WO2021082847A1 - Evaporation apparatus of vacuum film-plating machine - Google Patents

Evaporation apparatus of vacuum film-plating machine Download PDF

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Publication number
WO2021082847A1
WO2021082847A1 PCT/CN2020/118421 CN2020118421W WO2021082847A1 WO 2021082847 A1 WO2021082847 A1 WO 2021082847A1 CN 2020118421 W CN2020118421 W CN 2020118421W WO 2021082847 A1 WO2021082847 A1 WO 2021082847A1
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WIPO (PCT)
Prior art keywords
evaporation
boat
crucible
air
pipe
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PCT/CN2020/118421
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French (fr)
Chinese (zh)
Inventor
刘坤
关天恩
阮智伟
胡强
巴德纯
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东北大学
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Publication of WO2021082847A1 publication Critical patent/WO2021082847A1/en

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/228Gas flow assisted PVD deposition
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/24Vacuum evaporation
    • C23C14/26Vacuum evaporation by resistance or inductive heating of the source
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/56Apparatus specially adapted for continuous coating; Arrangements for maintaining the vacuum, e.g. vacuum locks

Definitions

  • This application relates to the technical field of vacuum coating, and mainly relates to an evaporation device of a vacuum evaporation coating machine.
  • Vacuum evaporation is the most common and widely used vacuum coating process.
  • the physical process of vacuum evaporation includes: evaporation or sublimation of the deposition material into gaseous particles ⁇ rapid transport of gaseous particles from the evaporation source to the surface of the substrate ⁇ adhesion of gaseous particles to the substrate The surface nucleates and grows into a solid film ⁇ the film atoms are reconstructed or chemically bonded.
  • the substrate into a vacuum chamber, heat the film material by resistance, electron beam, laser, etc., to evaporate or sublimate the film material, and vaporize into particles (atoms, molecules or groups of atoms) with a certain energy (0.1 ⁇ 0.3eV).
  • the gaseous particles are rapidly transported to the substrate in a substantially collision-free linear motion. Part of the particles that reach the surface of the substrate is reflected, and the other part is adsorbed on the substrate and diffused on the surface. A two-dimensional collision occurs between the deposited atoms to form clusters. It may evaporate after a short stay on the surface.
  • the particle clusters continuously collide with diffused particles, or adsorb single particles, or release single particles. This process is repeated. When the number of aggregated particles exceeds a certain critical value, it becomes a stable nucleus, and then continues to adsorb and diffuse particles to gradually grow up, and finally through the contact and merging of adjacent stable nuclei, a continuous film is formed.
  • One of the technical problems solved by the present application is an evaporation device used in a large-area high-speed winding coating process to reduce the sputtering phenomenon generated during the evaporation process.
  • an evaporation device for a vacuum coating machine comprising: an evaporation boat, the evaporation boat includes an evaporation boat inner layer, an evaporation boat outer layer and a movable cover, the evaporation boat inner layer is located in the evaporation boat Between the outer layer of the boat and the movable cover plate, the movable cover plate is provided with a plurality of evaporation holes, and the inner layer of the evaporation boat is provided with evaporation grooves corresponding to the evaporation holes. Arranged in a honeycomb pattern;
  • the heating system includes a plurality of relatively independent evaporation sources, the evaporation source is provided with an inner crucible, the inner crucible is nested in the evaporation groove, and the evaporation source can be placed in the inner crucible.
  • the objects in the crucible are heated;
  • An air distribution pipe is arranged at the upper end of the evaporation boat, the air distribution pipe is provided with an air inlet and a plurality of air outlets, the air inlet is connected to an external gas source, and the air outlet faces the Evaporation source.
  • the evaporation source adopts high-frequency induction heating
  • the evaporation source includes several induction coils, a heat insulation layer, and an outer crucible
  • the inner crucible is stacked in the outer crucible
  • the heat insulation layer is arranged in Between the side wall of the inner crucible and the side wall of the outer crucible, the induction coil is arranged between the side wall of the outer crucible and the inner layer of the evaporation boat.
  • the evaporation source further includes a gap adjustment gasket, and the gap adjustment gasket is located between the inner crucible and the thermal insulation layer.
  • the evaporation source is further provided with an electrode block, the electrode block is connected to an external AC power source, a plurality of the induction coils are connected in series to form a group of induction coil groups, and the plurality of groups of the induction coil groups are connected in parallel with each other.
  • the coil assembly is connected to the electrode block, and the induction coil is inside a hollow pipe, and the hollow pipe can circulate a coolant to cool the induction coil.
  • the inner layer of the evaporation boat is heated by resistance
  • the evaporation source is further provided with a pair of electrode blocks
  • the evaporation boat is located between the pair of electrode blocks and the end of the inner layer of the evaporation boat The part is connected with the electrode block, and the inner crucible and the inner layer of the evaporation boat are in contact with each other.
  • the outer layer of the evaporation boat is provided with a groove, and the movable cover plate can be clamped in the groove.
  • the air distribution pipe includes an air inlet pipe, a multi-stage shunt pipe, and an exhaust pipe that are connected in sequence, the exhaust pipe is parallel to the edge of the evaporation boat, and the air inlet is located at the On the intake pipeline, the air outlet is located on the exhaust pipeline.
  • the horizontal plane on which the axis of the exhaust pipe is located and the axis of the air outlet form an included angle of 10°-70°, and the distance between adjacent air outlets is equal.
  • the exhaust pipe includes a plurality of relatively independent exhaust branch pipes, each of the exhaust branch pipes can communicate with the corresponding branch pipeline, and the exhaust branch pipes are each provided with a plurality of the exhaust branch pipes.
  • the cross section of the inner crucible gradually expands from the bottom to the opening.
  • the beneficial effect of the application is that the application adopts the evaporation source of honeycomb structure, and the cross section of the crucible in each evaporation source gradually expands from the bottom to the opening, which increases the emission angle and mixing range of the evaporation gas, and can ensure the large-area heating of the material Uniformity during evaporation.
  • air distribution pipelines are installed on both sides. Each outlet on the air distribution pipeline can evenly and stably pass in the same flow of gas, ensuring the uniformity and adequacy of gas mixing during the chemical reaction.
  • the temperature of the material above the inner crucible is slightly lower than that of the material below the inner crucible, so it can avoid the excessive heating of the material surface and reduce the occurrence of sputtering. Suitable for large-area high-speed winding coating process
  • FIG. 1 is a schematic structural diagram of an evaporation device of a vacuum coating machine according to an embodiment of the application
  • FIG. 2 is a schematic diagram of a cross-sectional structure of an evaporation device of a vacuum coating machine using a high-frequency induction evaporation source according to an embodiment of the application;
  • FIG. 3 is a schematic cross-sectional structure diagram of another evaporation device of a vacuum coating machine using a resistance heating evaporation source provided by an embodiment of the application
  • Fig. 4 is a schematic structural diagram of an air distribution pipeline of an evaporation device of a vacuum coating machine according to an embodiment of the application.
  • FIG. 5 is a schematic diagram of a specific design case size of an exhaust pipe of an evaporation device of a vacuum coating machine according to an embodiment of the application.
  • the terms “connected”, “fixed”, etc. should be understood in a broad sense.
  • “fixed” can be a fixed connection, a detachable connection, or a whole; It can be a mechanical connection or an electrical connection; it can be a direct connection or an indirect connection through an intermediate medium, and it can be an internal communication between two components or an interaction relationship between two components, unless specifically defined otherwise.
  • “fixed” can be a fixed connection, a detachable connection, or a whole; It can be a mechanical connection or an electrical connection; it can be a direct connection or an indirect connection through an intermediate medium, and it can be an internal communication between two components or an interaction relationship between two components, unless specifically defined otherwise.
  • the present application provides an evaporation device of a vacuum coating machine, which includes: an evaporation boat 10 body, a heating system for heating a target material, and a gas distribution pipe 30 connected with an external gas source for supplying gas.
  • the evaporation boat 10 includes an evaporation boat inner layer 11, an evaporation boat outer layer 12 and a movable cover 13.
  • the evaporation boat 10 is elongated as a whole, and the inside of the evaporation boat 10 is provided with grooves.
  • the boat inner layer 11 and the movable cover plate 13 are located in the groove, the evaporation boat inner layer 11 is located between the evaporation boat outer layer 12 and the movable cover plate 13, and the movable cover plate 13 is provided with a plurality of evaporation holes (not marked).
  • the inner layer 11 is provided with evaporation grooves (not marked) corresponding to the evaporation holes.
  • the outer layer of the evaporation boat 12 is mainly used for isolation, protection and fixation.
  • the outer layer 12 of the boat is coated with an insulating and heat-insulating coating to improve the safety of the structure;
  • the heating system includes a plurality of relatively independent evaporation sources 20.
