WO2022215672A1 - Dispositif de mesure de potentiel - Google Patents

Dispositif de mesure de potentiel Download PDF

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Publication number
WO2022215672A1
WO2022215672A1 PCT/JP2022/017020 JP2022017020W WO2022215672A1 WO 2022215672 A1 WO2022215672 A1 WO 2022215672A1 JP 2022017020 W JP2022017020 W JP 2022017020W WO 2022215672 A1 WO2022215672 A1 WO 2022215672A1
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WIPO (PCT)
Prior art keywords
fabric
conductive block
measuring device
potential measuring
potential
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PCT/JP2022/017020
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English (en)
Japanese (ja)
Inventor
昌由 ▲高▼木
誠人 斉藤
雅之 辻
亮祐 海老名
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株式会社村田製作所
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Publication of WO2022215672A1 publication Critical patent/WO2022215672A1/fr

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06H—MARKING, INSPECTING, SEAMING OR SEVERING TEXTILE MATERIALS
    • D06H3/00—Inspecting textile materials
    • D06H3/10—Inspecting textile materials by non-optical apparatus
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R29/00—Arrangements for measuring or indicating electric quantities not covered by groups G01R19/00 - G01R27/00
    • G01R29/22—Measuring piezoelectric properties

Definitions

  • the present disclosure relates to a device for potential measurement of fabrics and the like. More specifically, the present disclosure relates to apparatus for measuring surface potentials that can occur in fabrics such as wovens, knits, nonwovens, and especially piezoelectric fabrics.
  • the conventional device described in Patent Document 1 can measure the piezoelectric properties of relatively hard piezoelectric materials such as films, but is not suitable for measuring the surface potential of soft piezoelectric fabrics such as woven fabrics, knitted fabrics, and non-woven fabrics. all right.
  • the crystals are oriented in one direction. It has been found that measuring the surface potential of fabrics is difficult.
  • Piezoelectric woven fabric and piezoelectric knitted fabric are disclosed in Patent Document 2, but the surface potential is measured by separately preparing a special measurement sample such as a filamentous piezoelectric body and using a tensile tester and a surface potential meter. It was
  • Piezoelectric fabrics such as woven fabrics, knitted fabrics, and nonwoven fabrics, especially piezoelectric fabrics such as knits, have relatively high stretchability. It was found that the surface potential was not stable and could not be measured.
  • a main object of the present disclosure is to provide an apparatus capable of more stably measuring the surface potential that can occur in fabrics such as woven fabrics, knitted fabrics, and non-woven fabrics.
  • the inventors tried to solve the above problems by dealing with them in a new direction, rather than dealing with them on the extension of the conventional technology. As a result, the present inventors have invented a device that achieves the above main objectives.
  • the present disclosure provides a measuring device for measuring the surface potential of a fabric.
  • the fabric potential measuring device includes a conductive block as a ground electrode, and has a pulling mechanism capable of pulling the fabric placed on the conductive block in at least one direction.
  • a device that can more stably measure the surface potential that can occur in fabrics such as woven fabrics, knitted fabrics, and non-woven fabrics. It should be noted that the effects described in this specification are only examples and are not limited, and additional effects may be provided.
  • FIG. 1 is a schematic diagram that schematically illustrates an apparatus according to an embodiment of the present disclosure.
  • Figure 2 is a schematic diagram that schematically illustrates a conductive block that can be used in an apparatus according to an embodiment of the present disclosure;
  • FIG. 3 is a schematic diagram that schematically illustrates an apparatus according to another embodiment of the present disclosure;
  • FIG. 4 is a top view of an apparatus according to one embodiment of the present disclosure;
  • 5 is a front perspective view of an apparatus according to an embodiment of the present disclosure;
  • FIG. FIG. 6 is a perspective view generally showing an apparatus according to one embodiment of the present disclosure;
  • FIG. 7 is a left perspective view of an apparatus according to an embodiment of the present disclosure;
  • Fig. 8 is a perspective view from the right side of an apparatus according to an embodiment of the present disclosure;
  • FIG. 1 is a schematic diagram that schematically illustrates an apparatus according to an embodiment of the present disclosure.
  • Figure 2 is a schematic diagram that schematically illustrates a conductive block that can be used in an
  • FIG. 9 is a rear view of an apparatus according to one embodiment of the present disclosure
  • Fig. 10 is a bottom view of an apparatus according to one embodiment of the present disclosure
  • Fig. 11 is a left side view of an apparatus according to an embodiment of the present disclosure
  • Fig. 12 is a right side view of an apparatus according to one embodiment of the present disclosure
  • Fig. 13 is a rear perspective view of an apparatus according to an embodiment of the present disclosure
  • FIG. 14 is a schematic diagram that schematically shows an example of a moving stage and fixed members that can be used in an apparatus according to an embodiment of the present disclosure
  • FIG. 15 is a photograph of a device (with arms open) according to an embodiment of the present disclosure
  • FIG. 16 is a photograph showing a state in which a fabric is fixed in an apparatus according to an embodiment of the present disclosure
  • FIG. 17 is a graph showing the results of measuring the surface potential of piezoelectric fabric using an apparatus according to an embodiment of the present disclosure in an example.
  • FIG. 18 is a photograph showing a thread comprising piezoelectric fibers secured in a device according to an embodiment of the present disclosure
  • FIG. 19 is a graph showing surface potential measurements of a yarn comprising piezoelectric fibers using a device according to an embodiment of the present disclosure.
  • the present disclosure relates to a measuring device for measuring the surface potential of fabric (hereinafter sometimes referred to as “the device of the present disclosure” or simply “the device”).
  • fabric means fabrics such as woven fabrics, knitted fabrics, and non-woven fabrics. More specifically, it means fabrics such as woven fabrics, knitted fabrics, and non-woven fabrics (hereinafter sometimes referred to as "piezoelectric fabrics”) containing piezoelectric fibers, which will be described in detail below.
  • piezoelectric fiber generally means a fiber or filament that can be displaced to generate an electric potential by applying an external force such as tension, strain or stress, as further described below.
