WO2021027241A1 - Gan-based radio frequency device having п-shaped gate and manufacturing method therefor - Google Patents

Gan-based radio frequency device having п-shaped gate and manufacturing method therefor Download PDF

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WO2021027241A1
WO2021027241A1 PCT/CN2019/130988 CN2019130988W WO2021027241A1 WO 2021027241 A1 WO2021027241 A1 WO 2021027241A1 CN 2019130988 W CN2019130988 W CN 2019130988W WO 2021027241 A1 WO2021027241 A1 WO 2021027241A1
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gate
electrode
layer
gan
drain electrode
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PCT/CN2019/130988
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French (fr)
Chinese (zh)
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王洪
刘晓艺
周泉斌
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中山市华南理工大学现代产业技术研究院
华南理工大学
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/401Multistep manufacturing processes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/41Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
    • H01L29/423Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions not carrying the current to be rectified, amplified or switched
    • H01L29/42312Gate electrodes for field effect devices
    • H01L29/42316Gate electrodes for field effect devices for field-effect transistors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66446Unipolar field-effect transistors with an active layer made of a group 13/15 material, e.g. group 13/15 velocity modulation transistor [VMT], group 13/15 negative resistance FET [NERFET]
    • H01L29/66462Unipolar field-effect transistors with an active layer made of a group 13/15 material, e.g. group 13/15 velocity modulation transistor [VMT], group 13/15 negative resistance FET [NERFET] with a heterojunction interface channel or gate, e.g. HFET, HIGFET, SISFET, HJFET, HEMT
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/778Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface

Definitions

  • the invention relates to a radio frequency device, and more specifically to a GaN-based radio frequency device with a ⁇ -type gate and a preparation method thereof.
  • GaN-based HEMT devices have a wide range of applications in satellite, communications, radar and other fields.
  • GaN belongs to group III nitrides, has excellent breakdown ability, higher electron density and speed, high temperature resistance and radiation resistance, and is suitable for the development of high-frequency, high-temperature and high-power electronic devices.
  • the gate electrode section of the device is usually T-shaped.
  • the contact length between the T-type gate electrode and the AlGaN/GaN heterojunction epitaxial layer is small, and a higher cut-off frequency f T can be obtained, and at the same time.
  • the T-shaped gate electrode has a large-volume gate cap, which increases the cross-sectional area of the gate electrode along the current conduction direction and reduces the parasitic resistance of the gate electrode, thereby increasing the maximum oscillation frequency f MAX .
  • the lithography method of radio frequency devices usually adopts electron beam lithography.
  • Electron beam lithography refers to the use of electron beams to create patterns on the surface. Since electrons are waves with extremely short wavelengths, compared with other optical lithography processes, electron beam lithography has a higher precision and can reach the nanometer level. Therefore, electron beam lithography can effectively meet the requirements of the gate electrode size in HEMT devices.
  • the volume of the gate cap of the T-shaped gate needs to be increased.
  • a double-layer or three-layer photoresist is used to strip the gate electrode metal, or a part of the gate dielectric layer is etched as a gate foot, and a gate cap is deposited on the gate dielectric layer to prepare radio frequency devices.
  • the second solution although a smaller gate electrode length and a larger gate electrode length can be achieved
  • the length of the gate cap but introduces etching damage, resulting in device degradation, and the contact area between the gate dielectric layer and the gate cap is too large, which increases the capacitance of the gate source and the gate drain, and reduces the maximum oscillation frequency of the device.
  • how to obtain a larger gate cap length while ensuring a smaller gate electrode length without introducing etch damage or gate source and gate drain capacitance to achieve higher frequencies is a GaN-based radio frequency device Problems to be solved.
  • the purpose of the present invention is to overcome the defects and limitations of the gate electrode preparation technology of the existing GaN-based HEMT device, and propose a GaN-based radio frequency device with a ⁇ -type gate and a preparation method thereof from the perspective of the shape of the gate electrode and the preparation process.
  • the gate length can be effectively reduced while keeping the gate resistance as constant as possible, and the device frequency can be increased.
  • the present invention provides a GaN-based radio frequency device with a ⁇ -type gate, comprising an AlGaN/GaN heterojunction epitaxial layer, the AlGaN/GaN heterojunction epitaxial layer is a boss structure, the upper part of the boss is an active area, and the active area Both ends of the upper surface are connected to the source electrode and the drain electrode.
  • the upper surface of the AlGaN/GaN heterojunction epitaxial layer is connected to the area outside the active area, the sidewall of the active area, and the upper surface of the active area is connected to the source electrode and the drain electrode.
  • the area, the source electrode and the drain electrode are covered with a gate dielectric layer.
  • the gate dielectric layer is provided with an opening on the upper surface of the source electrode and the drain electrode to expose the upper surface of the source electrode and the drain electrode.
  • the upper surface of the gate dielectric layer The surface is connected to the ⁇ -type gate electrode, which is located between the source electrode and the drain electrode.
  • the ⁇ -type gate electrode includes a gate cap and a gate pin. One end of the gate pin is connected to the upper surface of the gate dielectric layer, and the other end is connected to the bottom of the gate cap.
  • the surface is used to support the grid cap, the grid foot includes a first grid foot and a second grid foot, and there is a space between the first grid foot and the second grid foot.
  • the left and right length of the cross section of the grid foot is L g , 10nm ⁇ L g ⁇ 300nm; the upper and lower length of the cross section of the grid foot, that is the height is H g , 0nm ⁇ H g ⁇ 5L g ; perpendicular to the cross section of the grid foot
  • the thickness of the grid foot in the direction, that is, the width is W g , W g ⁇ 1.2 ⁇ m; the distance between the first grid foot and the second grid foot is L interval , 0nm ⁇ L interval ⁇ 6L g ;
  • the first gate foot and the source electrode are located on the same side, and the distance between the first gate foot and the source electrode is L gs , L gs >(L cap -L interval -2L g )/2;
  • the drain electrode is located on the same side, and the distance between the second gate pin and the drain electrode is L gd , L gd >(L cap -L interval -2L g )/2.
  • the source electrode and the drain electrode are Ti/Al/Ni/Au metal layers; the source electrode and the drain electrode are both cuboid, the length of the source electrode and the drain electrode are L s and L d , and the heights are H s and H d respectively ,
  • the AlGaN/GaN heterojunction epitaxial layer is circular, with a diameter of 2-10 inches, and a thickness of 200 ⁇ m-1mm;
  • the length of the active area is L, L ⁇ L sd , the height is H, 100nm ⁇ H ⁇ 1mm, and the width is W, W ⁇ W g ; the source electrode and the drain electrode are located at both ends of the upper surface of the active area, the source and drain electrodes The bottom surface is completely in contact with the top surface of the active area.
  • the distance between the edge of the lower surface of the source and drain electrode and the edge of the active region parallel to it is not less than 500nm (because the embodiment is 500nm, 1um cannot be used, please verify it).
  • the material of the gate dielectric layer is any one of insulating metal oxide, SiO 2 and Si 3 N 4 , and the thickness of the gate dielectric layer is not less than 1 nm.
  • the present invention also provides a method for preparing a GaN-based radio frequency device with a ⁇ -type gate as described above, which includes the following steps:
  • Preparation and cleaning of AlGaN/GaN heterojunction epitaxial layer soak the AlGaN/GaN heterojunction epitaxial layer in an acid solution to remove the oxide layer on the surface, and then use the organic solution ultrasonic method to remove AlGaN/GaN heterogeneity Organic matter on the surface of the junction epitaxial layer;
  • the gate dielectric layer the upper surface of the AlGaN/GaN heterojunction epitaxial layer is connected to the area outside the active area, the sidewalls of the active area, the upper surface of the active area is connected to the area outside the source electrode and the drain electrode, and the source A gate dielectric layer is deposited on the electrode and the drain electrode;
  • Preparation of the gate electrode deposit a double-layer photoresist on the upper surface of the gate dielectric layer and the upper surface of the exposed source and drain electrodes, and make the pattern area of the gate cap on the top photoresist, exposing part of the bottom layer Photoresist, make the pattern area of the gate pin on the exposed part of the bottom photoresist, deposit the gate electrode material layer on the upper surface of the top photoresist, the pattern area of the gate cap and the pattern area of the gate pin, and peel off the top layer photoresist The gate electrode material layer on the upper surface of the resist is removed, and the double-layer photoresist is removed to form a ⁇ -type gate electrode.
  • the method for depositing the gate dielectric layer in step (4) is any one of plasma-enhanced chemical vapor deposition, atomic layer deposition, and magnetron sputtering; wet etching is used in step (5) Or dry etching method to remove part of the gate dielectric layer on the upper surface of the source electrode and drain electrode; in step (6), electron beam lithography is used to make corresponding gate caps and gates on the double-layer photoresist. Foot graphics area.
  • the etching solution used in the wet etching is an acid etching solution, which can etch away insulating oxide, Si 3 N 4 or SiO 2 ; dry etching is an inductively coupled plasma etching process, reactive ion etching Process or any of other ion etching processes.
  • the double-layer photoresist is two immiscible electron beam photoresists.
  • the sensitivity of the bottom photoresist to electron beams is lower than the sensitivity of the top photoresist to electron beams.
  • the thickness is greater than the thickness of the bottom photoresist; in the process of using electron beam lithography, the exposure dose in the gate pattern area is greater than the exposure dose outside the gate pattern area; the gate electrode material layer is more than two metal layers, the bottom The metal of is more than one of nickel or platinum; the topmost metal is more than one of gold or copper; the total thickness of the gate electrode material layer is greater than the thickness of the bottom photoresist and less than the total thickness of the double-layer photoresist .
