WO2022045360A1 - Film - Google Patents

Abstract

Provided is a film having a lower CTE than a composite film containing a conventional cycloolefin-based polymer. The film contains a resin (A) and a cycloolefin-based polymer (B). The glass transition temperature and/or the melting point of the cycloolefin-based polymer (B) is 160°C or higher.

Description

the film

The present invention relates to a film that can be used as a substrate material compatible with a printed circuit board for a high frequency band and an antenna substrate, and a composition capable of forming the film.

With the full-scale spread of the 5th generation mobile communication system called 5G, there is a demand for printed circuits that can handle high frequency bands and printed wiring boards that can be used for antennas. However, in the high frequency band, the transmission loss derived from the substrate material has a significant effect, so it is important to select a substrate material that can suppress the transmission loss. For example, a copper-clad laminate called CCL has a structure in which copper foils are laminated on both surfaces of a resin layer via an adhesive. The transmission loss of the CCL can be suppressed by reducing the dielectric loss of the resin layer serving as the transmission line, particularly the dielectric loss tangent and the relative permittivity.
A cycloolefin-based polymer is known as a substrate material having a dielectric loss tangent or a low relative permittivity, and a film in which this cycloolefin-based polymer is composited with another resin has been studied. For example, Patent Document 1 discloses a low-dielectric resin composition containing a specific resin (A) and a cycloolefin polymer (B), and a film composed of the composition.

Japanese Unexamined Patent Publication No. 2017-125176

The resin layer in the CCL, which can handle the high frequency band, is required to reduce the CTE in order to reduce the dielectric loss and prevent peeling from the copper foil. However, according to the study of the present inventor, it has been found that the composite film as in Patent Document 1 may have a high CTE, and in particular, there is room for improvement in the cycloolefin polymer.
Therefore, an object of the present invention is to provide a film having a lower CTE than a conventional composite film containing a cycloolefin polymer and a composition capable of forming the film.

As a result of diligent studies to solve the above problems, the present inventor has made a glass transition temperature of the cycloolefin polymer (B) in a film containing the resin (A) and the cycloolefin polymer (B) (hereinafter referred to as “the glass transition temperature”). It has been found that the above-mentioned problems can be solved by adjusting at least one of the Tg) and the melting point to 160 ° C. or higher, and the present invention has been completed. That is, the present invention includes the following suitable forms.

[1] A film containing a resin (A) and a cycloolefin polymer (B), wherein at least one of the glass transition temperature and the melting point of the cycloolefin polymer (B) is 160 ° C. or higher.
[2] The film according to [1], wherein the distance between the HSP values of the resin (A) and the cycloolefin polymer (B) is 6 or more.
[3] The cycloolefin polymer (B) has the formula (I) :.

[In equation (I), m represents an integer of 0 or more,
R ⁷ to R ¹⁸ represent hydrogen atoms, halogen atoms or hydrocarbon groups having 1 to 20 carbon atoms independently of each other, and when a plurality of R ¹¹ to R ¹⁴ are present, they are independently and identical to each other. May be different, and R ¹⁶ and R ¹⁷ may be bonded to each other and form a ring with the carbon atom to which they are bonded.]
The film according to [1] or [2], which comprises a monomer unit (I) derived from cycloolefin represented by.
[4] The content of the monomer unit (I) in the cycloolefin-based polymer (B) is 60 mol% or more with respect to the total molar amount of the repeating units constituting the cycloolefin-based polymer (B). 3] The film according to.
[5] The cycloolefin-based polymer (B) is derived from at least one selected from the group consisting of ethylene, a linear α-olefin having 3 to 20 carbon atoms, and an aromatic vinyl compound having 8 to 20 carbon atoms. The film according to any one of [1] to [4], which comprises the monomer unit (II).
[6] The film according to any one of [1] to [5], wherein the cycloolefin polymer (B) has a weight average molecular weight (Mw) of 30,000 or more.
[7] The ratio (Mw / Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) of the cycloolefin polymer (B) is 2.5 or less, any of [1] to [6]. The film described in.
[8] The cycloolefin-based polymer (B) contains the two-chain structure of the monomer unit (I), and in the two-chain structure, the ratio of the meso-type two-chain to the racemic-type two-chain (meso-type two-chain). / The film according to any one of [1] to [7], wherein the racemic type two chains) is 0.50 or less.
[9] The content of the cycloolefin-based polymer (B) is 5 to 50% by mass with respect to the total mass of the resin (A) and the cycloolefin-based polymer (B) contained in the film, [1] to The film according to any one of [8].
[10] The resin (A) is at least one resin selected from the group consisting of a polyimide resin, a liquid crystal polymer, a fluororesin, an aromatic polyether resin and a maleimide resin, [1] to [9]. ] The film described in any of.
[11] The liquid crystal polymer has the formula (a1), the formula (a2) and the formula (a3):
-O-Ar ¹ -CO- (a1)
-CO-Ar ² -CO- (a2)
-X-Ar ³ -Y- (a3)
[(In formula (a1), Ar ¹ represents a 1,4-phenylene group, a 2,6-naphthylene group or a 4,4'-biphenylene group, and represents.
In formula (a2), Ar ² represents a 1,4-phenylene group, a 1,3-phenylene group or a 2,6-naphthylene group.
In formula (a3), Ar ³ represents a 1,4-phenylene group or a 1,3-phenylene group.
X represents -NH-
Y represents -O- or NH-]
The film according to [10], which is a liquid crystal polyester containing a structural unit represented by.
[12] The film according to any one of [1] to [11], wherein the glass transition temperature of the resin (A) is 180 ° C. or higher.
[13] A composition containing a resin (A), a cycloolefin polymer (B) and a solvent, wherein at least one of the glass transition temperature and the melting point of the cycloolefin polymer (B) is 160 ° C. or higher.
[14] The cycloolefin polymer (B) has the formula (I) :.

[In the formula (I), m represents an integer of 0 or more, R ⁷ to R ¹⁸ represent hydrogen atoms, halogen atoms or hydrocarbon groups having 1 to 20 carbon atoms independently of each other, and R ¹¹ to R ¹⁴ If there are a plurality of them, they may be independent of each other, the same or different, and R ¹⁶ and R ¹⁷ may be bonded to each other and form a ring with the carbon atom to which they are bonded. ]
The composition according to [13], which comprises a monomer unit (I) derived from cycloolefin represented by.
[15] The content of the monomer unit (I) in the cycloolefin polymer (B) is 60 mol% or more with respect to the total molar amount of the repeating units constituting the cycloolefin polymer (B). 14].

The film of the present invention has a lower CTE than the conventional composite film containing a cycloolefin polymer. Therefore, the film of the present invention can be suitably used as a material for a printed wiring board or the like that can be used for a printed circuit board or an antenna board.

[the film]
The film of the present invention contains a resin (A) and a cycloolefin polymer (B).

<Cycloolefin polymer (B)>
The cycloolefin-based polymer (B) contained in the film of the present invention (hereinafter, may be simply referred to as polymer (B)) includes a homopolymer and a copolymer.

At least one of the Tg and the melting point of the polymer (B) is 160 ° C. or higher. The present inventor uses a polymer (B) having at least one of Tg and a melting point of 160 ° C. or higher, preferably Tg of 160 ° C. or higher, as compared with a conventional composite film containing a cycloolefin-based polymer. We have found that CTE is reduced. This is because when at least one of the Tg and the melting point of the polymer (B) is adjusted to 160 ° C. or higher, the CTE of the polymer (B) itself is reduced, so that the polymer (B) is composited with the resin (A). It is presumed that this is because the CTE of the film is also reduced. In addition, in this specification, CTE means a linear expansion coefficient.

Furthermore, the present inventor has also found that when a polymer (B) having at least one of Tg and a melting point of 160 ° C. or higher is used, the bending resistance is unexpectedly improved. Usually, when Tg or at least one of the melting points is increased, the structure can be rigid, so that the flexibility is inferior and the bending resistance tends to be lowered. However, the film of the present invention is surprisingly excellent in bending. It can also be resistant. In addition, in this specification, bending resistance is not only resistance when it is bent once (hereinafter, may be referred to as one-time bending resistance), but also resistance when it is repeatedly bent (hereinafter, repeated bending resistance). It is a meaning including). Further, the mechanical property means a mechanical property including bending resistance and elastic modulus, and increasing or improving the mechanical property means, for example, increasing bending resistance and / or elastic modulus. Further, the dielectric property means a property related to dielectric including a dielectric loss, a relative permittivity and a dielectric loss tangent, and when the dielectric property is increased or improved, for example, the dielectric loss, the relative permittivity and / or the dielectric loss tangent is reduced. Show that.

On the other hand, when the Tg and the melting point of the polymer (B) are less than 160 ° C., the CTE of the polymer (B) can be high, so that the CTE of the obtained composite film tends to increase and the bending resistance tends to decrease. It is in.
The Tg of the polymer (B) is preferably 180 ° C. or higher, more preferably 200 ° C. or higher, still more preferably 220 ° C. or higher, still more preferably 240 ° C. or higher, and particularly preferably 260 ° C. or higher. When the polymer (B) is a crystalline polymer having a melting point, the melting point of the polymer (B) is preferably 180 ° C. or higher, more preferably 200 ° C. or higher, still more preferably 220 ° C. or higher, still more preferably 240 ° C. or higher. ° C. or higher, particularly preferably 260 ° C. or higher, preferably 500 ° C. or lower, more preferably 400 ° C. or lower, still more preferably 320 ° C. or lower. When at least one of the Tg and the melting point of the polymer (B) is at least one of the above lower limits, the CTE of the film is more likely to be reduced, and the heat resistance and mechanical properties, particularly bending resistance, are more likely to be enhanced. At least one of the Tg and the melting point of the polymer (B) is preferably 500 ° C. or lower, more preferably 400 ° C. or lower, still more preferably 320 ° C. or lower. When the Tg of the polymer (B) is not more than the above upper limit, the mechanical properties of the film, particularly the resistance to repeated bending, are likely to be enhanced. The Tg of the polymer (B) is a softening temperature measured by thermomechanical analysis (hereinafter, may be referred to as TMA) based on JIS K 7196, and can be measured by, for example, the method described in Examples. The melting point of the polymer (B) can be determined by measuring the melting peak temperature from the melting curve obtained by using, for example, a differential scanning calorimeter (DSC, manufactured by Hitachi High-Tech Science Co., Ltd.).

The monomer unit constituting the polymer (B) in the present invention is not particularly limited as long as the Tg and / or melting point of the polymer (B) is 160 ° C. or higher, but it is easy to improve the water absorption resistance and the dielectric property of the film. In addition, from the viewpoint that the CTE of the film can be easily reduced and the mechanical properties such as bending resistance can be easily enhanced, the polymer (B) is represented by the formula (I) :.

[In equation (I), m represents an integer of 0 or more,
R ⁷ to R ¹⁸ represent hydrogen atoms, halogen atoms or hydrocarbon groups having 1 to 20 carbon atoms independently of each other, and when a plurality of R ¹¹ to R ¹⁴ are present, they may be the same as each other. They may be different, and R ¹⁶ and R ¹⁷ may bond to each other and form a ring with the carbon atoms they bond to.]
It is preferable to contain the monomer unit (I) derived from cycloolefin represented by.

In equation (I), m is an integer of 0 or more. From the viewpoint that the CTE of the film can be easily reduced, the mechanical properties such as heat resistance and bending resistance can be easily improved, and the film can be easily obtained, the upper limit of m is preferably an integer of 3 or less, more preferably an integer of 2 or less. , More preferably an integer of 1 or less.

Examples of the hydrocarbon group having 1 to 20 carbon atoms, which is a member of the substituents of R ⁷ to R ¹⁸ , include an alkyl group such as a methyl group, an ethyl group, a propyl group, a butyl group, a hexyl group, an octyl group and a dodecyl group. An aryl group such as a phenyl group, a trill group, or a naphthyl group; an aralkyl group such as a benzyl group or a phenetyl group; Be done. Among these, an alkyl group, an aryl group or an aralkyl group may be used from the viewpoint of easily enhancing mechanical properties such as water absorption resistance, dielectric property, heat resistance and bending resistance of the film and easily reducing the CTE of the film. preferable. That is, R ⁷ to R ¹⁸ are preferably a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, or an aralkyl group having 7 to 20 carbon atoms, and are preferably a hydrogen atom or an aralkyl group having 1 to 20 carbon atoms. More preferably, it is an alkyl group of ~ 10.

Examples of the cycloolefin represented by the formula (I) include norbornene, 5-methylnorbornene, 5-ethylnorbornene, 5-butylnorbornene, 5-phenylnorbornene, 5-benzylnorbornene, tetracyclododecene and tricyclodecene. , Tricycloundecene, pentacyclopentadecene, pentacyclohexadecene, 8-methyltetracyclododecene, 8-ethyltetracyclododecene and the like. Among these, norbornene is preferable from the viewpoint of easy availability of raw material monomer, reduction of CTE, improvement of mechanical properties such as heat resistance and bending resistance. The cycloolefin represented by the formula (I) may be used alone or in combination of two or more.

In one embodiment of the invention, the polymer (B) preferably comprises a two-chain structure of monomeric units (I). By including the two-chain structure, the heat resistance is likely to be improved as compared with a polymer having the same content of the monomer unit (I). The presence or absence of the two-chain structure can be determined by ¹³ C-NMR spectrum analysis. For example, in the case of a tetracyclodecene-ethylene copolymer, signals derived from the ethylene-tetracyclodecene-ethylene chain, which is an isolated chain of tetracyclodecene, appear at around 54.7 ppm and around 51.1 ppm, and endo-exo bond. Ethylene-tetracyclodecene-tetracyclodecene-ethylene chain-derived signals, which are two chains of tetracyclodecene, are located near 51.5 ppm and around 50.8 ppm, and are exo-exo-bonded ethylene-tetracyclodecene-tetracyclo. Since the signal derived from the decene-ethylene chain appears at around 55.3 ppm and around 54.3 ppm, it can be determined by the signal pattern around 55 ppm and around 50 ppm.

The two-chain structure of the monomer unit (I) includes a meso-type two-chain structure represented by the following structural formula (II-1) or the following structural formula (II-2), and / or the following structural formula (III-). 1) or a racemo type two chain represented by the following structural formula (III-2) is included.

The ratio of the meso-type two-chain to the racemo-type two-chain (hereinafter, may be referred to as meso-type two-chain / racemo-type two-chain) is preferably 0.50 or less, more preferably 0.40 or less, still more preferably. It is 0.30 or less, particularly preferably 0.20 or less, preferably 0.01 or more, and more preferably 0.05 or more. When the ratio of the meso-type two-chain to the racemic-type two-chain is within the above range, the mechanical properties and heat resistance of the film can be easily improved. The ratio of the meso-type two-chain to the racemic-type two-chain is, for example, using ¹³ C-NMR in "RA Wendt, G. Fink, Macromol. Chem. Phys., 2001, 202, 3490" and "Special. It can be calculated based on the attribution described in "Kai 2008-285656", and specifically, it can be calculated by the method described in Examples. As a method for adjusting the meso-type two-chain and the racemo-type two-chain within the above range, there is a method of selecting a catalyst having an appropriate ligand width with respect to the bulkiness of the monomer. As the catalyst, for example, the catalyst described in JP-A-9-183809 can be used.

The content of the monomer unit (I) in the polymer (B) is preferably 60 mol% or more, more preferably 65 mol% or more, still more preferably 65 mol% or more, based on the total molar amount of the repeating units constituting the polymer (B). Is 70 mol% or more, particularly preferably 75 mol% or more, preferably 100 mol% or less, more preferably 99 mol% or less, still more preferably 98 mol% or less. When the content of the monomer unit (I) is at least the above lower limit, it is easy to increase Tg, so that it is easy to reduce the CTE of the film, and it is easy to improve heat resistance and mechanical properties, particularly bending resistance. When the content of the monomer unit (I) is not more than the above upper limit, it is easy to enhance mechanical properties such as bending resistance. The content of the monomeric unit (I) is based on the attribution described in "RA Wendt, G. Fink, Macromol. Chem. Phys., 2001, 202, 3490" using ¹³ C-NMR. It can be calculated, for example, by the method described in Examples.

The polymer (B) has ethylene, a linear α-olefin having 3 to 20 carbon atoms, and 8 to 20 carbon atoms from the viewpoint of easily reducing the CTE of the film and enhancing mechanical properties such as bending resistance. It preferably contains a monomer unit (II) derived from at least one selected from the group consisting of aromatic vinyl compounds, and more preferably contains a monomer unit (II) derived from ethylene.

Examples of the linear α-olefin having 3 to 20 carbon atoms include propylene, 1-butene, 1-pentene, 1-hexene, 1-heptene, 1-octene, 1-nonene, 1-decene and the like. .. Among these, propylene, 1-butene, 1-hexene or 1-octene is preferable, and propylene is preferable, from the viewpoint of easily reducing the CTE of the film and easily enhancing the mechanical properties such as bending resistance. More preferred. As the linear α-olefin having 3 to 20 carbon atoms, one type may be used alone, or two or more types may be used in combination. The "linear α-olefin" refers to a linear olefin having a carbon-carbon unsaturated double bond at the α-position.

Examples of the aromatic vinyl compound having 8 to 20 carbon atoms include styrene, methylstyrene, dimethylstyrene, ethylstyrene, tert-butylstyrene, vinylnaphthalene, vinylanthracene, diphenylethylene, isopropenylbenzene, isopropenyltoluene and isopropenyl. Examples thereof include ethylbenzene, isopropenylpropylbenzene, isopropenylbutylbenzene, isopropenylpentylbenzene, isopropenylhexylbenzene, isopropenyloctylbenzene, isopropenylnaphthalene, isopropenylanthracene and the like. Among these, styrene, methylstyrene or dimethylstyrene are preferable, and more preferably, from the viewpoint of easy availability of the raw material monomer, easy reduction of CTE of the film, and easy improvement of mechanical properties such as bending resistance. Examples include styrene. As the aromatic vinyl compound having 8 to 20 carbon atoms, one kind may be used alone, or two or more kinds may be used in combination.

In one embodiment of the present invention, the cycloolefin polymer is made from ethylene, propylene and styrene from the viewpoints of easy availability of raw material monomers, easy reduction of CTE of the film, and easy improvement of mechanical properties such as bending resistance. It may contain a monomer unit (II) derived from at least one selected from the group consisting of ethylene and styrene, more preferably a monomer unit (II) derived from at least one selected from the group consisting of ethylene and styrene. preferable.

The content of the monomer unit (II) in the polymer (B) is preferably 0 mol% or more, more preferably 0.01 mol% or more, based on the total molar amount of the repeating units constituting the polymer (B). It is more preferably 1 mol% or more, still more preferably 2 mol% or more, preferably 40 mol% or less, more preferably 35 mol% or less, still more preferably 30 mol% or less, and particularly preferably 25 mol% or less. When the content of the monomer unit (II) is at least the above lower limit, it is easy to improve mechanical properties such as bending resistance of the film, processability and moldability. When the content of the monomer unit (II) is not more than the above upper limit, it is easy to reduce the CTE of the film and to improve the mechanical properties such as heat resistance and bending resistance.

In one embodiment of the present invention, the polymer (B) is preferably a cycloolefin-based copolymer from the viewpoint of easily improving mechanical properties such as heat resistance, processability and bending resistance, and easily reducing CTE. , A group consisting of a monomer unit (I) derived from cycloolefin represented by the formula (I), ethylene, a linear α-olefin having 3 to 20 carbon atoms, and an aromatic vinyl compound having 8 to 20 carbon atoms. More preferably, it is a cycloolefinic copolymer containing a monomer unit (II) derived from at least one selected, and a monomer unit (I) derived from norbornene and a monomer unit derived from ethylene. It may be an ethylene-norbornene copolymer containing (II) or a styrene-norbornene copolymer containing a monomer unit (I) derived from norbornene and a monomer unit (II) derived from styrene. More preferred.

The polymer (B) may contain other monomeric units (III). Other monomeric units (III) include, for example, conjugated diene such as butadiene or isoprene; non-conjugated diene such as 1,4-pentadien; acrylic acid; acrylic acid ester such as methyl acrylate or ethyl acrylate; methacrylic. Acids; methacrylic acid esters such as methyl methacrylate or ethyl methacrylate; vinyl acetate and the like. The other monomer unit (III) can be used alone or in combination of two or more.
The polymer (B) can be used alone or in combination of two or more.

In one embodiment of the present invention, the weight average molecular weight of the polymer (B) (hereinafter, the weight average molecular weight may be abbreviated as Mw) is preferably 30,000 or more, more preferably 50,000 or more, still more preferably. It is 70,000 or more, particularly preferably 90,000 or more, preferably 2,000,000 or less, more preferably 1,000,000 or less, still more preferably 700,000 or less. When Mw is at least the above lower limit, heat resistance is likely to be increased and strength is likely to be improved. When Mw is not more than the above upper limit, it is easy to improve mechanical properties such as bending resistance and moldability.

In one embodiment of the present invention, the ratio (Mw / Mn) of Mw of the polymer (B) to the number average molecular weight (hereinafter, the number average molecular weight may be abbreviated as Mn) is preferably 2. 5 or less, more preferably 2.2 or less, still more preferably 2.0 or less, even more preferably 1.95 or less, particularly preferably 1.90 or less, preferably 1.30 or more, still more preferably 1. It is 50 or more, more preferably 1.60 or more, and particularly preferably 1.65 or more. When the Mw / Mn ratio is not more than the above upper limit, it is easy to improve mechanical properties such as bending resistance of the film, and when it is more than the above lower limit, it is easy to improve the moldability. In addition, Mw and Mn can be determined by gel permeation chromatography (hereinafter, may be abbreviated as GPC) measurement and converted to standard polystyrene, and can be determined, for example, by the method described in Examples.

In one embodiment of the present invention, the refractive index of the polymer (B) is preferably 1.600 or less, more preferably 1.570 or less, still more preferably 1. It is 550 or less, preferably 1.500 or more, and more preferably 1.520 or more. The refractive index of the polymer (B) can be measured by a refractometer, for example, by the method described in Examples.

In one embodiment of the present invention, the CTE of the polymer (B) is preferably 58 ppm / K or less, more preferably 55 ppm / K or less, still more preferably 50 ppm / K or less, preferably 0 ppm / K or more, more preferably. Is 0.01 ppm / K or more, more preferably 1 ppm / K or more, still more preferably 5 ppm / K or more. When the CTE of the polymer (B) is not more than the above upper limit, it is easy to reduce the CTE of the obtained film. Further, when CCL is produced by laminating with a copper foil, it is preferable to adjust the CTE of the film to around 20 ppm / K from the viewpoint of preventing the laminated film from peeling off. The polymer (B) having the optimum CTE can be selected according to the CTE of the resin to be mixed. The CTE can be measured by, for example, TMA, and can be obtained by the method described in Examples.

The content of the polymer (B) is usually 1% by mass or more, preferably 5% by mass or more, more preferably 10% by mass or more, based on the total mass of the polymer (B) and the resin (A) contained in the film. It is more preferably 15% by mass or more, preferably 65% by mass or less, preferably 50% by mass or less, more preferably 40% by mass or less, still more preferably 35% by mass or less. When the content of the polymer (B) is in the above range, it is easy to reduce the CTE of the film, and it is easy to improve the mechanical properties such as the dielectric property and the bending resistance. Further, in a film in which a particulate polymer (B) (hereinafter, may be referred to as a particulate polymer (B)) is dispersed, it is easy to improve the dispersibility, and as a result, the physical characteristics of the film, for example, thermal conductivity (or thermal diffusivity), are easily enhanced. It is easy to reduce variations such as rate).

The form of the polymer (B) contained in the film of the present invention is not particularly limited, and examples thereof include particle-like, fibrous, and sheet-like ones, which are easily uniformly dispersed in the film and have heat resistance and bending resistance. It is preferably in the form of particles from the viewpoint that it is easy to improve the target characteristics and reduce CTE.

The method for adjusting the Tg and the melting point of the polymer (B) is not particularly limited, and examples thereof include a method for appropriately adjusting the content of the monomer unit (I), the Mw of the polymer (B), the degree of crystallinity, and the like. .. The larger the content of the monomer unit (I), the Mw of the polymer (B), and at least one selected from the group consisting of the degree of crystallinity, the higher the Tg and melting point of the polymer (B) tend to be.

<Manufacturing method of polymer (B)>
The method for producing the polymer (B) is not particularly limited, but the monomer forming the polymer (B) in the presence of a catalyst using the transition metal complex (α) represented by the formula (IV) as one component. At least one single selected from the group consisting of, for example, a cycloolefin represented by the formula (I), the ethylene, a linear α-olefin having 3 to 20 carbon atoms, and an aromatic vinyl compound having 8 to 20 carbon atoms. It is preferably produced by polymerizing a weight and optionally the other monomer. In the production of the polymer (B) in the present invention, since the transition metal complex (α) represented by the formula (IV) is used, the content of the monomer unit (I) in the polymer (B) is significantly increased. It is easy to adjust Tg within the above range.

