WO2021100692A1 - Cleaning or hydrophilizing agent composition - Google Patents
Cleaning or hydrophilizing agent composition Download PDFInfo
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- WO2021100692A1 WO2021100692A1 PCT/JP2020/042754 JP2020042754W WO2021100692A1 WO 2021100692 A1 WO2021100692 A1 WO 2021100692A1 JP 2020042754 W JP2020042754 W JP 2020042754W WO 2021100692 A1 WO2021100692 A1 WO 2021100692A1
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- cleaning
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- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 229940099373 sudan iii Drugs 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- RULSWEULPANCDV-PIXUTMIVSA-N turanose Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](C(=O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O RULSWEULPANCDV-PIXUTMIVSA-N 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/8305—Mixtures of non-ionic with anionic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/18—Glass; Plastics
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/40—Specific cleaning or washing processes
- C11D2111/42—Application of foam or a temporary coating on the surface to be cleaned
Definitions
- the present invention relates to a cleaning or hydrophilizing agent composition and a method for cleaning or hydrophilizing a hard surface.
- Anionic surfactants are excellent in detergency and foaming properties, and are widely used as components of detergents.
- an internal olefin sulfonate obtained by using an internal olefin having a double bond inside instead of the end of the olefin chain as a raw material is known.
- the internal olefin sulfonate can be obtained, for example, by reacting the internal olefin with a gaseous sulfur trioxide-containing gas to sulfonate, neutralizing the obtained sulfonic acid, and further hydrolyzing the obtained sulfonic acid.
- Internal olefin sulfonates are known to have good biodegradability.
- a method of imparting antifouling property and decontaminating property to a hard surface a method of hydrophilizing treatment is known.
- the hard surface is hydrophilized, that is, the contact angle of the hard surface with water is lowered to make the hard surface wet easily with water, the dirt adhering to the hard surface after the treatment can be easily removed during cleaning.
- antistatic, prevention of frost formation of aluminum fins of heat exchangers, antifouling property of bathtub and toilet surface decontamination Etc. can be expected.
- US Pat. No. 5,078,916 describes a detergent composition containing an internal olefin sulfonate having 8 to 26 carbon atoms in which at least 25% by weight is in the form of beta-hydroxyalkane sulfonic acid.
- Japanese Unexamined Patent Publication No. 2016-35009 describes a biofilm remover composition for a hard surface containing 1% by mass or more and 40% by mass or less of an internal olefin sulfonate.
- 2016-147928 describes (a) an internal olefin sulfonate having 8 or more carbon atoms and 24 or less carbon atoms, (b) a fatty acid or a salt thereof having 8 or more carbon atoms and 22 or less carbon atoms, and (c) (c1).
- 2016-147927 describes (a) an internal olefin sulfonate having 8 or more carbon atoms and 24 or less carbon atoms, (b) a fatty acid having 8 or more carbon atoms and 22 or less carbon atoms or a salt thereof, and (c) 8 or more carbon atoms. , Amine oxide having a hydrocarbon group of 22 or less, and (d) alkyl succinic acid having an alkyl group having 8 or more carbon atoms and 22 or less carbon atoms, and alkenyl succinic acid having an alkenyl group having 8 or more carbon atoms and 22 carbon atoms or less.
- a dishwashing agent composition for hand washing each containing a salt and a compound selected from these anhydrides under predetermined conditions, and having a mass ratio of (d) / (a) of 0.01 or more and 1 or less. Has been done.
- the present invention provides a cleaning or hydrophilizing agent composition having excellent detergency and capable of imparting hydrophilicity to a hard surface, and a method for cleaning or hydrophilizing a hard surface.
- the present invention is a washing or hydrophilization treatment containing (A) anionic surfactant (hereinafter referred to as (A) component), (B) nonionic surfactant (hereinafter referred to as (B) component), and water. It is an agent composition As the component (A), (A1) branched anionic surfactant (hereinafter referred to as (A1) component), The present invention relates to a cleaning or hydrophilizing treatment agent composition containing (B1) a nonionic surfactant having a hydrocarbon group having 8 or more and 22 or less carbon atoms (hereinafter referred to as (B1) component) as a component (B).
- the present invention is a treatment liquid containing the component (A), the component (B), and water, and the component (A1) is used as the component (A), and the component (B1) is used as the component (B).
- the present invention relates to a method for cleaning or hydrophilizing a hard surface in which the contained treatment liquid is brought into contact with the hard surface.
- a cleaning or hydrophilic treatment agent composition which is excellent in detergency and can impart hydrophilicity to a hard surface, and a method for cleaning or hydrophilizing a hard surface.
- Embodiment for carrying out the invention [cleaning or hydrophilization treatment agent composition] ⁇ Ingredient (A)>
- the component (A) is an anionic surfactant.
- the cleaning or hydrophilizing treatment composition of the present invention contains (A1) a branched anionic surfactant as a component (A).
- the branched anionic surfactant is an anionic surfactant having a branched structure in which a hydrocarbon group, which is a hydrophobic portion, has a branched structure.
- the anionic surfactant has a hydrocarbon group in which the carbon atom bonded to the anionic group which is a hydrophilic portion is a secondary or tertiary carbon atom, the anionic surfactant has a branched structure.
- the content of the component (A) is a value calculated by assuming that the counter ion of the component (A) is a hydrogen ion, that is, an acid type conversion value is used.
- the mass ratio of the component (A) is converted using the acid type conversion value of the content of the component (A).
- Examples of the component (A1) include an anionic surfactant having a branched-chain hydrocarbon group having 8 or more and 30 or less carbon atoms.
- Examples of the component (A1) include an anionic surfactant having a branched chain hydrocarbon group having 8 or more carbon atoms and 30 or less carbon atoms and a sulfate ester group or a sulfonic acid group.
- the number of carbon atoms of the branched chain hydrocarbon group of the component (A1) is preferably 8 or more, more preferably 10 or more, further preferably 16 or more, and preferably 30 or less, more preferably 28 or less, still more preferably 24 or less. , More preferably 22 or less, still more preferably 20 or less.
- Examples of the branched-chain hydrocarbon group of the component (A1) include a branched-chain alkyl group, a branched-chain alkenyl group, and an aryl group having a branched-chain alkyl group.
- component (A1) examples include an anionic surfactant represented by the following general formula (A).
- R 1a and R 2a each independently represent a hydrocarbon group having 1 to 28 carbon atoms which may contain a substituent or a linking group.
- X represents a group selected from SO 3 M, COOM, and OSO 3 M.
- Y represents a single bond or a phenylene group.
- M represents a counterion.
- examples of the hydrocarbon group of R 1a and R 2a include an alkyl group, an alkenyl group and an aryl group. Alkyl or alkenyl groups are preferred.
- the hydrocarbon groups of R 1a and R 2a may contain a substituent such as a hydroxyl group or a linking group such as a COO group.
- the total number of carbon atoms of R 1a and R 2a is preferably 7 or more and 29 or less.
- the carbon number of the substituent or the linking group is not included in the carbon number of the hydrocarbon group of R 1a and R 2a.
- X is preferably SO 3 M.
- M includes alkali metal ion, alkaline earth metal (1/2 atom) ion, ammonium ion or organic ammonium ion.
- alkali metal ions are preferable, sodium ions and potassium ions are more preferable, and potassium ions are even more preferable.
- Y is preferably a single bond.
- component (A1) one selected from internal olefin sulfonate (IOS), linear alkylbenzene sulfonate (LAS), secondary alkane sulfonate (SAS) and dialkyl sulfosuccinate (DASS) or Examples thereof include two or more branched anionic surfactants.
- IOS internal olefin sulfonate
- LAS linear alkylbenzene sulfonate
- SAS secondary alkane sulfonate
- DASS dialkyl sulfosuccinate
- the component (A1) is preferably IOS from the viewpoint of improving cleaning performance and hydrophilicity performance.
- This carbon number is the carbon number in terms of an acid compound.
- IOS include alkali metal salts, alkaline earth metal (1/2 atom) salts, ammonium salts and organic ammonium salts.
- the alkali metal salt include sodium salt and potassium salt.
- alkaline earth metal salts include calcium salts and magnesium salts.
- the organic ammonium salt include an alkanolammonium salt having 2 or more and 6 or less carbon atoms.
- an alkali metal salt is preferable, and a potassium salt is more preferable, from the viewpoint of improving cleaning performance and hydrophilicity performance.
- the IOS of the present invention can be obtained by sulfonation, neutralization, hydrolysis, etc. of an internal olefin having a double bond inside the olefin chain (position of 2 or more positions).
- ⁇ -salton is quantitatively produced, and a part of ⁇ -salton is changed to ⁇ -salton and olefin sulfonic acid, which are further converted into hydroxyalkane sulfone in the neutralization / hydrolysis step. It is converted to an acid salt (H form) and an olefin sulfonate (O form) (for example, J. Am. Oil Chem. Soc. 69, 39 (1992)).
- H form acid salt
- O form olefin sulfonate
- IOS is a mixture of these, mainly a sulfonate in which a sulfonic acid group is present inside a hydrocarbon chain (hydroxyalkane chain in H form or olefin chain in O form) (position of 2 or more positions). is there.
- the substitution position distribution of the sulfonic acid group in the carbon chain of IOS can be quantified by a method such as gas chromatography or nuclear magnetic resonance spectrum.
- the proportion of IOS in which a sulfonic acid group is present at the 2-position of the hydrocarbon chain in IOS is preferably 5% or more, more preferably 5% or more, based on a molar standard or a mass standard, from the viewpoint of improving cleaning performance and hydrophilicity performance. It is 10% or more, preferably 45% or less, and more preferably 30% or less.
- the proportion of IOS in which a sulfonic acid group is present at the 1-position of the hydrocarbon chain in IOS is preferably 0.2% or more, based on a molar standard or a mass standard, from the viewpoint of improving cleaning performance and hydrophilicity performance. It is preferably 0.5% or more, more preferably 1.0% or more, and preferably 20% or less, more preferably 10% or less, still more preferably 5% or less, still more preferably 3% or less.
- the number of carbon atoms in the hydrocarbon chain of IOS is preferably 8 or more, more preferably 10 or more, further preferably 16 or more from the viewpoint of improving hydrophilicity performance, and preferably 22 from the viewpoint of improving cleaning performance. Below, it is more preferably 20 or less. That is, the cleaning or hydrophilizing treatment agent composition of the present invention contains IOS having a hydrocarbon chain having 16 or more and 20 or less carbon atoms as the component (A1) from the viewpoint of improving the cleaning performance and the hydrophilization performance. Is more preferable.
- the proportion of IOS having a hydrocarbon chain having 16 or more and 20 or less carbon atoms in IOS is preferably 50% by mass or more, more preferably 70% by mass or more, still more preferably, from the viewpoint of improving cleaning performance and hydrophilization performance. Is 80% by mass or more, more preferably 90% by mass or more, still more preferably 95% by mass or more, still more preferably 97% by mass or more, and preferably 100% by mass or less, 100% by mass. May be good.
- the molar ratio of H-form to O-form preferably exceeds 50/50, more preferably 70/30, from the viewpoint of improving cleaning performance and hydrophilization performance. And it is preferably 95/5 or less, more preferably 90/10 or less.
- the cleaning or hydrophilizing treatment agent composition of the present invention may contain a component (A) other than the component (A1).
- the ratio of the component (A1) to the component (A) is preferably 30% by mass or more, more preferably 50% by mass or more from the viewpoint of improving the hydrophilic performance. , More preferably 70% by mass or more, even more preferably 90% by mass or more, and preferably 100% by mass or less, and may be 100% by mass.
- the component (B) is a nonionic surfactant.
- the cleaning or hydrophilizing treatment agent composition of the present invention contains (B1) a nonionic surfactant having a hydrocarbon group having 8 or more and 22 or less carbon atoms as a component (B).
- the number of carbon atoms of the hydrocarbon group of the component (B1) is 8 or more, preferably 10 or more from the viewpoint of improving cleaning performance, and 22 or less, preferably 18 or less, more preferably from the viewpoint of improving hydrophilicity performance. Is 16 or less.
- the cleaning or hydrophilizing treatment composition of the present invention contains (B1-1-1) a linear hydrocarbon having 8 or more and 10 or less carbon atoms as a component (B1).
- Nonionic surfactant having a group [hereinafter referred to as (B1-1-1) component], (B1-1-2) Nonionic surfactant having a branched chain hydrocarbon group having 8 or more and 22 or less carbon atoms [hereinafter, (B1-1-2) component], (B1-2) Nonionic surfactant having a linear hydrocarbon group having 11 or more and 22 or less carbon atoms [hereinafter referred to as (B1-2) component], (B1- 3) Nonionic surfactant represented by the following general formula (b4) [hereinafter referred to as (B1-3) component], (B1-4) Nonionic surfactant represented by the following general formula (b5) [hereinafter, (B1-4) component], (B1-5) polyoxyalkylene glycerin fatty acid
- R 7 is a hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms
- R 8 is a hydrogen atom or a methyl group
- the EO group is an ethyleneoxy group
- n4 is the average number of moles added. It is a number selected from a number of 3 or more and 30 or less
- the BO group is a butyleneoxy group
- n5 is an average addition molar number
- EO and BO May be a random polymer or a block polymer.
- R 9 (OA 4) x G y (b5) [In the formula, R 9 is a hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms, OA 4 is one or more groups selected from alkyleneoxy groups, and G is a sugar having 5 or 6 carbon atoms. Derived residues, x is a number whose average value is 0 or more and 5 or less, and y is a number whose average value is 1 or more and 3 or less. ]
- the cleaning or hydrophilic treatment agent composition of the present invention is selected from the (B1-1) component and the (B1-1-2) component as the (B1) component from the viewpoint of improving the cleaning performance and the hydrophilicizing performance. It is more preferable to contain one or more nonionic surfactants [hereinafter referred to as (B1-1) component].
- (B1-1) component even when the carbon atom bonded to the alkyleneoxy group or the like in which the nonionic surfactant is a hydrophilic portion has a hydrocarbon group which is a secondary or tertiary carbon atom, it also has a hydrocarbon group of a branched chain. Use as a nonionic surfactant.
- Examples of the hydrocarbon group of the component (B1-1-1) include a group selected from a linear primary alkyl group and a linear primary alkenyl group. From the component (B1-1-1), the nonionic surfactant corresponding to the component (B1-3), the component (B1-4), and the component (B1-5) is excluded.
- the component (B1-1-1) is preferably a nonionic surfactant having one linear hydrocarbon group having 8 or more and 10 or less carbon atoms from the viewpoint of improving cleaning performance and hydrophilicity performance.
- Examples of the hydrocarbon group of the component (B1-1-2) include a group selected from a branched chain alkyl group, a straight chain secondary alkyl group, a branched chain alkenyl group, and a straight chain secondary alkenyl group. From the component (B1-1-2), the nonionic surfactant corresponding to the component (B1-3), the component (B1-4), and the component (B1-5) is excluded.
- the component (B1-1-2) is preferably a nonionic surfactant having one hydrocarbon group of a branched chain having 8 or more and 22 or less carbon atoms from the viewpoint of improving cleaning performance and hydrophilicity performance.
- the component (B1-1) may be a nonionic surfactant having an HLB of 11.5 or more, further 12.5 or more, and 15.4 or less, further 15.1 or less.
- This HLB is based on the Griffin method.
- HLB refers to HLB calculated by the following formula.
- the average molecular weight of the polyoxyethylene group represents the average molecular weight calculated from the average number of added moles when the number of added moles of the oxyethylene group has a distribution.
- the average molecular weight of the component (B1-1) is a molecular weight calculated by an average value when hydrophobic groups such as hydrocarbon groups have a distribution or when the number of added moles of polyoxyethylene groups has a distribution.
- HLB [(average molecular weight of polyoxyethylene group) / [average molecular weight of (B1-1) component]] ⁇ 20
- the oxyethylene group may be referred to as an ethyleneoxy group.
- the HLB of the component (B1-1) is "Journal of Colloid and Interface Science, Vol.107.No.1, September1985". Refers to those measured according to the method of Kunieda et al. Described in. This document is a method for measuring HLB based on the finding that a specific temperature (THLB) and the number of HLBs due to Griffin have a linear relationship.
- Examples of the component (B1-1-1) include a nonionic surfactant represented by the following general formula (b1).
- R 1- O- (A 1 O) n1- R 2 (b1) [In the formula, R 1 is a linear hydrocarbon group having 8 or more carbon atoms and 10 or less carbon atoms, R 2 is a hydrogen atom or a methyl group, and A 1 O group is one or two selected from alkyleneoxy groups. Based on the above, n1 is the average number of added moles, which is a number selected from 3 or more and 50 or less. ]
- R 1 is a linear hydrocarbon group having 8 or more carbon atoms and 10 or less carbon atoms.
- the carbon number of R 1 is 8 or more from the viewpoint of improving the cleaning performance, and 10 or less, more preferably 10 from the viewpoint of ensuring the hydrophilic performance.
- the linear hydrocarbon group of R 1 a group selected from a linear primary alkyl group and a linear primary alkenyl group is preferable, and a linear primary alkyl group is more preferable.
- R 2 is preferably a hydrogen atom.
- a 1 O group is one or more groups selected from alkyleneoxy group. When two or more kinds of alkyleneoxy groups are contained, it may be a block type bond or a random type bond.
- the A 1 O group is preferably an ethyleneoxy group from the viewpoint of improving the cleaning performance.
- n1 is the average number of added moles, which is a number selected from a number of 3 or more and 50 or less. The larger the number of n1, the higher the HLB value, and the smaller the number, the lower the HLB value.
- n1 is 3 or more, preferably 7 or more, from the viewpoint of improving hydrophilicity performance, and 50 or less, preferably 20 or less, from the viewpoint of improving cleaning performance and ensuring compounding stability of the composition. More preferably, it is 10 or less.
- the component (B1-1-1) is preferably polyoxyalkylene decyl or decenyl ether.
- the oxyalkylene preferably contains oxyethylene.
- the component (B1-1-1) is more preferably polyoxyethylene decyl or decenyl ether.
- Examples of the component (B1-1-2) include a nonionic surfactant represented by the following general formula (b2).
- R 3- O- (A 2 O) n2- R 4 (b2) [In the formula, R 3 is a hydrocarbon group of a branched chain having 8 or more carbon atoms and 22 or less carbon atoms, R 4 is a hydrogen atom or a methyl group, and A 2 O group is one or two selected from alkyleneoxy groups. Based on the above, n2 is the average number of added moles, which is a number selected from a number of 3 or more and 50 or less. ]
- R 3 is a branched-chain hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms.
- hydrocarbon group branched R 3 selected from the viewpoint of improving the cleaning performance and hydrophilic performance, branched-chain alkyl group, a linear secondary alkyl group, branched-chain alkenyl groups, and straight-chain secondary alkenyl group Is preferable, and a group selected from a branched chain alkyl group and a linear secondary alkyl group is more preferable.
- R 4 is preferably a hydrogen atom.
- a 2 O groups are one or more groups selected from alkyleneoxy group. When two or more kinds of alkyleneoxy groups are contained, it may be a block type bond or a random type bond.
- a 2 O group, from the viewpoint of improving the cleaning performance is preferably ethylene group.
- n2 is the average number of added moles, which is a number selected from a number of 3 or more and 50 or less. The larger the number of n2, the higher the HLB value, and the smaller the number, the lower the HLB value.
- n2 is 3 or more, preferably 6 or more, more preferably 8 or more, still more preferably 10 or more from the viewpoint of improving the hydrophilicity performance, and from the viewpoint of improving the cleaning performance and the compounding stability of the composition. From the viewpoint of securing, it is 50 or less, preferably 20 or less, and more preferably 15 or less.
- the component (B1-2) is a nonionic surfactant having a linear hydrocarbon group having 11 or more and 22 or less carbon atoms. From the component (B1-2), the nonionic surfactant corresponding to the component (B1-3), the component (B1-4), and the component (B1-5) is excluded. Examples of the component (B1-2) include a nonionic surfactant represented by the following general formula (b3).
- R 5- O- (A 3 O) n3- R 6 (b3) [In the formula, R 5 is a linear hydrocarbon group having 11 or more and 22 or less carbon atoms, R 6 is a hydrogen atom or a methyl group, and A 3 O group is one or 2 selected from alkyleneoxy groups. It is a group of seeds or more, and n3 is an average addition molar number, which is a number selected from a number of 3 or more and 50 or less. ]
- R 5 is a hydrocarbon group of a straight chain having 11 to 22 carbon atoms.
- the linear hydrocarbon group R 5, a group selected from linear primary alkyl radicals and linear primary alkenyl group is preferred.
- R 6 is preferably a hydrogen atom.
