WO2021000363A1 - Fabrication process for environmentally friendly insoles based on water hyacinth raw materials - Google Patents

Fabrication process for environmentally friendly insoles based on water hyacinth raw materials Download PDF

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Publication number
WO2021000363A1
WO2021000363A1 PCT/CN2019/097461 CN2019097461W WO2021000363A1 WO 2021000363 A1 WO2021000363 A1 WO 2021000363A1 CN 2019097461 W CN2019097461 W CN 2019097461W WO 2021000363 A1 WO2021000363 A1 WO 2021000363A1
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water hyacinth
sterilization
insole
foaming
raw materials
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PCT/CN2019/097461
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French (fr)
Chinese (zh)
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蒋荣军
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蒋荣军
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    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B17/00Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
    • A43B17/14Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined made of sponge, rubber, or plastic materials
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/02Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
    • A61L2/04Heat
    • A61L2/06Hot gas
    • A61L2/07Steam
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/26Accessories or devices or components used for biocidal treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066Use of inorganic compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0095Mixtures of at least two compounding ingredients belonging to different one-dot groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2499/00Characterised by the use of natural macromolecular compounds or of derivatives thereof not provided for in groups C08J2401/00 - C08J2407/00 or C08J2489/00 - C08J2497/00

Definitions

  • the invention relates to the technical field of insole preparation, and more specifically to an environmentally friendly insole preparation process based on water hyacinth raw materials.
  • Water hyacinth also known as Eichhornia crassipes
  • Eichhornia crassipes Water hyacinth
  • Water hyacinth is a floating herb. It is native to Brazil. It is now widely distributed in the Yangtze River and Yellow River basins of China and southern China. It likes a warm, humid and sunny environment. It is also highly adaptable and has a certain cold tolerance. In ponds, ditches and rice fields at an altitude of 200-1500 meters, it has also been widely grown in tropical Asia. Eichhornia crassipes is in suitable growth areas. It is often caused by excessive breeding, blocking waterways and affecting traffic. Eichhornia crassipes was once used by many countries Introduced, widely distributed all over the world, and also listed as one of the world's top 100 invasive alien species.
  • the whole grass is feed for livestock and poultry; the tender leaves and petioles can be used as vegetables, and the whole plant can also be used for medicinal purposes. It has cooling and detoxification and dehumidification. It has the effects of dispelling wind-heat and external application of heat sore.
  • insoles are widely used in the shoe industry, health care, and special functions; generally, they are divided into two modes: shoe industry application shoe factory application insole and market commodity type.
  • the shoe industry application insole is mainly to match the shoe size Make the corresponding shape for the bottom and midsole; make the size plate according to the last floor or panel, and make the corresponding shape.
  • Water hyacinth has become a common phenomenon in many places due to its strong environmental adaptability. Although water hyacinth has a certain purifying effect on the water environment, the material will be reversed. Water hyacinth will suffer from eutrophication. Mass reproduction, a barbaric blockade strategy was adopted on the water surface where they lived, blocking the sunlight, causing the underwater creatures to die without getting enough light, destroying the food chain of underwater animals, mainly reflected in the serious impact on our water environment And cause a large number of fish to die due to lack of oxygen. At present, water hyacinth can be found in 19 provinces (autonomous regions and municipalities) in North China, East China, Central China and South China.
  • the insoles on the market use more chemical materials, which not only have a high cost but also have a certain negative impact on the environment. Especially in such a large shoe market in my country, the unfavorable factors will be infinitely amplified, restricting the footwear industry. Further development.
  • the purpose of the present invention is to provide an environmentally friendly insole preparation process based on water hyacinth raw materials, which can realize the use of artificially salvaged fresh water hyacinth as the raw material, followed by washing, drying, high-temperature dehydration, and crushing.
  • Water hyacinth powder is prepared after powdering and high-temperature sterilization, and the essence is discarded from the dregs. The advantages and effects of water hyacinth are retained during the powdering process. At the same time, strict high-temperature sterilization is used to avoid harm to the human body.
  • the present invention adopts the following technical solutions.
  • An environmentally friendly insole preparation process based on water hyacinth raw materials includes the following steps:
  • High temperature sterilization treatment the water hyacinth powder is subjected to high temperature sterilization treatment through a sterilization device, and the high temperature steam temperature should be 120°C-180°C;
  • the sterilization device includes a sterilization reaction kettle, the sterilization reaction kettle is connected with a vacuum pump through a communication pipe, a vacuum valve is installed on the communication pipe, and the upper left end of the sterilization reaction kettle is connected with a feed three
  • the upper end of the sterilization reaction kettle is fixedly connected with a drive motor
  • the inside of the sterilization reaction kettle is provided with a stirring shaft
  • the output shaft of the drive motor penetrates the upper end of the sterilization reaction kettle and is fixedly connected with the stirring shaft
  • the lower left end of the sterilization reaction kettle is fixedly connected with a discharge port, which is convenient for high-temperature sterilization of water hyacinth powder with high efficiency and good effect.
  • a blanking plate is fixedly connected to the lower side of the inner end of the sterilization reactor, a number of evenly distributed blowing holes are cut on the blanking plate, and a ventilation screen is fixedly connected to the upper end of the blanking plate.
  • the lower end of the sterilization reactor is connected with a blower through the air pipe, which can assist the stirring shaft to diffuse the water hyacinth powder, and at the same time can use the gas blown from the blow hole to make the settled water hyacinth powder fly again and contact with high-temperature steam for destruction bacteria.
  • a precision filter is installed in one end of the feed three-way pipe leading to the water hyacinth powder, the stirring shaft adopts a spiral structure, and the inner end of the stirring shaft is fixedly connected with an electric heating wire, and the precision filter acts as a countermeasure
  • the filtering effect of impurities in water hyacinth powder and larger particle size powder, the stirring shaft can not only stir and diffuse to increase the sterilization rate and effect, but also can preheat the sterilization reactor and heat the high temperature steam, which significantly improves the high temperature steam The sterilization effect.
  • the high temperature sterilization treatment specifically includes the following steps:
  • the water hyacinth powder is further diffused repeatedly to increase the contact area with high-temperature steam and the number of sterilization times, thereby improving the all-round sterilization effect.
  • the foam material of the insole foam is 30-60% polyethylene, 10-25% talc, 0.5-2% cross-linking agent, 0.2-1% cross-linking aid, and 2-10 foaming agent. %, 3-5% foaming aid, 0.1-2% lubricant, 0.1-15% graphene, 0.1-15% silica, and the content ratio of water hyacinth powder to foaming material is 1:2-5 .
  • the polyethylene, talc, crosslinking agent, crosslinking assistant, foaming agent, foaming assistant, lubricant, graphene and silica were put into the mixer for mixing treatment respectively.
  • the foaming mixture is obtained, and the mixing treatment temperature is 125° C.-150° C., so that the foaming material can be fully stirred and mixed, thereby ensuring the overall performance of the insole after molding.
  • the molding temperature of the foaming of the insole is 160°C
  • the molding time is 30min-40min
  • the pressure is 10-15Mpa.
  • the water hyacinth is dried at a high temperature until the dehydration rate reaches 90%. If the dehydration rate is lower than 90%, continue high-temperature drying to increase the dehydration rate to reduce the influence of the water content of the water hyacinth on subsequent processes.
  • the finished product of the insole should undergo quality inspection, which includes Martindale wear resistance, color fastness to rubbing, breaking strength, elongation at break, elongation at fixed strength, aging resistance, breaking strength and resistance Color fastness to soaping. If the quality inspection is qualified, the finished insole enters the packaging and delivery process. If the quality inspection fails, the finished insole is discarded and recycled. Professional quality inspection of the finished insole made by the present invention must meet relevant standards and specifications. Only then can it flow to the market and strictly control the quality of insoles.
  • the sterilization device includes a sterilization reaction kettle.
  • the sterilization reaction kettle is connected with a vacuum pump through a connecting pipe, and the connecting pipe is equipped with a vacuum valve.
  • the upper left end of the sterilization reaction kettle is connected with a feed three-way pipe, and the upper end of the sterilization reaction kettle
  • the drive motor is fixedly connected, and the inside of the sterilization reactor is equipped with a stirring shaft.
  • the output shaft of the drive motor penetrates the upper end of the sterilization reactor and is fixedly connected with the stirring shaft.
