WO2022110708A1 - N08825 composite steel plate for high-corrosion-resistance container and preparation method therefor - Google Patents

N08825 composite steel plate for high-corrosion-resistance container and preparation method therefor Download PDF

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WO2022110708A1
WO2022110708A1 PCT/CN2021/096177 CN2021096177W WO2022110708A1 WO 2022110708 A1 WO2022110708 A1 WO 2022110708A1 CN 2021096177 W CN2021096177 W CN 2021096177W WO 2022110708 A1 WO2022110708 A1 WO 2022110708A1
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steel plate
rolling
composite
cladding
base layer
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PCT/CN2021/096177
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French (fr)
Chinese (zh)
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江姗
曾周燏
党军
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南京钢铁股份有限公司
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Priority to KR1020237018394A priority Critical patent/KR20230127987A/en
Publication of WO2022110708A1 publication Critical patent/WO2022110708A1/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
    • B32B15/011—Layered products comprising a layer of metal all layers being exclusively metallic all layers being formed of iron alloys or steels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21B—ROLLING OF METAL
    • B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/38—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling sheets of limited length, e.g. folded sheets, superimposed sheets, pack rolling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21B—ROLLING OF METAL
    • B21B47/00—Auxiliary arrangements, devices or methods in connection with rolling of multi-layer sheets of metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C37/00—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
    • B21C37/02—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
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    • B32B37/08—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the cooling method
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    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
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    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
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    • B32B7/04—Interconnection of layers
    • B32B7/10—Interconnection of layers at least one layer having inter-reactive properties
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
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    • C22C19/03—Alloys based on nickel or cobalt based on nickel
    • C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/051—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
    • C22C19/055—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 20% but less than 30%
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
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    • C22C30/02—Alloys containing less than 50% by weight of each constituent containing copper
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
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    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
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    • C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C—CHEMISTRY; METALLURGY
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B21B1/38—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling sheets of limited length, e.g. folded sheets, superimposed sheets, pack rolling
    • B21B2001/386—Plates
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    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
    • B32B2037/243—Coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B2307/70—Other properties
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Definitions

  • the invention relates to the technical field of iron and steel production, in particular to a N08825 composite steel plate for high corrosion-resistant containers and a preparation method thereof.
  • N08825 clad steel plate for high corrosion-resistant containers can effectively solve these problems. It uses N08825 as the cladding layer and the container steel as the base layer to give full play to their respective advantages, and has both the superior corrosion resistance of the cladding and the base layer. With high strength, the cost of the bimetallic container prepared by it is greatly reduced, and the service life is greatly prolonged.
  • the main production methods of nickel-based alloy clad plates include explosion cladding method and rolling cladding method.
  • the explosive compounding method has many disadvantages: it is difficult to ensure 100% bonding of the board surface, and the stability of compounding performance is poor; the specification and size are limited; affected by the climate and environment, the production efficiency is low; A series of problems such as noise treatment, personal safety protection and serious pollution.
  • the rolling composite method is to keep the surface of the base material and the cladding material in a clean state, and through the diffusion between atoms during heating and rolling deformation, the base layer and the cladding layer achieve continuous metallurgical bonding.
  • Nickel-based alloy composite plates for high corrosion-resistant containers have high performance requirements for both the base material and the cladding material, and are rarely reported in public reports.
  • Chinese Patent Application No. CN101559527A discloses an explosive welding method of N08825 nickel-based alloy clad steel plate, which may have unclad areas and needs repair welding, and in order to eliminate the stress generated during the explosion, heat treatment is also required. Corrosion resistance has a certain influence; Chinese patent application No.
  • CN109694989A discloses a 825/X70 nickel-based alloy composite plate and its production method, which adopts the method of vacuum electron beam welding to form a billet, but this method needs to be welded in a vacuum chamber, The input cost is increased, and the vacuuming takes a long time, and the production efficiency is not high. At the same time, because the thermal expansion coefficient of the nickel-based alloy and carbon steel is very different, the welding seam between the nickel-based alloy and the carbon steel is easy to crack during the heating process. Affect binding performance. Therefore, it is necessary to develop a nickel-based alloy composite plate for high corrosion-resistant containers with excellent comprehensive performance, low cost, simple production process and high production efficiency.
  • the present invention overcomes the shortcomings of the prior art, and provides a N08825 composite steel plate for high corrosion-resistant containers, which includes a base layer and a cladding layer, which are in a metallurgical bonding state.
  • the chemical composition and mass percentage of the base layer are as follows: C ⁇ 0.20%, Si ⁇ 0.55%, Mn: 0.5% ⁇ 1.7%, Cu ⁇ 0.30%, Ni ⁇ 0.30%, Cr ⁇ 0.30%, Mo ⁇ 0.08%, Nb ⁇ 0.050% , V ⁇ 0.050%, Ti ⁇ 0.030%, Alt ⁇ 0.020%, P ⁇ 0.025%, S ⁇ 0.010%, Cu+Ni+Cr+Mo ⁇ 0.70%, the balance is Fe and a small amount of inevitable impurities;
  • the coating is N08825, and its chemical composition and mass percentage are as follows: Ni: 38.0% ⁇ 46.0%, Cr: 19.5% ⁇ 23.5%, Fe ⁇ 22.0%, Mn ⁇ 1.00%, C ⁇ 0.05%, Cu: 1.5% ⁇ 3.0 %, Si ⁇ 0.5%, S ⁇ 0.030%, Al ⁇ 0.2%, Ti: 0.6% ⁇ 1.2%, Mo: 2.5% ⁇ 3.5%.
  • the total thickness of the composite steel plate is 10-60 mm, and the coating thickness is 1.0-6.0 mm.