- a 3 O groups are one or more groups selected from alkyleneoxy group. When two or more kinds of alkyleneoxy groups are contained, it may be a block type bond or a random type bond.
- a 3 O groups, from the viewpoint of improving the cleaning performance is preferably ethylene group.
- n3 is the average number of added moles, which is a number selected from a number of 3 or more and 50 or less. The larger the number of n3, the higher the HLB value, and the smaller the number, the lower the HLB value.
- n3 is 3 or more, preferably 7 or more, more preferably 10 or more from the viewpoint of improving hydrophilicity performance, and 50 or less from the viewpoint of improving cleaning performance and ensuring compounding stability of the composition. It is preferably 45 or less, more preferably 40 or less, still more preferably 35 or less, still more preferably 30 or less, and even more preferably 25 or less.
- the component (B1-3) is a nonionic surfactant represented by the following general formula (b4).
- R 7 is a hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms
- R 8 is a hydrogen atom or a methyl group
- the EO group is an ethyleneoxy group
- n4 is the average number of moles added. It is a number selected from a number of 3 or more and 30 or less
- the BO group is a butyleneoxy group
- n5 is an average addition molar number
- EO and BO. May be a random polymer or a block polymer.
- R 7 is a hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms.
- the hydrocarbon group of R 7 is selected from a linear primary alkyl group, a linear primary alkenyl group, a branched chain alkyl group, a linear secondary alkyl group, a branched chain alkenyl group, and a linear secondary alkenyl group.
- a group is preferable, and a group selected from a linear primary alkyl group and a branched chain alkyl group is more preferable.
- the carbon number of R 7 is 8 or more, preferably 10 or more, more preferably 12 or more from the viewpoint of improving cleaning performance, and 22 or less, preferably 18 or less, more preferably from the viewpoint of ensuring hydrophilicity performance. Is 16 or less.
- n4 is the average number of moles added, and is a number selected from a number of 3 or more and 30 or less. From the viewpoint of solubility, n4 is preferably 4 or more, more preferably 5 or more, further preferably 6 or more, and from the viewpoint of detergency, preferably 25 or less, more preferably 20 or less, still more preferably 15 or less. Is. In the general formula (b4), n5 is the average number of moles added, and is a number selected from a number of 1 or more and 15 or less.
- n5 is preferably 2 or more, more preferably 3 or more, further preferably 4 or more, and from the viewpoint of solubility, preferably 13 or less, more preferably 11 or less, still more preferably 9 or less. Is.
- the component (B1-4) is a nonionic surfactant represented by the following general formula (b5).
- R 9 (OA 4) x G y (b5) [In the formula, R 9 is a hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms, OA 4 is one or more groups selected from alkyleneoxy groups, and G is a sugar having 5 or 6 carbon atoms. Derived residues, x is a number whose average value is 0 or more and 5 or less, and y is a number whose average value is 1 or more and 3 or less. ]
- the carbon number of R 9 is 8 or more, preferably 10 or more, and 22 or less, preferably 20 or less, more preferably 18 or less, from the viewpoint of achieving both cleaning performance and hydrophilicity performance. , More preferably 16 or less. It is a straight chain or branched chain alkyl group, preferably a straight chain alkyl group.
- the hydrocarbon group of R 9 is selected from a linear primary alkyl group, a linear primary alkenyl group, a branched chain alkyl group, a linear secondary alkyl group, a branched chain alkenyl group, and a linear secondary alkenyl group.
- a group is preferable, and a group selected from a linear primary alkyl group and a branched chain alkyl group is more preferable.
- OA 4 in the general formula (b5) is one or more groups selected from alkyleneoxy groups, and ethyleneoxy groups are preferable.
- the structure of the residue derived from the sugar having 5 or 6 carbon atoms represented by G in the general formula (b5) is determined by the monosaccharide used or the sugar having 2 or more saccharides.
- G examples include residues derived from glucose, galactose, xylose, mannose, lyxose, arabinose, fructose or a mixture thereof for monosaccharides, and maltose, xylobiose, isomaltose, cellobiose, gentibios and lactose for disaccharides or more.
- preferred raw materials are glucose and fructose for monosaccharides, and maltose and sucrose for disaccharides and above.
- x is the average number of moles of OA 4 added, preferably 0 or more, preferably 5 or less, more preferably 3 or less, still more preferably 1 or less, and 0. There may be.
- the sugar chain binding mode is 1-2, 1-3, 1-4. , 1-6 bonds or ⁇ -, ⁇ -pyranoside bonds or furanoside bonds and any mixture thereof which is a mixed mode of binding thereof can be included.
- the average value of y in the general formula (b5) is 1 or more and 3 or less, preferably 2 or less, and more preferably 1.5 or less.
- the value of y (average degree of condensation of sugar) is measured by 1 1 H-NMR. As a specific measurement method, refer to Japanese Patent Application Laid-Open No. 8-53396, page 6, column 10, line 26 to page 7, column 11, line 15.
- the component (B1-5) is a polyoxyalkylene glycerin fatty acid ester.
- the polyoxyalkylene group of the component (B1-5) at least one selected from polyoxyethylene and polyoxypropylene is preferable from the viewpoint of water solubility, and polyoxyethylene is more preferable.
- the average number of moles of polyoxyalkylene added is preferably 2 or more, more preferably 3 or more, still more preferably 4 or more, and preferably 20 or less, more preferably 18 or less, still more preferably. It is 16 or less, more preferably 13 or less, and even more preferably 10 or less.
- the carbon number of the fatty acid portion of the component (B1-5) is preferably 8 or more, more preferably 10 or more, and preferably 22 or less, more preferably 20 or less, still more preferably 18 or less. is there. Further, as the fatty acid portion of the component (B1-5), a straight-chain or branched-chain saturated or unsaturated fatty acid is preferable, and a straight-chain or branched-chain saturated fatty acid is more preferable.
- the cleaning or hydrophilizing treatment composition of the present invention contains (B1-1-1) a nonionic surfactant represented by the general formula (b1) as a component (B), and (B1-1-2) the general.
- One or more nonionic surfactants selected from (B1-4) the nonionic surfactant represented by the general formula (b5) and (B1-5) polyoxyalkylene glycerin fatty acid ester It may be contained.
- the ratio of the component (B1) to the component (B) is preferably 30% by mass or more, more preferably 50% by mass or more from the viewpoint of improving the hydrophilic performance. , More preferably 70% by mass or more, further preferably 90% by mass or more, and preferably 100% by mass or less, and may be 100% by mass.
- the ratio of the component (B1-1) to the component (B1) is preferably 30% by mass or more, more preferably 70% by mass, from the viewpoint of improving the hydrophilic performance. % Or more, more preferably 90% by mass or more, and preferably 100% by mass or less, and may be 100% by mass.
- the component (A) is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, still more preferably 0, from the viewpoint of improving the cleaning performance. .5% by mass or more, more preferably 1% by mass or more, further preferably 5% by mass or more, and from the viewpoint of improving hydrophilicity performance, preferably 70% by mass or less, more preferably 40% by mass or less, still more preferable. Is contained in an amount of 20% by mass or less, more preferably 10% by mass or less.
- the component (A1) is preferably 0.01% by mass or more, more preferably 0.1% by mass, as the component (A) from the viewpoint of improving the cleaning performance.
- the above is more preferably 0.5% by mass or more, further preferably 1% by mass or more, further preferably 5% by mass or more, and from the viewpoint of improving the hydrophilization performance, preferably 70% by mass or less, more preferably 40. It is contained in an amount of% by mass or less, more preferably 20% by mass or less, still more preferably 10% by mass or less.
- the component (B) is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.1% by mass or more, from the viewpoint of improving the hydrophilization performance. 0.2% by mass or more, more preferably 0.5% by mass or more, further preferably 1% by mass or more, further preferably 2% by mass or more, and preferably 70% by mass or less from the viewpoint of improving cleaning performance. It is more preferably 10% by mass or less, further preferably 5% by mass or less, still more preferably 3% by mass or less.
- the component (B1) is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.1% by mass or more, from the viewpoint of improving the hydrophilization performance. 0.2% by mass or more, more preferably 0.5% by mass or more, further preferably 1% by mass or more, further preferably 2% by mass or more, and preferably 70% by mass or less from the viewpoint of improving cleaning performance. , More preferably 10% by mass or less, further preferably 5% by mass or less, still more preferably 3% by mass or less.
- the mass ratio (A) / (B) of the content of the component (A) to the content of the component (B) improves the cleaning performance and the hydrophilization performance.
- it is preferably 0.1 or more, more preferably 0.2 or more, still more preferably 0.5 or more, still more preferably 0.7 or more, still more preferably 1 or more, still more preferably 1.5 or more.
- More preferably 2 or more, even more preferably 2.5 or more, and preferably 15 or less, more preferably 11 or less, still more preferably 5 or less, even more preferably 4 or less, still more preferably 3 or less. is there.
- the mass ratio (A1) / (B1) of the content of the component (A1) to the content of the component (B1) improves the cleaning performance and the hydrophilization performance.
- it is preferably 0.1 or more, more preferably 0.2 or more, still more preferably 0.5 or more, still more preferably 0.7 or more, still more preferably 1 or more, still more preferably 1.5 or more.
- More preferably 2 or more, even more preferably 2.5 or more, and preferably 15 or less, more preferably 11 or less, still more preferably 5 or less, even more preferably 4 or less, still more preferably 3 or less. is there.
- the cleaning or hydrophilic treatment agent composition of the present invention may contain any component other than the component (A) and the component (B) as long as the effect of the present invention is not impaired.
- an optional component include a component (A), a surfactant other than the component (B), a chelating agent, an alkaline agent, an enzyme, and an inorganic salt (for example, an inorganic salt containing calcium or magnesium).
- the ratio of the total content of the component (A) and the component (B) in the total surfactant is preferably 60% by mass or more, more preferably 70% by mass or more. , More preferably 80% by mass or more, even more preferably 90% by mass or more, and preferably 100% by mass or less, and may be 100% by mass.
- the ratio of the total content of the component (A1) and the component (B1) in the total surfactant is preferably 60% by mass or more, more preferably 70% by mass or more. , More preferably 80% by mass or more, even more preferably 90% by mass or more, and preferably 100% by mass or less, and may be 100% by mass.
- the cleaning or hydrophilizing treatment agent composition of the present invention contains the component (A1) and the component (B1-1-1), the component (A1) and the component (B1-1-1) in all the surfactants.
- the ratio of the total content of is preferably 60% by mass or more, more preferably 70% by mass or more, further preferably 80% by mass or more, still more preferably 90% by mass or more, and preferably 100% by mass or less. , 100% by mass.
- the cleaning or hydrophilizing treatment agent composition of the present invention contains the component (A1) and the component (B1-1-2), the component (A1) and the component (B1-1-2) in all the surfactants.
- the ratio of the total content of is preferably 60% by mass or more, more preferably 70% by mass or more, further preferably 80% by mass or more, still more preferably 90% by mass or more, and preferably 100% by mass or less. , 100% by mass.
- the cleaning or hydrophilizing treatment agent composition of the present invention contains the component (A1) and the component (B1-2), the total content of the component (A1) and the component (B1-2) in all the surfactants. Is preferably 60% by mass or more, more preferably 70% by mass or more, still more preferably 80% by mass or more, still more preferably 90% by mass or more, and preferably 100% by mass or less, 100% by mass. May be.
- the cleaning or hydrophilizing treatment agent composition of the present invention contains the component (A1) and the component (B1-3), the total content of the component (A1) and the component (B1-3) in all the surfactants. Is preferably 60% by mass or more, more preferably 70% by mass or more, still more preferably 80% by mass or more, still more preferably 90% by mass or more, and preferably 100% by mass or less, 100% by mass. May be.
- the cleaning or hydrophilizing treatment agent composition of the present invention contains the component (A1) and the component (B1-4), the total content of the component (A1) and the component (B1-4) in all the surfactants. Is preferably 60% by mass or more, more preferably 70% by mass or more, still more preferably 80% by mass or more, still more preferably 90% by mass or more, and preferably 100% by mass or less, 100% by mass. May be.
- the cleaning or hydrophilizing treatment agent composition of the present invention contains the component (A1) and the component (B1-5), the total content of the component (A1) and the component (B1-5) in all the surfactants. Is preferably 60% by mass or more, more preferably 70% by mass or more, still more preferably 80% by mass or more, still more preferably 90% by mass or more, and preferably 100% by mass or less, 100% by mass. May be.
- the cleaning or hydrophilizing agent composition of the present invention contains water. Water is used in the amount of the balance of component (A), component (B) and any component.
- the cleaning or hydrophilizing treatment composition of the present invention can contain, for example, 20% by mass or more, further 30% by mass or more, and 99% by mass or less, further 98% by mass or less.
- the pH of the liquid washing or hydrophilizing treatment composition of the present invention at 20 ° C. is preferably 3 or more, more preferably 4 or more, and preferably 13 or less, more preferably 12 or less.
- the viscosity of the cleaning or hydrophilizing treatment composition of the present invention at 20 ° C. is preferably 1 mPa ⁇ s or more, more preferably 2 mPa ⁇ s or more, and preferably 10000 mPa ⁇ s or less, more preferably 5000 mPa ⁇ s or less. is there.
- This viscosity can be measured with a rotor and rotation speed according to the viscosity using a B-type viscometer (“TVB-10M” manufactured by Toki Sangyo Co., Ltd.).
- a composition having a low viscosity and cannot be measured with a B-type viscometer can be measured with a cone plate according to the viscosity using a rheometer (“Physica MCR301” manufactured by Anton Pearl Co., Ltd.).
- the cleaning or hydrophilizing agent composition of the present invention can be applied to various solid surfaces such as a hard surface, a cloth surface, a skin surface, and a hair surface.
- the cleaning or hydrophilizing agent composition of the present invention is preferably for hard surfaces.
- the hard surface include a hard surface made of a material such as plastic, ceramics, metal, wood, glass, rubber, and carbon material.
- the hard surface may be the surface of a hard article, for example, the surface of a hard article made of the above material.
- the plastic include acrylic resin, polyamide, polycarbonate, melamine, polyvinyl chloride, polyester, polystyrene, polyethylene, polypropylene, ABS, FRP (fiber reinforced plastic) and the like.
- Examples of the metal include alloys such as stainless steel, aluminum, and iron such as steel for automobiles.
- Examples of rubber include natural rubber and diene-based synthetic rubber.
- Examples of wood include wood used for flooring and the like. The wood used for flooring and the like may be surface-treated.
- the present invention is a treatment liquid containing the component (A), the component (B), and water (hereinafter, may be referred to as the treatment liquid of the present invention), and the component (A) includes the component (A1), ( Provided is a method for cleaning or hydrophilizing a hard surface in which a treatment liquid containing the component (B1) is brought into contact with the hard surface as the component B).
- the component (A), the component (B), and the hard surface are the same as those described in the cleaning or hydrophilizing treatment composition of the present invention.
- the matters described in the cleaning or hydrophilic treatment agent composition of the present invention can be appropriately applied to the method for cleaning or hydrophilizing a hard surface of the present invention.
- the component (A) and the component (B) in the method for hydrophilizing a solid surface of the present invention are preferred embodiments of the cleaning or hydrophilizing agent composition of the present invention. It is the same as the product (however, if necessary, the washing or hydrophilizing agent composition is replaced with the treatment liquid).
- the treatment liquid of the present invention may be the cleaning or hydrophilization treatment agent composition of the present invention, or is prepared by mixing the cleaning or hydrophilization treatment agent composition of the present invention with water. You can do it.
- the treatment liquid of the present invention is a liquid composition containing water, and is preferably an aqueous solution or an aqueous dispersion from the viewpoint of handling stability.
- the treatment liquid of the present invention preferably contains the component (A) in an amount of 0.001% by mass or more, more preferably 0.002% by mass or more, still more preferably 0.005% by mass or more. Then, from the viewpoint of improving the hydrophilization performance, it is preferably contained in an amount of 1% by mass or less, more preferably 0.5% by mass or less, still more preferably 0.1% by mass or less.
- the treatment liquid of the present invention contains the component (A1) as the component (A), preferably 0.001% by mass or more, more preferably 0.002% by mass or more, and further preferably 0, from the viewpoint of improving the cleaning performance.
- the content is preferably 1% by mass or less, more preferably 0.5% by mass or less, still more preferably 0.1% by mass or less.
- the cleaning or hydrophilic treatment agent composition of the present invention contains the component (A) or the component (A1) in this range, it can be used as it is as the treatment liquid of the present invention.
- the treatment liquid of the present invention preferably contains the component (B) in an amount of 0.001% by mass or more, more preferably 0.002% by mass or more, still more preferably 0.005% by mass or more, from the viewpoint of improving the hydrophilicity performance. From the viewpoint of improving the cleaning performance, the content is preferably 0.5% by mass or less, more preferably 0.1% by mass or less, still more preferably 0.05% by mass or less.
- the treatment liquid of the present invention preferably contains the component (B1) in an amount of 0.001% by mass or more, more preferably 0.002% by mass or more, still more preferably 0.005% by mass or more, from the viewpoint of improving the hydrophilicity performance.
- the content is preferably 0.5% by mass or less, more preferably 0.1% by mass or less, still more preferably 0.05% by mass or less.
- the cleaning or hydrophilic treatment agent composition of the present invention contains the component (B) or the component (B1) in this range, it can be used as it is as the treatment liquid of the present invention.
- the mass ratio (A) / (B) of the content of the component (A) to the content of the component (B) is preferably 0 from the viewpoint of improving the cleaning performance and the hydrophilization performance. .1 or more, more preferably 0.2 or more, still more preferably 0.5 or more, still more preferably 0.7 or more, still more preferably 1 or more, still more preferably 1.5 or more, still more preferably 2 Above, more preferably 2.5 or more, preferably 15 or less, more preferably 11 or less, still more preferably 5 or less, even more preferably 4 or less, still more preferably 3 or less.
- the mass ratio (A1) / (B1) of the content of the component (A1) to the content of the component (B1) is preferably 0 from the viewpoint of improving the cleaning performance and the hydrophilization performance. .1 or more, more preferably 0.2 or more, still more preferably 0.5 or more, still more preferably 0.7 or more, still more preferably 1 or more, still more preferably 1.5 or more, still more preferably 2 Above, more preferably 2.5 or more, preferably 15 or less, more preferably 11 or less, still more preferably 5 or less, even more preferably 4 or less, still more preferably 3 or less.
- the treatment liquid of the present invention is applied to a hard surface for preferably 0.1 seconds or longer, more preferably 0.5 seconds or longer, further preferably 1 second or longer, and preferably.
- Contact is carried out for 90 minutes or less, more preferably 60 minutes or less, still more preferably 30 minutes or less.
- the temperature of the treatment liquid of the present invention to be brought into contact with the hard surface is preferably 5 ° C. or higher, more preferably 10 ° C. or higher, more preferably 15 ° C. or higher, and hydrophilic from the viewpoint of improving the cleaning performance of the treatment liquid. From the viewpoint of improving the chemical conversion performance, the temperature is preferably 95 ° C. or lower, more preferably 90 ° C. or lower, and more preferably 80 ° C. or lower.
- the treatment liquid of the present invention can be brought into contact with a hard surface and then rubbed on the hard surface.
- the treatment liquid of the present invention is brought into contact with the hard surface, it is preferably 10 seconds or longer, more preferably 1 minute or longer, still more preferably 2 minutes or longer, and preferably. May be left for 30 minutes or less, more preferably 15 minutes or less, still more preferably 10 minutes or less.
- the temperature at which it is left to stand is preferably 0 ° C. or higher and 80 ° C. or lower.
- the treatment liquid of the present invention can be brought into contact with a hard surface, preferably left as described above, and then the hard surface can be rinsed with water.
- the treatment liquid of the present invention is used, the hydrophilic effect is maintained even when the hard surface after treatment is rinsed. Therefore, objects for which rinsing is desirable will have a more favorable effect.
- the hard surface can be dried.
- water having the same hardness as the water used for preparing the treatment liquid of the present invention it is preferable to use water having the same hardness as the water used for preparing the treatment liquid of the present invention. For example, water having a hardness of 4 ° dH or more and 100 ° dH or less can be used for rinsing.
- the method of contacting the hard surface with the treatment liquid of the present invention is not particularly limited.
- the following methods (i) to (iii) can be mentioned.
- (I) Method of immersing a hard article in the treatment liquid of the present invention (ii) Method of spraying or applying the treatment liquid of the present invention to a hard surface
- the immersion time is preferably 0.5 minutes or longer, more preferably 1 minute or longer, from the viewpoint of enhancing the hydrophilic performance of the treatment liquid of the present invention and from the viewpoint of economic efficiency. And preferably 60 minutes or less, more preferably 50 minutes or less.