  • the fabric potential measuring device of the present disclosure includes a conductive block as a ground electrode, and has a pulling mechanism capable of pulling the fabric placed on the conductive block in at least one direction. Further, in the fabric potential measuring device of the present disclosure, the surface potential of the fabric can be measured on the conductive block.
  • the device of the present disclosure is configured to be able to measure the surface potential of a cloth or fabric (F).
  • the device of the present disclosure comprises at least a conductive block (2) as a ground electrode, and has a pulling mechanism capable of pulling the fabric (F) placed on this conductive block (2) in at least one direction ( 1 and 3).
  • the pulling mechanism is not particularly limited as long as it can pull at least one end of the fabric (F). More preferably, the mechanism is capable of pulling at least two ends of the fabric (F) (see Figure 1).
  • the apparatus of the present disclosure may have a tensioning mechanism capable of tensioning the fabric (F) in two directions.
  • two ends of the fabric (F) are attached to at least two moving members (3), such as moving stages (3a, 3b), which can be coupled (or engaged or fitted) or connected to the device body (1).
  • the parts (Ta, Tb) are respectively fixed by fixing members (not shown) or the like, and the moving stages (3a, 3b) are moved to face each other, thereby moving the fabric (F) in two directions (for example, D 1 and D 2 ). direction).
  • the apparatus of the present disclosure may have a tensioning mechanism capable of pulling the fabric (F) in one direction. More specifically, one end of the fabric (F) is attached to at least one moving member (3), such as a moving stage (3), which can be coupled (or engaged or fitted) or connected to the device body (1) (Ta) is fixed using a fixing member (not shown) or the like, and the other end (Tb) of the fabric (F) is attached, for example, to an arbitrary portion of the device main body (1) by another fixing member (not shown). ) or the like, and moving the moving stage (3) may have a mechanism capable of pulling the cloth (F) in one direction (for example, the direction of D1).
  • a moving member (3) such as a moving stage (3), which can be coupled (or engaged or fitted) or connected to the device body (1) (Ta) is fixed using a fixing member (not shown) or the like
  • the other end (Tb) of the fabric (F) is attached, for example, to an arbitrary portion of the device main body (1) by another fixing member (not
  • one of the two moving stages (3a, 3b) is stationary or fixed, and the fabric (F) is pulled in one direction by moving only the other moving stage. good.
  • a conductive block (2) is attached to the device body (1), and the fabric (F) is attached to the main surface (or upper surface) of the conductive block (2).
  • the fabric (F) can be pulled in at least one direction while being arranged to press against.
  • the conductive block (2) can function as a ground electrode as detailed below, for example with a measurement electrode (50) attached to a cantilever (40) shown in FIGS. ), the surface potential of the fabric (F) can be measured.
  • the device of the present disclosure can more stably measure the surface potential of fabrics such as woven fabrics, knitted fabrics, and non-woven fabrics.
  • the conductive block in the apparatus of the present disclosure the fabric (F) can be supported from below, and displacement of the fabric (F) at the measurement point (P) can be suppressed. As a result, the surface potential of the fabric can be measured more stably.
  • the measuring point (P) is preferably positioned above the conductive block (2), for example above the geometric center of the main surface of the conductive block (2).
  • the “apparatus main body” means at least a conductive block and a part or member related to the tension mechanism (for example, a moving member such as a moving stage). means a part or member that can Although there are no particular restrictions on the shape and size of the device body, it preferably has a plate-like shape.
  • the device body is preferably conductive so that the conductive block functions as a ground electrode. More preferably, the device main body is made of a metal such as aluminum or an alloy (for example, stainless steel).
  • the term “conductive block” means a conductive part or member on which fabric can be placed (see FIGS. 1-3, especially FIG. 2).
  • a conductive block has the property of being conductive, that is, conducting electricity. In other words, the conductive block does not have insulating properties, that is, does not conduct electricity at all.
  • the conductive block may be composed of metals (eg, aluminum, gold, silver, copper, platinum) or alloys (eg, stainless steel), or the like. Since the conductive block has conductivity, it can function as a ground electrode. In other words, in the device of the present disclosure, a conductive block can be used to form a ground (GND).
  • GND ground
  • the conductive block may be directly or indirectly attached to the device body.
  • fasteners such as screws or bolt-nuts may be used, or the blocks may be fixed by welding or the like.
  • the conductive block When the conductive block is indirectly attached to the main body of the device, it may be fixed via other parts or members such as a support base and a pole (see FIGS. 4 to 13). At this time, it is preferable that the support base and the pole have conductivity.
  • the height of the conductive block can be arbitrarily adjusted by indirectly attaching the conductive block to the apparatus main body using a support stand or a pole.
  • the tension applied to the fabric can be adjusted by adjusting the height of the support base and the pole.
  • the shape and dimensions of the conductive block there are no particular restrictions on the shape and dimensions of the conductive block as long as it can come into contact with the fabric. In particular, it is preferable to have a shape and dimensions such that the main surface of the conductive block can come into contact with the fabric (see FIG. 2).
  • the "major surface" of the conductive block means the surface of the conductive block that has the largest geometrical area. It is preferable that the surface of the conductive block opposite to the surface facing the main body of the device is the main surface. In other words, it is preferable that the surface opposite to the main surface of the conductive block faces the main body of the device.
  • FIG. 2(A) shows a conductive block (2) that can be used in the device of the present disclosure
  • FIG. Cloth (F) is arranged on the main surface and shows a state in which they are in contact with each other.
  • the main surface of the conductive block (2) on the side on which the fabric (F) can be arranged may be raised to form a curved surface (see FIG. 2(A)).
  • the main surface of the conductive block (2) may be curved or arcuate in a cross-sectional view in the direction perpendicular to the longitudinal direction (or the width direction).
  • the main surface of the conductive block (2) may have a chevron shape or a semi-cylindrical shape.
  • the main surface of the conductive block (2) may have a geometric shape such as a triangle, a square, a polygon, or a trapezoid when viewed in cross section in the direction perpendicular to the longitudinal direction (or the width direction). Also, the corners may be rounded.
  • the shape of the main surface of the conductive block (2) is not limited to the shape described above, and may have various shapes.
