WO2021191210A1 - Utilisation de polymère styrène diène hydrogéné pour réduire les émissions de particules - Google Patents
Utilisation de polymère styrène diène hydrogéné pour réduire les émissions de particules Download PDFInfo
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- WO2021191210A1 WO2021191210A1 PCT/EP2021/057439 EP2021057439W WO2021191210A1 WO 2021191210 A1 WO2021191210 A1 WO 2021191210A1 EP 2021057439 W EP2021057439 W EP 2021057439W WO 2021191210 A1 WO2021191210 A1 WO 2021191210A1
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- hydrogenated
- lubricating composition
- particulate emissions
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- styrene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
- C10M143/12—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing conjugated diene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
- C10M143/10—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing aromatic monomer, e.g. styrene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/041—Mixtures of base-materials and additives the additives being macromolecular compounds only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/06—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/055—Particles related characteristics
- C10N2020/06—Particles of special shape or size
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/073—Star shaped polymers
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/02—Pour-point; Viscosity index
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/50—Emission or smoke controlling properties
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/54—Fuel economy
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/74—Noack Volatility
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2060/00—Chemical after-treatment of the constituents of the lubricating composition
- C10N2060/02—Reduction, e.g. hydrogenation
Definitions
- TITLE Use of hydrogenated styrene diene polymer to reduce particulate emissions
- the present invention relates to the use of hydrogenated styrene diene polymer to reduce particulate emissions from motor vehicles.
- An objective of the present invention is therefore to provide an additive for a lubricating composition having a direct impact on the emissions of particles.
- Another objective of the present invention is to provide a lubricating composition having a direct impact on the emissions of particles.
- particles denotes the particles emitted from the exhaust of motor vehicles. This represents a collection of microscopic particles ( ⁇ m or smaller in size). These substances are diverse and are included in vehicle exhaust gases produced by fuel combustion. These substances can be solid or liquid.
- the term particles includes the term soot, which is formed, oxidized and contains unburned hydrocarbons, oxygenated derivatives (ketones, esters, aldehydes, lactones, ethers, organic acids) and polycyclic aromatic hydrocarbons (the famous PAHs) accompanied by their nitrates, oxygenates, etc. There are also mineral (SO2, sulphates, etc.) and metallic derivatives.
- the present invention makes it possible to reduce the emissions of particles having a size greater than or equal to 23 nm.
- particle size is understood to mean particles, or agglomerate of particles, the size of which is between 23 and 100 nm, preferably between 23 and 60 nm, and more preferably between 23 and 40 nm. nm.
- the size of the particles can in particular be measured by spectrometry, for example using a spectrometer manufactured by the company Cambustion under the trade reference DMS500.
- reduction in particle emissions is understood to mean in particular the reduction in the number of particles, in particular of particles having a size greater than or equal to 23 nm. This includes reducing the number of particles emitted during a WLTC cycle. This is measured primarily by the number of kilometers traveled.
- the number of particles can in particular be measured by a particle counting device such as the device existing under the commercial reference AVL APC 489.
- the present application relates to the reduction of soot emissions.
- the present invention relates to the reduction of emissions of particles, preferably particles of size greater than or equal to 23 nm, preferably soot, during urban (low speed), peri-urban (moderate speed) and road cycles. (high speed) defined by the WLTC (or WLTP) (globally harmonized test procedure for light vehicles) and throughout the WLTC.
- the hydrogenated styrene diene polymer (or hydrogenated styrene / isoprene polymer) according to the invention is a copolymer of styrene and hydrogenated diene. It is one of the compounds classified as additives improving the viscosity index.
- the styrene / hydrogenated diene copolymer according to the invention can be chosen from copolymers in linear or star form, preferably star form.
- the styrene / hydrogenated diene copolymer can be chosen from block copolymers or random copolymers.
