WO2021070330A1 - Non-combustion heating type flavor inhaler - Google Patents
Non-combustion heating type flavor inhaler Download PDFInfo
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- WO2021070330A1 WO2021070330A1 PCT/JP2019/040038 JP2019040038W WO2021070330A1 WO 2021070330 A1 WO2021070330 A1 WO 2021070330A1 JP 2019040038 W JP2019040038 W JP 2019040038W WO 2021070330 A1 WO2021070330 A1 WO 2021070330A1
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- WIPO (PCT)
- Prior art keywords
- suction device
- center hole
- flavor suction
- filter
- hole filter
- Prior art date
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/20—Cigarettes specially adapted for simulated smoking devices
Definitions
- the present invention relates to a non-combustion heating type flavor suction device including a tobacco rod, a cooling segment, and a mouthpiece.
- Non-combustion heating type flavor suction devices are desired to have a certain thickness or more from the viewpoint of ease of insertion into the device and delivery of sufficient flavor and taste.
- the diameter of the non-combustion heating type flavor suction device increases, the amount of heat given to the device increases and the area in contact with the lips also increases. As a result, the temperature near the mouthpiece end rises, and the user may feel uncomfortable with the temperature near the mouthpiece end during use.
- An object of the present invention is to provide a non-combustion heating type flavor suction device in which the temperature near the mouthpiece end is not unpleasant for the user during use.
- the flavor suction device described in Patent Document 1 has a mouthpiece provided with a filter and a paper tube in this order toward the mouthpiece end direction.
- the inventors considered that there is room for improvement in the flavor suction device described in Patent Document 1, and completed the present invention. That is, the above-mentioned problem is solved by the following invention.
- a non-combustion heating type flavor suction device including a tobacco rod, a cooling segment, and a mouthpiece.
- the flavor suction device wherein the mouthpiece includes a filter and a center hole filter in this order toward the mouthpiece end direction.
- the flavor suction device according to [1] wherein the hole diameter of the center hole filter is 20 to 40% of the diameter of the center hole filter.
- the figure which shows the non-combustion heating type flavor suction device of this invention The figure which shows the non-combustion heating type flavor suction system of this invention Diagram showing a device for smoking test
- X to Y includes X and Y which are the fractional values thereof.
- Non-combustion heating type flavor suction device The non-combustion heating type flavor suction device of the present invention includes a tobacco rod, a cooling segment, and a mouthpiece, and the mouthpiece sets a filter and a center hole filter in this order toward the mouthpiece end. Be prepared.
- FIG. 1 shows an aspect of the non-combustion heating type flavor suction device of the present invention.
- 10 is a non-combustion heating type flavor suction device
- 1 is a tobacco rod
- 3 is a cooling segment
- 5 is a mouthpiece
- 52 is a filter
- 54 is a center hole filter
- 7 is a chip paper
- V ventilation.
- the diameter of the flavor suction device is preferably 6 to 8 mm. The diameter is defined as the average value of the diameters of the members constituting the flavor suction device.
- the tobacco rod is a substantially columnar member for generating a flavor component contained in a tobacco raw material, and includes a tobacco filler and a wrapper around the tobacco filler.
- the tobacco filler is not limited, and for example, tobacco engraving, tobacco sheet, or the like can be used.
- the wrapper may be filled with tobacco chopped by chopping dried tobacco leaves to a width of 0.8 to 1.2 mm.
- dried tobacco leaves are crushed to an average particle size of about 20 to 200 ⁇ m, homogenized, processed into a sheet, and cut into a width of 0.8 to 1.2 mm and filled in a wrapper. You may.
- the sheet may be gathered, folded, or swirled and filled therein without engraving.
- the sheet may be cut into strips and filled in the wrapper concentrically or so that the longitudinal direction of the strips is parallel to the longitudinal direction of the tobacco rod.
- Various tobacco leaves can be used, for example, yellow varieties, Burley varieties, Orient varieties, native varieties, other Nicotiana-Tabacam varieties, Nicotiana rustica varieties, and mixtures thereof.
- As the mixture a mixture obtained by appropriately blending each of the above varieties so as to obtain a desired taste can be used. Details of the tobacco varieties are disclosed in "Tobacco Encyclopedia, Tobacco Academic Studies Center, 2009.3.31".
- the method for producing the homogenized sheet that is, the method for crushing tobacco leaves and processing them into a homogenized sheet can be carried out by a known method. For example, the following methods can be selected.
- a method of making a papermaking sheet using a papermaking process A method in which an appropriate solvent such as water is mixed with crushed tobacco leaves to homogenize the mixture, and then the homogenized product is thinly cast on a metal plate or a metal plate belt and dried to prepare a cast sheet.
- a method of producing a rolled sheet by mixing an appropriate solvent such as water with crushed tobacco leaves and extruding the homogenized material into a sheet. Details of the types of the homogenized sheet are disclosed in "Tobacco Encyclopedia, Tobacco Academic Studies Center, 2009.3.31".
- the tobacco filling may contain water, and the content thereof may be 10 to 15% by weight, preferably 11 to 13% by weight, based on the total amount of the tobacco filling.
- a tobacco filling containing the amount of water is used, the generation of stains is suppressed, and the hoisting suitability of the tobacco rod during production is improved.
- the tobacco rod 1 may generate steam as it is heated. It is preferable to add an aerosol source such as a polyol such as glycerin, propylene glycol or 1,3-butanediol to the tobacco filler in order to promote the generation of aerosol.
- the amount of the aerosol source added is preferably 5 to 50% by weight, more preferably 10 to 30% by weight, based on the dry weight of the tobacco filler.
- the length of the tobacco rod 1 is not limited, but is preferably 15 to 25 mm.
- the diameter is not limited, but is preferably 6 to 8 mm.
- Tobacco rod 1 may contain a fragrance.
- the type of the flavor is not particularly limited, and the following can be mentioned from the viewpoint of imparting a good taste.
- the packing density of the tobacco filling is not particularly limited, but is usually 250 mg / cm 3 or more, preferably 320 mg / cm 3 or more, from the viewpoint of ensuring the characteristics of the non-combustion heating type flavor suction device and imparting a good taste. Is.
- the upper limit thereof is usually 800 mg / cm 3 or less, preferably 600 mg / cm 3 or less.
- the cooling segment is a member for promoting aerosolization by cooling the flavor components and steam generated in the tobacco rod 1.
- the cooling segment 3 may be a hollow paper tube.
- the paper tube is preferably composed of a card board having a higher rigidity than a wrapper or chip paper. Ventilation V (opening) may be provided in the paper tube. It is preferable that a plurality of ventilations are provided along the circumference of the paper tube. From the viewpoint of promoting aerosolization and cooling, the upper limit of the position where ventilation is provided from the mouthpiece side end of the cooling segment to the heating end is preferably within 4 mm from the mouthpiece side end of the cooling segment, and is preferably 2 mm. The range within is more preferable.
- the lower limit of the position where the ventilation is provided is preferably 0.5 mm or more, more preferably 1.0 mm or more from the mouthpiece side end of the cooling segment from the viewpoint of durability of the entire product. That is, in one embodiment, the ventilation is provided in the range of 0.5 to 4 mm upstream from the mouthpiece side end of the cooling segment, and in another embodiment, it is provided in the range of 1.0 to 2 mm. From the viewpoint of work efficiency, it is preferable that the ventilation is provided by laser processing the completed non-combustion heating type flavor suction device. Further, the cooling segment 3 may be filled with a gathered sheet in order to increase the heat exchange efficiency. The dimensions of the cooling segment 3 are not limited, but the length is preferably 15 to 25 mm, and the diameter is preferably 5.5 to 7.5 mm.
- the ventilation is preferably arranged in the circumferential direction of the outer peripheral surface of the cooling segment.
- the number of arrangements in the circumferential direction is not limited and may be two or more.
- the pore diameter is preferably 100 to 1000 ⁇ m, more preferably 300 to 800 ⁇ m.
- the opening shape is preferably substantially circular or substantially elliptical. In the case of a substantially elliptical shape, the major axis corresponds to the hole diameter.
- the cooling segment 3 is often less rigid than the tobacco rod 1.
- the diameter of the part having high rigidity is made smaller than the diameter of the part having low rigidity, defects are less likely to occur. Therefore, when the rigidity of the cooling segment 3 is higher than that of the tobacco rod 1, it is preferable that the diameter thereof is smaller than the diameter of the tobacco rod 1.
- the diameter of the cooling segment and the mouthpiece is preferably 6.9 mm.
- Mouthpiece is a member that constitutes the mouthpiece end.
- the mouthpiece 5 includes a filter 52 and a center hole filter 54 in this order toward the mouthpiece end direction.
- the filter 52 a known solid filter member such as an acetate filter or a paper filter can be used.
- the paper filter is a paper-filled filter prepared by processing paper with a crepe roller or the like to form wrinkles and winding it with a plug-winding paper.
- the acetate filter is a filter filled with cellulose acetate fibers.
- the single fineness of the fibers constituting the acetate filter is preferably 5 to 12 (denier / filament), and more preferably 5 to 8 (denier / filament).
- the total fineness of the fiber is preferably 12,000 to 35,000 (denier / total), more preferably 20,000 to 30,000 (denier / total).
- the filtration by the filter is small. If the single fineness is large, the filtration rate decreases, but on the other hand, it becomes difficult to manufacture an acetate filter. On the other hand, if the total fineness is small, the filtration rate is lowered, but if the total fineness is too small, the fiber packing density is excessively lowered and the hardness of the acetate filter is lowered. From these viewpoints, by setting the single fineness and the total fineness within the above numerical ranges, an acetate filter having a low filtration rate and suitable for use can be obtained.
- the cross-sectional shape of the fiber is not limited, but an R shape or a Y shape is preferable, and a Y shape is more preferable from the viewpoint of cost.
- triacetin can also be used as a plasticizer in order to increase the hardness of the filter.
- the amount of triacetin added is preferably 5 to 10% by weight based on the tow weight.
- the center hole filter 54 for example, one having a space provided in the center of the filter can be used.
- the hole diameter is preferably 20 to 70%, more preferably 20 to 40% of the filter diameter.
- the hole diameter is preferably 1.0 to 5.0 mm.
- the preferable lower limit value is 1.2 mm or more or 1.5 mm or more, and the preferable upper limit value is 4.5 mm or less, 3.0 mm or less, or 2.5 mm or less.
- the wall thickness (thickness of the wall portion) of the filter is preferably 1 to 3 mm, more preferably 2 to 3 mm.
- a filter having a diameter of 7 mm and a hole having a diameter of 4.5 mm can be mentioned.
- the cross-sectional area of the hole is preferably 0.7 to 20 mm 2 , more preferably 1.6 to 16 mm 2 .
- a center hole filter having a plurality of holes may be used. In this case, the plurality of holes may be arranged at equal intervals along the circumferential direction, for example.
- the total cross-sectional area of the plurality of holes is preferably 0.7 to 20 mm 2 , more preferably 1.6 to 16 mm 2 .
- the length of the filter 52 and the center hole filter 54 is preferably about 9 to 16% with respect to the total length of the non-combustion heating type flavor suction device 10, respectively. In one aspect, the length of each of the filter 52 and the center hole filter 54 is about 5 to 9 mm.
- Each of the filter 52 and the center hole filter 54 may be wound by a filter wrapper (filter inner wrapper), and they may be connected by a filter molding paper (filter outer wrapper).
- the diameter of the mouthpiece 5 is not limited, but is preferably the same as that of the cooling segment 3.
- the center hole filter 54 preferably has a certain hardness. This is because the center hole filter 54 is less likely to be deformed and the contact area with the user's lips is smaller, so that the user is less likely to feel an unpleasant temperature.
- the hardness in the present invention means resistance when a member is deformed, as disclosed in paragraphs 0010 to 0014 of Japanese Patent Application Laid-Open No. 2016-523565. Hardness can be determined from the change in diameter before and after applying a load to the side surface of the tobacco rod. Specifically, the hardness is measured as follows. 1) Place the center hole filter on the substrate so that its longitudinal direction is horizontal, and measure its height Ds. 2) The side surface of the center hole filter is pressurized and compressed using a pressurizing jig.
- the hardness of the center hole filter 54 is preferably 90% or more, more preferably 93% or more, and further preferably 95% or more.
- the upper limit is not limited, but is about 99% or less or 98% or less.
- the single fineness of the fibers constituting the center hole filter is preferably 5 to 12 (denier / filament), and more preferably 5 to 8 (denier / filament).
