WO2021106461A1 - 脱水装置、脱水圧縮システム、co2回収システム、および脱水装置の制御方法 - Google Patents
脱水装置、脱水圧縮システム、co2回収システム、および脱水装置の制御方法 Download PDFInfo
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- WO2021106461A1 WO2021106461A1 PCT/JP2020/040033 JP2020040033W WO2021106461A1 WO 2021106461 A1 WO2021106461 A1 WO 2021106461A1 JP 2020040033 W JP2020040033 W JP 2020040033W WO 2021106461 A1 WO2021106461 A1 WO 2021106461A1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1412—Controlling the absorption process
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/02—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in boilers or stills
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
- B01D3/143—Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1418—Recovery of products
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1425—Regeneration of liquid absorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1475—Removing carbon dioxide
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/18—Absorbing units; Liquid distributors therefor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/26—Drying gases or vapours
- B01D53/263—Drying gases or vapours by absorption
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
Definitions
- the present disclosure relates to a dehydrator, a dehydration compression system, a CO 2 recovery system, and a method for controlling the dehydrator that removes water from a process gas containing water.
- enhanced oil as an effective use of CO 2 dehydrated and compressed by a dehydration / compression system (for example, Patent Document 1) that recovers CO 2 from exhaust gas emitted from industrial equipment such as boilers and gas turbines and dehydrates / compresses it. It is planned to use the Enhanced Oil Recovery (EOR) method to press-fit the oil into the oil field or store it in the submerged layer to take measures against global warming.
- EOR Enhanced Oil Recovery
- the present disclosure has been made in view of such circumstances, and even when the inside of the absorbing portion is not sufficiently pressurized by the process gas, a treatment for removing water from the process gas with a dehydrating agent is performed. It is an object of the present invention to provide a dehydrator, a dehydration compression system, a CO 2 recovery system, and a control method for the dehydrator, which can prevent defects such as corrosion from occurring in the equipment on the downstream side.
- the dehydrator is a dehydrator that removes the water from a process gas containing water compressed by a compressor, and brings the process gas into contact with the dehydrating agent to form the dehydrating agent.
- An absorption unit that absorbs the water and removes the water from the process gas, a first pressure detection unit that detects the pressure inside the absorption unit, and the dehydrating agent in which the water is absorbed by the absorption unit.
- a distillation unit that heats to separate the water from the dehydrating agent, a transfer line that conveys the dehydrating agent from the absorption unit to the distillation unit, and a transfer line that is arranged in the transfer line and is conveyed from the absorption unit.
- a transfer pump that sucks a dehydrating agent and discharges it toward the distillation unit, a first bypass line that connects the transfer line on the upstream side of the transfer pump and the transfer line on the downstream side of the transfer pump, and the first bypass line.
- a first on-off valve arranged in one bypass line, a control unit for controlling the transfer pump and the first on-off valve, and the control unit have a first pressure detected by the first pressure detecting unit. When the pressure is lower than the predetermined pressure, the first on-off valve is closed and the transfer pump is controlled to operate. When the pressure detected by the first pressure detection unit is equal to or higher than the first predetermined pressure, the first pressure is detected. The on-off valve is opened and the transfer pump is controlled to be stopped.
- the control method of the dehydrator is a control method of the dehydrator for removing the moisture from the process gas containing the moisture compressed by the compressor, and the dehydrator is the process gas and dehydration.
- the dehydrating agent is brought into contact with the agent to heat the absorbing portion that causes the dehydrating agent to absorb the water and remove the water from the process gas, and the dehydrating agent that has absorbed the water in the absorbing unit.
- a distillation unit that separates the water from the absorption unit, a transfer line that conveys the dehydrating agent from the absorption unit to the distillation unit, and a transfer agent that is arranged in the transfer line and that is conveyed from the absorption unit is sucked.
- the transfer pump that discharges toward the distillation unit, the first bypass line that connects the transfer line on the upstream side of the transfer pump and the transfer line on the downstream side of the transfer pump, and the first bypass line are arranged.
- the first on-off valve is the first on-off valve when the pressure detected in the first control step of closing the first on-off valve and controlling the operation of the conveyor pump and the first pressure detection step is equal to or higher than the first predetermined pressure.
- a second control step of controlling the transfer pump to stop the transfer pump is provided.
- a process of removing water from the process gas with a dehydrating agent is performed to cause problems such as corrosion in the equipment on the downstream side.
- a dehydrator, a dehydration compression system, a CO 2 recovery system, and a method for controlling the dehydrator can be provided, which can prevent the occurrence of the gas.
- FIG. 1 is a schematic diagram of a CO 2 recovery apparatus installed in the CO 2 recovery system.
- the CO 2 recovery device 12 includes a cooling tower 14, a CO 2 absorption tower 22, and an absorption liquid regeneration tower 30.
- exhaust gas containing CO 2 emitted from industrial equipment such as a boiler or a gas turbine is supplied to the cooling tower 14 by a blower (not shown).
- the exhaust gas supplied to the cooling tower 14 is cooled by the cooling water.
- the cooling water used to cool the exhaust gas is supplied to the cooling tower 14 again through the cooler 18 by the pump 16 and injected in the tower.
- the cooled CO 2- containing exhaust gas is supplied from the lower part of the CO 2 absorption tower 22 via the exhaust gas line 20.
- a CO 2 absorption liquid (amine solution) based on alkanolamine is in countercurrent contact with the exhaust gas while passing through the filler 23.
- CO 2 in the exhaust gas is absorbed by the CO 2 absorbing liquid, and CO 2 is removed from the exhaust gas discharged from the industrial equipment.
- Purifying gas from which CO 2 has been removed is discharged from the top 22a of the CO 2 absorption tower 22.
- a mist eliminator 24 is provided above the CO 2 absorption tower 22 to condense the water vapor and the like and separate and remove it from the purification gas.
- the CO 2 absorption tower 22 is provided with a cooler 26 attached to the outside of the CO 2 absorption tower 22 and a pump 28 for circulating a part of condensed water between the cooler 26.
- the condensed water or the like cooled by the cooler 26 and supplied to the upper part of the CO 2 absorption tower 22 keeps the mist eliminator 24 at a low temperature, so that the purified gas passing through the mist eliminator 24 is cooled more reliably.
- the heat exchanger 36 heats the rich solution and cools the lean solution.
- CO 2 absorbent having absorbed CO 2 (rich solution) CO 2 is released by the endothermic reaction by countercurrent contact between passing through the filler 34 in the absorbent regenerator 30.
- rich solution reaches the bottom 30b of the absorption liquid regeneration tower 30
- most of the CO 2 is removed and the rich solution is regenerated as a lean solution.
- the regenerated lean solution is supplied as a CO 2 absorption liquid to the CO 2 absorption tower 22 again by a pump 38 via a lean solution cooling device (not shown) and reused.
- Lean solvent regenerated in the absorption regenerator 30 to emit CO 2 is refluxed by the pump 38 through the feed line L 2 in the CO 2 absorber 22. While the lean solution is refluxed, it is cooled by exchanging heat with the absorption liquid supplied from the CO 2 absorption tower 22 to the absorption liquid regeneration tower 30 in the heat exchanger 36, and further, a water-cooled cooler. 40 cools to a temperature suitable for absorbing CO 2.
- L 3 is a CO 2 emission line connected to the top portion 30 a of the absorption liquid regeneration tower 30.
- CO 2 discharged from the absorbent regenerator 30 by CO 2 discharge line L 3 is cooled through a cooler 42 using cooling water supplied to the scrubber 43.
- the CO 2 supplied to the scrubber 43 is separated from the water vapor.
- the separated CO 2 is supplied to the dehydration compression system 10.
- the condensed water separated in the scrubber 43 is returned to the upper part of the absorption liquid regeneration tower 30 by the pump 44.
- the refluxed condensed water cools the condensed portion 46 and suppresses the release of CO 2 absorbing liquid and the like.
- a part of the CO 2 absorbing solution stored in the bottom portion 30b of the absorbent regenerator 30 is supplied to reboiler 48 through the circulation passage L 4, which is heated by heat exchange with high-temperature steam flowing through the steam pipe 48a Later, it is returned to the absorption liquid regeneration tower 30.
- This heating CO 2 is released from the CO 2 absorbing solution in the bottom of the column 30b, also, CO 2 is released from the CO 2 absorbing solution also between indirect gas-liquid contact on the filler 34 to be heated ..
- FIG. 2 is a block diagram of the dehydration compression system according to the first embodiment.
- the dehydration compression system 10 includes a plurality of compressors 50 that compress the process gas supplied from the CO 2 recovery device 12.
- the plurality of compressors 50 are connected in series with respect to the flow of process gas.
- This process gas is CO 2 containing H 2 O.
- the dehydration compression system 10 of FIG. 2 is a case where the dehydration device 60 is installed between adjacent compressors among a plurality of compressors 50.
- the present embodiment will be described with reference to the compressor on the upstream side of the dehydrator 60 as a “compressor on the front stage side” and the compressor on the downstream side of the dehydrator device 60 as a “compressor on the rear stage side”.
- four compressors 50-1 to 50-4 are installed, and the dehydration device 60 is connected between the compressor 50-2 and the compressor 50-3.
- the compressors 50-1 and 50-2 constitute the compressor on the front stage side
- the compressors 50-3 and 50-4 constitute the compressor on the rear stage side.
- the number of compressors is not limited to four.
- the installation position of the dehydrator 60 is not limited to FIG.
- the dehydrator 60 may be installed between the compressor 50-1 and the compressor 50-2.
