WO2021079556A1 - Muffler and honeycomb structure for muffler - Google Patents

Muffler and honeycomb structure for muffler Download PDF

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Publication number
WO2021079556A1
WO2021079556A1 PCT/JP2020/023802 JP2020023802W WO2021079556A1 WO 2021079556 A1 WO2021079556 A1 WO 2021079556A1 JP 2020023802 W JP2020023802 W JP 2020023802W WO 2021079556 A1 WO2021079556 A1 WO 2021079556A1
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WIPO (PCT)
Prior art keywords
honeycomb structure
end surface
silencer
cells
face
Prior art date
Application number
PCT/JP2020/023802
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French (fr)
Japanese (ja)
Inventor
由紀夫 宮入
泰之 古田
昌明 桝田
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日本碍子株式会社
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Publication date
Application filed by 日本碍子株式会社 filed Critical 日本碍子株式会社
Priority to JP2021554065A priority Critical patent/JP7518848B2/en
Publication of WO2021079556A1 publication Critical patent/WO2021079556A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N1/00Silencing apparatus characterised by method of silencing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N1/00Silencing apparatus characterised by method of silencing
    • F01N1/02Silencing apparatus characterised by method of silencing by using resonance
    • F01N1/04Silencing apparatus characterised by method of silencing by using resonance having sound-absorbing materials in resonance chambers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/022Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/033Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
    • F01N3/035Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices with catalytic reactors, e.g. catalysed diesel particulate filters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus

Definitions

  • the present invention relates to a silencer and a honeycomb structure for a silencer.
  • Particulate matter such as soot contained in the exhaust gas of automobiles powered by internal combustion engines such as diesel engines and gasoline engines
  • PM internal combustion engines
  • the exhaust system of the automobile is provided with a dust collecting filter for collecting PM.
  • the internal combustion engine since the internal combustion engine generates an exhaust noise when exhausting the exhaust gas to the outside and also generates an intake noise when sucking air into the intake pipe, these intake and exhaust noises are generated in the exhaust system of the automobile.
  • a silencer hereinafter, also referred to as “muffler” for reduction is provided.
  • the exhaust gas contains harmful substances such as NOx, CO and HC
  • the exhaust system of the automobile is provided with a catalytic converter for reducing the amount of these harmful substances.
  • a silencer those having various structures are known.
  • the structure of the simplest silencer is simply a simple tube attached, but in order to enhance the silencer effect, the following methods (a) to (e) and methods of combining these are known.
  • Patent Documents 1 and 2). (A) Partially widen the cross-sectional area of the flow path of the silencer. (B) Inside the silencer, a double structure is provided through a pipe with a small hole called a punching pipe. (C) The inner wall of the silencer tube is provided with irregularities. (D) The silencer is provided with a structure (baffle) that serves as a barrier. (E) The internal space of the silencer is filled with a sound-absorbing material or structure. Further, in order to further enhance the muffling effect of the muffler, a plurality of mufflers may be provided in the exhaust system.
  • the present invention has been made to solve the above problems, and is a silencer and a honeycomb structure for a silencer, which have a good sound deadening function and can also have a function as a dust collecting filter or a catalytic converter. The purpose is to provide.
  • the present inventors have determined the effective flow path direction lengths of a plurality of cells for a honeycomb structure applicable to a dust collecting filter or a catalytic converter. It has been found that a good sound deadening function can be obtained in addition to the function of a dust collecting filter or a catalytic converter by controlling the non-uniformity, and the present invention has been completed.
  • the present invention is a silencer having a honeycomb structure inside a metal can.
  • the honeycomb structure A honeycomb structure having a outer peripheral wall and a porous partition wall provided inside the outer peripheral wall and partitioning a plurality of cells serving as a flow path for a fluid extending from a first end face to a second end face. It has a mesh sealing portion provided on at least one of the first end surface and the second end surface of the plurality of cells. It is a silencer having a non-uniform length in the effective flow path direction in the plurality of cells.
  • the present invention is a honeycomb structure portion having a porous partition wall provided inside the outer peripheral wall and the outer peripheral wall and partitioning a plurality of cells serving as a flow path of a fluid extending from a first end face to a second end face.
  • a honeycomb structure for a silencer which has a sealing portion provided on at least one of the first end surface and the second end surface of the plurality of cells, and has a non-uniform length in the effective flow path direction in the plurality of cells.
  • the body is a honeycomb structure portion having a porous partition wall provided inside the outer peripheral wall and the outer peripheral wall and partitioning a plurality of cells serving as a flow path of a fluid extending from a first end face to a second end face.
  • a silencer and a honeycomb structure for a silencer which have a good sound deadening function and can also have a function as a dust collecting filter or a catalytic converter.
  • the silencer according to the embodiment of the present invention includes a honeycomb structure inside a metal can.
  • the metal can is not particularly limited as long as it has a structure capable of providing a honeycomb structure inside, and a structure known in the art can be adopted.
  • the honeycomb structure includes a honeycomb structure portion provided on the outer peripheral wall and inside the outer peripheral wall, and having a porous partition wall for partitioning a plurality of cells serving as a flow path for a fluid extending from the first end face to the second end face.
  • a honeycomb structure having a mesh sealing portion provided on at least one of a first end face and a second end face of a plurality of cells is provided. Since this honeycomb structure is used for a silencer, it can be referred to as a honeycomb structure for a silencer.
  • FIG. 1 is a schematic view of a honeycomb structure used in the silencer according to the embodiment of the present invention.
  • A is a cross-sectional view parallel to the direction in which the cells of the honeycomb structure extend
  • B and C are end views of the first end face and the second end face perpendicular to the direction in which the cells of the honeycomb structure of A extend, respectively. is there.
  • the honeycomb structure 1 is provided inside the outer peripheral wall 2 and the outer peripheral wall 2, and serves as a flow path for a fluid extending from the first end surface 3a to the second end surface 3b.
  • the honeycomb structure portion 6 has a porous partition wall 5 for partitioning the cell 4 and a mesh sealing portion 7 provided on at least one of the first end surface 3a and the second end surface 3b of the plurality of cells 4.
  • the first end surface 3a is the fluid inflow side
  • the second end surface 3b is the fluid outflow side.
  • the sealing portion 7 has a non-uniform length L in the effective flow path direction in the plurality of cells 4.
  • the "effective flow path direction length L” means the length of the fluid flow path (cell 4) excluding the sealing portion 7 in the same cell. Since the frequency of the intake / exhaust sound attenuated in the honeycomb structure 1 depends on the length of the flow path (cell 4) through which the intake / exhaust sound passes together with the exhaust gas, the length in the effective flow path direction in the plurality of cells 4 By making L non-uniform, intake and exhaust sounds of various frequencies can be attenuated. Therefore, by using the honeycomb structure 1 having such a non-uniform length L in the effective flow path direction for the silencer, the sound deadening effect can be improved.
  • the ratio of the maximum value L max (L max / L min ) to the minimum value L min of the effective flow path direction length L is preferably 1.25 or more, more preferably 1.30 or more. ..
  • the upper limit of L max / L min is not particularly limited, but is generally 2.0 or less, preferably 1.9 or less.
  • the cell 4 in which the second end surface 3b is opened and the first end surface 3a is provided with the sealing portion 7 and the first end surface 3a are open.
  • the cells 4 provided with the sealing portions 7 on the second end surface 3b may be alternately arranged in a staggered manner. With such an arrangement, it is possible to achieve both a muffling function and a function as a dust collecting filter in a well-balanced manner.
  • the exhaust gas when the exhaust gas is supplied, the exhaust gas is internally provided from the first end surface 3a of the honeycomb structure 1 in which the sealing portion 7 is not provided. Inflow. Then, the exhaust gas passes through the porous partition wall 5 and is discharged from the second end surface 3b in which the sealing portion 7 is not provided. In this way, when the exhaust gas passes through the inside of the honeycomb structure 1, the intake / exhaust sounds of various frequencies can be attenuated. Further, when the exhaust gas passes through the inside of the honeycomb structure 1, the PM contained in the exhaust gas is captured by the partition wall 5, so that the honeycomb structure 1 can function as a dust collecting filter.
  • the catalyst when the catalyst is supported on the partition wall 5, when the exhaust gas passes through the inside of the honeycomb structure 1, harmful substances such as NOx, CO and HC contained in the exhaust gas are purified by the catalyst, so that the catalyst is used. It can also function as a converter.
  • the central regions of the first end surface 3a and the second end surface 3b have a staggered arrangement, and in the outer peripheral region located on the outer peripheral side of the central region, the first end surfaces 3a and the first end surface 3a and the first of the plurality of cells 4 are arranged.
  • the structure may have a structure in which the sealing portions 7 are provided on at least one of the two end faces 3b. With such a structure, the cross-sectional area of the flow path of the intake / exhaust sound that enters from the first end surface 3a of the honeycomb structure 1 together with the exhaust gas and passes through the second end surface 3b is the second end surface of the honeycomb structure 1. Since it suddenly expands when it passes through 3b, the muffling effect can be improved.
  • FIGS. 2 to 4 Specific examples (schematic views) of the honeycomb structure 1 having the above structure are shown in FIGS. 2 to 4.
  • A is a cross-sectional view parallel to the direction in which the cell 4 of the honeycomb structure 1 extends
  • B and C are first units perpendicular to the direction in which the cell 4 of the honeycomb structure 1 of A extends. It is an end view of the end face and the second end face.
  • the entire region of the first end surface 3a and the central region of the second end surface 3b have a staggered arrangement, and the honeycomb structure 1 is located on the outer peripheral side of the central region of the second end surface 3b. Sealing portions 7 are provided in all of the plurality of cells 4 in the located outer peripheral region.
  • the cross-sectional area of the flow path of the intake / exhaust sound entering from the first end surface 3a and passing through the second end surface 3b is sharply reduced immediately before the second end surface 3b. Then, it expands rapidly immediately after the second end surface 3b.
  • the honeycomb structure 1 shown by A to C in FIG. 3 has a staggered arrangement.
  • the central region of the first end surface 3a has a staggered arrangement
  • the sealing portions 7 are provided in all of the plurality of cells 4 in the outer peripheral region located on the outer peripheral side of the central region of the first end surface 3a. It may have no structure.
  • the cross-sectional area of the flow path of the intake / exhaust sound entering from the first end surface 3a and passing through the second end surface 3b is sharply reduced immediately before the second end surface 3b. Then, it expands rapidly immediately after the second end surface 3b.
  • the central region of the first end surface 3a has a staggered arrangement, and the outer peripheral region is located on the outer peripheral side of the central region of the first end surface 3a.
  • the structure may be such that all of the plurality of cells 4 in the above are provided with the sealing portions 7.
  • the cross-sectional area of the flow path of the intake / exhaust sound that enters from the first end surface 3a and passes through the second end surface 3b suddenly passes when it passes through the first end surface 3a. It is further reduced immediately before the second end surface 3b, and rapidly expanded immediately after the second end surface 3b.
  • the dotted line is the boundary line between the central region and the outer peripheral region on the first end surface 3a and the second end surface 3b, the inside of the dotted line represents the central region, and the outside of the dotted line represents the outer peripheral region. Therefore, in the present specification, the "outer peripheral region” means a region near the outer peripheral wall 2 when observing the first end surface 3a and the second end surface 3b, and the "central region” is more than the outer peripheral region. It means the inner area.
  • the size of the central region of the first end surface 3a and the second end surface 3b is not particularly limited, but the area of the second end surface 3b is from the viewpoint of sufficiently ensuring the sound deadening effect due to the rapid expansion of the flow path cross-sectional area of the intake and exhaust sounds. It is preferable to determine the area of the central region in the second end surface 3b according to the above. Specifically, the area of the second end surface 3b is preferably 1.1 times or more, and preferably 1.3 times or more, the area of the central region of the second end surface 3b. By controlling the area to such an area, it is possible to sufficiently obtain a muffling effect due to a rapid expansion of the flow path cross-sectional area of intake / exhaust sound.
