WO2022139745A1 - Antimicrobial cleaning product effective against insects - Google Patents

Antimicrobial cleaning product effective against insects Download PDF

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Publication number
WO2022139745A1
WO2022139745A1 PCT/TR2021/051263 TR2021051263W WO2022139745A1 WO 2022139745 A1 WO2022139745 A1 WO 2022139745A1 TR 2021051263 W TR2021051263 W TR 2021051263W WO 2022139745 A1 WO2022139745 A1 WO 2022139745A1
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Prior art keywords
weight
product
product according
oil
ratio
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PCT/TR2021/051263
Other languages
French (fr)
Inventor
Tugce KAYA
Zeynep ASKEROGLU
Original Assignee
Eczacibasi Tuketim Urunleri Sanayi Ve Ticaret Anonim Sirketi
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Publication of WO2022139745A1 publication Critical patent/WO2022139745A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0043—For use with aerosol devices
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust

Definitions

  • the subject of the invention relates to a cleaning product, which kills the pathogenic microorganisms present on the surface where it is applied, i.e. has antimicrobial property, and which further expels the insects from the surface.
  • Hygiene is one of the main factors affecting the human health. Accordingly, it is required to provide the ideal conditions of hygiene in the public spaces, such as health centers, schools, restaurants, shopping malls, hotels and the like, and in the private areas where the humans are present for meeting their basic needs.
  • the ideal conditions of hygiene are provided by way of effectively cleaning the surfaces in such spaces frequently contacted by the people. In case said surfaces are not cleaned effectively, the bacteria, virus and other pathogenic microorganisms accumulating on said surfaces spread to the skin of the persons upon contact and lead to the emergence of infections and other various health problems in any part of the skin or the body.
  • regular disinfection of the surfaces contacted by the people is the measure of first priority required to be taken to provide the ideal conditions of hygiene and to ensure that the diseases are not transmitted or not suffered at all.
  • the cleaning of said surfaces is performed with the cleaning products comprising chemicals with various properties.
  • the target contaminants, the cleaning performance and the properties affecting the performance are of importance for the choice of the products to be employed in the spaces requiring continuous cleaning.
  • Said properties include mainly the effect of a product on the stains left by the contaminants on the pathogenic microorganisms, the effect of a product on the pathogenic microorganisms and the persistency of these effects.
  • Some of the conventional surface cleaning products are the products enabling the contaminants on a surface to be readily removed with water from the ambience and not having any destructive effect on the pathogenic microorganisms, i.e. lacking antimicrobial property. While some other products have antimicrobial property, they are products that fall short in dissolving and removing from the ambience the other contaminants.
  • Majority of the baby care products, disinfectant sprays, wipes and similar cleaning products with antimicrobial action are alcohol-based and cause irritation in the skin and the respiratory tract in case of their frequent use.
  • insects Besides the pathogenic microorganisms, the flies, spiders and similar insects constitute another factor causing health problems in the humans.
  • the strong insecticides with long- lasting action are mainly used for the purposes of preventing the contact of the insects with the humans and precluding the spread of the diseases carried by these insects.
  • the chemical insecticide products are applied via the method of spraying on the surfaces in enclosed spaces, and in this way, the insects in the house environments are killed and the spread of the diseases like malaria carried by these insects is considerably prevented.
  • the frequent use of such products leads to environmental pollution and poisoning of other living beings as well.
  • a cleaning product which, in addition to providing the dirt removal performance expected from a standard surface cleaning product, is effective on the pathogenic microorganisms, i.e. has antimicrobial action, and at the same time prevents the flies and other pests from contacting the surfaces, has been developed within the scope of the invention. Because the use of the developed cleaning product alone, which is effective against the insects and which has the ability of disinfection, enables more than one function to be obtained at the same time, said product eliminates the necessity to successively use more than one product with chemical ingredients, and thus, it is ensured that the users are not exposed to high quantities of chemicals. By the use of a single product instead of more than one product, the costs are reduced and no undue workload is generated. Owing to the fact that it contains the natural ingredients that are harmless to health as the insect repellent agent, the product has no poisoning effect on the users and does not cause environmental pollution.
