WO2022105331A1 - Integrally-formed tungsten alloy bionic bait body and preparation process therefor - Google Patents
Integrally-formed tungsten alloy bionic bait body and preparation process therefor Download PDFInfo
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- WO2022105331A1 WO2022105331A1 PCT/CN2021/113484 CN2021113484W WO2022105331A1 WO 2022105331 A1 WO2022105331 A1 WO 2022105331A1 CN 2021113484 W CN2021113484 W CN 2021113484W WO 2022105331 A1 WO2022105331 A1 WO 2022105331A1
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- bait body
- powder
- tungsten alloy
- integrally formed
- fish bait
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- 239000011664 nicotinic acid Substances 0.000 title claims abstract description 72
- 229910001080 W alloy Inorganic materials 0.000 title claims abstract description 46
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 32
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 31
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 30
- 238000001746 injection moulding Methods 0.000 claims abstract description 29
- 239000002994 raw material Substances 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 claims abstract description 12
- 238000000465 moulding Methods 0.000 claims description 56
- 238000005238 degreasing Methods 0.000 claims description 53
- 239000002245 particle Substances 0.000 claims description 52
- 241000251468 Actinopterygii Species 0.000 claims description 46
- 239000003795 chemical substances by application Substances 0.000 claims description 39
- 239000011812 mixed powder Substances 0.000 claims description 39
- 239000012298 atmosphere Substances 0.000 claims description 28
- 238000005245 sintering Methods 0.000 claims description 25
- 239000001257 hydrogen Substances 0.000 claims description 24
- 229910052739 hydrogen Inorganic materials 0.000 claims description 24
- 239000008188 pellet Substances 0.000 claims description 24
- 238000010438 heat treatment Methods 0.000 claims description 17
- 238000002156 mixing Methods 0.000 claims description 10
- 230000001681 protective effect Effects 0.000 claims description 6
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 229910052786 argon Inorganic materials 0.000 claims description 2
- 239000001307 helium Substances 0.000 claims description 2
- 229910052734 helium Inorganic materials 0.000 claims description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 238000005303 weighing Methods 0.000 claims 1
- 239000002699 waste material Substances 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 2
- 239000003344 environmental pollutant Substances 0.000 abstract description 2
- 231100000719 pollutant Toxicity 0.000 abstract description 2
- 229910001220 stainless steel Inorganic materials 0.000 abstract description 2
- 238000004062 sedimentation Methods 0.000 abstract 2
- 238000003754 machining Methods 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 22
- 230000001788 irregular Effects 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 7
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- 238000000034 method Methods 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
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- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
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- 229910052759 nickel Inorganic materials 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; CARE OF BIRDS, FISHES, INSECTS; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K85/00—Artificial bait for fishing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/1017—Multiple heating or additional steps
- B22F3/1021—Removal of binder or filler
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/22—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces for producing castings from a slip
- B22F3/225—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces for producing castings from a slip by injection molding
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C27/00—Alloys based on rhenium or a refractory metal not mentioned in groups C22C14/00 or C22C16/00
- C22C27/04—Alloys based on tungsten or molybdenum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
Definitions
- the invention relates to the technical field of fishing gear, in particular to an integrally formed tungsten alloy bionic fish bait body and a preparation process thereof.
- the invention patent with publication number CN101720745B discloses a production process of a tungsten-based fish sinker, which uses three metal powder mixtures of W, Ni and Fe and polyamide as raw materials, the finished product is made by an injection molding process, but this kind of The wire lug strength of the product prepared by the method is weak, and the dimensional accuracy is not high, which affects the use effect.
- the first aspect the preparation technology of a kind of integral molding type tungsten alloy bionic fish bait body provided by the invention, comprises the steps:
- the average particle size of the tungsten powder is 1-5 ⁇ m.
- the average particle size of the nickel powder is 1-5 ⁇ m.
- the average particle size of the iron powder is 1-10 ⁇ m.
- the raw materials described in step (1) include: 70-97% of tungsten powder, 2-20% of nickel powder, and the balance of iron powder.
- the dosage of the molding agent is 3-10% of the total weight of the mixed powder and the molding agent.
- the heating rate of the thermal degreasing furnace is 1-10°C/min.
- the protective atmosphere is selected from one or more of hydrogen, nitrogen, helium and argon.
- the heating rate of the sintering furnace is 5-10°C/min.
- the sintering temperature after the heating of the sintering furnace is 1350-1500°C.
- the density of the integrally formed tungsten alloy fishing bait is 10-18.6 g/cm 3 .
- a bionic fish bait body provided by the present invention is obtained by the preparation process of the integrated tungsten alloy bionic fish bait described in the first aspect, and the bionic fish bait body is composed of a bionic fish bait body and at least one One-piece structure composed of wire lugs.
- the density of the bionic fish bait body made from tungsten alloy is large, the inertia of the bionic fish bait body of the present invention in water is larger than the inertia of the traditional bionic fish bait (material is usually lead) of the same volume, the present invention
- the settling speed of the bionic fish bait in the water is fast, which is more conducive to the user to grasp the settlement point of the fish bait;
- the present invention replaces traditional materials (such as lead, etc.) with tungsten alloy, which is more environmentally friendly;
- the tungsten alloy bionic fish bait body provided by the present invention has high strength, especially the wire lugs have excellent impact resistance, high dimensional accuracy and good practical use effect.
- FIG. 1 is a schematic structural diagram of an integrally formed tungsten alloy bionic fish bait body provided by an embodiment of the present invention.
- the finished product was prepared according to Example 1 of the invention patent with publication number CN101720745B.
- the present invention has also carried out the following tests on the products obtained from the above-mentioned embodiments and comparative examples:
- Density test use a two-dimensional projector for size test, and then use a precision balance for density test;
Abstract
Disclosed in the present invention are an integrally-formed tungsten alloy bionic bait body and a preparation process therefor. According to the present invention, the density of a bionic bait body prepared by taking tungsten powder, nickel powder, and iron powder as raw materials is large, the inertia of the bionic bait in water is larger than that of a conventional bionic bait having the same volume (the material is usually lead), and the sedimentation speed of the bionic bait in the water is high, which is more conducive to a user to master a sedimentation point of the bait; in the present invention, a tungsten alloy is used to replace a conventional material (such as lead), which is more environmentally friendly; the tungsten alloy bionic bait provided by the present invention is high in strength and excellent in impact resistance; the preparation process of the present invention is reasonable and scientific; the bionic bait body and a wire lug are integrally formed by using an injection molding process, so that the bionic bait body and the wire lug are not prone to falling off and are firm and stable, and no waste and waste acid and other pollutants are generated; and the step of machining and assembling a stainless steel wire lug does not need to be added subsequently, so that the production efficiency is high, and costs are reduced.
Description
INTEGRALLY-FORMED TUNGSTEN ALLOY BIONIC FISH BAIT BODY AND PREPARATION PROCESS THEREOFINTEGRALLY-FORMED TUNGSTEN ALLOY BIONIC FISH BAIT BODY AND PREPARATION PROCESS THEREOF
Integrally-formed tungsten alloy bionic fish bait body and manufacturing process thereofIntegrally-formed tungsten alloy bionic fish bait body and manufacturing process thereof
本发明涉及渔具技术领域,特别涉及一种一体成型式钨合金仿生鱼饵料本体及其制备工艺。The invention relates to the technical field of fishing gear, in particular to an integrally formed tungsten alloy bionic fish bait body and a preparation process thereof.
