WO2022217758A1 - Combined heat and power generation system based on high temperature and low temperature thermal storage media - Google Patents

Combined heat and power generation system based on high temperature and low temperature thermal storage media Download PDF

Info

Publication number
WO2022217758A1
WO2022217758A1 PCT/CN2021/104126 CN2021104126W WO2022217758A1 WO 2022217758 A1 WO2022217758 A1 WO 2022217758A1 CN 2021104126 W CN2021104126 W CN 2021104126W WO 2022217758 A1 WO2022217758 A1 WO 2022217758A1
Authority
WO
WIPO (PCT)
Prior art keywords
heat
low temperature
storage medium
low
pool
Prior art date
Application number
PCT/CN2021/104126
Other languages
French (fr)
Chinese (zh)
Inventor
钟崴
孙鹏
胡亚才
周懿
Original Assignee
浙江大学
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 浙江大学 filed Critical 浙江大学
Publication of WO2022217758A1 publication Critical patent/WO2022217758A1/en

Links

Images

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01DNON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
    • F01D15/00Adaptations of machines or engines for special use; Combinations of engines with devices driven thereby
    • F01D15/10Adaptations for driving, or combinations with, electric generators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K13/00General layout or general methods of operation of complete plants
    • F01K13/02Controlling, e.g. stopping or starting
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04DNON-POSITIVE-DISPLACEMENT PUMPS
    • F04D25/00Pumping installations or systems
    • F04D25/02Units comprising pumps and their driving means
    • F04D25/06Units comprising pumps and their driving means the pump being electrically driven
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B1/00Methods of steam generation characterised by form of heating method
    • F22B1/02Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
    • F22B1/028Steam generation using heat accumulators
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02JCIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
    • H02J15/00Systems for storing electric energy
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02JCIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
    • H02J3/00Circuit arrangements for ac mains or ac distribution networks
    • H02J3/28Arrangements for balancing of the load in a network by storage of energy
    • H02J3/32Arrangements for balancing of the load in a network by storage of energy using batteries with converting means
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/14Combined heat and power generation [CHP]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E70/00Other energy conversion or management systems reducing GHG emissions
    • Y02E70/30Systems combining energy storage with energy generation of non-fossil origin

