WO2022096843A1 - Dispositif, appareil et procédé de fabrication additive de composant métallique, composant d'alliage ou composant composite de matrice métallique - Google Patents
Dispositif, appareil et procédé de fabrication additive de composant métallique, composant d'alliage ou composant composite de matrice métallique Download PDFInfo
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- WO2022096843A1 WO2022096843A1 PCT/GB2021/000120 GB2021000120W WO2022096843A1 WO 2022096843 A1 WO2022096843 A1 WO 2022096843A1 GB 2021000120 W GB2021000120 W GB 2021000120W WO 2022096843 A1 WO2022096843 A1 WO 2022096843A1
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- source material
- induction heating
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- heating
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K13/00—Welding by high-frequency current heating
- B23K13/01—Welding by high-frequency current heating by induction heating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/20—Direct sintering or melting
- B22F10/25—Direct deposition of metal particles, e.g. direct metal deposition [DMD] or laser engineered net shaping [LENS]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/20—Direct sintering or melting
- B22F10/22—Direct deposition of molten metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F12/00—Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
- B22F12/10—Auxiliary heating means
- B22F12/13—Auxiliary heating means to preheat the material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F12/00—Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
- B22F12/50—Means for feeding of material, e.g. heads
- B22F12/53—Nozzles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K10/00—Welding or cutting by means of a plasma
- B23K10/02—Plasma welding
- B23K10/027—Welding for purposes other than joining, e.g. build-up welding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K13/00—Welding by high-frequency current heating
- B23K13/06—Welding by high-frequency current heating characterised by the shielding of the welding zone against influence of the surrounding atmosphere
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K9/00—Arc welding or cutting
- B23K9/10—Other electric circuits therefor; Protective circuits; Remote controls
- B23K9/1093—Consumable electrode or filler wire preheat circuits
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K9/00—Arc welding or cutting
- B23K9/32—Accessories
- B23K9/325—Devices for supplying or evacuating shielding gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y30/00—Apparatus for additive manufacturing; Details thereof or accessories therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
- B33Y70/10—Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/30—Plasma torches using applied electromagnetic fields, e.g. high frequency or microwave energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
Definitions
- AM additive manufacturing
- additive manufacturing is a rapidly developing field of manufacturing that is replacing traditional manufacturing processes.
- Additive manufacturing of components from metals, metal alloys as well as metal matrix composite is an emerging field that offers several salient benefits when compared against traditional manufacturing processes such a casting, forging and machining.
- Some of the salient benefits of AM processes are significant cost saving by maximising material usage with minimal waste and an increased design flexibility.
- AM processes do not require expensive tooling or dies and therefore provide flexibility to manufacture complex components with quick turnaround reducing production lead times and dependencies.
- AM can also be used to manufacture metal alloys and metal matrix composites that have superior physical and mechanical properties compared to pure metal components.
- Hascoet et al. published paper referenced herein presented an approach to depositing wire material on substrate using an induction coil.
- a U-shaped coil of single turn was used to melt the wire and heat the substrate or previous layer to an optimal temperature for good fusion.
- the method is difficult to deposit layers side by side.
- the deposited layers presented are not uniform and the material feed rate of up to lOOmm/min is very low compared against prevalent AM processes.
- it discloses a process of fully melting feedstock material and heating the substrate or previous layer which does not address the heat problem described below.
- Chinese patent number CN109550947A discloses the use of induction heating of metal wire for additive manufacturing. It describes a process for uniformly heating and melting feedstock material using high frequency current through concentric coils where the skin depth is half of the wire diameter. The process thus intends for full melting of wire material and does not address the heat issue described below. It also limits the wire size based on skin effect depth achievable and consequently does not provide a competitive deposition rate. Finally, the process also intends to apply the induction heating to heat the preceding deposited layer to ensure fusion by placing the coil close to the layer in similar manner to Hascoet et al.
- Powder bed AM typically uses a high power beam heat source to fuse powder to produce complex components to a very high level of accuracy.
- Wire AM is akin to welding with a filler material and produces near net shaped components at a much faster rate than powder AM. Both techniques rely on heating the feedstock material beyond its melting temperature creating a local melt pool to fuse material to a substrate or preceding layer and as such the component experiences very high levels of heating.
- DED Direct Energy Deposition
- arc-based deposition methods typically offer the highest of deposition rates (around lOkg/hr) by feeding material at very high feed rates.