  • the evaporation source 20 is provided with an inner crucible 21, the inner crucible 21 is nested in the evaporation groove, and the evaporation source 20 can be placed opposite to the inner crucible 21 The objects inside are heated;
  • the air distribution pipe 30 is arranged at the upper end of the evaporation boat 10, the air distribution pipe 30 is provided with an air inlet 31 and a plurality of air outlets 32, the air inlet 31 is connected to an external air source, and the air outlet 32 faces the evaporation source 20;
  • the evaporation source 20 is honeycomb, which can make the gas evaporated after heating the material in a large area very uniform;
  • the gas distribution pipe 30 is arranged above the evaporation boat 10, and the gas outlet 32 is directed to the evaporation source 20, which can combine the external air with the gas generated by the evaporation source 20 to evaporate the material to achieve a composite film coating.
  • the arrangement of the evaporation sources 20 in the evaporation boat 10 is at least 3 rows, and the length and number of the arrangement and the radius of the evaporation holes can be changed according to the specific plating requirements. In order to meet the needs of coating a larger area.
  • the evaporation source 20 of the present application adopts high-frequency induction heating.
  • This heating method is suitable for heating metal materials, and eddy currents are generated inside the metal materials in the inner crucible 21 by passing high-frequency alternating current.
  • a strong magnetic flux with an instantaneous change in polarity is generated in the induction coil 22, and the metal to be heat-treated is placed in the high-frequency coil, and the magnetic flux will penetrate the entire heated metal material.
  • the inside of the induction heating object is in the opposite direction to the induction heating current, and a corresponding strong eddy current is generated.
  • the evaporation source 20 includes several induction coils 22, a heat insulation layer 23, and an outer crucible 24.
  • the inner crucible 21 is stacked in the outer crucible 24, and the heat insulation layer 23 is set on the inner crucible 21.
  • the inner crucible 21 is made of high-temperature resistant graphite
  • the heat insulation layer 23 is made of carbon felt with good heat insulation performance
  • the induction coil 22 is made of copper with good conductivity.
  • the coil diameter is 1.5 cm, and the coil turns The number is 5 turns.
  • the inner crucible 21 of the evaporation source 20 has an inverted trapezoidal shape with a top circle diameter of 6 cm.
  • the outer crucible 24 is cylindrical.
  • the gap between the outer crucible 24 and the inner crucible 21 is filled with a heat-insulating material to form a heat-insulating layer 23 ,
  • Above the coil is the movable cover plate 13.
  • the movable cover plate 13 is opened.
  • the inner layer 11 of the evaporation boat is made of composite ceramics with good thermal and insulating properties to reduce the interference between the induction coils 22.
  • the evaporation source 20 also includes a gap adjustment gasket 25, which is located between the inner crucible 21 and the outer crucible 24.
  • the gap adjustment gasket 25 uses a high temperature resistant asbestos gasket, and the outer crucible
  • the material of 24 is alumina and other oxides.
  • the gap adjustment gasket 25 is a thin metal sheet with a thickness. The height of the inner crucible is adjusted by stacking, reducing the evaporation difference, ensuring the uniformity of the evaporation of each evaporation source, and further When the evaporation source 20 is installed, there is often a gap between the inner crucible 21 and the outer crucible 24.
  • the gap adjustment gasket 25 can effectively eliminate the gap and prevent accidents during heating.
  • the gap adjustment gasket 25 can also provide a good support to the inner crucible 21 to prevent the inner crucible 21 from tilting.
  • the evaporation source 20 is also provided with electrode blocks 26, the electrode blocks 26 are connected to an external AC power source, the electrode blocks 26 are a pair, respectively located at the two ends of the evaporation boat 10, for sealing the outer layer of the evaporation boat 12.
  • the evaporation source 20 provides a plurality of induction coils 22 in series to form a group of induction coils 22, and the groups of induction coils 22 are connected in parallel.
  • the inductive coils are connected in series according to eight adjacent groups to form an induction coil 22 group.
  • Each group of induction coils 22 are connected in parallel for heating, so the temperature of each part of the evaporation boat can be adjusted accurately according to the way that eight adjacent evaporation sources 20 are a group, and each evaporation source 20 is not installed.
  • the crucible can be selectively heated to improve the heating efficiency and the flexibility of the coating length design, so as to realize the full and efficient use of heat and energy.
  • the induction coil 22 group is connected with the electrode block 26 to facilitate current
  • the inside of the induction coil 22 is a hollow pipe, the hollow pipe can circulate coolant to cool the induction coil 22, and the induction coil 22 is cooled by cooling water to ensure that the coil can be in a high temperature environment working normally.
  • the inner layer 11 of the evaporation boat is the entire heating resistor, which generates heat through the thermal effect of direct current, and then transmits the heat to the inner crucible 21 through the thermal conduction effect. Furthermore, the non-metallic materials in the inner crucible can be heated.
  • the evaporation source 20 is also provided with a pair of electrode blocks 26. The pair of electrode blocks 26 are respectively connected to the positive and negative electrodes of the external DC power supply.
  • the evaporation boat 10 is located on the pair of electrode blocks 26.
  • the inner crucible 21 and the inner layer 11 of the evaporation boat are in contact with each other.
  • the pair of electrode blocks 26 can not only be used to seal the outer layer 12 of the evaporation boat, but also It can play the role of connecting the power supply and the inner layer 11 of the evaporation boat.
  • the direct current generated by the external DC power supply can flow to the inner layer 11 of the evaporation boat through the pair of electrode blocks 26, and then generate heat. It is heated by resistance and can be applied to those that cannot form eddy currents.
  • Non-metallic materials can not only be used to seal the outer layer 12 of the evaporation boat, but also It can play the role of connecting the power supply and the inner layer 11 of the evaporation boat.
  • the direct current generated by the external DC power supply can flow to the inner layer 11 of the evaporation boat through the pair of electrode blocks 26, and then generate heat. It is heated by resistance and can be applied to those that cannot form eddy currents.
  • Non-metallic materials are examples of the wires, tungsten, tungsten, tungsten, tungsten, tungsten, tungsten
  • the outer layer 12 of the evaporation boat is provided with a groove 14, and the movable cover plate 13 can be clamped in the groove 14.
  • the movable cover plate 15 is mainly used to fix the inner layer 11 of the evaporation boat and the induction coil. 22.
  • the above-mentioned components need to be disassembled in sequence, and the inner crucible 21 can be installed or unloaded with the movable cover plate 13 fixed.
  • the air distribution pipe 30 includes an air inlet pipe 33, a multi-stage shunt pipe 34, and an exhaust pipe 35 that are connected in sequence.
  • the exhaust pipe 35 is parallel to the edge of the evaporation boat 10, and the air inlet
  • the port 31 is located on the air inlet pipe 33, and the air outlet 32 is located on the exhaust pipe 35.
  • the air distribution pipe 30 adopts a binary structure, and one inlet pipe 33 is connected to two first-stage shunt pipes.
  • the multi-stage shunt pipe 34 can well control the pressure of the external air to ensure that the external air will not be over-pressured.
  • the boil-off gas on the evaporation source 20 is blown away, and the outside gas cannot be mixed with the boil-off gas evaporated from the evaporation source 20 because the pressure of the outside gas is too small.
  • the horizontal plane where the axis of the exhaust pipe 35 is located is at an angle of 10°-70° with the axis of the air outlet 32, and the distance between adjacent air outlets 32 is equal, in order to ensure that the external air can communicate with the evaporation source 20.
  • the evaporated boil-off gas can be mixed well.
  • the angle of the external gas sprayed from the gas outlet 32 needs to be inclined.
  • the inclination direction is toward the evaporation source 20, and the horizontal plane where the axis of the exhaust pipe 35 lies and the outlet 32
  • the angle between the axes of 10°-70° can ensure that the external air can be injected into the top of the evaporation source 20.
  • the equally spaced air outlets 32 can ensure the uniformity of the external air in the evaporation boat 10, thereby ensuring that the evaporation gas is The quality of the mixing reaction of the external air.
  • the exhaust pipe 35 includes a plurality of relatively independent exhaust branch pipes 36, and the exhaust branch pipes 36 can communicate with the corresponding branch pipe 34.
  • Each exhaust branch pipe 36 is provided with a plurality of air outlets 32 located in the exhaust pipe.
  • the diameter of the air outlet 32 in the middle of the branch pipe 36 is smaller than the diameter of the air outlet 32 located on both sides of the exhaust branch pipe 36.
  • the aperture size of each air outlet 32 is positively correlated with the distance from the air outlet 32 to the middle of the exhaust branch pipe 36. That is, the farther the position from the middle of the exhaust branch pipe 36 is, the larger the diameter of the small hole is.
  • each gas outlet 32 has the same gas output, and each gas outlet 32 on the gas distribution pipeline 30 can evenly and stably pass the same flow of gas, which ensures the uniformity and adequacy of gas mixing during the chemical reaction process.
  • the valve can be used to limit the gas flow, or the diameter of the gas outlet 32 can be adjusted. Restrictions, do not use air outlets with the same diameter, thereby ensuring the uniformity of air outlet.