近年来随着人们生活水平的提高,钓鱼运动随之兴起,其中鱼饵包括活饵以及仿生鱼饵料本体等,仿生鱼饵料本体以其方便快捷赢得了一片好评,不需要每次进行穿饵等动作,可以直接进行拋投动作。但是现有的仿生鱼饵料本体包括鱼饵本体以及线耳,现有的鱼饵本体大多采用铅来生产,线耳多为钢丝结构,鱼饵本体和线耳焊接在一起,或者通过化学粘合剂黏结,这种仿生鱼饵存在生产效率低、不环保、鱼饵本体和线耳易脱落等缺陷。而公开号为CN101720745B的发明专利虽然公开了一种钨基鱼坠的制作工艺,以W、Ni和Fe三种金属粉末混合物和聚酰胺为原料,采用注塑成型工艺制成成品,但是采用这种方法制得的产品的线耳强度较弱,而且尺寸精度不高,影响使用效果。In recent years, with the improvement of people's living standards, fishing sports have emerged. Among them, the bait includes live bait and bionic bait body. , you can directly perform the throwing action. However, the existing bionic bait body includes a bait body and a wire lug. Most of the existing bait bodies are produced with lead, and the wire lugs are mostly steel wire structures. The lure body and the wire lugs are welded together or bonded by chemical adhesives. The bionic bait has defects such as low production efficiency, unenvironmental protection, and easy falling off of the bait body and the wire ear. Although the invention patent with publication number CN101720745B discloses a production process of a tungsten-based fish sinker, which uses three metal powder mixtures of W, Ni and Fe and polyamide as raw materials, the finished product is made by an injection molding process, but this kind of The wire lug strength of the product prepared by the method is weak, and the dimensional accuracy is not high, which affects the use effect.
发明内容SUMMARY OF THE INVENTION
本发明的目的在于提供一种一体成型式钨合金仿生鱼饵料本体及其制备工艺,以解决上述技术问题。The purpose of the present invention is to provide an integrally formed tungsten alloy bionic fish bait body and a preparation process thereof, so as to solve the above-mentioned technical problems.
为了实现上述目的,本发明的技术方案为:In order to achieve the above object, the technical scheme of the present invention is:
第一方面,本发明提供的一种一体成型式钨合金仿生鱼饵料本体的制备工艺,包括如下 步骤:The first aspect, the preparation technology of a kind of integral molding type tungsten alloy bionic fish bait body provided by the invention, comprises the steps:
(1)称取下述按重量百分比计的原料:钨粉35~97%、镍粉2~35%、铁粉余量;(1) Weigh the following raw materials by weight: 35-97% of tungsten powder, 2-35% of nickel powder, and balance of iron powder;
(2)将钨粉、镍粉和铁粉加入混料机中混合3~20小时,得到混合粉体;(2) adding tungsten powder, nickel powder and iron powder into the mixer and mixing for 3-20 hours to obtain mixed powder;
(3)将所得的混合粉体和成型剂放入密炼机中,加热至110~130℃搅拌0.5~4小时,然后将物料倒出,再自然冷却至室温倒入破碎机中破碎得到破碎粒料;(3) Put the obtained mixed powder and molding agent into an internal mixer, heat to 110~130℃ and stir for 0.5~4 hours, then pour out the material, then naturally cool to room temperature and pour it into a crusher for crushing to obtain crushing pellets;
(4)将所得的破碎粒料加入注射成型机中,加热至110~130℃,通过注射成型得到要求产品成型坯料;(4) adding the obtained crushed pellets into an injection molding machine, heating to 110-130° C., and obtaining the required product molding blanks by injection molding;
(5)将成型坯料放入热脱脂炉,在真空或保护气氛中升温至800~1000℃,保温烧结30~120分钟,再自然冷却至室温得到脱脂坯料;(5) Put the formed blank into a thermal degreasing furnace, heat it up to 800-1000°C in a vacuum or a protective atmosphere, keep sintered for 30-120 minutes, and then naturally cool to room temperature to obtain a degreasing blank;
(6)将脱脂坯料放入烧结炉,在真空或保护气氛中升温至1300~1520℃,保温烧结60~180分钟,再自然冷却至室温得到一体成型式钨合金仿生鱼饵料本体。(6) Put the degreasing blank into a sintering furnace, heat it up to 1300-1520°C in a vacuum or a protective atmosphere, keep sintered for 60-180 minutes, and then naturally cool to room temperature to obtain an integrally formed tungsten alloy bionic fish bait body.
优选的,所述钨粉的平均粒径为1~5μm。Preferably, the average particle size of the tungsten powder is 1-5 μm.
优选的,所述镍粉的平均粒径为1~5μm。Preferably, the average particle size of the nickel powder is 1-5 μm.
优选的,所述铁粉的平均粒径为1~10μm。Preferably, the average particle size of the iron powder is 1-10 μm.
优选的,步骤(1)所述的原料,按重量百分比计,包括:钨粉70~97%、镍粉2~20%、铁粉余量。Preferably, the raw materials described in step (1), in terms of weight percentages, include: 70-97% of tungsten powder, 2-20% of nickel powder, and the balance of iron powder.
优选的,所述成型剂的用量为所述混合粉体和所述成型剂的总重量的3~10%。Preferably, the dosage of the molding agent is 3-10% of the total weight of the mixed powder and the molding agent.
优选的,所述破碎粉料的粒径不大于10mm。Preferably, the particle size of the crushed powder is not greater than 10 mm.
优选的,所述热脱脂炉的升温速率为1~10℃/min。Preferably, the heating rate of the thermal degreasing furnace is 1-10°C/min.
优选的,所述保护气氛选自氢气、氮气、氦气和氩气中的一种或多种。Preferably, the protective atmosphere is selected from one or more of hydrogen, nitrogen, helium and argon.
优选的,所述烧结炉的升温速率为5~10℃/min。Preferably, the heating rate of the sintering furnace is 5-10°C/min.
优选的,所述烧结炉升温后的烧结温度为1350~1500℃。Preferably, the sintering temperature after the heating of the sintering furnace is 1350-1500°C.
优选的,所述一体成型式钨合金鱼饵料的密度为10~18.6g/cm
3。
Preferably, the density of the integrally formed tungsten alloy fishing bait is 10-18.6 g/cm 3 .
第二方面,本发明提供的一种仿生鱼饵料本体为采用如第一方面所述的一体成型式钨合金仿生鱼饵的制备工艺制得,所述仿生鱼饵料本体为由仿生鱼饵本体及至少一个线耳组成的一体成型式结构。In the second aspect, a bionic fish bait body provided by the present invention is obtained by the preparation process of the integrated tungsten alloy bionic fish bait described in the first aspect, and the bionic fish bait body is composed of a bionic fish bait body and at least one One-piece structure composed of wire lugs.
与现有技术相比,本发明的有益效果在于:Compared with the prior art, the beneficial effects of the present invention are:
(1)以钨合金为原料制得的仿生鱼饵料本体的密度大,本发明的仿生鱼饵料本体在水中的惯性比同体积的传统仿生鱼饵料(材质通常为铅)的惯性大,本发明的仿生鱼饵料在水中的沉降速度快,更有利于使用者掌握鱼饵料的沉降点;(1) the density of the bionic fish bait body made from tungsten alloy is large, the inertia of the bionic fish bait body of the present invention in water is larger than the inertia of the traditional bionic fish bait (material is usually lead) of the same volume, the present invention The settling speed of the bionic fish bait in the water is fast, which is more conducive to the user to grasp the settlement point of the fish bait;
(2)本发明以钨合金取代传统材料(如铅等),更环保;(2) The present invention replaces traditional materials (such as lead, etc.) with tungsten alloy, which is more environmentally friendly;
(3)本发明提供的钨合金仿生鱼饵料本体的强度高,特别是线耳的耐冲击性优异,尺寸精度高,实际使用效果好。(3) The tungsten alloy bionic fish bait body provided by the present invention has high strength, especially the wire lugs have excellent impact resistance, high dimensional accuracy and good practical use effect.
