WO2021085445A1 - Method for manufacturing pregelatinized cereal flour - Google Patents

Method for manufacturing pregelatinized cereal flour Download PDF

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Publication number
WO2021085445A1
WO2021085445A1 PCT/JP2020/040336 JP2020040336W WO2021085445A1 WO 2021085445 A1 WO2021085445 A1 WO 2021085445A1 JP 2020040336 W JP2020040336 W JP 2020040336W WO 2021085445 A1 WO2021085445 A1 WO 2021085445A1
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WIPO (PCT)
Prior art keywords
flour
slurry
pregelatinized
pregelatinization
starch
Prior art date
Application number
PCT/JP2020/040336
Other languages
French (fr)
Japanese (ja)
Inventor
研一郎 高松
佑佳子 向後
孝雄 長井
亨 重松
隆弘 柳下
Original Assignee
株式会社日清製粉グループ本社
日清製粉株式会社
日清フーズ株式会社
日清製粉プレミックス株式会社
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Application filed by 株式会社日清製粉グループ本社, 日清製粉株式会社, 日清フーズ株式会社, 日清製粉プレミックス株式会社 filed Critical 株式会社日清製粉グループ本社
Priority to CN202080071611.9A priority Critical patent/CN114554865A/en
Priority to JP2021553637A priority patent/JP7564116B2/en
Priority to CA3157980A priority patent/CA3157980A1/en
Priority to AU2020374460A priority patent/AU2020374460A1/en
Priority to US17/765,371 priority patent/US20220361510A1/en
Publication of WO2021085445A1 publication Critical patent/WO2021085445A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D6/00Other treatment of flour or dough before baking, e.g. cooling, irradiating, heating
    • A21D6/003Heat treatment
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D13/00Finished or partly finished bakery products
    • A21D13/02Products made from whole meal; Products containing bran or rough-ground grain
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D13/00Finished or partly finished bakery products
    • A21D13/06Products with modified nutritive value, e.g. with modified starch content
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D6/00Other treatment of flour or dough before baking, e.g. cooling, irradiating, heating
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/212Starch; Modified starch; Starch derivatives, e.g. esters or ethers
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/109Types of pasta, e.g. macaroni or noodles
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/117Flakes or other shapes of ready-to-eat type; Semi-finished or partly-finished products therefor
    • A23L7/13Snacks or the like obtained by oil frying of a formed cereal dough
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B30/00Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
    • C08B30/06Drying; Forming
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B30/00Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
    • C08B30/12Degraded, destructured or non-chemically modified starch, e.g. mechanically, enzymatically or by irradiation; Bleaching of starch
    • C08B30/14Cold water dispersible or pregelatinised starch
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/02Starch; Degradation products thereof, e.g. dextrin

Definitions

  • the present invention relates to pregelatinized flours suitable for food use.
  • Pregelatinized starch is obtained by heating raw starch in the presence of water to gelatinize it. Due to pregelatinization, the molecular arrangement inside the starch granules is disrupted, and it appears as irreversible changes in properties such as swelling of starch granules, loss of birefringence, melting of natural crystallites, and solubilization of starch. For this reason, pregelatinized starch exhibits unique properties different from those of raw material starch, and is widely used in food applications and industrial applications.
  • a method for producing pregelatinized starch a method of drying a starch slurry using a spray dryer, a drum dryer, or the like is known. Further, a method of adding water to starch and heating while kneading with an extruder, a method of heating and humidifying by passing superheated steam into a container containing starch, and the like are also known.
  • Patent Document 1 as a method for producing a modified starch having desired swelling property and water retention, water is added to the raw material starch to adjust the water content to 26 to 59% by mass, and then water vapor is added to the particles of the raw material starch. And / or a method of contacting hot water to increase the amount of water is described.
  • Patent Document 2 200 to 5000 parts by mass of water is added to 100 parts by mass of flours as a method for producing an ⁇ product of flours having a porous structure and which can be used as an adsorbent for aroma components and the like.
  • a method of adding alcohol and freeze-drying after heat gelatinization is described. In the method described in Patent Document 2, it is said that the heating temperature at the time of heat gelatinization is kept above the gelatinization temperature, and in the examples, the flours are pregelatinized on a boiling water bath.
  • starch In foods containing starch as the main component, aging of starch becomes a problem.
  • the starch contained in the bakery foods ages during storage and storage, and as a result, the texture that was fluffy immediately after production becomes hard and dry.
  • melting in the mouth worsens.
  • Starch aging is a phenomenon in which pregelatinized starch releases the water it holds and transforms into beta crystals.
  • An object of the present invention is to provide pregelatinized starches that can improve the taste and texture of foods and impart aging resistance to foods.
  • the present invention is an pregelatinization step of heating a slurry containing 100 parts by mass of grains and 500 parts by mass or more of water under a condition that the product temperature of the slurry is 90 ° C. or higher to pregelatinize the starch contained in the grains.
  • a method for producing pregelatinized starch which comprises a step of drying the slurry that has undergone the pregelatinization step to obtain a solid substance, and in the pregelatinization step, the slurry is stirred while heating the slurry. is there.
  • the present invention is a method for producing a processed food using the pregelatinized cereal flour produced by the above-mentioned method for producing pregelatinized starches of the present invention.
  • the method for producing pregelatinized cereal flours of the present invention includes an pregelatinization step of heating an aqueous slurry containing cereal flours to pregelatinize (gelatinize) the starch contained in the cereal flours, and drying and solidifying the slurry. It has a drying step to obtain a product.
  • pregelatinization step of heating an aqueous slurry containing cereal flours to pregelatinize (gelatinize) the starch contained in the cereal flours, and drying and solidifying the slurry. It has a drying step to obtain a product.
  • Examples of the cereals used in the present invention include cereals and starches and whole grain flours, and one of these may be used alone or in combination of two or more depending on the use of the food containing the pregelatinized cereals. Can be done.
  • the grain that is the source of the flour, starch, and whole grain flour may be a porridge seed or a porridge seed.
  • the flour that can be used as flour may be any flour containing starch, and examples thereof include wheat flour, rice flour, buckwheat flour, rye flour, and soybean flour.
  • wheat flour include soft flour, medium-strength flour, strong flour, durum wheat flour, and durum semolina.
  • wheat flour is typically used as the flour.
  • starch examples include unprocessed starches such as potato starch, wheat starch, cornstarch, waxy cornstarch, rice starch, and tapioca starch, and these unprocessed starches are processed with fats and oils, etherified, esterified, and acetyl. Examples thereof include processed starch that has been subjected to one or more treatments such as conversion, cross-linking treatment, and oxidation treatment.
  • the "starch” starch used as a raw material for the pregelatinization step) here means "pure starch” isolated from plants such as wheat, and is distinguished from the starch contained in the flour.
  • the whole grain flour that can be used as cereals contains all of the three main components constituting the grain caryopsis (grain grain), that is, the endosperm part, the exodermis part, and the embryo part.
  • the grain that is the source of whole grain flour is not particularly limited as long as it can be used for food, and examples thereof include wheat, barley, barley, rye, and rice.
  • one kind of whole grain grain flour may be used, or a plurality of kinds of whole grain grain flour may be used in combination.
  • the word "cereal" in the name "whole grain flour” may be used in place of the name of the grain that is the source of the grain.
  • a whole grain grain derived from wheat caryopsis is "wheat whole grain flour”
  • a whole grain grain derived from barley caryopsis is "wheat whole grain flour”.
  • whole wheat flour whole wheat flour is typically used.
  • the method for producing pregelatinized starch of the present invention is a method for pregelatinizing starch contained in flours, in which a slurry containing 100 parts by mass of cereals and 500 parts by mass or more of water is prepared and the product temperature of the slurry is 90 ° C. or higher. It is characterized by adopting a method of heating under the above conditions.
  • the amount of water added to 100 parts by mass of flour is much smaller than 500 parts by mass, and is often 100 parts by mass or less, and the heating temperature is set to be heated.
  • the product temperature of an object is set to less than 90 ° C.
  • the structural change of starch caused by the pregelatinization treatment becomes different from that of the conventional pregelatinization treatment.
  • High quality pregelatinized starches that cannot be obtained by law can be obtained. Since a certain amount of water is usually contained in the flour, the total mass of the water present in the slurry is 500 parts by mass or more of the water content with respect to 100 parts by mass of the flour, and the flour. It is the total of the amount contained in 100 parts by mass (usually about 15 parts by mass or less).
  • whole grain grains have the advantages of being rich in nutritional components and high in dietary fiber content, but have the problem that they are difficult to actively use as foodstuffs because of their unique odor (bran odor) and acridness.
  • odor unique odor
  • acridness by pregelatinizing the whole grain grain under the above-mentioned high water content and high temperature conditions adopted in the present invention, the peculiar odor and acridness are reduced, and the advantages such as the nutritional value inherent in the whole grain grain are maintained. The palatability can be improved.
  • the product temperature that is, the heating temperature of the slurry in the pregelatinization step is at least 90 ° C. or higher, preferably 100 ° C. or higher, more preferably 105 ° C. or higher, still more preferably 110 to 140 ° C., still more preferably 115 to 135 ° C. It is preferably 120 to 130 ° C.
  • the higher the heating temperature of the slurry the more the reforming of the starch progresses and the predetermined effect of the present invention is likely to be achieved.
  • the heating temperature is too high, it is necessary to control the pressure in the container containing the slurry. Since the amount of heat such as steam increases, it may lead to an increase in production cost and a decrease in productivity.
  • the upper limit of the product temperature of the slurry in the pregelatinization step should be about 140 ° C. Is preferable. Heating under the condition that the product temperature of the slurry exceeds 100 ° C. can be carried out, for example, by heating the slurry in a pressurized atmosphere.
  • the time for maintaining the product temperature of the slurry at 90 ° C. or higher (preferably 100 ° C. or higher), that is, the heating time is preferably 1 minute or longer, more preferably 3 minutes or longer.
  • the upper limit of the heating time in the pregelatinization step is not particularly limited, but from the viewpoint of production efficiency, it is preferably 180 minutes or less, more preferably 120 minutes or less.
  • the heating temperature of the slurry in the pregelatinization step may be at least 90 ° C. or higher, preferably 95 ° C. or higher, and more preferably 100 ° C. or higher as described above. is there.
  • the heating time may also be in the above range.
  • the slurry to be heated in the pregelatinization step can be prepared by adding 500 parts by mass or more of water to 100 parts by mass of flours.
  • the amount of water added is preferably 600 to 2500 parts by mass, more preferably 700 to 2000 parts by mass, and further preferably 800 to 1500 parts by mass with respect to 100 parts by mass of the flour. If the amount of water added is less than 500 parts by mass with 100 parts by mass of the flour, the predetermined effect of the present invention is not sufficiently exhibited. On the contrary, if the amount of water added is too large, a large amount of time and energy are required to obtain a solid substance in the drying step of the slurry in the next step, which may lead to an increase in production cost and a decrease in production efficiency.
  • the slurry typically contains only cereals (flour, starch, whole grain flour) and water as a solvent, but other components, such as cereals, are modified to desired properties as needed.
  • the resulting starch modifier may be contained.
  • the flour modifier include a preparation for scientific treatment, amylase, and an enzyme such as a protease that decomposes a protein contained in the flour.
  • a reaction involving the flour modifier such as an enzymatic reaction occurs, and this reaction may be completed before the slurry is subjected to the pregelatinization step. Alternatively, it may occur during the implementation of the pregelatinization step.
  • the slurry may be prepared by adding water to the pretreated flours.
  • the pretreatment of flours can be carried out, for example, by adding various chemicals (enzymes, acids or alkaline agents, emulsifiers, catalysts, etc.) to the flours.
  • the method for heating the slurry is not particularly limited as long as it can cope with the above-mentioned high water content and high temperature conditions.
  • a typical method for heating a slurry is a method in which a slurry containing flours is placed in a container and the container is heated.
  • the slurry may be heated in a batch system or in a continuous system.
  • Examples of the container for accommodating the slurry when heating it include a pressure cooker when a batch type is adopted and a line mixer such as a static mixer when a continuous type is adopted.
  • the heating method is also not particularly limited, and examples thereof include an electric type, a gas type, and a steam type, and one of these can be used alone or in combination of two or more.
  • Examples of the steam type heating method include a method of directly introducing saturated steam or superheated steam into a container containing an object to be treated (flours).