  • the total length of the designed heating device is 1.6m.
  • the effective length of each section of the exhaust branch pipe 36 is 20cm, and there are 8 sections in total. If it is necessary to make 10 holes on each exhaust branch pipe 36 and distribute them symmetrically, the adjacent distance between each hole is 2 cm.
  • the schematic diagram of its dimensions is shown in Figure 5, and the specific calculation process is as follows:
  • the cross section of the inner crucible 21 gradually expands from the bottom to the opening.
  • the structure of the inner crucible 21 preferably adopts an inverted trapezoidal shape but is not limited to this shape. It may also be an inverted truncated cone shape, an inverted arch shape, etc.
  • the material above the inner crucible 21 The temperature is slightly lower than that of the material under the inner crucible 21, so that excessive heating of the surface of the material can be avoided.
  • the cross section of the inner crucible 21 is parallel to the gap adjustment gasket 25. Among them, the cross section of the inner crucible 21 refers to the cross section perpendicular to the axis of the inner crucible 21.
  • the angle between the generatrix of the inner crucible and the axis cannot be too large or too small. It is recommended to introduce Between 5° and 45°, the emission angle and mixing range of the vaporized gas are increased, so that the vaporized substance produced is easily distributed to the substrate to be coated.
  • This application can avoid excessive heating of the material surface, reduce the occurrence of sputtering, and is applied to the scene of large-area high-speed winding coating, so it has industrial applicability.

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  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
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Abstract

An evaporation apparatus of a vacuum film-plating machine, comprising: an evaporation boat (10), a heating system, and a gas distribution system, the evaporation boat (10) comprising an evaporation boat inner layer (11), an evaporation boat outer layer (12), and a moving cover plate (13), the evaporation boat inner layer (11) being positioned between the evaporation boat outer layer (12) and the moving cover plate (13), a plurality of evaporation holes being disposed on the moving cover plate (13), and evaporation grooves corresponding to the evaporation holes being disposed on the evaporation boat inner layer (11); the heating system comprises a plurality of mutually independent evaporation sources (20), the evaporation sources being provided with an inner crucible (21), the inner crucible (21) being nested in the evaporation groove, and the evaporation source (20) being capable of heating an object placed in the inner crucible (21); a gas distribution pipeline (30) with a multi-stage binary structure is also provided to implement control of the uniformity of the gas intake volume, such that the evaporation gas and the external introduced gas can fully mix to form a uniform composite film. The evaporation sources (20) using a honeycomb structure have a high heating efficiency, and are capable of ensuring uniformity when heating and evaporating a large surface area of material, reducing sputtering and being suitable for large-area high-speed winding and film-plating processes.

Description

一种真空镀膜机的蒸发装置Evaporation device of vacuum coating machine 技术领域Technical field
本申请涉及真空镀膜技术领域,主要涉及一种真空蒸发镀膜机的蒸发装置。This application relates to the technical field of vacuum coating, and mainly relates to an evaporation device of a vacuum evaporation coating machine.
背景技术Background technique
近年来,随着光学薄膜技术以及半导体科技的发展,真空镀膜技术在生产中的应用也越来越广泛与重要。真空蒸镀是最普遍、应用最广的真空镀膜工艺,真空蒸镀的物理过程包括:沉积材料蒸发或升华为气态粒子→气态粒子快速从蒸发源向基片表面输送→气态粒子附着在基片表面形核、长大成固体薄膜→薄膜原子重构或产生化学键合。In recent years, with the development of optical thin film technology and semiconductor technology, the application of vacuum coating technology in production has become more and more extensive and important. Vacuum evaporation is the most common and widely used vacuum coating process. The physical process of vacuum evaporation includes: evaporation or sublimation of the deposition material into gaseous particles → rapid transport of gaseous particles from the evaporation source to the surface of the substrate → adhesion of gaseous particles to the substrate The surface nucleates and grows into a solid film→the film atoms are reconstructed or chemically bonded.
将基片放入真空室内,以电阻、电子束、激光等方法加热膜料,使膜料蒸发或升华,气化为具有一定能量(0.1~0.3eV)的粒子(原子、分子或原子团)。气态粒子以基本无碰撞的直线运动飞速传送至基片,到达基片表面的粒子一部分被反射,另一部分吸附在基片上并发生表面扩散,沉积原子之间产生二维碰撞,形成簇团,有的可能在表面短时停留后又蒸发。粒子簇团不断地与扩散粒子相碰撞,或吸附单粒子,或放出单粒子。此过程反复进行,当聚集的粒子数超过某一临界值时就变为稳定的核,再继续吸附扩散粒子而逐步长大,最终通过相邻稳定核的接触、合并,形成连续薄膜。Put the substrate into a vacuum chamber, heat the film material by resistance, electron beam, laser, etc., to evaporate or sublimate the film material, and vaporize into particles (atoms, molecules or groups of atoms) with a certain energy (0.1~0.3eV). The gaseous particles are rapidly transported to the substrate in a substantially collision-free linear motion. Part of the particles that reach the surface of the substrate is reflected, and the other part is adsorbed on the substrate and diffused on the surface. A two-dimensional collision occurs between the deposited atoms to form clusters. It may evaporate after a short stay on the surface. The particle clusters continuously collide with diffused particles, or adsorb single particles, or release single particles. This process is repeated. When the number of aggregated particles exceeds a certain critical value, it becomes a stable nucleus, and then continues to adsorb and diffuse particles to gradually grow up, and finally through the contact and merging of adjacent stable nuclei, a continuous film is formed.
若需要高效镀制大面积薄膜,则需要真空卷绕镀膜工艺,在镀制大面积薄膜的时候,就需要对大量的基片进行加热,在现有的真空蒸镀设备中,采用的是小型蒸发舟对基片进行加热,蒸发量小而且加热效率低,蒸发过程中容易出现溅射现象,并不适合于大面积高速卷绕镀膜工艺。If large-area thin films need to be plated efficiently, a vacuum winding coating process is required. When large-area thin films are plated, a large number of substrates need to be heated. In the existing vacuum evaporation equipment, small-sized The evaporation boat heats the substrate, the evaporation is small and the heating efficiency is low, and the sputtering phenomenon is prone to occur during the evaporation process, which is not suitable for the large-area high-speed winding coating process.
发明内容Summary of the invention
本申请解决的技术问题之一用于大面积高速卷绕镀膜工艺的蒸发装 置,以减少蒸发过程产生的溅射现象。One of the technical problems solved by the present application is an evaporation device used in a large-area high-speed winding coating process to reduce the sputtering phenomenon generated during the evaporation process.
为了达到上述目的,本申请提供一种真空镀膜机的蒸发装置,包括:蒸发舟,所述蒸发舟包括有蒸发舟内层、蒸发舟外层和活动盖板,所述蒸发舟内层位于蒸发舟外层与活动盖板之间,所述活动盖板开设有多个蒸发孔,所述蒸发舟内层上开设有与所述蒸发孔对应的蒸发凹槽,蒸发孔与蒸发凹槽均按蜂窝状进行排布;In order to achieve the above objective, the present application provides an evaporation device for a vacuum coating machine, comprising: an evaporation boat, the evaporation boat includes an evaporation boat inner layer, an evaporation boat outer layer and a movable cover, the evaporation boat inner layer is located in the evaporation boat Between the outer layer of the boat and the movable cover plate, the movable cover plate is provided with a plurality of evaporation holes, and the inner layer of the evaporation boat is provided with evaporation grooves corresponding to the evaporation holes. Arranged in a honeycomb pattern;
加热系统,所述加热系统包括多个相对独立的蒸发源,所述蒸发源设置有内坩埚,所述内坩埚嵌套于所述蒸发凹槽内,所述蒸发源能够对放置在所述内坩埚内的物体进行加热;The heating system includes a plurality of relatively independent evaporation sources, the evaporation source is provided with an inner crucible, the inner crucible is nested in the evaporation groove, and the evaporation source can be placed in the inner crucible. The objects in the crucible are heated;
布气管道,所述布气管道设置在于所述蒸发舟上端,所述布气管道开设有进气口和多个出气口,所述进气口连接外部气体源,所述出气口朝向所述蒸发源。An air distribution pipe is arranged at the upper end of the evaporation boat, the air distribution pipe is provided with an air inlet and a plurality of air outlets, the air inlet is connected to an external gas source, and the air outlet faces the Evaporation source.
可选地,所述蒸发源采用高频感应加热,所述蒸发源包括若干个感应线圈、绝热层、外坩埚,所述内坩埚叠套于所述外坩埚内,且所述绝热层设置于所述内坩埚的侧壁与所述外坩埚的侧壁之间,所述感应线圈设置于所述外坩埚的侧壁与所述蒸发舟内层之间。Optionally, the evaporation source adopts high-frequency induction heating, the evaporation source includes several induction coils, a heat insulation layer, and an outer crucible, the inner crucible is stacked in the outer crucible, and the heat insulation layer is arranged in Between the side wall of the inner crucible and the side wall of the outer crucible, the induction coil is arranged between the side wall of the outer crucible and the inner layer of the evaporation boat.