[In equation (IV), M represents a Group 4 transition metal element in the Periodic Table of the Elements.
Cp represents a group having a cyclopentadienyl skeleton and represents
A represents a group 16 atom in the periodic table of elements,
T represents an atom of Group 14 in the periodic table of elements.
D ¹ and D ² are a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, and 6 to 20 carbon atoms. It represents an aryloxy group or a disubstituted amino group having 2 to 20 carbon atoms, which may be the same or different.
R ¹ to R ⁶ are a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, and an aryl having 6 to 20 carbon atoms. Represents an oxy group, a disubstituted amino group having 2 to 20 carbon atoms or a silyl group having 1 to 20 carbon atoms, which may be the same or different, and they may be arbitrarily bonded to form a ring. You may. ]

M is a transition metal element of Group 4 of the Periodic Table of Elements (IUPAC Inorganic Chemistry Naming Method Revised Edition 1989), and examples thereof include a titanium atom, a zirconium atom, and a hafnium atom.

Cp is a group having a cyclopentadienyl skeleton, and examples thereof include cyclopentadienyl, substituted cyclopentadienyl, indenyl, substituted indenyl, fluorenyl, substituted fluorenyl and the like. Specific examples include a cyclopentadienyl group, a methylcyclopentadienyl group, a tetramethylcyclopentadienyl group, an n-propylcyclopentadienyl group, an n-butylcyclopentadienyl group, and an isobutylcyclopentadienyl group. , Phenylcyclopentadienyl group, indenyl group, methylindenyl group, n-propylindenyl group, n-butylindenyl group, isobutylindenyl group, phenylindenyl group, fluorenyl group, methylfluorenyl group, n -A propylfluorenyl group, a phenylfluorenyl group, a dimethylfluorenyl group and the like can be mentioned. Among these, preferably a cyclopentadienyl group, a methylcyclopentadienyl group, a tetramethylcyclopentadienyl group, an n-butylcyclopentadienyl group, an isobutylcyclopentadienyl group, an indenyl group, a methylindenyl group. Alternatively, a fluorenyl group may be mentioned.

A is an atom of Group 16 in the periodic table of elements, and examples thereof include an oxygen atom and a sulfur atom. Among these, an oxygen atom is preferable.

T is an atom of Group 14 of the periodic table of elements, and examples thereof include a carbon atom, a silicon atom, and a germanium atom. Among these, a carbon atom or a silicon atom is preferable.

D ¹ and D ² are independent of each other, a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, and a carbon number of carbon atoms. It is an aryloxy group of 6 to 20 or a disubstituted amino group having 2 to 20 carbon atoms, which may be the same or different. Among these, a halogen atom is preferable.

Specific examples of cases where D ¹ and D ² are halogen atoms include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom.

When D ¹ and D ² are hydrocarbon groups, the number of carbon atoms thereof is preferably 1 to 10. Examples of the hydrocarbon group include methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, isobutyl group, sec-butyl group, tert-butyl group, n-pentyl group, neopentyl group and n-hexyl. Examples thereof include a group, an n-octyl group, a phenyl group, a 2-methylphenyl group, a 3-methylphenyl group, a 4-methylphenyl group, a naphthyl group, a benzyl group and the like.

Specific examples of cases where D ¹ and D ² are halogenated hydrocarbon groups include a fluoromethyl group, a difluoromethyl group, a 1-fluoroethyl group, a 1,1-difluoroethyl group, and a 1,2-difluoroethyl group. 1,1,2-trifluoroethyl group, tetrafluoroethyl group, chloromethyl group, dichloromethyl group, 1-chloroethyl group, 1,1-dichloroethyl group, 1,2-dichloroethyl group, 1,1,2 -Trichloroethyl group, 1,1,2,2-tetrachloroethyl group, bromomethyl group, dibromomethyl group, 1-bromoethyl group, 1,1-dibromoethyl group, 1,2-dibromoethyl group, 1,1,2 -Tribromoethyl group, 1,1,2,2-tetrabromoethyl group, 2-fluorophenyl group, 3-fluorophenyl group, 4-fluorophenyl group, 2,3-difluorophenyl group, 2,4-difluoro Phenyl group, 2,5-difluorophenyl group, 2,6-difluorophenyl group, 2,3,4-trifluorophenyl group, 2,3,5-trifluorophenyl group, 2,3,6-trifluorophenyl Group, 2,3,4,5-tetrafluorophenyl group, 2,3,4,6-tetrafluorophenyl group, pentafluorophenyl group, 2-chlorophenyl group, 3-chlorophenyl group, 4-chlorophenyl group, 2, 3-Dichlorophenyl group, 2,4-dichlorophenyl group, 2,5-dichlorophenyl group, 2,6-dichlorophenyl group, 2,3,4-trichlorophenyl group, 2,3,5-trichlorophenyl group, 2,3 6-Trichlorophenyl group, 2,3,4,5-tetrachlorophenyl group, 2,3,4,6-tetrachlorophenyl group, pentachlorophenyl group, 2-bromophenyl group, 3-bromophenyl group, 4-bromophenyl Group, 2,3-dibromophenyl group, 2,4-dibromophenyl group, 2,5-dibromophenyl group, 2,6-dibromophenyl group, 2,3,4-tribromophenyl group, 2,3,5 -Tribromophenyl group, 2,3,6-tribromophenyl group, 2,3,4,5-tetrabromophenyl group, 2,3,4,6-tetrabromophenyl group, pentabromophenyl group and the like. Be done.

Specific examples of the cases where D ¹ and D ² are alkoxy groups include a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, an n-butoxy group, an isobutoxy group, a sec-butoxy group, a tert-butoxy group and n-. Examples thereof include a pentoxy group, a neopentoxy group, an n-hexoxy group, an n-octoxy group and the like.

Specific examples of the cases where D ¹ and D ² are aryloxy groups include a phenoxy group, a 2-methylphenoxy group, a 3-methylphenoxy group, a 4-methylphenoxy group, a naphthyloxy group and the like.

When D ¹ and D ² are disubstituted amino groups, the disubstituted amino group is an amino group in which two substituents are bonded. Specific examples thereof include dimethylamino group, diethylamino group, di-n-propylamino group, diisopropylamino group, di-n-butylamino group, diisobutylamino group, di-sec-butylamino group and di-tert-butyl. Examples thereof include an amino group, a di-n-hexyl amino group, a di-n-octyl amino group, and a diphenyl amino group.

R ¹ to R ⁶ are independent of each other, a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, and a carbon number of carbon atoms. It represents an aryloxy group of 6 to 20, a disubstituted amino group of 2 to 20 carbon atoms or a silyl group of 1 to 20 carbon atoms, which may be the same or different, and they may be optionally bonded. May form a ring. Among these, a hydrocarbon group having 1 to 20 carbon atoms is preferable.

When R ¹ to R ⁶ are hydrocarbon groups, the number of carbon atoms is preferably 1 to 10. Specific examples thereof include methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, isobutyl group, sec-butyl group, tert-butyl group, n-pentyl group, neopentyl group and n-hexyl group. , N-octyl group, phenyl group, 2-methylphenyl group, 3-methylphenyl group, 4-methylphenyl group, 2,3-dimethylphenyl group, 2,4-dimethylphenyl group, 2,5-dimethylphenyl group , 2,6-dimethylphenyl group, 2,3,4-trimethylphenyl group, 2,3,5-trimethylphenyl group, 2,3,6-trimethylphenyl group, 2,3,4,5-tetramethylphenyl Groups, 2,3,4,6-tetramethylphenyl group, pentamethylphenyl group and the like can be mentioned.

Specific examples of cases where R ¹ to R ⁶ are a halogen atom, a halogenated hydrocarbon group, an alkoxy group, an aryloxy group, and a disubstituted amino group include D ¹ and D ² as a halogen atom and a halogenated hydrocarbon group. As specific examples in the case of an alkoxy group, an aryloxy group, and a disubstituted amino group, those exemplified above can be mentioned.

Specific examples of cases where R ¹ to R ⁶ are silyl groups include a trimethylsilyl group, a triethylsilyl group, a tri-n-propylsilyl group, a triisopropylsilyl group, a tri-n-butylsilyl group, a triisobutylsilyl group, and a tri. Examples thereof include -sec-butylsilyl group, tri-tert-butylsilyl group and triphenylsilyl group.

Specific examples of such a compound represented by the formula (IV) include isopropanol (cyclopentadienyl) (3-tert-butyl-5-methyl-2-phenoxy) titanium dichloride and isopropyridene (methylcyclo). Pentazienyl) (3-tert-butyl-5-methyl-2-phenoxy) Titanium dichloride, isopropylidene (dimethylcyclopentadienyl) (3-tert-butyl-5-methyl-2-phenoxy) Titanium dichloride, isopropi Reden (trimethylcyclopentadienyl) (3-tert-butyl-5-methyl-2-phenoxy) Titanium dichloride, isopropylidene (tetramethylcyclopentadienyl) (3-tert-butyl-5-methyl-2-phenoxy) ) Titanium dichloride, isopropylidene (n-propylcyclopentadienyl) (3-tert-butyl-5-methyl-2-phenoxy) Titanium dichloride, isopropylidene (n-butylcyclopentadienyl) (3-tert-butyl -5-Methyl-2-phenoxy) Titanium dichloride, isopropylidene (isobutylcyclopentadienyl) (3-tert-butyl-5-methyl-2-phenoxy) Titanium dichloride, isopropylidene (phenylcyclopentadienyl) (3) -Tert-Butyl-5-methyl-2-phenoxy) titanium dichloride, isopropylidene (cyclopentadienyl) (3-tert-butyl-2-phenoxy) titanium dichloride, isopropylidene (methylcyclopentadienyl) (3- tert-Butyl-2-phenoxy) Titanium dichloride, isopropylidene (dimethylcyclopentadienyl) (3-tert-butyl-2-phenoxy) Titanium dichloride, isopropyridene (trimethylcyclopentadienyl) (3-tert-butyl- 2-Phenoxy) Titanium dichloride, isopropanol (tetramethylcyclopentadienyl) (3-tert-butyl-2-phenoxy) Titanium dichloride, isopropyridene (n-propylcyclopentadienyl) (3-tert-butyl-2) -Phenoxy) Titanium dichloride, isopropylidene (n-butylcyclopentadienyl) (3-tert-butyl-2-phenoxy) Titanium dichloride, isopropyridene (isobutylcyclope) Ntadienyl) (3-tert-butyl-2-phenoxy) Titanium dichloride, isopropylidene (phenylcyclopentadienyl) (3-tert-butyl-2-phenoxy) Titanium dichloride, isopropylidene (cyclopentadienyl) (2- Phenoxy) Titanium Dichloride, Isopropyridene (Methylcyclopentadienyl) (2-Phenoxy) Titanium Dichloride, Isopropylidene (dimethylcyclopentadienyl) (2-Phenoxy) Titanium Dichloride, Isopropyridene (trimethylcyclopentadienyl) (2) -Phenoxy) Titanium Dichloride, Isopropyridene (Tetramethylcyclopentadienyl) (2-Phenoxy) Titanium Dichloride, Isopropyridene (n-propylcyclopentadienyl) (2-Phenoxy) Titanium Dichloride, Isopropyridene (n-Butylcyclo) Examples thereof include pentadienyl) (2-phenoxy) titanium dichloride, isopropylidene (isobutylcyclopentadienyl) (2-phenoxy) titanium dichloride, isopropyridene (phenylcyclopentadienyl) (2-phenoxy) titanium dichloride and the like.

Further, the compound in which titanium is changed to zirconium or hafnium in the above specific example, and the compound in which isopropridene is changed to dimethylsilylene, diphenylcilylene, and methylene including them can be similarly exemplified. Further, a compound in which dichloride is changed to dibromide, diiodide, dimethyl, dibenzyl, dimethoxydo, or diethoxyde can be similarly exemplified.

The transition metal complex (α) represented by the above formula (IV) can be used as a catalyst for producing the polymer (B) according to the embodiment of the present invention in combination with various co-catalysts. The cocatalyst is a compound that interacts with the transition metal complex (α) to produce a polymerization active species for cyclic olefins and alkenyl aromatic hydrocarbons. Examples thereof include organoaluminum compounds (β) and / or boron compounds (γ) represented by any of the following formulas (γ1) to (γ3), and these co-catalysts are used. The structure of the polymerization active species produced by this is not clear.

Equation (γ1) BQ ¹ Q ² Q ³
Equation (γ2) J ⁺ (BQ ¹ Q ² Q ³ Q ⁴ ) ^－
Equation (γ3) (L—H) ⁺ (BQ ¹ Q ² Q ³ Q ⁴ ) ^－
[In the formulas (γ1) to (γ3), B represents a boron atom in a trivalent valence state.
^Q1 to ^Q4 are independent of each other, a halogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group having 1 to 20 carbon atoms, a substituted silyl group having 1 to 20 carbon atoms, and 1 to 20 carbon atoms. Represents a 20 alkoxy group or a disubstituted amino group having 2 to 20 carbon atoms.
J ⁺ represents an inorganic or organic cation
L represents a neutral Lewis base and (L—H) ⁺ represents a Bronsted acid. ]

As the organoaluminum compound (β), a known organoaluminum compound can be used. Specific examples thereof include organoaluminum compounds represented by the formula (β1), cyclic aluminoxane having a structure represented by the formula (β2), and linear aluminoxane having a structure represented by the formula (β3). , These can be used alone or in combination of two or more.

Equation (β1) E ¹ _a AlZ _3-a
Equation (β2) {-Al (E ² ) -O-} _b
Equation (β3) E ³ {-Al (E ³ ) -O-} _c AlE ³ ₂
[In formulas (β1) to (β3), E1 ^, E2 and E3 represent hydrocarbon groups having ¹ to ⁸ carbon atoms independently of ^{each other} , and all E1, all E2 and all. E ³ may be the same or different, Z may represent hydrogen or halogen, all Z may be the same or different, and a represents an integer of 0-3. , B represent an integer of 2 or more, and c represents an integer of 1 or more. ]

Specific examples of the formula (β1) include trialkylaluminum such as trimethylaluminum, triethylaluminum, tripropylaluminum, triisobutylaluminum, and trihexylaluminum; dimethylaluminum chloride, diethylaluminum chloride, dipropylaluminum chloride, diisobutylaluminum chloride, and the like. Dialkylaluminum chloride such as dihexylaluminum chloride; alkylaluminum dichloride such as methylaluminum dichloride, ethylaluminum dichloride, propylaluminum dichloride, isobutylaluminum dichloride, hexylaluminum dichloride; dimethylaluminum hydride, diethylaluminum hydride, dipropylaluminum hydride, diisobutylaluminum hydride , Dialkylaluminum hydride such as dihexylaluminum hydride and the like. Among these, trialkylaluminum is preferable, and triethylaluminum or triisobutylaluminum is more preferable.

Specific examples of E ² and E ³ in the formula (β2) and the formula (β3) include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, an isobutyl group, an n-pentyl group and neopentyl. Examples thereof include an alkyl group such as a group. Among these, a methyl group or an isobutyl group is preferable. b is an integer of 2 or more, preferably an integer of 2 to 40. c is an integer of 1 or more, preferably an integer of 1 to 40.

The above aluminoxane is made by various methods. The method is not particularly limited, and it may be produced according to a known method. For example, a method for making a solution of trialkylaluminum, for example, trimethylaluminum, etc. in a suitable organic solvent, for example, benzene, an aliphatic hydrocarbon, etc., in contact with water, trialkylaluminum, for example, trimethylaluminum, etc. An example is a method of making the solution by contacting it with a metal salt containing water of crystallization, for example, copper sulfate hydrate.

As the boron compound (γ), any of the boron compounds represented by the formula (γ1), the formula (γ2) or the formula (γ3) can be used.

In the formula (γ1), B represents a boron atom in a trivalent valence state, and ^Q1 to ^Q3 are halogen atoms, hydrocarbon groups having 1 to 20 carbon atoms, and carbon atoms 1 to 20 independently of each other. Represents a halogenated hydrocarbon group, a substituted silyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms or a disubstituted amino group having 2 to 20 carbon atoms, which may be the same or different. May be good. ^Q1 to ^Q3 are independent of each other, preferably a halogen atom, a hydrocarbon group having 1 to 20 carbon atoms, or a halogenated hydrocarbon group having 1 to 20 carbon atoms.

Specific examples of the boron compound represented by the formula (γ1) include tris (pentafluorophenyl) borane, tris (2,3,5,6-tetrafluorophenyl) borane, and tris (2,3,4,5-). Examples thereof include tetrafluorophenyl) borane, tris (3,4,5-trifluorophenyl) borane, tris (2,3,4-trifluorophenyl) borane, phenylbis (pentafluorophenyl) borane, and the like, and tris is preferable. (Pentafluorophenyl) Borane can be mentioned.

In the formula (γ2), B represents a boron atom in a trivalent valence state, and ^Q1 to ^Q4 are the same as ^Q1 to ^Q3 in the above formula (γ1).
Further, J ⁺ represents an inorganic or organic cation.

Examples of the inorganic cation in J ⁺ include a ferrosenium cation, an alkyl-substituted ferrosenium cation, and a silver cation.
Examples of the organic cation in J ⁺ include triphenylmethyl cation and the like.
(BQ ¹ Q ² Q ³ Q ⁴ ) ^-As tetrakis (pentafluorophenyl) borate anion, tetrakis (2,3,5,6-tetrafluorophenyl) borate anion, tetrakis (2,3,4,5- Tetrafluorophenyl) borate anion, tetrakis (3,4,5-trifluorophenyl) borate anion, tetrakis (2,2,4-trifluorophenyl) borate anion, phenylbis (pentafluorophenyl) borate anion, tetrakis (3) , 5-Bistrifluoromethylphenyl) Borate anion and the like.

Specific combinations thereof include ferrosenium tetrakis (pentafluorophenyl) borate, 1,1'-dimethylferrosenium tetrakis (pentafluorophenyl) borate, silver tetrakis (pentafluorophenyl) borate, and triphenylmethyl tetrakis. Examples thereof include (pentafluorophenyl) borate, triphenylmethyltetrakis (3,5-bistrifluoromethylphenyl) borate, and preferably triphenylmethyltetrakis (pentafluorophenyl) borate.

In the formula (γ3), B represents boron in a trivalent valence state, and ^Q1 to ^Q4 are the same as ^Q1 to ^Q3 in the above formula (γ1). Further, L represents a neutral Lewis base, and (L—H) ⁺ represents a Bronsted acid.

In the formula (γ3), examples of the Bronsted acid (L—H) ⁺ include trialkyl-substituted ammonium cations, N, N-dialkylanilinium cations, dialkylammonium cations, and triallylphosphonium cations. As (BQ ¹ Q ² Q ³ Q ⁴ ) ^- , the same as described above can be mentioned.

Specific combinations thereof include triethylammonium tetrakis (pentafluorophenyl) borate, tripropylammonium tetrakis (pentafluorophenyl) borate, tri (n-butyl) ammonium tetrakis (pentafluorophenyl) borate, and tri (n-butyl). ) Ammonium tetrakis (3,5-bistrifluoromethylphenyl) borate, N, N-dimethylanilinium tetrakis (pentafluorophenyl) borate, N, N-diethylanilinium tetrakis (pentafluorophenyl) borate, N, N-2 , 4,6-Pentamethylanilinium tetrakis (pentafluorophenyl) borate, N, N-dimethylanilinium tetrakis (3,5-bistrifluoromethylphenyl) borate, di-iso-propylammonium tetrakis (pentafluorophenyl) borate , Dicyclohexylammonium tetrakis (pentafluorophenyl) borate, triphenylphosphonium tetrakis (pentafluorophenyl) borate, tri (methylphenyl) phosphonium tetrakis (pentafluorophenyl) borate, tri (dimethylphenyl) phosphonium tetrakis (pentafluorophenyl) borate, etc. Can be mentioned. Among these, tri (n-butyl) ammonium tetrakis (pentafluorophenyl) borate or N, N-dimethylanilinium tetrakis (pentafluorophenyl) borate is preferable.

As the co-catalyst, it is preferable to use organoaluminum compound (β) and compound (γ) in combination.

The transition metal complex (α) represented by the formula (IV), the organoaluminum compound (β) and / or the compound (γ) can be charged and used in any order at the time of polymerization, but any of them can be used. You may use the reaction product obtained by contacting the combination of the above in advance.

The molar ratio of the co-catalyst / transition metal complex (α) is preferably 0.01 to 10,000, more preferably 0.5 to 2,000. When the catalyst component is used in solution, the concentration of the transition metal complex (α) is preferably 0.0001 to 5 mmol / L, more preferably 0.001 to 1 mmol / L. The amount of the catalyst component used is preferably 0.00001 to 1 mol%, more preferably 0.0001 to 0.1 mol%, based on the total amount of all the monomers used.

The polymerization method of the polymer (B) according to the embodiment of the present invention is not particularly limited, and for example, a batch type or continuous type gas phase polymerization method, a bulk polymerization method, or a solution weight using an appropriate solvent is used. Any method such as a legal method or a slurry polymerization method can be adopted.

When a solvent is used, various solvents can be used under the condition that the catalyst is not inactivated, and examples of such a solvent include hydrocarbon solvents such as benzene, toluene, pentane, hexane, heptane, and cyclohexane; Examples thereof include halogenated hydrocarbon solvents such as dichloromethane and ethylene dichloride.

When a solvent is used, the ethylene partial pressure in the system during polymerization is, for example, 50 to 400 kPa, preferably 50 to 300 kPa, and the hydrogen partial pressure is preferably 0 to 100 kPa. When ethylene and hydrogen are introduced into the system, it is preferable to pressurize with the partial pressure of hydrogen and then pressurize with the partial pressure of ethylene. Further, after the solution of the cycloolefin represented by the formula (I) is charged into the polymerization reaction tank, toluene may be further charged.

The polymerization temperature is preferably 50 ° C. or higher, more preferably 50 to 150 ° C., and even more preferably 50 ° C. to 100 ° C. A chain transfer agent such as hydrogen can also be added to adjust the molecular weight of the polymer.

<Resin (A)>
The film of the present invention contains the resin (A). The resin (A) is a resin different from the polymer (B). When the resin (A) is a cycloolefin-based resin, it may be a cycloolefin-based resin having a different type from the polymer (B), for example, a different type of monomer unit constituting the resin, its content, and the like.

The resin (A) is not particularly limited, and for example, diallyl phthalate resin, silicone resin, phenol resin, unsaturated polyester resin, polyurethane resin, melamine resin, urea resin, xylene resin, furan resin, aniline resin, acetone-formaldehyde resin. Thermocurable resin selected from alkyd resin, maleimide resin, maleimide-cyanic acid ester resin, cyanate ester resin, benzoxazine resin, polybenzimidazole resin, and polycarbodiimide resin; olefin resin; acrylic resin; Styrene-based resin; Rubber-based resin; Fluorine-based resin; Vinyl-based resin; General-purpose engineering plastic; Super-engineering plastic such as liquid crystal polymer and aromatic polyether resin; Polyamide resin; Polygonide resin, Polyethyleneimide resin and other polyimide-based resin; In addition, biodegradable plastics and the like can be mentioned. Among these, at least one resin selected from the group consisting of polyimide resins, liquid crystal polymers, fluororesins, aromatic polyether resins and maleimide resins from the viewpoint of easily improving the heat resistance and dielectric properties of the film. It is preferably present, and more preferably a polyimide resin and / or a liquid crystal polymer. The resin (A) can be used alone or in combination of two or more.

The Tg of the resin (A) is preferably 100 ° C. or higher, more preferably 150 ° C. or higher, still more preferably 180 ° C. or higher, still more preferably 200 ° C. or higher, particularly preferably 300 ° C. or higher, and particularly more preferably 350 ° C. or higher. It is preferably 550 ° C. or lower. When the Tg of the resin (A) is at least the above lower limit, the surface smoothness, particle dispersibility and heat resistance of the obtained film can be easily improved, and the CTE can be easily reduced. When the Tg of the resin (A) is not more than the above upper limit, it is easy to enhance mechanical properties such as bending resistance. The Tg of the resin (A) can be obtained, for example, by performing dynamic viscoelasticity measurement (hereinafter, may be abbreviated as DMA measurement), and can be measured by the method described in Examples.

The Mw of the resin (A) is preferably 50,000 or more, more preferably 100,000 or more, still more preferably 150,000 or more, still more preferably 200,000 or more, and particularly preferably 250,000 in terms of polystyrene. The above is particularly preferably 300,000 or more, preferably 1,000,000 or less, more preferably 800,000 or less, still more preferably 700,000 or less, still more preferably 500,000 or less, and particularly preferably. It is 450,000 or less. When the Mw of the resin (A) is at least the above lower limit, the CTE of the film is likely to be reduced, and mechanical properties such as surface smoothness, particle dispersibility, heat resistance and bending resistance are likely to be enhanced. When the Mw of the resin (A) is not more than the above upper limit, the formability of the film is likely to be improved. The Mw of the resin (A) can be obtained by, for example, GPC measurement and converted to standard polystyrene, and can be obtained by, for example, the method described in Examples.