  • the pregelatinization step it is necessary to stir the slurry while heating the slurry. If the slurry is heated in a stationary state without stirring, the flours contained in the slurry may become lumpy, and pregelatinization (gelatinization) may be insufficient or non-uniform. By stirring the slurry during heating, such inconvenience is prevented and gelatinization of starch is promoted.
  • the method for stirring the slurry is not particularly limited as long as the contained flours can be dispersed throughout the slurry.
  • a known stirrer-equipped container equipped with a container and a stirrer to stir the contents of the container can be used and carried out according to a conventional method.
  • a static mixer can be exemplified.
  • a known ultrasonic vibration generating means can also be used as the slurry stirring means. In this case, the slurry is agitated by generating fine bubbles in the slurry by the vibration of the ultrasonic waves generated from the ultrasonic vibration generating means.
  • the amount of the solvent (water) contained in the slurry does not change during the heating of the slurry, that is, the pregelatinization treatment of the flours. This is because if the amount of solvent is significantly reduced (evaporated) during heating of the slurry, the promotion of pregelatinization may be suppressed.
  • the pregelatinization treatment is completed in a state containing 500 parts by mass or more of water with respect to 100 parts by mass of flours.
  • the container for accommodating the slurry is preferably one having pressure resistance.
  • the pressure in the pressurized atmosphere may be appropriately adjusted according to the amount of the solvent contained in the slurry and the heating temperature (product temperature of the slurry), and is not particularly limited. Since the upper limit temperature of the slurry due to heating depends on the pressure, it is preferable to set the pressure corresponding to the desired heating temperature.
  • the drying step the slurry that has undergone the above-mentioned pregelatinization step is dried to obtain a solid substance.
  • This solid matter is pregelatinized cereal flour, which is the production object of this production method.
  • the method for drying the slurry is not particularly limited, and a known drying method can be used, and examples thereof include freeze-drying, spray-drying using a spray dryer, and heat-drying using a drum dryer.
  • the degree of drying of the slurry is not particularly limited, but typically, the water content of the solid obtained by drying the slurry is the water content of general flours (flours used as raw materials in the pregelatinization step). Dry to the same extent.
  • General flours are usually about 15% by mass.
  • the solid matter obtained through the drying step may be crushed into powder if necessary.
  • the solid matter can be crushed according to a conventional method using a corby mill, a juicer, etc. for a household crusher, or a hammer mill, a pin mill, a jet mill, etc. for an industrial crusher, until the desired particle size is reached.
  • the solid material may be crushed.
  • the degree of pregelatinization (gelatinization) of the pregelatinized flour produced by the production method of the present invention can be preferably 90% or more, more preferably 95% or more.
  • the degree of pregelatinization refers to the degree of pregelatinization measured by the BAP method ( ⁇ -amylase / pullulanase method). The measurement of the degree of pregelatinization by the BAP method can be carried out as follows according to the previous report (Home Economics Magazine 32 (9), 653-659, 1981).
  • B-1) Sample flour (pregelatinized flour) is crushed with a homogenizer to a size of 100 mesh or less. Take 0.08 to 0.10 g of this crushed sample flour into a glass homogenizer.
  • B-2) 8.0 mL of demineralized water is added to the contents of the glass homogenizer, and the glass homogenizer is moved up and down 10 to 20 times to disperse the contents to obtain a dispersion liquid.
  • B-3) Take 2 mL each of the dispersion of B-2) in two 25 mL graduated test tubes, and one of the two is filled with 0.8 M acetate-Na acetate buffer. , The test area.
  • B-4) 0.2 mL of 10N sodium hydroxide solution was added to the other one of the two, and the mixture was reacted at 50 ° C. for 3 to 5 minutes to completely glue the dispersion of B-2). To make it. Then, 1.0 mL of a 2N acetic acid solution is added to the other one, the pH is adjusted to around 6.0, and the volume is adjusted with 0.8 M acetic acid-Na acetate buffer to prepare a gelatinized group. B-5) Take 0.4 mL each of the test solutions of the test group and gelatinized group prepared in B-3) and B-4), add 0.1 mL of the enzyme solution to each, and use the enzyme at 40 ° C. for 30 minutes. React to obtain a reacted solution.
  • the degree of pregelatinization is calculated by the following formula.
  • A, A', a, and a' are as follows.
  • A Absorbance of test group
  • A' Absorbance of gelatinized group
  • a Absorbance of blank in test group
  • a' Absorbance of blank in gelatinized group
  • pregelatinized flours produced by the production method of the present invention can be used in place of known pregelatinized flours and pregelatinized starches, and are typically used. Is used in the food industry, but can also be used in fields other than the food industry. Examples of the use of pregelatinized flours in the food industry are 1) thickening and retaining molds for applications that omit heat cooking (for example, instant soup), 2) modifying the dough of cake mixes and stabilizing the structure of frozen foods.
  • pregelatinized flour produced using corn flour as flour substitute for soup or easy cancer flour
  • pregelatinized flour manufactured using waxy corn flour as flour bean confectionery Clothes can be mentioned.
  • pregelatinized cereal flour produced using potato starch as the cereal flour sticking of feed; casting sand mold, incense, polishing grindstone, etc. Adhesion; household laundry paste; paper strength enhancer.
  • Pregelatinized flours can be used in the production of processed foods.
  • the processed foods referred to here are manufactured using cereal flour as a raw material.
  • cereal flour for example, bakery foods; noodles such as udon, somen, hiyamugi, Chinese noodles, pasta, instant noodles (including non-fried noodles); tempura, etc.
  • Fried foods such as fried, fried Tatsuta, and fritters, and other oil-boiled foods (foods manufactured through the oil-boiled process); powdered foods such as instant soup.
  • the noodles include noodle skins such as dumpling skin, shumai skin, and spring roll skin.
  • the processed food may be a frozen food.
  • the processed food can be produced according to a conventional method according to the type of the processed food.
  • Pregelatinized flours are suitable for the production of bakery foods.
  • bakery foods are given a fluffy softness, moist feeling, and chewy feeling, and aging resistance is imparted, and deterioration of taste and texture over time is suppressed.
  • cereals grain flour, starch, whole grain flour, etc.
  • optional ingredients such as yeast, leavening agent (baking powder, etc.), water, salt, and sugar as necessary. It is a food obtained by baking a fermented or non-fermented dough.
  • bakery foods include breads; pizzas; cakes; Japanese and Western baked goods such as waffles, shoes, biscuits, and baked buns; and fried sweets such as donuts.
  • breads include breads (for example, rolls, white breads, black breads, French breads, kanpans, koppe breads, croissants, etc.), cooked breads, sweet breads, and the like.
  • cakes include sponge cakes, butter cakes, roll cakes, hot cakes, busses, balmkuchens, pound cakes, cheesecakes, snack cakes, muffins, bars, cookies, pancakes and the like.
  • Examples 1 to 10, Comparative Examples 1 to 5 Wheat flour was used as the flour, and a predetermined amount of water was added to the flour to prepare an aqueous slurry. This slurry is placed in the pressure vessel of a pressure vessel equipped with a stirrer (rotatably installed paddle), and while stirring with the stirrer, it is heated by the heating method and heating temperature shown in Table 1 below to produce starch (wheat flour). ) Was gelatinized (gelatinized) (gelatinization step). The heating time in the pregelatinization step (the time for maintaining the heating temperature shown in Table 1 below) was 1 minute, 3 minutes, or 30 minutes.
  • pregelatinized wheat flours pregelatinized wheat flours
  • Examples 1 to 10, Comparative Examples 1 and 3 pregelatinized wheat flours
  • pregelatinized wheat flour was obtained in the same manner as in the above procedure except that 30 parts by mass of water was added to 100 parts by mass of wheat flour and heated with an extruder at a predetermined heating temperature for a predetermined time (Comparative Example 2). ..
  • pregelatinized wheat flour was produced without stirring the slurry while heating the slurry. Specifically, a predetermined amount of water was added to wheat flour to prepare an aqueous slurry, the slurry was filled in a retort pouch bag, sealed, and heat-treated at 120 ° C. for 3 minutes using an autoclave. After that, pregelatinized wheat flour was obtained in the same manner as described above (Comparative Examples 4 and 5). When this method was used, the slurry after heating by the autoclave, that is, after undergoing the pregelatinization step, had water separation and had a non-uniform viscosity (partially lumpy), and was not uniformly gelatinized. In addition, since the slurry was lumpy, the efficiency from freeze-drying to pulverization was also poor.
  • Examples 11 to 16, Comparative Examples 6 to 8 Whole wheat flour, cornstarch or wheat starch was used as the grain flour, and the pregelatinized wheat whole grain flour, pregelatinized cornstarch or ⁇ was carried out in the same manner as in the above-mentioned Example or Comparative Example except that the pregelatinization step was carried out under the conditions shown in Table 2 below. Chemicalized wheat starch was obtained.
  • Pancakes which are a type of bakery food, were produced using the baked confectionery mixes shown in Table 3 below. Specifically, 100 parts by mass of the mix, 25 parts by mass of sugar, 5 parts by mass of baking powder, 10 parts by mass of salad oil, 30 parts by mass of whole eggs, 50 parts by mass of milk and an appropriate amount of water are placed in a container and 120 times / minute.
  • the pancake dough was prepared by manually mixing and stirring at the number of rotations to prepare a pancake dough having a viscosity in the range of 5 to 10 Pa ⁇ s by a B-type viscosity meter at a product temperature of 25 ° C.
  • the amount of water blended was adjusted so that the viscosity of the pancake dough was within such a range. After allowing 10 minutes to let the prepared pancake dough rest, 55 g of the dough is poured onto a griddle plate, one side of the dough is baked at a temperature of 180 ° C. for 3 minutes, and then the dough is turned upside down. The other side was baked for 2 minutes to remove the rough heat, and then pancakes were produced.
  • Bread which is a kind of bakery food, was produced using a bread mix having the formulations shown in Table 4 below and using a commercially available home bakery (trade name "SD-BM103", manufactured by Panasonic Corporation). Specifically, 100 parts by mass of the mix, 4 parts by mass of butter, 6.8 parts by mass of sugar, 2.4 parts by mass of skim milk, 2 parts by mass of salt, and 1.1 parts by mass of dry yeast are put into a home bakery, and the home bakery is provided. Bread was made by selecting the "standard course”.
  • Non-fried instant Chinese noodles which are a kind of noodles, were produced using the raw material powders having the formulations shown in Table 5 below.
  • the raw material flour medium-strength flour (“Tokujaku” manufactured by Nisshin Flour Milling Co., Ltd.) was used as wheat flour, and oxidized tapioca starch (“MKK100” manufactured by Matsutani Chemical Industry Co., Ltd.) was used as starch.
  • noodle dough was prepared by kneading with a mixer for 10 minutes by a conventional method.
  • the noodle dough was rolled with a noodle-making roll to form a noodle band having a thickness of 1.2 mm, and further cut into noodle strings with a cutting blade (# 18 angle).
  • the noodle strings were steam-heat-treated with steam at a temperature of 100 ° C. for 2 minutes and 30 seconds, and then dried with hot air at 90 ° C. for 20 minutes to produce non-fried instant Chinese noodles.
  • Refrigerated boiled udon noodles which are a type of noodles (cooked refrigerated noodles), were produced using the raw material powders having the formulations shown in Table 6 below.
  • medium-strength flour (“Kaoru” manufactured by Nisshin Flour Milling Co., Ltd.) is used as wheat flour
  • acetylated tapioca starch (“hydrangea” manufactured by Matsutani Chemical Industry Co., Ltd.) is used as starch
  • Glico Foods Co., Ltd. is used as wheat protein.
  • the company-made "A Guru G” was used.
  • Gyoza rind which is a type of noodles (noodle skins), is produced using the raw material powders of the formulations shown in Table 7 below, and chilled gyoza, which is a type of cooked chilled dumplings, is further produced using the produced gyoza rind.
  • Manufactured As a specific procedure, first, 1 part by mass of salt and an appropriate amount of water were added to 100 parts by mass of the raw material flour, kneaded for 10 minutes, and then aged for 30 minutes to prepare a dough.
  • the dough was rolled by a conventional method to make the final noodle band thickness 1 mm, and then cut out with a mold having a diameter of 85 mm to produce raw dumpling skin.
  • 12 g of dumpling ingredients are wrapped in raw dumpling skin to produce raw dumplings, and after the raw dumplings are baked and cooked, they are stored in a refrigerator with an internal temperature of 4 ° C for 3 days to produce refrigerated grilled dumplings. did.
