WO2021179369A1 - 一种滤芯及其制备方法和口罩 - Google Patents

一种滤芯及其制备方法和口罩 Download PDF

Info

Publication number
WO2021179369A1
WO2021179369A1 PCT/CN2020/082817 CN2020082817W WO2021179369A1 WO 2021179369 A1 WO2021179369 A1 WO 2021179369A1 CN 2020082817 W CN2020082817 W CN 2020082817W WO 2021179369 A1 WO2021179369 A1 WO 2021179369A1
Authority
WO
WIPO (PCT)
Prior art keywords
filter element
layer
meltblown
fabric layer
microporous membrane
Prior art date
Application number
PCT/CN2020/082817
Other languages
English (en)
French (fr)
Inventor
池慧杰
Original Assignee
浙江东蒙医疗器械有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 浙江东蒙医疗器械有限公司 filed Critical 浙江东蒙医疗器械有限公司
Publication of WO2021179369A1 publication Critical patent/WO2021179369A1/zh

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B01D39/14—Other self-supporting filtering material ; Other filtering material
    • B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
    • B01D39/1607—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
    • B01D39/1623—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of synthetic origin
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
    • A41D13/05—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting only a particular body part
    • A41D13/11—Protective face masks, e.g. for surgical use, or for use in foul atmospheres
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/02—Layered materials
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/10—Impermeable to liquids, e.g. waterproof; Liquid-repellent
    • A41D31/102—Waterproof and breathable
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/14—Air permeable, i.e. capable of being penetrated by gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/0027—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions
    • B01D46/0032—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions using electrostatic forces to remove particles, e.g. electret filters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/10—Particle separators, e.g. dust precipitators, using filter plates, sheets or pads having plane surfaces
    • B01D46/12—Particle separators, e.g. dust precipitators, using filter plates, sheets or pads having plane surfaces in multiple arrangements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/54—Particle separators, e.g. dust precipitators, using ultra-fine filter sheets or diaphragms
    • B01D46/543—Particle separators, e.g. dust precipitators, using ultra-fine filter sheets or diaphragms using membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/56—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with multiple filtering elements, characterised by their mutual disposition
    • B01D46/62—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with multiple filtering elements, characterised by their mutual disposition connected in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/266—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by an apertured layer, the apertures going through the whole thickness of the layer, e.g. expanded metal, perforated layer, slit layer regular cells B32B3/12
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04—Additives and treatments of the filtering material
    • B01D2239/0435—Electret
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04—Additives and treatments of the filtering material
    • B01D2239/0442—Antimicrobial, antibacterial, antifungal additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
    • B01D2239/065—More than one layer present in the filtering material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/10—Filtering material manufacturing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0253—Polyolefin fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0276—Polyester fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/726—Permeability to liquids, absorption
    • B32B2307/7265—Non-permeable