  • Another object of the present invention is to provide a preparation method of N08825 composite steel plate for high corrosion-resistant containers, which specifically includes the following steps:
  • Blank processing According to the material and specification of the finished composite steel plate, prepare a pair of base and cladding blanks, and the size of the cladding blank is smaller than that of the base blank; use an abrasive belt to grind the surfaces to be joined between the base and the cladding blank, and remove the Surface oil, iron oxide scale;
  • release agent brushing apply release agent evenly on the non-bonded surfaces of the two cladding blanks respectively, and then dry them;
  • Heating send the four-layer composite blank to the heating furnace, the heating temperature is 1150 ⁇ 1260°C, the soaking time is ⁇ 0.15 ⁇ t minutes, the total heating time is (1.0 ⁇ 2.0) ⁇ t minutes, t is the total thickness of the composite blank, unit mm;
  • Veneer straightening Straighten the two clad steel plates to ensure that the unevenness is ⁇ 5mm/m; then polish the surface release agent of the cladding to clean the N08825 clad steel plate products for high corrosion-resistant containers.
  • step S2 the drying temperature ranges from 300 to 800°C.
  • step S5 if the clad steel plate needs to be widened, the first pass of rough rolling is descaled, and after the last pass of steel transfer, 2 passes of descaler are carried out continuously, and In the finishing rolling stage, the scales are removed continuously for 2 passes; if the composite steel plate is not widened, the first two passes of the rough rolling and finishing rolling stages are descaled.
  • step S6 the rolling speed of rough rolling is ⁇ 1.5 m/s.
  • the present invention ensures the good mechanical properties of the base layer by controlling the rolling, and at the same time, by controlling the cooling process, the high corrosion resistance of the cladding N08825 is guaranteed;
  • the present invention does not need to seal and weld the billet in the vacuum chamber, which greatly reduces the input cost; because the direct welding of N08825 and carbon steel is avoided, it can ensure that the composite billet will not crack during heating and rolling; and the billet assembly efficiency is relatively high. Vacuum electron beam welding is greatly improved, suitable for industrial mass production;
  • the present invention adopts the method of welding billet plus controlled rolling and controlled cooling to prepare N08825 clad steel plate for high corrosion-resistant container, which has a flat plate shape, more uniform coating thickness and better performance stability;
  • the composite steel plate does not need to be annealed, which further ensures the corrosion resistance of the coating;
  • the N08825 clad steel plate for high corrosion-resistant containers prepared by the present invention effectively reduces the amount of N08825 used, and can be used as a substitute for pure N08825 to manufacture chemical equipment, petroleum storage tanks, etc., while meeting its practicality requirements, It also prolongs the service life, greatly reduces the production cost, and has high economic benefits.
  • FIG. 1 is a photo of the metallographic structure of the composite interface of the steel plate prepared by the present invention.
  • a kind of N08825 clad steel plate for high corrosion resistance container and its preparation method provided by the following examples are composed of a cladding layer and a base layer, and the two are in a metallurgical bonding state.
  • the preparation method specifically includes the following steps:
  • Billet processing According to the material and specification of the finished composite steel plate, prepare a pair of base layer and cladding blank, and the size of the cladding blank is smaller than that of the base layer blank; use an abrasive belt to grind the to-be-bonded surface of the base layer and the cladding blank to remove Surface oil, iron oxide scale;
  • release agent brushing apply release agent evenly on the non-bonded surfaces of the two cladding blanks respectively, and then dry them, and the drying temperature ranges from 300 to 800 °C;
  • Heating send the four-layer composite blank to the heating furnace, the heating temperature is 1150 ⁇ 1260°C, the soaking time is ⁇ 0.15 ⁇ t minutes, the total heating time is (1.0 ⁇ 2.0) ⁇ t minutes, t is the total thickness of the composite blank, unit mm;
  • the descaling box is descaled at least one pass. If the composite steel plate needs to be widened, the first pass of rough rolling is to be descaled, and after the last transfer, two passes are continuously descaled, and the finish rolling is carried out. 2 consecutive steps of descaling; if the clad steel plate is not widened, the first two steps of rough rolling and finishing rolling are descaled;
  • Veneer straightening Straighten the two clad steel plates to ensure that the unevenness is ⁇ 5mm/m; then polish the surface release agent of the cladding to clean the N08825 clad steel plate products for high corrosion-resistant containers.
  • each embodiment steel plate The base chemical composition of each embodiment steel plate is shown in Table 1, the cladding chemical composition of each embodiment steel plate is shown in Table 2, the preparation process parameters of each embodiment steel plate are shown in Table 3, and the various properties of each embodiment steel plate are shown in Table 4:
  • the top is the coating layer N08825, and the bottom is the base layer Q345R. It can be seen that the composite interface is clean and free of inclusions, and the composite is good.
  • the N08825 clad steel plate for high corrosion-resistant containers prepared by the present invention effectively reduces the amount of N08825 used, and can be used as a substitute for pure N08825 for manufacturing chemical equipment, petroleum storage tanks, etc. At the same time, the service life is prolonged, the production cost is greatly reduced, and the utility model has high economic benefits.

Abstract

The present invention relates to the technical field of steel production, and provides an N08825 composite steel plate for a high-corrosion-resistance container, comprising a base layer and a coating which are in a metallurgical bonding state. The base layer comprises the following chemical components in percentage by mass: C≤0.20%, Si≤0.55%, Mn: 0.5%-1.7%, Cu≤0.30%, Ni≤0.30%, Cr≤0.30%, Mo≤0.08%, Nb≤0.050%, V≤0.050%, Ti≤0.030%, Alt≥0.020%, P≤0.025%, S≤0.010%, Cu+Ni+Cr+Mo≤0.70%, and the balance of Fe and other inevitable impurities. The coating is N08825 and comprises the following chemical components in percentage by mass: Ni: 38.0%-46.0%, Cr: 19.5%-23.5%, Fe≥22.0%, Mn≤1.00%, C≤0.05%, Cu: 1.5%-3.0%, Si≤0.5%, S≤0.030%, Al≤0.2%, Ti: 0.6%-1.2%, and Mo: 2.5%-3.5%.

Description

一种高耐蚀容器用N08825复合钢板及其制备方法A kind of N08825 composite steel plate for high corrosion resistance container and preparation method thereof 技术领域technical field
本发明涉及钢铁生产技术领域，特别是涉及一种高耐蚀容器用N08825复合钢板及其制备方法。The invention relates to the technical field of iron and steel production, in particular to a N08825 composite steel plate for high corrosion-resistant containers and a preparation method thereof.