Definitions

  • the invention relates to an energy storage and energy production system connected to a power grid, in particular to a heat and power cogeneration system based on a high and low temperature heat storage medium.
  • the invention provides a heat and power cogeneration system based on high and low temperature heat storage medium.
  • the system overcomes the disadvantages of traditional energy storage methods, High efficiency and flexible layout, it can be distributed in places where electric power and heat energy are needed, and provide electric power and steam for industrial parks flexibly.
  • a heat and power cogeneration system based on a high and low temperature heat storage medium of the present invention includes a low temperature heat storage device and a high temperature heat storage device, and a compressor system is arranged between the low temperature heat storage device and the high temperature heat storage device.
  • the system also includes a thermal power generation device and a thermal user;
  • the low-temperature thermal storage device is formed by connecting a low-temperature thermal storage medium storage tank and a low-temperature pool through a working fluid pipeline, and the high-temperature thermal storage device consists of a high-temperature thermal storage medium storage tank and a low-temperature thermal storage medium.
  • the high-temperature pool is formed by connecting the working fluid pipeline, and the compressor system is used to compress the low-temperature saturated steam output from the low-temperature pool and input it into the high-temperature pool; the compressor system and the thermal power generation device are all connected with the power grid, and take electricity from the power grid or Power transmission; the low temperature pool is connected with the low temperature heat source through the pipeline, and the low temperature heat source supplements the working medium and heat to the low temperature pool;
  • Low temperature pool and compressor system, compressor system and high temperature pool, high temperature pool and thermal power generation device, high temperature pool and heat user, thermal power generation device and low temperature pool, low temperature pool and low temperature heat source are sequentially provided with valves v1, v2, v3 , v4, v5, v6, different working processes are realized by controlling the switch of each valve.
  • low temperature heat storage medium in the storage tank of low temperature heat storage medium, such as magnesium chloride hexahydrate, paraffin, fatty acid, etc.
  • low temperature heat storage medium such as magnesium chloride hexahydrate, paraffin, fatty acid, etc.
  • the working medium is usually water, and it can also be other working medium such as lithium bromide solution.
  • the low temperature pool and the low temperature heat storage medium storage tank are communicated through the working fluid pipeline, and a heat exchanger is arranged in the low temperature heat storage medium storage tank.
  • the medium storage tank completes the exothermic or endothermic process with the low-temperature heat storage medium through the heat exchanger and returns to the low-temperature pool.
  • the compressor system is connected to the low temperature pool through the working fluid pipeline.
  • the compressor system draws electricity from the power grid, consumes electricity to extract the working fluid steam from the low temperature pool, compresses it into high temperature and high pressure high parameter steam, and transports the high parameter steam through the medium pipeline to the High temperature pool.
  • the high temperature pool and the high temperature heat storage medium storage tank are communicated through the working fluid pipeline.
  • high temperature heat storage medium in the high temperature heat storage medium storage tank such as LiNO3, polymer resin materials, etc.
  • the high temperature pool and the high temperature heat storage medium storage tank are communicated through the working medium pipeline, and a heat exchanger is arranged in the high temperature heat storage medium storage tank. The tank is returned to the high temperature pool after the heat release or heat absorption process with the high temperature heat storage medium is completed through the heat exchanger.
  • the high temperature pool is connected to the thermal power generation device (usually a steam turbine) and the heat user through the working fluid pipeline, and the high-parameter steam of the high temperature pool enters the steam turbine to do work or deliver it to the heat user.
  • the thermal power generation device usually a steam turbine
  • the steam turbine and the low temperature pool are connected by the working fluid pipeline.
  • the exhaust steam of the steam turbine enters the low temperature pool and releases heat to the low temperature heat storage medium storage tank, and then condenses into a liquid working medium again.
  • the heat released by the condensation of the spent steam is stored in the low temperature heat storage medium storage tank.
  • a low-temperature heat source is arranged outside the low-temperature pool and is connected to the low-temperature pool through a working fluid pipeline, and the working fluid and heat are supplemented from the low-temperature heat source to the low-temperature pool.
  • the low temperature heat source can be geothermal heat, industrial waste gas, etc.
  • low temperature and high temperature are relative terms, and are not limited to specific temperatures.
  • Both the low temperature heat storage medium and the high temperature heat storage medium are phase change materials, the melting point of the high temperature heat storage medium is higher than that of the low temperature heat storage medium, and the melting point of the material is selected according to the actual application;
  • the work of the cogeneration system based on high and low temperature heat storage medium can include two processes.
  • the first is the process of power consumption and heat storage.
  • When energy storage is required open the valves v1 and v2, start the compressor system, and use electricity to drive the compressor system to work.
  • the compressor system extracts working fluid vapor from the low temperature pool to reduce the pressure of the low temperature pool , resulting in a decrease in the saturation temperature of the working medium in the low-temperature pool.
  • the saturated liquid working medium with parameters in the low-temperature pool is T0 (temperature), P0 (pressure), and H0 (enthalpy), which absorbs the heat stored in the low-temperature heat storage medium storage tank and the low-temperature heat source.
  • the produced working fluid steam with parameters of T1, P1 and H1 the steam is compressed to the high temperature pool by the electric-driven compressor system, and converted into high temperature and high pressure working fluid steam with parameters of T2, P2 and H2, in the high temperature pool
  • the temperature of the high-parameter working fluid steam is higher than the phase transition temperature of the phase-change heat-storage medium in the high-temperature heat-storage medium storage tank
  • the energy is absorbed by the high-temperature heat-storage medium in the high-temperature heat-storage medium storage tank, and stored in the high-temperature heat-storage medium.
  • the high-parameter steam is condensed into a liquid saturated working medium, which is stored in a high-temperature pool.
  • valves v1 and v2 are closed; the second is the power generation and heating process.
  • Open the valves v3, v4, v5 the pressure drop in the high temperature pool causes the saturation temperature of the working medium in the high temperature pool to decrease, and the working medium absorbs the heat stored in the high temperature heat storage medium storage tank and evaporates into a high temperature and high pressure saturated working medium with parameters T3, P3 and H3 Steam, the working medium steam drives the steam turbine to generate electricity or supplies high-parameter steam to the outside world.
  • the exhaust steam with parameters T4, P4 and H4 generated by the steam turbine is discharged into the low temperature pool, and the pressure of the low temperature pool rises.
  • the spent steam When the temperature of the spent steam is higher than the low temperature heat storage medium storage tank When the heat storage temperature of the internal heat storage medium is reached, the spent steam releases heat to the heat storage medium through the heat exchanger in the low temperature heat storage medium storage tank, and the energy is stored in the low temperature heat storage medium storage tank, and the spent steam becomes saturated again.
  • the liquid working medium is stored in the low temperature pool, and the valves v3, v4 and v5 are closed after the power generation and heating process is completed. Due to reasons such as the inability to recover the working fluid during external heating and insufficient energy recovery of the exhausted steam in the low temperature pool, the working fluid and energy in the low temperature pool and the low temperature heat storage medium storage tank will decrease during operation.
  • the balance of material and energy in the tank needs to supplement the working medium and heat from the low-temperature heat source to the low-temperature pool.
  • the above two processes can be carried out separately or simultaneously according to the actual situation.
  • the energy products exported to the outside world can be either combined heat and power supply or pure heat supply.
  • the power supply efficiency is calculated by the following formula under the condition that the quality of the power generation working medium is m1 ton and the total efficiency of the generator and transmission system is ⁇ 3:
  • W1 (unit: kW ⁇ h) is the power generation
  • W2 (unit: kW ⁇ h) is the power consumption of the compressor system unit.
  • the system operates according to the process of power consumption and heat storage and pure heat supply. Under the condition that the quality of the heating medium is m2 tons, the heat pump coefficient is calculated by the following formula:
  • Q is the heat supply
  • W2 is the power consumption of the compressor system unit.
  • the cogeneration system based on high and low temperature heat storage medium is a high Efficient energy storage system, there is no large temperature difference heat transfer during the working fluid cycle, and the irreversible loss is small.
  • Third, the flexible conversion between external power supply and heating can flexibly adapt to the actual needs of the industrial park, realize greater consumption of new energy power generation for the industrial park, and reduce carbon emissions.
  • the system has a long service life and mature key technologies. The thermal devices and technologies used have mature application experience.
  • the scale of the equipment of this system should be large and small, and it can be applied in different occasions.
  • the key constituent equipment of the present invention has a large overlap with the traditional thermal power plant, and the original site and equipment of the thermal power plant can be used to transform the thermal power plant into a storage power plant according to this system, which is a new energy-led thermal power plant in the future.
  • the energy system offers a way out.
  • FIG. 1 is a schematic diagram of the composition of a heat and power cogeneration system based on a high and low temperature heat storage medium according to the present invention.
  • FIG. 2 is a pressure-entropy diagram of a working medium during operation of a cogeneration system based on a high and low temperature heat storage medium of the present invention.
  • the horizontal straight lines L1 and L2 in the figure are the phase transition temperature line of the low temperature phase change heat storage material and the phase change temperature line of the high temperature phase change heat storage material, respectively.
  • the pressure of the low temperature pool 2 decreases, which reduces the saturation temperature of the working medium in the low temperature pool 2.
  • the working fluid in the low temperature pool 2 absorbs the heat of the phase change material in the low temperature heat storage medium storage tank 1 and evaporates. is saturated steam, that is, from point 12 to point 2 in the pressure-entropy diagram in Figure 2.
  • the saturated steam in the low temperature pool 2 is compressed by the compressor system 3 to become high-temperature and high-pressure high-parameter steam, that is, from point 2 to point 3 in the pressure-entropy diagram in Figure 2.
  • the high-parameter steam enters the high-temperature pool 5, and then its heat is absorbed by the phase change material in the high-temperature heat storage medium storage tank 4. After the steam releases heat, it condenses into saturated water in the high-temperature pool 5, that is, in the pressure-entropy diagram in Fig. 2, from 3 o'clock to 41 o'clock.
  • electricity is drawn from the grid 8 through the compressor system 3, and the electricity in the grid 8 is stored in the heat storage tank 4 to complete the electricity storage process.
  • the heat recovered from the exhausted steam in the expansion exothermic power supply in the low temperature pool 2 and the heat released by the heating working medium during the compression heat storage operation may be unbalanced. If the heat recovered from the exhausted steam in the expansion exothermic power supply in the low temperature pool is less than the heat released by heating the working medium during the compression heat storage operation, it is necessary to open the valve v6 to supplement the heat in the low temperature pool from the low temperature heat source 9, so that the cycle can be maintained go down.
  • the power supply efficiency of the system is the power supply efficiency of the system.
  • W1 is the power generation
  • W2 is the power consumption of the compressor system unit.
  • the power supply efficiency of the electricity storage and heat storage device based on the cycle of high and low temperature heat storage medium is 42.25% when it operates in the compression heat storage-expansion heat release power generation mode.
  • the working medium is water
  • the phase transition temperature of the low temperature thermal storage material is 110°C
  • the phase transition temperature of the high temperature thermal storage material is 210°C.
  • the saturated steam in the low temperature pool 2 is compressed by the compressor system 3 to become high-temperature and high-pressure high-parameter steam, that is, from point 2 to point 3 in the pressure-entropy diagram in Figure 2.
  • the high-parameter steam enters the high-temperature pool 5, and then its heat is absorbed by the phase change material in the high-temperature heat storage medium storage tank 4. After the steam releases heat, it condenses into saturated water in the high-temperature pool 5, that is, in the pressure-entropy diagram in Fig. 2, from 3 o'clock to 41 o'clock.
  • electricity is drawn from the grid 8 through the compressor system 3, and the electricity in the grid 8 is stored in the heat storage tank 4 to complete the electricity storage process.
  • the pressure-entropy diagram of this process is shown in Figure 2.
  • the low-temperature pool 2 In order to ensure the normal operation of the low-temperature pool, when outputting hot water in this working mode, the low-temperature pool 2 must be supplemented with a working medium with the same parameters to make up for the loss of mass and energy in the output working medium, that is, open the valve v6, and send the flow from the low-temperature heat source 9 to the low-temperature heat source 9.
  • Low temperature pool 2 supplements energy and working medium.
  • the output steam increases the pressure, that is, the heat pump effect.
  • valve v6 Since the steam supplied to the heat user 7 cannot be recovered to the low temperature pool 2, the valve v6 needs to be opened to supplement the working medium and heat from the low temperature heat source 9 to the low temperature pool 2.
  • the heat pump coefficient is:
  • the pressure of the low temperature pool 2 decreases, which reduces the saturation temperature of the working medium in the low temperature pool 2.
  • the working fluid in the low temperature pool 2 absorbs the heat of the phase change material in the low temperature heat storage medium storage tank 1 and evaporates. is saturated steam, that is, from point 12 to point 2 in the pressure-entropy diagram in Figure 2.
  • the saturated steam in the low temperature pool 2 is compressed by the compressor system 3 to become high-temperature and high-pressure high-parameter steam, that is, from point 2 to point 3 in the pressure-entropy diagram in Figure 2.
  • the high-parameter steam enters the high-temperature pool 5, and then its heat is absorbed by the phase change material in the high-temperature heat storage medium storage tank 4. After the steam releases heat, it condenses into saturated water in the high-temperature pool 5, that is, in the pressure-entropy diagram in Fig. 2, from 3 o'clock to 41 o'clock.
  • electricity is drawn from the grid 8 through the compressor system 3, and the electricity in the grid 8 is stored in the heat storage tank 4 to complete the electricity storage process.
  • the saturated steam passing through the valve v3 enters the steam turbine 6 to generate power, and becomes wet steam at the outlet of the steam turbine 6, that is, from point 5 to point 6 in the pressure-entropy diagram in Figure 2.
  • the exhaust steam from the steam turbine 6 enters the low temperature pool, releases heat to the phase change material in the low temperature heat storage medium storage tank 1 and then condenses into a low temperature saturated liquid. During this process, the heat released by the wet steam is absorbed by the low temperature heat storage material and stored in the low temperature phase change material. , that is, from point 6 to point 11 in the pressure-entropy diagram in Figure 2.
  • the saturated steam passing through the valve v4 is delivered to the heat user 7 through the working fluid pipeline, and is used by the heat user.
  • the working fluid and energy in the low-temperature pool 2 and the low-temperature heat storage medium storage tank 1 will decrease during operation.
  • the balance of materials and energy in the low-temperature heat storage medium storage tank 1 needs to be supplemented with working medium and heat from the low-temperature heat source 9 to the low-temperature pool 2 .

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)

Abstract

A combined heat and power generation system based on high temperature and low temperature thermal storage media, which comprises a low temperature thermal storage apparatus, a high temperature thermal storage apparatus, a compressor system (3) arranged between the low temperature thermal storage apparatus and the high temperature thermal storage apparatus, a thermal power generation apparatus, and a user of heat (7); the low temperature thermal storage apparatus is formed from a low temperature thermal storage medium storage tank (1) and a low temperature pool (2) being connected by means of a working medium pipe, the high temperature thermal storage apparatus is formed from a high temperature thermal storage medium storage tank (4) and a high temperature pool (5) being connected by means of a working medium pipe, and the compressor system (3) is used for compressing low temperature saturated steam output from the low temperature pool (2) and inputting said steam into the high temperature pool (5); and the compressor system (3) and the thermal power generation apparatus are both in communication with a power grid (8), and acquire from or supply power to the power grid (8). The combined heat and power generation system is a highly efficient energy storage and peak regulation device. In the system, power and heat can simultaneously be stored, and power and heat can also simultaneously be provided, irreversible losses during energy storage and use can be satisfactorily reduced, and energy utilization efficiency and exergy efficiency are greatly improved.

