WO2022111007A1 - 一种聚碳酸酯/pct聚酯组合物及其制备方法和应用 - Google Patents

一种聚碳酸酯/pct聚酯组合物及其制备方法和应用 Download PDF

Info

Publication number
WO2022111007A1
WO2022111007A1 PCT/CN2021/119396 CN2021119396W WO2022111007A1 WO 2022111007 A1 WO2022111007 A1 WO 2022111007A1 CN 2021119396 W CN2021119396 W CN 2021119396W WO 2022111007 A1 WO2022111007 A1 WO 2022111007A1
Authority
WO
WIPO (PCT)
Prior art keywords
pct
polycarbonate
resin
polyester composition
polyester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2021/119396
Other languages
English (en)
French (fr)
Inventor
阎昆
黄险波
叶南飚
姜苏俊
曹民
杨汇鑫
蒋智强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kingfa Science and Technology Co Ltd
Zhuhai Vanteque Speciality Engineering Plastics Co Ltd
Original Assignee
Kingfa Science and Technology Co Ltd
Zhuhai Vanteque Speciality Engineering Plastics Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kingfa Science and Technology Co Ltd, Zhuhai Vanteque Speciality Engineering Plastics Co Ltd filed Critical Kingfa Science and Technology Co Ltd
Publication of WO2022111007A1 publication Critical patent/WO2022111007A1/zh
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80—Constructional details
    • H10H20/85—Packages
    • H10H20/855—Optical field-shaping means, e.g. lenses
    • H10H20/856—Reflecting means
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers

Definitions

  • the invention relates to the technical field of polymer materials, in particular to a polycarbonate/PCT polyester composition and a preparation method and application thereof.
  • Materials used for LED brackets are mainly high temperature resistant polyamide (PPA) and high temperature resistant polyester (polycyclohexyl terephthalate, PCT).
  • PPA high temperature resistant polyamide
  • PCT polycyclohexyl terephthalate
  • High temperature polyamide mainly including PA46, PA6T and PA9T
  • PA46, PA6T and PA9T has high initial whiteness, good heat resistance, high fluidity, suitable for injection molding process, and low cost, and is currently the mainstream material for LED brackets.
  • PA46, PA6T and PA9T the photothermal aging of PPA materials decays rapidly, and currently PPA materials can only be used for low-power products.
  • PCT With the introduction of high-voltage LEDs, PCT has greater advantages in the application of medium and high-power LED brackets due to its excellent high temperature resistance to color change.
  • Chinese patent applications 202010426329X and 202010452425.1 disclose the application of hyperbranched polyester resins in PCT resin compositions, which can improve the bonding force between molded products made of polyester resin compositions and silica gel, so that molded products and silica gel are not easily separated, At the same time, it has high reflectivity after adding white pigment.
  • the mechanical properties of the above two PCT resin compositions are poor, and a large amount of reinforcing materials need to be added, such as glass fibers, wollastonite, potassium titanate whiskers, kaolin, talc or mica, etc., which will inevitably reduce the PCT resin composition. of light transmittance.
  • the purpose of the present invention is to provide a polycarbonate/PCT polyester composition, which has the technical advantages of good mechanical properties and UV aging resistance.
  • Another object of the present invention is to provide a preparation method and application of the polycarbonate/PCT polyester composition.
  • a polycarbonate/PCT polyester composition comprising the following components:
  • the hyperbranched polyester is 0.3-0.6 parts.
  • the intrinsic viscosity of the PCT resin is 0.6-0.8 dL/g.
  • the melt mass flow rate of the polycarbonate resin is 10-30g/10min, and the conditions are 300°C and 1.20kgf.
  • the molecular weight of the hyperbranched polyester is 2000-10000 g/mol, and the number of carboxyl groups is 12-48/mol.
  • the hydroxyl-terminated hyperbranched polyester may be a carboxyl-terminated aliphatic hyperbranched polyester and/or a carboxyl-terminated aromatic hyperbranched polyester.
  • the hyperbranched polyesters used in the present application are commercially available.
  • reinforcing material is selected from at least one of glass fiber, wollastonite, potassium titanate whisker, kaolin, talc, mica .
  • the polycarbonate/PCT polyester composition of the present invention can also decide whether to add antioxidants, impact modifiers, flame retardants, fluorescent whitening agents, lubricants, plasticizers, thickeners, anti-oxidants, etc. Additives such as electrostatic agents, nucleating agents, UV stabilizers, mold release agents, and dyes.
  • the preparation method of the above-mentioned polycarbonate/PCT polyester composition comprises the following steps: uniformly mixing PCT resin with polycarbonate resin and reinforcing material, then melt-blending and extruding with hyperbranched polyester through a twin-screw extruder. After pelletizing to obtain a polyester resin composition, the temperature of the twin-screw extruder is set at 230-300°C.
  • the present invention can improve the mechanical properties by adding a certain amount of PC resin to the PCT resin.
  • PC resin due to the poor compatibility between PCT resin and PC resin, the problem of compatibility is solved by adding a certain amount of hyperbranched polyester with specific parameters.
  • hyperbranched polyester contains a large number of carboxyl groups, which can react with the end groups generated by the cleavage of PCT resin and PC resin, linking the two molecules through chemical bonds.
  • the cyclohexyl groups in the PCT molecular chain will be uniformly distributed in the composition.
  • higher energy is required for the transition of the cyclohexyl electrons to the transition state, and under UV irradiation, the stability of the molecular chain is better, and the UV resistance of the composition is higher.
  • the raw materials used in the following examples and comparative examples are derived from commercially available products.
  • PCT resin-A intrinsic viscosity: 0.719dL/g, Eastman Chemical Products, PCT36296;
  • PCT resin-B intrinsic viscosity: 0.65dL/g, SK Chemicals, 0302;
  • PCT resin-C intrinsic viscosity: 0.75dL/g, SK Chemicals, 0502;
  • PC resin-A The melt mass flow rate is 15g/10min, from Mitsubishi Engineering Plastics, S-3000R, the melt mass flow rate test temperature is 300°C, and the load is 1.20kgf;
  • PC resin-B The melt mass flow rate is 7.5g/10min, from Mitsubishi Engineering Plastics, S-1000R, the melt mass flow rate test temperature is 300°C, and the load is 1.20kgf;
  • PC resin-C the melt mass flow rate is 63g/10min, from Mitsubishi Engineering Plastics, H-4000, the melt mass flow rate test temperature is 300°C, and the load is 1.20kgf;
  • Hyperbranched polyester-A the molecular weight is 2100g/mol, the number of carboxyl groups is 12/mol, Wuhan Hyperbranched Resin Technology Co., Ltd.;
  • Hyperbranched polyester-B molecular weight is 5200g/mol, number of carboxyl groups is 24/mol, Wuhan Hyperbranched Resin Technology Co., Ltd.;
  • Hyperbranched polyester-C molecular weight is 9800g/mol, number of carboxyl groups is 48/mol, Wuhan Hyperbranched Resin Technology Co., Ltd.;
  • Hyperbranched polyester-D molecular weight is 1200g/mol, number of carboxyl groups is 4/mol, Wuhan Hyperbranched Resin Technology Co., Ltd.;
  • Hyperbranched polyester-E molecular weight is 950g/mol, number of carboxyl groups is 6/mol, Wuhan Hyperbranched Resin Technology Co., Ltd.;
  • Hyperbranched polyester-F the molecular weight is 12000g/mol, the number of carboxyl groups is 48/mol, Wuhan Hyperbranched Resin Technology Co., Ltd.;
  • Glass fiber F7x28: NITTO BOSEKI, Japan; chopped glass fiber CSG3PA- composed of E-glass with a length of 3mm, a main cross-sectional axis of 28 microns, a secondary cross-sectional axis of 7 microns, and an axial ratio of 4 (non-circular cross-section) 820, silica 60wt%-67wt%, alumina 33wt%-40wt%.
  • polyester resin composition mix PCT resin, polycarbonate resin, glass fiber uniformly, then melt blend with hyperbranched polyester through twin-screw extruder, extrude and pelletize, obtain
  • the temperature of the twin-screw extruder was set at 230 to 300°C.
  • UV resistance The light transmittance of the sample was measured on the sample after irradiating the sample with an LED light source at a wavelength of 460 nm for 500 hours in a constant temperature oven at 85° C. and 85% RH.
  • Table 1 Contents (parts by weight) and test results of each component of the polycarbonate/PCT polyester compositions of Examples 1-9
  • Example 7/8/9 it can be seen that the preferred addition amount of hyperbranched polyester can further inhibit UV aging.
  • Comparative Example 5 It can be seen from Comparative Example 5 that although an excessively high content of polycarbonate can improve the mechanical properties of the composition, it will further reduce the UV aging resistance.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明公开了一种聚碳酸酯/PCT聚酯组合物，按重量份计，包括以下组分：PCT树脂100份；聚碳酸酯树脂10-50份；超支化聚酯0.05-1份，其中，分子量为1000-11000g/mol，羧基数为4-48/mol。本发明的聚碳酸酯/PCT聚酯组合物解决了PCT树脂力学性能差的技术缺陷，也解决了PCT树脂和PC树脂组合物耐UV性能差的缺陷。