可选地,所述蒸发源还包括有调隙垫片,所述调隙垫片位于所述内坩埚与所述绝热层之间。Optionally, the evaporation source further includes a gap adjustment gasket, and the gap adjustment gasket is located between the inner crucible and the thermal insulation layer.
可选地,所述蒸发源还设置有电极块,所述电极块连接外部交流电源,多个所述感应线圈串联为一组感应线圈组,多组所述感应线圈组相互并联,所述感应线圈组与所述电极块相连,所述感应线圈内部为中空管路,所述中空管路能够循环通入冷却剂进行冷却所述感应线圈。Optionally, the evaporation source is further provided with an electrode block, the electrode block is connected to an external AC power source, a plurality of the induction coils are connected in series to form a group of induction coil groups, and the plurality of groups of the induction coil groups are connected in parallel with each other. The coil assembly is connected to the electrode block, and the induction coil is inside a hollow pipe, and the hollow pipe can circulate a coolant to cool the induction coil.
可选地,所述蒸发舟内层为电阻加热,所述蒸发源还设置有成对的电极块,所述蒸发舟位于成对的所述电极块之间且所述蒸发舟内层的端部与所述电极块连接,所述内坩埚与所述蒸发舟内层相互接触。Optionally, the inner layer of the evaporation boat is heated by resistance, the evaporation source is further provided with a pair of electrode blocks, the evaporation boat is located between the pair of electrode blocks and the end of the inner layer of the evaporation boat The part is connected with the electrode block, and the inner crucible and the inner layer of the evaporation boat are in contact with each other.
可选地,所述蒸发舟外层设置有沟槽,所述活动盖板能够卡持在所述沟槽内。Optionally, the outer layer of the evaporation boat is provided with a groove, and the movable cover plate can be clamped in the groove.
可选地,所述布气管道包括依次连通的进气管路、多级分流管路和排气管路,所述排气管路与所述蒸发舟的边缘平行,所述进气口位于所述进气管路上,所述出气口位于所述排气管路上。Optionally, the air distribution pipe includes an air inlet pipe, a multi-stage shunt pipe, and an exhaust pipe that are connected in sequence, the exhaust pipe is parallel to the edge of the evaporation boat, and the air inlet is located at the On the intake pipeline, the air outlet is located on the exhaust pipeline.
可选地,所述排气管路的轴线所在的水平面与所述出气口的轴线之间呈10°-70°夹角,相邻所述出气口之间的间距相等。Optionally, the horizontal plane on which the axis of the exhaust pipe is located and the axis of the air outlet form an included angle of 10°-70°, and the distance between adjacent air outlets is equal.
可选地,所述排气管路包括多个相对独立的排气支管,所述排气支管均能够与对应的所述分流管路连通,所述排气支管上均开设有多个所述出气口,位于所述排气支管的中部的所述出气口的直径小于位于所述排气支管的两侧的所述出气口的直径,每个所述出气口出气量相等。Optionally, the exhaust pipe includes a plurality of relatively independent exhaust branch pipes, each of the exhaust branch pipes can communicate with the corresponding branch pipeline, and the exhaust branch pipes are each provided with a plurality of the exhaust branch pipes. An air outlet, the diameter of the air outlet located in the middle of the exhaust branch pipe is smaller than the diameter of the air outlets located on both sides of the exhaust branch pipe, and each air outlet has the same amount of air output.
可选地,所述内坩埚的横截面从底部向开口逐渐扩大。Optionally, the cross section of the inner crucible gradually expands from the bottom to the opening.
本申请的有益效果是,本申请采用蜂窝状结构的蒸发源,各蒸发源内坩埚的横截面从底部向开口逐渐扩大,增大了蒸发气体的发射角以及混合范围,可以保证材料的大面积加热蒸发时的均匀性,同时在两侧安装布气管路,布气管路上的每个出气口都能均匀而稳定地通入同等流量的气体,保证了化合反应过程中气体混合的均匀性及充分性,保证了生成的复合薄膜的均匀性,同时蒸发源还具有较高加热效率,内坩埚上方材料温度略低于内坩埚下方材料,因此可以避免材料表面加热过于剧烈,减少溅射现象的发生,适用于大面积高速卷绕镀膜工艺The beneficial effect of the application is that the application adopts the evaporation source of honeycomb structure, and the cross section of the crucible in each evaporation source gradually expands from the bottom to the opening, which increases the emission angle and mixing range of the evaporation gas, and can ensure the large-area heating of the material Uniformity during evaporation. At the same time, air distribution pipelines are installed on both sides. Each outlet on the air distribution pipeline can evenly and stably pass in the same flow of gas, ensuring the uniformity and adequacy of gas mixing during the chemical reaction. , To ensure the uniformity of the composite film generated, and the evaporation source also has high heating efficiency, the temperature of the material above the inner crucible is slightly lower than that of the material below the inner crucible, so it can avoid the excessive heating of the material surface and reduce the occurrence of sputtering. Suitable for large-area high-speed winding coating process
附图说明Description of the drawings
通过阅读参照以下附图对非限制性实施例所作的详细描述:By reading the detailed description of the non-limiting embodiments with reference to the following drawings:
图1为本申请实施方式提供的一种真空镀膜机的蒸发装置的结构示意图;FIG. 1 is a schematic structural diagram of an evaporation device of a vacuum coating machine according to an embodiment of the application;
图2为本申请实施方式提供的一种真空镀膜机的蒸发装置的采用高频感应蒸发源的横截面结构示意图;2 is a schematic diagram of a cross-sectional structure of an evaporation device of a vacuum coating machine using a high-frequency induction evaporation source according to an embodiment of the application;
图3为本申请实施方式提供的另一种真空镀膜机的蒸发装置的采用电阻加热蒸发源的横截面结构示意图FIG. 3 is a schematic cross-sectional structure diagram of another evaporation device of a vacuum coating machine using a resistance heating evaporation source provided by an embodiment of the application
图4为本申请实施方式提供的一种真空镀膜机的蒸发装置的布气 管路的结构示意图。Fig. 4 is a schematic structural diagram of an air distribution pipeline of an evaporation device of a vacuum coating machine according to an embodiment of the application.
图5为本申请实施方式提供的一种真空镀膜机的蒸发装置的排气管路具体设计案例尺寸示意图。FIG. 5 is a schematic diagram of a specific design case size of an exhaust pipe of an evaporation device of a vacuum coating machine according to an embodiment of the application.
10:蒸发舟;11:蒸发舟内层;12:蒸发舟外层;13:活动盖板;14:沟槽;10: evaporation boat; 11: evaporation boat inner layer; 12: evaporation boat outer layer; 13: movable cover plate; 14: groove;
20:蒸发源;21:内坩埚;22:感应线圈;23:绝热层;24:外坩埚;25:调隙垫片;26:电极块;20: evaporation source; 21: inner crucible; 22: induction coil; 23: insulation layer; 24: outer crucible; 25: gap adjustment gasket; 26: electrode block;
30:布气管道;31:进气口;32:出气口;33:进气管路;34:分流管路;35:排气管路;36:排气支管。30: Air distribution pipeline; 31: Air inlet; 32: Air outlet; 33: Air inlet pipeline; 34: Diversion pipeline; 35: Exhaust pipeline; 36: Exhaust branch pipe.
具体实施方式Detailed ways
为了更好的解释本申请,以便于理解,下面结合附图,通过具体实施方式,对本申请作详细描述。In order to better explain the application and facilitate understanding, the application will be described in detail below through specific implementations in conjunction with the drawings.
需要说明,本申请实施例中所有方向性指示(诸如上、下、左、右、前、后……)仅用于解释在某一特定姿态(如附图所示)下各部件之间的相对位置关系、运动情况等,如果该特定姿态发生改变时,则该方向性指示也相应地随之改变。It should be noted that all directional indicators (such as up, down, left, right, front, back...) in the embodiments of this application are only used to explain the relationship between components in a specific posture (as shown in the accompanying drawings). If the relative position relationship, movement situation, etc. change, the directional indication will change accordingly.
另外,在本申请中如涉及“第一”、“第二”等的描述仅用于描述目的,而不能理解为指示或暗示其相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括至少一个该特征。在本申请的描述中,“多个”的含义是至少两个,例如两个,三个等,除非另有明确具体的限定。In addition, the descriptions related to "first", "second", etc. in this application are only for descriptive purposes, and cannot be understood as indicating or implying their relative importance or implicitly indicating the number of indicated technical features. Therefore, the features defined with "first" and "second" may explicitly or implicitly include at least one of the features. In the description of the present application, "a plurality of" means at least two, such as two, three, etc., unless specifically defined otherwise.