  • the cloth (F) can be pulled in a curved shape so as to press against the conductive block (2).
  • the fabric (F) can be pulled while the conductive block (2) is pressing against or tensioning the fabric (F) (see Figures 1 and 3). More specifically, the fabric ( F) can be pulled in the direction of D1 and / or D2 indicated by arrows in FIGS.
  • the fabric (F) can be relatively pressed from the lower side, so the fabric (F) at the measurement point (P) (see FIGS. 1 and 3) deviation can be suppressed. As a result, the surface potential of the fabric (F) can be measured more stably.
  • the measurement point (P) is preferably positioned at the point where the main surface of the conductive block (2) protrudes most or at the highest point.
  • the shape of the fabric (F) is not limited to a band like the illustrated form (see FIG. 2(B)).
  • pulling mechanism means a mechanism, structure or configuration capable of pulling in at least one direction a fabric that may be placed on a conductive block.
  • the direction in which the fabric is pulled is not particularly limited. It may be the direction perpendicular to the direction of D1 and/or D2 indicated by the arrows in FIGS. 1 and 3 , or the Z-axis direction (or vertical direction) shown in FIGS.
  • a drive means such as a motor may be used to move the conductive block (2) up and down in the vertical direction (Z-axis direction).
  • a mechanism that can pull the two ends (Ta, Tb) of the strip of fabric (F) in the left - right direction (D1 and/or D2 direction or X-axis direction) As such, for example, a tension mechanism using a moving member such as a moving stage as indicated by reference numeral 3 in FIGS. 1 and 3 may be used (more specifically, see FIGS. 4 and 14).
  • moving member refers to a part that can place and fix the end of the fabric, and can move, for example, in a movable manner by displacing the position, and thus can pull the fabric. Or means a member.
  • a moving stage indicated by reference numeral 3 in FIGS. 1 and 3 may be used as the moving member (see FIG. 14).
  • the fabric can be pulled in two opposite directions (eg, D1 and D2 indicated by arrows) by a pulling mechanism using two moving stages (3a, 3b).
  • a pulling mechanism using two moving stages (3a, 3b).
  • the two moving stages (3a, 3b) are preferably arranged opposite each other.
  • only one moving stage (3) may be used to pull the fabric (F) in only one direction (eg direction D1 indicated by arrow). Even in such a case, the presence of the conductive block (2) can significantly suppress the displacement of the fabric at the measurement point (P). As a result, the surface potential can be measured more stably.
  • the tensioning mechanism may be configured so that the fabric can be repeatedly tensioned and relaxed.
  • the surface potential of the fabric can be measured while maintaining a constant distance and cycle.
  • the fabric is a piezoelectric fabric, it is possible to measure the surface potential that may occur in the fabric during tension and relaxation of the fabric, in other words during stretching of the fabric. Incidentally, it is extremely difficult to measure the surface potential of such a piezoelectric fabric with a conventional measuring device.
  • the shape and dimensions of the moving member such as the moving stage are not particularly limited.
  • the moving stage may have a plate-like shape (see FIG. 14).
  • a fixing member may be used as a means for more reliably fixing the edge of the fabric to a moving member such as a moving stage or to the apparatus main body.
  • a fixing member for fixing to the stage) will be referred to as a "first fixing member”.
  • the other end (Tb) of the fabric (F) (hereinafter sometimes referred to as "second end") is a moving stage (3b) (hereinafter referred to as "second stage”
  • the fixing member for fixing to the second fixing member is referred to as a "second fixing member”.
  • a fixing member for fixing the other end (Tb) of the fabric (F) to the apparatus main body (1) in the tensioning mechanism shown in FIG. 3 is called a "fourth fixing member".
  • the fixing member may, for example, have a plate-like shape. More specifically, a fixing member having a plate-like shape and a moving stage having a similar plate-like shape are combined, and the cloth may be fixed by sandwiching the cloth between them (see FIG. 16). ).
  • FIGS. 4 to 14, particularly FIG. 14, a plate-like moving stage (3) and a plate-like fixed member (4) are used in combination, and a fabric is sandwiched between them, thereby moving the moving stage.
  • the fabric may be placed and fixed on (3) (see FIG. 16).
  • the dashed line indicates the position where the fixed member (4) can be arranged on the moving stage (3).
  • Fasteners such as screws or bolt-nuts may be used to connect the moving stage (3) and the stationary member (4) together (see Figures 15 and 16).
  • the opposing surfaces of the moving stage (3) and the fixed member (4) may be provided with recesses and protrusions that can be complementary engaged and/or fitted. By providing such unevenness, the fabric can be arranged and fixed more reliably.
  • the moving stage (3) may be provided with grooves (3g) as recesses, and the fixed member (4) may be provided with protrusions (4p) as protrusions.
  • the movable stage (3) may be provided with a convex portion
  • the fixed member (4) may be provided with a concave portion.
  • the moving stage (3) may be provided with both protrusions and recesses and the fixed member (4) may also be provided with both protrusions and recesses to engage and/or fit each other.
  • measuring electrode By measuring electrode is meant an electrode for measuring the surface potential of a fabric paired with a conductive block that can function as a ground electrode. Therefore, the type of the measuring electrode is not particularly limited as long as it can be paired with the conductive block to measure the potential (see FIGS. 1 and 3).
  • the measuring electrode may be, for example, a probe or tip of an Electric Force Microscope (EFM).
  • EFM Electric Force Microscope
  • the measuring electrodes may be provided on the cantilever.
  • a cantilever generally refers to a structure having one end that is fixed and the other end that is free.
  • a cantilever for example a microscope cantilever may be used.
  • a scanning microscope cantilever can be used as the cantilever.
  • the cantilever of an electric force microscope is used as the cantilever.
  • a measuring electrode is provided at the free end of such a cantilever.
  • An electric force microscope probe or stylus is preferably provided at the free end of the cantilever.
  • piezoelectric fabric By “piezoelectric fabric” is meant fabrics, such as wovens, knits, nonwovens, etc., comprising piezoelectric fibers as described below. In addition, the fabric is not limited to the piezoelectric fabric.