背景技术Background technique
煤炭、石油及天然气等能源的深度开发，推动了石油精炼、煤的气化与液化、天然气处理等石化工业的迅速发展，同时对压力容器用钢的质量也提出了更高的要求。在高含H 2S、CO 2等高腐蚀介质的环境下，容器设备不仅要有足够的强度，还须有良好的耐腐蚀性能，这就需要耐蚀性能更优良的高合金材料，如镍基合金。若直接采用镍基合金制造设备，则成本太高，且镍基合金作为抗腐蚀部分仅占三分之一厚度，这就造成材料的极大浪费。高耐蚀容器用N08825复合钢板的研制与开发则可有效解决这些问题，其以N08825作为覆层、容器钢作为基层，充分发挥各自的优点，兼具了覆层优越的耐蚀性和基层的高强度，由其制备的双金属容器成本大幅降低、使用寿命极大延长。 The in-depth development of energy sources such as coal, oil and natural gas has promoted the rapid development of petrochemical industries such as petroleum refining, coal gasification and liquefaction, and natural gas processing. At the same time, higher requirements have been placed on the quality of pressure vessel steel. In the environment with high content of H 2 S, CO 2 and other highly corrosive media, the container equipment must not only have sufficient strength, but also have good corrosion resistance, which requires high alloy materials with better corrosion resistance, such as nickel base alloy. If the nickel-based alloy is directly used to manufacture the equipment, the cost is too high, and the nickel-based alloy only accounts for one-third of the thickness as the anti-corrosion part, which results in a great waste of materials. The research and development of N08825 clad steel plate for high corrosion-resistant containers can effectively solve these problems. It uses N08825 as the cladding layer and the container steel as the base layer to give full play to their respective advantages, and has both the superior corrosion resistance of the cladding and the base layer. With high strength, the cost of the bimetallic container prepared by it is greatly reduced, and the service life is greatly prolonged.
目前，镍基合金复合板的主要生产方法有爆炸复合法和轧制复合法。爆炸复合法有诸多缺点：难以保证板面100％结合，复合性能稳定性较差；规格尺寸受到限制；受气候、环境的影响，生产效率低；同时还有炸药的存放、爆破地点的选择、噪音的处理、人身安全的保障及污染严重等一系列问题。轧制复合法是让基材和覆材处于表面洁净状态，通过加热和轧制变形时原子间的扩散作用使基层和覆层达到连续的冶金结合。At present, the main production methods of nickel-based alloy clad plates include explosion cladding method and rolling cladding method. The explosive compounding method has many disadvantages: it is difficult to ensure 100% bonding of the board surface, and the stability of compounding performance is poor; the specification and size are limited; affected by the climate and environment, the production efficiency is low; A series of problems such as noise treatment, personal safety protection and serious pollution. The rolling composite method is to keep the surface of the base material and the cladding material in a clean state, and through the diffusion between atoms during heating and rolling deformation, the base layer and the cladding layer achieve continuous metallurgical bonding.
高耐蚀容器用镍基合金复合板对基材和覆材的性能要求都较高，且很少见于公开报道。CN101559527A号中国专利申请公开了一种N08825镍基合金复合钢板的爆炸焊接方法，其可能存在未复合区而需要补焊，并且为消除爆炸时产生的应力，还需进行热处理，这对覆层的耐蚀性有一定影响；CN109694989A号中国专利申请公开了一种825/X70镍基合金复合板及其生产方法，其采用真空电 子束焊接组坯的方法，然而该法需在真空室内进行焊接，加大了投入成本，且抽真空耗时长，生产效率不高，同时由于镍基合金与碳钢的热膨胀系数有很大差异，加热过程中易使镍基合金与碳钢的焊缝裂开，影响结合性能。因此，需要研发一种综合性能优良、成本低廉、生产工序简单且生产效率高的高耐蚀容器用镍基合金复合板。Nickel-based alloy composite plates for high corrosion-resistant containers have high performance requirements for both the base material and the cladding material, and are rarely reported in public reports. Chinese Patent Application No. CN101559527A discloses an explosive welding method of N08825 nickel-based alloy clad steel plate, which may have unclad areas and needs repair welding, and in order to eliminate the stress generated during the explosion, heat treatment is also required. Corrosion resistance has a certain influence; Chinese patent application No. CN109694989A discloses a 825/X70 nickel-based alloy composite plate and its production method, which adopts the method of vacuum electron beam welding to form a billet, but this method needs to be welded in a vacuum chamber, The input cost is increased, and the vacuuming takes a long time, and the production efficiency is not high. At the same time, because the thermal expansion coefficient of the nickel-based alloy and carbon steel is very different, the welding seam between the nickel-based alloy and the carbon steel is easy to crack during the heating process. Affect binding performance. Therefore, it is necessary to develop a nickel-based alloy composite plate for high corrosion-resistant containers with excellent comprehensive performance, low cost, simple production process and high production efficiency.
发明内容SUMMARY OF THE INVENTION
本发明针对上述技术问题，克服现有技术的缺点，提供一种高耐蚀容器用N08825复合钢板，包括基层与覆层，两者之间呈冶金结合状态，In view of the above technical problems, the present invention overcomes the shortcomings of the prior art, and provides a N08825 composite steel plate for high corrosion-resistant containers, which includes a base layer and a cladding layer, which are in a metallurgical bonding state.