在本申请中,除非另有明确的规定和限定,术语“连接”、“固定”等应做广义理解,例如,“固定”可以是固定连接,也可以是可拆卸连接,或成一体;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通或两个元件的相互作用关系,除非另有明确的限定。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本申请中的具体含义。In this application, unless otherwise clearly specified and limited, the terms "connected", "fixed", etc. should be understood in a broad sense. For example, "fixed" can be a fixed connection, a detachable connection, or a whole; It can be a mechanical connection or an electrical connection; it can be a direct connection or an indirect connection through an intermediate medium, and it can be an internal communication between two components or an interaction relationship between two components, unless specifically defined otherwise. For those of ordinary skill in the art, the specific meanings of the above-mentioned terms in this application can be understood according to specific circumstances.
本申请提供一种真空镀膜机的蒸发装置,其包括:蒸发舟10本体、 用于加热靶材的加热系统、与外部气体源相连用来供应气体的布气管道30。The present application provides an evaporation device of a vacuum coating machine, which includes: an evaporation boat 10 body, a heating system for heating a target material, and a gas distribution pipe 30 connected with an external gas source for supplying gas.
蒸发舟10,蒸发舟10包括有蒸发舟内层11、蒸发舟外层12和活动盖板13,本实施方式中,蒸发舟10整体为长条形,蒸发舟10内部开设有凹槽,蒸发舟内层11和活动盖板13位于凹槽内,蒸发舟内层11位于蒸发舟外层12与活动盖板13之间,活动盖板13开设有多个蒸发孔(未标记),蒸发舟内层11上开设有与蒸发孔对应的蒸发凹槽(未标记),蒸发舟外层12的主要用于隔离防护和固定,材料选择耐高温的低电导率材料即可,必要时可在蒸发舟外层12内部涂上绝缘绝热涂层以提高结构的安全性;The evaporation boat 10 includes an evaporation boat inner layer 11, an evaporation boat outer layer 12 and a movable cover 13. In this embodiment, the evaporation boat 10 is elongated as a whole, and the inside of the evaporation boat 10 is provided with grooves. The boat inner layer 11 and the movable cover plate 13 are located in the groove, the evaporation boat inner layer 11 is located between the evaporation boat outer layer 12 and the movable cover plate 13, and the movable cover plate 13 is provided with a plurality of evaporation holes (not marked). The inner layer 11 is provided with evaporation grooves (not marked) corresponding to the evaporation holes. The outer layer of the evaporation boat 12 is mainly used for isolation, protection and fixation. The outer layer 12 of the boat is coated with an insulating and heat-insulating coating to improve the safety of the structure;
加热系统,加热系统包括多个相对独立的蒸发源20,本实施方式中,蒸发源20设置有内坩埚21,内坩埚21嵌套于蒸发凹槽内,蒸发源20能够对放置在内坩埚21内的物体进行加热;The heating system includes a plurality of relatively independent evaporation sources 20. In this embodiment, the evaporation source 20 is provided with an inner crucible 21, the inner crucible 21 is nested in the evaporation groove, and the evaporation source 20 can be placed opposite to the inner crucible 21 The objects inside are heated;
布气管道30,布气管道30设置在于蒸发舟10上端,布气管道30开设有进气口31和多个出气口32,进气口31连接外部气体源,出气口32朝向蒸发源20;The air distribution pipe 30 is arranged at the upper end of the evaporation boat 10, the air distribution pipe 30 is provided with an air inlet 31 and a plurality of air outlets 32, the air inlet 31 is connected to an external air source, and the air outlet 32 faces the evaporation source 20;
当需要加热靶材或其他材料时,只需将材料放入内坩埚21中,可以根据实际需要,选择不同数量的材料放入多个内坩埚21中,这样就能够保证每个材料都会受到均匀加热,不会产生加热不均的问题,减少蒸发过程产生的溅射现象,同时,蒸发源20的排列设置为蜂窝状,可以使得大面积加热材料后蒸发出来的气体非常均匀;When you need to heat the target or other materials, you only need to put the materials in the inner crucible 21. According to actual needs, you can select different amounts of materials and put them in the multiple inner crucibles 21, so as to ensure that each material will be uniformly received. Heating does not cause uneven heating and reduces the sputtering phenomenon during the evaporation process. At the same time, the arrangement of the evaporation source 20 is honeycomb, which can make the gas evaporated after heating the material in a large area very uniform;
进一步地,将布气管道30设置在蒸发舟10上方,同时将出气口32朝向蒸发源20,能够很好的将外部气体与蒸发源20蒸发材料产生的气体进行化合反应,达到镀制复合薄膜的要求;Further, the gas distribution pipe 30 is arranged above the evaporation boat 10, and the gas outlet 32 is directed to the evaporation source 20, which can combine the external air with the gas generated by the evaporation source 20 to evaporate the material to achieve a composite film coating. The requirements;
更进一步地,为了满足镀制大面积薄膜的需求,蒸发源20在蒸发舟10内的排列至少为3列,排列的长度和个数以及蒸发孔的半径可以根据具体的镀制需求来更改,以便满足更大面积镀制薄膜的需求。Furthermore, in order to meet the needs of coating large-area thin films, the arrangement of the evaporation sources 20 in the evaporation boat 10 is at least 3 rows, and the length and number of the arrangement and the radius of the evaporation holes can be changed according to the specific plating requirements. In order to meet the needs of coating a larger area.
如图2所示,在本实施方式中,本申请的蒸发源20采用高频感应加 热,该加热方式适用于加热金属材料,通过通入高频交流电使内坩埚21中的金属材料内部产生涡流,由感应线圈22内产生极性瞬间变化的强大磁束,将需要热处理的金属放置在高频线圈内,磁束就会贯通整个被加热的金属材料。在感应加热物体的内部与感应加热电流相反的方向,产生相对应的强大涡电流,同时因为感应加热的金属材料内存在电阻,因此产生强的焦耳热能,使感应加热物体物体温度迅速上升,从而达到热处理的目的,实现对金属材料的加热,蒸发源20包括若干个感应线圈22、绝热层23、外坩埚24,内坩埚21叠套于外坩埚24内,且绝热层23设置于内坩埚21的侧壁与外坩埚24的侧壁之间,用于隔绝内坩埚21的热量,避免内坩埚21的热量影响到感应线圈22,感应线圈22设置于外坩埚24的侧壁与蒸发舟内层11之间,本实施方式中,内坩埚21材料为耐高温的石墨,绝热层23为隔热性能良好的碳毡,感应线圈22材料为导电性良好的铜,线圈直径为1.5cm,线圈匝数为5匝,蒸发源20的内坩埚21为倒梯台形,顶圆直径为6cm,外坩埚24为圆柱形,外坩埚24和内坩埚21之间的空隙用绝热材料进行填充为绝热层23,线圈上方为活动盖板13,当需要安装或拆卸感应线圈22以及外坩埚24时,则活动盖板13开启。蒸发舟内层11的材料采用绝热性和绝缘性良好的复合陶瓷,以减少各感应线圈22之间的干涉。As shown in FIG. 2, in this embodiment, the evaporation source 20 of the present application adopts high-frequency induction heating. This heating method is suitable for heating metal materials, and eddy currents are generated inside the metal materials in the inner crucible 21 by passing high-frequency alternating current. , A strong magnetic flux with an instantaneous change in polarity is generated in the induction coil 22, and the metal to be heat-treated is placed in the high-frequency coil, and the magnetic flux will penetrate the entire heated metal material. The inside of the induction heating object is in the opposite direction to the induction heating current, and a corresponding strong eddy current is generated. At the same time, because of the resistance in the metal material of the induction heating, strong Joule heat is generated, which causes the temperature of the induction heating object to rise rapidly, thereby To achieve the purpose of heat treatment and realize the heating of metal materials, the evaporation source 20 includes several induction coils 22, a heat insulation layer 23, and an outer crucible 24. The inner crucible 21 is stacked in the outer crucible 24, and the heat insulation layer 23 is set on the inner crucible 21. Between the side wall of the outer crucible 24 and the side wall of the outer crucible 24, it is used to isolate the heat of the inner crucible 21 to prevent the heat of the inner crucible 21 from affecting the induction coil 22, which is arranged on the side wall of the outer crucible 24 and the inner layer of the evaporation boat 11, in this embodiment, the inner crucible 21 is made of high-temperature resistant graphite, the heat insulation layer 23 is made of carbon felt with good heat insulation performance, and the induction coil 22 is made of copper with good conductivity. The coil diameter is 1.5 cm, and the coil turns The number is 5 turns. The inner crucible 21 of the evaporation source 20 has an inverted trapezoidal shape with a top circle diameter of 6 cm. The outer crucible 24 is cylindrical. The gap between the outer crucible 24 and the inner crucible 21 is filled with a heat-insulating material to form a heat-insulating layer 23 , Above the coil is the movable cover plate 13. When the induction coil 22 and the outer crucible 24 need to be installed or removed, the movable cover plate 13 is opened. The inner layer 11 of the evaporation boat is made of composite ceramics with good thermal and insulating properties to reduce the interference between the induction coils 22.