  • the upper limit of the magnification of the area of the second end surface 3b with respect to the area of the central region of the second end surface 3b is not particularly limited, but is generally 3.0 times or less, preferably 2.5 times or less.
  • the shape of the honeycomb structure 6 is not particularly limited, and may be an elliptical column, a quadrangular column, another polygonal column, or the like, in addition to the cylinder illustrated above.
  • the shape of the cell 4 is not particularly limited, and on the end faces of the first end face 3a and the second end face 3b, in addition to the quadrangle exemplified above, a circle, an ellipse, a triangle, a hexagon, or another polygon may be used. May be good.
  • the cell density of the honeycomb structure portion 6 is not particularly limited, but is preferably 5 to 320 cells / cm 2 , more preferably 10 to 300 cells / cm 2 , and even more preferably 10 to 300 cells / cm 2 in the first end surface 3a and the second end surface 3b. 20-250 cells / cm 2 .
  • the cell density is not particularly limited, but is preferably 5 to 320 cells / cm 2 , more preferably 10 to 300 cells / cm 2 , and even more preferably 10 to 300 cells / cm 2 in the first end surface 3a and the second end surface 3b. 20-250 cells / cm 2 .
  • the thickness of the partition wall 5 is not particularly limited, but is preferably 0.1 to 1.0 mm, more preferably 0.2 to 0.6 mm. By setting the thickness of the partition wall 5 to 0.1 mm or more, the mechanical strength of the honeycomb structure 1 can be made sufficient. Further, by setting the thickness of the partition wall 5 to 1.0 mm or less, it is possible to suppress an increase in pressure loss due to a decrease in the opening area.
  • the thickness of the outer peripheral wall 2 is not particularly limited, but is preferably larger than the thickness of the partition wall 5. With such a configuration, it is possible to suppress destruction (for example, cracks, cracks, etc.) due to an external impact or the like. Specifically, the thickness of the outer peripheral wall 2 is preferably 0.3 mm to 10 mm, more preferably 0.5 mm to 5 mm, and even more preferably 1 mm to 3 mm.
  • the partition wall 5 and the outer peripheral wall 2 are mainly composed of ceramics.
  • “having ceramics as a main component” means that the mass ratio of ceramics to the mass of all components is 50% by mass or more.
  • ceramics include cordierite, mullite, silicon nitride, silicon carbide, aluminum titanate and the like. These can be used alone or in combination of two or more. By using such a material, characteristics such as mechanical strength and heat resistance of the honeycomb structure 1 can be ensured.
  • the partition wall 5 has a porosity of preferably 25% or more, more preferably 30% or more, still more preferably 35% or more. By setting the porosity in such a range, it is possible to secure the ease of flow (filtration rate) of the exhaust gas passing through the partition wall 5 of the honeycomb structure 1.
  • the upper limit of the porosity of the partition wall 5 is not particularly limited, but is generally 50% or less, preferably 45% or less. By setting the porosity in such a range, it is possible to suppress an increase in the pressure loss of the honeycomb structure 1.
  • the term "porosity" as used herein means a porosity measured by the mercury intrusion method in accordance with JIS R1655: 2003.
  • the partition wall 5 has an average pore diameter of preferably 5 ⁇ m, more preferably 7 ⁇ m or more.
  • the average pore diameter of the honeycomb structure 1 is preferably 25 ⁇ m or less, more preferably 20 ⁇ m or less.
  • the "average pore diameter" means the pore diameter at an integrated value of 50% in the pore distribution obtained by the mercury intrusion method in accordance with JIS R1655: 2003.
  • a surface layer having an average pore diameter of 5 ⁇ m or less may be provided on the surface of the partition wall 5.
  • the surface layer having such an average pore diameter it is possible to obtain a muffling effect by expanding the flow path cross-sectional area of the intake / exhaust sound even when the exhaust gas passes through the surface layer.
  • the surface layer preferably contains ceramics as a main component, and the same type of ceramics as the ceramics used for the partition wall 5 can be used.
  • the average pore diameter of the surface layer can be controlled by adjusting the particle size of the ceramic powder as a raw material, the type of binder, and the like.
  • the catalyst When a surface layer is formed on the surface of the partition wall 5 or the surface of the partition wall 5, the catalyst may be supported on the surface of the surface layer. By supporting the catalyst, harmful substances such as NOx, CO and HC contained in the exhaust gas can be purified, so that the function as a catalytic converter can be obtained.
  • a catalyst known in the art can be used as the catalyst. Examples of the catalyst include a three-way catalyst for purifying exhaust gas from a gasoline engine, an oxidation catalyst for purifying exhaust gas from a gasoline engine or a diesel engine, an SCR catalyst for purifying NOx selective reduction, and the like.
  • precious metals platinum, rhodium, palladium, ruthenium, indium, silver, and gold
  • Samalium, bismuth, and barium preferably containing at least one element selected from the group.
  • the above element may be contained as a simple substance of a metal, a metal oxide, or another metal compound.
  • the amount of the catalyst (catalyst metal + carrier) supported is not particularly limited, but is preferably 10 to 400 g / L.
  • the amount of the catalyst supported is not particularly limited, but is preferably 0.1 to 5 g / L.
  • the carrier is a carrier on which the catalyst metal is supported.
  • the carrier one containing at least one selected from the group consisting of alumina, ceria, and zirconia can be used.
  • the method for producing the honeycomb structure 1 is not particularly limited, and the honeycomb structure 1 can be manufactured according to a method known in the art.
  • the honeycomb structure 1 can be manufactured as follows. First, the clay containing the ceramic powder is extruded into a desired shape to prepare a honeycomb molded body. At this time, the shape and density of the cell 4, the shape and thickness of the partition wall 5 and the outer peripheral wall 2 can be controlled by selecting an appropriate shape of the base and jig.
  • the ceramic powder the above-mentioned ceramic powder, the raw material powder that becomes the above-mentioned ceramic after firing (for example, a cordierite raw material) and the like can be used.
  • the clay can contain a binder, a pore-forming agent, a dispersant, water, an organic solvent and the like.
  • the honeycomb structure portion 6 can be obtained by drying and firing the obtained honeycomb molded body.
  • the drying method is not particularly limited, and conventionally known drying methods such as hot air drying, microwave drying, dielectric drying, vacuum drying, vacuum drying, and freeze drying can be used. Among these, a drying method that combines hot air drying and microwave drying or dielectric drying is preferable in that the entire honeycomb molded body can be dried quickly and uniformly.
  • the honeycomb structure 6 is sealed.
  • the sealing may be performed before the honeycomb molded body is fired.
  • the sealing can be performed according to the conventional method of filling the sealing material.
  • a thin film film having an opening corresponding to the cell 4 of the end faces (first end face 3a and second end face 3b) of the honeycomb structure portion 6 on which the mesh sealing portion 7 is to be formed is attached.
  • the end face of the honeycomb structure portion 6 is immersed in a slurry-like eye-sealing material, and the eye-sealing material is allowed to enter the cell 4 of the honeycomb structure portion 6 which is not blocked by the thin film. It is possible to form the eye-sealing portion 7 filled with.
  • the length of the sealing portion 7 in the cell direction can be adjusted by immersing the end face of the honeycomb structure portion 6 in the sealing material. That is, in order to form the eye-sealing portion 7 so that the length L in the effective flow path direction in the plurality of cells 4 is non-uniform, thin film films having two or more types of opening patterns are prepared, and these thin films are prepared. The film may be sequentially used to change the depth at which the end face of the honeycomb structure 6 is immersed in the sealing material. As another method, by adjusting the area of the film opening, the sealing portion 7 can be formed so that the length L in the effective flow path direction in the plurality of cells 4 becomes non-uniform.
  • the amount of the eye-sealing material flowing into the cell 4 can be reduced, so that the eye-sealing portion 7 having a short cell-direction length is formed. can do. Therefore, by making the area of the film opening non-uniform, it is possible to form the eye-sealing portions 7 having non-uniform cell-direction lengths in the plurality of cells 4.
  • the silencer according to the embodiment of the present invention may include a tubular member in addition to the honeycomb structure 1.
  • FIG. 5 shows a cross-sectional view parallel to the axial direction of the tubular member of the silencer having such a structure.
  • the silencer 100 is fitted to the honeycomb structure 1 and the outer peripheral surface of the outer peripheral wall 2 of the honeycomb structure 1 and is axially outside the second end surface 3b which is the outflow side of the fluid. It is provided with a tubular member 10 having a portion extended to the honeycomb.
  • the flow path cross-sectional area of the intake / exhaust sound passing through the second end surface 3b of the honeycomb structure 1 is expanded to the inner diameter of the tubular member 10, so that the sound deadening effect can be improved.
  • the tubular member 10 preferably has a structure in which a portion extending outward in the axial direction from the second end surface 3b of the honeycomb structure 1 has an enlarged diameter.
  • FIG. 6 shows a cross-sectional view of the honeycomb structure 1 of the silencer 100 having such a structure parallel to the axial direction.
  • "a portion of the tubular member 10 extending axially outward from the second end surface 3b of the honeycomb structure 1" is the first portion of the honeycomb structure 1 in the axial direction of the tubular member 10. 2 It means a portion having a length from the end surface 3b to 1/2 of the axial length of the honeycomb structure 1. As shown in FIG.
  • the tubular member 10 in the silencer 100 has a structure in which a portion extending outward in the axial direction from the second end surface 3b of the honeycomb structure 1 has an enlarged diameter.
  • the cross-sectional area of the flow path of the intake / exhaust sound that has passed through the second end surface 3b of the honeycomb structure 1 is further expanded, so that the sound deadening effect can be further improved.
  • the maximum inner diameter of the portion of the tubular member 10 extending outward in the axial direction from the second end surface 3b of the honeycomb structure 1 is 1.1 times or more the area of the second end surface 3b of the honeycomb structure 1. It is preferable, and it is more preferable that it is 1.3 times or more. With such a configuration, it is possible to stably obtain a muffling effect due to a rapid expansion of the flow path cross-sectional area of the intake / exhaust sound passing through the second end surface 3b of the honeycomb structure 1.
  • the material of the tubular member 10 is not particularly limited, but for example, stainless steel, titanium alloy, copper alloy, aluminum alloy, brass and the like can be used. Among these, stainless steel is preferable because of its high durability and reliability and low cost.
  • the silencer 100 having the above structure can be manufactured according to a method known in the art.
  • the silencer 100 can be manufactured by fitting the tubular member 10 to the outer peripheral surface of the outer peripheral wall 2 of the honeycomb structure 1.
  • the fitting method is not particularly limited, but brazing, welding, diffusion joining and the like can be used in addition to the fixing method by fitting such as clearance fitting, tightening fitting and shrink fitting.
  • the silencer 100 may further include a fibrous sound absorbing material in addition to the metal can, the honeycomb structure 1 and the tubular member 10.
  • FIG. 7 shows a cross-sectional view of the tubular member 10 of the silencer 100 having such a structure parallel to the axial direction.
  • the silencer 100 includes a fibrous sound absorbing material 20 provided on the outer peripheral side of the tubular member 10 and held between the tubular member 10 and the metal can 30.
  • the tubular member 10 is provided with a small hole 11, and the sound deadening effect can be enhanced by allowing the fibrous sound absorbing material 20 to absorb the intake / exhaust sound through the small hole 11.
  • the position of the small hole 11 provided in the tubular member 10 is not particularly limited, but is axially outward from the first end surface 3a and / or the second end surface 3b of the honeycomb structure 1 in the axial direction of the tubular member 10. It is preferably a stretched portion.