  • An object of the invention is to develop a cleaning product, which, in addition to the standard cleaning ability, has antimicrobial action, and thus, disinfects the surfaces where it is applied.
  • Another object of the invention is to develop a cleaning product, which keeps the insects away from the surfaces where it is applied, and thus, prevents the spread of the diseases carried by the insects.
  • Another object of the invention is to develop a cleaning product, which alone achieves the functions realized through the successive use of multiple products according to the state of the art and reduces the exposure of the users to chemicals.
  • Another object of the invention is to develop a cleaning product, which is free of the irritant and/or toxic agents contained in the products with similar functions used according to the state of the art and does not lead to the health problems caused by such agents.
  • Another object of the invention is to develop a cleaning spray, which has the features described in the preceding objects of the invention and is easy to use.
  • the subject of the invention relates to a cleaning product, which kills the pathogenic microorganisms present on the surface where it is applied, i.e. has antimicrobial property, and which further expels the insects from the surface.
  • the cleaning product according to the invention basically comprises at least one antimicrobial agent, at least one insect repellent agent and at least one surfactant enabling to remove the dirt from the surface.
  • the cleaning product comprises, in addition to the main ingredients, water and preferably at least one solvent for enabling the product to evaporate in a controlled manner so that it does not leave any stain on the surface.
  • the product according to the invention comprises the antimicrobial agent at a ratio of 0.05- 5% by weight, the insect repellent agent at a ratio of 5-10% by weight and the surfactant at a ratio of 0.05-15% by weight.
  • the cleaning product comprises the water at a ratio of 40-90% by weight and the solvent at a ratio of 5-15% by weight.
  • the product according to the invention preferably comprises at least one of quaternary ammonium compounds, transition metals, organometallic compounds, perchlorates, charged halogen-containing compounds, charged organic peroxides, ionic polymers, ionic surfactants and the derivatives of these, as the antimicrobial agent.
  • the quaternary ammonium compounds which belong to the cationic surfactants, are the antimicrobial compounds capable of killing over 99% of the microorganisms at typical application concentrations. Unlike the other antimicrobial compounds, they are not chemically converted following their use, and therefore, they retain their antimicrobial action as long as they remain bound to the surfaces where they are applied.
  • Benzalconium chloride one of the quaternary ammonium compounds, is known to achieve high rate of disinfection for many microorganism species present on the skin and inorganic surfaces.
  • Benzalconium chloride compounds with carbon chain distributions of differing length and proportion are available.
  • Benzalconium chloride compounds are able to eliminate many of the pathogenic microorganisms accumulating on the surfaces.
  • the disinfectant action of these compounds varies according to the lengths and quantities of the carbon chains they contain.
  • the positively charged chlorhexidine gluconate another compound with quaternary ammonium structure, disrupts the integrity of the cell membrane by interacting with the negatively charged microbial cell surface and causes the cell death by penetrating the cell.
  • Didecyl ammonium chloride another compound with quaternary ammonium structure, is known to considerably prevent many infections caused especially by the methicillin-resistant S. aureus strains.
  • One of said embodiments of the product according to the invention comprises 0.05-5% by weight benzalconium chloride (50% C12, 30% C14, 17% C16, 3% C18) and/or benzalconium chloride (62-75% C12, 21-30% C14, 3% C16) and/or benzalconium chloride (5% C12, 60% C14, 30% C16, 5% C18) and/or benzalconium chloride (40% C12, 50% C14, 10% C16) and/or chlorhexidine gluconate and/or didecyl ammonium chloride, as the antimicrobial agent.
  • One of said embodiments of the product according to the invention comprises 0.05-2.5% by weight didecyl ammonium chloride, additionally 0.05-2.5% by weight benzalconium chloride (50% C12, 30% C14, 17% C16, 3% C18) or benzalconium chloride (62-75% C12, 21-30% C14, 3% C16) or chlorhexidine gluconate, as the antimicrobial agent.
  • the surface cleaning product according to the invention comprises at least one insect repellent agent.