The polyimide-based resin suitable as the resin (A) includes a resin containing a repeating structural unit containing an imide group (hereinafter, may be referred to as a polyimide resin), and a repeating structural unit containing both an imide group and an amide group. It is meant to include a resin to be used (hereinafter, may be referred to as a polyamide-imide resin) and a precursor before producing a polyimide-based resin by imidization. The precursor before producing the polyimide resin is a polyamic acid. In addition, in this specification, a "repeating structural unit" may be referred to as a "constituent unit". Further, the "constituent unit derived from" may be simply referred to as "unit", and for example, the constituent unit derived from a compound may be referred to as a compound unit.

In a preferred embodiment of the present invention, the film of the present invention has the formula (1): as the resin (A).

[In formula (1), X represents a divalent organic group.
Y represents a tetravalent organic group
* Represents a bond]
It is preferable to contain a polyimide resin having a structural unit represented by. When such a polyimide resin is contained, it is easy to reduce the CTE of the film, and it is easy to improve the mechanical properties such as heat resistance and bending resistance.

X in the formula (1) represents a divalent organic group independently of each other, and preferably represents a divalent organic group having 2 to 100 carbon atoms. Examples of the divalent organic group include a divalent aromatic group and a divalent aliphatic group, and examples of the divalent aliphatic group include a divalent acyclic aliphatic group or a divalent aliphatic group. Cyclic aliphatic groups can be mentioned. Among these, a divalent cyclic aliphatic group and a divalent aromatic group are preferable from the viewpoint of easily reducing the CTE of the film and easily enhancing the mechanical properties such as heat resistance and bending resistance. Aromatic groups are more preferred. In the divalent organic group, the hydrogen atom in the organic group may be substituted with a halogen atom, a hydrocarbon group, an alkoxy group or a halogenated hydrocarbon group, in which case the carbon number of these groups is preferably 1. ~ 8. In the present specification, the divalent aromatic group is a divalent organic group having an aromatic group, and an aliphatic group or another substituent may be contained in a part of the structure thereof. Further, the divalent aliphatic group is a divalent organic group having an aliphatic group, and a part of the structure thereof may contain other substituents, but does not contain an aromatic group.

In one embodiment of the present invention, the polyimide-based resin may contain a plurality of types of X, and the plurality of types of X may be the same as or different from each other. As X in the formula (1), for example, the group (structure) represented by the formulas (2) to (8); the hydrogen atom in the group represented by the formulas (5) to (8) is a methyl group. , Ethyl group, n-propyl group, isopropyl group, n-butyl group, isobutyl group, sec-butyl group, tert-butyl group, fluoro group, chloro group or trifluoromethyl group substituted group and the like.

[In the formulas (2) and (3 ^{), Ra and R b are} independent of each other, a halogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or 6 to 12 carbon atoms. The hydrogen atoms contained in ^{Ra and R b may} be substituted with halogen atoms independently of each other.
W is independent of each other, single bond, -O-, -CH _{2-, -CH 2 -} CH _2- , -CH (CH ₃ )-, -C (CH ₃ ) _2- , -C (CF ₃ ). _2- , -COO-, -OOC-, -SO _2- , -S-, -CO- or -N (R ^c )-, where R ^c is a carbon substituted with a hydrogen atom or a halogen atom. Represents a monovalent hydrocarbon group of numbers 1-12,
n is an integer of 0 to 4, t is an integer of 0 to 4, and u is an integer of 0 to 4.
* Represents a bond.
In formula (4), ring A represents a cycloalkane ring having 3 to 8 carbon atoms.
R ^d represents an alkyl group having 1 to 20 carbon atoms.
r represents an integer greater than or equal to 0 and less than or equal to (the number of carbon atoms in ring A-2).
S1 and S2 represent integers from 0 to 20 independently of each other.
* Represents a bond. ]

Other examples of X in the formula (1) include, for example, an ethylene group, a trimethylene group, a tetramethylene group, a pentamethylene group, a hexamethylene group, a propylene group, a 1,2-butanediyl group, and a 1,3-butanediyl group. , 1,12-Dodecandyl group, 2-methyl-1,2-propanediyl group, 2-methyl-1,3-propanediyl group and other linear or branched alkylene groups with divalent acyclic Examples include aliphatic groups. The hydrogen atom in the divalent acyclic aliphatic group may be substituted with a halogen atom, and the carbon atom may be substituted with a hetero atom, for example, an oxygen atom, a nitrogen atom or the like.

Among these, the polyimide-based resin in the present invention is represented by the formula (2) as X in the formula (1) from the viewpoint of easily achieving low dielectric loss, low CTE, high heat resistance and high mechanical properties of the film. It is preferable to include a structure represented by and / or a structure represented by the formula (3), and it is more preferable to include a structure represented by the formula (2).

In formulas (2) and (3), the bonds of each benzene ring or cyclohexane ring are at the ortho-position, meta-position, or para-position, or α-position, β-position, or β-position, respectively, based on −W—. It may be bonded to any of the γ positions, and from the viewpoint of easily reducing the CTE of the film and easily increasing the heat resistance and mechanical properties, the meta position or the para position, or the β position or the γ position is more preferable. Can bind to the para or γ position. R ^a and R ^b independently represent a halogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or an aryl group having 6 to 12 carbon atoms. Examples of the alkyl group having 1 to 6 carbon atoms include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, an isobutyl group, a sec-butyl group, a tert-butyl group and an n-pentyl group, and 2 -Methyl-butyl group, 3-methylbutyl group, 2-ethyl-propyl group, n-hexyl group and the like can be mentioned. Examples of the alkoxy group having 1 to 6 carbon atoms include a methoxy group, an ethoxy group, a propyloxy group, an isopropyloxy group, an n-butoxy group, an isobutoxy group, a sec-butoxy group, a tert-butoxy group, a pentyloxy group and a hexyloxy group. Examples include a group and a cyclohexyloxy group. Examples of the aryl group having 6 to 12 carbon atoms include a phenyl group, a tolyl group, a xylyl group, a naphthyl group and a biphenyl group. The hydrogen atom contained in Ra and R ^b may be substituted with ^a halogen atom independently of each other, and examples of the halogen atom include a fluorine atom, a chlorine atom, a bromine atom and an iodine atom. Among these, from the viewpoint of easily reducing the CTE of the film and easily improving the heat resistance and the dielectric property, ^{Ra and R b are} independent of each other and have an alkyl group having 1 to 6 carbon atoms or an alkyl group having 1 to 6 carbon atoms. It is preferably an alkyl fluoride group, more preferably an alkyl group having 1 to 3 carbon atoms or an alkyl fluoride group having 1 to 3 carbon atoms, and even more preferably a methyl group or a trifluoromethyl group.

In the formulas (2) and (3), t and u are integers of 0 to 4 independently of each other, which is preferable from the viewpoints that the CTE of the film can be easily reduced and the heat resistance and mechanical properties can be easily improved. Is an integer of 0 to 2, more preferably 0 or 1.

In equations (2) and (3), W is single-bonded independently of each other, -O-, -CH _{2-, -CH 2 -} CH _2- , -CH (CH ₃ )-, -C (CH). ₃ ) _2- , -C (CF ₃ ) _2- , -COO-, -OOC-, -SO _2- , -S-, -CO- or -N (R ^c ) -reduces the CTE of the film. Single bond, -O-, -CH _2- , -C (CH ₃ ) _2- , -C (CF ₃ ) ₂ are preferable from the viewpoint of easy to increase heat resistance and mechanical properties, especially bending resistance. -, -COO-, -OOC- or -CO-, more preferably single bond, -O-, -CH _2- , -C (CH ₃ ) ₂ -or-C (CF ₃ ) _2- .. R ^c represents a monovalent hydrocarbon group having 1 to 12 carbon atoms which may be substituted with a hydrogen atom or a halogen atom. Examples of the monovalent hydrocarbon group having 1 to 12 carbon atoms include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, an isobutyl group, a sec-butyl group, a tert-butyl group and an n-. Pentyl group, 2-methyl-butyl group, 3-methylbutyl group, 2-ethyl-propyl group, n-hexyl, n-heptyl group, n-octyl group, tert-octyl group, n-nonyl group and n-decyl group. Etc., which may be substituted with a halogen atom. Examples of the halogen atom include the same as above.

In the formulas (2) and (3), n is an integer of 0 to 4, and is preferably 0 from the viewpoint of easily reducing the CTE of the film and easily enhancing the mechanical properties such as heat resistance and bending resistance. An integer of ~ 3, more preferably 1 or 2. When n is 2 or more, the plurality of Ws, Ras, and ts may be the same or different from each other, and the positions of the bonds of each benzene ring with respect to ^−W— are also the same. It may or may not be different.

When the polyimide-based resin in the present invention contains both the structure represented by the formula (2) and the structure represented by the formula (3) as X in the formula (1), W and n in the formula (2). , R ^a , R ^b , t and u may be the same as or different from W, n, R ^a , R ^b , t and u in the formula (3) independently of each other.

In the formula (4), the ring A represents a cycloalkane ring having 3 to 8 carbon atoms. Examples of the cycloalkane ring include a cyclopropane ring, a cyclobutane ring, a cyclopentane ring, a cyclohexane ring, a cycloheptane ring, and a cyclooctane ring, and a cycloalkane ring having 4 to 6 carbon atoms is preferable. In ring A, the bonds may or may not be adjacent to each other. For example, when the ring A is a cyclohexane ring, the two bonds may be in the positional relationship of the α-position, the β-position, or the γ-position, and may be preferably in the positional relationship of the β-position or the γ-position.

R ^d in the formula (4) represents an alkyl group having 1 to 20 carbon atoms. Examples of the alkyl group having 1 to 20 carbon atoms include those exemplified above as the hydrocarbon group having 1 to ²⁰ carbon atoms in ^R7 to R18, and preferably represent an alkyl group having 1 to 10 carbon atoms. In equation (4), r represents an integer of 0 or more and (number of carbon atoms of ring A-2) or less. r is preferably 0 or more, and preferably 4 or less. S1 and S2 in the formula (4) represent integers of 0 to 20 independently of each other. S1 and S2 are independent of each other, preferably 0 or more, more preferably 2 or more, and preferably 15 or less.

Specific examples of the structures represented by the formulas (2) to (4) include the structures represented by the formulas (4') and the formulas (9) to (30). In these equations, * represents a bond.

In a preferred embodiment of the present invention, when X in the formula (1) includes a structure represented by the formula (2) and / or the formula (3), the X in the formula (1) is the formula (2). And / or the ratio of the structural unit represented by the formula (3) is preferably 30 mol% or more, more preferably 50 mol% or more, still more preferably, with respect to the total molar amount of the structural unit represented by the formula (1). Is 70 mol% or more, particularly preferably 90 mol% or more, and preferably 100 mol% or less. When the ratio of the structural unit represented by the formula (2) and / or the formula (3) is in the above range, X in the formula (1) can easily reduce the CTE of the film, and has heat resistance and dielectric properties. And it is easy to improve mechanical properties such as bending resistance. The ratio of the structural unit in which Y in the formula (1) is represented by the formula (2) and / or the formula (3) can be measured using, for example, ¹ H-NMR, or calculated from the charging ratio of the raw materials. You can also do it.

In the formula (1), Y represents a tetravalent organic group independently of each other, preferably a tetravalent organic group having 4 to 40 carbon atoms, and more preferably 4 having a cyclic structure and 4 to 40 carbon atoms. Represents a valence organic group. Examples of the cyclic structure include an alicyclic ring, an aromatic ring, and a heterocyclic structure. In the organic group, the hydrogen atom in the organic group may be substituted with a halogen atom, a hydrocarbon group, an alkoxy group or a halogenated hydrocarbon group, in which case the carbon number of these groups is preferably 1 to 8. Is. The polyimide-based resin of the present invention may contain a plurality of types of Y, and the plurality of types of Y may be the same as or different from each other. As Y, the group (structure) represented by the formulas (31) to (38); the hydrogen atom in the group represented by the formulas (34) to (38) is a methyl group, an ethyl group, or n-propyl. Group, isopropyl group, n-butyl group, isobutyl group, sec-butyl group, tert-butyl group, fluoro group, chloro group or trifluoromethyl group substituted group; tetravalent chain type with 1 to 8 carbon atoms. Examples include a hydrocarbon group.

[In formulas (31) to (33), R ¹⁹ to R ²⁶ have a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or 6 to 12 carbon atoms independently of each other. Hydrogen atoms representing an aryl group and contained in R ¹⁹ to R ²⁶ may be substituted with halogen atoms independently of each other.
V ¹ and V ² are independent of each other, single bond, -O-, -CH _{2-, -CH 2 -} CH _2- , -CH (CH ₃ )-, -C (CH ₃ ) _2- , -C. (CF ₃ ) _2- , -COO-, -OOC-, -SO _2- , -S-, -CO-, -N (R ^j )-, formula (a) or formula (b):

(In the formula (a), R ²⁷ to R ³⁰ represent hydrogen atoms or alkyl groups having 1 to 6 carbon atoms independently of each other.
Z represents -C (CH ₃ ) ₂ -or-C (CF ₃ ) _2-
i is an integer from 1 to 3
* Represents a bond)
^Rj represents a monovalent hydrocarbon group having 1 to 12 carbon atoms which may be substituted with a hydrogen atom or a halogen atom.
e and d represent integers from 0 to 2 independently of each other.
f represents an integer of 1 to 3 and represents
g and h represent integers from 0 to 4 independently of each other.
* Represents a bond]

Among these, the polyimide-based resin in the present invention is represented by the formula (31) as Y in the formula (1) from the viewpoint of easily reducing the CTE of the film and easily improving the heat resistance and mechanical properties. It preferably contains at least one structure selected from the group consisting of a structure, a structure represented by the formula (32) and a structure represented by the formula (33), and preferably includes a structure represented by the formula (31). Is more preferable.

In formulas (31) to (33), R ¹⁹ to R ²⁶ are independent of each other, a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or an aryl having 6 to 12 carbon atoms. Represents a group. Examples of the alkyl group having 1 to 6 carbon atoms, the alkoxy group having 1 to 6 carbon atoms and the aryl group having 6 to 12 carbon atoms include the alkyl group having 1 to 6 carbon atoms and the carbon number of carbon atoms in the formulas (2) and (3). Examples of the alkoxy group 1 to 6 and the aryl group having 6 to 12 carbon atoms are mentioned above. The hydrogen atoms contained in R ¹⁹ to R ²⁶ may be substituted with halogen atoms independently of each other, and examples of the halogen atoms include those mentioned above. Among these, from the viewpoint of easily improving the heat resistance and dielectric properties of the film, R ¹⁹ to R ²⁶ are preferably hydrogen atoms or alkyl groups having 1 to 6 carbon atoms independently of each other, and hydrogen atoms or 1 to 3 carbon atoms are preferable. Alkyl groups are more preferred, and hydrogen atoms are even more preferred.

In formula (31), V ¹ and V ² are single-bonded independently of each other, -O-, -CH _{2-, -CH 2 -} CH _2- , -CH (CH ₃ )-, -C (CH ₃ ). ) _2- , -C (CF ₃ ) _2- , -COO-, -OOC-, -SO _2- , -S-, -CO-, -N (R ^j )-, equation (a) or equation (b) ), Which is preferable from the viewpoint of easily reducing the CTE of the film and easily enhancing the mechanical properties such as heat resistance and bending resistance, preferably single bond, -O-, -CH _2- , -C (CH ₃ ) ₂ . -, -C (CF ₃ ) _2- , -COO-, -OOC- or -CO-, more preferably single bond, -O-, -C (CH ₃ ) ₂ -or-C (CF ₃ ) Represents _2- . R ^j represents a monovalent hydrocarbon group having 1 to 12 carbon atoms which may be substituted with a hydrogen atom or a halogen atom. Examples of the monovalent hydrocarbon group having 1 to 12 carbon atoms include those exemplified above.

In the formula (31), e and d represent integers of 0 to 2 independently of each other, and are preferably 0 or 1 from the viewpoint of easily reducing the CTE of the film and easily increasing the heat resistance and mechanical properties. Yes, more preferably e + d = 1.

In the formula (32), f represents an integer of 1 to 3, and is preferably 1 or 2, more preferably 1, from the viewpoint of easily reducing the CTE of the film and easily increasing the heat resistance and mechanical properties.

In the formula (33), g and h represent integers of 0 to 4 independently of each other, and are preferably 0 to 2 from the viewpoint of easily reducing the CTE of the film and easily increasing the heat resistance and mechanical properties. It is an integer, more preferably 0 or 1, and even more preferably an integer of g + h = 0 to 2.

In the formula (a), R ²⁷ to R ³⁰ represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms independently of each other. Examples of the alkyl group having 1 to 6 carbon atoms include those exemplified above as the alkyl group having 1 to 6 carbon atoms in the formulas (2) and (3). Among these, from the viewpoint of easily reducing the CTE of the film and easily improving the heat resistance and mechanical properties, R ²⁷ to R ³⁰ are more preferably hydrogen atoms or alkyl groups having 1 to 3 carbon atoms independently of each other. , Hydrogen atom is more preferable.

In formula (a), Z represents -C (CH ₃ ) _2- or -C (CF ₃ ) _2- . When Z has such a structure, it is easy to improve the heat resistance, the dielectric property, and the mechanical property of the film. i represents an integer of 1 to 3, and is preferably 1 or 2 from the viewpoint of easily reducing the CTE of the film and easily increasing the heat resistance and mechanical properties. When i is 2 or more, the plurality of Z and R ²⁷ to R ³⁰ may be the same or different from each other independently of each other.

Specific examples of the structures represented by the formulas (31) to (33) include the structures represented by the formulas (39) to (51). In these equations, * represents a bond.

In one embodiment of the present invention, when Y in the formula (1) includes at least one selected from the group consisting of the structures represented by the formulas (31) to (33), the formula (1) is used. Y is selected from the group consisting of the structures represented by the formulas (31) to (33), and the ratio of the constituent units represented by at least one is the total mole of the constituent units represented by the formula (1). With respect to the amount, it is preferably 30 mol% or more, more preferably 50 mol% or more, still more preferably 70 mol% or more, particularly preferably 90 mol% or more, and preferably 100 mol% or less. When the ratio of the structural unit represented by at least one selected from the group consisting of the structures represented by the formulas (31) to (33) in the formula (1) is within the above range, the film is formed. It is easy to reduce CTE and to improve heat resistance, dielectric property, water absorption resistance and mechanical property. The ratio of the structural unit represented by at least one selected from the group consisting of the structures represented by the formulas (31) to (33) in the formula (1) is determined by using, for example, ¹ H-NMR. It can be measured or calculated from the raw material charge ratio.

The polyimide-based resin in the present invention has a structural unit represented by the formula (52), a structural unit represented by the formula (53), and a structural unit represented by the formula (54), in addition to the structural unit represented by the formula (1). It may contain at least one selected from the group consisting of the represented building blocks.

[In the formula (52) and the formula (53), Y ¹ represents a tetravalent organic group.
Y ² represents a trivalent organic group
X ¹ and X ² represent divalent organic groups independently of each other.
* Represents a bond.
In formula (54), G and X represent divalent organic groups independently of each other.
* Represents a bond. ]

In a preferred embodiment of the invention, in formulas (52) and (53), Y ¹ is synonymous with Y in formula (1), and X ¹ and X ² are synonymous with X in formula (1). be. It is preferable that Y ² in the formula (53) is a group in which any one of the bonds of Y in the formula (1) is replaced with a hydrogen atom. As Y ² , a group in which any one of the bonds of the groups (structures) represented by the formulas (31) to (38) is replaced with a hydrogen atom; a chain hydrocarbon having a trivalent carbon number of 1 to 8 is used. The group etc. can be mentioned. In one embodiment of the present invention, the polyimide-based resin may contain a plurality of types of Y ¹ or Y ² , and the plurality of types of Y ¹ or Y ² may be the same as or different from each other.

In formula (54), G is a divalent organic group independently of each other, preferably substituted with a hydrocarbon group having 1 to 8 carbon atoms or a fluorine-substituted hydrocarbon group having 1 to 8 carbon atoms. It may be a divalent organic group having 2 to 100 carbon atoms, more preferably substituted with a hydrocarbon group having 1 to 8 carbon atoms or a fluorine-substituted hydrocarbon group having 1 to 8 carbon atoms. It represents a good, divalent organic group having a cyclic structure and having 2 to 100 carbon atoms. Examples of the cyclic structure include an alicyclic ring, an aromatic ring, and a heterocyclic structure. Examples of the organic group of G include a group in which two non-adjacent groups are replaced with hydrogen atoms and a divalent chain carbonization having 6 or less carbon atoms among the bonds of the groups represented by the formulas (31) to (38). A hydrogen group can be mentioned, and preferably, among the bonds of the groups represented by the formulas (39) to (51), a group in which two non-adjacent groups are replaced with a hydrogen atom can be mentioned.
X in the formula (54) is synonymous with X in the formula (1), and when the polyimide resin contains a structural unit represented by the formula (1) and a structural unit represented by the formula (54), each X in the structural unit may be the same or different. In one embodiment of the present invention, the polyimide-based resin may contain a plurality of types of X or G, and the plurality of types of X or G may be the same as or different from each other.

In one embodiment of the present invention, the polyimide resin is a structural unit represented by the formula (1), and in some cases, a structural unit represented by the formula (52), a structural unit represented by the formula (53), and a structural unit represented by the formula (53). It consists of at least one structural unit selected from the structural units represented by the formula (54). Further, from the viewpoint of easily reducing the CTE of the film and easily increasing the heat resistance, dielectric properties, and water absorption resistance, the ratio of the structural unit represented by the formula (1) in the polyimide resin is the polyimide resin. All the structural units included, for example, the structural unit represented by the formula (1), and in some cases, the structural unit represented by the formula (52), the structural unit represented by the formula (53), and the table by the formula (54). It is preferably 80 mol% or more, more preferably 90 mol% or more, still more preferably 95 mol% or more, based on the total molar amount of at least one constituent unit selected from the constituent units. In the polyimide resin, the upper limit of the ratio of the structural unit represented by the formula (1) is 100 mol% or less. The above ratio can be measured using, for example, ¹ H-NMR, or can be calculated from the charging ratio of raw materials. Further, the polyimide resin in the present invention is preferably a polyimide resin from the viewpoint of easily reducing the CTE of the film and easily increasing the heat resistance, the dielectric property, and the water absorption resistance.

In one embodiment of the present invention, the polyimide-based resin in the present invention may contain a halogen atom, preferably a fluorine atom, which can be introduced by, for example, the above-mentioned halogen-containing atom substituent or the like. When the polyimide resin contains a halogen atom, preferably a fluorine atom, it is easy to improve the optical property in addition to the heat resistance and the dielectric property. Preferred fluorine-containing substituents for containing a fluorine atom in the polyimide-based resin include, for example, a fluoro group and a trifluoromethyl group.

When the polyimide-based resin contains a halogen atom, the content of the halogen atom in the polyimide-based resin is preferably 0.1 to 40% by mass, more preferably 1 to 35% by mass, based on the mass of the polyimide-based resin. More preferably, it is 5 to 30% by mass. When the content of halogen atoms is at least the above lower limit, the heat resistance and dielectric properties of the film are likely to be improved. When the content of the halogen atom is not more than the above upper limit, the CTE can be reduced and the synthesis becomes easy.

The imidization ratio of the polyimide resin is preferably 90% or more, more preferably 93% or more, further preferably 95% or more, and usually 100% or less. From the viewpoint of easily improving the optical properties of the film, it is preferable that the imidization ratio is at least the above lower limit. The imidization ratio indicates the ratio of the molar amount of the imide bond in the polyimide-based resin to the value of twice the molar amount of the structural unit derived from the tetracarboxylic acid compound in the polyimide-based resin. When the polyimide resin contains a tricarboxylic acid compound, the value is twice the molar amount of the structural unit derived from the tetracarboxylic acid compound in the polyimide resin, and the molar amount of the structural unit derived from the tricarboxylic acid compound. The ratio of the molar amount of the imide bond in the polyimide resin to the total of the above is shown. The imidization rate can be determined by an IR method, an NMR method, or the like.

In one embodiment of the present invention, the content of the resin (A) is preferably 50% by mass or more, more preferably 60% by mass, based on the total mass of the resin (A) and the polymer (B) contained in the film. % Or more, more preferably 65% by mass or more, usually 99% by mass or less, preferably 95% by mass or less, more preferably 90% by mass or less, still more preferably 85% by mass or less. When the content of the resin (A) is in the above range, it is easy to reduce the CTE of the film and to improve the mechanical properties such as bending resistance. Further, in the film in which the particulate polymer (B) is dispersed, it is easy to improve the dispersibility, and as a result, it is easy to reduce the variation in the physical characteristics of the film, for example, the thermal conductivity.

