WO2022172914A1 - Engine for combusting hydrogen-oxygen - Google Patents

Engine for combusting hydrogen-oxygen Download PDF

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Publication number
WO2022172914A1
WO2022172914A1 PCT/JP2022/004907 JP2022004907W WO2022172914A1 WO 2022172914 A1 WO2022172914 A1 WO 2022172914A1 JP 2022004907 W JP2022004907 W JP 2022004907W WO 2022172914 A1 WO2022172914 A1 WO 2022172914A1
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Prior art keywords
water
engine
oxygen
hydrogen
gas
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PCT/JP2022/004907
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French (fr)
Japanese (ja)
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寛治 泉
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寛治 泉
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Priority to JP2022580632A priority Critical patent/JPWO2022172914A1/ja
Publication of WO2022172914A1 publication Critical patent/WO2022172914A1/en

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N5/00Exhaust or silencing apparatus combined or associated with devices profiting from exhaust energy
    • F01N5/02Exhaust or silencing apparatus combined or associated with devices profiting from exhaust energy the devices using heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N5/00Exhaust or silencing apparatus combined or associated with devices profiting from exhaust energy
    • F01N5/04Exhaust or silencing apparatus combined or associated with devices profiting from exhaust energy the devices using kinetic energy
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M21/00Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form
    • F02M21/02Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form for gaseous fuels
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M25/00Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture
    • F02M25/022Adding fuel and water emulsion, water or steam
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F03MACHINES OR ENGINES FOR LIQUIDS; WIND, SPRING, OR WEIGHT MOTORS; PRODUCING MECHANICAL POWER OR A REACTIVE PROPULSIVE THRUST, NOT OTHERWISE PROVIDED FOR
    • F03GSPRING, WEIGHT, INERTIA OR LIKE MOTORS; MECHANICAL-POWER PRODUCING DEVICES OR MECHANISMS, NOT OTHERWISE PROVIDED FOR OR USING ENERGY SOURCES NOT OTHERWISE PROVIDED FOR
    • F03G7/00Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for

Definitions

  • It relates to engines that do not emit carbon dioxide and that have a configuration in which the combustion gas of the engine is hydrogen and oxygen or hydrogen oxygen (Brown gas).
  • An engine combustion device Z provided with a configuration in which water is converted to steam by the heat of combustion of oxygen and hydrogen, and the steam is reacted to generate hydrogen, and the heat generated by the combustion provided in the combustion chamber
  • a technology of an engine combustion device further comprising means for generating hydrogen or a mixed gas containing hydrogen using the steam and sub-materials supplied to the hydrogen generating means.
  • WO2011/1259676 Power plant combined cycle heat engine consists of a fuel inlet for taking in fuel HOH gas (Brown gas) into the combustion chamber, a spark plug that ignites the fuel in the combustion chamber, and a A technology characterized by an internal combustion engine equipped with a piston that moves according to pressure changes and a motion conversion mechanism that converts the motion of the piston into rotational motion of an output shaft.
  • HOH gas HOH gas
  • This application ignites HOH gas (hereinafter Brown gas is referred to as HOH gas), injects water into the flame generated by the ignition to generate a reaction water flow, and uses the injection force of the reaction water flow.
  • HOH gas HOH gas
  • It is a cylindrical engine or cylindrical combustion device that does not have a structure such as a piston and cylinder.
  • JP-A-2-95440 Radiation catalyst and redox method and apparatus using the same A highly radioactive platinum group element is supported on a tungsten silicide fine particle semiconductor, and is a radiation catalyst that serves both as a source of radiation that serves as an energy source and as a catalyst. Electron-hole pairs are generated in the fine semiconductor particles by the high radiation generated from the highly radioactive platinum group element, which causes the oxidation-reduction reaction to occur. Such redox reactions can be used, for example, to split water to produce oxygen and hydrogen.
  • *It is a technology that can be used for the HOH gas generation means of the present application.
  • the first invention supplies one or more of hydrogen, oxygen, or water in any step of intake, compression, explosion, or exhaust of an internal combustion engine that burns hydrogen.
  • Hydrogen supply means HS, oxygen supply means OS, and water supply means WS are provided for supplying water in the step and hydrogen, oxygen, and water in the explosion step, and hydrogen, oxygen, and water are supplied in the intake step.
  • the water supplied in the explosion step absorbs the heat in the combustion chamber and expands its volume to generate water vapor Aa
  • the water supplied in the explosion step absorbs the combustion heat of hydrogen and oxygen to generate water vapor Ab, which dissipates the heat in the combustion chamber.
  • the steam Aa is combined with the steam Aa produced by the endothermic process to produce steam A.
  • An ignition means for igniting the oxygen and hydrogen introduced into the internal combustion engine is provided for combustion, and the oxygen and hydrogen are generated by combustion.
  • An engine that burns hydrogen and oxygen characterized in that the water vapor B and the water vapor A are discharged as exhaust gas.
  • the supply order of supplying one or more of water, oxygen, and hydrogen is set such that water is supplied in the intake step, and hydrogen, oxygen, and water are supplied in the explosion step, hydrogen supply means HS and oxygen supply.
  • Means OS Water supply means WS is provided to supply hydrogen, oxygen and water to the engine.
  • the order of supplying hydrogen and water in the explosion step, or 2 supplying water and hydrogen in the intake step, and oxygen and water in the explosion step, in the order of supply, or 3, exploding water in the intake step. It is also possible to ignite the above oxygen and hydrogen in the process and supply water at the "timing immediately after ignition", or 4. Explode water in the intake step. However, it is also possible to set the water supply order to supply water at a timing other than "timing immediately after ignition”.
  • Hydrogen is supplied by the hydrogen supply means HS, oxygen is supplied by the oxygen supply means OS, and water is supplied by the water supply means WS. (When 1 cc of water becomes steam, it becomes 1.8 L to 1.9 L of steam, which is 1800 to 1900 times as much).
  • the engine is characterized by a technology that can withstand the combustion of oxygen and hydrogen (provided with heat-resistant means).
  • the work load of the engine is increased when the piston descends, and when the water is supplied before the compression step, the compression ratio can be increased by the volume increase due to evaporation.
  • the explosion step water is supplied at the timing immediately after ignition to increase the work of the engine, and the water vapor generating means for generating steam to be introduced into the hydrogen generating means ZU and the oxygen generating means ZUO (described later).
  • the temperature at the center of the combustion flame is about 2800°C.
  • Either one or both of the hydrogen generating means ZU and the oxygen generating means ZUO are used in an engine using (enriched) oxygen and an engine using air (oxygen in), in which the temperature of the center of the combustion flame rises by about 47%. 47% more production of steam to be introduced can be calculated (this is the difference in oxygen density).
  • oxygen in oxygen in
  • a second invention is a configuration of an engine that burns hydrogen and oxygen and supplies water, and includes a hydrogen supply means HS for supplying hydrogen to the combustion nozzle and an oxygen supply means OS for supplying oxygen to the combustion nozzle.
  • ignition means for igniting the supplied hydrogen and oxygen; and ignition means for burning the hydrogen and oxygen to generate a flame 3F, and for injecting water between the flame 3F and the combustion chamber wall 3U of the engine.
  • Water supply means WS for supplying water and water injection means WJ for injecting the supplied water are provided, and the injected water absorbs combustion heat of hydrogen and oxygen to generate water vapor Ab.
  • An engine that burns hydrogen and oxygen is provided, characterized in that the steam B generated by the combustion of hydrogen and oxygen is discharged as exhaust from an exhaust port 5S.
  • hydrogen supply means for example, hydrogen cylinders (high-pressure hydrogen produced at a hydrogen production plant and filled (for example, hydrogen cylinders filled with compressed hydrogen)) or hydrogen generation means ZU provided in the engine Hydrogen produced (or via tank) supplied, or hydrogen produced by electrolysis of water with electricity generated by solar energy in stationary form, or by solar energy and photocatalyst system.
  • Hydrogen produced or via tank supplied, or hydrogen produced by electrolysis of water with electricity generated by solar energy in stationary form, or by solar energy and photocatalyst system.
  • There is a method of decomposing water a method of decomposing water with electricity generated by thermomagnetic power generation technology, and so on.
  • the supply means for either oxygen generated in is described as an explanatory case.
  • the oxygen supply means OS is, for example, an oxygen cylinder (high-pressure oxygen manufactured at an oxygen factory and filled (for example, an oxygen cylinder filled with compressed oxygen)) or an oxygen generation means ZUO provided in the engine.
  • Oxygen produced by (or via a tank) supplied in a stationary form of solar energy, or oxygen produced by electrolysis of water with electricity generated by solar energy in stationary form, or solar energy and Water is decomposed by a photocatalytic system, water is decomposed by electricity generated by thermomagnetic power generation technology, etc., but in this application, oxygen separated by the above oxygen cylinder or separation means, or oxygen provided in the engine Any supply means for oxygen generated by the generation means ZUO is described as an explanatory example.
  • a heat-resistant structure is provided between a combustion nozzle 2N for introducing water into a water channel and combusting hydrogen and oxygen and a combustion chamber wall, and a plurality of injection nozzles TJ for injecting water introduced into the water channel into the heat-resistant structure are provided.
  • Engine Combustion Device 2 Injects water directly to the combustion chamber wall by changing the direction of water injection to the combustion chamber wall from a water passage without providing the heat-resistant structure.
  • engine combustion device 2a In WO 2019/130619, a water passage is provided in the heat-resistant structure, water is introduced into the water passage, steam is generated in the process in which the introduced water passes through the water passage, and the generated steam is transferred to the combustion chamber and the hydrogen generating means.
  • Engine combustion device Z ..
  • the present application does not provide any of the water passages between the heat-resistant structure and the inner and outer walls of the engine, and the water passages in the heat-resistant structure.
  • the heat-resistant structure and the water injection nozzle (injected from the inner wall) for injecting water from the combustion chamber wall are not provided, and the water injection layer blocks the direct heat of the flame 3F between the flame 3F and the combustion chamber wall.
  • a third invention is an engine that burns HOH gas (Brown gas).
  • the engine comprises HOH gas supply means BS for supplying HOH gas to combustion nozzles BN and ignition means Bp for igniting the supplied HOH gas.
  • a water supply means WS for supplying water for injecting water into the flame 3F; and a water passage for injecting the supplied water into the flame 3F.
  • a heat-resistant structure for protecting the fire of the flame 3F
  • the fire structure is It is a configuration that assumes that the flame 3F is extinguished by a vortex that can occur in the atmosphere or water due to the injection of water and the ejection of steam, and it is a configuration that can be omitted if it is not necessary.
  • Reaction above To provide an engine for burning Brown gas (HOH gas) characterized by discharging a flame stream BFa directly into water or into the air.
  • Heat-resistant structural members include tungsten, thorium, zirconium oxide, and so on.
  • a fourth invention is an exhaust injection in which a combustion chamber BN is provided in the engine according to the third invention, and the reaction flame flow BFa generated by combustion is collectively ejected as injection exhaust BST (mainly water vapor and other hydrogen and oxygen gases).
  • An outlet BEJ is provided, a water passage WR for passing water is provided between the combustion chamber outer walls BI and BO, and a plurality of water injection nozzles WJ are provided for introducing water and injecting water from the combustion chamber wall BI into the combustion chamber.
  • the water is injected into the combustion chamber through the water passage, and the injected water absorbs the heat in the combustion chamber to generate water vapor A.
  • the water vapor A is discharged together with the reaction flame flow BFa through the exhaust pipe BEX from the exhaust injection port as injected exhaust.
  • ignition means Bp for igniting the supplied HOH gas; flame 3F generated by burning the HOH gas by ignition; Furthermore, the water injection means WJR for injecting the water to the flame 3F and the heat-resistant structure (fire protection structure) for protecting the fire of the flame 3F are provided, and the fire protection structure allows the flame 3F to jet water and steam.
  • the reaction flame BBF which is formed by injecting water into the flame 3F, is directly injected into the inner tank water to form the reaction flame.
  • Either one or both of the power generation device 7Eq generates driving force and electricity, and is introduced into a separation device BBst that separates brown gas and water vapor from the jetted waste water that flows through the device, and the separated brown gas is discharged into the gas tank. It is introduced into a brown gas supply means including BGT, and steam is supplied to the brown gas generator UBP using the radiation catalyst or the brown gas generator Bp that generates brown gas with electricity generated by the magnetothermal power generator 8E.
  • a brown gas supply means including BGT
  • steam is supplied to the brown gas generator UBP using the radiation catalyst or the brown gas generator Bp that generates brown gas with electricity generated by the magnetothermal power generator 8E.
  • a sixth invention is a power generation device 7Eq that introduces the steam generated by the engine according to the first invention to the second invention and the fourth invention, and generates electricity from the driving force generation device KD of the engine-mounted equipment. and HHO gas generating means for generating HHO gas.
  • a seventh invention is characterized in that an engine that burns HOH gas is mounted on a moving body, and resistance (resistance of water and air) generated by propulsion of the moving body is used as power generation power. and provide an engine that burns oxygen and supplies water. *The entire amount of the injection exhaust of the engine described in the above third and fourth inventions is injected from the injection port that injects into water or air, and the HOH gas of the on-board equipment is used as the driving force for the on-board equipment.
  • An engine burning loun gas (HOH gas) configured to generate electricity to supply self-sufficient means.
  • an engine equipped with an HOH gas generating means and an electricity generating means is mounted on a moving body for burning HOH gas, and the electricity generated by the engine is supplied to the equipment parking lot of the engine-mounted equipment.
  • a power receiving means for receiving power and a water supply means for supplying water to the engine are provided, the engine is operated while the engine-mounted equipment is parked, electricity is produced, the electricity is supplied to the power receiving equipment, and the water is supplied.
  • HOH gas Brown gas
  • Engine-equipped equipment described above e.g.
  • a ninth invention is a mobile body and seawater that are equipped with an electricity generation means and a hydrogen and oxygen generation means according to the first invention to the second invention and the fourth invention to the fifth invention.
  • Brown gas HH gas
  • means SP for generating fresh water and salt from the introduced seawater is provided when seawater is introduced as the water introduced into the engine of the desalination device.
  • HTES high temperature steam electrolysis
  • SOEC Solid Oxide Electrolysis Cell
  • the Gibbs energy change in water electrolysis becomes smaller than at room temperature, and the theoretical electrolysis voltage becomes lower.
  • the thermoneutral voltage theoretical operating voltage
  • the electrolysis voltage can be much lower than liquid electrolysis such as alkaline water electrolysis or PEM water electrolysis. Heat can be supplied directly to the reaction, saving power and avoiding the inefficiencies of converting heat to power. Therefore, much higher efficiency can be expected than other electrolysis methods.
  • thermoelectric energy converter JP 2012-52162 A method for producing and using hydrogen and oxygen.
  • a thermoelectric conversion module was prototyped using heat related to the technology for a thermoelectric conversion device that directly converts heat into electricity, and a power generation test was conducted.