其中,蒸发源20还包括有调隙垫片25,调隙垫片25位于内坩埚21与外坩埚24之间,在实施方式中,调隙垫片25采用耐高温的石棉垫片,外坩埚24的材料选择氧化铝等氧化物,调隙垫片25是厚度为一道的金属薄片,采用堆叠的方式调控内坩埚的高度,减小蒸发差异,保证各蒸发源蒸发量的均匀性,进一步地,在安装蒸发源20的时候,内坩埚21与外坩埚24之间往往会有间隙,如果存在间隙,间隙里的空气经过加热便会膨胀,进而影响蒸发源20零件的配合,调隙垫片25能够很好的将空隙消除,防止加热过程中发生意外,同时调隙垫片25也能够很好的提供支撑给内坩埚21,防止内坩埚21发生倾斜。Wherein, the evaporation source 20 also includes a gap adjustment gasket 25, which is located between the inner crucible 21 and the outer crucible 24. In the embodiment, the gap adjustment gasket 25 uses a high temperature resistant asbestos gasket, and the outer crucible The material of 24 is alumina and other oxides. The gap adjustment gasket 25 is a thin metal sheet with a thickness. The height of the inner crucible is adjusted by stacking, reducing the evaporation difference, ensuring the uniformity of the evaporation of each evaporation source, and further When the evaporation source 20 is installed, there is often a gap between the inner crucible 21 and the outer crucible 24. If there is a gap, the air in the gap will expand after heating, which will affect the fit of the evaporation source 20 parts, and the gap adjustment gasket 25 can effectively eliminate the gap and prevent accidents during heating. At the same time, the gap adjustment gasket 25 can also provide a good support to the inner crucible 21 to prevent the inner crucible 21 from tilting.
进一步地,参见图1、图2,蒸发源20还设置有电极块26,电极块 26连接外部交流电源,电极块26为一对,分别位于蒸发舟10两端,用于封闭蒸发舟外层12,蒸发源20提供多个感应线圈22串联为一组感应线圈22组,多组感应线圈22组相互并联,在本实施方式中,感性线圈按相邻八个一组串联为感应线圈22组、每组感应线圈22组相并联的混连方式进行加热,因此可以按照相邻八个蒸发源20为一组的方式来精确调节蒸发舟各个部位的温度,在未将每个蒸发源20装满材料的情况下可以对坩埚进行选择性地加热,提高加热效率以及镀膜长度设计的灵活性,实现对热量和能源的充分而高效的利用,同时感应线圈22组与电极块26相连,方便电流通过感应线圈22,感应线圈22内部为中空管路,中空管路能够循环通入冷却剂进行冷却感应线圈22,感应线圈22内部通入冷却水进行冷却,以确保线圈能在高温环境下正常运作。Further, referring to Figures 1 and 2, the evaporation source 20 is also provided with electrode blocks 26, the electrode blocks 26 are connected to an external AC power source, the electrode blocks 26 are a pair, respectively located at the two ends of the evaporation boat 10, for sealing the outer layer of the evaporation boat 12. The evaporation source 20 provides a plurality of induction coils 22 in series to form a group of induction coils 22, and the groups of induction coils 22 are connected in parallel. In this embodiment, the inductive coils are connected in series according to eight adjacent groups to form an induction coil 22 group. , Each group of induction coils 22 are connected in parallel for heating, so the temperature of each part of the evaporation boat can be adjusted accurately according to the way that eight adjacent evaporation sources 20 are a group, and each evaporation source 20 is not installed. When the material is full, the crucible can be selectively heated to improve the heating efficiency and the flexibility of the coating length design, so as to realize the full and efficient use of heat and energy. At the same time, the induction coil 22 group is connected with the electrode block 26 to facilitate current Through the induction coil 22, the inside of the induction coil 22 is a hollow pipe, the hollow pipe can circulate coolant to cool the induction coil 22, and the induction coil 22 is cooled by cooling water to ensure that the coil can be in a high temperature environment working normally.
如图3所示,在另一种实施方式中,对于非金属材料,蒸发舟内层11为整个加热电阻,通过直流电的热效应产生热量,然后通过热传导效应,将热量传达到内坩埚21上,进而能够加热内坩埚中的非金属材料,蒸发源20还设置有成对的电极块26,成对的电极块26分别连接外部直流电源的正极与负极,蒸发舟10位于成对的电极块26之间且蒸发舟内层11的端部与电极块连接,所述内坩埚21与所述蒸发舟内层11相互接触,成对的电极块26不仅能够用于封闭蒸发舟外层12,还能够起到连接电源与蒸发舟内层11的作用,外部直流电源产生的直流电能够通过成对的电极块26流向蒸发舟内层11,进而产生热量,采用电阻加热,能够适用于无法形成涡流的非金属材料。As shown in FIG. 3, in another embodiment, for non-metallic materials, the inner layer 11 of the evaporation boat is the entire heating resistor, which generates heat through the thermal effect of direct current, and then transmits the heat to the inner crucible 21 through the thermal conduction effect. Furthermore, the non-metallic materials in the inner crucible can be heated. The evaporation source 20 is also provided with a pair of electrode blocks 26. The pair of electrode blocks 26 are respectively connected to the positive and negative electrodes of the external DC power supply. The evaporation boat 10 is located on the pair of electrode blocks 26. The inner crucible 21 and the inner layer 11 of the evaporation boat are in contact with each other. The pair of electrode blocks 26 can not only be used to seal the outer layer 12 of the evaporation boat, but also It can play the role of connecting the power supply and the inner layer 11 of the evaporation boat. The direct current generated by the external DC power supply can flow to the inner layer 11 of the evaporation boat through the pair of electrode blocks 26, and then generate heat. It is heated by resistance and can be applied to those that cannot form eddy currents. Non-metallic materials.
进一步地,蒸发舟外层12设置有沟槽14,活动盖板13能够卡持在所述沟槽14内,在实施方式中,活动盖板15主要用于固定蒸发舟内层11、感应线圈22、外坩埚24等结构,当更换上述结构时,需要依次拆卸上述部件,同时内坩埚21可在活动盖板13固定的情况下安装或卸载。Further, the outer layer 12 of the evaporation boat is provided with a groove 14, and the movable cover plate 13 can be clamped in the groove 14. In the embodiment, the movable cover plate 15 is mainly used to fix the inner layer 11 of the evaporation boat and the induction coil. 22. For structures such as the outer crucible 24, when replacing the above-mentioned structures, the above-mentioned components need to be disassembled in sequence, and the inner crucible 21 can be installed or unloaded with the movable cover plate 13 fixed.
其中,参见,1、图4,布气管道30包括依次连通的进气管路33、多级分流管路34和排气管路35,排气管路35与蒸发舟10的边缘平行,进气口31位于进气管路33上,出气口32位于排气管路35上,在本实施 方式中,布气管道30采用二元型结构,一根进气管路33连接两根第一级分流管路34,一根上一级分流管路34连接两根下一级分流管路34,分流管路34级数大于3级,分流管路34各段路径相同,每一级管路的管径可以相同,也可以逐渐减小,最后外部气体从排气管路35上的出气口32喷出,多级的分流管路34能够很好的控制外部气体的压力,保证外部气体不会因为压力过大将蒸发源20上的蒸发气体吹散,也不会因为外部气体压力过小导致外部气体不能够与蒸发源20蒸发出来的蒸发气体进行混合。Among them, see Figure 1, Figure 4, the air distribution pipe 30 includes an air inlet pipe 33, a multi-stage shunt pipe 34, and an exhaust pipe 35 that are connected in sequence. The exhaust pipe 35 is parallel to the edge of the evaporation boat 10, and the air inlet The port 31 is located on the air inlet pipe 33, and the air outlet 32 is located on the exhaust pipe 35. In this embodiment, the air distribution pipe 30 adopts a binary structure, and one inlet pipe 33 is connected to two first-stage shunt pipes. Road 34, one upper-level shunt pipe 34 is connected to two lower-level shunt pipes 34, the number of shunt pipe 34 is greater than 3, the path of each section of shunt pipe 34 is the same, and the pipe diameter of each stage pipe can be Similarly, it can also be gradually reduced. Finally, the external air is ejected from the air outlet 32 on the exhaust pipe 35. The multi-stage shunt pipe 34 can well control the pressure of the external air to ensure that the external air will not be over-pressured. Generally, the boil-off gas on the evaporation source 20 is blown away, and the outside gas cannot be mixed with the boil-off gas evaporated from the evaporation source 20 because the pressure of the outside gas is too small.
