WO2020258418A1 - Organic light emitting display apparatus - Google Patents

Organic light emitting display apparatus Download PDF

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Publication number
WO2020258418A1
WO2020258418A1 PCT/CN2019/096790 CN2019096790W WO2020258418A1 WO 2020258418 A1 WO2020258418 A1 WO 2020258418A1 CN 2019096790 W CN2019096790 W CN 2019096790W WO 2020258418 A1 WO2020258418 A1 WO 2020258418A1
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Prior art keywords
layer
organic light
lower electrode
light emitting
display device
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PCT/CN2019/096790
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French (fr)
Chinese (zh)
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曾章和
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上海视涯信息科技有限公司
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Publication of WO2020258418A1 publication Critical patent/WO2020258418A1/en

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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/10OLED displays
    • H10K59/12Active-matrix OLED [AMOLED] displays
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/10OLED displays
    • H10K59/12Active-matrix OLED [AMOLED] displays
    • H10K59/122Pixel-defining structures or layers, e.g. banks

Definitions

  • the embodiment of the present invention relates to the field of display technology, and in particular to an organic light emitting display device.
  • FIG. 1 it is a schematic diagram of an organic light emitting display device in the prior art, which includes a substrate 10 on which a plurality of pixel units are arranged. The figure shows two pixel units U1 and U2. Each pixel unit includes an anode 11 arranged on the substrate 10, and a pixel defining layer 12 arranged on the upper layer of the anode 11 and located between the pixel units U1 and U2. The pixel defining layer 12 has a gentle slope shape due to the etching process .
  • the hole injection layer 13, the hole transport layer 14, and the electron blocking layer 15 formed on the pixel definition layer 12.
  • the hole injection layer 13, the hole transport layer 14, and the electron blocking layer 15 are all located between the pixel unit regions It is a connected connection structure.
  • the cathode 18 is a connected connection structure between the pixel unit regions. Under the structure of the organic light emitting display device described in FIG. 1, display crosstalk between the pixel units U1 and U2 will occur, that is, when the pixel unit U1 has a display signal, the carrier mobility is high due to the continuous structure of the film layer. Part of the display current is transferred to the pixel unit U2, so that the pixel unit U2 cannot display the predetermined pixel gray scale, which greatly affects the display effect of the organic light emitting display device.
  • the pixel definition layer is designed to have a multilayer structure or the anode is set to have a chamfered structure, and the film layer with high carrier mobility is disconnected to suppress the above-mentioned crosstalk failure.
  • FIG. 2 is a schematic diagram of an organic light emitting display device provided by the publication number CN103781215.
  • the pixel definition layer includes a first portion 150 and a second portion 155 disposed on the first portion 150, and a gap 156 is disposed between the first portion 150 and the second portion 155.
  • the organic light emitting layer 120 is arranged to be disconnected at the gap 156 to block crosstalk between pixel units.
  • FIG. 3 is a schematic diagram of an organic light-emitting display device provided by the publication number CN103891408. As shown in the figure, the anode 31 has a chamfer 31A, and the organic light-emitting layer 32A can be disconnected at the anode chamfer 31A to block crosstalk between pixel units.
  • the function of the pixel definition layer is to separate the pixel units, which are generally formed with a single-layer structure.
  • the pixel definition layer in the structure shown in Figure 2 requires two or more layers. Each layer structure needs to be formed separately, which increases the process steps. .
  • the second is that light leakage may occur.
  • the organic light-emitting layer 32A may not always be disconnected at the anode chamfer 31A, and it is very likely that a very thin continuous film layer is formed. Because the sheet resistance of the organic film layer 32A at the chamfer 31A will be small, a small resistance current path will be formed between the anode 31 and the cathode 33 in the area A in FIG. 3, so that the current is no longer lateral.
  • the transmission is in the area A, from the anode 31 and the organic light-emitting layer 32A to the cathode 122, and light leakage occurs in the area shown in A in the figure.