  • the shrimp tempura produced in this way was taken out of the oil tank, drained, left at room temperature (about 25 ° C) for 60 minutes, and then eaten by 10 specialized panelists, and the texture was evaluated according to the following evaluation criteria (out of 5 points). Was evaluated by.
  • the results (average score of 10 specialized panelists) are shown in Table 8 below.
  • pregelatinized starches that can improve the taste and texture of foods and impart aging resistance to foods are provided.
  • pregelatinized starches pregelatinized starches
  • Pregelatinized whole grain flour pregelatinized whole grain flour
  • the pregelatinized starch produced by the present invention is blended in a bakery food, the bakery food is given a fluffy softness, a moist feeling, and a chewy feeling, and is also imparted with aging resistance and has a taste and texture. Deterioration over time is suppressed.
  • the same effect can be obtained when the pregelatinized starch produced by the present invention is blended in noodles or oily foods, and when it is blended in instant noodles, the resilience at the time of reconstitution with hot water can be further improved. ..

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Abstract

This method for manufacturing a pregelatinized cereal flour has: a pregelatinization step for heating a slurry containing 100 mass parts of a grain flour and 500 mass parts or more of water so that the article temperature of the slurry is 90°C or higher, and pregelatinizing starch contained in the grain flour; and a step for drying the slurry that has been subjected to the pregelatinization step, and obtaining solid matter. In the pregelatinization step, the slurry is stirred while being heated. In the pregelatinization step, the slurry is preferably heated so that the article temperature thereof is 100°C or higher. The present invention provides a pregelatinized cereal flour with which it is possible to improve the flavor and texture of food and impart aging resistance to food.

Description

α化穀粉類の製造方法Manufacturing method of pregelatinized flour
 本発明は、食品用途に好適なα化穀粉類に関する。 The present invention relates to pregelatinized flours suitable for food use.
 α化澱粉は、原料澱粉を水分存在下で加熱してα化(糊化)させたものである。α化により、澱粉粒内部の分子配列が崩壊し、澱粉粒の膨潤、複屈折性の喪失、天然の微結晶の融解、澱粉の可溶化など、性状の不可逆変化として現れる。このため、α化澱粉は原料澱粉とは異なる特有の性状を示し、食品用途や工業用途など幅広く用いられている。α化澱粉の製造方法としては従来、澱粉のスラリーをスプレードライヤー、ドラムドライヤーなどを用いて乾燥する方法が知られている。また、澱粉に加水してエクストルーダーで混錬しつつ加熱する方法、澱粉が収容された容器内に過熱蒸気を通して加熱・加湿する方法なども知られている。 Pregelatinized starch is obtained by heating raw starch in the presence of water to gelatinize it. Due to pregelatinization, the molecular arrangement inside the starch granules is disrupted, and it appears as irreversible changes in properties such as swelling of starch granules, loss of birefringence, melting of natural crystallites, and solubilization of starch. For this reason, pregelatinized starch exhibits unique properties different from those of raw material starch, and is widely used in food applications and industrial applications. Conventionally, as a method for producing pregelatinized starch, a method of drying a starch slurry using a spray dryer, a drum dryer, or the like is known. Further, a method of adding water to starch and heating while kneading with an extruder, a method of heating and humidifying by passing superheated steam into a container containing starch, and the like are also known.
 特許文献1には、所望の膨潤性及び保水性を有する改質澱粉の製造方法として、原料澱粉に加水して水分量を26~59質量%に調湿した後、該原料澱粉の粒子に水蒸気及び/又は熱水を接触させて水分量を上昇させる方法が記載されている。特許文献2には、多孔質化した構造を有し、香気成分吸着剤などに利用可能な穀粉類α化物の製造方法として、穀粉類100質量部に対し水200~5000質量部を添加して加熱糊化させた後、アルコールを添加して凍結乾燥する方法が記載されている。特許文献2記載の方法では、加熱糊化する際の加熱温度に関し、糊化温度以上に保つとされており、実施例では穀粉類を沸騰湯浴上でα化させている。 According to Patent Document 1, as a method for producing a modified starch having desired swelling property and water retention, water is added to the raw material starch to adjust the water content to 26 to 59% by mass, and then water vapor is added to the particles of the raw material starch. And / or a method of contacting hot water to increase the amount of water is described. In Patent Document 2, 200 to 5000 parts by mass of water is added to 100 parts by mass of flours as a method for producing an α product of flours having a porous structure and which can be used as an adsorbent for aroma components and the like. A method of adding alcohol and freeze-drying after heat gelatinization is described. In the method described in Patent Document 2, it is said that the heating temperature at the time of heat gelatinization is kept above the gelatinization temperature, and in the examples, the flours are pregelatinized on a boiling water bath.
特開2014-205776号公報Japanese Unexamined Patent Publication No. 2014-2057776 特開平3-43052号公報Japanese Unexamined Patent Publication No. 3-43052
 澱粉を主成分とする食品においては、澱粉の老化が問題となる。例えばベーカリー食品においては、その貯蔵・保管中に、含有されている澱粉の老化が進行し、それに伴って、製造直後はふんわりした食感であったものが、硬くパサパサとした食感となったり、口溶けが悪化したりするという問題がある。澱粉の老化は、α化澱粉がその抱き込んでいた水分を放出してベータ結晶へと変化する現象である。食品の食味食感を高いレベルで改善するとともに、老化などの経時的劣化を抑制し得る技術が要望されている。 In foods containing starch as the main component, aging of starch becomes a problem. For example, in bakery foods, the starch contained in the bakery foods ages during storage and storage, and as a result, the texture that was fluffy immediately after production becomes hard and dry. , There is a problem that melting in the mouth worsens. Starch aging is a phenomenon in which pregelatinized starch releases the water it holds and transforms into beta crystals. There is a demand for a technique capable of improving the taste and texture of food at a high level and suppressing deterioration over time such as aging.
 本発明の課題は、食品の食味食感を向上させるとともに、食品に老化耐性を付与し得るα化澱粉類を提供することである。 An object of the present invention is to provide pregelatinized starches that can improve the taste and texture of foods and impart aging resistance to foods.
 本発明は、穀粉類100質量部及び水500質量部以上を含むスラリーを、該スラリーの品温が90℃以上となる条件で加熱し、該穀粉類に含まれる澱粉をα化するα化工程と、前記α化工程を経た前記スラリーを乾燥して固形物を得る工程とを有し、前記α化工程において、前記スラリーの加熱中に該スラリーを攪拌する、α化穀粉類の製造方法である。 The present invention is an pregelatinization step of heating a slurry containing 100 parts by mass of grains and 500 parts by mass or more of water under a condition that the product temperature of the slurry is 90 ° C. or higher to pregelatinize the starch contained in the grains. A method for producing pregelatinized starch, which comprises a step of drying the slurry that has undergone the pregelatinization step to obtain a solid substance, and in the pregelatinization step, the slurry is stirred while heating the slurry. is there.
 また本発明は、前記の本発明のα化澱粉類の製造方法で製造されたα化穀粉類を用いる、加工食品の製造方法である。 Further, the present invention is a method for producing a processed food using the pregelatinized cereal flour produced by the above-mentioned method for producing pregelatinized starches of the present invention.
 本発明のα化穀粉類の製造方法は、穀粉類を含む水性のスラリーを加熱して該穀粉類に含まれる澱粉をα化(糊化)するα化工程と、該スラリーを乾燥して固形物を得る乾燥工程とを有する。以下、各工程について説明する。 The method for producing pregelatinized cereal flours of the present invention includes an pregelatinization step of heating an aqueous slurry containing cereal flours to pregelatinize (gelatinize) the starch contained in the cereal flours, and drying and solidifying the slurry. It has a drying step to obtain a product. Hereinafter, each step will be described.
[α化工程]
 本発明で用いる穀粉類としては、穀粉及び澱粉並びに穀物全粒粉が挙げられ、α化穀粉類が配合される食品の用途等に応じて、これらの1種を単独で又は2種以上を組み合わせ用いることができる。穀粉、澱粉及び穀物全粒粉の供給源となる穀物は、粳種でもよく、糯種でもよい。
[Pregelatinization process]
Examples of the cereals used in the present invention include cereals and starches and whole grain flours, and one of these may be used alone or in combination of two or more depending on the use of the food containing the pregelatinized cereals. Can be done. The grain that is the source of the flour, starch, and whole grain flour may be a porridge seed or a porridge seed.
 穀粉類として使用可能な穀粉としては、澱粉質を含んでいる穀粉であればよく、例えば、小麦粉、米粉、そば粉、ライ麦粉、大豆粉等が挙げられる。小麦粉としては、例えば、薄力粉、中力粉、強力粉、デュラム小麦粉、デュラムセモリナが挙げられる。穀粉としては、典型的には、小麦粉が用いられる。 The flour that can be used as flour may be any flour containing starch, and examples thereof include wheat flour, rice flour, buckwheat flour, rye flour, and soybean flour. Examples of wheat flour include soft flour, medium-strength flour, strong flour, durum wheat flour, and durum semolina. As the flour, wheat flour is typically used.
 穀粉類として使用可能な澱粉としては、例えば、馬鈴薯澱粉、小麦澱粉、コーンスターチ、ワキシーコーンスターチ、米澱粉、タピオカ澱粉等の未加工澱粉、及びこれら未加工澱粉に油脂加工、エーテル化、エステル化、アセチル化、架橋処理、酸化処理等の処理の1つ以上を施した加工澱粉等が挙げられる。なお、ここでいう「澱粉」(α化工程の原材料として用いる澱粉)は、小麦等の植物から単離された「純粋な澱粉」を意味し、穀粉中に含まれる澱粉とは区別される。 Examples of starch that can be used as cereals include unprocessed starches such as potato starch, wheat starch, cornstarch, waxy cornstarch, rice starch, and tapioca starch, and these unprocessed starches are processed with fats and oils, etherified, esterified, and acetyl. Examples thereof include processed starch that has been subjected to one or more treatments such as conversion, cross-linking treatment, and oxidation treatment. The "starch" (starch used as a raw material for the pregelatinization step) here means "pure starch" isolated from plants such as wheat, and is distinguished from the starch contained in the flour.
 穀粉類として使用可能な穀物全粒粉は、穀物頴果(穀物粒)を構成する主要3成分の全て、すなわち胚乳部、外皮部及び胚部の全てを含有するものである。穀物全粒粉の供給源となる穀物は、食用に供することができれば特に制限されず、例えば、小麦、大麦、えん麦、ライ麦、米等が挙げられる。本発明では、1種類の穀物全粒粉を用いてもよく、複数種の穀物全粒粉を組み合わせ用いてもよい。なお、本明細書では、「穀物全粒粉」という称呼における「穀物」という語を、その供給源となった穀物の名称に代えて用いる場合がある。例えば、小麦の頴果由来の穀物全粒粉は「小麦全粒粉」、大麦の頴果由来の穀物全粒粉は「大麦全粒粉」である。穀物全粒粉としては、典型的には、小麦全粒粉が用いられる。 The whole grain flour that can be used as cereals contains all of the three main components constituting the grain caryopsis (grain grain), that is, the endosperm part, the exodermis part, and the embryo part. The grain that is the source of whole grain flour is not particularly limited as long as it can be used for food, and examples thereof include wheat, barley, barley, rye, and rice. In the present invention, one kind of whole grain grain flour may be used, or a plurality of kinds of whole grain grain flour may be used in combination. In this specification, the word "cereal" in the name "whole grain flour" may be used in place of the name of the grain that is the source of the grain. For example, a whole grain grain derived from wheat caryopsis is "wheat whole grain flour", and a whole grain grain derived from barley caryopsis is "wheat whole grain flour". As the whole grain flour, whole wheat flour is typically used.