  • Texttiles include, but are not limited to, basic fabrics such as plain weave, twill weave, satin weave, and any type of fabric may be used. As fabric, it is preferred to use a fabric comprising piezoelectric fibers as described below.
  • knitted fabric includes basic knitted fabrics such as weft knitting (horizontal knitting) and warp knitting (vertical knitting), but is not limited to these, and any kind of knitted fabric may be used. As knitted fabric, it is preferred to use a knitted fabric comprising piezoelectric fibers as described below.
  • nonwoven fabric is not particularly limited, and conventionally known nonwoven fabrics and nonwoven fabrics containing piezoelectric fibers described below can be used.
  • piezoelectric fiber means a fiber (or filament) capable of generating an electric charge by external energy to generate an electric potential and forming an electric field (hereinafter referred to as “potential generating fiber ( or filaments),”"charge-generating fibers (or filaments),” or “field-generating fibers (or filaments),” or simply “fibers” or “filaments.”
  • external energy for example, an external force (hereinafter sometimes referred to as “external force”), specifically a force that causes deformation or strain in the fiber and / or in the axial direction of the fiber
  • external force specifically a force that causes deformation or strain in the fiber and / or in the axial direction of the fiber
  • Such forces more particularly external forces such as tensile forces (e.g. tensile force in the axial direction of the fiber) and/or stress or strain forces (tensile stress or strain on the fiber) and/or forces in the transverse direction of the fiber is mentioned.
  • the fibers may be long fibers or short fibers.
  • the fibers may for example have a length (or dimension) of 0.01 mm or more, preferably 0.1 mm or more, more preferably 1 mm or more, even more preferably 10 mm or more or 20 mm or more or 30 mm or more.
  • the length may be appropriately selected depending on the desired application.
  • the upper limit of length is not particularly limited, and is, for example, 10000 mm, 100 mm, 50 mm or 15 mm.
  • the fibers may have a single fiber diameter of for example 0.001 ⁇ m (1 nm) to 1 mm, preferably 0.01 ⁇ m to 500 ⁇ m, more preferably 0.1 ⁇ m to 100 ⁇ m, especially 1 ⁇ m to 50 ⁇ m, such as 10 ⁇ m or 30 ⁇ m.
  • the single fiber diameter may be appropriately selected depending on the desired application.
  • the shape of the fiber is not particularly limited, but it may have, for example, a circular, elliptical, or irregular cross-section. It preferably has a circular cross-sectional shape.
  • Fibers are materials that have piezoelectric effect (polarization phenomenon due to external force) or piezoelectricity (the property of generating voltage when mechanical strain is applied, or conversely, mechanical strain when voltage is applied) (hereinafter referred to as “ (sometimes referred to as “piezoelectric material” or “piezoelectric body”).
  • the piezoelectric material can be used without any particular limitation as long as it has a piezoelectric effect or piezoelectricity, and may be an inorganic material such as piezoelectric ceramics or an organic material such as a polymer.
  • the piezoelectric material preferably comprises a "piezoelectric polymer".
  • piezoelectric polymers include “pyroelectric polymers having pyroelectric properties” and “non-pyroelectric piezoelectric polymers”.
  • piezoelectric polymer having pyroelectricity generally means a polymer material (polymer material or resin material) that has pyroelectricity and can generate an electric charge on its surface by applying a temperature change, for example.
  • a piezoelectric material consisting of Examples of such piezoelectric polymers include polyvinylidene fluoride (PVDF).
  • PVDF polyvinylidene fluoride
  • a “piezoelectric polymer without pyroelectricity” generally consists of a polymer material (polymeric material or resin material), except for the above “piezoelectric polymer with pyroelectricity” (hereinafter referred to as “piezoelectric polymer”). , sometimes referred to as “piezoelectric polymer”).
  • piezoelectric polymers include polylactic acid (PLA).
  • PLA polylactic acid
  • PLA poly-L-lactic acid
  • PLLA poly-L-lactic acid
  • PDLA poly-D-lactic acid
  • a copolymer of L-lactic acid and/or D-lactic acid and a compound copolymerizable with this L-lactic acid and/or D-lactic acid may be used as polylactic acid (PLA).
  • polylactic acid a polymer consisting essentially of repeating units derived from a monomer selected from the group consisting of L-lactic acid and D-lactic acid
  • L-lactic acid and/or D-lactic acid L-lactic acid and/or D-lactic acid and this L-lactic acid
  • a mixture of "copolymers of lactic acid and/or D-lactic acid with compounds copolymerizable with” may also be used.
  • polylactic acid-based polymer means "polylactic acid (a polymer consisting essentially of repeating units derived from a monomer selected from the group consisting of L-lactic acid and D-lactic acid)", "L-lactic acid and/or a copolymer of D-lactic acid with a compound copolymerizable with this L-lactic acid and/or D-lactic acid,” and mixtures thereof.
  • polylactic acid is particularly preferable, and it is most preferable to use L-lactic acid homopolymer (PLLA) and D-lactic acid homopolymer (PDLA).
  • PLLA L-lactic acid homopolymer
  • PDLA D-lactic acid homopolymer
  • the polylactic acid-based polymer may have a crystalline portion. Alternatively, at least a portion of the polymer may be crystallized.
  • the polylactic acid-based polymer it is preferable to use a polylactic acid-based polymer having piezoelectricity, in other words, a piezoelectric polylactic acid-based polymer, particularly a piezoelectric polylactic acid.
  • Polylactic acid is a chiral polymer, and the main chain has a helical structure.
  • Polylactic acid can exhibit piezoelectricity when uniaxially stretched to orient the molecules.
  • the piezoelectric constant may be increased by increasing the degree of crystallinity by applying heat treatment.
  • it is possible to increase the "piezoelectric constant" according to the "degree of crystallinity” Investigation of high piezoelectricity expression mechanism of solid phase stretched film using polylactic acid
  • optical purity (enantiomeric excess (ee)) of polylactic acid (PLA) is a value calculated by the following formula.