  • the present invention has the following technical effects and advantages:
  • the two gate pins of the ⁇ -type gate proposed by the present invention that are in direct contact with the AlGaN/GaN heterojunction epitaxial layer have a certain interval, which effectively reduces the gate electrode's resistance while ensuring that the gate resistance is almost unchanged. Length improves the cut-off frequency.
  • FIG. 1 is a flowchart of a method for manufacturing a GaN-based radio frequency device with a ⁇ -type gate provided in Embodiment 1;
  • 2 to 10 are cross-sectional views of a GaN-based radio frequency device with a ⁇ -type gate during the manufacturing process
  • FIG. 11 is a cross-sectional view of a comparative device (GaN-based radio frequency device with a traditional T-type gate) of a GaN-based radio frequency device with a ⁇ -type gate provided by the embodiment;
  • FIG. 12 is a graph of current gain versus frequency of a GaN-based radio frequency device with a ⁇ -type gate provided by an embodiment
  • FIG. 13 is a graph showing the variation of gate capacitance with frequency of a GaN-based radio frequency device with a ⁇ -type gate provided by an embodiment
  • the figure shows: 1-AlGaN/GaN heterojunction epitaxial layer; 2-active area; 3-source electrode; 4-drain electrode; 5-gate dielectric layer; 6-bottom photoresist; 7-top photolithography Glue; 8-grid cap; 9-grid foot; 901-first grid foot; 902-second grid foot.
  • This embodiment provides a GaN-based radio frequency device with a ⁇ -type gate. As shown in FIG. 10, it includes an AlGaN/GaN heterojunction epitaxial layer 1, and the AlGaN/GaN heterojunction epitaxial layer 1 has a boss structure. The upper part is the active area 2. Both ends of the upper surface of the active area 2 are connected to the source electrode 3 and the drain electrode 4 respectively. The upper surface of the AlGaN/GaN heterojunction epitaxial layer 1 is connected to the area outside the active area 2 and the active area 2. The sidewalls of the active region 2 and the upper surface of the active region 2 are connected to the area other than the source electrode 3 and the drain electrode 4.
  • the source electrode 3 and the drain electrode 4 are covered with a gate dielectric layer 5, and the gate dielectric layer 5 is in the source electrode 3 and the drain electrode.
  • the upper surface of the electrode 4 is provided with an opening to expose part of the upper surface of the source electrode 3 and the drain electrode 4.
  • the upper surface of the gate dielectric layer 5 is connected to the ⁇ -type gate electrode, which is located between the source electrode 3 and the drain electrode 4.
  • the ⁇ -type gate electrode includes a gate cap 8 and a gate pin 9. One end of the gate pin 9 is connected to the upper surface of the gate dielectric layer 5, and the other end is connected to the lower surface of the gate cap 8 to support the gate cap 8.
  • the lower surfaces of the source electrode and the drain electrode are completely in contact with the upper surface of the active region, and the distance between the edges of the source electrode and the drain electrode and the edge of the active region parallel to them is both 500 nm.
  • the AlGaN/GaN heterojunction epitaxial layer is circular with a diameter of 2 inches and a thickness of 800 ⁇ m.
  • the material of the gate dielectric layer is Si 3 N 4 , and the thickness of the gate dielectric layer is 20 nm.
  • This embodiment also provides a method for preparing the GaN-based radio frequency device with a ⁇ -type gate, as shown in FIG. 1, including the following steps:
  • Preparation and cleaning of AlGaN/GaN heterojunction epitaxial layer soak the AlGaN/GaN heterojunction epitaxial layer 1 in a mixed solution with a mass ratio of H 2 SO 4 and H 2 O 2 of 6:1 for 10 minutes (H 2 SO 4 and H 2 O 2 are commercially available), remove the oxide layer on the surface of the AlGaN/GaN heterojunction epitaxial layer 1, and then use acetone (commercially available) and isopropanol (commercially available) to ultrasonicate for 10 minutes to remove AlGaN /GaN heterojunction epitaxial layer 1 with organic matter.
  • a schematic diagram of the AlGaN/GaN heterojunction epitaxial layer 1 after step (1) is shown in Figure 2;
  • the upper surface of the AlGaN/GaN heterojunction epitaxial layer 1 is connected to the area outside the active area 2, the sidewalls of the active area 2, and the active area using the plasma-enhanced chemical vapor deposition method 2
  • the upper surface is connected to the area outside the source electrode 3 and the drain electrode 4, and a gate dielectric layer 5 is deposited on the source electrode 3 and the drain electrode 4.
  • the deposition conditions NH 3 flow rate is 25 sccm; content is 5% (volume) SiH 4
  • the flow rate of the mixed gas with N 2 is 900 sccm; the reaction temperature is 300 °C; the RF power is 50 W, as shown in Figure 5;
  • Preparation of the gate electrode deposit a double-layer photoresist on the upper surface of the gate dielectric layer 5 and the exposed part of the source electrode 3 and the drain electrode 4, and the bottom layer photoresist 6 is made of poly( ⁇ -methylbenzene).
  • the thickness is 300nm
  • the material of the top photoresist 7 is PMMA
  • the thickness is 800nm, as shown in Figure 7
  • the development rate of the top photoresist 7 is greater than that of the bottom photoresist 6, and the pattern area of the gate cap 8 is made on the top photoresist 7 using electron beam lithography
  • Expose part of the bottom layer photoresist 6, make the pattern area of the gate foot 9 on the exposed part of the bottom layer photoresist 6, the exposure dose in the pattern area of the gate foot 9 is 4.4C/m 2
  • the gate cap 8 The exposure dose of the area except the gate pin 9 is 2.4C/m 2 , after the photolithography, it is placed in a normal temperature (23°C) developer solution for 60 seconds, and then placed in a normal temperature (23°C) isopropano
  • the longitudinal section of the formed device is shown in Figure 8.
  • the pattern area of the gate cap 8 and the pattern area of the gate foot 9 are sequentially deposited nickel and gold material layers with thicknesses of 100 nm and 500 nm, respectively, as shown in FIG. 9.
  • the device after depositing the gate electrode material layer was placed in acetone solution, isopropanol solution and deionized water in sequence for 5 minutes, the gate electrode material layer on the upper surface of the top photoresist was stripped, and the double layer photoresist was removed to form a ⁇ Type gate electrode. As shown in Figure 10.
  • the method for preparing a GaN-based radio frequency device with a ⁇ -type gate proposed in the present invention fully takes advantage of the different dissolution rates of the electron beam photoresist in the same developer and the electron beam lithography process can simultaneously set different exposure doses for different patterns , Effectively reduce the length of the gate electrode.
  • the metal stripping method is used to avoid etching damage.
  • the stripped gate cap is air-isolated from the gate dielectric layer to reduce the gate capacitance. Therefore, GaN-based radio frequency devices with ⁇ -type gates can reach higher frequencies.
  • the gate metal is also deposited between the first gate pin and the second gate pin, which is a traditional GaN-based radio frequency device with a T-shaped gate.
  • the cross-sectional view is shown in FIG. 11.
  • Silvaco software was used to simulate the current gain and gate capacitance of the embodiment and the GaN-based radio frequency device with a T-shaped gate at different frequencies.
  • the simulation results are shown in Figs. 12 and 13.
  • the cut-off frequency of a GaN-based radio frequency device with a ⁇ -type gate is 70 GHz, which is nearly 30 GHz higher than that of a GaN-based radio frequency device with a T-type gate.

Abstract

A GaN-based radio frequency device having a П-shaped gate and a manufacturing method therefor. The device comprises an AlGaN/GaN heterojunction epitaxial layer (1); the AlGaN/GaN heterojunction epitaxial layer (1) is of a boss structure; the upper portion of the boss is an active region (2); two ends of the upper surface of the active region (2) are respectively connected to a source electrode (3) and a drain electrode (4); a gate dielectric layer (5) is provided in a region, etc., other than a region connected to the active region (2), of the upper surface of the AlGaN/GaN heterojunction epitaxial layer (1); the upper surface of the gate dielectric layer (5) is connected to a П-shaped gate electrode; and the П-shaped gate electrode is positioned between the source electrode (3) and the drain electrode (4). By means of two gate pins (9), having a certain interval and being in direct contact with the AlGaN/GaN heterojunction epitaxial layer (1), of the П-shaped gate, the length of the gate electrode is effectively reduced under the condition of ensuring that the gate resistance is nearly unchanged, and the cut-off frequency is improved.

Description

一种具有Π型栅的GaN基射频器件及其制备方法GaN-based radio frequency device with Π-shaped gate and preparation method thereof 技术领域Technical field
本发明涉及射频器件,更具体地说涉及一种具有Π型栅的GaN基射频器件及其制备方法。The invention relates to a radio frequency device, and more specifically to a GaN-based radio frequency device with a Π-type gate and a preparation method thereof.
背景技术Background technique
GaN基HEMT器件在卫星、通信、雷达等领域有着广泛的应用。GaN属于III族氮化物,具有出色的击穿能力、更高的电子密度及速度、耐高温和耐辐射等优势,适合发展高频、高温以及高功率的电子器件。并且AlGaN/GaN异质结在室温下由于自发极化效应和压电极化效应,在异质结界面存在高浓度的二维电子气,所以具有AlGaN/GaN异质结的器件具有高电子浓度与高电子迁移率,在5G网络基础设施的建设,反导雷达以及其他领域都有着广阔的应用前景。GaN-based HEMT devices have a wide range of applications in satellite, communications, radar and other fields. GaN belongs to group III nitrides, has excellent breakdown ability, higher electron density and speed, high temperature resistance and radiation resistance, and is suitable for the development of high-frequency, high-temperature and high-power electronic devices. In addition, due to the spontaneous polarization effect and piezoelectric polarization effect of AlGaN/GaN heterojunction at room temperature, there is a high concentration of two-dimensional electron gas at the heterojunction interface, so devices with AlGaN/GaN heterojunction have high electron concentration With high electron mobility, it has broad application prospects in the construction of 5G network infrastructure, anti-missile radar and other fields.
