WO2021150042A1 - Composition isolante pour câbles de véhicule et câble de véhicule fabriqué à l'aide de celle-ci - Google Patents

Composition isolante pour câbles de véhicule et câble de véhicule fabriqué à l'aide de celle-ci Download PDF

Info

Publication number
WO2021150042A1
WO2021150042A1 PCT/KR2021/000854 KR2021000854W WO2021150042A1 WO 2021150042 A1 WO2021150042 A1 WO 2021150042A1 KR 2021000854 W KR2021000854 W KR 2021000854W WO 2021150042 A1 WO2021150042 A1 WO 2021150042A1
Authority
WO
WIPO (PCT)
Prior art keywords
resin
weight
parts
automobile
cable
Prior art date
Application number
PCT/KR2021/000854
Other languages
English (en)
Korean (ko)
Inventor
박찬웅
김인하
Original Assignee
엘에스전선 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 엘에스전선 주식회사 filed Critical 엘에스전선 주식회사
Priority claimed from KR1020210008678A external-priority patent/KR20210095077A/ko
Publication of WO2021150042A1 publication Critical patent/WO2021150042A1/fr

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/014—Stabilisers against oxidation, heat, light or ozone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/016—Flame-proofing or flame-retarding additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
    • C08K5/3445—Five-membered rings
    • C08K5/3447—Five-membered rings condensed with carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene

Definitions

  • the present invention relates to an insulating composition for an automobile cable and an automobile cable manufactured using the same.
  • cables used in transportation means such as railway vehicles, ships, and automobiles require various properties according to their usage environment.
  • the physical properties required for automotive cables include oil resistance, heat resistance, cold resistance, and flexibility, and the required properties depend on the characteristics of each part or part of the vehicle, and on the basis of the conductor standard (1.5SQ). to 6.0SQ) or the shape of the thin wire (0.35SQ to 1.0SQ).
  • Patent Document 1 proposes a technology for an automobile cable having a coating composition having high flexibility and high heat resistance.
  • Patent Document 1 in the manufacture of a battery cable for a vehicle, forms a conductor wire of 19 ⁇ 61 annealed wires having a diameter of 0.18 mm to 0.30 mm inside the cable, and is applied to the outside of the conductor wire.
  • the cable is coated with a coating composition composed of 85% by weight of ethylene vinyl acetate (EVA), 10% by weight of high-density polyethylene (HDPE), and 5% by weight of polyolefin (PO).
  • EVA ethylene vinyl acetate
  • HDPE high-density polyethylene
  • PO polyolefin
  • It relates to a battery cable for automobiles, characterized in that it consists of a crosslinking reaction of irradiation through a stan roll.
  • Patent Document 1 Korean Patent Publication No. 10-0935853
  • An object of the present invention is to provide an insulation composition for an automobile cable capable of solving the problems of the prior art and an automobile cable manufactured using the same by conducting research on automobile cables that can increase production efficiency by simplifying the research and completing the development.
  • a base resin comprising a polyethylene-based resin; and an inorganic flame retardant, wherein the polyethylene-based resin provides an insulating composition for an automobile cable comprising a first resin having a melting point of 120°C to 140°C.
  • the first resin included in the polyethylene-based resin is a high-density polyethylene (HDPE) resin, a medium-density polyethylene (MDPE) resin, and a linear low-density polyethylene (LLDPE).
  • HDPE high-density polyethylene
  • MDPE medium-density polyethylene
  • LLDPE linear low-density polyethylene
  • the present invention provides an insulation composition for an automobile cable, characterized in that the base resin further comprises an ethylene copolymer.
  • the ethylene copolymer is ethylene ethylacrylate (EEA) resin, ethylene butylacrylate (EBA) resin, ethylene methyl acrylate (Ethylene methylacrylate, EMA) resin and ethylene vinyl acetate (Ethylene vinyl acetate, EVA) It provides an insulation composition for an automobile cable, characterized in that it contains one or more resins or copolymers thereof selected from the group consisting of resins.
  • the present invention provides an insulating composition for an automobile cable, characterized in that the base resin comprises 40 parts by weight to 70 parts by weight of a polyethylene-based resin and 15 parts by weight to 30 parts by weight of an ethylene copolymer.
  • the present invention provides an insulation composition for an automobile cable, characterized in that the polyethylene-based resin further comprises a second resin having a melting point of 95°C to 115°C.
  • the present invention provides an insulating composition for an automobile cable, characterized in that the polyethylene-based resin comprises 40 parts by weight to 60 parts by weight of the first resin and 1 part by weight to 20 parts by weight of the second resin.
  • the present invention provides an insulation composition for an automobile cable, characterized in that the content of the polar monomer contained in the ethylene copolymer is 10% by weight to 20% by weight.
  • the present invention provides an insulating composition for an automobile cable, characterized in that the inorganic flame retardant is an inorganic metal hydroxide flame retardant compatible with the base resin.
  • the present invention provides an insulating composition for an automobile cable, characterized in that it further comprises a compatibilizer capable of increasing the compatibility of the base resin and the inorganic flame retardant.
  • the present invention provides an insulation composition for an automobile cable, characterized in that the compatibilizer is maleic anhydride grafted polyethylene.
  • the present invention provides an insulation composition for an automobile cable, characterized in that the compatibilizer is included in an amount of 5 to 20 parts by weight based on 100 parts by weight of a mixture of the base resin and the flame retardant.
  • the present invention provides an insulation composition for an automobile cable, characterized in that the inorganic flame retardant is included in an amount of 80 parts by weight to 140 parts by weight based on 100 parts by weight of a mixture of the base resin and the compatibilizer.
  • the present invention provides an insulating composition for an automobile cable, characterized in that it further comprises an additive.
  • the present invention provides an insulation composition for an automobile cable, characterized in that the additive is at least one selected from the group consisting of antioxidants, crosslinking aids and lubricants.
  • the present invention provides an insulation composition for an automobile cable, characterized in that the additive is included in an amount of 15 to 20 parts by weight based on 100 parts by weight of a mixture of the base resin and the compatibilizer.
  • the present invention is a conductor; And it provides an automobile cable comprising an insulating layer made of the above-described insulating composition for automobile cables.