- the dehydrator 60 may be installed on the upstream side of the plurality of compressors 50 (that is, the upstream side of the compressor 50-1), and may be installed on the downstream side of the plurality of compressors 50 (that is, the compressor 50-4). It may be installed on the downstream side).
- Compressors 50-1 to 50-4 are provided with coolers 52-1 to 52-4 on the downstream side of the gas, respectively.
- the coolers 52-1 to 52-4 cool the process gas heated by being compressed by the compressors 50-1 to 50-4.
- the compressor 50-1 on the most upstream side is connected to the scrubber 54-1 on the upstream side.
- the scrubber 54-1 removes the H 2 O mist associated with the CO 2 recovered by the CO 2 recovery device 12 from the scrubber 43.
- scrubbers 54-2 and 54.3 are installed on the downstream side of the coolers 52-1 and 52-2.
- the scrubbers 54-2 and 54-3 recover the condensed H 2 O by reducing the saturation rate of H 2 O by compression.
- the compressor 50-1 and the compressor 50-2 arranged on the upstream side of the dehydrator 60 have members made of stainless steel including an inner peripheral surface that comes into contact with the process gas.
- a member including an inner peripheral surface in contact with the process gas is formed of carbon steel.
- the compressor 50-1 and the compressor 50-2 are made of stainless steel in order to increase the resistance to corrosion by moisture because the process gas containing moisture is supplied from the CO 2 recovery device 12. ..
- the compressor 50-3 and the compressor 50-4 are made of carbon steel because the process gas from which the water content has been removed is supplied by the dehydrator 60, so that there is no influence of corrosion due to the water content.
- the dehydrator 60 of the present embodiment includes an absorption column (absorption unit) 62, a distillation column (distillation unit; Still still) 72, a dehydrating agent transfer pump 73, a flash drum (evaporation unit) 74, a reboiler 82, and the like.
- a dehydration control device (control unit) 90 is provided.
- the absorption tower 62 is a device that brings CO 2 which is a process gas into contact with a dehydrating agent to allow the dehydrating agent to absorb water and remove the water from the process gas.
- the distillation column 72 is a device that separates water from the dehydrating agent by heating the dehydrating agent in which the water is absorbed in the absorbing tower 62.
- CO 2 (process gas) after being compressed by the compressor 50-2 is supplied into the absorption tower 62 from the lower part of the absorption tower 62 via the CO 2 supply line L 11.
- the filler 64 is housed inside the absorption tower 62, and the dehydrating agent is sprayed from the upper part of the filler.
- Dehydrating agent is a liquid that can be absorbed of H 2 O in CO 2, and the like specifically triethylene glycol (TEG), diethylene glycol (the DEG). While the sprayed dehydrating agent passes through the filler 64, CO 2 and the dehydrating agent come into countercurrent contact. As a result, H 2 O in CO 2 is absorbed by the dehydrating agent. In addition, a part of CO 2 (about 0.2 to 5%) is absorbed by the dehydrating agent.
- a mist eliminator 66 is installed on the upper part of the absorption tower 62. After H 2 O is removed, CO 2 (dry CO 2 ) passes through the mist eliminator 66 and is discharged to the dry CO 2 supply line (dry CO 2 transport path; discharge line) L 12 .
- the dry CO 2 discharged from the absorption tower 62 is cooled through the cooler 68 provided in the dry CO 2 supply line L 12, and then passed through the dry CO 2 supply line L 12 to the compressor 50-3 on the rear stage side. It is supplied to 50-4 and compressed. CO 2 after being compressed by the compressors 50-3 and 50-4 on the latter stage side is used, for example, in enhanced oil recovery (EOR).
- EOR enhanced oil recovery
- the dehydrating agent that has absorbed H 2 O and CO 2 is discharged from the absorption tower 62 through the dehydrating agent transport line L 21 under the filler 64.
- the dehydrating agent transfer line L 21 passes through the inside of the reflux capacitor 70 from the absorption tower 62 and is connected to the flash drum 74.
- the dehydrating agent existing under the filler 64 of the absorption tower 62 includes the pressure Pco inside the absorption tower 62 and the flash described later. Due to the pressure difference from the internal pressure Pfl of the drum 74, the pressure is transferred from the absorption tower 62 to the flash drum 74 via the dehydrating agent transfer line L 21. Here, it is assumed that the pressure Pfl inside the flash drum 74 is maintained at the second predetermined pressure Ppr2.
- the dehydrating agent is released from the absorption tower 62 by the pressure of the process gas itself. It can be conveyed to the flash drum 74 via the dehydrating agent transfer line L 21.
- the absorption tower 62 is provided with a pressure sensor (first pressure detection unit) 69 that detects the pressure inside the absorption tower 62.
- the pressure sensor 69 detects the pressure inside the absorption tower 62 and transmits the detected pressure to the dehydration control device 90.
- a dehydrating agent transporting pump 73 is arranged on the dehydrating agent transporting line L 21 for transporting the dehydrating agent from the absorption tower 62 to the flash drum 74.
- the dehydrating agent transfer pump 73 sucks the dehydrating agent transferred from the absorption column 62 and discharges it toward the distillation column 72.
- the operation of the dehydrating agent transfer pump 73 is controlled by a control signal transmitted from the dehydration control device 90 via a signal line (not shown).
- Dehydrator 60 includes a bypass line (first bypass line) L 25 connecting the upstream side of the dehydrating agent conveying line L 21 and the downstream dehydrating agent conveying line L 21 of the dehydrating agent transport pump 73.
- the dehydrating device 60 includes a first on-off valve 75 arranged at the bypass line (first bypass line) L 25. The open / closed state of the first on-off valve 75 is controlled by a control signal transmitted from the dehydration control device 90 via a signal line (not shown).
- the reflux capacitor 70 accommodates the dehydrating agent transfer line L 21.
- a gas containing high-temperature CO 2 and H 2 O at about 100 to 200 ° C. is circulated in the reflux condenser 70.
- the dehydrating agent passing through the dehydrating agent transport line L 21 is heated by indirectly exchanging heat with the gas containing the high temperature CO 2 and H 2 O.
- the dehydrating agent after heat exchange in the reflux condenser 70 is transferred to the upper part of the flash drum 74 via the dehydrating agent transport line L 21.
- the flash drum 74 is a device arranged between the dehydrating agent transport line L 21 and the dehydrating agent transport line L 22 and depressurizing the dehydrating agent to evaporate CO 2 and H 2 O absorbed by the dehydrating agent. ..
- the flash drum 74 receives a compressed gas (for example, compressed nitrogen, compressed air) having a predetermined pressure (for example, a pressure set in the range of 5 kg / cm 2 or more and 10 kg / cm 2 or less) from the compressed gas supply source 77. Be supplied.
- a compressed gas for example, compressed nitrogen, compressed air
- a predetermined pressure for example, a pressure set in the range of 5 kg / cm 2 or more and 10 kg / cm 2 or less
- the pressure of the process gas supplied from the CO 2 recovery device 12 to the dehydration compression system 10 is lower than the pressure of the compressed gas supplied from the compressed gas supply source 77.
- the compressed gas supply source 77 supplies the flash drum 74 with a compressed gas having a pressure higher than the pressure of the process gas supplied from the CO 2 recovery device 12 to the dehydration compression system 10.
- the flash drum 74 is provided with a pressure sensor (second pressure detection unit) 79 that detects the pressure Pfl inside the flash drum 74.
- the pressure sensor 79 detects the pressure inside the flash drum 74 and transmits the detected pressure to the dehydration control device 90.
- the dehydration control device 90 controls the supply state of the compressed gas by the compressed gas supply source 77 so that the pressure Pfl detected by the pressure sensor 79 becomes the second predetermined pressure Ppr2.
- the second predetermined pressure Ppr2 is lower than the first predetermined pressure Ppr1, and the dehydrating agent existing in the flash drum 74 is transferred from the flash drum 74 to the distillation column 72 in the dehydrating agent transport line L 22 and the dehydrating agent transport line L. It is a pressure that can be conveyed via 23.
- the dehydrating agent present in the flash drum 74 includes the pressure Pfl inside the flash drum 74 and the pressure Psc inside the distillation column 72 when the pressure Pfl inside the flash drum 74 is equal to or higher than the second predetermined pressure Ppr2. Due to the pressure difference between the two, the flash drum 74 is transported to the distillation column 72 via the dehydrating agent transport line L 22 and the dehydrating agent transport line L 23. Here, it is assumed that the pressure Psc inside the distillation column 72 is maintained at the atmospheric pressure Pap.
- the dehydrating agent is released from the flash drum 74 by the pressure of the process gas itself. It can be transported to the distillation column 72 via the dehydrating agent transport line L 22 and the dehydrating agent transport line L 23.
- the dehydrating agent supplied to the flash drum 74 is flushed (flashed) in the flash drum 74. At this time, most of the absorbed CO 2 (80% to 90%) and a small part of H 2 O are desorbed from the dehydrating agent. As a result, CO 2 is recovered from the dehydrating agent.
- the dehydrating agent is stored at the bottom of the flash drum 74. A small amount (10% to 20%) of CO 2 and H 2 O remains absorbed in the dehydrating agent.
- the CO 2 and H 2 O recovered in the flash drum 74 are discharged from the flash drum 74.
- the recovered CO 2 and H 2 O are supplied from, for example, the flash drum 74 to the process fluid flow passage L 41 on the gas upstream side of the compressor 50-1.
- CO 2 recovered by the dewatering device 60, together with the CO 2 recovered in the CO 2 recovering apparatus 12 is compressed by the compressor 50-1, 50-2, and is conveyed again to the dewatering device 60.