- Electron Beam Additive manufacturing (EBAM) is also an attractive process as the component is built under vacuum environment but is very expensive compared to arc processes.
- the heat applied can also introduce distortion depending on the geometry of component and the build sequence. Residual stress and shrinkage are observed due to the thermal cycles which can lead to cracking of the component when not addressed. The heat problem is further exacerbated as the size of component increases and therefore large-scale additive manufacturing will need careful management of heat. Despite these limiting factors, the industry has steadily adopted the AM process for metal, and it is now used in various industry such as aerospace, automotive, railway, tooling.
- AM processes Another important factor to consider on AM processes is the build rate.
- arc based processes offer the highest of deposition rate by feeding wire material at high speed of up to lOm/min.
- Medium to large scale components manufactured by AM for industrial applications demand high deposition rates for it to be provide tangible benefits.
- Prevalent AM processes typically feed wire material of less than 2mm in diameter. By using larger size wires or rods similar or higher deposition rates may be achieved despite feeding material at fraction of the feed rate.
- the invention aims to address the heat problem by introducing a deposition technique whereby the bulk of feedstock source material is not melted which represents a departure from prevalent AM processes.
- Another objective of the invention is to enable large scale additive manufacture of metal alloy and Metal Matrix Composite (MMC) component(s) using feedstock material comprising potentially multiple materials arranged in layers coaxially.
- An additive process for MMC and metal alloys is disclosed here in whereby a source material comprising of multiple layers of material arranged such that these layers are heated selectively and partially melted and then deposited for a layer by layer construction.
- Another object is to manufacture Functionally Graded Material (FGM) components using sequentially fed feedstock material with gradually varying composition.
- FGM Functionally Graded Material
- the invention proposes an integral energising method for improving the ability of the source material to fuse to a preceding deposition layer. Through heating of a shielding gas this energy is transferred to the deposition area improving the fusibility of the source material to the preceding layer.
- an induction heating process applies directed heat onto a material by passing an alternating electrical current through induction coils. It is a non-contact process and can scale from small fabrication in orders of microns to large scale component heating such as billets in the order of metres.
- the process uses alternating current passed around the coils to produce changing magnetic and electrical fields, the changing magnetic field induces current on a component placed inside the coil, heating it through generation of eddy currents.
- the invention described herein addresses the heat, oxidation and distortion issue described above.
- the process only melts the outer surface of the feedstock (the source) material by directing the heat to the outer surface of the source material and not heating the bulk inner material.
- Such a process requires only a fraction of heat to melt the outer layer and therefore consumes less energy.
- outer surface this may also be the outer surface of an inner core where a multi-layered source material is used.
- the frequency of applied alternating current dictates the type of heating on the component. At very low frequency such as mains frequency, through body or bulk heating is observed. This process is used in industry for processes typically involving large scale components. Processes such as forging, forming, melting, annealing and heat treatment use low frequency induction heating to evenly heat components. Medium frequency induction heating in the range of 1kHz to 50 kHz is applied in industry for similar applications but at reduced scale.
- the principle behind this aspect of the invention is explained by electromagnetic induction.
- the alternating current produces changing magnetic and electric fields around the coil, the rate of change of such fields is governed by the current frequency.
- the change in magnetic field induces electrical current in the material which heats the material through Joule heating.
- the frequency of the alternating current applied dictates the type of heating and at very high frequency the eddy current induced is concentrated on a thin outer layer, a phenomenon referred to as 'skin effect'.
- the thin layer is known as 'skin depth' or 'depth of penetration' and is the depth from the outer surface beyond which the magnitude of current drops exponentially. It is governed by the equation
- induction heating through the application of high frequency alternating current will concentrate the heat on the outer surface, rapidly increasing the temperature of the component up to its melting point within a fraction of a second.
- the skin depth for most conductive materials is less than a tenth of millimetre (0.1mm).
- this deposition layer can also be heated.
- the molten layer must wet the surface of the deposition layer. The wetting depends on several factors, most of which are associated with the characteristics of the surface being deposited upon. Most metals typically have a thin oxide layer which hinders wetting, further the application of a melt pool on a relatively cold surface compared to molten layer is also not conducive to wetting.
- Another issue with the process is that the feedstock is only heated inside the coil, so it will start to lose heat after passing through the coil, which can make it difficult to control the volume and geometry of the deposition.
- the invention herein employs the use of alternating electrical current above 1MHz which can energise gases passing through the coil separated by a dielectric layer.