- the method of spraying or applying the treatment liquid of the present invention to a hard surface can be appropriately selected depending on the size (area) of the solid surface and the like.
- a method in which the treatment liquid of the present invention is sprayed onto a hard surface by a spray or the like and then dried is preferable. If necessary, it may be sprayed and then rinsed with water. Further, after spraying, it may be spread thinly with a sponge or the like.
- the amount of the processing liquid of the present invention is sprayed or applied on hard surfaces, for example, if the content of the component (A) of the present invention is a treatment solution of the present invention of 0.1% by weight, preferably 10 cm 2 per 0. It is 001 mL or more and 1 mL or less.
- the treatment liquid of the present invention is used in the form of a cleaning or hydrophilizing treatment agent composition containing the components (A) and (B) of the present invention, and is brought into contact with a hard surface.
- a cleaning or hydrophilizing treatment composition containing the components (A) and (B) of the present invention, and is brought into contact with a hard surface.
- the pH is preferably 4 or more, preferably 10 or less, and more preferably 8 or less from the viewpoint of handling safety and prevention of damage to the hard surface. ..
- the present invention further discloses the following cleaning or hydrophilizing agent composition, and a method for cleaning or hydrophilizing a hard surface.
- the matters described in the cleaning or hydrophilic treatment agent composition of the present invention and the cleaning or hydrophilic treatment method for hard surfaces can be appropriately applied to each other.
- a component (A) anionic surfactant (hereinafter referred to as (A) component), (B) nonionic surfactant (hereinafter referred to as (B) component), and water.
- component (A) anionic surfactant
- B) component nonionic surfactant
- a cleaning or hydrophilizing treatment composition containing (B1) a nonionic surfactant having a hydrocarbon group having 8 or more and 22 or less carbon atoms hereinafter referred to as (B1) component
- the mass ratio (A) / (B) of the content of the component (A) to the content of the component (B) is preferably 0.1 or more, more preferably 0.2 or more, still more preferably 0.5 or more. , More preferably 0.7 or more, even more preferably 1 or more, even more preferably 1.5 or more, even more preferably 2 or more, even more preferably 2.5 or more, and preferably 15 or less.
- the cleaning or hydrophilizing agent composition according to ⁇ 1> preferably 11 or less, more preferably 5 or less, still more preferably 4 or less, still more preferably 3 or less.
- the mass ratio (A1) / (B1) of the content of the component (A1) to the content of the component (B1) is preferably 0.1 or more, more preferably 0.2 or more, still more preferably 0.5 or more. , More preferably 0.7 or more, even more preferably 1 or more, even more preferably 1.5 or more, even more preferably 2 or more, even more preferably 2.5 or more, and preferably 15 or less.
- the content of the component (A1) is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.5% by mass or more, still more preferably 1% by mass or more, still more preferably 5. From the viewpoint of improving the hydrophilization performance, it is preferably 70% by mass or less, more preferably 40% by mass or less, still more preferably 20% by mass or less, still more preferably 10% by mass or less, ⁇ 1. > To ⁇ 3> according to any of the cleaning or hydrophilization treatment agent compositions.
- the content of the component (B1) is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.2% by mass or more, still more preferably 0.5% by mass or more, and further. It is preferably 1% by mass or more, more preferably 2% by mass or more, and from the viewpoint of improving cleaning performance, it is preferably 70% by mass or less, more preferably 10% by mass or less, still more preferably 5% by mass or less, still more preferably. Is 3% by mass or less, the cleaning or hydrophilizing treatment agent composition according to any one of ⁇ 1> to ⁇ 4>.
- ⁇ 6> Any of ⁇ 1> to ⁇ 5>, wherein the component (A1) is one or more selected from an internal olefin sulfonate, an alkylbenzene sulfonate, a secondary alkane sulfonate, and a dialkyl sulfosuccinate.
- the cleaning or hydrophilizing agent composition according to the above.
- the component (A1) is an anionic surfactant having a branched chain hydrocarbon group having 8 or more and 30 or less carbon atoms, preferably a branched chain hydrocarbon group having 8 or more and 30 or less carbon atoms, and a sulfate ester group or a sulfonic acid.
- the number of carbon atoms of the branched chain hydrocarbon group of the component (A1) is preferably 8 or more, more preferably 10 or more, further preferably 16 or more, and preferably 30 or less, more preferably 28 or less, still more preferably 24 or less. , More preferably 22 or less, even more preferably 20 or less.
- Chemical treatment agent composition Chemical treatment agent composition.
- the cleaning or hydrophilic treatment agent composition according to any one of ⁇ 1> to ⁇ 8>, wherein the component (A1) is an internal olefin sulfonate (hereinafter referred to as IOS).
- IOS internal olefin sulfonate
- the proportion of IOS in which the sulfonic acid group is present at the 2-position of the hydrocarbon chain is preferably 5% or more, more preferably 10% or more, and preferably 45% or less on a molar basis or a mass basis.
- the cleaning or hydrophilic treatment agent composition according to ⁇ 9> or ⁇ 10> which is more preferably 30% or less.
- the proportion of IOS in which the sulfonic acid group is present at the 1-position of the hydrocarbon chain in IOS is preferably 0.2% or more, more preferably 0.5% or more, still more preferably 1 on a molar basis or a mass basis.
- Cleaning or hydrophilization treatment composition is 0.2% or more, more preferably 0.5% or more, still more preferably 1 on a molar basis or a mass basis.
- the proportion of IOS having a hydrocarbon chain having 16 or more and 20 or less carbon atoms in the IOS is preferably 50% by mass or more, more preferably 70% by mass or more, still more preferably 80% by mass or more, still more preferably 90% by mass. % Or more, more preferably 95% by mass or more, even more preferably 97% by mass or more, and preferably 100% by mass or less, 100% by mass, according to any one of ⁇ 9> to ⁇ 12>.
- Cleaning or hydrophilization treatment agent composition is preferably 50% by mass or more, more preferably 70% by mass or more, still more preferably 80% by mass or more, still more preferably 90% by mass.
- % Or more more, more preferably 95% by mass or more, even more preferably 97% by mass or more, and preferably 100% by mass or less, 100% by mass, according to any one of ⁇ 9> to ⁇ 12>.
- Cleaning or hydrophilization treatment agent composition is preferably 50% by mass or more, more preferably 70% by mass or more, still more preferably
- the molar ratio (H-form / O-form) of hydroxyalkane sulfonate (H-form) to olefin sulfonate (O-form) preferably exceeds 50/50, and more preferably exceeds 70/30.
- the component (B1) is (B1-1-1) a nonionic surfactant having a linear hydrocarbon group having 8 or more and 10 or less carbon atoms [hereinafter referred to as (B1-1-1) component], (B1-1). -2) Nonionic surfactant having a hydrocarbon group of a branched chain having 8 or more and 22 or less carbon atoms [hereinafter referred to as (B1-1-2) component], (B1-2) Linear chain having 11 or more and 22 or less carbon atoms.
- R 7 is a hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms
- R 8 is a hydrogen atom or a methyl group
- the EO group is an ethyleneoxy group
- n4 is the average number of moles added. It is a number selected from a number of 3 or more and 30 or less
- the BO group is a butyleneoxy group
- n5 is an average addition molar number
- EO and BO May be a random polymer or a block polymer.
- R 9 (OA 4) x G y (b5) [In the formula, R 9 is a hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms, OA 4 is one or more groups selected from alkyleneoxy groups, and G is a sugar having 5 or 6 carbon atoms. Derived residues, x is a number whose average value is 0 or more and 5 or less, and y is a number whose average value is 1 or more and 3 or less. ]
- the component (B1) is a nonionic surfactant having a linear hydrocarbon group having 8 or more and 10 or less carbon atoms (hereinafter referred to as (B1-1-1) component), and (B1-1-1).
- (B1-1-1) component a nonionic surfactant having a linear hydrocarbon group having 8 or more and 10 or less carbon atoms
- (B1-1-1) component a nonionic surfactant having a linear hydrocarbon group having 8 or more and 10 or less carbon atoms
- B1-1-1-1-1-1-1-1-1-1 One or more nonionic surfactants selected from nonionic surfactants having a hydrocarbon group of a branched chain having 8 or more and 22 or less carbon atoms
- the cleaning or hydrophilic treatment agent composition according to any one of ⁇ 1> to ⁇ 15>.
- ⁇ 20> The cleaning or hydrophilizing treatment agent composition according to any one of ⁇ 15> to ⁇ 19>, wherein the component (B1-2) is a nonionic surfactant represented by the following general formula (b3).
- R 5- O- (A 3 O) n3- R 6 (b3) [In the formula, R 5 is a linear hydrocarbon group having 11 or more and 22 or less carbon atoms, R 6 is a hydrogen atom or a methyl group, and A 3 O group is one or 2 selected from alkyleneoxy groups. It is a group of seeds or more, and n3 is an average addition molar number, which is a number selected from a number of 3 or more and 50 or less. ]
- the cleaning or hydrophilizing treatment agent composition according to any one of ⁇ 15> to ⁇ 20>, wherein the component (B1-3) is a nonionic surfactant represented by the following general formula (b4).
- R 7 is a hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms
- R 8 is a hydrogen atom or a methyl group
- the EO group is an ethyleneoxy group
- n4 is the average number of moles added.
- the BO group is a butyleneoxy group
- n5 is an average addition molar number
- EO and BO May be a random polymer or a block polymer.
- a treatment liquid containing (A) anionic surfactant (hereinafter referred to as (A) component), (B) nonionic surfactant (hereinafter referred to as (B) component), and water is brought into contact with a hard surface.
- the treatment liquid contains (A1) a branched anionic surfactant as a component (A).
- a method for cleaning or hydrophilizing a hard surface which comprises (B1) a nonionic surfactant having a hydrocarbon group having 8 or more and 22 or less carbon atoms as a component (B).
- ⁇ 25> The method for cleaning or hydrophilizing a hard surface according to ⁇ 24>, wherein the treatment liquid is brought into contact with a hard surface, and then the hard surface is rinsed with water.
- ⁇ 26> The hard surface according to ⁇ 24> or ⁇ 25>, wherein the treatment liquid is obtained by mixing the cleaning or hydrophilization treatment agent composition according to any one of ⁇ 1> to ⁇ 23> with water. Cleaning or hydrophilization treatment method.
- C18-IOS-K The potassium internal olefin sulfonic acid salt (C18-IOS-K) having 18 carbon atoms can be obtained, for example, in the following production example.
- a flask with a stirrer was loaded with 7,000 parts by mass of 1-octadecanol ("Calcol 8098" manufactured by Kao Corporation) and 700 parts by mass of ⁇ -alumina (manufactured by Strem Chemicals) as a catalyst, and heated to 280 ° C. under stirring.
- the reaction can be carried out while circulating nitrogen in the system to obtain a crude internal olefin.
- an internal olefin having 100% olefin purity and 18 carbon atoms can be obtained.
- Said internal olefin were placed in thin-film sulfonation reactor, the reactor 20 ° C. cooling water in the external jacket under conditions that liquid passing, sulfonated using SO 3 concentration 2.8% by volume of sulfur trioxide gas React.
- the reaction molar ratio (SO 3 / internal olefin) is set to 1.09, and the flow amounts of the internal olefin and SO 3 are set to carry out the reaction.
- the obtained sulfonate is added to an aqueous potassium hydroxide solution corresponding to 1.2 mol times the theoretical acid value, and the mixture is stirred at 30 ° C. for 1 hour for neutralization.
- the neutralized product can be hydrolyzed by heating it in an autoclave at 160 ° C. for 1 hour to obtain a crude product of an internal potassium olefin sulfonic acid salt.
- the crude product and ethanol are placed in a separatory funnel, and petroleum ether is added to extract and remove oil-soluble impurities. This operation is performed three times to evaporate and dry the aqueous phase side to obtain an internal olefin sulfonic acid potassium salt (C18-IOS-K) having 18 carbon atoms.
- C16-IOS-K The potassium internal olefin sulfonic acid salt (C16-IOS-K) having 16 carbon atoms can be obtained, for example, in the following production example.
- a flask with a stirrer was loaded with 7,000 parts by mass of 1-hexadecanol (“Calcol 6098” manufactured by Kao Corporation) and 700 parts by mass of ⁇ -alumina (manufactured by Strem Chemicals) as a catalyst, and heated to 280 ° C. under stirring.
- the reaction can be carried out while circulating nitrogen in the system to obtain a crude internal olefin. By distilling the crude internal olefin at 148-158 ° C.
- an internal olefin having 100% olefin purity and 18 carbon atoms can be obtained.
- Said internal olefin were placed in thin-film sulfonation reactor, the reactor 20 ° C. cooling water in the external jacket under conditions that liquid passing, sulfonated using SO 3 concentration 2.8% by volume of sulfur trioxide gas React.
- the reaction molar ratio (SO 3 / internal olefin) is set to 1.09, and the flow amounts of the internal olefin and SO 3 are set to carry out the reaction.
- the obtained sulfonate is added to an aqueous potassium hydroxide solution corresponding to 1.2 mol times the theoretical acid value, and the mixture is stirred at 30 ° C.
- the neutralized product can be hydrolyzed by heating it in an autoclave at 160 ° C. for 1 hour to obtain a crude product of an internal potassium olefin sulfonic acid salt.
- the crude product and ethanol are placed in a separatory funnel, and petroleum ether is added to extract and remove oil-soluble impurities. This operation is performed three times to evaporate and dry the aqueous phase side to obtain an internal olefin sulfonic acid potassium salt (C16-IOS-K) having 18 carbon atoms.
- C16-IOS-K internal olefin sulfonic acid potassium salt having 18 carbon atoms.
- the compounding amount of the component (A) in the table the value converted into the acid type (C16-IOS-H) is described.
- Neoperex G-15 Sodium dodecylbenzene sulfonate, Neoperex G-15, manufactured by Kao Corporation
- C12EO3 (B1-2) component, a nonionic surfactant obtained by adding an average of 3 mol of ethylene oxide to a linear primary alcohol having 12 carbon atoms, EMULGEN 103, Kao Co., Ltd.
- C12EO6 (B1-2) component, nonionic surfactant obtained by adding an average of 6 mol of ethylene oxide to a linear primary alcohol having 12 carbon atoms, EMULGEN 108, manufactured by Kao Co., Ltd.
- C12EO9: (B1-2) component Nonionic surfactant obtained by adding an average of 9 mol of ethylene oxide to a linear primary alcohol having 12 carbon atoms, EMULGEN 109P, manufactured by Kao Co., Ltd., C12EO12: (B1-2) component, linear primary primary alcohol having 12 carbon atoms.
- C12EO21 (B1- 2) Component, nonionic surfactant obtained by adding 21 mol of ethylene oxide to a linear primary alcohol having 12 carbon atoms on average, EMULGEN 121, manufactured by Kao Co., Ltd.
- C12EO41: (B1-2) component 12 carbon atoms
- C12EO47: (B1-2) component ethylene oxide to a linear primary alcohol having 12 carbon atoms
- Ethylene oxide was added to a nonionic surfactant obtained by adding an average of 47 mol of ethylene oxide, EMULGEN 150, C10EO5: (B1-1-1) component manufactured by Kao, and a linear primary alcohol having 10 carbon atoms by an average of 5 mol.
- Nonion surfactant obtained by adding an average of 8 mol of ethylene oxide to a linear primary alcohol having 10 carbon atoms which is a component of C10EO8: (B1-1-1) manufactured by BASF, Lutensol ON50.
- R 9 is an alkyl group having 8 to 10 carbon atoms
- x is 0, y is 1.5 to 1.8
- G is a residue derived from glucose.
- G is a residue derived from glucose, Glucopon 650EC, manufactured by BASF, C10-16APG: (B1-4) component, in general formula (b5), R 9 is an alkyl having 10 to 16 carbon atoms. Group, x is 0, y is 1.35 to 1.45, G is a residue derived from glucose, Mydol 10, manufactured by Kao Co., Ltd. C12-14APG: (B1-4) component, general formula ( In b5), R 9 is an alkyl group having 12 to 14 carbon atoms, x is 0, y is 1.35 to 1.45, and G is a residue derived from glucose, Mydol 12, manufactured by Kao Co., Ltd.
- ⁇ Washing test> A mixture of 100 g of beef tallow, 100 g of soybean oil, 2.5 g of monooleic acid, 1.0 g of Sudan III (manufactured by Wako Pure Chemical Industries, Ltd.), and 600 mL of chloroform was used as a model stain.
- the prepared model stains were uniformly applied to both sides of a 76 mm ⁇ 26 mm slide glass (S2441 manufactured by Matsunami Glass Industry Co., Ltd.) so that the total of both sides was 0.04 g, and the slide glass was prepared as a model oil-contaminated slide glass.
- the temperature of the treatment liquid was set to 30 ° C., and the mixture was stirred at a stirring speed of 250 rpm for 3 minutes and washed.
- the washed slide glass was transferred to a beaker containing 0.7 L of 8 ° dH water, rinsed at a stirring rate of 250 rpm for 1 minute, and dried at room temperature.
- the cleaning rate of the model oil-contaminated slide glass obtained in the above cleaning test was calculated from the following formula.
- the values in Tables 1 to 4 are the average values of the cleaning rates of 6 sheets.
- Cleaning rate (%) [1- (Glass weight after cleaning-Glass weight before applying model oil) / (Glass weight after applying model oil-Glass weight before applying model oil)] x 100
- one 26 mm ⁇ 76 mm glass plate (manufactured by Akebono Trading Company) was added, and the mixture was stirred at a stirring rate of 70 rpm for 15 minutes.
- the washing water in the tapper was drained, and 0.5 L of water having a new hardness of 8 ° dH was added to the tapper for rinsing, and the tapper was stirred at a stirring rate of 70 rpm for 1 minute for rinsing.
- the glass plate subjected to the hydrophilization treatment was dried overnight at room temperature.
- the contact angle of water in the dried glass was measured using an automatic contact angle measuring machine (DM-501Hi).
- the values in Tables 1 to 4 are the average values of the contact angles of the three points.
- the contact angle of the glass before the hydrophilization treatment is 32.9 °.
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Abstract
Description
アニオン性界面活性剤は、洗浄力及び起泡性に優れており、洗浄剤の成分として広く用いられている。アニオン性界面活性剤の一つとして、二重結合をオレフィン鎖の末端ではなく内部に有する内部オレフィンを原料として得られる内部オレフィンスルホン酸塩が知られている。内部オレフィンスルホン酸塩は、例えば内部オレフィンをガス状三酸化硫黄含有ガスと反応させてスルホン化し、その得られたスルホン酸を中和後、更に加水分解することにより得られる。内部オレフィンスルホン酸塩は、生分解性が良好であることが知られている。 Background Technology Anionic surfactants are excellent in detergency and foaming properties, and are widely used as components of detergents. As one of the anionic surfactants, an internal olefin sulfonate obtained by using an internal olefin having a double bond inside instead of the end of the olefin chain as a raw material is known. The internal olefin sulfonate can be obtained, for example, by reacting the internal olefin with a gaseous sulfur trioxide-containing gas to sulfonate, neutralizing the obtained sulfonic acid, and further hydrolyzing the obtained sulfonic acid. Internal olefin sulfonates are known to have good biodegradability.
特開2016-35009号公報には、内部オレフィンスルホン酸塩を1質量%以上40質量%以下含有する、硬質表面用バイオフィルム除去剤組成物が記載されている。
特開2016-147928号公報には、(a)炭素数8以上、24以下の内部オレフィンスルホン酸塩、(b)炭素数8以上、22以下の脂肪酸又はその塩、(c)(c1)特定のアルカノールアミド、(c2)特定の脂肪酸アミドプロピルベタイン及び(c3)特定のポリオキシエチレンアルキル又はアルケニルアミンから選ばれる1種以上の化合物を、それぞれ、所定条件で含有し、(c)/(a)の質量比が0.01以上、1以下である、手洗い用食器洗浄剤組成物が記載されている。
特開2016-147927号公報には、(a)炭素数8以上、24以下の内部オレフィンスルホン酸塩、(b)炭素数8以上、22以下の脂肪酸又はその塩、(c)炭素数8以上、22以下の炭化水素基を有するアミンオキシド、及び(d)炭素数8以上、22以下のアルキル基を有するアルキルコハク酸、炭素数8以上、22以下のアルケニル基を有するアルケニルコハク酸、これらの塩及びこれらの無水物から選ばれる化合物を、それぞれ、所定条件で含有し、(d)/(a)の質量比が0.01以上、1以下である、手洗い用食器洗浄剤組成物が記載されている。 US Pat. No. 5,078,916 describes a detergent composition containing an internal olefin sulfonate having 8 to 26 carbon atoms in which at least 25% by weight is in the form of beta-hydroxyalkane sulfonic acid.
