide, fluopyram, fluoroimide, furcarbanil, fluxapyroxad, fluquinconazole, fluconazole, fluconazole-cis , Fludioxonil, flusilazole, flusulfamide, flutianil, flutolanil, flutriafol, flufenoxystrobin, furfural, flumeciclos ( furmecyclox, flumetover, furmorph, flumorph, proquinazid, prochloraz, procymidone, prothiocarb, prothiocarbazole prothioconazole), propamocarb, propiconcarb, propiconazole, propineb, furophanate, probenazole, bromuconazole, hexachlorobutadiene, hexaconazole, Hexylthiofos, bethoxazin, benalaxyl, benalaxyl-M, benodanil, benomyl, pefazoate, benquinox, penconazole, penconazole, penconazole (Benzamorf), pencicuron (pencycuron), benzohydroxamic acid, benzovindiflupyr (benzovindiflupyr), bentaluron, benthiazole, bench abical -Isopropyl (benthiavalicarb-isopropyl), penthiopyrad (penthiopyrad), penflufen (boscalid), phosdiphen (phosdiphen), fosetyl (fosetyl), fosetyl aluminum (fosetyl-Al), polyoxins (polyoxins), polyoxoline (polyoxorim) ), Polycarbamate, folpet, formaldehyde, machine oil,
Maneb, mancozeb, mandipropamid, mandestrobin, microzoline, myclobutanil, mildiomycin, milneb, mecarbinzid, metacarbinzid Sulfocarb (methasulfocarb), metazoxolon (metazoxolon), metam (metam), metam sodium salt (metam-sodium), metalaxyl (metalaxyl), metalaxyl M (metalaxyl-M), methylam (metiram), methyl isothiocyanate (methyl) isothiocyanate, mepthyldinocap, metconazole, metsulfovax, metfuroxam, methfuroxam, metominostrobin, metrafenone, mepanipyrim, mefenopysum xam), mefentrifluconazole, meptyldinocap, mepronil, mebenil, medoil, iodomethane, rabenzazole, methyl bromide, chloride Benzalkonium chloride, basic copper chloride, basic copper sulfate, inorganic fungicides such as metallic silver, sodium hypochlorote, water Cupric hydroxide, wettable sulfur, calcium polysulfide, potassium hydrogen carbonate, sodium hydrogen carbonate, sulfur , Copper sulfate anhydride, nickel dimethyldithiocarbamate, 8-hydroxyquinoline copper (oxine) Examples thereof include copper-based compounds such as copper), zinc sulfate, copper sulfate pentahydrate, and the like.

Examples of biological pesticides include nuclear polyhedrosis virus (NPV), granulosis virus (GV), cytoplasmic polyhedrosis virus (CPV), insect poxvirus (Entomopoxi virus, EPV) ) And other virus preparations, Monocrosporium phymatophagum, Steinernema carpocapsae, Steinernema kushidai, Pasteuria penetrans, and Pasturia penetrans Microbial pesticides used as agents, such as Trichoderma lignorum, Agrobacterium radiobactor, non-pathogenic Erwinia carotovora, Bacillus subtilis Microbial pesticides, biological pesticides used as herbicides such as Xanthomonas campestris, Encarsia formosa, Aphidius colemani, Aphidoletes aphidimyza Natural enemies such as B. niger, Ori sauteria, and B. enigma, such as Diglyphus isaea, Dacnusa sibirica, Phytoseiulus persimilis, and Amblyseius cucumeris ), Etc., (Z) -10-tetradecenyl acetate, (E, Z) -4,10-tetradecadinyl acetate, (Z) -8-dodecenyl acetate, (Z) -11-tetradecenyl = Acetate, (Z) -13-ico Down-10-one, it can be used in combination with pheromones such as 14-methyl-1-octadecene.

  In addition, as a safener, it can be used in combination with, for example, isoxadifenethyl, flirazole, cyprosulfamide, ciomethrinyl, dichlormide, thiencarbazone methyl, fenchlorazole-ethyl, fluxophenim, benoxacol, mefenpyr-diethyl, etc. is there.

  Hereinafter, representative examples and test examples of the present invention will be shown, but the present invention is not limited thereto. In the examples, “part” means “part by mass”.