  • Optical purity (%) ⁇
  • the optical purity is 90% by weight or more, preferably 95% by weight or more or 97% by weight or more, more preferably 98% by weight or more and 100% by weight or less, and even more preferably 99% by weight. 0% by weight or more and 100% by weight or less, particularly preferably 99.0% by weight or more and 99.8% by weight or less.
  • L and D amounts of polylactic acid (PLA) for example, values obtained by a method using high performance liquid chromatography (HPLC) can be used.
  • the crystallinity of polylactic acid (PLA) is, for example, 15% or more, preferably 35% or more, more preferably 50% or more, and even more preferably 55% or more and 100% or less.
  • the crystallinity may be, for example, 35% or more and 50% or less, preferably 38% or more and 50% or less.
  • Crystallinity can be measured by, for example, a method using a differential scanning calorimeter (DSC: Differential Scanning Calorimetry) (for example, DSC7000X manufactured by Hitachi High-Tech Science Co., Ltd.), an X-ray diffraction method (XRD: X-ray diffraction) (for example, X-ray diffraction method using Rigaku UltraX 18), wide-angle X-ray diffraction measurement (WAXD: Wide Angle X-ray Diffraction).
  • DSC Differential Scanning Calorimetry
  • XRD X-ray diffraction
  • WAXD Wide Angle X-ray Diffraction
  • the measured value of crystallinity measured using WAXD and the measured value of crystallinity measured using DSC are found to be about 1.5 times different (DSC measured value/WAXD measured value A value ⁇ 1.5) is obtained.
  • polylactic acid-based polymers for example, polypeptide-based (e.g., poly( ⁇ -benzyl glutarate), poly( ⁇ -methyl glutarate), etc.), cellulose-based (e.g., cellulose acetate, cyanoethyl cellulose, etc.), Polybutyric acid-based (for example, poly( ⁇ -hydroxybutyric acid), etc.), polypropylene oxide-based, and other optically active polymers and derivatives thereof may be used as the piezoelectric polymer.
  • polypeptide-based e.g., poly( ⁇ -benzyl glutarate), poly( ⁇ -methyl glutarate), etc.
  • cellulose-based e.g., cellulose acetate, cyanoethyl cellulose, etc.
  • Polybutyric acid-based for example, poly( ⁇ -hydroxybutyric acid), etc.
  • polypropylene oxide-based for example, poly( ⁇ -hydroxybutyric acid), etc.
  • other optically active polymers and derivatives thereof may
  • the potential generating fibers or filaments of the present disclosure preferably do not contain additives such as plasticizers and/or lubricants.
  • additives such as plasticizers and/or lubricants.
  • plasticizer refers to a material that imparts flexibility to the potential generating fibers or filaments
  • lubricant refers to a material that improves the sliding of the molecules of the piezoelectric yarn.
  • polyethylene glycol, castor oil-based fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyethylene glycol fatty acid ester, stearamide and/or glycerin fatty acid ester, etc. are intended. These materials are not included in the voltage generating fibers or filaments of the present disclosure.
  • the potential-generating fibers or filaments of the present disclosure may contain an anti-hydrolysis agent.
  • it may contain a hydrolysis inhibitor for polylactic acid (PLA).
  • An example of an anti-hydrolysis agent may include carbodiimide. More preferably, it may contain a cyclic carbodiimide. More specifically, it may be a cyclic carbodiimide described in Japanese Patent No. 5475377. Such a cyclic carbodiimide can effectively seal the acidic groups of the polymer compound.
  • a carboxyl group blocking agent may be used in combination with the cyclic carbodiimide compound to the extent that the acidic groups of the polymer can be effectively blocked. Examples of such carboxyl group-capping agents include agents described in JP-A-2005-2174, such as epoxy compounds, oxazoline compounds and/or oxazine compounds.
  • Fibers can be produced as yarns in which multiple fibers are aligned (aligned yarns or untwisted yarns), or as twisted yarns (twisted yarns or twisted yarns), or as crimped yarns (crimped yarns or false twisted yarns ), which may be included in the fabric as a spun yarn (spun yarn).
  • the fibers that can be included in the fabric that can be used in the present disclosure are not limited to those mentioned above.
  • the apparatus of the present disclosure can measure the surface potential of not only the fabric but also the yarn (one piece) and the yarn bundle in the same manner as the fabric.
  • FIG. 4 A potential measuring device according to an embodiment of the present disclosure will be described in detail below with reference to FIGS. 4 to 13.
  • FIG. 4 A potential measuring device according to an embodiment of the present disclosure will be described in detail below with reference to FIGS. 4 to 13.
  • FIG. 4 to 13 show a potential measuring device 10 (hereinafter referred to as "device 10") according to an embodiment of the present disclosure.
  • device 10 a potential measuring device 10
  • FIG. 5 is a front perspective view of the device 10
  • FIG. 6 is a perspective view of the device 10 as a whole
  • FIG. 7 is a left side view of the device 10.
  • 8 is a right perspective view of device 10
  • FIG. 9 is a rear view of device 10
  • FIG. 10 is a bottom view of device
  • FIG. 12 is a right side view of the device 10
  • FIG. 13 is a perspective view of the device 10 viewed from the rear.
  • the device 10 is a measuring device capable of measuring the surface potential of fabric or the like.
  • the device 10 comprises a conductive block 2 which may function as a ground electrode and has a tensioning mechanism capable of pulling in at least one direction a fabric which may be placed on this conductive block 2 (see Figure 1).
  • the fabric can be pulled in the X - axis direction (eg, X1 and/or X2 directions shown in FIG . 4).
  • the device 10 can pull the fabric in a curved shape so as to press it against the conductive block 2 (see FIGS. 2(B) and 16). Since the conductive block 2 can function as a ground electrode, the surface potential of the fabric can be measured more stably by pressing the fabric against the conductive block 2 .
  • the main surface of the conductive block 2 on which the cloth can be placed in the device 10 is curved. More specifically, according to a cross-sectional view of the main surface of the conductive block 2 in the X-axis direction, the main surface of the conductive block 2 is drawn with a curved line. In other words, the main surface of the conductive block 2 is curved.