基层化学成分及质量百分比如下：C≤0.20％，Si≤0.55％，Mn：0.5％～1.7％，Cu≤0.30％，Ni≤0.30％，Cr≤0.30％，Mo≤0.08％，Nb≤0.050％，V≤0.050％，Ti≤0.030％，Alt≥0.020％，P≤0.025％，S≤0.010％，Cu+Ni+Cr+Mo≤0.70％，余量为Fe及少量不可避免的杂质；The chemical composition and mass percentage of the base layer are as follows: C≤0.20%, Si≤0.55%, Mn: 0.5%～1.7%, Cu≤0.30%, Ni≤0.30%, Cr≤0.30%, Mo≤0.08%, Nb≤0.050% , V≤0.050%, Ti≤0.030%, Alt≥0.020%, P≤0.025%, S≤0.010%, Cu+Ni+Cr+Mo≤0.70%, the balance is Fe and a small amount of inevitable impurities;
覆层为N08825，其化学成分及质量百分比如下：Ni：38.0％～46.0％，Cr：19.5％～23.5％，Fe≥22.0％，Mn≤1.00％，C≤0.05％，Cu：1.5％～3.0％，Si≤0.5％，S≤0.030％，Al≤0.2％，Ti：0.6％～1.2％，Mo：2.5％～3.5％。The coating is N08825, and its chemical composition and mass percentage are as follows: Ni: 38.0%～46.0%, Cr: 19.5%～23.5%, Fe≥22.0%, Mn≤1.00%, C≤0.05%, Cu: 1.5%～3.0 %, Si≤0.5%, S≤0.030%, Al≤0.2%, Ti: 0.6%～1.2%, Mo: 2.5%～3.5%.
本发明进一步限定的技术方案是：The technical scheme that the present invention is further limited is:
前所述的一种高耐蚀容器用N08825复合钢板，复合钢板总厚度为10～60mm，覆层厚度为1.0～6.0mm。In the aforementioned N08825 composite steel plate for high corrosion-resistant containers, the total thickness of the composite steel plate is 10-60 mm, and the coating thickness is 1.0-6.0 mm.
本发明的另一目的在于提供一种高耐蚀容器用N08825复合钢板的制备方法，具体包括如下步骤：Another object of the present invention is to provide a preparation method of N08825 composite steel plate for high corrosion-resistant containers, which specifically includes the following steps:
S1、坯料加工：根据成品复合钢板的材质、规格，准备基层和覆层坯料各一对，覆层坯料尺寸小于基层坯料；用砂带对基层和覆层坯料的待结合面进行打磨处理，清除表面油污、氧化铁皮；S1. Blank processing: According to the material and specification of the finished composite steel plate, prepare a pair of base and cladding blanks, and the size of the cladding blank is smaller than that of the base blank; use an abrasive belt to grind the surfaces to be joined between the base and the cladding blank, and remove the Surface oil, iron oxide scale;
S1、隔离剂涂刷：分别在两块覆层坯料的非结合表面均匀涂刷隔离剂，然 后烘干处理；S1, release agent brushing: apply release agent evenly on the non-bonded surfaces of the two cladding blanks respectively, and then dry them;
S3、组坯焊接：按照对称组坯方式以基层-覆层-覆层-基层的顺序堆放坯料，采用封条将上、下基层的四周点焊固定，封条高度为中间两块覆层的厚度之和，每边封条长度为基层边长，由此中间两块覆层处在封条围成的槽内；采用埋弧焊将基层与封条间的缝隙进行焊接，埋弧焊深度≥22mm，然后对复合坯进行抽真空处理；S3. Welding of blanks: stack the blanks in the order of base layer - cladding layer - covering layer - base layer according to the symmetrical method of forming blanks, and use seals to fix the upper and lower base layers by spot welding. The height of the seal is the thickness of the two middle cladding layers. And, the length of each seal strip is the length of the base layer, so the two middle cladding layers are in the groove enclosed by the seal strip; the gap between the base layer and the seal strip is welded by submerged arc welding, the depth of submerged arc welding is ≥ 22mm, and then the The composite blank is subjected to vacuum treatment;
S4、加热：将四层复合坯送至加热炉，加热温度1150～1260℃，均热时间≥0.15×t分钟，加热总时间(1.0～2.0)×t分钟，t为复合坯总厚度，单位mm；S4. Heating: send the four-layer composite blank to the heating furnace, the heating temperature is 1150～1260℃, the soaking time is ≥0.15×t minutes, the total heating time is (1.0～2.0)×t minutes, t is the total thickness of the composite blank, unit mm;
S5、除鳞：复合坯进入轧机前除鳞箱至少除鳞1道次，粗轧及精轧阶段均需除鳞；S5, descaling: before the composite billet enters the rolling mill, the descaling box needs at least one pass of descaling, and descaling is required in both rough rolling and finishing rolling;
S6、轧制：采用两阶段轧制法，粗轧采用低速大压下，成形道次压下率10％以上，粗轧总压下率65％以上；精轧阶段开轧温度900～980℃，终轧温度850～930℃；S6. Rolling: Two-stage rolling method is adopted, low-speed and high-pressure reduction is used for rough rolling, the reduction rate of forming passes is more than 10%, and the total reduction rate of rough rolling is more than 65%; the rolling temperature in the finishing rolling stage is 900-980 ℃ , the final rolling temperature is 850～930℃;
S7、冷却：轧后高速抛钢，复合钢板进入超快冷设备以＞10℃/s的冷速冷却至600～700℃；S7. Cooling: After rolling, the steel is thrown at a high speed, and the clad steel plate enters the ultra-fast cooling equipment and is cooled to 600-700°C at a cooling rate of >10°C/s;
S8、矫直：对复合钢板进行矫直1～3道次，不平度≤5mm/m；然后送至冷床冷却，待复合钢板表面温度≤300℃时，即可下线；S8. Straightening: Straighten the clad steel plate for 1 to 3 passes, and the unevenness is ≤5mm/m; then send it to a cooling bed for cooling, and when the surface temperature of the clad steel plate is ≤300°C, it can be off the assembly line;
S9、切割分板：采用等离子或火焰切割设备对复合钢板的头、尾及两边进行切割，上、下两张复合钢板分离，再将上层复合钢板翻面，使覆层朝上；S9, cutting and splitting: use plasma or flame cutting equipment to cut the head, tail and both sides of the composite steel plate, separate the upper and lower composite steel plates, and then turn the upper composite steel plate over to make the cladding face up;
S10、单板矫直：分别对两张复合钢板进行矫直处理，保证不平度≤5mm/m；然后将覆层表面隔离剂打磨干净，即可获得高耐蚀容器用N08825复合钢板产品。S10. Veneer straightening: Straighten the two clad steel plates to ensure that the unevenness is ≤5mm/m; then polish the surface release agent of the cladding to clean the N08825 clad steel plate products for high corrosion-resistant containers.