  • the lower left end of the sterilization reactor is fixedly connected with a discharge port for convenience High temperature sterilization of water hyacinth powder has high efficiency and good effect.
  • a blanking plate is fixedly connected to the lower side of the inner end of the sterilization reactor.
  • a number of evenly distributed blowing holes are cut on the blanking plate.
  • the upper end of the blanking plate is fixedly connected with a ventilation screen, and the lower end of the sterilization reactor passes through a wind pipe.
  • a blower is connected to assist the stirring shaft to diffuse the water hyacinth powder, and at the same time, the air blown from the blowing hole can make the settled water hyacinth powder fly again to contact with high-temperature steam for sterilization.
  • a precision filter is installed in one end of the feed tee pipe that leads to the water hyacinth powder, the stirring shaft adopts a spiral structure, and the inner end of the stirring shaft is fixedly connected with an electric heating wire.
  • the precision filter plays a role in preventing impurities in the water hyacinth powder.
  • the stirring shaft can not only stir and diffuse to increase the sterilization rate and effect, but also can preheat the sterilization reactor and heat the high temperature steam, which significantly improves the sterilization effect of the high temperature steam.
  • Finished insoles should undergo quality inspection, including Martindale wear resistance, color fastness to rubbing, breaking strength, elongation at break, elongation at fixed strength, aging resistance, breaking strength and color fastness to soaping If the quality inspection is qualified, the insole product will enter the packaging and delivery process. If the quality inspection is unqualified, the insole product will be discarded and recycled. Professional quality inspection of the insole product made by the present invention must meet the relevant standards and specifications before it can be sold to the market , Strictly control the quality of insoles.
  • FIG 1 is the main process flow diagram of the present invention
  • FIG. 2 is a schematic diagram of the structure of the sterilization device of the present invention.
  • Figure 3 is a schematic diagram of the structure of the finished insole of the present invention.
  • 1 Sterilization reactor 2 vacuum pump, 3 connecting pipe, 4 vacuum valve, 5 feeding three-way pipe, 6 precision filter, 7 discharge port, 8 blower, 9 drive motor, 10 stirring shaft, 11 blanking plate, 12 blowing holes, 13 ventilation screens.
  • An environmentally friendly insole preparation process based on water hyacinth raw materials includes the following steps:
  • the water hyacinth is dried at a high temperature until the dehydration rate reaches 90%. If the dehydration rate is less than 90%, continue high-temperature drying to increase the dehydration rate to reduce the influence of the water content of the water hyacinth on the subsequent processes.
  • High temperature sterilization treatment the water hyacinth powder is subjected to high temperature sterilization treatment through a sterilization device, wherein the high temperature steam temperature is preferably 120°C-180°C; the high temperature sterilization treatment specifically includes the following steps:
  • the molding temperature of the insole foam is 160°C
  • the molding time is 30min
  • the pressure is 10Mpa.
  • the sterilization device includes a sterilization reactor 1.
  • the sterilization reactor 1 is connected with a vacuum pump 2 through a connecting pipe 3, a vacuum valve 4 is installed on the connecting pipe 3, and the upper left end of the sterilization reactor 1 is connected with a feed Tee tube 5, the upper end of the sterilization reactor 1 is fixedly connected with a drive motor 9, and the inside of the sterilization reactor 1 is provided with a stirring shaft 10, and the output shaft of the drive motor 9 penetrates the upper end of the sterilization reactor 1 and is between the stirring shaft 10
  • Fixed connection, the lower left end of the sterilization reactor 1 is fixedly connected with a discharge port 7, which is convenient for high-temperature sterilization of water hyacinth powder, with high efficiency and good effect.
  • the lower side of the inner end of the sterilization reactor 1 is fixedly connected with a blanking plate 11, An air storage cavity is left between the blanking plate 11 and the inner bottom end of the sterilization reaction vessel 1, a number of evenly distributed blowing holes 12 are excavated on the blanking plate 11, and the upper end of the blanking plate 11 is fixedly connected with a ventilation screen 13,
  • the aperture of the aeration screen 13 is smaller than the particle size of the water hyacinth powder, and only gas is allowed to pass.
  • the lower end of the sterilization reactor 1 is connected with a blower 8 through an air pipe, which can assist the stirring shaft 10 to diffuse the water hyacinth powder and can also be used
  • the gas blown from the blowing hole 12 causes the settled water hyacinth powder to fly again and contact with high-temperature steam for sterilization.
  • a precision filter 6 is installed in the end of the feed tee tube 5 where the water hyacinth powder enters, and the stirring shaft 10 adopts a spiral.
  • the inner end of the stirring shaft 10 is fixedly connected with an electric heating wire, the precision filter 6 has a filtering effect on the impurities in the water hyacinth powder and the larger particle size powder, and the stirring shaft 10 can not only stir and diffuse, increase the sterilization rate and Effect, at the same time, the sterilization reactor 1 can be preheated and high-temperature steam insulation can be performed, which significantly improves the sterilization effect of the high-temperature steam.
  • the foaming material for insole foaming is polyethylene 55%, talc 15%, cross-linking agent 2%, cross-linking assistant 1%, foaming agent 5%, foaming assistant 5%, lubricant 1%, graphite Ene 10%, silicon dioxide 6%, and the content ratio of water hyacinth powder to foaming material is 1:4, polyethylene, talc, crosslinking agent, crosslinking assistant, foaming agent, foaming assistant , Lubricant, Graphene and Silica were separately put into the mixer for mixing treatment to obtain the foaming mixture.
  • the mixing treatment temperature is 150°C, which can make the foaming material get fully stirred and mixed, and thus ensure The overall performance of the insole after molding.
  • Finished insoles should undergo quality inspection, including Martindale wear resistance, color fastness to rubbing, breaking strength, elongation at break, elongation at fixed strength, aging resistance, breaking strength and color fastness to soaping. If the quality inspection is qualified, the insole product will enter the packaging and delivery process. If the quality inspection is unqualified, the insole product will be discarded and recycled.
  • the insole product prepared by the present invention is subject to professional quality inspection. The insole product must meet relevant standards and specifications before it can be sold to the market. Control the quality of insoles.
  • the foaming material for insole foaming is polyethylene 40%, talc 20%, crosslinking agent 1%, crosslinking assistant 0.5%, foaming agent 4%, foaming assistant 4%, lubricant 1%, graphite
  • the content ratio of the water hyacinth powder to the foaming material is 1:3, and the rest are the same as in Example 1.
  • the foaming material of the insole foaming is polyethylene 60%, talc powder 25%, crosslinking agent 2%, crosslinking assistant 1%, foaming agent 10%, foaming assistant 5%, lubricant 2% , Graphene 15%, silica 15%, and the content ratio of water hyacinth powder to foaming material is 1:2, and the rest are the same as in Example 1.
  • the method can realize the water hyacinth powder obtained by using the fresh water hyacinth manually salvaged as the raw material, washing and drying, high-temperature dehydration, crushing into powder, and high-temperature sterilization in order to prepare water hyacinth powder, the essence is taken and the dregs are discarded, and the water hyacinth powder is retained during the powdering process
  • the advantages and effects of water hyacinth while avoiding harm to the human body through strict high-temperature sterilization, and foaming it with foaming raw materials to make a large board, giving full play to its environmental protection and pollution-free, eliminating
  • the advantages of smelly, sweat-absorbing, non-toxic, tasteless, and vibration reduction have opened new gaps in the development of the insole industry, and at the same time promoted the environmental governance of the flood of water hyacinth, thereby forming a virtuous circle between the water hyacinth governance and the insole industry. Bora significantly improves economic and social benefits.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Epidemiology (AREA)
  • Inorganic Chemistry (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)

Abstract

A fabrication process for environmentally friendly insoles based on water hyacinth raw materials, comprising the following steps: manually harvesting water hyacinths, preprocessing, making water hyacinth powder, high temperature sterilization, shoe pad foaming, preliminary formation, and cutting pairs. The invention takes full advantage of the strengths of water hyacinths in terms of being environmentally-friendly, pollution-free, deodorizing, sweat-absorbing, non-toxic, odorless, and vibration damping.

Description

一种基于水葫芦原料的环保鞋垫制备工艺Environmental protection insole preparation process based on water hyacinth raw materials 技术领域Technical field
本发明涉及鞋垫制备技术领域,更具体地说,涉及一种基于水葫芦原料的环保鞋垫制备工艺。The invention relates to the technical field of insole preparation, and more specifically to an environmentally friendly insole preparation process based on water hyacinth raw materials.