  • a successful example of extracting 0.39 V has been published. Copper is used for the electrodes, and is bonded to each of the p and n materials by diffusion bonding. It is a technology that generates electricity by temperature difference.
  • the driving force generating device KD and the electricity generating means 7Eq introduce the exhaust gas and flow through the rotating blade body to generate electricity from the rotating force of the rotating blade body shaft portion and the rotation of the rotating blade body shaft portion. It is an existing technology that enables the driving force generation device KD and the electricity generation means 7Eq with the technology 1 device that coaxially provides a transmission structure for transmitting force (for example, a buvelt and a gear).
  • a magnetic circuit module is composed of a permanent magnet, a magnetic body, and a yoke wound with a coil for generating an induced electromotive force.
  • a technique for generating electricity by providing a pipe for supplying cold water and periodically opening and closing a valve provided in the pipe to give a temperature difference cycle to the magnetic body.
  • ⁇ JP 2004-197211 A hydrogen-oxygen mixed gas generator ⁇ JP 2009-35804 A large-capacity brown gas generator and its electrolytic cell.
  • ⁇ Properties of Brown gas HOH gas>
  • His technology involves a highly efficient electrolysis cell that decomposes water in a precise atom-to-atom ratio of two volumes of hydrogen to one volume of oxygen, producing hydrogen gas and oxygen gas
  • This discovery led to the establishment of the theory that hydrogen gas and oxygen gas are instantly, completely and in exactly the correct proportions (the "theoretical mixing ratio" in scientific parlance).
  • the above is a composition diagram in which the composition structure of Brown gas is 180 degrees, which is different from the 105 degrees of water molecules. 2. Theory of HOH Gas Water and electricity are the raw materials for making oxygen and hydrogen mixed gas (HOH gas).
  • HOH gas flame HOH gas flame has a notable feature and is quite different from the flame produced when mechanically combining oxygen gas and hydrogen gas. The unique nature of the extreme thermal energy produced by oxygen-hydrogen gas mixtures (HOH gas) appears to result from their interaction with the object being heated.
  • This high heat concentration of the flame is especially important when welding metals where the heat lost by conduction weakens the strength near the melting point.
  • a typical example of this is the welding of aluminum.
  • HSH gas oxygen-hydrogen mixed gas
  • the heat energy is concentrated in a narrow area and does its function without distributing the heat widely.
  • the cut is sufficiently smooth, partly due to this high heat concentration characteristic.
  • Pattern 1 an example of a pattern
  • Water is introduced in the intake process, the introduced water absorbs heat in the cylinder to generate steam A, the steam is compressed in the compression process, hydrogen and oxygen are introduced by direct injection in the explosion process, and are ignited by the ignition means. Ignite, burn hydrogen and oxygen, then ignite (immediately after) and introduce water.
  • the exhaust pressure increases the work of the engine.
  • the discharge pressure can be the introduction pressure of water and oxygen/hydrogen.
  • the hydrogen supply means HS in the above pattern is assumed to be a hydrogen cylinder (for example, a hydrogen cylinder filled with compressed hydrogen), and the oxygen supply means OS is assumed to be, for example, an oxygen cylinder (high-pressure oxygen manufactured and filled at an oxygen factory (for example, compressed If either an oxygen cylinder filled with oxygen)) or oxygen separated from air is used as a supply means, the combustion temperature can be raised and the amount of water supplied to the cylinder can be increased by the amount raised. For example, in a 4-cylinder engine with a displacement of 2000cc, it is 500cc per cylinder.
  • ⁇ Pattern 2 introduces oxygen and water in the intake process, introduces hydrogen by direct injection in the post-compression explosion process, ignites with the ignition means, hydrogen and oxygen burn, and ignites (immediately after) After water is introduced, an exhaust process is started.
  • Example pattern 3 introduces hydrogen and water in the intake process, introduces oxygen by direct injection in the post-compression explosion process, ignites with the ignition means, combusts hydrogen and oxygen, and introduces water at the timing of combustion. I'm doing It is also possible to omit the work of introducing water after the ignition of the above hydrogen and oxygen (immediately after) in the explosion process.
  • water can be supplied in the compression process, but the same effect can be obtained by supplying the water in the suction process.
  • the supply of water only has the effect of increasing the amount of steam produced and it is preferred to introduce water in the intake stroke and in the explosion stroke if the heat in the engine produces steam.
  • the amount of water that can be supplied into the engine is the amount that can be used to generate steam from water using the thermal energy of the explosion. It is necessary to secure the inlet temperature of the oxygen generator (for example, in the case of a steam electrolyzer, the inlet temperature is at least near the upper limit of the heat resistance temperature of the steam cracker) to a temperature at which hydrogen can be produced. *If the above cycle requires time for steaming, the speed may be, for example, 60/rpm/min.
  • the engine shown in FIG. 1 does not have a mechanical structure related to compression and rotation in the combustion chamber (cylindrical engine).
  • the feature of this engine is that hydrogen and oxygen (separated oxygen) are burned in the combustion chamber NE.
  • a heat absorbing means steam generation Water injection means WJ for injecting water in a shape forming the injection water layer WS of the means
  • WJ steam generation Water injection means WJ for injecting water in a shape forming the injection water layer WS of the means
  • the volume of the steam is expanded to about 1800 times to form a steam explosion)
  • the heat in the combustion chamber NE is absorbed, and the steam B and steam A generated by the combustion of hydrogen and oxygen are exhausted ( water vapor).
  • FIG. 10 is a view showing an example of the form of the jetted water layer formed by jetting from the jetting nozzle of the jetting water layer WS jetted from the water jetting means WJ.
  • the configuration is such that the direct heat to the combustion chamber wall 2U is blocked by the enclosing configuration, and WJ2 is configured such that the groove formed between the concave portion and the convex portion is a water injection nozzle.
  • WJ3 is a view of the water injection means WJ showing a configuration in which the water column shape is mixed in the injection water layer.
  • the engine shown in FIG. 2 is an engine that burns hydrogen/oxygen, and is an electrolysis oxygen/hydrogen gas generating means EH, a photocatalytic hydrogen/oxygen gas generating device PH, or a hydrogen/oxygen generating device RH using a radiation catalyst.
  • the hydrogen/oxygen generated by any one of the generators is supplied to a hydrogen supply means HS having a gas tank and an oxygen supply means OS, and the hydrogen supply means HS for supplying hydrogen to the combustion nozzle and the oxygen supply to the combustion nozzle.
  • an oxygen supply means OS an ignition means for igniting the supplied hydrogen and oxygen, and an ignition means for burning the hydrogen and oxygen to generate a flame 3F
  • water supply means WS for supplying water for injecting water between the flame 3F and the combustion chamber outer shell 3U of the engine; and water injection for injecting water between the supplied water and the combustion chamber outer shell 3U.
  • the injected water is a steam generating means for absorbing the combustion heat of hydrogen and oxygen to generate steam Ab, and is directly underwater as exhaust together with the steam B generated by the combustion of hydrogen and oxygen.
  • the engine shown in FIG. 3 is an engine that burns HOH gas, and the engine includes an ignition nozzle BN that ignites the HOH gas supplied from a Brown gas (HOH gas) supply means and a combustion nozzle BN that ignites the supplied HOH gas.
  • Means Bp HOH gas is burned by ignition to generate flame 3F
  • water supply means WS for supplying water for injecting water into flame 3F
  • water passage WJR for injecting the supplied water into flame 3F.
  • a heat-resistant structure that injects water from the water channel into the flame to generate a reactive flame flow BFa and protects the flame of the flame 3F
  • flame protection structure a heat-resistant structure that injects water from the water channel into the flame to generate a reactive flame flow BFa and protects the flame of the flame 3F
  • Water is injected into the flame 3F It is characterized in that the reaction flame BFa formed by this is discharged directly into water or air.
  • FIG. 3 is a schematic diagram of the cross section of the engine, which is attached to the equipment mounted on the engine (as an example, at the aft part of the hull), and configured to inject the reaction flame BFa generated by the engine into the water or the atmosphere.
  • the engine of this structure is an embodiment that is mounted on ships, flying objects (airplanes, rockets, flying limousine buses, etc.), and railway vehicles (bullet trains, etc.).
  • (B) is a view in the R arrow direction of A in which the engine is installed.
  • Fig. 4 shows a combustion chamber BN provided in the HOH gas engine BE shown in Fig. 3, and an exhaust outlet BEJ for ejecting a reaction flame flow BFa generated by combustion as an injection exhaust BST (mainly water vapor and other hydrogen and oxygen gases). is provided, and the force generated by the ejection is used as the propulsion force (for example, the rotational force of the rotor).
  • a water passage WR for passing water is provided between the outer walls BI and BO of the combustion chamber, and a plurality of water injection nozzles WJ for introducing water and injecting water into the combustion chamber are provided to the combustion chamber wall BI, and combustion is performed from the water passage.
  • FIG. D1 is a diagram showing flame 3F being generated
  • D2 is a diagram showing water injected from a water injection nozzle that injects into the flame, and the injected water intersects in the flame.
  • FIG. D3 is a diagram showing reaction flame flow BFa formed by water injected into the flame.
  • FIG. 5 shows a configuration in which the engine for burning HOH gas in FIG. 3 is provided in the inner tank IE water, One end of the inner tank IE filled with water is provided with an engine BEW, and the other end of the inner tank is provided with an exhaust port. Water supplied from the other end of the tank and water supplied from the water supply means WOS are sent through the outer layer OE to the one end of the inner tank IE to protect the fire source of the flame 3F (fire protection structure).
  • a water circulation loop WEX is provided to supply water so as to be sucked into the reaction flame flow BFa from the outside,
  • the HOH having an HOH gas tank BGT is supplied to the engine BEW by any one of the HOH gas generator BP, the photocatalytic generator BH, and the HOH gas generator UBP using a radiation catalyst.
  • the HOH gas is supplied from the gas supply means BS to the combustion nozzle BN, and the ignition means Bp ignites the supplied HOH gas.
  • water supply means WS for supplying water; Water injection means WJR for injecting the supplied water to the flame 3F, and a heat-resistant structure (a fire protection structure) for protecting the fire of the flame 3F.
  • the reaction flame BBF formed by injecting water to the flame 3F is directly injected into the water in the inner tank to form the reaction flame water flow BFa, and the water in the water-filled inner tank is collected and drained at the drain outlet.
  • the driving force and electricity 7E are generated by either or both of the driving force generating device KD that introduces the ejected wastewater and generates the driving force, or the power generating device 7Eq.
  • HOH gas is generated by the HOH gas generator UBP using radiation catalyst
  • Electricity 8E is generated by the thermomagnetic generator 8Eq, and the generated electricity 8E is further generated.
  • the electricity 7E obtained by flowing through the power generator 7Eq is further received and HOH gas is generated by the HOH gas generator Bp, B, HOH gas is generated by a generator Bh that generates a photocatalytic oxygen hydrogen gas (or HOH gas) that receives solar energy, and HOH gas is generated by an electrolysis HOH gas generator Bp.
  • HOH gas supply means BS having a gas tank.
  • the supplied water is supplied to the outer tank OE via the water supply means WOS, and the supplied water is the water sucked into the reaction flame flow BFa in the inner tank. is generated, and electricity 7E and 8E and driving force T are output.
  • a supply means WOS for the shortage of water in the outer layer OE is provided.
  • salt is separated by vaporizing seawater in a configuration in which the engine is provided with a salt extracting means WS.
  • the water vapor C obtained by separating and removing the salt by providing means for extracting the separated salt is fresh water.
  • FIG. 6 is a diagram showing a configuration in which a plurality of HOH gas combustion engines BEW shown in FIG. Schematic diagram of a configuration for generating electricity by providing a water resistance power generating means 6E for generating electricity by water resistance generated by propulsion of a ship, and generating HOH gas as a fuel from the generated electricity.
  • FIG. 7 is a cross-sectional view taken along line B-B of FIG. 6, showing an example of the arrangement of the engine and the installation of water resistance power generation means.
  • FIG. 8 shows a configuration in which the HOH gas combustion engine shown in FIG. 3 is used as an excavation unit BRG for excavating submarine resources. Control is performed by wired communication from the sea, and a plurality of excavation parts BRG are provided in the front part in a state of being skipped by one interval, and rare metals such as cobalt sticking to the bedrock are placed in the rear part so as to cover the part skipped in the front part. After stripping a certain area, the seawater is sucked into the ship with a pump.It is also possible to supply the above HOH gas from the sea.
  • Fig. 9 shows hydrogen gas generation in a ball mill vessel.
  • ⁇ Gifu Pharmaceutical University's Pharmaceutical Chemistry Laboratory found that when stainless steel balls and water are placed in a stainless steel ball mill container and rotated at high speed, the water decomposes and hydrogen gas is generated quantitatively (all the water used is hydrogen gas I found a thing that converts to .
  • a ball mill is a "coffee mill” that is familiar at home, and at the same time, it is a “device that finely grinds objects", and is used by rotating or vibrating together with metal or ceramic balls (Fritsch Japan Co., Ltd.) (manufactured and sold in Japan). Technology described in "ACS Sustainable Chem. Eng.
  • FIG. 10 presents a new concept called “nano-window," a nanometer-sized window smaller than an oxygen molecule, announced by the Institute of Materials Science for Environment and Energy, Interdisciplinary Research Group, Shinshu University.
  • Graphene with this "nano window” has been found to be able to separate oxygen from the atmosphere 2,000 times faster than the current rate. It is theoretically predicted that oxygen, nitrogen, argon, etc. can be selectively and extremely rapidly separated by attaching a "nano window” of the size of an oxygen molecule to graphene, which consists of a single layer of carbon atoms.
  • FIG. 2 is an image diagram of the structure of a “nano window” through which nitrogen molecules pass and separate oxygen molecules.
  • FIG. 11 shows that the Japan Science and Technology Agency (JST), whose research theme is energy efficiency, and Tohoku University are jointly developing a hydrogen production method that does not use expensive precious metals, and the hydrogen production method uses graphene.
  • JST Japan Science and Technology Agency
  • Tohoku University are jointly developing a hydrogen production method that does not use expensive precious metals
  • the hydrogen production method uses graphene.
  • ⁇ Three-dimensional nanoporous graphene,'' which has a three-dimensional structure and further replaces some of the carbon atoms with nitrogen and sulfur atoms, is used for the electrodes.
  • graphene becomes inhomogeneous due to nitrogen and sulfur atoms water reacts and generates hydrogen by electrolysis.
  • FIG. 4 is an image diagram of generating hydrogen from water on the outside and inside of a hollow tube. An example of hydrogen supply means. *Technology that can be used for electrodes in electrolysis and fuel cells.
  • ⁇ Fig. 12 is a separation image diagram of a high-performance oxygen separation membrane that separates oxygen from air developed by the Electric Power Technology Laboratory.
  • the separation membrane is a mixed conductor that conducts electrons as well as oxygen ions.
  • Oxygen molecules receive electrons on the air side of the membrane and are ionized ⁇ Oxygen ions move to the opposite side of the membrane due to ionic conduction ⁇ Electrons are released on the oxygen permeation side and return to oxygen molecules again ... High purity from air of oxygen can be obtained.
  • (B) is a diagram showing the size of the oxygen separation membrane of 27 CC/MIN/Cm2. An example of oxygen supply means.
  • FIG. 1 A diagram of a cylindrical engine that introduces hydrogen and oxygen and supplies water.
  • Fig. 2 is a schematic diagram of the engine of Fig. 2 provided in a multihull hydrofoil ship WFS; BB sectional drawing of FIG. The schematic which made the engine of FIG.