  • the insect repellent agent is preferably selected from the natural volatile oils with perfuming and flavoring properties wherein some of the volatile oils include lemongrass oil, fennel oil, lavender oil, peppermint oil, basil oil, thyme oil, tea tree oil, valerian oil and eucalyptus oil.
  • the natural volatile oils do not have harmful effects on the other living beings.
  • the product according to the invention comprises lemongrass oil as the insect repellent agent.
  • the surface cleaning product according to the invention comprises at least one surfactant.
  • the product according to the invention comprises at least one of the cationic surfactants, anionic surfactants or nonionic surfactants, as the surfactant.
  • the nonionic surfactant at least one of fatty alcohol-containing alkoxylate and alkyl polyglucoside compounds is used.
  • the product according to the invention comprises 0.05-5% by weight at least one cationic surfactant and 0.05-5% by weight at least one nonionic surfactant, as the surfactant.
  • the product according to the invention comprises 0.05-2.5% by weight fatty alcohol-containing alkoxylate and 0.05-2.5% by weight alkyl polyglucoside, as the nonionic surfactant. Owing to the combined used of the surfactants, the surface tension of the product is reduced and the obtained synergistic action increases the effect of the surfactants on the contaminants.
  • the product according to the invention comprises, in addition to the main ingredients, at least one odor fixing agent at a ratio of 3-5% by weight, for enhancing the persistency of the effect of the insect repellent agent.
  • the odor fixing agent is preferably selected from the compounds vanillin, fixolide and PPG-20 methyl glucose ether.
  • an alternative embodiment of the product according to the invention preferably comprises at least one polymeric additive at a ratio of 0.05-5% by weight.
  • Acrylic copolymer is preferably used as the polymeric additive.
  • the product according to the invention preferably comprises at least one of dipropylene glycol n-butyl ether, ethyl alcohol, propylene glycol n-butyl ether and diethylene glycol mono butyl ether, as the solvent.
  • the product according to the invention comprises 0.05-5% by weight at least one antimicrobial agent, 5-10% by weight at least one insect repellent agent, 0.05-15% by weight at least one surfactant, 40-90% by weight water, 5-15% by weight at least one solvent, 0.05-5% by weight at least one polymeric additive and 3-5% by weight at least one odor fixing agent.
  • fatty alcohol-containing alkoxylate, alkyl polyglucoside and a cationic surfactant are used as the surfactant
  • the lemongrass oil is used as the insect repellent agent
  • acrylic copolymer is used as the polymeric additive.
  • the product according to the invention comprises, at a ratio of 0.05-5% by weight, didecyl ammonium chloride or benzalconium chloride (50% C12, 30% C14, 17% C16, 3% C18) or benzalconium chloride (62-75% C12, 21-30% C14, 3% C16) or benzalconium chloride (5% C12, 60% C14, 30% C16, 5% C18) or benzalconium chloride (40% C12, 50% C14, 10% C16) or chlorhexidine gluconate, as the antimicrobial agent being a quaternary ammonium compound.
  • the product according to the invention comprises 0.05-2.5% by weight didecyl ammonium chloride, additionally 0.05-2.5% by weight benzalconium chloride (50% C12, 30% C14, 17% C16, 3% C18) or benzalconium chloride (62-75% C12, 21-30% C14, 3% C16) or chlorhexidine gluconate, as the antimicrobial agent being a quaternary ammonium compound.
  • the developed cleaning product in addition to providing the dirt removal performance expected from a standard surface cleaning product, is effective on the pathogenic microorganisms, i.e. has antimicrobial action, and disinfects the surfaces. At the same time, the product prevents the contact of the flies and other pests with the surfaces, and thus, prevents the spread of the diseases carried by the insects.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The subject of the invention relates to a cleaning product, which kills the pathogenic microorganisms present on the surface where it is applied, i.e. has antimicrobial property, and which further expels the insects from the surface. The cleaning product according to the invention basically comprises at least one antimicrobial agent, at least one insect repellent agent and at least one surfactant enabling to remove the dirt from the surface. The cleaning product comprises, in addition to the main ingredients, water and preferably at least one solvent.