对射频器件来说,频率参数是决定射频器件整体性能的关键参数。为了获得更大的频率,通常器件的栅电极截面为T型。T型栅电极与AlGaN/GaN异质结外延层接触的长度较小,可以获得较高的截止频率f T,同时。T型栅电极具有大体积的栅帽,增大了沿电流传导方向的栅电极的截面面积,减小了栅电极的寄生电阻,从而提高了最高振荡频率f MAXFor radio frequency devices, frequency parameters are key parameters that determine the overall performance of radio frequency devices. In order to obtain a larger frequency, the gate electrode section of the device is usually T-shaped. The contact length between the T-type gate electrode and the AlGaN/GaN heterojunction epitaxial layer is small, and a higher cut-off frequency f T can be obtained, and at the same time. The T-shaped gate electrode has a large-volume gate cap, which increases the cross-sectional area of the gate electrode along the current conduction direction and reduces the parasitic resistance of the gate electrode, thereby increasing the maximum oscillation frequency f MAX .
为了让射频器件具有更高的截止频率,需要降低器件与势垒层直接接触的栅电极长度。受到光刻设备的极限性能及设备成本的限制,射频器件的光刻方法通常采用电子束光刻。电子束光刻是指使用电子束在表面上制造图样。由于电子是一种波长极短的波,所以相对于其他光学光刻工艺,电子束光刻的精度更高,可以达到纳米量级。所以电子束光刻能够有效满足HEMT器件中栅电极尺寸的需求。In order for the radio frequency device to have a higher cutoff frequency, it is necessary to reduce the length of the gate electrode in direct contact between the device and the barrier layer. Limited by the extreme performance of the lithography equipment and the equipment cost, the lithography method of radio frequency devices usually adopts electron beam lithography. Electron beam lithography refers to the use of electron beams to create patterns on the surface. Since electrons are waves with extremely short wavelengths, compared with other optical lithography processes, electron beam lithography has a higher precision and can reach the nanometer level. Therefore, electron beam lithography can effectively meet the requirements of the gate electrode size in HEMT devices.
为了让射频器件具有更大的最高振荡频率,需要增大T型栅的栅帽体积。普遍采用双层或三层光刻胶剥离栅电极金属,或是刻蚀部分的栅介质层作为栅脚,在栅介质层上沉积栅帽的制作方法制备射频器件。第一种方案由于栅帽下方只有一个栅电极支撑,所以无法同时兼顾较小的栅电极长度和较大的栅帽长度; 第二种方案,虽然可以实现较小的栅电极长度和较大的栅帽长度,但引入了刻蚀损伤,导致器件退化,并且栅介质层与栅帽的接触面积过大,加大了栅源、栅漏的电容,降低了器件的最高振荡频率。基于以上情况,如何在保证较小的栅电极长度的情况下获得较大的栅帽长度,并且不引入刻蚀损伤或是栅源、栅漏的电容,达到更高的频率是GaN基射频器件亟待解决的问题。In order for the radio frequency device to have a larger maximum oscillation frequency, the volume of the gate cap of the T-shaped gate needs to be increased. Generally, a double-layer or three-layer photoresist is used to strip the gate electrode metal, or a part of the gate dielectric layer is etched as a gate foot, and a gate cap is deposited on the gate dielectric layer to prepare radio frequency devices. In the first solution, because there is only one gate electrode support under the gate cap, it cannot take into account both a smaller gate electrode length and a larger gate cap length; the second solution, although a smaller gate electrode length and a larger gate electrode length can be achieved The length of the gate cap, but introduces etching damage, resulting in device degradation, and the contact area between the gate dielectric layer and the gate cap is too large, which increases the capacitance of the gate source and the gate drain, and reduces the maximum oscillation frequency of the device. Based on the above situation, how to obtain a larger gate cap length while ensuring a smaller gate electrode length without introducing etch damage or gate source and gate drain capacitance to achieve higher frequencies is a GaN-based radio frequency device Problems to be solved.
发明概述Summary of the invention
技术问题technical problem
问题的解决方案The solution to the problem
技术解决方案Technical solutions
本发明的目的在于克服已有的GaN基HEMT器件的栅电极制备技术的缺陷以及局限,从栅电极的形状与制备工艺的角度提出一种具有Π型栅的GaN基射频器件及其制备方法,可以在保持栅阻尽量不变的情况下有效地减小栅长,提高器件频率。The purpose of the present invention is to overcome the defects and limitations of the gate electrode preparation technology of the existing GaN-based HEMT device, and propose a GaN-based radio frequency device with a Π-type gate and a preparation method thereof from the perspective of the shape of the gate electrode and the preparation process. The gate length can be effectively reduced while keeping the gate resistance as constant as possible, and the device frequency can be increased.
本发明的目的是通过以下技术方案之一实现的。The purpose of the present invention is achieved by one of the following technical solutions.
本发明提供了一种具有Π型栅的GaN基射频器件,包括AlGaN/GaN异质结外延层,AlGaN/GaN异质结外延层为凸台结构,凸台上部为有源区,有源区上表面的两端分别连接源电极和漏电极,AlGaN/GaN异质结外延层上表面连接有源区以外的区域、有源区的侧壁、有源区上表面连接源电极和漏电极以外的区域、源电极和漏电极上覆盖有一层栅介质层,所述栅介质层在源电极和漏电极的上表面均设有一开口,暴露源电极和漏电极部分上表面,栅介质层的上表面连接Π型栅电极,Π型栅电极位于源电极和漏电极之间,Π型栅电极包括栅帽和栅脚,栅脚的一端连接栅介质层的上表面,另一端连接栅帽的下表面,以支撑栅帽,所述栅脚包括第一栅脚和第二栅脚,第一栅脚和第二栅脚之间具有间距。The present invention provides a GaN-based radio frequency device with a Π-type gate, comprising an AlGaN/GaN heterojunction epitaxial layer, the AlGaN/GaN heterojunction epitaxial layer is a boss structure, the upper part of the boss is an active area, and the active area Both ends of the upper surface are connected to the source electrode and the drain electrode. The upper surface of the AlGaN/GaN heterojunction epitaxial layer is connected to the area outside the active area, the sidewall of the active area, and the upper surface of the active area is connected to the source electrode and the drain electrode. The area, the source electrode and the drain electrode are covered with a gate dielectric layer. The gate dielectric layer is provided with an opening on the upper surface of the source electrode and the drain electrode to expose the upper surface of the source electrode and the drain electrode. The upper surface of the gate dielectric layer The surface is connected to the Π-type gate electrode, which is located between the source electrode and the drain electrode. The Π-type gate electrode includes a gate cap and a gate pin. One end of the gate pin is connected to the upper surface of the gate dielectric layer, and the other end is connected to the bottom of the gate cap. The surface is used to support the grid cap, the grid foot includes a first grid foot and a second grid foot, and there is a space between the first grid foot and the second grid foot.
优选地,栅脚横截面的左右长度即长度为L g,10nm≤L g≤300nm;栅脚横截面的上下长度即高度为H g,0nm<H g≤5L g;垂直于栅脚横截面方向上栅脚的厚度即宽度为W g,W g≥1.2μm;第一栅脚和第二栅脚之间的间距为L interval,0nm<L interval≤6L gPreferably, the left and right length of the cross section of the grid foot is L g , 10nm≤L g ≤300nm; the upper and lower length of the cross section of the grid foot, that is the height is H g , 0nm<H g ≤5L g ; perpendicular to the cross section of the grid foot The thickness of the grid foot in the direction, that is, the width is W g , W g ≥1.2 μm; the distance between the first grid foot and the second grid foot is L interval , 0nm<L interval ≤6L g ;
栅帽的长度为L cap,2L g+L interval≤L cap≤6L g+2L interval;栅帽的高度为H cap,0nm <H cap≤18L g+3L interval;栅帽的宽度为W cap,W cap=W gThe length of the gate cap is L cap , 2L g +L interval ≤L cap ≤6L g +2L interval ; the height of the gate cap is H cap , 0nm <H cap ≤18L g +3L interval ; the width of the gate cap is W cap , W cap =W g .
优选地,第一栅脚与源电极位于同侧,第一栅脚与源电极之间的距离为L gs,L gs>(L cap-L interval-2L g)/2;第二栅脚与漏电极位于同侧,第二栅脚与漏电极之间的距离为L gd,L gd>(L cap-L interval-2L g)/2。 Preferably, the first gate foot and the source electrode are located on the same side, and the distance between the first gate foot and the source electrode is L gs , L gs >(L cap -L interval -2L g )/2; The drain electrode is located on the same side, and the distance between the second gate pin and the drain electrode is L gd , L gd >(L cap -L interval -2L g )/2.
优选地,源电极和漏电极为Ti/Al/Ni/Au金属层;源电极和漏电极均为长方体,源电极和漏电极的长度分别为L s和L d,高度分别为H s和H d,宽度分别为W s和W d,L s=L d≥10nm,H s=H d≥10nm,0nm<W s=W d≤W g,源电极和漏电极的间距为L sd,L sd=2L g+L interval+L gs+L gd+L s+L dPreferably, the source electrode and the drain electrode are Ti/Al/Ni/Au metal layers; the source electrode and the drain electrode are both cuboid, the length of the source electrode and the drain electrode are L s and L d , and the heights are H s and H d respectively , The widths are W s and W d , respectively, L s =L d ≥10nm, H s =H d ≥10nm, 0nm<W s =W d ≤W g , the distance between source electrode and drain electrode is L sd , L sd = 2L g +L interval +L gs +L gd +L s +L d .