- the total fineness of the fiber is preferably 30,000 to 60,000 (denier / total), and more preferably 35,000 to 45,000 (denier / total).
- the cross-sectional shape of the fiber is preferably R shape or Y shape, and the Y shape is more preferable from the viewpoint of cost. In the non-combustion heating type flavor suction device, the amount of aerosol produced is smaller than that in the normal combustion type flavor suction device, so that it is preferable that the aerosol loss in the center hole filter is small.
- the toe filling density of the wall portion of the center hole filter is high to some extent within the range where high-speed manufacturing is possible.
- a center hole filter having a low filtration rate and suitable for use can be obtained.
- triacetin can also be used as a plasticizer in order to increase the hardness of the filter.
- the amount of triacetin added is preferably 10 to 20% by weight based on the tow weight.
- Chip Paper 7 refers to paper used for connecting two or more of the tobacco rod 1, the cooling segment 3, and the mouthpiece 5.
- the wrapper refers to a paper for winding individual members constituting the tobacco rod 1, the cooling segment 3, or the mouthpiece 5.
- the base paper used for the chip paper and the wrapper is not limited, and examples thereof include those using cellulose fibers.
- a cellulose fiber either a plant-derived fiber or a chemically synthesized fiber may be used, or a mixture thereof may be used.
- plant-derived fibers include pulps such as flax fiber, wood fiber, and seed fiber, which may be unbleached colored unbleached pulp. It is preferable to use bleached pulp bleached with a bleaching agent such as a reducing agent.
- citric acid alkali metal salt or the like is used as an ordinary combustion regulator (combustion agent, etc.) that can affect the natural combustion speed of the wrapping paper.
- the wrapper since it is a heated flavor suction device, the wrapper does not have to contain a combustion regulator.
- the tobacco filler of the present invention may contain an aerosol generation source as described above. In this case, it is preferable to use oil-resistant and water-resistant wrapping paper as the chip paper.
- the lower limit of the basis weight of the wrapper is preferably 30 g / m 2 or more, more preferably 35 g / m 2 or more, and further preferably 40 g / m 2 or more.
- the upper limit is preferably 65 g / m 2 or less, more preferably 50 g / m 2 or less.
- the lower limit of the basis weight of the chip paper is preferably 20 g / m 2 or more, more preferably 25 g / m 2 or more, and further preferably 30 g / m 2 or more.
- the upper limit is preferably 50 g / m 2 or less, more preferably 45 g / m 2 or less, still more preferably 40 g / m 2 or less.
- Basis weight can be measured by the method specified in JIS P8124.
- the non-combustion heating type flavor suction device of the present invention may include members other than the above as long as the effects of the present invention are not impaired. Examples of such a member include a support member and the like. These members may be arranged at arbitrary positions, but are preferably not arranged at the mouthpiece end. Further, the non-combustion heating type flavor suction device of the present invention may be provided with a carbon heat source on the upstream side of the tobacco rod, that is, at the tip of the flavor suction device. In this embodiment, the tobacco rod is heated by a carbon heat source. However, the non-combustion heating type flavor suction device of the present invention is particularly useful for an electric heating system in which the heating temperature becomes higher than that of the carbon heat source heating system.
- the non-combustion heating type flavor suction device of the present invention does not make the user feel uncomfortable with the temperature near the mouthpiece end during use (during suction).
- the reason for this is not limited, but it can be inferred as follows.
- the non-combustion heating type flavor suction device of the present invention includes a filter 52 and a center hole filter 54 in this order as a mouthpiece in the direction of the mouthpiece end.
- the aerosol is first introduced into the filter 52.
- the ventilation resistance decreases and the flow path suddenly narrows.
- the flow velocity of the aerosol increases and the time of staying in the center hole filter 54 becomes shorter. Therefore, it is considered that the user is less likely to feel an unpleasant high temperature.
- the manufacturing method of the non-combustion heating type flavor suction device of the present invention is not limited, but the tobacco rod 1 and the mouthpiece 5 are prepared respectively, and the cooling segment 3 is formed between the tobacco rod 1 and the mouthpiece 5. Then, these can be manufactured by winding them with chip paper 7.
- a tobacco rod 1, a paper tube as a cooling segment 3, and a mouthpiece 5 are prepared respectively, and these three members are wound with chip paper 7. Can be manufactured.
- the non-combustion heating type flavor suction system of the present invention includes a non-combustion heating type flavor suction device 10 and a heater 30.
- the heater preferably electrically heats the tobacco rod 1.
- the heater preferably includes a heating unit including a power source or the like.
- FIG. 2 shows one aspect of the non-combustion heating type system of the present invention.
- 100 is a non-combustion heating type flavor suction system
- 10 is a non-combustion heating type flavor suction device
- 30 is a heating unit provided with a heater.
- the shape of the heater is not limited, and it may be arranged on the outer circumference of the tobacco rod 1 or may be inserted inside the tobacco rod 1.
- the heater may be, for example, a sheet heater, a flat plate heater, a tubular heater, or a needle heater.
- the sheet-shaped heater is a flexible sheet-shaped heater, and examples thereof include a heater containing a heat-resistant polymer film (thickness of about 20 to 225 ⁇ m) such as polyimide.
- the flat plate heater is a rigid flat plate heater (thickness of about 200 to 500 ⁇ m), and examples thereof include a heater having a resistance circuit on a flat plate base material and having the portion as a heat generating portion.
- the tubular heater is a hollow or solid tubular heater, and examples thereof include a heater having a resistance circuit on the outer peripheral surface and having the portion as a heat generating portion.
- the cross-sectional shape of the tubular heater may be a circle, an ellipse, a polygon, a polygon with rounded corners, or the like.
- the tubular heater and the needle-shaped heater are suitable for a method in which the tobacco rod 1 is inserted inside and heated from the inside.
- Example 1 The following members were prepared. Tobacco rod with a diameter of 7.1 mm and a length of 20 mm (manufactured by Japan Tobacco Inc.) Center hole filter (8Y-40000) with a diameter of 6.9 mm, a hole diameter of 4.5 mm, and a length of 8 mm. Acetate filter with a diameter of 6.9 mm and a length of 7 mm (5Y-30000) These members were arranged as shown in FIG. 1 and wrapped with chip paper of 24 mm ⁇ 40 mm to produce a non-combustion heating type flavor suction device.
- a heating device for heating the non-combustion heating type flavor suction device As a heating device for heating the non-combustion heating type flavor suction device, a cylindrical heater having a length of 22.5 mm and a diameter of 7.2, a battery for heating the heater, and a heater and a battery are controlled. A heating unit equipped with a control circuit and a housing for each member was prepared. The non-combustion heating type flavor suction device was inserted into the heater to obtain a non-combustion type heating type flavor suction system.
- the heater was heated to 230 ° C. within 17 seconds and maintained at that temperature for 23 seconds. Then, a smoking test was conducted using an automatic smoking device (RM26 manufactured by Borgwaldt). Specifically, the test was conducted using an apparatus as shown in FIG. In FIG. 3, 10 is a non-combustion heating type flavor suction device, 30 is a heating unit, 200 is an adapter, and 300 is an automatic smoking device.
- the adapter 200 houses the non-combustion heating type flavor suction device 10 and is connected to the automatic smoking device 300.
- K 1 is a fixed film thermocouples with polyimide tape 5mm position from mouth end a surface of the non-combustion heating type flavor suction device 10.
- K 2 is a wire thermocouple fixed to the adapter 200. The surface temperature of the mouthpiece by K 1, to measure the smoke temperature by K 2. The suction capacity was 35 mL / 2 sec. The results are shown in Table 1.
- Example 1 A non-combustion type heating type flavor suction system was prepared and evaluated in the same manner as in Example 1 except that the acetate filter and the center hole filter were replaced. The results are shown in Table 1.
- Non-combustion heating type flavor suction device 30 Heating unit equipped with a heater 100 Non-combustion heating type flavor suction system 200 Adapter 300 Automatic smoking device K 1 film thermocouple K 2 wire thermocouple
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Abstract
Provided is a non-combustion heating type flavor inhaler provided with a cigarette rod, a cooling segment, and a mouthpiece, wherein the mouthpiece is provided with a filter and a center hole filter toward the mouthpiece mouth end in this order.
Description
本発明はたばこロッド、冷却セグメント、およびマウスピースを備える非燃焼加熱型香味吸引器具に関する。
The present invention relates to a non-combustion heating type flavor suction device including a tobacco rod, a cooling segment, and a mouthpiece.
近年、非燃焼加熱型香味吸引器具をデバイスに挿入して使用する製品が市販されている(例えば特許文献1)。これらの非燃焼加熱型香味吸引器具は、デバイスへの挿入のしやすさや、十分な香喫味の送達の観点から、ある一定以上の太さが望まれる。しかし、非燃焼加熱型香味吸引器具の直径が大きくなると当該器具に与えられる熱量が増え、かつ唇と接触する面積も大きくなる。この結果、吸口端近傍の温度が上昇し、ユーザーが、使用時に吸口端近傍の温度を不快に感じるおそれがあった。
In recent years, a product in which a non-combustion heating type flavor suction device is inserted into a device and used is commercially available (for example, Patent Document 1). These non-combustion heating type flavor suction devices are desired to have a certain thickness or more from the viewpoint of ease of insertion into the device and delivery of sufficient flavor and taste. However, as the diameter of the non-combustion heating type flavor suction device increases, the amount of heat given to the device increases and the area in contact with the lips also increases. As a result, the temperature near the mouthpiece end rises, and the user may feel uncomfortable with the temperature near the mouthpiece end during use.
本発明は、使用時に吸口端近傍がユーザーにとって不快でない温度となる非燃焼加熱型香味吸引器具を提供することを課題とする。
An object of the present invention is to provide a non-combustion heating type flavor suction device in which the temperature near the mouthpiece end is not unpleasant for the user during use.
特許文献1に記載の香味吸引器具は、吸口端方向に向かってフィルタと紙管をこの順に備えるマウスピースを有する。しかし発明者らは、特許文献1に記載の香味吸引器具には改善の余地があると考え、本発明を完成した。すなわち、前記課題は以下の本発明によって解決される。
[1]たばこロッド、冷却セグメント、およびマウスピースを備える非燃焼加熱型香味吸引器具であって、
前記マウスピースが、吸口端方向に向かってフィルタとセンターホールフィルターをこの順に備える、前記香味吸引器具。
[2]前記センターホールフィルターの穴径は、当該センターホールフィルターの直径の20~40%である、[1]に記載の香味吸引器具。
[3]前記センターホールフィルターの下記方法で測定した硬さが90%以上である、[1]または[2]に記載の香味吸引器具。
測定方法
1)センターホールフィルターを、その長手方向が水平となるようにして基板の上に載置し、その高さDsを測定する。
2)加圧治具を用いて前記センターホールフィルター側面を加圧して圧縮する。
加圧:300g、加圧時間:10秒、加圧治具ヘッド径:φ12mm
3)加圧後の前記センターホールフィルターの高さDdを測定する
4)硬さH(%)を下記式より算出する。
H(%)=Dd/Ds×100
[4]前記硬さが95%以上である、[3]に記載の香味吸引器具。
[5]前記センターホールフィルターの肉厚が1~3mmである、[1]~[4]のいずれかに記載の香味吸引器具。
[6]前記センターホールフィルターの穴の断面積が、0.7~20mm2である、[1]~[5]のいずれかに記載の香味吸引器具。
[7]前記センターホールフィルターの単繊度が5~12(デニール/フィラメント)である、[1]~[6]のいずれかに記載の香味吸引器具。
[8]前記センターホールフィルターの単繊度が5~8(デニール/フィラメント)である、[7]に記載の香味吸引器具。
[9]前記センターホールフィルターの総繊度が30,000~60,000(デニール/トータル)である、[1]~[8]のいずれかに記載の香味吸引器具。
[10]前記センターホールフィルターの総繊度が35,000~45,000(デニール/トータル)である、[9]に記載の香味吸引器具。
[11]直径が6~8mmである、[1]~[10]のいずれかに記載の香味吸引器具。 The flavor suction device described inPatent Document 1 has a mouthpiece provided with a filter and a paper tube in this order toward the mouthpiece end direction. However, the inventors considered that there is room for improvement in the flavor suction device described in Patent Document 1, and completed the present invention. That is, the above-mentioned problem is solved by the following invention.
[1] A non-combustion heating type flavor suction device including a tobacco rod, a cooling segment, and a mouthpiece.