Description

ANTIMICROBIAL CLEANING PRODUCT EFFECTIVE AGAINST INSECTS
Subject of the Invention
The subject of the invention relates to a cleaning product, which kills the pathogenic microorganisms present on the surface where it is applied, i.e. has antimicrobial property, and which further expels the insects from the surface.
State of the Art
Hygiene is one of the main factors affecting the human health. Accordingly, it is required to provide the ideal conditions of hygiene in the public spaces, such as health centers, schools, restaurants, shopping malls, hotels and the like, and in the private areas where the humans are present for meeting their basic needs. The ideal conditions of hygiene are provided by way of effectively cleaning the surfaces in such spaces frequently contacted by the people. In case said surfaces are not cleaned effectively, the bacteria, virus and other pathogenic microorganisms accumulating on said surfaces spread to the skin of the persons upon contact and lead to the emergence of infections and other various health problems in any part of the skin or the body. As a result, regular disinfection of the surfaces contacted by the people is the measure of first priority required to be taken to provide the ideal conditions of hygiene and to ensure that the diseases are not transmitted or not suffered at all.
Currently, the cleaning of said surfaces is performed with the cleaning products comprising chemicals with various properties. The target contaminants, the cleaning performance and the properties affecting the performance are of importance for the choice of the products to be employed in the spaces requiring continuous cleaning. Said properties include mainly the effect of a product on the stains left by the contaminants on the pathogenic microorganisms, the effect of a product on the pathogenic microorganisms and the persistency of these effects.
Some of the conventional surface cleaning products are the products enabling the contaminants on a surface to be readily removed with water from the ambience and not having any destructive effect on the pathogenic microorganisms, i.e. lacking antimicrobial property. While some other products have antimicrobial property, they are products that fall short in dissolving and removing from the ambience the other contaminants. Majority of the baby care products, disinfectant sprays, wipes and similar cleaning products with antimicrobial action are alcohol-based and cause irritation in the skin and the respiratory tract in case of their frequent use.
Besides the pathogenic microorganisms, the flies, spiders and similar insects constitute another factor causing health problems in the humans. The strong insecticides with long- lasting action are mainly used for the purposes of preventing the contact of the insects with the humans and precluding the spread of the diseases carried by these insects. The chemical insecticide products are applied via the method of spraying on the surfaces in enclosed spaces, and in this way, the insects in the house environments are killed and the spread of the diseases like malaria carried by these insects is considerably prevented. However, the frequent use of such products leads to environmental pollution and poisoning of other living beings as well.
Today, the products are available, which are developed for eliminating only a specific pest type. Consequently, the users have to provide more than one product and apply all of these on the surface in cases where it is desired to remove more than one type of pest from the surface. This is a condition leading to financial losses and undue workload. In case the conventional surface cleaning products, each containing effective chemicals, are used successively and frequently, they, while preventing the diseases associated with pathogenic microorganisms and insects, this time lead to other health problems in the users due to the chemicals they contain at high doses. As a result, the cleaning products are needed, which enable to kill the pathogenic microorganisms as well as expel the pests from the surfaces and which do not harm the health of other living beings while performing these actions.
In orderto meet said need, a cleaning product, which, in addition to providing the dirt removal performance expected from a standard surface cleaning product, is effective on the pathogenic microorganisms, i.e. has antimicrobial action, and at the same time prevents the flies and other pests from contacting the surfaces, has been developed within the scope of the invention. Because the use of the developed cleaning product alone, which is effective against the insects and which has the ability of disinfection, enables more than one function to be obtained at the same time, said product eliminates the necessity to successively use more than one product with chemical ingredients, and thus, it is ensured that the users are not exposed to high quantities of chemicals. By the use of a single product instead of more than one product, the costs are reduced and no undue workload is generated. Owing to the fact that it contains the natural ingredients that are harmless to health as the insect repellent agent, the product has no poisoning effect on the users and does not cause environmental pollution.
Object of the Invention
An object of the invention is to develop a cleaning product, which, in addition to the standard cleaning ability, has antimicrobial action, and thus, disinfects the surfaces where it is applied.