Description

一种聚碳酸酯/PCT聚酯组合物及其制备方法和应用 技术领域
本发明涉及高分子材料技术领域，特别是涉及一种聚碳酸酯/PCT聚酯组合物及其制备方法和应用。
背景技术
发光二极管(LED)的诞生使得照明行业进入半导体照明时代。LED光源具有高可靠性、发光功率高、功耗低、相应速度快、寿命长、价格低、色彩丰富等优点。继煤气照明、白炽灯和荧光灯之后，LED成为新一代主流照明技术。随着时代的发展和科技的进步，LED已经广泛地应用于路灯、室内照明、背光显示屏、汽车前照灯、景观灯等各个领域。LED支架作为芯片承载体，既起导电作用又起导热作用，是LED器件不可或缺的关键辅料。用作LED支架的材料主要有耐高温聚酰胺(PPA)、和耐高温聚酯(聚对苯二甲酰环己基二甲酯，PCT)。耐高温聚酰胺(主要包括PA46、PA6T和PA9T)具有较高的初始白度，耐热性好、流动性高，适合注塑成型工艺，并且成本较低，目前是LED支架的主流材料。但是PPA材料的光热老化衰减较快，目前PPA材料只能用于小功率产品。随着高压LED的推出，PCT由于优异的耐高温变色性能，在中大功率LED支架上应用具有更大优势。
中国专利申请202010426329X和202010452425.1公开了超支化聚酯树脂在PCT树脂组合物中的应用，能够提升聚酯树脂组合物制得的模塑制品与硅胶的结合力，使得模塑制品与硅胶不易分离，同时在添加白色颜料后具有高的反射率。但是，上述两种PCT树脂组合物的力学性能差，需要加入大量的增强材料，如玻璃纤维、硅灰石、钛酸钾晶须、高岭土、滑石或云母等，这样势必会降低PCT树脂组合物的透光率。
发明内容
本发明的目的在于，提供一种聚碳酸酯/PCT聚酯组合物，具有力学性能好、耐UV老化的技术优点。
本发明的另一目的在于，提供该聚碳酸酯/PCT聚酯组合物的制备方法和应用。
本发明是通过一下技术方案实现的：
一种聚碳酸酯/PCT聚酯组合物，按重量份计，包括以下组分：
PCT树脂        100份；
聚碳酸酯树脂   10-50份；
超支化聚酯     0.05-1份，其中，分子量为1000-11000g/mol，羧基数为4-48/mol。
优选的，超支化聚酯0.3-0.6份。
所述的PCT树脂的特性粘度为0.6-0.8dL/g。
优选的，所述的聚碳酸酯树脂的熔体质量流动速率为10-30g/10min，条件为300℃、1.20kgf。
优选的，超支化聚酯的分子量为2000-10000g/mol，羧基数为12-48/mol。
所述端羟基超支化聚酯可以为端羧基脂肪族超支化聚酯和/或端羧基芳香族超支化聚酯。本申请使用的所述超支化聚酯可通过市售得到。
为了进一步提升力学性能，按重量份计，还包括0-20份增强材料；所述的增强材料选自玻璃纤维、硅灰石、钛酸钾晶须、高岭土、滑石、云母中的至少一种。
本发明的聚碳酸酯/PCT聚酯组合物还可以根据需要，决定是否加入抗氧化剂、抗冲改性剂、阻燃剂、荧光增白剂、润滑剂、增塑剂、增稠剂、抗静电剂、成核剂、UV稳定剂、脱模剂、染料等添加剂。
上述的聚碳酸酯/PCT聚酯组合物的制备方法，包括以下步骤：将PCT树脂与聚碳酸酯树脂、增强材料混合均匀，然后与超支化聚酯通过双螺杆挤出机熔融共混、挤出造粒，得到聚酯树脂组合物，双螺杆挤出机的温度设置为230～300℃。
上述的聚碳酸酯/PCT聚酯组合物的应用，用于制备LED反射板。
本发明具有如下有益效果：
本发明通过在PCT树脂中添加一定量的PC树脂，能够提升力学性能。但是由于PCT树脂与PC树脂的相容性差，通过添加一定量的特定参数的超支化聚酯，解决了相容性的问题。意外的发现，加入上述超支化聚酯后，PCT树脂/PC树脂组合物的耐紫外线光照的能力得到了提升。经分析，这是因为在PCT与PC共混挤出时，PC和PCT的分子链发生部分断裂。超支化聚酯含有大量的羧基，可以与PCT树脂和PC树脂断裂产生的端基进行反应，将两种分子通过化学键进行链接。因此，PCT分子链中的环己基将均匀地分布在组合物中。在这种情况下，环己基电子跃迁到过渡态需要更高的能量，在UV照射下，分子链的稳定性更好，组合物耐UV性能更高。
具体实施方式