Abstract

[Problem] 1. A measure capable of reducing the discharge of carbon dioxide causing global warming. 2. A measure described in item 1 for an engine that combusts HHO gas (Brown's gas). 3. A configuration in which the structure of item 2 are developed for an aircraft, a vessel, or a rocket. 4. A self-fueled configuration mounted to the abovementioned Brown's gas (HOH gas) engine. 5. A structure of a stationary form (e.g., power plant, factory, tracked vehicle, or vessel) of the abovementioned engine. 6. A simple excavator for deep sea minerals (rare metal including zinc, lead, gold, copper, and cobalt). The present invention addresses the problem of solving the abovementioned problems. [Solution] 1. A carbonless engine is provided with the feature of combusting Brown's gas and jetting a reaction flow generated by the combustion, and enables the production of electricity, the production of a drive force, and the production of Brown's gas by using the jet force of the reaction flow directly as a propulsive force or by receiving the jet force of a jet flow collected by a combustion chamber provided for collecting the jet flow. The engine is further provided with a hydrogen-oxygen generation device using a radiation catalyst and a thermomagnetic generator. Selected drawing: FIG. 3

Description

[規則26に基づく補充 28.02.2022] 水素・酸素を燃焼するエンジン[Replenishment based on Regulation 26 28.02.2022] Engines that burn hydrogen and oxygen
  エンジンの燃焼気体を水素と酸素とした構成か水素酸素(ブラウンガス)とした構成とした二酸化炭素の排出をしないエンジンに係る。 It relates to engines that do not emit carbon dioxide and that have a configuration in which the combustion gas of the engine is hydrogen and oxygen or hydrogen oxygen (Brown gas).
 ・水素と酸素を燃焼するエンジンに係る技術での空気中の酸素以外からの酸素使用は技術としては存在するが実施ベースでは普及していない。 ・窒素NOx及び二酸化炭素COを排出しないエンジンでHOHガスのみを燃焼するエンジンに係る技術は普及していない。 ・The use of oxygen from sources other than oxygen in the air in technology related to engines that burn hydrogen and oxygen exists as a technology, but it is not widespread on a practical basis.・Technology related to engines that burn only HOH gas without emitting nitrogen NOx and carbon dioxide CO2 is not widespread.
WO2019/130619 酸素と水素を燃焼させた熱で水を水蒸気にしており、該水蒸気を反応させて水素を生成する構成を設けたエンジン燃焼装置Zであって、燃焼室に設けられた燃焼による熱を受ける耐熱構造部に通水路を設け、該通水路内で水から水蒸気を生成し、該水蒸気を燃焼室に供給する供給ノズルとを備え、前記水素生成手段に副材料を供給する副材料供給手段を更に備え、水素生成手段に供給された水蒸気と副材料とを使用して水素もしくは水素を含む混合ガスを生成するエンジン燃焼装置の技術。WO2019/130619 An engine combustion device Z provided with a configuration in which water is converted to steam by the heat of combustion of oxygen and hydrogen, and the steam is reacted to generate hydrogen, and the heat generated by the combustion provided in the combustion chamber A supply nozzle for generating steam from water in the water passage, supplying the steam to the combustion chamber, and supplying the auxiliary material to the hydrogen generating means. A technology of an engine combustion device further comprising means for generating hydrogen or a mixed gas containing hydrogen using the steam and sub-materials supplied to the hydrogen generating means.
WO2011/1259676 動力プラントの複合サイクル 熱機関は、燃焼室内に燃料のHOHガス(ブラウンガス)を取り込むための燃料取込口と、燃焼室内の燃料に点火する点火プラグと、点火前後における燃焼室内の圧力変化に応じて運動するピストンと、ピストンの運動を出力軸の回転運動に変える運動変換機構とを備えた内燃機関であることを特徴とする技術。*本願はHOHガス(以後ブラウンガスをHOHガスと記載する)に点火し、点火して生成される火炎に水を噴射して反応水流を生成して該反応水流の噴射力を使用する構成のピストン・シリンダー等の構造を持たない筒型エンジン又は筒型燃焼装置である。WO2011/1259676 Power plant combined cycle heat engine consists of a fuel inlet for taking in fuel HOH gas (Brown gas) into the combustion chamber, a spark plug that ignites the fuel in the combustion chamber, and a A technology characterized by an internal combustion engine equipped with a piston that moves according to pressure changes and a motion conversion mechanism that converts the motion of the piston into rotational motion of an output shaft. *This application ignites HOH gas (hereinafter Brown gas is referred to as HOH gas), injects water into the flame generated by the ignition to generate a reaction water flow, and uses the injection force of the reaction water flow. It is a cylindrical engine or cylindrical combustion device that does not have a structure such as a piston and cylinder.
特開平2-95440 放射線触媒及びそれを用いた酸化還元方法と装置。タングステンシリサイド微粒子半導体に高放射性白金族元素を担持させ、エネルギー源となる放射線の発生源と触媒作用とを兼ねる放射線触媒で、このような放射線触媒を用い、それに被処理流体を接触させ、担持されている高放射性白金族元素から生じる高放射線により微粒子半導体に電子-正孔対を生成させて酸化還元反応を行わせる。このような酸化還元反応は、例えば水を分解して酸素と水素を製造するのに利用できる。*本願のHOHガス生成手段に使用出来る技術である。JP-A-2-95440 Radiation catalyst and redox method and apparatus using the same. A highly radioactive platinum group element is supported on a tungsten silicide fine particle semiconductor, and is a radiation catalyst that serves both as a source of radiation that serves as an energy source and as a catalyst. Electron-hole pairs are generated in the fine semiconductor particles by the high radiation generated from the highly radioactive platinum group element, which causes the oxidation-reduction reaction to occur. Such redox reactions can be used, for example, to split water to produce oxygen and hydrogen. *It is a technology that can be used for the HOH gas generation means of the present application.
1、地球温暖化の二酸化炭素の排出削減が出来る策を発明する。2、上記WO2019/130619よりより簡単な構造を発明する。3,現在流通しておるエンジンの燃料を水素と酸素としたディゼルエンジンDYかレシプロエンジンRSかロータリーエンジンREかのエンジンを主構造とした構成で二酸化炭素を排出しない策を発明する。4,水素酸素ガス(ブラウンガス=HOHガス)を燃焼するエンジンを発明する。5,上記エンジンの定置形態(発電所・工場・軌道車・船舶等)構造を発明する。6,深海鉱物(亜鉛・鉛・金・銅やコバルト等のレアメタル)の簡単な掘削機を発明する。 1. Invent measures that can reduce carbon dioxide emissions from global warming. 2. Invent a simpler structure than the above WO2019/130619. 3. To invent a measure that does not emit carbon dioxide with a configuration that has as its main structure a diesel engine DY, a reciprocating engine RS, or a rotary engine RE that uses hydrogen and oxygen as the fuels of the engines that are currently in circulation. 4, Invent an engine that burns hydrogen oxygen gas (Brown gas = HOH gas). 5. Invent the stationary structure of the above engine (power station, factory, rail car, ship, etc.). 6, Invent a simple excavator for deep sea minerals (rare metals such as zinc, lead, gold, copper and cobalt).
第一の発明は、水素を燃焼する内燃機関の吸気か、圧縮か、爆発か,排気かの何れかのステップで水素か酸素か水かの何れか1以上を供給する、供給順を、吸気ステップで水を、爆発ステップで水素と酸素と水を供給する、水素供給手段HSと酸素供給手段OSと、水供給手段WSを設けて水素と酸素と水を供給し、上記吸気ステップで供給された水は燃焼室内の熱を吸熱し体積を膨張させた水蒸気Aaを生成し、更に爆発ステップで供給された水は水素と酸素の燃焼熱を吸熱して水蒸気Abを生成し燃焼室内の熱を吸熱して生成された水蒸気Aaとを合わせて水蒸気Aとした水蒸気生成手段としており、上記内燃機関に導入された酸素と水素に点火する点火手段を設けて燃焼し、酸素と水素の燃焼で生成した水蒸気Bと前記水蒸気Aを排気として排出しておる事を特徴とする水素・酸素を燃焼するエンジン。
*上記第一の発明では水か酸素か水素かの何れか1以上を供給する供給順を、吸気ステップで水を、爆発ステップで水素と酸素と水を供給する、水素供給手段HSと酸素供給手段OS水供給手段WSを設けて水素と酸素と水をエンジンに供給し、としておるが水か酸素か水素かの何れか1以上を供給する供給順を、1,吸気ステップで水と酸素を、爆発ステップで水素と水を供給する供給順にする事も、2,吸気ステップで水と水素を、爆発ステップで酸素と水を供給する、供給順にする事も、3,吸気ステップで水を爆発工程で上記酸素と水素に点火し、「点火直後のタイミング」で水を供給する事も、4、吸気ステップで水を爆発工程で上記酸素と水素に点火し、点火直後のタイミングで水を供給する、「点火直後のタイミング」以外のタイミングで水を供給する水供給順とする事も出来る。
*該水素供給手段HSで水素を、酸素供給手段OSで酸素を、水供給手段WSで水を供給し、供給された水は、該水が上記水素と酸素の燃焼による熱で水を水蒸気Abにしており、(水1CCが水蒸気になると1800倍~1900倍の1.8L~1.9Lの水蒸気になる、)該水蒸気化でエンジン内の熱を吸熱しており、且つ、水の気化により、上記酸素と水素の燃焼に耐える(耐熱手段を設けた)エンジンとした技術を特徴とするものである。
*上記供給した水が気化することにより、ピストン下降時の気化ではエンジンの仕事量を多くしており、圧縮ステップ前の水の供給では気化による体積の増大分ほど圧縮比を上げることが出来ており、爆発ステップでは点火直後のタイミングで水を供給してエンジンの仕事量を多くして、更に水素生成手段ZU及び酸素生成手段ZUO(後記)に導入する水蒸気を生成する水蒸気生成手段としておる。
*(富化)酸素と水素の燃焼では燃焼炎の中心温度は2800℃程度で空気(中の酸素)と水素の燃焼では燃焼炎の中心温度は1900℃程度で(富化)酸素の使用により47%程度燃焼炎の中心温度が上がる、(富化)酸素を使用したエンジンと、空気(中の酸素)を使用したエンジンとでは上記水素生成手段ZU及び酸素生成手段ZUOの何れか一方か両方かに導入する水蒸気の製造を計算上47%多く出来る(酸素密度の差である)。
*上記エンジンの点火手段であるが、通念上、水(水蒸気)の中で燃料を燃焼させる事は思考常識から除外された技術であるが水素を燃料とした自動車が開発され、該水素自動車の点火手段が数多く発明されており、(例えば燃料直噴射技術)本願に於いては上記水素と酸素の点火技術としては公開され常識となった技術で対応すれば良い。
*燃焼ガスの持つ全エネルギー量はガス流量とその温度の積に比例するので、水素と(富化)酸素の燃焼で燃焼温度をUPした排気ガスを生成し、さらに水を水蒸気にする水蒸気生成手段で生成した水蒸気との両方でガス流量を多くしておりその上酸素の発熱反応による熱エネルギーで該燃焼ガスの持つ全エネルギー量を多くしておる。 
第二の発明は、水素と酸素を燃焼し水を供給するエンジンの構成であって、水素を燃焼ノズルに供給する、水素供給手段HSと、酸素を燃焼ノズルに供給する、酸素供給手段OSと、供給された水素と酸素に点火する点火手段と、点火により水素と酸素を燃焼して火炎3Fを生成し、該火炎3Fとエンジンの燃焼室壁3Uとの間に水を噴射する該水を供給する、水供給手段WSと、供給された該水を噴射する水噴射手段WJを設けた構造で、噴射した水は、水素と酸素の燃焼熱を吸熱して水蒸気Abを生成する水蒸気生成手段としており、水素と酸素の燃焼により生成される水蒸気Bとともに排気として排気口5Sから排出する構成にしておる事を特徴とする、水素と酸素を燃焼するエンジンを提供する。
*上記水素供給手段であるが、例えば水素ボンベ(水素製造所で製造され充填した高圧水素(例えば圧縮された水素を充填した水素ボンベ))か、該エンジン内に設けておる水素生成手段ZUで生成され(又はタンク経由で)供給される水素か、或いは定置形態での太陽光エネルギーで発電した電気で水を電気分解して製造された水素を供給する形態か、太陽光エネルギーと光触媒系で水を分解する形態か、熱磁気発電技術で生成した電気で水を分解するか、等々あるが本願では上記水素ボンベか分離手段により分離された水素か該エンジン内に設けておる酸素生成手段ZUOで生成される酸素かの何れかの供給手段を解説事例として記載しておる。*上記酸素供給手段OSであるが、例えば酸素ボンベ(酸素製造所で製造され充填した高圧酸素(例えば圧縮された酸素を充填した酸素ボンベ))か,該エンジン内に設けておる酸素生成手段ZUOで生成され(るか又はタンク経由で)供給される酸素か、或いは定置形態での太陽光エネルギーで発電した電気で水を電気分解して製造された酸素を供給する形態か、太陽光エネルギーと光触媒系で水を分解する形態か、熱磁気発電技術で生成した電気で水を分解するか、等々あるが本願では上記酸素ボンベか分離手段により分離された酸素か該エンジン内に設けておる酸素生成手段ZUOで生成される酸素かの何れかの供給手段を解説事例として記載しておる。(上記水素生成手段ZUで生成される材料を水とした生成手段では水素生成分離後の気体は酸素+水蒸気(鉄の酸化反応利用の水素生成技術では、鉄は酸素と反応するので酸素は生成しない)である.*現在製造されておる水素自動車は上記水素ボンベを水素供給手段としており、該自動車のエンジンに水を供給する手段を設けた構成が実現に一番近い構成であり該構成であってもエンジンの圧縮比を大きく出来ることで現在の燃費の向上に寄与する。*更に酸素供給手段OSを上記酸素ボンベとする事で酸素と水素の燃焼温度を上げ上記水供給手段の水供給量(水蒸気生成量)を増量する事が出来、エンジンの仕事量を多くするので走行距離を伸ばせ500/Km走行(1充填当たりの)が可能となる。*さらに上記水素供給手段を当該エンジン内で生成する水素生成手段ZUで水素を酸素生成手段ZUOで酸素を生成し供給するエンジンの構成にすればエンジン外からの水素の供給を不要に近づけられる(又は自給出来る)。*該発明の水素と酸素を燃焼し水を噴射する構造は、特許第5967682 富化酸素空気と燃料の燃焼で燃料を生成するエンジンの燃焼装置2,2aでは、燃焼室内外壁間に通水路MHを設けて該通水路に水を導入し、水素と酸素を燃焼する燃焼ノズル2Nと燃焼室内壁間に耐熱構造部を設け、上記通水路に導入した水を該耐熱構造部に噴射する噴射ノズルTJを複数設け該耐熱構造部に噴射する構成であり、(エンジンの燃焼装置2)上記耐熱構造部を設けないで通水路から燃焼室内壁に水を噴射する水の噴射方向を変えた燃焼室内壁に直接水を噴射する噴射ノズルMJを設けて噴射する構成であり、(エンジンの燃焼装置2a)、
上記WO2019/130619では上記耐熱構造部内に通水路を設けて該通水路に水を導入し、導入した水が通水路を通過する過程で水蒸気を生成し、生成した水蒸気を燃焼室及び水素生成手段に噴射する構成であり、(エンジンの燃焼装置Z)・・上記構成に対して本願は上記耐熱構造部及びエンジン内外壁間の通水路及び耐熱構造部内の通水路かの何れかは設けておらず、該耐熱構造部や燃焼室内壁から水を噴射する水噴射ノズル(内壁から噴射する)も設けない構成であり、上記火炎3Fと燃焼室内壁間に火炎3Fの直射熱を遮り水噴射層を形成する水噴射手段WJを設けておるだけの構成で水蒸気生成手段及び燃焼室内の熱を吸熱する吸熱手段とした上記エンジン燃焼装置2及び2a及びZのいずれの構造より簡単な構造(のエンジンに出来る)としており、簡単な構造にしたことがより早期に地球温暖化の二酸化炭素の排出削減が実施出来る策となった。
第三の発明はHOHガス(ブラウンガス)を燃焼するエンジンであって、該エンジンは、HOHガスガスを燃焼ノズルBNに供給するHOHガスガス供給手段BSと、供給されたHOHガスに点火する点火手段Bpと、点火手段BpによりHOHガスを燃焼して火炎3Fを生成しており、該火炎3Fに水を噴射する水を供給する水供給手段WSと、供給された該水を火炎3Fに噴射する水路WJRと、該水路WJRから水を火炎に噴射して反応火炎流BFaを生成しており、上記火炎3Fの火種を保護する耐熱構造部 (火種保護構造部)を備え、(該火種構造部は火炎3Fが水の噴射及び水蒸気の噴出で大気又は水中で起こりうる渦流で火炎3Fが消えることも想定される対策とした構成であり、必要が無い場合は省略可の構成である。)上記反応火炎流BFaを直接水中もしくは空気中に排出しておる事を特徴とするブラウンガス(HOHガス)を燃焼するエンジンを提供する。*耐熱構造部材には例えばタングステン、トリュウム、酸化ジリコニュウム等々ある。
第四の発明は第三の発明に記載のエンジンに燃焼室BNを設け、燃焼により生成された反応火炎流BFaをまとめて噴射排気BST(主に水蒸気その他水素・酸素ガス)として噴出する排気噴出口BEJを設け、上記燃焼室内外壁BI・BO間に水を通水する通水路WRを設け、水を導入し燃焼室内壁BIから燃焼室内に水を噴射する複数の水噴射ノズルWJを設けて該通水路から燃焼室内に噴射して、噴射した水は燃焼室内の熱を吸熱して水蒸気Aを生成し上記反応火炎流BFaと共に排気道BEXを通って排気噴射口から噴射排気として排出しておる事を特徴とするブラウンガス(HOHガス)を燃焼するエンジンを提供する。
第五の発明は第三の発明に記載のエンジンを、HOHガスを燃焼するエンジンの定置形態(定地形態=発電所・工場、定置=船舶、軌道車=鉄道・新幹線)エンジンで、HOHガス生成装置の電気分解系生成装置BPか光触媒系生成装置BHか放射線触媒使用のHOHガス生成装置UBPで生成されたHOHガスかの何れかのガスをHOHガスタンクBGT経由で燃焼ノズルBNに供給して、供給されたHOHガスに点火する点火手段Bpと、点火によりHOHガスを燃焼して火炎3Fを生成しており、該火炎3Fに水を噴射する水を供給する水供給手段WSと、供給された該水を火炎3Fに噴射する水噴射手段WJRと、火炎3Fの火種を保護する耐熱構造部 (火種保護構造部)を備え、該火種保護構造部は火炎3Fが水の噴射及び水蒸気の噴出で大気又は水中で起こりうる渦流で火炎3Fが消えることも想定される対策とした構成であり、必要が無い場合は省略可の構成である。
火炎3Fに水を噴射して形成される反応火炎BBFを直接内槽水中に噴射して反応火炎ており、排出された噴射排水を導入して駆動力を生成する駆動力生成装置KDか発電する発電装置7Eqかの何れか一方か両方かで駆動力及び電気を生成して、該装置を貫流した噴射排水からブラウンガス及び水蒸気を分離する分離装置BBstに導入して,分離したブラウンガスをガスタンクBGTを含むブラウンガス供給手段に導入しており、水蒸気を上記放射線触媒使用のブラウンガス生成装置UBPか磁気熱発電装置8Eで生成した電気でブラウンガスを生成するブラウンガス生成装置Bpかに供給する水蒸気とするか又は水供給手段をWOSに合流させるかの何れかにした構成で駆動力と電気の一方か両方かを出力として取り出しておる事を特徴とするブラウンガスを燃焼するエンジンを提供する。
第六の発明は、第一の発明から第二の発明及び第四の発明に記載のエンジンで生成した水蒸気を導入し、該エンジン搭載機器の駆動力生成装置KDか電気を生成する発電装置7Eqか、HHOガスを生成するHHOガス生成手段かの何れか1以上を設けておることを特徴とする、ブラウンガス(HOHガス)を燃焼するエンジンを提供する。
第七の発明は、HOHガスを燃焼するエンジンを移動体に搭載しており、該移動体の推進により発生する抵抗力(水・空気の抵抗)を発電動力としておることを特徴とする、水素と酸素を燃焼し水を供給するエンジンを提供する。*上記第三の発明及び第四の発明に記載のエンジンの噴射排気の全量を水中もしくは空気中に噴射する噴射口から噴射し、該搭載機器の駆動力とした構成で搭載機器のHOHガスを自給する手段に供給する電気を生成する構成としたラウンガス(HOHガス)を燃焼するエンジンを提供する。
第八の発明は、HOHガスを燃焼するエンジンにHOHガス生成手段及び電気生成手段を備えたエンジンを移動体に搭載しており、該エンジン搭載機器の駐機器場に上記エンジンで生成した電気を受電する受電手段と該エンジンに水を供給する水供給手段を設け、上記エンジン搭載機器の駐機器中に当該エンジンを稼働させ、電気を製造し該電気を上記受電設備に供給し、上記水を受給することを特徴とする、ブラウンガス(HOHガス)を燃焼するエンジンを提供する。*上記記載のエンジン搭載機器(例えば自動車・船舶(エンジンで海上を走行する例えばマリンジェットスキー等も含む)・航空機・建設機械(例えばショベルカー)・農耕機器(例えば耕運機・草刈り機)林業作業機器(例えばチェンソー)鉄道(例えばレール上を走行する電車)等)の駐機器場(例えば駐車場・船舶係留場・飛行場・建設機械保管場・農耕機器保管場・林業作業機器保管場・電車車庫)等)に上記エンジンで生成した電気を受電する受電手段と該エンジンに水を供給する水供給手段を設け上記エンジン搭載機器の駐機器中に当該エンジンを稼働させ電気を製造し該電気を上記受電設備に供給し上記水を受給する事を特徴とするもの。*上記移動体非稼働時を活用する手段によりエンジン内の停止・稼働の繰り返しによる該エンジンの構成材の疲労による亀裂破壊等を防止出来該エンジンの寿命延長に繋げるとともに該エンジン生成物の電気の販売もしくは使用(例えば自工場で使用)により該エンジンの原価償却を早く出来る。・すなわち上記移動体移動時は上記エンジンを稼働して燃料のHOHガスを生成し移動体のエネルギーとする仕事をし、移動と言う仕事を終えた後は上記移動体エンジンを稼働させ水を供給する水供給手段を設け、生成される電気を引き取り設備(外部社会電力エネルギー供給インフラへの電力供給)にて引き取らせるか更には電気駆動のエンジンに於いては蓄電装置の充電手段の電気とするかのいずれかにすることで該移動体非稼働時を活用する手段とする。
第九の発明は、第一の発明から第二の発明及び第四の発明から第五の発明に記載の電気生成手段及び水素と酸素生成手段を備えたエンジンは海を航行する移動体及び海水の真水化装置の前記エンジンに導入される前記水として海水を導入する場合に、前記導入された海水から真水と塩を生成する手段SPを設けたことを特徴とする、ブラウンガス(HOHガス)を燃焼するエンジンを提供する。
<上記問題を解決する手段の補足説明>
The first invention supplies one or more of hydrogen, oxygen, or water in any step of intake, compression, explosion, or exhaust of an internal combustion engine that burns hydrogen. Hydrogen supply means HS, oxygen supply means OS, and water supply means WS are provided for supplying water in the step and hydrogen, oxygen, and water in the explosion step, and hydrogen, oxygen, and water are supplied in the intake step. The water supplied in the explosion step absorbs the heat in the combustion chamber and expands its volume to generate water vapor Aa, and the water supplied in the explosion step absorbs the combustion heat of hydrogen and oxygen to generate water vapor Ab, which dissipates the heat in the combustion chamber. The steam Aa is combined with the steam Aa produced by the endothermic process to produce steam A. An ignition means for igniting the oxygen and hydrogen introduced into the internal combustion engine is provided for combustion, and the oxygen and hydrogen are generated by combustion. An engine that burns hydrogen and oxygen, characterized in that the water vapor B and the water vapor A are discharged as exhaust gas.
*In the above first invention, the supply order of supplying one or more of water, oxygen, and hydrogen is set such that water is supplied in the intake step, and hydrogen, oxygen, and water are supplied in the explosion step, hydrogen supply means HS and oxygen supply. Means OS Water supply means WS is provided to supply hydrogen, oxygen and water to the engine. , the order of supplying hydrogen and water in the explosion step, or 2, supplying water and hydrogen in the intake step, and oxygen and water in the explosion step, in the order of supply, or 3, exploding water in the intake step. It is also possible to ignite the above oxygen and hydrogen in the process and supply water at the "timing immediately after ignition", or 4. Explode water in the intake step. However, it is also possible to set the water supply order to supply water at a timing other than "timing immediately after ignition".
* Hydrogen is supplied by the hydrogen supply means HS, oxygen is supplied by the oxygen supply means OS, and water is supplied by the water supply means WS. (When 1 cc of water becomes steam, it becomes 1.8 L to 1.9 L of steam, which is 1800 to 1900 times as much). , The engine is characterized by a technology that can withstand the combustion of oxygen and hydrogen (provided with heat-resistant means).
*By evaporating the supplied water, the work load of the engine is increased when the piston descends, and when the water is supplied before the compression step, the compression ratio can be increased by the volume increase due to evaporation. In the explosion step, water is supplied at the timing immediately after ignition to increase the work of the engine, and the water vapor generating means for generating steam to be introduced into the hydrogen generating means ZU and the oxygen generating means ZUO (described later).
* (Enriched) When oxygen and hydrogen are burned, the temperature at the center of the combustion flame is about 2800°C. Either one or both of the hydrogen generating means ZU and the oxygen generating means ZUO are used in an engine using (enriched) oxygen and an engine using air (oxygen in), in which the temperature of the center of the combustion flame rises by about 47%. 47% more production of steam to be introduced can be calculated (this is the difference in oxygen density).