Japanese Unexamined Patent Publication No. 2016-35009 describes a biofilm remover composition for a hard surface containing 1% by mass or more and 40% by mass or less of an internal olefin sulfonate.
Japanese Unexamined Patent Publication No. 2016-147928 describes (a) an internal olefin sulfonate having 8 or more carbon atoms and 24 or less carbon atoms, (b) a fatty acid or a salt thereof having 8 or more carbon atoms and 22 or less carbon atoms, and (c) (c1). Alkanolamide, (c2) specific fatty acid amide propylbetaine, and (c3) one or more compounds selected from specific polyoxyethylene alkyl or alkenylamine, respectively, containing (c) / (a) under predetermined conditions. ) Is 0.01 or more and 1 or less, and a dishwashing agent composition for hand washing is described.
Japanese Unexamined Patent Publication No. 2016-147927 describes (a) an internal olefin sulfonate having 8 or more carbon atoms and 24 or less carbon atoms, (b) a fatty acid having 8 or more carbon atoms and 22 or less carbon atoms or a salt thereof, and (c) 8 or more carbon atoms. , Amine oxide having a hydrocarbon group of 22 or less, and (d) alkyl succinic acid having an alkyl group having 8 or more carbon atoms and 22 or less carbon atoms, and alkenyl succinic acid having an alkenyl group having 8 or more carbon atoms and 22 carbon atoms or less. Described is a dishwashing agent composition for hand washing, each containing a salt and a compound selected from these anhydrides under predetermined conditions, and having a mass ratio of (d) / (a) of 0.01 or more and 1 or less. Has been done.
本発明は、洗浄力に優れ、且つ硬質表面に対して親水性を付与できる洗浄又は親水化処理剤組成物及び硬質表面の洗浄又は親水化処理方法を提供する。 Outline of the Invention The present invention provides a cleaning or hydrophilizing agent composition having excellent detergency and capable of imparting hydrophilicity to a hard surface, and a method for cleaning or hydrophilizing a hard surface.
(A)成分として、(A1)分岐型陰イオン界面活性剤(以下、(A1)成分という)、
(B)成分として、(B1)炭素数8以上22以下の炭化水素基を有するノニオン界面活性剤(以下、(B1)成分という)を含有する洗浄又は親水化処理剤組成物に関する。 The present invention is a washing or hydrophilization treatment containing (A) anionic surfactant (hereinafter referred to as (A) component), (B) nonionic surfactant (hereinafter referred to as (B) component), and water. It is an agent composition
As the component (A), (A1) branched anionic surfactant (hereinafter referred to as (A1) component),
The present invention relates to a cleaning or hydrophilizing treatment agent composition containing (B1) a nonionic surfactant having a hydrocarbon group having 8 or more and 22 or less carbon atoms (hereinafter referred to as (B1) component) as a component (B).
〔洗浄又は親水化処理剤組成物〕
<(A)成分>
(A)成分は、アニオン界面活性剤である。
本発明の洗浄又は親水化処理剤組成物は、(A)成分として、(A1)分岐型陰イオン界面活性剤を含有する。分岐型陰イオン界面活性剤は、疎水性部分である炭化水素基が分岐構造を有する陰イオン界面活性剤である。なお、本発明では、陰イオン性界面活性剤が、親水性部分である陰イオン基に結合した炭素原子が2級又は3級炭素原子である炭化水素基を有する場合も、分岐構造を有する陰イオン界面活性剤であるとしてよい。なお、本発明では、(A)成分の含有量は、(A)成分の対イオンを水素イオンと仮定して算出した値、即ち酸型換算値を用いる。(A)成分に係る質量比は(A)成分の含有量の酸型換算値を用いて換算する。 Embodiment for carrying out the invention [cleaning or hydrophilization treatment agent composition]
<Ingredient (A)>
The component (A) is an anionic surfactant.
The cleaning or hydrophilizing treatment composition of the present invention contains (A1) a branched anionic surfactant as a component (A). The branched anionic surfactant is an anionic surfactant having a branched structure in which a hydrocarbon group, which is a hydrophobic portion, has a branched structure. In the present invention, even when the anionic surfactant has a hydrocarbon group in which the carbon atom bonded to the anionic group which is a hydrophilic portion is a secondary or tertiary carbon atom, the anionic surfactant has a branched structure. It may be an ionic surfactant. In the present invention, the content of the component (A) is a value calculated by assuming that the counter ion of the component (A) is a hydrogen ion, that is, an acid type conversion value is used. The mass ratio of the component (A) is converted using the acid type conversion value of the content of the component (A).
(A1)成分としては、炭素数8以上30以下の分岐鎖炭化水素基と、硫酸エステル基又はスルホン酸基とを有する陰イオン界面活性剤が挙げられる。 Examples of the component (A1) include an anionic surfactant having a branched-chain hydrocarbon group having 8 or more and 30 or less carbon atoms.
Examples of the component (A1) include an anionic surfactant having a branched chain hydrocarbon group having 8 or more carbon atoms and 30 or less carbon atoms and a sulfate ester group or a sulfonic acid group.
(A1)成分の分岐鎖炭化水素基としては、分岐鎖アルキル基、分岐鎖アルケニル基、又は分岐鎖アルキル基を有するアリール基が挙げられる。 The number of carbon atoms of the branched chain hydrocarbon group of the component (A1) is preferably 8 or more, more preferably 10 or more, further preferably 16 or more, and preferably 30 or less, more preferably 28 or less, still more preferably 24 or less. , More preferably 22 or less, still more preferably 20 or less.
Examples of the branched-chain hydrocarbon group of the component (A1) include a branched-chain alkyl group, a branched-chain alkenyl group, and an aryl group having a branched-chain alkyl group.
R1a、R2aの炭化水素基は、水酸基などの置換基又はCOO基などの連結基を含んでいてもよい。
R1aとR2aの炭素数の合計は、7以上29以下が好ましい。なお、置換基又は連結基の炭素数は、R1a、R2aの炭化水素基の炭素数には算入しない。
式(A)中、Xは、SO3Mが好ましい。
式(A)中、Mは、アルカリ金属イオン、アルカリ土類金属(1/2原子)イオン、アンモニウムイオン又は有機アンモニウムイオンが挙げられる。Mは、アルカリ金属イオンが好ましく、ナトリウムイオン、カリウムイオンがより好ましく、カリウムイオンが更に好ましい。
Yは単結合が好ましい。 In the formula (A), examples of the hydrocarbon group of R 1a and R 2a include an alkyl group, an alkenyl group and an aryl group. Alkyl or alkenyl groups are preferred.
The hydrocarbon groups of R 1a and R 2a may contain a substituent such as a hydroxyl group or a linking group such as a COO group.
The total number of carbon atoms of R 1a and R 2a is preferably 7 or more and 29 or less. The carbon number of the substituent or the linking group is not included in the carbon number of the hydrocarbon group of R 1a and R 2a.
In the formula (A), X is preferably SO 3 M.
In the formula (A), M includes alkali metal ion, alkaline earth metal (1/2 atom) ion, ammonium ion or organic ammonium ion. As M, alkali metal ions are preferable, sodium ions and potassium ions are more preferable, and potassium ions are even more preferable.
Y is preferably a single bond.
(B)成分は、ノニオン界面活性剤である。本発明の洗浄又は親水化処理剤組成物は、(B)成分として、(B1)炭素数8以上22以下の炭化水素基を有するノニオン界面活性剤を含有する。
(B1)成分の炭化水素基の炭素数は、洗浄性能を向上させる観点から、8以上、好ましくは10以上、そして、親水化性能を向上させる観点から、22以下、好ましくは18以下、より好ましくは16以下である。 <Ingredient (B)>
The component (B) is a nonionic surfactant. The cleaning or hydrophilizing treatment agent composition of the present invention contains (B1) a nonionic surfactant having a hydrocarbon group having 8 or more and 22 or less carbon atoms as a component (B).
The number of carbon atoms of the hydrocarbon group of the component (B1) is 8 or more, preferably 10 or more from the viewpoint of improving cleaning performance, and 22 or less, preferably 18 or less, more preferably from the viewpoint of improving hydrophilicity performance. Is 16 or less.
R7-O-[(EO)n4(BO)n5]-R8 (b4)
〔式中、R7は炭素数8以上22以下の炭化水素基であり、R8は水素原子又はメチル基であり、EO基はエチレンオキシ基であり、n4は平均付加モル数であって、3以上30以下の数から選択される数であり、BO基はブチレンオキシ基であり、n5は平均付加モル数であって、1以上15以下の数から選択される数であり、EOとBOはランダム重合体又はブロック重合体であってもよい。〕
R9(OA4)xGy (b5)
〔式中、R9は炭素数8以上22以下の炭化水素基であり、OA4はアルキレンオキシ基から選ばれる1種又は2種以上の基であり、Gは炭素数5又は6の糖に由来する残基であり、xはその平均値が0以上5以下の数であり、yはその平均値が1以上3以下となる数である。〕 From the viewpoint of improving cleaning performance and hydrophilization performance, the cleaning or hydrophilizing treatment composition of the present invention contains (B1-1-1) a linear hydrocarbon having 8 or more and 10 or less carbon atoms as a component (B1). Nonionic surfactant having a group [hereinafter referred to as (B1-1-1) component], (B1-1-2) Nonionic surfactant having a branched chain hydrocarbon group having 8 or more and 22 or less carbon atoms [hereinafter, (B1-1-2) component], (B1-2) Nonionic surfactant having a linear hydrocarbon group having 11 or more and 22 or less carbon atoms [hereinafter referred to as (B1-2) component], (B1- 3) Nonionic surfactant represented by the following general formula (b4) [hereinafter referred to as (B1-3) component], (B1-4) Nonionic surfactant represented by the following general formula (b5) [hereinafter, (B1-4) component], (B1-5) polyoxyalkylene glycerin fatty acid ester [hereinafter referred to as (B1-5) component] may contain one or more nonionic surfactants. preferable.
R 7- O-[(EO) n4 (BO) n5 ] -R 8 (b4)
[In the formula, R 7 is a hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms, R 8 is a hydrogen atom or a methyl group, the EO group is an ethyleneoxy group, and n4 is the average number of moles added. It is a number selected from a number of 3 or more and 30 or less, the BO group is a butyleneoxy group, n5 is an average addition molar number, and is a number selected from a number of 1 or more and 15 or less, EO and BO. May be a random polymer or a block polymer. ]
R 9 (OA 4) x G y (b5)
[In the formula, R 9 is a hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms, OA 4 is one or more groups selected from alkyleneoxy groups, and G is a sugar having 5 or 6 carbon atoms. Derived residues, x is a number whose average value is 0 or more and 5 or less, and y is a number whose average value is 1 or more and 3 or less. ]
本発明では、ノニオン界面活性剤が親水性部分であるアルキレンオキシ基等に結合した炭素原子が、2級又は3級炭素原子である炭化水素基を有する場合も、分岐鎖の炭化水素基を有するノニオン界面活性剤とする。 The cleaning or hydrophilic treatment agent composition of the present invention is selected from the (B1-1) component and the (B1-1-2) component as the (B1) component from the viewpoint of improving the cleaning performance and the hydrophilicizing performance. It is more preferable to contain one or more nonionic surfactants [hereinafter referred to as (B1-1) component].
In the present invention, even when the carbon atom bonded to the alkyleneoxy group or the like in which the nonionic surfactant is a hydrophilic portion has a hydrocarbon group which is a secondary or tertiary carbon atom, it also has a hydrocarbon group of a branched chain. Use as a nonionic surfactant.
(B1-1-2)成分の炭化水素基は、分岐鎖アルキル基、直鎖2級アルキル基、分岐鎖アルケニル基、及び直鎖2級アルケニル基から選ばれる基が挙げられる。(B1-1-2)成分からは、(B1-3)成分、(B1-4)成分、(B1-5)成分に該当するノニオン界面活性剤は除かれる。(B1-1-2)成分は、洗浄性能及び親水化性能を向上させる観点から、炭素数8以上22以下の分岐鎖の炭化水素基を1つ有するノニオン界面活性剤が好ましい。 Examples of the hydrocarbon group of the component (B1-1-1) include a group selected from a linear primary alkyl group and a linear primary alkenyl group. From the component (B1-1-1), the nonionic surfactant corresponding to the component (B1-3), the component (B1-4), and the component (B1-5) is excluded. The component (B1-1-1) is preferably a nonionic surfactant having one linear hydrocarbon group having 8 or more and 10 or less carbon atoms from the viewpoint of improving cleaning performance and hydrophilicity performance.
Examples of the hydrocarbon group of the component (B1-1-2) include a group selected from a branched chain alkyl group, a straight chain secondary alkyl group, a branched chain alkenyl group, and a straight chain secondary alkenyl group. From the component (B1-1-2), the nonionic surfactant corresponding to the component (B1-3), the component (B1-4), and the component (B1-5) is excluded. The component (B1-1-2) is preferably a nonionic surfactant having one hydrocarbon group of a branched chain having 8 or more and 22 or less carbon atoms from the viewpoint of improving cleaning performance and hydrophilicity performance.
このHLBは、Griffin法によるものである。ここで、(B1-1)成分がポリオキシエチレン基を含む場合、HLBは、下記式で算出されるHLBを言う。ポリオキシエチレン基の平均分子量とは、オキシエチレン基の付加モル数が分布を有する場合、平均付加モル数から算出された平均分子量を表す。また(B1-1)成分の平均分子量とは、炭化水素基などの疎水基が分布を有する場合やポリオキシエチレン基の付加モル数が分布を有する場合は、平均値で算出される分子量である。
HLB=〔(ポリオキシエチレン基の平均分子量)/〔(B1-1)成分の平均分子量〕〕×20
尚、以下に具体的なノニオン界面活性剤を例示するが、前記のオキシエチレン基をエチレンオキシ基と称する場合がある。
また、本発明において、(B1-1)成分がポリオキシエチレン基を含まない場合、(B1-1)成分のHLBは、“Journal of Colloid and Interface Science,Vol.107.No.1,September1985”に記載された国枝らの方法に従って測定されたものを言う。この文献には、特定の温度(THLB)とグリフィン(Griffin)によるHLB数とが線形関係にあるという知見に基づくHLBの測定法である。 The component (B1-1) may be a nonionic surfactant having an HLB of 11.5 or more, further 12.5 or more, and 15.4 or less, further 15.1 or less.
This HLB is based on the Griffin method. Here, when the component (B1-1) contains a polyoxyethylene group, HLB refers to HLB calculated by the following formula. The average molecular weight of the polyoxyethylene group represents the average molecular weight calculated from the average number of added moles when the number of added moles of the oxyethylene group has a distribution. The average molecular weight of the component (B1-1) is a molecular weight calculated by an average value when hydrophobic groups such as hydrocarbon groups have a distribution or when the number of added moles of polyoxyethylene groups has a distribution. ..
HLB = [(average molecular weight of polyoxyethylene group) / [average molecular weight of (B1-1) component]] × 20
Although specific nonionic surfactants are exemplified below, the oxyethylene group may be referred to as an ethyleneoxy group.
Further, in the present invention, when the component (B1-1) does not contain a polyoxyethylene group, the HLB of the component (B1-1) is "Journal of Colloid and Interface Science, Vol.107.No.1, September1985". Refers to those measured according to the method of Kunieda et al. Described in. This document is a method for measuring HLB based on the finding that a specific temperature (THLB) and the number of HLBs due to Griffin have a linear relationship.
R1-O-(A1O)n1-R2 (b1)
〔式中、R1は炭素数8以上10以下の直鎖の炭化水素基であり、R2は水素原子又はメチル基であり、A1O基はアルキレンオキシ基から選ばれる1種又は2種以上の基であり、n1は平均付加モル数であって、3以上50以下の数から選択される数である。〕 Examples of the component (B1-1-1) include a nonionic surfactant represented by the following general formula (b1).
R 1- O- (A 1 O) n1- R 2 (b1)
[In the formula, R 1 is a linear hydrocarbon group having 8 or more carbon atoms and 10 or less carbon atoms, R 2 is a hydrogen atom or a methyl group, and A 1 O group is one or two selected from alkyleneoxy groups. Based on the above, n1 is the average number of added moles, which is a number selected from 3 or more and 50 or less. ]
R1の直鎖の炭化水素基としては、直鎖1級アルキル基及び直鎖1級アルケニル基から選ばれる基が好ましく、直鎖1級アルキル基がより好ましい。
一般式(b1)中、R2は水素原子が好ましい。 In the general formula (b1), R 1 is a linear hydrocarbon group having 8 or more carbon atoms and 10 or less carbon atoms. The carbon number of R 1 is 8 or more from the viewpoint of improving the cleaning performance, and 10 or less, more preferably 10 from the viewpoint of ensuring the hydrophilic performance.
As the linear hydrocarbon group of R 1 , a group selected from a linear primary alkyl group and a linear primary alkenyl group is preferable, and a linear primary alkyl group is more preferable.
In the general formula (b1), R 2 is preferably a hydrogen atom.
R3-O-(A2O)n2-R4 (b2)
〔式中、R3は炭素数8以上22以下の分岐鎖の炭化水素基であり、R4は水素原子又はメチル基であり、A2O基はアルキレンオキシ基から選ばれる1種又は2種以上の基であり、n2は平均付加モル数であって、3以上50以下の数から選択される数である。〕 Examples of the component (B1-1-2) include a nonionic surfactant represented by the following general formula (b2).
R 3- O- (A 2 O) n2- R 4 (b2)
[In the formula, R 3 is a hydrocarbon group of a branched chain having 8 or more carbon atoms and 22 or less carbon atoms, R 4 is a hydrogen atom or a methyl group, and A 2 O group is one or two selected from alkyleneoxy groups. Based on the above, n2 is the average number of added moles, which is a number selected from a number of 3 or more and 50 or less. ]
R3の分岐鎖の炭化水素基としては、洗浄性能及び親水化性能を向上させる観点から、分岐鎖アルキル基、直鎖2級アルキル基、分岐鎖アルケニル基、及び直鎖2級アルケニル基から選ばれる基が好ましく、分岐鎖アルキル基及び直鎖2級アルキル基から選ばれる基がより好ましい。一般式(b2)中、R4は水素原子が好ましい。 In the general formula (b2), R 3 is a branched-chain hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms. The number of carbon atoms in R 3, from the viewpoint of improving the cleaning performance, 8 or more, preferably 10 or more, and, from the viewpoint of ensuring the hydrophilic performance, 22 or less, preferably 18 or less, more preferably 16 or less.
Examples of the hydrocarbon group branched R 3, selected from the viewpoint of improving the cleaning performance and hydrophilic performance, branched-chain alkyl group, a linear secondary alkyl group, branched-chain alkenyl groups, and straight-chain secondary alkenyl group Is preferable, and a group selected from a branched chain alkyl group and a linear secondary alkyl group is more preferable. In the general formula (b2), R 4 is preferably a hydrogen atom.
(B1-2)成分としては、下記一般式(b3)で表されるノニオン界面活性剤が挙げられる。
R5-O-(A3O)n3-R6 (b3)
〔式中、R5は、炭素数11以上22以下の直鎖の炭化水素基であり、R6は水素原子又はメチル基であり、A3O基はアルキレンオキシ基から選ばれる1種又は2種以上の基であり、n3は平均付加モル数であって、3以上50以下の数から選択される数である。〕 The component (B1-2) is a nonionic surfactant having a linear hydrocarbon group having 11 or more and 22 or less carbon atoms. From the component (B1-2), the nonionic surfactant corresponding to the component (B1-3), the component (B1-4), and the component (B1-5) is excluded.
Examples of the component (B1-2) include a nonionic surfactant represented by the following general formula (b3).
R 5- O- (A 3 O) n3- R 6 (b3)
[In the formula, R 5 is a linear hydrocarbon group having 11 or more and 22 or less carbon atoms, R 6 is a hydrogen atom or a methyl group, and A 3 O group is one or 2 selected from alkyleneoxy groups. It is a group of seeds or more, and n3 is an average addition molar number, which is a number selected from a number of 3 or more and 50 or less. ]
R5の直鎖の炭化水素基としては、直鎖1級アルキル基及び直鎖1級アルケニル基から選ばれる基が好ましい。
R5の炭素数は、親水化性能の向上の観点から、11以上、好ましくは12以上、そして、洗浄性能を向上させる観点から、好ましくは18以下、より好ましくは16以下、更に好ましくは14以下である。
一般式(b3)中、R6は水素原子が好ましい。 In the formula (b3), R 5 is a hydrocarbon group of a straight chain having 11 to 22 carbon atoms.
The linear hydrocarbon group R 5, a group selected from linear primary alkyl radicals and linear primary alkenyl group is preferred.