- the H 2 O recovered by the dehydrator 60 is removed from the CO 2 by passing through the scrubbers 54-1 to 54-3. The remaining H 2 O is further removed from CO 2 in the absorption tower 62 of the dehydrator 60 as described above.
- the dehydrating agent transfer line L 22 connects the flash drum 74 and the filter 78.
- the dehydrating agent is transported from the bottom of the flash drum 74 to the filter 78 via the dehydrating agent transport line L 22.
- the filter 78 removes solid matter (rust, etc.) contained in the dehydrating agent.
- the dehydrating agent transfer line L 23 connects the filter 78 and the distillation column 72.
- the dehydrating agent is discharged from the filter 78 and transported to the distillation column 72 via the dehydrating agent transport line L 23.
- a heat exchanger 80 is installed in the middle of the dehydrating agent transport line L 23. In the heat exchanger 80, heat exchange is performed between the dehydrating agent discharged from the filter 78 and the dehydrating agent discharged from the reboiler 82 described later. By this heat exchange, the dehydrating agent flowing through the dehydrating agent transport line L 23 is heated to about 150 ° C.
- the distillation column 72 houses the filler 88.
- the dehydrating agent supplied from the dehydrating agent transport line L 23 is heated in the distillation column 72, and CO 2 and H 2 O remaining in the dehydrating agent are released from the dehydrating agent and separated from the dehydrating agent.
- the released CO 2 and H 2 O pass through the reflux capacitor 70 and are discharged from the reflux capacitor 70.
- the released CO 2 and H 2 O are used for heat exchange with the dehydrating agent flowing through the dehydrating agent transport line L 21 when passing through the reflux capacitor 70 as described above.
- the dehydrating agent that has released CO 2 and H 2 O in the distillation column 72 is transported to the reboiler 82 and heated.
- the dehydrating agent transport line L 24 connects the reboiler 82 and the absorption tower 62.
- the heated dehydrating agent is discharged from the reboiler 82 through the dehydrating agent transport line L 24 by the operation of the pump 84.
- heat exchanger 80 of the intermediate position of a dehydrating agent conveying line L 24 heat is exchanged between the dehydrating agent flowing a dehydrating agent conveying line L 23, and a dehydrating agent that flows through the dehydrating agent conveying line L 24. After the heat exchange, the dehydrating agent is cooled by the cooler 86 and then circulated to the absorption tower 62.
- the dehydrating agent transported to the reboiler 82 contains a small amount of CO 2 and H 2 O.
- the reboiler 82 and the distillation column 72 communicate with each other, and the CO 2 and H 2 O released by the reboiler 82 pass through the distillation column 72 and are discharged from the reflux capacitor 70.
- the amount of CO 2 emitted from the reflux capacitor 70 is very small.
- the gas discharged from the reflux condenser 70 is discharged to the outside of the dehydration device 60 system.
- CO 2 generated when the dehydrating agent is regenerated in the dehydrating apparatus 60 is transported to the upstream side of the absorption tower 62 and dehydrated again, so that the amount of CO 2 loss is reduced.
- the dehydration control device 90 is a device that controls each part of the dehydration device 60. As will be described later, the dehydration control device 90 controls the operating state of the dehydrating agent transfer pump 73 and the opening / closing state of the first on-off valve 75 according to the pressure inside the absorption tower 62 transmitted from the pressure sensor 69.
- FIGS. 3 and 4 are flowcharts showing the processes executed by the dehydration compression system 10 according to the present embodiment.
- Each process shown in FIGS. 3 and 4 is executed by a dehydration control device 90 that controls the dehydration device 60 and a compression control device (not shown) that controls a plurality of compressors 50.
- the processes shown in the flowcharts of FIGS. 3 and 4 are processes executed when the dehydration compression system 10 is started.
- the process shown in the flowcharts of FIGS. 3 and 4 is started when the plurality of compressors 50 and the dehydrating device 60 of the dehydration compression system 10 are stopped. Since the plurality of compressors 50 are stopped when the dehydration compression system 10 is started, the process gas supplied from the CO 2 recovery device 12 is not compressed by the compressor 50-1 and the compressor 50-2.
- the process gas supplied to the absorption tower 62 is not compressed, and the compressed gas is not supplied to the flash drum 74. Therefore, the pressure difference between the pressure Pco inside the absorption tower 62 and the pressure Pfl inside the flash drum 74 does not become Ppr1-Ppr2 or more, and the dehydrating agent is flushed from the absorption tower 62 by the pressure of the process gas itself. It cannot be transported to the drum 74 via the dehydrating agent transport line L 21.
- Each process of the flowcharts shown in FIGS. 3 and 4 described below is performed by the dehydrating agent transfer pump 73 when the dehydrating agent cannot be transferred from the absorption tower 62 to the flash drum 74 due to the pressure of the process gas itself. It includes a process of transporting.
- step S101 the dehydration control device 90 controls the supply state of the compressed gas by the compressed gas supply source 77 so as to pressurize the flash drum 74 to the second predetermined pressure Ppr2.
- step S102 the dehydration control device 90 transmits a control signal for causing the pressure sensor 79 to detect the pressure Pfl inside the flash drum 74.
- the dehydration control device 90 detects the pressure Pfl transmitted from the pressure sensor 79 in response to the control signal transmitted to the pressure sensor 79.
- step S103 the dehydration control device 90 determines whether or not the pressure Pfl transmitted from the pressure sensor 79 is equal to or higher than the second predetermined pressure Ppr2. If YES, the process proceeds to step S104, and if NO, the step The process of S101 is executed again.
- step S104 the dehydration control device 90 stops the pressurization of the flash drum 74 by stopping the supply of the compressed gas from the compressed gas supply source 77 to the flash drum 74.
- step S105 the dehydration control apparatus 90, to the first on-off valve 75 provided in the bypass line L 25 closed, controls the first on-off valve 75.
- step S106 the dehydration control device 90 drives the dehydrating agent transport pump 73 to transport the dehydrating agent from the absorption tower 62 to the flash drum 74 via the dehydrating agent transport line L 21.
- the dehydrating agent transport pump 73 discharges the dehydrating agent supplied from the absorption tower 62 toward the flash drum 74, and transports the dehydrating agent via the dehydrating agent transport line L 21.
- the dehydrating agent transfer pump 73 is driven in step S106, the dehydrating agent is transferred from the absorption tower 62 to the flash drum 74. Further, since the pressure inside the flash drum 74 is equal to or higher than the second predetermined pressure Ppr2, the dehydrating agent is conveyed from the flash drum 74 to the distillation column 72. Further, the dehydrating agent is transferred to the absorption tower 62 through the dehydrating agent transport line L 24 by the operation of the pump 84. In this way, the dehydrating agent circulates in the order of the absorption column 62, the flash drum 74, the distillation column 72, and the absorption column 62.
- step S107 the compression control device (not shown) activates all of the plurality of compressors 50 and starts compression of the process gas supplied from the CO 2 recovery device 12.
- the compressor 50-1 and the compressor 50-2 compress the water-containing process gas supplied from the CO 2 recovery device 12, and supply the process gas to the CO 2 supply line L 11 of the dehydration device 60.
- the compressor 50-3 and the compressor 50-4 compress the process gas from which the water supplied from the dehydrator 60 has been removed and supply it to the equipment on the downstream side.
- step S108 the dehydration control device 90 transmits a control signal for causing the pressure sensor 69 to detect the pressure Pco inside the absorption tower 62.
- the dehydration control device 90 detects the pressure Pco transmitted from the pressure sensor 69 in response to the control signal transmitted to the pressure sensor 69.
- step S109 the dehydration control device 90 determines whether or not the pressure Pco transmitted from the pressure sensor 69 is equal to or higher than the first predetermined pressure Ppr1. If YES, the process proceeds to step S110, and if NO, the step The process of S108 is executed again.
- step S110 the dehydration control device 90 transmits a control signal for opening the first on-off valve 75.
- the first on-off valve 75 is opened in response to a control signal transmitted from the dehydration control device 90. Is it first on-off valve 75 and the open state, the pressure Pco becomes the first predetermined pressure Ppr1 above, the pressure of the process gas itself, the dehydrating agent, the dehydrating agent conveying line L 21 from the absorption tower 62 to flash drum 74 This is because it can be transported through.
- step S111 the dehydration control device 90 transmits a control signal for stopping the dehydrating agent transfer pump 73.
- the dehydrating agent transfer pump 73 stops the operation of sucking and discharging the dehydrating agent in response to the control signal received from the dehydration control device 90.
- step S112 the dehydration control device 90 transmits a control signal for causing the pressure sensor 69 to detect the pressure Pco inside the absorption tower 62.
- the dehydration control device 90 detects the pressure Pco transmitted from the pressure sensor 69 in response to the control signal transmitted to the pressure sensor 69.
- step S113 the dehydration control device 90 determines whether or not the pressure Pco transmitted from the pressure sensor 69 is equal to or higher than the first predetermined pressure Ppr1. If YES, the process proceeds to step S114, and if NO, the step The process proceeds to S115.
- step S114 the dehydration control device 90 and the compression control device determine whether or not the operation stop condition for stopping the dehydration compression system 10 is satisfied. If YES, the process proceeds to step S117, and if NO, the process proceeds to step S117. Step S112 is executed again.
- step S115 the dehydration control apparatus 90, to the first on-off valve 75 provided in the bypass line L 25 closed, controls the first on-off valve 75.
- step S116 the dehydration control device 90 drives the dehydrating agent transfer pump 73. Since the pressure Pco inside the absorption tower 62 has fallen below the first predetermined pressure Ppr1, the dehydrating agent is continuously transferred from the absorption tower 62 to the flash drum 74 by driving the dehydrating agent transfer pump 73.