*Although it is a means of ignition for the above engine, it is common knowledge that burning fuel in water (steam) is a technology that is excluded from common thinking, but automobiles using hydrogen as fuel have been developed. Many ignition means have been invented (for example, direct fuel injection technology), and in the present application, the ignition technology for hydrogen and oxygen that has been made public and has become common sense may be used.
*Since the total amount of energy possessed by the combustion gas is proportional to the product of the gas flow rate and its temperature, the combustion of hydrogen and (enriched) oxygen produces an exhaust gas with an increased combustion temperature, and also the water vapor generation. The gas flow rate is increased both with the water vapor generated by the means, and furthermore, the thermal energy from the exothermic reaction of oxygen increases the total amount of energy possessed by the combustion gas.
A second invention is a configuration of an engine that burns hydrogen and oxygen and supplies water, and includes a hydrogen supply means HS for supplying hydrogen to the combustion nozzle and an oxygen supply means OS for supplying oxygen to the combustion nozzle. , ignition means for igniting the supplied hydrogen and oxygen; and ignition means for burning the hydrogen and oxygen to generate a flame 3F, and for injecting water between the flame 3F and the combustion chamber wall 3U of the engine. Water supply means WS for supplying water and water injection means WJ for injecting the supplied water are provided, and the injected water absorbs combustion heat of hydrogen and oxygen to generate water vapor Ab. An engine that burns hydrogen and oxygen is provided, characterized in that the steam B generated by the combustion of hydrogen and oxygen is discharged as exhaust from an exhaust port 5S.
* Regarding the above hydrogen supply means, for example, hydrogen cylinders (high-pressure hydrogen produced at a hydrogen production plant and filled (for example, hydrogen cylinders filled with compressed hydrogen)) or hydrogen generation means ZU provided in the engine Hydrogen produced (or via tank) supplied, or hydrogen produced by electrolysis of water with electricity generated by solar energy in stationary form, or by solar energy and photocatalyst system. There is a method of decomposing water, a method of decomposing water with electricity generated by thermomagnetic power generation technology, and so on. The supply means for either oxygen generated in is described as an explanatory case. * The oxygen supply means OS is, for example, an oxygen cylinder (high-pressure oxygen manufactured at an oxygen factory and filled (for example, an oxygen cylinder filled with compressed oxygen)) or an oxygen generation means ZUO provided in the engine. Oxygen produced by (or via a tank) supplied in a stationary form of solar energy, or oxygen produced by electrolysis of water with electricity generated by solar energy in stationary form, or solar energy and Water is decomposed by a photocatalytic system, water is decomposed by electricity generated by thermomagnetic power generation technology, etc., but in this application, oxygen separated by the above oxygen cylinder or separation means, or oxygen provided in the engine Any supply means for oxygen generated by the generation means ZUO is described as an explanatory example. (In the generation means using water as the material generated by the hydrogen generation means ZU, the gas after hydrogen generation separation is oxygen + water vapor (In the hydrogen generation technology using the oxidation reaction of iron, iron reacts with oxygen, so oxygen is generated. *Currently manufactured hydrogen-powered vehicles use the above-mentioned hydrogen cylinders as means for supplying hydrogen, and the configuration in which means for supplying water to the engine of the vehicle is the closest to realization. Even if there is, the compression ratio of the engine can be increased, contributing to the improvement of current fuel consumption. It is possible to increase the amount of hydrogen (amount of water vapor generated) and increase the work load of the engine, so the mileage can be extended and 500/Km driving (per filling) is possible.*In addition, the above hydrogen supply means is installed in the engine. If the engine is constructed so that hydrogen is generated by the hydrogen generating means ZU and oxygen is generated and supplied by the oxygen generating means ZUO, the supply of hydrogen from outside the engine becomes nearly unnecessary (or self-sufficient).*Hydrogen of the invention The structure of burning oxygen and injecting water is described in Japanese Patent No. 5967682. In combustion devices 2 and 2a of an engine that generate fuel by combustion of oxygen-enriched air and fuel, a water passage MH is provided between the outer wall of the combustion chamber and the water passage is provided. A heat-resistant structure is provided between a combustion nozzle 2N for introducing water into a water channel and combusting hydrogen and oxygen and a combustion chamber wall, and a plurality of injection nozzles TJ for injecting water introduced into the water channel into the heat-resistant structure are provided. (Engine Combustion Device 2) Injects water directly to the combustion chamber wall by changing the direction of water injection to the combustion chamber wall from a water passage without providing the heat-resistant structure. (engine combustion device 2a),
In WO 2019/130619, a water passage is provided in the heat-resistant structure, water is introduced into the water passage, steam is generated in the process in which the introduced water passes through the water passage, and the generated steam is transferred to the combustion chamber and the hydrogen generating means. (Engine combustion device Z) .. In contrast to the above configuration, the present application does not provide any of the water passages between the heat-resistant structure and the inner and outer walls of the engine, and the water passages in the heat-resistant structure. In addition, the heat-resistant structure and the water injection nozzle (injected from the inner wall) for injecting water from the combustion chamber wall are not provided, and the water injection layer blocks the direct heat of the flame 3F between the flame 3F and the combustion chamber wall. A simpler structure than any of the above engine combustion devices 2, 2a and Z, which uses water vapor generating means and heat absorbing means for absorbing heat in the combustion chamber with a configuration only provided with water injection means WJ forming ), and the simple structure has become a measure that can reduce carbon dioxide emissions from global warming at an early stage.
A third invention is an engine that burns HOH gas (Brown gas). The engine comprises HOH gas supply means BS for supplying HOH gas to combustion nozzles BN and ignition means Bp for igniting the supplied HOH gas. a water supply means WS for supplying water for injecting water into the flame 3F; and a water passage for injecting the supplied water into the flame 3F. WJR, water is jetted from the water passage WJR to the flame to generate a reaction flame flow BFa, and a heat-resistant structure (a fire protection structure) for protecting the fire of the flame 3F is provided (the fire structure is It is a configuration that assumes that the flame 3F is extinguished by a vortex that can occur in the atmosphere or water due to the injection of water and the ejection of steam, and it is a configuration that can be omitted if it is not necessary.) Reaction above To provide an engine for burning Brown gas (HOH gas) characterized by discharging a flame stream BFa directly into water or into the air. * Heat-resistant structural members include tungsten, thorium, zirconium oxide, and so on.
A fourth invention is an exhaust injection in which a combustion chamber BN is provided in the engine according to the third invention, and the reaction flame flow BFa generated by combustion is collectively ejected as injection exhaust BST (mainly water vapor and other hydrogen and oxygen gases). An outlet BEJ is provided, a water passage WR for passing water is provided between the combustion chamber outer walls BI and BO, and a plurality of water injection nozzles WJ are provided for introducing water and injecting water from the combustion chamber wall BI into the combustion chamber. The water is injected into the combustion chamber through the water passage, and the injected water absorbs the heat in the combustion chamber to generate water vapor A. The water vapor A is discharged together with the reaction flame flow BFa through the exhaust pipe BEX from the exhaust injection port as injected exhaust. To provide an engine for burning Brown gas (HOH gas) characterized by a
The fifth invention is the engine described in the third invention in a stationary form of an engine that burns HOH gas (stationary form = power plant / factory, stationary = ship, rail car = railway / bullet train) engine, HOH gas Either the HOH gas generated by the electrolysis system generator BP, the photocatalyst system generator BH, or the HOH gas generator UBP using the radiation catalyst of the generator is supplied to the combustion nozzle BN via the HOH gas tank BGT. , ignition means Bp for igniting the supplied HOH gas; flame 3F generated by burning the HOH gas by ignition; Furthermore, the water injection means WJR for injecting the water to the flame 3F and the heat-resistant structure (fire protection structure) for protecting the fire of the flame 3F are provided, and the fire protection structure allows the flame 3F to jet water and steam. This is a configuration that assumes that the flame 3F is extinguished by a vortex that can occur in the atmosphere or water, and can be omitted if it is not necessary.
The reaction flame BBF, which is formed by injecting water into the flame 3F, is directly injected into the inner tank water to form the reaction flame. Either one or both of the power generation device 7Eq generates driving force and electricity, and is introduced into a separation device BBst that separates brown gas and water vapor from the jetted waste water that flows through the device, and the separated brown gas is discharged into the gas tank. It is introduced into a brown gas supply means including BGT, and steam is supplied to the brown gas generator UBP using the radiation catalyst or the brown gas generator Bp that generates brown gas with electricity generated by the magnetothermal power generator 8E. To provide an engine burning brown gas characterized in that one or both of a driving force and electricity are taken out as an output in a configuration in which steam is used or a water supply means is joined to a WOS. .
A sixth invention is a power generation device 7Eq that introduces the steam generated by the engine according to the first invention to the second invention and the fourth invention, and generates electricity from the driving force generation device KD of the engine-mounted equipment. and HHO gas generating means for generating HHO gas.
A seventh invention is characterized in that an engine that burns HOH gas is mounted on a moving body, and resistance (resistance of water and air) generated by propulsion of the moving body is used as power generation power. and provide an engine that burns oxygen and supplies water. *The entire amount of the injection exhaust of the engine described in the above third and fourth inventions is injected from the injection port that injects into water or air, and the HOH gas of the on-board equipment is used as the driving force for the on-board equipment. An engine burning loun gas (HOH gas) configured to generate electricity to supply self-sufficient means is provided.
In an eighth invention, an engine equipped with an HOH gas generating means and an electricity generating means is mounted on a moving body for burning HOH gas, and the electricity generated by the engine is supplied to the equipment parking lot of the engine-mounted equipment. A power receiving means for receiving power and a water supply means for supplying water to the engine are provided, the engine is operated while the engine-mounted equipment is parked, electricity is produced, the electricity is supplied to the power receiving equipment, and the water is supplied. To provide an engine burning Brown gas (HOH gas), characterized by receiving. * Engine-equipped equipment described above (e.g. automobiles, ships (including marine jet skis that run on the sea with engines, etc.), aircraft, construction machinery (e.g. excavators), agricultural equipment (e.g. cultivators, mowers), forestry equipment (e.g. chainsaws) railroads (e.g., trains running on rails), etc.) equipment parking lots (e.g., parking lots, ship moorings, airfields, construction machinery storage areas, agricultural equipment storage areas, forestry equipment storage areas, train depots), etc.) is provided with a power receiving means for receiving electricity generated by the engine and a water supply means for supplying water to the engine. It is characterized by supplying and receiving the above water. * By means of utilizing the non-operating time of the moving body, it is possible to prevent cracks and fractures due to fatigue of the components of the engine due to repeated stop and operation in the engine, which leads to extension of the life of the engine and electricity generated by the engine. The depreciation of the engine can be accelerated by sale or use (for example, use in own factory).・That is, when moving the moving body, the engine is operated to generate HOH gas as fuel and work as energy for the moving body, and after the work of moving is completed, the engine of the moving body is operated to supply water A water supply means is provided, and the generated electricity is taken by a take-back facility (power supply to the external social power energy supply infrastructure), or furthermore, in the case of an electrically driven engine, it is used as electricity for charging means of the storage device. By doing either one of the above, it is possible to utilize the non-operating time of the moving body.
A ninth invention is a mobile body and seawater that are equipped with an electricity generation means and a hydrogen and oxygen generation means according to the first invention to the second invention and the fourth invention to the fifth invention. Brown gas (HOH gas), characterized in that means SP for generating fresh water and salt from the introduced seawater is provided when seawater is introduced as the water introduced into the engine of the desalination device. provide an engine that burns
<Supplementary explanation of means to solve the above problem>
・水素キャリヤとしての水、水は1立方メートル当たり111kgの水素を含有している為液体水素1立方メートルの水素量71kg凌駕しています。
「水素生成手段ZU」
・Water as a hydrogen carrier. Since water contains 111 kg of hydrogen per 1 cubic meter, it surpasses 71 kg of hydrogen in 1 cubic meter of liquid hydrogen.
"Hydrogen generation means ZU"
・固体酸化物形水蒸気電解装置(特開2008-243744記載技術)400℃~600℃の作動温度においても、原子の透過性を向上させることができる金属薄膜を用いた水蒸気電解装置で該金属薄膜を金属組成物と、前記金属組成物の結晶粒界に分散させた酸化物とを含有する。前記金属組成物を構成する金属ターゲットと、前記酸化物を構成する酸化物ターゲットとを同時にスパッタリングして形成した技術。 ・Solid oxide steam electrolysis device (Technology described in JP-A-2008-243744) A steam electrolysis device using a metal thin film that can improve atomic permeability even at an operating temperature of 400°C to 600°C. and an oxide dispersed at the grain boundaries of said metal composition. A technique in which a metal target forming the metal composition and an oxide target forming the oxide are simultaneously sputtered.