优选地,所述AlGaN/GaN异质结外延层为圆形,直径为2-10inch,厚度为200μm-1mm;Preferably, the AlGaN/GaN heterojunction epitaxial layer is circular, with a diameter of 2-10 inches, and a thickness of 200 μm-1mm;
有源区的长度为L,L≥L sd,高度为H,100nm≤H≤1mm,宽度为W,W≥W g;源电极和漏电极位于有源区上表面的两端,源漏电极的下表面完全和有源区的上表面接触。 The length of the active area is L, L≥L sd , the height is H, 100nm≤H≤1mm, and the width is W, W≥W g ; the source electrode and the drain electrode are located at both ends of the upper surface of the active area, the source and drain electrodes The bottom surface is completely in contact with the top surface of the active area.
优选地,源漏电极的下表面的边缘距与之平行的有源区的边缘的距离不小于500nm(因为实施例是500nm,所以不能使用1um,请核实确认)。Preferably, the distance between the edge of the lower surface of the source and drain electrode and the edge of the active region parallel to it is not less than 500nm (because the embodiment is 500nm, 1um cannot be used, please verify it).
优选地,栅介质层的材料为绝缘金属氧化物、SiO 2和Si 3N 4中的任意一种,栅介质层的厚度不小于1nm。 Preferably, the material of the gate dielectric layer is any one of insulating metal oxide, SiO 2 and Si 3 N 4 , and the thickness of the gate dielectric layer is not less than 1 nm.
本发明还提供了一种制备如上所述具有Π型栅的GaN基射频器件的方法,包括以下步骤:The present invention also provides a method for preparing a GaN-based radio frequency device with a Π-type gate as described above, which includes the following steps:
(1)准备AlGaN/GaN异质结外延层及清洗:将AlGaN/GaN异质结外延层浸泡在酸性溶液中除去其表面的氧化层,再采用有机溶液超声的方法,除去AlGaN/GaN异质结外延层表面的有机物;(1) Preparation and cleaning of AlGaN/GaN heterojunction epitaxial layer: soak the AlGaN/GaN heterojunction epitaxial layer in an acid solution to remove the oxide layer on the surface, and then use the organic solution ultrasonic method to remove AlGaN/GaN heterogeneity Organic matter on the surface of the junction epitaxial layer;
(2)器件的相互隔离:在AlGaN/GaN异质结外延层上表面用光刻胶定义有源区的位置并将其覆盖,非有源区的AlGaN/GaN异质结外延层上表面被等离子体轰击刻蚀,刻蚀深度为200nm-600nm;(2) Mutual isolation of devices: define the position of the active area with photoresist on the upper surface of the AlGaN/GaN heterojunction epitaxial layer and cover it, and the upper surface of the AlGaN/GaN heterojunction epitaxial layer in the non-active area is covered by photoresist. Plasma bombardment etching, the etching depth is 200nm-600nm;
(3)剥离出源电极和漏电极,退火形成欧姆接触:使用光刻胶定义源电极和漏电极的位置及图形,使得源电极和漏电极的位置在有源区上表面的两端,非源电极并且非漏电极的区域被光刻胶覆盖,使用电子束蒸发或者磁控溅射的方 法和剥离工艺形成源电极和漏电极,最后在氮气氛围,800℃以上的温度中退火,使源电极、漏电极与AlGaN/GaN异质结外延层均形成欧姆接触;(3) Strip the source and drain electrodes, annealing to form an ohmic contact: Use photoresist to define the positions and patterns of the source and drain electrodes, so that the positions of the source and drain electrodes are at the two ends of the upper surface of the active area. The area of the source electrode and the non-drain electrode is covered by photoresist, the source electrode and the drain electrode are formed using electron beam evaporation or magnetron sputtering method and stripping process, and finally annealed in a nitrogen atmosphere at a temperature above 800°C to make the source The electrode, the drain electrode and the AlGaN/GaN heterojunction epitaxial layer all form an ohmic contact;
(4)沉积栅介质层:在AlGaN/GaN异质结外延层上表面连接有源区以外的区域、有源区的侧壁、有源区上表面连接源电极和漏电极以外的区域、源电极和漏电极上沉积一层栅介质层;(4) Deposition of the gate dielectric layer: the upper surface of the AlGaN/GaN heterojunction epitaxial layer is connected to the area outside the active area, the sidewalls of the active area, the upper surface of the active area is connected to the area outside the source electrode and the drain electrode, and the source A gate dielectric layer is deposited on the electrode and the drain electrode;
(5)去除源电极和漏电极上表面的部分栅介质层:源电极和漏电极以外的区域被光刻胶覆盖保护,将源电极和漏电极上表面的部分栅介质层移除,暴露源电极和漏电极的部分上表面;(5) Remove part of the gate dielectric layer on the upper surface of the source electrode and the drain electrode: the area outside the source electrode and the drain electrode is covered and protected by photoresist, remove part of the gate dielectric layer on the upper surface of the source electrode and the drain electrode to expose the source Part of the upper surface of the electrode and the drain electrode;
(6)制备栅电极:在栅介质层的上表面和暴露的源电极和漏电极部分上表面沉积双层光刻胶,在顶层光刻胶上做出栅帽的图形区域,暴露出部分底层光刻胶,在暴露的部分底层光刻胶上做出栅脚的图形区域,在顶层光刻胶上表面、栅帽的图形区域和栅脚的图形区域上沉积栅电极材料层,剥离顶层光刻胶上表面的栅电极材料层,并去除双层光刻胶,形成Π型栅电极。(6) Preparation of the gate electrode: deposit a double-layer photoresist on the upper surface of the gate dielectric layer and the upper surface of the exposed source and drain electrodes, and make the pattern area of the gate cap on the top photoresist, exposing part of the bottom layer Photoresist, make the pattern area of the gate pin on the exposed part of the bottom photoresist, deposit the gate electrode material layer on the upper surface of the top photoresist, the pattern area of the gate cap and the pattern area of the gate pin, and peel off the top layer photoresist The gate electrode material layer on the upper surface of the resist is removed, and the double-layer photoresist is removed to form a Π-type gate electrode.
优选地,步骤(4)中沉积栅介质层的方法为等离子体增强的化学气相沉积法、原子层淀积法、磁控溅射方法中的任意一种;步骤(5)中采用湿法腐蚀或干法刻蚀的方法将源电极和漏电极上表面的部分栅介质层移除;步骤(6)中用电子束光刻的方法在双层光刻胶上做出相应的栅帽和栅脚图形区域。Preferably, the method for depositing the gate dielectric layer in step (4) is any one of plasma-enhanced chemical vapor deposition, atomic layer deposition, and magnetron sputtering; wet etching is used in step (5) Or dry etching method to remove part of the gate dielectric layer on the upper surface of the source electrode and drain electrode; in step (6), electron beam lithography is used to make corresponding gate caps and gates on the double-layer photoresist. Foot graphics area.
优选地,所述湿法腐蚀采用的腐蚀溶液为酸性腐蚀液,可腐蚀掉绝缘性氧化物、Si 3N 4或SiO 2;干法刻蚀为感应耦合等离子体刻蚀工艺、反应离子刻蚀工艺或其他离子刻蚀工艺中的任意一种。 Preferably, the etching solution used in the wet etching is an acid etching solution, which can etch away insulating oxide, Si 3 N 4 or SiO 2 ; dry etching is an inductively coupled plasma etching process, reactive ion etching Process or any of other ion etching processes.
优选地,双层光刻胶为互不相溶的两种电子束光刻胶,底层光刻胶对电子束的敏感度低于顶层光刻胶对电子束的敏感度,顶层光刻胶的厚度大于底层光刻胶的厚度;在使用电子束光刻的过程中,栅脚图形区域的曝光剂量大于栅脚图形区域以外的曝光剂量;栅电极材料层为两层以上的金属层,最底层的金属为镍或铂中的一种以上;最顶层的金属为金或铜中的一种以上;栅电极材料层的总厚度大于底层光刻胶的厚度,小于双层光刻胶的总厚度。Preferably, the double-layer photoresist is two immiscible electron beam photoresists. The sensitivity of the bottom photoresist to electron beams is lower than the sensitivity of the top photoresist to electron beams. The thickness is greater than the thickness of the bottom photoresist; in the process of using electron beam lithography, the exposure dose in the gate pattern area is greater than the exposure dose outside the gate pattern area; the gate electrode material layer is more than two metal layers, the bottom The metal of is more than one of nickel or platinum; the topmost metal is more than one of gold or copper; the total thickness of the gate electrode material layer is greater than the thickness of the bottom photoresist and less than the total thickness of the double-layer photoresist .
发明的有益效果The beneficial effects of the invention
有益效果Beneficial effect
和现有技术相比,本发明具有以下技术效果和优点:Compared with the prior art, the present invention has the following technical effects and advantages:
(1)本发明提出的Π型栅的两个与AlGaN/GaN异质结外延层直接接触的具有一定间隔的栅脚,在保证栅阻近乎不变的情况下,有效地缩小了栅电极的长度,提高了截止频率。(1) The two gate pins of the Π-type gate proposed by the present invention that are in direct contact with the AlGaN/GaN heterojunction epitaxial layer have a certain interval, which effectively reduces the gate electrode's resistance while ensuring that the gate resistance is almost unchanged. Length improves the cut-off frequency.