Another object of the invention is to develop a cleaning product, which keeps the insects away from the surfaces where it is applied, and thus, prevents the spread of the diseases carried by the insects.
Another object of the invention is to develop a cleaning product, which alone achieves the functions realized through the successive use of multiple products according to the state of the art and reduces the exposure of the users to chemicals. Another object of the invention is to develop a cleaning product, which is free of the irritant and/or toxic agents contained in the products with similar functions used according to the state of the art and does not lead to the health problems caused by such agents.
Another object of the invention is to develop a cleaning spray, which has the features described in the preceding objects of the invention and is easy to use.
Description of the Invention
The subject of the invention relates to a cleaning product, which kills the pathogenic microorganisms present on the surface where it is applied, i.e. has antimicrobial property, and which further expels the insects from the surface.
The cleaning product according to the invention basically comprises at least one antimicrobial agent, at least one insect repellent agent and at least one surfactant enabling to remove the dirt from the surface. The cleaning product comprises, in addition to the main ingredients, water and preferably at least one solvent for enabling the product to evaporate in a controlled manner so that it does not leave any stain on the surface.
The product according to the invention comprises the antimicrobial agent at a ratio of 0.05- 5% by weight, the insect repellent agent at a ratio of 5-10% by weight and the surfactant at a ratio of 0.05-15% by weight. The cleaning product comprises the water at a ratio of 40-90% by weight and the solvent at a ratio of 5-15% by weight.
The product according to the invention preferably comprises at least one of quaternary ammonium compounds, transition metals, organometallic compounds, perchlorates, charged halogen-containing compounds, charged organic peroxides, ionic polymers, ionic surfactants and the derivatives of these, as the antimicrobial agent.
The quaternary ammonium compounds, which belong to the cationic surfactants, are the antimicrobial compounds capable of killing over 99% of the microorganisms at typical application concentrations. Unlike the other antimicrobial compounds, they are not chemically converted following their use, and therefore, they retain their antimicrobial action as long as they remain bound to the surfaces where they are applied.
Benzalconium chloride, one of the quaternary ammonium compounds, is known to achieve high rate of disinfection for many microorganism species present on the skin and inorganic surfaces. Benzalconium chloride compounds with carbon chain distributions of differing length and proportion are available. Benzalconium chloride compounds are able to eliminate many of the pathogenic microorganisms accumulating on the surfaces. The disinfectant action of these compounds varies according to the lengths and quantities of the carbon chains they contain. The positively charged chlorhexidine gluconate, another compound with quaternary ammonium structure, disrupts the integrity of the cell membrane by interacting with the negatively charged microbial cell surface and causes the cell death by penetrating the cell. Didecyl ammonium chloride, another compound with quaternary ammonium structure, is known to considerably prevent many infections caused especially by the methicillin-resistant S. aureus strains.
One of said embodiments of the product according to the invention comprises 0.05-5% by weight benzalconium chloride (50% C12, 30% C14, 17% C16, 3% C18) and/or benzalconium chloride (62-75% C12, 21-30% C14, 3% C16) and/or benzalconium chloride (5% C12, 60% C14, 30% C16, 5% C18) and/or benzalconium chloride (40% C12, 50% C14, 10% C16) and/or chlorhexidine gluconate and/or didecyl ammonium chloride, as the antimicrobial agent.
One of said embodiments of the product according to the invention comprises 0.05-2.5% by weight didecyl ammonium chloride, additionally 0.05-2.5% by weight benzalconium chloride (50% C12, 30% C14, 17% C16, 3% C18) or benzalconium chloride (62-75% C12, 21-30% C14, 3% C16) or chlorhexidine gluconate, as the antimicrobial agent.
In order to be able to repel the insects from the surface in addition to disinfecting the surface by eliminating the pathogenic microorganisms, the surface cleaning product according to the invention comprises at least one insect repellent agent.