・高温水蒸気電解(HTES)電解法による水素製造法とそのコスト(阿部 勲夫)から引用。高温水蒸気電解(HTES : High Temperature Electrolysis of Steam又はSOEC:Solid Oxide Electrolysis Cellと呼ばれる)とはアルカリ水電解やPEM水電解とは異なり、800℃から1000℃で水蒸気を、酸化ジルコニウムを主体とした無機の薄い固体電解質を用いて電解する方法である。逆反応の高温型燃料電池の技術を応用したもので、新しい方法であるため、開発の段階は未だ基礎的なものに留っている。固体酸化物電解質薄膜の両側に電極を付けて電解セルとする。通常は電解質薄膜を円筒形にして内外に両極を付けて電解セルを構成する。
両極で以下の反応が起こる。
(陰極) H2O + 2e- → O2-- + H2 ↑
(陽極) O2-- →2e- + 1 / 2 O2 ↑
全体で、 H2O → H2 + 1/ 2 O2
陰極側に供給された水蒸気は一部が水素になり、水素と水蒸気の混合物となる。ここで生成した酸化物イオンが固体電解質の薄膜の内部を、陰極側から陽極側に移動して酸素となる。固体電解質にはイットリウム等で修飾した酸化ジルコニウムの薄膜が使われる。前述の(図1の)ように温度が高くなると水電解のギブズエネルギー変化が常温より小さくなり、理論電解電圧が低くなる。また高温下では電極反応の速度が早くなるため、活性の強い触媒を用いなくても過電圧が低くなり、水の電解が熱中性電圧(理論稼働電圧)以下で可能であり、図1の吸熱領域で電解できる。電力はギブズエネルギー変化分(理論電解電圧)以上あれば、分解に必要な残りのエネルギーは熱の形で供給することができる。このため原理的には電解電圧はアルカリ水電解法やPEM水電解法のような液体電解よりもずっと低く出来る。熱を直接反応に供給できるので電力が節約でき、熱を電力に変換する効率の悪さを回避できる。このため他の電解方式よりもずっと高い効率が期待できる。
- Quoted from Hydrogen production method and its cost by high temperature steam electrolysis (HTES) electrolysis method (Isao Abe). High Temperature Electrolysis of Steam (HTES) or SOEC (Solid Oxide Electrolysis Cell) is different from alkaline water electrolysis and PEM water electrolysis. This is a method of electrolysis using a thin solid electrolyte. It is an application of reverse reaction high temperature fuel cell technology, and since it is a new method, the development stage is still at a basic level. Electrodes are attached to both sides of the solid oxide electrolyte thin film to form an electrolytic cell. Usually, an electrolytic cell is constructed by forming an electrolyte thin film into a cylindrical shape and attaching both inner and outer electrodes.
The following reactions occur at both poles.
(cathode) H2O + 2e- → O2-- + H2 ↑
(Anode) O2-- →2e- + 1 / 2 O2 ↑
Overall, H2O → H2 + 1/2 O2
A part of the water vapor supplied to the cathode side becomes hydrogen and becomes a mixture of hydrogen and water vapor. The oxide ions generated here move inside the thin film of the solid electrolyte from the cathode side to the anode side and become oxygen. A thin film of zirconium oxide modified with yttrium or the like is used as the solid electrolyte. As described above (FIG. 1), when the temperature rises, the Gibbs energy change in water electrolysis becomes smaller than at room temperature, and the theoretical electrolysis voltage becomes lower. In addition, since the electrode reaction speeds up at high temperatures, the overvoltage is low even without using a highly active catalyst, and water electrolysis is possible below the thermoneutral voltage (theoretical operating voltage). can be electrolyzed with If the power is equal to or greater than the Gibbs energy change (theoretical electrolysis voltage), the remaining energy required for decomposition can be supplied in the form of heat. Therefore, in principle, the electrolysis voltage can be much lower than liquid electrolysis such as alkaline water electrolysis or PEM water electrolysis. Heat can be supplied directly to the reaction, saving power and avoiding the inefficiencies of converting heat to power. Therefore, much higher efficiency can be expected than other electrolysis methods.
・電気生成手段*エンジンからの排気の熱をエネルギー変換手段で変換した「電気5E」。
「熱電エネルギー変換装置」
特開2012-52162水素および酸素の製造・使用方法。熱を電気に直接変換する熱電変換装置となる技術に係る熱で熱電変換モジュールが試作され、発電試験が実施されており、発電試験の結果(300℃に加熱し無負荷=電流ゼロ)起電力0.39Vを取り出すのに成功した事例が公開されておる、上記施策された発電モジュールは、p型材料にFe2V0.9Ti0.1Al2,n型材料にFe2val0.9si0.1を用いて18個の熱電素子からなるのである、 電極には銅が使用され、p,n各材料と拡散接合で接合しており、該モジュールの片方は20℃で一定とし、他方面を300℃に加熱し上下面の温度差により発電する技術である。*駆動力生成装置KDと電気生成手段7Eqは排気を導入して回転翼体を貫流して該回転翼体軸部の回転力を電気に生成する電気生成構造と該回転翼体軸部の回転力を伝達する伝達構造部(例えばブイヴェルト・歯車)を同軸に設ける技術1装置で駆動力生成装置KDと電気生成手段7Eqを可能としたもので既存技術である。*電気生成技術で、物質と材料研究開発機構の研究グループがAIを使った材料開発手法で、従来の磁石に比べて1.5倍強い「ネオジュウム磁石」を作る技術を発明した。=電気を生成する生成効率UPや発電機の小型化に繋げる技術。
・Electricity Generating Means* "Electricity 5E" which converts the heat of the exhaust from the engine with the energy conversion means.
"Thermoelectric energy converter"
JP 2012-52162 A method for producing and using hydrogen and oxygen. A thermoelectric conversion module was prototyped using heat related to the technology for a thermoelectric conversion device that directly converts heat into electricity, and a power generation test was conducted. A successful example of extracting 0.39 V has been published. Copper is used for the electrodes, and is bonded to each of the p and n materials by diffusion bonding. It is a technology that generates electricity by temperature difference. *The driving force generating device KD and the electricity generating means 7Eq introduce the exhaust gas and flow through the rotating blade body to generate electricity from the rotating force of the rotating blade body shaft portion and the rotation of the rotating blade body shaft portion. It is an existing technology that enables the driving force generation device KD and the electricity generation means 7Eq with the technology 1 device that coaxially provides a transmission structure for transmitting force (for example, a buvelt and a gear). *In electricity generation technology, a research group of the National Institute for Materials Science invented a technology to create a "neodymium magnet" that is 1.5 times stronger than conventional magnets, using a material development method using AI. =Technology that leads to increased efficiency in generating electricity and downsizing of generators.
「磁気熱発電」特開平1-5379 熱磁気発電方法及びその装置。永久磁石、磁性体、および誘導起電力発生用のコイルが巻かれた継鉄とで磁気回路モジュールを構成し、前記磁気回路モジュールを複数個配置すると共にこれらの磁気回路モジュールの磁性体に温水又は冷水を供給するための配管を設け、前記配管に設けられた弁を周期的に開閉させることにより前記磁性体に温度差のサイクルを与えて発電を行う技術。 "Magnetic thermal power generation" JP-A-1-5379 Thermal magnetic power generation method and apparatus. A magnetic circuit module is composed of a permanent magnet, a magnetic body, and a yoke wound with a coil for generating an induced electromotive force. A technique for generating electricity by providing a pipe for supplying cold water and periodically opening and closing a valve provided in the pipe to give a temperature difference cycle to the magnetic body.
<放射線触媒を使った水素&酸素生成手段>
*特開平2-95440放射線触媒及びそれを用いた酸化還元方法と装置。 酸化チタン等のn型機粒子半導体12にルテニウムー106等の高放射性白金族元素14を担持させた構造の触媒で単に被処理流体を接触させるだけで、常時酸化還元反応を継続させることが出来る。該放射線触媒を用いて水を分解し酸素と水素を製造する技術。・特開2006-248821 高レベル放射性廃棄物を線源とする放射線誘起反応による水素製造法。・特開2014-172772 燃料生成システム及び発電システム。・特許第4066320 放射線触媒装置並びに水素製造方法及びこれを利用した水素製造装置。・特開2003-275602 放射線触媒装置並びに水素製造方法及びこれを利用した水素製造装置や特開平2008-183602 他多くの技術が公開されておる。
<Hydrogen & Oxygen Generation Means Using Radiation Catalyst>
* JP-A-2-95440 Radiation catalyst and redox method and apparatus using the same. A catalyst having a structure in which a highly radioactive platinum group element 14 such as ruthenium-106 is supported on an n-type machine particle semiconductor 12 such as titanium oxide, and simply bringing the fluid to be treated into contact with the catalyst allows the oxidation-reduction reaction to continue at all times. A technology that uses the radiation catalyst to decompose water and produce oxygen and hydrogen. - JP-A-2006-248821 Hydrogen production method by radiation-induced reaction using high-level radioactive waste as a radiation source. - JP-A-2014-172772 Fuel generation system and power generation system.・Patent No. 4066320 Radiation catalyst device, hydrogen production method and hydrogen production device using the same. - JP-A-2003-275602 A radiation catalyst device, a method for producing hydrogen, a hydrogen-producing device using the same, JP-A-2008-183602, and many other technologies have been disclosed.
<ブラウンガス(HOHガス)供給手段>
*特開平10-266900 ブラウンガス発生装置及びブラウンガスを用いた走行用内燃機関。プラズマを発射するマルチアークを水中に照射することにより、水がブラウンガスに変化することを応用して、該ブラウンガスを走行内燃機関の燃料として使用する技術。
・特開2004-197211 水素酸素混合ガス発生装置・特開2009-35804 大容量ブラウンガス発生装置及びその電解槽。・特開2006-225685 燃焼ガス発生装置。上記技術や公知技術をHHOガス生成手段としておる。
<ブラウンガス=HOHガスの性質>
<Brown gas (HOH gas) supply means>
* JP-A-10-266900 An internal combustion engine for running using a brown gas generator and brown gas. A technology that utilizes the transformation of water into brown gas by irradiating water with a multi-arc that emits plasma, and uses the brown gas as fuel for a running internal combustion engine.
・JP 2004-197211 A hydrogen-oxygen mixed gas generator ・JP 2009-35804 A large-capacity brown gas generator and its electrolytic cell. - JP-A-2006-225685 Combustion gas generator. The above techniques and known techniques are used as HHO gas generating means.
<Properties of Brown gas = HOH gas>
1.HOHガスの概要 従来の電気分解法では、爆発の抑制を確実にするために、これら2つのガスを分離する不浸透性の薄膜を使っています。しかしながら、この不浸透性の仕切りを必要とすることは反応処理に要する電力を増やし、今日使われている技術の大部分を非経済的にしてしまっているのです。このような電気分解で生産されるガスは効率的、経済的なエネルギー源とは言えませんでした。*1970年代初頭、ユール・ブラウン教授(Prof. Yull Brown:ブルガリア生まれ)は水素と酸素の非爆発性混合体を作り出す水の電気分解のある方法を発見し、その後この混合体はブラウンズ・ガスと呼ばれています。・彼の技術は高効率の電気分解槽を含んでおり、この槽は水を水素の体積2に対し酸素の体積1という正確な原子対原子の割合で分解し、水素ガスと酸素ガスはその割合(プラス又はマイナス5%)が厳格に維持されれば安全に混合出来ることを発見しました。この発見から水素ガスと酸素ガスは即座に、完全に、正確に正しい割合(科学専門用語では「理論混合比」)で混ぜ合わされると言う理論を確立しました。
Figure JPOXMLDOC01-appb-I000001
上記はブラウンガスの組成構造が180度で水分子の105度とは異なっておる組成図。
2.HOHガスの理論
酸素、水素混合ガス(HOHガス)を作る原材料は水と電気です。1kwhの電力で約340リッターのガスを作る事が出来ますが、実質的にはどんな量の酸素、水素混合ガスでも、電解槽を直列につないだり、小型化したり、或は大型化したりすれば、どんな体積でも製造出来ます。*水1単位から1860単位のガスが生み出され、逆も同様です。点火によって酸素、水素混合ガスは爆縮し、爆縮が起こるとその結果1859単位の真空と1単位の水が生じます。*ブラウンガス=HOHのガスの炎には注目すべき特徴が有り、機械的に酸素ガスと水素ガスを結合する際に生ずる炎とは相当に異なっています。酸素、水素混合ガス(HOHガス)によって作り出される極度の熱エネルギーのユニークな性質は、加熱されている対象物質との相互作用からきているように見えます。
1. Overview of HOH Gas Conventional electrolysis uses an impermeable membrane to separate these two gases to ensure detonation suppression. However, the need for this impermeable partition increases the power required for reaction processing, making most of the techniques in use today uneconomical. The gas produced by such electrolysis was not an efficient and economical energy source. *In the early 1970s, Prof. Yull Brown (born in Bulgaria) discovered a certain method of electrolysis of water that produced a non-explosive mixture of hydrogen and oxygen, which was then called Brown's gas. is called His technology involves a highly efficient electrolysis cell that decomposes water in a precise atom-to-atom ratio of two volumes of hydrogen to one volume of oxygen, producing hydrogen gas and oxygen gas We have found that mixing is safe if the proportions (plus or minus 5%) are strictly maintained. This discovery led to the establishment of the theory that hydrogen gas and oxygen gas are instantly, completely and in exactly the correct proportions (the "theoretical mixing ratio" in scientific parlance).
Figure JPOXMLDOC01-appb-I000001
The above is a composition diagram in which the composition structure of Brown gas is 180 degrees, which is different from the 105 degrees of water molecules.
2. Theory of HOH Gas Water and electricity are the raw materials for making oxygen and hydrogen mixed gas (HOH gas). About 340 liters of gas can be produced with 1 kwh of electricity, but practically any amount of oxygen and hydrogen mixed gas can be produced by connecting electrolytic cells in series, miniaturizing or increasing the size. can be manufactured in any volume. * 1 unit of water produces 1860 units of gas and vice versa. Ignition causes the oxygen-hydrogen mixture to implode, and the implosion results in 1859 units of vacuum and 1 unit of water. *Brown gas = HOH gas flame has a notable feature and is quite different from the flame produced when mechanically combining oxygen gas and hydrogen gas. The unique nature of the extreme thermal energy produced by oxygen-hydrogen gas mixtures (HOH gas) appears to result from their interaction with the object being heated.
・酸素環境の中で水素を燃焼させれば、理論的には摂氏2210度から2900度の間の温度に達するはずです。タングステンが蒸発(昇華)するということは、これには摂氏5900度が必要で、これは炎の温度よりはるかに高い温度です。過去の実験ではタングステン棒(直径1/8インチ)が約30秒で昇華しました。 • Combustion of hydrogen in an oxygen environment should theoretically reach temperatures between 2210 and 2900 degrees Celsius. To evaporate (sublimate) tungsten, this requires a temperature of 5900 degrees Celsius, which is much higher than the flame temperature. In past experiments, a tungsten rod (1/8 inch diameter) sublimated in about 30 seconds.
*酸素、水素混合ガスの燃焼で実証された様々な事の中には、レンガに熱で貫通孔が開いた、レンガ同士が火山で見られるのと同様な火成岩に溶融した物質で溶着した、等という事が有ります。又、セラミック・タイルが炎で接合されましたし、鋼がレンガに溶着されました。 この注目すべき性質は熱が狭い部分に集中される事です。様々な分野の独立したコンサルタントが、むき出しの手で軟鉄片(長さ6インチ)の一端を持ち、この炎で他端から1インチ或はそれ以上のところを切断してこの状況を検証しました。切断の作業は熱が金属を通じて大量に伝わってくる前に完了しました。従来の溶接装置に通じている溶接技能者達は、そのような実験にはアスベスト入りの手袋が絶対に欠かせないと考えるでしょう。
 この炎の熱の集中度が強い事は、熱伝導で流れ出た熱が溶融点近傍の強度を落とすような種類の金属を溶接する場合には、特に重要な意味を持ちます。その代表的な例としては、アルミニュームの溶接がこれに該当します。酸素、水素混合ガス(HOHガス)を使えば、熱エネルギーは狭い部分に集中し、その熱を広く分散する事なしに、その機能を果たします。鋼鈑のロール切断を含む利用の場合には、切断部は充分に滑らかで、それにはこの熱集中度が強いという特性が一部寄与しているのです。
*Among the many things demonstrated in the combustion of oxygen-hydrogen gas mixtures, the bricks were pierced by heat, the bricks were fused together with molten material in igneous rock similar to that found in volcanoes, etc. Also, ceramic tiles were flame-bonded and steel was welded to bricks. A remarkable property of this is that the heat is concentrated in a small area. Independent consultants from various disciplines have validated this situation by holding a piece of soft iron (6 inches long) at one end with their bare hands and cutting an inch or more from the other end with this flame. . The cutting operation was completed before the heat was transferred through the metal in large quantities. Welders familiar with conventional welding equipment will find asbestos gloves absolutely essential for such experiments.
This high heat concentration of the flame is especially important when welding metals where the heat lost by conduction weakens the strength near the melting point. A typical example of this is the welding of aluminum. By using an oxygen-hydrogen mixed gas (HOH gas), the heat energy is concentrated in a narrow area and does its function without distributing the heat widely. For applications involving roll cutting of steel sheets, the cut is sufficiently smooth, partly due to this high heat concentration characteristic.
*ブラウンガス炎=HOHガス炎構成
Figure JPOXMLDOC01-appb-I000002
* Brown gas flame = HOH gas flame composition
Figure JPOXMLDOC01-appb-I000002
(株)光と風の研究所 所長  堀内 道夫談  *今一番出ているのは鉄とかステンレスの溶融切断です。これは産業としてまだあまり知られていませんけれども、ある程度普及し初めて浦安の鉄工団地などで使われています。
*例えば、今、岐阜・羽島の実験では1m3のブラウンガスをつくるのに大体2kW以下の電力で実際に賄われています。そうすると、コストパフォーマンスが非常に良くなって、従来の化石燃料の約2分の1のコストこれはカロリー計算では、1のエネルギーを入れて潜在エネルギーが3のエネルギーを持ったブラウンガスが出ている。・ブラウンガスにして貯蔵し貯まったら輸送する。*一つの例でいえば、大火の時に水を掛けるとかえって爆発する。水蒸気爆発というのと、もう1つは、水を4000℃ぐらいにしますと水素と酸素が30%ぐらい分かれる。つまり分離する。熱分解だけで水は水素と酸素……高温が条件で、4000℃とか、なかなか難しいわけですが、ブラウンガスがそれに到達しているので、ブラウンガス自身が水をまた加熱して一部ブラウンガスにして燃えますから、それでボンボン燃えるということが今言われています。*貯蔵は現在の流通形態では3気圧ぐらいですが韓国のある先生は10気圧以上上げるとそのまま水になってしまうと言っています。
Mr. Michio Horiuchi, Director, Light and Wind Laboratory Co., Ltd. *The most popular application is melting cutting of iron and stainless steel. Although this is still not well known as an industry, it has spread to some extent and is being used for the first time in the Urayasu Ironworks Complex.
*For example, in the current Gifu/Hashima experiment, 1m3 of brown gas is actually covered by less than 2kW of electricity. Then, the cost performance will be very good, and the cost of conventional fossil fuel will be about half. .・It will be stored as brown gas and transported when stored. *To give an example, if you pour water on it during a big fire, it will explode instead. Steam explosion and another is that when water is heated to about 4000°C, about 30% of hydrogen and oxygen are separated. In other words, separate. Just by thermal decomposition, water is hydrogen and oxygen... The condition is a high temperature, such as 4000 degrees Celsius, which is quite difficult, but brown gas has reached that temperature, so brown gas itself heats water again and part of it is brown gas. It is said that it burns with bonbons because it burns as it burns. *In the current distribution form, the storage is about 3 atm, but a Korean teacher says that if the pressure is increased by more than 10 atm, it will turn into water.
1、地球温暖化の二酸化炭素の排出削減が出来る策を発明出来た。2、上記WO2019/130619よりより簡単な構造を発明した。3,現在流通しておるエンジンの燃料を水素と酸素としたディゼルエンジンDYかレシプロエンジンRSかロータリーエンジンREかのエンジンを主構造とした構成で二酸化炭素を排出しない策を発明出来た。
4,水素酸素ガス(ブラウンガス=HOHガス)を燃焼するエンジンを発明出来た。
5,上記エンジンの定置形態(発電所・工場・軌道車・船舶等)構造を発明した。
6,深海鉱物(亜鉛・鉛・金・銅やコバルト等のレアメタル)の簡単な掘削機を発明出来た。
 