进一步地,排气管路35的轴线所在的水平面与出气口32的轴线之间呈10°-70°夹角,相邻出气口32之间的间距相等,为了保证外部气体能够与蒸发源20蒸发出来的蒸发气体能够很好的进行混合,外部气体从出气口32喷出的角度需要进行一定的倾斜,倾斜方向朝向蒸发源20,排气管路35的轴线所在的水平面与出气口32的轴线之间呈10°-70°夹角能够很好保证外部气体能够喷射进入蒸发源20上方,同时等间距的出气口32能够保证外部气体在蒸发舟10内的均匀性,进而保证蒸发气体与外部气体的混合反应的质量。Further, the horizontal plane where the axis of the exhaust pipe 35 is located is at an angle of 10°-70° with the axis of the air outlet 32, and the distance between adjacent air outlets 32 is equal, in order to ensure that the external air can communicate with the evaporation source 20. The evaporated boil-off gas can be mixed well. The angle of the external gas sprayed from the gas outlet 32 needs to be inclined. The inclination direction is toward the evaporation source 20, and the horizontal plane where the axis of the exhaust pipe 35 lies and the outlet 32 The angle between the axes of 10°-70° can ensure that the external air can be injected into the top of the evaporation source 20. At the same time, the equally spaced air outlets 32 can ensure the uniformity of the external air in the evaporation boat 10, thereby ensuring that the evaporation gas is The quality of the mixing reaction of the external air.
其中,排气管路35包括多个相对独立的排气支管36,排气支管36均能够与对应的分流管路34连通,排气支管36上均开设有多个出气口32,位于排气支管36的中部的出气口32的直径小于位于排气支管36的两侧的出气口32的直径,各个出气口32的孔径大小与出气口32的到排气支管36中部的距离呈正相关关系,即距离排气支管36中部越远位置的小孔孔径越大。Wherein, the exhaust pipe 35 includes a plurality of relatively independent exhaust branch pipes 36, and the exhaust branch pipes 36 can communicate with the corresponding branch pipe 34. Each exhaust branch pipe 36 is provided with a plurality of air outlets 32 located in the exhaust pipe. The diameter of the air outlet 32 in the middle of the branch pipe 36 is smaller than the diameter of the air outlet 32 located on both sides of the exhaust branch pipe 36. The aperture size of each air outlet 32 is positively correlated with the distance from the air outlet 32 to the middle of the exhaust branch pipe 36. That is, the farther the position from the middle of the exhaust branch pipe 36 is, the larger the diameter of the small hole is.
进一步地,每个出气口32出气量相等,布气管路30上的每个出气口32都能均匀而稳定地通入同等流量的气体,保证了化合反应过程中气体混合的均匀性及充分性,保证了生成的复合薄膜的均匀性,由于管路中有压差存在,因此当需要保证出气口32的出气量相等时,可以采用阀门限制气体流量的方式,或者对出气口32的口径进行限制,不采用直径大小相同的出气口,进而保证出气均匀性。在本实施方案中,所设计的 加热装置的总长为1.6m,若布气管路采用直径为8mm的相同气管,三级分布,则每节排气支管36有效长度为20cm,共8节。若需要在每根排气支管36上开取10个孔,按照对称分布,则每个孔相邻间距为2cm,排气支管36以中部为对称,两边各有5个气孔分布。假设通过计算需要通入总共20sccm流量的氧气,工作环境温度为500℃,则为保证出气均匀性,排气支管36以中部为对称轴,两侧的每个气孔从中部向两侧的孔径分别为d 1=2mm,d 2=2.05mm,d 3=2.09mm,d 4=2.12m,d 5=2.13mm,其尺寸示意图如图5所示,具体计算过程如下所示: Furthermore, each gas outlet 32 has the same gas output, and each gas outlet 32 on the gas distribution pipeline 30 can evenly and stably pass the same flow of gas, which ensures the uniformity and adequacy of gas mixing during the chemical reaction process. , To ensure the uniformity of the generated composite film, because there is a pressure difference in the pipeline, when it is necessary to ensure that the gas output of the gas outlet 32 is equal, the valve can be used to limit the gas flow, or the diameter of the gas outlet 32 can be adjusted. Restrictions, do not use air outlets with the same diameter, thereby ensuring the uniformity of air outlet. In this embodiment, the total length of the designed heating device is 1.6m. If the air distribution pipeline adopts the same air pipe with a diameter of 8mm and is distributed in three stages, the effective length of each section of the exhaust branch pipe 36 is 20cm, and there are 8 sections in total. If it is necessary to make 10 holes on each exhaust branch pipe 36 and distribute them symmetrically, the adjacent distance between each hole is 2 cm. The exhaust branch pipe 36 is symmetrical in the middle, and there are 5 air holes on each side. Assuming that a total of 20 sccm of oxygen is required through calculation, and the working environment temperature is 500 ℃, to ensure the uniformity of the air, the exhaust branch pipe 36 takes the middle as the axis of symmetry, and each pore on both sides has a diameter from the middle to the two sides. D 1 =2mm, d 2 =2.05mm, d 3 =2.09mm, d 4 =2.12m, d 5 =2.13mm. The schematic diagram of its dimensions is shown in Figure 5, and the specific calculation process is as follows:
排气支管36有效长度:L=2×10 -2m Effective length of exhaust branch pipe 36: L=2×10 -2 m
管径:D=8×10 -3m Pipe diameter: D=8×10 -3 m
壁厚:h=2×10 -3m Wall thickness: h=2×10 -3 m
气体流量:
Figure PCTCN2020118421-appb-000001
Gas flow:
Figure PCTCN2020118421-appb-000001
排气支管36单侧进气量:
Figure PCTCN2020118421-appb-000002
Air intake on one side of exhaust branch pipe 36:
Figure PCTCN2020118421-appb-000002
Figure PCTCN2020118421-appb-000003
Figure PCTCN2020118421-appb-000003
氧气分子量:
Figure PCTCN2020118421-appb-000004
Oxygen molecular weight:
Figure PCTCN2020118421-appb-000004
25℃氧气动力粘度:Z 0=2.055×10 -5Pa/s Oxygen dynamic viscosity at 25°C: Z 0 =2.055×10 -5 Pa/s
T 0=298k T 0 =298k
C=112kC=112k
T=773KT=773K
Figure PCTCN2020118421-appb-000005
则500℃下的氧气动力粘度为:
Figure PCTCN2020118421-appb-000005
Then the oxygen dynamic viscosity at 500°C is:
Figure PCTCN2020118421-appb-000006
特征参数B的计算如下:
Figure PCTCN2020118421-appb-000006
The calculation of characteristic parameter B is as follows:
Figure PCTCN2020118421-appb-000007
Figure PCTCN2020118421-appb-000007
Figure PCTCN2020118421-appb-000008
得:
by
Figure PCTCN2020118421-appb-000008
Get:
Figure PCTCN2020118421-appb-000009
Figure PCTCN2020118421-appb-000009
Figure PCTCN2020118421-appb-000010
Figure PCTCN2020118421-appb-000010
Figure PCTCN2020118421-appb-000011
Figure PCTCN2020118421-appb-000011
Figure PCTCN2020118421-appb-000012
Figure PCTCN2020118421-appb-000012
取d 1=2mm,代入上式计算,最终得出d 2=2.05mm,d 3=2.09mm,d 4=2.12m,d 5=2.13mm。 Take d 1 =2mm, substitute the above formula for calculation, and finally get d 2 =2.05mm, d 3 =2.09mm, d 4 =2.12m, and d 5 =2.13mm.
通过一系列计算和分流,保证了每个出气口32的出气流量是几乎相等的,避免了管路摩擦和内部压差对进气量分布的影响,考虑到加工精度问题,孔径大小需要进行圆整,以达到区分效果。此处由于数值选择问题计算结果难以实现加工,具体生产中可以更改相应外部条件以实现进气均匀性的优化。Through a series of calculations and diversions, it is ensured that the air flow rate of each air outlet 32 is almost equal, and the influence of pipeline friction and internal pressure difference on the air intake distribution is avoided. Considering the processing accuracy, the aperture size needs to be rounded. To achieve the distinguishing effect. Here, the calculation results of the numerical selection problem are difficult to realize processing, and the corresponding external conditions can be changed in the specific production to achieve the optimization of the uniformity of the intake air.
进一步地,内坩埚21的横截面从底部向开口逐渐扩大,内坩埚21的结构优先采用倒梯台形但不局限于该形,还可以是倒圆台形、倒拱形等,内坩埚21上方材料温度略低于内坩埚21下方材料,因此可以避免材料表面加热过于剧烈,上述内坩埚21的横截面与调隙垫片25平行。其中,内坩埚21的横截面是指与内坩埚21的轴线垂直的截面,当内坩埚21的结构采用倒圆台形时,内坩埚的母线与轴线夹角不能太大也不能太小,建议介于5°与45°之间,增大了蒸发气体的发射角以及混合范围,以便于产生的蒸发物质容易散发至待镀膜基片上。Further, the cross section of the inner crucible 21 gradually expands from the bottom to the opening. The structure of the inner crucible 21 preferably adopts an inverted trapezoidal shape but is not limited to this shape. It may also be an inverted truncated cone shape, an inverted arch shape, etc. The material above the inner crucible 21 The temperature is slightly lower than that of the material under the inner crucible 21, so that excessive heating of the surface of the material can be avoided. The cross section of the inner crucible 21 is parallel to the gap adjustment gasket 25. Among them, the cross section of the inner crucible 21 refers to the cross section perpendicular to the axis of the inner crucible 21. When the structure of the inner crucible 21 adopts a rounded frustum shape, the angle between the generatrix of the inner crucible and the axis cannot be too large or too small. It is recommended to introduce Between 5° and 45°, the emission angle and mixing range of the vaporized gas are increased, so that the vaporized substance produced is easily distributed to the substrate to be coated.