 本発明のα化澱粉類の製造方法は、穀粉類に含まれる澱粉のα化処理法として、穀粉類100質量部及び水500質量部以上を含むスラリーを、該スラリーの品温が90℃以上となる条件で加熱する方法を採用した点で特徴付けられる。従来行われている典型的なα化処理では、加水量は、対穀粉類100質量部で500質量部よりもはるかに少量で、100質量部以下とする場合が多く、加熱温度は、被加熱物の品温が90℃未満となるようにする場合が多い。本発明で採用した従来に無い高加水且つ高温の条件で穀粉類をα化処理することで、α化処理によって生じる澱粉の構造変化が、従来のα化処理によるものとは異なるものとなり、従来法では得られない高品質のα化穀粉類が得られる。なお、穀粉類には通常、一定量の水分が内在しているので、スラリー中に存在する水分の総質量は、穀粉類100質量部に対して、加水分の500質量部以上と、該穀粉類100質量部に内在する分(通常15質量部以下程度)との合計となる。 The method for producing pregelatinized starch of the present invention is a method for pregelatinizing starch contained in flours, in which a slurry containing 100 parts by mass of cereals and 500 parts by mass or more of water is prepared and the product temperature of the slurry is 90 ° C. or higher. It is characterized by adopting a method of heating under the above conditions. In a typical pregelatinization treatment performed conventionally, the amount of water added to 100 parts by mass of flour is much smaller than 500 parts by mass, and is often 100 parts by mass or less, and the heating temperature is set to be heated. In many cases, the product temperature of an object is set to less than 90 ° C. By pregelatinizing the flours under the unprecedented high water content and high temperature conditions adopted in the present invention, the structural change of starch caused by the pregelatinization treatment becomes different from that of the conventional pregelatinization treatment. High quality pregelatinized starches that cannot be obtained by law can be obtained. Since a certain amount of water is usually contained in the flour, the total mass of the water present in the slurry is 500 parts by mass or more of the water content with respect to 100 parts by mass of the flour, and the flour. It is the total of the amount contained in 100 parts by mass (usually about 15 parts by mass or less).
 また穀物全粒粉は、栄養成分が豊富、食物繊維含有量が多いといった利点を有する一方で、独特の臭み(フスマ臭)やエグミがあるため、食材として積極的に使用し難いという問題がある。しかし、本発明で採用した前記の高加水且つ高温の条件で穀物全粒粉をα化処理することで、その独特の臭みやエグミが低減され、穀物全粒粉が本来有する栄養価などの利点はそのままに、嗜好性を改善することができる。 In addition, whole grain grains have the advantages of being rich in nutritional components and high in dietary fiber content, but have the problem that they are difficult to actively use as foodstuffs because of their unique odor (bran odor) and acridness. However, by pregelatinizing the whole grain grain under the above-mentioned high water content and high temperature conditions adopted in the present invention, the peculiar odor and acridness are reduced, and the advantages such as the nutritional value inherent in the whole grain grain are maintained. The palatability can be improved.
 α化工程におけるスラリーの品温すなわち加熱温度は、少なくとも90℃以上であり、好ましくは100℃以上、より好ましくは105℃以上、更に好ましくは110~140℃、なお好ましくは115~135℃、よりなお好ましくは120~130℃である。一般に、スラリーの加熱温度が高いほど、澱粉の改質が進行し、本発明の所定の効果が奏されやすくなるが、加熱温度が高すぎると、スラリーを収容する容器内の圧力の管理や必要な蒸気等の熱量が増加するため、生産コストの上昇や生産性の低下に繋がるおそれがある。また、140℃を超える温度で小麦粉を処理すると、小麦粉内在のタンパク質やアミノ酸等がメイラード反応を生じ、変色するおそれがあるので、α化工程におけるスラリーの品温の上限は140℃程度とすることが好ましい。スラリーの品温が100℃超となる条件で加熱することは、例えばスラリーを加圧雰囲気で加熱することで実施できる。 The product temperature, that is, the heating temperature of the slurry in the pregelatinization step is at least 90 ° C. or higher, preferably 100 ° C. or higher, more preferably 105 ° C. or higher, still more preferably 110 to 140 ° C., still more preferably 115 to 135 ° C. It is preferably 120 to 130 ° C. In general, the higher the heating temperature of the slurry, the more the reforming of the starch progresses and the predetermined effect of the present invention is likely to be achieved. However, if the heating temperature is too high, it is necessary to control the pressure in the container containing the slurry. Since the amount of heat such as steam increases, it may lead to an increase in production cost and a decrease in productivity. Further, when wheat flour is processed at a temperature exceeding 140 ° C., proteins and amino acids contained in the wheat flour may cause a Maillard reaction and discolor. Therefore, the upper limit of the product temperature of the slurry in the pregelatinization step should be about 140 ° C. Is preferable. Heating under the condition that the product temperature of the slurry exceeds 100 ° C. can be carried out, for example, by heating the slurry in a pressurized atmosphere.
 また、α化工程において、スラリーの品温90℃以上(好ましくは100℃以上)を維持する時間すなわち加熱時間は、好ましくは1分以上、より好ましくは3分以上である。一方、α化工程における加熱時間の上限は特に制限されないが、生産効率の観点から、好ましくは180分以下、より好ましくは120分以下である。 Further, in the pregelatinization step, the time for maintaining the product temperature of the slurry at 90 ° C. or higher (preferably 100 ° C. or higher), that is, the heating time is preferably 1 minute or longer, more preferably 3 minutes or longer. On the other hand, the upper limit of the heating time in the pregelatinization step is not particularly limited, but from the viewpoint of production efficiency, it is preferably 180 minutes or less, more preferably 120 minutes or less.
 穀粉類として穀物全粒粉を用いる場合は、α化工程におけるスラリーの加熱温度は、前述のとおり少なくとも90℃以上であればよく、好ましくは95℃以上であり、より好ましくは100℃以上の前記範囲である。加熱時間についても前記範囲でよい。α化工程において穀粉全粒粉を斯かる条件で加熱することで、澱粉の改質効果が得られるほか、穀物全粒粉に含まれる外皮部(フスマ)に起因するフスマ臭やエグミを軽減することができる。 When whole grain flour is used as the cereal flour, the heating temperature of the slurry in the pregelatinization step may be at least 90 ° C. or higher, preferably 95 ° C. or higher, and more preferably 100 ° C. or higher as described above. is there. The heating time may also be in the above range. By heating the whole grain flour under such conditions in the pregelatinization step, the effect of modifying the starch can be obtained, and the bran odor and acridness caused by the exodermis (bran) contained in the whole grain flour can be reduced.
 α化工程における被加熱物であるスラリーは、穀粉類100質量部に対して500質量部以上の水を加えることで調製することができる。加水量は、穀粉類100質量部に対して、好ましくは600~2500質量部、より好ましくは700~2000質量部、更に好ましくは800~1500質量部である。加水量が対穀粉類100質量部で500質量部未満では、本発明の所定の効果が十分に奏されない。逆に加水量が多すぎると、次工程のスラリーの乾燥工程で固形物を得るために多くの時間及びエネルギーが必要となり、生産コストの上昇、生産効率の低下を招くおそれがある。 The slurry to be heated in the pregelatinization step can be prepared by adding 500 parts by mass or more of water to 100 parts by mass of flours. The amount of water added is preferably 600 to 2500 parts by mass, more preferably 700 to 2000 parts by mass, and further preferably 800 to 1500 parts by mass with respect to 100 parts by mass of the flour. If the amount of water added is less than 500 parts by mass with 100 parts by mass of the flour, the predetermined effect of the present invention is not sufficiently exhibited. On the contrary, if the amount of water added is too large, a large amount of time and energy are required to obtain a solid substance in the drying step of the slurry in the next step, which may lead to an increase in production cost and a decrease in production efficiency.
 スラリーは、典型的には、穀粉類(穀粉、澱粉、穀物全粒粉)及び溶媒としての水のみを含有するが、必要に応じ、これら以外の成分、例えば、穀粉類を所望の性質に改質し得る穀粉類改質剤を含有してもよい。穀粉類改質剤としては例えば、科学的処理を行う製剤やアミラーゼ、また穀粉に含まれるタンパクを分解するプロテアーゼなどの酵素等が挙げられる。穀粉類改質剤を含有するスラリーにおいては、酵素反応などの、穀粉類改質剤が関わる反応が生じるところ、この反応は、該スラリーをα化工程に供する前に終了していてもよく、あるいはα化工程の実施中に生じていてもよい。 The slurry typically contains only cereals (flour, starch, whole grain flour) and water as a solvent, but other components, such as cereals, are modified to desired properties as needed. The resulting starch modifier may be contained. Examples of the flour modifier include a preparation for scientific treatment, amylase, and an enzyme such as a protease that decomposes a protein contained in the flour. In a slurry containing a flour modifier, a reaction involving the flour modifier such as an enzymatic reaction occurs, and this reaction may be completed before the slurry is subjected to the pregelatinization step. Alternatively, it may occur during the implementation of the pregelatinization step.
 また、穀粉類としては、前処理が施されたものを用いることもできる。つまり、前処理が施された穀粉類に加水してスラリーを調製してもよい。穀粉類の前処理は、例えば、穀粉類に各種の薬剤(酵素、酸又はアルカリ剤、乳化剤、触媒等)を添加することで実施できる。 Further, as the flours, those that have been pretreated can also be used. That is, the slurry may be prepared by adding water to the pretreated flours. The pretreatment of flours can be carried out, for example, by adding various chemicals (enzymes, acids or alkaline agents, emulsifiers, catalysts, etc.) to the flours.
 α化工程において、スラリーの加熱方法(穀粉類のα化処理の方法)は、前記の高加水且つ高温の条件に対応できる方法であればよく、特に制限されない。典型的なスラリーの加熱方法は、容器に穀粉類を含むスラリーを収容し、該容器を加熱する方法である。スラリーの加熱は、バッチ式で行ってもよく、連続式で行ってもよい。スラリーを加熱する際にこれを収容する容器としては、バッチ式を採用する場合には圧力釜、連続式を採用する場合にはスタティックミキサーなどのラインミキサーをそれぞれ例示できる。加熱方法も特に制限されず、例えば、電気式、ガス式、蒸気式が挙げられ、これらの1種を単独で又は2種以上を組み合わせて用いることできる。蒸気式の加熱方法としては、例えば、被処理物(穀粉類)が収容された容器内に飽和蒸気又は過熱蒸気を直接導入する方法が挙げられる。 In the pregelatinization step, the method for heating the slurry (method for pregelatinization of flours) is not particularly limited as long as it can cope with the above-mentioned high water content and high temperature conditions. A typical method for heating a slurry is a method in which a slurry containing flours is placed in a container and the container is heated. The slurry may be heated in a batch system or in a continuous system. Examples of the container for accommodating the slurry when heating it include a pressure cooker when a batch type is adopted and a line mixer such as a static mixer when a continuous type is adopted. The heating method is also not particularly limited, and examples thereof include an electric type, a gas type, and a steam type, and one of these can be used alone or in combination of two or more. Examples of the steam type heating method include a method of directly introducing saturated steam or superheated steam into a container containing an object to be treated (flours).
 α化工程においては、スラリーの加熱中に該スラリーを攪拌することを要する。スラリーを攪拌せず、静置した状態で加熱すると、該スラリーに含有されている穀粉類がダマになってしまい、α化(糊化)が不十分・不均一となる場合がある。加熱中にスラリーを攪拌することで、このような不都合が防止され、澱粉のα化が促進される。スラリーの攪拌方法は、含有されている穀粉類がスラリー全体に分散され得る方法であればよく特に制限されない。典型的には、容器と該容器の内容物を攪拌する攪拌機とを備えた、公知の攪拌機付き容器を用い、常法に従って実施することができる。例えば、スラリーの加熱をバッチ式で行う場合は、攪拌羽根を有する装置を例示でき、連続式で行う場合は、スタティックミキサーを例示できる。また、スラリーの攪拌手段としては、公知の超音波振動発生手段を用いることもできる。この場合、超音波振動発生手段から発生した超音波の振動により、スラリー中に細かい気泡を発生させてスラリーを攪拌する。 In the pregelatinization step, it is necessary to stir the slurry while heating the slurry. If the slurry is heated in a stationary state without stirring, the flours contained in the slurry may become lumpy, and pregelatinization (gelatinization) may be insufficient or non-uniform. By stirring the slurry during heating, such inconvenience is prevented and gelatinization of starch is promoted. The method for stirring the slurry is not particularly limited as long as the contained flours can be dispersed throughout the slurry. Typically, a known stirrer-equipped container equipped with a container and a stirrer to stir the contents of the container can be used and carried out according to a conventional method. For example, when the slurry is heated in a batch manner, an apparatus having a stirring blade can be exemplified, and when the slurry is heated in a continuous manner, a static mixer can be exemplified. Further, as the slurry stirring means, a known ultrasonic vibration generating means can also be used. In this case, the slurry is agitated by generating fine bubbles in the slurry by the vibration of the ultrasonic waves generated from the ultrasonic vibration generating means.