As described above, the polyimide-based resin in the present invention includes a precursor before imidizing the polyimide-based resin. When the polyimide resin is a polyamic acid, the polyamic acid is the formula (1'):

[In equation (1'), Y and X represent Y and X in equation (1)]
Includes building blocks represented by.

<Manufacturing method of resin (A)>
The resin (A) contained in the film of the present invention may be a commercially available product or may be produced by a conventional method. In one embodiment of the present invention, the resin (A) is preferably a polyimide resin. The method for producing the polyimide resin is not particularly limited, and the polyimide resin is, for example, by a method including a step of reacting a diamine compound with a tetracarboxylic acid compound to obtain a polyamic acid and a step of imidizing the polyamic acid. Can be manufactured. When the resin (A) is a polyamic acid, the step of obtaining the polyamic acid may be carried out. In addition to the tetracarboxylic acid compound, a dicarboxylic acid compound or a tricarboxylic acid compound may be reacted.

Examples of the tetracarboxylic acid compound used for synthesizing the polyimide resin include aromatic tetracarboxylic acid compounds such as aromatic tetracarboxylic acid dianhydride; and aliphatic tetracarboxylic acid compounds such as aliphatic tetracarboxylic acid dianhydride. Can be mentioned. The tetracarboxylic acid compound may be used alone or in combination of two or more. The tetracarboxylic acid compound may be a tetracarboxylic acid compound analog such as an acid chloride compound in addition to the dianhydride.

Specific examples of the tetracarboxylic acid compound include pyromellitic anhydride (hereinafter, may be abbreviated as PMDA), 4,4'-(4,4'-isopropylidene diphenoxy), and diphthalic anhydride (hereinafter, BPADA). (May be abbreviated), 1,4,5,8-naphthalenetetracarboxylic acid dianhydride, 3,3', 4,4'-biphenyltetracarboxylic acid dianhydride (hereinafter, may be abbreviated as BPDA), 4,4'-(Hexafluoroisopropylidene) diphthalic acid dianhydride (hereinafter, may be abbreviated as 6FDA), 4,4'-oxydiphthalic acid anhydride (hereinafter, may be abbreviated as ODPA), 2,2 ', 3,3'-, 2,3,3', 4'-or 3,3', 4,4'-benzophenone tetracarboxylic acid dianhydride, 2,3', 3,4'-biphenyltetracarboxylic Acid dianhydride, 2,2', 3,3'-biphenyltetracarboxylic acid dianhydride, 2,3', 3,4'-diphenyl ether tetracarboxylic acid dianhydride, bis (2,3-dicarboxyphenyl) ) Ether dianhydride, 3,3 ", 4,4"-, 2,3,3 ", 4"-or 2,2 ", 3,3" -p-terphenyltetracarboxylic acid dianhydride, 2 , 2-bis (2,3- or 3,4-dicarboxyphenyl) -propane dianhydride, bis (2,3- or 3.4-dicarboxyphenyl) methane dianhydride, 1,1-bis (2,3- or 3.4-dicarboxyphenyl) 2,3- or 3,4-dicarboxyphenyl) ethane dianhydride, 1,2,7,8-, 1,2,6,7- or 1,2,9,10-phenanthrene-tetracarboxylic acid di Anhydride, 2,2-bis (3,4-dicarboxyphenyl) tetrafluoropropane dianhydride, 1,2,4,5-cyclohexanetetracarboxylic acid dianhydride (hereinafter, may be abbreviated as HPMDA), 2,3,5,6-Cyclohexanetetracarboxylic acid dianhydride, 2,3,6,7-naphthalenetetracarboxylic acid dianhydride, 1,2,5,6-naphthalenetetracarboxylic acid dianhydride, cyclopentane -1,2,3,4-tetracarboxylic acid dianhydride, 4,4'-bis (2,3-dicarboxyphenoxy) diphenylmethane dianhydride, 1,2,3,4-cyclobutanetetracarboxylic acid dianhydride, 1,2,3,4-cyclobutanetetracarboxylic acid dianhydride (Hereinafter, sometimes abbreviated as CBDA), norbornan-2-spiro-α'-spiro-2 "-norbornan-5,5', 6,6'-tetracarboxylic acid anhydride, p-phenylenebis (trimeritate) Anhydride), 3,3', 4,4'-diphenylsulfonate Tracarboxylic acid dianhydride, 2,3,6,7-anthracentetracarboxylic acid dianhydride, 4,8-dimethyl-1,2,3,5,6,7-hexahydronaphthalene-1,2,5 , 6-Tetracarboxylic acid dianhydride, 2,6- or 2,7-dichloronaphthalene-1,4,5,8-tetracarboxylic acid dianhydride, 2,3,6,7-(or 1,4) , 5,8-) Tetrachloronaphthalene-1,4,5,8- (or 2,3,6,7-) Tetracarboxylic acid dianhydride, 2,3,8,9-,3,4,9 , 10-, 4,5,10,11-or 5,6,11,12-perylene-tetracarboxylic acid dianhydride, pyrazine-2,3,5,6-tetracarboxylic acid dianhydride, pyrrolidine-2 , 3,4,5-Tetracarboxylic acid dianhydride, thiophene-2,3,4,5-tetracarboxylic acid dianhydride, bis (2,3- or 3,4-dicarboxyphenyl) sulfonate dianhydride And so on. Among these, PMDA, BPDA, 6FDA, BPADA, ODPA, HPMDA, CBDA are easy to reduce the CTE of the film and to improve the mechanical properties such as heat resistance, dielectric property, water absorption resistance, and bending resistance. , P-Phenylenebis (trimeritate anhydride) is preferred. These tetracarboxylic acid compounds can be used alone or in combination of two or more.

Examples of the diamine compound used for synthesizing the polyimide resin include aliphatic diamines, aromatic diamines and mixtures thereof. In addition, in this embodiment, "aromatic diamine" represents a diamine having an aromatic ring, and an aliphatic group or another substituent may be contained in a part of the structure thereof. The aromatic ring may be a monocyclic ring or a condensed ring, and examples thereof include a benzene ring, a naphthalene ring, an anthracene ring, and a fluorene ring, but the aromatic ring is not limited thereto. Among these, a benzene ring is preferable. Further, the "aliphatic diamine" represents a diamine having an aliphatic group, and may contain other substituents as a part of its structure, but does not have an aromatic ring.

Specific examples of the diamine compound include 1,4-diaminocyclohexane, 4,4'-diamino-2,2'-dimethylbiphenyl (hereinafter, may be abbreviated as m-TB), and 4,4'-diamino-3. , 3'-dimethylbiphenyl, 2,2'-bis (trifluoromethyl) -4,4'-diaminodiphenyl (hereinafter abbreviated as TFMB), 4,4'-diaminodiphenyl ether, 1,3-bis (3-Aminophenoxy) benzene (hereinafter, may be abbreviated as 1,3-APB), 1,4-bis (4-aminophenoxy) benzene (hereinafter, may be abbreviated as 1,4-APB), 1 , 3-Bis (4-aminophenoxy) benzene, 2,2'-bis [4- (4-aminophenoxy) phenyl] propane, 2,2'-dimethyl-4,4'-diaminobiphenyl, 3,3' -Dihydroxy-4,4'-diaminobiphenyl, 2,2-bis- [4- (3-aminophenoxy) phenyl] propane, bis [4- (4-aminophenoxy)] biphenyl, bis [4- (3- (3-aminophenoxy)] Aminophenoxy) Biphenyl, bis [1- (4-aminophenoxy)] biphenyl, bis [1- (3-aminophenoxy)] biphenyl, bis [4- (4-aminophenoxy) phenyl] methane, bis [4- (4- (4-aminophenoxy)] 3-Aminophenoxy) phenyl] methane, bis [4- (4-aminophenoxy) phenyl] ether, bis [4- (3-aminophenoxy) phenyl] ether, bis [4- (4-aminophenoxy)] benzophenone, Bis [4- (3-aminophenoxy)] benzophenone, 2,2-bis- [4- (4-aminophenoxy) phenyl] hexafluoropropane, 2,2-bis- [4- (3-aminophenoxy) phenyl ] Hexafluoropropane, 4,4'-methylenedi-o-toluidine, 4,4'-methylenedi-2,6-xylidine, 4,4'-methylene-2,6-diethylaniline, 4,4'-methylenedi. Aniline, 3,3'-methylenedianiline, 4,4'-diaminodiphenylpropane, 3,3'-diaminodiphenylpropane, 4,4'-diaminodiphenylethane, 3,3'-diaminodiphenylethane, 4,4 '-Diaminodiphenylmethane, 3,3'-diaminodiphenylmethane, 3,3-diaminodiphenyl ether, 3,4'-diaminodiphenyl ether, benzidine, 3,3'-diaminobiphenyl, 3,3'-dimethoxybenze Gin, 4,4 "-diamino-p-terphenyl, 3,3" -diamino-p-terphenyl, m-phenylenediamine, p-phenylenediamine (sometimes abbreviated as p-PDA), 2,2- Bis [4- (4-aminophenoxy) phenyl] Propane (sometimes abbreviated as BAPP), 1,4-bis (4-aminophenoxy) benzene, 1,3-bis (4-aminophenoxy) benzene, resorcinol- Bis (3-aminophenyl) ether, 4,4'-[1,4-phenylenebis (1-methylethylidene)] bisaniline, 4,4'-[1,3-phenylenebis (1-methylethylidene)] bisaniline , Bis (p-aminocyclohexyl) methane, bis (p-β-amino-t-butylphenyl) ether, bis (p-β-methyl-δ-aminopentyl) benzene, p-bis (2-methyl-4-) Aminopentyl) benzene, p-bis (1,1-dimethyl-5-aminopentyl) benzene, 1,5-diaminonaphthalene, 2,6-diaminonaphthalene, 2,4-bis (β-amino-t-butyl) Toluene, 2,4-diaminotoluene, m-xylene-2,5-diamine, p-xylene-2,5-diamine, m-xylylene diamine, p-xylylene diamine, piperazine, 4,4'-diamino- 2,2'-bis (trifluoromethyl) bicyclohexane, 4,4'-diaminodicyclohexylmethane, 4,4 "-diamino-p-terphenyl, bis (4-aminophenyl) terephthalate, 1,4-bis ( 4-Aminophenoxy) -2,5-di-tert-butylbenzene, 4,4'-(1,3-phenylenediisopropyridene) bisaniline, 1,4-bis [2- (4-aminophenyl) -2 -Propyl] benzene, 2,4-diamino-3,5-diethyltoluene, 2,6-diamino-3,5-diethyltoluene, 4,4'-bis (3-aminophenoxy) biphenyl, 4,4'- (Hexafluoropropyridene) dianiline, 1,2-diaminoethane, 1,3-diaminopropane, 1,4-diaminobutane, 1,5-diaminopentane, 1,6-diaminohexinsan, 1,2-diaminopropane , 1,2-Diaminobutane, 1,3-diaminobutane, 2-methyl-1,2-diaminopropane, 2-methyl-1,3-diaminopropane, 1,3-bis (aminomethyl) cyclohexane, 1, 4-bis (aminomethyl) cyclohe Xan, norbornenandiamine, 2'-methoxy-4,4'-diaminobenzanilide, 4,4'-diaminobenzanilide, bis [4- (4-aminophenoxy) phenyl] sulfone, bis [4- (3-amino) Phenoxy) phenyl] sulfone, 9,9-bis [4- (4-aminophenoxy) phenyl] fluorene, 9,9-bis [4- (3-aminophenoxy) phenyl] fluorene, 4,4'-diaminodiphenyl sulfide , 3,3'-diaminodiphenyl sulfide, 4,4'-diaminodiphenyl sulfone, 3,3'-diaminodiphenyl sulfone, 2,5-diamino-1,3,4-oxadiazole, bis [4,4' -(4-Aminophenoxy)] benzanilide, bis [4,4'-(3-aminophenoxy)] benzanilide, 2,6-diaminopyridine, 2,5-diaminopyridine and the like. Among these, 1,4-diaminocyclohexane, 4,4'-diaminodiphenyl ether, TFMB, 4 from the viewpoint of easily reducing the CTE of the film and easily improving the heat resistance, water absorption resistance, dielectric property and mechanical property. , 4'-methylenedianiline, 3,3'-methylenedianiline, p-PDA, benzene, 4,4'-diaminodicyclohexylmethane, 4,4'-diamino-2,2'-bis (trifluoromethyl) Bicyclohexane, m-TB, 4,4 "-diamino-p-terphenyl, bis (4-aminophenyl) terephthalate, 1,4-bis (4-aminophenoxy) -2,5-di-tert-butylbenzene , 1,3-APB, 1,4-APB, resorcinol-bis (3-aminophenyl) ether, 4,4'-(1,3-phenylenediisopropyridene) bisaniline, 1,4-bis [2- ( 4-Aminophenyl) -2-propyl] Benzene, 2,4-diamino-3,5-diethyltoluene, 2,6-diamino-3,5-diethyltoluene, 4,4'-bis (3-aminophenoxy) Biphenyl, 4,4'-(hexafluoropropyridene) dianiline and the like are preferable. The diamine compound can be used alone or in combination of two or more.

In addition to the tetracarboxylic acid compounds used in the resin synthesis, the polyimide-based resin contains other tetracarboxylic acids, dicarboxylic acids, tricarboxylic acids, and anhydrides thereof, as long as the various physical properties of the film are not impaired. The derivative may be further reacted.

Examples of other tetracarboxylic acids include water adducts of the anhydrides of the above tetracarboxylic acid compounds.

Examples of the dicarboxylic acid compound include aromatic dicarboxylic acids, aliphatic dicarboxylic acids, acid chloride compounds related thereto, acid anhydrides, and the like, and two or more of them may be used in combination. Specific examples include a dicarboxylic acid compound of terephthalic acid; isophthalic acid; naphthalenedicarboxylic acid; 4,4'-biphenyldicarboxylic acid; 3,3'-biphenyldicarboxylic acid; a chain hydrocarbon having 8 or less carbon atoms, and 2 Compounds in which one benzoic acid is linked by a single bond, -O-, -CH _2- , -C (CH ₃ ) _2- , -C (CF ₃ ) _2- , -SO _2- or a phenylene group, and their compounds. Examples include acid chloride compounds.

Examples of the tricarboxylic acid compound include aromatic tricarboxylic acids, aliphatic tricarboxylic acids, acid chloride compounds related thereto, acid anhydrides, and the like, and two or more of them may be used in combination. Specific examples include anhydrate of 1,2,4-benzenetricarboxylic acid; 2,3,6-naphthalentricarboxylic acid-2,3-anhydride; a single bond of phthalic anhydride and benzoic acid, -O-. , -CH _2- , -C (CH ₃ ) _2- , -C (CF ₃ ) _2- , -SO _2- or compounds linked with a phenylene group.

In the production of the polyimide-based resin, the amount of the diamine compound, the tetracarboxylic acid compound, the dicarboxylic acid compound and the tricarboxylic acid compound to be used can be appropriately selected according to the ratio of each structural unit of the desired resin.
In a preferred embodiment of the present invention, the amount of the diamine compound used is preferably 0.94 mol or more, more preferably 0.96 mol or more, still more preferably 0.98 mol or more, particularly preferably 0.98 mol or more, relative to 1 mol of the tetracarboxylic acid compound. It is preferably 0.99 mol or more, preferably 1.20 mol or less, more preferably 1.10 mol or less, still more preferably 1.05 mol or less, and particularly preferably 1.02 mol or less. When the amount of the diamine compound used with respect to the tetracarboxylic acid compound is within the above range, the CTE of the obtained film can be easily reduced, and the mechanical and optical properties such as heat resistance, dielectric properties, water absorption resistance, and bending resistance can be obtained. Easy to raise.

The reaction temperature of the diamine compound and the tetracarboxylic acid compound is not particularly limited and may be, for example, 5 to 200 ° C., and the reaction time is also not particularly limited and may be, for example, about 30 minutes to 72 hours. In a preferred embodiment of the invention, the reaction temperature is preferably 5-50 ° C, more preferably 10-40 ° C, and the reaction time is preferably 3-24 hours. With such a reaction temperature and reaction time, it is easy to reduce the CTE of the obtained film, and it is easy to improve mechanical properties such as heat resistance, dielectric properties, water absorption resistance, and bending resistance, and optical properties.

The reaction between the diamine compound and the tetracarboxylic acid compound is preferably carried out in a solvent. The solvent is not particularly limited as long as it does not affect the reaction, and is, for example, water, methanol, ethanol, ethylene glycol, isopropyl alcohol, propylene glycol, ethylene glycol methyl ether, ethylene glycol butyl ether, 1-methoxy-2-propanol, and the like. Alcohol-based solvents such as 2-butoxyethanol and propylene glycol monomethyl ether; phenolic solvents such as phenol and cresol; ethyl acetate, butyl acetate, ethylene glycol methyl ether acetate, γ-butyrolactone (hereinafter, may be abbreviated as GBL), Ester-based solvents such as γ-valerolactone, propylene glycol methyl ether acetate, ethyl lactate; ketone solvents such as acetone, methyl ethyl ketone, cyclopentanone, cyclohexanone, 2-heptanone, and methylisobutylketone; fats such as pentane, hexane, and heptane. Group hydrocarbon solvent; alicyclic hydrocarbon solvent such as ethylcyclohexane; aromatic hydrocarbon solvent such as toluene and xylene; nitrile solvent such as acetonitrile; ether solvent such as tetrahydrofuran and dimethoxyethane; chlorine such as chloroform and chlorobenzene Containing solvent; Amid-based solvent such as N, N-dimethylacetamide (hereinafter, may be abbreviated as DMAc), N, N-dimethylformamide (hereinafter, may be abbreviated as DMF); Sulfur-containing solvent; carbonate solvent such as ethylene carbonate and propylene carbonate; pyrrolidone solvent such as N-methylpyrrolidone (hereinafter, may be abbreviated as NMP); and combinations thereof. Among these, a phenol-based solvent, an amide-based solvent, and a pyrrolidone-based solvent can be preferably used from the viewpoint of solubility.

The reaction between the diamine compound and the tetracarboxylic acid compound may be carried out under conditions of an inert atmosphere (nitrogen atmosphere, argon atmosphere, etc.) or reduced pressure, if necessary, and the reaction may be carried out under the conditions of an inert atmosphere (nitrogen atmosphere, argon atmosphere, etc.), such as an inert atmosphere, for example, a nitrogen atmosphere or an argon atmosphere. It is preferably carried out with stirring in a tightly controlled dehydration solvent.

In the imidization step, imidization may be performed using an imidization catalyst, imidization may be performed by heating, or a combination thereof may be used. Examples of the imidization catalyst used in the imidization step include aliphatic amines such as tripropylamine, dibutylpropylamine and ethyldibutylamine; N-ethylpiperidine, N-propylpiperidin, N-butylpyrolidin and N-butylpiperidine. And alicyclic amines such as N-propylhexahydroazepine (monocyclic); azabicyclo [2.2.1] heptane, azabicyclo [3.2.1] octane, azabicyclo [2.2.2] octane, and Alicyclic amines such as azabicyclo [3.2.2] nonane (polycyclic); as well as pyridine, 2-methylpyridine (2-picolin), 3-methylpyridine (3-picolin), 4-methylpyridine (4). -Picolin), 2-ethylpyridine, 3-ethylpyridine, 4-ethylpyridine, 2,4-dimethylpyridine, 2,4,6-trimethylpyridine, 3,4-cyclopentenopyridine, 5,6,7, Examples include aromatic amines such as 8-tetrahydroisoquinoline and isoquinoline. Further, from the viewpoint of facilitating the imidization reaction, it is preferable to use an acid anhydride together with the imidization catalyst. Examples of the acid anhydride include conventional acid anhydrides used in the imidization reaction, and specific examples thereof include acetic anhydride, propionic anhydride, aliphatic acid anhydrides such as butyric anhydride, and aromatics such as phthalic acid. Acid anhydride and the like can be mentioned. The imidization step by heating may be carried out in a solvent in which a polyamic acid is dissolved, or may be carried out in a filmed state as described later.

In one embodiment of the present invention, when imidized, the reaction temperature is usually 20 to 250 ° C., and the reaction time is preferably 30 minutes to 24 hours, more preferably 1 to 12 hours.

The polyimide-based resin may be separated and purified by a conventional method, for example, a separation means such as filtration, concentration, extraction, crystallization, recrystallization, or column chromatography, or a separation means combining these, which is preferable. In the embodiment, it can be isolated by adding a large amount of alcohol such as methanol to the reaction solution containing the resin, precipitating the resin, and performing concentration, filtration, drying and the like.
It should be noted that a polyimide resin precursor such as polyamic acid may be produced, and a varnish containing the polyimide resin precursor may be used to produce a composition containing the polyimide resin precursor and the polymer (B). .. In the film forming step in the film production described later, a film containing the polyimide resin and the polymer (B) may be produced by imidizing the polyimide resin precursor at the same time as drying. In this case, the polyimide-based resin precursor may be a solid, preferably powder, or a varnish in which the polyimide-based resin precursor is dissolved in a solvent.

Suitable liquid crystal polymers of the resin (A) include liquid crystal polyesters, and preferably liquid crystal polyesters containing structural units represented by the following formulas (a1), (a2) and (a3). ..
-O-Ar ¹ -CO- (a1)
-CO-Ar ² -CO- (a2)
-X-Ar ³ -Y- (a3)
[In the formula (a1), Ar ¹ represents a 1,4-phenylene group, a 2,6-naphthylene group or a 4,4'-biphenylene group.
In formula (a2), Ar ² represents a 1,4-phenylene group, a 1,3-phenylene group or a 2,6-naphthylene group.
In formula (a3), Ar ³ represents a 1,4-phenylene group or a 1,3-phenylene group.
X represents -NH-
Y represents —O— or NH—. ]

The content of the structural unit represented by the formula (a1) is 30 to 80 mol%, and the content of the structural unit represented by the formula (a2) is 10 to 10 to 100 mol% of the total structural unit of the liquid crystal polyester. Liquid crystal polyester having a content of 35 mol% and a structural unit represented by the formula (a3) of 10 to 35 mol% is preferable.

The structural unit represented by the formula (a1) is a structural unit derived from an aromatic hydroxycarboxylic acid, and the structural unit represented by the formula (a2) is a structural unit derived from an aromatic dicarboxylic acid, represented by the formula (a3). The structural unit is an aromatic diamine or a structural unit derived from an aromatic amine having a phenolic hydroxyl group.

In the present embodiment, Ar ¹ is a 2,6-naphthylene group, Ar ² is a 1,3-phenylene group, Ar ³ is a 1,4-phenylene group, and Y is −O. The liquid crystal polyester which is − is preferable.

Examples of the structural unit represented by the formula (a1) include p-hydroxybenzoic acid, 2-hydroxy-6-naphthoic acid, and structural units derived from 4-hydroxy-4'-biphenylcarboxylic acid. The liquid crystal polyester may contain two or more kinds of the structural units. Of these, structural units derived from 2-hydroxy-6-naphthoic acid are preferred.
The content of the structural unit represented by the formula (a1) is preferably 30 mol% or more and 80 mol% or less, more preferably 40 mol% or more and 70, with respect to 100 mol% of the total structural unit of the liquid crystal polyester. It is mol% or less, more preferably 45 mol% or more and 65 mol% or less.

Examples of the structural unit represented by the formula (a2) include terephthalic acid, isophthalic acid, and structural units derived from 2,6-naphthalenedicarboxylic acid. The liquid crystal polyester may contain two or more kinds of the structural units. Of these, structural units derived from isophthalic acid are preferred.
The content of the structural unit represented by the formula (a2) is preferably 10 mol% or more and 35 mol% or less, and more preferably 15 mol% or more and 30% with respect to 100 mol% of the total structural unit of the liquid crystal polyester. It is 17.5 mol% or more, more preferably 27.5 mol% or less, and more preferably 17.5 mol% or more.

Examples of the structural unit represented by the formula (a3) include 3-aminophenol, 4-aminophenol, 1,4-phenylenediamine, 1,3-phenylenediamine, and structural units derived from 4-aminobenzoic acid. .. The liquid crystal polyester may contain two or more kinds of the structural units. Of these, structural units derived from 4-aminophenol are preferable.
The content of the structural unit represented by the formula (a3) is preferably 10 mol% or more and 35 mol% or less, and more preferably 15 mol% or more and 30% with respect to 100 mol% of the total structural unit of the liquid crystal polyester. It is 17.5 mol% or more, more preferably 27.5 mol% or less, and more preferably 17.5 mol% or more.

The liquid crystal polyester used in this embodiment can be produced, for example, by the method described in JP-A-2019-163431.