  • the shape and size of the small holes 11 provided in the tubular member 10 are not particularly limited, and may be appropriately adjusted according to the type of the fibrous sound absorbing material 20 to be used.
  • the fibrous sound absorbing material 20 is not particularly limited, but for example, glass wool, rock wool, steel wool, ceramic wool, or the like can be used. Among these, glass wool is preferable from the viewpoint of sound deadening effect.
  • the metal can 30 forms a space with the tubular member 10 and holds the fibrous sound absorbing material 20 housed in the space.
  • the shape of the metal can 30 is not particularly limited as long as it can hold the fibrous sound absorbing material 20 provided on the outer peripheral side of the tubular member 10, and may be, for example, tubular.
  • the material of the metal can 30 is not particularly limited, and the same material as that of the tubular member 10 can be used.
  • the silencer 100 according to the embodiment of the present invention may further include a silencer structure known in the art in addition to the above structure.
  • a silencer structure known in the art in addition to the above structure.
  • Examples of the known sound deadening structure include a structure (jammer plate) that serves as a barrier.
  • the silencer 100 having the above structure can be manufactured according to a method known in the art.
  • the silencer 100 is manufactured by arranging the fibrous sound absorbing material 20 on the outer peripheral side of the tubular member 10 fitted to the outer peripheral surface of the outer peripheral wall 2 of the honeycomb structure 1 and accommodating it in the metal can 30. can do.
  • the tubular member 10 and the metal can 30 may be joined by welding or the like.
  • Example 1 A cylindrical honeycomb molded body was obtained by throwing clay containing a cordierite-forming raw material into an extrusion molding machine and extrusion molding. Next, after drying the honeycomb molded product, both end faces were cut so as to have a predetermined size to obtain a honeycomb dried product. Next, using a plurality of thin films having different opening patterns and a sealing material containing the same components as the honeycomb molded body, the cells on the first end face and the second end face of the honeycomb dried body are sealed with each other.
  • a honeycomb structure made of cordierite was obtained by firing at 1400 ° C.
  • the depth of immersion in the sealing material is the same, and in the sealing of the cells on the second end face, the depth of immersion in the sealing material is changed. went.
  • the mesh sealing has a structure shown in FIGS. 1A to 1C, that is, a cell in which the mesh sealing portion is provided only on the first end surface and a cell in which the mesh sealing portion is provided only on the second end surface. And were arranged alternately in a staggered pattern.
  • the obtained honeycomb structure had a diameter of 118.4 mm, an axial length of 127 mm, a partition wall thickness of 0.3 mm, an outer peripheral wall thickness of 1 mm, a cell density of 31 cells / cm 2 , a porosity of the partition wall of 48%, and an average pore diameter. It was 12 ⁇ m. The porosity and the average pore diameter were measured by the above method.
  • Example 2 Similar to Example 1 except that when sealing a part of the cells on the second end face of the honeycomb dried body, the depth of immersing the second end face of the honeycomb dried body in the eye sealing material was increased. A honeycomb structure was obtained.
  • Example 1 A honeycomb structure was obtained in the same manner as in Example 1 except that the seal was not sealed.
  • Comparative Example 2 When sealing the cells of the first end face and the second end face of the honeycomb dried body, the depth of immersing the first end face and the second end face of the honeycomb dried body in the eye sealing material was the same. A honeycomb structure was obtained in the same manner as in Example 1.
  • the honeycomb structures obtained in the above Examples and Comparative Examples are cut in parallel with the extending direction of the cells of the honeycomb structure, and then the cross-sectional observation thereof is performed to observe the first end surface and the second end surface of the plurality of cells.
  • the length of the sealing portion formed in the cell in the cell direction was measured, and the length in the effective flow path direction was calculated.
  • the silencer using the honeycomb structures of Examples 1 and 2 having non-uniform lengths in the effective flow path direction did not form a mesh sealing portion, and the honeycomb structure of Comparative Example 1 was not formed.
  • the sound pressure level was lower than that of the silencer using the body and the silencer using the honeycomb structure of Comparative Example 2 having a uniform length in the effective flow path direction.
  • a muffler and a honeycomb structure for a muffler that have a good muffling function and can also have a function as a dust collecting filter or a catalytic converter. Can be done.

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Abstract

Provided is a muffler comprising a honeycomb structure 1 inside a metal can. The honeycomb structure 1 comprises a honeycomb structure section 6 and mesh sealing parts 7. The honeycomb structure section 6 has an outer circumferential wall 2, and porous partitioning walls 5 that are provided inside the outer circumferential wall 2 and that demarcate and form a plurality of cells 4 which serve as fluid channels extending from a first end face 3a to a second end face 3b. The mesh sealing parts 7 are provided at the first end surface 3a and/or the second end surface 3b of the plurality of cells 4, and the effective lengths of the plurality of cells 4 are uneven in the flow channel direction.

Description

消音器及び消音器用ハニカム構造体Honeycomb structure for silencer and silencer
 本発明は、消音器及び消音器用ハニカム構造体に関する。 The present invention relates to a silencer and a honeycomb structure for a silencer.
 ディーゼルエンジン、ガソリンエンジンなどの内燃機関を動力源とする自動車の排気ガスに含まれるススなどの粒子状物質(以下、「パティキュレートマター」又は「PM」ともいう)は、人体の健康に影響を与えるため、自動車の排気系には、PMを捕集するための集塵用フィルタが設けられている。また、内燃機関は、排気ガスを外部へ排出する際に排気音を発生させるとともに、吸気管に空気を吸い込む際に吸気音を発生させるため、自動車の排気系には、これらの吸排気音を低減するための消音器(以下、「マフラー」ともいう)が設けられている。さらに、排気ガスには、NOx、CO及びHCなどの有害物質が含まれているため、自動車の排気系には、これらの有害物質の量を低減するための触媒コンバータが設けられている。 Particulate matter such as soot contained in the exhaust gas of automobiles powered by internal combustion engines such as diesel engines and gasoline engines (hereinafter, also referred to as "particulate matter" or "PM") affects human health. In order to provide this, the exhaust system of the automobile is provided with a dust collecting filter for collecting PM. Further, since the internal combustion engine generates an exhaust noise when exhausting the exhaust gas to the outside and also generates an intake noise when sucking air into the intake pipe, these intake and exhaust noises are generated in the exhaust system of the automobile. A silencer (hereinafter, also referred to as "muffler") for reduction is provided. Further, since the exhaust gas contains harmful substances such as NOx, CO and HC, the exhaust system of the automobile is provided with a catalytic converter for reducing the amount of these harmful substances.
 消音器としては、様々な構造のものが知られている。最も簡単な消音器の構造は単純な管を取り付けただけのものであるが、消音効果を高めるために下記の(a)~(e)のような方法や、これらを組み合わせる方法が知られている(特許文献1及び2)。
 (a)消音器の流路の断面積を部分的に広くする。
 (b)消音器の内部に、パンチングパイプと呼ばれる小孔が開いた管を通した二重構造を設ける。
 (c)消音器の管の内壁に凹凸を設ける。
 (d)消音器に障壁となる構造(バッフル)を設ける。
 (e)消音器の内部空間に吸音性を有する材料又は構造物を充填する。
 また、消音器の消音効果を更に高めるために、複数の消音器が排気系に設けられる場合もある。
As a silencer, those having various structures are known. The structure of the simplest silencer is simply a simple tube attached, but in order to enhance the silencer effect, the following methods (a) to (e) and methods of combining these are known. (Patent Documents 1 and 2).
(A) Partially widen the cross-sectional area of the flow path of the silencer.
(B) Inside the silencer, a double structure is provided through a pipe with a small hole called a punching pipe.
(C) The inner wall of the silencer tube is provided with irregularities.
(D) The silencer is provided with a structure (baffle) that serves as a barrier.
(E) The internal space of the silencer is filled with a sound-absorbing material or structure.
Further, in order to further enhance the muffling effect of the muffler, a plurality of mufflers may be provided in the exhaust system.
実開平2-22614号公報Jikkenhei 2-22614 特開平11-223119号公報Japanese Unexamined Patent Publication No. 11-223119
 近年、コンパクトな排気系への要求が高まっており、排気系に設けられる消音器、集塵用フィルタ及び触媒コンバータの設置スペースが足りなくなっている。
 本発明は、上記の課題を解決するためになされたものであり、消音機能が良好であるとともに、集塵用フィルタ又は触媒コンバータとしての機能も有することが可能な消音器及び消音器用ハニカム構造体を提供することを目的とする。
In recent years, the demand for a compact exhaust system has been increasing, and the space for installing a silencer, a dust collector filter, and a catalytic converter provided in the exhaust system has become insufficient.
The present invention has been made to solve the above problems, and is a silencer and a honeycomb structure for a silencer, which have a good sound deadening function and can also have a function as a dust collecting filter or a catalytic converter. The purpose is to provide.
 本発明者らは、上記の課題を解決するために鋭意研究を行った結果、集塵用フィルタ又は触媒コンバータに適用可能なハニカム構造体に対して、複数のセルの有効流路方向長さを不均一に制御することにより、集塵用フィルタ又は触媒コンバータの機能に加えて良好な消音機能が得られることを見出し、本発明を完成するに至った。 As a result of diligent research to solve the above problems, the present inventors have determined the effective flow path direction lengths of a plurality of cells for a honeycomb structure applicable to a dust collecting filter or a catalytic converter. It has been found that a good sound deadening function can be obtained in addition to the function of a dust collecting filter or a catalytic converter by controlling the non-uniformity, and the present invention has been completed.
 すなわち、本発明は、金属缶の内部にハニカム構造体を備える消音器であって、
 前記ハニカム構造体が、
 外周壁、及び前記外周壁の内側に設けられ、第1端面から第2端面まで延びる流体の流路となる複数のセルを区画形成する多孔質の隔壁を有するハニカム構造部と、
 複数の前記セルの前記第1端面及び前記第2端面の少なくとも一方に設けられた目封止部と
を有し、
 複数の前記セルにおける有効流路方向長さが不均一である、消音器である。
That is, the present invention is a silencer having a honeycomb structure inside a metal can.
The honeycomb structure
A honeycomb structure having a outer peripheral wall and a porous partition wall provided inside the outer peripheral wall and partitioning a plurality of cells serving as a flow path for a fluid extending from a first end face to a second end face.
It has a mesh sealing portion provided on at least one of the first end surface and the second end surface of the plurality of cells.
It is a silencer having a non-uniform length in the effective flow path direction in the plurality of cells.
 また、本発明は、外周壁、及び前記外周壁の内側に設けられ、第1端面から第2端面まで延びる流体の流路となる複数のセルを区画形成する多孔質の隔壁を有するハニカム構造部と、
 複数の前記セルの前記第1端面及び前記第2端面の少なくとも一方に設けられた目封止部と
を有し、複数の前記セルにおける有効流路方向長さが不均一である消音器用ハニカム構造体である。
Further, the present invention is a honeycomb structure portion having a porous partition wall provided inside the outer peripheral wall and the outer peripheral wall and partitioning a plurality of cells serving as a flow path of a fluid extending from a first end face to a second end face. When,
A honeycomb structure for a silencer, which has a sealing portion provided on at least one of the first end surface and the second end surface of the plurality of cells, and has a non-uniform length in the effective flow path direction in the plurality of cells. The body.
 本発明によれば、消音機能が良好であるとともに、集塵用フィルタ又は触媒コンバータとしての機能も有することが可能な消音器及び消音器用ハニカム構造体を提供することができる。 According to the present invention, it is possible to provide a silencer and a honeycomb structure for a silencer, which have a good sound deadening function and can also have a function as a dust collecting filter or a catalytic converter.