- the dehydrating agent transport pump 73 discharges the dehydrating agent supplied from the absorption tower 62 toward the flash drum 74, and transports the dehydrating agent via the dehydrating agent transport line L 21.
- step S117 since the compression control device satisfies the operation stop condition for stopping the dehydration compression system 10, all of the plurality of compressors 50 are stopped. By stopping the compressor 50, the supply of the process gas from the compressor 50 to the CO 2 supply line L 11 is stopped.
- step S118 the dehydration control device 90 stops the dehydration device 60 because the operation stop condition for stopping the dehydration compression system 10 is satisfied. Each part of the dehydration device 60 stops its operation in response to the control signal transmitted from the dehydration control device 90.
- the absorption tower 62 detected by the pressure sensor 69 at the time of starting when the process gas is supplied in a state where the process gas is not sufficiently compressed by the compressor 50.
- the first on-off valve 75 arranged in the bypass line L 25 connecting the upstream side and the downstream side of the dehydrating agent transfer pump 73 is closed.
- the dehydrating agent transfer pump 73 operates. Therefore, even when the pressure Pco inside the absorption column 62 is lower than the first predetermined pressure Ppr1, the dehydrating agent is transported from the absorption column 62 to the distillation column 72, and the dehydrating agent removes water from the process gas. It can be performed.
- the pressure Pco inside the absorption tower 62 detected by the pressure sensor 69 is equal to or higher than the first predetermined pressure Ppr1, it is arranged on the bypass line L 25 connecting the upstream side and the downstream side of the dehydrating agent transfer pump 73.
- the first on-off valve 75 is opened and the dehydrating agent transfer pump 73 is stopped. Therefore, when the pressure Pco inside the absorption column 62 is equal to or higher than the first predetermined pressure Ppr1, the pressure Pco inside the absorption column 62 moves from the absorption column 62 to the distillation column 72 without using the dehydrating agent transfer pump 73.
- the dehydrating agent is transported, and the dehydrating agent can be used to remove water from the process gas.
- the dehydrator 60 even when the inside of the absorption tower 62 is not sufficiently pressurized by the process gas, the process of removing water from the process gas with the dehydrating agent is performed. This can prevent problems such as corrosion from occurring in the equipment on the downstream side.
- FIG. 5 is a block diagram of the dehydration compression system 10A according to the present embodiment. This embodiment is a modification of the first embodiment. Unless otherwise specified below, the present embodiment is the same as that of the first embodiment, and the description below will be omitted.
- the dehydration compression system 10 of the first embodiment supplies compressed gas from the compressed gas supply source 77 to the flash drum 74, and controls the pressure Pfl inside the flash drum 74 to be equal to or higher than the second predetermined pressure Ppr2. there were.
- the dehydration compression system 10A of the present embodiment does not provide the compressed gas supply source 77 and prevents the dehydrating agent from passing through the flash drum 74 when the dehydration compression system 10 is started.
- the dehydrating apparatus 60A of the dehydration compression system 10A has a dehydrating agent transport line L 21 on the upstream side of the flash drum 74 and a dehydrating agent transport line L 22 on the downstream side of the flash drum 74.
- a bypass line (second bypass line) L 26 to be connected is provided.
- Dewatering device 60A is provided with a second on-off valve 76 disposed in the bypass line L 26.
- the open / closed state of the second on-off valve 76 is controlled by a control signal transmitted from the dehydration control device 90 via a signal line (not shown).
- the second on-off valve 76 is closed when the dehydrating agent supplied from the absorption tower 62 is supplied to the flash drum 74 via the dehydrating agent transport line L 21, and is opened when the dehydrating agent is not supplied to the flush drum 74. It becomes a state.
- the dehydrating device 60A is provided on the upstream on-off valve 95 arranged on the dehydrating agent transport line L 21 on the upstream side of the flush drum 74 and on the dehydrating agent transport line L 22 on the downstream side of the flush drum 74. It is provided with a downstream on-off valve 96 to be arranged.
- the upstream on-off valve 95 and the downstream on-off valve 96 are opened when the dehydrating agent supplied from the absorption tower 62 is supplied to the flush drum 74 via the dehydrating agent transport line L 21, and the dehydrating agent is supplied to the flush drum 74. It will be closed if it is not supplied to.
- FIGS. 6 and 7 are flowcharts showing the processes executed by the dehydration compression system 10A according to the present embodiment.
- Each process shown in FIGS. 6 and 7 is executed by a dehydration control device 90 that controls the dehydration device 60A and a compression control device (not shown) that controls a plurality of compressors 50.
- the processes shown in the flowcharts of FIGS. 6 and 7 are processes executed when the dehydration compression system 10A is started, as in the first embodiment.
- the process gas supplied to the absorption tower 62 is not compressed, and the compressed gas is not supplied to the flash drum 74. Therefore, not only the pressure difference between the inside pressure Pfl of the flash drum 74 and PPR1-PPR2 above, the pressure of the process gas itself, the dehydrating agent, the dehydrating agent conveying line L 21 from the absorption tower 62 to flash drum 74 Cannot be transported through.
- the dehydration apparatus 60 of the first embodiment when the dehydration compression system 10 is started, the compressed gas is supplied to the flash drum 74 from the compressed gas supply source 77, so that the pressure difference from the pressure Pfl inside the flash drum 74 is Ppr1. -Ppr2 or more.
- the dehydrating device 60A of the present embodiment prevents the flash drum 74 from passing through when the dehydration compression system 10A is started.
- the dehydration control device 90 opens the second on-off valve 76 and closes the upstream on-off valve 95 and the downstream on-off valve 96 in steps S201 to S203 shown in FIGS. 6 and 7. it is, so as dehydrating agent is transported from the absorption tower 62 through the bypass line L 26 to the distillation column 72.
- step S201 the dehydration control device 90 controls the second on-off valve 76 so as to open the second on-off valve 76 provided on the bypass line L 26.
- step S202 the dehydration control device 90 controls the upstream on-off valve 95 so as to close the upstream on-off valve 95 provided on the dehydrating agent transport line L 21 on the upstream side of the flush drum 74.
- step S203 the dehydration control device 90 controls the downstream on-off valve 96 so as to close the downstream on-off valve 96 provided on the dehydrating agent transport line L 22 on the downstream side of the flush drum 74.
- step S204 the dehydration control device 90 controls the first on-off valve 75 so as to close the first on-off valve 75 provided on the bypass line L 25.
- step S205 the dehydration control device 90 transfers the dehydrating agent from the absorption column 62 to the distillation column 72 by the dehydrating agent transport line L 21 , bypass line L 25 , bypass line L 26 , dehydrating agent transport line L 22 , and dehydrating agent transport line.
- the dehydrating agent transfer pump 73 is driven for transfer via L 23.
- the dehydrating agent transfer pump 73 discharges the dehydrating agent supplied from the absorption column 62 toward the distillation column 72.
- the dehydrating agent transfer pump 73 is driven in step S205, the dehydrating agent is transferred from the absorption column 62 to the distillation column 72. Further, the dehydrating agent is transferred to the absorption tower 62 through the dehydrating agent transport line L 24 by the operation of the pump 84. In this way, the dehydrating agent circulates in the order of the absorption column 62, the distillation column 72, and the absorption column 62.
- step S206 the compression control device (not shown) activates all of the plurality of compressors 50 and starts compression of the process gas supplied from the CO 2 recovery device 12.
- the compressor 50-1 and the compressor 50-2 compress the water-containing process gas supplied from the CO 2 recovery device 12, and supply the process gas to the CO 2 supply line L 11 of the dehydration device 60.
- the compressor 50-3 and the compressor 50-4 compress the process gas from which the water supplied from the dehydrator 60 has been removed and supply it to the equipment on the downstream side.
- step S207 the dehydration control device 90 transmits a control signal for causing the pressure sensor 69 to detect the pressure Pco inside the absorption tower 62.
- the dehydration control device 90 detects the pressure Pco transmitted from the pressure sensor 69 in response to the control signal transmitted to the pressure sensor 69.
- step S208 the dehydration control device 90 determines whether or not the pressure Pco transmitted from the pressure sensor 69 is equal to or higher than the first predetermined pressure Ppr1. If YES, the process proceeds to step S209, and if NO, the step The process of S207 is executed again.
- step S209 the dehydration control device 90 transmits a control signal for opening the first on-off valve 75.
- the first on-off valve 75 is opened in response to a control signal transmitted from the dehydration control device 90. Is it first on-off valve 75 and the open state, the pressure Pco becomes the first predetermined pressure Ppr1 above, the pressure of the process gas itself, the dehydrating agent, the dehydrating agent conveying line L 21 from the absorption tower 62 to flash drum 74 This is because it can be transported through.
- step S210 the dehydration control device 90 transmits a control signal for stopping the dehydrating agent transfer pump 73.
- the dehydrating agent transfer pump 73 stops the operation of sucking and discharging the dehydrating agent in response to the control signal received from the dehydration control device 90.
- step S211 the dehydration control device 90 controls the upstream on-off valve 95 so as to open the upstream on-off valve 95 provided on the dehydrating agent transport line L 21 on the upstream side of the flush drum 74.
- step S212 the dehydration control device 90 controls the downstream on-off valve 96 so as to open the downstream on-off valve 96 provided on the dehydrating agent transport line L 22 on the downstream side of the flush drum 74.
- step S213 the dehydration control device 90 controls the second on-off valve 76 so as to close the second on-off valve 76 provided on the bypass line L 26. Since the second on-off valve 76 is in the closed state and the upstream on-off valve 95 and the downstream on-off valve 96 are in the open state, the dehydrating agent is supplied from the absorption tower 62 to the flush drum 74.