The flavor suction device, wherein the mouthpiece includes a filter and a center hole filter in this order toward the mouthpiece end direction.
[2] The flavor suction device according to [1], wherein the hole diameter of the center hole filter is 20 to 40% of the diameter of the center hole filter.
[3] The flavor suction device according to [1] or [2], wherein the hardness of the center hole filter measured by the following method is 90% or more.
Measuring method 1) Place the center hole filter on the substrate so that its longitudinal direction is horizontal, and measure its height Ds.
2) The side surface of the center hole filter is pressurized and compressed using a pressurizing jig.
Pressurization: 300 g, pressurization time: 10 seconds, pressurization jig head diameter: φ12 mm
3) Measure the height Dd of the center hole filter after pressurization. 4) Calculate the hardness H (%) from the following formula.
H (%) = Dd / Ds × 100
[4] The flavor suction device according to [3], wherein the hardness is 95% or more.
[5] The flavor suction device according to any one of [1] to [4], wherein the center hole filter has a wall thickness of 1 to 3 mm.
[6] The flavor suction device according to any one of [1] to [5], wherein the cross-sectional area of the hole of the center hole filter is 0.7 to 20 mm 2.
[7] The flavor suction device according to any one of [1] to [6], wherein the center hole filter has a single fineness of 5 to 12 (denier / filament).
[8] The flavor suction device according to [7], wherein the center hole filter has a single fineness of 5 to 8 (denier / filament).
[9] The flavor suction device according to any one of [1] to [8], wherein the center hole filter has a total fineness of 30,000 to 60,000 (denier / total).
[10] The flavor suction device according to [9], wherein the center hole filter has a total fineness of 35,000 to 45,000 (denier / total).
[11] The flavor suction device according to any one of [1] to [10], which has a diameter of 6 to 8 mm.
[1]たばこロッド、冷却セグメント、およびマウスピースを備える非燃焼加熱型香味吸引器具であって、
前記マウスピースが、吸口端方向に向かってフィルタとセンターホールフィルターをこの順に備える、前記香味吸引器具。
[2]前記センターホールフィルターの穴径は、当該センターホールフィルターの直径の20~40%である、[1]に記載の香味吸引器具。
[3]前記センターホールフィルターの下記方法で測定した硬さが90%以上である、[1]または[2]に記載の香味吸引器具。
測定方法
1)センターホールフィルターを、その長手方向が水平となるようにして基板の上に載置し、その高さDsを測定する。
2)加圧治具を用いて前記センターホールフィルター側面を加圧して圧縮する。
加圧:300g、加圧時間:10秒、加圧治具ヘッド径:φ12mm
3)加圧後の前記センターホールフィルターの高さDdを測定する
4)硬さH(%)を下記式より算出する。
H(%)=Dd/Ds×100
[4]前記硬さが95%以上である、[3]に記載の香味吸引器具。
[5]前記センターホールフィルターの肉厚が1~3mmである、[1]~[4]のいずれかに記載の香味吸引器具。
[6]前記センターホールフィルターの穴の断面積が、0.7~20mm2である、[1]~[5]のいずれかに記載の香味吸引器具。
[7]前記センターホールフィルターの単繊度が5~12(デニール/フィラメント)である、[1]~[6]のいずれかに記載の香味吸引器具。
[8]前記センターホールフィルターの単繊度が5~8(デニール/フィラメント)である、[7]に記載の香味吸引器具。
[9]前記センターホールフィルターの総繊度が30,000~60,000(デニール/トータル)である、[1]~[8]のいずれかに記載の香味吸引器具。
[10]前記センターホールフィルターの総繊度が35,000~45,000(デニール/トータル)である、[9]に記載の香味吸引器具。
[11]直径が6~8mmである、[1]~[10]のいずれかに記載の香味吸引器具。 The flavor suction device described in
[1] A non-combustion heating type flavor suction device including a tobacco rod, a cooling segment, and a mouthpiece.
The flavor suction device, wherein the mouthpiece includes a filter and a center hole filter in this order toward the mouthpiece end direction.
[2] The flavor suction device according to [1], wherein the hole diameter of the center hole filter is 20 to 40% of the diameter of the center hole filter.
[3] The flavor suction device according to [1] or [2], wherein the hardness of the center hole filter measured by the following method is 90% or more.
Measuring method 1) Place the center hole filter on the substrate so that its longitudinal direction is horizontal, and measure its height Ds.
2) The side surface of the center hole filter is pressurized and compressed using a pressurizing jig.
Pressurization: 300 g, pressurization time: 10 seconds, pressurization jig head diameter: φ12 mm
3) Measure the height Dd of the center hole filter after pressurization. 4) Calculate the hardness H (%) from the following formula.
H (%) = Dd / Ds × 100
[4] The flavor suction device according to [3], wherein the hardness is 95% or more.
[5] The flavor suction device according to any one of [1] to [4], wherein the center hole filter has a wall thickness of 1 to 3 mm.
[6] The flavor suction device according to any one of [1] to [5], wherein the cross-sectional area of the hole of the center hole filter is 0.7 to 20 mm 2.
[7] The flavor suction device according to any one of [1] to [6], wherein the center hole filter has a single fineness of 5 to 12 (denier / filament).
[8] The flavor suction device according to [7], wherein the center hole filter has a single fineness of 5 to 8 (denier / filament).
[9] The flavor suction device according to any one of [1] to [8], wherein the center hole filter has a total fineness of 30,000 to 60,000 (denier / total).
[10] The flavor suction device according to [9], wherein the center hole filter has a total fineness of 35,000 to 45,000 (denier / total).
[11] The flavor suction device according to any one of [1] to [10], which has a diameter of 6 to 8 mm.
本発明によって、使用時に吸口端近傍がユーザーにとって不快でない温度となる非燃焼加熱型香味吸引器具を提供できる。
INDUSTRIAL APPLICABILITY According to the present invention, it is possible to provide a non-combustion heating type flavor suction device in which the temperature near the mouthpiece end is not unpleasant for the user during use.
以下、本発明を詳細に説明する。本発明において「X~Y」はその端値であるXおよびYを含む。
Hereinafter, the present invention will be described in detail. In the present invention, "X to Y" includes X and Y which are the fractional values thereof.
1.非燃焼加熱型香味吸引器具
本発明の非燃焼加熱型香味吸引器具は、たばこロッド、冷却セグメント、およびマウスピースを備え、当該マウスピースが、吸口端方向に向かってフィルタとセンターホールフィルターをこの順に備える。図1は本発明の非燃焼加熱型香味吸引器具の一態様を示す。図中、10は非燃焼加熱型香味吸引器具、1はたばこロッド、3は冷却セグメント、5はマウスピース、52はフィルタ、54はセンターホールフィルター、7はチップペーパ、Vはベンチレーションである。香味吸引器具の直径は好ましくは6~8mmである。当該直径は香味吸引器具を構成する部材の直径の平均値として定義される。 1. 1. Non-combustion heating type flavor suction device The non-combustion heating type flavor suction device of the present invention includes a tobacco rod, a cooling segment, and a mouthpiece, and the mouthpiece sets a filter and a center hole filter in this order toward the mouthpiece end. Be prepared. FIG. 1 shows an aspect of the non-combustion heating type flavor suction device of the present invention. In the figure, 10 is a non-combustion heating type flavor suction device, 1 is a tobacco rod, 3 is a cooling segment, 5 is a mouthpiece, 52 is a filter, 54 is a center hole filter, 7 is a chip paper, and V is ventilation. The diameter of the flavor suction device is preferably 6 to 8 mm. The diameter is defined as the average value of the diameters of the members constituting the flavor suction device.
本発明の非燃焼加熱型香味吸引器具は、たばこロッド、冷却セグメント、およびマウスピースを備え、当該マウスピースが、吸口端方向に向かってフィルタとセンターホールフィルターをこの順に備える。図1は本発明の非燃焼加熱型香味吸引器具の一態様を示す。図中、10は非燃焼加熱型香味吸引器具、1はたばこロッド、3は冷却セグメント、5はマウスピース、52はフィルタ、54はセンターホールフィルター、7はチップペーパ、Vはベンチレーションである。香味吸引器具の直径は好ましくは6~8mmである。当該直径は香味吸引器具を構成する部材の直径の平均値として定義される。 1. 1. Non-combustion heating type flavor suction device The non-combustion heating type flavor suction device of the present invention includes a tobacco rod, a cooling segment, and a mouthpiece, and the mouthpiece sets a filter and a center hole filter in this order toward the mouthpiece end. Be prepared. FIG. 1 shows an aspect of the non-combustion heating type flavor suction device of the present invention. In the figure, 10 is a non-combustion heating type flavor suction device, 1 is a tobacco rod, 3 is a cooling segment, 5 is a mouthpiece, 52 is a filter, 54 is a center hole filter, 7 is a chip paper, and V is ventilation. The diameter of the flavor suction device is preferably 6 to 8 mm. The diameter is defined as the average value of the diameters of the members constituting the flavor suction device.
(1)たばこロッド
たばこロッドとは、たばこ原料に含まれる香喫味成分を発生するための略円柱状の部材であり、たばこ充填材とその周囲を巻装するラッパーを備える。たばこ充填材としては限定されず、例えばたばこ刻、たばこシート等を使用できる。具体的には、乾燥したたばこ葉を幅0.8~1.2mmに裁刻したたばこ刻をラッパー内に充填してよい。また乾燥したたばこ葉を平均粒径が20~200μm程度になるように粉砕して均一化したものをシート加工し、それを幅0.8~1.2mmに裁刻したものをラッパー内に充填してもよい。当該シートを裁刻せずにギャザー加工、折り畳み、あるいは渦巻き状にして内に充填してもよい。当該シートを短冊状に裁断してこれらをラッパー内に、同心円状にあるいは短冊の長手方向がたばこロッドの長手方向と平行になるように充填してもよい。 (1) Tobacco rod The tobacco rod is a substantially columnar member for generating a flavor component contained in a tobacco raw material, and includes a tobacco filler and a wrapper around the tobacco filler. The tobacco filler is not limited, and for example, tobacco engraving, tobacco sheet, or the like can be used. Specifically, the wrapper may be filled with tobacco chopped by chopping dried tobacco leaves to a width of 0.8 to 1.2 mm. In addition, dried tobacco leaves are crushed to an average particle size of about 20 to 200 μm, homogenized, processed into a sheet, and cut into a width of 0.8 to 1.2 mm and filled in a wrapper. You may. The sheet may be gathered, folded, or swirled and filled therein without engraving. The sheet may be cut into strips and filled in the wrapper concentrically or so that the longitudinal direction of the strips is parallel to the longitudinal direction of the tobacco rod.
たばこロッドとは、たばこ原料に含まれる香喫味成分を発生するための略円柱状の部材であり、たばこ充填材とその周囲を巻装するラッパーを備える。たばこ充填材としては限定されず、例えばたばこ刻、たばこシート等を使用できる。具体的には、乾燥したたばこ葉を幅0.8~1.2mmに裁刻したたばこ刻をラッパー内に充填してよい。また乾燥したたばこ葉を平均粒径が20~200μm程度になるように粉砕して均一化したものをシート加工し、それを幅0.8~1.2mmに裁刻したものをラッパー内に充填してもよい。当該シートを裁刻せずにギャザー加工、折り畳み、あるいは渦巻き状にして内に充填してもよい。当該シートを短冊状に裁断してこれらをラッパー内に、同心円状にあるいは短冊の長手方向がたばこロッドの長手方向と平行になるように充填してもよい。 (1) Tobacco rod The tobacco rod is a substantially columnar member for generating a flavor component contained in a tobacco raw material, and includes a tobacco filler and a wrapper around the tobacco filler. The tobacco filler is not limited, and for example, tobacco engraving, tobacco sheet, or the like can be used. Specifically, the wrapper may be filled with tobacco chopped by chopping dried tobacco leaves to a width of 0.8 to 1.2 mm. In addition, dried tobacco leaves are crushed to an average particle size of about 20 to 200 μm, homogenized, processed into a sheet, and cut into a width of 0.8 to 1.2 mm and filled in a wrapper. You may. The sheet may be gathered, folded, or swirled and filled therein without engraving. The sheet may be cut into strips and filled in the wrapper concentrically or so that the longitudinal direction of the strips is parallel to the longitudinal direction of the tobacco rod.