 α化工程において、スラリーの加熱中すなわち穀粉類のα化処理中は、該スラリーに含まれる溶媒(水)の量が変化しないことが好ましい。スラリーの加熱中に溶媒量が大きく減少する(蒸発する)と、α化の促進が抑制されるおそれがあるためである。好ましくは、穀粉類100質量部に対して水500質量部以上を含む状態で、α化処理を完了する。 In the pregelatinization step, it is preferable that the amount of the solvent (water) contained in the slurry does not change during the heating of the slurry, that is, the pregelatinization treatment of the flours. This is because if the amount of solvent is significantly reduced (evaporated) during heating of the slurry, the promotion of pregelatinization may be suppressed. Preferably, the pregelatinization treatment is completed in a state containing 500 parts by mass or more of water with respect to 100 parts by mass of flours.
 スラリーの加熱中にスラリーに含まれる溶媒の量を変化させないようにする方法の一例として、スラリーを加圧雰囲気で加熱する方法が挙げられる。すなわち、1気圧超の雰囲気圧力下においてスラリーを加熱する。この場合、スラリーを収容する容器は、耐圧性を有するものが好ましい。加圧雰囲気の圧力は、スラリーに含まれる溶媒の量や加熱温度(スラリーの品温)に応じて適宜調整すればよく、特に制限されない。加熱に伴うスラリーの上限温度は圧力に依存するため、求める加熱温度に対応した圧力に設定することが好ましい。 As an example of a method of keeping the amount of the solvent contained in the slurry unchanged during heating of the slurry, there is a method of heating the slurry in a pressurized atmosphere. That is, the slurry is heated under an atmospheric pressure of more than 1 atm. In this case, the container for accommodating the slurry is preferably one having pressure resistance. The pressure in the pressurized atmosphere may be appropriately adjusted according to the amount of the solvent contained in the slurry and the heating temperature (product temperature of the slurry), and is not particularly limited. Since the upper limit temperature of the slurry due to heating depends on the pressure, it is preferable to set the pressure corresponding to the desired heating temperature.
[乾燥工程]
 乾燥工程では、前述のα化工程を経たスラリーを乾燥して固形物を得る。この固形物は、本製造方法の製造目的物であるα化穀粉類である。スラリーの乾燥方法は特に制限されず、公知の乾燥方法を利用することができ、例えば、凍結乾燥、スプレードライヤーなどを用いた噴霧乾燥、ドラムドライヤーを用いた加熱乾燥などが挙げられる。スラリーの乾燥の程度は特に制限されないが、典型的には、スラリーを乾燥して得られる固形物の含水量が、一般の穀粉類(α化工程で原材料として用いた穀粉類)の含水量と同程度になるまで乾燥する。一般の穀粉類は通常15質量%程度である。
[Drying process]
In the drying step, the slurry that has undergone the above-mentioned pregelatinization step is dried to obtain a solid substance. This solid matter is pregelatinized cereal flour, which is the production object of this production method. The method for drying the slurry is not particularly limited, and a known drying method can be used, and examples thereof include freeze-drying, spray-drying using a spray dryer, and heat-drying using a drum dryer. The degree of drying of the slurry is not particularly limited, but typically, the water content of the solid obtained by drying the slurry is the water content of general flours (flours used as raw materials in the pregelatinization step). Dry to the same extent. General flours are usually about 15% by mass.
 乾燥工程を経て得られた固形物すなわちα化穀粉類は、必要に応じ、粉砕して粉末にしてもよい。固形物の粉砕は、家庭用粉砕機であればコービーミルやジューサー等、産業用粉砕機であればハンマーミル、ピンミルやジェットミル等を用いて常法に従って行うことができ、所望の粒度になるまで固形物を粉砕すればよい。 The solid matter obtained through the drying step, that is, pregelatinized cereal flour, may be crushed into powder if necessary. The solid matter can be crushed according to a conventional method using a corby mill, a juicer, etc. for a household crusher, or a hammer mill, a pin mill, a jet mill, etc. for an industrial crusher, until the desired particle size is reached. The solid material may be crushed.
 本発明の製造方法によって製造されたα化穀粉類のα化度(糊化度)は、好ましくは90%以上、より好ましくは95%以上であり得る。このような高α化度のα化穀粉類を食品に配合することで、その食品の食味食感が大幅に向上し、更には食品に老化耐性が付与される。本明細書において、α化度とは、BAP法(β-アミラーゼ・プルラナーゼ法)で測定されたα化度をいう。BAP法によるα化度の測定は、既報(家政学雑誌32(9),653-659,1981)に準じて、以下のとおりに実施することができる。 The degree of pregelatinization (gelatinization) of the pregelatinized flour produced by the production method of the present invention can be preferably 90% or more, more preferably 95% or more. By blending the pregelatinized cereal flours having such a high degree of pregelatinization into the food, the taste and texture of the food is significantly improved, and the food is further imparted with aging resistance. In the present specification, the degree of pregelatinization refers to the degree of pregelatinization measured by the BAP method (β-amylase / pullulanase method). The measurement of the degree of pregelatinization by the BAP method can be carried out as follows according to the previous report (Home Economics Magazine 32 (9), 653-659, 1981).
〔β-アミラーゼ・プルラナーゼ法によるα化度の測定法〕
(A)試薬
 使用する試薬は、以下のとおりである。
 1)0.8M酢酸-酢酸Na緩衝液
 2)10N水酸化ナトリウム溶液
 3)2N酢酸溶液
 4)酵素溶液:β-アミラーゼ(ナガセケムテックス(株),#1500S)0.017g及びプルラナーゼ(林原生物化学研究所、No.31001)0.17gを前記0.8M酢酸-酢酸Na緩衝液に溶かして100mLとしたもの。
 5)失活酵素溶液:前記酵素溶液を10分間煮沸させて調製したもの。
 6)ソモギー試薬及びネルソン試薬(還元糖量の測定用試薬)
[Measurement of pregelatinization by β-amylase / pullulanase method]
(A) Reagents The reagents used are as follows.
1) 0.8M acetic acid-Na acetate buffer 2) 10N sodium hydroxide solution 3) 2N acetic acid solution 4) Enzyme solution: β-amylase (Nagasechemtex Co., Ltd., # 1500S) 0.017 g and pluranase (forest protozoa) Chemical Laboratory, No. 31001) 0.17 g was dissolved in the 0.8M acetic acid-Na acetate buffer to make 100 mL.
5) Inactivated enzyme solution: A solution prepared by boiling the enzyme solution for 10 minutes.
6) Somogie reagent and Nelson reagent (reagent for measuring the amount of reducing sugar)
(B)測定方法
 B-1)サンプル穀粉(α化穀粉類)をホモジナイザーで粉砕し、100メッシュ以下とする。この粉砕したサンプル穀粉0.08~0.10gをガラスホモジナイザーに取る。
 B-2)ガラスホモジナイザーの内容物に脱塩水8.0mLを加え、該ガラスホモジナイザーを10~20回上下させて該内容物の分散を行い、分散液を得る。
 B-3)2本の25mL容目盛り付き試験管に前記B-2)の分散液を2mLずつとり、その2本のうちの1本は、0.8M酢酸-酢酸Na緩衝液で定容し、試験区とする。
 B-4)前記2本のうちの他の1本に、10N水酸化ナトリウム溶液0.2mLを添加し、50℃で3~5分間反応させ、前記B-2)の分散液を完全に糊化させる。その後、該他の1本に2N酢酸溶液1.0mLを添加し、pHを6.0付近に調整した後、0.8M酢酸-酢酸Na緩衝液で定容し、糊化区とする。
 B-5)前記B-3)及びB-4)で調製した試験区及び糊化区の試験液をそれぞれ0.4mLとり、それぞれに酵素溶液0.1mLを加えて、40℃で30分間酵素反応させ、反応済液を得る。同時に、ブランクとして、酵素溶液の代わりに失活酵素溶液0.1mLを加えたものも調製する。酵素反応は途中で反応液を時々攪拌させながら行う。
 B-6)前記反応済液及びブランクそれぞれの0.5mLにソモギー試薬0.5mLを添加し、沸騰浴中で15分間煮沸する。煮沸後、流水中で5分間冷却した後、ネルソン試薬1.0mLを添加・攪拌し、15分間放置する。
 B-7)その後、前記反応済液及びブランクそれぞれに脱塩水8.00mLを加えて攪拌し、500nmの吸光度を測定する。
(B) Measurement method B-1) Sample flour (pregelatinized flour) is crushed with a homogenizer to a size of 100 mesh or less. Take 0.08 to 0.10 g of this crushed sample flour into a glass homogenizer.
B-2) 8.0 mL of demineralized water is added to the contents of the glass homogenizer, and the glass homogenizer is moved up and down 10 to 20 times to disperse the contents to obtain a dispersion liquid.
B-3) Take 2 mL each of the dispersion of B-2) in two 25 mL graduated test tubes, and one of the two is filled with 0.8 M acetate-Na acetate buffer. , The test area.
B-4) 0.2 mL of 10N sodium hydroxide solution was added to the other one of the two, and the mixture was reacted at 50 ° C. for 3 to 5 minutes to completely glue the dispersion of B-2). To make it. Then, 1.0 mL of a 2N acetic acid solution is added to the other one, the pH is adjusted to around 6.0, and the volume is adjusted with 0.8 M acetic acid-Na acetate buffer to prepare a gelatinized group.
B-5) Take 0.4 mL each of the test solutions of the test group and gelatinized group prepared in B-3) and B-4), add 0.1 mL of the enzyme solution to each, and use the enzyme at 40 ° C. for 30 minutes. React to obtain a reacted solution. At the same time, as a blank, 0.1 mL of an inactivating enzyme solution is added instead of the enzyme solution. The enzymatic reaction is carried out with occasional stirring of the reaction solution on the way.
B-6) Add 0.5 mL of somogie reagent to 0.5 mL of each of the reacted solution and blank, and boil for 15 minutes in a boiling bath. After boiling, cool in running water for 5 minutes, add 1.0 mL of Nelson reagent, stir, and leave for 15 minutes.
B-7) After that, 8.00 mL of desalted water is added to each of the reacted solution and the blank, and the mixture is stirred and the absorbance at 500 nm is measured.
(C)α化度の算出
 下式によりα化度を算出する。
 α化度(%)={(試験液の分解率)/(完全糊化試験液の分解率)}×100
       ={(A-a)/(A’-a’)}×100
 前記式中、A、A’、a、及びa’は下記のとおりである。
  A =試験区の吸光度
  A’=糊化区の吸光度
  a =試験区のブランクの吸光度
  a’=糊化区のブランクの吸光度
(C) Calculation of the degree of pregelatinization The degree of pregelatinization is calculated by the following formula.
Degree of pregelatinization (%) = {(decomposition rate of test solution) / (decomposition rate of complete gelatinization test solution)} x 100
= {(A-a) / (A'-a')} x 100
In the above formula, A, A', a, and a'are as follows.
A = Absorbance of test group A'= Absorbance of gelatinized group a = Absorbance of blank in test group a'= Absorbance of blank in gelatinized group
 本発明の製造方法によって製造されたα化穀粉類(以下、単に「α化穀粉類」ともいう。)は、公知のα化穀粉やα化澱粉の代わりに使用することができ、典型的には、食品工業分野で使用されるが、食品工業分野以外の分野で使用することもできる。食品工業分野でのα化穀粉類の使用例として、1)熱調理を省く用途(例えばインスタントスープ)の増粘や保型、2)ケーキミックスの生地の改質や冷凍食品の組織の安定化、3)穀粉類としてコーンスターチを用いて製造されたα化穀粉類の場合、スープやらくがん粉の代用、4)穀粉類としてワキシーコーンスターチを用いて製造されたα化穀粉類の場合、豆菓子の衣が挙げられる。また、食品工業分野以外の分野でのα化穀粉類の使用例として、穀粉類として馬鈴薯澱粉を用いて製造されたα化穀粉類の場合、飼料の粘結;鋳物砂型、線香、研磨砥石等の粘結;家庭用洗濯ノリ;紙力増強剤が挙げられる。 The pregelatinized flours produced by the production method of the present invention (hereinafter, also simply referred to as “pregelatinized flours”) can be used in place of known pregelatinized flours and pregelatinized starches, and are typically used. Is used in the food industry, but can also be used in fields other than the food industry. Examples of the use of pregelatinized flours in the food industry are 1) thickening and retaining molds for applications that omit heat cooking (for example, instant soup), 2) modifying the dough of cake mixes and stabilizing the structure of frozen foods. 3) In the case of pregelatinized flour produced using corn flour as flour, substitute for soup or easy cancer flour 4) In the case of pregelatinized flour manufactured using waxy corn flour as flour, bean confectionery Clothes can be mentioned. In addition, as an example of the use of pregelatinized cereal flour in fields other than the food industry field, in the case of pregelatinized cereal flour produced using potato starch as the cereal flour, sticking of feed; casting sand mold, incense, polishing grindstone, etc. Adhesion; household laundry paste; paper strength enhancer.