  • the present invention provides an organic light emitting display device, the organic light emitting display device includes a plurality of organic light emitting units; each of the organic light emitting units includes a lower electrode arranged on a substrate, and is arranged on the lower electrode The organic light-emitting layer, the upper electrode provided on the organic light-emitting layer;
  • the lower electrode includes a first portion of a lower electrode and a second portion of the lower electrode that are stacked; the first portion of the lower electrode is disposed on the substrate, and the side of the first portion of the lower electrode is The included angle is greater than or equal to 90 degrees; the second part of the bottom electrode is disposed on the first part of the bottom electrode, and the included angle between the side of the second part of the bottom electrode and the top surface of the first part of the bottom electrode Less than 90 degrees;
  • It also includes a pixel definition layer disposed between the plurality of organic light emitting units and covering the side of the lower electrode, and the pixel definition layer includes a first part of the pixel definition layer covering the side of the first part of the lower electrode The second part of the pixel definition layer covering the side of the second part of the lower electrode; the angle between the first part of the pixel definition layer and the substrate is greater than or equal to 90 degrees; the second part of the pixel definition layer and the The included angle of the top surface of the first part of the lower electrode is less than 90 degrees;
  • the organic light-emitting layer of the plurality of organic light-emitting units includes multiple organic film layers, and at least part of the organic film layers are disconnected at the pixel defining layer.
  • the included angle between the side edge of the first part of the bottom electrode and the substrate is greater than 135 degrees and less than or equal to 150 degrees.
  • the included angle between the side of the second portion of the lower electrode and the top surface of the first portion of the lower electrode is greater than or equal to 30 degrees and less than or equal to 60 degrees.
  • the lower electrode further includes a third portion of the lower electrode disposed under the first portion of the lower electrode.
  • the lower electrode further includes a third portion of the lower electrode disposed above the second portion of the lower electrode.
  • the organic light-emitting layer includes a stacked first organic film layer, and a stacked second organic film layer disposed on the first organic film layer; the first organic film layer is on the pixel defining layer ⁇ disconnect.
  • the thickness of the first organic film layer is less than or equal to the thickness of the first portion of the bottom electrode; the sum of the thicknesses of the first organic film layer and the second organic film layer is greater than the first portion of the bottom electrode.
  • the thickness of the section is less than or equal to the thickness of the first portion of the bottom electrode; the sum of the thicknesses of the first organic film layer and the second organic film layer is greater than the first portion of the bottom electrode.
  • the upper electrodes of the plurality of organic light emitting units are connected to each other.
  • the first organic film layer includes a hole injection layer and a hole transport layer that are sequentially stacked;
  • the second organic film layer includes an electron blocking layer, an organic light-emitting material layer, and a hole that are stacked sequentially. Barrier layer, electron transport layer.
  • the first organic film layer includes a first hole injection layer, a first hole transport layer, a first electron blocking layer, a first organic light-emitting material layer, a first hole blocking layer, A charge generation layer, a second hole injection layer, a second hole transport layer; the second organic film layer includes a second electron blocking layer, a second organic light-emitting material layer, and a second hole blocking layer that are sequentially stacked , Electron transport layer.
  • the organic light emitting display device is a silicon-based micro organic light emitting display device.
  • the organic light-emitting display device utilizes a two-layer structure or a multi-layer structure of the lower electrode, which is a common structure in organic light-emitting display devices, and does not need to increase the number of lower electrode film layers and corresponding components on the basis of the prior art.
  • Film process, and the use of a two-layer or multi-layer structure of the bottom electrode only needs to form a pixel definition layer according to the shape of the bottom electrode, which can cut off some organic film layers and prevent crosstalk between pixel units.
  • the process is simplified.
  • the pixel definition layer if part of the organic film layer is not completely disconnected, a very thin continuous film layer is formed.
  • the pixel definition layer separates the organic film layer from the lower electrode, A current path with low resistance will not be formed between the upper electrode, so that light leakage will not occur, and the display effect of the organic light emitting display device is improved.
  • FIG. 1 is a schematic diagram of an organic light emitting display device in the prior art
  • FIG. 2 is a schematic diagram of another organic light emitting display device in the prior art
  • FIG. 3 is a schematic diagram of another organic light emitting display device in the prior art
  • FIG. 4 is a schematic diagram of an organic light emitting display device provided by an embodiment of the present invention.
  • 5 and 6 are schematic diagrams of a method for forming a pixel definition layer
  • FIG. 7 to 10 are schematic diagrams of the structure of the lower electrode in several embodiments.
  • FIG. 4 is a schematic diagram of an organic light-emitting display device provided by an implementation of the present invention.
  • the organic light-emitting display device 20 includes a plurality of organic light-emitting units 21; each organic light-emitting unit 21 includes a substrate 22
  • the lower electrode 23 is an anode
  • the upper electrode 25 is a cathode.
  • the lower electrode 23 includes a lower electrode first part 231 and a lower electrode second part 232 that are stacked.
  • the bottom electrode first portion 231 is disposed on the substrate 22, and the angle ⁇ 1 between the side of the bottom electrode first portion 231 and the substrate 22 is greater than or equal to 90 degrees.