本発明の実施形態に係る消音器に用いられるハニカム構造体の概略図である。It is the schematic of the honeycomb structure used for the silencer which concerns on embodiment of this invention. 本発明の実施形態に係る消音器に用いられるハニカム構造体の概略図である。It is the schematic of the honeycomb structure used for the silencer which concerns on embodiment of this invention. 本発明の実施形態に係る消音器に用いられるハニカム構造体の概略図である。It is the schematic of the honeycomb structure used for the silencer which concerns on embodiment of this invention. 本発明の実施形態に係る消音器に用いられるハニカム構造体の概略図である。It is the schematic of the honeycomb structure used for the silencer which concerns on embodiment of this invention. 本発明の実施形態に係る消音器のハニカム構造体の軸方向に平行な断面図である。It is sectional drawing parallel to the axial direction of the honeycomb structure of the silencer which concerns on embodiment of this invention. 本発明の実施形態に係る消音器のハニカム構造体の軸方向に平行な断面図である。It is sectional drawing parallel to the axial direction of the honeycomb structure of the silencer which concerns on embodiment of this invention. 本発明の実施形態に係る消音器のハニカム構造体の軸方向に平行な断面図である。It is sectional drawing parallel to the axial direction of the honeycomb structure of the silencer which concerns on embodiment of this invention.
 以下、本発明の実施形態について、図面を参照しながら具体的に説明する。本発明は以下の実施形態に限定されるものではなく、本発明の趣旨を逸脱しない範囲で、当業者の通常の知識に基づいて、以下の実施形態に対し変更、改良などが適宜加えられたものも本発明の範囲に入ることが理解されるべきである。 Hereinafter, embodiments of the present invention will be specifically described with reference to the drawings. The present invention is not limited to the following embodiments, and changes, improvements, etc. have been appropriately added to the following embodiments based on the ordinary knowledge of those skilled in the art without departing from the spirit of the present invention. It should be understood that things also fall within the scope of the present invention.
 本発明の実施形態に係る消音器は、金属缶の内部にハニカム構造体を備える。
 金属缶としては、内部にハニカム構造体を備えることが可能な構造を有するものであれば特に限定されず、当該技術分野において公知の構造を採用することができる。
 ハニカム構造体は、外周壁、及び外周壁の内側に設けられ、第1端面から第2端面まで延びる流体の流路となる複数のセルを区画形成する多孔質の隔壁を有するハニカム構造部と、複数のセルの第1端面及び第2端面の少なくとも一方に設けられた目封止部とを有するハニカム構造体を備える。このハニカム構造体は、消音器に用いられるため、消音器用ハニカム構造体と称することができる。
The silencer according to the embodiment of the present invention includes a honeycomb structure inside a metal can.
The metal can is not particularly limited as long as it has a structure capable of providing a honeycomb structure inside, and a structure known in the art can be adopted.
The honeycomb structure includes a honeycomb structure portion provided on the outer peripheral wall and inside the outer peripheral wall, and having a porous partition wall for partitioning a plurality of cells serving as a flow path for a fluid extending from the first end face to the second end face. A honeycomb structure having a mesh sealing portion provided on at least one of a first end face and a second end face of a plurality of cells is provided. Since this honeycomb structure is used for a silencer, it can be referred to as a honeycomb structure for a silencer.
 図1は、本発明の実施形態に係る消音器に用いられるハニカム構造体の概略図である。Aは、このハニカム構造体のセルが延びる方向に平行な断面図であり、B及びCはそれぞれ、Aのハニカム構造体のセルが延びる方向に垂直な第1端面及び第2端面の端面図である。
 図1のA~Cに示されるように、ハニカム構造体1は、外周壁2、及び外周壁2の内側に設けられ、第1端面3aから第2端面3bまで延びる流体の流路となる複数のセル4を区画形成する多孔質の隔壁5を有するハニカム構造部6と、複数のセル4の第1端面3a及び第2端面3bの少なくとも一方に設けられた目封止部7とを有する。なお、第1端面3aが流体の流入側であり、第2端面3bが流体の流出側である。
FIG. 1 is a schematic view of a honeycomb structure used in the silencer according to the embodiment of the present invention. A is a cross-sectional view parallel to the direction in which the cells of the honeycomb structure extend, and B and C are end views of the first end face and the second end face perpendicular to the direction in which the cells of the honeycomb structure of A extend, respectively. is there.
As shown in FIGS. 1A to 1C, the honeycomb structure 1 is provided inside the outer peripheral wall 2 and the outer peripheral wall 2, and serves as a flow path for a fluid extending from the first end surface 3a to the second end surface 3b. It has a honeycomb structure portion 6 having a porous partition wall 5 for partitioning the cell 4 and a mesh sealing portion 7 provided on at least one of the first end surface 3a and the second end surface 3b of the plurality of cells 4. The first end surface 3a is the fluid inflow side, and the second end surface 3b is the fluid outflow side.
 目封止部7は、複数のセル4における有効流路方向長さLが不均一である。
 ここで、本明細書において「有効流路方向長さL」とは、同一のセルにおいて、目封止部7を除いた流体の流路(セル4)の長さのことを意味する。
 ハニカム構造体1において減衰させる吸排気音の周波数は、排気ガスとともに吸排気音が通過する流路(セル4)の長さに依存しているため、複数のセル4における有効流路方向長さLを不均一とすることにより、様々な周波数の吸排気音を減衰させることができる。そのため、このような不均一な有効流路方向長さLを有するハニカム構造体1を消音器に用いることにより、消音効果を向上させることができる。
The sealing portion 7 has a non-uniform length L in the effective flow path direction in the plurality of cells 4.
Here, in the present specification, the "effective flow path direction length L" means the length of the fluid flow path (cell 4) excluding the sealing portion 7 in the same cell.
Since the frequency of the intake / exhaust sound attenuated in the honeycomb structure 1 depends on the length of the flow path (cell 4) through which the intake / exhaust sound passes together with the exhaust gas, the length in the effective flow path direction in the plurality of cells 4 By making L non-uniform, intake and exhaust sounds of various frequencies can be attenuated. Therefore, by using the honeycomb structure 1 having such a non-uniform length L in the effective flow path direction for the silencer, the sound deadening effect can be improved.
 複数のセル4は、有効流路方向長さLの最小値Lminに対する最大値Lmaxの比(Lmax/Lmin)が、好ましくは1.25以上、より好ましくは1.30以上である。このような範囲にLmax/Lminを制御することにより、様々な周波数の吸排気音を減衰させる効果を安定して高めることができる。
 なお、Lmax/Lminの上限値は、特に限定されないが、一般的に2.0以下、好ましくは1.9以下である。
In the plurality of cells 4, the ratio of the maximum value L max (L max / L min ) to the minimum value L min of the effective flow path direction length L is preferably 1.25 or more, more preferably 1.30 or more. .. By controlling L max / L min within such a range, the effect of attenuating the intake and exhaust sounds of various frequencies can be stably enhanced.
The upper limit of L max / L min is not particularly limited, but is generally 2.0 or less, preferably 1.9 or less.
 ハニカム構造体1は、図1のB及びCに示されるような、第2端面3bが開口して第1端面3aに目封止部7が設けられたセル4と、第1端面3aが開口して第2端面3bに目封止部7が設けられたセル4とが千鳥状となるように交互に配置されている形態とすることができる。このような配置にすることにより、消音機能と集塵用フィルタとしての機能とをバランス良く両立させることができる。 In the honeycomb structure 1, as shown in B and C of FIG. 1, the cell 4 in which the second end surface 3b is opened and the first end surface 3a is provided with the sealing portion 7 and the first end surface 3a are open. Then, the cells 4 provided with the sealing portions 7 on the second end surface 3b may be alternately arranged in a staggered manner. With such an arrangement, it is possible to achieve both a muffling function and a function as a dust collecting filter in a well-balanced manner.
 上記のような構造を有するハニカム構造体1を備える消音器では、排気ガスが供給されると、ハニカム構造体1の目封止部7が設けられていない第1端面3aから排気ガスが内部に流入する。そして、排気ガスは多孔質の隔壁5を通過して目封止部7が設けられていない第2端面3bから排出される。このようにして排気ガスがハニカム構造体1の内部を通過する際に様々な周波数の吸排気音を減衰させることができる。また、排気ガスがハニカム構造体1の内部を通過する際、排気ガスに含まれるPMが隔壁5に捕捉されるため、このハニカム構造体1を集塵用フィルタとして機能させることができる。さらに、隔壁5に触媒を担持させた場合、排気ガスがハニカム構造体1の内部を通過する際に、排気ガスに含まれるNOx、CO及びHCなどの有害物質が触媒によって浄化されるため、触媒コンバータとしても機能させることができる。 In the silencer provided with the honeycomb structure 1 having the above structure, when the exhaust gas is supplied, the exhaust gas is internally provided from the first end surface 3a of the honeycomb structure 1 in which the sealing portion 7 is not provided. Inflow. Then, the exhaust gas passes through the porous partition wall 5 and is discharged from the second end surface 3b in which the sealing portion 7 is not provided. In this way, when the exhaust gas passes through the inside of the honeycomb structure 1, the intake / exhaust sounds of various frequencies can be attenuated. Further, when the exhaust gas passes through the inside of the honeycomb structure 1, the PM contained in the exhaust gas is captured by the partition wall 5, so that the honeycomb structure 1 can function as a dust collecting filter. Further, when the catalyst is supported on the partition wall 5, when the exhaust gas passes through the inside of the honeycomb structure 1, harmful substances such as NOx, CO and HC contained in the exhaust gas are purified by the catalyst, so that the catalyst is used. It can also function as a converter.
 ハニカム構造体1は、第1端面3a及び第2端面3bの中央領域が千鳥状の配置を有するとともに、中央領域の外周側に位置する外周領域において、複数のセル4の第1端面3a及び第2端面3bの少なくとも一方の全てに目封止部7が設けられた構造を有していてもよい。このような構造とすることにより、排気ガスとともにハニカム構造体1の第1端面3aから入って第2端面3bを通過する吸排気音の流路の断面積が、ハニカム構造体1の第2端面3bを通過した時点で急に拡大するため、消音効果を向上させることができる。 In the honeycomb structure 1, the central regions of the first end surface 3a and the second end surface 3b have a staggered arrangement, and in the outer peripheral region located on the outer peripheral side of the central region, the first end surfaces 3a and the first end surface 3a and the first of the plurality of cells 4 are arranged. The structure may have a structure in which the sealing portions 7 are provided on at least one of the two end faces 3b. With such a structure, the cross-sectional area of the flow path of the intake / exhaust sound that enters from the first end surface 3a of the honeycomb structure 1 together with the exhaust gas and passes through the second end surface 3b is the second end surface of the honeycomb structure 1. Since it suddenly expands when it passes through 3b, the muffling effect can be improved.
 上記のような構造を有するハニカム構造体1の具体例(概略図)を図2~4に示す。図2~4において、Aは、ハニカム構造体1のセル4が延びる方向に平行な断面図であり、B及びCはそれぞれ、Aのハニカム構造体1のセル4が延びる方向に垂直な第1端面及び第2端面の端面図である。 Specific examples (schematic views) of the honeycomb structure 1 having the above structure are shown in FIGS. 2 to 4. In FIGS. 2 to 4, A is a cross-sectional view parallel to the direction in which the cell 4 of the honeycomb structure 1 extends, and B and C are first units perpendicular to the direction in which the cell 4 of the honeycomb structure 1 of A extends. It is an end view of the end face and the second end face.