 α化穀粉類は、加工食品の製造に用いることができる。ここでいう加工食品は、穀粉類を原材料として用いて製造されるものであり、例えば、ベーカリー食品;うどん、そうめん、ひやむぎ、中華麺、パスタ、即席麺(ノンフライ含む)等の麺類;天ぷら、から揚げ、竜田揚げ、フリッター等の揚げ物類、その他の油ちょう食品(油ちょう工程を経て製造される食品);インスタントスープなどの粉末食品が挙げられる。前記麺類には、餃子の皮、焼売の皮、春巻きの皮等の麺皮類が包含される。加工食品は冷凍食品であってもよい。α化穀粉類をこれらの加工食品の製造に用いることで、これらの食品の食味食感を向上させるとともに老化耐性を付与し、即席麺においては更に湯戻り性の向上効果などが奏され得る。加工食品の製造は、当該加工食品の種類に応じて常法に従って行うことができる。 Pregelatinized flours can be used in the production of processed foods. The processed foods referred to here are manufactured using cereal flour as a raw material. For example, bakery foods; noodles such as udon, somen, hiyamugi, Chinese noodles, pasta, instant noodles (including non-fried noodles); tempura, etc. Fried foods such as fried, fried Tatsuta, and fritters, and other oil-boiled foods (foods manufactured through the oil-boiled process); powdered foods such as instant soup. The noodles include noodle skins such as dumpling skin, shumai skin, and spring roll skin. The processed food may be a frozen food. By using pregelatinized cereal flours in the production of these processed foods, the taste and texture of these foods can be improved and aging resistance can be imparted, and instant noodles can further improve the rehydration property. The processed food can be produced according to a conventional method according to the type of the processed food.
 α化穀粉類は、ベーカリー食品の製造に好適である。α化澱粉類をベーカリー食品に配合することで、ベーカリー食品にふんわりとした柔らかさ、しっとり感、もっちり感が付与されるとともに、老化耐性が付与され、食味食感の経時的劣化が抑制される。ベーカリー食品は、穀粉類(穀粉、澱粉、穀物全粒粉等)を必須成分とし、これに必要に応じてイーストや膨張剤(ベーキングパウダー等)、水、食塩、砂糖などの任意成分を加えて得られた発酵又は非発酵生地を、焼成して得られる食品である。ベーカリー食品の具体例として、例えば、パン類;ピザ類;ケーキ類;ワッフル、シュー、ビスケット、焼き饅頭等の和洋焼き菓子;ドーナツ等の揚げ菓子等が挙げられる。パン類としては、食パン(例えばロールパン、白パン、黒パン、フランスパン、乾パン、コッペパン、クロワッサン等)、調理パン、菓子パン等が挙げられる。ケーキ類としては、スポンジケーキ、バターケーキ、ロールケーキ、ホットケーキ、ブッセ、バームクーヘン、パウンドケーキ、チーズケーキ、スナックケーキ、マフィン、バー、クッキー、パンケーキ等が挙げられる。 Pregelatinized flours are suitable for the production of bakery foods. By blending pregelatinized starches in bakery foods, bakery foods are given a fluffy softness, moist feeling, and chewy feeling, and aging resistance is imparted, and deterioration of taste and texture over time is suppressed. To. Bakery foods are obtained by using cereals (grain flour, starch, whole grain flour, etc.) as essential ingredients, and adding optional ingredients such as yeast, leavening agent (baking powder, etc.), water, salt, and sugar as necessary. It is a food obtained by baking a fermented or non-fermented dough. Specific examples of bakery foods include breads; pizzas; cakes; Japanese and Western baked goods such as waffles, shoes, biscuits, and baked buns; and fried sweets such as donuts. Examples of breads include breads (for example, rolls, white breads, black breads, French breads, kanpans, koppe breads, croissants, etc.), cooked breads, sweet breads, and the like. Examples of cakes include sponge cakes, butter cakes, roll cakes, hot cakes, busses, balmkuchens, pound cakes, cheesecakes, snack cakes, muffins, bars, cookies, pancakes and the like.
 以下、実施例により本発明を更に説明するが、本発明は以下の実施例に限定されるものではない。 Hereinafter, the present invention will be further described with reference to Examples, but the present invention is not limited to the following Examples.
〔実施例1~10、比較例1~5〕
 穀粉類として小麦粉を用い、小麦粉に所定量の水を加えて水性のスラリーを調製した。このスラリーを、攪拌機(回転可能に設置されたパドル)付き圧力容器の該圧力容器に入れ、該攪拌機で攪拌しつつ、下記表1に示す加熱方法及び加熱温度で加熱して、穀粉類(小麦粉)に含まれる澱粉をα化(糊化)した(α化工程)。α化工程における加熱時間(下記表1に示す加熱温度を保持した時間)は1分間、3分間又は30分間とした。次に、α化工程を経たスラリー(糊化液)を市販の凍結乾燥機(商品名「ジェネシスSQ」、SPインダストリーズ社製)を用いて凍結乾燥し、固形物を得た。次に、得られた固形物を市販のコーヒーミルを用いて粉砕し、目的のα化小麦粉(α化穀粉類)を得た(実施例1~10、比較例1及び3)。
 また、小麦粉100質量部に30質量部の水を添加し、エクストルーダーにて所定の加熱温度で所定時間加熱した以外は、前記の手順と同様にしてα化小麦粉を得た(比較例2)。
 また、α化工程においてスラリーの加熱中に該スラリーを攪拌せずにα化小麦粉を製造した。具体的には、小麦粉に所定量の水を加えて水性のスラリーを調製し、このスラリーをレトルトパウチ袋に充填、密閉し、オートクレーブを用いて、120℃達温3分で加熱処理した。それ以降は前記の手順と同様にしてα化小麦粉を得た(比較例4及び5)。この方法で行った際、オートクレーブによる加熱後すなわちα化工程を経たスラリーは、離水が生じ、不均一な粘度(部分的にダマ状)となっており、均一に糊化がなされていなかった。また、スラリーがダマ状になっていたことから、凍結乾燥から粉末化するまでの効率も悪かった。
[Examples 1 to 10, Comparative Examples 1 to 5]
Wheat flour was used as the flour, and a predetermined amount of water was added to the flour to prepare an aqueous slurry. This slurry is placed in the pressure vessel of a pressure vessel equipped with a stirrer (rotatably installed paddle), and while stirring with the stirrer, it is heated by the heating method and heating temperature shown in Table 1 below to produce starch (wheat flour). ) Was gelatinized (gelatinized) (gelatinization step). The heating time in the pregelatinization step (the time for maintaining the heating temperature shown in Table 1 below) was 1 minute, 3 minutes, or 30 minutes. Next, the slurry (gelatinized liquid) that had undergone the pregelatinization step was freeze-dried using a commercially available freeze-dryer (trade name "Genesis SQ", manufactured by SP Industries, Ltd.) to obtain a solid substance. Next, the obtained solid matter was pulverized using a commercially available coffee mill to obtain the desired pregelatinized wheat flour (pregelatinized flours) (Examples 1 to 10, Comparative Examples 1 and 3).
Further, pregelatinized wheat flour was obtained in the same manner as in the above procedure except that 30 parts by mass of water was added to 100 parts by mass of wheat flour and heated with an extruder at a predetermined heating temperature for a predetermined time (Comparative Example 2). ..
Further, in the pregelatinization step, pregelatinized wheat flour was produced without stirring the slurry while heating the slurry. Specifically, a predetermined amount of water was added to wheat flour to prepare an aqueous slurry, the slurry was filled in a retort pouch bag, sealed, and heat-treated at 120 ° C. for 3 minutes using an autoclave. After that, pregelatinized wheat flour was obtained in the same manner as described above (Comparative Examples 4 and 5). When this method was used, the slurry after heating by the autoclave, that is, after undergoing the pregelatinization step, had water separation and had a non-uniform viscosity (partially lumpy), and was not uniformly gelatinized. In addition, since the slurry was lumpy, the efficiency from freeze-drying to pulverization was also poor.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
〔実施例11~16、比較例6~8〕
 穀粉類として小麦全粒粉、コーンスターチ又は小麦澱粉を用い、下記表2に示す条件でα化工程を実施した以外は、前記の実施例又は比較例と同様にしてα化小麦全粒粉、α化コーンスターチ又はα化小麦澱粉を得た。
[Examples 11 to 16, Comparative Examples 6 to 8]
Whole wheat flour, cornstarch or wheat starch was used as the grain flour, and the pregelatinized wheat whole grain flour, pregelatinized cornstarch or α was carried out in the same manner as in the above-mentioned Example or Comparative Example except that the pregelatinization step was carried out under the conditions shown in Table 2 below. Chemicalized wheat starch was obtained.
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
〔製造例A1~A22:パンケーキの製造〕
 下記表3に示す配合の焼き菓子用ミックスを用いて、ベーカリー食品の一種であるパンケーキを製造した。具体的には、ミックス100質量部、砂糖25質量部、ベーキングパウダー5質量部、サラダ油10質量部、全卵30質量部、牛乳50質量部及び適量の水を容器に入れ、120回/分の回転数で手動にて混合攪拌をし、品温25℃でのB型粘度計による粘度が5~10Pa・sの範囲にあるパンケーキ生地を調製した。水の配合量は、パンケーキ生地の粘度が斯かる範囲になる範囲に調整した。調製したパンケーキ生地について10分間の寝かし時間を取った後、グリドルのプレート上に該生地を55g流し込み、該プレートの温度180℃で該生地の片面を3分間焼成した後、該生地を上下反転させて反対側の面を2分間焼成し、粗熱をとった後、パンケーキを製造した。
[Manufacturing Examples A1 to A22: Manufacture of pancakes]
Pancakes, which are a type of bakery food, were produced using the baked confectionery mixes shown in Table 3 below. Specifically, 100 parts by mass of the mix, 25 parts by mass of sugar, 5 parts by mass of baking powder, 10 parts by mass of salad oil, 30 parts by mass of whole eggs, 50 parts by mass of milk and an appropriate amount of water are placed in a container and 120 times / minute. The pancake dough was prepared by manually mixing and stirring at the number of rotations to prepare a pancake dough having a viscosity in the range of 5 to 10 Pa · s by a B-type viscosity meter at a product temperature of 25 ° C. The amount of water blended was adjusted so that the viscosity of the pancake dough was within such a range. After allowing 10 minutes to let the prepared pancake dough rest, 55 g of the dough is poured onto a griddle plate, one side of the dough is baked at a temperature of 180 ° C. for 3 minutes, and then the dough is turned upside down. The other side was baked for 2 minutes to remove the rough heat, and then pancakes were produced.
 こうして製造したパンケーキの一部を、常温環境下で30分間放冷した後に、10名の専門パネラーに食してもらい、その際の食感(製造直後の食感)を下記評価基準(5点満点)により評価してもらった。
 また、製造したパンケーキの他の一部を、庫内温度4℃の冷蔵庫に3日間収容して保管し、チルド保存パンケーキを得た。このチルド保存パンケーキを、常温環境下で20分間放置した後、適当な大きさにカットし、10名の専門パネラーに食してもらい、その際の食感(冷蔵保管後の食感)を下記評価基準(5点満点)により評価してもらった。
 また、製造したパンケーキの更に他の一部を、庫内温度-18℃の冷凍庫に2カ月間収容して保管し、冷凍パンケーキを得た。この冷凍パンケーキを、常温環境下で20分間放置した後、適当な大きさにカットし、10名の専門パネラーに食してもらい、その際の食感(冷凍保管後の食感)を下記評価基準(5点満点)により評価してもらった。
 以上の結果(10名の専門パネラーの平均点)を下記表3に示す。
After allowing a part of the pancakes produced in this way to cool for 30 minutes in a room temperature environment, 10 specialized panelists were asked to eat them, and the texture (texture immediately after production) at that time was evaluated according to the following evaluation criteria (5 points). It was evaluated by (perfect score).