Description

一种基于高低温蓄热介质的热电联产系统A cogeneration system based on high and low temperature heat storage medium 技术领域technical field
本发明涉及一种与电网连接的储能及能源生产系统,尤其涉及一种基于高低温蓄热介质的热电联产系统。The invention relates to an energy storage and energy production system connected to a power grid, in particular to a heat and power cogeneration system based on a high and low temperature heat storage medium.
背景技术Background technique
由于国际社会对能源、气候与环境的重视,中国政府已承诺,到2030年单位GDP的二氧化碳排放量比2005年下降60%~65%。在此背景下,风电、光电等可再生能源在未来将更大规模地发展。然而,风电、光电等可再生能源发电具有波动性,新能源发电规模大幅度发展会导致弃风、弃光现象愈加严重,造成了能源浪费,给电网调峰带来了困难,需要储电技术来存储新能源过饱和发电,实现电网削峰填谷,减少弃风、弃光造成的能源浪费。工业园区作为拥有大量燃煤供汽发电机组的电热消耗大户,需要承担起提高新能源供能占比,降低碳排放的责任。工业园区在新能源发电过饱和时大规模蓄电蓄电,在用能负荷高的时候采用储存下来的新能源电力供能是减少碳排放的有效手段。然而常用的蓄电方式如抽水蓄能工程建设受地理条件严格限制、站点资源较偏僻。蓄电池充放电功率有限、充电时间长、维护成本高。高温熔融盐蓄电在发电过程中存在很大的
Figure PCTCN2021104126-appb-000001
损失和低温热源浪费。为了同时满足工业园区的用电用热和减少碳排放的需求,为工业园区开发一种高效率的储能发电系统,取代传统燃煤发电供热机组具有重要的意义。
As the international community attaches great importance to energy, climate and environment, the Chinese government has promised to reduce carbon dioxide emissions per unit of GDP by 60% to 65% compared with 2005 levels by 2030. In this context, renewable energy sources such as wind power and photovoltaics will develop on a larger scale in the future. However, renewable energy power generation such as wind power and photovoltaics is volatile, and the large-scale development of new energy power generation will lead to more serious abandonment of wind and light, resulting in energy waste and difficulty in peak regulation of the power grid. Power storage technology is required. To store the supersaturated power generation of new energy, realize the peak shaving and valley filling of the power grid, and reduce the energy waste caused by the abandonment of wind and light. As a large consumer of electricity and heat with a large number of coal-fired steam supply generator sets, the industrial park needs to assume the responsibility of increasing the proportion of new energy supply and reducing carbon emissions. Large-scale power storage in industrial parks when new energy power generation is oversaturated, and using stored new energy power to supply energy when energy load is high is an effective way to reduce carbon emissions. However, the commonly used power storage methods, such as pumped storage projects, are strictly limited by geographical conditions and the site resources are relatively remote. The charging and discharging power of the battery is limited, the charging time is long, and the maintenance cost is high. High temperature molten salt electricity storage has a great impact on the power generation process.
Figure PCTCN2021104126-appb-000001
loss and waste of low temperature heat sources. In order to meet the needs of electricity and heat consumption and reducing carbon emissions in industrial parks at the same time, it is of great significance to develop a high-efficiency energy storage power generation system for industrial parks to replace traditional coal-fired power generation and heating units.
此外,风电、光电等可再生能源大规模发展,在未来会造成大量传统火电机组的关停,造成设备投资浪费。如果能提供一种方法将这些设备利用起来,在未来以新能源为主导的能源体系中将发电厂改造成蓄电厂,将极大地减少浪费,推动新能源发电大规模发展。In addition, the large-scale development of renewable energy sources such as wind power and photovoltaics will lead to the shutdown of a large number of traditional thermal power units in the future, resulting in a waste of equipment investment. If a method can be provided to utilize these devices and transform power plants into storage power plants in the future energy system dominated by new energy, it will greatly reduce waste and promote the large-scale development of new energy power generation.
发明内容SUMMARY OF THE INVENTION
为了使工业园区以蓄电的方式更多消纳光伏、风电等新能源发电,解决弃光、弃风问题,实现减碳目标,同时参与电网调峰,实现削峰填谷。本发明提供了一种基于高低温蓄热介质的热电联产系统。该系统克服了传统储能方式的弊端,
Figure PCTCN2021104126-appb-000002
效率高布置灵活,可分布式地布置在需要电能和热能的地方,为工业园区灵活提供电能和蒸汽。
In order to make the industrial park consume more photovoltaic, wind power and other new energy power generation in the form of electricity storage, solve the problem of abandoning light and wind, and achieve the goal of carbon reduction. The invention provides a heat and power cogeneration system based on high and low temperature heat storage medium. The system overcomes the disadvantages of traditional energy storage methods,
Figure PCTCN2021104126-appb-000002
High efficiency and flexible layout, it can be distributed in places where electric power and heat energy are needed, and provide electric power and steam for industrial parks flexibly.
为实现上述目的,本发明的一种基于高低温蓄热介质的热电联产系统,包括低温蓄热装置、高温蓄热装置,在低温蓄热装置、高温蓄热装置之间设有压气机系统,该系统还包括热发电装置和热用户;所述的低温蓄热装置由低温蓄热介质储罐和低温池通过工质管道连接形成,所述高温蓄热装置由高温蓄热介质储罐和高温池通过工质管道连接形成,压气机系统用于将低温池输出的低温饱和蒸汽进行压缩并输入高温池中;所述压气机系统、热发电装置均与电网连通,向电网中取电或送电;低温池通过管道与低温热源连通,由低温热源向低温池补充工质和热量;In order to achieve the above purpose, a heat and power cogeneration system based on a high and low temperature heat storage medium of the present invention includes a low temperature heat storage device and a high temperature heat storage device, and a compressor system is arranged between the low temperature heat storage device and the high temperature heat storage device. , the system also includes a thermal power generation device and a thermal user; the low-temperature thermal storage device is formed by connecting a low-temperature thermal storage medium storage tank and a low-temperature pool through a working fluid pipeline, and the high-temperature thermal storage device consists of a high-temperature thermal storage medium storage tank and a low-temperature thermal storage medium. The high-temperature pool is formed by connecting the working fluid pipeline, and the compressor system is used to compress the low-temperature saturated steam output from the low-temperature pool and input it into the high-temperature pool; the compressor system and the thermal power generation device are all connected with the power grid, and take electricity from the power grid or Power transmission; the low temperature pool is connected with the low temperature heat source through the pipeline, and the low temperature heat source supplements the working medium and heat to the low temperature pool;
低温池和压气机系统、压气机系统和高温池、高温池和热发电装置、高温池和热用户、热发电装置和低温池、低温池和低温热源之间依次设有阀门v1、v2、v3、v4、v5、v6,通过控制各阀门的开关实现不同的工作过程。Low temperature pool and compressor system, compressor system and high temperature pool, high temperature pool and thermal power generation device, high temperature pool and heat user, thermal power generation device and low temperature pool, low temperature pool and low temperature heat source are sequentially provided with valves v1, v2, v3 , v4, v5, v6, different working processes are realized by controlling the switch of each valve.
低温蓄热介质储罐中有低温蓄热介质,如六水氯化镁、石蜡、脂肪酸等。低温池内有汽液共存的饱和工质,工质通常是水,也可以是溴化锂溶液等其他工质。低温池和低温蓄热介质储罐通过工质管道连通,低温蓄热介质储罐内设置有换热器,工质可在低温池通过工质管道流向低温蓄热介质储罐,在低温蓄热介质储罐内通过换热器完成与低温蓄热介质放热或吸热过程后返回低温池。There are low temperature heat storage medium in the storage tank of low temperature heat storage medium, such as magnesium chloride hexahydrate, paraffin, fatty acid, etc. There is a saturated working medium with vapor and liquid coexisting in the low temperature pool. The working medium is usually water, and it can also be other working medium such as lithium bromide solution. The low temperature pool and the low temperature heat storage medium storage tank are communicated through the working fluid pipeline, and a heat exchanger is arranged in the low temperature heat storage medium storage tank. The medium storage tank completes the exothermic or endothermic process with the low-temperature heat storage medium through the heat exchanger and returns to the low-temperature pool.
压气机系统与低温池通过工质管道相连,压气机系统从电网取电,消耗电能从低温池抽取工质蒸汽,将其压缩为高温高压的高参数蒸汽,通过介质管道将高参数蒸汽输送向高温池。The compressor system is connected to the low temperature pool through the working fluid pipeline. The compressor system draws electricity from the power grid, consumes electricity to extract the working fluid steam from the low temperature pool, compresses it into high temperature and high pressure high parameter steam, and transports the high parameter steam through the medium pipeline to the High temperature pool.
高温池和高温蓄热介质储罐通过工质管道连通。高温蓄热介质储罐中有高温蓄热介质,如LiNO3、高分子树脂材料等。高温池内有汽液共存的饱和工质。高温池和高温蓄热介质储罐通过工质管道连通,高温蓄热介质储罐内设置有换热器,工质可在高温池通过管道流向高温蓄热介质储罐,在高温蓄热介质储罐内通过换热器完成与高温蓄热介质放热或吸热过程后返回高温池。The high temperature pool and the high temperature heat storage medium storage tank are communicated through the working fluid pipeline. There are high temperature heat storage medium in the high temperature heat storage medium storage tank, such as LiNO3, polymer resin materials, etc. There is a saturated working medium with vapor and liquid coexisting in the high temperature pool. The high temperature pool and the high temperature heat storage medium storage tank are communicated through the working medium pipeline, and a heat exchanger is arranged in the high temperature heat storage medium storage tank. The tank is returned to the high temperature pool after the heat release or heat absorption process with the high temperature heat storage medium is completed through the heat exchanger.