The number of carbon atoms in R 5, from the viewpoint of improving the hydrophilic properties, 11 or more, preferably 12 or more, and, from the viewpoint of improving the cleaning performance, preferably 18 or less, more preferably 16 or less, more preferably 14 or less Is.
In the general formula (b3), R 6 is preferably a hydrogen atom.
R7-O-[(EO)n4(BO)n5]-R8 (b4)
〔式中、R7は炭素数8以上22以下の炭化水素基であり、R8は水素原子又はメチル基であり、EO基はエチレンオキシ基であり、n4は平均付加モル数であって、3以上30以下の数から選択される数であり、BO基はブチレンオキシ基であり、n5は平均付加モル数であって、1以上15以下の数から選択される数であり、EOとBOはランダム重合体又はブロック重合体であってもよい。〕 The component (B1-3) is a nonionic surfactant represented by the following general formula (b4).
R 7- O-[(EO) n4 (BO) n5 ] -R 8 (b4)
[In the formula, R 7 is a hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms, R 8 is a hydrogen atom or a methyl group, the EO group is an ethyleneoxy group, and n4 is the average number of moles added. It is a number selected from a number of 3 or more and 30 or less, the BO group is a butyleneoxy group, n5 is an average addition molar number, and is a number selected from a number of 1 or more and 15 or less, EO and BO. May be a random polymer or a block polymer. ]
R7の炭化水素基としては、直鎖1級アルキル基、直鎖1級アルケニル基、分岐鎖アルキル基、直鎖2級アルキル基、分岐鎖アルケニル基、及び直鎖2級アルケニル基から選ばれる基が好ましく、直鎖1級アルキル基及び分岐鎖アルキル基から選ばれる基がより好ましい。
R7の炭素数は、洗浄性能を向上させる観点から、8以上、好ましくは10以上、より好ましくは12以上、そして、親水化性能を確保する観点から、22以下、好ましくは18以下、より好ましくは16以下である。 In the general formula (b4), R 7 is a hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms.
The hydrocarbon group of R 7 is selected from a linear primary alkyl group, a linear primary alkenyl group, a branched chain alkyl group, a linear secondary alkyl group, a branched chain alkenyl group, and a linear secondary alkenyl group. A group is preferable, and a group selected from a linear primary alkyl group and a branched chain alkyl group is more preferable.
The carbon number of R 7 is 8 or more, preferably 10 or more, more preferably 12 or more from the viewpoint of improving cleaning performance, and 22 or less, preferably 18 or less, more preferably from the viewpoint of ensuring hydrophilicity performance. Is 16 or less.
一般式(b4)中、n5は平均付加モル数であって、1以上15以下の数から選択される数である。n5は、洗浄性の観点から、好ましくは2以上、より好ましくは3以上、更に好ましくは4以上、そして、溶解性の観点から、好ましくは13以下、より好ましくは11以下、更に好ましくは9以下である。 In the general formula (b4), n4 is the average number of moles added, and is a number selected from a number of 3 or more and 30 or less. From the viewpoint of solubility, n4 is preferably 4 or more, more preferably 5 or more, further preferably 6 or more, and from the viewpoint of detergency, preferably 25 or less, more preferably 20 or less, still more preferably 15 or less. Is.
In the general formula (b4), n5 is the average number of moles added, and is a number selected from a number of 1 or more and 15 or less. From the viewpoint of detergency, n5 is preferably 2 or more, more preferably 3 or more, further preferably 4 or more, and from the viewpoint of solubility, preferably 13 or less, more preferably 11 or less, still more preferably 9 or less. Is.
R9(OA4)xGy (b5)
〔式中、R9は炭素数8以上22以下の炭化水素基であり、OA4はアルキレンオキシ基から選ばれる1種又は2種以上の基であり、Gは炭素数5又は6の糖に由来する残基であり、xはその平均値が0以上5以下の数であり、yはその平均値が1以上3以下となる数である。〕 The component (B1-4) is a nonionic surfactant represented by the following general formula (b5).
R 9 (OA 4) x G y (b5)
[In the formula, R 9 is a hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms, OA 4 is one or more groups selected from alkyleneoxy groups, and G is a sugar having 5 or 6 carbon atoms. Derived residues, x is a number whose average value is 0 or more and 5 or less, and y is a number whose average value is 1 or more and 3 or less. ]
上記一般式(b5)中のOA4はアルキレンオキシ基から選ばれる1種又は2種以上の基であり、エチレンオキシ基が好ましい。
上記一般式(b5)中のGで示される炭素数5又は6の糖に由来する残基は、使用される単糖類もしくは2糖類以上の糖によってその構造が決定される。Gとしては、単糖類ではグルコース、ガラクトース、キシロース、マンノース、リキソース、アラビノース、フルクトース又はこれらの混合物等に由来する残基が挙げられ、2糖類以上ではマルトース、キシロビオース、イソマルトース、セロビオース、ゲンチビオース、ラクトース、スクロース、ニゲロース、ツラノース、ラフィノース、ゲンチアノース、メンジトース又はこれらの混合物等に由来する残基が挙げられる。これらのうち好ましい原料は、単糖類ではグルコース及びフルクトースであり、2糖類以上ではマルトース及びスクロースである。
上記一般式(b5)中のxは、OA4の平均付加モル数であり、好ましくは0以上、そして、好ましくは5以下、より好ましくは3以下、更に好ましくは1以下であり、また0であってもよい。
上記一般式(b5)中のyの平均値が1より大きい場合、つまり2糖類以上の糖鎖を親水性基とする場合、糖鎖の結合様式が1-2、1-3、1-4、1-6結合又はα-、β-ピラノシド結合もしくはフラノシド結合及びこれらの混合された結合様式である任意の混合物を含むことが可能である。
上記一般式(b5)中のyは、その平均値が、1以上、そして、3以下、好ましくは2以下、より好ましくは1.5以下である。このyの値(糖の平均縮合度)は1H-NMRにより測定する。具体的な測定方法としては、特開平8-53696号公報第6頁第10欄26行目~7頁第11欄15行目を参照する。 In the above general formula (b5), the carbon number of R 9 is 8 or more, preferably 10 or more, and 22 or less, preferably 20 or less, more preferably 18 or less, from the viewpoint of achieving both cleaning performance and hydrophilicity performance. , More preferably 16 or less. It is a straight chain or branched chain alkyl group, preferably a straight chain alkyl group. The hydrocarbon group of R 9 is selected from a linear primary alkyl group, a linear primary alkenyl group, a branched chain alkyl group, a linear secondary alkyl group, a branched chain alkenyl group, and a linear secondary alkenyl group. A group is preferable, and a group selected from a linear primary alkyl group and a branched chain alkyl group is more preferable.
OA 4 in the general formula (b5) is one or more groups selected from alkyleneoxy groups, and ethyleneoxy groups are preferable.
The structure of the residue derived from the sugar having 5 or 6 carbon atoms represented by G in the general formula (b5) is determined by the monosaccharide used or the sugar having 2 or more saccharides. Examples of G include residues derived from glucose, galactose, xylose, mannose, lyxose, arabinose, fructose or a mixture thereof for monosaccharides, and maltose, xylobiose, isomaltose, cellobiose, gentibios and lactose for disaccharides or more. , Sculose, nigerose, turanose, raffinose, gentianose, menditos or mixtures thereof and the like. Of these, preferred raw materials are glucose and fructose for monosaccharides, and maltose and sucrose for disaccharides and above.
In the general formula (b5), x is the average number of moles of OA 4 added, preferably 0 or more, preferably 5 or less, more preferably 3 or less, still more preferably 1 or less, and 0. There may be.
When the average value of y in the above general formula (b5) is larger than 1, that is, when a sugar chain of 2 or more sugars is used as a hydrophilic group, the sugar chain binding mode is 1-2, 1-3, 1-4. , 1-6 bonds or α-, β-pyranoside bonds or furanoside bonds and any mixture thereof which is a mixed mode of binding thereof can be included.
The average value of y in the general formula (b5) is 1 or more and 3 or less, preferably 2 or less, and more preferably 1.5 or less. The value of y (average degree of condensation of sugar) is measured by 1 1 H-NMR. As a specific measurement method, refer to Japanese Patent Application Laid-Open No. 8-53396, page 6, column 10, line 26 to page 7, column 11, line 15.
(B1-5)成分のポリオキシアルキレン基としては、水溶性の観点から、ポリオキシエチレン、及びポリオキシプロピレンから選ばれる1種以上が好ましく、ポリオオキシエチレンがより好ましい。またポリオキシアルキレンの平均付加モル数は、水溶性の観点から、好ましくは2以上、より好ましくは3以上、更に好ましくは4以上、そして、好ましくは20以下、より好ましくは18以下、更に好ましくは16以下、より更に好ましくは13以下、より更に好ましくは10以下である。
(B1-5)成分の脂肪酸部分の炭素数は、洗浄性の観点から、好ましくは8以上、より好ましくは10以上、そして、好ましくは22以下、より好ましくは20以下、更に好ましくは18以下である。また(B1-5)成分の脂肪酸部分は、直鎖又は分岐鎖の飽和又は不飽和の脂肪酸が好ましく、直鎖又は分岐鎖の飽和の脂肪酸がより好ましい。 The component (B1-5) is a polyoxyalkylene glycerin fatty acid ester.
As the polyoxyalkylene group of the component (B1-5), at least one selected from polyoxyethylene and polyoxypropylene is preferable from the viewpoint of water solubility, and polyoxyethylene is more preferable. From the viewpoint of water solubility, the average number of moles of polyoxyalkylene added is preferably 2 or more, more preferably 3 or more, still more preferably 4 or more, and preferably 20 or less, more preferably 18 or less, still more preferably. It is 16 or less, more preferably 13 or less, and even more preferably 10 or less.
From the viewpoint of detergency, the carbon number of the fatty acid portion of the component (B1-5) is preferably 8 or more, more preferably 10 or more, and preferably 22 or less, more preferably 20 or less, still more preferably 18 or less. is there. Further, as the fatty acid portion of the component (B1-5), a straight-chain or branched-chain saturated or unsaturated fatty acid is preferable, and a straight-chain or branched-chain saturated fatty acid is more preferable.
本発明の洗浄又は親水化処理剤組成物は、(A)成分を、洗浄性能を向上させる観点から、好ましくは0.01質量%以上、より好ましくは0.1質量%以上、更に好ましくは0.5質量%以上、更に好ましくは1質量%以上、更に好ましくは5質量%以上、そして、親水化性能を向上させる観点から、好ましくは70質量%以下、より好ましくは40質量%以下、更に好ましくは20質量%以下、更に好ましくは10質量%以下含有する。
本発明の洗浄又は親水化処理剤組成物は、(A)成分として、(A1)成分を、洗浄性能を向上させる観点から、好ましくは0.01質量%以上、より好ましくは0.1質量%以上、更に好ましくは0.5質量%以上、更に好ましくは1質量%以上、更に好ましくは5質量%以上、そして、親水化性能を向上させる観点から、好ましくは70質量%以下、より好ましくは40質量%以下、更に好ましくは20質量%以下、更に好ましくは10質量%以下含有する。 <Composition, etc.>
In the cleaning or hydrophilizing treatment composition of the present invention, the component (A) is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, still more preferably 0, from the viewpoint of improving the cleaning performance. .5% by mass or more, more preferably 1% by mass or more, further preferably 5% by mass or more, and from the viewpoint of improving hydrophilicity performance, preferably 70% by mass or less, more preferably 40% by mass or less, still more preferable. Is contained in an amount of 20% by mass or less, more preferably 10% by mass or less.
In the cleaning or hydrophilizing treatment composition of the present invention, the component (A1) is preferably 0.01% by mass or more, more preferably 0.1% by mass, as the component (A) from the viewpoint of improving the cleaning performance. The above is more preferably 0.5% by mass or more, further preferably 1% by mass or more, further preferably 5% by mass or more, and from the viewpoint of improving the hydrophilization performance, preferably 70% by mass or less, more preferably 40. It is contained in an amount of% by mass or less, more preferably 20% by mass or less, still more preferably 10% by mass or less.
本発明の洗浄又は親水化処理剤組成物は、(B1)成分を、親水化性能を向上させる観点から、好ましくは0.01質量%以上、より好ましくは0.1質量%以上、更に好ましくは0.2質量%以上、より更に好ましくは0.5質量%以上、更に好ましくは1質量%以上、更に好ましくは2質量%以上、そして、洗浄性能を向上させる観点から、好ましくは70質量%以下、より好ましくは10質量%以下、更に好ましくは5質量%以下、更に好ましくは3質量%以下含有する。 In the cleaning or hydrophilization treatment composition of the present invention, the component (B) is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.1% by mass or more, from the viewpoint of improving the hydrophilization performance. 0.2% by mass or more, more preferably 0.5% by mass or more, further preferably 1% by mass or more, further preferably 2% by mass or more, and preferably 70% by mass or less from the viewpoint of improving cleaning performance. It is more preferably 10% by mass or less, further preferably 5% by mass or less, still more preferably 3% by mass or less.
In the cleaning or hydrophilization treatment composition of the present invention, the component (B1) is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.1% by mass or more, from the viewpoint of improving the hydrophilization performance. 0.2% by mass or more, more preferably 0.5% by mass or more, further preferably 1% by mass or more, further preferably 2% by mass or more, and preferably 70% by mass or less from the viewpoint of improving cleaning performance. , More preferably 10% by mass or less, further preferably 5% by mass or less, still more preferably 3% by mass or less.
本発明の洗浄又は親水化処理剤組成物において、(A1)成分の含有量と(B1)成分の含有量との質量比(A1)/(B1)が、洗浄性能及び親水化性能を向上させる観点から、好ましくは0.1以上、より好ましくは0.2以上、更に好ましくは0.5以上、より更に好ましくは0.7以上、より更に好ましくは1以上、より更に好ましくは1.5以上、より更に好ましくは2以上、より更に好ましくは2.5以上、そして、好ましくは15以下、より好ましくは11以下、更に好ましくは5以下、より更に好ましくは4以下、より更に好ましくは3以下である。 In the cleaning or hydrophilization treatment composition of the present invention, the mass ratio (A) / (B) of the content of the component (A) to the content of the component (B) improves the cleaning performance and the hydrophilization performance. From the viewpoint, it is preferably 0.1 or more, more preferably 0.2 or more, still more preferably 0.5 or more, still more preferably 0.7 or more, still more preferably 1 or more, still more preferably 1.5 or more. , More preferably 2 or more, even more preferably 2.5 or more, and preferably 15 or less, more preferably 11 or less, still more preferably 5 or less, even more preferably 4 or less, still more preferably 3 or less. is there.
In the cleaning or hydrophilization treatment composition of the present invention, the mass ratio (A1) / (B1) of the content of the component (A1) to the content of the component (B1) improves the cleaning performance and the hydrophilization performance. From the viewpoint, it is preferably 0.1 or more, more preferably 0.2 or more, still more preferably 0.5 or more, still more preferably 0.7 or more, still more preferably 1 or more, still more preferably 1.5 or more. , More preferably 2 or more, even more preferably 2.5 or more, and preferably 15 or less, more preferably 11 or less, still more preferably 5 or less, even more preferably 4 or less, still more preferably 3 or less. is there.
本発明は、(A)成分、(B)成分、及び水を含有する処理液(以下、本発明の処理液という場合もある)であって、(A)成分として、(A1)成分、(B)成分として、(B1)成分を含有する処理液を硬質表面に接触させる、硬質表面の洗浄又は親水化方法を提供する。(A)成分、(B)成分、硬質表面は、本発明の洗浄又は親水化処理剤組成物で述べたものと同じである。本発明の硬質表面の洗浄又は親水化方法には、本発明の洗浄又は親水化処理剤組成物で述べた事項を適宜適用することができる。例えば、本発明の固体表面の親水化方法における(A)成分、(B)成分の具体例や処理液中の含有量、質量比などの好ましい態様は、本発明の洗浄又は親水化処理剤組成物(ただし必要に応じて洗浄又は親水化剤組成物を処理液と置き換える)と同じである。
本発明の処理液は、本発明の洗浄又は親水化処理剤組成物であってもよく、また、本発明の洗浄又は親水化処理剤組成物と水とを混合して調製されたものであってよい。 [Method of cleaning or hydrophilizing hard surface]
The present invention is a treatment liquid containing the component (A), the component (B), and water (hereinafter, may be referred to as the treatment liquid of the present invention), and the component (A) includes the component (A1), ( Provided is a method for cleaning or hydrophilizing a hard surface in which a treatment liquid containing the component (B1) is brought into contact with the hard surface as the component B). The component (A), the component (B), and the hard surface are the same as those described in the cleaning or hydrophilizing treatment composition of the present invention. The matters described in the cleaning or hydrophilic treatment agent composition of the present invention can be appropriately applied to the method for cleaning or hydrophilizing a hard surface of the present invention. For example, specific examples of the component (A) and the component (B) in the method for hydrophilizing a solid surface of the present invention, the content in the treatment liquid, the mass ratio, and the like are preferred embodiments of the cleaning or hydrophilizing agent composition of the present invention. It is the same as the product (however, if necessary, the washing or hydrophilizing agent composition is replaced with the treatment liquid).
The treatment liquid of the present invention may be the cleaning or hydrophilization treatment agent composition of the present invention, or is prepared by mixing the cleaning or hydrophilization treatment agent composition of the present invention with water. You can do it.
本発明の処理液は、(A)成分として、(A1)成分を、洗浄性能を向上させる観点から、好ましくは0.001質量%以上、より好ましくは0.002質量%以上、更に好ましくは0.005質量%以上、そして、親水化性能を向上させる観点から、好ましくは1質量%以下、より好ましくは0.5質量%以下、更に好ましくは0.1質量%以下含有する。
本発明の洗浄又は親水化処理剤組成物が(A)成分、又は(A1)成分、をこの範囲で含有する場合、そのまま本発明の処理液として用いることができる。 From the viewpoint of improving the cleaning performance, the treatment liquid of the present invention preferably contains the component (A) in an amount of 0.001% by mass or more, more preferably 0.002% by mass or more, still more preferably 0.005% by mass or more. Then, from the viewpoint of improving the hydrophilization performance, it is preferably contained in an amount of 1% by mass or less, more preferably 0.5% by mass or less, still more preferably 0.1% by mass or less.
The treatment liquid of the present invention contains the component (A1) as the component (A), preferably 0.001% by mass or more, more preferably 0.002% by mass or more, and further preferably 0, from the viewpoint of improving the cleaning performance. From the viewpoint of improving the hydrophilization performance, the content is preferably 1% by mass or less, more preferably 0.5% by mass or less, still more preferably 0.1% by mass or less.
When the cleaning or hydrophilic treatment agent composition of the present invention contains the component (A) or the component (A1) in this range, it can be used as it is as the treatment liquid of the present invention.
本発明の処理液は、(B1)成分を、親水化性能を向上させる観点から、好ましくは0.001質量%以上、より好ましくは0.002質量%以上、更に好ましくは0.005質量%以上、そして、洗浄性能を向上させる観点から、好ましくは0.5質量%以下、より好ましくは0.1質量%以下、更に好ましくは0.05質量%以下含有する。
本発明の洗浄又は親水化処理剤組成物が(B)成分、又は(B1)成分をこの範囲で含有する場合、そのまま本発明の処理液として用いることができる。 The treatment liquid of the present invention preferably contains the component (B) in an amount of 0.001% by mass or more, more preferably 0.002% by mass or more, still more preferably 0.005% by mass or more, from the viewpoint of improving the hydrophilicity performance. From the viewpoint of improving the cleaning performance, the content is preferably 0.5% by mass or less, more preferably 0.1% by mass or less, still more preferably 0.05% by mass or less.
The treatment liquid of the present invention preferably contains the component (B1) in an amount of 0.001% by mass or more, more preferably 0.002% by mass or more, still more preferably 0.005% by mass or more, from the viewpoint of improving the hydrophilicity performance. From the viewpoint of improving the cleaning performance, the content is preferably 0.5% by mass or less, more preferably 0.1% by mass or less, still more preferably 0.05% by mass or less.
When the cleaning or hydrophilic treatment agent composition of the present invention contains the component (B) or the component (B1) in this range, it can be used as it is as the treatment liquid of the present invention.