Further, another part of the produced pancake was stored in a refrigerator having an internal temperature of 4 ° C. for 3 days to obtain a chilled pancake. After leaving this chilled pancake in a room temperature environment for 20 minutes, cut it to an appropriate size and have 10 specialized panelists eat it, and the texture at that time (texture after refrigerated storage) is as follows. We had them evaluate according to evaluation criteria (out of 5 points).
Further, another part of the produced pancake was stored in a freezer having an internal temperature of −18 ° C. for 2 months to obtain a frozen pancake. After leaving this frozen pancake in a room temperature environment for 20 minutes, it is cut into an appropriate size and eaten by 10 specialized panelists, and the texture at that time (texture after frozen storage) is evaluated as follows. We had them evaluate by criteria (out of 5 points).
The above results (average score of 10 specialized panelists) are shown in Table 3 below.
<パンケーキの食感の評価基準>
 5点:内相はふんわりとして柔らかく、しっとりとした食感を有し、歯切れ、口溶けともに良好。
 4点:内相はふんわりとして柔らかい食感を有し、歯切れ、口溶けはやや良好。
 3点:内相はややふんわりとし、また、ややヒキがあるため、澱粉の老化感を感じ、歯切れ、口溶けにやや物足りなさがあるものの、問題ないレベル。
 2点:内相はふんわり感が弱く、且つヒキとパサつきがあり澱粉の老化感が強いため、歯切れ、口溶けが悪い。
 1点:内部の食感が硬く、且つ強いヒキと強いパサつきがあり澱粉の老化感が非常に強いため、歯切れ、口溶けが非常に悪い。
<Evaluation criteria for pancake texture>
5 points: The internal phase is soft and fluffy, has a moist texture, and has good crispness and melting in the mouth.
4 points: The internal phase has a soft and soft texture, and the crispness and melting in the mouth are slightly good.
3 points: The internal phase is a little fluffy, and because it has a little fluff, it feels like the starch is aging, and although it is a little unsatisfactory in terms of crispness and melting in the mouth, there is no problem.
2 points: The internal phase has a weak fluffy feeling, and has a dry feeling and a strong aging feeling of starch, so that it is not crisp and melts in the mouth.
1 point: The texture inside is hard, and the starch has a strong texture and a strong dryness, and the starch has a very strong aging feeling, so that it is very crisp and melts in the mouth.
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
〔製造例B1~B8:パンの製造〕
 下記表4に示す配合のパン用ミックスを用い、且つ市販のホームベーカリー(商品名「SD-BM103」、パナソニック社製)を用いて、ベーカリー食品の一種であるパンを製造した。具体的には、ミックス100質量部、バター4質量部、砂糖6.8質量部、スキムミルク2.4質量部、食塩2質量部、ドライイースト1.1質量部をホームベーカリーに入れ、該ホームベーカリーが備える「標準コース」を選択してパンを製造した。
[Production Examples B1 to B8: Bread Production]
Bread, which is a kind of bakery food, was produced using a bread mix having the formulations shown in Table 4 below and using a commercially available home bakery (trade name "SD-BM103", manufactured by Panasonic Corporation). Specifically, 100 parts by mass of the mix, 4 parts by mass of butter, 6.8 parts by mass of sugar, 2.4 parts by mass of skim milk, 2 parts by mass of salt, and 1.1 parts by mass of dry yeast are put into a home bakery, and the home bakery is provided. Bread was made by selecting the "standard course".
 こうして製造したパンの一部を、常温環境下で30分間放冷した後に、10名の専門パネラーに食してもらい、その際の触感、食感及び風味(製造直後の触感、食感及び風味)を下記評価基準(5点満点又は3点満点)により評価してもらった。結果(10名の専門パネラーの平均点)を下記表4に示す。 After allowing a part of the bread produced in this way to cool for 30 minutes in a room temperature environment, 10 specialized panelists were asked to eat it, and the texture, texture and flavor at that time (texture, texture and flavor immediately after production). Was evaluated according to the following evaluation criteria (out of 5 points or out of 3 points). The results (average score of 10 specialized panelists) are shown in Table 4 below.
<パンの触感の評価基準>
 5点:内相はふんわりとして柔らかく、しっとりとしている。
 4点:内相はふんわりとして柔らかく、ややしっとりしている。
 3点:内相はややふんわりで、しっとりとしている。
 2点:内相はふんわり感が弱く、パサつく。
 1点:内部の触感が硬く、乾燥している。
<パンの食感の評価基準>
 3点:しっとりとして、もっちりしている。
 2点:ややもっちりしている。
 1点:歯切れがよくて、サクイ。
<パンの風味の評価基準>
 5点:香ばしい穀物の香りを強く感じ、甘みを感じる。
 4点:香ばしい穀物の香りがし、甘みを感じ、エグミがない。
 3点:フスマ臭を感じ、エグミも感じるが、問題ないレベル。 
 2点:フスマ臭がやや強く、エグミを感じる。
 1点:フスマ臭が強く、エグミが強い。
<Evaluation criteria for bread tactile sensation>
5 points: The interior phase is fluffy, soft and moist.
4 points: The interior phase is soft and soft, and slightly moist.
3 points: The interior minister is a little fluffy and moist.
2 points: The interior phase has a weak fluffy feeling and is dry.
1 point: The inside feels hard and dry.
<Evaluation criteria for bread texture>
3 points: Moist and chewy.
2 points: It's a little tight.
1 point: Crisp and crispy.
<Evaluation criteria for bread flavor>
5 points: Strongly feel the fragrant grain scent and sweetness.
4 points: It has a fragrant grain scent, sweetness, and no acridness.
3 points: I feel a smoky smell and an acridness, but there is no problem.
2 points: The smell of fusuma is a little strong, and you can feel the acridness.
1 point: Strong odor of fusuma and strong acridness.
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000004
〔製造例C1~C5:即席麺の製造〕
 下記表5に示す配合の原料粉を用いて、麺類の一種であるノンフライ即席中華麺を製造した。原料粉において、小麦粉として中力粉(日清製粉株式社製「特雀」)を用い、澱粉として酸化タピオカ澱粉(松谷化学工業株式会社製「MKK100」)を用いた。具体的な手順としては、先ず、原料粉100質量部に、食塩1質量部及びかんすい(オリエンタル酵母工業株式会社製「赤かんすい」)0.4質量部を溶解した水を適量添加し、製麺用ミキサーで常法により10分間混捏して麺生地を調製した。次に、麺生地を製麺ロールにより圧延して厚さ1.2mmの麺帯とし、更に、切刃(#18番角)により麺線に切り出した。次に、麺線を温度100℃の蒸気で2分30秒間蒸熱処理した後、90℃の熱風で20分間乾燥して、ノンフライ即席中華麺を製造した。
[Manufacturing Examples C1 to C5: Manufacture of instant noodles]
Non-fried instant Chinese noodles, which are a kind of noodles, were produced using the raw material powders having the formulations shown in Table 5 below. As the raw material flour, medium-strength flour (“Tokujaku” manufactured by Nisshin Flour Milling Co., Ltd.) was used as wheat flour, and oxidized tapioca starch (“MKK100” manufactured by Matsutani Chemical Industry Co., Ltd.) was used as starch. As a specific procedure, first, an appropriate amount of water in which 1 part by mass of salt and 0.4 parts by mass of Kansui (“Akakansui” manufactured by Oriental Yeast Industry Co., Ltd.) is dissolved in 100 parts by mass of raw material flour is added to make noodles. The noodle dough was prepared by kneading with a mixer for 10 minutes by a conventional method. Next, the noodle dough was rolled with a noodle-making roll to form a noodle band having a thickness of 1.2 mm, and further cut into noodle strings with a cutting blade (# 18 angle). Next, the noodle strings were steam-heat-treated with steam at a temperature of 100 ° C. for 2 minutes and 30 seconds, and then dried with hot air at 90 ° C. for 20 minutes to produce non-fried instant Chinese noodles.
 こうして製造した即席麺70gを容器に収納し、該容器に沸騰水を450ml加えて、該容器に蓋をして4分間静置した後、容器内の湯を除いて10名の専門パネラーに食してもらい、湯戻しの際の復元性、食感(粘弾性)を下記評価基準により評価してもらった。結果(10名の専門パネラーの平均点)を下記表5に示す。 70 g of instant noodles produced in this way is stored in a container, 450 ml of boiling water is added to the container, the container is covered and allowed to stand for 4 minutes, and then the hot water in the container is removed and eaten by 10 specialized panelists. We asked them to evaluate the resilience and texture (viscoelasticity) when reconstituted in hot water according to the following evaluation criteria. The results (average score of 10 specialized panelists) are shown in Table 5 below.
<即席麺の復元性の評価基準>
 5点:十分可食状態であり、良好。
 4点:ほぼ可食状態であり、やや良好。
 3点:大部分は可食状態であるが、一部に芯が残る。
 2点:麺線表面は可食状態であるが、麺線の中心部には芯が残り、やや不良。
 1点:麺線表面及び中心部が硬く、不良。
<即席麺の食感の評価基準>
 5点:粘りと弾力のバランスが非常によく、極めて良好。
 4点:粘りと弾力のバランスが良く、良好。
 3点:粘りと弾力のバランスがやや良く、やや良好。
 2点:粘りと弾力のバランスがやや悪く、やや不良。
 1点:粘りと弾力のバランスが悪く、不良。
<Evaluation criteria for resilience of instant noodles>
5 points: Sufficiently edible and good.
4 points: Almost edible and slightly good.
3 points: Most are edible, but some cores remain.
2 points: The surface of the noodle string is edible, but the core remains in the center of the noodle string, which is a little defective.
1 point: The surface and center of the noodle string are hard and defective.
<Evaluation criteria for texture of instant noodles>
5 points: Very good balance of stickiness and elasticity.
4 points: Good balance between stickiness and elasticity.
3 points: The balance between stickiness and elasticity is a little good, and a little good.
2 points: The balance between stickiness and elasticity is a little bad, and it is a little bad.
1 point: Poor balance between stickiness and elasticity.
Figure JPOXMLDOC01-appb-T000005
Figure JPOXMLDOC01-appb-T000005
〔製造例D1~D7:冷蔵茹でうどんの製造〕
 下記表6に示す配合の原料粉を用いて、麺類(調理済み冷蔵麺類)の一種である冷蔵茹でうどんを製造した。原料粉において、小麦粉として中力粉(日清製粉株式社製「薫風」)を用い、澱粉としてアセチル化タピオカ澱粉(松谷化学工業株式会社製「あじさい」)を用い、小麦蛋白としてグリコ栄養食品株式会社製「A グルG」を用いた。具体的な手順としては、先ず、原料粉100質量部に、食塩3質量部を溶解した水を適量添加し、-90kPaの減圧下で混捏し麺生地を調製した。次に、麺生地を圧延し、切刃(#10番角)により厚み3mmの麺線に切り出した。次に、麺線を沸騰したお湯で茹でた後、水洗冷却し、冷却した麺線100質量部に、ほぐれ剤(不二製油株式会社製「ソヤアップM3000」)3質量部をスプレーにより均一に付着させて茹でうどんを得た。この茹でうどんを庫内温度5℃の冷蔵庫に24時間保管して、冷蔵茹でうどんを製造した。
[Manufacturing Examples D1 to D7: Production of Refrigerated Boiled Udon]
Refrigerated boiled udon noodles, which are a type of noodles (cooked refrigerated noodles), were produced using the raw material powders having the formulations shown in Table 6 below. In the raw material flour, medium-strength flour (“Kaoru” manufactured by Nisshin Flour Milling Co., Ltd.) is used as wheat flour, acetylated tapioca starch (“hydrangea” manufactured by Matsutani Chemical Industry Co., Ltd.) is used as starch, and Glico Foods Co., Ltd. is used as wheat protein. The company-made "A Guru G" was used. As a specific procedure, first, an appropriate amount of water in which 3 parts by mass of salt was dissolved was added to 100 parts by mass of the raw material flour, and the noodle dough was kneaded under a reduced pressure of −90 kPa to prepare a noodle dough. Next, the noodle dough was rolled and cut into a noodle wire having a thickness of 3 mm with a cutting blade (# 10 angle). Next, the noodle strings are boiled in boiling water, washed with water and cooled, and 3 parts by mass of a loosening agent (“Soyaup M3000” manufactured by Fuji Oil Co., Ltd.) is uniformly adhered to 100 parts by mass of the cooled noodle strings by spraying. I got boiled udon noodles. This boiled udon was stored in a refrigerator having an internal temperature of 5 ° C. for 24 hours to produce refrigerated boiled udon.