(2)本发明提出的Π型栅的栅帽和栅介质层存在空气隔离,减少栅介质层与栅电极金属的接触面积,减小了栅电容的增加;(2) There is air isolation between the gate cap and the gate dielectric layer of the Π-type gate proposed in the present invention, which reduces the contact area between the gate dielectric layer and the gate electrode metal, and reduces the increase in gate capacitance;
(3)本发明提出的Π型栅电极的制备方法中采用剥离的方法,其中只需一次电子束光刻,无需刻蚀,也不需二次对准,既防止了刻蚀损伤,又简化了工艺。(3) In the preparation method of the Π-type gate electrode proposed in the present invention, a stripping method is adopted, in which only one electron beam lithography is required, no etching is required, and no secondary alignment is required, which not only prevents etching damage, but also simplifies了 Process.
对附图的简要说明Brief description of the drawings
附图说明Description of the drawings
图1是实施例1提供的具有Π型栅的GaN基射频器件制备方法的流程图;FIG. 1 is a flowchart of a method for manufacturing a GaN-based radio frequency device with a Π-type gate provided in Embodiment 1;
图2-图10是具有Π型栅的GaN基射频器件在制备过程中的截面图;2 to 10 are cross-sectional views of a GaN-based radio frequency device with a Π-type gate during the manufacturing process;
图11是实施例提供的具有Π型栅的GaN基射频器件的对比器件(具有传统T型栅的GaN基射频器件)的截面图;11 is a cross-sectional view of a comparative device (GaN-based radio frequency device with a traditional T-type gate) of a GaN-based radio frequency device with a Π-type gate provided by the embodiment;
图12是实施例提供的具有Π型栅的GaN基射频器件的电流增益随频率变化的曲线图;FIG. 12 is a graph of current gain versus frequency of a GaN-based radio frequency device with a Π-type gate provided by an embodiment;
图13是实施例提供的具有Π型栅的GaN基射频器件的栅极电容随频率变化的曲线图;FIG. 13 is a graph showing the variation of gate capacitance with frequency of a GaN-based radio frequency device with a Π-type gate provided by an embodiment;
图中示出:1-AlGaN/GaN异质结外延层;2-有源区;3-源电极;4-漏电极;5-栅介质层;6-底层光刻胶;7-顶层光刻胶;8-栅帽;9-栅脚;901-第一栅脚;902-第二栅脚。The figure shows: 1-AlGaN/GaN heterojunction epitaxial layer; 2-active area; 3-source electrode; 4-drain electrode; 5-gate dielectric layer; 6-bottom photoresist; 7-top photolithography Glue; 8-grid cap; 9-grid foot; 901-first grid foot; 902-second grid foot.
本发明的各附图仅为示意以更容易了解本发明,其具体比例可依照设计需求进行调整。文中所描述的图形中相对元件的上下关系,在本领域技术人员应能理解是指构件的相对位置而言。The drawings of the present invention are only schematic for easier understanding of the present invention, and the specific proportions can be adjusted according to design requirements. The up-down relationship of the relative elements in the graphics described in the text should be understood by those skilled in the art as referring to the relative positions of the components.
发明实施例Invention embodiment
本发明的实施方式Embodiments of the invention
以下结合具体实施例和附图对本发明的具体实施作进一步说明,但本发明的实 施不限于此。The specific implementation of the present invention will be further described below with reference to specific embodiments and drawings, but the implementation of the present invention is not limited to this.
实施例Example
本实施例提供了一种具有Π型栅的GaN基射频器件,如图10所示,包括AlGaN/GaN异质结外延层1,AlGaN/GaN异质结外延层1为凸台结构,凸台上部为有源区2,有源区2上表面的两端分别连接源电极3和漏电极4,AlGaN/GaN异质结外延层1上表面连接有源区2以外的区域、有源区2的侧壁、有源区2上表面连接源电极3和漏电极4以外的区域、源电极3和漏电极4上覆盖有一层栅介质层5,所述栅介质层5在源电极3和漏电极4的上表面均设有一开口,暴露源电极3和漏电极4部分上表面,栅介质层5的上表面连接Π型栅电极,Π型栅电极位于源电极3和漏电极4之间,Π型栅电极包括栅帽8和栅脚9,栅脚9的一端连接栅介质层5的上表面,另一端连接栅帽8的下表面,以支撑栅帽8。This embodiment provides a GaN-based radio frequency device with a Π-type gate. As shown in FIG. 10, it includes an AlGaN/GaN heterojunction epitaxial layer 1, and the AlGaN/GaN heterojunction epitaxial layer 1 has a boss structure. The upper part is the active area 2. Both ends of the upper surface of the active area 2 are connected to the source electrode 3 and the drain electrode 4 respectively. The upper surface of the AlGaN/GaN heterojunction epitaxial layer 1 is connected to the area outside the active area 2 and the active area 2. The sidewalls of the active region 2 and the upper surface of the active region 2 are connected to the area other than the source electrode 3 and the drain electrode 4. The source electrode 3 and the drain electrode 4 are covered with a gate dielectric layer 5, and the gate dielectric layer 5 is in the source electrode 3 and the drain electrode. The upper surface of the electrode 4 is provided with an opening to expose part of the upper surface of the source electrode 3 and the drain electrode 4. The upper surface of the gate dielectric layer 5 is connected to the Π-type gate electrode, which is located between the source electrode 3 and the drain electrode 4. The Π-type gate electrode includes a gate cap 8 and a gate pin 9. One end of the gate pin 9 is connected to the upper surface of the gate dielectric layer 5, and the other end is connected to the lower surface of the gate cap 8 to support the gate cap 8.
栅脚的高度为H g,H g=300nm;所述栅脚9包括第一栅脚901和第二栅脚902,第一栅脚901和第二栅脚902的长度均为L g,L g=100nm,宽度均为W g,W g=100μm,第一栅脚901和第二栅脚902之间的间距为L interval,L interval=300nm;栅帽8的高度为H cap,H cap=300nm,长度为L cap,L cap=1μm,宽度为W cap,W cap=100μm。第一栅脚901与源电极3位于同侧,第一栅脚901与源电极3之间的距离为L gs,L gs=2μm。第二栅脚902与漏电极4位于同侧,第二栅脚902与漏电极4之间的距离为L gd,L gd=2μm。 The height of the grid foot is H g , H g =300 nm; the grid foot 9 includes a first grid foot 901 and a second grid foot 902, and the lengths of the first grid foot 901 and the second grid foot 902 are both L g , L g =100nm, width W g , W g =100μm, the distance between the first grid foot 901 and the second grid foot 902 is L interval , L interval =300nm; the height of the grid cap 8 is H cap , H cap =300nm, the length is L cap , L cap =1 μm, the width is W cap , W cap =100 μm. The first gate foot 901 and the source electrode 3 are located on the same side, and the distance between the first gate foot 901 and the source electrode 3 is L gs , L gs =2 μm. The second gate leg 902 and the drain electrode 4 are located on the same side, and the distance between the second gate leg 902 and the drain electrode 4 is L gd , L gd = 2 μm.
源电极和漏电极为Ti/Al/Ni/Au金属层;源电极和漏电极均为长方体,其高度分别为H s和H d,H s=H d=620nm,长度分别为L s和L d,L s=L d=500nm,宽度分别为W s和W d,W s=W d=100μm,源电极和漏电极的间距为L sd,L sd=5.5μm。源电极和漏电极的下表面完全和有源区的上表面接触,源电极和漏电极的边缘距与之平行的有源区的边缘的距离均为500nm。有源区的高度为H,H=350nm,长度为L,L=6.5μm,宽度为W,W=101μm。所述AlGaN/GaN异质结外延层为圆形,直径为2inch,厚度为800μm。 The source electrode and the drain electrode are Ti/Al/Ni/Au metal layers; the source electrode and the drain electrode are both rectangular parallelepiped, the heights of which are H s and H d , H s = H d = 620 nm, and the lengths are L s and L d respectively , L s =L d =500nm, the widths are W s and W d , W s =W d =100 μm, the distance between the source electrode and the drain electrode is L sd , L sd =5.5 μm. The lower surfaces of the source electrode and the drain electrode are completely in contact with the upper surface of the active region, and the distance between the edges of the source electrode and the drain electrode and the edge of the active region parallel to them is both 500 nm. The height of the active region is H, H=350nm, the length is L, L=6.5μm, the width is W, W=101μm. The AlGaN/GaN heterojunction epitaxial layer is circular with a diameter of 2 inches and a thickness of 800 μm.
栅介质层的材料为Si 3N 4,栅介质层的厚度为20nm。 The material of the gate dielectric layer is Si 3 N 4 , and the thickness of the gate dielectric layer is 20 nm.