本発明の処理液において、(A1)成分の含有量と(B1)成分の含有量との質量比(A1)/(B1)が、洗浄性能及び親水化性能を向上させる観点から、好ましくは0.1以上、より好ましくは0.2以上、更に好ましくは0.5以上、より更に好ましくは0.7以上、より更に好ましくは1以上、より更に好ましくは1.5以上、より更に好ましくは2以上、より更に好ましくは2.5以上、そして、好ましくは15以下、より好ましくは11以下、更に好ましくは5以下、より更に好ましくは4以下、より更に好ましくは3以下である。 In the treatment liquid of the present invention, the mass ratio (A) / (B) of the content of the component (A) to the content of the component (B) is preferably 0 from the viewpoint of improving the cleaning performance and the hydrophilization performance. .1 or more, more preferably 0.2 or more, still more preferably 0.5 or more, still more preferably 0.7 or more, still more preferably 1 or more, still more preferably 1.5 or more, still more preferably 2 Above, more preferably 2.5 or more, preferably 15 or less, more preferably 11 or less, still more preferably 5 or less, even more preferably 4 or less, still more preferably 3 or less.
In the treatment liquid of the present invention, the mass ratio (A1) / (B1) of the content of the component (A1) to the content of the component (B1) is preferably 0 from the viewpoint of improving the cleaning performance and the hydrophilization performance. .1 or more, more preferably 0.2 or more, still more preferably 0.5 or more, still more preferably 0.7 or more, still more preferably 1 or more, still more preferably 1.5 or more, still more preferably 2 Above, more preferably 2.5 or more, preferably 15 or less, more preferably 11 or less, still more preferably 5 or less, even more preferably 4 or less, still more preferably 3 or less.
(i)本発明の処理液に硬質物品を浸漬させる方法
(ii)本発明の処理液を硬質表面に噴霧又は塗布する方法
(iii)本発明の処理液で常法に従い硬質表面を洗浄又は親水化処理する方法
前記(i)の方法において、浸漬する時間は、本発明の処理液の親水化性能を高める観
点及び経済性の観点から、好ましくは0.5分以上、より好ましくは1分以上であり、そして、好ましくは60分以下、より好ましくは50分以下である。
前記(ii)の方法において、本発明の処理液を硬質表面に噴霧又は塗布する方法は、固体表面の広さ(面積)等に応じて適宜選択できる。本発明の処理液を硬質表面にスプレー等で噴霧した後、乾燥する方法が好ましい。必要に応じて、噴霧した後、水ですすいでもよい。また、噴霧した後、スポンジ等を用いて薄く塗りのばしてもよい。
硬質表面に噴霧又は塗布する本発明の処理液の量は、例えば、本発明の(A)成分の含有量が0.1質量%の本発明の処理液の場合、好ましくは10cm2あたり0.001mL以上1mL以下である。
前記(iii)の方法において、本発明の処理液は、本発明の(A)成分及び(B)成分
を含有する洗浄又は親水化処理剤組成物の形態で使用し、硬質表面と接触させることが好ましい。かかる洗浄又は親水化処理剤組成物の形態とする場合、取扱いの安全性、及び硬質表面の損傷防止の観点から、そのpHは4以上が好ましく、そして、10以下が好ましく、8以下がより好ましい。 The method of contacting the hard surface with the treatment liquid of the present invention is not particularly limited. For example, the following methods (i) to (iii) can be mentioned.
(I) Method of immersing a hard article in the treatment liquid of the present invention (ii) Method of spraying or applying the treatment liquid of the present invention to a hard surface (iii) Cleaning or hydrophilicity of the hard surface with the treatment liquid of the present invention according to a conventional method Method of chemical treatment In the method (i) above, the immersion time is preferably 0.5 minutes or longer, more preferably 1 minute or longer, from the viewpoint of enhancing the hydrophilic performance of the treatment liquid of the present invention and from the viewpoint of economic efficiency. And preferably 60 minutes or less, more preferably 50 minutes or less.
In the method (ii), the method of spraying or applying the treatment liquid of the present invention to a hard surface can be appropriately selected depending on the size (area) of the solid surface and the like. A method in which the treatment liquid of the present invention is sprayed onto a hard surface by a spray or the like and then dried is preferable. If necessary, it may be sprayed and then rinsed with water. Further, after spraying, it may be spread thinly with a sponge or the like.
The amount of the processing liquid of the present invention is sprayed or applied on hard surfaces, for example, if the content of the component (A) of the present invention is a treatment solution of the present invention of 0.1% by weight, preferably 10 cm 2 per 0. It is 001 mL or more and 1 mL or less.
In the method (iii) above, the treatment liquid of the present invention is used in the form of a cleaning or hydrophilizing treatment agent composition containing the components (A) and (B) of the present invention, and is brought into contact with a hard surface. Is preferable. In the form of such a cleaning or hydrophilizing treatment composition, the pH is preferably 4 or more, preferably 10 or less, and more preferably 8 or less from the viewpoint of handling safety and prevention of damage to the hard surface. ..
(A)アニオン界面活性剤(以下、(A)成分という)と、(B)ノニオン界面活性剤(以下、(B)成分という)と、水とを含有する洗浄又は親水化処理剤組成物であって、
(A)成分として、(A1)分岐型陰イオン界面活性剤(以下、(A1)成分という)、
(B)成分として、(B1)炭素数8以上22以下の炭化水素基を有するノニオン界面活性剤(以下、(B1)成分という)を含有する洗浄又は親水化処理剤組成物。 <1>
A cleaning or hydrophilizing treatment composition containing (A) anionic surfactant (hereinafter referred to as (A) component), (B) nonionic surfactant (hereinafter referred to as (B) component), and water. There,
As the component (A), (A1) branched anionic surfactant (hereinafter referred to as (A1) component),
A cleaning or hydrophilizing treatment composition containing (B1) a nonionic surfactant having a hydrocarbon group having 8 or more and 22 or less carbon atoms (hereinafter referred to as (B1) component) as a component (B).
(A)成分の含有量と(B)成分の含有量との質量比(A)/(B)が、好ましくは0.1以上、より好ましくは0.2以上、更に好ましくは0.5以上、より更に好ましくは0.7以上、より更に好ましくは1以上、より更に好ましくは1.5以上、より更に好ましくは2以上、より更に好ましくは2.5以上、そして、好ましくは15以下、より好ましくは11以下、更に好ましくは5以下、より更に好ましくは4以下、より更に好ましくは3以下である、<1>記載の洗浄又は親水化処理剤組成物。 <2>
The mass ratio (A) / (B) of the content of the component (A) to the content of the component (B) is preferably 0.1 or more, more preferably 0.2 or more, still more preferably 0.5 or more. , More preferably 0.7 or more, even more preferably 1 or more, even more preferably 1.5 or more, even more preferably 2 or more, even more preferably 2.5 or more, and preferably 15 or less. The cleaning or hydrophilizing agent composition according to <1>, preferably 11 or less, more preferably 5 or less, still more preferably 4 or less, still more preferably 3 or less.
(A1)成分の含有量と(B1)成分の含有量との質量比(A1)/(B1)が、好ましくは0.1以上、より好ましくは0.2以上、更に好ましくは0.5以上、より更に好ましくは0.7以上、より更に好ましくは1以上、より更に好ましくは1.5以上、より更に好ましくは2以上、より更に好ましくは2.5以上、そして、好ましくは15以下、より好ましくは11以下、更に好ましくは5以下、より更に好ましくは4以下、より更に好ましくは3以下である、<1>又は<2>記載の洗浄又は親水化処理剤組成物。 <3>
The mass ratio (A1) / (B1) of the content of the component (A1) to the content of the component (B1) is preferably 0.1 or more, more preferably 0.2 or more, still more preferably 0.5 or more. , More preferably 0.7 or more, even more preferably 1 or more, even more preferably 1.5 or more, even more preferably 2 or more, even more preferably 2.5 or more, and preferably 15 or less. The cleaning or hydrophilizing treatment composition according to <1> or <2>, preferably 11 or less, more preferably 5 or less, still more preferably 4 or less, still more preferably 3 or less.
(A1)成分の含有量が、好ましくは0.01質量%以上、より好ましくは0.1質量%以上、更に好ましくは0.5質量%以上、更に好ましくは1質量%以上、更に好ましくは5質量%以上、そして、親水化性能を向上させる観点から、好ましくは70質量%以下、より好ましくは40質量%以下、更に好ましくは20質量%以下、更に好ましくは10質量%以下である、<1>~<3>の何れか記載の洗浄又は親水化処理剤組成物。 <4>
The content of the component (A1) is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.5% by mass or more, still more preferably 1% by mass or more, still more preferably 5. From the viewpoint of improving the hydrophilization performance, it is preferably 70% by mass or less, more preferably 40% by mass or less, still more preferably 20% by mass or less, still more preferably 10% by mass or less, <1. > To <3> according to any of the cleaning or hydrophilization treatment agent compositions.
(B1)成分の含有量が、好ましくは0.01質量%以上、より好ましくは0.1質量%以上、更に好ましくは0.2質量%以上、より更に好ましくは0.5質量%以上、更に好ましくは1質量%以上、更に好ましくは2質量%以上、そして、洗浄性能を向上させる観点から、好ましくは70質量%以下、より好ましくは10質量%以下、更に好ましくは5質量%以下、更に好ましくは3質量%以下である、<1>~<4>の何れか記載の洗浄又は親水化処理剤組成物。 <5>
The content of the component (B1) is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.2% by mass or more, still more preferably 0.5% by mass or more, and further. It is preferably 1% by mass or more, more preferably 2% by mass or more, and from the viewpoint of improving cleaning performance, it is preferably 70% by mass or less, more preferably 10% by mass or less, still more preferably 5% by mass or less, still more preferably. Is 3% by mass or less, the cleaning or hydrophilizing treatment agent composition according to any one of <1> to <4>.
(A1)成分が、内部オレフィンスルホン酸塩、アルキルベンゼンスルホン酸塩、第二級アルカンスルホン酸塩及びジアルキルスルホコハク酸塩から選ばれる1種又は2種以上である、<1>~<5>の何れか記載の洗浄又は親水化処理剤組成物。 <6>
Any of <1> to <5>, wherein the component (A1) is one or more selected from an internal olefin sulfonate, an alkylbenzene sulfonate, a secondary alkane sulfonate, and a dialkyl sulfosuccinate. The cleaning or hydrophilizing agent composition according to the above.
(A1)成分が、炭素数8以上30以下の分岐鎖炭化水素基を有する陰イオン界面活性剤である、好ましくは炭素数8以上30以下の分岐鎖炭化水素基と、硫酸エステル基又はスルホン酸基とを有する陰イオン界面活性剤である、<1>~<6>の何れか記載の洗浄又は親水化処理剤組成物。 <7>
The component (A1) is an anionic surfactant having a branched chain hydrocarbon group having 8 or more and 30 or less carbon atoms, preferably a branched chain hydrocarbon group having 8 or more and 30 or less carbon atoms, and a sulfate ester group or a sulfonic acid. The cleaning or hydrophilic treatment agent composition according to any one of <1> to <6>, which is an anionic surfactant having a group.
(A1)成分の分岐鎖炭化水素基の炭素数が、好ましくは8以上、より好ましくは10以上、更に好ましくは16以上、そして、好ましくは30以下、より好ましくは28以下、更に好ましくは24以下、更に好ましくは22以下、更に好ましくは20以下であり、
(A1)成分の分岐鎖炭化水素基が、分岐鎖アルキル基、分岐鎖アルケニル基、又は分岐鎖アルキル基を有するアリール基が挙げられる、<1>~<7>の何れか記載の洗浄又は親水化処理剤組成物。 <8>
The number of carbon atoms of the branched chain hydrocarbon group of the component (A1) is preferably 8 or more, more preferably 10 or more, further preferably 16 or more, and preferably 30 or less, more preferably 28 or less, still more preferably 24 or less. , More preferably 22 or less, even more preferably 20 or less.
The washing or hydrophilicity according to any one of <1> to <7>, wherein the branched-chain hydrocarbon group of the component (A1) includes a branched-chain alkyl group, a branched-chain alkenyl group, or an aryl group having a branched-chain alkyl group. Chemical treatment agent composition.
(A1)成分が、内部オレフィンスルホン酸塩(以下、IOSという)である、<1>~<8>の何れか記載の洗浄又は親水化処理剤組成物。 <9>
The cleaning or hydrophilic treatment agent composition according to any one of <1> to <8>, wherein the component (A1) is an internal olefin sulfonate (hereinafter referred to as IOS).
ISOの炭化水素鎖の炭素数が8以上22以下である、<9>記載の洗浄又は親水化処理剤組成物。 <10>
The cleaning or hydrophilizing treatment agent composition according to <9>, wherein the ISO hydrocarbon chain has 8 or more and 22 or less carbon atoms.
IOS中、スルホン酸基が前記炭化水素鎖の2位に存在するIOSの割合が、モル基準又は質量基準で、好ましくは5%以上、より好ましくは10%以上、そして、好ましくは45%以下、より好ましくは30%以下である、<9>又は<10>記載の洗浄又は親水化処理剤組成物。 <11>
In IOS, the proportion of IOS in which the sulfonic acid group is present at the 2-position of the hydrocarbon chain is preferably 5% or more, more preferably 10% or more, and preferably 45% or less on a molar basis or a mass basis. The cleaning or hydrophilic treatment agent composition according to <9> or <10>, which is more preferably 30% or less.
IOS中、スルホン酸基が前記炭化水素鎖の1位に存在するIOSの割合が、モル基準又は質量基準で、好ましくは0.2%以上、より好ましくは0.5%以上、更に好ましくは1.0%以上、そして、好ましくは20%以下、より好ましくは10%以下、更に好ましくは5%以下、より更に好ましくは3%以下である、<9>~<11>の何れかに記載の洗浄又は親水化処理剤組成物。 <12>
The proportion of IOS in which the sulfonic acid group is present at the 1-position of the hydrocarbon chain in IOS is preferably 0.2% or more, more preferably 0.5% or more, still more preferably 1 on a molar basis or a mass basis. The description according to any one of <9> to <11>, which is 0.0% or more, preferably 20% or less, more preferably 10% or less, still more preferably 5% or less, still more preferably 3% or less. Cleaning or hydrophilization treatment composition.
IOS中、炭素数が16以上20以下の炭化水素鎖を有するIOSの割合が、好ましくは50質量%以上、より好ましくは70質量%以上、更に好ましくは80質量%以上、より更に好ましくは90質量%以上、より更に好ましくは95質量%以上、より更に好ましくは97質量%以上、そして、好ましくは100質量%以下であり、100質量%である、<9>~<12>の何れかに記載の洗浄又は親水化処理剤組成物。 <13>
The proportion of IOS having a hydrocarbon chain having 16 or more and 20 or less carbon atoms in the IOS is preferably 50% by mass or more, more preferably 70% by mass or more, still more preferably 80% by mass or more, still more preferably 90% by mass. % Or more, more preferably 95% by mass or more, even more preferably 97% by mass or more, and preferably 100% by mass or less, 100% by mass, according to any one of <9> to <12>. Cleaning or hydrophilization treatment agent composition.
IOS中、ヒドロキシアルカンスルホン酸塩(H体)とオレフィンスルホン酸塩(O体)とのモル比(H体/O体)が、好ましくは50/50を超え、より好ましくは70/30を超え、そして、好ましくは95/5以下、より好ましくは90/10以下である、<9>~<13>の何れかに記載の洗浄又は親水化処理剤組成物。 <14>
In IOS, the molar ratio (H-form / O-form) of hydroxyalkane sulfonate (H-form) to olefin sulfonate (O-form) preferably exceeds 50/50, and more preferably exceeds 70/30. The cleaning or hydrophilizing agent composition according to any one of <9> to <13>, preferably 95/5 or less, more preferably 90/10 or less.
(B1)成分が、(B1-1-1)炭素数8以上10以下の直鎖の炭化水素基を有するノニオン界面活性剤〔以下、(B1-1-1)成分という〕、(B1-1-2)炭素数8以上22以下の分岐鎖の炭化水素基を有するノニオン界面活性剤〔以下、(B1-1-2)成分という〕、(B1-2)炭素数11以上22以下の直鎖の炭化水素基を有するノニオン界面活性剤、(B1-3)下記一般式(b4)で表されるノニオン界面活性剤、(B1-4)下記一般式(b5)で表されるノニオン界面活性剤、及び(B1-5)ポリオキシアルキレングリセリン脂肪酸エステルから選ばれる1種又は2種以上のノニオン界面活性剤である、<1>~<14>の何れかに記載の洗浄又は親水化処理剤組成物。
R7-O-[(EO)n4(BO)n5]-R8 (b4)
〔式中、R7は炭素数8以上22以下の炭化水素基であり、R8は水素原子又はメチル基であり、EO基はエチレンオキシ基であり、n4は平均付加モル数であって、3以上30以下の数から選択される数であり、BO基はブチレンオキシ基であり、n5は平均付加モル数であって、1以上15以下の数から選択される数であり、EOとBOはランダム重合体又はブロック重合体であってもよい。〕
R9(OA4)xGy (b5)
〔式中、R9は炭素数8以上22以下の炭化水素基であり、OA4はアルキレンオキシ基から選ばれる1種又は2種以上の基であり、Gは炭素数5又は6の糖に由来する残基であり、xはその平均値が0以上5以下の数であり、yはその平均値が1以上3以下となる数である。〕 <15>
The component (B1) is (B1-1-1) a nonionic surfactant having a linear hydrocarbon group having 8 or more and 10 or less carbon atoms [hereinafter referred to as (B1-1-1) component], (B1-1). -2) Nonionic surfactant having a hydrocarbon group of a branched chain having 8 or more and 22 or less carbon atoms [hereinafter referred to as (B1-1-2) component], (B1-2) Linear chain having 11 or more and 22 or less carbon atoms. Nonionic surfactant having a hydrocarbon group of (B1-3) Nonionic surfactant represented by the following general formula (b4), (B1-4) Nonionic surfactant represented by the following general formula (b5) The cleaning or hydrophilic treatment agent composition according to any one of <1> to <14>, which is one or more nonionic surfactants selected from (B1-5) polyoxyalkylene glycerin fatty acid esters. Stuff.
R 7- O-[(EO) n4 (BO) n5 ] -R 8 (b4)
[In the formula, R 7 is a hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms, R 8 is a hydrogen atom or a methyl group, the EO group is an ethyleneoxy group, and n4 is the average number of moles added. It is a number selected from a number of 3 or more and 30 or less, the BO group is a butyleneoxy group, n5 is an average addition molar number, and is a number selected from a number of 1 or more and 15 or less, EO and BO. May be a random polymer or a block polymer. ]
R 9 (OA 4) x G y (b5)
[In the formula, R 9 is a hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms, OA 4 is one or more groups selected from alkyleneoxy groups, and G is a sugar having 5 or 6 carbon atoms. Derived residues, x is a number whose average value is 0 or more and 5 or less, and y is a number whose average value is 1 or more and 3 or less. ]
(B1)成分が、(B1-1-1)炭素数8以上10以下の直鎖の炭化水素基を有するノニオン界面活性剤(以下、(B1-1-1)成分という)、及び(B1-1-2)炭素数8以上22以下の分岐鎖の炭化水素基を有するノニオン界面活性剤(以下、(B1-1-2)成分という)から選ばれる1種又は2種以上のノニオン界面活性剤である、<1>~<15>の何れかに記載の洗浄又は親水化処理剤組成物。 <16>
The component (B1) is a nonionic surfactant having a linear hydrocarbon group having 8 or more and 10 or less carbon atoms (hereinafter referred to as (B1-1-1) component), and (B1-1-1). 1-2) One or more nonionic surfactants selected from nonionic surfactants having a hydrocarbon group of a branched chain having 8 or more and 22 or less carbon atoms (hereinafter referred to as (B1-1-2) component). The cleaning or hydrophilic treatment agent composition according to any one of <1> to <15>.
(B1-1-1)成分が、下記一般式(b1)で表されるノニオン界面活性剤である、<15>又は<16>記載の洗浄又は親水化処理剤組成物。
R1-O-(A1O)n1-R2 (b1)
〔式中、R1は炭素数8以上10以下の直鎖の炭化水素基であり、R2は水素原子又はメチル基であり、A1O基はアルキレンオキシ基から選ばれる1種又は2種以上の基であり、n1は平均付加モル数であって、5以上50以下の数から選択される数である。〕 <17>
The cleaning or hydrophilizing treatment agent composition according to <15> or <16>, wherein the component (B1-1-1) is a nonionic surfactant represented by the following general formula (b1).
R 1- O- (A 1 O) n1- R 2 (b1)
[In the formula, R 1 is a linear hydrocarbon group having 8 or more carbon atoms and 10 or less carbon atoms, R 2 is a hydrogen atom or a methyl group, and A 1 O group is one or two selected from alkyleneoxy groups. Based on the above, n1 is the average number of added moles, which is a number selected from 5 or more and 50 or less. ]
(B1-1-1)成分が、ポリオキシエチレンデシル又はデセニルエーテルである<15>~<17>の何れかに記載の洗浄又は親水化処理剤組成物。 <18>
The cleaning or hydrophilic treatment agent composition according to any one of <15> to <17>, wherein the component (B1-1-1) is polyoxyethylene decyl or decenyl ether.