- the energised gas can therefore be used to heat the substrate or preceding layer and aid wetting of the partially melted deposit.
- MMC metal matrix composite
- FGM functional graded material
- MMC is a composite material where reinforcement material is embedded in a metal matrix.
- MMC comprises of at least two constituent parts: a) a matrix of for example metal or alloy such as Al, Ti, Cu, Co-Ni, Steel etc and b) reinforcement made from another metal or metal alloy or ceramic material such as Alumina, SiC, Zirconia, TiN, CBN etc in the form of either particulate, powder, whisker or fibres.
- MMC components can be fabricated by various methods but the commonly used method is either stir casting or infiltration method whereby the reinforcement is fed onto a molten metal matrix.
- a cored or coaxial wire or rod is used where the reinforcement material is surrounded by the metal matrix.
- the reinforcement may be coated or mixed with wetting agents to aid wetting with the metal matrix.
- the matrix material has a lower melting temperature compared to the reinforcement.
- induction heating the metal melts and infuses with the reinforcing material and is deposited on surface by wetting and fusing the molten metal layer.
- a complex MMC structure can be produced from feedstock comprising of several layers of matrix and reinforcements.
- the principle method of deposition is as follows.
- An alternating electrical current of suitable frequencies and power are supplied to an induction coil (From lOOKHz up to and including 100MHz) heating the feedstock material (source material) through induction skin effect heating.
- the feedstock material is fed through the torch (torch and nozzle are used inter-changeably through-out and apply to the same feature) by rollers driven by a motor controlled through the control unit and is insulated from the coil by a dielectric tube.
- changes in magnetic flux induce current on the material that concentrate on a thin layer on the outer surface of material referred to as skin depth.
- the thickness of the layer or depth of penetration depends on the frequency of current as well as resistivity and permeability of the source material.
- the thin layer on the outer surface is rapidly heated through Joule heating from the induced current.
- the current intensity drops exponentially beyond the skin depth and therefore the inner bulk material does not experience heating from induction coil and only experiences heat through conduction from the heated outer layer.
- the thin layer on the outer surface of material is melted.
- the molten layer will grow inward upon continued application of heat which can be controlled by adjusting the feed rate and current so that the bulk material is not melted.
- the feedstock material with the molten outer layer is then deposited onto the substrate or component by wetting the surface with the molten material creating a fused layer.
- a shielding gas may be fed through the torch (nozzle) to prevent oxidation of the molten layer.
- the shielding gas is typically is an inert gas such as Argon, Helium but can also be mixture of gas with traces of active elements like Hydrogen etc.
- the shielding gas can be energised by the electric and magnetic field of the coil(s) as well as the induced fields on the material.
- the energised gas can also aid wetting of the molten layer on the deposition surface by supplying additional heat to the deposition surface.
- a component can thus be produced by depositing the partially melted material layer by layer. It will be appreciated by the skilled reader that by varying the induction frequency used to heat the source material and the induction frequency used to heat the shielding gas the invention also encompasses full melt additive manufacturing processes.
- the method of deposition using cored wire or coaxial wire comprising of more than one material is similar in that it relies on the outer molten layer to wet and fuse on the depositing surface.
- the heating regime is however more complex, and the process relies on melting at least one part of one constituent material.
- the feedstock is made from materials grouped coaxially such that the outer layer comprises a material with lower melting temperature than the inner material.
- the feedstock can also be configured to have multiple layers of materials such that the outer and selective inner layers undergo partial melting.
- the heating regime will be dictated by the material properties, only freely conductive materials will experience heating from the induction coil directly and the heating rate will differ based on the material properties.
- a secondary source of heat is applied in the form of gas plasma produced by an induction coupled torch (nozzle) which also relies on an alternating current in the MHz range to generate the plasma.
- the plasma is used to energise the surface for deposition and improve wetting of the molten material.
- the heat from the plasma can also be used to sustain the molten layer and prevent the feedstock material from freezing before deposition.
- a further torch (nozzle) can be applied for scenarios where the primary torch is not able to produce sufficient energised gas to energise sufficiently the deposition layer.
- the feedstock material is in a form of a rod stored in magazine configured to feed them sequentially.
- the rods are arranged in the order of sequence and selected such that the composition of material gradually varies between each rod.
- the final component will have a varying composition over its volume, producing a functionally graded structure.