(4)本发明的制备工艺流程合理科学,采用注射成型的工艺使仿生鱼饵本体和线耳一体成型,不易脱落,坚固稳定,而且无废料、废酸等污染物,后续不需要增加机械加工和装配不锈钢线耳工序,生产效率高。(4) The preparation process of the present invention is reasonable and scientific, and the bionic bait body and the wire lug are integrally formed by the injection molding process, which is not easy to fall off, is firm and stable, and has no waste, waste acid and other pollutants. The process of assembling stainless steel wire lugs has high production efficiency.
图1为本发明实施例提供的一体成型式钨合金仿生鱼饵料本体的结构示意图。1 is a schematic structural diagram of an integrally formed tungsten alloy bionic fish bait body provided by an embodiment of the present invention.
下面对本发明的具体实施方式作进一步说明。在此需要说明的是,对于这些实施方式的说明用于帮助理解本发明,但并不构成对本发明的限定。此外,下面所描述的本发明各个实施方式中所涉及的技术特征只要彼此之间未构成冲突就可以相互组合。The specific embodiments of the present invention will be further described below. It should be noted here that the descriptions of these embodiments are used to help the understanding of the present invention, but do not constitute a limitation of the present invention. In addition, the technical features involved in the various embodiments of the present invention described below can be combined with each other as long as they do not conflict with each other.
实施例1Example 1
本实施例提供的一体成型式钨合金鱼饵料的制备工艺,包括如下步骤:The preparation process of the one-piece tungsten alloy fishing bait provided by this embodiment includes the following steps:
(1)称取下述按重量百分比计的原料:钨粉(平均粒径为2.5μm)78%、镍粉(平均粒径为3μm)16%、铁粉(平均粒径为4μm)余量;(1) Weigh the following raw materials by weight percentage: tungsten powder (average particle size is 2.5 μm) 78%, nickel powder (average particle size is 3 μm) 16%, iron powder (average particle size is 4 μm) balance ;
(2)将钨粉、镍粉和铁粉加入混料机中混合10小时,得到混合粉体;(2) adding tungsten powder, nickel powder and iron powder into the mixer and mixing for 10 hours to obtain mixed powder;
(3)将所得的混合粉体和成型剂放入密炼机中,其中,成型剂的用量为混合粉体和成型剂的总重量的6%,加热至120℃搅拌1小时,然后将物料倒出,再自然冷却至室温倒入破碎机中破碎得到粒径为10mm以下且形状不规则的粒料;(3) put the obtained mixed powder and the molding agent into the internal mixer, wherein, the consumption of the molding agent is 6% of the total weight of the mixed powder and the molding agent, heated to 120 ° C and stirred for 1 hour, and then the material Pour out, then naturally cool to room temperature and pour into a crusher to be crushed to obtain pellets with a particle size of less than 10 mm and an irregular shape;
(4)将所得的破碎粒料加入注射成型机中,加热至120℃,通过注射成型后得到成型坯料;(4) adding the obtained broken pellets into an injection molding machine, heating to 120° C., and obtaining a molding blank after injection molding;
(5)将成型坯料放入热脱脂炉,在氢气气氛中以4℃/min的速率升温至900℃,保温脱脂60分钟,再自然冷却至室温得到脱脂坯料;(5) put the formed blank into a thermal degreasing furnace, heat up to 900° C. at a rate of 4° C./min in a hydrogen atmosphere, hold the temperature for 60 minutes, and then naturally cool to room temperature to obtain a degreasing blank;
(6)将脱脂坯料放入烧结炉,在氢气气氛中以8℃/min的速率升温至1450℃,保温烧结120分钟,再自然冷却至室温得到一体成型式钨合金鱼饵料(其结构如图1所示,由仿生鱼饵本体1及两个线耳2组成的一体成型式结构)。(6) Put the degreasing billet into the sintering furnace, heat it up to 1450°C at a rate of 8°C/min in a hydrogen atmosphere, keep sintering for 120 minutes, and then naturally cool to room temperature to obtain an integrated tungsten alloy fishing bait (its structure is shown in the figure). 1, an integrally formed structure composed of a bionic bait body 1 and two wire lugs 2).
实施例2Example 2
本实施例提供的一体成型式钨合仿生鱼饵料本体的制备工艺,包括如下步骤:The preparation process of the integrally formed tungsten composite bionic fish bait body provided by this embodiment includes the following steps:
(1)称取下述按重量百分比计的原料:钨粉(平均粒径为3.5μm)93%、镍粉(平均粒 径为7μm)7%、铁粉(平均粒径为10μm)余量;(1) Weigh the following raw materials by weight percentage: tungsten powder (average particle size is 3.5 μm) 93%, nickel powder (average particle size is 7 μm) 7%, iron powder (average particle size is 10 μm) balance ;
(2)将钨粉、镍粉和铁粉加入混料机中混合15小时,得到混合粉体;(2) adding tungsten powder, nickel powder and iron powder into the mixer and mixing for 15 hours to obtain mixed powder;
(3)将所得的混合粉体和成型剂放入密炼机中,其中,成型剂的用量为混合粉体和成型剂的总重量的8%,加热至110℃搅拌4小时,然后将物料倒出,再自然冷却至室温倒入破碎机中破碎得到粒径为10mm以下且形状不规则的粒料;(3) put the obtained mixed powder and the molding agent into the internal mixer, wherein, the consumption of the molding agent is 8% of the total weight of the mixed powder and the molding agent, heated to 110 ° C and stirred for 4 hours, then the material Pour out, then naturally cool to room temperature and pour into a crusher to be crushed to obtain pellets with a particle size of less than 10 mm and an irregular shape;
(4)将所得的粒料加入注射成型机中,加热至110℃,通过注射成型得到成型坯料;(4) adding the obtained pellets into an injection molding machine, heating to 110° C., and obtaining a molding blank by injection molding;
(5)将成型坯料放入热脱脂炉,在氢气气氛中以3℃/min的速率升温至900℃,保温脱脂120分钟,再自然冷却至室温得到脱脂坯料;(5) putting the forming blank into a thermal degreasing furnace, heating up to 900 ℃ at a rate of 3 ℃/min in a hydrogen atmosphere, degreasing for 120 minutes, and then naturally cooled to room temperature to obtain a degreasing blank;
(6)将脱脂坯料放入烧结炉,在氢气气氛中以6℃/min的速率升温至1420℃,保温烧结120分钟,再自然冷却至室温得到一体成型式钨合金仿生鱼饵料本体(其结构如图1所示,由仿生鱼饵本体1及两个线耳2组成的一体成型式结构)。(6) Put the degreasing blank into the sintering furnace, heat it up to 1420°C at a rate of 6°C/min in a hydrogen atmosphere, keep sintering for 120 minutes, and then naturally cool to room temperature to obtain an integrally formed tungsten alloy bionic fish bait body (its structure As shown in Fig. 1, an integrally formed structure composed of a bionic bait body 1 and two wire lugs 2).