The insect repellent agent is preferably selected from the natural volatile oils with perfuming and flavoring properties wherein some of the volatile oils include lemongrass oil, fennel oil, lavender oil, peppermint oil, basil oil, thyme oil, tea tree oil, valerian oil and eucalyptus oil. Unlike the conventional insect repellents containing the chemical agents the high doses of which are toxic for the other living beings also, the natural volatile oils do not have harmful effects on the other living beings.
In some preferred embodiments, the product according to the invention comprises lemongrass oil as the insect repellent agent.
In order to be able to remove the oil and similar contaminants, in addition to disinfecting the surface by eliminating the pathogenic microorganisms and repelling the insects from the surface, the surface cleaning product according to the invention comprises at least one surfactant.
The product according to the invention comprises at least one of the cationic surfactants, anionic surfactants or nonionic surfactants, as the surfactant. As the nonionic surfactant, at least one of fatty alcohol-containing alkoxylate and alkyl polyglucoside compounds is used.
In some preferred embodiments, the product according to the invention comprises 0.05-5% by weight at least one cationic surfactant and 0.05-5% by weight at least one nonionic surfactant, as the surfactant.
In one of said alternative embodiments, the product according to the invention comprises 0.05-2.5% by weight fatty alcohol-containing alkoxylate and 0.05-2.5% by weight alkyl polyglucoside, as the nonionic surfactant. Owing to the combined used of the surfactants, the surface tension of the product is reduced and the obtained synergistic action increases the effect of the surfactants on the contaminants.
In an alternative embodiment, the product according to the invention comprises, in addition to the main ingredients, at least one odor fixing agent at a ratio of 3-5% by weight, for enhancing the persistency of the effect of the insect repellent agent. The odor fixing agent is preferably selected from the compounds vanillin, fixolide and PPG-20 methyl glucose ether.
In order to improve the surface cleaning performance, an alternative embodiment of the product according to the invention preferably comprises at least one polymeric additive at a ratio of 0.05-5% by weight. Acrylic copolymer is preferably used as the polymeric additive.
The product according to the invention preferably comprises at least one of dipropylene glycol n-butyl ether, ethyl alcohol, propylene glycol n-butyl ether and diethylene glycol mono butyl ether, as the solvent.
In an alternative embodiment, the product according to the invention comprises 0.05-5% by weight at least one antimicrobial agent, 5-10% by weight at least one insect repellent agent, 0.05-15% by weight at least one surfactant, 40-90% by weight water, 5-15% by weight at least one solvent, 0.05-5% by weight at least one polymeric additive and 3-5% by weight at least one odor fixing agent. In said embodiment of the product, fatty alcohol-containing alkoxylate, alkyl polyglucoside and a cationic surfactant, each at a ratio of 0.05-5% by weight, are used as the surfactant, the lemongrass oil is used as the insect repellent agent and acrylic copolymer is used as the polymeric additive.
In one of said embodiments, the product according to the invention comprises, at a ratio of 0.05-5% by weight, didecyl ammonium chloride or benzalconium chloride (50% C12, 30% C14, 17% C16, 3% C18) or benzalconium chloride (62-75% C12, 21-30% C14, 3% C16) or benzalconium chloride (5% C12, 60% C14, 30% C16, 5% C18) or benzalconium chloride (40% C12, 50% C14, 10% C16) or chlorhexidine gluconate, as the antimicrobial agent being a quaternary ammonium compound.
In one of said embodiments, the product according to the invention comprises 0.05-2.5% by weight didecyl ammonium chloride, additionally 0.05-2.5% by weight benzalconium chloride (50% C12, 30% C14, 17% C16, 3% C18) or benzalconium chloride (62-75% C12, 21-30% C14, 3% C16) or chlorhexidine gluconate, as the antimicrobial agent being a quaternary ammonium compound.
The developed cleaning product, in addition to providing the dirt removal performance expected from a standard surface cleaning product, is effective on the pathogenic microorganisms, i.e. has antimicrobial action, and disinfects the surfaces. At the same time, the product prevents the contact of the flies and other pests with the surfaces, and thus, prevents the spread of the diseases carried by the insects.