 図2のA~Cで示されるハニカム構造体1は、第1端面3aの全領域及び第2端面3bの中央領域が千鳥状の配置を有するとともに、第2端面3bの中央領域の外周側に位置する外周領域における複数のセル4の全てに目封止部7が設けられている。図2のA~Cで示されるハニカム構造体1は、第1端面3aから入って第2端面3bを通過する吸排気音の流路の断面積が、第2端面3bの直前で急激に縮小し、第2端面3bの直後で急拡大する。
 また、図2のA~Cで示されるハニカム構造体1は、第1端面3aの全領域が千鳥状の配置を有しているが、図3のA~Cで示されるハニカム構造体1のように、第1端面3aの中央領域が千鳥状配置を有し、第1端面3aの中央領域の外周側に位置する外周領域における複数のセル4の全てに目封止部7が設けられていない構造としてもよい。図3のA~Cで示されるハニカム構造体1は、第1端面3aから入って第2端面3bを通過する吸排気音の流路の断面積が、第2端面3bの直前で急激に縮小し、第2端面3bの直後で急拡大する。
 さらに、図4のA~Cで示されるハニカム構造体1のように、第1端面3aの中央領域が千鳥状の配置を有し、第1端面3aの中央領域の外周側に位置する外周領域における複数のセル4の全てに目封止部7が設けられている構造としてもよい。図4のA~Cで示されるハニカム構造体1は、第1端面3aから入って第2端面3bを通過する吸排気音の流路の断面積が、第1端面3aを通過する時点で急激に縮小し、第2端面3bの直前で更に縮小し、第2端面3bの直後で急拡大する。
 なお、上記の図において、点線は、第1端面3a及び第2端面3bにおける中央領域と外周領域との境界線であり、点線の内側が中央領域、点線の外側が外周領域を表す。したがって、本明細書において「外周領域」とは、第1端面3a及び第2端面3bを観察した場合に、外周壁2の近傍領域のことを意味し、「中央領域」とは外周領域よりも内側の領域のことを意味する。
In the honeycomb structure 1 shown by FIGS. 2A to 2C, the entire region of the first end surface 3a and the central region of the second end surface 3b have a staggered arrangement, and the honeycomb structure 1 is located on the outer peripheral side of the central region of the second end surface 3b. Sealing portions 7 are provided in all of the plurality of cells 4 in the located outer peripheral region. In the honeycomb structure 1 shown by FIGS. 2A to 2C, the cross-sectional area of the flow path of the intake / exhaust sound entering from the first end surface 3a and passing through the second end surface 3b is sharply reduced immediately before the second end surface 3b. Then, it expands rapidly immediately after the second end surface 3b.
Further, the honeycomb structure 1 shown by A to C in FIG. 2 has a staggered arrangement in the entire region of the first end surface 3a, but the honeycomb structure 1 shown by A to C in FIG. 3 has a staggered arrangement. As described above, the central region of the first end surface 3a has a staggered arrangement, and the sealing portions 7 are provided in all of the plurality of cells 4 in the outer peripheral region located on the outer peripheral side of the central region of the first end surface 3a. It may have no structure. In the honeycomb structure 1 shown by FIGS. 3A to 3C, the cross-sectional area of the flow path of the intake / exhaust sound entering from the first end surface 3a and passing through the second end surface 3b is sharply reduced immediately before the second end surface 3b. Then, it expands rapidly immediately after the second end surface 3b.
Further, as in the honeycomb structure 1 shown by FIGS. 4A to 4C, the central region of the first end surface 3a has a staggered arrangement, and the outer peripheral region is located on the outer peripheral side of the central region of the first end surface 3a. The structure may be such that all of the plurality of cells 4 in the above are provided with the sealing portions 7. In the honeycomb structure 1 shown by FIGS. 4A to 4C, the cross-sectional area of the flow path of the intake / exhaust sound that enters from the first end surface 3a and passes through the second end surface 3b suddenly passes when it passes through the first end surface 3a. It is further reduced immediately before the second end surface 3b, and rapidly expanded immediately after the second end surface 3b.
In the above figure, the dotted line is the boundary line between the central region and the outer peripheral region on the first end surface 3a and the second end surface 3b, the inside of the dotted line represents the central region, and the outside of the dotted line represents the outer peripheral region. Therefore, in the present specification, the "outer peripheral region" means a region near the outer peripheral wall 2 when observing the first end surface 3a and the second end surface 3b, and the "central region" is more than the outer peripheral region. It means the inner area.
 第1端面3a及び第2端面3bにおける中央領域の大きさは、特に限定されないが、吸排気音の流路断面積の急拡大による消音効果を十分に確保する観点から、第2端面3bの面積に応じて第2端面3bにおける中央領域の面積を決定することが好ましい。具体的には、第2端面3bの面積が、第2端面3bの中央領域の面積の1.1倍以上であることが好ましく、1.3倍以上であることが好ましい。このような面積に制御することにより、吸排気音の流路断面積の急拡大による消音効果を十分に得ることができる。
 なお、第2端面3bの中央領域の面積に対する第2端面3bの面積の倍率の上限は、特に限定されないが、一般的に3.0倍以下、好ましくは2.5倍以下である。
The size of the central region of the first end surface 3a and the second end surface 3b is not particularly limited, but the area of the second end surface 3b is from the viewpoint of sufficiently ensuring the sound deadening effect due to the rapid expansion of the flow path cross-sectional area of the intake and exhaust sounds. It is preferable to determine the area of the central region in the second end surface 3b according to the above. Specifically, the area of the second end surface 3b is preferably 1.1 times or more, and preferably 1.3 times or more, the area of the central region of the second end surface 3b. By controlling the area to such an area, it is possible to sufficiently obtain a muffling effect due to a rapid expansion of the flow path cross-sectional area of intake / exhaust sound.
The upper limit of the magnification of the area of the second end surface 3b with respect to the area of the central region of the second end surface 3b is not particularly limited, but is generally 3.0 times or less, preferably 2.5 times or less.
 ハニカム構造部6の形状としては、特に限定されず、上記で例示した円柱以外に、楕円柱、四角柱又はその他の多角柱などとしてもよい。
 セル4の形状としては、特に限定されず、第1端面3a及び第2端面3bの端面において、上記で例示した四角形以外に、円形、楕円形、三角形、六角形、又はその他の多角形などとしてもよい。
The shape of the honeycomb structure 6 is not particularly limited, and may be an elliptical column, a quadrangular column, another polygonal column, or the like, in addition to the cylinder illustrated above.
The shape of the cell 4 is not particularly limited, and on the end faces of the first end face 3a and the second end face 3b, in addition to the quadrangle exemplified above, a circle, an ellipse, a triangle, a hexagon, or another polygon may be used. May be good.
 ハニカム構造部6のセル密度としては、特に限定されないが、第1端面3a及び第2端面3bにおいて、好ましくは5~320セル/cm2、より好ましくは10~300セル/cm2、更に好ましくは20~250セル/cm2である。セル密度を5セル/cm2以上とすることにより、隔壁5の強度、ひいては柱状のハニカム構造部6自体の強度及び有効GSA(幾何学的表面積)を十分に確保することができる。また、セル密度を320セル/cm2以下とすることにより、圧力損失の増大を抑制することができる。 The cell density of the honeycomb structure portion 6 is not particularly limited, but is preferably 5 to 320 cells / cm 2 , more preferably 10 to 300 cells / cm 2 , and even more preferably 10 to 300 cells / cm 2 in the first end surface 3a and the second end surface 3b. 20-250 cells / cm 2 . By setting the cell density to 5 cells / cm 2 or more, the strength of the partition wall 5, the strength of the columnar honeycomb structure 6 itself, and the effective GSA (geometric surface area) can be sufficiently secured. Further, by setting the cell density to 320 cells / cm 2 or less, an increase in pressure loss can be suppressed.
 隔壁5の厚みは、特に限定されないが、好ましくは0.1~1.0mm、より好ましくは0.2~0.6mmである。隔壁5の厚みを0.1mm以上とすることにより、ハニカム構造体1の機械的強度を十分なものとすることができる。また、隔壁5の厚さを1.0mm以下とすることにより、開口面積の低下によって圧力損失が大きくなることを抑制することができる。
 外周壁2の厚みは、特に限定されないが、隔壁5の厚みよりも大きいことが好ましい。このような構成とすることにより、外部からの衝撃などによる破壊(例えば、ひび、割れなど)を抑制することができる。具体的には、外周壁2の厚みは、好ましくは0.3mm~10mm、より好ましくは0.5mm~5mm、更に好ましくは1mm~3mmである。
The thickness of the partition wall 5 is not particularly limited, but is preferably 0.1 to 1.0 mm, more preferably 0.2 to 0.6 mm. By setting the thickness of the partition wall 5 to 0.1 mm or more, the mechanical strength of the honeycomb structure 1 can be made sufficient. Further, by setting the thickness of the partition wall 5 to 1.0 mm or less, it is possible to suppress an increase in pressure loss due to a decrease in the opening area.
The thickness of the outer peripheral wall 2 is not particularly limited, but is preferably larger than the thickness of the partition wall 5. With such a configuration, it is possible to suppress destruction (for example, cracks, cracks, etc.) due to an external impact or the like. Specifically, the thickness of the outer peripheral wall 2 is preferably 0.3 mm to 10 mm, more preferably 0.5 mm to 5 mm, and even more preferably 1 mm to 3 mm.
 隔壁5及び外周壁2は、セラミックスを主成分とすることが好ましい。ここで、本明細書において「セラミックスを主成分とする」とは、全成分の質量に占めるセラミックスの質量比率が50質量%以上であることをいう。セラミックスの例としては、コージェライト、ムライト、窒化珪素、炭化珪素、チタン酸アルミニウムなどが挙げられる。これらは単独又は2種以上を組み合わせて用いることができる。このような材料を用いることにより、ハニカム構造体1の機械的強度及び耐熱性などの特性を確保することができる。 It is preferable that the partition wall 5 and the outer peripheral wall 2 are mainly composed of ceramics. Here, in the present specification, "having ceramics as a main component" means that the mass ratio of ceramics to the mass of all components is 50% by mass or more. Examples of ceramics include cordierite, mullite, silicon nitride, silicon carbide, aluminum titanate and the like. These can be used alone or in combination of two or more. By using such a material, characteristics such as mechanical strength and heat resistance of the honeycomb structure 1 can be ensured.
 隔壁5は、気孔率が、好ましくは25%以上、より好ましくは30%以上、更に好ましくは35%以上である。このような範囲の気孔率とすることにより、ハニカム構造体1の隔壁5を通過する排気ガスの流れ易さ(ろ過速度)を確保することができる。一方、隔壁5の気孔率の上限は、特に限定されないが、一般的に50%以下、好ましくは45%以下である。このような範囲の気孔率とすることにより、ハニカム構造体1の圧力損失の増大を抑制することができる。
 ここで、本明細書において「気孔率」とは、JIS R1655:2003に準拠し、水銀圧入法によって測定される気孔率を意味する。
The partition wall 5 has a porosity of preferably 25% or more, more preferably 30% or more, still more preferably 35% or more. By setting the porosity in such a range, it is possible to secure the ease of flow (filtration rate) of the exhaust gas passing through the partition wall 5 of the honeycomb structure 1. On the other hand, the upper limit of the porosity of the partition wall 5 is not particularly limited, but is generally 50% or less, preferably 45% or less. By setting the porosity in such a range, it is possible to suppress an increase in the pressure loss of the honeycomb structure 1.
Here, the term "porosity" as used herein means a porosity measured by the mercury intrusion method in accordance with JIS R1655: 2003.