实施例3Example 3
本实施例提供的一体成型式钨合金仿生鱼饵料本体的制备工艺,包括如下步骤:The preparation process of the integrally formed tungsten alloy bionic fish bait body provided by this embodiment includes the following steps:
(1)称取下述按重量百分比计的原料:钨粉(平均粒径为5μm)97%、镍粉(平均粒径为5μm)2.1%、铁粉(平均粒径为5μm)余量;(1) Weigh the following raw materials by weight: 97% of tungsten powder (average particle size is 5 μm), nickel powder (average particle size is 5 μm) 2.1%, iron powder (average particle size is 5 μm) remainder;
(2)将钨粉、镍粉和铁粉加入混料机中混合10小时,得到混合粉体;(2) adding tungsten powder, nickel powder and iron powder into the mixer and mixing for 10 hours to obtain mixed powder;
(3)将所得的混合粉体和成型剂放入密炼机中,其中,成型剂的用量为混合粉体和成型剂的总重量的3.5%,加热至130℃搅拌1.5小时,然后将物料倒出,再自然冷却至室温倒入破碎机中破碎得到粒径为10mm以下且形状不规则的粒料;(3) put the obtained mixed powder and the molding agent into the internal mixer, wherein, the consumption of the molding agent is 3.5% of the total weight of the mixed powder and the molding agent, heated to 130 ° C and stirred for 1.5 hours, and then the material Pour out, then naturally cool to room temperature and pour into a crusher to be crushed to obtain pellets with a particle size of less than 10 mm and an irregular shape;
(4)将所得的粒料加入注射成型机中,加热至130℃,通过注射成型得到成型坯料;(4) adding the obtained pellets into an injection molding machine, heating to 130° C., and obtaining a molding blank by injection molding;
(5)将成型坯料放入热脱脂炉,在氢气气氛中以4℃/min的速率升温至900℃,保温脱脂70分钟,再自然冷却至室温得到脱脂坯料;(5) put the formed blank into a thermal degreasing furnace, heat up to 900° C. at a rate of 4° C./min in a hydrogen atmosphere, keep degreasing for 70 minutes, and then naturally cool to room temperature to obtain a degreasing blank;
(6)将脱脂坯料放入烧结炉,在氢气气氛中以8℃/min的速率升温至1500℃,保温烧结120分钟,再自然冷却至室温得到一体成型式钨合金仿生鱼饵料本体(其结构如图1所示,由仿生鱼饵本体1及两个线耳2组成的一体成型式结构)。(6) Put the degreasing blank into the sintering furnace, heat it up to 1500°C at a rate of 8°C/min in a hydrogen atmosphere, keep sintered for 120 minutes, and then naturally cool to room temperature to obtain an integrally formed tungsten alloy bionic fish bait body (its structure As shown in Fig. 1, an integrally formed structure composed of a bionic bait body 1 and two wire lugs 2).
实施例4Example 4
本实施例提供的一体成型式钨合金仿生鱼饵料本体的制备工艺,包括如下步骤:The preparation process of the integrally formed tungsten alloy bionic fish bait body provided by this embodiment includes the following steps:
(1)称取下述按重量百分比计的原料:钨粉(平均粒径为2.5μm)80%、镍粉(平均粒径为3μm)14%、铁粉(平均粒径为4μm)余量;(1) Weigh the following raw materials by weight: 80% tungsten powder (average particle size is 2.5 μm), nickel powder (average particle size is 3 μm) 14%, iron powder (average particle size is 4 μm) balance ;
(2)将钨粉、镍粉和铁粉加入混料机中混合10小时,得到混合粉体;(2) adding tungsten powder, nickel powder and iron powder into the mixer and mixing for 10 hours to obtain mixed powder;
(3)将所得的混合粉体和成型剂放入密炼机中,其中,成型剂的用量为混合粉体和成型 剂的总重量的6%,加热至120℃搅拌1小时,然后将物料倒出,再自然冷却至室温倒入破碎机中破碎得到粒径为10mm以下且形状不规则的粒料;(3) put the obtained mixed powder and the molding agent into the internal mixer, wherein, the consumption of the molding agent is 6% of the total weight of the mixed powder and the molding agent, heated to 120 ° C and stirred for 1 hour, and then the material Pour out, then naturally cool to room temperature and pour into a crusher to be crushed to obtain pellets with a particle size of less than 10 mm and an irregular shape;
(4)将所得的粒料加入注射成型机中,加热至120℃,通过注射成型得到成型坯料;(4) adding the obtained pellets into an injection molding machine, heating to 120° C., and obtaining molding blanks by injection molding;
(5)将成型坯料放入热脱脂炉,在氢气气氛中以10℃/min的速率升温至1000℃,保温脱脂30分钟,再自然冷却至室温得到脱脂坯料;(5) put the formed blank into a thermal degreasing furnace, heat up to 1000° C. at a rate of 10° C./min in a hydrogen atmosphere, keep degreasing for 30 minutes, and then naturally cool to room temperature to obtain a degreasing blank;
(6)将脱脂坯料放入烧结炉,在氢气气氛中以10℃/min的速率升温至1380℃,保温烧结180分钟,再自然冷却至室温得到一体成型式钨合金仿生鱼饵料本体(其结构如图1所示,由仿生鱼饵本体1及两个线耳2组成的一体成型式结构)。(6) Put the degreasing blank into the sintering furnace, heat it up to 1380°C at a rate of 10°C/min in a hydrogen atmosphere, keep sintering for 180 minutes, and then naturally cool to room temperature to obtain an integrated tungsten alloy bionic fish bait body (its structure As shown in Fig. 1, an integrally formed structure composed of a bionic bait body 1 and two wire lugs 2).
实施例5Example 5
本实施例提供的一体成型式钨合金仿生鱼饵料本体的制备工艺,包括如下步骤:The preparation process of the integrally formed tungsten alloy bionic fish bait body provided by this embodiment includes the following steps:
(1)称取下述按重量百分比计的原料:钨粉(平均粒径为2.5μm)95%、镍粉(平均粒径为3μm)3.5%、铁粉(平均粒径为4μm)余量;(1) Weigh the following raw materials by weight percentage: tungsten powder (average particle size is 2.5 μm) 95%, nickel powder (average particle size is 3 μm) 3.5%, iron powder (average particle size is 4 μm) balance ;
(2)将钨粉、镍粉和铁粉加入混料机中混合10小时,得到混合粉体;(2) adding tungsten powder, nickel powder and iron powder into the mixer and mixing for 10 hours to obtain mixed powder;
(3)将所得的混合粉体和成型剂放入密炼机中,其中,成型剂的用量为混合粉体和成型剂的总重量的4.6%,加热至120℃搅拌1小时,然后将物料倒出,再自然冷却至室温倒入破碎机中破碎得到粒径为10mm以下且形状不规则的粒料;(3) put the obtained mixed powder and the molding agent into the internal mixer, wherein, the consumption of the molding agent is 4.6% of the total weight of the mixed powder and the molding agent, heated to 120 ° C and stirred for 1 hour, and then the material Pour out, then naturally cool to room temperature and pour into a crusher to be crushed to obtain pellets with a particle size of less than 10 mm and an irregular shape;
(4)将所得的粒料加入注射成型机中,加热至120℃,通过注射成型得到成型坯料;(4) adding the obtained pellets into an injection molding machine, heating to 120° C., and obtaining molding blanks by injection molding;
(5)将成型坯料放入热脱脂炉,在氢气气氛中以1℃/min的速率升温至800℃,保温脱脂120分钟,再自然冷却至室温得到脱脂坯料;(5) put the formed blank into a thermal degreasing furnace, heat up to 800° C. at a rate of 1° C./min in a hydrogen atmosphere, degreasing for 120 minutes, and then naturally cool to room temperature to obtain a degreasing blank;
(6)将脱脂坯料放入烧结炉,在氢气气氛中以5℃/min的速率升温至1500℃,保温烧结60分钟,再自然冷却至室温得到一体成型式钨合金仿生鱼饵料本体(其结构如图1所示,由仿生鱼饵本体1及两个线耳2组成的一体成型式结构)。(6) Put the degreasing blank into the sintering furnace, heat it up to 1500°C at a rate of 5°C/min in a hydrogen atmosphere, keep sintering for 60 minutes, and then naturally cool to room temperature to obtain an integrally formed tungsten alloy bionic fish bait body (its structure As shown in Fig. 1, an integrally formed structure composed of a bionic bait body 1 and two wire lugs 2).