  • the cross-sectional shape of the main surface of the conductive block 2 in the X-axis direction may have a trapezoidal shape with rounded corners. With such a shape, when the cloth is pressed against the conductive block 2, it is possible to suppress the displacement of the cloth at the measurement point (P). As a result, the surface potential of the fabric can be measured more stably.
  • the tensioning mechanism allows the fabric to be pulled in two opposite directions (see, eg, FIGS. 1 and 16). More specifically, the fabric can be pulled in the X1 and X2 directions shown in FIG . By pulling the cloth in two directions opposite to each other, it is possible to more significantly suppress the displacement of the cloth at the measurement point (P) located above the conductive block 2 . As a result, the surface potential of the fabric can be measured more stably.
  • the fabric can be repeatedly stretched and loosened by the tensioning mechanism.
  • the fabric can be stretched at regular intervals and/or at regular intervals.
  • the surface potential of the fabric can be measured in the meantime.
  • the surface potential of the fabric can be measured as the fabric expands and contracts. In other words, it is possible to confirm the correlation between the expansion and contraction of the fabric and the surface potential.
  • the amount of displacement of the fabric is, for example, 0.1% or more and 65% or less.
  • the displacement speed of the fabric is, for example, 0.1 mm/sec or more and 50 mm/sec or less.
  • the pull cycle is, for example, 0.1 Hz or more and 10 Hz or less.
  • the device 10 as a tension mechanism, there are two moving stages (3a, 3b) that can be arranged on both sides of the conductive block 2, and one end (Ta) of the cloth is attached to one of the two moving stages (3a). It has at least a first fixing member (4a) for fixing and a second fixing member (4b) for fixing the other end (Tb) of the fabric to the other (3b) of the two moving stages ( See Figure 4).
  • the two moving stages (3a, 3b) move in opposite directions to pull the cloth in opposite directions at the same time. More specifically, the two moving stages (3a, 3b) move in opposite directions along the X axis in directions X1 and X2, respectively , so that the fabric can be pulled in opposite directions at the same time.
  • the moving stages (3a, 3b) and the fixed members (4a, 4b) each have a plate-like shape.
  • the moving stage 3 and the fixed member 4 can be coupled (or engaged) to each other by fasteners such as screws or bolt-nuts through a plurality of holes (3h, 4h) that can correspond to each other as required. matable or mateable).
  • the movable stage 3 and fixed member 4 shown in FIG. 14 can correspond to the movable stage 3a and fixed member 4a shown in FIGS.
  • the moving stage 3b and fixed member 4b shown in FIGS. 4 to 13 can be formed symmetrically with the moving stage 3 and fixed member 4 shown in FIG. 14, respectively. Further, the moving stage 3 and the fixed member 4 shown in FIG.
  • the fixed member 4 can be arranged on the portion of the moving stage 3 indicated by the broken line.
  • the end portion of the cloth can be arranged and fixed on the movable stage 3 (see FIG. 16).
  • the groove 3g of the moving stage 3 and the raised portion 4p of the fixing member 4 have complementary shapes, the edge of the cloth can be fixed more reliably (see FIG. 16).
  • the two moving stages (3a, 3b) shown in FIGS. 4 to 13 are coupled (or engaged or fitted) to the apparatus main body 1 in a manner movable with respect to the apparatus main body 1.
  • the two moving stages (3a, 3b) are preferably slidably coupled (or engaged or fitted) to the apparatus main body 1 respectively.
  • rails are provided on the main body 1, and the surfaces of the moving stages (3a, 3b) facing the apparatus main body 1 correspond to the rails provided on the main body 1.
  • a part or member having a groove having a complementary shape may be provided, or wheels may be provided on the surfaces of the moving stages (3a, 3b) facing the main body 1 of the apparatus.
  • the two moving stages (3a, 3b) preferably move in conjunction with each other. For example, it is preferable to move away from each other along the X axis. They are also preferably moved toward each other along the X axis. More preferably, they reciprocate along the X-axis so as to move away from each other or toward each other.
  • the fabric can be stretched and loosened by reciprocating motion of the two moving stages (3a, 3b).
  • the fabric can be repeatedly stretched and loosened periodically.
  • one of the two moving stages (3a, 3b) may be stopped, preferably fixed, without interlocking the two moving stages (3a, 3b), and only the other of the two moving stages may be moved.
  • the fabric can be pulled in one direction in the same manner as in the embodiment shown in FIG. Even in such a case, the apparatus 10 can stably measure the surface potential of the fabric.
  • the two moving stages (3a, 3b) can each move, for example, within a range of 0.1 mm or more and 16 mm or less along the X axis.
  • the apparatus 10 may have a drive motor 5 for moving the two motion stages (3a, 3b) (see Figures 7-12).
  • the drive motor 5 is preferably arranged below the main body 1 (in the illustrated form, in the Z2 direction) (see FIGS. 9 to 12). More preferably, the drive motor 5 is arranged between the main body 1 and a pedestal (hereinafter also referred to as "base") 9 (see FIGS. 11 and 12).
  • the pedestal 9 may consist of an upper pedestal 9a for supporting the drive motor and a lower pedestal 9b for mounting the device 10 (see FIGS. 11 and 12).
  • a plurality of struts (11a, 11b) may be interposed between the upper base 9a and the main body 1 (see FIGS. 9, 11 and 12).
  • the upper pedestal 9a may be provided with a handle 12 for carrying the device 10 (see FIGS. 9 and 10).
  • the drive motor 5 may have a cable 14 for supplying power (see FIGS. 4, 8 and 10).
  • the drive motor 5 is preferably arranged in a direction transverse to the apparatus main body 1, for example, along the Y-axis shown in FIG.
  • the drive motor 5 may have a shaft 13, for example along the Y-axis shown in FIG. 4 (see FIGS. 10-12).
  • Shaft 13 can move, for example, along the Y-axis shown in FIG. More specifically, shaft 13 is movable in directions Y1 and Y2 , and more preferably reciprocating in directions Y1 and Y2 .
  • a movable part 6 may be attached to the shaft 13 of the drive motor 5 .
  • the movable part 6 may consist of a first movable part 6a that can slide on the case of the drive motor, and a second movable part 6b that can be coupled to the first movable part 6a (FIGS. 10 and 10). 11 and FIG. 12).