- step S214 the dehydration control device 90 transmits a control signal for causing the pressure sensor 69 to detect the pressure Pco inside the absorption tower 62.
- the dehydration control device 90 detects the pressure Pco transmitted from the pressure sensor 69 in response to the control signal transmitted to the pressure sensor 69.
- step S215 the dehydration control device 90 determines whether or not the pressure Pco transmitted from the pressure sensor 69 is equal to or higher than the first predetermined pressure Ppr1. If YES, the process proceeds to step S216. If NO, the process proceeds to step S216. Proceed to process to S217.
- step S216 the dehydration control device 90 and the compression control device determine whether or not the operation stop condition for stopping the dehydration compression system 10A is satisfied. If YES, the process proceeds to step S222, and if NO, the process proceeds to step S222. Step S214 is executed again.
- step S217 the dehydration control device 90 controls the second on-off valve 76 so as to open the second on-off valve 76 provided on the bypass line L 26.
- step S218 the dehydration control device 90 controls the upstream on-off valve 95 so as to close the upstream on-off valve 95 provided on the dehydrating agent transport line L 21 on the upstream side of the flush drum 74.
- step S219 the dehydration control device 90 controls the downstream on-off valve 96 so as to close the downstream on-off valve 96 provided on the dehydrating agent transport line L 22 on the downstream side of the flush drum 74.
- step S220 the dehydration control device 90 controls the first on-off valve 75 so as to close the first on-off valve 75 provided on the bypass line L 25.
- step S221 the dehydration control device 90 drives the dehydrating agent transfer pump 73. Since the pressure Pco inside the absorption tower 62 has fallen below the first predetermined pressure Ppr1, the dehydrating agent is continuously transferred from the absorption tower 62 to the flash drum 74 by driving the dehydrating agent transfer pump 73.
- the dehydrating agent transport pump 73 discharges the dehydrating agent supplied from the absorption tower 62 toward the flash drum 74, and transports the dehydrating agent via the dehydrating agent transport line L 21.
- step S222 since the compression control device satisfies the operation stop condition for stopping the dehydration compression system 10A, all of the plurality of compressors 50 are stopped. By stopping the compressor 50, the supply of the process gas from the compressor 50 to the CO 2 supply line L 11 is stopped.
- step S223 the dehydration control device 90 stops the dehydration device 60A because the operation stop condition for stopping the dehydration compression system 10A is satisfied. Each part of the dehydration device 60A stops its operation in response to the control signal transmitted from the dehydration control device 90.
- the dehydrator 60A of the present embodiment for example, when the process gas is supplied by the compressor 50 in a state where the process gas is not sufficiently compressed, the pressure inside the absorption tower 62 detected by the pressure sensor 69 is the first.
- the second on-off valve 76 arranged in the bypass line L 26 connecting the upstream side and the downstream side of the flash drum 74 is opened. Therefore, even if the pressure Pfl inside the flash drum 74 is not sufficient to convey the dehydrating agent to the distillation column 72, the dehydrating agent is conveyed from the absorption column 62 to the distillation column 72, and the dehydrating agent causes the process gas. It is possible to carry out a treatment for removing water from the water. Further, the dehydrating agent can be conveyed from the absorption column 62 to the distillation column 72 without providing a pressurizing source for pressurizing the inside of the flash drum 74.
- FIG. 8 is a block diagram of the dehydration compression system 10B according to the present embodiment. This embodiment is a modification of the first embodiment. Unless otherwise specified below, the present embodiment is the same as that of the first embodiment, and the description below will be omitted.
- the dehydration compression system 10 of the first embodiment when the pressure Pfl inside the absorption tower 62 is lower than the first predetermined pressure Ppr1, the dehydrating agent transfer pump 73 is driven to flush the dehydrating agent from the absorption tower 62 to the flash drum 74. It was to be transported to.
- the dehydration compression system 10B of the present embodiment bypasses the absorption tower 62 without passing through the dehydration device 60B until the inside of the absorption tower 62 is pressurized to the first predetermined pressure Ppr1 or more at the time of start-up. ..
- dehydrating apparatus 60A dehydration compression system 10B As shown in FIG. 8, dehydrating apparatus 60A dehydration compression system 10B according to this embodiment, the compressed gas supply source (pressing) 67, a connecting line L 13, a supply valve 97, a connecting valve 98, It is provided with a discharge valve 99.
- the compressed gas supply source 67, the supply valve 97, the connecting valve 98, and the discharge valve 99 are controlled by a control signal transmitted from the dehydration control device 90.
- the compressed gas supply source 67 is a device that supplies a compressed gas (pressurizing gas) to the inside of the absorption tower 62.
- the compressed gas supply source 67 is supplied with a compressed gas (for example, compressed nitrogen, compressed air) having a predetermined pressure (for example, a pressure set in the range of 5 kg / cm 2 or more and 10 kg / cm 2 or less).
- the connecting line L 13 is a pipe that connects the CO 2 supply line L 11 and the dry CO 2 supply line L 12.
- the connecting line L 13 is used to bypass the dehydration device 60B at the time of starting the dehydration compression system 10B until the inside of the absorption tower 62 is pressurized to the first predetermined pressure Ppr1 or higher.
- the supply valve 97 is an on-off valve arranged on the CO 2 supply line L 11 on the downstream side of the connection position with the connection line L 13.
- the supply valve 97 is opened when the process gas is supplied to the dehydrating device 60B, and closed when the process gas is bypassed without being supplied to the dehydrating device 60B.
- Connecting valve 98 is a switch valve which is arranged in connection line L 13. The connecting valve 98 is closed when the process gas is supplied to the dehydrating device 60B, and is opened when the process gas is bypassed without being supplied to the dehydrating device 60B.
- the discharge valve 99 is an on-off valve arranged on the dry CO 2 supply line L 12 on the upstream side of the connection position with the connection line L 13.
- the discharge valve 99 is opened when the process gas is supplied to the dehydrating device 60B, and closed when the process gas is bypassed without being supplied to the dehydrating device 60B.
- FIGS. 9 and 10 are flowcharts showing the processes executed by the dehydration compression system 10B according to the present embodiment.
- Each process shown in FIGS. 9 and 10 is executed by a dehydration control device 90 that controls the dehydration device 60B and a compression control device (not shown) that controls a plurality of compressors 50.
- the processes shown in the flowcharts of FIGS. 9 and 10 are the processes executed when the dehydration compression system 10B is started, as in the first embodiment.
- step S301 the dehydration control device 90 controls the connecting valve 98 so that the connecting valve 98 provided on the connecting line L 13 is opened.
- step S302 the dehydration control device 90 controls the supply valve 97 so that the supply valve 97 provided in the CO 2 supply line L 11 is closed.
- step S303 the dehydration control device 90 controls the discharge valve 99 so as to close the discharge valve 99 provided in the dry CO 2 supply line L 12.
- step S304 the compression control device (not shown) controls the compressor 50 so as to start all the activations of the plurality of compressors 50.
- the compressor 50-1 and the compressor 50-2 compress the process gas containing water supplied from the CO 2 recovery device 12, and supply the process gas from the CO 2 supply line L 11 to the connection line L 13 .
- Compressor 50-3 and the compressor 50-4 it compresses the process gas containing moisture to be supplied from the connecting line L 13, and supplies to the downstream side of the device.
- step S305 the dehydration control device 90 controls the supply state of the compressed gas by the compressed gas supply source 67 so as to pressurize the absorption tower 62 to the first predetermined pressure Ppr1.
- step S306 the dehydration control device 90 transmits a control signal for causing the pressure sensor 69 to detect the pressure Pco inside the absorption tower 62.
- the dehydration control device 90 detects the pressure Pco transmitted from the pressure sensor 69 in response to the control signal transmitted to the pressure sensor 69.
- step S307 the dehydration control device 90 determines whether or not the pressure Pco transmitted from the pressure sensor 69 is equal to or higher than the first predetermined pressure Ppr1. If YES, the process proceeds to step S308. If NO, the process proceeds to step S308. The process of S305 is executed again.
- step S308 the dehydration control device 90 controls the supply state of the compressed gas by the compressed gas supply source 77 so as to pressurize the flash drum 74 to the second predetermined pressure Ppr2.
- step S309 the dehydration control device 90 transmits a control signal for causing the pressure sensor 79 to detect the pressure Pfl inside the flash drum 74.
- the dehydration control device 90 detects the pressure Pfl transmitted from the pressure sensor 79 in response to the control signal transmitted to the pressure sensor 79.
- step S310 the dehydration control device 90 determines whether or not the pressure Pfl transmitted from the pressure sensor 79 is equal to or higher than the second predetermined pressure Ppr2. If YES, the process proceeds to step S311. If NO, the process proceeds to step S311. The process of S308 is executed again.
- step S311 the compression control device determines whether or not all the activations of the plurality of compressors 50 have been completed. If YES, the process proceeds to step S312, and if NO, the process of step S311 is executed again. ..
- step S312 the dehydration control device 90 controls the discharge valve 99 so as to open the discharge valve 99 provided in the dry CO 2 supply line L 12.
- step S313 the dehydration control device 90 controls the supply valve 97 so as to open the supply valve 97 provided in the CO 2 supply line L 11.
- step S314 the dehydration control apparatus 90, a connecting valve 98 provided in the connection line L 13 to the closed state, it controls the connection valve 98.
- the discharge valve 99 and the supply valve 97 are in the open state and the connecting valve 98 is in the closed state, the process gas supplied from the CO 2 recovery device 12 is supplied to the dehydration device 60B via the CO 2 supply line L 11. It becomes a state.