たばこ葉としては様々なものを用いることができ、例えば、黄色種、バーレー種、オリエント種、在来種、その他のニコチアナ-タバカム系品種、ニコチアナ-ルスチカ系品種、およびこれらの混合物を使用できる。混合物としては、目的とする味となるように前記の各品種を適宜ブレンドしたものを用いることができる。前記たばこの品種の詳細は、「たばこの事典、たばこ総合研究センター、2009.3.31」に開示されている。
Various tobacco leaves can be used, for example, yellow varieties, Burley varieties, Orient varieties, native varieties, other Nicotiana-Tabacam varieties, Nicotiana rustica varieties, and mixtures thereof. As the mixture, a mixture obtained by appropriately blending each of the above varieties so as to obtain a desired taste can be used. Details of the tobacco varieties are disclosed in "Tobacco Encyclopedia, Tobacco Academic Studies Center, 2009.3.31".
前記均一化シートの製造方法、すなわち、たばこ葉を粉砕して均一化シートに加工する方法は、公知の方法で実施できる。例えば、以下の方法を選択できる。抄紙プロセスを用いて抄造シートを作製する方法。水等の適切な溶媒を、粉砕したたばこ葉に混ぜて均一化した後に金属製板もしくは金属製板ベルトの上に均一化物を薄くキャスティングし、乾燥させてキャストシートを作製する方法。水等の適切な溶媒を、粉砕したたばこ葉に混ぜて均一化したものをシート状に押し出し成型して圧延シートを作製する方法。前記均一化シートの種類については、「たばこの事典、たばこ総合研究センター、2009.3.31」に詳細が開示されている。
The method for producing the homogenized sheet, that is, the method for crushing tobacco leaves and processing them into a homogenized sheet can be carried out by a known method. For example, the following methods can be selected. A method of making a papermaking sheet using a papermaking process. A method in which an appropriate solvent such as water is mixed with crushed tobacco leaves to homogenize the mixture, and then the homogenized product is thinly cast on a metal plate or a metal plate belt and dried to prepare a cast sheet. A method of producing a rolled sheet by mixing an appropriate solvent such as water with crushed tobacco leaves and extruding the homogenized material into a sheet. Details of the types of the homogenized sheet are disclosed in "Tobacco Encyclopedia, Tobacco Academic Studies Center, 2009.3.31".
たばこ充填物は水分を含んでいてよく、その含有量はたばこ充填物の全量に対して10~15重量%であってよく、11~13重量%であることが好ましい。当該量の水分を含む含有量たばこ充填物を用いると、染みの発生が抑制され、また、たばこロッドの製造時の巻上適性が良好となる。
The tobacco filling may contain water, and the content thereof may be 10 to 15% by weight, preferably 11 to 13% by weight, based on the total amount of the tobacco filling. When a tobacco filling containing the amount of water is used, the generation of stains is suppressed, and the hoisting suitability of the tobacco rod during production is improved.
たばこロッド1は、加熱に伴って蒸気を発生してもよい。エアロゾルの発生を促進するためにたばこ充填材にグリセリン、プロピレングリコール、1,3-ブタンジオール等のポリオール等のエアロゾル源を添加することが好ましい。エアロゾル源の添加量は、たばこ充填剤の乾燥重量に対して5~50重量%が好ましく、10~30重量%がより好ましい。たばこロッド1の長さは限定されないが15~25mmであることが好ましい。その直径も限定されないが6~8mmであることが好ましい。
The tobacco rod 1 may generate steam as it is heated. It is preferable to add an aerosol source such as a polyol such as glycerin, propylene glycol or 1,3-butanediol to the tobacco filler in order to promote the generation of aerosol. The amount of the aerosol source added is preferably 5 to 50% by weight, more preferably 10 to 30% by weight, based on the dry weight of the tobacco filler. The length of the tobacco rod 1 is not limited, but is preferably 15 to 25 mm. The diameter is not limited, but is preferably 6 to 8 mm.
たばこロッド1は香料を含んでいてもよい。当該香料の種類は、特に限定されず、良好な喫味を付与する観点から、以下のものを挙げることができる。アセトアニソール、アセトフェノン、アセチルピラジン、2-アセチルチアゾール、アルファルファエキストラクト、アミルアルコール、酪酸アミル、トランス-アネトール、スターアニス油、リンゴ果汁、ペルーバルサム油、ミツロウアブソリュート、ベンズアルデヒド、ベンゾインレジノイド、ベンジルアルコール、安息香酸ベンジル、フェニル酢酸ベンジル、プロピオン酸ベンジル、2,3-ブタンジオン、2-ブタノール、酪酸ブチル、酪酸、カラメル、カルダモン油、キャロブアブソリュート、β-カロテン、ニンジンジュース、L-カルボン、β-カリオフィレン、カシア樹皮油、シダーウッド油、セロリーシード油、カモミル油、シンナムアルデヒド、ケイ皮酸、シンナミルアルコール、ケイ皮酸シンナミル、シトロネラ油、DL-シトロネロール、クラリセージエキストラクト、ココア、コーヒー、コニャック油、コリアンダー油、クミンアルデヒド、ダバナ油、δ-デカラクトン、γ-デカラクトン、デカン酸、ディルハーブ油、3,4-ジメチル-1,2-シクロペンタンジオン、4,5-ジメチル-3-ヒドロキシ-2,5-ジヒドロフラン-2-オン、3,7-ジメチル-6-オクテン酸、2,3-ジメチルピラジン、2,5-ジメチルピラジン、2,6-ジメチルピラジン、2-メチル酪酸エチル、酢酸エチル、酪酸エチル、ヘキサン酸エチル、イソ吉草酸エチル、乳酸エチル、ラウリン酸エチル、レブリン酸エチル、エチルマルトール、オクタン酸エチル、オレイン酸エチル、パルミチン酸エチル、フェニル酢酸エチル、プロピオン酸エチル、ステアリン酸エチル、吉草酸エチル、エチルバニリン、エチルバニリングルコシド、2-エチル-3,(5または6)-ジメチルピラジン、5-エチル-3-ヒドロキシ-4-メチル-2(5H)-フラノン、2-エチル-3-メチルピラジン、ユーカリプトール、フェネグリークアブソリュート、ジェネアブソリュート、リンドウ根インフュージョン、ゲラニオール、酢酸ゲラニル、ブドウ果汁、グアヤコール、グァバエキストラクト、γ-ヘプタラクトン、γ-ヘキサラクトン、ヘキサン酸、シス-3-ヘキセン-1-オール、酢酸ヘキシル、ヘキシルアルコール、フェニル酢酸ヘキシル、ハチミツ、4-ヒドロキシ-3-ペンテン酸ラクトン、4-ヒドロキシ-4-(3-ヒドロキシ-1-ブテニル)-3,5,5-トリメチル-2-シクロヘキセン-1-オン、4-(パラ-ヒドロキシフェニル)-2-ブタノン、4-ヒドロキシウンデカン酸ナトリウム、インモルテルアブソリュート、β-イオノン、酢酸イソアミル、酪酸イソアミル、フェニル酢酸イソアミル、酢酸イソブチル、フェニル酢酸イソブチル、ジャスミンアブソリュート、コーラナッツティンクチャー、ラブダナム油、レモンテルペンレス油、カンゾウエキストラクト、リナロール、酢酸リナリル、ロベージ根油、マルトール、メープルシロップ、メンソール、メントン、酢酸L-メンチル、パラメトキシベンズアルデヒド、メチル-2-ピロリルケトン、アントラニル酸メチル、フェニル酢酸メチル、サリチル酸メチル、4’-メチルアセトフェノン、メチルシクロペンテノロン、3-メチル吉草酸、ミモザアブソリュート、トウミツ、ミリスチン酸、ネロール、ネロリドール、γ-ノナラクトン、ナツメグ油、δ-オクタラクトン、オクタナール、オクタン酸、オレンジフラワー油、オレンジ油、オリス根油、パルミチン酸、ω-ペンタデカラクトン、ペパーミント油、プチグレインパラグアイ油、フェネチルアルコール、フェニル酢酸フェネチル、フェニル酢酸、ピペロナール、プラムエキストラクト、プロペニルグアエトール、酢酸プロピル、3-プロピリデンフタリド、プルーン果汁、ピルビン酸、レーズンエキストラクト、ローズ油、ラム酒、セージ油、サンダルウッド油、スペアミント油、スチラックスアブソリュート、マリーゴールド油、ティーディスティレート、α-テルピネオール、酢酸テルピニル、5,6,7,8-テトラヒドロキノキサリン、1,5,5,9-テトラメチル-13-オキサシクロ(8.3.0.0(4.9))トリデカン、2,3,5,6-テトラメチルピラジン、タイム油、トマトエキストラクト、2-トリデカノン、クエン酸トリエチル、4-(2,6,6-トリメチル-1-シクロヘキセニル)2-ブテン-4-オン、2,6,6-トリメチル-2-シクロヘキセン-1,4-ジオン、4-(2,6,6-トリメチル-1,3-シクロヘキサジエニル)2-ブテン-4-オン、2,3,5-トリメチルピラジン、γ-ウンデカラクトン、γ-バレロラクトン、バニラエキストラクト、バニリン、ベラトルアルデヒド、バイオレットリーフアブソリュート、N-エチル-p-メンタン-3-カルボアミド(WS-3)、エチル-2-(p-メンタン-3-カルボキサミド)アセテート(WS-5)。中でもメンソールが好ましい。また、これらの香料は単独で用いてもよく、または2種以上を併用してもよい。
Tobacco rod 1 may contain a fragrance. The type of the flavor is not particularly limited, and the following can be mentioned from the viewpoint of imparting a good taste. Acetanisol, acetophenone, acetylpyrazine, 2-acetylthiazole, alfalfa extract, amyl alcohol, amyl butyrate, trans-annetol, staranis oil, apple juice, peruvian balsam oil, honeylow absolute, benzaldehyde, benzoin resinoid, benzyl alcohol, benzo Benzyl acid, benzyl phenylacetate, benzyl propionate, 2,3-butandione, 2-butanol, butyl butyrate, butyric acid, caramel, cardamon oil, carob absolute, β-carotene, carrot juice, L-carboxylic, β-cariophyllene, cassia Bark oil, cedar wood oil, celery seed oil, camomill oil, cinnamaldehyde, silicic acid, cinnamyl alcohol, cinnamyl silicate oil, citronella oil, DL-citronellol, clarisage extract, cocoa, coffee, cognac oil, coriander oil, Cuminaldehyde, dabana oil, δ-decalactone, γ-decalactone, decanoic acid, dilherb oil, 3,4-dimethyl-1,2-cyclopentandione, 4,5-dimethyl-3-hydroxy-2,5-dihydro Fran-2-one, 3,7-dimethyl-6-octenoic acid, 2,3-dimethylpyrazine, 2,5-dimethylpyrazine, 2,6-dimethylpyrazine, ethyl 2-methylbutyrate, ethyl acetate, ethyl butyrate, Ethyl hexanoate, ethyl isovalerate, ethyl lactate, ethyl laurate, ethyl levulinate, ethyl maltol, ethyl octanate, ethyl oleate, ethyl palmitate, ethyl phenylacetate, ethyl propionate, ethyl stearate, ethyl valerate , Ethyl vanillin, ethyl vanillin glucoside, 2-ethyl-3, (5 or 6) -dimethylpyrazine, 5-ethyl-3-hydroxy-4-methyl-2 (5H) -furanone, 2-ethyl-3-methylpyrazine , Eucalyptor, Fenegrik Absolute, Gene Absolute, Lindou Root Infusion, Geraniol, Geranyl Acetate, Grape Juice, Guayacol, Guava Extract, γ-Heptalactone, γ-Hexalactone, Hexanoic Acid, Sis-3-hexene-1 -Ol, hexyl acetate, hexyl alcohol, hexyl phenylacetate, honey, 4-hydroxy-3-pentenoic acid lactone, 4-hydroxy-4- (3-hydroxy-1-butenyl) -3,5,5-trimethyl-2 -Cyclohe Xen-1-one, 4- (para-hydroxyphenyl) -2-butanone, sodium 4-hydroxyundecanoate, immortelle absolute, β-ionone, isoamyl acetate, isoamyl butyrate, isoamyl phenylacetate, isobutyl acetate, phenylacetic acid Isobutyl, jasmine absolute, cola nut tincture, labdanum oil, lemon terpenless oil, kanzo extract, linalol, linaryl acetate, lobage root oil, maltol, maple syrup, menthol, menthon, L-mentyl acetate, paramethoxybenzaldehyde, methyl -2-Pyrrolyl ketone, Methyl anthranilate, Methyl phenylacetate, Methyl salicylate, 4'-Methylacetophenone, Methylcyclopentenolone, 3-Methylvaleric acid, Mimosa absolute, Toumitsu, Myristic acid, Nerol, Nerolidol, γ-Nonalactone, Natsumeg oil, δ-octalactone, octanal, octanoic acid, orange flower oil, orange oil, oris root oil, palmitic acid, ω-pentadecalactone, peppermint oil, petitgrain paraguay oil, phenethyl alcohol, phenylacetate phenethyl, phenylacetic acid , Piperonal, plum extract, propenylguaetol, propyl acetate, 3-propylidenephthalide, prune juice, pyruvate, raisin extract, rose oil, lamb liquor, sage oil, sandalwood oil, sparemint oil, stylux Absolute, Marigold Oil, Tea Distillate, α-Terpineol, Terpinyl Acetate, 5,6,7,8-Tetrahydroquinoxalin, 1,5,5,9-Tetramethyl-13-oxacyclo (8.3.0.0) (4.9)) Tridecane, 2,3,5,6-tetramethylpyrazine, thyme oil, tomato extract, 2-toridecanone, triethyl citrate, 4- (2,6,6-trimethyl-1-cyclohexenyl) ) 2-Buten-4-one, 2,6,6-trimethyl-2-cyclohexene-1,4-dione, 4- (2,6,6-trimethyl-1,3-cyclohexadienyl) 2-butene- 4-one, 2,3,5-trimethylpyrazine, γ-undecalactone, γ-valerolactone, vanilla extract, vanillin, veratoraldehyde, violet leaf absolute, N-ethyl-p-menthan-3-carbamide ( WS-3), ethyl-2- (p-menthane) -3-Carboxamide) Acetate (WS-5). Of these, menthol is preferable. In addition, these fragrances may be used alone or in combination of two or more.