<Film>
The film of the present invention contains a resin (A) and a polymer (B), and since at least one of the Tg and the melting point of the polymer (B) is 160 ° C. or higher, a composite containing a conventional cycloolefin-based polymer. Compared with film, CTE can be reduced. Furthermore, the film of the present invention can exhibit excellent mechanical properties, particularly bending resistance, despite the fact that at least one of the Tg and the melting point of the polymer (B), particularly Tg, is large. Therefore, the film of the present invention can have both reduced CTE and excellent heat resistance and mechanical properties, particularly bending resistance.

In one embodiment of the present invention, the film of the present invention preferably has a distance between the HSP values of the resin (A) and the polymer (B) in a specific range.
HSP is a Hansen solubility parameter (δ), defined by a three-dimensional parameter of (δD, δP, δH), and the formula (X) :.
δ ² = (δD) ² + (δP) ² + (δH) ² ... (X)
[In equation (X), δD represents the Lоndоn dispersion force term, δP represents the molecular polarization term (dipole interpole force term), and δH represents the hydrogen bond term].
Represented by. Details of HSP are described in "PROPERTIES OF POLYMERS" (Author: WDVANKREVEREN, Publisher: ELSEVIER SCIENTFIC PUBLISHING COMPANY, 1989, 5th edition). The Hansen solubility parameters δD, δP, and δH can be calculated using HSPiP (Hansen Sоlubility Parameters in Practice), a program developed by Dr. Hansen's group who proposed the Hansen solubility parameter, for example, in Examples. The described Ver. 4.1.07 and the like can be used. The details of the Hansen-dissolved sphere method will be described below. The component of interest is dissolved in a solvent having a known HSP value, and the solubility of the component in a specific solvent is evaluated. The solubility is evaluated by visually determining whether or not the target component is dissolved in the solvent. This is done for multiple solvents. As the type of the solvent, it is preferable to use a solvent having a wide range of δt, more specifically, 10 kinds or more, more preferably 15 kinds or more, still more preferably 18 kinds or more. Next, the HSP having a composition targeting the center coordinates (δd, δp, δh) of the Hansen sphere obtained by inputting the obtained solubility evaluation result into HSPiP is used. In addition to the above methods, HSP may be obtained from a structural formula using, for example, numerical values or literature values in a database of HSPiP, or HSPiP may be used. In the present specification, the value of the Hansen solubility parameter is referred to as an HSP value, and the HSP value represents a value at 25 ° C. The HSP value of the resin (A), the HSP value of the polymer (B), and the HSP value of the solvent may be obtained by any of the above methods, for example, by the method described in Examples. ..

The distance between the Hansen solubility parameters (hereinafter, may be abbreviated as HSP) of two substances is called the distance between HSP values. The distance between HSPs (Ra) is an index showing the affinity between the two substances, and the smaller the value, the higher the affinity between the two substances. On the contrary, the larger the Ra value, the lower the affinity between the two substances, that is, the more difficult it is to be compatible.
The distance between the HSP values determines the Hansen solubility parameters δA and δB of the two substances A and B, respectively.
δA = (δDA, δPA, δHA)
δB = (δDB, δPB, δHB)
Assuming that the distance between HSPs (Ra) is the equation (Y) :.
Ra = [4 × (δDA-δDB) ² + (δPA-δPB) ² + (δHA-δHB) ² ] ^0.5 ... (Y)
Can be calculated by.
In this specification, the HSP value and the distance between the HSP values are as defined above, and can be obtained according to the above method.

In a preferred embodiment of the present invention, the film of the present invention has mechanical properties such as heat resistance, dielectric properties and bending resistance even when the distance between the HSP values of the resin (A) and the polymer (B) is relatively large. Excellent and can reduce CTE. Therefore, in the film of the present invention, the distance between the HSP values of the resin (A) and the polymer (B) is preferably 6.0 or more, more preferably 7.0 or more, still more preferably 8.0 or more.
The distance between the HSP values of the resin (A) and the polymer (B) is preferably 30 or less, more preferably 25 or less, still more preferably 20 or less, from the viewpoint of the affinity between the resin and the polymer.

In one embodiment of the present invention, the total mass of the resin (A) and the particulate polymer (B) contained in the film is preferably 40% by mass or more, more preferably 60% by mass or more, based on the mass of the film. It is more preferably 80% by mass or more, particularly preferably 90% by mass or more, and preferably 100% by mass or less. When the total mass of the resin (A) and the particulate polymer (B) contained in the film is at least the above lower limit, the CTE of the film can be easily reduced and the mechanical properties such as dielectric properties and bending resistance can be easily enhanced. Further, in the film in which the particulate polymer (B) is dispersed, it is easy to improve the dispersibility, and as a result, it is easy to reduce the variation in the physical characteristics of the film, for example, the thermal conductivity (or thermal diffusivity).

In the film of the present invention, the average primary particle size of the particulate polymer (B) is 15 μm or less, preferably 10 μm or less, more preferably 5 μm or less, still more preferably 3 μm or less, still more preferably 1 μm or less, and particularly preferably. It is 0.8 μm or less, more preferably 0.5 μm or less, preferably 0.01 μm or more, more preferably 0.03 μm or more, still more preferably 0.05 μm or more. When the average primary particle diameter of the particulate polymer (B) is at least the above lower limit, it is easy to improve the mechanical properties of the film. When the average primary particles of the particulate polymer (B) are not more than the above upper limit, it is easy to enhance mechanical properties such as particle dispersibility, surface smoothness, water absorption resistance and bending resistance of the film. The average primary particle diameter of the particulate polymer (B) can be determined by image analysis observed with an electron microscope, and can be determined, for example, by the method described in Examples.

In a preferred embodiment of the present invention, the film of the present invention preferably contains the resin (A) and the particulate polymer (B), and the particulate polymer (B) is dispersed with respect to the resin (A). , Preferably a uniformly dispersed composite film. For example, it is preferable that the composite film has a sea-island structure, the resin (A) is the sea, and the particulate polymer (B) is the island. Such a composite film tends to enhance mechanical properties such as heat resistance, dielectric properties and bending resistance, and tends to reduce CTE. By setting the distance between the HSP values of the resin (A) and the polymer (B) to be equal to or higher than the above lower limit, the particulate polymer (B) can be easily dispersed uniformly in the film.

In one embodiment of the present invention, the CTE of the film of the present invention can be appropriately designed according to the intended use. When CCL is produced by laminating with a copper film, it is preferable to adjust the CTE of the film to around 20 ppm / K from the viewpoint of preventing peeling of the laminated film. The CTE of the film can be adjusted by the CTE of the resin (A) and the particulate polymer (B) to be mixed, the mixing amount, and the like. From the viewpoint of reducing CTE, it is preferable to mix the particulate polymer (B) having a high Tg. The CTE can be measured by TMA, for example, by the method described in Examples.

The bending resistance of the film of the present invention can be evaluated by, for example, the deformation height after the bending test (hereinafter, may be referred to as a mandrel test), and the smaller the deformation height after the bending test, the greater the bending resistance. The film of the present invention has a deformation height of preferably 10 mm or less, more preferably 7 mm or less, still more preferably 4 mm or less, still more preferably 2 mm or less, particularly preferably 2 mm or less after one bending in a mandrel test having a diameter of 2 mm. It is 1 mm or less. Further, in the mandrel test having a diameter of 2 mm, the film of the present invention has a deformation height of preferably 15 mm or less, more preferably 13 mm or less, still more preferably 10 mm or less, still more preferably 5 mm or less after repeated bending 10 times. It is particularly preferably 2 mm or less. When the deformation height after one bending or the deformation height after 10 times of repeated bending is not more than the above upper limit, excellent bending resistance is likely to be developed. The lower limit of the deformation height after one bending and the deformation height after 10 times of repeated bending is 0 mm or more, respectively. The deformation height after one-time bending and the deformation height after ten-time repeated bending can be measured by, for example, the method described in Examples.

The film of the present invention may contain additives, if necessary. Additives include, for example, antioxidants, flame retardants, cross-linking agents, surfactants, compatibilizers, imidization catalysts, weathering agents, lubricants, antiblocking agents, antistatic agents, antifogging agents, drip-free agents, pigments. , Fillers and the like. Additives can be used alone or in combination of two or more.

In one embodiment of the present invention, the film of the present invention has low CTE, high heat resistance, and high bending because the particulate polymer (B) exhibits high particle dispersibility even if it does not contain a compatibilizer. Can develop mechanical properties such as resistance. Therefore, in the film of the present invention, the content of the compatibilizer is preferably 5 parts by mass or less, more preferably 1 part by mass or less, and further preferably 0.1 part by mass with respect to 100 parts by mass of the resin (A). Below, it is even more preferably less than 0.1 parts by mass, particularly preferably 0.05 parts by mass or less, particularly more preferably 0.01 parts by mass or less, and particularly still more preferably 0.001 parts by mass or less, and most preferably. It may be 0 parts by mass. Further, for example, when the resin (A) is a polyimide resin precursor such as polyamic acid and thermal imidization is required at the time of film production, inhibition of imidization by a compatibilizer or a compatibilizer by heating may be used. From the viewpoint of preventing deterioration of the characteristics of the film due to deterioration, the content of the compatibilizer is preferably less than 0.1 part by mass within the above range. The content of the compatibilizer may be based on 100 parts by mass of the total of the resin (A) and the polymer (B) instead of 100 parts by mass of the resin (A).

The thickness of the film of the present invention can be appropriately selected depending on the intended use, and is preferably 5 μm or more, more preferably 10 μm or more, still more preferably 20 μm or more, preferably 500 μm or less, more preferably 300 μm or less, still more preferably. It is 100 μm or less, particularly preferably 80 μm or less. The thickness of the film can be measured using a film thickness meter or the like, and can be measured, for example, by the method described in Examples. When the film of the present invention is a multilayer film, the above thickness represents the thickness of the single layer portion.

The film of the present invention may be a single-layer film or a multilayer film containing at least one layer made of the film of the present invention. The multilayer film can include other layers (or other films). Even in such a case, the film of the present invention includes all the layers. Examples of the other layer include a functional layer and the like. Examples of the functional layer include a primer layer, a gas barrier layer, an adhesive layer, and a protective layer. The functional layer can be used alone or in combination of two or more.

The film of the present invention may be subjected to surface treatment such as corona discharge treatment, flame treatment, plasma treatment, ozone treatment, etc. by a method usually industrially adopted.

The film of the present invention is not limited to the above embodiment, and various modifications can be made without departing from the gist of the present invention. Further, the configurations and methods of embodiments other than the above may be arbitrarily adopted and combined, and the configurations and methods according to the above one embodiment are applied to the configurations and methods according to the other embodiments described above. You may.

In addition to the low dielectric loss, the film according to the embodiment of the present invention has a lower CTE than the conventional composite film containing a cycloolefin polymer. Further, it is excellent in heat resistance and mechanical properties, especially bending resistance. Therefore, it can be suitably used as a substrate material compatible with a printed circuit board for a high frequency band and an antenna substrate. For example, CCL has a structure in which copper foils are laminated on both surfaces of a resin layer via an adhesive. When the film of the present invention is used as the resin layer, since the CTE is reduced, peeling between the copper foil and the resin layer can be effectively suppressed as compared with the conventional film. Further, since it has excellent mechanical properties, particularly bending resistance, it is resistant to plastic deformation, does not easily have curl, and can be used as a flexible substrate material.
The film of the present invention is also suitably used for other industrial materials such as automobile parts and electric / electronic parts; optical materials such as lenses, prisms, optical fibers, and recording media.

[Film manufacturing method]
The method for producing the film of the present invention is not particularly limited, but for example, the following steps:
(A) Composition preparation step of preparing a composition containing the resin (A), the polymer (B) and the solvent,
It is produced by a method including (b) a coating step of applying the composition to a substrate to form a coating film, and (c) a film forming step of drying the applied liquid (coating film) to form a film. be able to. When the resin (A) is a polyimide resin, a step of completing the imidization reaction may be included in the thermal imidization.

In the composition preparation step, the composition may be prepared, for example, by mixing the resin (A), the polymer (B) and the solvent, and optionally the additive.

Here, in a preferred embodiment of the present invention, as described above, the particulate polymer (B) is dispersed with respect to the film containing the resin (A) and the particulate polymer (B), more preferably the resin (A). It is preferable to form the finished film. The composition preparation step for forming a film in such a preferred embodiment is shown below.

(Composition preparation process)
The composition in a preferred embodiment comprises a resin (A), a particulate polymer (B) and a solvent.

The method for producing the composition is a step (1) of dissolving the polymer (B) in a first solvent to obtain a polymer (B) solution.
After the polymer (B) solution is brought into contact with the second solvent, the first solvent is distilled off and a dispersion liquid containing the particulate polymer (B) (hereinafter, may be referred to as a particulate polymer (B) dispersion liquid). ); And the step (3) of adding the resin (A) to the particulate polymer (B) dispersion. When such a production method is used, the agglomeration of the particles of the polymer (B) can be suppressed, so that the particle size can be easily reduced and the dispersibility can be easily improved. Therefore, it is easy to obtain a film having surface smoothness and high mechanical properties (particularly high bending resistance).

In the step (1), the polymer (B) is dissolved in the first solvent to obtain a polymer (B) solution. The form of the polymer (B) to be dissolved in the first solvent is not particularly limited. The first solvent is not particularly limited as long as the polymer (B) can be dissolved, and is, for example, a hydrocarbon solvent such as benzene, toluene, pentane, hexane, heptane, cyclohexane, xylene; a halogen such as dichloromethane and ethylene dichloride. Examples thereof include a hydrocarbon solvent. Of these, hydrocarbon solvents are preferred. When the first solvent contains a hydrocarbon solvent, the solubility of the polymer (B) and the first solvent is enhanced, so that the particle size of the particulate polymer (B) can be easily reduced and the dispersibility can be easily improved. As a result, it is easy to obtain a film having a smooth surface, high particle dispersibility, high heat resistance, high mechanical properties, particularly high bending resistance and low CTE (hereinafter, the description of the effect after "as a result" is omitted. Sometimes). The first solvent can be used alone or in combination of two or more.

As described above, the first solvent is a solvent in which the polymer (B) is dissolved. Here, in the present specification, the evaluation of "dissolving" or "not dissolving" can be performed according to the method described in <Evaluation of solubility> in Examples.

In one embodiment of the present invention, the distance between the HSP values of the first solvent and the polymer (B) is preferably 4.0 or less, more preferably 3.0 or less, still more preferably 2.5 or less. When the distance between the HSP values is not more than the above upper limit, the solubility of the first solvent and the polymer (B) is increased, so that the particle size of the particulate polymer (B) can be easily reduced and the dispersibility is improved. Cheap. The lower limit of the distance between HSP values usually exceeds 0.

In one embodiment of the present invention, it is preferable that the distance between the HSP values of the first solvent and the polymer (B) is smaller than the radius of interaction of the polymer (B). With such a relationship, the polymer (B) is easily dissolved in the first solvent, so that the particle size of the particulate polymer (B) can be easily reduced and the dispersibility can be easily improved. Further, in the present specification, the interaction radius is a plurality of solvents capable of dissolving a specific polymer, that is, when the Hansen solubility parameter of a good solvent is plotted in a three-dimensional HSP space, the plots of the good solvents are similar to each other. In other words, it tends to gather in a spherical shape at a close position, that is, at the coordinates, and refers to the radius of the sphere, that is, the Hansen solubility sphere. It can be said that a solute having a long interaction radius is easily soluble in many solvents, and a solute having a short interaction radius is easily soluble in a small number of solvents and difficult to be soluble in many solvents. For a specific unknown polymer, it is investigated whether various solvents are good solvents or poor solvents by conducting a solubility test, and the results are input to HSPiP to interact with the polymers. The radius is calculated. Hereinafter, in the present specification, the "interaction radius" is as defined above, and can be obtained according to the above method.

In one embodiment of the present invention, the solubility of the polymer (B) in the first solvent is preferably greater than the solubility of the polymer (B) in the second solvent. With such a relationship, it is easy to obtain a particulate polymer (B) having a small particle size and good dispersibility. The solubility of the polymer (B) in the solvent can be measured by the following method. Add 1,000 mg of polymer (B) and 3 mL of solvent to the sample bottle, and stir at room temperature for 2 hours. Next, the solid phase and the liquid phase were separated by filtration, and the solid phase was dried at 80 ° C. for 2 hours under reduced pressure, and then the mass: X (mg) was measured, and the solubility Y (mg / mL) was measured by the following formula. ) Can be obtained.
Y = (1,000-X) / 3
In addition, for example, in the above definition, when the polymer (B) corresponds to "dissolves" in the first solvent and "insoluble" in the second solvent, the solubility in the first solvent is clearly higher. Therefore, it is not necessary to measure the solubility.

In one embodiment of the present invention, the first solvent is preferably a solvent in which the resin (A) does not dissolve. With such a solvent, the particle size of the particulate polymer (B) can be easily reduced and the dispersibility can be easily improved.

In one embodiment of the present invention, the distance between the HSP values of the first solvent and the resin (A) is preferably 5.0 or more, more preferably 6.0 or more, still more preferably 7.0 or more, and even more preferably. Is 8.0 or more, particularly preferably 9.0 or more. When the distance between the HSP values is not more than the above lower limit, the resin (A) is less likely to be dissolved in the first solvent, so that the particle size of the particulate polymer (B) can be easily reduced and the dispersibility can be easily improved. The upper limit of the distance between the HSP values of the first solvent and the resin (A) is preferably 30.0 or less, more preferably 27.0 or less, still more preferably 25.0 or less, still more preferably 23.0 or less. It is particularly preferably 21.0 or less. When the distance between the HSP values of the first solvent and the resin (A) is not more than the above upper limit, it is easy to suppress the aggregation of the particulate polymer (B), so that the dispersibility of the particles can be easily improved, and the obtained film can be obtained. It is easy to improve the particle dispersibility of.

In one embodiment of the present invention, the distance between the HSP values of the first solvent and the resin (A) is preferably larger than the interaction radius of the resin (A). With such a relationship, since the resin (A) is difficult to dissolve in the first solvent, it is easy to suppress the formation of aggregates of the particulate polymer (B) and it is easy to improve the dispersibility. Further, it is easy to improve mechanical properties such as surface smoothness, particle dispersibility, heat resistance and bending resistance of the obtained film, and it is easy to reduce CTE.

The content of the polymer (B) in the polymer (B) solution is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.1% by mass or more, still more preferably. It is 0.5% by mass or more, preferably 20% by mass or less, more preferably 10% by mass or less, and further preferably 5% by mass or less. When the content of the polymer (B) in the solution is at least the above lower limit, the composition can be easily adjusted. Further, when the content of the polymer (B) in the solution is not more than the above upper limit, it is easy to obtain a dispersion liquid and a film having a small particle size and high dispersibility.

The method for dissolving the polymer (B) in the first solvent is not particularly limited, but for example, the first solvent may be added to the polymer (B), or the polymer (B) may be added to the first solvent. It may be either or both. Further, it may be dissolved by heating or the like depending on the solubility of the first solvent in the polymer (B).

The step (2) is a step of contacting the polymer (B) solution with the second solvent and then distilling off the first solvent to obtain a particulate polymer (B) dispersion liquid.

The second solvent is not particularly limited as long as it is a solvent that can produce the particulate polymer (B) by contact with the polymer (B) solution, and is, for example, an amide solvent such as DMAc or DMF; GBL, γ-valero. Examples thereof include lactone-based solvents such as lactones; sulfur-containing solvents such as dimethyl sulfoxide, dimethyl sulfoxide and sulfolane; carbonate-based solvents such as ethylene carbonate and propylene carbonate; pyrrolidone-based solvents such as N-methylpyrrolidone; and combinations thereof. Among these, the viewpoint that it is easy to suppress the aggregation of the particulate polymer (B), and it is easy to obtain a film having high particle dispersibility, smooth surface, low CTE, high heat resistance and high mechanical properties, particularly high bending resistance. Therefore, at least one selected from the group consisting of an amide-based solvent, a lactone-based solvent, and a pyrrolidone-based solvent is preferable. These solvents can be used alone or in combination of two or more. Further, the particulate polymer (B) dispersion liquid may contain water, an alcohol solvent, a ketone solvent, an acyclic ester solvent, an ether solvent and the like.

In one embodiment of the present invention, the second solvent has a distance between the HSP values of the polymer (B) of preferably 8.5 or more, more preferably 9.0 or more, still more preferably 10.0 or more, still more preferably. Is 11.0 or more. When the distance between the HSP values is at least the above lower limit, it is easy to suppress the aggregation of the particles of the polymer (B), and it is easy to reduce the particle size, so that the dispersibility of the particles is easy to be improved. As a result, it is easy to enhance mechanical properties such as particle dispersibility, surface smoothness, heat resistance and bending resistance of the obtained film. The upper limit of the distance between the HSP values of the second solvent and the polymer (B) is preferably 30.0 or less, more preferably 25.0 or less, still more preferably 20.0. When the distance between the HSP values of the second solvent and the polymer (B) is not more than the above upper limit, it is easy to suppress the aggregation of the particulate polymer (B), so that the dispersibility of the particles can be easily improved. It is easy to improve the particle dispersibility of the film to be obtained.

In one embodiment of the present invention, it is preferable that the distance between the HSP values of the second solvent and the polymer (B) is larger than the radius of interaction of the polymer (B). With such a relationship, the polymer (B) is difficult to dissolve in the second solvent, so that the particle size of the particulate polymer (B) in the particulate polymer (B) dispersion can be easily reduced and the dispersibility can be improved. Easy to improve.

In one embodiment of the present invention, the second solvent is preferably a solvent in which the polymer (B) does not dissolve. With such a solvent, it is easy to suppress the aggregation of the particulate polymer (B), so that it is easy to reduce the particle size and improve the dispersibility of the particles.

In one embodiment of the present invention, the second solvent is preferably a solvent in which the resin (A) is dissolved. With such a solvent, the particulate polymer (B) is likely to be dispersed in the obtained composition and film with a small particle size. In addition, the film tends to form a sea-island structure.

In one embodiment of the present invention, the HSP value distance between the second solvent and the resin (A) is preferably 10.0 or less, more preferably 9.5 or less, still more preferably 9.0 or less, and particularly preferably 8. It is 5.5 or less, preferably 0.01 or more, and more preferably 0.1 or more. When the distance between the HSP values is not more than the above upper limit, the affinity between the second solvent and the resin (A) can be improved. Therefore, in the obtained composition and film, a particulate polymer (B) having a small particle size is used. ) Is easy to disperse.

In one embodiment of the present invention, the distance between the HSP values of the second solvent and the resin (A) is preferably smaller than the interaction radius of the resin (A). With such a relationship, the resin (A) is easily dissolved in the second solvent, so that the particulate polymer (B) is easily dispersed in the obtained composition and film with a small particle size.

The method of contacting the polymer (B) solution with the second solvent is not particularly limited, and examples thereof include a method of mixing the polymer (B) solution and the second solvent. Specifically, a method of adding the polymer (B) solution to the second solvent and a method of adding the second solvent to the polymer (B) solution can be exemplified. By contacting in this way, the particulate polymer (B) having a small particle size can be precipitated or dispersed in the mixed solution of the second solvent and the first solvent. As long as the particulate polymer (B) does not aggregate, a small amount of the resin (A) or other additives may be added at any time during the step (2).

The amount of the polymer (B) solution to be brought into contact with the second solvent is preferably 0.01 part by mass or more, more preferably 0.1 part by mass or more, still more preferably, with respect to 1 part by mass of the amount of the second solvent used. Is 0.3 parts by mass or more, particularly preferably 0.7 parts by mass or more, preferably 100 parts by mass or less, more preferably 10 parts by mass or less, still more preferably 3 parts by mass or less, and particularly preferably 1.5 parts by mass. It is less than a part. When the amount of the polymer (B) solution to be brought into contact with the second solvent is within the above range, it is easy to suppress the aggregation of the particulate polymer (B), so that the particle size is easily reduced and the dispersibility of the particles is improved. It's easy to do.

In step (2), the polymer (B) solution is brought into contact with the second solvent, and then the first solvent is distilled off. Distillation of the first solvent can enhance the dispersion stability of the particulate polymer (B). Further, the polymer (B) may be further precipitated by distilling off the first solvent. The first solvent may be distilled off or removed at least partially, and the first solvent may remain in the dispersion liquid containing the particulate polymer (B). From the viewpoint of easily suppressing the aggregation of the polymer (B) and easily preparing the dispersion liquid, it is preferable that the first solvent partially remains or is partially contained in the particulate polymer (B) dispersion liquid.

In the step (2), the method for distilling off the first solvent is not particularly limited, and a method for distilling off under reduced pressure using an evaporator or the like is exemplified. The pressure and temperature at the time of distillation can be appropriately selected according to the characteristics such as the boiling points of the first solvent and the second solvent. In this production method, since the first solvent is distilled off from the mixed solution of the first solvent and the second solvent, the boiling point of the first solvent is usually lower than the boiling point of the second solvent.