- step S315 the dehydration control device 90 transmits a control signal for causing the pressure sensor 69 to detect the pressure Pco inside the absorption tower 62.
- the dehydration control device 90 detects the pressure Pco transmitted from the pressure sensor 69 in response to the control signal transmitted to the pressure sensor 69.
- step S316 the dehydration control device 90 determines whether or not the pressure Pco transmitted from the pressure sensor 69 is equal to or higher than the first predetermined pressure Ppr1. If YES, the process proceeds to step S317. If NO, the process proceeds to step S317. The process proceeds to S318.
- step S317 the dehydration control device 90 and the compression control device determine whether or not the operation stop condition for stopping the dehydration compression system 10B is satisfied. If YES, the process proceeds to step S321, and if NO, the process proceeds to step S321. Step S315 is executed again.
- step S318 the dehydration control apparatus 90, to the connecting valve 98 provided in the connecting line L 13 in the open state, and controls the connection valve 98.
- step S319 the dehydration control device 90 controls the supply valve 97 so that the supply valve 97 provided in the CO 2 supply line L 11 is closed.
- step S320 the dehydration control device 90 controls the discharge valve 99 so as to close the discharge valve 99 provided in the dry CO 2 supply line L 12.
- step S321 since the compression control device satisfies the operation stop condition for stopping the dehydration compression system 10B, all of the plurality of compressors 50 are stopped. By stopping the compressor 50, the supply of the process gas from the compressor 50 to the CO 2 supply line L 11 is stopped.
- step S322 the dehydration control device 90 stops the dehydration device 60B because the operation stop condition for stopping the dehydration compression system 10B is satisfied. Each part of the dehydration device 60B stops its operation in response to the control signal transmitted from the dehydration control device 90.
- the supply valve 97 is closed and the connecting valve 98 is opened, so that the process gas supplied to the CO 2 supply line L 11 is passed through the connecting line L 13. Te leads to dry CO 2 supply line L 12. Therefore, when the pressure Pco inside the absorption tower 62 is lower than the first predetermined pressure Ppr1, the absorption tower 62 is added by the compressed gas supplied from the compressed gas supply source 67 without supplying the process gas to the absorption tower 62. Can be squeezed.
- the supply valve 97 is opened and the connecting valve 98 is closed to supply CO 2.
- the process gas supplied to the line L 11 is supplied to the absorption tower 62. Therefore, when the pressure Pco inside the absorption tower 62 is equal to or higher than the first predetermined pressure Ppr1, the process gas is supplied to the absorption tower 62, and the pressure Pco inside the absorption tower 62 causes the absorption tower 62 to move to the distillation tower 72.
- a process of transporting the dehydrating agent and removing water from the process gas with the dehydrating agent can be performed.
- the dehydrator (60) described in each of the above-described embodiments is grasped as follows, for example.
- the dehydrator (60) according to the present disclosure removes the moisture from the process gas containing moisture compressed by the compressor (50), brings the process gas into contact with the dehydrating agent, and causes the dehydrating agent to have the moisture.
- the water was absorbed by the absorption tower (62), the first pressure detection unit (69) that detects the pressure inside the absorption unit, and the absorption tower.
- a distillation section (72) that heats the dehydrating agent to separate the water from the dehydrating agent, a transport line (L 21 , L 23 ) that transports the dehydrating agent from the absorbing section to the distilling section, and the transport.
- a transfer pump (73) arranged on a line and sucking the dehydrating agent conveyed from the absorption unit and discharging the dehydrating agent toward the distillation unit, and the transfer line and the transfer pump on the upstream side of the transfer pump.
- a unit (90) is provided, and when the pressure detected by the first pressure detection unit is lower than the first predetermined pressure, the control unit closes the first on-off valve and operates the transfer pump.
- the first on-off valve is opened and the transfer pump is stopped.
- the dehydrator for example, when the process gas is supplied by the compressor in a state where the process gas is not sufficiently compressed, the pressure inside the absorption unit detected by the first pressure detection unit is the first pressure.
- the first on-off valve arranged in the first bypass line connecting the upstream side and the downstream side of the transfer pump is closed and the transfer pump operates. Therefore, even when the pressure inside the absorption unit is lower than the first predetermined pressure, the dehydrating agent is transported from the absorbing unit to the distillation unit, and the dehydrating agent can be used to remove water from the process gas. ..
- the first opening / closing is arranged in the first bypass line connecting the upstream side and the downstream side of the transfer pump.
- the valve opens and the transfer pump stops. Therefore, when the pressure inside the absorption unit is equal to or higher than the first predetermined pressure, the dehydrating agent is transferred from the absorption unit to the distillation unit by the pressure inside the absorption unit without using a transfer pump, and the dehydrating agent processes the process.
- a process for removing water from the gas can be performed.
- the dehydrator According to the dehydrator according to the present disclosure, even when the inside of the absorbing portion is not sufficiently pressurized by the process gas, a process of removing water from the process gas with a dehydrating agent is performed downstream. It is possible to prevent problems such as corrosion from occurring in the equipment on the side.
- the first predetermined pressure is a pressure capable of transporting the dehydrating agent from the absorbing portion to the distillation portion via the transport line.
- the first on-off valve arranged in the first bypass line connecting the upstream side and the downstream side of the transfer pump is closed and the transfer pump operates. To do. Therefore, even when the inside of the absorbing portion is not sufficiently pressurized by the process gas, it is possible to perform a process of removing water from the process gas with a dehydrating agent.
- an evaporating unit (74) arranged on the transport line and depressurizing the dehydrating agent to evaporate the process gas absorbed by the dehydrating agent, and an upstream side of the evaporating unit.
- a second bypass line (L 26 ) connecting the transfer line and the transfer line on the downstream side of the evaporation unit, and a second on-off valve (76) arranged on the second bypass line are provided.
- the control unit controls to open the second on-off valve when the pressure detected by the first pressure detection unit is lower than the first predetermined pressure, and the pressure detected by the first pressure detection unit is the pressure. When the pressure is equal to or higher than the first predetermined pressure, the second on-off valve is controlled to be closed.
- the dehydrator for example, when the process gas is supplied by the compressor in a state where it is not sufficiently compressed, the pressure inside the absorption unit detected by the first pressure detection unit is the first pressure.
- the second on-off valve arranged in the second bypass line connecting the upstream side and the downstream side of the evaporation portion is opened. Therefore, even if the pressure inside the evaporation section is not sufficient to transport the dehydrating agent to the distillation section, the dehydrating agent is transported from the absorbing section to the distillation section, and the dehydrating agent removes water from the process gas. Processing can be performed. Further, the dehydrating agent can be conveyed from the absorbing portion to the distillation portion without providing a pressurizing source for pressurizing the inside of the evaporation portion.
- the second opening / closing is arranged on the second bypass line connecting the upstream side and the downstream side of the evaporation unit.
- the valve is closed. Therefore, when the pressure inside the evaporating part is equal to or higher than the second predetermined pressure and the process gas absorbed by the dehydrating agent can be appropriately evaporated, the process gas absorbed by the dehydrating agent is evaporated before dehydration.
- the agent is transported to the upstream portion, and the dehydrating agent can be used to remove water from the process gas.
- the second predetermined pressure is a pressure capable of transporting the dehydrating agent from the evaporation section to the distillation section via the transport line.
- the second on-off valve arranged in the second bypass line connecting the upstream side and the downstream side of the evaporating portion is opened. Therefore, even when the inside of the evaporation section is not sufficiently pressurized by the process gas, the dehydrating agent is transported from the absorbing section to the distillation section, and the dehydrating agent removes water from the process gas. it can.
- the dehydrator (60) removes the moisture from the process gas containing moisture compressed by the compressor (50), brings the process gas into contact with the dehydrating agent, and causes the dehydrating agent to have the moisture.
- the absorption unit (62) that absorbs the gas to remove the water from the process gas
- the pressure unit (67) that supplies the pressurizing gas to the absorption unit
- the pressure detection that detects the pressure inside the absorption unit.
- a unit (69) a distillation unit (72) that heats the dehydrating agent in which the water is absorbed in the absorption tower to separate the water from the dehydrating agent, and the process gas compressed by the compressor.
- the discharge line (L 12 ) for discharging the process gas, the connecting line (L 13 ) connecting the supply line and the discharge line, and the connecting line are arranged on the supply line on the downstream side of the connecting position with the connecting line. Controls the supply valve (97), the connecting valve (98) arranged in the connecting line, the discharge valve (99) arranged in the discharge line, the supply valve, the connecting valve, and the discharge valve.
- a control unit (90) is provided, and when the pressure detected by the pressure detection unit is lower than a predetermined pressure, the control unit closes the supply valve and the discharge valve and opens the connecting valve. When the pressure detected by the pressure detecting unit is equal to or higher than the predetermined pressure, the supply valve and the discharge valve are opened and the connecting valve is closed.
- the dehydrator for example, when the process gas is supplied by the compressor in a state where the process gas is not sufficiently compressed, the pressure inside the absorption unit detected by the pressure detection unit is higher than the predetermined pressure. When it is low, the supply valve and the discharge valve are closed and the connecting valve is opened, so that the process gas supplied to the supply line is guided to the discharge line via the connecting line. Therefore, when the pressure inside the absorption unit is lower than the predetermined pressure, the absorption unit can be pressurized by the pressurizing gas supplied from the pressurizing unit without supplying the process gas to the absorption unit.
- the predetermined pressure is a pressure capable of transporting the dehydrating agent from the absorbing portion to the distillation portion via the transport line.