Definitions

  • the invention belongs to the technical field of filtration, and specifically relates to a filter element, a preparation method thereof, and a mask.
  • PM2.5 fine particulate matter
  • PM2.5 has a small particle size, large area, strong activity, and is easily accompanied by toxic and harmful substances (for example, heavy metals, microorganisms, etc.)
  • toxic and harmful substances for example, heavy metals, microorganisms, etc.
  • the stay in the atmosphere is long and the transportation distance is long, so it has a greater impact on human health and the quality of the atmospheric environment.
  • the research and production of masks such as particulate matter, anti-virus, and germs have attracted widespread attention from all walks of life.
  • the main material that brings virus filtering effect to medical protective masks and medical surgical masks is the extremely fine and electrostatic inner filter cloth-meltblown non-woven fabric.
  • medical surgical masks In terms of mask composition, medical surgical masks generally have three layers, the inner and outer layers are spunbonded non-woven fabrics, and the middle filter layer is melt-blown non-woven fabrics. Melt-blown non-woven fabric is an important raw material for medical surgical masks and N95 masks. There is a difference in the amount of the two.
  • Medical surgical masks are generally SMS structure (two spunbond layers S and one meltblown layer M), which can filter N95 masks with 95% fine particles are sometimes made of SMMMS non-woven fabrics (two spunbond layers S and three meltblown layers M), and the amount of meltblown cloth is much higher than that of ordinary masks.
  • meltblown non-woven fabric As the filter layer of a mask, meltblown non-woven fabric is very important. In production, the number of meltblown layers can be increased to ensure better antibacterial barrier properties. However, too many meltblown layers will make it difficult for users to breathe. Therefore, the isolation effect of the mask is often judged from the difficulty of breathing of the mask. The more difficult the breathing, the better the barrier effect. For example, in practical applications, the filtration efficiency of N95 is better than that of medical surgical masks, but the user is wearing the process, It is obvious that the breathing resistance of N95 is greater. If the meltblown layer becomes a thin film, all viruses and bacteria can be effectively blocked, but the user feels that the respiratory resistance becomes greater or even unable to breathe, and the filtration efficiency of the mask will not be discussed.
  • the meltblown layer mostly uses PP meltblown nonwoven fabric, which is a kind of ultrafine electrostatic fiber cloth.
  • PP meltblown nonwoven fabric which is a kind of ultrafine electrostatic fiber cloth.
  • dust, viruses and bacteria encounter the polypropylene meltblown nonwoven fabric, they will be electrostatically adsorbed on the polypropylene meltblown nonwoven fabric.
  • the surface of the polypropylene meltblown non-woven fabric is impenetrable and plays a role in isolating germs.
  • it is difficult to remove them by washing, and washing with water will destroy the absorption of static electricity. Therefore, most of the current masks are disposable masks, which causes a waste of resources.
  • One of the objectives of the present invention is to provide a filter element with both high filtration efficiency and low ventilation resistance performance.
  • a filter element includes a microporous membrane layer, and a first meltblown nonwoven fabric layer and a second meltblown nonwoven fabric layer on both sides of the microporous membrane layer; wherein the first meltblown nonwoven fabric The layer and the second melt-blown non-woven fabric layer are both multi-component melt-blown non-woven fabrics.
  • Microporous membrane is a polymer membrane with a microporous structure, generally a porous membrane with a pore size between 5.0 nanometers and 1.0 mm. Because of its dense porosity, uniform membrane structure and good air permeability, it has become widely used.
  • the layer on the one hand, is used as a support material to avoid damage to the microporous membrane layer during production, transportation or use.
  • the electrostatic adsorption of the multi-component meltblown non-woven fabric can play a multi-layer filtering function. Can further increase the filtration efficiency of the filter element.
  • the microporous membrane layer adopts PTFE microporous membrane; PTFE micropores are evenly distributed, and it is a flexible and elastic microporous material. There are countless invisible pores on the membrane layer.
  • the pore size of these pores is Small, usually a few microns, even 0.01 microns, large porosity, uniform pore size distribution, breathable and impermeable, it is an ideal choice as a filter element.
  • the pore size of the microporous membrane layer is 1 to 5 ⁇ m, and the pore size under this condition can not only ensure the filtration performance of the microporous membrane, but also protect the good ventilation performance.
  • the thickness of the PTFE microporous membrane layer is 2 ⁇ m.
  • the multi-component meltblown nonwoven fabric includes PP and/or PE;
  • PP is the main material of the meltblown nonwoven fabric commonly used in the prior art. It is a kind of ultrafine electrostatic fiber cloth that can capture dust When droplets containing viruses and bacteria come close to the meltblown nonwoven fabric, they will be electrostatically adsorbed on the surface of the nonwoven fabric and cannot pass through.
  • the higher the PP melt index the higher the fluidity at high temperatures, and it is easy to block micro
  • the micropores on the porous membrane layer increase the ventilation resistance. Therefore, using PP as the supporting material and controlling the volume ratio of PP in the meltblown non-woven fabric will help to further improve the filtration efficiency of the filter element without increasing the ventilation resistance.
  • PE can block the penetration of bacterial particles and liquid penetration, has good air permeability, effectively isolates water, discharges heat and moisture, and greatly improves the comfort performance.
  • the first meltblown non-woven fabric layer and the second meltblown non-woven fabric layer are both made of PP and PET two-component composite material (indicated by "PP/PET”) two-component melt-blown non-woven fabric Or PE and PET two-component composite material (indicated by "PE/PET”) melt blown non-woven fabric; PET has excellent tensile and elongation properties, can effectively support the entire non-woven fabric structure, the glass transition temperature of PET Compared with PE or PP, both are lower. When compounded with PP or PE at a suitable temperature, it can effectively avoid the adhesion of multi-component melt-blown non-woven fabrics to the hot pressing device, which greatly saves energy consumption and improves production efficiency.
  • the volume percentage of the PET in the PP/PET or PE/PET two-component meltblown non-woven fabric is 70-80%;
  • the volume ratio of PP or PE in the woven fabric is too high, it is easy to adhere to the electromagnetic induction heating roller, resulting in failure to produce, and when the ratio is too low, the composite firmness is very low and cannot be applied.
  • the microporous film layer and the first meltblown nonwoven fabric layer or the second meltblown nonwoven fabric layer further include a silver ion layer, and silver ions are positively charged cations with strong oxidation.
  • silver ions can be lethal to many kinds of pathogenic bacteria, fungi, molds, parasites and viruses. Setting a silver ion layer in the filter element helps to improve the filtration efficiency of the filter element.
  • the second objective of the present invention is to provide a method for preparing the above-mentioned filter element.
  • a method for preparing a filter element is to use a thermal composite process to composite the first meltblown non-woven fabric layer and the second meltblown nonwoven fabric layer on the microporous film layer at one time, and then perform a thermal composite and a molding once.
  • thermal compounding process adopts a thermal compounding machine with heat rollers.
  • the thermal compounding process conditions are: the temperature of the heating roller is 110-160° C., the pressure of the heating roller is 150-200 N/cm 2 , and the linear speed of the thermal compounding is 10-25 m/min.
  • the thermal compounding process conditions are: when passing through the thermal compounding machine, the temperature of the heating roller is 155° C., the pressure of the heating roller is 180 N/cm 2 , and the linear speed of the thermal compounding is 20 m/min.
  • the third objective of the present invention is to provide a mask that has the functions and performance of high filtration efficiency and low ventilation resistance.