实施例6Example 6
称取下述按重量百分比计的原料:钨粉(平均粒径为2μm)83%、镍粉(平均粒径为4μm)12%、铁粉(平均粒径为5μm)余量;将钨粉、镍粉和铁粉加入混料机中混合10小时,得到混合粉体;将所得的混合粉体和成型剂放入密炼机中,其中,成型剂的用量为混合粉体和成型剂的总重量的6%,加热至120℃搅拌1小时,然后将物料倒出,再自然冷却至室温倒入破碎机中破碎得到粒径为10mm以下且形状不规则的粒料;将所得的破碎粒料加入注射成型机中,加热至120℃,通过注射成型后得到成型坯料;将成型坯料放入热脱脂炉,在氢气气氛中以4℃/min的速率升温至900℃,保温脱脂60分钟,再自然冷却至室温得到脱脂坯料;将脱脂坯料放入烧结炉,在氢气气氛中以8℃/min的速率升温至1450℃,保温烧结120分钟, 再自然冷却至室温得到一体成型式钨合金仿生鱼饵料本体(其结构如图1所示,由仿生鱼饵本体1及两个线耳2组成的一体成型式结构)。Weigh the following raw materials by weight percentage: 83% tungsten powder (average particle size is 2 μm), nickel powder (average particle size is 4 μm) 12%, iron powder (average particle size is 5 μm) remainder; , nickel powder and iron powder are added in the mixer and mixed for 10 hours to obtain the mixed powder; the obtained mixed powder and the molding agent are put into the internal mixer, wherein, the consumption of the molding agent is the amount of the mixed powder and the molding agent. 6% of the total weight, heated to 120 ° C and stirred for 1 hour, then poured out the material, then cooled to room temperature and poured into a crusher to be crushed to obtain pellets with a particle size of 10 mm or less and irregular shapes; The raw material is added to the injection molding machine, heated to 120 °C, and the molding blank is obtained after injection molding; the molding blank is placed in a thermal degreasing furnace, heated to 900 °C at a rate of 4 °C/min in a hydrogen atmosphere, and degreasing for 60 minutes. Then naturally cool to room temperature to obtain degreasing blanks; put the degreasing blanks into a sintering furnace, heat up to 1450 °C at a rate of 8 °C/min in a hydrogen atmosphere, keep sintered for 120 minutes, and then naturally cool to room temperature to obtain an integrated tungsten alloy bionic Fishing bait body (its structure is shown in Figure 1, an integrally formed structure composed of a bionic fishing bait body 1 and two wire lugs 2).
实施例7Example 7
称取下述按重量百分比计的原料:钨粉(平均粒径为2μm)60%、镍粉(平均粒径为4μm)35%、铁粉(平均粒径为5μm)余量;将钨粉、镍粉和铁粉加入混料机中混合10小时,得到混合粉体;将所得的混合粉体和成型剂放入密炼机中,其中,成型剂的用量为混合粉体和成型剂的总重量的6%,加热至120℃搅拌1小时,然后将物料倒出,再自然冷却至室温倒入破碎机中破碎得到粒径为10mm以下且形状不规则的粒料;将所得的破碎粒料加入注射成型机中,加热至120℃,通过注射成型后得到成型坯料;将成型坯料放入热脱脂炉,在氢气气氛中以4℃/min的速率升温至900℃,保温脱脂60分钟,再自然冷却至室温得到脱脂坯料;将脱脂坯料放入烧结炉,在氢气气氛中以8℃/min的速率升温至1450℃,保温烧结120分钟,再自然冷却至室温得到一体成型式钨合金仿生鱼饵料本体(其结构如图1所示,由仿生鱼饵本体1及两个线耳2组成的一体成型式结构)。Weigh the following raw materials by weight: 60% tungsten powder (average particle size is 2 μm), nickel powder (average particle size is 4 μm) 35%, iron powder (average particle size is 5 μm) remainder; , nickel powder and iron powder are added in the mixer and mixed for 10 hours to obtain the mixed powder; the obtained mixed powder and the molding agent are put into the internal mixer, wherein, the consumption of the molding agent is the amount of the mixed powder and the molding agent. 6% of the total weight, heated to 120 ° C and stirred for 1 hour, then poured out the material, then cooled to room temperature and poured into a crusher to be crushed to obtain pellets with a particle size of 10 mm or less and irregular shapes; The raw material is added to the injection molding machine, heated to 120 °C, and the molding blank is obtained after injection molding; the molding blank is placed in a thermal degreasing furnace, heated to 900 °C at a rate of 4 °C/min in a hydrogen atmosphere, and degreasing for 60 minutes. Then naturally cool to room temperature to obtain degreasing blanks; put the degreasing blanks into a sintering furnace, heat up to 1450 °C at a rate of 8 °C/min in a hydrogen atmosphere, keep sintered for 120 minutes, and then naturally cool to room temperature to obtain an integrated tungsten alloy bionic Fishing bait body (its structure is shown in Figure 1, an integrally formed structure composed of a bionic fishing bait body 1 and two wire lugs 2).
实施例8Example 8
称取下述按重量百分比计的原料:钨粉(平均粒径为2μm)35%、镍粉(平均粒径为4μm)35%、铁粉(平均粒径为5μm)余量;将钨粉、镍粉和铁粉加入混料机中混合10小时,得到混合粉体;将所得的混合粉体和成型剂放入密炼机中,其中,成型剂的用量为混合粉体和成型剂的总重量的6%,加热至120℃搅拌1小时,然后将物料倒出,再自然冷却至室温倒入破碎机中破碎得到粒径为10mm以下且形状不规则的粒料;将所得的破碎粒料加入注射成型机中,加热至120℃,通过注射成型后得到成型坯料;将成型坯料放入热脱脂炉,在氢气气氛中以4℃/min的速率升温至900℃,保温脱脂60分钟,再自然冷却至室温得到脱脂坯料;将脱脂坯料放入烧结炉,在氢气气氛中以8℃/min的速率升温至1450℃,保温烧结120分钟,再自然冷却至室温得到一体成型式钨合金仿生鱼饵料本体(其结构如图1所示,由仿生鱼饵本体1及两个线耳2组成的一体成型式结构)。Weigh the following raw materials by weight percentage: tungsten powder (average particle size is 2 μm) 35%, nickel powder (average particle size is 4 μm) 35%, iron powder (average particle size is 5 μm) remainder; , nickel powder and iron powder are added in the mixer and mixed for 10 hours to obtain the mixed powder; the obtained mixed powder and the molding agent are put into the internal mixer, wherein, the consumption of the molding agent is the amount of the mixed powder and the molding agent. 6% of the total weight, heated to 120 ° C and stirred for 1 hour, then poured out the material, then cooled to room temperature and poured into a crusher to be crushed to obtain pellets with a particle size of 10 mm or less and irregular shapes; The raw material is added to the injection molding machine, heated to 120 °C, and the molding blank is obtained after injection molding; the molding blank is placed in a thermal degreasing furnace, heated to 900 °C at a rate of 4 °C/min in a hydrogen atmosphere, and degreasing for 60 minutes. Then naturally cool to room temperature to obtain degreasing blanks; put the degreasing blanks into a sintering furnace, heat up to 1450 °C at a rate of 8 °C/min in a hydrogen atmosphere, keep sintered for 120 minutes, and then naturally cool to room temperature to obtain an integrated tungsten alloy bionic Fishing bait body (its structure is shown in Figure 1, an integrally formed structure composed of a bionic fishing bait body 1 and two wire lugs 2).