  • the present invention provides an automobile cable, characterized in that the conductor has a standard of 0.35SQ to 1.0SQ, and the automobile cable satisfies Equations 1 and 2 below.
  • Equation 1 X 1 means the evaluation value of scrape abrasion resistance of the automobile cable measured according to ISO 19642 standard when the size of the conductor is 0.35SQ, and X 2 is the standard of ISO 19642 when the size of the conductor is 0.5SQ.
  • X 3 means the evaluation value of the scrape abrasion resistance of the automobile cable measured according to the ISO 19642 standard when the size of the conductor is 0.75SQ
  • X 4 is the evaluation value of the scrape abrasion resistance of the conductor
  • the standard is 1.0SQ
  • Y means the flame retardance evaluation value of the automobile cable measured according to the ISO 19642 standard.
  • the insulating composition for automobile cables according to the present invention secures physical properties that can satisfy the international standardization standards (ISO 19642) required for automobile cables when the insulating layer prepared from the insulating composition for automobile cables is included in automobile cables
  • ISO 19642 the international standardization standards
  • the insulating layer prepared from the insulating composition for automobile cables is included in automobile cables
  • the car cable is applied in the form of a thin wire (0.35SQ to 1.0SQ)
  • the insulation composition for automobile cables according to the present invention is applied in the form of fine wires (0.35SQ to 1.0SQ) of automobile cables of all standards in the previous insulation composition for automobile cables, and is a component to ensure the necessary properties in each specification It was developed with a focus on compatibility and mixing ratio between livers, and since it can be manufactured without major changes to the manufacturing process, production cost and production efficiency can be increased.
  • FIG 1 shows an automobile cable according to the present invention.
  • the insulation composition for a vehicle cable according to the present invention and a vehicle cable manufactured using the same will be sequentially described in detail, but the scope of the insulation composition for a vehicle cable and the vehicle cable manufactured using the same is limited by the following description it is not
  • the present invention relates to a composition for cables.
  • the present invention relates to an insulation composition for a cable that can be applied in the form of a thin wire to a transportation means such as an automobile among the composition for a cable (hereinafter referred to as "insulation composition for an automobile cable").
  • the insulation composition for an automobile cable may include a base resin, and the base resin may include a polyethylene-based resin.
  • the base resin may include the polyethylene-based resin described above in order to increase abrasion resistance and/or flame retardancy, which are basic properties required for an automobile cable including an insulating layer prepared from the insulating composition for automobile cables according to the present invention.
  • the polyethylene-based resin may include a first resin having a melting point of 120°C to 140°C.
  • the polyethylene-based resin includes the first resin having the melting point range, it is easy to secure physical properties such as abrasion resistance of the cable product manufactured from the insulation composition for automobile cables according to the present invention, and if the melting point of the first resin is When the temperature is less than 120 °C, there is a problem in that it is difficult to secure the required physical properties of wear resistance.
  • the first resin included in the polyethylene-based resin is a high-density polyethylene (HDPE) resin, a medium-density polyethylene (MDPE) resin, and a linear low-density polyethylene (LLDPE) resin. It may be at least one resin selected from
  • HDPE high-density polyethylene resin
  • MDPE medium-density polyethylene resin
  • LLDPE linear low-density polyethylene resin
  • the polyethylene-based resin may further include a second resin having a melting point of 95°C to 115°C.
  • the second resin if it is a resin having the melting point range, it may be used without particular limitation, but preferably, a low density polyethylene (LDPE) resin may be used.
  • LDPE low density polyethylene
  • the polyethylene-based resin may be included in a mixed resin form in which one or two or more resins are mixed, and when used in a mixed resin form in which two or more resins are mixed, the first resin and the second resin
  • each melting point of the first resin and the second resin is not particularly problematic as long as it is within the above range, but on the premise that physical properties such as abrasion resistance and flexibility described below are simultaneously satisfied.
  • the upper or lower limit may be changed.
  • the polyethylene-based resin when used in a mixed resin form, may include 40 parts by weight to 60 parts by weight, 45 parts by weight to 60 parts by weight, or 45 parts by weight to 55 parts by weight; and 1 part by weight to 20 parts by weight, 5 parts by weight to 20 parts by weight, or 5 parts by weight to 15 parts by weight of the second resin.
  • the polyethylene-based resin when used in the form of a mixed resin, the polyethylene-based resin preferably includes the first resin and the second resin in the above-mentioned mixing ratio, and when it is out of the mixing ratio, that is, the first resin is 40 weight
  • the first resin when less than part or more than 20 parts by weight of the second resin is included, it may be difficult to secure physical properties such as abrasion resistance, and when the first resin is more than 60 parts by weight or the second resin is included less than 1 part by weight, flexibility and cold resistance, etc. There may be problems that may make it difficult to secure the physical properties of