下面结合具体实施例和对比实施例来进一步说明本发明，以下具体实施例均为本发明较佳的实施方式，但本发明的实施方式并不受下述实施例的限制，特别并不局限于下述具体实施例中所使用的各组分原料的型号。
以下实施例和对比例所用原料来源于市售产品。
PCT树脂-A：特性粘度为：0.719dL/g，伊士曼化工产品公司(Eastman Chemical Products)，PCT36296；
PCT树脂-B：特性粘度为：0.65dL/g，SK化学(SK Chemicals)，0302；
PCT树脂-C：特性粘度为：0.75dL/g，SK化学(SK Chemicals)，0502；
PC树脂-A：熔体质量流动速率为15g/10min，来自三菱工程塑料，S-3000R，熔体质量流动速率测试温度为300℃，负荷为1.20kgf；
PC树脂-B：熔体质量流动速率为7.5g/10min，来自三菱工程塑料，S-1000R，熔体质量流动速率测试温度为300℃，负荷为1.20kgf；
PC树脂-C：熔体质量流动速率为63g/10min，来自三菱工程塑料，H-4000，熔体质量流动速率测试温度为300℃，负荷为1.20kgf；
超支化聚酯-A：分子量为2100g/mol，羧基数为12/mol，武汉超支化树脂科技有限公司；
超支化聚酯-B：分子量为5200g/mol，羧基数为24/mol，，武汉超支化树脂科技有限公司；
超支化聚酯-C：分子量为9800g/mol，羧基数为48/mol，，武汉超支化树脂科技有限公司；
超支化聚酯-D：分子量为1200g/mol，羧基数为4/mol，武汉超支化树脂科技有限公司；
超支化聚酯-E：分子量为950g/mol，羧基数为6/mol，，武汉超支化树脂科技有限公司；
超支化聚酯-F：分子量为12000g/mol，羧基数为48/mol，武汉超支化树脂科技有限公司；
玻璃纤维：F7x28：NITTO BOSEKI，Japan；由长3mm、主横截面轴28微米、副横截面轴7微米、轴比4(非圆形横截面)的E-玻璃构成的短切玻璃纤维CSG3PA-820，二氧化硅60wt％～67wt％，氧化铝33wt％～40wt％。
实施例和对比例聚酯树脂组合物的制备方法：将PCT树脂、聚碳酸酯树脂、玻璃纤维混合均匀，然后与超支化聚酯通过双螺杆挤出机熔融共混、挤出造粒，得到聚酯树脂组合物，双螺杆挤出机的温度设置为230～300℃。
各项性能测试方法：
(1)力学性能测试：拉伸强度按照GB/T1447-2005《纤维增强塑料拉伸性能试验方法》测试，弯曲强度按照GB/T1449-2005《纤维增强塑料弯曲性能试验方法》测试。
(2)耐UV性：在85℃和85％RH的恒温烘箱中用LED光源在460nm的波长下照射样品500小时之后在样品上测定样品的透光率。
表1：实施例1-9聚碳酸酯/PCT聚酯组合物各组分含量(重量份)及测试结果
Figure PCTCN2021119396-appb-000001
Figure PCTCN2021119396-appb-000002
由实施例2-4可知，本申请的技术方案适用于现有的能够应用于LED支架的PCT树脂。
由实施例1/2/5/6可知，聚碳酸酯含量的上升。拉伸强度和弯曲强度上升，但是耐UV老化性会下降。再参考实施例7/8/9可知，优选的超支化聚酯添加量能够进一步抑制UV老化。
表2：实施例10-15聚碳酸酯/PCT聚酯组合物各组分含量(重量份)及测试结果
Figure PCTCN2021119396-appb-000003
由实施例2/10/11可知，优选聚碳酸酯的熔体质量流动速率为10-30g/10min，条件为300℃、1.20kgf。
由实施例2/12/13/14可知，优选分子量为2000-10000g/mol，羧基数为12-48/mol。
表3：对比例聚碳酸酯/PCT聚酯组合物各组分含量(重量份)及测试结果
Figure PCTCN2021119396-appb-000004
由对比例1/2可知，超支化聚酯的分子量和羧基数不在本申请限定的范围内时，对于UV老化性能的提升不明显。
由对比例3/4可知，超支化聚酯的含量过高反而会降低力学性能。
由对比例5可知，过高含量的聚碳酸酯，虽然能够提升组合物的力学性能，但是也会进一步降低UV耐老化性能。