高温池通过工质管道与热发电装置(通常为汽轮机)和热用户相连,高温池的高参数蒸汽进入汽轮机做功或者输送给热用户。The high temperature pool is connected to the thermal power generation device (usually a steam turbine) and the heat user through the working fluid pipeline, and the high-parameter steam of the high temperature pool enters the steam turbine to do work or deliver it to the heat user.
汽轮机和低温池通过工质管道相连,汽轮机排汽进入低温池后向低温蓄热介质储罐放热,再次凝结为液态工质,乏汽凝结放出的热量储存在低温蓄热介质储罐中。The steam turbine and the low temperature pool are connected by the working fluid pipeline. The exhaust steam of the steam turbine enters the low temperature pool and releases heat to the low temperature heat storage medium storage tank, and then condenses into a liquid working medium again. The heat released by the condensation of the spent steam is stored in the low temperature heat storage medium storage tank.
低温池外设有低温热源与低温池通过工质管道连接,从低温热源向低温池补充工质和热量。低温热源可以是地热、工业废汽等。A low-temperature heat source is arranged outside the low-temperature pool and is connected to the low-temperature pool through a working fluid pipeline, and the working fluid and heat are supplemented from the low-temperature heat source to the low-temperature pool. The low temperature heat source can be geothermal heat, industrial waste gas, etc.
本发明方案中低温、高温二者为相对而言的,并非对具体温度的限定。低温蓄热介质与高温蓄热介质均为相变材料,高温蓄热介质的熔点高于低温蓄热介质,根据实际应用选取材料熔点;In the solution of the present invention, low temperature and high temperature are relative terms, and are not limited to specific temperatures. Both the low temperature heat storage medium and the high temperature heat storage medium are phase change materials, the melting point of the high temperature heat storage medium is higher than that of the low temperature heat storage medium, and the melting point of the material is selected according to the actual application;
本发明所述的一种基于高低温蓄热介质的热电联产系统,其工作可以包括两个过程。第一是耗电储热过程,在需要储能时,打开阀门v1、v2,启动压气机系统,利用电力驱动压气机系统工作,压气机系统从低温池抽取工质蒸汽降低了低温池的压力,致使低温池内工质的饱和温度降低,低温池内参数为T0(温度)、P0(压力)、H0(焓)的饱和液态工质在吸收低温蓄热介质储罐所储热量以及低温热源的共同作用下蒸发,产生的参数为T1、P1、H1的工质蒸汽,蒸汽经电力驱动的压气机系统压缩至高温池,转变成参数为T2、P2、H2的高温高压工质蒸汽,在高温池中,高参数工质蒸汽的温度由于高于高温蓄热介质储罐内相变蓄热介质的相变温度,能量被高温蓄热介质储罐中的高温蓄热介质吸收,储存在高温蓄热介质储罐中,高参数蒸汽凝结为液态饱和工质,储存在高温池中,耗电储热过程结束后关闭阀门v1、v2;第二是发电供热过程,在外界需要热能及电力时,打开阀门v3、v4、v5,高温池的压力下降致使高温池内的工质饱和温度降低,工质吸收高温蓄热介质储罐内储存的热量蒸发为参数T3、P3、H3的高温高压饱和工质蒸汽,工质蒸汽驱动汽轮机发电或对外供应高参数蒸汽,汽轮机发电产生参数为T4、P4、H4的乏汽排入低温池,低温池压力上升,当乏汽温度高于低温蓄热介质储罐内蓄热介质的蓄热温度时,乏汽通过低温蓄热介质储罐内的换热器向蓄热介质放热,将能量储存在低温蓄热介质储罐中,乏汽则再次变成饱和液态工质储于低温池,发电供热过程结束后关闭阀门v3、v4、v5。由于对外供热时工质无法回收及低温池内乏汽能量回收不足等原因,低温池和低温蓄热介质储罐中工质和能量会在运行中减少,为了维持低温池和低温蓄热介质储罐内物质和能量的平衡,需要从低温热源向低温池补充工质和热量。上述两个过程,根据实际情况,既可分开进行,又可同时进行。对外输出的能源产品,既可以是热电联供,也可纯供热。The work of the cogeneration system based on high and low temperature heat storage medium according to the present invention can include two processes. The first is the process of power consumption and heat storage. When energy storage is required, open the valves v1 and v2, start the compressor system, and use electricity to drive the compressor system to work. The compressor system extracts working fluid vapor from the low temperature pool to reduce the pressure of the low temperature pool , resulting in a decrease in the saturation temperature of the working medium in the low-temperature pool. The saturated liquid working medium with parameters in the low-temperature pool is T0 (temperature), P0 (pressure), and H0 (enthalpy), which absorbs the heat stored in the low-temperature heat storage medium storage tank and the low-temperature heat source. Under the action of evaporation, the produced working fluid steam with parameters of T1, P1 and H1, the steam is compressed to the high temperature pool by the electric-driven compressor system, and converted into high temperature and high pressure working fluid steam with parameters of T2, P2 and H2, in the high temperature pool Because the temperature of the high-parameter working fluid steam is higher than the phase transition temperature of the phase-change heat-storage medium in the high-temperature heat-storage medium storage tank, the energy is absorbed by the high-temperature heat-storage medium in the high-temperature heat-storage medium storage tank, and stored in the high-temperature heat-storage medium. In the medium storage tank, the high-parameter steam is condensed into a liquid saturated working medium, which is stored in a high-temperature pool. After the power consumption and heat storage process, the valves v1 and v2 are closed; the second is the power generation and heating process. Open the valves v3, v4, v5, the pressure drop in the high temperature pool causes the saturation temperature of the working medium in the high temperature pool to decrease, and the working medium absorbs the heat stored in the high temperature heat storage medium storage tank and evaporates into a high temperature and high pressure saturated working medium with parameters T3, P3 and H3 Steam, the working medium steam drives the steam turbine to generate electricity or supplies high-parameter steam to the outside world. The exhaust steam with parameters T4, P4 and H4 generated by the steam turbine is discharged into the low temperature pool, and the pressure of the low temperature pool rises. When the temperature of the spent steam is higher than the low temperature heat storage medium storage tank When the heat storage temperature of the internal heat storage medium is reached, the spent steam releases heat to the heat storage medium through the heat exchanger in the low temperature heat storage medium storage tank, and the energy is stored in the low temperature heat storage medium storage tank, and the spent steam becomes saturated again. The liquid working medium is stored in the low temperature pool, and the valves v3, v4 and v5 are closed after the power generation and heating process is completed. Due to reasons such as the inability to recover the working fluid during external heating and insufficient energy recovery of the exhausted steam in the low temperature pool, the working fluid and energy in the low temperature pool and the low temperature heat storage medium storage tank will decrease during operation. In order to maintain the low temperature pool and the low temperature heat storage medium storage The balance of material and energy in the tank needs to supplement the working medium and heat from the low-temperature heat source to the low-temperature pool. The above two processes can be carried out separately or simultaneously according to the actual situation. The energy products exported to the outside world can be either combined heat and power supply or pure heat supply.
本系统按耗电储热过程和纯发电过程运行时,在发电工质质量为m1吨,发 电机及传动系统总效率为η3的情况下,供电效率由下式计算:When the system operates according to the power consumption and heat storage process and the pure power generation process, the power supply efficiency is calculated by the following formula under the condition that the quality of the power generation working medium is m1 ton and the total efficiency of the generator and transmission system is η3:
Figure PCTCN2021104126-appb-000003
Figure PCTCN2021104126-appb-000003
其中,W1(单位:kW·h)为发电量,W2(单位:kW·h)为压气机系统机组耗功。Among them, W1 (unit: kW·h) is the power generation, and W2 (unit: kW·h) is the power consumption of the compressor system unit.
W1的计算方式如下:W1 is calculated as follows:
W1=(H3-H4)*m1*η3/3.6W1=(H3-H4)*m1*η3/3.6
W2的计算方式如下:W2 is calculated as follows:
W2=(H2-H1)*m1/3.6W2=(H2-H1)*m1/3.6
本系统在按耗电储热过程和纯供热过程运行,在供热工质质量为m2吨的情况下,热泵系数由下式计算:The system operates according to the process of power consumption and heat storage and pure heat supply. Under the condition that the quality of the heating medium is m2 tons, the heat pump coefficient is calculated by the following formula:
Figure PCTCN2021104126-appb-000004
Figure PCTCN2021104126-appb-000004
其中,Q为供热量,W2为压气机系统机组耗功。Among them, Q is the heat supply, and W2 is the power consumption of the compressor system unit.
Q的计算方式如下:Q is calculated as follows:
Q=(H3-H0)*m2/3.6Q=(H3-H0)*m2/3.6
W2的计算方式如下:W2 is calculated as follows:
W2=(H2-H1)*m2/3.6W2=(H2-H1)*m2/3.6
本发明的有益效果如下所述:第一,本基于高低温蓄热介质的热电联产系统是一种高
Figure PCTCN2021104126-appb-000005
效率的储能系统,工质循环过程中不存在大温差换热,不可逆损失较小。第二,本系统纯供热运行时,使用低价的电能产生热泵效应,充分发挥了电的高品质性能。第三,对外供电供热之间的灵活转换,可以灵活适应工业园区的实际需求,为工业园区实现更大的新能源发电消纳,减少碳排放。第四,本系统寿命长,关键技术成熟,所利用的热力装置及技术有成熟的应用经验。第五,本系统设备规模宜大宜小,可在不同的场合得到应用。第六,本发明的关键组成设备与传统火电厂存在大量重叠,可利用火电厂原有的场地和设备,将火电厂按照本系统改造成蓄电厂,为火电厂在未来以新能源为主导的能源体系中提供了一条出路。
The beneficial effects of the present invention are as follows: First, the cogeneration system based on high and low temperature heat storage medium is a high
Figure PCTCN2021104126-appb-000005