  • the insulating composition for a vehicle cable according to the present invention may further include an ethylene copolymer in addition to the above-mentioned polyethylene-based resin as a base resin.
  • the ethylene copolymer it may be added to be used in the form of a mixed resin to simultaneously secure filler loading, printability and flame retardancy, including insufficient flexibility of the above-mentioned polyethylene-based resin, and due to the input of the ethylene copolymer It is possible to secure the flexibility and workability required for the insulation composition for an automobile cable according to the present invention.
  • the ethylene copolymer is an ethylene ethylacrylate (EEA) resin, an ethylene butylacrylate (EBA) resin, an ethylene methylacrylate (EMA) resin, and an ethylene vinyl acetate resin.
  • EVA ethylene ethylacrylate
  • EBA ethylene butylacrylate
  • EMA ethylene methylacrylate
  • ethylene vinyl acetate resin At least one resin selected from the group consisting of (Ethylene vinyl acetate, EVA) resin or a copolymer thereof may be included, but preferably ethylene ethyl acrylate or a copolymer thereof.
  • the polar monomer content included in the ethylene copolymer may be 10 wt% to 20 wt% in consideration of the harmonization between physical properties required for the final product, and for preferred use, for example, as the ethylene copolymer
  • the ethyl acrylate (EA) contained in the ethylene ethyl acrylate (EEA) may be 10 wt% to 20 wt%, and ethyl acrylate (EA) in this range
  • ethylene ethyl acrylate (EEA) containing ethylene is used, flexibility and processability, which are physical properties to be secured, can be further improved.
  • the ethylene ethyl acrylate (EEA) used as the ethylene copolymer preferably has a melting point of 90°C to 110°C, preferably around 100°C.
  • the insulating composition for a vehicle cable according to the present invention is not particularly limited when, as a base resin, an ethylene copolymer in addition to the above-mentioned polyethylene-based resin is included, for example, the base resin may be 40 parts by weight of a polyethylene-based resin to 70 parts by weight, 45 parts by weight to 65 parts by weight, or 50 parts by weight to 60 parts by weight; and 15 parts by weight to 30 parts by weight, 15 parts by weight to 25 parts by weight, or 20 parts by weight to 25 parts by weight of the ethylene copolymer.
  • the base resin is out of the mixing ratio of the above range, that is, when less than 40 parts by weight of the polyethylene-based resin or when the ethylene copolymer is more than 30 parts by weight, there may be a problem in not satisfying the required abrasion resistance and heat resistance
  • the insulation composition for an automobile cable according to the present invention Silver may have a problem in that it cannot simultaneously satisfy abrasion resistance, heat resistance, flexibility, and processability.
  • the insulation composition for a vehicle cable according to the present invention may include a flame retardant in addition to the base resin described above to ensure flame retardancy, and in this case, may include a flame retardant compatible with the base resin.
  • the flame retardant includes magnesium hydroxide, aluminum hydroxide, a mixture of huntite and hydromagnesite, inorganic flame retardants that are metal hydroxides such as hydromagnesite or magnesium hydroxide, organic phosphorus-based, halogen-based, melamine-based compounds, and organic flame retardants such as nanoclay.
  • an inorganic flame retardant may be used, and more preferably, an inorganic metal hydroxide flame retardant compatible with the base resin may be included in order to secure the unit cost of the cable product and ease of compounding.
  • compatibility may mean a property that specific components can be mixed with each other, and more specifically, a specific component in the form of a compatibilizer or without a separate compatibilizer. It may mean including all properties that can be mixed with each other.
  • a compatibilizer capable of increasing compatibility between the base resin and the inorganic flame retardant may be additionally included.
  • the type of the compatibilizer is not particularly limited, but for example, maleic anhydride-grafted polyethylene or maleic anhydride-grafted ethylene vinyl acetate (Maleic Anhydride grafted Ethylene Vinyl) Acetate) can be used, but maleic anhydride-grafted polyethylene is preferable in terms of securing the physical properties of abrasion resistance to a required level.
  • the insulation composition for a vehicle cable according to the present invention additionally includes a compatibilizer capable of increasing the compatibility of the base resin and the inorganic flame retardant, based on 100 parts by weight of a mixture of the base resin and the flame retardant, It may be included in an amount of 5 parts by weight to 20 parts by weight, 10 parts by weight to 20 parts by weight, or 10 parts by weight to 15 parts by weight.
  • a compatibilizer capable of increasing the compatibility of the base resin and the inorganic flame retardant, based on 100 parts by weight of a mixture of the base resin and the flame retardant, It may be included in an amount of 5 parts by weight to 20 parts by weight, 10 parts by weight to 20 parts by weight, or 10 parts by weight to 15 parts by weight.
  • the compatibilizer is preferably included within the above range, and when it is outside the above range, for example, when it is included in less than 5 parts by weight based on 100 parts by weight of a mixture of the base resin and the flame retardant, the base resin and the flame retardant.
  • compatibility between cables is lowered, abrasion resistance and flame retardancy may occur when manufacturing a cable product, and if it contains more than 20 parts by weight, problems may occur in securing flexibility, extrusion processability, and cold resistance when manufacturing cable products.