本实施例还提供了一种制备所述具有Π型栅的GaN基射频器件的方法,如图1所示,包括以下步骤:This embodiment also provides a method for preparing the GaN-based radio frequency device with a Π-type gate, as shown in FIG. 1, including the following steps:
(1)准备AlGaN/GaN异质结外延层及清洗:将AlGaN/GaN异质结外延层1浸泡于H 2SO 4和H 2O 2质量比为6∶1的混合溶液中10分钟(H 2SO 4和H 2O 2均为市售),除去AlGaN/GaN异质结外延层1表面的氧化层,再采用丙酮(市售)和异丙醇(市售)分别超声10min,除去AlGaN/GaN异质结外延层1表面的有机物,步骤(1)处理后的AlGaN/GaN异质结外延层1的示意图如图2所示; (1) Preparation and cleaning of AlGaN/GaN heterojunction epitaxial layer: soak the AlGaN/GaN heterojunction epitaxial layer 1 in a mixed solution with a mass ratio of H 2 SO 4 and H 2 O 2 of 6:1 for 10 minutes (H 2 SO 4 and H 2 O 2 are commercially available), remove the oxide layer on the surface of the AlGaN/GaN heterojunction epitaxial layer 1, and then use acetone (commercially available) and isopropanol (commercially available) to ultrasonicate for 10 minutes to remove AlGaN /GaN heterojunction epitaxial layer 1 with organic matter. A schematic diagram of the AlGaN/GaN heterojunction epitaxial layer 1 after step (1) is shown in Figure 2;
(2)器件的相互隔离:在AlGaN/GaN异质结外延层1上表面用光刻胶定义有源区2的位置并将其覆盖,非有源区的AlGaN/GaN异质结外延层上表面被等离子体轰击刻蚀,刻蚀深度为350nm,AlGaN/GaN异质结外延层1形成凸台结构,如图3所示,刻蚀的具体条件:BCl 3流量为10sccm,Cl 2流量为90sccm,RF射频功率为500W,ICP功率为365W; (2) Mutual isolation of devices: Use photoresist on the upper surface of the AlGaN/GaN heterojunction epitaxial layer 1 to define the position of the active area 2 and cover it, on the AlGaN/GaN heterojunction epitaxial layer in the non-active area The surface is etched by plasma bombardment, the etching depth is 350nm, and the AlGaN/GaN heterojunction epitaxial layer 1 forms a bump structure, as shown in Figure 3, the specific etching conditions: BCl 3 flow rate is 10 sccm, Cl 2 flow rate is 90sccm, RF power is 500W, ICP power is 365W;
(3)剥离出源电极和漏电极,退火形成欧姆接触:使用光刻胶定义源电极3和漏电极4的位置及图形,使得源电极3和漏电极4的位置在有源区3上表面的两端,非源电极并且非漏电极的区域被光刻胶覆盖,使用电子束蒸发方法沉积Ti/Al/Ni/Au金属层,再使用剥离工艺形成源电极3和漏电极4,最后在氮气氛围,850℃的温度中退火,使源电极3、漏电极4与AlGaN/GaN异质结外延层1均形成欧姆接触,如图4所示;(3) Strip the source and drain electrodes, annealing to form an ohmic contact: use photoresist to define the position and pattern of the source electrode 3 and the drain electrode 4 so that the position of the source electrode 3 and the drain electrode 4 is on the upper surface of the active area 3 Both ends of the non-source electrode and non-drain electrode area are covered by photoresist, use electron beam evaporation method to deposit Ti/Al/Ni/Au metal layer, and then use the lift-off process to form the source electrode 3 and the drain electrode 4, and finally Annealing in a nitrogen atmosphere at a temperature of 850°C makes the source electrode 3, the drain electrode 4 and the AlGaN/GaN heterojunction epitaxial layer 1 all form an ohmic contact, as shown in Figure 4;
(4)沉积栅介质层:采用等离子体增强的化学气相积的方法在AlGaN/GaN异质结外延层1上表面连接有源区2以外的区域、有源区2的侧壁、有源区2上表面连接源电极3和漏电极4以外的区域、源电极3和漏电极4上沉积一层栅介质层5,沉积条件:NH 3流量为25sccm;含量为5%(体积)的SiH 4和N 2混合气体流量为900sccm;反应温度为300℃;射频功率为50W,如图5所示; (4) Deposition of the gate dielectric layer: the upper surface of the AlGaN/GaN heterojunction epitaxial layer 1 is connected to the area outside the active area 2, the sidewalls of the active area 2, and the active area using the plasma-enhanced chemical vapor deposition method 2 The upper surface is connected to the area outside the source electrode 3 and the drain electrode 4, and a gate dielectric layer 5 is deposited on the source electrode 3 and the drain electrode 4. The deposition conditions: NH 3 flow rate is 25 sccm; content is 5% (volume) SiH 4 The flow rate of the mixed gas with N 2 is 900 sccm; the reaction temperature is 300 ℃; the RF power is 50 W, as shown in Figure 5;
(5)去除源电极和漏电极上表面的部分栅介质层:源电极3和漏电极4以外的区域被光刻胶覆盖保护,采用感应耦合等离子刻蚀工艺将源电极3和漏电极4上表面的部分栅介质层5移除,暴露源电极3和漏电极4的部分上表面,如图6所示,刻蚀工艺条件为:CHF 3流量为50sccm;O 2流量为10sccm;RF射频功率为60W;ICP功率为600W; (5) Remove part of the gate dielectric layer on the upper surface of the source electrode and the drain electrode: the area outside the source electrode 3 and the drain electrode 4 is covered and protected by photoresist, and the source electrode 3 and the drain electrode 4 are covered by an inductively coupled plasma etching process. Part of the gate dielectric layer 5 on the surface is removed, exposing part of the upper surface of the source electrode 3 and the drain electrode 4, as shown in Figure 6, the etching process conditions are: CHF 3 flow rate is 50 sccm; O 2 flow rate is 10 sccm; RF power 60W; ICP power is 600W;
(6)制备栅电极:在栅介质层5的上表面和暴露的源电极3和漏电极4部分上表面沉积双层光刻胶,底层光刻胶6的材料为聚(α-甲基苯乙烯-co-α-氯丙烯酸甲 酯),厚度为300nm,顶层光刻胶7的材料为PMMA,厚度为800nm,如图7所示;底层光刻胶6和顶层光刻胶7的显影液均为MIBK∶IPA=1∶3(体积比),顶层光刻胶7的显影速率大于底层光刻胶6,使用电子束光刻方法在顶层光刻胶7上做出栅帽8的图形区域,暴露出部分底层光刻胶6,在暴露的部分底层光刻胶6上做出栅脚9的图形区域,在栅脚9的图形区域的曝光剂量为4.4C/m 2,栅帽8中除栅脚9的区域的曝光剂量为2.4C/m 2,光刻后,静置放入常温(23℃)的显影液中60s,再放入常温(23℃)异丙醇溶液中30s,用氮气吹干,形成的器件纵截面如图8所示。在顶层光刻胶7上表面、栅帽8的图形区域和栅脚9的图形区域上使用电子束蒸发工艺依次沉积镍和金材料层,厚度分别为100nm和500nm,如图9所示。 (6) Preparation of the gate electrode: deposit a double-layer photoresist on the upper surface of the gate dielectric layer 5 and the exposed part of the source electrode 3 and the drain electrode 4, and the bottom layer photoresist 6 is made of poly(α-methylbenzene). Ethylene-co-α-methyl chloroacrylate), the thickness is 300nm, the material of the top photoresist 7 is PMMA, the thickness is 800nm, as shown in Figure 7; the developer of the bottom photoresist 6 and the top photoresist 7 All are MIBK:IPA=1:3 (volume ratio), the development rate of the top photoresist 7 is greater than that of the bottom photoresist 6, and the pattern area of the gate cap 8 is made on the top photoresist 7 using electron beam lithography , Expose part of the bottom layer photoresist 6, make the pattern area of the gate foot 9 on the exposed part of the bottom layer photoresist 6, the exposure dose in the pattern area of the gate foot 9 is 4.4C/m 2 , the gate cap 8 The exposure dose of the area except the gate pin 9 is 2.4C/m 2 , after the photolithography, it is placed in a normal temperature (23°C) developer solution for 60 seconds, and then placed in a normal temperature (23°C) isopropanol solution for 30 seconds. Blow dry with nitrogen, and the longitudinal section of the formed device is shown in Figure 8. On the upper surface of the top layer photoresist 7, the pattern area of the gate cap 8 and the pattern area of the gate foot 9 are sequentially deposited nickel and gold material layers with thicknesses of 100 nm and 500 nm, respectively, as shown in FIG. 9.
将沉积栅电极材料层后的器件依次放入丙酮溶液、异丙醇溶液和去离子水中静置5min,剥离顶层光刻胶上表面的栅电极材料层,并去除双层光刻胶,形成Π型栅电极。如图10所示。The device after depositing the gate electrode material layer was placed in acetone solution, isopropanol solution and deionized water in sequence for 5 minutes, the gate electrode material layer on the upper surface of the top photoresist was stripped, and the double layer photoresist was removed to form a Π Type gate electrode. As shown in Figure 10.
本发明提出的具有Π型栅的GaN基射频器件的制备方法,充分发挥了电子束光刻胶在相同显影液的不同溶解速率和电子束光刻工艺可以同时对不同图形设置不同曝光剂量的特性,有效地减小栅电极的长度。采用金属剥离的方式,避免了刻蚀损伤。剥离后的栅帽与栅介质层空气隔离,减小栅电容。所以具有Π型栅的GaN基射频器件可以达到更高的频率。The method for preparing a GaN-based radio frequency device with a Π-type gate proposed in the present invention fully takes advantage of the different dissolution rates of the electron beam photoresist in the same developer and the electron beam lithography process can simultaneously set different exposure doses for different patterns , Effectively reduce the length of the gate electrode. The metal stripping method is used to avoid etching damage. The stripped gate cap is air-isolated from the gate dielectric layer to reduce the gate capacitance. Therefore, GaN-based radio frequency devices with Π-type gates can reach higher frequencies.
将第一栅脚与第二栅脚中间的部分也沉积栅极金属,则为传统的具有T型栅的GaN基射频器件,其截面图如图11所示。使用Silvaco软件对实施例和具有T型栅的GaN基射频器件在不同频率下的电流增益以及栅极电容进行了仿真,仿真结果如图12,13所示。如图12所示,具有Π型栅的GaN基射频器件的截止频率为70GHz,比具有T型栅的GaN基射频器件的截止频率高了近30GHz。如图13所示,具有Π型栅的GaN基射频器件在Vds=2V,Vg=-5.5V的直流条件下,电容接近45fF,比具有T型栅的GaN基射频器件减小了约25%。The gate metal is also deposited between the first gate pin and the second gate pin, which is a traditional GaN-based radio frequency device with a T-shaped gate. The cross-sectional view is shown in FIG. 11. Silvaco software was used to simulate the current gain and gate capacitance of the embodiment and the GaN-based radio frequency device with a T-shaped gate at different frequencies. The simulation results are shown in Figs. 12 and 13. As shown in Figure 12, the cut-off frequency of a GaN-based radio frequency device with a Π-type gate is 70 GHz, which is nearly 30 GHz higher than that of a GaN-based radio frequency device with a T-type gate. As shown in Figure 13, a GaN-based RF device with a Π-type gate has a capacitance close to 45fF under the DC condition of Vds=2V and Vg=-5.5V, which is about 25% less than a GaN-based RF device with a T-type gate. .