- the torch is configured with two sets of coils operating at different frequencies.
- a nozzle (5) for additive manufacturing comprising: a passage for permitting source materials (4) to pass through the nozzle (5); the nozzle being configured to receive a shielding gas (9) an induction heating coil (12) for heating the source materials (4); Characterised in that the nozzle further comprises a further heating means (13) for heating the shielding gas (9) into a plasma to heat a deposition layer (3).
- this further heating of the shielding gas allows for a more efficient fusion of the source material to the deposition layer and allows the induction heating of the source material to be limited to a peripheral skin layer and yet still achieve good fusion of the source material to the deposition layer.
- the heat experienced by the source material is significantly limited to the skin layer i.e. the nozzle is configured to concentrate the heating to a relatively thin skin layer. This requires only a fraction of heat to melt the outer layer of the source material and therefore consumes significantly less energy than known processes and also reduces the unwanted effects discussed with the known deposition techniques.
- the further heating means (13) comprises an induction heating coil (13) to provide inductive heating of the shielding gas (9). Beneficially this unifies the heating methods used for the source material and the shielding gas. Using induction heating to energise the shielding gas uses less energy than other standard methods.
- This configuration provides for an induction plasma torch which can be powered by same power supply as nozzle (5) and can be tailored to provide energy to heat as well as manipulate the deposited layer in order to produce desired geometry and surface finish.
- the induction heating coil (12) is capable of operation under an alternating electrical current in the frequency range of lOOKHz to 100MHz. This range allows the heating effect of the induction coil to be limited to only a very minor skin layer of the source material which avoids unnecessary and unwanted material changes found with other though body heating methods.
- the induction heating coil (13) is capable of operation under an alternating electrical current in the frequency range of 1MHz to 100GHz. This range is optimal for the energisation of the shielding gas.
- the nozzle (5) comprises a plurality of discrete induction heating coils (12). Beneficially this allows for graded and progressive heating of the source material.
- the plurality of induction heating coils (12) are configurable to be operable at different frequencies. This allows for a graded heating effect to be achieved.
- an apparatus for additive manufacturing comprising:
- a control unit (10) for controlling at least one of: the rate of induction heating, the rate of movement of the source material (4) through the passage, the flow rate of the shielding gas (9) and / or and the relative movement of the nozzle (5) in relation to the deposition layer (3).
- the apparatus may further comprise a means (14) for moving the further heating means (13) relative to the deposition layer (3) and / or the nozzle (5). Beneficially this allows for more adaptability in the amount of heating of the deposition layer is applied.
- the apparatus is characterised in that it comprises a plurality of nozzles (5) and in that the dimensions of the source material (4) may be different for each nozzle (5). Beneficially this allows for a more refined, smother surface build of the end component.
- the apparatus relates to the form in which the material is expelled from the nozzle, i.e. they can be of a similar form of differing overall cross sectional area taken at plane transverse to the plane of the material passing through the nozzle or indeed they can have a different cross sectional form altogether.
- the apparatus may comprise a low atmosphere or vacuum chamber (15) for substantially enclosing the nozzle (5) and the deposition layer (3).
- a low atmosphere or vacuum chamber for substantially enclosing the nozzle (5) and the deposition layer (3).
- this allows for a significant reduction in the risk of oxidation for the deposition layer.
- the heating of the shielding gas allows for a more efficient fusion of the source material to the deposition layer and allows the induction heating of the source material to be limited to a peripheral skin layer through judicious selection of the excitation frequencies.
- the method of additive manufacturing further comprises at least the steps of:
- the method is characterised in that the at least part electrically conductive source material (4) is constructed at least in part from a metallic constituent.
- Metals are commonly available conductive materials and offer great strength benefit for additive manufacturing. It also beneficially allows for a less aggressive heating regime to be used for fusing metallic source materials. Metals form an ideal material choice for this method of additive manufacturing using induction skin heating to only melt a thin layer of the source material.
- the method is characterised in that the melting only a limited peripheral portion is achieved through the application of induction heating of the at least part electrically conductive source material (4) using an electrical alternating current of frequencies of lOOKHz to 100MHz.
- these high frequencies ensure the heating of the source material is confined to a peripheral skin layer of the source material and requires less energy than other known processes. This also means that it overcomes the issues of heat penetrating the rest of the source material changing its overall material properties.