Formulation Example 1 Emulsion Compound (I) 5 parts thiazinyl 10 parts xylene 63 parts N-methylpyrrolidone 12 parts Mixture of polyoxyethylene nonylphenyl ether and calcium alkylbenzenesulfonate 10 parts The above components are mixed and dissolved uniformly to obtain an emulsion.

Formulation Example 2 Dust Compound (II) 5 parts Pyraflufenethyl 5 parts Clay powder 78 parts Diatomaceous earth powder 12 parts The above is uniformly mixed and ground to obtain a powder.

Formulation Example 3 Granules Compound (II) 4 parts Orthosulfamron 6 parts Bentonite / clay mixed powder 85 parts lignin calcium sulfonate 5 parts or more uniformly mixed, kneaded with an appropriate amount of water, granulated and dried Use granules.

Formulation Example 4 Wetting agent Compound (I) 2 parts Indanophan 2 parts Kaolin, synthetic highly dispersed silicic acid 88 parts Mixture of polyoxyethylene nonylphenyl ether and calcium alkylbenzenesulfonate 8 parts The above is uniformly mixed and ground to obtain a wettable powder.

Formulation Example 5 Hydrating agent Compound (II) 3 parts Flubendiamide 5 parts Kaolin and synthetic highly dispersed silicic acid 85 parts Polyoxyethylene nonylphenyl ether and calcium alkylbenzenesulfonate 7 parts .

Formulation Example 6 Flowable agent Compound (I) 5 parts Indanophan 3 parts Solpol 3105 (manufactured by Toho Chemical Co., Ltd.) 5 parts propylene glycol 7 parts Rhodopol 23 (manufactured by Solvay Nikka) 0.2 parts water 79.8 parts To obtain an aqueous suspension (flowable agent).

Test Example 1 Application test for prevention of rice blast disease A mixture of compound (I) and thiazinyl prepared in accordance with Formulation Example 1 and each single agent with water in 6-leaf rice cultivated in a pot (variety: Kinnanfu) Dilute to predetermined concentration and spray with foliage. After spraying, the pots are cultivated in a greenhouse, and after 7 days of treatment, sprayed with a spore suspension of Pyricularia oryzae. After inoculation, the number of lesions is examined for 7 days under humid conditions at 20 ° C., and the control effect is calculated according to the following formula. At the same time, E (expected value) according to the following Colby equation is obtained. (See Colby, SR, Weeds 15: 20-22 (1967)).

(Equation 1)
E (expected value) = X + Y− (X × Y / 100)

Here, E (expected value) is the control effect (herbicidal effect, bactericidal effect, insecticidal effect) expected when compound (I) or (II) is mixed with pg / ha and active ingredient A is qg / ha. X represents a controlling effect when the compound (I) or (II) is treated with pg / ha, Y represents a controlling effect when the active ingredient A is treated with qg / ha (in the above, p and q are optional) Indicates the number).
It can be said that the combination shows a synergistic effect if the control effect when the two kinds of pest control agents are actually mixed exceeds this E (expected value).

Criterion of disease index 0: no disease 1: lesion area rate 1-10%
2: Disease spot rate 11 to 20%
3: Disease area ratio 21-30%
4: Disease area ratio 31-40%
5: lesion area rate 41-50%
6: lesion area rate 51-60%
7: lesion area rate 61-70%
8: lesion area rate 71 to 80%
9: Disease spot area rate 81-90%
10: disease spot area rate 91-100%

(Equation 2)
(Disease incidence index of untreated area-Disease index of treated area)
Control effect (%) = × 100
Disease index of untreated areas

  The control effect of the combination of compound (I) and thiazinyl in the spray prevention effect test for rice blast exceeds the E (expected value) obtained from Colby's formula when each compound is used alone. The effect is recognized.

Test Example 2 Test of control effect against Japanese moth (Plutella xylostella) A kanran (variety: YR Harenori) was planted in a glass greenhouse and inoculated with 3 moths at 12 to 15 leaves. The number of parasites before drug treatment per three strains is investigated, and the mixture of compound (II) and fulvendiamide and each single agent are diluted with water to a predetermined concentration in accordance with Formulation Example 5, and the drug solution is sprayed on kanran. The number of parasites is examined 2 days after spraying and 6 days after spraying, and the control effect is calculated by formula 3. Similarly to Test Example 1, E (expected value) is obtained by Colby's equation.