背景技术Background technique
水葫芦又名凤眼蓝,浮水草本,原产巴西,现广布于中国长江、黄河流域及华南各省,喜欢温暖湿润、阳光充足的环境,适应性也很强,具有一定的耐寒能力,生于海拔200-1500米的水塘、沟渠及稻田中,亚洲热带地区也已广泛生长,凤眼蓝在生长适宜区,常由于过度繁殖,阻塞水道,影响交通,凤眼蓝曾一度被很多国家引进,广泛分布于世界各地,亦被列入世界百大外来入侵种之一,全草为家畜、家禽饲料;嫩叶及叶柄可作蔬菜,全株也可供药用,有清凉解毒、除湿祛风热以及外敷热疮等功效。Water hyacinth, also known as Eichhornia crassipes, is a floating herb. It is native to Brazil. It is now widely distributed in the Yangtze River and Yellow River basins of China and southern China. It likes a warm, humid and sunny environment. It is also highly adaptable and has a certain cold tolerance. In ponds, ditches and rice fields at an altitude of 200-1500 meters, it has also been widely grown in tropical Asia. Eichhornia crassipes is in suitable growth areas. It is often caused by excessive breeding, blocking waterways and affecting traffic. Eichhornia crassipes was once used by many countries Introduced, widely distributed all over the world, and also listed as one of the world's top 100 invasive alien species. The whole grass is feed for livestock and poultry; the tender leaves and petioles can be used as vegetables, and the whole plant can also be used for medicinal purposes. It has cooling and detoxification and dehumidification. It has the effects of dispelling wind-heat and external application of heat sore.
鞋业在我国的消费品行业中占据了举足轻重的一席地位,2009年前中国鞋类产品有70%以上出口到全球其它国家,中国鞋类出口经历过一轮高速增长后,增速从2005-2008年出现放缓迹象,但鞋类出口仍保持7%以上的增速,根据统计局对中国鞋类市场的分析,2003年中国城镇、农村消费鞋类产品分别为13.4亿双和7.7亿双,到2008年则分别达到17.2亿双和8.6亿双,总量达25.8亿双,超过美国同年鞋类产品消费的24亿双,占全球消费总量的13%左右,中国成为全球最大的鞋类产品消费国;其中鞋垫大量应用于制鞋业、保健、特殊功用;一般分为制鞋业应用型鞋厂应用型鞋垫和市场商品型两种模式,制鞋业应用的鞋垫主要是配合鞋子大底、中底、做出相应的型体;按照楦底板或者面板制作尺码板,并制作出相应的形状。The footwear industry occupies a pivotal position in China’s consumer goods industry. Before 2009, more than 70% of Chinese footwear products were exported to other countries in the world. After a round of rapid growth in China’s footwear exports, the growth rate has increased from 2005 to 2008. There were signs of slowdown in the year, but footwear exports still maintained a growth rate of more than 7%. According to the analysis of the Chinese footwear market by the Statistics Bureau, in 2003, China’s urban and rural consumption of footwear products were 1.34 billion pairs and 770 million pairs, respectively. By 2008, they reached 1.72 billion pairs and 860 million pairs, totaling 2.58 billion pairs, surpassing the 2.4 billion pairs of footwear consumption in the United States in the same year, accounting for about 13% of global consumption. China has become the world's largest footwear. Product consumption country; among them, insoles are widely used in the shoe industry, health care, and special functions; generally, they are divided into two modes: shoe industry application shoe factory application insole and market commodity type. The shoe industry application insole is mainly to match the shoe size Make the corresponding shape for the bottom and midsole; make the size plate according to the last floor or panel, and make the corresponding shape.
水葫芦因其极强的环境适应力在各个地方过度繁殖,已经成为许多地方司空见惯的现象了,尽管水葫芦对水体环境具有一定的净化作用,但是物极 必反,水葫芦在富营养化的环境下会大量繁殖,对其生活的水面采取了野蛮的封锁策略,挡住了阳光,导致水下的生物得不到足够的光照而死亡,破坏水下动物的食物链,主要体现在严重影响了我们的水质环境及造成大量鱼类的缺氧而死亡,目前,水葫芦能见于我国华北、华东、华中和华南的19个省(自治区、直辖市),我国主要城市湖泊如太湖、滇池也都倍受水葫芦蔓延成灾的困扰。截止目前,并没有有效的环保途径控制和减少水葫芦的蔓延,也考虑到尽可能不产生次生污染物的原则,目前水葫芦的治理主要是以打捞为主,目前,针对打捞出的水葫芦生物量,利用的方式主要有:饲料化、肥料化、用于造纸、制作手工艺品和家具、用做食用菌培养的基质等,但是难以真正有效的融入到人们的生活中而形成产业链。Water hyacinth has become a common phenomenon in many places due to its strong environmental adaptability. Although water hyacinth has a certain purifying effect on the water environment, the material will be reversed. Water hyacinth will suffer from eutrophication. Mass reproduction, a barbaric blockade strategy was adopted on the water surface where they lived, blocking the sunlight, causing the underwater creatures to die without getting enough light, destroying the food chain of underwater animals, mainly reflected in the serious impact on our water environment And cause a large number of fish to die due to lack of oxygen. At present, water hyacinth can be found in 19 provinces (autonomous regions and municipalities) in North China, East China, Central China and South China. China’s major urban lakes such as Taihu Lake and Dianchi Lake are also affected by the spread of water hyacinth. Disaster trouble. Up to now, there is no effective environmental protection method to control and reduce the spread of water hyacinth, and the principle of not producing secondary pollutants as much as possible is also considered. At present, the treatment of water hyacinth is mainly based on salvage. Gourd biomass is mainly used in feed, fertilizer, papermaking, handicrafts and furniture, as a substrate for cultivating edible fungi, etc., but it is difficult to truly and effectively integrate into people’s lives to form an industrial chain .
目前市场上的鞋垫均采用较多的化学材料,不仅成本较高同时对环境具有一定的不利影响,尤其是在我国如此大的鞋业市场上,不利因素会被无限放大,制约着鞋业的进一步发展。At present, the insoles on the market use more chemical materials, which not only have a high cost but also have a certain negative impact on the environment. Especially in such a large shoe market in my country, the unfavorable factors will be infinitely amplified, restricting the footwear industry. Further development.
发明内容Summary of the invention
1.要解决的技术问题1. Technical problems to be solved
针对现有技术中存在的问题,本发明的目的在于提供一种基于水葫芦原料的环保鞋垫制备工艺,它可以实现将人工打捞上的新鲜水葫芦作为原料,依次经过清洗晾晒、高温脱水、破碎成粉和高温灭菌处理后制得水葫芦粉末,取其精华弃其糟粕,制粉过程中保留水葫芦带来的优势和作用,同时通过严格的高温灭菌处理来避免对人体的危害,并将其与发泡原材料混炼后发泡制得大块板材,充分发挥其环保无公害、除臭、吸汗、无毒、无味、减振的优点,打开鞋垫产业发展的新缺口,同时也促进水葫芦泛滥的环境治理,进而形成水葫芦治理和鞋垫产业之间的良性循环,通过变废为宝来显著提高经济效益和社会效益。In view of the problems in the prior art, the purpose of the present invention is to provide an environmentally friendly insole preparation process based on water hyacinth raw materials, which can realize the use of artificially salvaged fresh water hyacinth as the raw material, followed by washing, drying, high-temperature dehydration, and crushing. Water hyacinth powder is prepared after powdering and high-temperature sterilization, and the essence is discarded from the dregs. The advantages and effects of water hyacinth are retained during the powdering process. At the same time, strict high-temperature sterilization is used to avoid harm to the human body. It is mixed with foaming raw materials and then foamed to make a large plate, which gives full play to its advantages of environmental protection, pollution-free, deodorization, sweat absorption, non-toxic, tasteless, and vibration reduction, opening a new gap in the development of the insole industry, and also Promote the environmental governance of water hyacinth flooding, and then form a virtuous circle between water hyacinth governance and the insole industry, and significantly improve economic and social benefits by turning waste into treasure.
2.技术方案2. Technical solution
为解决上述问题,本发明采用如下的技术方案。To solve the above problems, the present invention adopts the following technical solutions.