  • the inorganic flame retardant may be included in an amount of 80 parts by weight to 140 parts by weight or 90 parts by weight to 140 parts by weight, more preferably 90 parts by weight to 130 parts by weight, based on 100 parts by weight of the mixture of the base resin and the compatibilizer.
  • the insulation composition for automobile cables according to the present invention including the inorganic flame retardant includes the insulation composition for automobile cables, including securing sufficient flame retardancy and long-term/short-term heat resistance It is possible to satisfy physical properties such as abrasion resistance required of the manufactured cable.
  • the insulation composition for an automobile cable according to the present invention may further include an additive in addition to the above-described components.
  • the additive is not particularly limited, but may be, for example, at least one selected from the group consisting of antioxidants, crosslinking aids and lubricants.
  • the content is not particularly limited, but for example, about 15 parts by weight to 20 parts by weight, 15 parts by weight to about 100 parts by weight based on 100 parts by weight of the base resin and compatibilizer mixed. 18 parts by weight or 16 parts by weight to 18 parts by weight may be included.
  • the insulation composition for an automobile cable according to the present invention may further include other additives in addition to the above-described components.
  • the other additives include high molecular weight wax, low molecular weight wax, polyolefin wax, paraffin wax, paraffin oil, stearic acid, metal soap, organic silicone, fatty acid ester, fatty acid amide, fatty alcohol, strengthening agent, release agent, UV absorber, stabilizer, pigment , may be at least one selected from the group consisting of dyes, colorants, antistatic agents, foaming agents and metal deactivators.
  • the invention also relates to a cable.
  • the present invention relates to an automobile cable comprising an insulating layer made of the insulating composition for automobile cables.
  • FIG 1 shows an automobile cable according to the present invention.
  • the vehicle cable 10 includes a conductor 100 ; and an insulating layer 200 made of the above-described insulating composition for automobile cables.
  • the conductor 100 may have a composite stranded wire structure in which a plurality of metal wires are twisted at a constant pitch, and the metal wire may be made of a single metal or at least two or more metal alloys. That is, the metal element wire may be made of a metal selected from copper, aluminum, iron, nickel, or an alloy of these metals, but is not particularly limited thereto, and is preferably in the form of an annealed wire.
  • the insulating layer 200 is an insulating layer made of the above-described insulating composition for automobile cables, and the same description as described above will be omitted below.
  • the diameter of the conductor 100 may be appropriately selected depending on the capacity of the cable including the conductor 100, and the thickness of the insulating layer 200 may be appropriately selected depending on the voltage of the cable including the same.
  • the automobile cable when the conductor has a standard of 0.35SQ to 1.0SQ, the automobile cable may satisfy Equations 1 and 2 below.
  • Equation 1 X 1 means the evaluation value of scrape abrasion resistance of the automobile cable measured according to ISO 19642 standard when the size of the conductor is 0.35SQ, and X 2 is the standard of ISO 19642 when the size of the conductor is 0.5SQ.
  • X 3 means the evaluation value of the scrape abrasion resistance of the automobile cable measured according to the ISO 19642 standard when the size of the conductor is 0.75SQ
  • X 4 is the evaluation value of the scrape abrasion resistance of the conductor
  • the standard is 1.0SQ
  • Y means the flame retardance evaluation value of the automobile cable measured according to the ISO 19642 standard.
  • Equations 1 and 2 scrape abrasion resistance and flame retardancy according to ISO 19642, a new standard among international standardization standards for automobile electric wires, respectively, can be confirmed.
  • the automobile cable is a thin wire (0.35SQ to 1.0SQ) Since scrape abrasion resistance and flame retardancy, which are typical physical properties required as a form, can be secured at the same time, product applicability can be improved.
  • the wear resistance evaluation value required in Equation 1 that is, the "scrape abrasion resistance evaluation value”
  • the “scrape abrasion resistance evaluation value” it is a value that may vary depending on the specification of the conductor, for example, when the specification of the conductor is 0.5SQ, 300 times or more, In the case of 0.75SQ, it can be based on the evaluation value of the scrape wear resistance of more than 350 times and when it is 1.0SQ, more than 400 times of scrape wear resistance. Likewise, since all of the above criteria can be satisfied, product applicability is very good.
  • an automotive cable sample including an insulation layer prepared therefrom was prepared using the insulation composition for vehicle cables for each Example and Comparative Example.
  • a compound was prepared by mixing at 150° C. for 30 minutes using a kneader facility (capacity 3L) at the same component and content ratio as in [Table 1], and using the prepared compound, a single screw extruder ( ⁇ : 45) mm) to prepare a wire.
  • a single screw extruder ⁇ : 45
  • 0.35SQ (thin wire) wire was applied to the annealed wire, and the prepared sample was subjected to an electron beam crosslinking process, and then the physical properties described below were evaluated.