  • a mask includes the above-mentioned filter element or has a filter element prepared by the preparation method.
  • the above-mentioned filter element can also be used to prepare a protective mask or other protective articles or filtering devices with filtering effect.
  • the filter element of the present invention uses a PTFE microporous membrane layer with a particle size of 1 to 5 ⁇ m as the core filter layer, and multi-component melt-blown non-woven fabrics such as PP/PE, PE/PET, PP/PE/PET as the supporting material, Compounded on both sides of the PTFE microporous membrane layer, the use of the porous structure of the microporous material, uniform pore size distribution, and good air permeability provide a good guarantee for the filtration efficiency of the filter element; the use of multi-component meltblown non-woven fabrics
  • the performance of the composite material reduces the ventilation resistance of the filter element while protecting the microporous membrane from damage; the multi-layer filtration also further improves the filtration efficiency of the filter element.
  • the filtering efficiency of the mask prepared by the filter element can reach more than 95%, the suction resistance can be as low as 16.9Pa, and it has the excellent performance of high filtering efficiency and low ventilation resistance.
  • the preparation method of the filter element provided by the present invention uses a thermal laminating machine with a thermal roller to reasonably control the working conditions of the thermal roller without any adhesive, and can be molded at one time after only one thermal composite pressure, which is compared with common ones. Need to go through two thermal compounding processes, the melt flow area of the multi-component melt blown non-woven fabric is significantly reduced. This process can significantly reduce the melt flow area of the multi-component composite material on both sides of the microporous film, and reduce the microporous film The blockage of the layer, therefore, the use of the two sides of the present invention to simultaneously heat composite to make the filter element once formed has lower ventilation resistance. In addition, only one heat pressing treatment can effectively reduce the microporous membrane that is easy to be damaged under multiple high temperatures. The problem.
  • the PTFE microporous membrane itself has the characteristics of air permeability and impermeability, it can withstand water washing, disinfection and other treatments.
  • Masks including the filter element of the present invention or the filter element prepared by the preparation method of the present invention have the advantage of being reusable. The filtration efficiency after the second washing can still reach more than 95%, which prolongs the life of the mask and greatly saves resources.
  • a filter element comprising a PTFE microporous membrane layer with a particle size of 1 ⁇ m, and a first meltblown nonwoven fabric layer and a second meltblown nonwoven fabric layer on both sides of the microporous membrane layer;
  • the first meltblown nonwoven fabric layer and the second meltblown nonwoven fabric layer are both PE/PET two-component meltblown nonwoven fabrics
  • the volume ratio of PE to PET in the PE/PET two-component meltblown non-woven fabric is 2:8;
  • the preparation method of the above-mentioned filter element is as follows: the first meltblown non-woven fabric layer and the second meltblown non-woven fabric layer are composited on both sides of the microporous film layer at one time by using a thermal composite machine with a thermal roller.
  • the thermal compounding process conditions are: when the material passes through the thermal compounding machine, the heating roller temperature is 110°C, the heating roller pressure is 150N/cm 2 , and the thermal compounding linear speed is 10m/min;
  • the mask is made by the conventional method in the prior art.
  • a filter element comprising a PTFE microporous membrane layer with a particle size of 2 ⁇ m, and a first meltblown nonwoven fabric layer and a second meltblown nonwoven fabric layer on both sides of the microporous membrane layer;
  • the first meltblown nonwoven fabric layer and the second meltblown nonwoven fabric layer are both PP/PET two-component meltblown nonwoven fabrics
  • the volume ratio of PP to PET in the PP/PET two-component meltblown non-woven fabric is 2.5: 7.5;
  • the preparation method of the above-mentioned filter element is as follows: the first meltblown non-woven fabric layer and the second meltblown non-woven fabric layer are composited on both sides of the microporous film layer at one time by using a thermal composite machine with a thermal roller.
  • the thermal compounding process conditions are: when the material passes through the thermal compounding machine, the temperature of the heating roller is 155°C, the pressure of the heating roller is 180N/cm 2 , and the linear speed of the thermal compounding is 20m/min;
  • the mask is made by the conventional method in the prior art.
  • a filter element comprising a PTFE microporous membrane layer with a particle size of 3 ⁇ m, and a first meltblown nonwoven fabric layer and a second meltblown nonwoven fabric layer on both sides of the microporous membrane layer;
  • the first melt-blown non-woven fabric layer is a PE/PET two-component melt-blown non-woven fabric;
  • the second melt-blown non-woven fabric layer is a PP/PET two-component melt-blown non-woven fabric;
  • the volume ratio of PP to PET in the PE/PET two-component melt-blown non-woven fabric is 3:7; the volume ratio of PP to PET in the PP/PET two-component melt-blown non-woven fabric is 2:8;
  • the preparation method of the above-mentioned filter element is as follows: the first meltblown non-woven fabric layer and the second meltblown non-woven fabric layer are composited on both sides of the microporous film layer at one time by using a thermal composite machine with a thermal roller.
  • the thermal compounding process conditions are: when the material passes through the thermal compounding machine, the temperature of the heating roller is 125°C, the pressure of the heating roller is 190N/cm 2 , and the linear speed of the thermal compounding is 15m/min;
  • the mask is made by the conventional method in the prior art.
  • a filter element comprising a PTFE microporous membrane layer with a particle diameter of 5 ⁇ m, and a first meltblown nonwoven fabric layer and a second meltblown nonwoven fabric layer on both sides of the microporous membrane layer;
  • the first meltblown nonwoven fabric layer and the second meltblown nonwoven fabric layer are both PP/PE/PET three-component meltblown nonwoven fabrics;
  • the volume ratio of the PP/PE/PET three-component meltblown non-woven fabric is 2:1:7 at one time;
  • the preparation method of the above-mentioned filter element is as follows: the first meltblown non-woven fabric layer and the second meltblown non-woven fabric layer are composited on both sides of the microporous film layer at one time by using a thermal composite machine with a thermal roller.
  • the thermal compounding process conditions are: when the material passes through the thermal compounding machine, the temperature of the heating roller is 160°C, the pressure of the heating roller is 200N/cm 2 , and the linear speed of the thermal compounding is 25m/min;
  • the mask is made by the conventional method in the prior art.
  • the difference is that the particle size of the PTFE microporous membrane layer is 10 ⁇ m.
  • the difference is that the volume ratio of the PP/PET two-component meltblown non-woven fabric is 4:6.
  • the thermal compounding process conditions are: first compound the first melt-blown non-woven fabric layer on one side of the PTFE microporous membrane layer, and then compound the second melt-blown non-woven fabric layer On the other side of the PTFE microporous membrane layer.
  • the filtration efficiency is higher than 99.97%, reaching the level 3 filtration level, it also seriously increases the suction resistance, which will cause the mask to be unable to be used normally;
  • the PP/PET two-component meltblown non-woven fabric used in Comparative Example 2 The volume ratio is 4:6. It was found that part of the meltblown non-woven fabric would adhere to the heat roller during production, resulting in abnormal production; Comparative Example 3 used the first and second meltblown non-woven fabrics to be thermally combined.
  • the second meltblown non-woven fabric is compounded on both sides of the PTFE microporous membrane. The two high-temperature hot-pressing treatments cause the PP/PE melting process area to increase, resulting in the blockage of the PTFE microporous membrane, and finally resulting in a significant suction resistance of the mask Increase.
  • Control group commercially available medical N95 masks

