WO2021171222A1 - Dry shampoo composition - Google Patents
Dry shampoo composition Download PDFInfo
- Publication number
- WO2021171222A1 WO2021171222A1 PCT/IB2021/051584 IB2021051584W WO2021171222A1 WO 2021171222 A1 WO2021171222 A1 WO 2021171222A1 IB 2021051584 W IB2021051584 W IB 2021051584W WO 2021171222 A1 WO2021171222 A1 WO 2021171222A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- dry shampoo
- hair
- shampoo composition
- dry
- composition
- Prior art date
Links
- 239000002453 shampoo Substances 0.000 title claims abstract description 251
- 239000000203 mixture Substances 0.000 title claims abstract description 232
- 210000004209 hair Anatomy 0.000 claims abstract description 145
- 239000003086 colorant Substances 0.000 claims abstract description 38
- 229920002472 Starch Polymers 0.000 claims abstract description 24
- 239000002318 adhesion promoter Substances 0.000 claims abstract description 24
- 235000019698 starch Nutrition 0.000 claims abstract description 23
- 239000008107 starch Substances 0.000 claims abstract description 22
- 239000003380 propellant Substances 0.000 claims abstract description 16
- 239000003205 fragrance Substances 0.000 claims abstract description 11
- 239000002904 solvent Substances 0.000 claims abstract description 5
- 238000004040 coloring Methods 0.000 claims abstract 3
- 239000002245 particle Substances 0.000 claims description 66
- 239000000463 material Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 18
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 12
- 239000003093 cationic surfactant Substances 0.000 claims description 7
- 239000003208 petroleum Substances 0.000 claims description 7
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- 229940100486 rice starch Drugs 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 abstract description 6
- 239000004615 ingredient Substances 0.000 abstract description 4
- 238000009472 formulation Methods 0.000 description 59
- 230000003750 conditioning effect Effects 0.000 description 15
- 230000001680 brushing effect Effects 0.000 description 14
- 230000000694 effects Effects 0.000 description 14
- 230000005923 long-lasting effect Effects 0.000 description 11
- 238000002835 absorbance Methods 0.000 description 10
- 239000003921 oil Substances 0.000 description 10
- 235000019198 oils Nutrition 0.000 description 10
- 238000007619 statistical method Methods 0.000 description 10
- 239000000443 aerosol Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 230000008901 benefit Effects 0.000 description 7
- 239000000835 fiber Substances 0.000 description 7
- 235000019441 ethanol Nutrition 0.000 description 6
- 229940095673 shampoo product Drugs 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 239000003974 emollient agent Substances 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 239000013068 control sample Substances 0.000 description 4
- 206010019049 Hair texture abnormal Diseases 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000002596 correlated effect Effects 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- -1 C12 alkane Chemical class 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 229940008099 dimethicone Drugs 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 2
- 229940073551 distearyldimonium chloride Drugs 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- 239000001062 red colorant Substances 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 244000303965 Cyamopsis psoralioides Species 0.000 description 1
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 101150049278 US20 gene Proteins 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 229920013822 aminosilicone Polymers 0.000 description 1
- 239000010478 argan oil Substances 0.000 description 1
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 1
- 229940075506 behentrimonium chloride Drugs 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 150000001767 cationic compounds Chemical class 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 229940099112 cornstarch Drugs 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 231100000640 hair analysis Toxicity 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical class C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- WJBRBPDFVDNVRL-UHFFFAOYSA-N propane;1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound CCC.FC(F)(F)C(Cl)(Cl)Cl WJBRBPDFVDNVRL-UHFFFAOYSA-N 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 229940100445 wheat starch Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/31—Anhydrous
Definitions
- the present disclosure relates to compositions for cleaning hair, and more particularly to a dry shampoo composition.
- This disclosure relates to a natural, dry shampoo and conditioning composition capable of providing longer lasting color effect and imparting superior cleaning and conditioning ability on hair.
- Dry hair cleaning compositions for the rapid cleansing of hair are well known Dry shampoo can be defined as a shampoo in a powder form, used without the addition of water. These known compositions can be used on dry hair in order to freshen up the hair and/or to remove excess oils and other undesirables found on dirty hair. These known compositions are particularly useful when time is short and one cannot wash the hair using wet shampoo.
- a common conventional format of dry shampoo is a composition in the form of an aerosol.
- the aerosol is sprayed into the roots of the hair, massaged in, and combed, a process which can be done very quickly due to the no-rinse formulation.
- the powders used in dry shampoos are conventionally a starch or starch derivative. Although different starches offer different claimed benefits, they all come to the same end result: quick hair cleaning.
- Dry shampoo compositions are well known to the market. See, e.g., PCT/US20 17/064721 and U.S. Pat. Appl. No. 15/796,884 filed Oct. 30, 2017 to Henkel AG & Co., which are herein incorporated by reference.
- Many conventional dry shampoo compositions have the drawback that the powder applied to the hair leaves a white/off-white residue after use, which is a negative experience for the consumer with standard non-colored dry shampoos.
- a consumer may choose to use a colored dry shampoo product
- Colored dry shampoo can be defined as a dry shampoo with colored powder, used without the addition of water.
- a colored dry shampoo product can be designed for covering gray/white hairs and roots with different color than the main body of hair for different color hairs.
- many conventional colored dry shampoo compositions do not provide a long-lasting color effect because the dry shampoo is coming off the hair more quickly than desired. This problem has been addressed in certain conventional colored dry shampoo compositions by using standard silicone technology used in many conventional hair care products. Mary of these products comprise dimethicone(silicone).
- a dry shampoo composition comprising a starch material, a color adhesion promoter, particularly a long chain alkane, and optionally a propellant.
- the dry shampoo composition can further comprise a fragrance, for example.