  • the first movable portion 6a may have a side surface or a cross section along the Y-axis having a shape such as an L shape (see FIGS. 11 and 12).
  • the second movable portion 6b may have a shape such as a plate shape or a block shape (see FIGS. 6 to 8).
  • the apparatus 10 has a plurality of arms or links (7a, 7b) connecting a movable part 6, more specifically a second movable part 6b, attached to a drive motor 5, to the motion stages (3a, 3b). You can do it.
  • One end of the arms (7a, 7b) is rotatably coupled (or engaged or fitted) with the movement stage (3a, 3b), and the other end of the arms (7a, 7b) is the second It may be rotatably coupled (or engaged or fitted) with the movable portion 6b.
  • the movement of the drive motor 5 along the Y-axis can be converted into the movement of the moving stages (3a, 3b) along the X-axis (see FIG. 4).
  • the two arms (7a, 7b) can simultaneously move the two moving stages (3a, 3b) facing each other in the direction along the X-axis.
  • the arms (7a, 7b) preferably have a plate-like shape.
  • the corners of the plate-like arms (7a, 7b) may be rounded, and preferably have an elliptical (or oval or oval) shape when viewed from above.
  • the elliptical shape of the arms (7a, 7b) can prevent the arms (7a, 7b) from contacting and interfering with each other at the joint of the second movable part 6b.
  • the apparatus 10 may comprise tension bars (8a, 8b) between the motion stages (3a, 3b) and the conductive block 2 (see Figures 4, 15 and 16).
  • Tension bars (8a, 8b) can assist in pressing the fabric against the conductive block 2.
  • FIG. By providing the tension bars (8a, 8b), it is possible to suppress or limit the movement of the fabric on the main surface of the conductive block 2, especially at the measurement point (P). Also, by providing the tension bars (8a, 8b), the main surface of the conductive block 2 can be more reliably brought into contact with the fabric, and GND can be formed more reliably. As a result, the surface potential of the fabric can be measured more stably.
  • the tension bars (8a, 8b) the cloth presses the conductive block 2 in the direction from Z1 to Z2 from above. The pressing force in one direction can be adjusted more appropriately.
  • the device 10 is configured to be able to pull or push up the fabric in the direction normal to the main surface of the conductive block 2 on which the fabric may be placed (or in the Z - axis direction, more specifically in the Z2 direction). (See FIGS. 11 and 12). In other words, the device 10 can press the fabric in the normal direction (or the Z - axis direction, more specifically the Z1 direction) to the main surface of the conductive block 2 on which the fabric can be placed. may be configured. In the embodiments shown in FIGS. 4 to 13, the conductive block 2 is placed on a support base and attached to the device main body 1 via a plurality of poles for adjusting the height.
  • the conductive block 2 can be raised and lowered in the height direction (or the Z - axis direction, more specifically, the Z1 and/or Z2 direction) by making the pole movable to raise and lower the support table on which it is placed. .
  • the conductive block 2 may be moved by a fixed distance and/or a fixed period. More preferably, the conductive block 2 may be reciprocated. By doing so, the fabric can be pulled or pushed up in the normal direction (or the height direction or the Z - axis direction, more specifically, the Z1 direction) with respect to the main surface of the conductive block 2 .
  • an elevator such as a motor, may be used to move the conductive block 2 up and down along the Z axis.
  • the conductive block 2 can move along the Z-axis within a range of, for example, 0.1 mm or more and 16 mm or less.
  • the support base and the pole for adjusting the height are preferably conductive, and more preferably made of a metal such as aluminum or an alloy such as stainless steel.
  • the conductive block 2 may be made of a highly conductive metal such as gold, silver, copper, platinum, or an alloy such as stainless steel.
  • the conductive block comprises metal, more preferably copper.
  • the device 10 may further have a measuring electrode 50 provided so as to face the conductive block 2 (see FIG. 1).
  • the measurement electrode 50 can be paired with the conductive block 2 that can function as a ground electrode to more stably measure the surface potential of the fabric.
  • the measuring electrode 50 is an electric force microscope (EFM) probe.
  • EFM electric force microscope
  • the device 10 preferably further comprises a cantilever 40 provided with a measuring electrode 50 (see FIG. 1).
  • the measuring electrode 50 can be positioned above the measuring point (P) more accurately, and the surface potential of the fabric can be measured more accurately.
  • the fabric is a piezoelectric fabric. More preferably, the piezoelectric fabric comprises piezoelectric fibers comprising polylactic acid.
  • the piezoelectric fabric especially the piezoelectric fabric contains polylactic acid
  • the piezoelectric fabric, especially the knitted fabric such as knit which can be composed of fibers or yarns containing polylactic acid, It was difficult to stably measure the surface potential.
  • the surface potential can be measured more stably.
  • the device of the present disclosure may alternatively be a device capable of pulling fabric in one direction, for example as shown in FIG.
  • a tension mechanism a moving stage 3 that can be arranged on one side of the conductive block 2 and a third fixing member (not shown) for fixing one end (Ta) of the fabric (F) to this moving stage 3 ) and a fourth fixing member (not shown) for fixing the other end (Tb) of the fabric (F) to the device main body 1 .
  • the movable stage 3 can be the same as the movable stages (3a, 3b) of the device 10
  • the third fixed member is also the same as the fixed members (4a, 4b) of the device 10. can do.
  • the position where the other end (Tb) of the fabric (F) is fixed to the apparatus main body 1 is not particularly limited.
  • a fixing member such as an anchor may be separately provided in the device main body 1 as a fourth fixing member.
  • the same fixing members (4a, 4b) of the device 10 may be used.
  • movement of the moving stage 3 can pull the fabric (F) in one direction. According to such an embodiment, it is possible to stably measure the surface potential of the fabric more easily with a smaller number of parts.
  • the device of the present disclosure relates to a measuring device capable of measuring the surface potential of a yarn or yarn bundle.
  • the potential measuring device comprises a conductive block (2) as a ground electrode and has a pulling mechanism capable of pulling in at least one direction the thread or thread bundle placed on the conductive block (2).