1. I was able to invent a measure that can reduce the emission of carbon dioxide that causes global warming. 2. Invented a simpler structure than the above WO2019/130619. 3. We were able to invent a measure that does not emit carbon dioxide with a configuration that uses a diesel engine DY, a reciprocating engine RS, or a rotary engine RE as the main structure of the currently distributed engine fueled by hydrogen and oxygen.
4, I was able to invent an engine that burns hydrogen oxygen gas (Brown gas = HOH gas).
5.Invented the stationary structure of the above engine (power plant, factory, rail car, ship, etc.).
6, I was able to invent a simple excavator for deep sea minerals (rare metals such as zinc, lead, gold, copper and cobalt).
現在商品化されておるエンジンの代表として4サイクルレシプロエンジンの吸気・圧縮・爆発・排気の工程で水及び水素及び酸素(分離された酸素)を導入するタイミングで、・パターン1  (パターンの一例)上記吸気工程で水を導入し、導入した水がシリンダー内の熱を吸熱し水蒸気Aを生成し該水蒸気を圧縮工程で圧縮し、爆発工程で水素及び酸素を直噴射で導入され、点火手段で点火し水素と酸素を燃焼し更に点火(直後のタイミングで)し、水を導入する。(この作業は排気の全量が多くなると排出圧が高くなる、)該排気圧がエンジンの仕事量を多くする。*排出圧を水及び酸素・水素の導入圧とする事ができる。 At the timing of introducing water, hydrogen, and oxygen (separated oxygen) in the intake, compression, explosion, and exhaust processes of a 4-cycle reciprocating engine as a representative of the engines currently on the market, Pattern 1 (an example of a pattern) Water is introduced in the intake process, the introduced water absorbs heat in the cylinder to generate steam A, the steam is compressed in the compression process, hydrogen and oxygen are introduced by direct injection in the explosion process, and are ignited by the ignition means. Ignite, burn hydrogen and oxygen, then ignite (immediately after) and introduce water. (This work increases the exhaust pressure as the total exhaust volume increases.) The exhaust pressure increases the work of the engine. *The discharge pressure can be the introduction pressure of water and oxygen/hydrogen.
*上記パターンに於ける水素供給手段HSを水素ボンベ(例えば圧縮された水素を充填した水素ボンベ)として、酸素供給手段OSを例えば酸素ボンベ(酸素製造所で製造され充填した高圧酸素(例えば圧縮された酸素を充填した酸素ボンベ))か、空気より分離された酸素の何れかの供給手段とすれば,燃焼温度を高くして、高くした分だけシリンダー内への水の供給量を増やす事が出来る、例えば排気量2000CC4気筒のエンジンで1気筒当たり500CCであり、ここに導入する水を1CC増やすと1800CCの水蒸気を製造出来ることになる。 *The hydrogen supply means HS in the above pattern is assumed to be a hydrogen cylinder (for example, a hydrogen cylinder filled with compressed hydrogen), and the oxygen supply means OS is assumed to be, for example, an oxygen cylinder (high-pressure oxygen manufactured and filled at an oxygen factory (for example, compressed If either an oxygen cylinder filled with oxygen)) or oxygen separated from air is used as a supply means, the combustion temperature can be raised and the amount of water supplied to the cylinder can be increased by the amount raised. For example, in a 4-cylinder engine with a displacement of 2000cc, it is 500cc per cylinder.
・パターン2は吸気工程で酸素と水を導入しており、圧縮後爆発工程で水素を直噴射で導入され、点火手段で点火され、水素と酸素が燃焼し、更に点火(直後のタイミングで)後水を導入し排気工程に入る。・例示パターン3は吸気工程で水素と水を導入しており、圧縮後爆発工程で酸素を直噴射で導入され、点火手段で点火され、水素と酸素が燃焼し、燃焼したタイミングで水を導入しておる。該爆発工程で上記水素と酸素が燃焼した点火後(直後のタイミングで)水を導入する作業を省略する事も出来る。 Pattern 2 introduces oxygen and water in the intake process, introduces hydrogen by direct injection in the post-compression explosion process, ignites with the ignition means, hydrogen and oxygen burn, and ignites (immediately after) After water is introduced, an exhaust process is started.・Example pattern 3 introduces hydrogen and water in the intake process, introduces oxygen by direct injection in the post-compression explosion process, ignites with the ignition means, combusts hydrogen and oxygen, and introduces water at the timing of combustion. I'm doing It is also possible to omit the work of introducing water after the ignition of the above hydrogen and oxygen (immediately after) in the explosion process.
上記の外のパターンでは圧縮工程で水を供給することも出来るが、該水の供給を吸入工程でするのも同じ効果であり又排気工程で水を供給することも出来るが、排気工程での水の供給は、水蒸気の生成量を増大させる効果しかなく該エンジン内の熱で水蒸気を生成するのであれば吸気工程で及び爆発工程で水を導入するのが好ましい。水をエンジン内に供給出来る量は上記爆発の熱エネルギーで水を水蒸気に生成出来る量であり、更に下流に電気生成手段と水素及び酸素生成手段の水素及び酸素生成装置を設ける場合は該水素及び酸素生成装置の入口温度を(例えば水蒸気電気分解装置の場合入口温度を少なくとも該水蒸気分解装置の耐熱温度上限近くの温度)水素を生成出来る温度に確保する必要がある。
*上記サイクルで水蒸気化に係る時間が必要な場合には例えば60/rpm/minであっても良い。
In patterns other than the above, water can be supplied in the compression process, but the same effect can be obtained by supplying the water in the suction process. The supply of water only has the effect of increasing the amount of steam produced and it is preferred to introduce water in the intake stroke and in the explosion stroke if the heat in the engine produces steam. The amount of water that can be supplied into the engine is the amount that can be used to generate steam from water using the thermal energy of the explosion. It is necessary to secure the inlet temperature of the oxygen generator (for example, in the case of a steam electrolyzer, the inlet temperature is at least near the upper limit of the heat resistance temperature of the steam cracker) to a temperature at which hydrogen can be produced.
*If the above cycle requires time for steaming, the speed may be, for example, 60/rpm/min.
図1に記載のエンジンは燃焼室部内に圧縮・回転に係る機械的構造を持たないエンジンで(筒型エンジン)該エンジンの特徴は水素と酸素(分離された酸素)を燃焼室NE内で燃焼し燃焼により形成される火炎3F(火炎中心温度は略2800℃となる)と燃焼室壁の間に火炎の直射熱の伝熱をさえぎり、かつ、該熱を吸熱してくれる吸熱手段(水蒸気生成手段)の噴射水層WSを形成する形状に水を噴射する水噴射手段WJを設けており、該水噴射手段により噴射した水は火炎3Fの熱で水を水蒸気Aにする水蒸気生成手段(水の体積を概略1800倍に膨張させた水蒸気で水蒸気爆発の形態)とするとともに、燃焼室NE内の熱を吸熱しており、水素と酸素の燃焼で生成される水蒸気Bと水蒸気Aを排気(水蒸気)として排出しておる。 上記水噴射手段WJの水噴射ノズルから噴射された噴射水層WSの噴射ノズルから噴射され形成された噴射水層の形態例を図示した図であり、WJ1及びWJ2は噴射水層が火炎3Fを囲む形態で燃焼室壁2Uへの直射熱を遮る構成で、WJ2は噴射ノズル部を凹部と凸部との間に形成しておる溝部を水噴射ノズルとした構成。WJ3は噴射水層中に水柱形状も混在しておる形態を表した水噴射手段WJ部の図。
 