Efficient energy storage system, there is no large temperature difference heat transfer during the working fluid cycle, and the irreversible loss is small. Second, when the system operates purely for heating, it uses low-cost electric energy to generate a heat pump effect, giving full play to the high-quality performance of electricity. Third, the flexible conversion between external power supply and heating can flexibly adapt to the actual needs of the industrial park, realize greater consumption of new energy power generation for the industrial park, and reduce carbon emissions. Fourth, the system has a long service life and mature key technologies. The thermal devices and technologies used have mature application experience. Fifth, the scale of the equipment of this system should be large and small, and it can be applied in different occasions. Sixth, the key constituent equipment of the present invention has a large overlap with the traditional thermal power plant, and the original site and equipment of the thermal power plant can be used to transform the thermal power plant into a storage power plant according to this system, which is a new energy-led thermal power plant in the future. The energy system offers a way out.
附图说明Description of drawings
图1为本发明的一种基于高低温蓄热介质的热电联产系统构成原理图。FIG. 1 is a schematic diagram of the composition of a heat and power cogeneration system based on a high and low temperature heat storage medium according to the present invention.
图2为本发明的一种基于高低温蓄热介质的热电联产系统运行时工质的压力-熵图。图中水平直线L1、L2分别为低温相变蓄热材料的相变温度线和高温相变蓄热材料的相变温度线。FIG. 2 is a pressure-entropy diagram of a working medium during operation of a cogeneration system based on a high and low temperature heat storage medium of the present invention. The horizontal straight lines L1 and L2 in the figure are the phase transition temperature line of the low temperature phase change heat storage material and the phase change temperature line of the high temperature phase change heat storage material, respectively.
具体实施方式Detailed ways
实施例1:Example 1:
耗电储热-纯发电模式,选择工质为水,质量m=1000t,低温蓄热材料相变温度为110℃,高温蓄热材料相变温度为210℃。耗电储热运行时,如图1所示。打开阀门v1、v2,打开压气机系统3,低温池2压力降低致使低温池2内工质饱和温度降低,低温池2中的工质吸收低温蓄热介质储罐1中相变材料的热量蒸发为饱和汽,即在图2压力-熵图中从12点到2点。低温池2内的饱和汽被压气机系统3压缩后成为高温高压的高参数蒸汽,即在图2压力-熵图中从2点到3点。高参数蒸汽进入高温池5,然后其热量被高温蓄热介质储罐4内的相变材料吸收,蒸汽放热后在高温池5内凝结成饱和水,即在图2压力-熵图中从3点到41点。此过程通过压气机系统3向电网8取电,将电网8中的电储存在储热罐4中,完成蓄电过程。In the power consumption and heat storage-pure power generation mode, the working medium is water, the mass m=1000t, the phase transition temperature of the low temperature thermal storage material is 110℃, and the phase transition temperature of the high temperature thermal storage material is 210℃. When running with power consumption and heat storage, as shown in Figure 1. Open the valves v1 and v2, and open the compressor system 3. The pressure of the low temperature pool 2 decreases, which reduces the saturation temperature of the working medium in the low temperature pool 2. The working fluid in the low temperature pool 2 absorbs the heat of the phase change material in the low temperature heat storage medium storage tank 1 and evaporates. is saturated steam, that is, from point 12 to point 2 in the pressure-entropy diagram in Figure 2. The saturated steam in the low temperature pool 2 is compressed by the compressor system 3 to become high-temperature and high-pressure high-parameter steam, that is, from point 2 to point 3 in the pressure-entropy diagram in Figure 2. The high-parameter steam enters the high-temperature pool 5, and then its heat is absorbed by the phase change material in the high-temperature heat storage medium storage tank 4. After the steam releases heat, it condenses into saturated water in the high-temperature pool 5, that is, in the pressure-entropy diagram in Fig. 2, from 3 o'clock to 41 o'clock. In this process, electricity is drawn from the grid 8 through the compressor system 3, and the electricity in the grid 8 is stored in the heat storage tank 4 to complete the electricity storage process.
放热供电时,打开阀门v3、v5启动汽轮机6,高温池5压力降低,其内部工质的饱和温度下降,工质吸收高温蓄热介质储罐4中的热量蒸发变为饱和汽,即在图2压力-熵图中从42点到5点。饱和蒸汽进入汽轮机6做功发电,在汽轮机6出口变为湿蒸汽,即在图2压力-熵图中从5点到6点。汽轮机6排汽进入低温池,对低温蓄热介质储罐1内相变材料放热后凝结成为低温饱和液体,这个过程中湿蒸汽放出的热量被低温蓄热材料吸收,储存在低温相变材料中,即在图2压力-熵图中从6点到11点。完成一个循环。When exothermic power supply, open the valve v3, v5 to start the steam turbine 6, the pressure of the high temperature pool 5 decreases, the saturation temperature of the internal working fluid drops, the working fluid absorbs the heat in the high temperature heat storage medium storage tank 4 and evaporates into saturated steam, that is, in the Figure 2. Pressure-entropy diagram from point 42 to point 5. The saturated steam enters the steam turbine 6 to generate power, and becomes wet steam at the outlet of the steam turbine 6, that is, from point 5 to point 6 in the pressure-entropy diagram in Fig. 2 . The exhaust steam from the steam turbine 6 enters the low temperature pool, releases heat to the phase change material in the low temperature heat storage medium storage tank 1 and then condenses into a low temperature saturated liquid. During this process, the heat released by the wet steam is absorbed by the low temperature heat storage material and stored in the low temperature phase change material. , that is, from point 6 to point 11 in the pressure-entropy diagram in Figure 2. complete a cycle.
在循环过程中,低温池2在膨胀放热供电中从乏汽回收的热量和在压缩蓄热运行时加热工质放出的热量可能不平衡。如果低温池在膨胀放热供电中从乏汽回收的热量少于在压缩蓄热运行时加热工质放出的热量,需要打开阀门v6从低温热源9补充低温池中的热量,以使循环可以维持下去。During the cycle, the heat recovered from the exhausted steam in the expansion exothermic power supply in the low temperature pool 2 and the heat released by the heating working medium during the compression heat storage operation may be unbalanced. If the heat recovered from the exhausted steam in the expansion exothermic power supply in the low temperature pool is less than the heat released by heating the working medium during the compression heat storage operation, it is necessary to open the valve v6 to supplement the heat in the low temperature pool from the low temperature heat source 9, so that the cycle can be maintained go down.
取压气机系统系统综合效率η1=0.86,汽轮机相对内效率η2=0.86,发电机及传动装置综合效率η3=0.98的工况下,压缩蓄热运行时,低温池中水的参数为T0=105℃,P0=0.1209MP,H0=440.2111KJ/Kg,低温池出口蒸汽参数为T1=106℃, P1=0.1209MP,H1=2683.4KJ/Kg。压气机系统出口绝热参数为T21=461.262℃,P21=2.1068MP,H21=3381.451KJ/Kg,每千克蒸汽压气机系统绝热做功w21=H21-H1=698.058KJ/Kg,每千克蒸汽压气机系统实际做功w2=w21/η1=811.696KJ/Kg;压气机系统出口实际参数为T2=512.724,P2=2.106MP,H2=H1+w2=3495.088KJ/Kg。膨胀放热供电运行时,高温池出口蒸汽参数为T3=206℃,P3=1.7243MP,H3=2794.8KJ/Kg。汽轮机排汽绝热参数T41=115.000℃,P41=0.169MP,干度X41=0.862,H41=2392.036KJ/Kg。汽轮机等熵做功w41=H3-H41=402.7987KJ/Kg,汽轮机实际做功为w4=w41*η2=342.943KJ/Kg。汽轮机排汽实际参数为T4=115.000℃,P4=0.169MP,H4=H3-w4=2451.959KJ/Kg,干度X4=0.889。Taking the overall system efficiency of the compressor system η1=0.86, the relative internal efficiency of the steam turbine η2=0.86, and the overall efficiency of the generator and transmission η3=0.98, the parameters of the water in the low-temperature pool are T0=105 during compression and heat storage operation. ℃, P0=0.1209MP, H0=440.2111KJ/Kg, the steam parameters at the outlet of the low temperature pool are T1=106℃, P1=0.1209MP, H1=2683.4KJ/Kg. The adiabatic parameters at the outlet of the compressor system are T21=461.262°C, P21=2.1068MP, H21=3381.451KJ/Kg, and the adiabatic work per kilogram of the steam compressor system w21=H21-H1=698.058KJ/Kg, the actual performance of the steam compressor system per kilogram The work w2=w21/η1=811.696KJ/Kg; the actual parameters of the compressor system outlet are T2=512.724, P2=2.106MP, H2=H1+w2=3495.088KJ/Kg. When the expansion and exothermic power supply is running, the steam parameters at the outlet of the high temperature pool are T3=206℃, P3=1.7243MP, and H3=2794.8KJ/Kg. Turbine exhaust steam adiabatic parameters T41=115.000℃, P41=0.169MP, dryness X41=0.862, H41=2392.036KJ/Kg. The isentropic work of the steam turbine is w41=H3-H41=402.7987KJ/Kg, and the actual work of the steam turbine is w4=w41*η2=342.943KJ/Kg. The actual parameters of steam turbine exhaust are T4=115.000℃, P4=0.169MP, H4=H3-w4=2451.959KJ/Kg, dryness X4=0.889.
该系统的供电效率为The power supply efficiency of the system is
Figure PCTCN2021104126-appb-000006
Figure PCTCN2021104126-appb-000006
其中,W1为发电量,W2为压气机系统机组耗功。Among them, W1 is the power generation, and W2 is the power consumption of the compressor system unit.
W1的计算方式如下:W1 is calculated as follows:
W1=(H3-H41)*η2*η3*m/3.6W1=(H3-H41)*η2*η3*m/3.6
经计算W1=95261.89974kW·hAfter calculation, W1=95261.89974kW·h
W2的计算方式如下:W2 is calculated as follows:
W2=(H21-H1)/η1*m/3.6W2=(H21-H1)/η1*m/3.6
经计算W2=225471.012kW·hAfter calculation, W2=225471.012kW·h
经计算,本基于高低温蓄热介质循环的蓄电蓄热装置在按照压缩蓄热-膨胀放热发电模式运行时的供电效率为42.25%。It is calculated that the power supply efficiency of the electricity storage and heat storage device based on the cycle of high and low temperature heat storage medium is 42.25% when it operates in the compression heat storage-expansion heat release power generation mode.
实施例2:Example 2:
耗电储热-纯供热模式,选择工质为水,质量m=1000t,低温蓄热材料相变温度为110℃,高温蓄热材料相变温度为210℃。耗电储热运行时,如图1所示。打开阀门v1、v2,打开压气机系统3,低温池2压力降低致使低温池2内工质饱和温度降低,低温池2中的工质吸收低温蓄热介质储罐1中相变材料的热量蒸发为饱和汽,即在图2压力-熵图中从12点到2点。低温池2内的饱和汽被压气机 系统3压缩后成为高温高压的高参数蒸汽,即在图2压力-熵图中从2点到3点。高参数蒸汽进入高温池5,然后其热量被高温蓄热介质储罐4内的相变材料吸收,蒸汽放热后在高温池5内凝结成饱和水,即在图2压力-熵图中从3点到41点。此过程通过压气机系统3向电网8取电,将电网8中的电储存在储热罐4中,完成蓄电过程。此过程的压力-熵图如图2所示。Power consumption and heat storage - pure heat supply mode, the working medium is water, the mass is m=1000t, the phase transition temperature of the low temperature thermal storage material is 110°C, and the phase transition temperature of the high temperature thermal storage material is 210°C. When running with power consumption and heat storage, as shown in Figure 1. Open the valves v1 and v2, and open the compressor system 3. The pressure of the low temperature pool 2 decreases, which reduces the saturation temperature of the working medium in the low temperature pool 2. The working fluid in the low temperature pool 2 absorbs the heat of the phase change material in the low temperature heat storage medium storage tank 1 and evaporates. is saturated steam, that is, from point 12 to point 2 in the pressure-entropy diagram in Figure 2. The saturated steam in the low temperature pool 2 is compressed by the compressor system 3 to become high-temperature and high-pressure high-parameter steam, that is, from point 2 to point 3 in the pressure-entropy diagram in Figure 2. The high-parameter steam enters the high-temperature pool 5, and then its heat is absorbed by the phase change material in the high-temperature heat storage medium storage tank 4. After the steam releases heat, it condenses into saturated water in the high-temperature pool 5, that is, in the pressure-entropy diagram in Fig. 2, from 3 o'clock to 41 o'clock. In this process, electricity is drawn from the grid 8 through the compressor system 3, and the electricity in the grid 8 is stored in the heat storage tank 4 to complete the electricity storage process. The pressure-entropy diagram of this process is shown in Figure 2.
对外供热时,打开高温池出口阀门v4,高温池压力降低,其内部工质的饱和温度下降,工质吸收高温蓄热介质储罐中的热量蒸发变为饱和汽即在图2压力-熵图中从42点到5点。饱和汽通过工质管道输送给热用户7,被热用户利用。为了保证低温池的正常工作,此种工作模式对外输出热水时必须向低温池2补充同样参数的工质,以弥补输出工质中质量与能量损失,即打开阀门v6,从低温热源9向低温池2补充能量和工质。与一般电加热不同的是输出的蒸汽增加了压力,即热泵效应。When supplying heat to the outside, open the outlet valve v4 of the high-temperature pool, the pressure of the high-temperature pool decreases, the saturation temperature of the internal working fluid decreases, and the working fluid absorbs the heat in the high-temperature heat storage medium storage tank and evaporates into saturated steam, which is the pressure-entropy in Figure 2. From 42 o'clock to 5 o'clock in the picture. The saturated steam is delivered to the heat user 7 through the working fluid pipeline, and is utilized by the heat user. In order to ensure the normal operation of the low-temperature pool, when outputting hot water in this working mode, the low-temperature pool 2 must be supplemented with a working medium with the same parameters to make up for the loss of mass and energy in the output working medium, that is, open the valve v6, and send the flow from the low-temperature heat source 9 to the low-temperature heat source 9. Low temperature pool 2 supplements energy and working medium. Unlike general electric heating, the output steam increases the pressure, that is, the heat pump effect.
供给热用户7的蒸汽由于无法回收到低温池2,需要打开阀门v6从低温热源9向低温池2补充工质和热量。Since the steam supplied to the heat user 7 cannot be recovered to the low temperature pool 2, the valve v6 needs to be opened to supplement the working medium and heat from the low temperature heat source 9 to the low temperature pool 2.
取压气机系统系统综合效率η1=0.86,压缩蓄热运行时,低温池中水的参数为T0=105℃,P0=0.1209MP,H0=440.2111KJ/Kg,低温池出口蒸汽参数为T1=106℃,P1=0.1209MP,H1=2683.4KJ/Kg。压气机系统出口绝热参数为T21=461.262℃,P21=2.1068MP,H21=3381.451KJ/Kg,每千克蒸汽压气机系统绝热做功w21=H21-H1=698.058KJ/Kg,每千克蒸汽压气机系统实际做功w2=w21/η1=811.696KJ/Kg;压气机系统出口实际参数为T2=512.724,P2=2.106MP,H2=H1+w2=3495.088KJ/Kg。膨胀放热供电运行时,高温池出口对外供汽参数为:T3=206℃,P3=1.7243MP,H3=2794.8KJ/Kg。Take the overall efficiency of the compressor system η1=0.86, when the compression heat storage operation, the parameters of the water in the low temperature pool are T0=105℃, P0=0.1209MP, H0=440.2111KJ/Kg, and the steam parameters at the outlet of the low temperature pool are T1=106 ℃, P1=0.1209MP, H1=2683.4KJ/Kg. The adiabatic parameters at the outlet of the compressor system are T21=461.262°C, P21=2.1068MP, H21=3381.451KJ/Kg, and the adiabatic work per kilogram of the steam compressor system w21=H21-H1=698.058KJ/Kg, the actual performance of the steam compressor system per kilogram The work w2=w21/η1=811.696KJ/Kg; the actual parameters of the compressor system outlet are T2=512.724, P2=2.106MP, H2=H1+w2=3495.088KJ/Kg. When the expansion and exothermic power supply is running, the external steam supply parameters at the outlet of the high temperature pool are: T3=206℃, P3=1.7243MP, H3=2794.8KJ/Kg.
热泵系数为:The heat pump coefficient is:
Figure PCTCN2021104126-appb-000007
Figure PCTCN2021104126-appb-000007
计算得热泵系数为E=2.901The calculated heat pump coefficient is E=2.901
实施例3:Example 3:
耗电储热-热电联产模式,选择工质为水,质量m=1000t,低温蓄热材料相变温度为110℃,高温蓄热材料相变温度为210℃。耗电储热运行时,如图1所 示。打开阀门v1、v2,打开压气机系统3,低温池2压力降低致使低温池2内工质饱和温度降低,低温池2中的工质吸收低温蓄热介质储罐1中相变材料的热量蒸发为饱和汽,即在图2压力-熵图中从12点到2点。低温池2内的饱和汽被压气机系统3压缩后成为高温高压的高参数蒸汽,即在图2压力-熵图中从2点到3点。高参数蒸汽进入高温池5,然后其热量被高温蓄热介质储罐4内的相变材料吸收,蒸汽放热后在高温池5内凝结成饱和水,即在图2压力-熵图中从3点到41点。此过程通过压气机系统3向电网8取电,将电网8中的电储存在储热罐4中,完成蓄电过程。In the power consumption and heat storage-cogeneration mode, the working medium is selected as water, the mass m=1000t, the phase transition temperature of the low temperature thermal storage material is 110℃, and the phase transition temperature of the high temperature thermal storage material is 210℃. When running with power consumption and heat storage, as shown in Figure 1. Open the valves v1 and v2, and open the compressor system 3. The pressure of the low temperature pool 2 decreases, which reduces the saturation temperature of the working medium in the low temperature pool 2. The working fluid in the low temperature pool 2 absorbs the heat of the phase change material in the low temperature heat storage medium storage tank 1 and evaporates. is saturated steam, that is, from point 12 to point 2 in the pressure-entropy diagram in Figure 2. The saturated steam in the low temperature pool 2 is compressed by the compressor system 3 to become high-temperature and high-pressure high-parameter steam, that is, from point 2 to point 3 in the pressure-entropy diagram in Figure 2. The high-parameter steam enters the high-temperature pool 5, and then its heat is absorbed by the phase change material in the high-temperature heat storage medium storage tank 4. After the steam releases heat, it condenses into saturated water in the high-temperature pool 5, that is, in the pressure-entropy diagram in Fig. 2, from 3 o'clock to 41 o'clock. In this process, electricity is drawn from the grid 8 through the compressor system 3, and the electricity in the grid 8 is stored in the heat storage tank 4 to complete the electricity storage process.
热电联产时,打开阀门v5,并将高温池出口阀门v4、v3根据供电和供热的需求分别设置合理的开度,高温池5压力降低,其内部工质的饱和温度下降,工质吸收高温蓄热介质储罐4中的热量蒸发变为饱和汽,即在图2压力-熵图中从42点到5点。从高温池出来的蒸汽流分为两股,分别至汽轮机发电和至热用户供热,实现热电联产。In the case of cogeneration, open the valve v5, and set the outlet valves v4 and v3 of the high temperature pool to a reasonable opening degree according to the needs of power supply and heat supply. The heat in the high temperature heat storage medium storage tank 4 evaporates and becomes saturated steam, that is, from point 42 to point 5 in the pressure-entropy diagram in FIG. 2 . The steam flow from the high temperature pool is divided into two parts, which are respectively sent to the steam turbine for power generation and to the heat user for heat supply to realize cogeneration.
经过阀门v3的饱和蒸汽进入汽轮机6做功发电,在汽轮机6出口变为湿蒸汽,即在图2压力-熵图中从5点到6点。汽轮机6排汽进入低温池,对低温蓄热介质储罐1内相变材料放热后凝结成为低温饱和液体,这个过程中湿蒸汽放出的热量被低温蓄热材料吸收,储存在低温相变材料中,即在图2压力-熵图中从6点到11点。The saturated steam passing through the valve v3 enters the steam turbine 6 to generate power, and becomes wet steam at the outlet of the steam turbine 6, that is, from point 5 to point 6 in the pressure-entropy diagram in Figure 2. The exhaust steam from the steam turbine 6 enters the low temperature pool, releases heat to the phase change material in the low temperature heat storage medium storage tank 1 and then condenses into a low temperature saturated liquid. During this process, the heat released by the wet steam is absorbed by the low temperature heat storage material and stored in the low temperature phase change material. , that is, from point 6 to point 11 in the pressure-entropy diagram in Figure 2.
经过阀门v4的饱和汽通过工质管道输送给热用户7,被热用户利用。The saturated steam passing through the valve v4 is delivered to the heat user 7 through the working fluid pipeline, and is used by the heat user.
由于对外供热时工质无法回收及低温池2内乏汽能量回收不足等原因,低温池2和低温蓄热介质储罐1中工质和能量会在运行中减少,为了维持低温池2和低温蓄热介质储罐1内物质和能量的平衡,需要从低温热源9向低温池2补充工质和热量。Due to reasons such as the inability to recover the working fluid during external heating and insufficient energy recovery of the exhausted steam in the low-temperature pool 2, the working fluid and energy in the low-temperature pool 2 and the low-temperature heat storage medium storage tank 1 will decrease during operation. The balance of materials and energy in the low-temperature heat storage medium storage tank 1 needs to be supplemented with working medium and heat from the low-temperature heat source 9 to the low-temperature pool 2 .