一种基于水葫芦原料的环保鞋垫制备工艺,包括以下步骤:An environmentally friendly insole preparation process based on water hyacinth raw materials includes the following steps:
S1、人工打捞起新鲜水葫芦,清洗多余附着物后进行自然摊铺晾晒;S1. Fresh water hyacinths are picked up manually, and the excess attachments are cleaned and then spread and dried naturally;
S2、预处理,将晒干后的水葫芦在80-120℃的抽真空条件下进行高温烘干灭菌;S2, pretreatment, drying and sterilizing the dried water hyacinth at a high temperature under vacuum conditions of 80-120℃;
S3、水葫芦制粉,通过粉碎机将烘干后的水葫芦进行均匀粉碎得到水葫芦粉末,粉碎后的水葫芦粉末粒径为40-60目;S3. Making water hyacinth powder, uniformly pulverizing the dried water hyacinth by a pulverizer to obtain water hyacinth powder, the particle size of the water hyacinth powder after crushing is 40-60 mesh;
S4、高温灭菌处理,通过灭菌装置对水葫芦粉末进行高温灭菌处理,其中高温蒸汽温度宜为120℃-180℃;S4. High temperature sterilization treatment, the water hyacinth powder is subjected to high temperature sterilization treatment through a sterilization device, and the high temperature steam temperature should be 120°C-180°C;
S5、鞋垫发泡,将水葫芦粉末与发泡材料进行搅拌,均匀混合后的物料倒入发泡机加磁模具内,进行模压发泡,发泡完毕,卸压跳模,取出大块板材;S5. Foaming the insole. Stir the water hyacinth powder and the foaming material. Pour the evenly mixed material into the foaming machine and the magnetic mold for compression and foaming. After the foaming is completed, the pressure is released and the mold is removed, and the large plate is taken out ;
S6、初步成型,将S5中的发泡所得板材裁剪成若干份20*18cm的矩形板材,并置入定制化模具中热压成型,得到初步成型的鞋垫;S6. Preliminary forming, cutting the foamed sheet in S5 into several 20*18cm rectangular sheets, and placing them in a customized mold for hot pressing to obtain a preliminary formed insole;
S7、裁断斩双,将初步成型的鞋垫经过裁断机进行裁断,并进行整理修边作业,得到鞋垫成品。S7. Cut and cut the pair, cut the preliminarily formed insole through a cutting machine, and perform finishing and trimming operations to obtain the finished insole.
进一步的,所述灭菌装置包括灭菌反应釜,所述灭菌反应釜通过连通管连接有真空泵,所述连通管上安装有真空阀,所述灭菌反应釜左上端连接有进料三通管,所述灭菌反应釜上端固定连接有驱动电机,所述灭菌反应釜内侧设有搅拌轴,所述驱动电机的输出轴贯穿灭菌反应釜上端并与搅拌轴之间固定连接,所述灭菌反应釜左下端固定连接有出料口,方便对水葫芦粉末进行高温灭菌,效率高效果好。Further, the sterilization device includes a sterilization reaction kettle, the sterilization reaction kettle is connected with a vacuum pump through a communication pipe, a vacuum valve is installed on the communication pipe, and the upper left end of the sterilization reaction kettle is connected with a feed three The upper end of the sterilization reaction kettle is fixedly connected with a drive motor, the inside of the sterilization reaction kettle is provided with a stirring shaft, and the output shaft of the drive motor penetrates the upper end of the sterilization reaction kettle and is fixedly connected with the stirring shaft, The lower left end of the sterilization reaction kettle is fixedly connected with a discharge port, which is convenient for high-temperature sterilization of water hyacinth powder with high efficiency and good effect.
进一步的,所述灭菌反应釜内端下侧固定连接有落料板,所述落料板上开凿有若干均匀分布的吹气孔,所述落料板上端固定连接有通气隔网,所述灭菌反应釜下端通过风管连接有鼓风机,可以辅助搅拌轴起到扩散水葫芦粉 末的作用,同时可以利用从吹气孔中吹出的气体使得沉降下来的水葫芦粉末再次飞扬与高温蒸汽接触进行灭菌。Further, a blanking plate is fixedly connected to the lower side of the inner end of the sterilization reactor, a number of evenly distributed blowing holes are cut on the blanking plate, and a ventilation screen is fixedly connected to the upper end of the blanking plate. The lower end of the sterilization reactor is connected with a blower through the air pipe, which can assist the stirring shaft to diffuse the water hyacinth powder, and at the same time can use the gas blown from the blow hole to make the settled water hyacinth powder fly again and contact with high-temperature steam for destruction bacteria.
进一步的,所述进料三通管通入水葫芦粉的一端内安装有精密过滤器,所述搅拌轴采用螺旋式结构,所述搅拌轴内端固定连接有电热丝,精密过滤器起到对水葫芦粉内杂质和较大粒径粉末的过滤效果,搅拌轴不仅可以起到搅拌扩散提高灭菌速率和效果,同时可以对灭菌反应釜进行预热和高温蒸汽的保温,显著提高高温蒸汽的灭菌效果。Further, a precision filter is installed in one end of the feed three-way pipe leading to the water hyacinth powder, the stirring shaft adopts a spiral structure, and the inner end of the stirring shaft is fixedly connected with an electric heating wire, and the precision filter acts as a countermeasure The filtering effect of impurities in water hyacinth powder and larger particle size powder, the stirring shaft can not only stir and diffuse to increase the sterilization rate and effect, but also can preheat the sterilization reactor and heat the high temperature steam, which significantly improves the high temperature steam The sterilization effect.
进一步的,所述高温灭菌处理具体包括以下步骤:Further, the high temperature sterilization treatment specifically includes the following steps:
S41、先制造真空灭菌环境并进行预热;S41. Create a vacuum sterilization environment and preheat it;
S42、同时通入水葫芦粉和高温蒸汽,并进行扩散搅拌;S42. Pass water hyacinth powder and high-temperature steam at the same time, and perform diffusion stirring;
S43、借助外力进一步反复扩散水葫芦粉来增大与高温蒸汽的接触面积和灭菌次数,进而提高全方位的灭菌效果。S43. With the help of external force, the water hyacinth powder is further diffused repeatedly to increase the contact area with high-temperature steam and the number of sterilization times, thereby improving the all-round sterilization effect.
进一步的,所述鞋垫发泡的发泡材料为聚乙烯30-60%、滑石粉10-25%、交联剂0.5-2%、交联助剂0.2-1%、发泡剂2-10%、发泡助剂3-5%、润滑剂0.1-2%、石墨烯0.1-15%、二氧化硅0.1-15%,且水葫芦粉末与发泡材料的含量比为1:2-5。Further, the foam material of the insole foam is 30-60% polyethylene, 10-25% talc, 0.5-2% cross-linking agent, 0.2-1% cross-linking aid, and 2-10 foaming agent. %, 3-5% foaming aid, 0.1-2% lubricant, 0.1-15% graphene, 0.1-15% silica, and the content ratio of water hyacinth powder to foaming material is 1:2-5 .
进一步的,将聚乙烯、滑石粉、交联剂、交联助剂、发泡剂、发泡助剂、润滑剂、石墨烯和二氧化硅分别投入至混炼机中进行混炼处理,以获得发泡混合料,混炼处理温度为125℃-150℃,可以使得发泡材料得到充分的搅拌混合,进而保证鞋垫成型后的整体性能。Further, the polyethylene, talc, crosslinking agent, crosslinking assistant, foaming agent, foaming assistant, lubricant, graphene and silica were put into the mixer for mixing treatment respectively. The foaming mixture is obtained, and the mixing treatment temperature is 125° C.-150° C., so that the foaming material can be fully stirred and mixed, thereby ensuring the overall performance of the insole after molding.
进一步的,所述鞋垫发泡的模压温度为160℃,模压时间为30min-40min,压力为10-15Mpa。Further, the molding temperature of the foaming of the insole is 160°C, the molding time is 30min-40min, and the pressure is 10-15Mpa.
进一步的,所述预处理中对水葫芦高温烘干至脱水率达到90%,若脱水率低于90%,继续高温烘干,提高脱水率来降低水葫芦所含水分对后续工序的影响。Further, in the pretreatment, the water hyacinth is dried at a high temperature until the dehydration rate reaches 90%. If the dehydration rate is lower than 90%, continue high-temperature drying to increase the dehydration rate to reduce the influence of the water content of the water hyacinth on subsequent processes.