- the pressure inside the absorption unit is equal to or higher than the predetermined pressure
- the process gas supplied to the supply line is supplied to the absorption unit. Therefore, the dehydrating agent can be transported from the absorbing portion to the distillation portion by the pressure inside the absorbing portion, and the dehydrating agent can be used to remove water from the process gas.
- the dehydration compression system (10) is derived from the dehydration apparatus according to any one of the above, the first compressor (50-1, 50-2) for compressing a process gas containing water, and the dehydration apparatus.
- a second compressor (50-3, 50-4) for supplying the process gas from which the water has been removed and compressing the process gas is provided.
- the dehydration compression system according to the present disclosure even when the inside of the absorbing portion is not sufficiently pressurized by the process gas, the process of removing water from the process gas with the dehydrating agent can be performed. Therefore, it is possible to prevent the process gas containing water from being supplied to the second compressor that compresses the process gas supplied from the dehydrator, causing problems such as corrosion.
- CO 2 recovery system contacting the exhaust gas and the CO 2 absorbing solution containing CO 2 to remove CO 2 in the flue gas in the CO 2 absorber (22), with the CO 2 absorption tower while compressing the absorbing solution regeneration tower CO 2 from the CO 2 absorbent having absorbed to release the CO 2 and (30), the CO 2 released by the absorbing solution regeneration tower, contained in the CO 2
- the above-mentioned dehydration compression system for removing water is provided.
- the CO 2 recovery system according to the present disclosure even when the inside of the absorption unit is not sufficiently pressurized by the process gas, it is possible to perform a process of removing water from the process gas with a dehydrating agent. Therefore, it is possible to prevent the process gas containing water from being supplied to the second compressor that compresses the process gas supplied from the dehydrator, causing problems such as corrosion.
- the control method of the dehydrator according to the present disclosure is a control method of the dehydrator that removes the water from a process gas containing water compressed by a compressor, and the dehydrator uses the process gas and a dehydrating agent.
- the absorption unit that causes the dehydrating agent to absorb the water and removes the water from the process gas, and the dehydrating agent that has absorbed the water in the absorption tower are heated and the water content is removed from the dehydrating agent.
- a distillation unit that separates the gas, a transfer line that conveys the dehydrating agent from the absorption unit to the distillation unit, and the distillation unit that is arranged in the transfer line and sucks the dehydrating agent that is conveyed from the absorption unit.
- a transfer pump that discharges toward the center, a first bypass line that connects the transfer line on the upstream side of the transfer pump and the transfer line on the downstream side of the transfer pump, and a first bypass line arranged on the first bypass line.
- the first opening / closing step which has an on-off valve and detects the pressure inside the absorbing portion, and the first opening / closing when the pressure detected in the first pressure detecting step is lower than the first predetermined pressure.
- the first on-off valve is opened when the pressure detected in the first control step of closing the valve and controlling the operation of the transfer pump and the pressure detected in the first pressure detection step is equal to or higher than the first predetermined pressure.
- a second control step of controlling the transfer pump to be stopped is provided.
- the control method of the dehydrator according to the present disclosure is a control method of the dehydrator that removes the water from a process gas containing water compressed by a compressor, and the dehydrator uses the process gas and a dehydrating agent.
- An absorption unit that causes the dehydrating agent to absorb the water content to remove the water content from the process gas, a pressurizing unit that supplies a pressurizing gas to the absorption unit, and the absorption tower absorb the water content.
- a distillation unit that heats the dehydrated agent to separate the water from the dehydrating agent, a supply line that supplies the process gas compressed by the compressor to the absorption unit, and a distillation unit from the absorption unit.
- the control method of the dehydrator when the pressure inside the absorption unit is lower than the predetermined pressure, it is absorbed by the pressurizing gas supplied from the pressurizing unit without supplying the process gas to the absorbing unit.
- the part can be pressurized.
- the process gas is supplied to the absorption unit, the dehydrating agent is conveyed from the absorption unit to the distillation unit by the pressure inside the absorption unit, and the process is carried out by the dehydrating agent.
- a process for removing water from the gas can be performed.
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Abstract
Description
図2は、第1実施形態に係る脱水圧縮システムの構成図である。
脱水圧縮システム10は、CO2回収装置12から供給されたプロセスガスを圧縮する複数の圧縮機50を備えている。複数の圧縮機50は、プロセスガスの流れに対して直列に接続されている。このプロセスガスはH2Oを含むCO2である。
次に、本開示の第2実施形態に係る脱水圧縮システム10Aについて図面を参照して説明する。図5は、本実施形態に係る脱水圧縮システム10Aの構成図である。本実施形態は、第1実施形態の変形例である。以下で特に説明する場合を除き、本実施形態は、第1実施形態と同様であるものとし、以下での説明を省略する。
ステップS203で、脱水制御装置90は、フラッシュドラム74の下流側の脱水剤搬送ラインL22に設けられた下流側開閉弁96を閉状態とするよう、下流側開閉弁96を制御する。
ステップS212で、脱水制御装置90は、フラッシュドラム74の下流側の脱水剤搬送ラインL22に設けられた下流側開閉弁96を開状態とするよう、下流側開閉弁96を制御する。
ステップS219で、脱水制御装置90は、フラッシュドラム74の下流側の脱水剤搬送ラインL22に設けられた下流側開閉弁96を閉状態とするよう、下流側開閉弁96を制御する。
次に、本開示の第3実施形態に係る脱水圧縮システム10Bについて図面を参照して説明する。図8は、本実施形態に係る脱水圧縮システム10Bの構成図である。本実施形態は、第1実施形態の変形例である。以下で特に説明する場合を除き、本実施形態は、第1実施形態と同様であるものとし、以下での説明を省略する。