  • the second portion 232 of the lower electrode is disposed on the first portion 231 of the lower electrode, and the angle ⁇ 2 between the side of the second portion 232 of the lower electrode and the top surface of the first portion 231 of the lower electrode is less than 90 degrees.
  • the organic light emitting display device 20 further includes a pixel defining layer 26 arranged between the plurality of organic light emitting units 21, and the pixel defining layer 26 is formed into a film according to the shape of the side of the lower electrode 23 and covers the side of the lower electrode 23.
  • the pixel definition layer includes a pixel definition layer first part 261 covering the side of the lower electrode first part 231 and a pixel definition layer second part 262 covering the side of the lower electrode second part 232.
  • the angle ⁇ 1 between the first part 261 of the pixel definition layer and the substrate 22 is greater than or equal to 90 degrees, and the angle ⁇ 2 between the second part 262 of the pixel definition layer and the top surface of the first part 231 of the bottom electrode is less than 90 degrees.
  • FIG. 5 and FIG. 6 a schematic diagram of a method for forming a pixel definition layer.
  • the pixel defining layer is formed after the bottom electrode 23 is formed.
  • the pixel definition layer is deposited and formed on the upper layer of the lower electrode 23.
  • the pixel definition layer is generally formed by a chemical vapor deposition process.
  • the film forming material is introduced into the reaction chamber in a gaseous state, and then a chemical reaction occurs between the materials to deposit
  • the upper layer of the lower electrode 23 can therefore form a pixel definition layer 260 covering the side of the lower electrode 23 and having the same shape as the side of the lower electrode 23.
  • the pixel definition layer 260 is a whole layer structure.
  • the pixel definition layer 260 includes a pixel definition layer first part 261 covering the side of the lower electrode first part 231, and a pixel definition layer first part 262 covering the side of the lower electrode second part 232.
  • the pixel definition layer 260 also includes a portion covering the top surface of the lower electrode 23 and a portion of the substrate 22 covering the space between two adjacent lower electrodes 23.
  • a photoresist layer is formed on the entire pixel defining layer 260, and the photoresist layer is exposed and developed to form a patterned photoresist layer 27.
  • the patterned photoresist layer 27 exposes the top surface of the lower electrode 23. And cover other positions.
  • the pixel defining layer 260 is etched using the patterned photoresist layer 27 as a mask, the pixel defining layer 260 on the top surface of the lower electrode 23 is removed, and then the patterned photoresist layer 27 is removed.
  • the etched pixel definition layer 260 includes a first part 261 of a pixel definition layer covering the side of the first part 231 of the lower electrode, a second part 262 of a pixel definition layer covering the side of the second part 232 of the lower electrode, and covering two adjacent ones.
  • the third portion 263 of the pixel definition layer in the space between the lower electrodes 23.
  • an organic light emitting layer 24 is formed on the pixel definition layer after the etching is completed.
  • the organic light emitting layer 24 includes multiple organic film layers, wherein at least part of the organic film layers are disconnected at the pixel definition layer.
  • the same organic film layer of the plurality of organic light-emitting units 21 of the organic light-emitting display device 20 is formed in the same evaporation process using an open mask.
  • the open mask only shields the peripheral area of the display device, which reduces the display area. Both the organic light emitting unit area and the spacer area are exposed.
  • the organic film layer material is first heated and vaporized, and the vaporized organic film layer material diffuses on the substrate 22 and adheres. Because the vaporized organic film material has low energy and poor film coverage, when it diffuses to the first part 261 of the pixel definition layer and the second part 262 of the pixel definition layer, the second part 262 of the pixel definition layer blocks the pixel definition layer. In the first part 261, the organic film layer material cannot be continuously attached to the first part 261 of the pixel definition layer and the second part 262 of the pixel definition layer, thereby forming a disconnected structure.
  • the lower electrode 23 is arranged in the shape described above, so that the pixel defining layer 26 is also formed into a film according to the shape of the side surface of the lower electrode 23, and the organic film layer formed on the pixel defining layer 26 will be on the pixel defining layer. , So as to eliminate crosstalk between adjacent organic light emitting units 21.
  • the included angle ⁇ 1 between the side of the first part 231 of the bottom electrode and the substrate 22 is greater than 135 degrees and less than or equal to 150 degrees.
  • the angle ⁇ 2 between the side of the second portion 232 of the lower electrode and the top surface of the first portion 231 of the lower electrode is greater than or equal to 30 degrees and less than or equal to 60 degrees.
  • the pixel definition layer is formed into a film according to the shape of the bottom electrode, and the angle ⁇ 1 between the first portion 261 of the pixel definition layer and the substrate 22 is also greater than 135 degrees and less than or equal to 150 degrees.