进一步的,所述鞋垫成品应经过质检,所述质检包括马丁代尔耐磨性能、摩擦色牢度、断裂强度、断裂伸长率、定强伸长率、耐老化、破裂强度和耐皂洗色牢度,若质检合格,则鞋垫成品进入包装出厂程序,若质检不合格,则鞋垫成品作废弃回收处理,对本发明制得的鞋垫成品进行专业质检,必须满足相关标准规范后才能流向市场,严格把控鞋垫质量。Further, the finished product of the insole should undergo quality inspection, which includes Martindale wear resistance, color fastness to rubbing, breaking strength, elongation at break, elongation at fixed strength, aging resistance, breaking strength and resistance Color fastness to soaping. If the quality inspection is qualified, the finished insole enters the packaging and delivery process. If the quality inspection fails, the finished insole is discarded and recycled. Professional quality inspection of the finished insole made by the present invention must meet relevant standards and specifications. Only then can it flow to the market and strictly control the quality of insoles.
3.有益效果3. Beneficial effects
相比于现有技术,本发明的优点在于:Compared with the prior art, the advantages of the present invention are:
(1)本方案可以实现将人工打捞上的新鲜水葫芦作为原料,依次经过清洗晾晒、高温脱水、破碎成粉和高温灭菌处理后制得水葫芦粉末,取其精华弃其糟粕,制粉过程中保留水葫芦带来的优势和作用,同时通过严格的高温灭菌处理来避免对人体的危害,并将其与发泡原材料混炼后发泡制得大块板材,充分发挥其环保无公害、除臭、吸汗、无毒、无味、减振的优点,打开鞋垫产业发展的新缺口,同时也促进水葫芦泛滥的环境治理,进而形成水葫芦治理和鞋垫产业之间的良性循环,通过变废为宝来显著提高经济效益和社会效益。(1) This scheme can realize the use of fresh water hyacinth manually salvaged as raw material, and then after washing and drying, high-temperature dehydration, crushing into powder and high-temperature sterilization, water hyacinth powder is prepared, and the essence is discarded and the dregs are used for powdering. In the process, the advantages and functions of water hyacinth are retained, and at the same time, strict high-temperature sterilization is adopted to avoid harm to the human body. After mixing it with foaming raw materials, foaming is made into a large board, giving full play to its environmental protection. The advantages of pollution, deodorization, sweat absorption, non-toxic, tasteless, and vibration reduction have opened up new gaps in the development of the insole industry, and at the same time promoted the environmental governance of the flood of water hyacinth, thereby forming a virtuous circle between water hyacinth governance and the insole industry. Turning waste into Bora significantly improves economic and social benefits.
(2)灭菌装置包括灭菌反应釜,灭菌反应釜通过连通管连接有真空泵,连通管上安装有真空阀,灭菌反应釜左上端连接有进料三通管,灭菌反应釜上端固定连接有驱动电机,灭菌反应釜内侧设有搅拌轴,驱动电机的输出轴贯穿灭菌反应釜上端并与搅拌轴之间固定连接,灭菌反应釜左下端固定连接有出料口,方便对水葫芦粉末进行高温灭菌,效率高效果好。(2) The sterilization device includes a sterilization reaction kettle. The sterilization reaction kettle is connected with a vacuum pump through a connecting pipe, and the connecting pipe is equipped with a vacuum valve. The upper left end of the sterilization reaction kettle is connected with a feed three-way pipe, and the upper end of the sterilization reaction kettle The drive motor is fixedly connected, and the inside of the sterilization reactor is equipped with a stirring shaft. The output shaft of the drive motor penetrates the upper end of the sterilization reactor and is fixedly connected with the stirring shaft. The lower left end of the sterilization reactor is fixedly connected with a discharge port for convenience High temperature sterilization of water hyacinth powder has high efficiency and good effect.
(3)灭菌反应釜内端下侧固定连接有落料板,落料板上开凿有若干均匀分布的吹气孔,落料板上端固定连接有通气隔网,灭菌反应釜下端通过风管连接有鼓风机,可以辅助搅拌轴起到扩散水葫芦粉末的作用,同时可以利用从吹气孔中吹出的气体使得沉降下来的水葫芦粉末再次飞扬与高温蒸汽接触进行灭菌。(3) A blanking plate is fixedly connected to the lower side of the inner end of the sterilization reactor. A number of evenly distributed blowing holes are cut on the blanking plate. The upper end of the blanking plate is fixedly connected with a ventilation screen, and the lower end of the sterilization reactor passes through a wind pipe. A blower is connected to assist the stirring shaft to diffuse the water hyacinth powder, and at the same time, the air blown from the blowing hole can make the settled water hyacinth powder fly again to contact with high-temperature steam for sterilization.
(4)进料三通管通入水葫芦粉的一端内安装有精密过滤器,搅拌轴采用螺旋式结构,搅拌轴内端固定连接有电热丝,精密过滤器起到对水葫芦粉内杂质和较大粒径粉末的过滤效果,搅拌轴不仅可以起到搅拌扩散提高灭菌速率和效果,同时可以对灭菌反应釜进行预热和高温蒸汽的保温,显著提高高温蒸汽的灭菌效果。(4) A precision filter is installed in one end of the feed tee pipe that leads to the water hyacinth powder, the stirring shaft adopts a spiral structure, and the inner end of the stirring shaft is fixedly connected with an electric heating wire. The precision filter plays a role in preventing impurities in the water hyacinth powder. With the filtering effect of larger particle size powder, the stirring shaft can not only stir and diffuse to increase the sterilization rate and effect, but also can preheat the sterilization reactor and heat the high temperature steam, which significantly improves the sterilization effect of the high temperature steam.
(5)预处理中对水葫芦高温烘干至脱水率达到90%,若脱水率低于90%,继续高温烘干,提高脱水率来降低水葫芦所含水分对后续工序的影响。(5) Dry the water hyacinth at a high temperature in the pretreatment until the dehydration rate reaches 90%. If the dehydration rate is lower than 90%, continue high-temperature drying to increase the dehydration rate to reduce the influence of the water content of the water hyacinth on the subsequent processes.
(6)鞋垫成品应经过质检,质检包括马丁代尔耐磨性能、摩擦色牢度、断裂强度、断裂伸长率、定强伸长率、耐老化、破裂强度和耐皂洗色牢度,若质检合格,则鞋垫成品进入包装出厂程序,若质检不合格,则鞋垫成品作废弃回收处理,对本发明制得的鞋垫成品进行专业质检,必须满足相关标准规范后才能流向市场,严格把控鞋垫质量。(6) Finished insoles should undergo quality inspection, including Martindale wear resistance, color fastness to rubbing, breaking strength, elongation at break, elongation at fixed strength, aging resistance, breaking strength and color fastness to soaping If the quality inspection is qualified, the insole product will enter the packaging and delivery process. If the quality inspection is unqualified, the insole product will be discarded and recycled. Professional quality inspection of the insole product made by the present invention must meet the relevant standards and specifications before it can be sold to the market , Strictly control the quality of insoles.
附图说明Description of the drawings
图1为本发明的主要的工艺流程图;Figure 1 is the main process flow diagram of the present invention;
图2为本发明的灭菌装置的结构示意图;Figure 2 is a schematic diagram of the structure of the sterilization device of the present invention;
图3为本发明的鞋垫成品的结构示意图。Figure 3 is a schematic diagram of the structure of the finished insole of the present invention.
图中标号说明:Explanation of labels in the figure:
1灭菌反应釜、2真空泵、3连通管、4真空阀、5进料三通管、6精密过滤器、7出料口、8鼓风机、9驱动电机、10搅拌轴、11落料板、12吹气孔、13通气隔网。1 Sterilization reactor, 2 vacuum pump, 3 connecting pipe, 4 vacuum valve, 5 feeding three-way pipe, 6 precision filter, 7 discharge port, 8 blower, 9 drive motor, 10 stirring shaft, 11 blanking plate, 12 blowing holes, 13 ventilation screens.
具体实施方式Detailed ways
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述;显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例,基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The following will clearly and completely describe the technical solutions in the embodiments of the present invention with reference to the accompanying drawings in the embodiments of the present invention; obviously, the described embodiments are only a part of the embodiments of the present invention, not all the embodiments, based on The embodiments of the present invention, and all other embodiments obtained by those of ordinary skill in the art without creative work, fall within the protection scope of the present invention.