- the content of hydrogenated diene units is from 50 to 98%, preferably from 60 to 98%, more preferably from 70 to 97%, even more preferably from 75 to 96% by mass, relative to the mass of the copolymer .
- the content of styrene units is from 2 to 50%, preferably from 2 to 40%, more preferably from 3 to 30%, even more preferably from 4 to 25% by mass, relative to the mass of the copolymer.
- the styrene / hydrogenated diene copolymer according to the invention has a weight average molecular mass Mw ranging from 100,000 to 800,000 Da, preferably from 200,000 to 700,000 Da, more preferably from 300,000 to 600 000 Da, even more preferably from 400,000 to 500,000 Da.
- the styrene / hydrogenated diene copolymer according to the invention has a number-average molecular mass Mn ranging from 50,000 to 800,000 Da, preferably from 75,000 to 600,000 Da, more preferably from 100 000 to 500,000 Da, even more preferably 100,000 to 200,000 Da.
- the styrene / hydrogenated diene copolymer according to the invention has a dispersity index ranging from 1 to 4, preferably from 1.2 to 3.5, more preferably from 1.5 to 3 , 5, even more preferably from 2 to 3.
- the hydrogenated styrene diene copolymer is used in an amount of 0.1 to 15% by weight relative to the total weight of the lubricating composition.
- This quantity is understood as a quantity of active polymer material (dry extract).
- the copolymer of styrene and of hydrogenated diene used in the context of the present invention may be in the form of a dispersion in a mineral or synthetic oil, and more particularly in a group III oil according to the API classification.
- the hydrogenated diene unit is a hydrogenated butadiene or hydrogenated isoprene unit, this is then referred to as a hydrogenated styrene / butadiene polymer or a hydrogenated styrene / isoprene polymer.
- the hydrogenated diene unit is a hydrogenated isoprene unit, this is then referred to as a hydrogenated styrene / isoprene polymer.
- the base oil used in the lubricating compositions of the invention can be oils of mineral or synthetic origin belonging to groups I to V according to the classes defined by the API classification (or their equivalents according to the ATIEL classification (Table 1). or their mixtures.
- the mineral base oils of the invention include any type of base oil obtained by atomospheric and vacuum distillation of crude petroleum, followed by refining operations such as solvent extraction, deasphalting, solvent dewaxing, hydrotreatment, hydrocracking, hydroisomerization and hydrofinishing.
- the base oils of the lubricating compositions according to the invention can also be chosen from synthetic oils, such as certain esters of carboxylic acids and alcohols, and polyalphaolefins.
- the polyalphaolefins used as base oil are for example obtained from monomers comprising from 4 to 32 carbon atoms, for example from octene or decene, and for which the viscosity at 100 ° C is between 1 , 5 and 15 mm2.s-1 according to ASTM D445.
- Their average molar mass is generally between 250 and 3000 according to the ASTM D5296 standard.
- the lubricating composition according to the invention can comprise at least 50% by weight of base oil relative to the total weight of the composition. More advantageously, the lubricating composition according to the invention comprises at least 60% by weight, or even at least 70% by weight, of base oils relative to the total weight of the lubricating composition. More preferably, the lubricating composition according to the invention comprises from 75 to 97% by weight of base oils relative to the total weight of the composition.
- composition of the invention can also include at least one additive.
- the preferred additives for the lubricating composition according to the invention are chosen from detergent additives, the friction modifying additives differ from the molybdenum compounds defined above, extreme pressure additives, dispersants, pour point activators, anti- mousse, thickeners and mixtures thereof.
- the lubricating compositions according to the invention comprise at least one extreme pressure additive, or a mixture.
- Anti-wear additives and extreme pressure additives protect surface friction by forming a protective film adsorbed on its surfaces.
- the anti-wear additives are chosen from additives comprising phosphorus and sulfur such as the metals alkylthiophosphate, in particular zinc alkylthiophosphate, and more precisely zinc dialkyldithiophosphate or ZnDTP.