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Physical Education & Sports Medicine (AREA)
  • Respiratory Apparatuses And Protective Means (AREA)
  • Filtering Materials (AREA)

Abstract

本发明属于过滤技术领域，涉及一种滤芯，包括微孔膜层，以及位于所述微孔膜层两侧的第一熔喷无纺布层和第二熔喷无纺布层；该滤芯的制备方法如下：采用热复合工艺将所述第一熔喷无纺布层和第二熔喷无纺布层一次性复合在所述微孔膜层的两侧；由本发明的滤芯制备而成的口罩均能保证95％以上的过滤效率，且通气阻力平均低至70Pa，兼具有高过滤效率和低通气阻力的优异性能，此外，该口罩水洗后可重复使用，可大大节约资源。

Description

一种滤芯及其制备方法和口罩 技术领域
本发明属于过滤技术领域，具体涉及一种滤芯及其制备方法和口罩。
背景技术
近年来，高密度人口的经济及社会活动导致空气中排放大量细颗粒物(PM 2.5)，PM2.5粒径小，面积大，活性强，易附带有毒、有害物质(例如，重金属、微生物等)，且在大气中的停留时间长、输送距离远，因而对人体健康和大气环境质量的影响更大，严重时可能引发癌症及其它严重疾病，特别是自2003年非典型性肺炎爆发以来，过滤颗粒物、防病毒、病菌等口罩的研究和生产引起了社会各界的广泛关注，2019年底新冠病毒肺炎疫情来袭，全国各地口罩等医疗防护用品更是供不应求，一时间水涨船高。面对自然环境中潜藏的PM 2.5、细菌、病毒等隐患，为保障个人的健康和生活、工作环境的清洁，提供基础防御细颗粒物、病菌的口罩将成为大众日常必需品，这一趋势将促使人们对口罩的过滤效率和佩戴舒适度有更高的要求。
而给医用防护口罩和医用外科口罩带来病毒过滤作用的主要材料，就是极细密且带静电的内层过滤布——熔喷无纺布。从口罩构成来看，医用外科口罩一般共有三层，内外两层均为纺粘无纺布，中间的过滤层为熔喷无纺布。熔喷无纺布作为医用外科口罩与N95口罩的重要原材料，两者在用量上有区别，医用外科口罩一般为SMS结构(两层纺粘层S及一层熔喷层M)，而能过滤95％微细颗粒的N95口罩有时则需使用SMMMS无纺布(两层纺粘层S及三层熔喷层M)制作，熔喷布的用量大大高于普通口罩。
作为口罩的过滤层，熔喷无纺布显得至关重要，生产中可以通过增加熔喷层的层数以保证更好的抗菌阻隔性，但是，熔喷层过多会造成使用者呼吸比较困难，所以往往从口罩呼吸的难易程度来判断口罩的隔绝效果，呼吸越困难，则阻隔效果更好，例如实际应用中，N95的过滤效率优于医用外科口罩，但是使用者在佩戴过程中，会明显感到N95的呼吸阻力较大。如果熔喷层变为薄膜，病毒、细菌可以全部有效阻隔，但使用者感到呼吸阻力变大甚至无法呼吸，口罩的过滤效率如何也将无从谈起。
另外，现有技术中熔喷层多采用PP熔喷无纺布，这是一种超细静电纤维布，当粉尘、病毒和细菌遇到聚丙烯熔喷无纺布后，会被静电吸附在聚丙烯熔喷无纺布表面，无法透过，起到隔绝病菌的作用，但是粉尘、病毒和细菌被超细静电纤维捕捉住后，很难通过清洗而脱离，且 水洗会被破坏静电的吸尘能力，所以目前大多数口罩为一次性使用口罩，造成资源浪费。
因此，开发一种既能保障高过滤效率，又具备低通气阻力的滤芯，进而提高口罩的防护要求和佩戴舒适度，成为亟待解决的问题。
发明内容
本发明的目的之一在于：提供一种兼具高过滤效率高和低通气阻力性能的滤芯。
为了实现上述目的，本发明提供如下技术方案：
一种滤芯，包括微孔膜层，以及位于所述微孔膜层两侧的第一熔喷无纺布层和第二熔喷无纺布层；其中，所述第一熔喷无纺布层和第二熔喷无纺布层均采用多组份熔喷无纺布。
微孔膜是一种高分子膜，具有微孔结构，一般是孔径在5.0纳米～1.0毫米之间的多孔膜，因其多孔致密、膜结构均匀同时透气性好的特性，成为广为应用的新型过滤材料，作为滤芯的过滤膜层，在保持空气流通的同时，对空气中的颗粒、病菌有较好的隔绝作用；微孔膜层的两侧均设置有多组份熔喷无纺布层，一方面是作为支撑材料，用来避免微孔膜层在生产、运输或使用时出现破损，另一方面，多组份熔喷无纺布的静电吸附作用可以起到多层过滤作用，可以进一步增加滤芯的过滤效率。
进一步地，所述微孔膜层采用PTFE微孔膜；PTFE微孔分布均匀，是一种柔韧而富有弹性的微孔材料，膜层上存在无数肉眼不可见的小孔，这些小孔的孔径小，一般多为几个微米，甚至0.01个微米，孔隙率大，孔径分布均匀，具有透气不透水的特性，是作为滤芯的理想选择。
优选地，所述微孔膜层的孔径为1～5μm，该条件下的孔径既能保障微孔膜的过滤性能，又能保护良好的通气性能。
更为优选地，所述PTFE微孔膜层的厚度为2μm。