 隔壁5は、平均細孔径が、好ましくは5μm、より好ましくは7μm以上である。このような範囲の平均細孔径とすることにより、圧力損失の増大を抑えることができる。特に、粒子状物質がハニカム構造体1に堆積した場合であっても、ハニカム構造体1の圧力損失の増大を抑制することができる。また、ハニカム構造体1の平均細孔径は、好ましくは25μm以下、より好ましくは20μm以下である。このような範囲の平均細孔径とすることにより、粒子状物質の素抜けを抑制することができる。
 ここで、本明細書において「平均細孔径」とは、JIS R1655:2003に準拠し、水銀圧入法によって求めた細孔分布における積算値50%での細孔径を意味する。
The partition wall 5 has an average pore diameter of preferably 5 μm, more preferably 7 μm or more. By setting the average pore diameter in such a range, an increase in pressure loss can be suppressed. In particular, even when the particulate matter is deposited on the honeycomb structure 1, it is possible to suppress an increase in the pressure loss of the honeycomb structure 1. The average pore diameter of the honeycomb structure 1 is preferably 25 μm or less, more preferably 20 μm or less. By setting the average pore diameter in such a range, it is possible to suppress the loss of particulate matter.
Here, in the present specification, the "average pore diameter" means the pore diameter at an integrated value of 50% in the pore distribution obtained by the mercury intrusion method in accordance with JIS R1655: 2003.
 隔壁5の表面には、平均細孔径が5μm以下の表面層が設けられていてもよい。このような平均細孔径の表面層を設けることにより、排気ガスが表面層を通過する際にも吸排気音の流路断面積の拡大による消音効果を得ることができる。
 表面層は、隔壁5と同様にセラミックスを主成分とすることが好ましく、隔壁5に用いられるセラミックスと同種のものを用いることができる。表面層の平均細孔径は、原料であるセラミックス粉末の粒径や結合材の種類などを調整することによって制御することができる。
A surface layer having an average pore diameter of 5 μm or less may be provided on the surface of the partition wall 5. By providing the surface layer having such an average pore diameter, it is possible to obtain a muffling effect by expanding the flow path cross-sectional area of the intake / exhaust sound even when the exhaust gas passes through the surface layer.
As with the partition wall 5, the surface layer preferably contains ceramics as a main component, and the same type of ceramics as the ceramics used for the partition wall 5 can be used. The average pore diameter of the surface layer can be controlled by adjusting the particle size of the ceramic powder as a raw material, the type of binder, and the like.
 隔壁5の表面、又は隔壁5の表面に表面層が形成されている場合には表面層の表面には、触媒が担持されていてもよい。触媒を担持させることにより、排気ガスに含まれるNOx、CO及びHCなどの有害物質を浄化することができるため、触媒コンバータとしての機能を得ることができる。
 触媒としては、当該技術分野において公知のものを用いることができる。触媒の例としては、ガソリンエンジン排気ガス浄化用の三元触媒、ガソリンエンジン又はディーゼルエンジン排気ガス浄化用の酸化触媒、NOx選択還元用のSCR触媒などが挙げられる。具体的には、貴金属(白金、ロジウム、パラジウム、ルテニウム、インジウム、銀、及び金)、アルミニウム、ニッケル、ジルコニウム、チタン、セリウム、コバルト、マンガン、亜鉛、銅、スズ、鉄、ニオブ、マグネシウム、ランタン、サマリウム、ビスマス、及びバリウムからなる群から選択された元素を少なくとも一種を含有するものであることが好ましい。上記元素は、金属単体、金属酸化物、又はそれ以外の金属化合物として含有されていてもよい。
When a surface layer is formed on the surface of the partition wall 5 or the surface of the partition wall 5, the catalyst may be supported on the surface of the surface layer. By supporting the catalyst, harmful substances such as NOx, CO and HC contained in the exhaust gas can be purified, so that the function as a catalytic converter can be obtained.
As the catalyst, a catalyst known in the art can be used. Examples of the catalyst include a three-way catalyst for purifying exhaust gas from a gasoline engine, an oxidation catalyst for purifying exhaust gas from a gasoline engine or a diesel engine, an SCR catalyst for purifying NOx selective reduction, and the like. Specifically, precious metals (platinum, rhodium, palladium, ruthenium, indium, silver, and gold), aluminum, nickel, zirconium, titanium, cerium, cobalt, manganese, zinc, copper, tin, iron, niobium, magnesium, lantern. , Samalium, bismuth, and barium, preferably containing at least one element selected from the group. The above element may be contained as a simple substance of a metal, a metal oxide, or another metal compound.
 触媒(触媒金属+担持体)の担持量としては、特に限定されないが、好ましくは10~400g/Lである。また、貴金属を含む触媒を用いる場合、その担持量は、特に限定されないが、好ましくは0.1~5g/Lである。触媒(触媒金属+担持体)の担持量を10g/L以上とすることにより、触媒作用が発現し易くなる。また、触媒(触媒金属+担持体)の担持量を400g/L以下とすることにより、圧力損失及び製造コストの上昇を抑えることができる。なお、担持体とは、触媒金属が担持される担体のことである。担持体としては、アルミナ、セリア、及びジルコニアからなる群より選択される少なくとも一種を含有するものを用いることができる。 The amount of the catalyst (catalyst metal + carrier) supported is not particularly limited, but is preferably 10 to 400 g / L. When a catalyst containing a noble metal is used, the amount of the catalyst supported is not particularly limited, but is preferably 0.1 to 5 g / L. By setting the carrying amount of the catalyst (catalyst metal + carrier) to 10 g / L or more, the catalytic action can be easily exhibited. Further, by setting the supported amount of the catalyst (catalyst metal + carrier) to 400 g / L or less, it is possible to suppress the pressure loss and the increase in the manufacturing cost. The carrier is a carrier on which the catalyst metal is supported. As the carrier, one containing at least one selected from the group consisting of alumina, ceria, and zirconia can be used.
 ハニカム構造体1の製造方法は、特に限定されず、当該技術分野において公知の方法に準じて実施することができる。例えば、ハニカム構造体1は、次のようにして製造することができる。
 まず、セラミックス粉末を含む坏土を所望の形状に押し出し、ハニカム成形体を作製する。このとき、適切な形態の口金及び治具を選択することにより、セル4の形状及び密度、隔壁5及び外周壁2の形状及び厚さなどを制御することができる。なお、セラミックス粉末としては、前述のセラミックスの粉末や、焼成後に前述のセラミックスとなる原料粉末(例えば、コージェライト化原料)などを用いることができる。また、坏土は、バインダー、造孔剤、分散剤、水、有機溶媒などを含むことができる。そして、得られたハニカム成形体を乾燥して焼成することにより、ハニカム構造部6を得ることができる。乾燥方法としては、特に限定されず、熱風乾燥、マイクロ波乾燥、誘電乾燥、減圧乾燥、真空乾燥、凍結乾燥等の従来公知の乾燥方法を用いることができる。これらの中でも、ハニカム成形体全体を迅速且つ均一に乾燥することができる点で、熱風乾燥と、マイクロ波乾燥又は誘電乾燥とを組み合わせた乾燥方法が好ましい。
The method for producing the honeycomb structure 1 is not particularly limited, and the honeycomb structure 1 can be manufactured according to a method known in the art. For example, the honeycomb structure 1 can be manufactured as follows.
First, the clay containing the ceramic powder is extruded into a desired shape to prepare a honeycomb molded body. At this time, the shape and density of the cell 4, the shape and thickness of the partition wall 5 and the outer peripheral wall 2 can be controlled by selecting an appropriate shape of the base and jig. As the ceramic powder, the above-mentioned ceramic powder, the raw material powder that becomes the above-mentioned ceramic after firing (for example, a cordierite raw material) and the like can be used. In addition, the clay can contain a binder, a pore-forming agent, a dispersant, water, an organic solvent and the like. Then, the honeycomb structure portion 6 can be obtained by drying and firing the obtained honeycomb molded body. The drying method is not particularly limited, and conventionally known drying methods such as hot air drying, microwave drying, dielectric drying, vacuum drying, vacuum drying, and freeze drying can be used. Among these, a drying method that combines hot air drying and microwave drying or dielectric drying is preferable in that the entire honeycomb molded body can be dried quickly and uniformly.
 次に、ハニカム構造部6に対して目封止を行う。なお、目封止は、ハニカム成形体を焼成する前に行ってもよい。目封止は、目封止材を充填する従来の方法に準じて行うことができる。例えば、目封止部7を形成すべきハニカム構造部6の端面(第1端面3a及び第2端面3b)のセル4に対応する箇所が開口した薄膜フィルムを貼り付ける。そして、ハニカム構造部6の端面をスラリー状の目封止材に浸漬し、薄膜フィルムで塞がれていないハニカム構造部6のセル4に目封止材を進入させることにより、目封止材が充填された目封止部7を形成することができる。 Next, the honeycomb structure 6 is sealed. The sealing may be performed before the honeycomb molded body is fired. The sealing can be performed according to the conventional method of filling the sealing material. For example, a thin film film having an opening corresponding to the cell 4 of the end faces (first end face 3a and second end face 3b) of the honeycomb structure portion 6 on which the mesh sealing portion 7 is to be formed is attached. Then, the end face of the honeycomb structure portion 6 is immersed in a slurry-like eye-sealing material, and the eye-sealing material is allowed to enter the cell 4 of the honeycomb structure portion 6 which is not blocked by the thin film. It is possible to form the eye-sealing portion 7 filled with.
 目封止部7のセル方向長さは、ハニカム構造部6の端面を目封止材に浸漬する深さで調整することができる。すなわち、複数のセル4における有効流路方向長さLが不均一となるように目封止部7を形成するためには、2種以上の開口パターンを有する薄膜フィルムを準備し、これらの薄膜フィルムを順次使用してハニカム構造部6の端面を目封止材に浸漬する深さを変えればよい。
 その他の方法としては、フィルム開口部の面積を調整することによっても、複数のセル4における有効流路方向長さLが不均一となるように目封止部7を形成することができる。例えば、フィルム開口部の面積を小さくすることにより、セル4に流れ込む目封止材の量を少なくすることができるため、目封止部7のセル方向長さが短い目封止部7を形成することができる。そのため、フィルム開口部の面積を不均一とすることにより、複数のセル4にセル方向長さが不均一な目封止部7を形成することができる。
The length of the sealing portion 7 in the cell direction can be adjusted by immersing the end face of the honeycomb structure portion 6 in the sealing material. That is, in order to form the eye-sealing portion 7 so that the length L in the effective flow path direction in the plurality of cells 4 is non-uniform, thin film films having two or more types of opening patterns are prepared, and these thin films are prepared. The film may be sequentially used to change the depth at which the end face of the honeycomb structure 6 is immersed in the sealing material.
As another method, by adjusting the area of the film opening, the sealing portion 7 can be formed so that the length L in the effective flow path direction in the plurality of cells 4 becomes non-uniform. For example, by reducing the area of the film opening, the amount of the eye-sealing material flowing into the cell 4 can be reduced, so that the eye-sealing portion 7 having a short cell-direction length is formed. can do. Therefore, by making the area of the film opening non-uniform, it is possible to form the eye-sealing portions 7 having non-uniform cell-direction lengths in the plurality of cells 4.
 本発明の実施形態に係る消音器は、ハニカム構造体1に加えて筒状部材を備えることができる。このような構造を有する消音器の筒状部材の軸方向に平行な断面図を図5に示す。
 図5に示されるように、消音器100は、ハニカム構造体1と、ハニカム構造体1の外周壁2の外周面に嵌合され、流体の流出側となる第2端面3bよりも軸方向外側に延伸した部分を有する筒状部材10とを備えている。このような構造とすることにより、ハニカム構造体1の第2端面3bを通過した吸排気音の流路断面積が筒状部材10の内径まで拡大するため、消音効果を向上させることができる。
The silencer according to the embodiment of the present invention may include a tubular member in addition to the honeycomb structure 1. FIG. 5 shows a cross-sectional view parallel to the axial direction of the tubular member of the silencer having such a structure.