  • scrape abrasion resistance was evaluated based on ISO 19642 standards. In addition, the scrape abrasion resistance was evaluated in the same manner with the conductors being 0.5SQ, 0.75SQ and 1.0SQ.
  • 0.35SQ is suitable for automotive wire applications if the wire pressed with a load of 7N rubs against the scrape and does not energize while passing at least 150 times (scrape abrasion resistance evaluation value) reciprocating.
  • the "evaluation value of scrape abrasion resistance” means the number of reciprocations of scrape when energized in the aforementioned evaluation of scrape wear resistance, and according to the standard of the conductor, 0.5SQ is 300 times or more, 0.75SQ is 350 or more and 1.0SQ are based on the evaluation of scrape abrasion resistance of 400 or more.
  • heat resistance is divided into long-term heat resistance and short-term heat resistance, and long-term heat resistance is to check whether insulation breakdown does not occur while applying a voltage of 1 kV in water for 1 minute after the sample is kept at 150 ° C./3,000 hr, and short-term heat resistance is the sample After staying at 175 ° C./240 hr, it is again retained in a -25 ° C chamber for 4 hours, and then it is checked whether it passes the low temperature bending test.
  • long-term heat resistance should not cause dielectric breakdown while applying a voltage of 1 kV in water for 1 minute after holding the sample at 150°C/3,000hrs, and short-term heat resistance is -25°C after staying at 175°C/240hrs of the sample. If it passes the low temperature bending test in the chamber, it is suitable for automotive wire applications.
  • the low-temperature winding is hung on the sample according to the size of each conductor in an oven at -40°C and the weight specified in the specification is wound after staying in the chamber for 4 hours. It is to check whether insulation breakdown does not occur while applying a voltage of 1 kV among them.
  • the low-temperature winding does not generate cracks by hanging the weight specified in the standard according to the size of each conductor in an oven at -40°C and winding it after staying in the chamber for 4 hours, and then 1kV in water for 1 minute. If insulation breakdown does not occur while applying a voltage of
  • the flame retardancy is, the sample and the burner are fixed at an angle of 45° from the ground, and the sample and the burner are perpendicular to each other, and then the burner flame is applied to the sample for 15 seconds to achieve a combustion length of 550 mm or less within 30 seconds. It is to check whether it is digested.
  • the sample and the burner fix the sample and the burner at an angle of 45° from the ground, but make sure that the sample and the burner are perpendicular to each other, and then apply the burner flame to the sample for 15 seconds and within 30 seconds (flammability evaluation value). If it is extinguished with a combustion length of 550 mm or less, it is suitable for automotive wire applications.
  • the "flammability evaluation value" refers to the time that the sample burned in the above-described flame retardancy evaluation is extinguished by itself.
  • the sandpaper abrasion resistance is measured using a sandpaper tape with a conductive band of 5 mm to 10 mm perpendicular to the edge of the sandpaper at a maximum interval of 75 mm, and the wire pressed with a load of 0.1 kg rubs against the sandpaper by 250 mm It is to check whether electricity is not applied while passing (sandpaper abrasion resistance evaluation value).
  • the "sandpaper abrasion resistance evaluation value” refers to a length through which the sandpaper passes while rubbing against the sample.
  • the high temperature pressure is, after applying a load of 0.6N to the sample with a blade-shaped blade in an oven at 150° C. for 4 hours, whether cracks occur and whether a crack occurs after applying a voltage of 1 kV in water for 1 minute. It is to check whether insulation breakdown occurs.
  • the low-temperature impact was performed by placing the device located on the foam rubber pad together with the sample in a freezer (-15°C) for 4 hours, then dropping the hammer from a height of 100 mm to apply the impact, and whether or not cracks occurred If it does not occur, it is to check whether insulation breakdown occurs while applying a voltage of 1kV in water for 1 minute.
  • the device placed on the foam rubber pad is placed in the freezer together with the sample for 4 hours, then the hammer is dropped from a height of 100 mm and impact is applied. If insulation breakdown does not occur while voltage is applied, it is suitable for automotive wire applications.
  • thermal shock was evaluated according to ISO 19642 standard.
  • the thermal shock is performed by winding the sample on a mandrel that is 1.5 times the outer diameter of the sample in an oven at 200° C., and hanging a weight specified in the specification according to the size of each conductor on the sample, staying in the chamber for 6 hours, and winding it to crack It is to check whether or not dielectric breakdown occurs while applying a voltage of 1kV in water for 1 minute after that if cracks do not occur.
  • the sample is wound on a mandrel that is 1.5 times the outer diameter of the sample in an oven at 200°C, a weight specified in the specification is hung on the sample according to the size of each conductor, stayed in the chamber for 6 hours, and then wound If cracks do not occur and insulation breakdown does not occur while applying a voltage of 1kV in water for 1 minute, it is suitable for automotive wire applications
  • the insulation composition for automobile cables according to the present invention scrape wear resistance, heat resistance, low temperature winding, flame retardancy, sandpaper abrasion resistance, high temperature pressure, It can satisfy both the criteria of low-temperature shock and thermal shock properties.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Insulated Conductors (AREA)