进一步地，所述多组份熔喷无纺布中包括PP和/或PE；PP是现有技术中常用的熔喷无纺布主要材质，它是一种超细静电纤维布，可以捕捉粉尘，含有病毒、细菌的飞沫靠近熔喷无纺布后，会被静电吸附在无纺布表面，无法透过，但是PP熔融指数越高，在高温下具有较高的流动性，容易堵塞微孔膜层上的微孔，导致通气阻力增加，故以PP为支撑材料，并通过控制熔喷无纺布中PP的体积占比，有助于在进一步提高滤芯过滤效率的同时不增加通气阻力的负担；而PE可以阻隔细菌粒子穿透和液体渗透，透气性好，效隔离水分，排出热气和湿气，舒适性能大大提高。
优选地，所述第一熔喷无纺布层和第二熔喷无纺布层均采用PP与PET双组份复合材料(用“PP/PET”示)的双组份熔喷无纺布或PE与PET双组份复合材料(用“PE/PET”表示)的 熔喷无纺布；PET具有优异的抗拉及延伸性能，能够有效支撑整个无纺布结构，PET的玻璃态转化温度相较于PE或PP都低，在适宜的温度下与PP或PE复合时，可以有效避免多组份熔喷无纺布粘附在热压器件上，大大节约能耗，提高生产效率。
更为优选地，所述PET在PP/PET或PE/PET双组份熔喷无纺布中的体积百分比为70～80％；研究中发现PP/PET或PE/PET双组份熔喷无纺布中PP或PE的体积占比过高时，容易粘附在电磁感应加热辊上，导致无法进行生产，而占过低时，复合牢固度很低，也无法应用。
可选择地，所述微孔膜层与第一熔喷无纺布层或第二熔喷无纺布层之间还包括银离子层，银离子为携带正电荷的阳离子，具有较强的氧化作用，实践经验证明，银离子对众多种类的致病细菌、真菌、霉菌、寄生虫和病毒能起致死的作用，在滤芯中设置银离子层，有助于提高滤芯的病菌过滤效率。
本发明的目的之二在于：提供一种上述滤芯的制备方法。
为了实现上述目的，本发明提供如下技术方案：
一种滤芯的制备方法，采用热复合工艺将所述第一熔喷无纺布层和第二熔喷无纺布层一次性复合在所述微孔膜层，经过一次热复合，一次成型。
进一步地，所述热复合工艺采用具有热辊的热复合机。
进一步地，所述热复合工艺条件为：热辊温度为110～160℃，热辊压力为150～200N/cm 2，热复合线速度为10～25m/min。
优选地，所述热复合工艺条件为：经过热复合机时，热辊温度为155℃，热辊压力为180N/cm 2，热复合线速度为20m/min。
本发明的目的之三在于：提供一种口罩，使之具备过滤效率高且通气阻力低的功能和性能。
为了实现上述目的，本发明提供如下技术方案：
一种口罩，包括上述滤芯或具有采用所述制备方法制备的滤芯。
可选择地，上述滤芯还可以用于制备防护面罩或其他具有过滤作用的防护用品或过滤装置。
本发明的有益效果在于：
1.本发明的滤芯采用粒径为1～5μm的PTFE微孔膜层作为核心过滤层，PP/PE、PE/PET、PP/PE/PET等多组份熔喷无纺布作为支撑材料，复合在PTFE微孔膜层的两侧，利用微孔材料的多孔结构，孔径分布均匀，透气性好等特性为该滤芯的过滤效率提供很好的保障；利用多组 份熔喷无纺布的复合材料性能，在保护微孔膜不受损的作用下减少了该滤芯的通气阻力；多层过滤也进一步提高了该滤芯的过滤效率。由该滤芯制备的口罩的过滤效率均能达到95％以上，吸气阻力可低至16.9Pa，兼具有高过滤效率和低通气阻力的优异性能。
2.本发明提供的滤芯的制备方法，利用具有热辊的热复合机，合理控制热辊的工作条件，无需任何胶黏剂，仅经过一次热复合压力便可一次成型，相较于常见的需要经过两次热复合的工艺，多组份熔喷无纺布的熔融流动区域显著减小，该工艺可以显著减少微孔膜两侧的多组份复合材料的熔融流动区域，减少微孔膜层的堵塞，因此，利用本发明双侧同时热复合使其一次成型的滤芯有更低的通气阻力，此外，仅经过一次热压处理还可以有效减少微孔膜在多次高温下易产生破损的问题。
3.由于PTFE微孔膜自身还具有透气不透水的特性，经得起水洗、消毒等处理，包括本发明滤芯或具有采用本发明制备方法制备的滤芯的口罩具有可重复使用的优势，经过二次水洗后的过滤效率仍然可以达到95％以上，延长了口罩使用的寿命，可大大节约资源。
具体实施方式
实施例1
一种滤芯，包括粒径为1μm的PTFE微孔膜层，以及位于所述微孔膜层两侧的第一熔喷无纺布层和第二熔喷无纺布层；
第一熔喷无纺布层和第二熔喷无纺布层均为PE/PET双组份熔喷无纺布；
其中，PE/PET双组份熔喷无纺布中PE与PET的体积比为2：8；
上述滤芯的制备方法如下：采用具有热辊的热复合机将所述第一熔喷无纺布层和第二熔喷无纺布层一次性复合在所述微孔膜层的两侧。其中，热复合工艺条件为：材料经过热复合机时热辊温度为110℃，热辊压力为150N/cm 2，热复合线速度为10m/min；
使用上述滤芯，采用现有技术中的常规方法制得口罩。
实施例2
一种滤芯，包括粒径为2μm的PTFE微孔膜层，以及位于所述微孔膜层两侧的第一熔喷无纺布层和第二熔喷无纺布层；