  • the angle ⁇ 2 between the second portion 262 of the pixel definition layer and the top surface of the first portion 231 of the bottom electrode is also greater than or equal to 30 degrees and less than or equal to 60 degrees.
  • the above-mentioned angle range process is easier to control and has good process stability.
  • the lower electrode has a two-layer structure, and the two-layer structure or the multi-layer structure of the lower electrode is a common structure in organic light emitting display devices.
  • the bottom electrode first portion 231 is a contact electrode layer that enhances the contact strength between the electrode and the substrate 22.
  • the substrate 22 also includes a substrate on which other film layers have been deposited.
  • the bottom electrode first portion 231 can enhance and The other material layers on the substrate 22 are in contact with strong materials.
  • the material of the first part 231 of the lower electrode is at least one metal selected from the group consisting of silver, neodymium, chromium, indium, tin, zinc, cadmium, titanium, aluminum, magnesium, and molybdenum.
  • the second portion 232 of the lower electrode is a conductive metal layer with strong conductivity.
  • the organic light emitting unit 21 is an organic light emitting unit with a microcavity structure
  • the lower electrode 23 includes a reflective material
  • the upper electrode 25 includes a transflective material
  • a resonant cavity is formed between the lower electrode 23 and the upper electrode 25.
  • the first part 231 of the bottom electrode is a reflective metal layer, such as silver or an alloy containing silver.
  • the second part 232 of the lower electrode is an optical adjustment layer formed of a transparent conductive metal.
  • the material of the second part 232 of the lower electrode may be indium tin oxide or indium zinc oxide.
  • the two-layer structure or multi-layer structure of the bottom electrode is a common structure in organic light-emitting display devices, there is no need to increase the number of bottom electrode film layers and the corresponding film forming process on the basis of the prior art, and use two or more layers.
  • the bottom electrode of the layer structure only needs to form a pixel definition layer according to the shape of the bottom electrode, which can cut off part of the organic film layer and prevent crosstalk between pixel units. Compared with the pixels formed by multiple film formation and etching For the definition layer, the process is simplified.
  • at the pixel definition layer if part of the organic film layer 24 is not completely broken, a very thin continuous film layer is formed.
  • the organic film layer 24 and the lower The electrodes 23 are separated, and a current path with low resistance is not formed between the lower electrode and the upper electrode, so that light leakage does not occur in the area A, and the display effect of the organic light emitting display device is improved.
  • the lower electrode may also have a structure other than that shown in FIG. 4. Please refer to FIGS. 7 to 10, which are schematic diagrams of the structure of the lower electrode in several embodiments.
  • the width of the top surface of the first portion 231 of the bottom electrode is smaller than the width of the bottom surface of the second portion 232 of the bottom electrode.
  • the angle of the second electrode part 232 meets the requirements, and the width relationship between the first part 231 of the bottom electrode and the second part 232 of the bottom electrode is not limited.
  • FIG. 8 is a schematic diagram of the structure of the lower electrode in another embodiment
  • FIG. 9 is a schematic diagram of the structure of the lower electrode in the third embodiment.
  • the lower electrode further includes a third portion 233 of the lower electrode under the first portion 231 of the lower electrode.
  • the third portion 233 of the lower electrode is formed of a third conductive film layer different from the first portion 231 of the lower electrode and the second portion 232 of the lower electrode.
  • the angle between the side and the bottom surface of the third portion 233 of the lower electrode is less than 90 degrees.
  • the angle between the side edge and the bottom surface of the third portion 233 of the lower electrode is greater than 90 degrees.
  • the structure of the third part 233 of the lower electrode can be in various forms, for example, it can also be arranged such that the side edge is perpendicular to the bottom surface.
  • Figures 8 and 9 only schematically list two structures, but the present invention is not limited to these two structures.
  • the third bottom electrode 233 does not affect the structure of the bottom electrode first part 231 and the bottom electrode second part 232. , It can be any structure.
  • FIG. 10 is a schematic diagram of the structure of the lower electrode in the fourth embodiment.
  • the lower electrode further includes a third portion 233 of the lower electrode located above the second portion 232 of the lower electrode.
  • the third portion 233 of the lower electrode is formed of a third conductive film layer different from the first portion 231 of the lower electrode and the second portion 232 of the lower electrode.
  • the bottom surface width of the lower electrode third portion 233 is less than or equal to the top surface width of the lower electrode second portion 232, and the side surface of the lower electrode third portion 233
  • the angle with the bottom surface is less than 90 degrees, and the side surface of the third part 233 of the lower electrode is a gentle slope structure, which is beneficial to the formation of a continuous film layer when the upper electrode located on it forms a film.