As shown in FIG. 5, the silencer 100 is fitted to the honeycomb structure 1 and the outer peripheral surface of the outer peripheral wall 2 of the honeycomb structure 1 and is axially outside the second end surface 3b which is the outflow side of the fluid. It is provided with a tubular member 10 having a portion extended to the honeycomb. With such a structure, the flow path cross-sectional area of the intake / exhaust sound passing through the second end surface 3b of the honeycomb structure 1 is expanded to the inner diameter of the tubular member 10, so that the sound deadening effect can be improved.
 筒状部材10は、ハニカム構造体1の第2端面3bよりも軸方向外側に延伸した部分が拡径した構造を有することが好ましい。このような構造を有する消音器100のハニカム構造体1の軸方向に平行な断面図を図6に示す。
 なお、本明細書において「筒状部材10の、ハニカム構造体1の第2端面3bよりも軸方向外側に延伸した部分」とは、筒状部材10の軸方向において、ハニカム構造体1の第2端面3bからハニカム構造体1の軸方向長さの1/2までの長さの部分のことを意味する。
 図6に示されるように、消音器100における筒状部材10は、ハニカム構造体1の第2端面3bよりも軸方向外側に延伸した部分が拡径した構造を有する。このような構造とすることにより、ハニカム構造体1の第2端面3bを通過した吸排気音の流路断面積が更に拡大するため、消音効果をより一層向上させることができる。
The tubular member 10 preferably has a structure in which a portion extending outward in the axial direction from the second end surface 3b of the honeycomb structure 1 has an enlarged diameter. FIG. 6 shows a cross-sectional view of the honeycomb structure 1 of the silencer 100 having such a structure parallel to the axial direction.
In the present specification, "a portion of the tubular member 10 extending axially outward from the second end surface 3b of the honeycomb structure 1" is the first portion of the honeycomb structure 1 in the axial direction of the tubular member 10. 2 It means a portion having a length from the end surface 3b to 1/2 of the axial length of the honeycomb structure 1.
As shown in FIG. 6, the tubular member 10 in the silencer 100 has a structure in which a portion extending outward in the axial direction from the second end surface 3b of the honeycomb structure 1 has an enlarged diameter. With such a structure, the cross-sectional area of the flow path of the intake / exhaust sound that has passed through the second end surface 3b of the honeycomb structure 1 is further expanded, so that the sound deadening effect can be further improved.
 筒状部材10は、ハニカム構造体1の第2端面3bよりも軸方向外側に延伸した部分の内径の最大値が、ハニカム構造体1の第2端面3bの面積の1.1倍以上であることが好ましく、1.3倍以上であることがより好ましい。このような構成とすることにより、ハニカム構造体1の第2端面3bを通過した吸排気音の流路断面積の急拡大による消音効果を安定して得ることができる。 The maximum inner diameter of the portion of the tubular member 10 extending outward in the axial direction from the second end surface 3b of the honeycomb structure 1 is 1.1 times or more the area of the second end surface 3b of the honeycomb structure 1. It is preferable, and it is more preferable that it is 1.3 times or more. With such a configuration, it is possible to stably obtain a muffling effect due to a rapid expansion of the flow path cross-sectional area of the intake / exhaust sound passing through the second end surface 3b of the honeycomb structure 1.
 筒状部材10の材料としては、特に限定されないが、例えば、ステンレス、チタン合金、銅合金、アルミ合金、真鍮などを用いることができる。これらの中でも、耐久信頼性が高く、安価という理由により、ステンレスが好ましい。 The material of the tubular member 10 is not particularly limited, but for example, stainless steel, titanium alloy, copper alloy, aluminum alloy, brass and the like can be used. Among these, stainless steel is preferable because of its high durability and reliability and low cost.
 上記のような構造を有する消音器100は、当該技術分野において公知の方法に準じて製造することができる。例えば、消音器100は、ハニカム構造体1の外周壁2の外周面に筒状部材10を嵌合させることによって製造することができる。嵌合方法としては、特に限定されないが、すきま嵌め、締まり嵌め、焼き嵌めなどの嵌め合いによる固定方法の他、ろう付け、溶接、拡散接合などを用いることができる。 The silencer 100 having the above structure can be manufactured according to a method known in the art. For example, the silencer 100 can be manufactured by fitting the tubular member 10 to the outer peripheral surface of the outer peripheral wall 2 of the honeycomb structure 1. The fitting method is not particularly limited, but brazing, welding, diffusion joining and the like can be used in addition to the fixing method by fitting such as clearance fitting, tightening fitting and shrink fitting.
 本発明の実施形態に係る消音器100は、上記の金属缶、ハニカム構造体1及び筒状部材10に加えて、繊維状吸音材を更に備えることができる。このような構造を有する消音器100の筒状部材10の軸方向に平行な断面図を図7に示す。
 図7に示されるように、消音器100は、筒状部材10の外周側に設けられ、筒状部材10と金属缶30との間に保持される繊維状吸音材20を備えている。
 筒状部材10には小孔11が設けられており、小孔11を通じて吸排気音を繊維状吸音材20に吸収させることにより、消音効果を高めることができる。
The silencer 100 according to the embodiment of the present invention may further include a fibrous sound absorbing material in addition to the metal can, the honeycomb structure 1 and the tubular member 10. FIG. 7 shows a cross-sectional view of the tubular member 10 of the silencer 100 having such a structure parallel to the axial direction.
As shown in FIG. 7, the silencer 100 includes a fibrous sound absorbing material 20 provided on the outer peripheral side of the tubular member 10 and held between the tubular member 10 and the metal can 30.
The tubular member 10 is provided with a small hole 11, and the sound deadening effect can be enhanced by allowing the fibrous sound absorbing material 20 to absorb the intake / exhaust sound through the small hole 11.
 筒状部材10に設けられる小孔11の位置は、特に限定されないが、筒状部材10の軸方向において、ハニカム構造体1の第1端面3a及び/又は第2端面3bよりも軸方向外側に延伸した部分であることが好ましい。
 筒状部材10に設けられる小孔11の形状及び大きさは、特に限定されず、使用する繊維状吸音材20の種類などに応じて適宜調整すればよい。
The position of the small hole 11 provided in the tubular member 10 is not particularly limited, but is axially outward from the first end surface 3a and / or the second end surface 3b of the honeycomb structure 1 in the axial direction of the tubular member 10. It is preferably a stretched portion.
The shape and size of the small holes 11 provided in the tubular member 10 are not particularly limited, and may be appropriately adjusted according to the type of the fibrous sound absorbing material 20 to be used.
 繊維状吸音材20としては、特に限定されないが、例えば、グラスウール、ロックウール、スチールウール、セラミックウールなどを用いることができる。これらの中でも、消音効果の観点からグラスウールが好ましい。 The fibrous sound absorbing material 20 is not particularly limited, but for example, glass wool, rock wool, steel wool, ceramic wool, or the like can be used. Among these, glass wool is preferable from the viewpoint of sound deadening effect.
 金属缶30は、筒状部材10との間に空間を形成し、空間内に収容された繊維状吸音材20を保持する。
 金属缶30の形状としては、筒状部材10の外周側に設けられた繊維状吸音材20を保持することが可能な形状であれば特に限定されず、例えば、筒状とすることができる。
 金属缶30の材料としては、特に限定されず、筒状部材10と同様のものを用いることができる。
The metal can 30 forms a space with the tubular member 10 and holds the fibrous sound absorbing material 20 housed in the space.
The shape of the metal can 30 is not particularly limited as long as it can hold the fibrous sound absorbing material 20 provided on the outer peripheral side of the tubular member 10, and may be, for example, tubular.
The material of the metal can 30 is not particularly limited, and the same material as that of the tubular member 10 can be used.
 本発明の実施形態に係る消音器100は、上記の構造に加えて、当該技術分野において公知の消音構造を更に備えることができる。公知の消音構造としては、障壁となる構造(じゃま板)などが挙げられる。 The silencer 100 according to the embodiment of the present invention may further include a silencer structure known in the art in addition to the above structure. Examples of the known sound deadening structure include a structure (jammer plate) that serves as a barrier.
 上記のような構造を有する消音器100は、当該技術分野において公知の方法に準じて製造することができる。例えば、消音器100は、ハニカム構造体1の外周壁2の外周面に嵌合させた筒状部材10の外周側に繊維状吸音材20を配置し、金属缶30内に収容することによって製造することができる。また、筒状部材10と金属缶30との間は、溶接などによって接合すればよい。 The silencer 100 having the above structure can be manufactured according to a method known in the art. For example, the silencer 100 is manufactured by arranging the fibrous sound absorbing material 20 on the outer peripheral side of the tubular member 10 fitted to the outer peripheral surface of the outer peripheral wall 2 of the honeycomb structure 1 and accommodating it in the metal can 30. can do. Further, the tubular member 10 and the metal can 30 may be joined by welding or the like.
 以下、本発明を実施例によって更に具体的に説明するが、本発明はこれらの実施例によって何ら限定されるものではない。 Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to these Examples.
(実施例1)
 コージェライト化原料を含む坏土を押出成形機に投入して押出成形することにより円柱状のハニカム成形体を得た。次に、このハニカム成形体を乾燥させた後、所定の寸法となるように両端面を切断してハニカム乾燥体を得た。次に、開口パターンが異なる複数枚の薄膜フィルム、及びハニカム成形体と同じ成分を含む目封止材を用いて、ハニカム乾燥体の第1端面及び第2端面のセルに対してそれぞれ目封止を行った後、1400℃で焼成することによってコージェライト製のハニカム構造体を得た。第1端面のセルの目封止では、目封止材に浸漬する深さを全て同じにして行い、第2端面のセルの目封止では、目封止材に浸漬する深さを変えて行った。また、目封止は、図1のA~Cに示される構造、すなわち、第1端面のみに目封止部が設けられたセルと、第2端面のみに目封止部が設けられたセルとが交互に配置された千鳥状配置とした。
(Example 1)
A cylindrical honeycomb molded body was obtained by throwing clay containing a cordierite-forming raw material into an extrusion molding machine and extrusion molding. Next, after drying the honeycomb molded product, both end faces were cut so as to have a predetermined size to obtain a honeycomb dried product. Next, using a plurality of thin films having different opening patterns and a sealing material containing the same components as the honeycomb molded body, the cells on the first end face and the second end face of the honeycomb dried body are sealed with each other. A honeycomb structure made of cordierite was obtained by firing at 1400 ° C. In the sealing of the cells on the first end face, the depth of immersion in the sealing material is the same, and in the sealing of the cells on the second end face, the depth of immersion in the sealing material is changed. went. Further, the mesh sealing has a structure shown in FIGS. 1A to 1C, that is, a cell in which the mesh sealing portion is provided only on the first end surface and a cell in which the mesh sealing portion is provided only on the second end surface. And were arranged alternately in a staggered pattern.
 得られたハニカム構造体は、直径118.4mm、軸方向長さ127mm、隔壁の厚み0.3mm、外周壁の厚み1mm、セル密度31セル/cm2、隔壁の気孔率48%、平均細孔径12μmであった。なお、気孔率及び平均細孔径は上述の方法で測定した。 The obtained honeycomb structure had a diameter of 118.4 mm, an axial length of 127 mm, a partition wall thickness of 0.3 mm, an outer peripheral wall thickness of 1 mm, a cell density of 31 cells / cm 2 , a porosity of the partition wall of 48%, and an average pore diameter. It was 12 μm. The porosity and the average pore diameter were measured by the above method.
(実施例2)
 ハニカム乾燥体の第2端面の一部のセルを目封止する際に、ハニカム乾燥体の第2端面を目封止材に浸漬する深さを大きくしたこと以外は実施例1と同様にしてハニカム構造体を得た。
(Example 2)
Similar to Example 1 except that when sealing a part of the cells on the second end face of the honeycomb dried body, the depth of immersing the second end face of the honeycomb dried body in the eye sealing material was increased. A honeycomb structure was obtained.
