WO2021075802A1 - Appareil de production d'hydrogène à reformage à la vapeur hautement efficace avec hydrodésulfuration - Google Patents

Appareil de production d'hydrogène à reformage à la vapeur hautement efficace avec hydrodésulfuration Download PDF

Info

Publication number
WO2021075802A1
WO2021075802A1 PCT/KR2020/013827 KR2020013827W WO2021075802A1 WO 2021075802 A1 WO2021075802 A1 WO 2021075802A1 KR 2020013827 W KR2020013827 W KR 2020013827W WO 2021075802 A1 WO2021075802 A1 WO 2021075802A1
Authority
WO
WIPO (PCT)
Prior art keywords
heat exchanger
raw material
gas
hydrogen
heat
Prior art date
Application number
PCT/KR2020/013827
Other languages
English (en)
Korean (ko)
Inventor
김명준
최준태
이재원
Original Assignee
주식회사 트리신
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 주식회사 트리신 filed Critical 주식회사 트리신
Publication of WO2021075802A1 publication Critical patent/WO2021075802A1/fr

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C01B2203/0425—In-situ adsorption process during hydrogen production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0833—Heating by indirect heat exchange with hot fluids, other than combustion gases, product gases or non-combustive exothermic reaction product gases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C01B2203/1058—Nickel catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1258—Pre-treatment of the feed
    • C01B2203/1264—Catalytic pre-treatment of the feed
    • C01B2203/127—Catalytic desulfurisation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

L'efficacité thermique de la production d'hydrogène est très importante pour un petit appareil de production d'hydrogène utilisé dans une pile à combustible, une station d'hydrogène, etc. à la différence d'une installation à grande échelle pour produire de l'hydrogène. De plus, des arrêts et des démarrages fréquents du fait des caractéristiques de l'appareil nécessitent non seulement la facilité de fonctionnement, mais nécessitent également qu'un processus de post-opération atteigne rapidement une condition souhaitée et soit stabilisé. En outre, une excellente performance de désulfuration est requise pour utiliser du gaz naturel, du GPL, du naphta, etc. en tant que matières premières. La présente invention suggère un procédé dans lequel l'efficacité thermique est maximisée, la performance de désulfuration est améliorée, et les conditions de fonctionnement souhaitées peuvent être rapidement obtenues après l'exécution d'un procédé.
PCT/KR2020/013827 2019-10-14 2020-10-12 Appareil de production d'hydrogène à reformage à la vapeur hautement efficace avec hydrodésulfuration WO2021075802A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020190126736A KR102094646B1 (ko) 2019-10-14 2019-10-14 수소탈황을 구비한 고효율 스팀 리포밍 수소 제조 장치
KR10-2019-0126736 2019-10-14

Publications (1)

Publication Number Publication Date
WO2021075802A1 true WO2021075802A1 (fr) 2021-04-22

Family

ID=70003066

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2020/013827 WO2021075802A1 (fr) 2019-10-14 2020-10-12 Appareil de production d'hydrogène à reformage à la vapeur hautement efficace avec hydrodésulfuration

Country Status (2)

Country Link
KR (1) KR102094646B1 (fr)
WO (1) WO2021075802A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11814288B2 (en) 2021-11-18 2023-11-14 8 Rivers Capital, Llc Oxy-fuel heated hydrogen production process
US11859517B2 (en) 2019-06-13 2024-01-02 8 Rivers Capital, Llc Power production with cogeneration of further products
US11891950B2 (en) 2016-11-09 2024-02-06 8 Rivers Capital, Llc Systems and methods for power production with integrated production of hydrogen

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102094646B1 (ko) * 2019-10-14 2020-03-30 주식회사 트리신 수소탈황을 구비한 고효율 스팀 리포밍 수소 제조 장치
CN113620244B (zh) * 2020-05-07 2023-04-07 中国石油化工股份有限公司 一种天然气水蒸汽重整制氢的系统及其方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101300331B1 (ko) * 2007-11-01 2013-08-28 에스케이이노베이션 주식회사 용이한 초기 구동, 운전 안정성 및 높은 열효율을 갖는수소발생 장치
US9624105B1 (en) * 2015-11-24 2017-04-18 Air Products And Chemicals, Inc. Process for producing hydrogen with reduced corrosion
JP2018012635A (ja) * 2016-06-28 2018-01-25 イエフペ エネルジ ヌヴェルＩｆｐ Ｅｎｅｒｇｉｅｓ Ｎｏｕｖｅｌｌｅｓ 天然ガスの水蒸気改質方法であって、２基の燃焼チャンバを有し、この２基の燃焼チャンバは、方法に必要な熱を供給する高温煙霧を発生させ、かつ、直列にまたは並列に接続される、方法
KR101851457B1 (ko) * 2016-08-23 2018-04-25 한국가스공사 개질 시스템
KR101873961B1 (ko) * 2016-09-02 2018-07-03 재단법인 포항산업과학연구원 제철 부생가스를 이용한 환원가스 제조 방법 및 그 제조 장치
KR102094646B1 (ko) * 2019-10-14 2020-03-30 주식회사 트리신 수소탈황을 구비한 고효율 스팀 리포밍 수소 제조 장치