ステップS303で、脱水制御装置90は、ドライCO2供給ラインL12に設けられた排出弁99を閉状態とするよう、排出弁99を制御する。
ステップS313で、脱水制御装置90は、CO2供給ラインL11に設けられた供給弁97を開状態とするよう、供給弁97を制御する。
ステップS319で、脱水制御装置90は、CO2供給ラインL11に設けられた供給弁97を閉状態とするよう、供給弁97を制御する。
ステップS320で、脱水制御装置90は、ドライCO2供給ラインL12に設けられた排出弁99を閉状態とするよう、排出弁99を制御する。
本開示に係る脱水装置(60)は、圧縮機(50)により圧縮された水分を含むプロセスガスから前記水分を除去し、前記プロセスガスと脱水剤とを接触させて、前記脱水剤に前記水分を吸収させて前記プロセスガスから前記水分を除去する吸収部(62)と、前記吸収部の内部の圧力を検出する第1圧力検出部(69)と、前記吸収塔で前記水分が吸収された前記脱水剤を加熱して前記脱水剤から前記水分を分離する蒸留部(72)と、前記吸収部から前記蒸留部へ前記脱水剤を搬送する搬送ライン(L21,L23)と、前記搬送ラインに配置されるとともに前記吸収部から搬送される前記脱水剤を吸引して前記蒸留部へ向けて吐出する搬送ポンプ(73)と、前記搬送ポンプの上流側の前記搬送ラインと前記搬送ポンプの下流側の前記搬送ラインを連結する第1バイパスライン(L25)と、前記第1バイパスラインに配置される第1開閉弁(75)と、前記搬送ポンプおよび前記第1開閉弁を制御する制御部(90)と、を備え、前記制御部は、前記第1圧力検出部が検出する圧力が第1所定圧力よりも低い場合は前記第1開閉弁を閉状態とし前記搬送ポンプを動作させるよう制御し、前記第1圧力検出部が検出する圧力が前記第1所定圧力以上である場合は前記第1開閉弁を開状態とし前記搬送ポンプを停止させるよう制御する。
本開示に係る脱水圧縮システムによれば、吸収部の内部がプロセスガスにより十分に加圧されていない場合であっても、脱水剤によりプロセスガスから水分を除去する処理を行うことができる。そのため、脱水装置から供給されるプロセスガスを圧縮する第2圧縮機に水分を含むプロセスガスが供給されて腐食等の不具合が発生することを防止することができる。
本開示に係るCO2回収システムによれば、吸収部の内部がプロセスガスにより十分に加圧されていない場合であっても、脱水剤によりプロセスガスから水分を除去する処理を行うことができる。そのため、脱水装置から供給されるプロセスガスを圧縮する第2圧縮機に水分を含むプロセスガスが供給されて腐食等の不具合が発生することを防止することができる。
22 CO2吸収塔
30 吸収液再生塔
50,50-1,50-2,50-3,50-4 圧縮機
60,60A,60B 脱水装置
62 吸収塔(吸収部)
67 圧縮気体供給源(加圧部)
69 圧力センサ(第1圧力検出部)
72 蒸留塔(蒸留部)
73 脱水剤搬送ポンプ
74 フラッシュドラム(蒸発部)
75 第1開閉弁
76 第2開閉弁
77 圧縮気体供給源
79 圧力センサ(第2圧力検出部)
84 ポンプ
90 脱水制御装置(制御部)
95 上流側開閉弁
96 下流側開閉弁
97 供給弁
98 連結弁
99 排出弁
L11 CO2供給ライン
L12 ドライCO2供給ライン
L13 連結ライン
L21,L22,L23,L24 脱水剤搬送ライン
L25 バイパスライン(第1バイパスライン)
L26 バイパスライン(第2バイパスライン)
Claims (10)
- 圧縮機により圧縮された水分を含むプロセスガスから前記水分を除去する脱水装置であって、
前記プロセスガスと脱水剤とを接触させて、前記脱水剤に前記水分を吸収させて前記プロセスガスから前記水分を除去する吸収部と、
前記吸収部の内部の圧力を検出する第1圧力検出部と、
前記吸収部で前記水分が吸収された前記脱水剤を加熱して前記脱水剤から前記水分を分離する蒸留部と、
前記吸収部から前記蒸留部へ前記脱水剤を搬送する搬送ラインと、
前記搬送ラインに配置されるとともに前記吸収部から搬送される前記脱水剤を吸引して前記蒸留部へ向けて吐出する搬送ポンプと、
前記搬送ポンプの上流側の前記搬送ラインと前記搬送ポンプの下流側の前記搬送ラインを連結する第1バイパスラインと、
前記第1バイパスラインに配置される第1開閉弁と、
前記搬送ポンプおよび前記第1開閉弁を制御する制御部と、を備え、
前記制御部は、前記第1圧力検出部が検出する圧力が第1所定圧力よりも低い場合は前記第1開閉弁を閉状態とし前記搬送ポンプを動作させるよう制御し、前記第1圧力検出部が検出する圧力が前記第1所定圧力以上である場合は前記第1開閉弁を開状態とし前記搬送ポンプを停止させるよう制御する脱水装置。 - 前記第1所定圧力は、前記吸収部から前記蒸留部まで前記搬送ラインを介して前記脱水剤を搬送させることが可能な圧力である請求項1に記載の脱水装置。
- 前記搬送ラインに配置されるとともに前記脱水剤を減圧して前記脱水剤に吸収された前記プロセスガスを蒸発させる蒸発部と、
前記蒸発部の上流側の前記搬送ラインと前記蒸発部の下流側の前記搬送ラインを連結する第2バイパスラインと、
前記第2バイパスラインに配置される第2開閉弁と、を備え、
前記制御部は、前記第1圧力検出部が検出する圧力が前記第1所定圧力よりも低い場合は前記第2開閉弁を開状態とするよう制御し、前記第1圧力検出部が検出する圧力が前記第1所定圧力以上である場合は前記第2開閉弁を閉状態とするよう制御する請求項1に記載の脱水装置。 - 前記第1所定圧力は、前記吸収部から前記蒸留部まで前記搬送ラインを介して前記脱水剤を搬送させることが可能な圧力である請求項3に記載の脱水装置。
- 圧縮機により圧縮された水分を含むプロセスガスから前記水分を除去する脱水装置であって、
前記プロセスガスと脱水剤とを接触させて、前記脱水剤に前記水分を吸収させて前記プロセスガスから前記水分を除去する吸収部と、
前記吸収部に加圧用気体を供給する加圧部と、
前記吸収部の内部の圧力を検出する圧力検出部と、
前記吸収部で前記水分が吸収された前記脱水剤を加熱して前記脱水剤から前記水分を分離する蒸留部と、
前記圧縮機により圧縮された前記プロセスガスを前記吸収部へ供給する供給ラインと、
前記吸収部から前記蒸留部へ前記脱水剤を搬送する搬送ラインと、
前記吸収部で前記水分が除去された前記プロセスガスを排出する排出ラインと、
前記供給ラインと前記排出ラインとを連結する連結ラインと、
前記連結ラインとの連結位置よりも下流側において前記供給ラインに配置される供給弁と、
前記連結ラインに配置される連結弁と、
前記排出ラインに配置される排出弁と、
前記供給弁、前記連結弁および前記排出弁を制御する制御部と、を備え、
前記制御部は、前記圧力検出部が検出する圧力が所定圧力よりも低い場合は前記供給弁および前記排出弁を閉状態とし前記連結弁を開状態とするよう制御し、前記圧力検出部が検出する圧力が前記所定圧力以上である場合は前記供給弁および前記排出弁を開状態とし前記連結弁を閉状態とするよう制御する脱水装置。 - 前記所定圧力は、前記吸収部から前記蒸留部まで前記搬送ラインを介して前記脱水剤を搬送させることが可能な圧力である請求項5に記載の脱水装置。
- 請求項1から請求項6のいずれか一項に記載の脱水装置と、
水分を含むプロセスガスを圧縮する第1圧縮機と、
前記脱水装置から前記水分が除去された前記プロセスガスが供給されるとともに該プロセスガスを圧縮する第2圧縮機と、を備える脱水圧縮システム。 - CO2を含有する排ガスとCO2吸収液とを接触させて前記排ガス中のCO2を除去するCO2吸収塔と、
前記CO2吸収塔で前記CO2を吸収した前記CO2吸収液から前記CO2を放出させる吸収液再生塔と、
前記吸収液再生塔で放出された前記CO2を圧縮するとともに、前記CO2に含まれる水分を除去する請求項7に記載の脱水圧縮システムと、を備えるCO2回収システム。 - 圧縮機により圧縮された水分を含むプロセスガスから前記水分を除去する脱水装置の制御方法であって、
前記脱水装置は、
前記プロセスガスと脱水剤とを接触させて、前記脱水剤に前記水分を吸収させて前記プロセスガスから前記水分を除去する吸収部と、
前記吸収部で前記水分が吸収された前記脱水剤を加熱して前記脱水剤から前記水分を分離する蒸留部と、
前記吸収部から前記蒸留部へ前記脱水剤を搬送する搬送ラインと、
前記搬送ラインに配置されるとともに前記吸収部から搬送される前記脱水剤を吸引して前記蒸留部へ向けて吐出する搬送ポンプと、
前記搬送ポンプの上流側の前記搬送ラインと前記搬送ポンプの下流側の前記搬送ラインを連結する第1バイパスラインと、
前記第1バイパスラインに配置される第1開閉弁と、を有し、
前記吸収部の内部の圧力を検出する第1圧力検出工程と、
前記第1圧力検出工程で検出された圧力が第1所定圧力よりも低い場合に前記第1開閉弁を閉状態とし前記搬送ポンプを動作させるよう制御する第1制御工程と、
前記第1圧力検出工程で検出された圧力が前記第1所定圧力以上である場合に前記第1開閉弁を開状態とし前記搬送ポンプを停止させるよう制御する第2制御工程と、を備える脱水装置の制御方法。 - 圧縮機により圧縮された水分を含むプロセスガスから前記水分を除去する脱水装置の制御方法であって、
前記脱水装置は、
前記プロセスガスと脱水剤とを接触させて、前記脱水剤に前記水分を吸収させて前記プロセスガスから前記水分を除去する吸収部と、
前記吸収部に加圧用気体を供給する加圧部と、
前記吸収部で前記水分が吸収された前記脱水剤を加熱して前記脱水剤から前記水分を分離する蒸留部と、
前記圧縮機により圧縮された前記プロセスガスを前記吸収部へ供給する供給ラインと、
前記吸収部から前記蒸留部へ前記脱水剤を搬送する搬送ラインと、
前記吸収部で前記水分が除去された前記プロセスガスを排出する排出ラインと、
前記供給ラインと前記排出ラインとを連結する連結ラインと、
前記連結ラインとの連結位置よりも下流側において前記供給ラインに配置される供給弁と、
前記連結ラインに配置される連結弁と、
前記排出ラインに配置される排出弁と、を有し、
前記吸収部の内部の圧力を検出する圧力検出工程と、
前記圧力検出工程で検出された圧力が所定圧力よりも低い場合に前記供給弁および前記排出弁を閉状態とし前記連結弁を開状態とするよう制御する第1制御工程と、
前記圧力検出工程で検出される圧力が前記所定圧力以上である場合に前記供給弁および前記排出弁を開状態とし前記連結弁を閉状態とするよう制御する第2制御工程と、を備える脱水装置の制御方法。
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003260349A (ja) * | 2002-03-11 | 2003-09-16 | Toshiba Corp | 反応容器への被処理流体投入装置 |
JP2007333278A (ja) * | 2006-06-14 | 2007-12-27 | Kajima Corp | 蒸発装置 |
JP2010266155A (ja) * | 2009-05-15 | 2010-11-25 | Ebara Corp | 二酸化炭素液化装置 |
WO2015129628A1 (ja) * | 2014-02-25 | 2015-09-03 | 三菱重工業株式会社 | 脱水圧縮システム及びco2回収システム |
WO2019123969A1 (ja) * | 2017-12-20 | 2019-06-27 | 株式会社神戸製鋼所 | 圧縮機およびその運転方法 |
-
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Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003260349A (ja) * | 2002-03-11 | 2003-09-16 | Toshiba Corp | 反応容器への被処理流体投入装置 |
JP2007333278A (ja) * | 2006-06-14 | 2007-12-27 | Kajima Corp | 蒸発装置 |
JP2010266155A (ja) * | 2009-05-15 | 2010-11-25 | Ebara Corp | 二酸化炭素液化装置 |
WO2015129628A1 (ja) * | 2014-02-25 | 2015-09-03 | 三菱重工業株式会社 | 脱水圧縮システム及びco2回収システム |
US9352273B2 (en) | 2014-02-25 | 2016-05-31 | Mitsubishi Heavy Industries, Ltd. | Dehydration-compression system and CO2 recovery system |
WO2019123969A1 (ja) * | 2017-12-20 | 2019-06-27 | 株式会社神戸製鋼所 | 圧縮機およびその運転方法 |
Non-Patent Citations (1)
Title |
---|
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AU2020394004A1 (en) | 2022-05-12 |
EP4032599B1 (en) | 2024-01-17 |
EP4032599A4 (en) | 2022-11-30 |
CA3162197A1 (en) | 2021-06-03 |
US20210154617A1 (en) | 2021-05-27 |
JPWO2021106461A1 (ja) | 2021-06-03 |
US11192061B2 (en) | 2021-12-07 |
AU2020394004B2 (en) | 2023-05-18 |
JP7250957B2 (ja) | 2023-04-03 |
EP4032599A1 (en) | 2022-07-27 |
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