前所述的一种高耐蚀容器用N08825复合钢板的制备方法，步骤S2中，烘干温度范围300～800℃。In the aforementioned preparation method of N08825 composite steel plate for high corrosion-resistant containers, in step S2, the drying temperature ranges from 300 to 800°C.
前所述的一种高耐蚀容器用N08825复合钢板的制备方法，步骤S5中，若复合钢板需展宽，则粗轧首道次除鳞，最后1次转钢后连续除鳞2道，且精轧阶段连续除鳞2道；若复合钢板不展宽，则粗轧及精轧阶段的前两道次均除鳞。In the above-mentioned preparation method of N08825 clad steel plate for high corrosion-resistant containers, in step S5, if the clad steel plate needs to be widened, the first pass of rough rolling is descaled, and after the last pass of steel transfer, 2 passes of descaler are carried out continuously, and In the finishing rolling stage, the scales are removed continuously for 2 passes; if the composite steel plate is not widened, the first two passes of the rough rolling and finishing rolling stages are descaled.
前所述的一种高耐蚀容器用N08825复合钢板的制备方法，步骤S6中，粗轧轧制速度≤1.5m/s。In the aforementioned preparation method of N08825 clad steel plate for high corrosion-resistant containers, in step S6, the rolling speed of rough rolling is ≤1.5 m/s.
本发明的有益效果是：The beneficial effects of the present invention are:
(1)本发明通过控制轧制，保证了基层良好的机械性能，同时通过控制冷却工艺，保证了覆层N08825的高耐蚀性能；(1) The present invention ensures the good mechanical properties of the base layer by controlling the rolling, and at the same time, by controlling the cooling process, the high corrosion resistance of the cladding N08825 is guaranteed;
(2)本发明无需在真空室内进行封焊组坯，大大降低了投入成本；因避免了N08825与碳钢的直接焊接，可保证复合坯在加热、轧制过程不开裂；且组坯效率较真空电子束焊接大大提高，适用于工业大规模生产；(2) The present invention does not need to seal and weld the billet in the vacuum chamber, which greatly reduces the input cost; because the direct welding of N08825 and carbon steel is avoided, it can ensure that the composite billet will not crack during heating and rolling; and the billet assembly efficiency is relatively high. Vacuum electron beam welding is greatly improved, suitable for industrial mass production;
(3)本发明与爆炸复合相比，本发明采用焊接组坯加控轧控冷的方式制备高耐蚀容器用N08825复合钢板，板形平整、覆层厚度更均匀、性能稳定性更好；另外，复合钢板无需进行退火处理，进一步保证了覆层的耐蚀性能；(3) Compared with explosive compounding, the present invention adopts the method of welding billet plus controlled rolling and controlled cooling to prepare N08825 clad steel plate for high corrosion-resistant container, which has a flat plate shape, more uniform coating thickness and better performance stability; In addition, the composite steel plate does not need to be annealed, which further ensures the corrosion resistance of the coating;
(4)本发明制备的高耐蚀容器用N08825复合钢板，有效地减少了N08825的使用量，可以作为纯N08825制造化工设备、石油储罐等的替代产品，在满足其实用性要求的同时，还延长了使用寿命，也极大地降低了生产成本，具有较高的经济效益。(4) The N08825 clad steel plate for high corrosion-resistant containers prepared by the present invention effectively reduces the amount of N08825 used, and can be used as a substitute for pure N08825 to manufacture chemical equipment, petroleum storage tanks, etc., while meeting its practicality requirements, It also prolongs the service life, greatly reduces the production cost, and has high economic benefits.
附图说明Description of drawings
图1为本发明制备的钢板复合界面的金相组织照片。FIG. 1 is a photo of the metallographic structure of the composite interface of the steel plate prepared by the present invention.
具体实施方式Detailed ways
以下实施例提供的一种高耐蚀容器用N08825复合钢板及其制备方法，由覆层与基层组成，两者之间呈冶金结合状态。A kind of N08825 clad steel plate for high corrosion resistance container and its preparation method provided by the following examples are composed of a cladding layer and a base layer, and the two are in a metallurgical bonding state.
制备方法具体包括如下步骤：The preparation method specifically includes the following steps:
S1、坯料加工：根据成品复合钢板的材质、规格，准备基层和覆层坯料各一对，覆层坯料尺寸小于基层坯料；用砂带对基层和覆层坯料的待结合面进行打磨处理，清除表面油污、氧化铁皮；S1. Billet processing: According to the material and specification of the finished composite steel plate, prepare a pair of base layer and cladding blank, and the size of the cladding blank is smaller than that of the base layer blank; use an abrasive belt to grind the to-be-bonded surface of the base layer and the cladding blank to remove Surface oil, iron oxide scale;
S1、隔离剂涂刷：分别在两块覆层坯料的非结合表面均匀涂刷隔离剂，然后烘干处理，烘干温度范围300～800℃；S1, release agent brushing: apply release agent evenly on the non-bonded surfaces of the two cladding blanks respectively, and then dry them, and the drying temperature ranges from 300 to 800 °C;
S3、组坯焊接：按照对称组坯方式以基层-覆层-覆层-基层的顺序堆放坯料，采用封条将上、下基层的四周点焊固定，封条高度为中间两块覆层的厚度之和，每边封条长度为基层边长，由此中间两块覆层处在封条围成的槽内；采用埋弧焊将基层与封条间的缝隙进行焊接，埋弧焊深度≥22mm，然后对复合坯进行抽真空处理；S3. Welding of blanks: stack the blanks in the order of base layer - cladding layer - covering layer - base layer according to the symmetrical method of forming blanks, and use seals to fix the upper and lower base layers by spot welding. The height of the seal is the thickness of the two middle cladding layers. And, the length of each seal strip is the length of the base layer, so the two middle cladding layers are in the groove enclosed by the seal strip; the gap between the base layer and the seal strip is welded by submerged arc welding, the depth of submerged arc welding is ≥ 22mm, and then the The composite blank is subjected to vacuum treatment;