  • the organic light-emitting layer 24 is a structure in which a multilayer film layer is laminated, and it is only necessary to disconnect the film layer with high carrier mobility that is prone to lateral leakage in the multilayer film layer between the pixel units.
  • the organic light-emitting layer 24 may include a first organic film layer 241 and a second organic film layer 242 disposed on the first organic film layer 241.
  • the first organic film layer 241 includes an organic film layer with high carrier mobility and easy lateral conduction.
  • the organic film layer in the second organic film layer 242 has a low carrier mobility and is not prone to lateral conduction.
  • the thickness of the first organic film layer 241 is set to be less than or equal to the thickness of the first portion 231 of the lower electrode, and the first organic film layer 241 is disconnected at the pixel defining layer 26.
  • the sum of the thicknesses of the first organic film layer 241 and the second organic film layer 242 is set to be greater than the thickness of the first portion 231 of the lower electrode, and at the same time, because the sides of the second portion 232 of the lower electrode and the top surface of the first portion 231 of the lower electrode are sandwiched
  • the angle ⁇ 2 is less than 90 degrees.
  • the second portion 262 of the pixel definition layer also forms a structure in which the angle ⁇ 2 with the top surface of the first portion 231 of the lower electrode is less than 90 degrees in accordance with the shape of the side of the second portion 232 of the lower electrode, that is, the pixel
  • the second portion 262 of the definition layer forms a gentle slope, and when each layer of the second organic film layer 242 is formed on the gentle slope, a continuous layer structure is formed.
  • the first organic film layer 241 may include a hole injection layer and a hole transport layer that are sequentially stacked.
  • the hole injection layer and the hole transport layer have high carrier mobility and are prone to lateral leakage between pixel units. Therefore, the hole injection layer and the hole transport layer are set in a disconnected structure.
  • the second organic film layer 242 on the hole injection layer and the hole transport layer includes other film layers, which have low carrier mobility and do not need to be disconnected between pixel units.
  • the second organic film layer 242 includes an electron blocking layer, an organic light-emitting material layer, a hole blocking layer, an electron transport layer, etc., which are sequentially stacked.
  • the organic light-emitting display unit includes two superimposed organic light-emitting units, and each organic light-emitting unit includes a film layer with a larger carrier mobility, and these film layers need to be disconnected between the pixel units.
  • the first organic film layer includes a first hole injection layer, a first hole transport layer, a first electron blocking layer, a first organic light-emitting material layer, a first hole blocking layer, a charge generation layer, and a Two hole injection layer, second hole transport layer.
  • the second organic film layer includes a second electron blocking layer, a second organic light-emitting material layer, a second hole blocking layer, and an electron transport layer that are sequentially stacked.
  • the organic light emitting display device provided by the embodiment of the present invention is a silicon-based micro organic light emitting display device.
  • the silicon-based miniature organic light-emitting display device is based on a single crystal silicon chip, and the pixel size is 1/10 of that of the traditional display device, and the fineness is much higher than that of the traditional device, and can be used to form a micro display.
  • Silicon-based micro organic light-emitting display devices have a broad market application space, and are particularly suitable for use in helmet-mounted displays, stereoscopic display mirrors, and glasses-type displays. Because of the small pixel size of the silicon-based micro organic light-emitting display device, each film layer of the organic light-emitting layer is easier to display crosstalk. Therefore, the structure provided by the embodiment of the present invention is more suitable for silicon-based micro organic light-emitting display devices, and can improve the silicon-based micro organic light-emitting display. The display effect of the device.
  • the organic light-emitting display device utilizes a two-layer structure or a multi-layer structure of the lower electrode, which is a common structure in organic light-emitting display devices, and does not need to increase the number of lower electrode film layers and corresponding components on the basis of the prior art.
  • Film process, and the use of a two-layer or multi-layer structure of the bottom electrode only needs to form a pixel definition layer according to the shape of the bottom electrode, which can cut off some organic film layers and prevent crosstalk between pixel units.
  • the process is simplified.
  • the pixel definition layer if part of the organic film layer is not completely disconnected, a very thin continuous film layer is formed.
  • the pixel definition layer separates the organic film layer from the lower electrode, A current path with low resistance will not be formed between the upper electrode, so that light leakage will not occur, and the display effect of the organic light emitting display device is improved.