Claims

1. An antimicrobial cleaning product effective against insects characterized in that the product comprises
• at least one antimicrobial agent,
• at least one insect repellent agent and
• at least one surfactant.
2. A product according to Claim 1 characterized in that the product comprises the antimicrobial agent at a ratio of 0.05-5% by weight.
3. A product according to Claim 1 characterized in that the product comprises two antimicrobial agents each at a ratio of 0.05-2.5% by weight.
4. A product according to any one of Claims 1-3 characterized in that the product comprises at least one antimicrobial agent selected from quaternary ammonium compounds, transition metals, organometallic compounds, perchlorates, charged halogen-containing compounds, charged organic peroxides, ionic polymers, ionic surfactants or the derivatives of these.
5. A product according to any one of Claims 1-3 characterized in that the product comprises at least one of quaternary ammonium compounds as the antimicrobial agent.
6. A product according to any one of Claims 1-3 characterized in that the product comprises at least one of the compounds benzalconium chloride (50% C12, 30% C14, 17% C16, 3% C18) or benzalconium chloride (62-75% C12, 21-30% C14, 3% C16) or benzalconium chloride (5% C12, 60% C14, 30% C16, 5% C18) or benzalconium chloride (40% C12, 50% C14, 10% C16) or chlorhexidine gluconate or didecyl ammonium chloride, as the antimicrobial agent.
7. A product according to Claim 3 characterized in that the product comprises didecyl ammonium chloride, additionally benzalconium chloride (50% C12, 30% C14, 17% C16, 3% C18) or benzalconium chloride (62-75% C12, 21-30% C14, 3% C16) or chlorhexidine gluconate, as the antimicrobial agent.
8. A product according to any one of the preceding claims characterized in that the product comprises the insect repellent agent at a ratio of 5-10% by weight.
9. A product according to Claim 1 or Claim 8 characterized in that the product comprises at least one of the volatile oils as the insect repellent agent.
10. A product according to Claim 1 or Claim 8 characterized in that the product comprises at least one insect repellent agent selected from lemongrass oil, fennel oil, lavender oil, peppermint oil, basil oil, thyme oil, tea tree oil, valerian oil and eucalyptus oil as the.
11. A product according to Claim 1 or Claim 8 characterized in that the product comprises lemongrass oil as the insect repellent agent.
6
12. A product according to any one of the preceding claims characterized in that the product comprises said surfactant at a ratio of 0.05-15% by weight.
13. A product according to Claim 1 or Claim 12 characterized in that the product comprises at least one surfactant selected from anionic, cationic and nonionic surfactants.
14. A product according to any one of claims 1-11 characterized in that the product comprises 0.05-5% by weight at least one cationic surfactant and 0.05-5% by weight at least one nonionic surfactant.
15. A product according to according to any one of claims 1-11 characterized in that the product comprises fatty alcohol-containing alkoxylate and alkyl polyglucoside, each at a ratio of 0.05-2.5% by weight, as surfactant.
16. A product according to any one of the preceding claims characterized in that the product comprises at least one solvent.
17. A product according to Claim 16 characterized in that the product comprises said solvent at a ratio of 5-15% by weight.
18. A product according to Claim 16 or Claim 17 characterized in that the product comprises at least one solvent selected from dipropylene glycol n-butyl ether, ethyl alcohol, propylene glycol n-butyl ether and diethylene glycol mono butyl ether.
19. A product according to any one of the preceding claims characterized in that the product comprises 40-90% by weight water.
20. A product according to any one of the preceding claims characterized in that the product comprises at least one polymeric additive.
21. A product according to Claim 20 characterized in that the product comprises said polymeric additive at a ratio of 0.05-5% by weight.
22. A product according to Claim 20 or Claim 21 characterized in that the product comprises acrylic copolymer as the polymeric additive.
23. A product according to any one of the preceding claims characterized in that the product comprises at least one odor fixing agent.
24. A product according to Claim 23 characterized in that the product comprises said odor fixing agent at a ratio of 3-5% by weight.
25. A product according to Claim 23 or Claim 24 characterized in that the product comprises at least one odor fixing agent selected form vanillin, fixolide and PPG-20 methyl glucose ether.