在本发明的描述中,需要说明的是,术语“上”、“下”、“内”、“外”、“顶/底端”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性。In the description of the present invention, it should be noted that the directions or positional relationships indicated by the terms "upper", "lower", "inner", "outer", and "top/bottom" are based on the directions shown in the drawings. Or the positional relationship is only for the convenience of describing the present invention and simplifying the description, rather than indicating or implying that the pointed device or element must have a specific orientation, be constructed and operated in a specific orientation, and therefore cannot be understood as a limitation of the present invention. In addition, the terms "first" and "second" are only used for descriptive purposes, and cannot be understood as indicating or implying relative importance.
在本发明的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”、“设置有”、“套设/接”、“连接”等,应做广义理解,例如“连接”,可以是固定连接,也可以是可拆卸连接,或一体地连接,可以是机械连接,也可以是电连接,可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通,对于本领域的普通技术人员而言,可以具体情况理解上述术语在本发明中的具体含义。In the description of the present invention, it should be noted that, unless otherwise clearly defined and defined, the terms "installed", "provided with", "set/connected", "connected", etc., should be interpreted broadly, such as " "Connected" can be a fixed connection, a detachable connection, or an integral connection, a mechanical connection, an electrical connection, a direct connection, or an indirect connection through an intermediate medium, and it can be inside two components. For those of ordinary skill in the art, the specific meaning of the above-mentioned terms in the present invention can be understood under specific circumstances.
实施例1:Example 1:
请参阅图1,一种基于水葫芦原料的环保鞋垫制备工艺,包括以下步骤:Please refer to Figure 1. An environmentally friendly insole preparation process based on water hyacinth raw materials includes the following steps:
S1、人工打捞起新鲜水葫芦,清洗多余附着物后进行自然摊铺晾晒;S1. Fresh water hyacinths are picked up manually, and the excess attachments are cleaned and then spread and dried naturally;
S2、预处理,将晒干后的水葫芦在100℃的抽真空条件下进行高温烘干灭菌;S2, pretreatment, drying and sterilizing the dried water hyacinth at a high temperature under a vacuum condition of 100°C;
预处理中对水葫芦高温烘干至脱水率达到90%,若脱水率低于90%,继续高温烘干,提高脱水率来降低水葫芦所含水分对后续工序的影响。In the pretreatment, the water hyacinth is dried at a high temperature until the dehydration rate reaches 90%. If the dehydration rate is less than 90%, continue high-temperature drying to increase the dehydration rate to reduce the influence of the water content of the water hyacinth on the subsequent processes.
S3、水葫芦制粉,通过粉碎机将烘干后的水葫芦进行均匀粉碎得到水葫芦粉末,粉碎后的水葫芦粉末粒径为40-60目;S3. Making water hyacinth powder, uniformly pulverizing the dried water hyacinth by a pulverizer to obtain water hyacinth powder, the particle size of the water hyacinth powder after crushing is 40-60 mesh;
S4、高温灭菌处理,通过灭菌装置对水葫芦粉末进行高温灭菌处理,其中高温蒸汽温度宜为120℃-180℃;所述高温灭菌处理具体包括以下步骤:S4. High temperature sterilization treatment, the water hyacinth powder is subjected to high temperature sterilization treatment through a sterilization device, wherein the high temperature steam temperature is preferably 120°C-180°C; the high temperature sterilization treatment specifically includes the following steps:
S41、先制造真空灭菌环境并进行预热;S41. Create a vacuum sterilization environment and preheat it;
S42、同时通入水葫芦粉和150℃的高温蒸汽,并进行扩散搅拌;S42. Simultaneously pass water hyacinth powder and high temperature steam at 150°C, and perform diffusion stirring;
S43、借助外力进一步反复扩散水葫芦粉来增大与高温蒸汽的接触面积和灭菌次数,进而提高全方位的灭菌效果;S43. With the help of external force, the water hyacinth powder is further diffused repeatedly to increase the contact area with high-temperature steam and the number of sterilization, thereby improving the all-round sterilization effect;
S5、鞋垫发泡,将水葫芦粉末与发泡材料进行搅拌,均匀混合后的物料倒入发泡机加磁模具内,进行模压发泡,发泡完毕,卸压跳模,取出大块板材;S5. Foaming the insole. Stir the water hyacinth powder and the foaming material. Pour the evenly mixed material into the foaming machine and the magnetic mold for compression and foaming. After the foaming is completed, the pressure is released and the mold is removed, and the large plate is taken out ;
鞋垫发泡的模压温度为160℃,模压时间为30min,压力为10Mpa。The molding temperature of the insole foam is 160°C, the molding time is 30min, and the pressure is 10Mpa.
S6、初步成型,将S5中的发泡所得板材裁剪成若干份20*18cm的矩形板材,并置入定制化模具中热压成型,得到初步成型的鞋垫;S6. Preliminary forming, cutting the foamed sheet in S5 into several 20*18cm rectangular sheets, and placing them in a customized mold for hot pressing to obtain a preliminary formed insole;
S7、裁断斩双,将初步成型的鞋垫经过裁断机进行裁断,并进行整理修边作业,得到鞋垫成品。S7. Cut and cut the pair, cut the preliminarily formed insole through a cutting machine, and perform finishing and trimming operations to obtain the finished insole.
请参阅图2,灭菌装置包括灭菌反应釜1,灭菌反应釜1通过连通管3连接有真空泵2,连通管3上安装有真空阀4,灭菌反应釜1左上端连接有进料三通管5,灭菌反应釜1上端固定连接有驱动电机9,灭菌反应釜1内侧设有搅拌轴10,驱动电机9的输出轴贯穿灭菌反应釜1上端并与搅拌轴10之间固定连接,灭菌反应釜1左下端固定连接有出料口7,方便对水葫芦粉末进行高温灭菌,效率高效果好,灭菌反应釜1内端下侧固定连接有落料板11,落料板11与灭菌反应釜1内底端之间留设有储气腔,落料板11上开凿有若干均匀分布的吹气孔12,落料板11上端固定连接有通气隔网13,通气隔网13的孔径小于水葫芦粉末的粒径,只允许气体通过,灭菌反应釜1下端通过风管连接有鼓风机8,可以辅助搅拌轴10起到扩散水葫芦粉末的作用,同时可以利用从吹气孔12中吹出的气体使得沉降下来的水葫芦粉末再次飞扬与高温蒸汽接触进行灭菌,进料三通管5通入水葫芦粉的一端内安装有精密过滤器6,搅拌轴10采用螺旋式结构,搅拌轴10内端固定连接有电热丝,精密过滤器6起到对水葫芦粉内杂质和较大粒径粉末的过滤效果,搅拌轴10不仅可以起到搅拌扩散提高灭菌速率和效果,同时可以对灭菌反应釜1进行预热和高温蒸 汽的保温,显著提高高温蒸汽的灭菌效果。Please refer to Figure 2. The sterilization device includes a sterilization reactor 1. The sterilization reactor 1 is connected with a vacuum pump 2 through a connecting pipe 3, a vacuum valve 4 is installed on the connecting pipe 3, and the upper left end of the sterilization reactor 1 is connected with a feed Tee tube 5, the upper end of the sterilization reactor 1 is fixedly connected with a drive motor 9, and the inside of the sterilization reactor 1 is provided with a stirring shaft 10, and the output shaft of the drive motor 9 penetrates the upper end of the sterilization reactor 1 and is between the stirring shaft 10 Fixed connection, the lower left end of the sterilization reactor 1 is fixedly connected with a discharge port 7, which is convenient for high-temperature sterilization of water hyacinth powder, with high efficiency and good effect. The lower side of the inner end of the sterilization reactor 1 is fixedly connected with a blanking plate 11, An air storage cavity is left between the blanking plate 11 and the inner bottom end of the sterilization reaction vessel 1, a number of evenly distributed blowing holes 12 are excavated on the blanking plate 11, and the upper end of the blanking plate 11 is fixedly connected with a ventilation screen 13, The aperture of the aeration screen 13 is smaller than the particle size of the water hyacinth powder, and only gas is allowed to pass. The lower end of the sterilization reactor 1 is connected with a blower 8 through an air pipe, which can assist the stirring shaft 10 to diffuse the water hyacinth powder and can also be used The gas blown from the blowing hole 12 causes the settled water hyacinth powder to fly again and contact with high-temperature steam for sterilization. A precision filter 6 is installed in the end of the feed tee tube 5 where the water hyacinth powder enters, and the stirring shaft 10 adopts a spiral. Type structure, the inner end of the stirring shaft 10 is fixedly connected with an electric heating wire, the precision filter 6 has a filtering effect on the impurities in the water hyacinth powder and the larger particle size powder, and the stirring shaft 10 can not only stir and diffuse, increase the sterilization rate and Effect, at the same time, the sterilization reactor 1 can be preheated and high-temperature steam insulation can be performed, which significantly improves the sterilization effect of the high-temperature steam.