第一熔喷无纺布层和第二熔喷无纺布层均为PP/PET双组份熔喷无纺布；
其中，PP/PET双组份熔喷无纺布中PP与PET的体积比为2.5：7.5；
上述滤芯的制备方法如下：采用具有热辊的热复合机将所述第一熔喷无纺布层和第二熔喷无纺布层一次性复合在所述微孔膜层的两侧。其中，热复合工艺条件为：材料经过热复合机时热辊温度为155℃，热辊压力为180N/cm 2，热复合线速度为20m/min；
使用上述滤芯，采用现有技术中的常规方法制得口罩。
实施例3
一种滤芯，包括粒径为3μm的PTFE微孔膜层，以及位于所述微孔膜层两侧的第一熔喷无纺布层和第二熔喷无纺布层；
第一熔喷无纺布层为PE/PET双组份熔喷无纺布；第二熔喷无纺布层为PP/PET双组份熔喷无纺布；
其中，PE/PET双组份熔喷无纺布中PP与PET的体积比为3：7：PP/PET双组份熔喷无纺布中PP与PET的体积比为2：8；
上述滤芯的制备方法如下：采用具有热辊的热复合机将所述第一熔喷无纺布层和第二熔喷无纺布层一次性复合在所述微孔膜层的两侧。其中，热复合工艺条件为：材料经过热复合机时热辊温度为125℃，热辊压力为190N/cm 2，热复合线速度为15m/min；
使用上述滤芯，采用现有技术中的常规方法制得口罩。
实施例4
一种滤芯，包括粒径为5μm的PTFE微孔膜层，以及位于所述微孔膜层两侧的第一熔喷无纺布层和第二熔喷无纺布层；
第一熔喷无纺布层和第二熔喷无纺布层均为PP/PE/PET三组份熔喷无纺布；
其中，PP/PE/PET三组份熔喷无纺布中的体积比一次为2：1：7；
上述滤芯的制备方法如下：采用具有热辊的热复合机将所述第一熔喷无纺布层和第二熔喷无纺布层一次性复合在所述微孔膜层的两侧。其中，热复合工艺条件为：材料经过热复合机时热辊温度为160℃，热辊压力为200N/cm 2，热复合线速度为25m/min；
使用上述滤芯，采用现有技术中的常规方法制得口罩。
对比例1
参照实施例2的制备条件，不同的是，PTFE微孔膜层的粒径为10μm。
对比例2
参照实施例2的制备条件，不同的是，PP/PET双组份熔喷无纺布的体积比为4：6。
对比例3
参照实施例2的制备条件，不同的是，热复合工艺条件为：先将第一熔喷无纺布层复合在PTFE微孔膜层的一侧，再将第二熔喷无纺布层复合在PTFE微孔膜层的另一侧。
市售样品
市售的医用N95口罩。
按照GB19083-2010《医用防护口罩技术要求》标准，在空气流量(85±2)L/min条件下，进行相应产品的过滤效率和吸气阻力性能进行测试，测试结果如表1。
表1 本发明实施例和对比例性能测试结果
项目 吸气阻力(Pa) 0.1μm～0.2μm 0.2μm～0.3μm 0.3μm～0.5μm
实施例1 16.9Pa ≥95 ≥95 ≥99
实施例2 26.2Pa ≥95 ≥99 ≥99
实施例3 79.2Pa ≥95 ≥99 ≥99
实施例4 151.5Pa ≥99.97 ≥99.97 ≥99.97
对比例1 431.3Pa ≥99.97 ≥99.97 ≥99.97
对比例2 —— —— —— ——
对比例3 357.1Pa ≥99.97 ≥99.97 ≥99.97
市售样品 175.4Pa ≥95 ≥95 ≥95
由表1中实施例1～4和对比例1～2性能测试结果可以看出，本发明条件下制备的口罩的过滤效率均在95％以上，达到市售的医用N95口罩的水平，同时，各实施例的吸气阻力也显著低于市售样品，达到了高滤过效率和低通气阻力的效果；与实施例2相比，对比例1采用了粒径为10μm的PTFE微孔膜，虽然过滤效率均高于99.97％，达到了3级过滤等级，但是也严重增加了吸气阻力，这将导致口罩无法正常使用；对比例2采用的PP/PET双组份熔喷无纺布的体积比为4：6，生产中发现部分熔喷无纺布会粘附在热辊上，导致无法正常生产；对比例3则是通过前后两次热复合分别将第一熔喷无纺布和第二熔喷无纺布复合在PTFE微孔膜的两侧，两次高温热压处理造成PP/PE的熔融流程区域增大，导致PTFE微孔膜的堵塞，最终致使口罩的吸气阻力显著增加。
水洗后口罩性能的对比实验
实验组：本发明实施例2制备的口罩；
对照组：市售的医用N95口罩；
实验方法：在相同条件下，将口罩放入清水中清洗5min，自然晾干后测试口罩的性能，测试后再重复上述过程1次，实验结果如表2所示。
表2 水洗后口罩性能对比结果
Figure PCTCN2020082817-appb-000001
从表2水洗后口罩性能对比结果可以看出，以静电吸附熔喷布发挥主要过滤作用的市售的医用N95口罩，在水洗之后过滤效率显著下降，而本发明实施例2制备的口罩的过滤效率仍然可以保持在95％以上，说明本发明提供的口罩耐水洗，在合理的水洗之后，能够重复使用，可以大大节约口罩资源。