上述实施例仅为本发明的优选实例,不构成对本发明的任何限制,显然对于本领域的专业人员来说,在了解本发明的内容及原理后,能够在不背离本发明的原理和范围的情况下,根据本发明的方法进行形式和细节上的各种修正和改变 ,但是这些基于本发明的修正和改变仍在本发明的权利要求保护。The above-mentioned embodiments are only preferred examples of the present invention and do not constitute any limitation to the present invention. Obviously, for those skilled in the art, after understanding the content and principles of the present invention, they can do so without departing from the principles and scope of the present invention. In this case, various modifications and changes in form and details are made according to the method of the present invention, but these modifications and changes based on the present invention are still protected by the claims of the present invention.

Claims (10)

  1. 一种具有∏型栅的GaN基射频器件,其特征在于,包括AlGaN/GaN异质结外延层,AlGaN/GaN异质结外延层为凸台结构,凸台上部为有源区,有源区上表面的两端分别连接源电极和漏电极,AlGaN/GaN异质结外延层上表面连接有源区以外的区域、有源区的侧壁、有源区上表面连接源电极和漏电极以外的区域、源电极和漏电极上覆盖有一层栅介质层,所述栅介质层在源电极和漏电极的上表面均设有一开口,暴露源电极和漏电极部分上表面,栅介质层的上表面连接∏型栅电极,∏型栅电极位于源电极和漏电极之间,∏型栅电极包括栅帽和栅脚,栅脚的一端连接栅介质层的上表面,另一端连接栅帽的下表面,以支撑栅帽,所述栅脚包括第一栅脚和第二栅脚,第一栅脚和第二栅脚之间具有间距。A GaN-based radio frequency device with a ∏-shaped gate, which is characterized in that it comprises an AlGaN/GaN heterojunction epitaxial layer, the AlGaN/GaN heterojunction epitaxial layer is a boss structure, the upper part of the boss is an active area, and the active area Both ends of the upper surface are connected to the source electrode and the drain electrode. The upper surface of the AlGaN/GaN heterojunction epitaxial layer is connected to the area outside the active area, the sidewall of the active area, and the upper surface of the active area is connected to the source electrode and the drain electrode. The area, the source electrode and the drain electrode are covered with a gate dielectric layer. The gate dielectric layer is provided with an opening on the upper surface of the source electrode and the drain electrode to expose the upper surface of the source electrode and the drain electrode. The upper surface of the gate dielectric layer The surface is connected to the ∏ gate electrode. The ∏ gate electrode is located between the source electrode and the drain electrode. The ∏ gate electrode includes a gate cap and a gate pin. One end of the gate pin is connected to the upper surface of the gate dielectric layer, and the other end is connected to the bottom of the gate cap. The surface is used to support the grid cap, the grid foot includes a first grid foot and a second grid foot, and there is a space between the first grid foot and the second grid foot.
  2. 根据权利要求1所述的具有∏型栅的GaN基射频器件,其特征在于,栅脚横截面的左右长度即长度为L g,10nm≤L g≤300nm;栅脚横截面的上下长度即高度为H g,0nm<H g≤5L g;垂直于栅脚横截面方向上栅脚的厚度即宽度为W g,W g≥1.2μm;第一栅脚和第二栅脚之间的间距为L interval,0nm<L interval≤6L gThe GaN-based radio frequency device with a ∏-shaped gate according to claim 1, wherein the left and right length of the cross section of the gate leg is L g , and 10 nm ≤ L g ≤ 300 nm; the upper and lower length of the cross section of the gate leg is the height Is H g , 0nm<H g ≤5L g ; the thickness of the grid foot perpendicular to the cross-sectional direction of the grid foot is W g , W g ≥1.2μm; the distance between the first grid foot and the second grid foot is L interval ,0nm<L interval ≤6L g ;
    栅帽的长度为L cap,2L g+L interval≤L cap≤6L g+2L interval;栅帽的高度为H cap,0nm<H cap≤18L g+3L interval;栅帽的宽度为W cap,W cap=W gThe length of the gate cap is L cap , 2L g +L interval ≤L cap ≤6L g +2L interval ; the height of the gate cap is H cap , 0nm<H cap ≤18L g +3L interval ; the width of the gate cap is W cap , W cap =W g .
  3. 根据权利要求2所述的具有∏型栅的GaN基射频器件,其特征在于,第一栅脚与源电极位于同侧,第一栅脚与源电极之间的距离为L gs,L gs>(L cap-L interval-2L g)/2;第二栅脚与漏电极位于同侧,第二栅脚与漏电极之间的距离为L gd,L gd>(L cap-L interval-2L g)/2。 The GaN-based radio frequency device with a ∏-shaped gate according to claim 2, wherein the first gate pin and the source electrode are located on the same side, and the distance between the first gate pin and the source electrode is L gs , L gs > (L cap -L interval -2L g )/2; the second gate foot and the drain electrode are on the same side, the distance between the second gate foot and the drain electrode is L gd , L gd >(L cap -L interval -2L g )/2.
  4. 根据权利要求2所述的具有∏型栅的GaN基射频器件,其特征在于,源电极和漏电极为Ti/Al/Ni/Au金属层;源电极和漏电极均为长方体,源电极和漏电极的长度分别为L s和L d,高度分别为H s和H d,宽度分别为W s和W d,L s=L d≥10nm,H s=H d≥10nm,0nm<W s=W d≤W g,源电极和漏电极的间距为L sd,L sd=2L g+L interval+L gs+L gd+L s+L dThe GaN-based radio frequency device with a ∏-shaped gate according to claim 2, wherein the source electrode and the drain electrode are Ti/Al/Ni/Au metal layers; the source electrode and the drain electrode are both rectangular parallelepiped, the source electrode and the drain electrode The length is L s and L d , the height is H s and H d , the width is W s and W d , L s =L d ≥10nm, H s =H d ≥10nm, 0nm<W s =W d ≤ W g , the distance between the source electrode and the drain electrode is L sd , and L sd = 2L g +L interval +L gs +L gd +L s +L d .
  5. 根据权利要求2所述的具有∏型栅的GaN基射频器件,其特征在于,所述AlGaN/GaN异质结外延层为圆形,直径为2-10inch,厚度为200μm-1mm;The GaN-based radio frequency device with a ∏-shaped gate according to claim 2, wherein the AlGaN/GaN heterojunction epitaxial layer is circular, with a diameter of 2-10 inches, and a thickness of 200 μm-1mm;
    有源区的长度为L,L≥L sd,高度为H,100nm≤H≤1mm,宽度为W,W≥W g;源电极和漏电极位于有源区上表面的两端,源漏电极的下表面完全和有源区的上表面接触。 The length of the active area is L, L≥L sd , the height is H, 100nm≤H≤1mm, and the width is W, W≥W g ; the source electrode and the drain electrode are located at both ends of the upper surface of the active area, the source and drain electrodes The bottom surface is completely in contact with the top surface of the active area.
  6. 根据权利要求1所述的具有∏型栅的GaN基射频器件,其特征在于,栅介质层的材料为绝缘金属氧化物、SiO 2和Si 3N 4中的任意一种,栅介质层的厚度不小于1nm。 The GaN-based radio frequency device with a ∏-shaped gate according to claim 1, wherein the material of the gate dielectric layer is any one of insulating metal oxide, SiO 2 and Si 3 N 4 , and the thickness of the gate dielectric layer Not less than 1nm.