  • the tension mechanism that can be used in the above embodiments can be used without any particular restrictions.
  • the surface potential of the yarn or yarn bundle can be stably measured in the same manner as the cloth.
  • a yarn comprising piezoelectric fibers is preferred as the yarn.
  • a yarn comprising piezoelectric fibers comprising polylactic acid as the yarn is more preferred.
  • the bundle may be, for example, a bundle or braid of yarns comprising piezoelectric fibers. There is no particular limit to the number of fibers contained in the yarn bundle.
  • any of the devices of the present disclosure may be assembled. In other words, any device of the present disclosure may be disassembleable.
  • the apparatus of the present disclosure is not limited to the embodiments illustrated above.
  • Example 1 The following fabric was fixed to the apparatus shown in FIGS. 4 to 13, and the surface potential of the fabric was measured under the following conditions (see FIG. 16).
  • ⁇ Fabric Cloth containing piezoelectric fiber Single knit 46G cotton sheeting
  • This fabric used 84T72 untwisted yarn containing piezoelectric fibers. This yarn is a non-twisted yarn (number of filaments: 72, filament diameter: 10 ⁇ m, yarn diameter: 0.1 mm).
  • Displacement speed: 20mm/sec Number of measurements N 1
  • Fig. 17 shows the measured surface potential
  • Example 2 The following yarns were fixed in the apparatus shown in FIGS. 4 to 13, and the surface potentials of the yarns were measured under the following conditions.
  • ⁇ Yarn Thread containing piezoelectric fiber T16 84T24 Z1000T (with steam set at 85°C for 40 minutes)
  • This yarn is a Z yarn (number of filaments: 24, filament diameter: 19 ⁇ m) containing PLLA piezoelectric fibers (polylactic acid with an optical purity of 99% or more, a crystallinity of 44%, a crystal size of 13.5 nm, and an orientation of 90%).
  • thread diameter 0.1 mm
  • Displacement 1% (preliminary stretch: 0%, stretch during measurement: 1%)
  • the surface potential was measured by setting a probe of an electric force microscope: Model 1100TN manufactured by Trek Corporation as a measuring electrode on the cantilever, and performing it between this measuring electrode and a copper conductive block.
  • the graph of FIG. 19 shows the results of measuring the surface potential of the yarn. From the graph shown in FIG. 19, it was found that the surface potential of the yarn ranged from +0.7V to +2.9V (average 1.9V). The value of the surface potential of this yarn was almost the same as the value measured with an electric force microscope with the yarn covered with a conductor as in the conventional method.
  • the device of the present disclosure can be used, for example, to measure the surface potential of fabrics such as woven fabrics, knitted fabrics, and non-woven fabrics.
  • the device of the present disclosure can be used to measure the surface potential of fabrics comprising piezoelectric fibers.
  • the apparatus of the present disclosure can also measure the surface potential of yarns or bundles of yarns comprising piezoelectric fibers.
  • the apparatus of the present disclosure can also be used for antibacterial tests based on the surface potential of fabrics, fibers, yarns, and the like.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Textile Engineering (AREA)
  • Treatment Of Fiber Materials (AREA)

Abstract

L'invention concerne un dispositif qui peut mesurer de façon plus stable le potentiel de surface qui peut apparaître au niveau d'un tissu tel qu'un tissu tissé, un tissu tricoté et un tissu non-tissé. Selon la présente invention, un dispositif de mesure pour la mesure du potentiel de surface d'un tissu comprend un bloc conducteur sous la forme d'une électrode de masse et possède un mécanisme de traction qui peut tirer un tissu agencé sur le bloc conducteur dans au moins une direction.
PCT/JP2022/017020 2021-04-08 2022-03-29 Dispositif de mesure de potentiel WO2022215672A1 (fr)

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WO2023233881A1 (fr) * 2022-05-30 2023-12-07 株式会社村田製作所 Fil, tissu et vêtement
US12110618B2 (en) 2022-02-04 2024-10-08 Murata Manufacturing Co., Ltd. Knitted fabric structure, socks, arm cover, leggings, and shirt

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JP2009032598A (ja) * 2007-07-27 2009-02-12 Sumitomo Electric Ind Ltd 試料用ステージ及び試料の分析方法
JP2014044068A (ja) * 2012-08-24 2014-03-13 Universal Seikan Kk 二軸引張試験装置
WO2019093447A1 (fr) * 2017-11-08 2019-05-16 ソニー株式会社 Support d'enregistrement magnétique
JP2019513981A (ja) * 2016-04-08 2019-05-30 トレック インコーポレイテッド シールディングに優れる静電気力検出器および静電気力検出器の使用方法関連出願の相互参照 本願は、２０１６年４月８日に出願された米国仮特許出願番号第６２／３２０４０９号の優先権を主張するものである。
WO2020241432A1 (fr) * 2019-05-28 2020-12-03 帝人フロンティア株式会社 Fil et tissu

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Publication number Priority date Publication date Assignee Title
JP2009032598A (ja) * 2007-07-27 2009-02-12 Sumitomo Electric Ind Ltd 試料用ステージ及び試料の分析方法
JP2014044068A (ja) * 2012-08-24 2014-03-13 Universal Seikan Kk 二軸引張試験装置
JP2019513981A (ja) * 2016-04-08 2019-05-30 トレック インコーポレイテッド シールディングに優れる静電気力検出器および静電気力検出器の使用方法関連出願の相互参照 本願は、２０１６年４月８日に出願された米国仮特許出願番号第６２／３２０４０９号の優先権を主張するものである。
WO2019093447A1 (fr) * 2017-11-08 2019-05-16 ソニー株式会社 Support d'enregistrement magnétique
WO2020241432A1 (fr) * 2019-05-28 2020-12-03 帝人フロンティア株式会社 Fil et tissu

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12110618B2 (en) 2022-02-04 2024-10-08 Murata Manufacturing Co., Ltd. Knitted fabric structure, socks, arm cover, leggings, and shirt
WO2023233881A1 (fr) * 2022-05-30 2023-12-07 株式会社村田製作所 Fil, tissu et vêtement

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