- the preferred compounds are of formula Zn ((SP (S) (OR) (OR ')) 2, in which R and R', identical or different, independently represent an alkyl group, preferably an alkyl group comprising from 1 to 18 carbon atoms.
- Amine phosphates are also antiwear additives which can be used in the lubricating compositions of the invention.
- the phosphorus atoms provided by these additives can act as a poison in automobile catalytic systems since they generate ash. It is possible to minimize these effects by substituting part of the amine phosphates with additives which do not provide phosphorus, such as for example polysulfides, in particular olefins containing sulfur.
- the lubricating compositions according to the invention can comprise from 0.01 to 6% by weight, preferably from 0.05 to 4% by weight, more preferably from 0.1 to 2% by weight relative to the total weight of lubricating composition, anti-wear and extreme pressure additives.
- the lubricating compositions according to the invention comprise from 0.01 to 6% by weight, preferably from 0.05 to 4% by weight, more preferably from 0.1 to 2% by weight relative to the total weight of composition lubricant, anti-wear additives (or anti-wear compound).
- compositions according to the invention can comprise at least one friction modifier additive different from the molybdenum compounds of the invention.
- the friction modifying additives can in particular be chosen from compounds providing metallic elements and ashless compounds.
- the compounds providing metallic elements mention may be made of transition metal complexes such as Mo, Sb, Sn, Fe, Cu, Zn for which the ligands may be hydrocarbon compounds comprising oxygen or nitrogen atoms. , sulfur or phosphorus.
- the ashless friction modifier additives are generally of organic origin or can be chosen from fatty acid monoesters and polyols, alkoxylated amines, alkoxylated fatty amines, fatty epoxides, fatty epoxy borates, amines fatty or acid esters of glycerol.
- fatty compounds comprising at least one hydrocarbon group comprising from 10 to 24 carbon atoms.
- the lubricating composition according to the invention can comprise from 0.01 to 2% by weight or from 0.01 to 5% by weight, preferably from 0.1 to 1.5% by weight or from 0.1 to 2 % by weight relative to the total weight of the lubricating composition, of friction modifier additive different from the molybdenum compounds according to the invention.
- the lubricating composition according to the invention can comprise at least one antioxidant additive.
- Antioxidant additives generally retard the degradation of the lubricant composition. This degradation is most often expressed by the formation of deposit, by the presence of sludge or by an increase in the viscosity of the lubricating composition.
- Antioxidant additives generally act as free radical inhibitors or destructive hydroperoxide inhibitors.
- antioxidants currently used, mention may be made of phenolic-type antioxidants, amine-type antioxidants, and antioxidants containing sulfur and phosphorus. Some of these antioxidants, for example those comprising sulfur and phosphorus can generate ash.
- the phenolic antioxidant additives can be ash free or in the form of neutral or basic metal salts.
- the antioxidant additives can in particular be chosen from sterically hindered phenols, esters of sterically hindered phenols, sterically hindered phenols comprising a thioether bridge, diphenylamines, diphenylamines substituted with at least one C1 to C12 alkyl group, N, N '-dialkyl-aryl-diamines and mixtures thereof.
- the sterically hindered phenols are chosen from compounds comprising a phenol group for which at least one of the carbon atoms in the vicinity of the carbon atom carrying the alcohol function is substituted by at least one alkyl group in C1 to C10, preferably a C1 to C6 alkyl group, preferably a C4 alkyl group, preferably a tert-butyl group.
- Amine compounds are another class of antioxidant additives which can be used, optionally in combination with phenolic antioxidant additives.
- amine compounds are aromatic amines, for example aromatic amines of formula NRaRbRc in which Ra represents an aliphatic group or an aromatic group, optionally substituted, Rb represents an aromatic group, optionally substituted, Rc represents a hydrogen atom, an alkyl group, an aryl group or a group of formula RdS (0) zRe in which Rd represents an alkylene or alkenylene group, Re represents an alkyl group, an alkenyl group or an aryl group and z represents 0, 1 or 2.