Claims (7)

  1. 一种基于高低温蓄热介质的热电联产系统,其特征在于:包括低温蓄热装置、高温蓄热装置,在低温蓄热装置、高温蓄热装置之间设有压气机系统,该系统还包括热发电装置和热用户;所述的低温蓄热装置由低温蓄热介质储罐(1)和低温池(2)通过工质管道连接形成,所述高温蓄热装置由高温蓄热介质储罐(4)和高温池(5)通过工质管道连接形成,压气机系统(3)用于将低温池输出的低温饱和蒸汽进行压缩并输入高温池中;所述压气机系统(3)、热发电装置均与电网(8)连通,向电网(8)中取电或送电;低温池(2)通过管道与低温热源(9)连通,由低温热源向低温池(2)补充工质和热量;A heat and power cogeneration system based on a high and low temperature heat storage medium, characterized in that it comprises a low temperature heat storage device and a high temperature heat storage device, and a compressor system is arranged between the low temperature heat storage device and the high temperature heat storage device, and the system also It includes a thermal power generation device and a thermal user; the low-temperature thermal storage device is formed by connecting a low-temperature thermal storage medium storage tank (1) and a low-temperature pool (2) through a working fluid pipeline, and the high-temperature thermal storage device is stored by a high-temperature thermal storage medium. The tank (4) and the high temperature pool (5) are formed by connecting the working fluid pipeline, and the compressor system (3) is used to compress the low temperature saturated steam output from the low temperature pool and input it into the high temperature pool; the compressor system (3), The thermal power generation devices are all connected with the power grid (8), and take or send electricity to the power grid (8); the low-temperature pool (2) is connected with the low-temperature heat source (9) through a pipeline, and the low-temperature heat source supplements the working medium to the low-temperature pool (2) and heat;
    低温池和压气机系统、压气机系统和高温池、高温池和热发电装置(6)、高温池和热用户(7)、热发电装置和低温池、低温池和低温热源之间依次设有阀门v1、v2、v3、v4、v5、v6,通过控制各阀门的开关实现不同的工作过程。The low temperature pool and the compressor system, the compressor system and the high temperature pool, the high temperature pool and the thermal power generation device (6), the high temperature pool and the heat user (7), the thermal power generation device and the low temperature pool, and between the low temperature pool and the low temperature heat source are arranged in sequence. Valves v1, v2, v3, v4, v5, v6 realize different working processes by controlling the switches of each valve.
  2. 根据权利要求1所述的一种基于高低温蓄热介质的热电联产系统,其特征在于:所述的低温蓄热介质储罐(1)中设有换热器和低温蓄热介质,所述的高温蓄热介质储罐(4)中设有换热器和高温蓄热介质,低温蓄热介质与高温蓄热介质均为相变材料,高温蓄热介质的熔点高于低温蓄热介质,根据实际应用选取材料熔点;所述的低温池(2)与高温池(5)中均设有汽液两相的饱和工质;低温池内工质流向低温蓄热介质储罐,通过换热器完成与低温蓄热介质放热或吸热过程后返回低温池;高温池内工质流向高温蓄热介质储罐,通过换热器完成与高温蓄热介质放热或吸热过程后返回高温池。A cogeneration system based on a high and low temperature heat storage medium according to claim 1, characterized in that: the low temperature heat storage medium storage tank (1) is provided with a heat exchanger and a low temperature heat storage medium, so The high temperature heat storage medium storage tank (4) is provided with a heat exchanger and a high temperature heat storage medium, the low temperature heat storage medium and the high temperature heat storage medium are both phase change materials, and the melting point of the high temperature heat storage medium is higher than that of the low temperature heat storage medium , select the melting point of the material according to the actual application; the low temperature pool (2) and the high temperature pool (5) are both provided with a saturated working medium of vapor and liquid; the working medium in the low temperature pool flows to the low temperature heat storage medium storage tank, and the heat exchange The working medium in the high temperature pool flows to the storage tank of the high temperature heat storage medium, and returns to the high temperature pool after the heat release or heat absorption process with the high temperature heat storage medium is completed through the heat exchanger. .
  3. 根据权利要求1所述的一种基于高低温蓄热介质的热电联产系统,其特征在于,所述的热发电装置(6)为汽轮机。The heat and power cogeneration system based on a high and low temperature heat storage medium according to claim 1, characterized in that the thermal power generation device (6) is a steam turbine.
  4. 根据权利要求3所述的一种基于高低温蓄热介质的热电联产系统,其特征在于,所述系统可同时储电储热,又可同时供电供热,包括耗电储热过程及发电供热过程,所述发电供热过程包括纯发电模式、纯供热模式、热电联产模式。A cogeneration system based on high and low temperature heat storage medium according to claim 3, characterized in that the system can store electricity and heat at the same time, and can also supply power and heat at the same time, including the process of power consumption and heat storage and power generation. The heat supply process, the power generation and heat supply process includes a pure power generation mode, a pure heat supply mode, and a combined heat and power mode.
  5. 根据权利要求3所述的一种基于高低温蓄热介质的热电联产系统,其特征在于,打开阀门v1、v2,打开压气机系统;压气机系统向电网取电,从低温池抽取工质蒸汽,致使低温池内工质的饱和温度降低,低温池内饱和液态工质吸收低温蓄热罐所储热量以及低温热源的共同作用下蒸发产生蒸汽,经压气机系统 压缩至高温池,被高温蓄热介质储罐中的高温蓄热介质吸收,凝结为液态饱和工质,从而将电网中的电能储存在高温蓄热介质储罐中,实现耗电储热过程。A cogeneration system based on high and low temperature heat storage medium according to claim 3, characterized in that, the valves v1 and v2 are opened, and the compressor system is opened; the compressor system draws electricity from the power grid, and extracts working fluid from the low temperature pool The steam reduces the saturation temperature of the working medium in the low temperature pool. The saturated liquid working medium in the low temperature pool absorbs the heat stored in the low temperature heat storage tank and evaporates under the combined action of the low temperature heat source to generate steam, which is compressed to the high temperature pool by the compressor system and stored in the high temperature heat. The high temperature heat storage medium in the medium storage tank is absorbed and condensed into a liquid saturated working medium, so that the electric energy in the power grid is stored in the high temperature heat storage medium storage tank to realize the process of power consumption and heat storage.
  6. 根据权利要求3所述的一种基于高低温蓄热介质的热电联产系统,其特征在于,打开阀门v3、v5,启动汽轮机,并打开阀门v6;高温池压力降低,其内部工质的饱和温度下降,工质吸收高温蓄热介质储罐中的热量蒸发变为饱和蒸汽,饱和蒸汽进入汽轮机(6)做功发电,汽轮机排汽进入低温池,对低温蓄热介质储罐内低温蓄热介质放热后凝结成为低温饱和液体,这个过程中汽轮机排汽放出的热量被低温蓄热介质吸收并储存,实现发电供热过程的纯发电模式。A cogeneration system based on high and low temperature heat storage medium according to claim 3, characterized in that, open the valves v3, v5, start the steam turbine, and open the valve v6; When the temperature drops, the working fluid absorbs the heat in the high-temperature heat storage medium storage tank and evaporates into saturated steam. The saturated steam enters the steam turbine (6) to generate power, and the steam turbine exhaust steam enters the low-temperature pool, and the low-temperature heat storage medium in the low-temperature heat storage medium storage tank is used for the low-temperature heat storage medium. After the heat is released, it condenses into a low-temperature saturated liquid. In this process, the heat released by the steam turbine exhaust is absorbed and stored by the low-temperature heat storage medium, and the pure power generation mode of the power generation and heat supply process is realized.
  7. 根据权利要求3所述的一种基于高低温蓄热介质的热电联产系统,其特征在于,打开阀门v4,并打开阀门v6;高温池压力降低,其内部工质的饱和温度下降,工质吸收高温蓄热介质储罐中的热量蒸发变为饱和汽输送给热用户(7),被热用户利用,实现发电供热过程的纯供热模式。A cogeneration system based on high and low temperature heat storage medium according to claim 3, characterized in that, open the valve v4 and open the valve v6; the pressure of the high temperature pool decreases, the saturation temperature of the internal working fluid decreases, and the working fluid decreases. The heat absorbed in the high temperature heat storage medium storage tank is evaporated into saturated steam and sent to the heat user (7) to be utilized by the heat user to realize the pure heat supply mode of the power generation and heat supply process.
PCT/CN2021/104126 2021-04-16 2021-07-02 Combined heat and power generation system based on high temperature and low temperature thermal storage media WO2022217758A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN202110409691.0A CN113153449B (en) 2021-04-16 2021-04-16 Combined heat and power generation system based on high-low temperature heat storage medium
CN202110409691.0 2021-04-16