Claims (8)

  1. 一种聚碳酸酯/PCT聚酯组合物，其特征在于，按重量份计，包括以下组分：
    PCT树脂       100份；
    聚碳酸酯树脂  10-50份；
    超支化聚酯    0.05-1份，其中，分子量为1000-11000g/mol，羧基数为4-48/mol。
  2. 根据权利要求1所述的聚碳酸酯/PCT聚酯组合物，其特征在于，超支化聚酯0.3-0.6份。
  3. 根据权利要求1所述的聚碳酸酯/PCT聚酯组合物，其特征在于，所述的PCT树脂的特性粘度为0.65-0.75dL/g。
  4. 根据权利要求1或2所述的聚碳酸酯/PCT聚酯组合物，其特征在于，所述的聚碳酸酯树脂的熔体质量流动速率为10-30g/10min，条件为300℃、1.20kgf。
  5. 根据权利要求1或2所述的聚碳酸酯/PCT聚酯组合物，其特征在于，超支化聚酯的分子量为2000-10000g/mol，羧基数为12-48/mol。
  6. 根据权利要求1或2所述的聚碳酸酯/PCT聚酯组合物，其特征在于，按重量份计，还包括0-20份增强材料；所述的增强材料选自玻璃纤维、硅灰石、钛酸钾晶须、高岭土、滑石、云母中的至少一种。
  7. 权利要求1-6任一项所述的聚碳酸酯/PCT聚酯组合物的制备方法，其特征在于，包括以下步骤：将PCT树脂与聚碳酸酯树脂、增强材料混合均匀，然后与超支化聚酯通过双螺杆挤出机熔融共混、挤出造粒，得到聚碳酸酯/PCT聚酯组合物，双螺杆挤出机的温度设置为230～300℃。
  8. 权利要求1-6任一项所述的聚碳酸酯/PCT聚酯组合物的应用，其特征在于，用于制备LED反射板。
PCT/CN2021/119396 2020-11-30 2021-09-18 一种聚碳酸酯/pct聚酯组合物及其制备方法和应用 Ceased WO2022111007A1 (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN202011371298.9 2020-11-30
CN202011371298.9A CN112538240B (zh) 2020-11-30 2020-11-30 一种聚碳酸酯/pct聚酯组合物及其制备方法和应用

Publications (1)

Publication Number Publication Date
WO2022111007A1 true WO2022111007A1 (zh) 2022-06-02

Family

ID=75016422

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2021/119396 Ceased WO2022111007A1 (zh) 2020-11-30 2021-09-18 一种聚碳酸酯/pct聚酯组合物及其制备方法和应用

Country Status (2)

Country Link
CN (1) CN112538240B (zh)
WO (1) WO2022111007A1 (zh)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112538240B (zh) * 2020-11-30 2022-07-19 金发科技股份有限公司 一种聚碳酸酯/pct聚酯组合物及其制备方法和应用

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101906244A (zh) * 2010-08-12 2010-12-08 东莞市信诺橡塑工业有限公司 聚碳酸酯组合物及其制备方法
US20110152456A1 (en) * 2009-12-17 2011-06-23 E. I. Du Pont De Nemours And Company Polyester Compositions with Good Melt Rheological Properties
CN102408682A (zh) * 2005-01-14 2012-04-11 巴斯夫欧洲公司 耐水解的可流动性聚酯
CN102947087A (zh) * 2010-06-14 2013-02-27 纳幕尔杜邦公司 耐长期户外暴露的聚酯复合结构及其制备方法
CN103865246A (zh) * 2012-12-14 2014-06-18 苏州汉扬精密电子有限公司 一种玻璃纤维增强树脂组合物
CN111117192A (zh) * 2019-12-28 2020-05-08 会通新材料股份有限公司 一种高cti值、高灼热丝、低热球压痕的聚碳酸酯/聚酯合金及其制备方法
CN112538240A (zh) * 2020-11-30 2021-03-23 金发科技股份有限公司 一种聚碳酸酯/pct聚酯组合物及其制备方法和应用