Abstract

La présente invention concerne : une composition isolante pour câbles de véhicule ; et un câble de véhicule fabriqué à l'aide de celle-ci. Lorsqu'une couche isolante fabriquée à partir de la composition isolante pour câbles de véhicule est incluse dans un câble de véhicule, le câble de véhicule peut atteindre un excellent niveau de résistance à l'abrasion et d'ininflammabilité, qui sont des propriétés physiques que des câbles de véhicule de toutes normes nécessitent pour répondre aux normes internationales (ISO19642), lorsqu'ils sont appliqués sous la forme d'un fil mince (0,35 SQ à 1,0 SQ). Le câble de véhicule peut être fabriqué sans modifications significatives du processus de fabrication et peut ainsi réduire les coûts de fabrication et augmenter l'efficacité de fabrication.
PCT/KR2021/000854 2020-01-22 2021-01-21 Composition isolante pour câbles de véhicule et câble de véhicule fabriqué à l'aide de celle-ci WO2021150042A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR20200008472 2020-01-22
KR10-2020-0008472 2020-01-22
KR10-2021-0008678 2021-01-21
KR1020210008678A KR20210095077A (ko) 2020-01-22 2021-01-21 자동차 케이블용 절연 조성물 및 이를 이용하여 제조된 자동차 케이블

Publications (1)

Publication Number Publication Date
WO2021150042A1 true WO2021150042A1 (fr) 2021-07-29

Family

ID=76992637

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2021/000854 WO2021150042A1 (fr) 2020-01-22 2021-01-21 Composition isolante pour câbles de véhicule et câble de véhicule fabriqué à l'aide de celle-ci

Country Status (1)

Country Link
WO (1) WO2021150042A1 (fr)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010061908A (ko) * 1999-12-30 2001-07-07 권문구 고온용 폴리올레핀 난연 절연 조성물
KR20040098415A (ko) * 2003-05-15 2004-11-20 엘지전선 주식회사 비할로겐계 난연 조성물 및 이를 이용한 자동차용 전선
KR100716381B1 (ko) * 2006-02-15 2007-05-11 엘에스전선 주식회사 전선 피복용 절연재 제조용 조성물 및 이를 이용하여제조된 전선
JP2010108683A (ja) * 2008-10-29 2010-05-13 Sumitomo Wiring Syst Ltd 絶縁電線
KR20190119706A (ko) * 2018-04-13 2019-10-23 경기대학교 산학협력단 난연제 및 이를 포함하는 열가소성 수지 조성물