- the dry shampoo is substantially free of silicones.
- the dry shampoo is substantially free of petroleum-based cationic surfactants.
- the color adhesion promoter comprises a C 13 -C 15 alkane. In some embodiments, the color adhesion promoter comprises hemisqualane.
- the starch material of the dry shampoo composition can comprise a rice starch, for example.
- the dry shampoo composition can comprise at least 0.1 weight percent of the starch material, based on the total weight of the dry shampoo composition; at least 0.1 weight percent of the color adhesion promoter, based on the total weight of the dry shampoo composition; and at least 50 weight percent of the propellant, based on the total weight of the dry shampoo composition.
- the dry shampoo composition can comprise about 1 to about 12 weight percent of the starch material, based on the total weight of the dry shampoo composition; about 1 to about 12 weight percent of the color adhesion promoter, based on the total weight of the dry shampoo composition; and about 40 to about 95 weight percent of the propellant, based on the total weight of the dry shampoo composition.
- the present disclosure also relates to a method of cleansing and conditioning hair.
- the method can comprise applying a dry shampoo composition according to the present disclosure to the hair.
- the method can comprise spraying or sprinkling the dry shampoo composition on the hair and combing the dry shampoo composition through the hair.
- the dry shampoo composition can particularly be effective to provide long-lasting color application to the hair.
- FIG. 1 is a plot of the quantity of shampoo particles remaining in a hair sample by number of combings after treatment of hair with different dry shampoo compositions
- FIGs. 2A-B are high resolution image of natural white hair tresses after different dry shampoo formulations have been applied thereto;
- FIG. 3 is a series of high resolution images of a hair tress treated with a colored dry shampoo control formulation after several combings of the treated tress;
- FIG. 4 is a series of high resolution images of a hair tress treated with a colored dry shampoo formulation according to an embodiment the present disclosure after several combings of the treated tress;
- FIG. 5 is a plot of the Luminance evolution after combing for several samples treated with different colored dry shampoo compositions
- FIG. 6 is a plot of the quantity of dry shampoo particles after combing for several samples treated with different colored dry shampoo compositions
- FIG. 7 is a plot of the average hair tress weight after combing for several samples treated with different colored dry shampoo compositions
- FIG. 8 is a plot showing the average dry shampoo weight proportion after combing for several samples treated with different colored dry shampoo compositions
- FIG. 9 is a plot showing the correlation between Absorbance and Weight for a control formulation after different numbers of combings
- FIG. 10 is a plot showing the correlation between Absorbance and Weight for a formulation according to an embodiment of the dry shampoo compositions described herein after different numbers of combings.
- FIG. 11 is a graph showing the evolution of the mean heterogeneity parameter after each combing on hair tresses treated with a control dry shampoo formulation and for hair tresses treated with a dry shampoo formulation according to an embodiment of the present disclosure.
- a dry shampoo composition which can be topically applied to hair.
- dry shampoo composition is understood to relate to a product that is effective to cleanse hair without any necessity for rinsing with water following application.
- Wet shampoo compositions are understood to be applied to wet hair, lathered, and then rinsed away with added water.
- a dry shampoo composition can be applied to hair and then optionally be brushed through the hair with the fingers or a utensil (e.g., a comb or brush) to effect the cleansing effect. No rinsing with water is required.
- a certain amount of liquid components may be included in a dry shampoo composition.
- a dry shampoo composition as disclosed herein comprises less than 5 weight percent, less than 2 weight percent, less than 1 weight percent, or less than 0.1 weight percent of an aqueous component, particularly water, based on the total weight of the dry shampoo composition.
- the dry shampoo composition can be sprinkled into the hair, or may be sprinkled into a user’s hands and then applied to the hair.
- the dry shampoo composition can be in the form of an aerosol which can be sprayed onto the hair of a user.
- the applied composition can be distributed through the hair by massaging into the hair, for example, in order to remove grease, oil and other undesirable elements from soiled hair. Any excess or residual dry shampoo composition powder can be removed from the hair by combing or brushing the hair, for example.
- the dry shampoo composition may leave little or no visible residue in the hair after application.
- the dry shampoo composition can include a plurality of components including, but not limited to, compounds for oil absorption, color adhesion promoters, and emollients.
- the diy shampoo composition can further include additional components such as fragrances, color additives, propellants, natural oil (e.g., coconut oil or argan oil), synthetic oil, and the like.
- a dry shampoo composition of the present disclosure can comprise one or more of each type of component. However, each type of component is not necessarily present in different embodiments of the dry shampoo compositions described herein.
- the dry shampoo composition can comprise a cleaning agent useful for removing (e.g., absorbing) oil, grease, and other undesirable elements from hair.
- the dry shampoo composition can comprise at least one starch material that is effective to absorb at least a portion of arty oils present on hair.
- Starch materials useful in the present disclosure include cornstarch, potato starch, tapioca starch, rice starch, wheat starch, cassaya starch, and combinations thereof.
- the dry shampoo composition comprises rice starch.
- a starch material can be modified (e.g., through processes such as esterification, etherification, oxidation, acid hydrolysis, crosslinking, or enzyme conversion) or unmodified.
- the weight percentage of starch material in the dry shampoo composition can be about 0.1% to about 15%, about 1% to about 12%, about 2% to about 10%, or about 4% to about 8%. In certain embodiments, the weight percentage of starch material in the dry shampoo composition, based on the total weight of the dry shampoo composition, can be at least about 0.1%, at least about 1%, or at least about 4%, preferably with an upper range limit of about 50% by weight.
- the dry shampoo composition can comprise at least one colorant effective for imparting color to hair.
- the colorant(s) can be in powdered form. Any hair colorant known in the art can be used in the dry shampoo compositions described herein for example, the colorant can be a blonde colorant, a brunette colorant, a red colorant, a light colorant, a dark colorant, etc.