- Sulfur-containing alkyl phenols or their alkali or alkaline earth metal salts can also be used as antioxidant additives.
- antioxidant additives are compounds comprising copper, eg copper thio- or dithiophosphate, copper and carboxylic acid salts, dithiocarbamates, sulfonates, phenates, copper acetylacetonates. Copper I and II salts, salts of succinic acid or succinic anhydride can also be used.
- the lubricating compositions according to the invention can also comprise any type of antioxidant known to those skilled in the art.
- the lubricating composition comprises at least one antioxidant additive free of ash.
- the lubricating composition according to the invention comprises, from 0.1 to 2% by weight relative to the total weight of the composition, of at least one antioxidant additive.
- the lubricating composition according to the invention can also comprise at least one detergent additive.
- Detergent additives generally reduce the formation of deposits on the surface of metal parts by dissolving the by-products of oxidation and combustion.
- detergent additives which can be used in the lubricating compositions according to the invention are generally known to those skilled in the art.
- Detergent additives can be anionic compounds comprising a long lipophilic hydrocarbon chain and a hydrophobic head.
- the associated cation can be a metal cation of an alkali or alkaline earth metal.
- the detergent additives are preferably chosen from alkali or alkaline earth metal salts of carboxylic acid, sulfonates, salicylates, naphthenates, as well as salts of phenates.
- the alkali and alkaline earth metals are preferably calcium, magnesium, sodium or barium.
- metal salts generally include the metal in a stoichiometric amount or in excess, that is to say in a content greater than the stoichiometric content.
- overbased detergents the excess metal implying the overbased nature of the detergent additive is generally in the form of an oil insoluble metal salt, for example carbonate, hydroxide, oxalate, acetate, glutamate, preferably carbonate.
- the lubricating composition according to the invention can comprise from 0.5 to 8% or from 2 to 4% by weight of overbased detergent additive relative to the total weight of the lubricating composition.
- the lubricating composition according to the invention can also include a pour point depressant additive.
- the pour point depressant additive By slowing the formation of paraffin crystals, the pour point depressant additive generally improves the cold behavior of the lubricant composition according to the invention.
- alkyl polymethacrylates there may be mentioned, alkyl polymethacrylates, polyacrylates, polyarylamides, polyalkylphenols, polyalkylnaphthalene, alkyl polystyrenes.
- the lubricating composition according to the invention can also comprise a dispersing agent.
- the dispersing agents can be chosen from Mannich bases, succinimides and their derivatives. Also advantageously, the lubricating composition according to the invention can comprise from 0.2 to 10% by weight of dispersing agent relative to the total weight of lubricating composition.
- the lubricating composition according to the invention can also further comprise at least one other additional polymer improving the viscosity index.
- additional polymer improving the viscosity index there may be mentioned polymeric esters, homopolymers or copolymers, hydrogenated or not, of styrene, butadiene, and isoprene, polymethacrylates (PMA).
- the lubricating composition according to the invention can comprise from 1 to 15% by weight, relative to the total weight of lubricating composition, of additive improving the viscosity index.
- the lubricating composition according to the invention can also comprise at least one thickening agent.
- the lubricating composition according to the invention can also comprise an anti-foaming agent and a demulsifying agent.
- the lubricating composition of the invention further comprises at least one anti-wear agent, in particular based on Zinc, in particular ZnDTP.
- the present invention also relates to the use of the lubricating composition according to the invention for reducing the friction of the mechanical parts of an engine, at least one of the parts comprising a coating of amorphous carbon type, preferably hydrogenated amorphous carbon.
- the present invention also relates to the use of a hydrogenated styrene diene polymer in an engine lubricating composition to reduce particulate emissions.