实施例9Example 9
本实施例提供的一体成型式钨合金鱼饵料本体的制备工艺,包括如下步骤:The preparation process of the integrally formed tungsten alloy fishing bait body provided by this embodiment includes the following steps:
(1)称取下述按重量百分比计的原料:钨粉(平均粒径为2.5μm)78%、镍粉(平均粒径为3μm)16%、铁粉(平均粒径为4μm)余量;(1) Weigh the following raw materials by weight percentage: tungsten powder (average particle size is 2.5 μm) 78%, nickel powder (average particle size is 3 μm) 16%, iron powder (average particle size is 4 μm) balance ;
(2)将钨粉、镍粉和铁粉加入混料机中混合3小时,得到混合粉体;(2) adding tungsten powder, nickel powder and iron powder into the mixer and mixing for 3 hours to obtain mixed powder;
(3)将所得的混合粉体和成型剂放入密炼机中,其中,成型剂的用量为混合粉体和成型剂的总重量的6%,加热至110℃搅拌4小时,然后将物料倒出,再自然冷却至室温倒入破碎 机中破碎得到粒径为10mm以下且形状不规则的粒料;(3) put the obtained mixed powder and the molding agent into the internal mixer, wherein, the consumption of the molding agent is 6% of the total weight of the mixed powder and the molding agent, heated to 110 ° C and stirred for 4 hours, and then the material was Pour out, then naturally cool to room temperature and pour into a crusher to be crushed to obtain pellets with a particle size of less than 10 mm and an irregular shape;
(4)将所得的破碎粒料加入注射成型机中,加热至110℃,通过注射成型后得到成型坯料;(4) adding the obtained crushed pellets into an injection molding machine, heating to 110° C., and obtaining a molding blank after injection molding;
(5)将成型坯料放入热脱脂炉,在氢气气氛中以1℃/min的速率升温至800℃,保温脱脂60分钟,再自然冷却至室温得到脱脂坯料;(5) Put the formed blank into a thermal degreasing furnace, heat up to 800° C. at a rate of 1° C./min in a hydrogen atmosphere, keep the temperature for degreasing for 60 minutes, and then naturally cool to room temperature to obtain a degreasing blank;
(6)将脱脂坯料放入烧结炉,在氢气气氛中以5℃/min的速率升温至1300℃,保温烧结60分钟,再自然冷却至室温得到一体成型式钨合金仿生鱼饵料本体(其结构如图1所示,由仿生鱼饵本体1及两个线耳2组成的一体成型式结构)。(6) Put the degreasing blank into the sintering furnace, heat it up to 1300°C at a rate of 5°C/min in a hydrogen atmosphere, keep sintering for 60 minutes, and then naturally cool to room temperature to obtain an integrally formed tungsten alloy bionic fish bait body (its structure As shown in Fig. 1, an integrally formed structure composed of a bionic bait body 1 and two wire lugs 2).
实施例10Example 10
本实施例提供的一体成型式钨合金鱼饵料本体的制备工艺,包括如下步骤:The preparation process of the integrally formed tungsten alloy fishing bait body provided by this embodiment includes the following steps:
(1)称取下述按重量百分比计的原料:钨粉(平均粒径为2.5μm)78%、镍粉(平均粒径为3μm)16%、铁粉(平均粒径为4μm)余量;(1) Weigh the following raw materials by weight percentage: tungsten powder (average particle size is 2.5 μm) 78%, nickel powder (average particle size is 3 μm) 16%, iron powder (average particle size is 4 μm) balance ;
(2)将钨粉、镍粉和铁粉加入混料机中混合20小时,得到混合粉体;(2) adding tungsten powder, nickel powder and iron powder into the mixer and mixing for 20 hours to obtain mixed powder;
(3)将所得的混合粉体和成型剂放入密炼机中,其中,成型剂的用量为混合粉体和成型剂的总重量的6%,加热至130℃搅拌0.5小时,然后将物料倒出,再自然冷却至室温倒入破碎机中破碎得到粒径为10mm以下且形状不规则的粒料;(3) put the obtained mixed powder and the molding agent into the internal mixer, wherein, the consumption of the molding agent is 6% of the total weight of the mixed powder and the molding agent, heated to 130 ° C and stirred for 0.5 hours, and then the material Pour out, then naturally cool to room temperature and pour into a crusher to be crushed to obtain pellets with a particle size of less than 10 mm and an irregular shape;
(4)将所得的破碎粒料加入注射成型机中,加热至130℃,通过注射成型后得到成型坯料;(4) adding the obtained crushed pellets into an injection molding machine, heating to 130° C., and obtaining a molding blank after injection molding;
(5)将成型坯料放入热脱脂炉,在氢气气氛中以5℃/min的速率升温至1000℃,保温脱脂60分钟,再自然冷却至室温得到脱脂坯料;(5) put the formed blank into a thermal degreasing furnace, heat up to 1000 ℃ at a rate of 5 ℃/min in a hydrogen atmosphere, keep degreasing for 60 minutes, and then naturally cool to room temperature to obtain a degreasing blank;
(6)将脱脂坯料放入烧结炉,在氢气气氛中以10℃/min的速率升温至1380℃,保温烧结120分钟,再自然冷却至室温得到一体成型式钨合金仿生鱼饵料本体(其结构如图1所示,由仿生鱼饵本体1及两个线耳2组成的一体成型式结构)。(6) Put the degreasing billet into the sintering furnace, heat it up to 1380°C at a rate of 10°C/min in a hydrogen atmosphere, keep sintering for 120 minutes, and then naturally cool to room temperature to obtain an integrated tungsten alloy bionic fish bait body (its structure As shown in Fig. 1, an integrally formed structure composed of a bionic bait body 1 and two wire lugs 2).