The engine shown in FIG. 1 does not have a mechanical structure related to compression and rotation in the combustion chamber (cylindrical engine). The feature of this engine is that hydrogen and oxygen (separated oxygen) are burned in the combustion chamber NE. A heat absorbing means (steam generation Water injection means WJ for injecting water in a shape forming the injection water layer WS of the means) is provided, and the water injected by the water injection means converts water into steam A by the heat of the flame 3F. The volume of the steam is expanded to about 1800 times to form a steam explosion), and the heat in the combustion chamber NE is absorbed, and the steam B and steam A generated by the combustion of hydrogen and oxygen are exhausted ( water vapor). FIG. 10 is a view showing an example of the form of the jetted water layer formed by jetting from the jetting nozzle of the jetting water layer WS jetted from the water jetting means WJ. The configuration is such that the direct heat to the combustion chamber wall 2U is blocked by the enclosing configuration, and WJ2 is configured such that the groove formed between the concave portion and the convex portion is a water injection nozzle. WJ3 is a view of the water injection means WJ showing a configuration in which the water column shape is mixed in the injection water layer.
 図2に記載のエンジンは水素・酸素を燃焼するエンジンであって、電気分解系酸素・水素ガス生成手段EHか、光触媒系水素・酸素ガス生成装置PHか放射線触媒使用の水素・酸素生成装置RHかの何れかの生成装置で生成した水素・酸素をガスタンクを有する水素供給手段HS及び酸素供給手段OSに供給しており、水素を燃焼ノズルに供給する、水素供給手段HSと、酸素を燃焼ノズルに供給する、酸素供給手段OSと、供給された水素と酸素に点火する点火手段と、点火により水素と酸素を燃焼して火炎3Fを生成し、
該火炎3Fとエンジンの燃焼室外殻3Uとの間に水を噴射する該水を供給する、水供給手段WSと、供給された該水を燃焼室外殻3Uとの間に水を噴射する水噴射手段WJを設けた構造で、噴射した水は、水素と酸素の燃焼熱を吸熱して水蒸気Abを生成する水蒸気生成手段としており、水素と酸素の燃焼により生成される水蒸気Bとともに排気として直接水中か大気中に排出しておる事を特徴とする、水素・酸素を燃焼するエンジン。
The engine shown in FIG. 2 is an engine that burns hydrogen/oxygen, and is an electrolysis oxygen/hydrogen gas generating means EH, a photocatalytic hydrogen/oxygen gas generating device PH, or a hydrogen/oxygen generating device RH using a radiation catalyst. The hydrogen/oxygen generated by any one of the generators is supplied to a hydrogen supply means HS having a gas tank and an oxygen supply means OS, and the hydrogen supply means HS for supplying hydrogen to the combustion nozzle and the oxygen supply to the combustion nozzle. an oxygen supply means OS, an ignition means for igniting the supplied hydrogen and oxygen, and an ignition means for burning the hydrogen and oxygen to generate a flame 3F,
water supply means WS for supplying water for injecting water between the flame 3F and the combustion chamber outer shell 3U of the engine; and water injection for injecting water between the supplied water and the combustion chamber outer shell 3U. In the structure provided with the means WJ, the injected water is a steam generating means for absorbing the combustion heat of hydrogen and oxygen to generate steam Ab, and is directly underwater as exhaust together with the steam B generated by the combustion of hydrogen and oxygen. An engine that burns hydrogen and oxygen, characterized by discharging into the atmosphere.
 図3に記載のエンジンはHOHガスを燃焼するエンジンであって、該エンジンは、ブラウンガス(HOHガス)供給手段から供給されたHOHガスを燃焼ノズルBNと、供給されたHOHガスに点火する点火手段Bpと、点火によりHOHガス燃焼して火炎3Fを生成しており、該火炎3Fに水を噴射する水を供給する水供給手段WSと、供給された該水を火炎3Fに噴射する水路WJRと、該水路から水を火炎に噴射して反応火炎流BFaを生成し、火炎3Fの火種を保護する耐熱構造部 (火種保護構造部)とを備え、(該火種構造部は火炎3Fが水の噴射及び水蒸気の噴出で大気又は水中で起こりうる渦流で火炎3Fが消えることも想定される対策とした構成であり、必要が無い場合は省略可の構成である。)火炎3Fに水を噴射して形成される反応火炎BFaを直接水中もしくは空気中に排出しておる事を特徴とする。*3図の(A)はエンジンの断面の概略図で該エンジン搭載機器に (一例として船体後尾部に) 取り付け、該エンジンで生成された反応火炎BFaを水中もしくは大気中に噴射する構成にしたもので、この構造のエンジンは船舶・飛翔体(飛行機・ロケット・空飛ぶリムジンバス等)・軌道車(新幹線等)搭載とした実施例である。 (B)はAのR矢視でエンジン取り付け状態R矢視方向図である。 The engine shown in FIG. 3 is an engine that burns HOH gas, and the engine includes an ignition nozzle BN that ignites the HOH gas supplied from a Brown gas (HOH gas) supply means and a combustion nozzle BN that ignites the supplied HOH gas. Means Bp, HOH gas is burned by ignition to generate flame 3F, water supply means WS for supplying water for injecting water into flame 3F, and water passage WJR for injecting the supplied water into flame 3F. and a heat-resistant structure (flame protection structure) that injects water from the water channel into the flame to generate a reactive flame flow BFa and protects the flame of the flame 3F, It is a configuration that assumes that the flame 3F will disappear due to the vortex that can occur in the atmosphere or water due to the injection of water vapor and the ejection of water vapor, and it is a configuration that can be omitted if it is not necessary.) Water is injected into the flame 3F It is characterized in that the reaction flame BFa formed by this is discharged directly into water or air. * Figure 3 (A) is a schematic diagram of the cross section of the engine, which is attached to the equipment mounted on the engine (as an example, at the aft part of the hull), and configured to inject the reaction flame BFa generated by the engine into the water or the atmosphere. The engine of this structure is an embodiment that is mounted on ships, flying objects (airplanes, rockets, flying limousine buses, etc.), and railway vehicles (bullet trains, etc.). (B) is a view in the R arrow direction of A in which the engine is installed.
4図は、3図のHOHガスエンジンBEに燃焼室BNを設け、燃焼により生成された反応火炎流BFaをまとめて噴射排気BST(主に水蒸気その他水素・酸素ガス)として噴出する排気噴出口BEJを設け、噴出して、噴出による力を推進力(例えば回転翼体の回転力)としておる構成。 上記燃焼室内外壁BI・BO間に水を通水する通水路WRを設け、水を導入し燃焼室内壁BIに燃焼室内に水を噴射する複数の水噴射ノズルWJを設けて該通水路から燃焼室内に噴射して、噴射した水は燃焼室内の熱を吸熱して水蒸気Aを生成し上記反応火炎流BFaと共に排気道BEXを通って排気噴射口から噴射排気として排出しておる事を表した図。 図D1は火炎3Fが生成されておる図、D2は火炎に噴射する水噴射ノズルから水を噴射し噴射した水は火炎中で交叉する形態に噴射されておる図。ブラウンガスの火炎3Fの中心部(段落[0018]*ブラウンガス炎=HOHガス炎構成を参照)が高温部であるので、高温部に水を噴射しておる事を表した図。図D3は火炎に噴射した水で反応火炎流BFaを形成しておる図。 Fig. 4 shows a combustion chamber BN provided in the HOH gas engine BE shown in Fig. 3, and an exhaust outlet BEJ for ejecting a reaction flame flow BFa generated by combustion as an injection exhaust BST (mainly water vapor and other hydrogen and oxygen gases). is provided, and the force generated by the ejection is used as the propulsion force (for example, the rotational force of the rotor). A water passage WR for passing water is provided between the outer walls BI and BO of the combustion chamber, and a plurality of water injection nozzles WJ for introducing water and injecting water into the combustion chamber are provided to the combustion chamber wall BI, and combustion is performed from the water passage. Injected into the chamber, the injected water absorbs the heat in the combustion chamber to generate water vapor A, which along with the reaction flame flow BFa passes through the exhaust path BEX and is discharged as injection exhaust from the exhaust injection port. figure. Figure D1 is a diagram showing flame 3F being generated, and D2 is a diagram showing water injected from a water injection nozzle that injects into the flame, and the injected water intersects in the flame. A diagram showing that the center of the brown gas flame 3F (see paragraph [0018] * Brown gas flame = HOH gas flame configuration) is a high temperature part, so water is injected to the high temperature part. FIG. D3 is a diagram showing reaction flame flow BFa formed by water injected into the flame.
図5は図3のHOHガスを燃焼するエンジンを内槽IE水中に設けた構成であって、
水を張った内槽IE一方端にエンジンBEWを設け、内槽他端に排気口を設けた構成の内槽にしており、該内槽IE外側に水を張った外槽OEを設け上記内槽他端側から供給された水と水供給手段WOSから供給された水と共にを外層OE内を内槽IE一方端側に送り、火炎3Fの火種を保護する耐熱構造部 (火種保護構造部)外側から反応火炎流BFaに吸い込まれる様に水を供給する、水循環ループWEXを構成する様に設けており、
上記エンジンBEWにHOHガス生成装置の電気分解系生成装置BPか光触媒系生成装置BHか放射線触媒使用のHOHガス生成装置UBPかの何れか1以上で生成されたHOHガスをHOHガスタンクBGTを有するHOHガス供給手段BSから燃焼ノズルBNに供給して、供給されたHOHガスに点火する点火手段Bpと、点火によりHOHガスを燃焼して火炎3Fを生成しており、該火炎3Fに水を噴射する水を供給する水供給手段WSと、
供給された該水を火炎3Fに噴射する水噴射手段WJRと、火炎3Fの火種を保護する耐熱構造部 (火種保護構造部)とを備え、該火種構造部は火炎3Fが水の噴射及び水蒸気の噴出で大気又は水中で起こりうる渦流で火炎3Fが消えることも想定される対策とした構成であり、必要が無い場合は省略可の構成である。
火炎3Fに水を噴射して形成される反応火炎BBFを直接内槽水中に噴射して反応火炎水流BFaを形成し水を張った内槽中の水を排出する排水口に集水して排水口から排出しており、排出された噴射排水を導入して駆動力を生成する駆動力生成装置KDか発電装置7Eqかの何れか一方か両方かで駆動力及び電気7Eを生成して、該装置を貫流した噴射排水からHOHガス及び水蒸気を分離する分離装置BSTに導入して、
A、分離した水蒸気の供給を受け、1、放射線触媒使用のHOHガス生成装置UBPでHOHガスを生成して、2,熱磁気発電装置8Eqで電気8Eを生成して、生成した電気8Eを更に受けてHOHガス生成装置BpでHOHガスを生成して、3,上記発電装置7Eqを貫流して得られた電気7Eを更に受けてHOHガス生成装置BpでHOHガスを生成して、
B、太陽光エネルギーを受けた光触媒系酸素水素ガス(又はHOHガス)を生成装置する生成装置BhでHOHガスを生成して、C、電気分解系HOHガス生成装置BpでHOHガスを生成して、上記A、B、Cで生成されたHOHガスをHOHガス供給手段BS(ガスタンクを有する)とした構成を表したフロー図で、上記HOHガス分離装置BBstで分離した残りの水蒸気を外槽OEの水供給手段WOS経由で外槽OEに供給し,供給された水は内槽で反応火炎流BFaに吸い込まれる水とした水循環ループWEXを構成した定置形態HOHガス燃焼エンジンBEで駆動力か電気を生成して、電気7E・8Eと駆動力Tを出力とする構成である。*上記外層OEの水不足分の供給手段WOSを設けておる。
FIG. 5 shows a configuration in which the engine for burning HOH gas in FIG. 3 is provided in the inner tank IE water,
One end of the inner tank IE filled with water is provided with an engine BEW, and the other end of the inner tank is provided with an exhaust port. Water supplied from the other end of the tank and water supplied from the water supply means WOS are sent through the outer layer OE to the one end of the inner tank IE to protect the fire source of the flame 3F (fire protection structure). A water circulation loop WEX is provided to supply water so as to be sucked into the reaction flame flow BFa from the outside,
The HOH having an HOH gas tank BGT is supplied to the engine BEW by any one of the HOH gas generator BP, the photocatalytic generator BH, and the HOH gas generator UBP using a radiation catalyst. The HOH gas is supplied from the gas supply means BS to the combustion nozzle BN, and the ignition means Bp ignites the supplied HOH gas. water supply means WS for supplying water;
Water injection means WJR for injecting the supplied water to the flame 3F, and a heat-resistant structure (a fire protection structure) for protecting the fire of the flame 3F. This is a configuration as a countermeasure against the possibility that the flame 3F is extinguished by a vortex that can occur in the air or water due to the ejection of the flame, and can be omitted if it is not necessary.
The reaction flame BBF formed by injecting water to the flame 3F is directly injected into the water in the inner tank to form the reaction flame water flow BFa, and the water in the water-filled inner tank is collected and drained at the drain outlet. The driving force and electricity 7E are generated by either or both of the driving force generating device KD that introduces the ejected wastewater and generates the driving force, or the power generating device 7Eq. Introduced into a separation device BST that separates HOH gas and water vapor from the jetted wastewater flowing through the device,
A. Separated water vapor is supplied, 1. HOH gas is generated by the HOH gas generator UBP using radiation catalyst, 2. Electricity 8E is generated by the thermomagnetic generator 8Eq, and the generated electricity 8E is further generated. 3. The electricity 7E obtained by flowing through the power generator 7Eq is further received and HOH gas is generated by the HOH gas generator Bp,
B, HOH gas is generated by a generator Bh that generates a photocatalytic oxygen hydrogen gas (or HOH gas) that receives solar energy, and HOH gas is generated by an electrolysis HOH gas generator Bp. , B, and C above are HOH gas supply means BS (having a gas tank). The supplied water is supplied to the outer tank OE via the water supply means WOS, and the supplied water is the water sucked into the reaction flame flow BFa in the inner tank. is generated, and electricity 7E and 8E and driving force T are output. * A supply means WOS for the shortage of water in the outer layer OE is provided.
HOHガスを燃焼するエンジンBEに供給する水を海水としたエンジンBWSで、該エンジンに塩取り出し手段WSを設けた構成で海水を水蒸気化すると塩が分離される。この分離された塩を取り出す手段(例えばスチームトラップ形態・予分離室を設ける)を設けて塩を分離除去した水蒸気Cは真水であり、一巡の仕事を終えた水蒸気を冷却(自然冷却でも良い)する。・・・・飲料水になる。(海水の真水化手段になる。) In an engine BWS using seawater as water to be supplied to an engine BE that burns HOH gas, salt is separated by vaporizing seawater in a configuration in which the engine is provided with a salt extracting means WS. The water vapor C obtained by separating and removing the salt by providing means for extracting the separated salt (for example, in the form of a steam trap, providing a pre-separation chamber) is fresh water. do.・・・It becomes drinking water. (It becomes a means of turning seawater into fresh water.)
図6は図3に記載のHOHガス燃焼エンジンBEWを多胴船体水中翼船FFSに複数設けた構成を表した図であって、該エンジンを前進用・後退用・方向変更用と複数設け、船の推進により生ずる水の抵抗力で電気を生成する水の抵抗力発電手段6Eを設けて発電し、発電した電気で燃料のHOHガスを生成する構成とした概略図。図7は図6のB-B断面図でエンジンの配置及び水の抵抗力発電手段の設置例図。 FIG. 6 is a diagram showing a configuration in which a plurality of HOH gas combustion engines BEW shown in FIG. Schematic diagram of a configuration for generating electricity by providing a water resistance power generating means 6E for generating electricity by water resistance generated by propulsion of a ship, and generating HOH gas as a fuel from the generated electricity. FIG. 7 is a cross-sectional view taken along line B-B of FIG. 6, showing an example of the arrangement of the engine and the installation of water resistance power generation means.
図8は図3に記載のHOHガス燃焼エンジンを海底資源を掘削する掘削部BRGとした構成で、例えば放射線触媒使用のHOHガス生成装置とHOHガスタンクと掘削部BRG設けた無人の掘削機に操作制御を海上からの有線通信で行い該掘削部BRGを一間隔飛ばした状態に複数前部に設け後部に前部で飛ばした部分をカバーするように設け岩盤に張り付く状態のコバルトなどのレアメタルを岩盤から剥ぎ取る作業をフルタイムで行い一定面積の剥ぎ取りが終わった後ポンプで海水と共に船に吸いあげる・・作業で上記HOHガスの供給を海上からとする事でも対応出来る事を表して居る。*該掘削部の構成を火炎噴射とした例図であるが、エネルギー源のHOHガスを自給するか海上から供給する構成であるので機械的掘削(例えば、はつりや・ドリル・カッター・ショベル等々)部とすることも出来る。 FIG. 8 shows a configuration in which the HOH gas combustion engine shown in FIG. 3 is used as an excavation unit BRG for excavating submarine resources. Control is performed by wired communication from the sea, and a plurality of excavation parts BRG are provided in the front part in a state of being skipped by one interval, and rare metals such as cobalt sticking to the bedrock are placed in the rear part so as to cover the part skipped in the front part. After stripping a certain area, the seawater is sucked into the ship with a pump.It is also possible to supply the above HOH gas from the sea. *Although this is an example diagram in which the construction of the excavation section is a flame injection, the HOH gas as an energy source is self-sufficient or is supplied from the sea, so mechanical excavation (for example, a chipper, a drill, a cutter, a shovel, etc.) It can also be made into a part.
図9は・ボールミル容器で水素ガス生成。
・岐阜薬科大学薬品化学研究室は、ステンレス製のボールミル容器にステンレスのボールと水を入れて高速で回転すると、水が分解して水素ガスが定量的に生成する(使った水がすべて水素ガスに変換する)事を発見しました。なを、ボールミルとは家庭でなじみのある「コーヒーミル」と同時に、「物体を細かく粉砕する装置」で、金属やセラミック製のボールとともに回転、あるいは振動させて使用します(フリッチュ・ジャパン株式会社で製造販売)。「ACS Sustainable Chem.Eng.「2015,3,683-689」と「Chem Sue Chem 2015,8,3773-3776」に記載されておる技術
 ステンレスを構成している金属(ステンレスは鉄、クロム、ニッケルを主成分とする合金)によって反応が加速されると同時に、ボールミルの回転で生じるステンレス同士の衝突、摩擦などの機械的エネルギーにより効率よく水素が生成する。
この際水素の発生に伴って複製する酸素はステンレスを構成する金属が酸素と反応して金属酸化物(主として酸化鉄)に変換されることで酸素が除去されるため酸素ガスは全く検出されない事を表した図。水素供給手段の1例。
Fig. 9 shows hydrogen gas generation in a ball mill vessel.
・Gifu Pharmaceutical University's Pharmaceutical Chemistry Laboratory found that when stainless steel balls and water are placed in a stainless steel ball mill container and rotated at high speed, the water decomposes and hydrogen gas is generated quantitatively (all the water used is hydrogen gas I found a thing that converts to . A ball mill is a "coffee mill" that is familiar at home, and at the same time, it is a "device that finely grinds objects", and is used by rotating or vibrating together with metal or ceramic balls (Fritsch Japan Co., Ltd.) (manufactured and sold in Japan). Technology described in "ACS Sustainable Chem. Eng. 2015, 3, 683-689" and "Chem Sue Chem 2015, 8, 3773-3776" At the same time as the reaction is accelerated by the component alloy), hydrogen is efficiently generated by mechanical energy such as collision and friction between stainless steels generated by the rotation of the ball mill.
At this time, the oxygen that replicates with the generation of hydrogen is removed by the metals that make up the stainless steel reacting with oxygen and being converted into metal oxides (mainly iron oxides), so oxygen gas is not detected at all. A diagram representing An example of hydrogen supply means.
・図10は信州大学先鋭領域融合研究群環境・エネルギー材料科学研究所が発表した酸素分子より小さなナノメートルサイズの窓「ナノ窓」と言う新概念を発表。この「ナノ窓」があるグラフェンは、大気からの酸素の分離速度を現状より2000倍に出来ることをつきとめた。炭素原子一層からなるグラフェンに酸素分子程度の大きさの「ナノ窓」をつけると、酸素・窒素・アルゴン等を選択的且つ、極めて迅速に分離できることを理論的に予測、「ナノ窓」には酸素と水素原子を含む窓枠があり、その窓枠が競争的に働いて酸素分子を優先的に透過・分離出来る機構を明らかにした。ナノ窓で窒素分子が透過し酸素分子を分離する「ナノ窓」の構造のイメージ図である。酸素の供給手段の1例 ・Fig. 10 presents a new concept called "nano-window," a nanometer-sized window smaller than an oxygen molecule, announced by the Institute of Materials Science for Environment and Energy, Interdisciplinary Research Group, Shinshu University. Graphene with this "nano window" has been found to be able to separate oxygen from the atmosphere 2,000 times faster than the current rate. It is theoretically predicted that oxygen, nitrogen, argon, etc. can be selectively and extremely rapidly separated by attaching a "nano window" of the size of an oxygen molecule to graphene, which consists of a single layer of carbon atoms. There is a window frame containing oxygen and hydrogen atoms, and the mechanism that the window frame works competitively to preferentially permeate and separate oxygen molecules was clarified. FIG. 2 is an image diagram of the structure of a “nano window” through which nitrogen molecules pass and separate oxygen molecules. An example of oxygen supply means
・図11はエネルギー高効率化を研究テーマに掲げる科学技術振興機構(JST)と東北大学が共同で高価な貴金属を使わない水素の製造方法を開発しており、該水素の製造方法はグラフェンを3次元の構造にして、更に炭素原子の一部を窒素原子と硫黄原子に置き換えた「3次元ナノ多孔質グラフェン」を電極に利用する。 窒素原子や硫黄原子によってグラフェンが不均質な状態になると、水が反応して電気分解によって水素を発生させる、
 3次元で中空状の多孔質の構造をとることによって、僅か1グラムのグラフェンでも表面積が800平方メートルにもなる。従来の白金などを使った電極と比べ500倍程度の表面積に拡大出来、反応を広い面積で起こすことが可能にする。*図は「三次元ナノ多孔質グラフェン」の模型。中空状のチューブの外側と内側で水から水素を生成するイメージ図である。水素供給手段の1例。*電気分解や燃料電池の電極に使用出来る技術。
・Fig. 11 shows that the Japan Science and Technology Agency (JST), whose research theme is energy efficiency, and Tohoku University are jointly developing a hydrogen production method that does not use expensive precious metals, and the hydrogen production method uses graphene. ``Three-dimensional nanoporous graphene,'' which has a three-dimensional structure and further replaces some of the carbon atoms with nitrogen and sulfur atoms, is used for the electrodes. When graphene becomes inhomogeneous due to nitrogen and sulfur atoms, water reacts and generates hydrogen by electrolysis.
By adopting a three-dimensional, hollow, porous structure, even 1 gram of graphene has a surface area of 800 square meters. The surface area can be expanded to about 500 times that of conventional electrodes using platinum or the like, enabling reactions to occur over a wide area. * The figure is a model of "three-dimensional nanoporous graphene". FIG. 4 is an image diagram of generating hydrogen from water on the outside and inside of a hollow tube. An example of hydrogen supply means. *Technology that can be used for electrodes in electrolysis and fuel cells.
・図12(A)は電力技術研究所が開発した空気から酸素を分離する、高性能酸素分離膜の分離イメージ図であって、該分離膜は酸素イオンと同時に電子も伝導する混合伝導体であって、膜の空気側で酸素分子が電子を受け取りイオン化→イオン電導により酸素イオンが膜の反対側に移動→酸素透過側で電子を放出し、再び酸素分子に戻る・・・空気中から高純度の酸素を得る事が出来る。(B)は27CC/MIN/Cm2の酸素分離膜の大きさを表した図。酸素供給手段の1例。 ・ Fig. 12 (A) is a separation image diagram of a high-performance oxygen separation membrane that separates oxygen from air developed by the Electric Power Technology Laboratory. The separation membrane is a mixed conductor that conducts electrons as well as oxygen ions. Oxygen molecules receive electrons on the air side of the membrane and are ionized → Oxygen ions move to the opposite side of the membrane due to ionic conduction → Electrons are released on the oxygen permeation side and return to oxygen molecules again ... High purity from air of oxygen can be obtained. (B) is a diagram showing the size of the oxygen separation membrane of 27 CC/MIN/Cm2. An example of oxygen supply means.
水素と酸素を導入し水を供給する筒型エンジン図。A diagram of a cylindrical engine that introduces hydrogen and oxygen and supplies water. 燃焼室を持たない水素・酸素を燃焼し水を導入するエンジンに供給する酸素・水素生成装置のフロー図。A flow diagram of an oxygen/hydrogen generator that burns hydrogen/oxygen and supplies water to an engine that does not have a combustion chamber and introduces water. HOHガス燃焼エンジン直噴型エンジン図。HOH gas combustion engine direct injection type engine diagram. 3図のエンジンに燃焼室を設けたHOHガスエンジンBEの概略図。Schematic of the HOH gas engine BE which provided the combustion chamber in the engine of FIG. 3. FIG. 水を張った内槽の内槽右端部に3図のエンジンを設けた内槽と水循環ループを外層に設け動力・電気を出力としておる定置形態ブラウンガス燃焼エンジンB7E概略図。Schematic diagram of a stationary Brown gas combustion engine B7E in which a water circulation loop is provided in the outer layer and a water circulation loop is provided at the right end of the inner tank filled with water to generate power and electricity. 2図のエンジンを多胴船体水中翼船WFSに設けた概略図。Fig. 2 is a schematic diagram of the engine of Fig. 2 provided in a multihull hydrofoil ship WFS; 6図のB-B断面図。BB sectional drawing of FIG. 3図のエンジンを海底資源掘削機とした概略図。The schematic which made the engine of FIG. 3 into the submarine resource excavator. ボールミルを利用して水から水素を生成するイメージ図。An image diagram of generating hydrogen from water using a ball mill. 空気から酸素を分離するナノ窓のイメージ図。An image of a nano window that separates oxygen from air. 三次元ナノ多孔質グラフェンで水から水素を生成するイメージ図。Conceptual diagram of generating hydrogen from water using three-dimensional nanoporous graphene. 空気から酸素を分離する分離膜のイメージ図。An image diagram of a separation membrane that separates oxygen from air.