S4、加热：将四层复合坯送至加热炉，加热温度1150～1260℃，均热时间≥0.15×t分钟，加热总时间(1.0～2.0)×t分钟，t为复合坯总厚度，单位mm；S4. Heating: send the four-layer composite blank to the heating furnace, the heating temperature is 1150～1260℃, the soaking time is ≥0.15×t minutes, the total heating time is (1.0～2.0)×t minutes, t is the total thickness of the composite blank, unit mm;
S5、除鳞：复合坯进入轧机前除鳞箱至少除鳞1道次，若复合钢板需展宽，则粗轧首道次除鳞，最后1次转钢后连续除鳞2道，且精轧阶段连续除鳞2道；若复合钢板不展宽，则粗轧及精轧阶段的前两道次均除鳞；S5, descaling: before the composite billet enters the rolling mill, the descaling box is descaled at least one pass. If the composite steel plate needs to be widened, the first pass of rough rolling is to be descaled, and after the last transfer, two passes are continuously descaled, and the finish rolling is carried out. 2 consecutive steps of descaling; if the clad steel plate is not widened, the first two steps of rough rolling and finishing rolling are descaled;
S6、轧制：采用两阶段轧制法，粗轧采用低速大压下，粗轧轧制速度≤1.5m/s，成形道次压下率10％以上，粗轧总压下率65％以上；精轧阶段开轧温度900～980℃，终轧温度850～930℃；S6. Rolling: Two-stage rolling method is adopted. Rough rolling adopts low speed and large reduction, rough rolling rolling speed is less than or equal to 1.5m/s, the reduction rate of forming passes is more than 10%, and the total reduction rate of rough rolling is more than 65%. ; In the finishing rolling stage, the starting temperature is 900 to 980 °C, and the final rolling temperature is 850 to 930 °C;
S7、冷却：轧后高速抛钢，复合钢板进入超快冷设备以＞10℃/s的冷速冷却至600～700℃；S7. Cooling: After rolling, the steel is thrown at a high speed, and the clad steel plate enters the ultra-fast cooling equipment and is cooled to 600-700°C at a cooling rate of >10°C/s;
S8、矫直：对复合钢板进行矫直1～3道次，不平度≤5mm/m；然后送至冷床冷却，待复合钢板表面温度≤300℃时，即可下线；S8. Straightening: Straighten the clad steel plate for 1 to 3 passes, and the unevenness is ≤5mm/m; then send it to a cooling bed for cooling, and when the surface temperature of the clad steel plate is ≤300°C, it can be off the assembly line;
S9、切割分板：采用等离子或火焰切割设备对复合钢板的头、尾及两边进行切割，上、下两张复合钢板分离，再将上层复合钢板翻面，使覆层朝上；S9, cutting and splitting: use plasma or flame cutting equipment to cut the head, tail and both sides of the composite steel plate, separate the upper and lower composite steel plates, and then turn the upper composite steel plate over to make the cladding face up;
S10、单板矫直：分别对两张复合钢板进行矫直处理，保证不平度≤5mm/m；然后将覆层表面隔离剂打磨干净，即可获得高耐蚀容器用N08825复合钢板产品。S10. Veneer straightening: Straighten the two clad steel plates to ensure that the unevenness is ≤5mm/m; then polish the surface release agent of the cladding to clean the N08825 clad steel plate products for high corrosion-resistant containers.
各实施例钢板的基层化学成分如表1，各实施例钢板的覆层化学成分如表2，各实施例钢板的制备工艺参数如表3，各实施例钢板的各项性能如表4：The base chemical composition of each embodiment steel plate is shown in Table 1, the cladding chemical composition of each embodiment steel plate is shown in Table 2, the preparation process parameters of each embodiment steel plate are shown in Table 3, and the various properties of each embodiment steel plate are shown in Table 4:
表1实施例1-4钢板基层化学成分Table 1 Example 1-4 Chemical composition of steel plate base
Figure PCTCN2021096177-appb-000001
Figure PCTCN2021096177-appb-000001
表2实施例1-4钢板覆层化学成分Table 2 Examples 1-4 steel plate coating chemical composition
Figure PCTCN2021096177-appb-000002
Figure PCTCN2021096177-appb-000002
表3实施例1-4钢板制备工艺参数Table 3 embodiment 1-4 steel plate preparation process parameters
Figure PCTCN2021096177-appb-000003
Figure PCTCN2021096177-appb-000003
表4实施例1-4钢板各项性能Table 4 Various properties of steel plates in Examples 1-4
Figure PCTCN2021096177-appb-000004
Figure PCTCN2021096177-appb-000004
如图1所示，上面为覆层N08825，下面为基层Q345R，可见复合界面洁净、无夹杂，复合良好。As shown in Figure 1, the top is the coating layer N08825, and the bottom is the base layer Q345R. It can be seen that the composite interface is clean and free of inclusions, and the composite is good.
综上所述，本发明制备的高耐蚀容器用N08825复合钢板，有效地减少了N08825的使用量，可以作为纯N08825制造化工设备、石油储罐等的替代产品，在满足其实用性要求的同时，还延长了使用寿命，也极大地降低了生产成本，具有较高的经济效益。To sum up, the N08825 clad steel plate for high corrosion-resistant containers prepared by the present invention effectively reduces the amount of N08825 used, and can be used as a substitute for pure N08825 for manufacturing chemical equipment, petroleum storage tanks, etc. At the same time, the service life is prolonged, the production cost is greatly reduced, and the utility model has high economic benefits.
除上述实施例外，本发明还可以有其他实施方式。凡采用等同替换或等效变换形成的技术方案，均落在本发明要求的保护范围。In addition to the above-described embodiments, the present invention may also have other embodiments. All technical solutions formed by equivalent replacement or equivalent transformation fall within the protection scope of the present invention.