对比例1Comparative Example 1
本对比例提供的一体成型式钨合金鱼饵料本体的制备工艺,包括如下步骤:The preparation process of the one-piece tungsten alloy fishing bait body provided by this comparative example includes the following steps:
(1)称取下述按重量百分比计的原料:钨粉(平均粒径为2.5μm)78%、镍粉(平均粒径为3μm)16%、铁粉(平均粒径为4μm)余量;(1) Weigh the following raw materials by weight percentage: tungsten powder (average particle size is 2.5 μm) 78%, nickel powder (average particle size is 3 μm) 16%, iron powder (average particle size is 4 μm) balance ;
(2)将钨粉、镍粉和铁粉加入混料机中混合10小时,得到混合粉体;(2) adding tungsten powder, nickel powder and iron powder into the mixer and mixing for 10 hours to obtain mixed powder;
(3)将所得的混合粉体和成型剂放入密炼机中,其中,成型剂的用量为混合粉体和成型剂的总重量的6%,加热至120℃搅拌1小时,然后将物料倒出,再自然冷却至室温倒入破碎机中破碎得到粒径为10mm以下且形状不规则的粒料;(3) put the obtained mixed powder and the molding agent into the internal mixer, wherein, the consumption of the molding agent is 6% of the total weight of the mixed powder and the molding agent, heated to 120 ° C and stirred for 1 hour, and then the material Pour out, then naturally cool to room temperature and pour into a crusher to be crushed to obtain pellets with a particle size of less than 10 mm and an irregular shape;
(4)将所得的粒料加入注射成型机中,加热至120℃,通过注射成型得到成型坯料;(4) adding the obtained pellets into an injection molding machine, heating to 120° C., and obtaining molding blanks by injection molding;
(5)将成型坯料放入脱脂溶剂中脱脂后,再放入热脱脂炉,在氢气气氛中以4℃/min的速率升温至600℃,保温脱脂5小时,再自然冷却至室温得到脱脂坯料;(5) Put the formed blank into a degreasing solvent for degreasing, then put it into a hot degreasing furnace, heat it up to 600° C. at a rate of 4° C./min in a hydrogen atmosphere, keep degreasing for 5 hours, and then naturally cool to room temperature to obtain a degreasing blank. ;
(6)将脱脂坯料放入烧结炉,在氢气气氛中以8℃/min的速率升温至1400℃,保温烧结120分钟,再自然冷却至室温得到一体成型式钨合金仿生鱼饵料本体。(6) Put the degreasing blank into a sintering furnace, heat it up to 1400°C at a rate of 8°C/min in a hydrogen atmosphere, keep sintered for 120 minutes, and then naturally cool to room temperature to obtain an integrated tungsten alloy bionic fish bait body.
对比例2Comparative Example 2
按照公开号为CN101720745B的发明专利的实施例1制得成品。The finished product was prepared according to Example 1 of the invention patent with publication number CN101720745B.
为了进一步说明本发明的有益效果,本发明上述实施例和对比例所得产品的尺寸及重量的精度进行测试,测试结果如表1所示。In order to further illustrate the beneficial effects of the present invention, the accuracy of the size and weight of the products obtained in the above embodiments and comparative examples of the present invention are tested, and the test results are shown in Table 1.
表1精度测试结果Table 1 Accuracy test results
序号serial number | 样品来源Sample source | 长度精度-/+%Length Precision -/+% | 宽度精度-/+%width precision -/+% | 厚度精度-/+%Thickness Accuracy -/+% | 重量精度-/+%Weight Accuracy -/+% |
11 | 实施例1Example 1 | 1.451.45 | 1.391.39 | 1.191.19 | 2.782.78 |
22 | 实施例2Example 2 | 1.391.39 | 1.191.19 | 1.151.15 | 2.462.46 |
33 | 实施例3Example 3 | 1.291.29 | 1.101.10 | 1.091.09 | 1.961.96 |
44 | 实施例4Example 4 | 1.391.39 | 1.301.30 | 1.221.22 | 2.822.82 |
55 | 实施例5Example 5 | 1.461.46 | 1.381.38 | 1.111.11 | 2.152.15 |
66 | 实施例6Example 6 | 1.291.29 | 1.181.18 | 1.131.13 | 2.012.01 |
77 | 实施例7Example 7 | 1.351.35 | 1.301.30 | 1.191.19 | 2.132.13 |
88 | 实施例8Example 8 | 1.421.42 | 1.391.39 | 1.261.26 | 2.762.76 |
99 | 实施例9Example 9 | 1.321.32 | 1.271.27 | 1.181.18 | 2.552.55 |
1010 | 实施例10Example 10 | 1.451.45 | 1.351.35 | 1.251.25 | 2.812.81 |
1111 | 对比例1Comparative Example 1 | 2.022.02 | 1.591.59 | 1.551.55 | 8.28.2 |
1212 | 对比例2Comparative Example 2 | 2.132.13 | 1.651.65 | 1.601.60 | 5.765.76 |
而实际从使用效果的要求来看,一般认为产品尺寸精度控制在-/+1.5%以内,重量精度控制在-/+3.0%以内为优秀,使用效果好。In fact, from the requirements of the use effect, it is generally considered that the dimensional accuracy of the product is controlled within -/+1.5%, and the weight accuracy is controlled within -/+3.0% to be excellent, and the use effect is good.
为了进一步说明本发明的有益效果,本发明还对上述实施例和对比例所得产品进行了如下测试:In order to further illustrate the beneficial effects of the present invention, the present invention has also carried out the following tests on the products obtained from the above-mentioned embodiments and comparative examples:
(1)密度测试:利用二次元投影仪进行尺寸测试,然后利用精密天平进行密度测试;(1) Density test: use a two-dimensional projector for size test, and then use a precision balance for density test;
(2)抛落试验:将仿生鱼饵料本体挂在钓鱼线上,在水泥场地上进行10米高抛落50次;(2) Drop test: hang the bionic bait body on the fishing line, and drop it 50 times from a height of 10 meters on the cement field;
(3)抗拉强度测试:选用羊角锤的拉力试验机,将仿生鱼饵料本体的上端固定,在仿生 鱼饵料本体的下端施加600N、1000N的拉力,测试仿生鱼饵料本体产品的抗拉强度。(3) Tensile strength test: use a claw hammer tensile tester, fix the upper end of the bionic fish bait body, and apply a tensile force of 600N and 1000N to the lower end of the bionic fish bait body to test the bionic fish bait. The tensile strength of the body product.
上述密度测试、抛落试验、抗拉强测试的结果如表2所示。The results of the above density test, drop test, and tensile strength test are shown in Table 2.
表2密度测试、抛落试验、抗拉强测试的结果Table 2 Results of density test, drop test and tensile strength test
以上对本发明的实施方式作了详细说明,但本发明不限于所描述的实施方式。对于本领域的技术人员而言,在不脱离本发明原理和精神的情况下,对这些实施方式进行多种变化、修改、替换和变型,仍落入本发明的保护范围内。The embodiments of the present invention have been described above in detail, but the present invention is not limited to the described embodiments. For those skilled in the art, without departing from the principle and spirit of the present invention, various changes, modifications, substitutions and alterations can be made to these embodiments, which still fall within the protection scope of the present invention.
Claims (10)
- 一种一体成型式钨合金仿生鱼饵料本体的制备工艺,其特征在于,包括如下步骤:A preparation process of an integrally formed tungsten alloy bionic fish bait body, characterized in that it comprises the following steps:(1)称取下述按重量百分比计的原料:钨粉35~97%、镍粉2~35%、铁粉余量;(1) Take by weighing the following raw materials by weight: 35-97% of tungsten powder, 2-35% of nickel powder, and balance of iron powder;(2)将钨粉、镍粉和铁粉加入混料机中混合3~20小时,得到混合粉体;(2) adding tungsten powder, nickel powder and iron powder into the mixer and mixing for 3-20 hours to obtain mixed powder;(3)将所得的混合粉体和成型剂放入密炼机中,加热至110~130℃搅拌0.5~4小时,然后将物料倒出,再自然冷却至室温倒入破碎机中破碎得到破碎粒料;(3) Put the obtained mixed powder and molding agent into an internal mixer, heat to 110-130 ° C and stir for 0.5-4 hours, then pour out the material, then naturally cool to room temperature and pour it into a crusher for crushing to obtain crushing pellets;(4)将所得的破碎粒料加入注射成型机中,加热至110~130℃,通过注射成型得到要求产品形状的成型坯料;(4) adding the obtained crushed pellets into an injection molding machine, heating to 110-130° C., and obtaining a molding blank of the required product shape by injection molding;(5)将成型坯料放入热脱脂炉,在真空或保护气氛条件下升温至800~1000℃,保温烧结30~120分钟,再自然冷却至室温得到脱脂坯料;(5) Put the formed blank into a thermal degreasing furnace, heat it up to 800-1000°C under vacuum or protective atmosphere, keep sintered for 30-120 minutes, and then naturally cool to room temperature to obtain a degreasing blank;(6)将脱脂坯料放入烧结炉,在真空或保护气氛条件下升温至1300~1520℃,保温烧结60~180分钟,再自然冷却至室温得到一体成型式钨合金仿生鱼饵料本体。(6) Put the degreasing blank into a sintering furnace, heat it up to 1300-1520°C under vacuum or protective atmosphere, keep sintered for 60-180 minutes, and then naturally cool to room temperature to obtain an integrally formed tungsten alloy bionic fish bait body.