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Abstract

The present invention provides an organic light emitting display apparatus, comprising multiple organic light emitting units. Each organic light emitting unit comprises a lower electrode provided on a substrate, an organic light emitting layer provided on the lower electrode, and an upper electrode provided on the organic light emitting layer. The lower electrode comprises a lower electrode first portion and a lower electrode second portion arranged in a stacked manner. The lower electrode first portion is provided on the substrate. An included angle between a side edge of the lower electrode first portion and the substrate is greater than or equal to 90 degrees. The lower electrode second portion is provided on the lower electrode first portion. An included angle between a side edge of the lower electrode second portion and a top surface of the lower electrode first portion is less than 90 degrees. The apparatus further comprises a pixel definition layer provided between the multiple organic light emitting units and covering a side edge of the lower electrode. The pixel definition layer is formed into a film according to the shape of the side edge of the lower electrode. The organic light emitting layers of the multiple organic light emitting units comprise multiple organic film layers. At least part of the organic film layers are disconnected at the pixel definition layer.

Description

一种有机发光显示装置Organic light emitting display device 技术领域Technical field
本发明实施例涉及显示技术领域,尤其涉及一种有机发光显示装置。The embodiment of the present invention relates to the field of display technology, and in particular to an organic light emitting display device.
背景技术Background technique
有机发光显示装置,有相邻像素单元串扰的问题。如图1所示,为现有技术中一种有机发光显示装置的示意图,包括基板10,该基板10上设置有多个像素单元,图中示出了两个像素单元U1和U2。每个像素单元包括设置于基板10上的阳极11,设置于阳极11上层并位于各像素单元U1、U2之间的像素定义层12,该像素定义层12由于刻蚀工艺而形成缓坡状的形态。形成在像素定义层12上的空穴注入层13、空穴传输层14、电子阻挡层15,该空穴注入层13、空穴传输层14、电子阻挡层15都是在各像素单元区域间为相连的连接结构。设置在各像素单元区域内的有机发光层19,设置在有机发光层19上的空穴阻挡层16,设置在空穴阻挡层16上的电子传输层17,设置在电子传输层17上的阴极18,阴极18在各像素单元区域间为相连的连接结构。在图1所述的有机发光显示装置结构下,会发生像素单元U1和U2之间的显示串扰,即当像素单元U1有显示信号时,因连续结构的膜层中有载流子迁移率高的膜层,部分显示电流被传输到了像素单元U2处,使得像素单元U2不能显示预定的像素灰阶,这使得有机发光显示装置的显示效果大受影响。Organic light-emitting display devices have the problem of crosstalk between adjacent pixel units. As shown in FIG. 1, it is a schematic diagram of an organic light emitting display device in the prior art, which includes a substrate 10 on which a plurality of pixel units are arranged. The figure shows two pixel units U1 and U2. Each pixel unit includes an anode 11 arranged on the substrate 10, and a pixel defining layer 12 arranged on the upper layer of the anode 11 and located between the pixel units U1 and U2. The pixel defining layer 12 has a gentle slope shape due to the etching process . The hole injection layer 13, the hole transport layer 14, and the electron blocking layer 15 formed on the pixel definition layer 12. The hole injection layer 13, the hole transport layer 14, and the electron blocking layer 15 are all located between the pixel unit regions It is a connected connection structure. The organic light-emitting layer 19 disposed in the area of each pixel unit, the hole blocking layer 16 disposed on the organic light-emitting layer 19, the electron transport layer 17 disposed on the hole blocking layer 16, the cathode disposed on the electron transport layer 17 18. The cathode 18 is a connected connection structure between the pixel unit regions. Under the structure of the organic light emitting display device described in FIG. 1, display crosstalk between the pixel units U1 and U2 will occur, that is, when the pixel unit U1 has a display signal, the carrier mobility is high due to the continuous structure of the film layer. Part of the display current is transferred to the pixel unit U2, so that the pixel unit U2 cannot display the predetermined pixel gray scale, which greatly affects the display effect of the organic light emitting display device.