- the weight percentage of the colorant(s) in the dry shampoo compositions can be about 0.01% to about 5%, about 0.05 to about 2%, or about 0.5 to about 1.5%. In certain embodiments, the weight percentage of the colorant(s) in the dry shampoo composition, based on the total weight of the dry shampoo composition, can be at least about 0.01%, at least about 0.05%, or at least about 1%, preferably with an upper limit of about 5% by weight
- the dry shampoo composition can comprise a coloring agent formed of a mixture of a starch material and a colorant effective for imparting color to hair.
- the starch material and the colorant which can also be in powdered form, can be blended and then passed through a pin mill for example, which effectively pulverizes the blend together to provide a uniform mix of color and starch materials.
- Any hair colorant known in the art can be mixed with the starch material.
- the colorant can be a blonde colorant, a brunette colorant, a red colorant, a light colorant, a dark colorant, etc.
- the weight ratio of starch material to colorant within the mixture can be in the range of about 4:1 to about 1:0, or about 9:1 to about 1:0.
- the dry- weight percentage of the starch material based on the total weight of the coloring agent (i.e., the mixture of starch material and colorant), is at least about 85%, at least about 90% at least about 95%, or at least about 98%, preferably with an upper range limit of about 99% by weight.
- the weight percentage of the coloring agent in the dry shampoo compositions can be about 0.01% to about 5% about 0.05 to about 2% or about 0.5 to about 1.5%. In certain embodiments, the weight percentage of the coloring agent in the dry shampoo composition, based on the total weight of the dry shampoo composition, can be at least about 0.01% at least about 0.05% or at least about 1% preferably with an upper limit of about 5% by weight.
- the dry shampoo composition can comprise at least one color adhesion promoter useful for increasing the adhesion of color (e.g., in the form of at least one colorant or a coloring agent as described above) to hair.
- a long chain alkane can significantly increase the adhesion of a colored dry shampoo composition to treated hair.
- a long chain alkane is at least a C 10 alkane or at least a C 12 alkane, preferably up to a C 40 alkane.
- the dry shampoo composition can comprise a color adhesion promoter in the form of a C 13 -C 15 alkane.
- the color adhesion promoter comprises a squalane and/or one or more derivatives thereof, particularly hemisqualane.
- hemisqualane has a high degree of spread ability, which translates into very good film forming activity evenly coating the hair fiber, thereby resulting in good conditioning performance (slip/combing, static reduction, etc.). Volumizing effects have also been demonstrated with hemisqualane, indicating that there are definite attractions between the hydrophobic regions of the interior of the hair fiber and hemisqualane, causing the migration of it from the surface. It was surprisingly found that these properties enhance adherence of the colorant(s) and/or the starch/colorant mixtures described herein to the hair fibers.
- the weight percentage of the color adhesion promoters) in the dry shampoo composition can be about 0.1% to about 15%, about 1% to about 12% about 2% to about 10% or about 0.1% to about 2%.
- the weight percentage of the color adhesion promoters) in the diy shampoo composition can be at least about 0.1%, at least about 1% or at least about 4% preferably with an upper limit of about 50% by weight.
- the dry shampoo composition can comprise can comprise an emollient useful for moisturizing the hair and thus acting as a conditioning/anti-static agent. Conditioning can separately mean providing a moisturizing effect to the hair and/or providing softness and smoothness to the hair.
- long chain alkanes as described herein above, can function as a conditioning agent in addition to a color adhesion promoter. However, for the purposes of the present disclosure, long chain alkanes are classified herein as color adhesion promoters.
- Conditioning agents known in the art include, but are not limited to, silicones (e.g., phenyl trimethicones, dimethicones, cyclomethicones, dimethicone copolyols, amino silicones, etc.), petroleum-based cationic surfactants, distearyldimonium chloride, guar compounds including cationic polymers and guar gum, poly cationic compounds designated as polyquatemium 4, 6, 7,
- conditioning agents may provide other functions, such as being a solvent or a flow aid. Preferably, any such conditioning agents are present only in minor concentrations.
- conditioning agents can be expressly excluded from the dry shampoo composition.
- the dry shampoo composition can be substantially free of conditioning agents. As used herein, the term “substantially free of’ means that the specified component is present in an amount of less than 0.1 percent by weight, based on the total weight of the composition.
- the dry shampoo composition can be entirely free of conditioning agents, meaning that not even trace amounts of conditioning agents are present in the dry shampoo composition beyond the one or more long chain alkanes described herein above, which can also function as a hydrophobic emollient.
- the dry shampoo composition is substantially or entirely free of silicones and/or petroleum-based cationic surfactants.
- the term “petroleum-based cationic surfactants” refers to cationic surfactants that are derived from or which include petroleum, and such surfactants can be expressly excluded from the composition.
- cctrimonium chloride or behentrimonium chloride are quaternary ammonium compounds. These compounds are prepared by the alkylation of tertiary amines with a halocarbon/hydrocarbon. As is known in the art, hydrocarbons are (mainly) petroleum-based. In some embodiments, the dry shampoo composition is substantially or entirety free of distearyldimonium chloride, for example.
- the weight percentage of the emollient(s) in the dry shampoo composition can be about 0.1% to about 15%, about 1% to about 12%, about 2% to about 10%, or about 4% to about 8%. In certain embodiments, the weight percentage of emollient(s) in the dry shampoo composition, based on the total weight of the dry shampoo composition, can be at least about 0.1%, at least about 1%, or at least about 4%, preferably with an upper limit of about 50% by weight.
- the dry shampoo composition can comprise at least one alcohol.
- the alcohol can be used as a base to dissolve other ingredients (e.g., the at least one color adhesion promoter and/or the at least one conditioning/anti-static agent) in order to provide better adhesion and refreshment of the dry shampoo composition to the treated hair.