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010061908A (ko) * 1999-12-30 2001-07-07 권문구 고온용 폴리올레핀 난연 절연 조성물
KR20040098415A (ko) * 2003-05-15 2004-11-20 엘지전선 주식회사 비할로겐계 난연 조성물 및 이를 이용한 자동차용 전선
KR100716381B1 (ko) * 2006-02-15 2007-05-11 엘에스전선 주식회사 전선 피복용 절연재 제조용 조성물 및 이를 이용하여제조된 전선
JP2010108683A (ja) * 2008-10-29 2010-05-13 Sumitomo Wiring Syst Ltd 絶縁電線
KR20190119706A (ko) * 2018-04-13 2019-10-23 경기대학교 산학협력단 난연제 및 이를 포함하는 열가소성 수지 조성물

Similar Documents

Publication Publication Date Title
EP2417194A2 (fr) Composition de polyéthylène non réticulé pour câble d'alimentation
KR102482859B1 (ko) 내한성 및 유연성이 우수한 절연 조성물 및 이로부터 형성된 절연층을 포함하는 케이블
EP3955265A1 (fr) Câble résistant au feu à agencement à double couche d'isolation
KR101496967B1 (ko) 실리콘 함유 열가소성 엘라스토머 조성물, 이를 이용하여 제조된 절연체 및 이를 포함하는 전선 및 케이블
WO2021150042A1 (fr) Composition isolante pour câbles de véhicule et câble de véhicule fabriqué à l'aide de celle-ci
WO2021150070A1 (fr) Composition isolante pour câble de véhicule et câble de véhicule fabriqué en l'utilisant
WO2021133052A1 (fr) Composition de résine isolante à base de polyoléfine retardatrice de flamme à faible toxicité, fil électrique isolé et procédé de production de fil électrique isolé
WO2018151421A1 (fr) Composition de polymère pour câble haute tension, et câble comprenant une couche d'isolation et une couche de gaine qui sont constituées de celle-ci
JP2012057075A (ja) 剥離性を有する難燃性組成物、難燃性樹脂の製造方法および絶縁電線
WO2020213942A1 (fr) Câble comprenant une couche isolante formée à partir d'une composition isolante ayant une excellente flexibilité et une excellente résistance à l'huile
WO2020145738A1 (fr) Câble hautement ignifuge
WO2020251225A1 (fr) Composition de résine pour isolation externe de câble aérien, câble aérien comprenant une isolation externe de câble aérien fabriquée à partir de celle-ci, et son procédé de fabrication
EP0084048A4 (fr) Compositions de retardement de flamme, procede de preparation et leurs produits de cables et fils.
WO2020138956A1 (fr) Composition de résine pour gaine de câble et fil électrique la comprenant
WO2019035526A1 (fr) Composition de gaine présentant une ininflammabilité et une résistance à l'eau, et câble comportant une couche de gaine formée à partir de celle-ci
KR101781643B1 (ko) 고난연성 절연재료 조성물
JP2000336225A (ja) 難燃性樹脂組成物およびそれを用いた電線・ケーブル
WO2013100414A1 (fr) Composition de résine thermoplastique et produit moulé la comprenant
JPH03203123A (ja) 難燃性電線・ケーブル
WO2016104888A1 (fr) Composition isolante sans halogène possédant une excellente résistance aux huiles et une excellente résistance au froid, et fil comprenant une couche isolante formée à partir de cette composition
WO2013100349A1 (fr) Composition de résine thermoplastique ininflammable et produit moulé comprenant celle-ci
KR20200078402A (ko) 용이하게 박리가능한 반도전층을 포함하는 케이블
KR20160087188A (ko) 우수한 내화 성능을 갖는 통신 케이블
JP7159913B2 (ja) 絶縁電線およびケーブル
KR100836990B1 (ko) 전선 피복용 절연재 제조용 조성물 및 이를 이용하여제조된 전선

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 21743765

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 21743765

Country of ref document: EP

Kind code of ref document: A1