たばこ充填物の充填密度は特に限定されないが、非燃焼加熱型香味吸引器具の特性を担保し、良好な喫味を付与する観点から、通常250mg/cm3以上であり、好ましくは320mg/cm3以上である。また、その上限は通常800mg/cm3以下であり、好ましくは600mg/cm3以下である。
The packing density of the tobacco filling is not particularly limited, but is usually 250 mg / cm 3 or more, preferably 320 mg / cm 3 or more, from the viewpoint of ensuring the characteristics of the non-combustion heating type flavor suction device and imparting a good taste. Is. The upper limit thereof is usually 800 mg / cm 3 or less, preferably 600 mg / cm 3 or less.
(2)冷却セグメント
冷却セグメントは、たばこロッド1で発生した香喫味成分や蒸気を冷却する等してエアロゾル化を促進するための部材である。冷却セグメント3は中空の紙管であってよい。紙管はラッパーやチップペーパよりも剛性の高いカードボードで構成されることが好ましい。当該紙管には、ベンチレーションV(開孔)を設けてもよい。ベンチレーションは紙管の円周に沿って複数設けられることが好ましい。冷却セグメントの吸口側端部から加熱端に向かって、ベンチレーションが設けられる位置の上限は、エアロゾル化の促進や冷却の観点から、冷却セグメントの吸口側端部から4mm以内の範囲が好ましく、2mm以内の範囲がさらに好ましい。また、ベンチレーションが設けられる位置の下限は、製品全体の耐久性の観点から、冷却セグメントの吸口側端部から0.5mm以上が好ましく1.0mm以上がさらに好ましい。すなわち、一態様において、ベンチレーションは冷却セグメントの吸口側端部から上流に向かって0.5~4mmの範囲に設けられ、別態様において1.0~2mmの範囲に設けられる。作業効率の観点から、ベンチレーションは、完成した非燃焼加熱型香味吸引器具にレーザー加工を施して設けることが好ましい。また冷却セグメント3内には、熱交換効率を高めるためにギャザー付けされたシートを充填してもよい。冷却セグメント3の寸法は限定されないが、長さは15~25mmであることが好ましく、直径は5.5~7.5mmであることが好ましい。 (2) Cooling segment The cooling segment is a member for promoting aerosolization by cooling the flavor components and steam generated in thetobacco rod 1. The cooling segment 3 may be a hollow paper tube. The paper tube is preferably composed of a card board having a higher rigidity than a wrapper or chip paper. Ventilation V (opening) may be provided in the paper tube. It is preferable that a plurality of ventilations are provided along the circumference of the paper tube. From the viewpoint of promoting aerosolization and cooling, the upper limit of the position where ventilation is provided from the mouthpiece side end of the cooling segment to the heating end is preferably within 4 mm from the mouthpiece side end of the cooling segment, and is preferably 2 mm. The range within is more preferable. Further, the lower limit of the position where the ventilation is provided is preferably 0.5 mm or more, more preferably 1.0 mm or more from the mouthpiece side end of the cooling segment from the viewpoint of durability of the entire product. That is, in one embodiment, the ventilation is provided in the range of 0.5 to 4 mm upstream from the mouthpiece side end of the cooling segment, and in another embodiment, it is provided in the range of 1.0 to 2 mm. From the viewpoint of work efficiency, it is preferable that the ventilation is provided by laser processing the completed non-combustion heating type flavor suction device. Further, the cooling segment 3 may be filled with a gathered sheet in order to increase the heat exchange efficiency. The dimensions of the cooling segment 3 are not limited, but the length is preferably 15 to 25 mm, and the diameter is preferably 5.5 to 7.5 mm.
冷却セグメントは、たばこロッド1で発生した香喫味成分や蒸気を冷却する等してエアロゾル化を促進するための部材である。冷却セグメント3は中空の紙管であってよい。紙管はラッパーやチップペーパよりも剛性の高いカードボードで構成されることが好ましい。当該紙管には、ベンチレーションV(開孔)を設けてもよい。ベンチレーションは紙管の円周に沿って複数設けられることが好ましい。冷却セグメントの吸口側端部から加熱端に向かって、ベンチレーションが設けられる位置の上限は、エアロゾル化の促進や冷却の観点から、冷却セグメントの吸口側端部から4mm以内の範囲が好ましく、2mm以内の範囲がさらに好ましい。また、ベンチレーションが設けられる位置の下限は、製品全体の耐久性の観点から、冷却セグメントの吸口側端部から0.5mm以上が好ましく1.0mm以上がさらに好ましい。すなわち、一態様において、ベンチレーションは冷却セグメントの吸口側端部から上流に向かって0.5~4mmの範囲に設けられ、別態様において1.0~2mmの範囲に設けられる。作業効率の観点から、ベンチレーションは、完成した非燃焼加熱型香味吸引器具にレーザー加工を施して設けることが好ましい。また冷却セグメント3内には、熱交換効率を高めるためにギャザー付けされたシートを充填してもよい。冷却セグメント3の寸法は限定されないが、長さは15~25mmであることが好ましく、直径は5.5~7.5mmであることが好ましい。 (2) Cooling segment The cooling segment is a member for promoting aerosolization by cooling the flavor components and steam generated in the
前述のとおり、ベンチレーションは冷却セグメントの外周面の周方向に配置されることが好ましい。その周方向の配置の数は、限定されず2つ以上であればよい。孔径は100~1000μmであることが好ましく、300~800μmであることがより好ましい。開孔形状は略円形または略楕円形であることが好ましい。略楕円形の場合、長径が孔径に相当する。
As described above, the ventilation is preferably arranged in the circumferential direction of the outer peripheral surface of the cooling segment. The number of arrangements in the circumferential direction is not limited and may be two or more. The pore diameter is preferably 100 to 1000 μm, more preferably 300 to 800 μm. The opening shape is preferably substantially circular or substantially elliptical. In the case of a substantially elliptical shape, the major axis corresponds to the hole diameter.
冷却セグメント3はたばこロッド1に比べて剛性が低い場合が多い。このような異なる剛性を持つパーツをチップペーパで接続する場合、剛性が高いパーツの直径を剛性が低いパーツの直径よりも小さくすると不良が発生しにくい。したがって、たばこロッド1に比べて冷却セグメント3の剛性が高い場合は、その直径をたばこロッド1の直径より小さくすることが好ましい。例えば、たばこロッドの直径が7mmである場合、冷却セグメント、マウスピースの直径は好ましくは6.9mmである。
The cooling segment 3 is often less rigid than the tobacco rod 1. When connecting parts having such different rigidity with chip paper, if the diameter of the part having high rigidity is made smaller than the diameter of the part having low rigidity, defects are less likely to occur. Therefore, when the rigidity of the cooling segment 3 is higher than that of the tobacco rod 1, it is preferable that the diameter thereof is smaller than the diameter of the tobacco rod 1. For example, when the diameter of the tobacco rod is 7 mm, the diameter of the cooling segment and the mouthpiece is preferably 6.9 mm.
(3)マウスピース
マウスピースは吸口端を構成する部材である。本発明においてマウスピース5は、吸口端方向に向かってフィルタ52とセンターホールフィルター54をこの順に備える。 (3) Mouthpiece The mouthpiece is a member that constitutes the mouthpiece end. In the present invention, themouthpiece 5 includes a filter 52 and a center hole filter 54 in this order toward the mouthpiece end direction.
マウスピースは吸口端を構成する部材である。本発明においてマウスピース5は、吸口端方向に向かってフィルタ52とセンターホールフィルター54をこの順に備える。 (3) Mouthpiece The mouthpiece is a member that constitutes the mouthpiece end. In the present invention, the
(3-1)フィルタ
フィルタ52としてはアセテートフィルターやペーパーフィルター等の公知の中実なフィルタ部材を使用できる。ペーパーフィルターとは、紙をクレープローラ等で加工して皺を付けこれをプラグ巻取紙で巻上げて調製される、紙が充填されたフィルタである。アセテートフィルターとはセルロースアセテート繊維が充填されたフィルタである。アセテートフィルターを構成する繊維の単繊度は、好ましくは5~12(デニール/フィラメント)であり、より好ましくは5~8(デニール/フィラメント)である。当該繊維の総繊度は、好ましくは12,000~35,000(デニール/トータル)であり、より好ましくは20,000~30,000(デニール/トータル)である。非燃焼加熱型香味吸引器具においては、エアロゾル生成量が通常の燃焼型香味吸引器具と比較して少ないため、フィルタによる濾過は少ないことが好ましい。単繊度が大きいと濾過率は低下するが、一方でアセテートフィルターの製造が困難となる。一方、総繊度が小さいと濾過率は下がるが、総繊度が小さすぎると繊維充填密度が過度に低下してアセテートフィルターの硬さが低下する。これらの観点から、前記単繊度と総繊度を前記数値範囲にすることで濾過率が低く、かつ使用に適したアセテートフィルターを得ることができる。前記繊維の断面形状は限定されないが、R形状またはY形状が好ましく、コストの観点からはY形状がより好ましい。また、フィルタ硬さを高めるために、可塑剤としてトリアセチンを用いることもできる。トリアセチンの添加量は、トウ重量に対して5~10重量%であることが好ましい。 (3-1) Filter As thefilter 52, a known solid filter member such as an acetate filter or a paper filter can be used. The paper filter is a paper-filled filter prepared by processing paper with a crepe roller or the like to form wrinkles and winding it with a plug-winding paper. The acetate filter is a filter filled with cellulose acetate fibers. The single fineness of the fibers constituting the acetate filter is preferably 5 to 12 (denier / filament), and more preferably 5 to 8 (denier / filament). The total fineness of the fiber is preferably 12,000 to 35,000 (denier / total), more preferably 20,000 to 30,000 (denier / total). In the non-combustion heating type flavor suction device, since the amount of aerosol produced is smaller than that of the normal combustion type flavor suction device, it is preferable that the filtration by the filter is small. If the single fineness is large, the filtration rate decreases, but on the other hand, it becomes difficult to manufacture an acetate filter. On the other hand, if the total fineness is small, the filtration rate is lowered, but if the total fineness is too small, the fiber packing density is excessively lowered and the hardness of the acetate filter is lowered. From these viewpoints, by setting the single fineness and the total fineness within the above numerical ranges, an acetate filter having a low filtration rate and suitable for use can be obtained. The cross-sectional shape of the fiber is not limited, but an R shape or a Y shape is preferable, and a Y shape is more preferable from the viewpoint of cost. In addition, triacetin can also be used as a plasticizer in order to increase the hardness of the filter. The amount of triacetin added is preferably 5 to 10% by weight based on the tow weight.