7
26. A product according to Claim 1 characterized in that it comprises
• antimicrobial agent at a ratio of 0.05-5% by weight,
• insect repellent agent at a ratio of 5-10% by weight, and
• surfactant at a ratio of 0.05-15% by weight.
27. A product according to Claim 26 characterized in that
• the antimicrobial agent/agents is/are at least one compound selected from benzalconium chloride (50% C12, 30% C14, 17% C16, 3% C18) or benzalconium chloride (62-75% C12, 21-30% C14, 3% C16) or benzalconium chloride (5% C12, 60% C14, 30% C16, 5% C18) or benzalconium chloride (40% C12, 50% C14, 10% C16) or chlorhexidine gluconate or didecyl ammonium chloride, at a ratio of 0.05-5% by weight or 0.05-2.5% by weight didecyl ammonium chloride and additionally 0.05-2.5% by weight benzalconium chloride (50% C12, 30% C14, 17% C16, 3% C18) or benzalconium chloride (62-75% C12, 21-30% C14, 3% C16) or chlorhexidine gluconate,
• the surfactants are at least one cationic surfactant at a ratio of 0.05 by weight, fatty alcohol-containing alkoxylate at a ratio of 0.05-2.5% by weight and alkyl polyglucoside at a ratio of 0.05-2.5% by weight and
• the insect repellent agent is at least one compound selected from lemongrass oil, fennel oil, lavender oil, peppermint oil, basil oil, thyme oil, tea tree oil, valerian oil and eucalyptus oil, preferably lemongrass oil.
28. A product according to Claim 26 or Claim 27 characterized in that the product additionally comprises
• 40-90% by weight water,
• 5-15% by weight at least one solvent,
• 0.05-5% by weight at least one polymeric additive, and
• 3-5% by weight at least one odor fixing agent.
29. A product according to Claim 28 characterized in that
• the solvent is at least one compound selected from dipropylene glycol n-butyl ether, ethyl alcohol, propylene glycol n-butyl ether and diethylene glycol mono butyl ether,
• the odor fixing agent is at least one compound selected from vanillin, fixolide and PPG- 20 methyl glucose ether, and
• the polymeric additive is acrylic copolymer.
30. A product according to any one of the preceding claims characterized in that the product is in spray form.
8
PCT/TR2021/051263 2020-12-24 2021-11-22 Antimicrobial cleaning product effective against insects WO2022139745A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TR2020/21525 2020-12-24
TR2020/21525A TR202021525A1 (en) 2020-12-24 2020-12-24 ANTIMICROBIAL CLEANING PRODUCT AGAINST INSECTS

Publications (1)

Publication Number Publication Date
WO2022139745A1 true WO2022139745A1 (en) 2022-06-30

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TR (1) TR202021525A1 (en)
WO (1) WO2022139745A1 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0677579A1 (en) * 1994-04-15 1995-10-18 Colgate-Palmolive Company Microemulsion liquid cleaning compositions with insect repellent
WO1997043369A1 (en) * 1996-05-09 1997-11-20 Unilever Plc Insect-repellent compositions comprising antimicrobial agents and nonionic surfactant
WO1998018891A1 (en) * 1996-10-30 1998-05-07 Johan A. Benckiser Gmbh Detergent insect repellent composition for solid surface
US20110263665A1 (en) * 2007-09-17 2011-10-27 Byotrol Plc Formulations comprising an anti-microbial composition

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0677579A1 (en) * 1994-04-15 1995-10-18 Colgate-Palmolive Company Microemulsion liquid cleaning compositions with insect repellent
WO1997043369A1 (en) * 1996-05-09 1997-11-20 Unilever Plc Insect-repellent compositions comprising antimicrobial agents and nonionic surfactant
WO1998018891A1 (en) * 1996-10-30 1998-05-07 Johan A. Benckiser Gmbh Detergent insect repellent composition for solid surface
US20110263665A1 (en) * 2007-09-17 2011-10-27 Byotrol Plc Formulations comprising an anti-microbial composition

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