上述仅为本申请的实施方式而已,并不用于限制本申请。对于本领域技术人员来说,本申请可以有各种更改和变化。凡在本申请的精神和原理的内所作的任何修改、等同替换、改进等,均应包括在本申请的权利要求范围之内。The above are only the implementation manners of the application, and are not used to limit the application. For those skilled in the art, this application can have various modifications and changes. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of this application shall be included in the scope of the claims of this application.
工业实用性Industrial applicability
本申请能够避免材料表面加热过于剧烈,减少溅射现象的发生,应用在大面积高速卷绕镀膜的场景,因此具有工业实用性。This application can avoid excessive heating of the material surface, reduce the occurrence of sputtering, and is applied to the scene of large-area high-speed winding coating, so it has industrial applicability.

Claims (10)

  1. 一种真空镀膜机的蒸发装置,其中,所述蒸发装置包括:An evaporation device of a vacuum coating machine, wherein the evaporation device includes:
    蒸发舟,所述蒸发舟包括有蒸发舟内层、蒸发舟外层和活动盖板,所述蒸发舟内层位于蒸发舟外层与活动盖板之间,所述活动盖板开设有多个蒸发孔,所述蒸发舟内层上开设有与所述蒸发孔对应的蒸发凹槽,蒸发孔与蒸发凹槽均按蜂窝状进行排布;The evaporation boat includes an inner layer of the evaporation boat, an outer layer of the evaporation boat, and a movable cover plate. The inner layer of the evaporation boat is located between the outer layer of the evaporation boat and the movable cover plate. The movable cover plate is provided with a plurality of Evaporation holes, the inner layer of the evaporation boat is provided with evaporation grooves corresponding to the evaporation holes, and the evaporation holes and the evaporation grooves are arranged in a honeycomb shape;
    加热系统,所述加热系统包括多个相对独立的蒸发源,所述蒸发源设置有内坩埚,所述内坩埚嵌套于所述蒸发凹槽内,所述蒸发源能够对放置在所述内坩埚内的物体进行加热;The heating system includes a plurality of relatively independent evaporation sources, the evaporation source is provided with an inner crucible, the inner crucible is nested in the evaporation groove, and the evaporation source can be placed in the inner crucible. The objects in the crucible are heated;
    布气管道,所述布气管道设置在于所述蒸发舟上端,所述布气管道开设有进气口和多个出气口,所述进气口连接外部气体源,所述出气口朝向所述蒸发源。An air distribution pipe is arranged at the upper end of the evaporation boat, the air distribution pipe is provided with an air inlet and a plurality of air outlets, the air inlet is connected to an external gas source, and the air outlet faces the Evaporation source.
  2. 如权利要求1中所述的真空镀膜机的蒸发装置,其中:所述蒸发源采用高频感应加热,所述蒸发源包括若干个感应线圈、绝热层、外坩埚,所述内坩埚叠套于所述外坩埚内,且所述绝热层设置于所述内坩埚的侧壁与所述外坩埚的侧壁之间,所述感应线圈设置于所述外坩埚的侧壁与所述蒸发舟内层之间。The evaporation device of the vacuum coating machine according to claim 1, wherein: the evaporation source adopts high-frequency induction heating, and the evaporation source includes a plurality of induction coils, a heat insulation layer, and an outer crucible, and the inner crucible is overlapped with In the outer crucible, and the heat insulating layer is arranged between the side wall of the inner crucible and the side wall of the outer crucible, and the induction coil is arranged in the side wall of the outer crucible and the evaporation boat Between layers.
  3. 如权利要求2中所述的真空镀膜机的蒸发装置,其中:所述蒸发源还包括有调隙垫片,所述调隙垫片位于所述内坩埚与所述绝热层之间。The evaporation device of the vacuum coating machine according to claim 2, wherein: the evaporation source further comprises a gap adjustment gasket, and the gap adjustment gasket is located between the inner crucible and the heat insulating layer.
  4. 如权利要求3所述的真空镀膜机的蒸发装置,其中:所述蒸发源还设置有电极块,所述电极块连接外部交流电源,多个所述感应线圈串联为一组感应线圈组,多组所述感应线圈组相互并联,所述感应线圈组与所述电极块相连,所述感应线圈内部为中空管路,所述中空管路能够循环通入冷却剂进行冷却所述感应线圈。The evaporation device of a vacuum coating machine according to claim 3, wherein: the evaporation source is further provided with an electrode block, the electrode block is connected to an external AC power supply, and a plurality of the induction coils are connected in series to form a group of induction coils, and The induction coil groups are connected in parallel with each other, the induction coil groups are connected to the electrode blocks, the induction coils are internally hollow pipes, and the hollow pipes can circulate a coolant to cool the induction coils .
  5. 如权利要求1中所述的真空镀膜机的蒸发装置,其中:所述蒸发舟内层为电阻加热,所述蒸发源还设置有成对的电极块,所述蒸发舟 位于成对的所述电极块之间且所述蒸发舟内层的端部与所述电极块连接,所述内坩埚与所述蒸发舟内层相互接触。The evaporation device of a vacuum coating machine according to claim 1, wherein: the inner layer of the evaporation boat is resistance heating, the evaporation source is also provided with a pair of electrode blocks, and the evaporation boat is located in the pair of the The electrode blocks and the end of the inner layer of the evaporation boat are connected to the electrode blocks, and the inner crucible and the inner layer of the evaporation boat are in contact with each other.
  6. 如权利要求1-5中任意一项所述的真空镀膜机的蒸发装置,其中:所述蒸发舟外层设置有沟槽,所述活动盖板能够卡持在所述沟槽内。The evaporation device of a vacuum coating machine according to any one of claims 1 to 5, wherein: the outer layer of the evaporation boat is provided with a groove, and the movable cover plate can be clamped in the groove.
  7. 如权利要求1-5中任意一项所述真空镀膜机的蒸发装置,其中:所述布气管道包括依次连通的进气管路、多级分流管路和排气管路,所述排气管路与所述蒸发舟的边缘平行,所述进气口位于所述进气管路上,所述出气口位于所述排气管路上。The evaporation device of the vacuum coating machine according to any one of claims 1 to 5, wherein: the air distribution pipe includes an intake pipe, a multi-stage shunt pipe, and an exhaust pipe that are connected in sequence, and the exhaust pipe The path is parallel to the edge of the evaporation boat, the air inlet is located on the air inlet pipe, and the air outlet is located on the exhaust pipe.
  8. 如权利要求7中所述真空镀膜机的蒸发装置,其中:所述排气管路的轴线所在的水平面与所述出气口的轴线之间呈10°-70°夹角,相邻所述出气口之间的间距相等。The evaporation device of the vacuum coating machine according to claim 7, wherein: the horizontal plane where the axis of the exhaust pipe is located and the axis of the air outlet are at an angle of 10°-70°, adjacent to the outlet The spacing between the air ports is equal.
  9. 如权利要求7中所述的真空镀膜机的蒸发装置,其中:所述排气管路包括多个相对独立的排气支管,所述排气支管均能够与对应的所述分流管路连通,所述排气支管上均开设有多个所述出气口,位于所述排气支管的中部的所述出气口的直径小于位于所述排气支管的两侧的所述出气口的直径,每个所述出气口出气量相等。The evaporation device of a vacuum coating machine according to claim 7, wherein: the exhaust pipe includes a plurality of relatively independent exhaust branch pipes, and the exhaust branch pipes can communicate with the corresponding branch pipes, The exhaust branch pipe is provided with a plurality of the air outlets, and the diameter of the air outlet located in the middle of the exhaust branch pipe is smaller than the diameter of the air outlets located on both sides of the exhaust branch pipe. The air output of each of the air outlets is equal.
  10. 如权利要求1-5中任意一项所述的真空镀膜机的蒸发装置,其中:所述内坩埚的横截面从底部向开口逐渐扩大。The evaporation device of the vacuum coating machine according to any one of claims 1 to 5, wherein: the cross section of the inner crucible gradually expands from the bottom to the opening.
PCT/CN2020/118421 2019-10-30 2020-09-28 Evaporation apparatus of vacuum film-plating machine WO2021082847A1 (en)

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