Claims (10)

  1. 一种滤芯，其特征在于：包括微孔膜层，以及位于所述微孔膜层两侧的第一熔喷无纺布层和第二熔喷无纺布层；
    其中，所述第一熔喷无纺布层和第二熔喷无纺布层均采用多组份熔喷无纺布。
  2. 根据权利要求1所述的一种滤芯，其特征在于：所述微孔膜层采用PTFE微孔膜。
  3. 根据权利要求2所述的一种滤芯，其特征在于：所述PTFE微孔膜的孔径为1～5μm；
  4. 根据权利要求1～3任一项所述的一种滤芯，其特征在于：所述多组份熔喷无纺布包括PP和/或PE。
  5. 根据权利要求4所述的一种滤芯，其特征在于：所述第一熔喷无纺布层和第二熔喷无纺布层均采用PP/PET或PE/PET双组份熔喷无纺布；所述PET在所述PP/PET或PE/PET双组份熔喷无纺布中的体积百分比为70～80％。
  6. 一种如权利要求4所述的滤芯的制备方法，其特征在于：采用热复合工艺将所述第一熔喷无纺布层和第二熔喷无纺布层一次性复合在所述微孔膜层的两侧。
  7. 根据权利要求5所述的一种滤芯的制备方法，其特征在于：所述热复合工艺采用具有热辊的热复合机；所述热复合工艺条件为：所述热辊温度为110～160℃，热辊压力为150～200N/cm 2，热复合线速度为10～25m/min。
  8. 根据权利要求6所述的一种滤芯的制备方法，其特征在于：所述热复合工艺条件为：所述热辊温度为155℃，热辊压力为180N/cm 2，热复合线速度为20m/min。
  9. 一种口罩，其特征在于：包括权利要求4所述的滤芯。
  10. 一种口罩，其特征在于：具有采用权利要求6～8任一项所述的制备方法制备的滤芯。
PCT/CN2020/082817 2020-03-09 2020-04-01 一种滤芯及其制备方法和口罩 WO2021179369A1 (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN202010158052.7 2020-03-09
CN202010158052.7A CN111330356A (zh) 2020-03-09 2020-03-09 一种滤芯及其制备方法和口罩

Publications (1)

Publication Number Publication Date
WO2021179369A1 true WO2021179369A1 (zh) 2021-09-16