Claims (6)

  1. 一种高耐蚀容器用N08825复合钢板，其特征在于：包括基层与覆层，两者之间呈冶金结合状态，A N08825 composite steel plate for high corrosion-resistant containers, characterized in that it includes a base layer and a cladding layer, and the two are in a metallurgical bonding state,
    基层化学成分及质量百分比如下：C≤0.20％，Si≤0.55％，Mn：0.5％～1.7％，Cu≤0.30％，Ni≤0.30％，Cr≤0.30％，Mo≤0.08％，Nb≤0.050％，V≤0.050％，Ti≤0.030％，Alt≥0.020％，P≤0.025％，S≤0.010％，Cu+Ni+Cr+Mo≤0.70％，余量为Fe及少量不可避免的杂质；The chemical composition and mass percentage of the base layer are as follows: C≤0.20%, Si≤0.55%, Mn: 0.5%～1.7%, Cu≤0.30%, Ni≤0.30%, Cr≤0.30%, Mo≤0.08%, Nb≤0.050% , V≤0.050%, Ti≤0.030%, Alt≥0.020%, P≤0.025%, S≤0.010%, Cu+Ni+Cr+Mo≤0.70%, the balance is Fe and a small amount of inevitable impurities;
    覆层为N08825，其化学成分及质量百分比如下：Ni：38.0％～46.0％，Cr：19.5％～23.5％，Fe≥22.0％，Mn≤1.00％，C≤0.05％，Cu：1.5％～3.0％，Si≤0.5％，S≤0.030％，Al≤0.2％，Ti：0.6％～1.2％，Mo：2.5％～3.5％。The coating is N08825, and its chemical composition and mass percentage are as follows: Ni: 38.0%～46.0%, Cr: 19.5%～23.5%, Fe≥22.0%, Mn≤1.00%, C≤0.05%, Cu: 1.5%～3.0 %, Si≤0.5%, S≤0.030%, Al≤0.2%, Ti: 0.6%～1.2%, Mo: 2.5%～3.5%.
  2. 根据权利要求1所述的一种高耐蚀容器用N08825复合钢板，其特征在于：复合钢板总厚度为10～60mm，覆层厚度为1.0～6.0mm。The N08825 composite steel plate for high corrosion-resistant containers according to claim 1, characterized in that: the total thickness of the composite steel plate is 10-60 mm, and the coating thickness is 1.0-6.0 mm.
  3. 一种高耐蚀容器用N08825复合钢板的制备方法，其特征在于：应用于权利要求1-2任意一项，具体包括如下步骤：A preparation method of N08825 clad steel plate for high corrosion-resistant containers, characterized in that: applied to any one of claims 1-2, and specifically comprising the following steps:
    S1、坯料加工：根据成品复合钢板的材质、规格，准备基层和覆层坯料各一对，覆层坯料尺寸小于基层坯料；用砂带对基层和覆层坯料的待结合面进行打磨处理，清除表面油污、氧化铁皮；S1. Billet processing: According to the material and specification of the finished composite steel plate, prepare a pair of base layer and cladding blank, and the size of the cladding blank is smaller than that of the base layer blank; use an abrasive belt to grind the to-be-bonded surface of the base layer and the cladding blank to remove Surface oil, iron oxide scale;
    S1、隔离剂涂刷：分别在两块覆层坯料的非结合表面均匀涂刷隔离剂，然后烘干处理；S1, release agent brushing: apply release agent evenly on the non-bonded surfaces of the two cladding blanks respectively, and then dry them;
    S3、组坯焊接：按照对称组坯方式以基层-覆层-覆层-基层的顺序堆放坯料，采用封条将上、下基层的四周点焊固定，封条高度为中间两块覆层的厚度之和，每边封条长度为基层边长，由此中间两块覆层处在封条围成的槽内；采用埋弧焊将基层与封条间的缝隙进行焊接，埋弧焊深度≥22mm，然后对复合坯进行抽真空处理；S3. Welding of blanks: stack the blanks in the order of base layer - cladding layer - covering layer - base layer according to the symmetrical method of forming blanks, and use seals to fix the upper and lower base layers by spot welding. The height of the seal is the thickness of the two middle cladding layers. And, the length of each seal strip is the length of the base layer, so the two middle cladding layers are in the groove enclosed by the seal strip; the gap between the base layer and the seal strip is welded by submerged arc welding, the depth of submerged arc welding is ≥ 22mm, and then the The composite blank is subjected to vacuum treatment;
    S4、加热：将四层复合坯送至加热炉，加热温度1150～1260℃，均热时间≥0.15×t分钟，加热总时间(1.0～2.0)×t分钟，t为复合坯总厚度，单位mm；S4. Heating: send the four-layer composite blank to the heating furnace, the heating temperature is 1150～1260℃, the soaking time is ≥0.15×t minutes, the total heating time is (1.0～2.0)×t minutes, t is the total thickness of the composite blank, unit mm;
    S5、除鳞：复合坯进入轧机前除鳞箱至少除鳞1道次，粗轧及精轧阶段均需除鳞；S5, descaling: before the composite billet enters the rolling mill, the descaling box needs at least one pass of descaling, and descaling is required in both rough rolling and finishing rolling;
    S6、轧制：采用两阶段轧制法，粗轧采用低速大压下，成形道次压下率10％以上，粗轧总压下率65％以上；精轧阶段开轧温度900～980℃，终轧温度850～930℃；S6. Rolling: Two-stage rolling method is adopted, low-speed and high-pressure reduction is used for rough rolling, the reduction rate of forming passes is more than 10%, and the total reduction rate of rough rolling is more than 65%; the rolling temperature in the finishing rolling stage is 900-980 ℃ , the final rolling temperature is 850～930℃;
    S7、冷却：轧后高速抛钢，复合钢板进入超快冷设备以＞10℃/s的冷速冷却至600～700℃；S7. Cooling: After rolling, the steel is thrown at a high speed, and the clad steel plate enters the ultra-fast cooling equipment and is cooled to 600-700°C at a cooling rate of >10°C/s;
    S8、矫直：对复合钢板进行矫直1～3道次，不平度≤5mm/m；然后送至冷床冷却，待复合钢板表面温度≤300℃时，即可下线；S8. Straightening: Straighten the clad steel plate for 1 to 3 passes, and the unevenness is ≤5mm/m; then send it to a cooling bed for cooling, and when the surface temperature of the clad steel plate is ≤300°C, it can be off the assembly line;
    S9、切割分板：采用等离子或火焰切割设备对复合钢板的头、尾及两边进行切割，上、下两张复合钢板分离，再将上层复合钢板翻面，使覆层朝上；S9, cutting and splitting: use plasma or flame cutting equipment to cut the head, tail and both sides of the composite steel plate, separate the upper and lower composite steel plates, and then turn the upper composite steel plate over to make the cladding face up;
    S10、单板矫直：分别对两张复合钢板进行矫直处理，保证不平度≤5mm/m；然后将覆层表面隔离剂打磨干净，即可获得高耐蚀容器用N08825复合钢板产品。S10. Veneer straightening: Straighten the two clad steel plates to ensure that the unevenness is ≤5mm/m; then polish the surface release agent of the cladding to clean the N08825 clad steel plate products for high corrosion-resistant containers.