(B1-1-2)成分が、下記一般式(b2)で表されるノニオン界面活性剤である、<15>~<18>の何れかに記載の洗浄又は親水化処理剤組成物。
R3-O-(A2O)n2-R4 (b2)
〔式中、R3は炭素数8以上22以下の分岐鎖の炭化水素基であり、R4は水素原子又はメチル基であり、A2O基はアルキレンオキシ基から選ばれる1種又は2種以上の基であり、n2は平均付加モル数であって、3以上50以下の数から選択される数である。〕 <19>
The cleaning or hydrophilizing treatment agent composition according to any one of <15> to <18>, wherein the component (B1-1-2) is a nonionic surfactant represented by the following general formula (b2).
R 3- O- (A 2 O) n2- R 4 (b2)
[In the formula, R 3 is a hydrocarbon group of a branched chain having 8 or more carbon atoms and 22 or less carbon atoms, R 4 is a hydrogen atom or a methyl group, and A 2 O group is one or two selected from alkyleneoxy groups. Based on the above, n2 is the average number of added moles, which is a number selected from a number of 3 or more and 50 or less. ]
(B1-2)成分が、下記一般式(b3)で表されるノニオン界面活性剤である、<15>~<19>の何れかに記載の洗浄又は親水化処理剤組成物。
R5-O-(A3O)n3-R6 (b3)
〔式中、R5は、炭素数11以上22以下の直鎖の炭化水素基であり、R6は水素原子又はメチル基であり、A3O基はアルキレンオキシ基から選ばれる1種又は2種以上の基であり、n3は平均付加モル数であって、3以上50以下の数から選択される数である。〕 <20>
The cleaning or hydrophilizing treatment agent composition according to any one of <15> to <19>, wherein the component (B1-2) is a nonionic surfactant represented by the following general formula (b3).
R 5- O- (A 3 O) n3- R 6 (b3)
[In the formula, R 5 is a linear hydrocarbon group having 11 or more and 22 or less carbon atoms, R 6 is a hydrogen atom or a methyl group, and A 3 O group is one or 2 selected from alkyleneoxy groups. It is a group of seeds or more, and n3 is an average addition molar number, which is a number selected from a number of 3 or more and 50 or less. ]
(B1-3)成分が、下記一般式(b4)で表されるノニオン界面活性剤である、<15>~<20>の何れかに記載の洗浄又は親水化処理剤組成物。
R7-O-[(EO)n4(BO)n5]-R8 (b4)
〔式中、R7は炭素数8以上22以下の炭化水素基であり、R8は水素原子又はメチル基であり、EO基はエチレンオキシ基であり、n4は平均付加モル数であって、3以上30以下の数から選択される数であり、BO基はブチレンオキシ基であり、n5は平均付加モル数であって、1以上15以下の数から選択される数であり、EOとBOはランダム重合体又はブロック重合体であってもよい。〕 <21>
The cleaning or hydrophilizing treatment agent composition according to any one of <15> to <20>, wherein the component (B1-3) is a nonionic surfactant represented by the following general formula (b4).
R 7- O-[(EO) n4 (BO) n5 ] -R 8 (b4)
[In the formula, R 7 is a hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms, R 8 is a hydrogen atom or a methyl group, the EO group is an ethyleneoxy group, and n4 is the average number of moles added. It is a number selected from a number of 3 or more and 30 or less, the BO group is a butyleneoxy group, n5 is an average addition molar number, and is a number selected from a number of 1 or more and 15 or less, EO and BO. May be a random polymer or a block polymer. ]
(B1-4)成分が、下記一般式(b5)で表されるノニオン界面活性剤である、<15>~<21>の何れかに記載の洗浄又は親水化処理剤組成物。
R9(OA4)xGy (b5)
〔式中、R9は炭素数8以上22以下の炭化水素基であり、OA4はアルキレンオキシ基から選ばれる1種又は2種以上の基であり、Gは炭素数5又は6の糖に由来する残基であり、xはその平均値が0以上5以下の数であり、yはその平均値が1以上3以下となる数である。〕 <22>
The cleaning or hydrophilizing treatment agent composition according to any one of <15> to <21>, wherein the component (B1-4) is a nonionic surfactant represented by the following general formula (b5).
R 9 (OA 4) x G y (b5)
[In the formula, R 9 is a hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms, OA 4 is one or more groups selected from alkyleneoxy groups, and G is a sugar having 5 or 6 carbon atoms. Derived residues, x is a number whose average value is 0 or more and 5 or less, and y is a number whose average value is 1 or more and 3 or less. ]
硬質表面用である、<1>~<22>の何れかに記載の洗浄又は親水化処理剤組成物。 <23>
The cleaning or hydrophilizing treatment agent composition according to any one of <1> to <22>, which is used for a hard surface.
(A)アニオン界面活性剤(以下、(A)成分という)と、(B)ノニオン界面活性剤(以下、(B)成分という)と、水とを含有する処理液を、硬質表面に接触させる、硬質表面の洗浄又は親水化処理方法であって、
前記処理液が
(A)成分として、(A1)分岐型陰イオン界面活性剤、
(B)成分として、(B1)炭素数8以上22以下の炭化水素基を有するノニオン界面活性剤
を含有する、硬質表面の洗浄又は親水化処理方法。 <24>
A treatment liquid containing (A) anionic surfactant (hereinafter referred to as (A) component), (B) nonionic surfactant (hereinafter referred to as (B) component), and water is brought into contact with a hard surface. , A method for cleaning or hydrophilizing hard surfaces,
The treatment liquid contains (A1) a branched anionic surfactant as a component (A).
A method for cleaning or hydrophilizing a hard surface, which comprises (B1) a nonionic surfactant having a hydrocarbon group having 8 or more and 22 or less carbon atoms as a component (B).
処理液を硬質表面に接触させた後、該硬質表面を水ですすぐ、<24>記載の硬質表面の洗浄又は親水化処理方法。 <25>
The method for cleaning or hydrophilizing a hard surface according to <24>, wherein the treatment liquid is brought into contact with a hard surface, and then the hard surface is rinsed with water.
処理液が、<1>~<23>の何れかに記載の洗浄又は親水化処理剤組成物と水とを混合して得られたものである、<24>または<25>記載の硬質表面の洗浄又は親水化処理方法。 <26>
The hard surface according to <24> or <25>, wherein the treatment liquid is obtained by mixing the cleaning or hydrophilization treatment agent composition according to any one of <1> to <23> with water. Cleaning or hydrophilization treatment method.
表中の成分は、以下のものを用いた。 Examples The components in the table used were as follows.
[製造例1](C18-IOS-Kの製造)
炭素数18の内部オレフィンスルホン酸カリウム塩(C18-IOS-K)は、例えば、以下の製造例で得ることができる。
攪拌装置付きフラスコに、1-オクタデカノール(花王社製「カルコール 8098」)7000質量部と、触媒としてγ-アルミナ(Strem Chemicals 社製)700質量部とを装填し、攪拌下、280℃にて、系内に窒素を流通させながら反応を行い、粗内部オレフィンを得ることができる。前記粗内部オレフィンを、148-158℃、0.5mmHgで蒸留することで、オレフィン純度100%の炭素数18の内部オレフィンを得ることができる。前記内部オレフィンを、薄膜式スルホン化反応器に入れ、反応器外部ジャケットに20℃の冷却水を通液する条件下で、SO3濃度2.8容量%の三酸化硫黄ガスを用いてスルホン化反応を行う。反応モル比(SO3/内部オレフィン)は、1.09になるように、前記内部オレフィン及びSO3の流通量を設定し、反応を行う。得られるスルホン化物を、理論酸価に対し1.2モル倍に相当する水酸化カリウム水溶液へ添加し、30℃で1時間、攪拌し、中和を行う。中和物をオートクレーブ中で160℃、1時間加熱することで加水分解を行い、内部オレフィンスルホン酸カリウム塩の粗生成物を得ることができる。分液漏斗に、前記粗生成物と、エタノールとを入れ、石油エーテルを加えて油溶性の不純物を抽出除去する。この操作を3回おこない、水相側を蒸発乾固して、炭素数18の内部オレフィンスルホン酸カリウム塩(C18-IOS-K)を得ることができる。
なお、表中の(A)成分の配合量は、酸型(C18-IOS-H)に換算した値を記載する。 <Ingredient (A)>
[Manufacturing Example 1] (Manufacturing of C18-IOS-K)
The potassium internal olefin sulfonic acid salt (C18-IOS-K) having 18 carbon atoms can be obtained, for example, in the following production example.
A flask with a stirrer was loaded with 7,000 parts by mass of 1-octadecanol ("Calcol 8098" manufactured by Kao Corporation) and 700 parts by mass of γ-alumina (manufactured by Strem Chemicals) as a catalyst, and heated to 280 ° C. under stirring. The reaction can be carried out while circulating nitrogen in the system to obtain a crude internal olefin. By distilling the crude internal olefin at 148-158 ° C. and 0.5 mmHg, an internal olefin having 100% olefin purity and 18 carbon atoms can be obtained. Said internal olefin were placed in thin-film sulfonation reactor, the reactor 20 ° C. cooling water in the external jacket under conditions that liquid passing, sulfonated using SO 3 concentration 2.8% by volume of sulfur trioxide gas React. The reaction molar ratio (SO 3 / internal olefin) is set to 1.09, and the flow amounts of the internal olefin and SO 3 are set to carry out the reaction. The obtained sulfonate is added to an aqueous potassium hydroxide solution corresponding to 1.2 mol times the theoretical acid value, and the mixture is stirred at 30 ° C. for 1 hour for neutralization. The neutralized product can be hydrolyzed by heating it in an autoclave at 160 ° C. for 1 hour to obtain a crude product of an internal potassium olefin sulfonic acid salt. The crude product and ethanol are placed in a separatory funnel, and petroleum ether is added to extract and remove oil-soluble impurities. This operation is performed three times to evaporate and dry the aqueous phase side to obtain an internal olefin sulfonic acid potassium salt (C18-IOS-K) having 18 carbon atoms.
As the blending amount of the component (A) in the table, the value converted into the acid type (C18-IOS-H) is described.
炭素数16の内部オレフィンスルホン酸カリウム塩(C16-IOS-K)は、例えば、以下の製造例で得ることができる。
攪拌装置付きフラスコに、1-ヘキサデカノール(花王社製「カルコール6098」)7000質量部と、触媒としてγ-アルミナ(Strem Chemicals 社製)700質量部とを装填し、攪拌下、280℃にて、系内に窒素を流通させながら反応を行い、粗内部オレフィンを得ることができる。前記粗内部オレフィンを、148-158℃、0.5mmHgで蒸留することで、オレフィン純度100%の炭素数18の内部オレフィンを得ることができる。前記内部オレフィンを、薄膜式スルホン化反応器に入れ、反応器外部ジャケットに20℃の冷却水を通液する条件下で、SO3濃度2.8容量%の三酸化硫黄ガスを用いてスルホン化反応を行う。反応モル比(SO3/内部オレフィン)は、1.09になるように、前記内部オレフィン及びSO3の流通量を設定し、反応を行う。得られるスルホン化物を、理論酸価に対し1.2モル倍に相当する水酸化カリウム水溶液へ添加し、30℃で1時間、攪拌し、中和を行う。中和物をオートクレーブ中で160℃、1時間加熱することで加水分解を行い、内部オレフィンスルホン酸カリウム塩の粗生成物を得ることができる。分液漏斗に、前記粗生成物と、エタノールとを入れ、石油エーテルを加えて油溶性の不純物を抽出除去する。この操作を3回おこない、水相側を蒸発乾固して、炭素数18の内部オレフィンスルホン酸カリウム塩(C16-IOS-K)を得ることができる。
なお、表中の(A)成分の配合量は、酸型(C16-IOS-H)に換算した値を記載する。 [Manufacturing Example 2] (Manufacturing of C16-IOS-K)
The potassium internal olefin sulfonic acid salt (C16-IOS-K) having 16 carbon atoms can be obtained, for example, in the following production example.
A flask with a stirrer was loaded with 7,000 parts by mass of 1-hexadecanol (“Calcol 6098” manufactured by Kao Corporation) and 700 parts by mass of γ-alumina (manufactured by Strem Chemicals) as a catalyst, and heated to 280 ° C. under stirring. The reaction can be carried out while circulating nitrogen in the system to obtain a crude internal olefin. By distilling the crude internal olefin at 148-158 ° C. and 0.5 mmHg, an internal olefin having 100% olefin purity and 18 carbon atoms can be obtained. Said internal olefin were placed in thin-film sulfonation reactor, the reactor 20 ° C. cooling water in the external jacket under conditions that liquid passing, sulfonated using SO 3 concentration 2.8% by volume of sulfur trioxide gas React. The reaction molar ratio (SO 3 / internal olefin) is set to 1.09, and the flow amounts of the internal olefin and SO 3 are set to carry out the reaction. The obtained sulfonate is added to an aqueous potassium hydroxide solution corresponding to 1.2 mol times the theoretical acid value, and the mixture is stirred at 30 ° C. for 1 hour for neutralization. The neutralized product can be hydrolyzed by heating it in an autoclave at 160 ° C. for 1 hour to obtain a crude product of an internal potassium olefin sulfonic acid salt. The crude product and ethanol are placed in a separatory funnel, and petroleum ether is added to extract and remove oil-soluble impurities. This operation is performed three times to evaporate and dry the aqueous phase side to obtain an internal olefin sulfonic acid potassium salt (C16-IOS-K) having 18 carbon atoms.
In addition, as the compounding amount of the component (A) in the table, the value converted into the acid type (C16-IOS-H) is described.
・C10(Guerbet)EO8:(B1-1-2)成分、炭素数10のゲルベアルコールにエチレンオキサイドを平均8モル付加して得たノニオン界面活性剤、Lutensol XP80、BASF社製
・C10(Guerbet)EO14:(B1-1-2)成分、炭素数10のゲルベアルコールにエチレンオキサイドを平均14モル付加して得たノニオン界面活性剤、Lutensol XP140、BASF社製
・Sec-(C12-14)EO5:(B1-1-2)成分、炭素数12~14の2級アルコールにエチレンオキサイドを平均5モル付加して得たノニオン界面活性剤、NIKKOL BT-5、日光ケミカルズ社製
・Sec-(C12-14)EO7:(B1-1-2)成分、炭素数12~14の2級アルコールにエチレンオキサイドを平均7モル付加して得たノニオン界面活性剤、NIKKOL BT-7、日光ケミカルズ社製
・Sec-(C12-14)EO9:(B1-1-2)成分、炭素数12~14の2級アルコールにエチレンオキサイドを平均9モル付加して得たノニオン界面活性剤、NIKKOL BT-9、日光ケミカルズ社製
・Sec-(C12-14)EO12:(B1-1-2)成分、炭素数12~14の2級アルコールにエチレンオキサイドを平均12モル付加して得たノニオン界面活性剤、NIKKOL BT-12、日光ケミカルズ社製
・C12EO3:(B1-2)成分、炭素数12の直鎖1級アルコールにエチレンオキサイドを平均3モル付加して得たノニオン界面活性剤、EMULGEN 103、花王社製
・C12EO6:(B1-2)成分、炭素数12の直鎖1級アルコールにエチレンオキサイドを平均6モル付加して得たノニオン界面活性剤、EMULGEN 108、花王社製
・C12EO9:(B1-2)成分、炭素数12の直鎖1級アルコールにエチレンオキサイドを平均9モル付加して得たノニオン界面活性剤、EMULGEN 109P、花王社製
・C12EO12:(B1-2)成分、炭素数12の直鎖1級アルコールにエチレンオキサイドを平均12モル付加して得たノニオン界面活性剤、EMULGEN 120、花王社製
・C12EO16:(B1-2)成分、炭素数12の直鎖1級アルコールにエチレンオキサイドを平均16モル付加して得たノニオン界面活性剤、EMULGEN 116、花王社製
・C12EO21:(B1-2)成分、炭素数12の直鎖1級アルコールにエチレンオキサイドを平均21モル付加して得たノニオン界面活性剤、EMULGEN 121、花王社製
・C12EO41:(B1-2)成分、炭素数12の直鎖1級アルコールにエチレンオキサイドを平均41モル付加して得たノニオン界面活性剤、EMULGEN 130K、花王社製
・C12EO47:(B1-2)成分、炭素数12の直鎖1級アルコールにエチレンオキサイドを平均47モル付加して得たノニオン界面活性剤、EMULGEN 150、花王社製
・C10EO5:(B1-1-1)成分、炭素数10の直鎖1級アルコールにエチレンオキサイドを平均5モル付加して得たノニオン界面活性剤、Lutensol ON50、BASF社製
・C10EO8:(B1-1-1)成分、炭素数10の直鎖1級アルコールにエチレンオキサイドを平均8モル付加して得たノニオン界面活性剤、Lutensol ON80、BASF社製
・Plurafac LF221:(B1-3)成分、脂肪族アルコールにエチレンオキサイドとブチレンオキサイドを付加して得たノニオン界面活性剤、Plurafac LF221、BASF社製
・C8-10APG:(B1-4)成分、一般式(b5)中、R9が炭素数8~10のアルキル基、xが0、yが1.5~1.8、Gがグルコースに由来する残基である化合物、Glucopon 225DK、BASF社製
・C8-16APG:(B1-4)成分、一般式(b5)中、R9が炭素数8~16のアルキル基、xが0、yが1.45~1.75、Gがグルコースに由来する残基である化合物、Glucopon 650EC、BASF社製
・C10-16APG:(B1-4)成分、一般式(b5)中、R9が炭素数10~16のアルキル基、xが0、yが1.35~1.45、Gがグルコースに由来する残基である化合物、マイドール 10、花王社製
・C12-14APG:(B1-4)成分、一般式(b5)中、R9が炭素数12~14のアルキル基、xが0、yが1.35~1.45、Gがグルコースに由来する残基である化合物、マイドール 12、花王社製
・Levenol F200:(B1-5)成分、ポリオキシエチレン(6)グリセリンヤシ油脂肪酸エステル(カッコ内はエチレンオキシドの付加モル数)、Levenol F200、花王社製 <Ingredient (B)>
-C10 (Guerbet) EO8: (B1-1-2) component, a nonionic surfactant obtained by adding an average of 8 mol of ethylene oxide to gelve alcohol having 10 carbon atoms, Lutensol XP80, manufactured by BASF, C10 (Guerbet) EO14: (B1-1-2) component, nonionic surfactant obtained by adding an average of 14 mol of ethylene oxide to gelve alcohol having 10 carbon atoms, Lutensol XP140, BASF, Sec- (C12-14) EO5: (B1-1-2) component, a nonionic surfactant obtained by adding an average of 5 mol of ethylene oxide to a secondary alcohol having 12 to 14 carbon atoms, NIKKOL BT-5, manufactured by Nikko Chemicals, Sec- (C12-) 14) EO7: (B1-1-2) component, a nonionic surfactant obtained by adding an average of 7 mol of ethylene oxide to a secondary alcohol having 12 to 14 carbon atoms, NIKKOL BT-7, manufactured by Nikko Chemicals, Inc., Sec -(C12-14) EO9: (B1-1-2) component, a nonionic surfactant obtained by adding an average of 9 mol of ethylene oxide to a secondary alcohol having 12 to 14 carbon atoms, NIKKOL BT-9, Nikko Chemicals NIKKOL BT-, a nonionic surfactant obtained by adding an average of 12 mol of ethylene oxide to a secondary alcohol having 12 to 14 carbon atoms, which is a component of Sec- (C12-14) EO12: (B1-1-2). 12, Nikko Chemicals Co., Ltd. C12EO3: (B1-2) component, a nonionic surfactant obtained by adding an average of 3 mol of ethylene oxide to a linear primary alcohol having 12 carbon atoms, EMULGEN 103, Kao Co., Ltd. C12EO6 : (B1-2) component, nonionic surfactant obtained by adding an average of 6 mol of ethylene oxide to a linear primary alcohol having 12 carbon atoms, EMULGEN 108, manufactured by Kao Co., Ltd. C12EO9: (B1-2) component, Nonionic surfactant obtained by adding an average of 9 mol of ethylene oxide to a linear primary alcohol having 12 carbon atoms, EMULGEN 109P, manufactured by Kao Co., Ltd., C12EO12: (B1-2) component, linear primary primary alcohol having 12 carbon atoms. Nonionic surfactant obtained by adding an average of 12 mol of ethylene oxide to alcohol, EMULGEN 120, manufactured by Kao Co., Ltd., C12EO16: (B1-2) component, an average of 16 mol of ethylene oxide in a linear primary alcohol having 12 carbon atoms. Nonion surfactant obtained by addition, EMULGEN 116, manufactured by Kao Co., Ltd. ・ C12EO21: (B1- 2) Component, nonionic surfactant obtained by adding 21 mol of ethylene oxide to a linear primary alcohol having 12 carbon atoms on average, EMULGEN 121, manufactured by Kao Co., Ltd. C12EO41: (B1-2) component, 12 carbon atoms Nonionic surfactant obtained by adding 41 mol of ethylene oxide to a linear primary alcohol on average, EMULGEN 130K, manufactured by Kao Co., Ltd. C12EO47: (B1-2) component, ethylene oxide to a linear primary alcohol having 12 carbon atoms Ethylene oxide was added to a nonionic surfactant obtained by adding an average of 47 mol of ethylene oxide, EMULGEN 150, C10EO5: (B1-1-1) component manufactured by Kao, and a linear primary alcohol having 10 carbon atoms by an average of 5 mol. Nonion surfactant obtained by adding an average of 8 mol of ethylene oxide to a linear primary alcohol having 10 carbon atoms, which is a component of C10EO8: (B1-1-1) manufactured by BASF, Lutensol ON50. Agent, Lutensol ON80, BASF, Plurafac LF221: (B1-3) component, nonionic surfactant obtained by adding ethylene oxide and butylene oxide to aliphatic alcohol, Plurafac LF221, BASF, C8-10APG: In the component (B1-4), the general formula (b5), R 9 is an alkyl group having 8 to 10 carbon atoms, x is 0, y is 1.5 to 1.8, and G is a residue derived from glucose. Compound, Glucopon 225DK, manufactured by BASF, C8-16APG: (B1-4) component, in general formula (b5), R 9 is an alkyl group having 8 to 16 carbon atoms, x is 0, y is 1.45 to 1. .75, Compound in which G is a residue derived from glucose, Glucopon 650EC, manufactured by BASF, C10-16APG: (B1-4) component, in general formula (b5), R 9 is an alkyl having 10 to 16 carbon atoms. Group, x is 0, y is 1.35 to 1.45, G is a residue derived from glucose, Mydol 10, manufactured by Kao Co., Ltd. C12-14APG: (B1-4) component, general formula ( In b5), R 9 is an alkyl group having 12 to 14 carbon atoms, x is 0, y is 1.35 to 1.45, and G is a residue derived from glucose, Mydol 12, manufactured by Kao Co., Ltd. Levenol F200: (B1-5) component, polyoxyethylene (6) glycerin palm oil fatty acid ester (the number of moles of ethylene oxide added in parentheses), Levenol F200, manufactured by Kao
牛脂100g、大豆油100g、モノオレイン酸2.5g、スダンIII(和光純薬社製)1.0g、クロロホルム600mLを混合したものをモデル汚れとした。調製したモデル汚れを、76mm×26mmのスライドガラス(松浪硝子工業社製 S2441)の両面に、両面の合計が0.04gとなるように均一に塗布したものをモデル油脂汚染スライドガラスとした。
洗浄には、脱イオン水に塩化カルシウムと塩化マグネシウムを質量比で2:1の割合で投入し、硬度8°dHに調製した水を用いた。調製した水0.7Lに対して表1~4に記載の洗浄又は親水化処理剤組成物を混合し、処理液とした。処理液中の(A)成分及び(B)成分の合計濃度が0.023質量%となるように混合した。リーナッツ試験器を用いて、洗浄試験用の1リットルのガラスビーカーに、処理液0.7Lとモデル油脂汚染スライドガラス(松浪硝子工業社製 S2441)6枚を試験器にセットした。処理液の温度は30℃に設定し、撹拌数250rpmで3分間攪拌し、洗浄した。洗浄後のスライドガラスを8°dH水0.7Lが入ったビーカーへ移し替えて、撹拌数250rpmで1分間濯ぎ、室温で乾燥させた。
上記の洗浄試験で得られたモデル油脂汚染スライドガラスの洗浄率を下記式より算出した。表1~4中の値は、6枚の洗浄率の平均値である。
洗浄率(%) = [1-(洗浄後のガラス重さ-モデル油脂塗布前のガラス重さ)/(モデル油脂塗布後のガラス重さ-モデル油脂塗布前のガラス重さ)]×100 <Washing test>
A mixture of 100 g of beef tallow, 100 g of soybean oil, 2.5 g of monooleic acid, 1.0 g of Sudan III (manufactured by Wako Pure Chemical Industries, Ltd.), and 600 mL of chloroform was used as a model stain. The prepared model stains were uniformly applied to both sides of a 76 mm × 26 mm slide glass (S2441 manufactured by Matsunami Glass Industry Co., Ltd.) so that the total of both sides was 0.04 g, and the slide glass was prepared as a model oil-contaminated slide glass.