- the alcohol can be ethyl alcohol.
- the weight percentage of alcohol(s) in the dry shampoo composition can be about 0.1% to about 15%, about 1% to about 12%, about 2% to about 10%, or about 4% to about 8%. In certain embodiments, the weight percentage of alcohol(s) in the dry shampoo composition, based on the total weight of the dry shampoo composition, can be at least about 0.1%, at least about 1%, or at least about 4% preferably with an upper limit of about 20% by weight
- the dry shampoo composition can comprise at least one fragrance.
- a fragrance can be provided in the form of an essential oil.
- the weight percentage of one or more fragrances in the dry shampoo composition, based on the total weight of the dry shampoo composition can be about 0.01% to about 3%, about 0.1% to about 2%, or about 0.1% to about 1%.
- the weight percentage of a fragrance in the dry shampoo composition, based on the total weight of the dry shampoo composition can be at least about 0.01%, at least about 0.1%, or at least about 1%, preferably with an upper limit of about 10% by weight.
- the dry shampoo composition can further include at least one additive useful for adding volume to the treated hair, providing color protection of the treated hair, providing sebum control of the treated hair, providing UV protection of the treated hair, providing frizz control of the treated hair, adding/adjusting texture of the treated hair, and/or enhancing styling of the treated hair.
- the at least one additive can be in the form of an extract.
- the weight percentage of one or more additives in the dry shampoo composition can be about 0.01% to about 3%, about 0.1% to about 2%, or about 0.1% to about 1 %. In certain embodiments, the weight percentage of an additive in the dry shampoo composition, based on the total weight of the dry shampoo composition, can be at least about 0.01%, at least about 0.1%, or at least about 1%, preferably with an upper limit of about 10% by weight
- a dry shampoo composition is provided as an aerosol (e.g., an aerosol diy shampoo composition) and can comprise at least one propellant.
- propellants include butane, isobutane, propane, liquefied petroleum gas, dimethyl ether, trichlorofluoromethane, dichlorodifluoromethane, dichlorotetrafluoro thane, monochlorodifluoromethane, trichlorotrifluoroethane propane, carbon dioxide, nitrous oxide, and combinations thereof.
- propellants include butane, isobutane, propane, liquefied petroleum gas, dimethyl ether, trichlorofluoromethane, dichlorodifluoromethane, dichlorotetrafluoro thane, monochlorodifluoromethane, trichlorotrifluoroethane propane, carbon dioxide, nitrous oxide, and combinations thereof.
- aerosol dry shampoo composition refers to a composition comprising a
- a dry shampoo composition When a dry shampoo composition is provided as an aerosol as compared to a powder, it may advantageously allow for the dry' shampoo composition to be applied in a diffusive manner, and may increase the transparency of the dry shampoo composition when compared to powder application. After spraying the aerosol dry shampoo composition onto the hair, the propellant in the dry shampoo composition evaporates and a dry powder remains.
- the weight percentage of the propellant in the dry shampoo composition can be about 20% to about 98%, about 40% to about 95%, or about 76% to about 90%.
- the weight percentage of carrier material in the dry shampoo composition can be at least about 20%, at least about 40%, at least about 60%, or at least about 80%, preferably with an upper limit of about 98% by weight.
- the present dry shampoo composition not only provides a cleansing effect but also provides long- lasting color effect to the treated hair.
- the dry shampoo compositions described herein can be designed for covering gray/white hairs and/or hair roots with different color than the color of the main body of hair.
- a method of preparing a dry shampoo product can comprise providing a delivery container, adding an oil absorbing agent mixed with at least one colorant to the delivery container, adding a color adhesion promoter to the container (separately or in combination with a fragrance), and adding a propellant to the delivery container.
- the method of preparing a dry shampoo product can comprise providing a delivery container, adding a color adhesion promoter to the container (separately or in combination with a fragrance), adding an oil absorbing agent mixed with at least one colorant to the delivery container, and adding a propellant to the delivery container.
- the method of preparing a dry shampoo product can comprise providing a delivery container, adding a dry shampoo composition to the container, and adding a propellant to the delivery container, wherein the dry shampoo composition comprises a color adhesion promoter, optionally a fragrance, an oil absorbing agent, and a colorant.
- a colored dry shampoo composition according to the present disclosure was prepared.
- the composition is provided in Table 1 (with weight percentage ranges being based on the total weight of the respective dry shampoo composition).
- Table 1 Composition of the Colored Dry Shampoo Composition of the Present Disclosure
- each ingredient in phase A was added and mixed.
- each ingredient in phase B was added and mixed.
- a product dispensing can was then filled with mixed phase B.
- the product dispensing can was then filled with mixed phase A.
- Phase C was added to the dispensing can via a gassing hose.
- Example 2 Product testing showed that the dry shampoo gave hair a cleaner feeling and look after use, and that the dry shampoo worked in a short period of time and was quick/efficient to use.
- the dry shampoo composition also provided long-lasting color effect, as described in more detail in Example 2 below.
- a sample dry shampoo composition was prepared according to Example 1 above.
- a control sample was also prepared for comparison purposes.
- the control formula was prepared according to the method outlined in Example 1 above, except the control formula does not include any hemisqualanes.
- the control composition is provided in Table 2 (with weight percentage ranges being based on the total weight of the respective dry shampoo composition).
- Table 2 Composition of the Colored Dry Shampoo Control Composition
- instrumental deposition analysis was used to analyze the long-lasting benefit of the two formulas.
- high resolution images of natural white hair tresses were captured.
- each of the Example 1 formula and the control formula were applied to separate white hair tress samples.
- High resolution images of the treated hair tresses were captured after application of the dry shampoo formulas.