The content of the first solvent contained in the particulate polymer (B) dispersion obtained after distilling off the first solvent is preferably 120 parts by mass or less, more preferably 120 parts by mass with respect to 100 parts by mass of the content of the second solvent. 100 parts by mass or less, more preferably 60 parts by mass or less, still more preferably 45 parts by mass or less, particularly preferably 40 parts by mass or less, particularly more preferably 35 parts by mass or less, particularly still more preferably 30 parts by mass or less, particularly further. It is less than 30 parts by mass, most preferably 25 parts by mass or less, preferably 0.01 parts by mass or more, more preferably 0.05 parts by mass or more, still more preferably 0.1 parts by mass or more. When the content of the first solvent is not more than the above upper limit, it is easy to suppress the aggregation of the particulate polymer (B), so that it is easy to reduce the particle size and improve the dispersibility of the particles. As a result, it is easy to enhance mechanical properties such as particle dispersibility, surface smoothness and bending resistance of the obtained film. Further, when the content of the first solvent is at least the above lower limit, it is easy to prepare the dispersion liquid.

In one embodiment of the present invention, the content of the solvent contained in the particulate polymer (B) dispersion is preferably 50% by mass or more, more preferably 70% by mass or more, and further, with respect to the mass of the dispersion. It is preferably 90% by mass or more, particularly preferably 95% by mass or more, preferably 99.99% by mass or less, more preferably 99.9% by mass or less, still more preferably 99% by mass or less, and particularly preferably 95% by mass. It is as follows. When the content of the solvent is in the above range, it is easy to suppress the aggregation of the particulate polymer (B), so that it is easy to reduce the particle size and improve the dispersibility of the particles. As a result, it is easy to improve mechanical properties such as particle dispersibility, surface smoothness and bending resistance of the obtained film.

In one embodiment of the present invention, the solvent contained in the particulate polymer (B) dispersion may contain other solvents other than the first solvent and the second solvent as long as the effects of the present invention are not impaired. .. The other solvent is not particularly limited, and a conventional solvent can be used. In one embodiment of the present invention, the total mass of the first solvent and the second solvent is preferably 50% by mass or more, more preferably 70% by mass or more, still more preferably, with respect to the mass of the solvent contained in the dispersion liquid. Is 90% by mass or more, more preferably 95% by mass or more, and preferably 100% by mass or less. When the total mass of the first solvent and the second solvent is in the above range, it is easy to suppress the aggregation of the particulate polymer (B), so that it is easy to reduce the particle size and improve the dispersibility of the particles. As a result, it is easy to improve mechanical properties such as particle dispersibility, surface smoothness, and bending resistance of the obtained film.

The content of the particulate polymer (B) contained in the particulate polymer (B) dispersion obtained after distilling off the first solvent is preferably 0.01 with respect to the mass of the particulate polymer (B) dispersion. By mass or more, more preferably 0.1% by mass or more, still more preferably 1% by mass or more, preferably 50% by mass or less, more preferably 30% by mass or less, still more preferably 10% by mass or less, particularly preferably. It is 5% by mass or less. When the content of the polymer (B) is in the above range, the dispersibility of the particles is likely to be improved, so that the mechanical properties such as the particle dispersibility, surface smoothness, and bending resistance of the obtained film are likely to be improved.

It is preferable that the particulate polymer (B) dispersion liquid contains the particulate polymer (B) having a median diameter of 0.01 to 15 μm. The median diameter of the particulate polymer (B) is preferably 0.01 μm or more, more preferably 0.03 μm or more, still more preferably 0.05 μm or more, preferably 15 μm or less, more preferably 10 μm or less, still more preferably. It is 5 μm or less, more preferably 3 μm or less, particularly preferably 1 μm or less, particularly more preferably 0.8 μm or less, and particularly preferably 0.5 μm or less. When the median diameter of the particulate polymer (B) in the dispersion is not less than the above lower limit, it is easy to improve the dielectric properties of the film formed from the composition, and it is easy to manufacture the film, which is not more than the above upper limit. And, it is easy to enhance mechanical properties such as particle dispersibility, surface smoothness, water absorption resistance and bending resistance of the film formed from the composition. The median diameter of the particulate polymer (B) in the dispersion can be determined by a scattering type particle size distribution measurement using laser diffraction, for example, by the method described in Examples. In the present specification, the median diameter is also referred to as D50, and indicates a value in which the number of particles of the particulate polymer (B) on the side smaller than the value is equal to the number of particles on the side larger than the value.

The step (3) is a step of adding the resin (A) to the particulate polymer (B) dispersion liquid. The resin (A) to be added may be in the form of a solid, preferably powder, or may be in the form of a varnish in which the resin (A) is dissolved in a predetermined solvent, for example, a second solvent. In one embodiment of the invention, in step (3), the polyimide resin or polyamic acid can be added in the form of a solid, preferably powder or varnish. When the resin (A) is added in the form of a varnish, the content of the resin (A) in the varnish is preferably 0.1% by mass or more, more preferably 1% by mass or more, based on the mass of the varnish. It is more preferably 5% by mass or more, still more preferably 10% by mass or more, preferably 50% by mass or less, more preferably 30% by mass or less, still more preferably 20% by mass or less. When the content of the resin (A) in the varnish is in the above range, film formation is facilitated, which is advantageous from the viewpoint of film production.

The resin (A) added in the step (3) is preferably 50% by mass or more, more preferably 50% by mass or more, based on the total mass of the polymer (B) and the resin (A) in the particulate polymer (B) dispersion. It is 60% by mass or more, more preferably 65% by mass or more, preferably 95% by mass or less, more preferably 93% by mass or less, still more preferably 90% by mass or less. When the content of the resin (A) added in the step (3) is at least the above lower limit, film formation becomes easy, which is advantageous from the viewpoint of film production. Further, when the content of the resin (A) added in the step (3) is not more than the above upper limit, the dispersibility of the particulate polymer (B) is likely to be improved, so that the particle dispersibility and surface smoothness of the obtained film are smooth. It is easy to enhance mechanical properties such as properties and bending resistance.

The method of adding the resin (A) to the particulate polymer (B) dispersion is not particularly limited, and the resin (A) may be added at once, or the resin (A) may be added in a plurality of times. You may.

The composition preparation step according to the embodiment of the present invention may include steps other than the steps (1) to (3) as long as the effects of the present invention are not impaired, and the resin (A) and the polymer (B) may be included. ) Other polymers or additives, such as the additives exemplified above, may be used.
In a preferred embodiment of the present invention, the resin (A) is added to the particulate polymer (B) dispersion, but the powder polymer (B) may be added to the varnish of the resin (A). .. As shown in the step (3), the varnish of the resin (A) may be a solution of the resin (A) in a predetermined solvent, for example, a first solvent, or a precursor of the resin (A). When the resin solution for synthesizing the above, for example, the resin (A) is a polyimide resin, it may be a polyamic acid solution (at least a solution containing a polyamic acid and a synthetic solvent).

The content of the particulate polymer (B) contained in the composition obtained in the composition preparation step is usually 1% by mass or more, preferably 1% by mass or more, based on the total mass of the resin (A) and the particulate polymer (B). It is 5% by mass or more, more preferably 10% by mass or more, further preferably 15% by mass or more, preferably 50% by mass or less, more preferably 40% by mass or less, still more preferably 35% by mass or less. When the content of the particulate polymer (B) contained in the composition is at least the above lower limit, the dispersibility of the particulate polymer (B) is likely to be enhanced, so that the particle dispersibility and surface smoothness of the obtained film can be improved. And it is easy to improve mechanical properties such as bending resistance. Further, when the content of the particulate polymer (B) contained in the composition is not more than the above upper limit, film formation becomes easy, which is advantageous from the viewpoint of film production. If the dispersibility of the particles in the film is high, the thermal conductivity and the uniformity of CTE are high. Therefore, for example, when the film is used as the resin layer of CCL, it is easy to suppress the peeling of the film and the copper foil. Become.
In a preferred embodiment of the present invention, the resin (A) is added to the particulate polymer (B) dispersion, but the powder polymer (B) may be added to the varnish of the resin (A). ..

In one embodiment of the present invention, the total mass of the resin (A) and the particulate polymer (B) contained in the composition is preferably 1% by mass or more, more preferably 3% by mass or more, still more preferably 5% by mass. The above is preferably 50% by mass or less, more preferably 40% by mass or less, still more preferably 30% by mass or less, still more preferably 20% by mass or less, and particularly preferably 10% by mass or less. When the total mass of the resin (A) and the particulate polymer (B) contained in the composition is in the above range, the dispersibility of the particulate polymer (B) is likely to be enhanced, so that the particle dispersibility and the surface of the obtained film are easy to increase. It is easy to improve mechanical properties such as smoothness and bending resistance. Further, since the film can be easily formed, it is advantageous from the viewpoint of film production.

The content of the first solvent contained in the composition obtained in the composition preparation step is preferably 120 parts by mass or less, more preferably 100 parts by mass or less, still more preferably 100 parts by mass, based on 100 parts by mass of the second solvent. Is 60 parts by mass or less, more preferably 45 parts by mass or less, particularly preferably 40 parts by mass or less, particularly more preferably 35 parts by mass or less, particularly still more preferably 30 parts by mass or less, and particularly even more preferably less than 30 parts by mass. , Most preferably 25 parts by mass or less, preferably 0.01 parts by mass or more, more preferably 0.05 parts by mass or more, still more preferably 0.1 parts by mass or more. When the content of the first solvent is not more than the above upper limit, it is easy to enhance mechanical properties such as particle dispersibility, surface smoothness and bending resistance in the obtained film. Further, when the content of the first solvent is at least the above lower limit, it is easy to prepare the composition.

In one embodiment of the present invention, the content of the solvent contained in the composition obtained in the composition preparation step can be selected from the same range as the content of the solvent contained in the particulate polymer (B) dispersion. When the content of the solvent contained in the composition is in the above range, it is easy to enhance mechanical properties such as particle dispersibility, surface smoothness and bending resistance in the obtained film.

In one embodiment of the present invention, the total mass of the first solvent and the second solvent with respect to the solvent contained in the composition is the first solvent and the second solvent with respect to the solvent contained in the particulate polymer (B) dispersion liquid. It can be selected from the same range as the total mass of. When the total mass of the first solvent and the second solvent contained in the composition is in the above range, it is easy to enhance mechanical properties such as particle dispersibility, surface smoothness and bending resistance in the obtained film.

The median diameter of the particulate polymer (B) in the composition obtained in the composition preparation step can be selected from the same range as the median diameter of the particulate polymer (B) in the above dispersion liquid. The method for determining the median diameter of the particulate polymer (B) in the composition is not particularly limited, but can be determined by, for example, a centrifugal sedimentation type particle size distribution measuring device or an ultrasonic attenuation type particle size distribution measuring device. In the step (3), when the resin (A) is added to the dispersion liquid of the particulate polymer (B) in an amount within a range that does not affect the particle size of the particulate polymer (B) to form a composition, it is dispersed. It is also possible to measure the particle size in the liquid and use this as the particle size in the composition.

(Coating process and film forming process)
The coating step is a step of applying the compositions obtained in the above steps (1) to (3) to a substrate to form a coating film.

In the coating process, the composition is applied onto the substrate by a known coating method to form a coating film. Known coating methods include, for example, wire bar coating method, reverse coating, roll coating method such as gravure coating, die coating method, comma coating method, lip coating method, spin coating method, screen printing coating method, fountain coating method, and dipping method. , Spray method, curtain coating method, slot coating method, hypersalivation forming method and the like.

Examples of the base material include a copper plate (including copper foil), a SUS plate (including SUS foil and SUS belt), a glass substrate, a PET film, a PEN film, another polyimide resin film, a polyamide resin film and the like. Among them, copper plate, SUS plate, glass substrate, PET film, PEN film and the like are preferable from the viewpoint of excellent heat resistance, and copper plate, SUS plate, glass substrate and the like are more preferable from the viewpoint of adhesion to the film and cost. Alternatively, a PET film or the like can be mentioned.

In the film forming step, the film can be formed by drying the coating film and peeling it from the substrate. In one embodiment of the present invention, when the base material is a copper foil, a film is formed without peeling the coating film from the copper foil, and a laminate in which the film is laminated on the obtained copper foil is copper-clad. It can also be used for laminated boards. In the case of peeling, a drying step of further drying the film may be performed after the peeling. The drying of the coating film can be appropriately selected depending on the heat resistance of the resin (A) and the like, but in one embodiment of the present invention, the temperature is 50 to 450 ° C, preferably 55 to 400 ° C, more preferably 70 to 380 ° C. It can be carried out at a temperature, and in another embodiment of the present invention, it can be carried out at a temperature of 50 to 350 ° C., preferably 70 to 300 ° C. In a preferred embodiment of the present invention, it is preferable to carry out drying step by step. By performing the drying step by step, the composition can be dried uniformly, and the Tg of the obtained film can be improved, so that it is easy to achieve reduction of CTE and improvement of mechanical properties such as bending resistance. For example, after heating at a relatively low temperature of 50 to 150 ° C., heating may be performed at 200 to 450 ° C., preferably 200 to 350 ° C. The drying or heating time is preferably 5 minutes to 10 hours, more preferably 10 minutes to 5 hours. By gradually heating from a low temperature to a high temperature in such a range, it is easy to improve the optical properties and Tg of the obtained film. If necessary, the coating film may be dried under inert atmosphere conditions such as in nitrogen or argon, under vacuum or reduced pressure conditions, and / or under ventilation.
In the case of stepwise drying, the coating film may be continuously dried after the coating film is peeled off from the base material during the stepwise drying, and after all the drying is completed, the coating film is applied from the base material ( The film) may be peeled off. For example, the coating film may be peeled off from the substrate after the first step of drying to perform the second and subsequent drying steps, or the coating film (film) may be peeled off from the substrate after all the drying steps are completed. good. The first step of drying may be pre-drying.

When the base material is a copper foil, for example, the film may be peeled off from the copper foil as the base material by etching and removing the copper foil with a ferric chloride solution or the like.

In one embodiment of the present invention, when the resin (A) in the composition is a polyimide resin precursor, for example, a polyamic acid, and a polyimide resin is produced during film production, the composition is applied to a substrate and then applied. It is preferably thermally imidized by heating. By the heating, drying for removing the solvent and thermal imidization can be performed at the same time. The drying and imidization temperature is usually in the range of 50 to 450 ° C., and from the viewpoint of easily obtaining a smooth film, it is preferable to perform heating step by step. For example, the solvent may be removed by heating at a relatively low temperature of 50 to 150 ° C., and then gradually heated to a temperature in the range of 300 to 450 ° C. The heating time can be selected from the same range as the above range, for example.

When the film of the present invention is a multilayer film, it can be produced by, for example, a multilayer film forming method such as a coextrusion processing method, an extrusion laminating method, a thermal laminating method, or a dry laminating method.

[Composition]
The present invention includes a composition comprising a resin (A), a polymer (B) and a solvent, wherein at least one of the Tg and the melting point of the polymer (B) is 160 ° C. or higher. The composition of the present invention is preferably the composition described in the section [Method for producing a film], and the resin (A), the polymer (B) and the solvent contained in the composition are [film] and [film]. The same as that described in the section of [Manufacturing method].

Since the composition of the present invention contains a resin (A), a polymer (B) and a solvent, and at least one of the Tg and the melting point of the polymer (B) is 160 ° C. or higher, a conventional cycloolefin-based polymer can be used. It is possible to form a film having a reduced CTE as compared with the composite film containing the compound. Furthermore, the composition of the present invention can form a film capable of exhibiting excellent mechanical properties, particularly bending resistance, in spite of having at least one of the Tg and the melting point of the polymer (B), particularly a large Tg. Therefore, the composition of the present invention can form a film having both reduced CTE and excellent heat resistance and mechanical properties, particularly bending resistance.

Hereinafter, the present invention will be described in more detail based on Examples and Comparative Examples, but the present invention is not limited to the following Examples. First, the measurement method will be described.

<Norbornene (NB) content>
The content of the monomer unit derived from norbornene (also referred to as “NB content”) in the cycloolefin copolymer obtained in the production example was measured using ¹³ C-NMR. ¹³ C-NMR measurement conditions are as follows.
Equipment: Bruker AVANCE600, 10mm cryoprobe Measurement temperature: 135 ° C
Measurement method: Proton decoupling method Concentration: 100 mg / mL
Number of integrations: 1024 Pulse width: 45 degrees Pulse repetition time: 4 seconds Chemical shift value Criteria: Tetramethylsilane Solvent: 1,2-dichlorobenzene-d ₄ and 1,1,2,2-tetrachloroethane-d ₂ The NB content in the mixed solvent cycloolefin copolymer having a volume ratio of 85:15 is based on 1,2-dichlorobenzene (127.68 ppm) as "RA Wendt, G. Fink, Macromol. Chem. Phys. It was calculated based on the attribution described in ", 2001, 202, 3490". Specifically, the signal integral value observed at the chemical shift value of 44.0-52.0 ppm in the spectrum chart measured using ¹³ C-NMR: _{IC2, C3} (carbon at the 2nd and 3rd positions of the norbornene ring). (Derived from the atom), signal integrated value observed at a chemical shift value of _27.0-33.0 ppm: IC5 _{, C6} + ICE (derived from the carbon atom at the 5th and 6th positions of the norbornene ring and the carbon atom of the ethylene part ) From the following formula.
NB content (mol%) = _{IC2, C3} / ( _{IC5, C6} + _ICE ) x 100

<Distance between Hansen solubility parameter (HSP) and HSP value>
The Hansen solubility parameter (HSP) of the cycloolefin copolymer, polyimide resin, liquid polyester and solvent obtained in the production example, and the distance between HSP values were determined as follows.

(Hansen solubility parameter (HSP) of solvent)
For the HSP value of the solvent, the values in the database of HSPiP (Ver. 4.1.07) were used, and δD of GBL was 18.0 MPa ^0.5 , δP was 16.6 MPa ^0.5 , and δH was 7.4 MPa ^0. The DMAc δD is 16.8 MPa ^0.5 , the δP is 11.5 MPa ^0.5 , the δH is 9.4 MPa ^0.5 , the NMP δD is 18.0 MPa ^0.5 , and the ^δP is 12.3 MPa ⁰ . 5.5, ^δH was set to 7.2 MPa ^0.5 , δD of toluene was set to 18.0 MPa ^0.5 , δP was set to 1.4 MPa ^0.5 , and δH was set to 2.0 MPa ^0.5 .

(HSP of cycloolefin copolymer)
The solubility of the cycloolefin copolymer in various solvents was evaluated. For the evaluation of solubility, use a solvent with a known solubility parameter in a transparent container (refer to the HSPiP database, solvent used: methyl chloride, 1,4-dichlorobenzene, chloroform, toluene, p-xylene, GBL, DMAc, NMP. , Water, acetone, diiodomethane, butyl benzoate) 10 mL and 0.1 g of cycloolefin copolymer were added to prepare a mixed solution. The obtained mixed solution was subjected to ultrasonic treatment for a total of 6 hours. The appearance of the mixed solution after the ultrasonic treatment was visually observed, and the solubility of each resin in the solvent was evaluated based on the following evaluation criteria from the obtained observation results.
(Evaluation criteria)
2: The appearance of the mixed solution is cloudy and precipitates at room temperature, but the appearance of the mixed solution becomes transparent by heating to 50 ° C. and stirring with a stirrer for 30 minutes.
1: The appearance of the mixture is transparent at room temperature.
0: The appearance of the mixed solution is cloudy and precipitates at room temperature, and the appearance of the mixed solution does not become transparent even when heated to 50 ° C. and stirred with a stirrer for 30 minutes.

From the evaluation results of the solubility of the obtained cycloolefin copolymer in a solvent, the HSP value was calculated by the above-mentioned Hansen-dissolved sphere method using HSPiP.

(HSP of polyimide resin)
The solubility of the polyimide resin in various solvents was evaluated. For evaluation of solubility, use a solvent with known solubility parameters in a transparent container (see HSPiP database, solvents used: acetone, toluene, ethanol, tetrahydrofuran, N, N-dimethylformamide, dimethyl sulfoxide, hexane, GBP, ethyl. Acetate, methyl ethyl ketone, propylene glycol monomethyl ether, 1-butanol, N-methylformamide, 1-methylnaphthalene, bromobenzene, 1-methylimidazole, pyrazole, acetic acid) Add 10 mL and 0.1 g of polyimide resin to mix. Prepared. The obtained mixed solution was subjected to ultrasonic treatment for a total of 6 hours. The appearance of the mixed solution after the ultrasonic treatment was visually observed, and the solubility of each resin in the solvent was evaluated based on the following evaluation criteria from the obtained observation results.
(Evaluation criteria)
1: The appearance of the mixed solution is cloudy.
0: The appearance of the mixed solution is transparent.

From the evaluation result of the solubility of the obtained polyimide resin in the solvent, the HSP value was calculated by the above-mentioned Hansen-dissolved sphere method using HSPiP.

(Liquid crystal polyester HSP)
Using HSPiP (Ver. 4.1.07), HSP was obtained from the structural formula.

(Distance between HSP values)
The distance (Ra) between the HSP values of the two substances was determined according to the formula (Y).

<Meso-type two-chain / Racemo-type two-chain>
The ratio of the meso-type two-chain of the norbornene two-chain to the racemo-type two-chain (meso-type two-chain / racemo-type two-chain) of the cycloolefin copolymer obtained in the production example is the above-mentioned NB content using ¹³ C-NMR. It was measured under the same conditions as the measurement of.
The meso-type / racemo-type two-chain of the norbornene two-chain is based on 1,1,2,2-tetrachloroethane (74.24 ppm), and is described in “RAWendt, G.Fink, Macromol.Chem. It was calculated based on the attribution described in "Phys., 2001, 202, 3490" and "Japanese Patent Laid-Open No. 2008-285656". Specifically, the meso-type two-chain / racemo-type two-chain has a signal integral value observed at a chemical shift value of 27.5-28.4 ppm in the spectrum chart measured using ¹³ C-NMR: IC5 _{. C6} -m (derived from carbon atoms at positions 5 and 6 of the meso-type two-chain norbornene ring), signal integrated values observed at a chemical shift value of 28.4-29.6 ppm: IC5 _{, C6} -r (racemo type) It was obtained from the following formula from the carbon atom at the 5th and 6th positions of the two-chain norbornene ring).
Meso-type two-chain / Racemo-type two-chain = IC5 _{, C6} -m / _{IC5, C6} -r

<Refractive index>
The refractive index of the cycloolefin copolymer obtained in the production example was determined by measuring under the following conditions using a sheet-shaped sample formed to a thickness of 100 μm with a vacuum press.
Equipment: Abbe refractometer manufactured by Atago Co., Ltd., TYPE-3
Light source wavelength: 589.3 nm
Intermediate solution: 1-bromonaphthalene Measurement temperature: 23 ± 1 ° C

<Glass transition temperature>
(Cycloolefin copolymer)
The Tg of the cycloolefin copolymer obtained in the production example was determined by measuring the softening temperature by TMA based on JIS K 7196. Specifically, a sample (thickness: 1.0 mm) obtained by molding a cycloolefin copolymer into a sheet with a vacuum press is measured under the following conditions, and the onset of displacement when the indenter sinks into the sample is defined as the softening temperature. did.
Equipment: "TMA / SS6200" manufactured by Hitachi High-Tech Science Corporation
Indenter diameter: 1 mm
Load: 780mN
Temperature program: Temperature rise from 20 ° C to 380 ° C at a rate of 5 ° C / min

(Polyimide resin and liquid crystal polyester)
The Tg of the polyimide resin and the liquid crystal polyester obtained in the production example was determined by the following measurements. Using DMA Q800 manufactured by TA Instrument, measurement under the following samples and conditions was performed to obtain a tan δ curve, which is the ratio of the loss modulus to the storage modulus, and then the peak of the tan δ curve peaked. Tg was calculated from.
Sample: Length 5-15 mm, Width 5 mm
Experimental mode: DMA Multi-Freequency-Strine
Detailed experimental mode conditions:
(1) Clamp: Tension: Film
(2) Implement: 5 μm
(3) Frequency: 10Hz (no fluctuation in all temperature sections)
(4) Preload Force: 0.01N
(5) Force Track: 125N
Temperature conditions: (1) Temperature rise range: Room temperature to 400 ° C., (2) Temperature rise rate: 5 ° C./min Main collected data: (1) Storage modulus (E'), (2) Loss elastic modulus (Loss modulus, E "), (3) tanδ (E" / E')

<Mw and Mn of cycloolefin copolymer>
The polystyrene-equivalent Mw and Mn of the cycloolefin copolymer obtained in the production example were measured using GPC. The GPC measurement was performed under the following conditions, and the peak was specified by defining the baseline on the chromatogram based on the description of ISO16014-1.