- the induction heating of the shielding gas is powered by an electrical alternating current of frequencies of 1MHz to 100GHz. This is an ideal frequency range to excite the general common forms of shielding gas used in the field.
- the at least part electrically conductive source materials (4) comprise a metal matrix composite formed of cored wire, coaxial wires and / or rods. Having a conductive element greatly increases the inductive heating effect. By conductive it is meant that this element has free electrons and is easily able to pass an electrical current without undue burden.
- the at least part electrically conductive source material (4) comprises at least two constituent materials formed of; a metal matrix composite and; a reinforcement material arranged coaxially metal matrix composite.
- the reinforcement material can provide beneficial component properties of the final product.
- the at least part electrically conductive source materials (4) comprises a functional gradient material formed of coaxial rods with gradually varying composition and which are stacked sequentially in a magazine and fed in the manner of the sequence to deposit and produce a gradually varying material composition over the volume of the final component or structure. This beneficially allows a greater control of the attributes of the final product.
- the source material (4) for use in the method may comprise a plurality of discrete material layers. Beneficially this allows differing material properties within each of the layers.
- the outer layer can be chosen to have a lower melting temperature than the inner or vice versa for example.
- the discrete material layers may comprise material in the form of rods, tubes, powder, whiskers, fibre, particulates, or paste.
- the discrete material layers are configured to be formed of a plurality of material types comprising metal, metal alloy, ceramic, or semiconductor material.
- Figure 1 shows a schematic of the system for additively manufacturing by addition of a deposition layer 3 creating component 2, on a work surface (substrate) 1 which as illustrated can be configured to move in three direction or rotate around the two axes.
- the system comprises at least one torch (nozzle) 5 to deposit the source material 4 and feed unit 6 to deliver the source material 4, both mounted on a motion system or robot 8 capable of movement across six axes, three linear and three rotational.
- a central control unit 10 controls, the movement of motion systems 1 & 8; control process parameters such as input power to torch (nozzle) 5 from supply 11, wire feed rate from feed unit 6, shielding gas flow through flow control units 9.
- the feedstock source material 4 is illustrated as wire but can be in the form of solid wire, cored wire, coaxial wire or rods.
- the material normally has at least in part a conductive constituent e.g. a conductive coating.
- the material may be stored in a wire spool or a magazine for rods.
- the material in the form of wire limits the diameter size as it becomes less flexible with the increase in size and therefore for diameter above 5mm, the feedstock material in the form of rods is preferred.
- the feedstock material comprises at least two constituent material, optionally the arrangement is for the conducting material with lower melting temperature to be on the outer layer.
- the other material may be of conducting or non-conducting nature such as ceramics and in the form of solid, particulate, powder, paste, whisker or fibres.
- the material may also be coated or mixed with wetting agents to ensure wetting and or infusion of lower melting materials.
- the multi material feedstock material can be in the form of wire or rods.
- the feedstock is fed from a feed unit 6 attached to the torch (nozzle) 5 and comprises a suitable arrangement of rollers driven by motors to feed the source material 4.
- the feed unit stores the feedstock source material in either reel for wire as illustrated or in a magazine for rods.
- the magazine unit for storing rods is capable of feeding the rods sequentially to a prescribed order.
- the torch 5 also houses the induction coil 12 which is water cooled and separated from the feedstock source material 4 by a dielectric material for example quartz tube to enable energising of shielding gas fed through the torch as well prevent short circuit
- the induction coil is powered by an alternating electrical supply 11 that provides alternating current in the frequency range of lOOKHz up to 100MHz.
- the control unit 10 can be programmed to deliver desired current to the induction coil 12 as necessary.
- the size of the torch 5 and the tube is dictated by the size and type of feedstock source material 4. Larger diameter feedstock source material 4 would require a bigger torch 5.
- Shielding gas 9 is supplied to the torch through a suitable reservoir with mass flow control unit connected to control unit to regulate flow rates.
- the shielding gas 9 typically is an inert gas such as Argon or Helium but a gaseous mixture containing low volume of active elements such as hydrogen can also be used.
- a secondary heat source in the form of induction plasma torch 13 connected to a motion control system 8 capable of movement in 6 axes controlled via control unit 10.
- the plasma torch is powered by either same power source or a separate power source 11.
- Plasma gas 14 is fed to the torch to produce the plasma flame which is used to energise the surface of component being deposited and also prevents the molten layer of material from freezing before deposition.
- Both torches can be setup in various configuration with respect to the substrate.