 こうして製造した冷蔵茹でうどんを10名の専門パネラーに冷蔵状態のまま食してもらい、食感(粘弾性)を下記評価基準(5点満点)により評価してもらった。結果(10名の専門パネラーの平均点)を下記表6に示す。 The refrigerated boiled udon noodles produced in this way were eaten by 10 specialized panelists in a refrigerated state, and the texture (viscoelasticity) was evaluated according to the following evaluation criteria (out of 5 points). The results (average score of 10 specialized panelists) are shown in Table 6 below.
<冷蔵茹でうどんの食感の評価基準>
 5点:粘りと弾力のバランスが非常によく、極めて良好。
 4点:粘りと弾力のバランスが良く、良好。
 3点:粘りと弾力のバランスがやや良く、やや良好。
 2点:粘りと弾力のバランスがやや悪く、やや不良。
 1点:粘りと弾力のバランスが悪く、不良。
<Evaluation criteria for the texture of refrigerated boiled udon noodles>
5 points: Very good balance of stickiness and elasticity.
4 points: Good balance between stickiness and elasticity.
3 points: The balance between stickiness and elasticity is a little good, and a little good.
2 points: The balance between stickiness and elasticity is a little bad, and it is a little bad.
1 point: Poor balance between stickiness and elasticity.
Figure JPOXMLDOC01-appb-T000006
Figure JPOXMLDOC01-appb-T000006
〔製造例E1~E5:冷蔵焼き餃子の製造〕
 下記表7に示す配合の原料粉を用いて、麺類(麺皮類)の一種である餃子皮を製造し、更に、製造した餃子皮を用いて調理済み冷蔵餃子の一種である冷蔵焼き餃子を製造した。具体的な手順としては、先ず、原料粉100質量部に、食塩1質量部及び水を適量添加して10分間混捏した後、30分間熟成させて生地を調製した。次に、生地を常法により圧延し最終麺帯厚を1mmとした後、直径85mmの型で切り抜き、生餃子皮を製造した。次に、生餃子皮に餃子の具を12g包餡して生餃子を製造し、この生餃子を焼成調理した後、庫内温度4℃の冷蔵庫に3日間保管して、冷蔵焼き餃子を製造した。
[Manufacturing Examples E1 to E5: Production of refrigerated roasted dumplings]
Gyoza rind, which is a type of noodles (noodle skins), is produced using the raw material powders of the formulations shown in Table 7 below, and chilled gyoza, which is a type of cooked chilled dumplings, is further produced using the produced gyoza rind. Manufactured. As a specific procedure, first, 1 part by mass of salt and an appropriate amount of water were added to 100 parts by mass of the raw material flour, kneaded for 10 minutes, and then aged for 30 minutes to prepare a dough. Next, the dough was rolled by a conventional method to make the final noodle band thickness 1 mm, and then cut out with a mold having a diameter of 85 mm to produce raw dumpling skin. Next, 12 g of dumpling ingredients are wrapped in raw dumpling skin to produce raw dumplings, and after the raw dumplings are baked and cooked, they are stored in a refrigerator with an internal temperature of 4 ° C for 3 days to produce refrigerated grilled dumplings. did.
 こうして製造した冷蔵焼き餃子を耐熱性容器に5個入れて電子レンジにて加熱(500W/1分30秒)した後に、10名の専門パネラーに食してもらい、食感を下記評価基準(5点満点)により評価してもらった。結果(10名の専門パネラーの平均点)を下記表7に示す。 After putting 5 pieces of refrigerated roasted dumplings produced in this way in a heat-resistant container and heating them in a microwave oven (500 W / 1 minute 30 seconds), 10 specialized panelists were asked to eat them, and the texture was evaluated according to the following evaluation criteria (5 points). It was evaluated by (perfect score). The results (average score of 10 specialized panelists) are shown in Table 7 below.
<焼き餃子の食感の評価基準>
 5点:口溶けが非常によく、硬さが全く無く、良好。
 4点:口溶けがよく、硬さが無く、やや良好。
 3点:口溶け、硬さともに普通。
 2点:口溶けが悪く、硬さがあり、やや不良。
 1点:口溶けが非常に悪く、硬い食感であり、不良。
<Evaluation criteria for the texture of roasted dumplings>
5 points: Very good melting in the mouth, no hardness at all, good.
4 points: Good melting in the mouth, no hardness, slightly good.
3 points: Melting in the mouth and hardness are normal.
2 points: Poor melting in the mouth, hardness, and slightly poor.
1 point: Very poor melting in the mouth, hard texture, and poor.
Figure JPOXMLDOC01-appb-T000007
Figure JPOXMLDOC01-appb-T000007
〔製造例F1~F5:えび天ぷらの製造〕
 下記表7に示す配合の天ぷら衣用ミックスを用いて、油ちょう食品の一種であるえび天ぷらを製造した。天ぷら衣用ミックスにおいて、小麦粉として薄力粉(日清製粉株式社製「フラワー」)を用い、澱粉として小麦澱粉(グリコ栄養食品株式会社製「食品用加工澱粉 銀鱗」)を用いた。具体的な手順としては、先ず、天ぷら衣用ミックス100質量部に水を適量添加して衣液を調製した。次に、衣液に具材としての尾付きえび(20g/頭)を入れてよく絡めた後、衣液が付着したえびを、170℃に熱したサラダ油の入った油槽で2分30秒間油ちょうし、えび天ぷらを製造した。
[Manufacturing example F1 to F5: Production of shrimp tempura]
Shrimp tempura, which is a kind of oily food, was produced by using the tempura batter mix having the composition shown in Table 7 below. In the tempura batter mix, soft flour (“Flower” manufactured by Nisshin Flour Milling Co., Ltd.) was used as the wheat flour, and wheat starch (“Processed starch for food silver scale” manufactured by Glico Foods Co., Ltd.) was used as the starch. As a specific procedure, first, an appropriate amount of water was added to 100 parts by mass of the tempura batter mix to prepare a batter solution. Next, put the tailed shrimp (20 g / head) as an ingredient in the batter and entangle it well, and then oil the shrimp with the batter in an oil tank containing salad oil heated to 170 ° C for 2 minutes and 30 seconds. Manufactured shrimp tempura.
 こうして製造したえび天ぷらを、油槽から取り出して油切りした後に室温(約25℃)にて60分間放置した後、10名の専門パネラーに食してもらい、食感を下記評価基準(5点満点)により評価してもらった。結果(10名の専門パネラーの平均点)を下記表8に示す。 The shrimp tempura produced in this way was taken out of the oil tank, drained, left at room temperature (about 25 ° C) for 60 minutes, and then eaten by 10 specialized panelists, and the texture was evaluated according to the following evaluation criteria (out of 5 points). Was evaluated by. The results (average score of 10 specialized panelists) are shown in Table 8 below.
<えび天ぷらの食感の評価基準>
 5点:衣がサクサクとして歯脆さに富み、極めて良好。
 4点:衣がサクサクとしており、良好。
 3点:衣がややサクサク感に欠けるが、やや良好。
 2点:衣がやや硬いかベタついており、サクサク感に乏しい。
 1点:衣がやや硬すぎるかベタつきが強く、サクサク感がなく、不良。
<Evaluation criteria for texture of shrimp tempura>
5 points: The batter is crispy and has a lot of brittle teeth, which is extremely good.
4 points: The batter is crispy and good.
3 points: The batter lacks a crispy texture, but is slightly good.
2 points: The batter is a little hard or sticky, and it lacks a crisp feeling.
1 point: The batter is a little too hard or sticky, there is no crispness, and it is defective.
Figure JPOXMLDOC01-appb-T000008
Figure JPOXMLDOC01-appb-T000008
 本発明によれば、食品の食味食感を向上させるとともに、食品に老化耐性を付与し得るα化澱粉類が提供される。
 また、穀粉類として穀物全粒粉を用いた場合には、穀物全粒粉に特有の臭みやエグミが低減され、且つ食品の食味食感を向上させるとともに、食品に老化耐性を付与し得るα化澱粉類(α化全粒粉)が提供される。
 本発明によって製造されたα化澱粉類をベーカリー食品に配合した場合には、ベーカリー食品にふんわりとした柔らかさ、しっとり感、もっちり感が付与されるとともに、老化耐性が付与され、食味食感の経時的劣化が抑制される。本発明によって製造されたα化澱粉類を麺類又は油ちょう食品に配合した場合にも同様の効果が奏され、即席麺に配合した場合には更に、湯戻しの際の復元性が向上し得る。
According to the present invention, pregelatinized starches that can improve the taste and texture of foods and impart aging resistance to foods are provided.
In addition, when whole grain grains are used as the grain flours, pregelatinized starches (pregelatinized starches) that can reduce the odor and acridness peculiar to whole grain grains, improve the taste and texture of foods, and impart aging resistance to foods. Pregelatinized whole grain flour) is provided.
When the pregelatinized starch produced by the present invention is blended in a bakery food, the bakery food is given a fluffy softness, a moist feeling, and a chewy feeling, and is also imparted with aging resistance and has a taste and texture. Deterioration over time is suppressed. The same effect can be obtained when the pregelatinized starch produced by the present invention is blended in noodles or oily foods, and when it is blended in instant noodles, the resilience at the time of reconstitution with hot water can be further improved. ..

Claims (10)

  1.  穀粉類100質量部及び水500質量部以上を含むスラリーを、該スラリーの品温が90℃以上となる条件で加熱し、該穀粉類に含まれる澱粉をα化するα化工程と、
     前記α化工程を経た前記スラリーを乾燥して固形物を得る工程とを有し、
     前記α化工程において、前記スラリーの加熱中に該スラリーを攪拌する、α化穀粉類の製造方法。
    A pregelatinization step of heating a slurry containing 100 parts by mass of flour and 500 parts by mass or more of water under a condition that the product temperature of the slurry is 90 ° C. or higher to pregelatinize the starch contained in the flour.
    It has a step of drying the slurry that has undergone the pregelatinization step to obtain a solid substance.
    A method for producing pregelatinized flour, in which the slurry is agitated while the slurry is being heated in the pregelatinization step.
  2.  前記α化工程において、前記スラリーをその品温が100℃以上となる条件で加熱する、請求項1に記載のα化穀粉類の製造方法。 The method for producing pregelatinized flours according to claim 1, wherein in the pregelatinization step, the slurry is heated under conditions where the product temperature is 100 ° C. or higher.
  3.  前記α化工程において、前記スラリーをその品温が110~140℃となる条件で加熱する、請求項1又は2に記載のα化穀粉類の製造方法。 The method for producing pregelatinized flours according to claim 1 or 2, wherein in the pregelatinization step, the slurry is heated under conditions where the product temperature is 110 to 140 ° C.
  4.  前記穀粉類として小麦粉を用いる、請求項1~3の何れか1項に記載のα化穀粉類の製造方法。 The method for producing pregelatinized flour according to any one of claims 1 to 3, wherein wheat flour is used as the flour.
  5.  前記穀粉類として穀物全粒粉を用いる、請求項1~3の何れか1項に記載のα化穀粉類の製造方法。 The method for producing pregelatinized cereals according to any one of claims 1 to 3, wherein whole grain flour is used as the cereal flour.
  6.  前記α化工程において、前記スラリーの加熱中に該スラリーに含まれる溶媒の量が変化しないようにする、請求項1~5の何れか1項に記載のα化穀粉類の製造方法。 The method for producing pregelatinized flour according to any one of claims 1 to 5, wherein in the pregelatinization step, the amount of the solvent contained in the slurry does not change during heating of the slurry.
  7.  前記α化工程において、前記スラリーを加圧雰囲気で加熱する、請求項6に記載のα化穀粉類の製造方法。 The method for producing pregelatinized flours according to claim 6, wherein in the pregelatinization step, the slurry is heated in a pressurized atmosphere.
  8.  製造されたα化穀粉類のα化度が90%以上である、請求項1~7の何れか1項に記載のα化穀粉類の製造方法。 The method for producing pregelatinized flour according to any one of claims 1 to 7, wherein the degree of pregelatinization of the produced pregelatinized flour is 90% or more.
  9.  請求項1~8の何れか1項に記載の製造方法で製造されたα化穀粉類を用いる、加工食品の製造方法。 A method for producing a processed food using pregelatinized cereal flour produced by the production method according to any one of claims 1 to 8.
  10.  前記加工食品がベーカリー食品、麺類又は油ちょう食品である、請求項9に記載の加工食品の製造方法。 The method for producing a processed food according to claim 9, wherein the processed food is a bakery food, noodles or oily food.
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