(GPC device and software)
Equipment: HLC-8121GPC / HT (manufactured by Tosoh Corporation)
Measurement software: GPC-8020 modelII data collection Version 4.32 (manufactured by Tosoh Corporation)
Analysis software: GPC-8020 modelII data analysis Version 4.32 (manufactured by Tosoh Corporation)

(Measurement condition)
GPC column: TSKgel GMH6-HT with an inner diameter of 7.8 mm and a length of 300 mm (manufactured by Tosoh Corporation) connected in three Mobile phases: Orthodichlorobenzene (manufactured by Fujifilm Wako Pure Chemical Industries, Ltd., special grade) 2,6- Di-tert-butyl-4-methylphenol (hereinafter, may be referred to as BHT) was added and used at a concentration of 0.1 w / V, that is, 0.1 g / 100 mL.
Flow rate: 1 mL / min Column oven temperature: 140 ° C
Autosampler temperature: 140 ° C
System oven temperature: 40 ° C
Detection: Differential Refractometer Detector (RID)
RID cell temperature: 140 ° C
Sample solution injection amount: 300 μL
Standard material for GPC column calibration: Standard polystyrene manufactured by Tosoh Corporation is weighed in the combination shown in Table 1 below, 5 mL of ortodichlorobenzene having the same composition as the mobile phase is added to each combination, and the mixture is dissolved at room temperature for 2 hours to prepare. did. The column was calibrated using the obtained GPC column calibration standard material, and then the sample was measured as shown below.

(Sample solution preparation conditions)
Solvent: BHT was added to orthodichlorobenzene (manufactured by Fujifilm Wako Pure Chemical Industries, Ltd., special grade) at a concentration of 0.1 w / V, that is, 0.1 g / 100 mL.
Sample solution concentration: 1 mg / mL
Automatic shaker for melting: DF-8020 (manufactured by Tosoh Corporation)
Dissolution conditions: A 5 mg sample is enclosed in a 1,000 mesh SUS wire mesh bag, the wire mesh bag containing the sample is placed in a test tube, and 5 mL of orthodichlorobenzene having the same composition as the mobile phase is added to the test tube. The lid was covered with aluminum foil, the test tube was set in DF-8020, and the mixture was stirred at 140 ° C. for 120 minutes at a stirring rate of 60 reciprocating / min. GPC measurement was performed using the stirred solution as a sample.

<Mw of polyimide resin>
The polystyrene-equivalent Mw of the polyimide resin obtained in the production example was measured using GPC. GPC measurement was performed under the following conditions.
GPC measurement (1) Pretreatment method Add DMF eluent (10 mmol / L lithium bromide-added DMF solution) to the sample to a concentration of 2 mg / mL, heat with stirring at 80 ° C. for 30 minutes, cool, and then cool. The solution filtered by a 0.45 μm membrane filter was used as a measurement solution.
(2) Measurement condition column: TSKgel SuperAWM-H x 2 + SuperAW2500 x 1 (three lines with an inner diameter of 6.0 mm and a length of 150 mm are connected)
Eluent: DMF (10 mmol / L lithium bromide added)
Flow rate: 1.0 mL / min Detector: RI detector Column temperature: 40 ° C
Injection volume: 100 μL
Molecular weight standard: Standard polystyrene

<Liquid crystal polyester Mw>
The Mw of the liquid crystal polyester was measured by GPC under the following conditions.
(1) Pretreatment method About 2 mL of pentafluorophenol was added to about 4.86 mg of the sample, and the mixture was heated and stirred for 2 hours, and then cooled to 40 to 50 ° C. with stirring as it was. Approximately 4.24 mL of chloroform was added with stirring and filtered through a 0.45 μm membrane filter as the measurement solution.
(2) GPC equipment HLC8220GPC manufactured by Tosoh Corporation
(3) Measurement conditions Column: TSKgel SuperHM-H × 2
(Two pieces with an inner diameter of 6.0 mm and a length of 150 mm are connected)
Eluent: Pentafluorophenol (PFP) / chloroform (mass ratio 35/65)
Flow rate: 0.4 mL / min Detector: Differential refractometer (RI) detector Column temperature: 40 ° C
Injection volume: 20 μL
Molecular weight standard: Standard polystyrene

<Evaluation of solubility>
The evaluation of whether or not the cycloolefin copolymer, the polyimide resin, the polyamic acid and the liquid crystal polyester were dissolved in the solvents used in Examples and Comparative Examples was performed as follows.
First, 9.9 g of the solvent is weighed in a 30 mL glass screw tube, and a magnetic stirrer is further added and stirred. 0.1 g of the polymer or resin is added thereto, and the mixture is stirred at 24 ° C. for 24 hours. After stirring for 24 hours, if the solid could not be visually confirmed and the solution was transparent, it was evaluated as "dissolved". On the other hand, if the solid can be visually confirmed or the solution is opaque, it is evaluated as "not soluble".

<Solvent content in particulate cycloolefin copolymer dispersion>
The solvent content in the particulate cycloolefin copolymer dispersions obtained in Examples and Comparative Examples was measured by gas chromatography. Specifically, the measurement was carried out under the following conditions, and the solvent content in the particulate cycloolefin copolymer dispersion was calculated from one inspection amount.
Equipment: Agilent 7890B gas chromatograph (manufactured by Agilent Technologies)
Column: DB-5 (manufactured by Agilent Technologies, Inc.)
Carrier gas: Helium inlet temperature: 200 ° C
Detector temperature: 250 ° C
Internal standard: Benzyl alcohol Solvent: Chloroform

<Thickness of composite film>
For the thickness of the composite film obtained in Examples and Comparative Examples, a Digimatic Indicator (ID-C112XBS, manufactured by Mitutoyo Co., Ltd.) was used to measure the thickness of any 5 or more points of the film, and the thickness thereof was measured. The average value was taken as the thickness.

<Particulate particle size of cycloolefin copolymer in dispersion and composition>
The median diameter of the particulate cycloolefin copolymer in the particulate cycloolefin copolymer dispersion obtained in the examples was determined by the scattering type particle size distribution measurement using laser diffraction.
Specifically, the particulate cycloolefin copolymer dispersion obtained in the example is placed in a glass cell having a capacity of 3.5 mL, and the same solvent (GBL, DMAc or NMP) as the solvent contained in the dispersion is further added. The mixture was added and diluted 1000-fold to obtain a dispersion sample containing the particulate cycloolefin copolymer. The obtained dispersion sample was measured using a laser diffraction / scattering type particle size distribution measuring device (manufactured by Malvern Panasonic, model: NanоZS, refractive index: 1.70-0.20i), and the particulate cycloolefin copolymer was measured. The median diameter was calculated. In Examples 1, 6, 7 and 13, a polyimide resin, a liquid crystal polyester solution, or a polyamic acid solution was added to the particulate cycloolefin copolymer dispersion in an amount within a range that does not affect the particle size. The particle size of the particulate cycloolefin copolymer in the dispersion measured above was defined as the particle size of the particulate cycloolefin copolymer in the composition.

<Average primary particle size of cycloolefin copolymer in composite film>
For the composite film obtained in Examples 1, 6, 7, and 13, a cross-sectional observation of the composite film was performed using a scanning transmission electron microscope (STEM), and particles of 50 or more particles were observed from the observed cross-sectional image. The diameters were measured and the average value thereof was taken as the average primary particle diameter.
(STEM observation measurement conditions)
Device name: HeLiоsG4UX (flake making device) manufactured by Japan FEI Co., Ltd.
Hitachi High-Tech Co., Ltd. S-5500 (for STEM observation)
Acceleration voltage: 30kv
Magnification: 20000 times

<CTE>
(CTE of composite film)
The CTEs of the composite film, the polyimide film and the liquid crystal polyester film obtained in Examples, Comparative Examples and Reference Examples were measured by TMA, respectively. Specifically, the measurement was performed under the following conditions, and the CTE at 50 ° C to 100 ° C was calculated.

[Composite film and polyimide film obtained in Examples 1 to 7, Example 13, Comparative Example 1 and Reference Examples 1 and 2]
Equipment: TMA / SS7100 manufactured by Hitachi High-Tech Science Corporation
Indenter (probe) diameter: 3.5 mm
Load: 50.0mN
Temperature program: Temperature rise from 20 ° C to 130 ° C at a rate of 5 ° C / min Specimen: 40 mm × 10 mm × 50 μm (varies depending on film thickness) rectangular parallelepiped

[Composite film and liquid crystal polyester film obtained in Examples 8 to 12 and Reference Example 3]
Equipment: TMA8310 manufactured by Rigaku Co., Ltd.
Indenter (probe) diameter: 3.5 mm
Load: 25.0mN
Temperature program: Temperature rise from 20 ° C to 250 ° C at a rate of 5 ° C / min Specimen: 24 mm x 5 mm x 30 μm (varies depending on film thickness) rectangular parallelepiped

(CTE of cycloolefin copolymer)
The CTE of the cycloolefin copolymer was measured using TMA under the following conditions, and the CTE at 50 ° C to 100 ° C was calculated.
Equipment: TMA / SS6200 manufactured by Hitachi High-Tech Science Corporation
Indenter (probe) diameter: 3.5 mm Load: 38.5 mN Temperature program: Temperature rise from 20 ° C to 130 ° C at a rate of 5 ° C / min Specimen: 10 mm x 10 mm x 1 mm rectangular parallelepiped

<One-time bending resistance of composite film>
The one-time bending resistance of the composite films obtained in Examples and Comparative Examples was measured by the following method.
The center of the film with a length of 40 mm and a width of 10 mm cut out by a dumbbell cutter, specifically, at a position 20 mm from the end of the film in the length direction of the film to the center, and 2 mmΦ so as to be parallel to the length direction of the film. The iron core (sometimes called mandrel) was installed, bent so that the center of the film was in contact with the iron core, fixed so that the surfaces of the bent film were parallel, and allowed to stand for 10 seconds. At this time, the bent film was fixed to both sides of a glass substrate having a thickness of 2 mm so as to maintain parallelism during the test.
After the above test, the film was allowed to stand for 10 minutes, half of the film was fixed to the floor surface, and the length between the end of the film opposite to the end fixed to the floor surface and the floor surface, that is, the deformation after one bending. The height was measured and evaluated as the one-time bending resistance of the film.

<Repeat bending resistance of composite film>
Regarding the repeated bending resistance of the composite films obtained in Examples and Comparative Examples, the same method was used except that the film was fixed in the same manner as the one-time bending resistance and the bending for fixing for 10 seconds was repeated 10 times. The length between the edge of the film and the floor surface, that is, the deformation height after 10 times of repeated bending was measured, and this was evaluated as the resistance to repeated bending of the film.

<Measurement of permittivity and dielectric loss tangent of composite film>
The permittivity and dielectric loss tangent of the liquid crystal polyester-cycloolefin copolymer composite film obtained in Examples 8 to 12 and the liquid crystal polyester film obtained in Reference Example 3 are CFT-500 type manufactured by Shimadzu Corporation. ) Was melted at 350 ° C., and then cooled and solidified to prepare a tablet having a diameter of 1 cm and a thickness of 0.5 cm, and the relative permittivity and dielectric loss tangent at 1 GHz were measured under the following conditions.
-Measurement method: Capacitance method (Device: Impedance analyzer (Agilent model: E4991A))
-Electrode model: 16453A
-Measurement environment: 23 ° C, 50% RH
・ Applied voltage: 1V

<Measurement of flow start temperature of liquid crystal polyester>
The flow start temperature of the liquid crystal polyester obtained in Production Example 11 was measured as follows. Using a flow tester (manufactured by Shimadzu Corporation, CFT-500 type), about 2 g of liquid crystal polyester is filled into a cylinder equipped with a die having a nozzle with an inner diameter of 1 mm and a length of 10 mm, and 9.8 MPa (100 kg / 100 kg /). Under the load of cm ² ), the liquid crystal polyester was melted while raising the temperature at a rate of 4 ° C./min, extruded from the nozzle, and the temperature showing the viscosity of 4800 Pa · s (48,000 P) was measured, and the flow was started. The temperature was set.

<Viscosity measurement of liquid crystal polyester solution>
The viscosity of the liquid crystal polyester solution obtained in Production Example 11 was measured using a B-type viscometer (TV-22 manufactured by Toki Sangyo Co., Ltd.) under the following measurement conditions.
Measurement conditions: temperature 23 ° C, rotor speed 20 rpm

<Details of reagents>
Toluene manufactured by Sumitomo Chemical Industries, Ltd., styrene manufactured by Wako Pure Chemical Industries, Ltd., 2-norbornene manufactured by Arakawa Chemical Industries, Ltd. (hereinafter referred to as NB), and Toso Finechem (hereinafter referred to as NB) are used for the synthesis of cycloolefin copolymers. Triisobutylaluminum (hereinafter referred to as TIBA) manufactured by AGC Inc. and N, N-dimethylanilinium tetrakis (pentafluorophenyl) borate (hereinafter referred to as AB) manufactured by AGC Inc. were used.

Toluene was dehydrated using Molecular Sieves 13X (manufactured by Union Showa Co., Ltd.) and activated alumina (manufactured by Sumitomo Chemical Co., Ltd., NKHD-24), and then nitrogen gas was blown into the toluene to remove dissolved oxygen. used.

After dissolving NB in toluene, it is dehydrated using Molecular Sieves 13X (manufactured by Union Showa Co., Ltd.) and activated alumina (manufactured by Sumitomo Chemical Co., Ltd., NKHD-24), and then nitrogen gas is blown into the NB. A solution from which dissolved oxygen was removed was used (hereinafter referred to as NB solution). The NB concentration in the NB solution was measured by using gas chromatography.

Isopropyridene (cyclopentadienyl) (3-tert-butyl-5-methyl-2-phenoxy) Titanium dichloride (hereinafter referred to as a complex) is synthesized according to the method described in JP-A-9-183809. did.

[Manufacturing of cycloolefin copolymer solution]
<Manufacturing example 1>
To the autoclave whose inside was dried under reduced pressure, 1,501 mL (NB concentration: 3.00 mol / L) of the NB solution was added, and the temperature was raised to 60 ° C. After pressurizing with ethylene partial pressure: 100 kPa while stirring the inside of the system, 4.0 mL (concentration: 1.0 mol / L) of hexane solution of TIBA, 0.16 g of AB, and 10.0 mL of toluene solution of the complex ( Concentration: 10 mmol / L) was added to initiate polymerization of ethylene and NB. During the polymerization, the temperature in the system was kept at 60 ° C., and ethylene was continuously supplied to keep the pressure in the system at the starting value. After 3 hours had passed from the start of the polymerization, 5.0 mL of water was added to stop the polymerization, and the solution in the autoclave was withdrawn. To the extracted solution, 1,500 g of toluene and 100 g of magnesium sulfate were added and stirred, and then 100 mL of water was added and stirred, and the solid was removed by filtration. The obtained liquid was added dropwise to acetone, and the precipitated powder was isolated by filtration. The isolated powder was further washed with acetone and dried under reduced pressure at 120 ° C. for 2 hours to obtain 210.0 g of a cycloolefin copolymer having a median diameter of 335 μm. In the obtained cycloolefin copolymer, the NB content was 84.1 mL, the Tg was 293 ° C, the Mw was 521,000, and the Mw / Mn was 1.87. Further, the δD of the cycloolefin copolymer is 17.7 MPa ^0.5 , the δP is 2.1 MPa ^0.5 , the δH is 3.9 MPa ^0.5 , and the meso-type two-chain / racemo-type two-chain is. It was 0.19, had a refractive index of 1.538, and had a CTE of 49.4 ppm / K.
Table 2 shows the synthesis conditions of Production Example 1 and Production Examples 2 to 4 described later. This cycloolefin copolymer was dissolved in a toluene solution at a concentration of 2% by mass to obtain a cycloolefin copolymer solution 1.

<Manufacturing example 2>
A cycloolefin copolymer and a cycloolefin copolymer solution were obtained in the same manner as in Production Example 1 except that the synthesis conditions were changed to the synthesis conditions shown in Production Example 2 in Table 2. In the obtained cycloolefin copolymer, the NB content was 79.2 mL and the Tg was 276 ° C. The meso-type two-chain / racemo-type two-chain of the cycloolefin copolymer was 0.11, the refractive index was 1.527, and the CTE was 48.3 ppm / K.

<Manufacturing example 3>
Using a solution obtained by adding 852 mL of toluene to an NB solution having an NB concentration of 7.36 mol / L, the same procedure as in Production Example 1 was applied except that the synthesis conditions were changed to the synthesis conditions described in Production Example 3 in Table 2. Cycloolefin copolymer and cycloolefin copolymer solution were obtained. The NB content of the obtained cycloolefin copolymer was 95.1 mL, and the Tg was over 330 ° C.

<Manufacturing example 4>
Using a solution obtained by adding 852 mL of toluene to an NB solution having an NB concentration of 7.36 mol / L, the same procedure as in Production Example 1 was applied except that the synthesis conditions were changed to the synthesis conditions described in Production Example 4 in Table 2. Cycloolefin copolymer and cycloolefin copolymer solution were obtained. The NB content of the obtained cycloolefin copolymer was 70.7 mol%, and the Tg was 222 ° C. The meso-type two-chain / racemo-type two-chain of the cycloolefin copolymer was 0.11, and the refractive index was 1.533.

<Manufacturing example 5>
TOPAS6015 (manufactured by Polyplastics Co., Ltd.) was used as the cycloolefin copolymer. The CTE of TOPAS6015 was 60 ppm / K. Further, a cycloolefin copolymer solution was obtained in the same manner as in Production Example 1 except that TOPAS6015 was used as the cycloolefin copolymer.

[Manufacturing of Cycloolefin Copolymer Crushed Powder 1]
<Manufacturing example 6>
611.7 L of NB solution (NB concentration: 3.00 mol / L) was added to the reaction kettle whose inside was dried under reduced pressure, and the temperature was raised to 60 ° C. After pressurizing with ethylene partial pressure: 100 kPa while stirring the inside of the system, 0.51 L (concentration: 0.6 mol / L) of hexane solution of TIBA and 40.8 L (concentration: 1.0 mmol / L) of toluene solution of AB. L) and 2.0 L (concentration: 10 mmol / L) of a toluene solution of the complex were added to initiate polymerization of ethylene and NB. During the polymerization, the temperature in the system was kept at 60 ° C., and ethylene was continuously supplied to keep the pressure in the system at the starting value. After 170 minutes had passed from the start of the polymerization and the ethylene consumption reached 3.0 kg, 1.0 L of water was added to terminate the polymerization. 612 L (concentration: 0.1 mol / L) of an aqueous NaOH solution was added to the reaction vessel, and the mixture was stirred for 30 minutes. Stirring was stopped, the aqueous solution was withdrawn, 612 L of water was added, and the mixture was stirred for 30 minutes. Further, 612 L of water was added and stirred for 30 minutes, then a solution of 942 L of toluene and 49.5 L of acetone was added to the reaction vessel, then 314 L of acetone was added, and the precipitated powder was isolated by filtration. The isolated powder was further washed with acetone and dried under reduced pressure at 120 ° C. for 2 hours to give 60.0 kg of cycloolefin copolymer. In the obtained cycloolefin copolymer, the NB content was 92.3 mol%, Tg was 308 ° C., Mw was 852,000, and Mw / Mn was 1.81. Further, the δD of the cycloolefin copolymer was 17.7 MPa ^0.5 , the δP was 2.1 MPa ^0.5 , the δH was 3.9 MPa ^0.5 , and the CTE was 44.5 ppm / K. .. The synthesis conditions are shown in Table 3.
This cycloolefin copolymer was pulverized with a counter jet mill manufactured by Hosokawa Micron Co., Ltd. and classified by a filter to obtain a cycloolefin copolymer crushed powder having a median diameter of 2.6 μm.

[Manufacturing of Cycloolefin Copolymer Crushed Powder 2]
<Manufacturing example 7>
The cycloolefin copolymer obtained in Production Example 6 was pulverized with a counter jet mill manufactured by Hosokawa Micron Co., Ltd. and classified by a filter to obtain cycloolefin copolymer crushed powder 2 having a median diameter of 10 μm.

[Manufacturing of cycloolefin copolymer solution]
<Manufacturing example 8>
To the autoclave whose inside was dried under reduced pressure, 1,427 mL of NB solution (NB concentration: 3.00 mol / L) and 55.2 mL of styrene were added, and the temperature was raised to 80 ° C. While stirring the inside of the system, add 3.0 mL (concentration: 1.0 mol / L) of hexane solution of TIBA, 0.32 g of AB, and 15.0 mL (concentration: 10 mmol / L) of toluene solution of the complex, and NB. And styrene polymerization was started. The temperature in the system was kept at 80 ° C. during the polymerization. After 2 hours from the start of the polymerization, 3.0 mL of water was added to stop the polymerization, and the solution in the autoclave was withdrawn. The obtained liquid was added dropwise to acetone in the extracted solution, and the precipitated powder was isolated by filtration. The isolated powder was further washed with acetone and dried under reduced pressure at 150 ° C. for 2 hours to obtain 198.3 g of a cycloolefin copolymer. In the obtained cycloolefin copolymer, the NB content was 96.3 mol%, Mw was 79,000, Mw / Mn was 1.83, and Tg was more than 300 ° C. The δD of the cycloolefin copolymer was 17.7 MPa ^0.5 , the δP was 2.1 MPa ^0.5 , and the δH was 3.9 MPa ^0.5 . Table 3 shows the synthesis conditions of Production Example 2. This cycloolefin copolymer was dissolved in a toluene solution at a concentration of 2% by mass to obtain a cycloolefin copolymer solution.

[Synthesis of polyimide resin]
<Manufacturing example 9>
A reactor equipped with a silica gel tube, a stirrer and a thermometer in a separable flask, and an oil bath were prepared. After making the inside of the flask a nitrogen atmosphere using dry nitrogen, 75.52 g of 6FDA and 519.84 g of DMAc were added. 54.44 g of TFMB was added while stirring this at 400 rpm, and stirring was continued until the contents of the flask became a uniform solution. Subsequently, stirring was continued for another 20 hours while adjusting the temperature inside the container to be in the range of 20 to 30 ° C. using an oil bath, and the reaction was carried out to generate a polyamic acid. After 30 minutes, the stirring speed was changed to 100 rpm. After stirring for 20 hours, the reaction system temperature was returned to room temperature, and 649.8 g of DMAc was added to adjust the polymer concentration to 10% by mass. Further, 32.27 g of pyridine and 41.65 g of acetic anhydride were added, and the mixture was stirred at room temperature for 10 hours for imidization. The polyimide varnish was taken out from the reaction vessel. The obtained polyimide varnish was dropped into methanol for reprecipitation, and the obtained powder was heated and dried to remove the solvent to obtain a polyimide resin as a solid content. The δD of the obtained polyimide resin was 18.1 MPa ^{0.5, the δP was 8.3 MPa 0.5 ,} and the δH was 9.3 MPa ^0.5 . The Mw of the polyimide resin was 334,300, and the Tg was 361 ° C.

[Synthesis of polyamic acid]
<Manufacturing example 10>
A reactor equipped with a silica gel tube, a stirrer and a thermometer in a separable flask, and an oil bath were prepared. 27.83 g of BPDA, 13.76 g of PMDA, and 34.00 g of m-TB were placed in this flask. While stirring this at 400 rpm, 428.35 g of DMAc was added, and stirring was continued until the contents of the flask became a uniform solution. Subsequently, stirring was continued for another 3 hours while adjusting the temperature inside the container to be in the range of 20 to 30 ° C. using an oil bath, and the reaction was carried out to obtain a polyamic acid solution.

[Manufacturing of liquid crystal polyester solution]
<Manufacturing example 11>
Reactor equipped with stirrer, torque meter, nitrogen gas introduction tube, thermometer and reflux condenser, 6-hydroxy-2-naphthoic acid 940.9 g, N-acetyl-4-aminophenol 377.9 g, isophthalic acid After adding 415.3 g and 867.8 g of anhydrous acetic acid and replacing the gas in the reactor with nitrogen gas, the temperature was raised from room temperature to 140 ° C. over 60 minutes with stirring under a nitrogen gas stream at 140 ° C. It was refluxed for 3 hours. Then, while distilling off by-product acetic acid and unreacted acetic anhydride, the temperature was raised from 150 ° C. to 300 ° C. over 5 hours, held at 300 ° C. for 30 minutes, and then the contents were taken out from the reactor and brought to room temperature. Cooled. The obtained solid matter was pulverized with a pulverizer to obtain a powdery liquid crystal polyester (L1). The flow start temperature of the liquid crystal polyester (L1) measured by the method described above was 193.3 ° C.
The liquid crystal polyester (L1) is heated from room temperature to 160 ° C. over 2 hours and 20 minutes under a nitrogen atmosphere, then heated from 160 ° C. to 180 ° C. over 3 hours and 20 minutes, and held at 180 ° C. for 5 hours. As a result, solid-phase polymerization was carried out, the mixture was cooled, and then the mixture was pulverized with a pulverizer to obtain a powdery liquid crystal polyester (L2). The flow start temperature of the liquid crystal polyester (L2) measured by the method described above was 220 ° C.
The temperature of the liquid crystal polyester (L2) is raised from room temperature to 180 ° C. for 1 hour and 25 minutes under a nitrogen atmosphere, then the temperature is raised from 180 ° C. to 255 ° C. for 6 hours and 40 minutes, and the temperature is maintained at 255 ° C. for 5 hours. After solid-phase polymerization, the mixture was cooled to obtain a powdery liquid crystal polyester (L). The flow start temperature of the liquid crystal polyester (L) measured by the method described above was 302 ° C. The δD of the obtained liquid crystal polyester (L) was 20.9 MPa ^{0.5, the δP was 8.3 MPa 0.5 ,} and the δH was 4.7 MPa ^0.5 . The liquid crystal polyester had a Mw of 180,000 and a Tg of 190 ° C.
8 parts by mass of liquid crystal polyester (L) was added to 92 parts by mass of NMP, and the mixture was stirred at 140 ° C. for 4 hours under a nitrogen atmosphere to prepare a liquid crystal polyester solution. The viscosity of the liquid crystal polyester solution measured by the method described below was 955 mPa · s.