- the present invention also relates to a method of reducing the emission of particles in an engine, preferably a gas, gasoline, diesel or even hybrid engine, comprising the use of a lubricating composition comprising a base oil and a hydrogenated styrene diene polymer.
- the present invention also relates to a method of reducing the emission of particles in an engine, preferably a gas, gasoline, diesel or even hybrid engine, lubricated with a lubricating composition comprising the addition in said lubricating composition of a hydrogenated styrene diene polymer.
- the hydrogenated styrene diene polymer, the particles, the base oil and the lubricating composition being as defined above.
- the present invention covers all motorized vehicles, in particular vehicles comprising a 2-stroke or 4-stroke engine, gasoline, diesel, hybrid and gas engines.
- the present invention covers all motorized vehicles, preferably comprising at least one combustion engine, in particular heavy vehicles or light vehicles.
- Example 1 Lubricating Compositions The following lubricating compositions were prepared according to Table 2 below.
- Example 2 Measurement of the number of particles emitted The compositions of Example 1 were subjected to the WLTC test and the quantity of particles per kilometer traveled having a size greater than or equal to 23 nm emitted at the end of each cycle was measured.
- the engine tests were carried out on 4-cylinder in-line turbocharged engines. The tests are carried out at the same starting temperature of the engine. All other test bench conditions were also held constant. The sampling for the exhaust gas measurements was carried out in the raw exhaust gas before the exhaust system but after the aftertreatment systems. Thus, the effects observed are indeed due to the sole use of the lubricating composition and therefore to the use of the hydrogenated styrene-diene polymer and not to any other criterion such as the presence of a driver, the weight of the vehicle, the temperature. , humidity, etc.
- the particle size distribution was measured in parallel by a Cambustion differential mobility spectrometer (DMS500). It uses high voltage discharge to charge each particle in proportion to its area. The charged particles are introduced into a classification section with a strong radial electric field. This field causes the particles to drift through a flow in a column towards the electrometer detectors. The particles are detected at different distances in the column, depending on their aerodynamic resistance / load ratio. The outputs of the 22 electrometers are processed in real time at 10 Hz to provide spectral data and other measurements.
- DMS500 Cambustion differential mobility spectrometer
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Abstract
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Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
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CN202180023945.3A CN115335496B (zh) | 2020-03-25 | 2021-03-23 | 氢化二烯苯乙烯聚合物用于减少微粒排放的用途 |
KR1020227036748A KR20220153648A (ko) | 2020-03-25 | 2021-03-23 | 미립자 배출을 감소시키기 위한 수소화된 디엔 스티렌 폴리머의 용도 |
JP2022557068A JP2023518480A (ja) | 2020-03-25 | 2021-03-23 | 粒子排出物を削減するための水素化ジエンスチレンポリマーの使用 |
EP21714145.6A EP4127113A1 (fr) | 2020-03-25 | 2021-03-23 | Utilisation de polymère styrène diène hydrogéné pour réduire les émissions de particules |
US17/913,607 US20230141132A1 (en) | 2020-03-25 | 2021-03-23 | Use of hydrogenated diene styrene polymer to reduce particulate emissions |
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FRFR2002902 | 2020-03-25 | ||
FR2002902A FR3108620B1 (fr) | 2020-03-25 | 2020-03-25 | Utilisation de polymère styrène diène hydrogéné pour réduire les émissions de particules |
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WO2021191210A1 true WO2021191210A1 (fr) | 2021-09-30 |