  4. 根据权利要求3所述的一种高耐蚀容器用N08825复合钢板的制备方法，其特征在于：所述步骤S2中，烘干温度范围300～800℃。The method for preparing a N08825 composite steel plate for a high corrosion-resistant container according to claim 3, characterized in that: in the step S2, the drying temperature ranges from 300 to 800°C.
  5. 根据权利要求3所述的一种高耐蚀容器用N08825复合钢板的制备方法，其特征在于：所述步骤S5中，若复合钢板需展宽，则粗轧首道次除鳞，最后1次转钢后连续除鳞2道，且精轧阶段连续除鳞2道；若复合钢板不展宽，则粗轧及精轧阶段的前两道次均除鳞。The method for preparing a N08825 clad steel plate for high corrosion-resistant containers according to claim 3, characterized in that: in the step S5, if the clad steel plate needs to be widened, the first pass of rough rolling is descaled, and the last pass of rolling is performed. After the steel, 2 successive descaling steps are performed, and 2 successive descaling steps are performed in the finishing rolling stage; if the clad steel plate is not widened, the first two steps of the rough rolling and finishing rolling stages are descaled.
  6. 根据权利要求3所述的一种高耐蚀容器用N08825复合钢板的制备方法，其特征在于：所述步骤S6中，粗轧轧制速度≤1.5m/s。The method for preparing a N08825 clad steel plate for high corrosion-resistant containers according to claim 3, characterized in that: in the step S6, the rough rolling speed is less than or equal to 1.5 m/s.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116099875A (en) * 2023-04-12 2023-05-12 江苏省沙钢钢铁研究院有限公司 Stainless steel composite board with excellent plate shape and preparation method thereof

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112721349A (en) * 2020-11-27 2021-04-30 南京钢铁股份有限公司 N08825 composite steel plate for high-corrosion-resistance container and preparation method thereof
CN114134401A (en) * 2021-05-11 2022-03-04 江阴兴澄特种钢铁有限公司 P355GH steel plate for papermaking drying cylinder and manufacturing method thereof
CN113182373B (en) * 2021-05-18 2023-05-09 山西太钢不锈钢股份有限公司 Extrusion method of nickel-based alloy seamless steel tube

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06234083A (en) * 1993-02-09 1994-08-23 Yamaki Kogyo Kk Titanium clad stainless steel plate and its production
CN201626141U (en) * 2009-12-31 2010-11-10 四川惊雷科技股份有限公司 NO8825 nickel-based alloy clad steel plate
CN104138920A (en) * 2014-06-26 2014-11-12 济钢集团有限公司 Method for manufacturing rolled metal composite plate with pipeline steel as base material
CN106271414A (en) * 2016-08-23 2017-01-04 南京钢铁股份有限公司 A kind of preparation method of TMCP type bridge stainless steel clad plate
CN106807752A (en) * 2017-03-02 2017-06-09 番禺珠江钢管（连云港）有限公司 A kind of composite metal plate is prepared and rolling integrated-type production system and preparation method
CN107775280A (en) * 2016-08-29 2018-03-09 中国石油天然气集团公司 A kind of manufacture method of N08825 nickel-base alloys composite-curve
CN108723712A (en) * 2018-05-29 2018-11-02 南京钢铁股份有限公司 A kind of high anti-corrosion container super austenitic stainless steel composite plate and preparation method
CN112721349A (en) * 2020-11-27 2021-04-30 南京钢铁股份有限公司 N08825 composite steel plate for high-corrosion-resistance container and preparation method thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109694989B (en) * 2017-10-20 2020-09-01 鞍钢股份有限公司 825/X70 nickel-based alloy composite plate and production method thereof
CN107914439B (en) * 2017-12-28 2023-07-04 安徽中钢联新材料有限公司 Assembly structure and method for rolling titanium composite steel plate by vacuum blank making

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06234083A (en) * 1993-02-09 1994-08-23 Yamaki Kogyo Kk Titanium clad stainless steel plate and its production
CN201626141U (en) * 2009-12-31 2010-11-10 四川惊雷科技股份有限公司 NO8825 nickel-based alloy clad steel plate
CN104138920A (en) * 2014-06-26 2014-11-12 济钢集团有限公司 Method for manufacturing rolled metal composite plate with pipeline steel as base material
CN106271414A (en) * 2016-08-23 2017-01-04 南京钢铁股份有限公司 A kind of preparation method of TMCP type bridge stainless steel clad plate
CN107775280A (en) * 2016-08-29 2018-03-09 中国石油天然气集团公司 A kind of manufacture method of N08825 nickel-base alloys composite-curve
CN106807752A (en) * 2017-03-02 2017-06-09 番禺珠江钢管（连云港）有限公司 A kind of composite metal plate is prepared and rolling integrated-type production system and preparation method
CN108723712A (en) * 2018-05-29 2018-11-02 南京钢铁股份有限公司 A kind of high anti-corrosion container super austenitic stainless steel composite plate and preparation method
CN112721349A (en) * 2020-11-27 2021-04-30 南京钢铁股份有限公司 N08825 composite steel plate for high-corrosion-resistance container and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116099875A (en) * 2023-04-12 2023-05-12 江苏省沙钢钢铁研究院有限公司 Stainless steel composite board with excellent plate shape and preparation method thereof
CN116099875B (en) * 2023-04-12 2023-07-04 江苏省沙钢钢铁研究院有限公司 Stainless steel composite board with excellent plate shape and preparation method thereof

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