- FIG. 2(a) is a high resolution image of natural white hair tresses after the control formula has been applied thereto.
- FIG. 2(b) is a high resolution image of natural white hair tresses after the Example 1 formula has been applied thereto.
- FIG. 3 is a series of the high resolution images captured for the hair tress treated with the colored dry shampoo control formulation after the combings of the treated tress.
- FIG. 4 is a series of the high resolution images of the hair tress treated with a colored dry shampoo formulation according to an embodiment the present disclosure (Example 1) after several combings of the treated tress. Both the hair tress treated with the control formula and the hair tress treated with the Example 1 formula become lighter after each subsequent combing, however, the control sample lightens more rapidly.
- luminance L* values were calculated for each of the images (which were captured for 6 samples treated with the control formula and 6 samples treated with the Example 1 formula) and the mean values were computed.
- the luminance (L*) values for the samples after the combings are provided in Table 3 below.
- Table 3 Luminance (L*) values for hair tresses treated with a control formula and hair tresses treated with the Example 1 formula after combings
- the values in Table 3 show a very good luminance consistency of the white hair tresses (before treatment with a colored dry shampoo formulation) that were used in this study.
- the Luminance values after application of the colored dry shampoo control formulation are higher than the luminance values after application of the colored dry shampoo Example 1 formulation.
- FIG. 5 is a plot of the luminance evolution after combing for each of the samples.
- the quantity of dry shampoo particles adhered to the hair tress samples was correlated with the luminance values. Dry shampoo particles absorb emitting light, and thus it was assumed that the concentration of dry shampoo particles is proportional to the measured luminance. It was further estimated that the absorbance coefficient is very close for the two tested dry shampoo compositions (i.e., the control formulation and the Example 1 formulation). The quantity of remaining dry shampoo particles was thus determined based on the luminance values provided in Table 3 above, with product application considered as 100% of particle concentration and original white hair (without any product) considered as 0% particle concentration. Table 4 below shows the quantity of dry shampoo particles for each of the treated tresses after each combing.
- Table 4 Quantity of dry shampoo particles (%) for hair tresses treated with a control formula and hair tresses treated with the Example 1 formula after combings
- FIG. 6 shows the quantity of dry shampoo particles after each combing for each of the samples tested.
- FIG. 1 is a plot of the average quantity of dry shampoo particles after each combing for the hair tresses treated with the control formulation and the average quantity of dry shampoo particles after each combing for the hair tresses treated with the Example 1 formulation.
- a strong decrease in the quantity of dry shampoo particles was observed after the first 4 combings for each of the two formulations, although the decrease was greater with the tresses treated with the control formulation. After the first four brushings, the decrease in the number of dry shampoo particles was almost linear until 10 brushings. The last brushings only had a small effect on the number of dry shampoo particles.
- Table 5 shows the statistical analysis for each of the time points (i.e., combing points) shown in FIG. 6. The p-value significance was defined under 0.05.
- Table 6 Normalized quantity of dry shampoo particles (%) for hair tresses treated with a control formula and hair tresses treated with the Example 1 formula after combings
- Example 1 formulation stays longer on the treated hair tresses than the control formulation. Accordingly, formulations prepared according to the present disclosure (i.e., including a hemisqualane) provide more long-lasting color effect than a dry shampoo composition which does not include a hemisqualane.
- a sample dry shampoo composition was prepared according to Example 1 above.
- a control sample was also prepared for comparison purposes.
- the control formula was prepared according to the method outlined in Example 1 above, except the control formula does not include any hemisqualanes.
- the control composition is provided in Table 2 above (with weight percentage ranges being based on the total weight of the respective dry shampoo composition).
- Example 1 and control formulas were prepared, instrumental deposition analysis was used to analyze the long-lasting benefit of the two formulas. First, high resolution images of natural white hair tresses were captured. Next, each of the Example 1 formula and the control formula were applied to separate white hair tress samples. High resolution images of the treated hair tresses were captured after application of the dry shampoo formulas. A color chart was used to validate the color calibration parameters during the acquisition of the high resolution images. 30 samples were prepared for each of the two formulations. Similar to Example 2 above, the hair tresses treated with the control formulation had a higher luminance than the hair tresses treated with Example 1 formula.
- the treated tresses were each combed 10 times and high resolution images were captured after each of the 10 combings.
- the treated tresses were each combed another 10 times (20 total brushings) and high resolution images were captured.
- the treated tresses were each combed another 20 times (40 brushings total) and high resolution images were captured. Similar to Example 2 above, both the hair tress treated with the control formula and the hair tress treated with the Example 1 formula become lighter after each subsequent combing, however, the control sample lightens more rapidly.
- luminance L* values were calculated (three repetitions for each of the brushings measured) for each of the images (which were captured for 30 samples treated with the control formula and 30 samples treated with the Example 1 formula) and the mean values were computed.
- the luminance (L*) values for the samples after the combings are provided in Table 7 below. Several hair tresses were removed because they were considered outliers.
- the values in Table 7 show a very good luminance consistency of the white hair tresses (before treatment with a colored dry shampoo formulation) that were used in this study with an average L* value of 82. Similar to Example 2 above, the Luminance values after application of the colored dry shampoo control formulation are higher than the luminance values after application of the colored dry shampoo Example 1 formulation. The higher luminance values indicate that less of the pigmented dry shampoo particles adhered to the hair tress. An increase of the luminance over time was also observed due to the reduction of the number of pigmented dry shampoo particles after combing.