Claims (9)

  1. 水素を燃焼する内燃機関の吸気か、圧縮か、爆発か,排気かの何れかのステップで水素か酸素か水かの何れか1以上を供給する、供給順を、吸気ステップで水を、爆発ステップで水素と酸素と水を供給する、水素供給手段HSと酸素供給手段OSと、水供給手段WSを設けて水素と酸素と水を供給し、上記吸気ステップで供給された水は燃焼室内の熱を吸熱し体積を膨張させた水蒸気Aaを生成し、更に爆発ステップで供給された水は水素と酸素の燃焼熱を吸熱して水蒸気Abを生成し燃焼室内の熱を吸熱して生成された水蒸気Aaとを合わせて水蒸気Aとした水蒸気生成手段としており、
    上記内燃機関に導入された酸素と水素に点火する点火手段を設けて燃焼し、酸素と水素の燃焼で生成した水蒸気Bと前記水蒸気Aを排気として排出しておる事を特徴とする水素・酸素を燃焼するエンジン。 
    Supply one or more of hydrogen, oxygen, or water in any step of intake, compression, explosion, or exhaust of an internal combustion engine burning hydrogen, supply order, water in intake step, explosion Hydrogen supply means HS, oxygen supply means OS, and water supply means WS are provided for supplying hydrogen, oxygen, and water in the step to supply hydrogen, oxygen, and water. Water vapor Aa is generated by absorbing heat and expanding its volume, and the water supplied in the explosion step absorbs the combustion heat of hydrogen and oxygen to generate water vapor Ab, which absorbs the heat in the combustion chamber. The water vapor generating means is combined with water vapor Aa to obtain water vapor A,
    An ignition means for igniting the oxygen and hydrogen introduced into the internal combustion engine is provided for combustion, and the steam B generated by the combustion of oxygen and hydrogen and the steam A are discharged as exhaust gas. engine that burns
  2. 水素と酸素を燃焼し水を供給するエンジンの構成であって、
    水素を燃焼ノズルに供給する、水素供給手段HSと、酸素を燃焼ノズルに供給する、酸素供給手段OSと、供給された水素と酸素に点火する点火手段と、点火により水素と酸素を燃焼して火炎3Fを生成し、該火炎3Fとエンジンの燃焼室壁3Uとの間に水を噴射する該水を供給する、水供給手段WSと、供給された該水を噴射する水噴射手段WJを設けた構造で、噴射した水は、水素と酸素の燃焼熱を吸熱して水蒸気Abを生成する水蒸気生成手段としており、水素と酸素の燃焼により生成される水蒸気Bとともに排気として排気口5Sから排出する構成にしておる事を特徴とする、水素と酸素を燃焼するエンジン。
    A configuration of an engine that burns hydrogen and oxygen and supplies water,
    hydrogen supply means HS for supplying hydrogen to the combustion nozzle; oxygen supply means OS for supplying oxygen to the combustion nozzle; ignition means for igniting the supplied hydrogen and oxygen; A water supply means WS for generating a flame 3F and supplying water for injecting water between the flame 3F and the combustion chamber wall 3U of the engine, and a water injection means WJ for injecting the supplied water are provided. In this structure, the injected water serves as steam generating means for absorbing the combustion heat of hydrogen and oxygen to generate steam Ab, and is discharged from the exhaust port 5S as exhaust together with the steam B generated by the combustion of hydrogen and oxygen. An engine that burns hydrogen and oxygen, characterized by:
  3. ブラウンガスを燃焼するエンジンであって、
    該エンジンはブラウンガスを燃焼ノズルBNに供給するブラウンガス供給手段BSと、供給されたブラウンガスに点火する点火手段Bpと、点火手段Bpによりブラウンガスを燃焼して火炎3Fを生成しており、該火炎3Fに水を噴射する水を供給する水供給手段WSと、供給された該水を火炎BFに噴射する水路WJRと、該水路から水を火炎に噴射して反応火炎流BFaを生成しており、上記火炎3Fの火種を保護する耐熱構造部を備え、上記反応火炎流BFaを直接水中もしくは空気中に排出しておる事を特徴とする水素・酸素を燃焼するエンジン。
    An engine burning brown gas,
    The engine includes brown gas supply means BS for supplying brown gas to combustion nozzles BN, ignition means Bp for igniting the supplied brown gas, and combustion of brown gas by the ignition means Bp to generate flame 3F, A water supply means WS for supplying water for injecting water to the flame 3F, a water passage WJR for injecting the supplied water to the flame BF, and a reaction flame flow BFa by injecting water from the water passage to the flame. and a heat-resistant structure for protecting the source of the flame 3F, and discharging the reaction flame flow BFa directly into water or air.
  4. 上記請求項3記載のエンジンに燃焼室BNを設け、燃焼により生成された反応火炎流BFaをまとめて噴射排気BSTとして噴出する排気噴出口BEJを設け、
    上記燃焼室内外壁BI・BO間に水を通水する通水路WRを設け、水を導入し燃焼室内壁BIから燃焼室内に水を噴射する複数の水噴射ノズルWJを設けて該通水路から燃焼室内に噴射して、噴射した水は燃焼室内の熱を吸熱して水蒸気Aを生成し上記反応火炎流BFaと共に排気道BEXを通って排気噴射口から噴射排気として排出しておる事を特徴とする水素・酸素を燃焼するエンジン。
    The engine according to claim 3 is provided with a combustion chamber BN, and an exhaust outlet BEJ for collectively ejecting the reaction flame flow BFa generated by combustion as an injection exhaust BST,
    A water passage WR for passing water is provided between the outer walls BI and BO of the combustion chamber, and a plurality of water injection nozzles WJ for introducing water and injecting water from the combustion chamber wall BI into the combustion chamber are provided, and combustion is performed from the water passage. It is characterized in that the injected water absorbs the heat in the combustion chamber to generate water vapor A, which is discharged as injection exhaust from the exhaust outlet through the exhaust pipe BEX together with the reaction flame flow BFa. An engine that burns hydrogen and oxygen.
  5. 上記請求項3に記載のブラウンガスを燃焼するエンジンの定置形態エンジンで、
    HOHガス生成装置の電気分解系生成装置BPか光触媒系生成装置BHか放射線触媒使用のブラウンガス生成装置UBPで生成されたブラウンガスかの何れかのガスをブラウンガスタンクBGT経由で燃焼ノズルBNに供給して、供給されたブラウンガスに点火する点火手段Bpと、 点火によりブラウンガスを燃焼して火炎3Fを生成しており、該火炎3Fに水を噴射する水を供給する水供給手段WSと、供給された該水を火炎3Fに噴射する水噴射手段WJRと、火炎3Fの火種を保護する耐熱構造部を備え、
    火炎3Fに水を噴射して形成される反応火炎BBFを直接内槽水中に噴射して反応火炎水流BFaを形成し水を張った内槽中の水を排出する排水口に集水して排水口から排出しており、排出された噴射排水を導入して駆動力を生成する駆動力生成装置KDか発電する発電装置7Eqかの何れか一方か両方かで駆動力及び電気を生成して、該装置を貫流した噴射排水からブラウンガス及び水蒸気を分離する分離装置BBstに導入して,分離したブラウンガスをガスタンクBGTを含むブラウンガス供給手段に導入しており、水蒸気を上記放射線触媒使用のブラウンガス生成装置UBPか磁気熱発電装置8Eで生成した電気でブラウンガスを生成するブラウンガス生成装置Bpかに供給する水蒸気とするか又は水供給手段をWOSに合流させるかの何れかにした構成で駆動力と電気の一方か両方かを出力として取り出しておる事を特徴とするブラウンガスを燃焼するエンジン。
    A stationary configuration engine of an engine burning brown gas according to claim 3,
    Either the brown gas generated by the electrolysis system generator BP of the HOH gas generator, the photocatalyst system generator BH, or the brown gas generator UBP using the radiation catalyst is supplied to the combustion nozzle BN via the brown gas tank BGT. igniting means Bp for igniting the supplied brown gas; and water supply means WS for supplying water for injecting water into the flame 3F, which burns the brown gas by ignition to generate the flame 3F; Equipped with a water injection means WJR for injecting the supplied water to the flame 3F, and a heat-resistant structure for protecting the flame 3F,
    The reaction flame BBF formed by injecting water to the flame 3F is directly injected into the water in the inner tank to form the reaction flame water flow BFa, and the water in the water-filled inner tank is collected and drained at the drain outlet. The driving force and electricity are generated by either or both of the driving force generation device KD that introduces the discharged jetted water and generates the driving force or the power generation device 7Eq that generates electricity, A separation device BBst for separating Brown gas and steam from jetted wastewater flowing through the device is introduced into a Brown gas supply means including a gas tank BGT, and the steam is introduced into a brown gas supply means including a gas tank BGT. Either the gas generator UBP or the electricity generated by the magnetothermal power generator 8E is used to supply steam to the Brown gas generator Bp that generates Brown gas, or the water supply means is merged with the WOS. An engine that burns brown gas and is characterized by taking out one or both of driving force and electricity as output.
  6. 請求項1から請求項2及び請求項4に記載のエンジンの何れかのエンジンで生成した水蒸気を導入し、該エンジン搭載機器の駆動力生成装置KDか電気を生成する電気生成装置EDか、水素・酸素を生成する水素・酸素生成手段かブラウンガスを生成するブラウンガス生成手段かの何れか1以上を設けておることを特徴とする水素・酸素を燃焼するエンジン。 Steam generated by any one of the engines according to claims 1 to 2 and claim 4 is introduced, and the driving force generation device KD for the engine-mounted equipment, the electricity generation device ED for generating electricity, or hydrogen - An engine that burns hydrogen and oxygen, characterized by being provided with one or more of hydrogen/oxygen generating means for generating oxygen and brown gas generating means for generating brown gas.
  7. ブラウンガスを燃焼するエンジンを移動体に搭載しており、該移動体の推進により発生する抵抗力を発電動力としておることを特徴とする水素・酸素を燃焼するエンジン。 1. An engine that burns hydrogen and oxygen, characterized in that an engine that burns Brown's gas is mounted on a moving body, and resistance generated by propulsion of the moving body is used as power generation power.
  8. ブラウンガスを燃焼するエンジンにブラウンガス生成手段及び電気生成手段を備えたエンジンを移動体に搭載しており、該エンジン搭載機器の駐機器場に上記エンジンで生成した電気を受電する受電手段と該エンジンに水を供給する水供給手段を設け、上記エンジン搭載機器の駐機器中に当該エンジンを稼働させ、電気を製造し該電気を上記受電設備に供給し、上記水を受給することを特徴とする、水素・酸素を燃焼するエンジン。 An engine equipped with a brown gas generating means and an electricity generating means in an engine that burns brown gas is mounted on a moving body, and a power receiving means for receiving electricity generated by the engine and the power receiving means in a parking space of the engine-mounted equipment. A water supply means for supplying water to the engine is provided, and the engine is operated while the engine-mounted equipment is parked to produce electricity, supply the electricity to the power receiving equipment, and receive the water. An engine that burns hydrogen and oxygen.
  9. 請求項1から請求項2及び請求項4から請求項5に記載のエンジンに、電気生成手段及び、水素・酸素を生成手段を備えたエンジンは海を航行する移動体及び海水の真水化装置の前記エンジンに導入される前記水として海水を導入する場合に、前記導入された海水から真水と塩を生成する手段SPを設けたことを特徴とする水素・酸素を燃焼するエンジン。
     
     
     
     
    The engine according to any one of claims 1 to 2 and 4 to 5, which is equipped with an electricity generation means and a hydrogen/oxygen generation means, is used for a mobile body that travels in the sea and a seawater desalination device. An engine that burns hydrogen and oxygen, characterized in that means SP for generating fresh water and salt from the introduced seawater is provided when seawater is introduced as the water introduced into the engine.



PCT/JP2022/004907 2021-02-15 2022-02-08 Engine for combusting hydrogen-oxygen WO2022172914A1 (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10266900A (en) * 1997-03-27 1998-10-06 Manyo Hozen Kenkyusho:Kk Brown gas generating device, and travelling internal combustion engine using brown gas
JPH11332215A (en) * 1998-05-19 1999-11-30 Manyo Hozen Kenkyusho:Kk Electric apparatus made of normal temperature superconducting material employing battery power supply
JP2001231106A (en) * 2000-02-10 2001-08-24 Toyota Motor Corp Vehicle
JP2004155879A (en) * 2002-11-06 2004-06-03 Mitsubishi Heavy Ind Ltd Gasification melting system equipped with generator
JP2008063980A (en) * 2006-09-06 2008-03-21 Tomoki Yamazaki Oxyhydrogen gas two-stroke engine
KR101532508B1 (en) * 2014-01-27 2015-06-29 충남대학교산학협력단 a mixture fuel of water electrolysis gas and the water vapor, and this mixture blended fossil fuel, and the combustion method with these
JP2018025375A (en) * 2016-07-31 2018-02-15 寛治 泉 Constitution method for engine burning hydrogen and oxygen

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10266900A (en) * 1997-03-27 1998-10-06 Manyo Hozen Kenkyusho:Kk Brown gas generating device, and travelling internal combustion engine using brown gas
JPH11332215A (en) * 1998-05-19 1999-11-30 Manyo Hozen Kenkyusho:Kk Electric apparatus made of normal temperature superconducting material employing battery power supply
JP2001231106A (en) * 2000-02-10 2001-08-24 Toyota Motor Corp Vehicle
JP2004155879A (en) * 2002-11-06 2004-06-03 Mitsubishi Heavy Ind Ltd Gasification melting system equipped with generator
JP2008063980A (en) * 2006-09-06 2008-03-21 Tomoki Yamazaki Oxyhydrogen gas two-stroke engine
KR101532508B1 (en) * 2014-01-27 2015-06-29 충남대학교산학협력단 a mixture fuel of water electrolysis gas and the water vapor, and this mixture blended fossil fuel, and the combustion method with these
JP2018025375A (en) * 2016-07-31 2018-02-15 寛治 泉 Constitution method for engine burning hydrogen and oxygen

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