(Equation 3)
Control effect (%) = 100 − {(Ta × Cb) / (Tb × Ca)} × 100
Ta = number of parasites after treatment of drug in treatment group Tb = number of parasites before treatment of drug in treatment group Ca = number of parasites after treatment of drug in untreated group Cb = number of parasites before treatment of drug in untreated group

  The control effect of the composition comprising a combination of compound (II) and fulvendiamide in the control effect test against white moth exceeds E (expected value) obtained from Colby's formula when each compound is used alone, and has a synergistic effect. Is recognized.

Test Example 3 Test of foliage treatment effect on oaks A resin vat with a treatment test area of 100 cm @ 2 is filled with a pelagic soil and uniformly seeded with oak seeds. Thereafter, the water was submerged to a depth of 5 cm, the cultivation management was continued in the greenhouse, and the compound (I) and indhanophane prepared according to Formulation Example 6 were prepared when the growth weeds of the test weed reached the 2.0 to 2.5 leaf stage. A predetermined effective dosage of each of the mixture and each single agent is processed. Then, it is grown in a greenhouse and its control effect is determined after 28 days of treatment. The control effect is determined according to the 100-point method (0 (same as no treatment) to 100 (complete withering)) by naked eye determination. Similarly to Test Example 1, the expected value due to the mixed use is obtained from the Colby equation.

  In the foliar treatment effect test on the oak, the control effect of the composition combining the compound (I) and indanophan exceeds the E (expected value) obtained from the Colby formula when each compound is used alone, and the synergistic effect is obtained. Is recognized

The control effect of the composition comprising the compound (I) or (II), which is the active ingredient A, and the active ingredient B is E (expected value) obtained from the Colby formula when each compound is used alone. Synergistic effects are observed.

  The compound according to the present invention has an excellent control effect against a wide range of pests and is useful.

Claims (5)

Active ingredient A represented by the following chemical formula,
Or at least one or two or more compounds selected from salts thereof;
The following active ingredient B,
Isoprothiolane, basic copper sulfate, fluoroimide, flutolanil, phenoxanil, tiadinil, buprofezin, isoprocarb (MIPC), fenobucarb ), Fenpyroximate, tebufenpyrad, tolfenpyrad, flubendiamide, flubendiamide, metaflumizone, pyrifluquinazon, chlorphthalim, chlorphthalim, pyraflufen-ethyl, pyraflufen-ethyl, pyraflufen-ethyl indanofan), isouron, orthosulfamuron, pyriprole, piflubumide, pyraziflumid, 5- (1, One or more compounds selected from 3-dioxan-2-yl) -4- [4- (trifluoromethyl)] benzyloxypyrimidine and hydroxyquinoline copper or a salt thereof; A pesticidal composition containing as an active ingredient. The pesticidal composition according to claim 1, comprising 0.01 to 5000 parts by mass of active ingredient B with respect to 1 part by mass of active ingredient A.   A method for using a pest control composition, which comprises applying an effective amount of the pest control composition according to claim 1 or 2 to a target crop, a seed of the target crop, soil, or a cultivation carrier.   A method for controlling pests, which comprises applying an effective amount of the pest control composition according to claim 1 or 2 to a target crop, seeds of the target crop, soil, or a cultivation carrier. Active ingredient A represented by the following chemical formula,
Or at least one or two or more compounds selected from salts thereof;
The following active ingredient B,
Isoprothiolane, basic copper sulfate, fluoroimide, flutolanil, phenoxanil, tiadinil, buprofezin, isoprocarb (MIPC), fenobucarb ), Fenpyroximate, tebufenpyrad, tolfenpyrad, flubendiamide, flubendiamide, metaflumizone, pyrifluquinazon, chlorphthalim, chlorphthalim, pyraflufen-ethyl, pyraflufen-ethyl, pyraflufen-ethyl indanofan), isouron, orthosulfamuron, pyriprole, piflubumide, pyraziflumid, 5- (1, One or more compounds selected from 3-dioxan-2-yl) -4- [4- (trifluoromethyl)] benzyloxypyrimidine and hydroxyquinoline copper or a salt thereof; Is applied to the target crop, the seed of the target crop, the soil, and the cultivation carrier at the same time.