现有技术中,有将像素定义层设计为具有多层的结构或者将阳极设置为具有倒角的结构,将载流子迁移率高的膜层断开,来抑制上述串扰不良,如公开号为CN103781215的专利,请参考图2,图2为公开号为CN103781215提供的有机发光显示装置的示意图。如图所示,像素定义层包括第一部分150 和设置于第一部分150上的第二部分155,第一部分150和第二部分155之间设置有一个空隙156。设置有机发光层120在空隙156处断开,以阻断像素单元之间的串扰。图3为公开号为CN103891408提供的有机发光显示装置的示意图。如图所示,阳极31具有倒角31A,有机发光层32A可以在阳极倒角31A处断开,以阻断像素单元之间的串扰。In the prior art, the pixel definition layer is designed to have a multilayer structure or the anode is set to have a chamfered structure, and the film layer with high carrier mobility is disconnected to suppress the above-mentioned crosstalk failure. It is a patent of CN103781215, please refer to FIG. 2, which is a schematic diagram of an organic light emitting display device provided by the publication number CN103781215. As shown in the figure, the pixel definition layer includes a first portion 150 and a second portion 155 disposed on the first portion 150, and a gap 156 is disposed between the first portion 150 and the second portion 155. The organic light emitting layer 120 is arranged to be disconnected at the gap 156 to block crosstalk between pixel units. FIG. 3 is a schematic diagram of an organic light-emitting display device provided by the publication number CN103891408. As shown in the figure, the anode 31 has a chamfer 31A, and the organic light-emitting layer 32A can be disconnected at the anode chamfer 31A to block crosstalk between pixel units.
但是上述结构都存在明显的缺点。第一是使得制程复杂化。像素定义层的作用是分离像素单元,一般都是用单层结构形成,图2所示结构中像素定义层需要两层或者多层结构,每层结构都需要单独成膜形成,增加了工艺步骤。第二是可能出现漏光。如图3所示,有机发光层32A在阳极倒角31A处未必都能断开,极有可能是形成了极薄的连续膜层。因为有机膜层32A在倒角31A处的膜层薄电阻就会小,在图3中的区域A处,在阳极31到阴极33之间会形成一个电阻小的电流路径,从而电流不再横向传递而是在区域A处,从阳极31、有机发光层32A向阴极122传递,图中A所示区域会发生漏光。However, the above structures have obvious disadvantages. The first is to complicate the manufacturing process. The function of the pixel definition layer is to separate the pixel units, which are generally formed with a single-layer structure. The pixel definition layer in the structure shown in Figure 2 requires two or more layers. Each layer structure needs to be formed separately, which increases the process steps. . The second is that light leakage may occur. As shown in FIG. 3, the organic light-emitting layer 32A may not always be disconnected at the anode chamfer 31A, and it is very likely that a very thin continuous film layer is formed. Because the sheet resistance of the organic film layer 32A at the chamfer 31A will be small, a small resistance current path will be formed between the anode 31 and the cathode 33 in the area A in FIG. 3, so that the current is no longer lateral. The transmission is in the area A, from the anode 31 and the organic light-emitting layer 32A to the cathode 122, and light leakage occurs in the area shown in A in the figure.
发明内容Summary of the invention
有鉴于此,本发明提供一种有机发光显示装置,所述有机发光显示装置包括多个有机发光单元;每个所述有机发光单元包括设置于基板上的下电极、设置于所述下电极上的有机发光层、设置于所述有机发光层上的上电极;In view of this, the present invention provides an organic light emitting display device, the organic light emitting display device includes a plurality of organic light emitting units; each of the organic light emitting units includes a lower electrode arranged on a substrate, and is arranged on the lower electrode The organic light-emitting layer, the upper electrode provided on the organic light-emitting layer;
所述下电极包括层叠设置的下电极第一部、下电极第二部;所述下电极第一部设置于所述基板上,并且所述下电极第一部的侧边和所述基板的夹角大于等于90度;所述下电极第二部设置于所述下电极第一部上,并且所述下电极第二部的侧边和所述下电极第一部的顶面的夹角小于90度;The lower electrode includes a first portion of a lower electrode and a second portion of the lower electrode that are stacked; the first portion of the lower electrode is disposed on the substrate, and the side of the first portion of the lower electrode is The included angle is greater than or equal to 90 degrees; the second part of the bottom electrode is disposed on the first part of the bottom electrode, and the included angle between the side of the second part of the bottom electrode and the top surface of the first part of the bottom electrode Less than 90 degrees;
还包括设置于所述多个有机发光单元之间并覆盖所述下电极侧边的像素定义层,所述像素定义层包括覆盖所述下电极第一部的侧边的像素定义层第一部、覆盖所述下电极第二部的侧边的像素定义层第二部;所述像素定义层第一部和所述基板的夹角大于等于90度;所述像素定义层第二部和所述下 电极第一部的顶面的夹角小于90度;It also includes a pixel definition layer disposed between the plurality of organic light emitting units and covering the side of the lower electrode, and the pixel definition layer includes a first part of the pixel definition layer covering the side of the first part of the lower electrode The second part of the pixel definition layer covering the side of the second part of the lower electrode; the angle between the first part of the pixel definition layer and the substrate is greater than or equal to 90 degrees; the second part of the pixel definition layer and the The included angle of the top surface of the first part of the lower electrode is less than 90 degrees;
所述多个有机发光单元的有机发光层包括多层有机膜层,至少部分所述有机膜层在所述像素定义层处断开。The organic light-emitting layer of the plurality of organic light-emitting units includes multiple organic film layers, and at least part of the organic film layers are disconnected at the pixel defining layer.