フィルタ52としてはアセテートフィルターやペーパーフィルター等の公知の中実なフィルタ部材を使用できる。ペーパーフィルターとは、紙をクレープローラ等で加工して皺を付けこれをプラグ巻取紙で巻上げて調製される、紙が充填されたフィルタである。アセテートフィルターとはセルロースアセテート繊維が充填されたフィルタである。アセテートフィルターを構成する繊維の単繊度は、好ましくは5~12(デニール/フィラメント)であり、より好ましくは5~8(デニール/フィラメント)である。当該繊維の総繊度は、好ましくは12,000~35,000(デニール/トータル)であり、より好ましくは20,000~30,000(デニール/トータル)である。非燃焼加熱型香味吸引器具においては、エアロゾル生成量が通常の燃焼型香味吸引器具と比較して少ないため、フィルタによる濾過は少ないことが好ましい。単繊度が大きいと濾過率は低下するが、一方でアセテートフィルターの製造が困難となる。一方、総繊度が小さいと濾過率は下がるが、総繊度が小さすぎると繊維充填密度が過度に低下してアセテートフィルターの硬さが低下する。これらの観点から、前記単繊度と総繊度を前記数値範囲にすることで濾過率が低く、かつ使用に適したアセテートフィルターを得ることができる。前記繊維の断面形状は限定されないが、R形状またはY形状が好ましく、コストの観点からはY形状がより好ましい。また、フィルタ硬さを高めるために、可塑剤としてトリアセチンを用いることもできる。トリアセチンの添加量は、トウ重量に対して5~10重量%であることが好ましい。 (3-1) Filter As the
(3-2)センターホールフィルター
センターホールフィルター54としては、例えばフィルタの中央部に空間を設けたものを使用できる。この場合、穴径はフィルタ直径の20~70%であることが好ましく、20~40%であることがさらに好ましい。具体的に穴径は、好ましくは1.0~5.0mmである。その好ましい下限値は、1.2mm以上または1.5mm以上であり、その好ましい上限値は、4.5mm以下、3.0mm以下、または2.5mm以下である。フィルタの肉厚(壁部の厚み)は、好ましくは1~3mm、より好ましくは2~3mmである。穴径が下限値以下である穴の成形は困難であり、内壁に毛羽立ちが生じてしまいエアロゾルが補足され、デリバリー効率が低下することがある。また穴径が下限値以下である穴を形成するマンドレルの耐久性に問題が生じ、マンドレルが製造中に振動して穴がうねる等の穴の形状が不安定となる。また穴径が条件値を超えると、フィルタ硬さが担保できずに咥え心地が低下し、さらには肉厚が薄くなるので唾液等で濡れた場合に耐久性が低下するおそれもある。一態様において、センターホールフィルターとして、7mm直径のフィルタに径4.5mmの穴を設けたものが挙げられる。また、穴の断面積は、好ましくは0.7~20mm2であり、より好ましくは1.6~16mm2である。また、別態様として複数の穴孔を有するセンターホールフィルターを使用してもよい。この場合、複数の穴は例えば円周方向に沿って等間隔に配置されてもよい。複数の穴の合計の断面積は、好ましくは0.7~20mm2であり、より好ましくは1.6~16mm2である。 (3-2) Center Hall Filter As thecenter hole filter 54, for example, one having a space provided in the center of the filter can be used. In this case, the hole diameter is preferably 20 to 70%, more preferably 20 to 40% of the filter diameter. Specifically, the hole diameter is preferably 1.0 to 5.0 mm. The preferable lower limit value is 1.2 mm or more or 1.5 mm or more, and the preferable upper limit value is 4.5 mm or less, 3.0 mm or less, or 2.5 mm or less. The wall thickness (thickness of the wall portion) of the filter is preferably 1 to 3 mm, more preferably 2 to 3 mm. It is difficult to form a hole having a hole diameter of less than or equal to the lower limit value, and fluffing may occur on the inner wall to supplement the aerosol and reduce the delivery efficiency. In addition, there is a problem in the durability of the mandrel that forms a hole whose hole diameter is not more than the lower limit, and the shape of the hole becomes unstable, such as the mandrel vibrating during manufacturing and the hole undulates. Further, if the hole diameter exceeds the condition value, the hardness of the filter cannot be guaranteed and the gripping comfort is lowered, and further, the wall thickness is thinned, so that the durability may be lowered when wet with saliva or the like. In one aspect, as the center hole filter, a filter having a diameter of 7 mm and a hole having a diameter of 4.5 mm can be mentioned. The cross-sectional area of the hole is preferably 0.7 to 20 mm 2 , more preferably 1.6 to 16 mm 2 . Alternatively, a center hole filter having a plurality of holes may be used. In this case, the plurality of holes may be arranged at equal intervals along the circumferential direction, for example. The total cross-sectional area of the plurality of holes is preferably 0.7 to 20 mm 2 , more preferably 1.6 to 16 mm 2 .
センターホールフィルター54としては、例えばフィルタの中央部に空間を設けたものを使用できる。この場合、穴径はフィルタ直径の20~70%であることが好ましく、20~40%であることがさらに好ましい。具体的に穴径は、好ましくは1.0~5.0mmである。その好ましい下限値は、1.2mm以上または1.5mm以上であり、その好ましい上限値は、4.5mm以下、3.0mm以下、または2.5mm以下である。フィルタの肉厚(壁部の厚み)は、好ましくは1~3mm、より好ましくは2~3mmである。穴径が下限値以下である穴の成形は困難であり、内壁に毛羽立ちが生じてしまいエアロゾルが補足され、デリバリー効率が低下することがある。また穴径が下限値以下である穴を形成するマンドレルの耐久性に問題が生じ、マンドレルが製造中に振動して穴がうねる等の穴の形状が不安定となる。また穴径が条件値を超えると、フィルタ硬さが担保できずに咥え心地が低下し、さらには肉厚が薄くなるので唾液等で濡れた場合に耐久性が低下するおそれもある。一態様において、センターホールフィルターとして、7mm直径のフィルタに径4.5mmの穴を設けたものが挙げられる。また、穴の断面積は、好ましくは0.7~20mm2であり、より好ましくは1.6~16mm2である。また、別態様として複数の穴孔を有するセンターホールフィルターを使用してもよい。この場合、複数の穴は例えば円周方向に沿って等間隔に配置されてもよい。複数の穴の合計の断面積は、好ましくは0.7~20mm2であり、より好ましくは1.6~16mm2である。 (3-2) Center Hall Filter As the
フィルタ52とセンターホールフィルター54の長さはそれぞれ非燃焼加熱型香味吸引器具10の全長に対し、9~16%程度であることが好ましい。一態様においてフィルタ52とセンターホールフィルター54のそれぞれの長さは5~9mm程度である。
The length of the filter 52 and the center hole filter 54 is preferably about 9 to 16% with respect to the total length of the non-combustion heating type flavor suction device 10, respectively. In one aspect, the length of each of the filter 52 and the center hole filter 54 is about 5 to 9 mm.
フィルタ52とセンターホールフィルター54のそれぞれがフィルターラッパー(フィルターインナーラッパー)によって巻装され、それらがフィルタ成型紙(フィルターアウターラッパー)によって接続されていてもよい。マウスピース5の直径は限定されないが、冷却セグメント3と同じであることが好ましい。
Each of the filter 52 and the center hole filter 54 may be wound by a filter wrapper (filter inner wrapper), and they may be connected by a filter molding paper (filter outer wrapper). The diameter of the mouthpiece 5 is not limited, but is preferably the same as that of the cooling segment 3.
センターホールフィルター54はある一定の硬さを有することが好ましい。センターホールフィルター54が変形しにくく、ユーザーの唇との接触面積が小さくなるので、ユーザーが不快な温度を感じにくくなるからである。本発明における硬さは、特表2016-523565号公報明細書段落0010~0014に開示されているとおり、部材が変形するときの抵抗を意味する。たばこロッドの側面に負荷をかける前と後での直径の変化から硬さを求めることができる。具体的に、硬さは以下のようにして測定される。
1)センターホールフィルターを、その長手方向が水平となるようにして基板の上に載置し、その高さDsを測定する。
2)加圧治具を用いて前記センターホールフィルター側面を加圧して圧縮する。
加圧:300g、加圧時間:10秒、加圧治具ヘッド径:φ12mm
3)加圧後の前記センターホールフィルターの高さDdを測定する
4)硬さH(%)を下記式より算出する。
H(%)=Dd/Ds×100 Thecenter hole filter 54 preferably has a certain hardness. This is because the center hole filter 54 is less likely to be deformed and the contact area with the user's lips is smaller, so that the user is less likely to feel an unpleasant temperature. The hardness in the present invention means resistance when a member is deformed, as disclosed in paragraphs 0010 to 0014 of Japanese Patent Application Laid-Open No. 2016-523565. Hardness can be determined from the change in diameter before and after applying a load to the side surface of the tobacco rod. Specifically, the hardness is measured as follows.
1) Place the center hole filter on the substrate so that its longitudinal direction is horizontal, and measure its height Ds.
2) The side surface of the center hole filter is pressurized and compressed using a pressurizing jig.
Pressurization: 300 g, pressurization time: 10 seconds, pressurization jig head diameter: φ12 mm
3) Measure the height Dd of the center hole filter after pressurization. 4) Calculate the hardness H (%) from the following formula.
H (%) = Dd / Ds × 100
1)センターホールフィルターを、その長手方向が水平となるようにして基板の上に載置し、その高さDsを測定する。
2)加圧治具を用いて前記センターホールフィルター側面を加圧して圧縮する。
加圧:300g、加圧時間:10秒、加圧治具ヘッド径:φ12mm
3)加圧後の前記センターホールフィルターの高さDdを測定する
4)硬さH(%)を下記式より算出する。
H(%)=Dd/Ds×100 The
1) Place the center hole filter on the substrate so that its longitudinal direction is horizontal, and measure its height Ds.
2) The side surface of the center hole filter is pressurized and compressed using a pressurizing jig.
Pressurization: 300 g, pressurization time: 10 seconds, pressurization jig head diameter: φ12 mm
3) Measure the height Dd of the center hole filter after pressurization. 4) Calculate the hardness H (%) from the following formula.
H (%) = Dd / Ds × 100
センターホールフィルター54の硬さは、好ましくは90%以上、より好ましくは93%以上、さらに好ましくは95%以上である。その上限は限定されないが、99%以下または98%以下程度である。
The hardness of the center hole filter 54 is preferably 90% or more, more preferably 93% or more, and further preferably 95% or more. The upper limit is not limited, but is about 99% or less or 98% or less.
センターホールフィルターを構成する繊維の単繊度は、好ましくは5~12(デニール/フィラメント)であり、より好ましくは5~8(デニール/フィラメント)である。また、当該繊維の総繊度は、好ましくは30,000~60,000(デニール/トータル)であり、より好ましくは35,000~45,000(デニール/トータル)である。繊維の断面形状は好ましくはR形状またはY形状であり、コスト面からはY形状がより好ましい。非燃焼加熱型香味吸引器具においては、エアロゾル生成量が通常の燃焼型香味吸引器具と比較して少ないため、センターホールフィルターにおけるエアロゾルのロスは少ないことが好ましい。センターホールフィルターの壁部(ニク部)の繊維の充填密度が低すぎると、当該部分でエアロゾルが濾過されてしまう。したがって、センターホールフィルターは高速製造が可能である範囲で壁部のトウ充填密度がある程度高いことが好ましい。前記単繊度と総繊度を前記数値範囲にすることで濾過率が低く、かつ使用に適したセンターホールフィルターを得ることができる。また、フィルタ硬さを高めるために、可塑剤としてトリアセチンを用いることもできる。トリアセチンの添加量は、トウ重量に対して10~20重量%であることが好ましい。
The single fineness of the fibers constituting the center hole filter is preferably 5 to 12 (denier / filament), and more preferably 5 to 8 (denier / filament). The total fineness of the fiber is preferably 30,000 to 60,000 (denier / total), and more preferably 35,000 to 45,000 (denier / total). The cross-sectional shape of the fiber is preferably R shape or Y shape, and the Y shape is more preferable from the viewpoint of cost. In the non-combustion heating type flavor suction device, the amount of aerosol produced is smaller than that in the normal combustion type flavor suction device, so that it is preferable that the aerosol loss in the center hole filter is small. If the fiber filling density of the wall portion (nik portion) of the center hole filter is too low, the aerosol will be filtered at that portion. Therefore, it is preferable that the toe filling density of the wall portion of the center hole filter is high to some extent within the range where high-speed manufacturing is possible. By setting the single fineness and the total fineness within the above numerical ranges, a center hole filter having a low filtration rate and suitable for use can be obtained. In addition, triacetin can also be used as a plasticizer in order to increase the hardness of the filter. The amount of triacetin added is preferably 10 to 20% by weight based on the tow weight.