- the quantity of dry shampoo particles adhered to the hair tress samples was correlated with the luminance values. Dry shampoo particles absorb emitting light, and thus it was assumed that the concentration of dry shampoo particles is proportional to the measured luminance. It was further estimated that the absorbance coefficient is very close for the two tested dry shampoo compositions (i.e., the control formulation and the Example 1 formulation). The quantity of remaining dry shampoo particles was thus determined based on the luminance values provided in Table 3 above, with product application considered as 100% of particle concentration and original white hair (without any product) considered as 0% particle concentration. Table 8 below shows the quantity of dry shampoo particles for each of the treated tresses after each combing. Table 8: Quantity of dry shampoo particles (%) for hair tresses treated with a control formula and hair tresses treated with the Example 1 formula after combings
- Table 9 shows the statistical analysis for each of the time points (i.e., combing points). The p-value significance was defined under 0.05. Table 9: Statistical Analysis of the Quantity of Particles Data
- Table 10 Statistical analysis for normalized quantity of dry shampoo particles (%) for hair tresses treated with a control formula and hair tresses treated with the Example 1 formula after combings
- FIG. 7 is a plot showing the average hair tress weight at each of the combings. Table 11: Hair tress weight (mg)
- the evolution of the average weight of the hair tresses is similar to the particles quantity analysis.
- Example 1 formulation stays longer on the treated hair tresses than the control formulation, which is easier to remove even after the first combing.
- the weight of the dry shampoo and the concentration (based on the weight) of the remaining particles was analyzed. Table 12 below shows the normalized remaining particles weight values.
- FIG. 8 is a plot showing the average dry shampoo weight proportion at each of the combings.
- control formulation 50% of the product was removed after the first shaking, as compared to the hair tresses treated with the formulation according to Example 1 above, wherein only 38% of the dry shampoo formulation was removed.
- the control formulation was faster to remove and after 10 combings, only 18% of the product remained on the hair, as compared to the hair tresses treated with the formulation according to Example 1, wherein 25% of the product remained after 10 combings.
- FIG. 9 shows the correlation between Absorbance and Weight for the control formulation.
- FIG. 10 shows the correlation between Absorbance and Weight for the formulation according to Example 1 above. It was noted that the correlation factor between the luminance and the weight using a second degree polynomial function was very good with a correlation factor of 99.24% for the control dry shampoo and 97.59% for the Example 1 dry shampoo. This means that it is possible to estimate the weight of the remaining particles from the images based on the absorbance values, but the transfer function depends on the dry shampoo particles absorbance.
- FIG. 11 is a graph showing the evolution of the mean heterogeneity parameter after each combing on the 30 hair tresses for the control dry shampoo formulation and for the dry shampoo formulation according to Example 1 above. It was observed that the Control dry shampoo is less homogenous just after application. After the 2 nd combing, the color heterogeneity index for the two colored dry shampoo formulations is significantly different.
- Table 14 below shows the evolution of the color heterogeneity index for the 2 dry shampoo formulations. It was observed that after the 4 th combing, the color homogeneity of the Control dry shampoo is stable whereas the color homogeneity of the dry shampoo formulation according to Example 1 above is stable after 2 combings and remains higher. After 40 combings, the color heterogeneity index difference between the Control formulation and the Example formulation is about 28%.
- formulations prepared according to the present disclosure provide more long-lasting color effect than a dry shampoo composition which does not include a hemisqualane.
- the control dry shampoo was faster to remove from the hair tresses with 14% differences from the Example 1 dry shampoo after the first real combing. After 40 combings, 11% of the product remained for the control dry shampoo and 15% remained for the Example 1 dry shampoo. It was further noted that the hair tresses treated with the Example 1 dry shampoo were initially darker than the hair tresses treated with the control dry shampoo, and they remained darker at each measured combing throughout the 40 combings.
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP21760189.7A EP4110266A4 (en) | 2020-02-28 | 2021-02-25 | Dry shampoo composition |
AU2021226179A AU2021226179B2 (en) | 2020-02-28 | 2021-02-25 | Dry shampoo composition |
CN202180017203.XA CN115175655A (en) | 2020-02-28 | 2021-02-25 | Dry shampoo composition |
CA3168334A CA3168334A1 (en) | 2020-02-28 | 2021-02-25 | Dry shampoo composition |