Publications (1)

Publication Number Publication Date
WO2022217758A1 true WO2022217758A1 (en) 2022-10-20

Family

ID=76868230

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2021/104126 WO2022217758A1 (en) 2021-04-16 2021-07-02 Combined heat and power generation system based on high temperature and low temperature thermal storage media

Country Status (2)

Country Link
CN (1) CN113153449B (en)
WO (1) WO2022217758A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115789743A (en) * 2022-11-11 2023-03-14 清华大学 Cogeneration flexible system and operation method thereof
CN116247828A (en) * 2023-05-12 2023-06-09 长江三峡集团实业发展(北京)有限公司 Energy storage system based on Carnot battery and geothermal energy

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114251147A (en) * 2021-10-14 2022-03-29 杭州英集动力科技有限公司 Cogeneration system and method based on carbon dioxide energy storage and utilizing environmental waste heat
CN115234318B (en) * 2022-09-22 2023-01-31 百穰新能源科技(深圳)有限公司 Carbon dioxide energy storage system matched with thermal power plant deep peak regulation and control method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008185245A (en) * 2007-01-29 2008-08-14 Osaka Gas Co Ltd Compression type heat pump device, operation method of the same, and cogeneration system
CN102721222A (en) * 2012-06-07 2012-10-10 何秀锦 System for recovering waste heat of process cooling water
CN103822518A (en) * 2014-02-28 2014-05-28 常熟喷嘴厂有限公司 Efficient high-capacity medium-high temperature heat storage heat exchanger
WO2016181884A1 (en) * 2015-05-11 2016-11-17 株式会社神戸製鋼所 Compressed air energy storage and power generation device
CN106677969A (en) * 2017-02-23 2017-05-17 王政玉 Energy storage device
CN211573739U (en) * 2019-11-27 2020-09-25 中国科学院工程热物理研究所 Compressed air energy storage system
CN112283068A (en) * 2020-10-12 2021-01-29 国网江苏省电力有限公司镇江供电分公司 Compressed air energy storage and supply device

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013001348A1 (en) * 2013-01-28 2014-07-31 Holger Lange Method for operating turbine system at partial load operation, involves directly feeding a working fluid of turbine with pump or compressor unit from space to downstream of turbine in space behind closed throttle element
CN103233820B (en) * 2013-05-10 2016-06-08 华北电力大学(保定) Caes and the integrated power generation system of combined cycle
CN106215682B (en) * 2016-08-05 2019-03-12 东南大学 A kind of CO towards Gas Generator Set heating-cooling-power cogeneration system2Method for catching
CN106322485A (en) * 2016-09-30 2017-01-11 西安热工研究院有限公司 Thermoelectricity energy storage distributed heat supply system
CN111058910B (en) * 2019-12-12 2021-08-13 西安交通大学 Pressurized-water heat storage and energy storage system and energy storage and release method

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008185245A (en) * 2007-01-29 2008-08-14 Osaka Gas Co Ltd Compression type heat pump device, operation method of the same, and cogeneration system
CN102721222A (en) * 2012-06-07 2012-10-10 何秀锦 System for recovering waste heat of process cooling water
CN103822518A (en) * 2014-02-28 2014-05-28 常熟喷嘴厂有限公司 Efficient high-capacity medium-high temperature heat storage heat exchanger
WO2016181884A1 (en) * 2015-05-11 2016-11-17 株式会社神戸製鋼所 Compressed air energy storage and power generation device
CN106677969A (en) * 2017-02-23 2017-05-17 王政玉 Energy storage device
CN211573739U (en) * 2019-11-27 2020-09-25 中国科学院工程热物理研究所 Compressed air energy storage system
CN112283068A (en) * 2020-10-12 2021-01-29 国网江苏省电力有限公司镇江供电分公司 Compressed air energy storage and supply device

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115789743A (en) * 2022-11-11 2023-03-14 清华大学 Cogeneration flexible system and operation method thereof
CN115789743B (en) * 2022-11-11 2024-04-09 清华大学 Flexible cogeneration system and operation method thereof
CN116247828A (en) * 2023-05-12 2023-06-09 长江三峡集团实业发展(北京)有限公司 Energy storage system based on Carnot battery and geothermal energy
CN116247828B (en) * 2023-05-12 2023-07-21 长江三峡集团实业发展(北京)有限公司 Energy storage system based on Carnot battery and geothermal energy

Also Published As

Publication number Publication date
CN113153449A (en) 2021-07-23
CN113153449B (en) 2023-04-11

Similar Documents

Publication Publication Date Title
WO2022217758A1 (en) Combined heat and power generation system based on high temperature and low temperature thermal storage media
JP5508540B2 (en) Supercritical air energy storage system
CN102758748B (en) High-pressure liquid air energy storage/release system
CN108800628B (en) Combined heat and power system based on solar thermochemical energy storage
CN102758690A (en) Efficient high-pressure liquid air energy storage/release system
CN110905747A (en) Combined power cycle power generation system utilizing high-temperature solar energy and LNG cold energy
CN110552750B (en) Non-azeotropic organic Rankine-dual-injection combined cooling, heating and power system
CN204923571U (en) Thermoelectric cold trigeminy supplies system based on heat pump technique and compressed air electric power storage technique
CN202811079U (en) High-efficiency and high-pressure liquid air energy storage/ release system
CN202811238U (en) High-pressure liquid-state air energy storage/release system
CN202220630U (en) Low-temperature waste heat recovery plant used in petrochemical industry
CN113540504B (en) Heat pump-hydrogen energy composite energy storage power generation method and device
CN113417703B (en) Solar wet helium turbine circulation electricity-water-salt three-coproduction zero-emission system and method
CN106194299A (en) A kind of carbon trapping and supercritical CO2the electricity generation system of Brayton cycle coupling
CN113803156A (en) Combined cooling heating and power system of ORC-jet type refrigerating device
CN116164573B (en) Dry ice energy storage system and method based on carbon dioxide gas-solid phase transition
Mojtahed et al. Hybrid Hydrogen production: Application of CO2 heat pump for the high-temperature water electrolysis process
CN115200067A (en) Distributed heat pump electricity storage system capable of realizing building electricity storage and heat supply functions
CN210829414U (en) Electric power energy storage device based on phase change heat storage
CN115031283A (en) Thermoelectric flexible storage and supply system and operation method thereof
CN113824139B (en) Thermal power plant Carnot battery energy storage transformation method and device
CN115653713B (en) Thermal mass energy storage device based on heat pump cycle and control method
WO2015012448A1 (en) Small hydroelectric complex power generation system
CN116247827B (en) Industrial park comprehensive energy system and operation method thereof
CN113339091B (en) Brayton-kalina circulating energy storage and power supply method and device

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 21936630

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 21936630

Country of ref document: EP

Kind code of ref document: A1