For washing, calcium chloride and magnesium chloride were added to deionized water at a mass ratio of 2: 1 to prepare water having a hardness of 8 ° dH. The washing or hydrophilizing treatment agent compositions shown in Tables 1 to 4 were mixed with 0.7 L of the prepared water to prepare a treatment liquid. The components (A) and (B) in the treatment liquid were mixed so as to have a total concentration of 0.023% by mass. Using a leanut tester, 0.7 L of treatment liquid and 6 pieces of model oil-contaminated slide glass (S2441 manufactured by Matsunami Glass Industry Co., Ltd.) were set in a 1-liter glass beaker for a cleaning test. The temperature of the treatment liquid was set to 30 ° C., and the mixture was stirred at a stirring speed of 250 rpm for 3 minutes and washed. The washed slide glass was transferred to a beaker containing 0.7 L of 8 ° dH water, rinsed at a stirring rate of 250 rpm for 1 minute, and dried at room temperature.
The cleaning rate of the model oil-contaminated slide glass obtained in the above cleaning test was calculated from the following formula. The values in Tables 1 to 4 are the average values of the cleaning rates of 6 sheets.
Cleaning rate (%) = [1- (Glass weight after cleaning-Glass weight before applying model oil) / (Glass weight after applying model oil-Glass weight before applying model oil)] x 100
容量0.85Lのポリプロピレン製タッパー(ASVEL社製)を用いて、上記で調製した硬度8°dH水0.5Lに、表1~4に記載の洗浄又は親水化処理剤組成物を混合し、処理液とした。処理液中の(A)成分及び(B)成分の合計濃度が0.025質量%になるように添加し、処理液を得た。処理温度は25℃で一定とし、バイオシェーカーにより撹拌数70rpmで15分間溶液を混合した。つぎに、26mm×76mmのガラス板(あけぼの商会社製)1枚を加え、撹拌数70rpmで15分間攪拌した。攪拌後、タッパー中の洗浄水を廃水し、濯ぎとして、新たな硬度8°dH水0.5Lをタッパーに加えて、撹拌数70rpmで1分間攪拌し、濯ぎを行った。濯ぎを2回実施後、親水化処理に供したガラス板を一晩室温で乾燥させた。
乾燥後のガラスにおける水の接触角を、自動接触角測定機(DM-501Hi)を用いて測定した。表1~4中の値は、3点の接触角の平均値である。なお、親水化処理前のガラスの接触角は32.9°である。 <Hydrophilic evaluation process and contact angle measurement method>
Using a polypropylene tapper (manufactured by ASVEL) having a capacity of 0.85 L, the cleaning or hydrophilization treatment composition shown in Tables 1 to 4 was mixed with 0.5 L of water having a hardness of 8 ° dH prepared above. It was used as a treatment liquid. The components (A) and (B) in the treatment liquid were added so as to have a total concentration of 0.025% by mass to obtain a treatment liquid. The treatment temperature was kept constant at 25 ° C., and the solution was mixed with a bioshaker at a stirring rate of 70 rpm for 15 minutes. Next, one 26 mm × 76 mm glass plate (manufactured by Akebono Trading Company) was added, and the mixture was stirred at a stirring rate of 70 rpm for 15 minutes. After stirring, the washing water in the tapper was drained, and 0.5 L of water having a new hardness of 8 ° dH was added to the tapper for rinsing, and the tapper was stirred at a stirring rate of 70 rpm for 1 minute for rinsing. After rinsing twice, the glass plate subjected to the hydrophilization treatment was dried overnight at room temperature.
The contact angle of water in the dried glass was measured using an automatic contact angle measuring machine (DM-501Hi). The values in Tables 1 to 4 are the average values of the contact angles of the three points. The contact angle of the glass before the hydrophilization treatment is 32.9 °.
Claims (15)
- (A)アニオン界面活性剤(以下、(A)成分という)と、(B)ノニオン界面活性剤(以下、(B)成分という)と、水とを含有する洗浄又は親水化処理剤組成物であって、
(A)成分として、(A1)分岐型陰イオン界面活性剤(以下、(A1)成分という)、
(B)成分として、(B1)炭素数8以上22以下の炭化水素基を有するノニオン界面活性剤(以下、(B1)成分という)を含有する洗浄又は親水化処理剤組成物。 A cleaning or hydrophilizing treatment composition containing (A) anionic surfactant (hereinafter referred to as (A) component), (B) nonionic surfactant (hereinafter referred to as (B) component), and water. There,
As the component (A), (A1) branched anionic surfactant (hereinafter referred to as (A1) component),
A cleaning or hydrophilizing treatment composition containing (B1) a nonionic surfactant having a hydrocarbon group having 8 or more and 22 or less carbon atoms (hereinafter referred to as (B1) component) as a component (B). - (A1)成分の含有量が、0.01質量%以上70質量%以下である、請求項1記載の洗浄又は親水化処理剤組成物。 The cleaning or hydrophilizing treatment agent composition according to claim 1, wherein the content of the component (A1) is 0.01% by mass or more and 70% by mass or less.
- (B1)成分の含有量が、0.01質量%以上70質量%以下である、請求項1又は2記載の洗浄又は親水化処理剤組成物。 The cleaning or hydrophilic treatment agent composition according to claim 1 or 2, wherein the content of the component (B1) is 0.01% by mass or more and 70% by mass or less.
- (A1)成分が、内部オレフィンスルホン酸塩、アルキルベンゼンスルホン酸塩、第二級アルカンスルホン酸塩及びジアルキルスルホコハク酸塩から選ばれる1種又は2種以上である、請求項1~3の何れか1項記載の洗浄又は親水化処理剤組成物。 Any one of claims 1 to 3, wherein the component (A1) is one or more selected from an internal olefin sulfonate, an alkylbenzene sulfonate, a secondary alkane sulfonate and a dialkyl sulfosuccinate. The cleaning or hydrophilizing agent composition according to the above item.
- (A1)成分が、内部オレフィンスルホン酸塩である、請求項1~3の何れか1項記載の洗浄又は親水化処理剤組成物。 The cleaning or hydrophilic treatment agent composition according to any one of claims 1 to 3, wherein the component (A1) is an internal olefin sulfonate.
- 内部オレフィンスルホン酸塩の炭化水素鎖の炭素数が8以上22以下である、請求項5記載の洗浄又は親水化処理剤組成物。 The cleaning or hydrophilization treatment agent composition according to claim 5, wherein the hydrocarbon chain of the internal olefin sulfonate has 8 or more and 22 or less carbon atoms.
- (B1)成分が、(B1-1-1)炭素数8以上10以下の直鎖の炭化水素基を有するノニオン界面活性剤〔以下、(B1-1-1)成分という〕、(B1-1-2)炭素数8以上22以下の分岐鎖の炭化水素基を有するノニオン界面活性剤〔以下、(B1-1-2)成分という〕、(B1-2)炭素数11以上22以下の直鎖の炭化水素基を有するノニオン界面活性剤、(B1-3)下記一般式(b4)で表されるノニオン界面活性剤、(B1-4)下記一般式(b5)で表されるノニオン界面活性剤、及び(B1-5)ポリオキシアルキレングリセリン脂肪酸エステルから選ばれる1種又は2種以上のノニオン界面活性剤である、請求項1~6の何れか1項記載の洗浄又は親水化処理剤組成物。
R7-O-[(EO)n4(BO)n5]-R8 (b4)
〔式中、R7は炭素数8以上22以下の炭化水素基であり、R8は水素原子又はメチル基であり、EO基はエチレンオキシ基であり、n4は平均付加モル数であって、3以上30以下の数から選択される数であり、BO基はブチレンオキシ基であり、n5は平均付加モル数であって、1以上15以下の数から選択される数であり、EOとBOはランダム重合体又はブロック重合体であってもよい。〕
R9(OA4)xGy (b5)
〔式中、R9は炭素数8以上22以下の炭化水素基であり、OA4はアルキレンオキシ基から選ばれる1種又は2種以上の基であり、Gは炭素数5又は6の糖に由来する残基であり、xはその平均値が0以上5以下の数であり、yはその平均値が1以上3以下となる数である。〕 The component (B1) is (B1-1-1) a nonionic surfactant having a linear hydrocarbon group having 8 or more and 10 or less carbon atoms [hereinafter referred to as (B1-1-1) component], (B1-1). -2) Nonionic surfactant having a hydrocarbon group of a branched chain having 8 or more and 22 or less carbon atoms [hereinafter referred to as (B1-1-2) component], (B1-2) Linear chain having 11 or more and 22 or less carbon atoms. Nonionic surfactant having a hydrocarbon group of (B1-3) Nonionic surfactant represented by the following general formula (b4), (B1-4) Nonionic surfactant represented by the following general formula (b5) The cleaning or hydrophilic treatment agent composition according to any one of claims 1 to 6, which is one or more nonionic surfactants selected from (B1-5) polyoxyalkylene glycerin fatty acid esters. ..
R 7- O-[(EO) n4 (BO) n5 ] -R 8 (b4)
[In the formula, R 7 is a hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms, R 8 is a hydrogen atom or a methyl group, the EO group is an ethyleneoxy group, and n4 is the average number of moles added. It is a number selected from a number of 3 or more and 30 or less, the BO group is a butyleneoxy group, n5 is an average addition molar number, and is a number selected from a number of 1 or more and 15 or less, EO and BO. May be a random polymer or a block polymer. ]
R 9 (OA 4) x G y (b5)
[In the formula, R 9 is a hydrocarbon group having 8 or more carbon atoms and 22 or less carbon atoms, OA 4 is one or more groups selected from alkyleneoxy groups, and G is a sugar having 5 or 6 carbon atoms. Derived residues, x is a number whose average value is 0 or more and 5 or less, and y is a number whose average value is 1 or more and 3 or less. ] - (B1)成分が、(B1-1-1)炭素数8以上10以下の直鎖の炭化水素基を有するノニオン界面活性剤(以下、(B1-1-1)成分という)、及び(B1-1-2)炭素数8以上22以下の分岐鎖の炭化水素基を有するノニオン界面活性剤(以下、(B1-1-2)成分という)から選ばれる1種又は2種以上のノニオン界面活性剤である、請求項1~6の何れか1項記載の洗浄又は親水化処理剤組成物。 The component (B1) is (B1-1-1) a nonionic surfactant having a linear hydrocarbon group having 8 or more and 10 or less carbon atoms (hereinafter referred to as (B1-1-1) component), and (B1-1-1). 1-2) One or more nonionic surfactants selected from nonionic surfactants having a hydrocarbon group of a branched chain having 8 or more and 22 or less carbon atoms (hereinafter referred to as (B1-1-2) component). The cleaning or hydrophilic treatment agent composition according to any one of claims 1 to 6.
- (B1-1-1)成分が、下記一般式(b1)で表されるノニオン界面活性剤である、請求項7又は8記載の洗浄又は親水化処理剤組成物。
R1-O-(A1O)n1-R2 (b1)
〔式中、R1は炭素数8以上10以下の直鎖の炭化水素基であり、R2は水素原子又はメチル基であり、A1O基はアルキレンオキシ基から選ばれる1種又は2種以上の基であり、n1は平均付加モル数であって、5以上50以下の数から選択される数である。〕 The cleaning or hydrophilizing treatment composition according to claim 7 or 8, wherein the component (B1-1-1) is a nonionic surfactant represented by the following general formula (b1).
R 1- O- (A 1 O) n1- R 2 (b1)
[In the formula, R 1 is a linear hydrocarbon group having 8 or more carbon atoms and 10 or less carbon atoms, R 2 is a hydrogen atom or a methyl group, and A 1 O group is one or two selected from alkyleneoxy groups. Based on the above, n1 is the average number of added moles, which is a number selected from 5 or more and 50 or less. ] - (B1-1-2)成分が、下記一般式(b2)で表されるノニオン界面活性剤である、請求項7又は8記載の洗浄又は親水化処理剤組成物。
R3-O-(A2O)n2-R4 (b2)
〔式中、R3は炭素数8以上22以下の分岐鎖の炭化水素基であり、R4は水素原子又はメチル基であり、A2O基はアルキレンオキシ基から選ばれる1種又は2種以上の基であり、n2は平均付加モル数であって、3以上50以下の数から選択される数である。〕 The cleaning or hydrophilizing treatment composition according to claim 7 or 8, wherein the component (B1-1-2) is a nonionic surfactant represented by the following general formula (b2).
R 3- O- (A 2 O) n2- R 4 (b2)
[In the formula, R 3 is a hydrocarbon group of a branched chain having 8 or more carbon atoms and 22 or less carbon atoms, R 4 is a hydrogen atom or a methyl group, and A 2 O group is one or two selected from alkyleneoxy groups. Based on the above, n2 is the average number of added moles, which is a number selected from a number of 3 or more and 50 or less. ] - (A1)成分の含有量と(B1)成分の含有量との質量比(A1)/(B1)が、0.1以上15以下である、請求項1~10の何れか1項記載の洗浄又は親水化処理剤組成物。 The cleaning according to any one of claims 1 to 10, wherein the mass ratio (A1) / (B1) of the content of the component (A1) to the content of the component (B1) is 0.1 or more and 15 or less. Alternatively, a hydrophilization treatment agent composition.
- 硬質表面用である、請求項1~11の何れか1項記載の洗浄又は親水化処理剤組成物。 The cleaning or hydrophilizing treatment agent composition according to any one of claims 1 to 11, which is used for a hard surface.
- (A)アニオン界面活性剤(以下、(A)成分という)と、(B)ノニオン界面活性剤(以下、(B)成分という)と、水とを含有する処理液を、硬質表面に接触させる、硬質表面の洗浄又は親水化処理方法であって、
前記処理液が
(A)成分として、(A1)分岐型陰イオン界面活性剤、
(B)成分として、(B1)炭素数8以上22以下の炭化水素基を有するノニオン界面活性剤
を含有する、硬質表面の洗浄又は親水化処理方法。 A treatment liquid containing (A) anionic surfactant (hereinafter referred to as (A) component), (B) nonionic surfactant (hereinafter referred to as (B) component), and water is brought into contact with a hard surface. , A method for cleaning or hydrophilizing hard surfaces,
The treatment liquid contains (A1) a branched anionic surfactant as a component (A).
A method for cleaning or hydrophilizing a hard surface, which comprises (B1) a nonionic surfactant having a hydrocarbon group having 8 or more and 22 or less carbon atoms as a component (B). - 処理液を硬質表面に接触させた後、該硬質表面を水ですすぐ、請求項13記載の硬質表面の洗浄又は親水化処理方法。 The method for cleaning or hydrophilizing a hard surface according to claim 13, wherein the treatment liquid is brought into contact with a hard surface, and then the hard surface is rinsed with water.
- 処理液が、請求項1~12の何れか1項記載の洗浄又は親水化処理剤組成物と水とを混合して得られたものである、請求項13又は14記載の硬質表面の洗浄又は親水化処理方法。 The cleaning or cleaning of the hard surface according to claim 13 or 14, wherein the treatment liquid is obtained by mixing the cleaning or hydrophilic treatment agent composition according to any one of claims 1 to 12 with water. Hydrophilization treatment method.
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US17/766,566 US20230287301A1 (en) | 2019-11-21 | 2020-11-17 | Cleaning or hydrophilizing agent composition |
BR112022006158A BR112022006158A2 (en) | 2019-11-21 | 2020-11-17 | METHOD FOR HYDROPHILIZING A DIFFICULT CLEANING SURFACE AND HYDROPHILIZING AGENTS COMPOSITION |
JP2021558390A JPWO2021100692A1 (en) | 2019-11-21 | 2020-11-17 | |
AU2020385819A AU2020385819A1 (en) | 2019-11-21 | 2020-11-17 | Cleaning or hydrophilizing agent composition |
EP20889550.8A EP4063032A4 (en) | 2019-11-21 | 2020-11-17 | Cleaning or hydrophilizing agent composition |
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AU2020385819A1 (en) | 2022-06-02 |
EP4063032A1 (en) | 2022-09-28 |
MX2022005315A (en) | 2022-05-26 |
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TW202132552A (en) | 2021-09-01 |
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