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US (1) | US20230141132A1 (fr) |
EP (1) | EP4127113A1 (fr) |
JP (1) | JP2023518480A (fr) |
KR (1) | KR20220153648A (fr) |
CN (1) | CN115335496B (fr) |
FR (1) | FR3108620B1 (fr) |
WO (1) | WO2021191210A1 (fr) |
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FR3140887A1 (fr) * | 2022-10-12 | 2024-04-19 | Totalenergies Onetech | Utilisation d’une huile de base spécifique pour réduire les émissions de particules |
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WO2018065606A1 (fr) * | 2016-10-07 | 2018-04-12 | Total Marketing Services | Composition lubrifiante pour moteur marin ou moteur stationnaire |
WO2019202150A1 (fr) * | 2018-04-20 | 2019-10-24 | Total Marketing Services | Composition lubrifiante pour moteurs industriels a potentiel fe amplifie |
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US7163913B2 (en) * | 2003-07-01 | 2007-01-16 | Infineum International Limited | Viscosity index improvers for lubricating oil compositions |
ES2380949T3 (es) * | 2005-11-03 | 2012-05-21 | Infineum International Limited | Copolímeros de dibloques lineales como aditivos anti-desgaste para lubricantes de cárter de motores de combustión interna |
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EP2363454B1 (fr) * | 2010-02-23 | 2018-09-26 | Infineum International Limited | Utilisation d'une composition d'huile lubrifiante |
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EP2607461B1 (fr) * | 2011-12-21 | 2018-01-17 | Infineum International Limited | Lubrification de moteur marin |
US9133413B2 (en) * | 2011-12-21 | 2015-09-15 | Infineum International Limited | Viscosity index improvers for lubricating oil compositions |
US20140162924A1 (en) * | 2012-12-10 | 2014-06-12 | Raymond F. Watts | Method of improving the efficiency of automotive transmissions |
ES2719785T3 (es) * | 2013-03-21 | 2019-07-16 | Infineum Int Ltd | Lubricación de motor marino |
EP2980193A4 (fr) * | 2013-03-28 | 2016-11-16 | Jx Nippon Oil & Energy Corp | Composition d'huile moteur économisant le carburant |
WO2015097152A1 (fr) * | 2013-12-24 | 2015-07-02 | Shell Internationale Research Maatschappij B.V. | Composition lubrifiante |
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US20150184108A1 (en) * | 2014-01-02 | 2015-07-02 | Rajiv Taribagil | Viscosity index improver concentrates for lubricating oil compositions |
EP3116979B1 (fr) * | 2014-03-12 | 2018-11-14 | The Lubrizol Corporation | Méthode de lubrification d'un moteur de combustion |
EP3257920A1 (fr) * | 2016-06-17 | 2017-12-20 | Total Marketing Services | Polymères de lubrifiant |
-
2020
- 2020-03-25 FR FR2002902A patent/FR3108620B1/fr active Active
-
2021
- 2021-03-23 JP JP2022557068A patent/JP2023518480A/ja active Pending
- 2021-03-23 CN CN202180023945.3A patent/CN115335496B/zh active Active
- 2021-03-23 KR KR1020227036748A patent/KR20220153648A/ko unknown
- 2021-03-23 EP EP21714145.6A patent/EP4127113A1/fr active Pending
- 2021-03-23 US US17/913,607 patent/US20230141132A1/en active Pending
- 2021-03-23 WO PCT/EP2021/057439 patent/WO2021191210A1/fr unknown
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018065606A1 (fr) * | 2016-10-07 | 2018-04-12 | Total Marketing Services | Composition lubrifiante pour moteur marin ou moteur stationnaire |
WO2019202150A1 (fr) * | 2018-04-20 | 2019-10-24 | Total Marketing Services | Composition lubrifiante pour moteurs industriels a potentiel fe amplifie |
Also Published As
Publication number | Publication date |
---|---|
US20230141132A1 (en) | 2023-05-11 |
FR3108620B1 (fr) | 2022-09-09 |
CN115335496B (zh) | 2023-08-04 |
JP2023518480A (ja) | 2023-05-01 |
FR3108620A1 (fr) | 2021-10-01 |
CN115335496A (zh) | 2022-11-11 |
EP4127113A1 (fr) | 2023-02-08 |
KR20220153648A (ko) | 2022-11-18 |
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