- the torches can be parallel to the substrate/ previous layer i.e. 0°/180° or any angle between 0 to 180°.
- the plasma torch 13 is connected to the torch unit (nozzle) 5 and driven by the same motion system.
- FIG 4 multiple torches that are independent of each other is illustrated where one torch unit is connected to a plasma torch. This enables higher deposition rate. This configuration also allows to use different size of feed material and torches to improve surface finish of final component.
- Embodiments in Fig 1 to 4 can be housed in vacuum or inert atmosphere chamber 15 as illustrated in Figure 5 for system in Fig 1.
- Figure 6 is an illustration of the torch showing the induction coil 12 powered by the power supply 11 and the feed source material 4 enclosed inside a dielectric material and shielding gas 9 fed to the torch (nozzle 5).
- Figures 7 and 8 illustrate various combinations of feedstock source material 4 possible for deposition.
- Figure 7 show cored wire / rod where both materials can be solid metal or metallic alloy or the inner material is in the form of powder, whisker, fibre or paste made of either ceramic, dielectric, semiconductor or metals. The configuration will facilitate manufacture of a metal alloys as well as metal matrix alloy.
- Figure 8 shows a coaxial configuration of three materials. The possible stacking sequence are that all three layers comprise conductive metal or metal alloys, or the middle layer may constitute a nonconducting material in various forms described earlier sandwiched between the metal layers which may be of differing composition or same.
- Figure 9 shows a configuration using source material in the form of rods which may be of single material or comprised of plurality of materials arranged coaxially.
- the rods are stored and arranged sequentially in the magazine and is fed onto the nozzle sequentially by a driving mechanism (not shown) like typical drive unit used on wires.
- the figure illustrates various size (diameter) rods which may be of same or differing composition that are fed in a sequence which will enable manufacture of functionally graded material.
- An alternating current of suitable frequency in the regions of 100kHz to 100MHz and power is supplied to the induction coil 12 to heat the feedstock source material 4.
- Feedstock source material 4 is driven through motors in the feed unit 6 controlled by the control unit 10, as the material passes through the torch (nozzle) 5 changes in magnetic flux induces current on the source material 4 such that they are concentrated in the outer layer of the source material 4 referred to as skin depth.
- This region of the source material 4 is heated rapidly through Joule heating beyond the melting temperature of the source material 4.
- Shielding gas 9 supplied to the torch (nozzle) 5 prevents the molten region from oxidation and can also optionally energise an area of the deposition layer.
- the feed rate is selected to prevent complete melting of the source material 4 through transfer of heat on conduction.
- the partially melted source material 4 is then deposited on the component surface 2 or substrate 1, at a suitable angle using the molten outer layer to wet and fuse on the deposition area. It is to be understood that by deposition layer (3) this refers either to the initial substrate layer or a preceding layer of fused source material (4).
- MMC metal matrix composite
- FGM functional graded material
- MMC is a composite material where reinforcement materials are embedded in a metal matrix.
- MMC comprises of at least two constituent parts: a) matrix of either metal or alloy such as Al, Ti, Cu, Co-Ni, Steel etc and b) reinforcement made from another metal or metal alloy or ceramic material such as Alumina, SiC, Zirconia, TiN, CBN etc in the form of either particulate, powder, whisker or fibres.
- MMC components can be fabricated by various methods but the commonly used method is either stir casting or infiltration method whereby the reinforcement is fed onto a molten metal matrix.
- a cored or coaxial wire or rod is used where the reinforcement material is surrounded by the metal matrix.
- the reinforcement may be coated or mixed with wetting agents to aid wetting with the metal matrix.
- the matrix material has lower melting temperature compared to the reinforcement.
- the metal melts and infuses with the reinforcing material and is deposited on surface by wetting and fusing the molten metal layer.
- FGM Functional graded materials
- a novel approach to FGM components is also proposed using the coaxial rods stacked in a magazine and fed to the torch sequentially.
- the rods can be made from gradually differing composition of materials, thereby depositing material with gradual change in composition and properties
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Plasma & Fusion (AREA)
- Physics & Mathematics (AREA)
- Ceramic Engineering (AREA)
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- Powder Metallurgy (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Dans divers modes de réalisation, la présente invention concerne un système et un procédé de fabrication additive d'un composant métallique, composant d'alliage ou composant composite de matrice métallique par l'application d'un chauffage par induction d'un matériau de charge d'alimentation sous la forme d'un fil, d'un fil fourré ou de tiges combinées à un chauffage par induction d'un gaz de protection pour exciter une couche de dépôt. En particulier, un nouveau procédé de dépôt est proposé, la charge d'alimentation du matériau étant déposée par fusion locale uniquement de la surface externe du matériau par chauffage par induction à effet de peau tandis que la masse de matériau ne subit pas de fusion.