[Example 1]
100.0 g of the cycloolefin copolymer solution obtained in Production Example 1 and 98.0 g of GBL were mixed and distilled off at 50 hPa at 80 ° C. for 2 hours under reduced pressure to distill off toluene to obtain a particulate cycloolefin copolymer dispersion. rice field. The toluene content of the obtained dispersion was 0.6 parts by mass with respect to 100 parts by mass of GBL.
To 30.0 g of the obtained dispersion (2.0% by mass of the particulate cycloolefin copolymer), 1.2 g of the polyimide resin obtained above was added to obtain a composition as a polyimide-cycloolefin copolymer mixed solution. rice field. The median diameter of the particulate cycloolefin copolymer in the particulate cycloolefin copolymer dispersion and the composition measured by the above method was 0.14 μm, respectively.
The obtained composition was salivated on a glass substrate, and a coating film was formed at a linear velocity of 0.4 m / min. The coating film is heated at 70 ° C. for 60 minutes, the film is peeled off from the glass substrate, the film is fixed with a metal frame, and the film is further heated at 200 ° C. for 1 hour to obtain a polyimide-cycloolefin copolymer composite film having a thickness of 50 μm. Got In the obtained film, the content of the particulate cycloolefin copolymer was 33.3% by mass with respect to the total mass of the polyimide resin and the particulate cycloolefin copolymer. The average primary particle size of the particulate cycloolefin copolymer in the obtained composite film was 0.16 μm. The distance between the HSP values of the cycloolefin copolymer and the polyimide resin used in Example 1 is 8.3, the distance between the HSP values of the cycloolefin copolymer and toluene is 2.1, and the distance between the cycloolefin copolymer and GBP is 2.1. The distance between the HSP values was 14.9, the distance between the HSP values of the polyimide resin and toluene was 10.0, and the distance between the HSP values of the polyimide resin and GBL was 8.5.
By the above solubility evaluation method, the cycloolefin copolymer used in Example 1 was dissolved in toluene and not in GBL. Further, the polyimide resin was dissolved in GBL and not in toluene.

[Example 2]
The composition as a polyimide-cycloolefin copolymer mixed solution and the polyimide-cycloolefin copolymer composite film having a thickness of 50 μm were prepared in the same manner as in Example 1 except that the cycloolefin copolymer solution obtained in Production Example 2 was used. Obtained. In the obtained film, the content of the particulate cycloolefin copolymer was 33.3% by mass with respect to the total mass of the polyimide resin and the particulate cycloolefin copolymer. The distance between the HSP values of the cycloolefin copolymer and the polyimide resin used in Example 2 is 8.3, the distance between the HSP values of the cycloolefin copolymer and toluene is 2.1, and the distance between the cycloolefin copolymer and GBP is 2.1. The distance between the HSP values was 14.9, the distance between the HSP values of the polyimide resin and toluene was 10.0, and the distance between the HSP values of the polyimide resin and GBL was 8.5.
By the above solubility evaluation method, the cycloolefin copolymer used in Example 2 was dissolved in toluene and not in GBL.

[Example 3]
A composition as a polyimide-cycloolefin copolymer mixed solution and a polyimide-cycloolefin copolymer composite film having a thickness of 50 μm were prepared in the same manner as in Example 1 except that the cycloolefin copolymer solution obtained in Production Example 3 was used. Obtained. In the obtained film, the content of the particulate cycloolefin copolymer was 33.3% by mass with respect to the total mass of the polyimide resin and the particulate cycloolefin copolymer. The distance between the HSP values of the cycloolefin copolymer and the polyimide resin used in Example 3 is 8.3, the distance between the HSP values of the cycloolefin copolymer and toluene is 2.1, and the distance between the cycloolefin copolymer and GBP is 2.1. The distance between the HSP values was 14.9, the distance between the HSP values of the polyimide resin and toluene was 10.0, and the distance between the HSP values of the polyimide resin and GBL was 8.5.
By the above solubility evaluation method, the cycloolefin copolymer used in Example 3 was dissolved in toluene and not in GBL.

[Example 4]
A composition as a polyimide-cycloolefin copolymer mixed solution and a polyimide-cycloolefin copolymer composite film having a thickness of 50 μm were prepared in the same manner as in Example 1 except that the cycloolefin copolymer solution obtained in Production Example 4 was used. Obtained. In the obtained film, the content of the particulate cycloolefin copolymer was 33.3% by mass with respect to the total mass of the polyimide resin and the particulate cycloolefin copolymer. The distance between the HSP values of the cycloolefin copolymer and the polyimide resin used in Example 4 is 8.3, the distance between the HSP values of the cycloolefin copolymer and toluene is 2.1, and the distance between the cycloolefin copolymer and GBP is 2.1. The distance between the HSP values was 14.9, the distance between the HSP values of the polyimide resin and toluene was 10.0, and the distance between the HSP values of the polyimide resin and GBL was 8.5.
By the above solubility evaluation method, the cycloolefin copolymer used in Example 4 was dissolved in toluene and not in GBL.

[Example 5]
100.0 g of the cycloolefin copolymer solution obtained in Production Example 2 and 98.0 g of DMAc were mixed and distilled off at 50 hPa at 80 ° C. for 2 hours under reduced pressure to distill off toluene to obtain a particulate cycloolefin copolymer dispersion. Obtained. The toluene content of the obtained dispersion was 0.6 parts by mass with respect to 100 parts by mass of DMAc. 6.6 g (15% by mass of polyamic acid) of the polyamic acid solution was added to 30.0 g (2.0% by mass of the particulate cycloolefin copolymer) of the obtained dispersion, and the composition as a polyamic acid-cycloolefin copolymer mixed solution was added. I got something.
The obtained composition was subjected to salivation molding on a glass substrate to prepare a coating film at a linear speed of 0.4 m / min. The coating film is heated at 70 ° C. for 60 minutes, the polyamic acid-cycloolefin copolymer composite film is peeled off from the glass substrate, the film is fixed with a metal frame, and the polyamic acid-cycloolefin is gradually increased to 360 ° C. in 30 minutes. By heating the copolymer composite film, the polyamic acid was imidized to obtain a polyimide-cycloolefin copolymer composite film having a thickness of 25 μm. In the obtained film, the content of the particulate cycloolefin copolymer was 37.7% by mass with respect to the total mass of the polyimide resin and the particulate cycloolefin copolymer.
The distance between the HSP values of the cycloolefin copolymer used in Example 5 and the obtained polyimide resin is 6.0 or more, and the distance between the HSP values of the cycloolefin copolymer and toluene is 2.1. The distance between the HSP values of the cycloolefin copolymer and DMAc was 11.5.
According to the above solubility evaluation method, the polyamic acid used in Example 5 was dissolved in DMAc and not in toluene.

[Comparative Example 1]
A polyimide-cycloolefin copolymer composite film having a thickness of 50 μm was obtained in the same manner as in Example 1 except that the cycloolefin copolymer solution obtained in Production Example 5 was used. In the obtained film, the content of the particulate cycloolefin copolymer was 33.3% by mass with respect to the total mass of the polyimide resin and the particulate cycloolefin copolymer.

[Example 6]
The cycloolefin copolymer crushed powder 17.31 g and DMAc 52.03 g obtained in Production Example 6 were mixed and stirred to obtain a dispersion liquid. 100 g of a polyamic acid solution (15% by mass of a polyamic acid) was added to the obtained dispersion to obtain a composition as a polyamic acid-cycloolefin copolymer mixed solution. The median diameter of the particulate cycloolefin copolymer in the dispersion and the composition measured by the above method was 2.6 μm, respectively.
The obtained composition was subjected to salivation molding on a glass substrate to prepare a coating film at a linear speed of 0.4 m / min. The coating film was heated at 50 ° C. for 80 minutes, the polyamic acid-cycloolefin copolymer composite film was peeled off from the glass substrate, the film was fixed with a metal frame, and the film was further heated at 360 ° C. for 15 minutes under a nitrogen atmosphere. The polyamic acid was imidized to obtain a polyimide-cycloolefin copolymer composite film having a thickness of 50 μm. In the obtained film, the content of the particulate cycloolefin copolymer was 32.8% by mass with respect to the total mass of the polyimide resin and the particulate cycloolefin copolymer. The average primary particle size of the particulate cycloolefin copolymer in the obtained composite film was 2.7 μm.
The distance between the HSP values of the cycloolefin copolymer and the polyamic acid used in Example 6 was 6.0 or more, and the distance between the HSP values of the cycloolefin copolymer and the DMAc was 11.5. Further, the distance between the HSP values of the cycloolefin copolymer used in Example 6 and the polyimide resin obtained by imidizing the polyamic acid was 6.0 or more.
By the above solubility evaluation method, the cycloolefin copolymer used in Example 6 was dissolved in toluene and not in DMAc. Further, the polyamic acid was dissolved in DMAc and not in toluene.

[Example 7]
100.0 g of the cycloolefin copolymer solution obtained in Production Example 1 and 98.0 g of NMP were mixed and distilled off at 50 hPa at 80 ° C. for 2 hours under reduced pressure to distill off toluene to obtain a particulate cycloolefin copolymer dispersion. Obtained. The toluene content of the obtained dispersion was 0.6 parts by mass with respect to 100 parts by mass of NMP.
To 30.0 g of the obtained particulate cycloolefin copolymer dispersion (2.0% by mass of the particulate cycloolefin copolymer), 17.5 g of the liquid crystal polyester solution obtained in Production Example 11 was added, and the liquid crystal polyester-cycloolefin was added. The composition was obtained as a mixed solution of copolymers. The median diameter of the particulate cycloolefin copolymer in the particulate cycloolefin copolymer dispersion and the composition measured by the above method was 0.14 μm, respectively.
The obtained composition was subjected to salivation molding on a copper foil to prepare a coating film at a linear speed of 0.4 m / min. The coating film was heated at 60 ° C. for 4 hours to obtain a laminate having a copper foil and a liquid crystal polyester precursor-cycloolefin copolymer composite film, and then the laminate was fixed with a metal frame and further under a nitrogen atmosphere, 310. By heating the laminate at ° C. for 4 hours, a laminate having a copper foil and a liquid crystal polyester-cycloolefin copolymer composite film was obtained. The obtained laminate was immersed in a ferric chloride solution for 10 minutes to remove the copper foil by etching to obtain a liquid crystal polyester-cycloolefin copolymer composite film having a thickness of 30 μm. In the obtained film, the content of the particulate cycloolefin copolymer was 30.0% by mass with respect to the total mass of the liquid crystal polyester and the particulate cycloolefin copolymer. The average primary particle size of the particulate cycloolefin copolymer in the composite film was 0.17 μm.
The distance between the HSP values of the cycloolefin copolymer and the liquid crystal polyester used in Example 7 is 8.9, the distance between the HSP values of the cycloolefin copolymer and toluene is 2.1, and the distance between the cycloolefin copolymer and NMP is 2.1. The distance between the HSP values was 10.7, the distance between the HSP values of the liquid crystal polyester and toluene was 9.4, and the distance between the HSP values of the liquid crystal polyester and NMP was 7.5.
According to the above solubility evaluation method, the cycloolefin copolymer used in Example 7 was dissolved in toluene and not in NMP. The liquid crystal polyester used in Example 7 was dissolved in NMP and not in toluene.

[Example 8]
The liquid crystal polyester solution obtained in Production Example 11 and the liquid crystal polyester solution obtained in Production Example 7 so that the content of the particulate cycloolefin copolymer is 10% by mass with respect to the total mass of the liquid crystal polyester and the particulate cycloolefin copolymer. The resulting cycloolefin copolymer crushed powder 2 was mixed, and a composition as a liquid crystal polyester-cycloolefin copolymer mixed solution was obtained using a stirring defoaming device (AR-500, manufactured by Shinky Co., Ltd.).
The obtained composition was used with a film applicator with a micrometer (manufactured by Tester Sangyo Co., Ltd.) so that the thickness of the cast film was 260 μm on the roughened surface of (JXEFL-V2 12 μm manufactured by JX Nippon Mining & Metals Co., Ltd.). After casting using an automatic coating device (manufactured by Tester Sangyo Co., Ltd., model: PI-1210), the film is dried at 40 ° C. and normal pressure (1 atm) for 4 hours to remove the cast film. The solvent was partially removed to obtain a film with a copper foil. The copper foil-attached film was further heat-treated in a hot air oven under a nitrogen atmosphere from room temperature to 310 ° C. for 4 hours and kept at that temperature for 2 hours to obtain a heat-treated copper foil-attached film. rice field. The copper foil-attached film was etched and removed using a ferric chloride solution to obtain a liquid crystal polyester-cycloolefin copolymer composite film having a thickness of 27 μm. The obtained composite film had a dielectric constant of 2.90 and a dielectric loss tangent of 0.0032.
The distance between the HSP values of the cycloolefin copolymer and the liquid crystal polyester used in Example 8 is 8.9, the distance between the HSP values of the cycloolefin copolymer and toluene is 2.1, and the distance between the cycloolefin copolymer and NMP is 2.1. The distance between the HSP values was 10.7, the distance between the HSP values of the liquid crystal polyester and toluene was 9.4, and the distance between the HSP values of the liquid crystal polyester and NMP was 7.5.

[Example 9]
The liquid crystal polyester solution obtained in Production Example 11 and the liquid crystal polyester solution obtained in Production Example 7 so that the content of the particulate cycloolefin copolymer is 20% by mass with respect to the total mass of the liquid crystal polyester and the particulate cycloolefin copolymer. The obtained cycloolefin copolymer crushed powder 2 was mixed to obtain a liquid crystal polyester-cycloolefin copolymer composite film having a thickness of 28 μm in the same manner as in Example 8 except that the thickness of the cast film was 240 μm. The obtained composite film had a dielectric constant of 2.81 and a dielectric loss tangent of 0.0028.

[Example 10]
The liquid crystal polyester solution obtained in Production Example 11 and the liquid crystal polyester solution obtained in Production Example 7 so that the content of the particulate cycloolefin copolymer is 30% by mass with respect to the total mass of the liquid crystal polyester and the particulate cycloolefin copolymer. The obtained cycloolefin copolymer crushed powder 2 was mixed to obtain a liquid crystal polyester-cycloolefin copolymer composite film having a thickness of 30 μm in the same manner as in Example 8 except that the thickness of the cast film was 220 μm. The obtained composite film had a dielectric constant of 2.67 and a dielectric loss tangent of 0.0024.

[Example 11]
The liquid crystal polyester solution obtained in Production Example 11 and the liquid crystal polyester solution obtained in Production Example 7 so that the content of the particulate cycloolefin copolymer is 50% by mass with respect to the total mass of the liquid crystal polyester and the particulate cycloolefin copolymer. The obtained cycloolefin copolymer crushed powder 2 was mixed to obtain a liquid crystal polyester-cycloolefin copolymer composite film having a thickness of 29 μm in the same manner as in Example 8 except that the thickness of the cast film was 280 μm. The obtained composite film had a dielectric constant of 2.54 and a dielectric loss tangent of 0.0017.

[Example 12]
The liquid crystal polyester solution obtained in Production Example 11 and the liquid crystal polyester solution obtained in Production Example 7 so that the content of the particulate cycloolefin copolymer is 60% by mass with respect to the total mass of the liquid crystal polyester and the particulate cycloolefin copolymer. The obtained cycloolefin copolymer crushed powder 2 was mixed to obtain a liquid crystal polyester-cycloolefin copolymer composite film having a thickness of 33 μm in the same manner as in Example 8 except that the thickness of the cast film was 280 μm. The obtained composite film had a dielectric constant of 2.45 and a dielectric loss tangent of 0.0015.

[Example 13]
100.0 g of the cycloolefin copolymer solution obtained in Production Example 8 and 98.0 g of DMAc were mixed, distilled off under reduced pressure at 50 hPa and 80 ° C. for 2 hours, and toluene was distilled off to distill off toluene. Got The toluene content of the obtained dispersion was 0.6 parts by mass with respect to 100 parts by mass of DMAc.
To 30.0 g of the obtained particulate cycloolefin copolymer dispersion (2.0% by mass of the particulate cycloolefin copolymer), 8.0 g of the polyamic acid solution (15% by mass) obtained in Production Example 10 was added. The composition was obtained as a mixed solution of polyamic acid-cycloolefin copolymer. The median diameter of the particulate cycloolefin copolymer in the particulate cycloolefin copolymer dispersion and the composition measured by the above method was 0.13 μm, respectively.
The obtained composition was subjected to salivation molding on a glass substrate to prepare a coating film at a linear speed of 0.4 m / min. The coating film is heated at 70 ° C. for 60 minutes, the polyamic acid-cycloolefin copolymer composite film is peeled off from the glass substrate, the film is fixed with a metal frame, and the polyamic acid is gradually increased to 360 ° C. in 30 minutes under a nitrogen atmosphere. By heating the acid-cycloolefin copolymer composite film, the polyamic acid was imidized to obtain a polyimide-cycloolefin copolymer composite film having a thickness of 30 μm. In the obtained film, the content of the particulate cycloolefin copolymer was 33.3% by mass with respect to the total mass of the polyimide resin and the particulate cycloolefin copolymer. The average primary particle size of the particulate cycloolefin copolymer in the composite film was 0.15 μm.
The distance between the HSP values of the cycloolefin copolymer and the polyamic acid used in Example 13 is 6.0 or more, and the distance between the HSP values of the cycloolefin copolymer and toluene is 2.1. The distance between the HSP values with DMAc was 11.5. Further, the distance between the HSP values of the cycloolefin copolymer used in Example 13 and the polyimide resin obtained by imidizing the polyamic acid was 6.0 or more.
By the above solubility evaluation method, the cycloolefin copolymer used in Example 13 was dissolved in toluene and not in DMAc. The polyamic acid used in Example 13 was soluble in DMAc and not in toluene.

The CTE, single bending resistance and repeated bending resistance of the polyimide-cycloolefin copolymer composite films obtained in Examples and Comparative Examples were measured according to the above method. The obtained results are shown in Table 3. Table 3 shows the NB content, Tg, Mw, and Mw / Mn of the cycloolefin copolymers used in Examples and Comparative Examples.

[Reference Example 1]
15 g of the polyimide resin obtained above was dissolved in 85 g of GBL to obtain a polyimide resin solution. The obtained mixed solution was subjected to hypersalivation on glass to prepare a coating film at a linear velocity of 0.4 m / min. The coating film was heated at 70 ° C. for 60 minutes to peel off the film from the glass substrate, and then the film was fixed with a metal frame and further heated at 200 ° C. for 1 hour to obtain a polyimide film having a thickness of 50 μm. The CTE of the obtained polyimide film was 39 ppm / K.

[Reference Example 2]
A polyimide film having a thickness of 30 μm was obtained in the same manner as in Example 6 except that the polyamic acid solution obtained in Production Example 10 was used as the composition. The CTE of the obtained polyimide film was 9 ppm / K.

[Reference Example 3]
As the composition, the liquid crystal polyester solution obtained in Production Example 11 was used, and a liquid crystal polyester film having a thickness of 27 μm was obtained in the same manner as in Example 8 except that the thickness of the casting film was set to 300 μm. The CTE of the obtained liquid crystal polyester film was 33 ppm / K, the dielectric constant was 3.30, and the dielectric loss tangent was 0.0040.

As shown in Table 3, it was found that the films obtained in Examples 1 to 13 had a lower CTE than that of Comparative Example 1. Furthermore, it was found that the films obtained in Examples 1 to 11 and 13 were excellent in one-time bending resistance and repeated bending resistance as compared with Comparative Example 1.

Claims (15)

1. A film containing a resin (A) and a cycloolefin polymer (B), wherein at least one of the glass transition temperature and the melting point of the cycloolefin polymer (B) is 160 ° C. or higher.
2. The film according to claim 1, wherein the distance between the HSP values of the resin (A) and the cycloolefin polymer (B) is 6 or more.
3. The cycloolefin polymer (B) has the formula (I) :.
   

   

   [In the formula (I), m represents an integer of 0 or more, R ⁷ to R ¹⁸ represent hydrogen atoms, halogen atoms or hydrocarbon groups having 1 to 20 carbon atoms independently of each other, and R ¹¹ to R ¹⁴ If there are a plurality of them, they may be independent of each other, the same or different, and R ¹⁶ and R ¹⁷ may be bonded to each other and form a ring with the carbon atom to which they are bonded. ]
   The film according to claim 1 or 2, which comprises a monomer unit (I) derived from cycloolefin represented by.
4. The content of the monomer unit (I) in the cycloolefin polymer (B) is 60 mol% or more with respect to the total molar amount of the repeating units constituting the cycloolefin polymer (B), according to claim 3. The film described.
5. The cycloolefin-based polymer (B) is a monomer derived from at least one selected from the group consisting of ethylene, a linear α-olefin having 3 to 20 carbon atoms and an aromatic vinyl compound having 8 to 20 carbon atoms. The film according to any one of claims 1 to 4, which comprises unit (II).
6. The film according to any one of claims 1 to 5, wherein the cycloolefin polymer (B) has a weight average molecular weight (Mw) of 30,000 or more.
7. The film according to any one of claims 1 to 6, wherein the ratio (Mw / Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) of the cycloolefin polymer (B) is 2.5 or less.
8. The cycloolefin polymer (B) contains the two-chain structure of the monomer unit (I), and in the two-chain structure, the ratio of the meso-type two-chain to the racemo-type two-chain (meso-type two-chain / racemo-type). The film according to any one of claims 1 to 7, wherein the two chains) are 0.50 or less.
9. Any of claims 1 to 8, wherein the content of the cycloolefin polymer (B) is 5 to 50% by mass with respect to the total mass of the resin (A) and the cycloolefin polymer (B) contained in the film. The film described in Crab.
10. The resin (A) is any one of claims 1 to 9, wherein the resin (A) is at least one resin selected from the group consisting of a polyimide resin, a liquid crystal polymer, a fluororesin, an aromatic polyether resin and a maleimide resin. The film described.
11. The liquid crystal polymer has the formula (a1), the formula (a2) and the formula (a3):
    -O-Ar ¹ -CO- (a1)
    -CO-Ar ² -CO- (a2)
    -X-Ar ³ -Y- (a3)
    [(In formula (a1), Ar ¹ represents a 1,4-phenylene group, a 2,6-naphthylene group or a 4,4'-biphenylene group, and represents.
    In formula (a2), Ar ² represents a 1,4-phenylene group, a 1,3-phenylene group or a 2,6-naphthylene group.
    In formula (a3), Ar ³ represents a 1,4-phenylene group or a 1,3-phenylene group.
    X represents -NH-
    Y represents -O- or NH-]
    The film according to claim 10, which is a liquid crystal polyester containing a structural unit represented by.
12. The film according to any one of claims 1 to 11, wherein the glass transition temperature of the resin (A) is 180 ° C. or higher.
13. A composition containing a resin (A), a cycloolefin polymer (B) and a solvent, wherein at least one of the glass transition temperature and the melting point of the cycloolefin polymer (B) is 160 ° C. or higher.
14. The cycloolefin polymer (B) has the formula (I) :.
    

    

    [In the formula (I), m represents an integer of 0 or more, R ⁷ to R ¹⁸ represent hydrogen atoms, halogen atoms or hydrocarbon groups having 1 to 20 carbon atoms independently of each other, and R ¹¹ to R ¹⁴ If there are a plurality of them, they may be independent of each other, the same or different, and R ¹⁶ and R ¹⁷ may be bonded to each other and form a ring with the carbon atom to which they are bonded. ]
    The composition according to claim 13, which comprises the monomer unit (I) derived from cycloolefin represented by.
15. The content of the monomer unit (I) in the cycloolefin polymer (B) is 60 mol% or more with respect to the total molar amount of the repeating units constituting the cycloolefin polymer (B), according to claim 14. The composition described.