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111763408B (zh) * 2020-05-19 2022-08-19 金发科技股份有限公司 一种聚酯树脂组合物及其制备方法和应用
CN111732819B (zh) * 2020-05-26 2022-08-19 金发科技股份有限公司 一种聚酯树脂组合物及其制备方法和应用

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102408682A (zh) * 2005-01-14 2012-04-11 巴斯夫欧洲公司 耐水解的可流动性聚酯
US20110152456A1 (en) * 2009-12-17 2011-06-23 E. I. Du Pont De Nemours And Company Polyester Compositions with Good Melt Rheological Properties
CN102947087A (zh) * 2010-06-14 2013-02-27 纳幕尔杜邦公司 耐长期户外暴露的聚酯复合结构及其制备方法
CN101906244A (zh) * 2010-08-12 2010-12-08 东莞市信诺橡塑工业有限公司 聚碳酸酯组合物及其制备方法
CN103865246A (zh) * 2012-12-14 2014-06-18 苏州汉扬精密电子有限公司 一种玻璃纤维增强树脂组合物
CN111117192A (zh) * 2019-12-28 2020-05-08 会通新材料股份有限公司 一种高cti值、高灼热丝、低热球压痕的聚碳酸酯/聚酯合金及其制备方法
CN112538240A (zh) * 2020-11-30 2021-03-23 金发科技股份有限公司 一种聚碳酸酯/pct聚酯组合物及其制备方法和应用

Also Published As

Publication number Publication date
CN112538240A (zh) 2021-03-23
CN112538240B (zh) 2022-07-19

Similar Documents

Publication Publication Date Title
CN1331945C (zh) 反射板用树脂组合物
JP4685406B2 (ja) 改質耐候性ポリエステル成形用組成物
US9346933B2 (en) Reflectors for light-emitting diode assemblies containing a white pigment
CN103910979B (zh) 用于发光装置反射器的聚酯树脂组合物和使用其的模制品
CN111732819B (zh) 一种聚酯树脂组合物及其制备方法和应用
US20080153954A1 (en) Reinforced PCT compositions
CN1449429A (zh) 芳香族聚碳酸酯树脂组合物及成型品
CN106317797B (zh) 具有优异的抗冲击性和光可靠性的聚酯树脂组合物及使用其的模制品
CN104650547B (zh) 一种反射板用聚酯组合物
CN111763408B (zh) 一种聚酯树脂组合物及其制备方法和应用
CN101563423A (zh) 尼龙聚合物复合材料
CN110527258A (zh) 耐热和光的聚合物组合物
WO2022111007A1 (zh) 一种聚碳酸酯/pct聚酯组合物及其制备方法和应用
CN105440601A (zh) 一种pbt/pct合成材料
CN116462941B (zh) 一种聚酯组合物及其制备方法和应用
JP2001354855A (ja) ポリアリーレンスルフィド樹脂組成物及びその成形体
US11345810B2 (en) PBT composite material having high heat resistance and high gloss for vehicle mirror and method for preparing the same
CN103740068A (zh) 一种低翘曲高灼热丝阻燃玻纤增强复合材料及其制备方法
WO2023040735A1 (zh) 一种聚酯树脂组合物及其制备方法和应用
CN114773800B (zh) 一种聚酯组合物及其制备方法和应用
CN106459567A (zh) 反射材料用聚酯树脂组合物及包含其的反射板
CN115895201A (zh) 适用于制作反光杯的高反射率pbt组合物及其制备和应用
CN112552656A (zh) 一种聚酯树脂组合物及其制备方法和应用
CN111218094B (zh) 热塑性树脂组合物和由其形成的模制品
CN110791020A (zh) 一种透明阻燃光扩散聚丙烯材料及其制备方法

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 21896511

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 21896511

Country of ref document: EP

Kind code of ref document: A1

32PN Ep: public notification in the ep bulletin as address of the adressee cannot be established

Free format text: NOTING OF LOSS OF RIGHTS PURSUANT TO RULE 112(1) EPC (EPO FORM 1205A DATED 18/10/2023).

122 Ep: pct application non-entry in european phase

Ref document number: 21896511

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: P2025-00559

Country of ref document: AE