  7. 制备如权利要求1至6任一项所述具有∏型栅的GaN基射频器件的方法,其特征在于,包括以下步骤:The method for manufacturing a GaN-based radio frequency device with a ∏-shaped gate according to any one of claims 1 to 6, characterized in that it comprises the following steps:
    (1)准备AlGaN/GaN异质结外延层及清洗:将AlGaN/GaN异质结外延层浸泡在酸性溶液中除去其表面的氧化层,再采用有机溶液超声的方法,除去AlGaN/GaN异质结外延层表面的有机物;(1) Preparation and cleaning of AlGaN/GaN heterojunction epitaxial layer: soak the AlGaN/GaN heterojunction epitaxial layer in an acid solution to remove the oxide layer on the surface, and then use the organic solution ultrasonic method to remove AlGaN/GaN heterogeneity Organic matter on the surface of the junction epitaxial layer;
    (2)器件的相互隔离:在AlGaN/GaN异质结外延层上表面用光刻胶定义有源区的位置并将其覆盖,非有源区的AlGaN/GaN异质结外延层上表面被等离子体轰击刻蚀,刻蚀深度为200nm-600nm;(2) Mutual isolation of devices: define the position of the active area with photoresist on the upper surface of the AlGaN/GaN heterojunction epitaxial layer and cover it, and the upper surface of the AlGaN/GaN heterojunction epitaxial layer in the non-active area is covered by photoresist. Plasma bombardment etching, the etching depth is 200nm-600nm;
    (3)剥离出源电极和漏电极,退火形成欧姆接触:使用光刻胶定义源电极和漏电极的位置及图形,使得源电极和漏电极的位置在有源区上表面的两端,非源电极并且非漏电极的区域被光刻胶覆盖,使用电子束蒸发或者磁控溅射的方法和剥离工艺形成源电极和漏电极,最后在氮气氛围,800℃以上的温度中退火,使源电极、漏电极与AlGaN/GaN异质结外延层均形成欧姆接触;(3) Strip the source and drain electrodes, annealing to form an ohmic contact: Use photoresist to define the positions and patterns of the source and drain electrodes, so that the positions of the source and drain electrodes are at the two ends of the upper surface of the active area. The area of the source electrode and the non-drain electrode is covered by photoresist, the source electrode and the drain electrode are formed using electron beam evaporation or magnetron sputtering method and stripping process, and finally annealed in a nitrogen atmosphere at a temperature above 800°C to make the source The electrode, the drain electrode and the AlGaN/GaN heterojunction epitaxial layer all form an ohmic contact;
    (4)沉积栅介质层:在AlGaN/GaN异质结外延层上表面连接有源区以外的区域、有源区的侧壁、有源区上表面连接源电极和漏电极以外的区域、源电极和漏电极上沉积一层栅介质层;(4) Deposition of the gate dielectric layer: the upper surface of the AlGaN/GaN heterojunction epitaxial layer is connected to the area outside the active area, the sidewalls of the active area, the upper surface of the active area is connected to the area outside the source electrode and the drain electrode, and the source A gate dielectric layer is deposited on the electrode and the drain electrode;
    (5)去除源电极和漏电极上表面的部分栅介质层:源电极和漏电极以外的区域被光刻胶覆盖保护,将源电极和漏电极上表面的部分栅介质层移除,暴露源电极和漏电极的部分上表面;(5) Remove part of the gate dielectric layer on the upper surface of the source electrode and the drain electrode: the area outside the source electrode and the drain electrode is covered and protected by photoresist, remove part of the gate dielectric layer on the upper surface of the source electrode and the drain electrode to expose the source Part of the upper surface of the electrode and the drain electrode;
    (6)制备栅电极:在栅介质层的上表面和暴露的源电极和漏电极部分上表面沉积双层光刻胶,在顶层光刻胶上做出栅帽的图形区域,暴露出部分底层光刻胶,在暴露的部分底层光刻胶上做出栅脚的图形区域,在顶层光刻胶上表面、栅帽的图形区域和栅脚的图形区域上沉积栅电极材料层,剥离顶层光刻胶上表面的栅电极材料层,并去除双层光刻胶,形成∏型栅电极。(6) Preparation of the gate electrode: deposit a double-layer photoresist on the upper surface of the gate dielectric layer and the upper surface of the exposed source and drain electrodes, and make the pattern area of the gate cap on the top photoresist, exposing part of the bottom layer Photoresist, make the pattern area of the gate pin on the exposed part of the bottom photoresist, deposit the gate electrode material layer on the upper surface of the top photoresist, the pattern area of the gate cap and the pattern area of the gate pin, and peel off the top layer photoresist The gate electrode material layer on the upper surface of the resist is removed and the double-layer photoresist is removed to form a ∏-shaped gate electrode.
  8. 根据权利要求7所述的制备具有∏型栅的GaN基射频器件的方法,其特征在于,步骤(4)中沉积栅介质层的方法为等离子体增强的化学气相沉积法、原子层淀积法、磁控溅射方法中的任意一种;步骤(5)中采用湿法腐蚀或干法刻蚀的方法将源电极和漏电极上表面的部分栅介质层移除;步骤(6)中用电子束光刻的方法在双层光刻胶上做出相应的栅帽和栅脚图形区域。The method for preparing a GaN-based radio frequency device with a ∏-shaped gate according to claim 7, wherein the method for depositing the gate dielectric layer in step (4) is plasma-enhanced chemical vapor deposition, atomic layer deposition Any of the magnetron sputtering methods; in step (5), wet etching or dry etching is used to remove part of the gate dielectric layer on the upper surface of the source electrode and the drain electrode; in step (6), The electron beam lithography method makes the corresponding grid cap and grid foot pattern area on the double-layer photoresist.
  9. 根据权利要求8所述的制备具有∏型栅的GaN基射频器件的方法,其特征在于,所述湿法腐蚀采用的腐蚀溶液为酸性腐蚀液,可腐蚀掉绝缘性氧化物、Si 3N 4或SiO 2;干法刻蚀为感应耦合等离子体刻蚀工艺、反应离子刻蚀工艺或其他离子刻蚀工艺中的任意一种。 The method for preparing a GaN-based radio frequency device with a ∏-shaped gate according to claim 8, wherein the etching solution used in the wet etching is an acidic etching solution, which can etch away insulating oxides, Si 3 N 4 Or SiO 2 ; dry etching is any of an inductively coupled plasma etching process, a reactive ion etching process, or other ion etching processes.
  10. 根据权利要求8所述的制备具有∏型栅的GaN基射频器件的方法,其特征在于,双层光刻胶为互不相溶的两种电子束光刻胶,底层光刻胶对电子束的敏感度低于顶层光刻胶对电子束的敏感度,顶层光刻胶的厚度大于底层光刻胶的厚度;在使用电子束光刻的过程中,栅脚图形区域的曝光剂量大于栅脚图形区域以外的曝光剂量;栅电极材料层为两层以上的金属层,最底层的金属层为镍或铂中的一种以上;最顶层的金属层为金或铜中的一种以上;栅电极材料层的总厚度大于底层光刻胶的厚度,小于双层光刻胶的总 厚度。The method for preparing a GaN-based radio frequency device with a ∏-shaped gate according to claim 8, wherein the double-layer photoresist is two immiscible electron beam photoresists, and the bottom photoresist is opposite to the electron beam The sensitivity of the top layer photoresist is lower than that of the electron beam, and the thickness of the top layer photoresist is greater than that of the bottom layer; in the process of using electron beam lithography, the exposure dose of the grid foot pattern area is greater than that of the grid foot Exposure dose outside the pattern area; the gate electrode material layer is more than two metal layers, the bottom metal layer is more than one of nickel or platinum; the top metal layer is more than one of gold or copper; The total thickness of the electrode material layer is greater than the thickness of the bottom layer photoresist and less than the total thickness of the double layer photoresist.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113380884A (en) * 2021-06-08 2021-09-10 上海新微半导体有限公司 Grid electrode of HEMT device, HEMT device and preparation method of HEMT device

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110600542A (en) * 2019-08-13 2019-12-20 中山市华南理工大学现代产业技术研究院 GaN-based radio frequency device with П type gate and preparation method thereof
CN112713185B (en) * 2020-12-21 2022-07-22 西安电子科技大学 T-shaped gate with supporting structure, preparation method thereof and semiconductor power device
CN113257910B (en) * 2021-05-11 2023-01-03 华南师范大学 Comb-type gate structure HEMT radio frequency device and preparation method thereof
CN113257901A (en) * 2021-05-11 2021-08-13 华南师范大学 Radio frequency HEMT device with grid air cavity structure and preparation method thereof
CN115394842A (en) * 2022-05-16 2022-11-25 山东大学 InAlN/GaN HEMT with high power gain cut-off frequency and preparation method thereof
CN115881795A (en) * 2022-09-07 2023-03-31 乂馆信息科技(上海)有限公司 HEMT device

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5970328A (en) * 1996-12-21 1999-10-19 Electronics And Telecommunications Research Institute Fabrication method of T-shaped gate electrode in semiconductor device
CN101017854A (en) * 2006-12-31 2007-08-15 电子科技大学 GaN base transistor with high electronic transfer rate
CN102130160A (en) * 2011-01-06 2011-07-20 西安电子科技大学 Groove-shaped channel AlGaN/GaN-reinforced high electron mobility transistor (HEMT) component and manufacturing method thereof
CN102201334A (en) * 2011-05-23 2011-09-28 中国科学院微电子研究所 Method for manufacturing T-shaped grid structure with U-shaped grid feet
CN104037214A (en) * 2014-06-26 2014-09-10 中国电子科技集团公司第十三研究所 Grid-control semiconductor device for improving short channel effect
CN104952916A (en) * 2015-04-27 2015-09-30 中国电子科技集团公司第五十五研究所 GaN HEMT insulated gate of low interfacial state and manufacture method of insulated gate
CN110600542A (en) * 2019-08-13 2019-12-20 中山市华南理工大学现代产业技术研究院 GaN-based radio frequency device with П type gate and preparation method thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105428236A (en) * 2015-12-30 2016-03-23 桂林电子科技大学 GaN HEMT radio frequency device and gate self-aligning preparation method thereof
CN211929494U (en) * 2019-08-13 2020-11-13 中山市华南理工大学现代产业技术研究院 GaN-based radio frequency device with II-shaped grids

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5970328A (en) * 1996-12-21 1999-10-19 Electronics And Telecommunications Research Institute Fabrication method of T-shaped gate electrode in semiconductor device
CN101017854A (en) * 2006-12-31 2007-08-15 电子科技大学 GaN base transistor with high electronic transfer rate
CN102130160A (en) * 2011-01-06 2011-07-20 西安电子科技大学 Groove-shaped channel AlGaN/GaN-reinforced high electron mobility transistor (HEMT) component and manufacturing method thereof
CN102201334A (en) * 2011-05-23 2011-09-28 中国科学院微电子研究所 Method for manufacturing T-shaped grid structure with U-shaped grid feet
CN104037214A (en) * 2014-06-26 2014-09-10 中国电子科技集团公司第十三研究所 Grid-control semiconductor device for improving short channel effect
CN104952916A (en) * 2015-04-27 2015-09-30 中国电子科技集团公司第五十五研究所 GaN HEMT insulated gate of low interfacial state and manufacture method of insulated gate
CN110600542A (en) * 2019-08-13 2019-12-20 中山市华南理工大学现代产业技术研究院 GaN-based radio frequency device with П type gate and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113380884A (en) * 2021-06-08 2021-09-10 上海新微半导体有限公司 Grid electrode of HEMT device, HEMT device and preparation method of HEMT device

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