MX2022010655A MX2022010655A (en) | 2020-02-28 | 2021-02-25 | Dry shampoo composition. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US202062983261P | 2020-02-28 | 2020-02-28 | |
US62/983,261 | 2020-02-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2021171222A1 true WO2021171222A1 (en) | 2021-09-02 |
Family
ID=77463278
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2021/051584 WO2021171222A1 (en) | 2020-02-28 | 2021-02-25 | Dry shampoo composition |
Country Status (7)
Country | Link |
---|---|
US (1) | US11931433B2 (en) |
EP (1) | EP4110266A4 (en) |
CN (1) | CN115175655A (en) |
AU (1) | AU2021226179B2 (en) |
CA (1) | CA3168334A1 (en) |
MX (1) | MX2022010655A (en) |
WO (1) | WO2021171222A1 (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018106694A1 (en) * | 2016-12-06 | 2018-06-14 | Church & Dwight Co., Inc. | Dry shampoo composition |
GB2570560A (en) * | 2017-12-07 | 2019-07-31 | Henkel Kgaa | Propellant-free dry shampoo |
Family Cites Families (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA903084A (en) * | 1972-06-20 | Lukesch Heinz | Composition and method for de-greasing and cleaning hair | |
DE2943521A1 (en) | 1979-10-27 | 1981-05-07 | Wella Ag, 6100 Darmstadt | Aerosol compsn. contg. hydrophilic and hydrophobic components - in which hydrophobic components are filled into aerosol container as soln. in hydrophobic propellant |
DE19627498A1 (en) | 1996-07-08 | 1998-01-15 | Nat Starch Chem Invest | Starchy cleaning and care products |
DE602004028079D1 (en) | 2003-08-06 | 2010-08-26 | Kao Corp | Cosmetic aerosol composition |
FR2904542B1 (en) | 2006-08-03 | 2011-06-24 | Soc Extraction Principes Actif | USE OF EXTRACT OF COCOA BEANS AS AN ACTIVE AGENT TO INCREASE MELANIN SYNTHESIS IN MELANOCYTES |
EP1932503A1 (en) | 2006-12-13 | 2008-06-18 | KPSS-Kao Professional Salon Services GmbH | Aerosol hair styling composition comprising natural starch |
US9327144B2 (en) | 2009-03-13 | 2016-05-03 | Elc Management Llc | Powder compositions containing edible grains |
DE102011085694A1 (en) | 2011-11-03 | 2013-05-08 | Beiersdorf Ag | Cosmetic preparation with powdered hydrophilic substances |
DE102011088397A1 (en) | 2011-12-13 | 2013-06-13 | Henkel Ag & Co. Kgaa | Compositions for coloring keratinic fibers |
FR2990133B1 (en) | 2012-05-07 | 2017-08-11 | Oreal | AEROSOL DEVICE BASED ON ABSORBENT SEBUM POWDER AND INSOLUBLE MINERAL COMPOUND IN SPECIAL WATER |
FR3004929B1 (en) * | 2013-04-30 | 2015-04-10 | Oreal | AEROSOL DEVICE BASED ON SEBUM ABSORBENT POWDER AND CALCIUM CARBONATE |
GB2520326A (en) | 2013-11-15 | 2015-05-20 | Emma Neame | Composition |
FR3017288B1 (en) | 2014-02-10 | 2019-06-07 | Bbr | COSMETIC COMPOSITION SUITABLE FOR MODIFYING THE COLOR OF KERATIN FIBERS, IN PARTICULAR HAIR |
DE102014206532A1 (en) | 2014-04-04 | 2015-10-08 | Henkel Ag & Co. Kgaa | Fashionable aerosol dyes |
FR3023479B1 (en) | 2014-07-09 | 2016-07-22 | Oreal | ANHYDROUS AEROSOL COMPOSITION BASED ON PARTICLES ENCAPSULATING A BENEFICIAL AGENT |
FR3027799B1 (en) | 2014-10-29 | 2017-12-08 | Oreal | ANHYDROUS COMPOSITION BASED ON STENCIL POWDER AND / OR ABSORBENT OF SEBUM AND PARTICLES ENCAPSULATING A BENEFICIAL AGENT |
WO2016005703A1 (en) * | 2014-07-09 | 2016-01-14 | L'oreal | Anhydrous composition based on styling and/or sebum-absorbing powder and on particles encapsulating a beneficial agent |
FR3027800B1 (en) | 2014-10-29 | 2018-01-26 | L'oreal | COMPOSITION BASED ON SEBUM-COATING AND / OR ABSORBENT POWDER AND ALUMINUM SALT |
FR3027798B1 (en) * | 2014-10-29 | 2017-12-22 | Oreal | COMPOSITION BASED ON SEBUM-COATING AND / OR ABSORBENT POWDER AND ZINC SALT |
CN107106441B (en) * | 2014-12-17 | 2020-09-25 | 诺赛尔股份有限公司 | Method for inhibiting copper deposition on hair |
GB2537648B (en) | 2015-04-22 | 2020-01-08 | Cosmetic Warriors Ltd | Composition |
WO2017059136A1 (en) | 2015-10-02 | 2017-04-06 | Amyris, Inc. | Compositions containing bio-based farnesene or compounds derived therefrom and their use in consumer and industrial products |
FR3046071B1 (en) | 2015-12-23 | 2018-02-16 | L'oreal | COMPOSITION COMPRISING AT LEAST TWO DISTINCT AMIDES AND A COLORING AGENT |
NL2016944B1 (en) | 2016-06-10 | 2018-01-24 | Pcp1501 Ip Joint Venture B V | Anti-chafing spray composition |
WO2017217971A1 (en) | 2016-06-14 | 2017-12-21 | American Spraytech, L.L.C. | Sprayable color composition for hair |
CN109843381A (en) | 2016-10-21 | 2019-06-04 | 宝洁公司 | For providing the concentrated type shampoo foam of hair-care beneficial effect |
DE102016225660A1 (en) | 2016-12-20 | 2018-06-21 | Henkel Ag & Co. Kgaa | Preparations and methods for hair cleansing |
DE102017220775A1 (en) | 2017-11-21 | 2019-05-23 | Henkel Ag & Co. Kgaa | Sprayable cosmetic with color effect |
DE102017220773A1 (en) | 2017-11-21 | 2019-05-23 | Henkel Ag & Co. Kgaa | Sprayable cosmetic with color effect |
FR3065875B1 (en) * | 2017-05-02 | 2021-12-10 | Henkel Ag & Co Kgaa | AGENT AND METHOD FOR CLEANING THE HAIR |
DE102018205095B4 (en) * | 2018-04-05 | 2023-10-26 | Henkel Ag & Co. Kgaa | Cosmetic composition for hair cleansing |
WO2018216242A1 (en) | 2017-05-23 | 2018-11-29 | 東洋エアゾール工業株式会社 | Aerosol composition for hair and aerosol product for hair |
US11998631B2 (en) * | 2017-07-06 | 2024-06-04 | American Spraytech, L.L.C. | Dry shampoo mousse composition for hair |