(比較例1)
 目封止を行わなかったこと以外は実施例1と同様にしてハニカム構造体を得た。
(比較例2)
 ハニカム乾燥体の第1端面及び第2端面のセルを目封止する際に、ハニカム乾燥体の第1端面及び第2端面を目封止材に浸漬する深さを全て同じにしたこと以外は実施例1と同様にしてハニカム構造体を得た。
(Comparative Example 1)
A honeycomb structure was obtained in the same manner as in Example 1 except that the seal was not sealed.
(Comparative Example 2)
When sealing the cells of the first end face and the second end face of the honeycomb dried body, the depth of immersing the first end face and the second end face of the honeycomb dried body in the eye sealing material was the same. A honeycomb structure was obtained in the same manner as in Example 1.
(有効流路方向長さ)
 上記の実施例及び比較例で得られたハニカム構造体について、ハニカム構造体のセルが延びる方向と平行に切断した後、その断面観察を行うことによって、複数のセルにおける第1端面及び第2端面に形成された目封止部のセル方向長さ(セルが延びる方向の長さ)を測定し、有効流路方向長さを算出した。
(Length in the effective flow path direction)
The honeycomb structures obtained in the above Examples and Comparative Examples are cut in parallel with the extending direction of the cells of the honeycomb structure, and then the cross-sectional observation thereof is performed to observe the first end surface and the second end surface of the plurality of cells. The length of the sealing portion formed in the cell in the cell direction (the length in the direction in which the cell extends) was measured, and the length in the effective flow path direction was calculated.
(消音効果試験)
 上記の実施例及び比較例で得られたハニカム構造体の外周壁の外周面に筒状部材を嵌合して消音器を作製した。次に、2Lガソリンエンジンの排気系に設けられた2つのマフラーのうちの1つ目のマフラーを取り外し、その位置に上記で作製した消音器を設けた。そして、エンジン回転速度2000rpm、スロットル全開(WOT)の条件でガソリンエンジンを稼働させ、マフラー下流のテールパイプの出口において、音圧測定器を用いて音圧レベルを測定した。
 上記の各評価結果を表1に示す。
(Silencer effect test)
A tubular member was fitted to the outer peripheral surface of the outer peripheral wall of the honeycomb structure obtained in the above Examples and Comparative Examples to produce a silencer. Next, the first muffler of the two mufflers provided in the exhaust system of the 2L gasoline engine was removed, and the silencer produced above was provided at that position. Then, the gasoline engine was operated under the conditions of an engine rotation speed of 2000 rpm and a throttle fully opened (WOT), and the sound pressure level was measured using a sound pressure measuring device at the outlet of the tail pipe downstream of the muffler.
The results of each of the above evaluations are shown in Table 1.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
 表1に示されるように、有効流路方向長さが不均一である実施例1及び2のハニカム構造体を用いた消音器は、目封止部を形成しなかった比較例1のハニカム構造体を用いた消音器及び有効流路方向長さが均一である比較例2のハニカム構造体を用いた消音器に比べて、音圧レベルが低くなった。 As shown in Table 1, the silencer using the honeycomb structures of Examples 1 and 2 having non-uniform lengths in the effective flow path direction did not form a mesh sealing portion, and the honeycomb structure of Comparative Example 1 was not formed. The sound pressure level was lower than that of the silencer using the body and the silencer using the honeycomb structure of Comparative Example 2 having a uniform length in the effective flow path direction.
 以上の結果からわかるように、本発明によれば、消音機能が良好であるとともに、集塵用フィルタ又は触媒コンバータとしての機能も有することが可能な消音器及び消音器用ハニカム構造体を提供することができる。 As can be seen from the above results, according to the present invention, there is provided a muffler and a honeycomb structure for a muffler that have a good muffling function and can also have a function as a dust collecting filter or a catalytic converter. Can be done.
 1 ハニカム構造体
 2 外周壁
 3a 第1端面
 3b 第2端面
 4 セル
 5 隔壁
 6 ハニカム構造部
 7 目封止部
 10 筒状部材
 11 小孔
 20 繊維状吸音材
 30 金属缶
 100 消音器
1 Honeycomb structure 2 Outer wall 3a 1st end face 3b 2nd end face 4 Cell 5 Partition 6 Honeycomb structure 7th Sealing part 10 Cylindrical member 11 Small hole 20 Fibrous sound absorbing material 30 Metal can 100 Silencer

Claims (16)

  1.  金属缶の内部にハニカム構造体を備える消音器であって、
     前記ハニカム構造体が、
     外周壁、及び前記外周壁の内側に設けられ、第1端面から第2端面まで延びる流体の流路となる複数のセルを区画形成する多孔質の隔壁を有するハニカム構造部と、
     複数の前記セルの前記第1端面及び前記第2端面の少なくとも一方に設けられた目封止部と
    を有し、
     複数の前記セルにおける有効流路方向長さが不均一である、消音器。
    A silencer with a honeycomb structure inside a metal can
    The honeycomb structure
    A honeycomb structure having a outer peripheral wall and a porous partition wall provided inside the outer peripheral wall and partitioning a plurality of cells serving as a flow path for a fluid extending from a first end face to a second end face.
    It has a mesh sealing portion provided on at least one of the first end surface and the second end surface of the plurality of cells.
    A silencer having a non-uniform length in the effective flow path direction in the plurality of cells.
  2.  複数の前記セルは、前記有効流路方向長さの最小値Lminに対する最大値Lmaxの比(Lmax/Lmin)が1.25以上である、請求項1に記載の消音器。 The silencer according to claim 1, wherein the plurality of cells have a ratio (L max / L min ) of a maximum value L max to a minimum value L min of the length in the effective flow path direction of 1.25 or more.
  3.  前記比率が1.30以上である、請求項2に記載の消音器。 The silencer according to claim 2, wherein the ratio is 1.30 or more.
  4.  前記ハニカム構造体は、前記第2端面が開口して前記第1端面に前記目封止部が設けられた前記セルと、前記第1端面が開口して前記第2端面に前記目封止部が設けられた前記セルと、が千鳥状となるように交互に配置されている、請求項1~3のいずれか一項に記載の消音器。 The honeycomb structure includes the cell in which the second end surface is opened and the eye sealing portion is provided on the first end surface, and the first end surface is opened and the eye sealing portion is provided on the second end surface. The silencer according to any one of claims 1 to 3, wherein the cells provided with the cells and the cells are arranged alternately so as to be staggered.
  5.  前記ハニカム構造体は、前記第1端面及び前記第2端面の中央領域が前記千鳥状の配置を有し、
     前記中央領域の外周側に位置する外周領域において、複数の前記セルの前記第1端面及び前記第2端面の少なくとも一方の全てに前記目封止部が設けられている、請求項4に記載の消音器。
    In the honeycomb structure, the central region of the first end face and the second end face has the staggered arrangement.
    The fourth aspect of the present invention, wherein in the outer peripheral region located on the outer peripheral side of the central region, the eye-sealing portion is provided on at least one of the first end surface and the second end surface of the plurality of cells. Silencer.
  6.  前記中央領域の外周側に位置する外周領域において、複数の前記セルの前記第2端面の全てに前記目封止部が設けられており、
     前記第1端面が前記流体の流入側であり、前記第2端面が前記流体の流出側である、請求項5に記載の消音器。
    In the outer peripheral region located on the outer peripheral side of the central region, the sealing portions are provided on all of the second end faces of the plurality of cells.
    The silencer according to claim 5, wherein the first end face is the inflow side of the fluid and the second end face is the outflow side of the fluid.
  7.  前記第2端面の面積が、前記第2端面の前記中央領域の面積の1.1倍以上である、請求項5又は6に記載の消音器。 The silencer according to claim 5 or 6, wherein the area of the second end face is 1.1 times or more the area of the central region of the second end face.
  8.  前記第2端面の面積が、前記第2端面の前記中央領域の面積の1.3倍以上である、請求項7に記載の消音器。 The silencer according to claim 7, wherein the area of the second end face is 1.3 times or more the area of the central region of the second end face.
  9.  前記隔壁は、コージェライト、ムライト、窒化珪素、炭化珪素及びチタン酸アルミニウムから選択される1種以上を主成分とし、気孔率が25%以上、平均細孔径が5~25μmである、請求項1~8のいずれか一項に記載の消音器。 The partition wall is mainly composed of one or more selected from cordierite, mullite, silicon nitride, silicon carbide and aluminum titanate, has a porosity of 25% or more, and has an average pore diameter of 5 to 25 μm. The silencer according to any one of 8 to 8.
  10.  平均細孔径が5μm以下の表面層が前記隔壁の表面に設けられている、請求項1~9のいずれか一項に記載の消音器。 The silencer according to any one of claims 1 to 9, wherein a surface layer having an average pore diameter of 5 μm or less is provided on the surface of the partition wall.
  11.  前記隔壁の表面、又は前記隔壁の表面に前記表面層が形成されている場合には前記表面層の表面に触媒が担持されている、請求項1~10のいずれか一項に記載の消音器。 The silencer according to any one of claims 1 to 10, wherein a catalyst is supported on the surface of the partition wall or, when the surface layer is formed on the surface of the partition wall, on the surface of the surface layer. ..
  12.  前記ハニカム構造体の外周壁の外周面に嵌合され、前記流体の流出側となる前記第2端面よりも軸方向外側に延伸した部分を有する筒状部材を更に備える、請求項1~11のいずれか一項に記載の消音器。 Claims 1 to 11 further include a tubular member fitted to the outer peripheral surface of the outer peripheral wall of the honeycomb structure and having a portion extending axially outward from the second end surface which is the outflow side of the fluid. The silencer described in any one item.
  13.  前記筒状部材の前記延伸した部分の内径の最大値が、前記ハニカム構造体の前記第2端面の面積の1.1倍以上である、請求項12に記載の消音器。 The silencer according to claim 12, wherein the maximum value of the inner diameter of the stretched portion of the tubular member is 1.1 times or more the area of the second end surface of the honeycomb structure.
  14.  前記筒状部材の前記延伸した部分の内径の最大値が、前記ハニカム構造体の前記第2端面の面積の1.3倍以上である、請求項13に記載の消音器。 The silencer according to claim 13, wherein the maximum value of the inner diameter of the stretched portion of the tubular member is 1.3 times or more the area of the second end surface of the honeycomb structure.
  15.  前記消音器が、前記筒状部材の外周側に設けられ、前記筒状部材と前記金属缶との間に保持される繊維状吸音材を更に備える、請求項12~14のいずれか一項に記載の消音器。 The silencer is provided on the outer peripheral side of the tubular member, and further includes a fibrous sound absorbing material held between the tubular member and the metal can, according to any one of claims 12 to 14. Described silencer.
  16.  外周壁、及び前記外周壁の内側に設けられ、第1端面から第2端面まで延びる流体の流路となる複数のセルを区画形成する多孔質の隔壁を有するハニカム構造部と、
     複数の前記セルの前記第1端面及び前記第2端面の少なくとも一方に設けられた目封止部と
    を有し、複数の前記セルにおける有効流路方向長さが不均一である消音器用ハニカム構造体。
    A honeycomb structure having a outer peripheral wall and a porous partition wall provided inside the outer peripheral wall and partitioning a plurality of cells serving as a flow path for a fluid extending from a first end face to a second end face.
    A honeycomb structure for a silencer, which has a sealing portion provided on at least one of the first end surface and the second end surface of the plurality of cells, and has a non-uniform length in the effective flow path direction in the plurality of cells. body.
PCT/JP2020/023802 2019-10-25 2020-06-17 Muffler and honeycomb structure for muffler WO2021079556A1 (en)

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