Family

ID=71174298

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2020/082817 WO2021179369A1 (zh) 2020-03-09 2020-04-01 一种滤芯及其制备方法和口罩

Country Status (2)

Country Link
CN (1) CN111330356A (zh)
WO (1) WO2021179369A1 (zh)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111907085A (zh) * 2020-07-28 2020-11-10 江苏康隆迪超净科技有限公司 一种熔喷布覆膜ptfe复合新材料及其制备工艺
CN112626717A (zh) * 2020-10-20 2021-04-09 美洁纳米科技(苏州)有限公司 抗菌、抗病毒的一价铜-碳复合无纺布及其制备方法和应用

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103230707A (zh) * 2013-04-27 2013-08-07 中材科技股份有限公司 一种净化pm2.5口罩专用覆膜无纺布及其制备方法
CN203264448U (zh) * 2013-04-27 2013-11-06 中材科技股份有限公司 一种净化pm2.5口罩专用覆膜无纺布
CN204973323U (zh) * 2015-08-25 2016-01-20 上海市凌桥环保设备厂有限公司 复合滤材及低阻力复合滤纸
CN206760826U (zh) * 2017-04-24 2017-12-19 佛山市高科合创科技有限公司 一种可更换滤芯的防pm2.5口罩及其滤芯
CN109228569A (zh) * 2018-08-08 2019-01-18 蚌埠市明威滤清器有限公司 一种用聚四氟乙烯微孔膜-熔喷非织造材料制备滤清器用复合高效滤材的方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090107922A1 (en) * 2007-10-26 2009-04-30 General Electric Company Membrane, water treatment system, and associated method
CN103768867B (zh) * 2013-12-27 2016-05-18 杭州大立过滤设备有限公司 卷绕式深层过滤滤芯及滤芯的卷绕装置
CN107264000A (zh) * 2017-07-26 2017-10-20 太仓市梓怡纺织有限公司 一种熔喷无纺布与纳米纤维的复合方法
CN107754449A (zh) * 2017-10-21 2018-03-06 浙江华基环保科技有限公司 一种复合非织造过滤材料及其制备方法
CN109011918B (zh) * 2018-08-01 2021-01-08 太仓安佑无纺科技有限公司 一种口罩中间夹层过滤材料的制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103230707A (zh) * 2013-04-27 2013-08-07 中材科技股份有限公司 一种净化pm2.5口罩专用覆膜无纺布及其制备方法
CN203264448U (zh) * 2013-04-27 2013-11-06 中材科技股份有限公司 一种净化pm2.5口罩专用覆膜无纺布
CN204973323U (zh) * 2015-08-25 2016-01-20 上海市凌桥环保设备厂有限公司 复合滤材及低阻力复合滤纸
CN206760826U (zh) * 2017-04-24 2017-12-19 佛山市高科合创科技有限公司 一种可更换滤芯的防pm2.5口罩及其滤芯
CN109228569A (zh) * 2018-08-08 2019-01-18 蚌埠市明威滤清器有限公司 一种用聚四氟乙烯微孔膜-熔喷非织造材料制备滤清器用复合高效滤材的方法

Also Published As

Publication number Publication date
CN111330356A (zh) 2020-06-26

Similar Documents

Publication Publication Date Title
CN111235756B (zh) 一种新型防尘、抗菌、抗病毒纳米纤维口罩
US20110232653A1 (en) Antimicrobial, dustproof fabric and mask
EP3237088A1 (en) Protective masks with coating comprising different electrospun fibers interweaved with each other, formulations forming the same, and method of producing thereof
CN202445177U (zh) 一种可有效过滤pm2.5的口罩滤片
CN105771421A (zh) 一种过滤口罩用无纺布复合材料
WO2021179369A1 (zh) 一种滤芯及其制备方法和口罩
JP2008188082A (ja) マスク
CN111974088B (zh) 一种滤材的制作方法
CN111775520A (zh) 一种过滤口罩用无纺布复合材料
JP3236878U (ja) 多機能布及び多機能マスク
JP2005124777A (ja) 感染予防マスク
CN203425408U (zh) 一种口罩或鼻罩用的抑菌防尘层状结构
TWM605981U (zh) 具微多孔薄膜與抗病毒不織布結合成形之複合材料
CN111616450A (zh) 一种非医用纳米膜过滤口罩
Wang et al. Reusable electrospun nanofibrous membranes with antibacterial activity for air filtration
CN203290258U (zh) 一种多功能防护口罩
KR102606143B1 (ko) 항바이러스 필터여재, 이를 포함하는 에어필터 유닛 및 공조장치
KR20140002111A (ko) 바이러스 살균 필터 및 이를 이용한 마스크
CN205682517U (zh) 一种ct触媒口罩
CN212814481U (zh) 一种抗菌、抗病毒、可多次重复使用的高性能防护口罩
CN213663797U (zh) 一种电子杀菌口罩
WO2021189762A1 (zh) 一种聚四氟乙烯复合过滤材料
CN213404957U (zh) 一种口罩
CN203710564U (zh) 一种防雾霾抑菌口罩滤片
CN111165939A (zh) 一种负离子抗菌防霾口罩

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 20924597

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 20924597

Country of ref document: EP

Kind code of ref document: A1