鞋垫发泡的发泡材料为聚乙烯55%、滑石粉15%、交联剂2%、交联助剂1%、发泡剂5%、发泡助剂5%、润滑剂1%、石墨烯10%、二氧化硅6%,且水葫芦粉末与发泡材料的含量比为1:4,将聚乙烯、滑石粉、交联剂、交联助剂、发泡剂、发泡助剂、润滑剂、石墨烯和二氧化硅分别投入至混炼机中进行混炼处理,以获得发泡混合料,混炼处理温度为150℃,可以使得发泡材料得到充分的搅拌混合,进而保证鞋垫成型后的整体性能。The foaming material for insole foaming is polyethylene 55%, talc 15%, cross-linking agent 2%, cross-linking assistant 1%, foaming agent 5%, foaming assistant 5%, lubricant 1%, graphite Ene 10%, silicon dioxide 6%, and the content ratio of water hyacinth powder to foaming material is 1:4, polyethylene, talc, crosslinking agent, crosslinking assistant, foaming agent, foaming assistant , Lubricant, Graphene and Silica were separately put into the mixer for mixing treatment to obtain the foaming mixture. The mixing treatment temperature is 150°C, which can make the foaming material get fully stirred and mixed, and thus ensure The overall performance of the insole after molding.
鞋垫成品应经过质检,质检包括马丁代尔耐磨性能、摩擦色牢度、断裂强度、断裂伸长率、定强伸长率、耐老化、破裂强度和耐皂洗色牢度,若质检合格,则鞋垫成品进入包装出厂程序,若质检不合格,则鞋垫成品作废弃回收处理,对本发明制得的鞋垫成品进行专业质检,必须满足相关标准规范后才能流向市场,严格把控鞋垫质量。Finished insoles should undergo quality inspection, including Martindale wear resistance, color fastness to rubbing, breaking strength, elongation at break, elongation at fixed strength, aging resistance, breaking strength and color fastness to soaping. If the quality inspection is qualified, the insole product will enter the packaging and delivery process. If the quality inspection is unqualified, the insole product will be discarded and recycled. The insole product prepared by the present invention is subject to professional quality inspection. The insole product must meet relevant standards and specifications before it can be sold to the market. Control the quality of insoles.
实施例2:Example 2:
鞋垫发泡的发泡材料为聚乙烯40%、滑石粉20%、交联剂1%、交联助剂0.5%、发泡剂4%、发泡助剂4%、润滑剂1%、石墨烯5%、二氧化硅8%,且水葫芦粉末与发泡材料的含量比为1:3,其余均与实施例1一致。The foaming material for insole foaming is polyethylene 40%, talc 20%, crosslinking agent 1%, crosslinking assistant 0.5%, foaming agent 4%, foaming assistant 4%, lubricant 1%, graphite The content ratio of the water hyacinth powder to the foaming material is 1:3, and the rest are the same as in Example 1.
实施例3:Example 3:
所述鞋垫发泡的发泡材料为聚乙烯60%、滑石粉25%、交联剂2%、交联助剂1%、发泡剂10%、发泡助剂5%、润滑剂2%、石墨烯15%、二氧化硅15%,且水葫芦粉末与发泡材料的含量比为1:2,其余均与实施例1一致。The foaming material of the insole foaming is polyethylene 60%, talc powder 25%, crosslinking agent 2%, crosslinking assistant 1%, foaming agent 10%, foaming assistant 5%, lubricant 2% , Graphene 15%, silica 15%, and the content ratio of water hyacinth powder to foaming material is 1:2, and the rest are the same as in Example 1.
本发明可以实现将人工打捞上的新鲜水葫芦作为原料,依次经过清洗晾晒、高温脱水、破碎成粉和高温灭菌处理后制得水葫芦粉末,取其精华弃其糟粕,制粉过程中保留水葫芦带来的优势和作用,同时通过严格的高温灭菌处理来避免对人体的危害,并将其与发泡原材料混炼后发泡制得大块板材,充分发挥其环保无公害、除臭、吸汗、无毒、无味、减振的优点,打开鞋垫 产业发展的新缺口,同时也促进水葫芦泛滥的环境治理,进而形成水葫芦治理和鞋垫产业之间的良性循环,通过变废为宝来显著提高经济效益和社会效益。The method can realize the water hyacinth powder obtained by using the fresh water hyacinth manually salvaged as the raw material, washing and drying, high-temperature dehydration, crushing into powder, and high-temperature sterilization in order to prepare water hyacinth powder, the essence is taken and the dregs are discarded, and the water hyacinth powder is retained during the powdering process The advantages and effects of water hyacinth, while avoiding harm to the human body through strict high-temperature sterilization, and foaming it with foaming raw materials to make a large board, giving full play to its environmental protection and pollution-free, eliminating The advantages of smelly, sweat-absorbing, non-toxic, tasteless, and vibration reduction have opened new gaps in the development of the insole industry, and at the same time promoted the environmental governance of the flood of water hyacinth, thereby forming a virtuous circle between the water hyacinth governance and the insole industry. Bora significantly improves economic and social benefits.
以上所述,仅为本发明较佳的具体实施方式;但本发明的保护范围并不局限于此。任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其改进构思加以等同替换或改变,都应涵盖在本发明的保护范围内。The above are only preferred specific embodiments of the present invention; but the protection scope of the present invention is not limited thereto. Any person familiar with the technical field within the technical scope disclosed in the present invention, equivalent replacements or changes according to the technical solution and improvement concept of the present invention shall be covered by the protection scope of the present invention.

Claims (10)

  1. 一种基于水葫芦原料的环保鞋垫制备工艺,其特征在于:包括以下步骤:An environmentally friendly insole preparation process based on water hyacinth raw materials is characterized in that it comprises the following steps:
    S1、人工打捞起新鲜水葫芦,清洗多余附着物后进行自然摊铺晾晒;S1. Fresh water hyacinths are picked up manually, and the excess attachments are cleaned and then spread and dried naturally;
    S2、预处理,将晒干后的水葫芦在80-120℃的抽真空条件下进行高温烘干灭菌;S2, pretreatment, drying and sterilizing the dried water hyacinth at a high temperature under vacuum conditions of 80-120℃;
    S3、水葫芦制粉,通过粉碎机将烘干后的水葫芦进行均匀粉碎得到水葫芦粉末,粉碎后的水葫芦粉末粒径为40-60目;S3. Making water hyacinth powder, uniformly pulverizing the dried water hyacinth by a pulverizer to obtain water hyacinth powder, the particle size of the water hyacinth powder after crushing is 40-60 mesh;
    S4、高温灭菌处理,通过灭菌装置对水葫芦粉末进行高温灭菌处理,其中高温蒸汽温度宜为120℃-180℃;S4. High temperature sterilization treatment, the water hyacinth powder is subjected to high temperature sterilization treatment through a sterilization device, and the high temperature steam temperature should be 120°C-180°C;
    S5、鞋垫发泡,将水葫芦粉末与发泡材料进行搅拌,均匀混合后的物料倒入发泡机加磁模具内,进行模压发泡,发泡完毕,卸压跳模,取出大块板材;S5. Foaming the insole. Stir the water hyacinth powder and the foaming material. Pour the evenly mixed material into the foaming machine and the magnetic mold for compression and foaming. After the foaming is completed, the pressure is released and the mold is removed, and the large plate is taken out ;
    S6、初步成型,将S5中的发泡所得板材裁剪成若干份20*18cm的矩形板材,并置入定制化模具中热压成型,得到初步成型的鞋垫;S6. Preliminary forming, cutting the foamed sheet in S5 into several 20*18cm rectangular sheets, and placing them in a customized mold for hot pressing to obtain a preliminary formed insole;
    S7、裁断斩双,将初步成型的鞋垫经过裁断机进行裁断,并进行整理修边作业,得到鞋垫成品。S7. Cut and cut the pair, cut the preliminarily formed insole through a cutting machine, and perform finishing and trimming operations to obtain the finished insole.