Applications Claiming Priority (2)
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GB2017521.2 | 2020-11-05 | ||
GBGB2017521.2A GB202017521D0 (en) | 2020-11-05 | 2020-11-05 | A device, apparatus and method of additive manufacturing metal components, alloy components or metal matrix composite components |
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WO2022096843A1 true WO2022096843A1 (fr) | 2022-05-12 |
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PCT/GB2021/000120 WO2022096843A1 (fr) | 2020-11-05 | 2021-11-05 | Dispositif, appareil et procédé de fabrication additive de composant métallique, composant d'alliage ou composant composite de matrice métallique |
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WO (1) | WO2022096843A1 (fr) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017152142A1 (fr) * | 2016-03-03 | 2017-09-08 | Desktop Metal, Inc. | Fabrication additive avec matériaux de construction métalliques |
US20180311727A1 (en) * | 2015-04-07 | 2018-11-01 | Eder Numero 1 | Three-dimensional printing device using inductive and resistive devices |
EP3435744A1 (fr) * | 2017-07-28 | 2019-01-30 | United Technologies Corporation | Procédé et dispositif de fabrication additive de composants |
CN109550947A (zh) | 2017-09-26 | 2019-04-02 | 中国石油大学(华东) | 一种基于超高频感应加热的金属沉积成形方法及装置 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20140008354A1 (en) * | 2012-07-06 | 2014-01-09 | Lincoln Global, Inc. | Method and system of using induction heating to heat consumable during hot wire process |
US10766802B2 (en) * | 2014-11-29 | 2020-09-08 | National Tsing Hua University | Flexible 3D freeform techniques |
US10357920B2 (en) * | 2017-01-17 | 2019-07-23 | Obsidian Advanced Manufacturing, Llc | Gas phase integrated multimaterial printhead for additive manufacturing |
-
2020
- 2020-11-05 GB GBGB2017521.2A patent/GB202017521D0/en not_active Ceased
-
2021
- 2021-11-05 WO PCT/GB2021/000120 patent/WO2022096843A1/fr active Application Filing
- 2021-11-05 GB GB2115934.8A patent/GB2602713A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20180311727A1 (en) * | 2015-04-07 | 2018-11-01 | Eder Numero 1 | Three-dimensional printing device using inductive and resistive devices |
WO2017152142A1 (fr) * | 2016-03-03 | 2017-09-08 | Desktop Metal, Inc. | Fabrication additive avec matériaux de construction métalliques |
EP3435744A1 (fr) * | 2017-07-28 | 2019-01-30 | United Technologies Corporation | Procédé et dispositif de fabrication additive de composants |
US10349510B2 (en) | 2017-07-28 | 2019-07-09 | United Technologies Corporation | Method for additively manufacturing components |
CN109550947A (zh) | 2017-09-26 | 2019-04-02 | 中国石油大学(华东) | 一种基于超高频感应加热的金属沉积成形方法及装置 |
Non-Patent Citations (2)
Title |
---|
SHARMA GOURAV K ET AL: "On the suitability of induction heating system for metal additive manufacturing", INSTITUTION OF MECHANICAL ENGINEERS. PROCEEDINGS. JOURNAL OF ENGINEERING MANUFACTURE., vol. 235, no. 1-2, 14 July 2020 (2020-07-14), GB, pages 219 - 229, XP055890452, ISSN: 0954-4054, Retrieved from the Internet <URL:http://journals.sagepub.com/doi/full-xml/10.1177/0954405420937854> DOI: 10.1177/0954405420937854 * |
SUN RUI ET AL: "Understanding the thermal process during laser assisted ultra-high frequency induction deposition with wire feeding", INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, vol. 153, 1 June 2020 (2020-06-01), AMSTERDAM, NL, pages 119536, XP055872294, ISSN: 0017-9310, DOI: 10.1016/j.ijheatmasstransfer.2020.119536 * |
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GB2602713A (en) | 2022-07-13 |
GB202017521D0 (en) | 2020-12-23 |
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