- 根据权利要求1所述的一体成型式钨合金仿生鱼饵料本体的制备工艺,其特征在于,所述钨粉的平均粒径为1~5μm;所述镍粉的平均粒径为1~5μm;所述铁粉的平均粒径为1~10μm。The process for preparing an integrally formed tungsten alloy bionic fish bait body according to claim 1, wherein the average particle size of the tungsten powder is 1-5 μm; the average particle size of the nickel powder is 1-5 μm; The average particle size of the iron powder is 1-10 μm.
- 根据权利要求1所述的一体成型式钨合金仿生鱼饵料本体的制备工艺,其特征在于,步骤(1)所述的原料,按重量百分比计,包括:钨粉70~97%、镍粉2~20%、铁粉余量。The process for preparing an integrally formed tungsten alloy bionic fish bait body according to claim 1, wherein the raw materials in step (1), by weight percentage, include: 70-97% of tungsten powder, 2 ~20%, the balance of iron powder.
- 根据权利要求1所述的一体成型式钨合金仿生鱼饵料本体的制备工艺,其特征在于,所述成型剂的用量为所述混合粉体和所述成型剂的总重量的3~10%。The process for preparing an integrally formed tungsten alloy bionic fish bait body according to claim 1, wherein the amount of the molding agent is 3-10% of the total weight of the mixed powder and the molding agent.
- 根据权利要求1所述的一体成型式钨合金仿生鱼饵料本体的制备工艺,其特征在于,破碎粒料的粒径不大于10mm。The process for preparing an integrally formed tungsten alloy bionic fish bait body according to claim 1, wherein the particle size of the broken pellets is not greater than 10 mm.
- 根据权利要求1所述的一体成型式钨合金仿生鱼饵料本体的制备工艺,其特征在于,所述热脱脂炉的升温速率为1~10℃/min。The process for preparing an integrally formed tungsten alloy bionic fish bait body according to claim 1, wherein the heating rate of the thermal degreasing furnace is 1-10°C/min.
- 根据权利要求1所述的一体成型式钨合金仿生鱼饵料本体的制备工艺,其特征在于,步骤(5)-(6)中所述的保护气氛选自氢气、氮气、氦气和氩气中的一种或多种。The process for preparing an integrally formed tungsten alloy bionic fish bait body according to claim 1, wherein the protective atmosphere described in steps (5)-(6) is selected from hydrogen, nitrogen, helium and argon one or more of.
- 根据权利要求1所述的一体成型式钨合金仿生鱼饵料本体的制备工艺,其特征在于,所述烧结炉的升温速率为5~10℃/min,所述烧结炉升温后的烧结温度为1350~1500℃。The process for preparing an integrally formed tungsten alloy bionic fish bait body according to claim 1, wherein the heating rate of the sintering furnace is 5-10 °C/min, and the sintering temperature after the heating of the sintering furnace is 1350 °C ~1500℃.
- 根据权利要求1所述的一体成型式钨合金仿生鱼饵料本体的制备工艺,其特征在于,所述一体成型式钨合金仿生鱼饵料本体的密度为10~18.6g/cm 3。 The preparation process of the integrally formed tungsten alloy bionic fish bait body according to claim 1, wherein the density of the integrally formed tungsten alloy bionic fish bait body is 10-18.6 g/cm 3 .
- 一种仿生鱼饵料本体,其特征在于,为采用如权利要求1所述的一体成型式钨合金 仿生鱼饵料本体的制备工艺制得,所述仿生鱼饵料本体为由仿生鱼饵本体及至少一个线耳组成的一体成型式结构。A bionic fish bait body is characterized in that, it is obtained by adopting the preparation process of the integrally formed tungsten alloy bionic fish bait body according to claim 1, and the bionic fish bait body is composed of a bionic fish bait body and at least one thread. The one-piece structure of the ear.
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Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000157129A (en) * | 1998-11-25 | 2000-06-13 | Mitsubishi Materials Corp | Sinker for fishing tackle |
CN101623760A (en) * | 2009-07-24 | 2010-01-13 | 厦门理工学院 | Application of micro injection molding technique for preparing tungsten-base alloy product and micro injection molding method of tungsten-base alloy powder |
CN101720745A (en) * | 2009-12-24 | 2010-06-09 | 株洲乐泰金属粉末制品有限公司 | High-gravity tungsten-base fish pendant and manufacture process thereof |
CN102443726A (en) * | 2011-12-05 | 2012-05-09 | 株洲乐泰金属粉末制品有限公司 | Tungsten alloy fishing weight and production process thereof |
CN106041093A (en) * | 2016-08-25 | 2016-10-26 | 山东金聚粉末冶金有限公司 | Process for producing powder injection tungsten alloy sinker |
CN110883335A (en) * | 2019-11-05 | 2020-03-17 | 厦门虹鹭钨钼工业有限公司 | Preparation method of integrated tungsten alloy lure |
CN112548101A (en) * | 2020-11-18 | 2021-03-26 | 广州市华司特合金制品有限公司 | Integrally-formed tungsten alloy bionic fish bait body and preparation process thereof |
-
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- 2021-08-19 WO PCT/CN2021/113484 patent/WO2022105331A1/en active Application Filing
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000157129A (en) * | 1998-11-25 | 2000-06-13 | Mitsubishi Materials Corp | Sinker for fishing tackle |
CN101623760A (en) * | 2009-07-24 | 2010-01-13 | 厦门理工学院 | Application of micro injection molding technique for preparing tungsten-base alloy product and micro injection molding method of tungsten-base alloy powder |
CN101720745A (en) * | 2009-12-24 | 2010-06-09 | 株洲乐泰金属粉末制品有限公司 | High-gravity tungsten-base fish pendant and manufacture process thereof |
CN102443726A (en) * | 2011-12-05 | 2012-05-09 | 株洲乐泰金属粉末制品有限公司 | Tungsten alloy fishing weight and production process thereof |
CN106041093A (en) * | 2016-08-25 | 2016-10-26 | 山东金聚粉末冶金有限公司 | Process for producing powder injection tungsten alloy sinker |
CN110883335A (en) * | 2019-11-05 | 2020-03-17 | 厦门虹鹭钨钼工业有限公司 | Preparation method of integrated tungsten alloy lure |
CN112548101A (en) * | 2020-11-18 | 2021-03-26 | 广州市华司特合金制品有限公司 | Integrally-formed tungsten alloy bionic fish bait body and preparation process thereof |
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