(4)チップペーパ
チップペーパ7は、たばこロッド1、冷却セグメント3、マウスピース5のうち2つ以上を接続するために用いる紙をいう。一方、ラッパーは、たばこロッド1、冷却セグメント3、またはマウスピース5を構成する個々の部材を巻装するための紙をいう。 (4) Chip Paper Thechip paper 7 refers to paper used for connecting two or more of the tobacco rod 1, the cooling segment 3, and the mouthpiece 5. On the other hand, the wrapper refers to a paper for winding individual members constituting the tobacco rod 1, the cooling segment 3, or the mouthpiece 5.
チップペーパ7は、たばこロッド1、冷却セグメント3、マウスピース5のうち2つ以上を接続するために用いる紙をいう。一方、ラッパーは、たばこロッド1、冷却セグメント3、またはマウスピース5を構成する個々の部材を巻装するための紙をいう。 (4) Chip Paper The
チップペーパおよびラッパーに用いられる原紙は、限定されず、セルロース繊維を用いたものを挙げることができる。そのようなセルロース繊維としては、植物由来のもの、化学合成されたもののいずれを用いてもよく、これらの混合物であってもよい。植物由来の繊維としては、亜麻繊維や木材繊維、種子繊維等のパルプが挙げられ、漂白していない有色の未晒パルプとしてもよいが、白く清潔感のある外観とするために、酸化剤、還元剤等の漂白剤を用いて漂白した晒パルプの使用が好ましい。
The base paper used for the chip paper and the wrapper is not limited, and examples thereof include those using cellulose fibers. As such a cellulose fiber, either a plant-derived fiber or a chemically synthesized fiber may be used, or a mixture thereof may be used. Examples of plant-derived fibers include pulps such as flax fiber, wood fiber, and seed fiber, which may be unbleached colored unbleached pulp. It is preferable to use bleached pulp bleached with a bleaching agent such as a reducing agent.
通常のシガレット用の巻紙の場合、巻紙の自然燃焼速度に影響を及ぼし得る通常の燃焼調節剤(助燃剤等)としてクエン酸アルカリ金属塩等が使用される。本発明では加熱型香味吸引器具品とするため、ラッパーは燃焼調節剤を含まなくてもよい。また、通常のシガレットと異なり、前述のとおり本発明のたばこ充填材にはエアロゾル発生源が含まれうる。この場合、チップペーパとして耐油性、耐水性巻紙を用いることが好ましい。
In the case of ordinary cigarette wrapping paper, citric acid alkali metal salt or the like is used as an ordinary combustion regulator (combustion agent, etc.) that can affect the natural combustion speed of the wrapping paper. In the present invention, since it is a heated flavor suction device, the wrapper does not have to contain a combustion regulator. Further, unlike ordinary cigarettes, the tobacco filler of the present invention may contain an aerosol generation source as described above. In this case, it is preferable to use oil-resistant and water-resistant wrapping paper as the chip paper.
ラッパーの坪量の下限は、好ましくは30g/m2以上であり、より好ましくは35g/m2以上であり、さらに好ましくは40g/m2以上である。上限は、好ましくは65g/m2以下、より好ましくは50g/m2以下である。また、チップペーパの坪量の下限は、好ましくは20g/m2以上であり、より好ましくは25g/m2以上であり、さらに好ましくは30g/m2以上である。上限は、好ましくは50g/m2以下、より好ましくは45g/m2以下、さらに好ましくは40g/m2以下である。坪量は、JIS P8124に規定される方法で測定することができる。
The lower limit of the basis weight of the wrapper is preferably 30 g / m 2 or more, more preferably 35 g / m 2 or more, and further preferably 40 g / m 2 or more. The upper limit is preferably 65 g / m 2 or less, more preferably 50 g / m 2 or less. The lower limit of the basis weight of the chip paper is preferably 20 g / m 2 or more, more preferably 25 g / m 2 or more, and further preferably 30 g / m 2 or more. The upper limit is preferably 50 g / m 2 or less, more preferably 45 g / m 2 or less, still more preferably 40 g / m 2 or less. Basis weight can be measured by the method specified in JIS P8124.
本発明の非燃焼加熱型香味吸引器具は、発明の効果を損なわない範囲で、上記以外の部材を備えていてもよい。このような部材としては、支持部材等が挙げられる。これらの部材は任意の位置に配置されてよいが、吸口端部には配置されないことが好ましい。また、本発明の非燃焼加熱型香味吸引器具はたばこロッドの上流側、すなわち香味吸引器具の先端部に、炭素熱源を備えていてもよい。この態様においては、たばこロッドは炭素熱源によって加熱される。しかしながら、本発明の非燃焼加熱型香味吸引器具は、炭素熱源加熱方式に比べて加熱温度がより高温になる電気加熱方式のシステムに特に有用である。
The non-combustion heating type flavor suction device of the present invention may include members other than the above as long as the effects of the present invention are not impaired. Examples of such a member include a support member and the like. These members may be arranged at arbitrary positions, but are preferably not arranged at the mouthpiece end. Further, the non-combustion heating type flavor suction device of the present invention may be provided with a carbon heat source on the upstream side of the tobacco rod, that is, at the tip of the flavor suction device. In this embodiment, the tobacco rod is heated by a carbon heat source. However, the non-combustion heating type flavor suction device of the present invention is particularly useful for an electric heating system in which the heating temperature becomes higher than that of the carbon heat source heating system.
本発明の非燃焼加熱型香味吸引器具は、ユーザーが使用時(吸引時)に吸口端近傍の温度を不快に感じない。この理由は限定されないが次のように推察される。本発明の非燃焼加熱型香味吸引器具は、マウスピースとして吸口端方向にフィルタ52とセンターホールフィルター54をこの順に備える。エアロゾルはまずフィルタ52に導入される。フィルタ52からセンターホール54に導入される際、通気抵抗が低下し、かつ流路が急に狭くなる。この際、エアロゾルは流速が上昇しセンターホールフィルター54に滞留する時間が短くなる。このため、ユーザーは不快な高い温度を感じにくくなると考えられる。
The non-combustion heating type flavor suction device of the present invention does not make the user feel uncomfortable with the temperature near the mouthpiece end during use (during suction). The reason for this is not limited, but it can be inferred as follows. The non-combustion heating type flavor suction device of the present invention includes a filter 52 and a center hole filter 54 in this order as a mouthpiece in the direction of the mouthpiece end. The aerosol is first introduced into the filter 52. When introduced from the filter 52 into the center hole 54, the ventilation resistance decreases and the flow path suddenly narrows. At this time, the flow velocity of the aerosol increases and the time of staying in the center hole filter 54 becomes shorter. Therefore, it is considered that the user is less likely to feel an unpleasant high temperature.
2.製造方法
本発明の非燃焼加熱型香味吸引器具の製造方法は限定されないが、たばこロッド1、マウスピース5をそれぞれ準備して、たばこロッド1とマウスピース5の間に冷却セグメント3を形成するようにして、これらをチップペーパ7で巻装して製造できる。あるいは、本発明の非燃焼加熱型香味吸引器具は、たばこロッド1と、冷却セグメント3としての紙管と、マウスピース5をそれぞれ準備して、これら3つの部材をチップペーパ7で巻装して製造できる。 2. Manufacturing Method The manufacturing method of the non-combustion heating type flavor suction device of the present invention is not limited, but thetobacco rod 1 and the mouthpiece 5 are prepared respectively, and the cooling segment 3 is formed between the tobacco rod 1 and the mouthpiece 5. Then, these can be manufactured by winding them with chip paper 7. Alternatively, in the non-combustion heating type flavor suction device of the present invention, a tobacco rod 1, a paper tube as a cooling segment 3, and a mouthpiece 5 are prepared respectively, and these three members are wound with chip paper 7. Can be manufactured.
本発明の非燃焼加熱型香味吸引器具の製造方法は限定されないが、たばこロッド1、マウスピース5をそれぞれ準備して、たばこロッド1とマウスピース5の間に冷却セグメント3を形成するようにして、これらをチップペーパ7で巻装して製造できる。あるいは、本発明の非燃焼加熱型香味吸引器具は、たばこロッド1と、冷却セグメント3としての紙管と、マウスピース5をそれぞれ準備して、これら3つの部材をチップペーパ7で巻装して製造できる。 2. Manufacturing Method The manufacturing method of the non-combustion heating type flavor suction device of the present invention is not limited, but the
3.非燃焼加熱型香味吸引システム
本発明の非燃焼加熱型香味吸引システムは、非燃焼加熱型香味吸引器具10とヒーター30を備える。ヒーターは、好ましくは電気的にたばこロッド1を加熱する。ヒーターは電源等を備える加熱ユニットを備えることが好ましい。図2に本発明の非燃焼加熱型システムの一態様を示す。図中、100は非燃焼加熱型香味吸引システム、10は非燃焼加熱型香味吸引器具、30はヒーターを備える加熱ユニットである。 3. 3. Non-combustion heating type flavor suction system The non-combustion heating type flavor suction system of the present invention includes a non-combustion heating typeflavor suction device 10 and a heater 30. The heater preferably electrically heats the tobacco rod 1. The heater preferably includes a heating unit including a power source or the like. FIG. 2 shows one aspect of the non-combustion heating type system of the present invention. In the figure, 100 is a non-combustion heating type flavor suction system, 10 is a non-combustion heating type flavor suction device, and 30 is a heating unit provided with a heater.
本発明の非燃焼加熱型香味吸引システムは、非燃焼加熱型香味吸引器具10とヒーター30を備える。ヒーターは、好ましくは電気的にたばこロッド1を加熱する。ヒーターは電源等を備える加熱ユニットを備えることが好ましい。図2に本発明の非燃焼加熱型システムの一態様を示す。図中、100は非燃焼加熱型香味吸引システム、10は非燃焼加熱型香味吸引器具、30はヒーターを備える加熱ユニットである。 3. 3. Non-combustion heating type flavor suction system The non-combustion heating type flavor suction system of the present invention includes a non-combustion heating type
ヒーターの形状は限定されず、たばこロッド1の外周に配置されてもよく、たばこロッド1の内部に挿入されてもよい。ヒーターは、例えばシート状ヒーター、平板状ヒーター、筒状ヒーター、ニードル状ヒーターであってよい。シート状ヒーターとは柔軟なシート形のヒーターであり、例えばポリイミド等の耐熱性ポリマーのフィルム(厚み20~225μm程度)を含むヒーターが挙げられる。平板状ヒーターとは剛直な平板形のヒーター(厚み200~500μm程度)であり、例えば平板基材上に抵抗回路を有し当該部分を発熱部とするヒーターが挙げられる。筒状ヒーターとは中空または中実の筒形のヒーターであり、例えば、外周面に抵抗回路を有し当該部分を発熱部とするヒーターが挙げられる。筒状ヒーターの断面形状は円、楕円、多角、角丸多角等であってよい。筒状ヒーターやニードル状ヒーターは、たばこロッド1の内部に挿入され内部から加熱する方式に好適である。
The shape of the heater is not limited, and it may be arranged on the outer circumference of the tobacco rod 1 or may be inserted inside the tobacco rod 1. The heater may be, for example, a sheet heater, a flat plate heater, a tubular heater, or a needle heater. The sheet-shaped heater is a flexible sheet-shaped heater, and examples thereof include a heater containing a heat-resistant polymer film (thickness of about 20 to 225 μm) such as polyimide. The flat plate heater is a rigid flat plate heater (thickness of about 200 to 500 μm), and examples thereof include a heater having a resistance circuit on a flat plate base material and having the portion as a heat generating portion. The tubular heater is a hollow or solid tubular heater, and examples thereof include a heater having a resistance circuit on the outer peripheral surface and having the portion as a heat generating portion. The cross-sectional shape of the tubular heater may be a circle, an ellipse, a polygon, a polygon with rounded corners, or the like. The tubular heater and the needle-shaped heater are suitable for a method in which the tobacco rod 1 is inserted inside and heated from the inside.
[実施例1]
以下の部材を準備した。
直径7.1mm、長さ20mmのたばこロッド(日本たばこ産業株式会社製)
直径6.9mm、穴径4.5mm、長さ8mmのセンターホールフィルター(8Y-40000)
直径6.9mm、長さ7mmのアセテートフィルター(5Y-30000)
これらの部材を図1に示すように配置し、24mm×40mmのチップペーパで巻装して非燃焼加熱型香味吸引器具を製造した。 [Example 1]
The following members were prepared.