JP2020528935A (en) | 2017-07-26 | 2020-10-01 | オワ ヘアケア, インク.Owa Haircare, Inc. | Naturally-derived powder shampoo that does not contain sulfate |
DE102017215328A1 (en) * | 2017-09-01 | 2019-03-07 | Henkel Ag & Co. Kgaa | Propellant-containing cosmetic compositions with pigment-containing starch particles and anionic polymer |
RU2742123C1 (en) | 2017-09-20 | 2021-02-02 | Као Корпорейшн | Powdered composition including direct dyes for hair |
FR3071413B1 (en) | 2017-09-25 | 2021-07-23 | Danielle Roches | READY-TO-USE SEMI-PERMANENT NON-OXIDIZING DYE FOR EYEBROWS |
US20200054534A1 (en) * | 2017-10-04 | 2020-02-20 | Mana Products, Inc. | Dry composition for removing oils from hair and methods for fabrication of dry compositions |
KR101997440B1 (en) | 2017-10-27 | 2019-07-08 | 코스맥스 주식회사 | Powder cosmetic composition comprising starch |
FR3075637B1 (en) | 2017-12-22 | 2019-11-22 | L'oreal | HAIR COLORING PROCESS COMPRISING A COLORING STEP WITH HENNE AND / OR INDIGO AND A PROCESSING STEP COMPRISING THE APPLICATION OF AQUEOUS PHASE, A FATTY PHASE AND A DIRECT COLOR |
US11229589B2 (en) | 2018-03-01 | 2022-01-25 | Inolex Investment Corporation | Natural hydrocarbon/ester compositions with improved sensory properties, formulations and related methods |
JP7301501B2 (en) | 2018-04-06 | 2023-07-03 | ロレアル | Composition for keratin fibers |
-
2021
- 2021-02-25 MX MX2022010655A patent/MX2022010655A/en unknown
- 2021-02-25 AU AU2021226179A patent/AU2021226179B2/en active Active
- 2021-02-25 EP EP21760189.7A patent/EP4110266A4/en active Pending
- 2021-02-25 US US17/185,676 patent/US11931433B2/en active Active
- 2021-02-25 CN CN202180017203.XA patent/CN115175655A/en active Pending
- 2021-02-25 WO PCT/IB2021/051584 patent/WO2021171222A1/en active Application Filing
- 2021-02-25 CA CA3168334A patent/CA3168334A1/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018106694A1 (en) * | 2016-12-06 | 2018-06-14 | Church & Dwight Co., Inc. | Dry shampoo composition |
GB2570560A (en) * | 2017-12-07 | 2019-07-31 | Henkel Kgaa | Propellant-free dry shampoo |
Non-Patent Citations (4)
Title |
---|
BATISTE, BATISTE DRY SHAMPOO DARK AND BROWN 200MI, 23 November 2015 (2015-11-23), XP055850183, Retrieved from the Internet <URL:https://www.tesco.com/groceries/en-GB/products/275711193> [retrieved on 20210430] * |
HUMBLEBEE & ME, NEOSSANCE HEMISQUALANE, 14 March 2019 (2019-03-14), XP055850184, Retrieved from the Internet <URL:https://www.humblebeeandme.com/project/neossance-hemisqualane> [retrieved on 20210430] * |
O'LENICK, COMPARATIVELY SPEAKING: NATURAL - VS. MINERAL-BASED COLORANTS, 30 March 2011 (2011-03-30), XP055850187, Retrieved from the Internet <URL:https://www.cosmeticsandtoiletries.com/formulating/function/pigment/l18610674.html> [retrieved on 20210430] * |
See also references of EP4110266A4 * |
Also Published As
Publication number | Publication date |
---|---|
US20210267855A1 (en) | 2021-09-02 |
CA3168334A1 (en) | 2021-09-02 |
EP4110266A1 (en) | 2023-01-04 |
US11931433B2 (en) | 2024-03-19 |
CN115175655A (en) | 2022-10-11 |
AU2021226179B2 (en) | 2024-02-15 |
AU2021226179A1 (en) | 2022-09-15 |
MX2022010655A (en) | 2022-10-21 |
EP4110266A4 (en) | 2024-03-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
AU614750B2 (en) | Shine hair conditioner | |
JP3081049B2 (en) | Hair composition | |
CA3045469C (en) | Dry shampoo composition | |
JP2820329B2 (en) | Hair cosmetics | |
JP2008512418A (en) | Hair care composition | |
AU2020265432B2 (en) | Rinse-free shampoo composition | |
US5393521A (en) | Hair treatments utilizing polymethylalkylsiloxanes | |
MX2013014219A (en) | Clear hair care composition comprising base oil and silicone. | |
JPH07502540A (en) | hair conditioner | |
JP7430288B2 (en) | Composition for strengthening keratin fibers | |
AU2021226179B2 (en) | Dry shampoo composition | |
JP2017206483A (en) | Hair cosmetic | |
JP2003212739A (en) | Hairdressing composition | |
JP6282841B2 (en) | Multi-agent hair treatment | |
JPS62501003A (en) | Hair conditioning compositions and methods | |
JP2004035542A (en) | Mono and dialkylquat in foaming hair conditioning composition | |
WO2017192990A1 (en) | Hair relaxer compositions and method | |
JP2002338442A (en) | Hair hard-treating agent | |
JP2023005273A (en) | hair treatment agent | |
JP2023081072A (en) | Hair composition | |
JP2023097465A (en) | Hair cosmetic | |
JPH0745384B2 (en) | Hair cosmetics | |
JPH10273427A (en) | Hair-treating agent composition | |
MXPA00010163A (en) | Cosmetic emulsion compositions containing a vinyldimethicone/dimethicone copolymer and a surfactant and their uses | |
WO2012140192A1 (en) | Composition comprising a nonionic surfactant, a polycondensate of ethylene oxide and of propylene oxide and a monoalcohol |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 21760189 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 3168334 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2021226179 Country of ref document: AU |
|
ENP | Entry into the national phase |
Ref document number: 2021226179 Country of ref document: AU Date of ref document: 20210225 Kind code of ref document: A |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 2021760189 Country of ref document: EP Effective date: 20220928 |