  2. 根据权利要求1所述的一种基于水葫芦原料的环保鞋垫制备工艺,其特征在于:所述灭菌装置包括灭菌反应釜(1),所述灭菌反应釜(1)通过连通管(3)连接有真空泵(2),所述连通管(3)上安装有真空阀(4),所述灭菌反应釜(1)左上端连接有进料三通管(5),所述灭菌反应釜(1)上端固定连接有驱动电机(9),所述灭菌反应釜(1)内侧设有搅拌轴(10),所述驱动电机(9)的输出轴贯穿灭菌反应釜(1)上端并与搅拌轴(10)之间固定连接,所述灭菌反应釜(1)左下端固定连接有出料口(7)。An environmentally friendly insole preparation process based on water hyacinth raw materials according to claim 1, characterized in that: the sterilization device comprises a sterilization reaction kettle (1), and the sterilization reaction kettle (1) passes through a communicating pipe ( 3) A vacuum pump (2) is connected, a vacuum valve (4) is installed on the connecting pipe (3), and a feed three-way pipe (5) is connected to the upper left end of the sterilization reactor (1), The upper end of the bacteria reaction kettle (1) is fixedly connected with a drive motor (9), the inside of the sterilization reaction kettle (1) is provided with a stirring shaft (10), and the output shaft of the drive motor (9) penetrates the sterilization reaction kettle ( 1) The upper end is fixedly connected with the stirring shaft (10), and the lower left end of the sterilization reaction vessel (1) is fixedly connected with a discharge port (7).
  3. 根据权利要求2所述的一种基于水葫芦原料的环保鞋垫制备工艺,其特征在于:所述灭菌反应釜(1)内端下侧固定连接有落料板(11),所述落 料板(11)上开凿有若干均匀分布的吹气孔(12),所述落料板(11)上端固定连接有通气隔网(13),所述灭菌反应釜(1)下端通过风管连接有鼓风机(8)。An environmentally friendly insole preparation process based on water hyacinth raw materials according to claim 2, characterized in that: the lower side of the inner end of the sterilization reaction kettle (1) is fixedly connected with a blanking plate (11), and the blanking A number of evenly distributed blowing holes (12) are excavated on the plate (11), the upper end of the blanking plate (11) is fixedly connected with a ventilation screen (13), and the lower end of the sterilization reactor (1) is connected by a wind pipe There is a blower (8).
  4. 根据权利要求2所述的一种基于水葫芦原料的环保鞋垫制备工艺,其特征在于:所述进料三通管(5)通入水葫芦粉的一端内安装有精密过滤器(6),所述搅拌轴(10)采用螺旋式结构,所述搅拌轴(10)内端固定连接有电热丝。An environmentally friendly insole preparation process based on water hyacinth raw materials according to claim 2, characterized in that: a precision filter (6) is installed in one end of the feed three-way pipe (5) that passes into the water hyacinth powder, and The stirring shaft (10) adopts a spiral structure, and the inner end of the stirring shaft (10) is fixedly connected with an electric heating wire.
  5. 根据权利要求1所述的一种基于水葫芦原料的环保鞋垫制备工艺,其特征在于:所述高温灭菌处理具体包括以下步骤:The preparation process of environmentally friendly insoles based on water hyacinth raw materials according to claim 1, wherein the high temperature sterilization treatment specifically includes the following steps:
    S41、先制造真空灭菌环境并进行预热;S41. Create a vacuum sterilization environment and preheat it;
    S42、同时通入水葫芦粉和高温蒸汽,并进行扩散搅拌;S42. Pass water hyacinth powder and high-temperature steam at the same time, and perform diffusion stirring;
    S43、借助外力进一步反复扩散水葫芦粉来增大与高温蒸汽的接触面积和灭菌次数,进而提高全方位的灭菌效果。S43. With the help of external force, the water hyacinth powder is further diffused repeatedly to increase the contact area with high-temperature steam and the number of sterilization times, thereby improving the all-round sterilization effect.
  6. 根据权利要求1所述的一种基于水葫芦原料的环保鞋垫制备工艺,其特征在于:所述鞋垫发泡的发泡材料为聚乙烯30-60%、滑石粉10-25%、交联剂0.5-2%、交联助剂0.2-1%、发泡剂2-10%、发泡助剂3-5%、润滑剂0.1-2%、石墨烯0.1-15%、二氧化硅0.1-15%,且水葫芦粉末与发泡材料的含量比为1:2-5。The preparation process of an environmentally friendly insole based on water hyacinth raw materials according to claim 1, characterized in that the foaming material of the insole is 30-60% polyethylene, 10-25% talc, and crosslinking agent. 0.5-2%, crosslinking aid 0.2-1%, foaming agent 2-10%, foaming aid 3-5%, lubricant 0.1-2%, graphene 0.1-15%, silica 0.1- 15%, and the content ratio of water hyacinth powder to foam material is 1:2-5.
  7. 根据权利要求4所述的一种基于水葫芦原料的环保鞋垫制备工艺,其特征在于:将聚乙烯、滑石粉、交联剂、交联助剂、发泡剂、发泡助剂、润滑剂、石墨烯和二氧化硅分别投入至混炼机中进行混炼处理,以获得发泡混合料,混炼处理温度为125℃-150℃。The preparation process of an environmentally friendly insole based on water hyacinth raw materials according to claim 4, characterized in that: polyethylene, talc, crosslinking agent, crosslinking assistant, foaming agent, foaming assistant, lubricant , Graphene and silica are separately put into a mixer for mixing treatment to obtain a foamed mixture, and the mixing treatment temperature is 125°C-150°C.
  8. 根据权利要求1所述的一种基于水葫芦原料的环保鞋垫制备工艺,其特征在于:所述鞋垫发泡的模压温度为160℃,模压时间为30min-40min,压力为10-15Mpa。An environmentally friendly insole preparation process based on water hyacinth raw materials according to claim 1, characterized in that the molding temperature of the foaming of the insole is 160°C, the molding time is 30min-40min, and the pressure is 10-15Mpa.
  9. 根据权利要求1所述的一种基于水葫芦原料的环保鞋垫制备工艺,其特征在于:所述预处理中对水葫芦高温烘干至脱水率达到90%,若脱水率低于90%,继续高温烘干。The preparation process of environmentally friendly insoles based on raw materials of water hyacinth according to claim 1, characterized in that: in the pretreatment, the water hyacinth is dried at a high temperature until the dehydration rate reaches 90%, and if the dehydration rate is less than 90%, continue Dry at high temperature.
  10. 根据权利要求1所述的一种基于水葫芦原料的环保鞋垫制备工艺,其特征在于:所述鞋垫成品应经过质检,所述质检包括马丁代尔耐磨性能、摩擦色牢度、断裂强度、断裂伸长率、定强伸长率、耐老化、破裂强度和耐皂洗色牢度,若质检合格,则鞋垫成品进入包装出厂程序,若质检不合格,则鞋垫成品作废弃回收处理。The preparation process of an environmentally friendly insole based on water hyacinth raw materials according to claim 1, characterized in that: the finished insole should undergo quality inspection, and the quality inspection includes Martindale wear resistance, rubbing color fastness, and fracture Strength, elongation at break, elongation at fixed strength, aging resistance, rupture strength and color fastness to soaping. If the quality inspection is qualified, the finished insole will enter the packaging and delivery process. If the quality inspection fails, the finished insole will be discarded. Recycling.
PCT/CN2019/097461 2019-07-02 2019-07-24 Fabrication process for environmentally friendly insoles based on water hyacinth raw materials WO2021000363A1 (en)

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CN111543733A (en) * 2020-05-19 2020-08-18 时红光 Insole and insole containing Carex meyeriana powder and manufacturing process thereof
CN111642862A (en) * 2020-06-17 2020-09-11 深圳市迪思美科技有限公司 Production process of environment-friendly insole
CN114274631B (en) * 2021-12-20 2024-05-03 福建省华志新材料科技有限公司 Preparation process of modified insole

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