Tobacco rod with a diameter of 7.1 mm and a length of 20 mm (manufactured by Japan Tobacco Inc.)
Center hole filter (8Y-40000) with a diameter of 6.9 mm, a hole diameter of 4.5 mm, and a length of 8 mm.
Acetate filter with a diameter of 6.9 mm and a length of 7 mm (5Y-30000)
These members were arranged as shown in FIG. 1 and wrapped with chip paper of 24 mm × 40 mm to produce a non-combustion heating type flavor suction device.
以下の部材を準備した。
直径7.1mm、長さ20mmのたばこロッド(日本たばこ産業株式会社製)
直径6.9mm、穴径4.5mm、長さ8mmのセンターホールフィルター(8Y-40000)
直径6.9mm、長さ7mmのアセテートフィルター(5Y-30000)
これらの部材を図1に示すように配置し、24mm×40mmのチップペーパで巻装して非燃焼加熱型香味吸引器具を製造した。 [Example 1]
The following members were prepared.
Tobacco rod with a diameter of 7.1 mm and a length of 20 mm (manufactured by Japan Tobacco Inc.)
Center hole filter (8Y-40000) with a diameter of 6.9 mm, a hole diameter of 4.5 mm, and a length of 8 mm.
Acetate filter with a diameter of 6.9 mm and a length of 7 mm (5Y-30000)
These members were arranged as shown in FIG. 1 and wrapped with chip paper of 24 mm × 40 mm to produce a non-combustion heating type flavor suction device.
当該非燃焼加熱型香味吸引器具を加熱するための加熱デバイスとして、長さ22.5mm、直径7.2の円筒状ヒーターと、当該ヒーターを加熱するためのバッテリと、ヒーターおよびバッテリを制御するための制御回路と、各部材を主要するためのハウジングを備えた加熱ユニットを準備した。当該ヒーター内に前記非燃焼加熱型香味吸引器具を挿入して、非燃焼型加熱型香味吸引システムを得た。
As a heating device for heating the non-combustion heating type flavor suction device, a cylindrical heater having a length of 22.5 mm and a diameter of 7.2, a battery for heating the heater, and a heater and a battery are controlled. A heating unit equipped with a control circuit and a housing for each member was prepared. The non-combustion heating type flavor suction device was inserted into the heater to obtain a non-combustion type heating type flavor suction system.
ヒーターを17秒間以内で230℃まで昇温し、当該温度を23秒間維持した。その後、自動喫煙装置(Bolgwaldt社製RM26)を用い喫煙試験を行った。具体的には図3に示すような装置を用いて試験を行った。図3中、10は非燃焼加熱型香味吸引器具、30は加熱ユニット、200はアダプター、300は自動喫煙装置である。アダプター200は非燃焼加熱型香味吸引器具10を収容し、自動喫煙装置300に接続されている。K1は、非燃焼加熱型香味吸引器具10の表面であって吸口端から5mmの位置にポリイミドテープを用いて固定された皮膜熱電対である。K2は、アダプター200に固定された素線熱電対である。K1によってマウスピースの表面温度を、K2によって煙温度を測定した。吸引容量は35mL/2secとした。結果を表1に示す。
The heater was heated to 230 ° C. within 17 seconds and maintained at that temperature for 23 seconds. Then, a smoking test was conducted using an automatic smoking device (RM26 manufactured by Borgwaldt). Specifically, the test was conducted using an apparatus as shown in FIG. In FIG. 3, 10 is a non-combustion heating type flavor suction device, 30 is a heating unit, 200 is an adapter, and 300 is an automatic smoking device. The adapter 200 houses the non-combustion heating type flavor suction device 10 and is connected to the automatic smoking device 300. K 1 is a fixed film thermocouples with polyimide tape 5mm position from mouth end a surface of the non-combustion heating type flavor suction device 10. K 2 is a wire thermocouple fixed to the adapter 200. The surface temperature of the mouthpiece by K 1, to measure the smoke temperature by K 2. The suction capacity was 35 mL / 2 sec. The results are shown in Table 1.
[比較例1]
アセテートフィルターとセンターホールフィルターを入れ替えた以外は実施例1と同様にして非燃焼型加熱型香味吸引システムを調製し、評価した。結果を表1に示す。 [Comparative Example 1]
A non-combustion type heating type flavor suction system was prepared and evaluated in the same manner as in Example 1 except that the acetate filter and the center hole filter were replaced. The results are shown in Table 1.
アセテートフィルターとセンターホールフィルターを入れ替えた以外は実施例1と同様にして非燃焼型加熱型香味吸引システムを調製し、評価した。結果を表1に示す。 [Comparative Example 1]
A non-combustion type heating type flavor suction system was prepared and evaluated in the same manner as in Example 1 except that the acetate filter and the center hole filter were replaced. The results are shown in Table 1.
本発明の非燃焼加熱型香味吸引器具システムは、比較用のシステムに比べてマウスピース部の表面温度が低いことが明らかとなった。ユーザーは、本発明の非燃焼加熱型香味吸引器具システムを快適に使用できる。
It was clarified that the surface temperature of the mouthpiece portion of the non-combustion heating type flavor suction device system of the present invention was lower than that of the comparison system. The user can comfortably use the non-combustion heating type flavor suction device system of the present invention.
1 たばこロッド
3 冷却セグメント
5 マウスピース
52 フィルタ
54 センターホールフィルター
7 チップペーパ
V ベンチレーション
10 非燃焼加熱型香味吸引器具
30 ヒーターを備える加熱ユニット
100 非燃焼加熱型香味吸引システム
200 アダプター
300 自動喫煙装置
K1 皮膜熱電対
K2 素線熱電対
1Tobacco rod 3 Cooling segment 5 Mouthpiece 52 Filter 54 Center hole filter 7 Chip paper V ventilation
10 Non-combustion heating typeflavor suction device 30 Heating unit equipped with a heater 100 Non-combustion heating type flavor suction system
200Adapter 300 Automatic smoking device K 1 film thermocouple K 2 wire thermocouple
3 冷却セグメント
5 マウスピース
52 フィルタ
54 センターホールフィルター
7 チップペーパ
V ベンチレーション
10 非燃焼加熱型香味吸引器具
30 ヒーターを備える加熱ユニット
100 非燃焼加熱型香味吸引システム
200 アダプター
300 自動喫煙装置
K1 皮膜熱電対
K2 素線熱電対
1
10 Non-combustion heating type
200
Claims (11)
- たばこロッド、冷却セグメント、およびマウスピースを備える非燃焼加熱型香味吸引器具であって、
前記マウスピースが、吸口端方向に向かってフィルタとセンターホールフィルターをこの順に備える、前記香味吸引器具。 A non-combustion heated flavor suction device with a tobacco rod, cooling segment, and mouthpiece.
The flavor suction device, wherein the mouthpiece includes a filter and a center hole filter in this order toward the mouthpiece end direction. - 前記センターホールフィルターの穴径は、当該センターホールフィルターの直径の20~40%である、請求項1に記載の香味吸引器具。 The flavor suction device according to claim 1, wherein the hole diameter of the center hole filter is 20 to 40% of the diameter of the center hole filter.
- 前記センターホールフィルターの下記方法で測定した硬さが90%以上である、請求項1または2に記載の香味吸引器具。
測定方法
1)センターホールフィルターを、その長手方向が水平となるようにして基板の上に載置し、その高さDsを測定する。
2)加圧治具を用いて前記センターホールフィルター側面を加圧して圧縮する。
加圧:300g、加圧時間:10秒、加圧治具ヘッド径:φ12mm
3)加圧後の前記センターホールフィルターの高さDdを測定する
4)硬さH(%)を下記式より算出する。
H(%)=Dd/Ds×100 The flavor suction device according to claim 1 or 2, wherein the hardness of the center hole filter measured by the following method is 90% or more.
Measuring method 1) Place the center hole filter on the substrate so that its longitudinal direction is horizontal, and measure its height Ds.
2) The side surface of the center hole filter is pressurized and compressed using a pressurizing jig.
Pressurization: 300 g, pressurization time: 10 seconds, pressurization jig head diameter: φ12 mm
3) Measure the height Dd of the center hole filter after pressurization. 4) Calculate the hardness H (%) from the following formula.
H (%) = Dd / Ds × 100 - 前記硬さが95%以上である、請求項3に記載の香味吸引器具。 The flavor suction device according to claim 3, wherein the hardness is 95% or more.
- 前記センターホールフィルターの肉厚が1~3mmである、請求項1~4のいずれかに記載の香味吸引器具。 The flavor suction device according to any one of claims 1 to 4, wherein the center hole filter has a wall thickness of 1 to 3 mm.
- 前記センターホールフィルターの穴の断面積が、0.7~20mm2である、請求項1~5のいずれかに記載の香味吸引器具。 The flavor suction device according to any one of claims 1 to 5, wherein the cross-sectional area of the hole of the center hole filter is 0.7 to 20 mm 2.
- 前記センターホールフィルターの単繊度が5~12(デニール/フィラメント)である、請求項1~6のいずれかに記載の香味吸引器具。 The flavor suction device according to any one of claims 1 to 6, wherein the center hole filter has a single fineness of 5 to 12 (denier / filament).
- 前記センターホールフィルターの単繊度が5~8(デニール/フィラメント)である、請求項7に記載の香味吸引器具。 The flavor suction device according to claim 7, wherein the center hole filter has a single fineness of 5 to 8 (denier / filament).
- 前記センターホールフィルターの総繊度が30,000~60,000(デニール/トータル)である、請求項1~8のいずれかに記載の香味吸引器具。 The flavor suction device according to any one of claims 1 to 8, wherein the total fineness of the center hole filter is 30,000 to 60,000 (denier / total).
- 前記センターホールフィルターの総繊度が35,000~45,000(デニール/トータル)である、請求項9に記載の香味吸引器具。 The flavor suction device according to claim 9, wherein the center hole filter has a total fineness of 35,000 to 45,000 (denier / total).
- 直径が6~8mmである、請求項1~10のいずれかに記載の香味吸引器具。
The flavor suction device according to any one of claims 1 to 10, which has a diameter of 6 to 8 mm.
Priority Applications (5)
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JP2021551044A JP7350870B2 (en) | 2019-10-10 | 2019-10-10 | Non-combustion heated flavor suction device |
PCT/JP2019/040038 WO2021070330A1 (en) | 2019-10-10 | 2019-10-10 | Non-combustion heating type flavor inhaler |
EP19948515.2A EP4042888A4 (en) | 2019-10-10 | 2019-10-10 | Non-combustion heating type flavor inhaler |
TW109106043A TW202114547A (en) | 2019-10-10 | 2020-02-25 | Non-combustion heating type flavor inhaler |
JP2023109979A JP2023123799A (en) | 2019-10-10 | 2023-07-04 | Non-combustion heating type flavor suction tool |
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WO2022230866A1 (en) * | 2021-04-27 | 2022-11-03 | 日本たばこ産業株式会社 | Tobacco sheet for non-combustion heating type flavor inhalers and method for producing same, non-combustion heating type flavor inhaler, and non-combustion heating type flavor inhalation system |
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2019
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- 2019-10-10 WO PCT/JP2019/040038 patent/WO2021070330A1/en unknown
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2020
- 2020-02-25 TW TW109106043A patent/TW202114547A/en unknown
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2023
- 2023-07-04 JP JP2023109979A patent/JP2023123799A/en active Pending
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2022230866A1 (en) * | 2021-04-27 | 2022-11-03 | 日本たばこ産業株式会社 | Tobacco sheet for non-combustion heating type flavor inhalers and method for producing same, non-combustion heating type flavor inhaler, and non-combustion heating type flavor inhalation system |
JP7545576B2 (en) | 2021-04-27 | 2024-09-04 | 日本たばこ産業株式会社 | Tobacco sheet for non-combustion heating type flavor inhaler and manufacturing method thereof, non-combustion heating type flavor inhaler, and non-combustion heating type flavor inhalation system |
Also Published As
Publication number | Publication date |
---|---|
TW202114547A (en) | 2021-04-16 |
EP4042888A4 (en) | 2023-06-28 |
JPWO2021070330A1 (en) | 2021-04-15 |
JP7350870B2 (en) | 2023-09-26 |
JP2023123799A (en) | 2023-09-05 |
EP4042888A1 (en) | 2022-08-17 |
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