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5165832B2 (ja) 2005-01-28 2013-03-21 エア・ウォーター株式会社 水素発生装置および方法
KR101773387B1 (ko) 2016-02-16 2017-08-31 최은영 테이크아웃 컵용 친환경 종이 캐리어
KR101832136B1 (ko) 2016-06-13 2018-02-27 한국에너지기술연구원 축열식 연소 방식의 고효율 컴팩트 수증기 개질 장치

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101300331B1 (ko) * 2007-11-01 2013-08-28 에스케이이노베이션 주식회사 용이한 초기 구동, 운전 안정성 및 높은 열효율을 갖는수소발생 장치
US9624105B1 (en) * 2015-11-24 2017-04-18 Air Products And Chemicals, Inc. Process for producing hydrogen with reduced corrosion
JP2018012635A (ja) * 2016-06-28 2018-01-25 イエフペ エネルジ ヌヴェルＩｆｐ Ｅｎｅｒｇｉｅｓ Ｎｏｕｖｅｌｌｅｓ 天然ガスの水蒸気改質方法であって、２基の燃焼チャンバを有し、この２基の燃焼チャンバは、方法に必要な熱を供給する高温煙霧を発生させ、かつ、直列にまたは並列に接続される、方法
KR101851457B1 (ko) * 2016-08-23 2018-04-25 한국가스공사 개질 시스템
KR101873961B1 (ko) * 2016-09-02 2018-07-03 재단법인 포항산업과학연구원 제철 부생가스를 이용한 환원가스 제조 방법 및 그 제조 장치
KR102094646B1 (ko) * 2019-10-14 2020-03-30 주식회사 트리신 수소탈황을 구비한 고효율 스팀 리포밍 수소 제조 장치

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11891950B2 (en) 2016-11-09 2024-02-06 8 Rivers Capital, Llc Systems and methods for power production with integrated production of hydrogen
US11859517B2 (en) 2019-06-13 2024-01-02 8 Rivers Capital, Llc Power production with cogeneration of further products
US11814288B2 (en) 2021-11-18 2023-11-14 8 Rivers Capital, Llc Oxy-fuel heated hydrogen production process

Also Published As

Publication number Publication date
KR102094646B1 (ko) 2020-03-30

Similar Documents

Publication Publication Date Title
WO2021075802A1 (fr) Appareil de production d'hydrogène à reformage à la vapeur hautement efficace avec hydrodésulfuration
US8926866B2 (en) Hydrogen generating apparatus using steam reforming reaction
US6190623B1 (en) Apparatus for providing a pure hydrogen stream for use with fuel cells
US6793698B1 (en) Fuel processor reactor with integrated pre-reforming zone
US6299994B1 (en) Process for providing a pure hydrogen stream for use with fuel cells
US6280864B1 (en) Control system for providing hydrogen for use with fuel cells
CN106784940B (zh) 一种固体氧化物燃料电池发电系统
EP0600621A1 (fr) Dispositif combiné de reformage et de conversion catalytique de monoxyde de carbone
JPS62148303A (ja) 水素含有ガスの製造方法、燃料電池への水素燃料の連続的供給方法、反応装置及び燃料電池システム
US20230416085A1 (en) A process for producing a hydrogen-comprising product gas from a hydrocarbon
CA3126614A1 (fr) Production de gaz de synthese par reformage de methane a la vapeur
TW574137B (en) Process and apparatus for producing hydrogen
US6342197B1 (en) Multi-stage combustion for fuel processing for use with fuel cell
JP2019085317A (ja) 水素発生装置
KR20120115880A (ko) 고분자 전해질 연료전지용 수소생산시스템
CN215611423U (zh) 一种甲烷转化系统
US8173082B1 (en) JP-8 fuel processor system
JP2016184550A (ja) ガス製造装置
JP2001043881A (ja) 固体電解質型燃料電池モジュール
EP4279445B1 (fr) Installation et procédé de production et de séparation de gaz de synthèse
WO2018101587A1 (fr) Système de pile à combustible utilisant du combustible liquide et du peroxyde d'hydrogène, et procédé de fonctionnement de pile à combustible
CN108931150B (zh) 天然气制氢系统中的集成式换热设备
KR20100048635A (ko) 높은 열효율을 가지는 연료전지용 천연 가스 개질기
JPH06104000A (ja) 燃料電池発電装置
US20100183487A1 (en) Highly heat integrated fuel processor for hydrogen production

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 20876173

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

32PN Ep: public notification in the ep bulletin as address of the adressee cannot be established

Free format text: NOTING OF LOSS OF RIGHTS PURSUANT TO RULE 112(1) EPC (EPO FORM 1205A DATED 09/09/2022)

122 Ep: pct application non-entry in european phase

Ref document number: 20876173

Country of ref document: EP

Kind code of ref document: A1