可选地,所述下电极第一部的侧边和所述基板的夹角大于135度、小于等于150度。Optionally, the included angle between the side edge of the first part of the bottom electrode and the substrate is greater than 135 degrees and less than or equal to 150 degrees.
可选地,所述下电极第二部的侧边和所述下电极第一部的顶面的夹角大于等于30度、小于等于60度。Optionally, the included angle between the side of the second portion of the lower electrode and the top surface of the first portion of the lower electrode is greater than or equal to 30 degrees and less than or equal to 60 degrees.
可选地,所述下电极还包括设置于所述下电极第一部下方的下电极第三部。Optionally, the lower electrode further includes a third portion of the lower electrode disposed under the first portion of the lower electrode.
可选地,所述下电极还包括设置于所述下电极第二部上方的下电极第三部。Optionally, the lower electrode further includes a third portion of the lower electrode disposed above the second portion of the lower electrode.
可选地,所述有机发光层包括层叠的第一有机膜层、设置于所述第一有机膜层上的层叠的第二有机膜层;所述第一有机膜层在所述像素定义层处断开。Optionally, the organic light-emitting layer includes a stacked first organic film layer, and a stacked second organic film layer disposed on the first organic film layer; the first organic film layer is on the pixel defining layer处 disconnect.
可选地,所述第一有机膜层的厚度小于等于所述下电极第一部的厚度;所述第一有机膜层和所述第二有机膜层的厚度和大于所述下电极第一部的厚度。Optionally, the thickness of the first organic film layer is less than or equal to the thickness of the first portion of the bottom electrode; the sum of the thicknesses of the first organic film layer and the second organic film layer is greater than the first portion of the bottom electrode. The thickness of the section.
可选地,所述多个有机发光单元的上电极相互连接。Optionally, the upper electrodes of the plurality of organic light emitting units are connected to each other.
可选地,所述第一有机膜层包括依次层叠设置的空穴注入层、空穴传输层;所述第二有机膜层包括依次叠层设置的电子阻挡层、有机发光材料层、空穴阻挡层、电子传输层。Optionally, the first organic film layer includes a hole injection layer and a hole transport layer that are sequentially stacked; the second organic film layer includes an electron blocking layer, an organic light-emitting material layer, and a hole that are stacked sequentially. Barrier layer, electron transport layer.
可选地,所述第一有机膜层包括依次层叠设置的第一空穴注入层、第一空穴传输层、第一电子阻挡层、第一有机发光材料层、第一空穴阻挡层、电荷生成层、第二空穴注入层、第二空穴传输层;所述第二有机膜层包括依次叠层设置的第二电子阻挡层、第二有机发光材料层、第二空穴阻挡层、电子传输层。Optionally, the first organic film layer includes a first hole injection layer, a first hole transport layer, a first electron blocking layer, a first organic light-emitting material layer, a first hole blocking layer, A charge generation layer, a second hole injection layer, a second hole transport layer; the second organic film layer includes a second electron blocking layer, a second organic light-emitting material layer, and a second hole blocking layer that are sequentially stacked , Electron transport layer.
可选地,所述有机发光显示装置为硅基微型有机发光显示装置。Optionally, the organic light emitting display device is a silicon-based micro organic light emitting display device.
本发明提供的有机发光显示装置,利用下电极两层结构或者多层结构在有机发光显示装置中为常见结构,不需要在现有技术的基础上再增加下电极膜层的数量及对应的成膜工艺,而利用两层或多层结构的下电极,只需要按照下电极的形状形成像素定义层,就可以起到断开部分有机膜层、阻止像素单元之间串扰的作用,相比于多次成膜刻蚀成型的像素定义层来说,简化了工艺。另外,在像素定义层处,有机膜层中如果有部分膜层没有彻底断开,形成了极薄的连续膜层,但因为有像素定义层将有机膜层和下电极隔开,从下电极到上电极之间不会形成电阻小的电流路径,从而不会发生漏光的情况,提高了有机发光显示装置的显示效果。The organic light-emitting display device provided by the present invention utilizes a two-layer structure or a multi-layer structure of the lower electrode, which is a common structure in organic light-emitting display devices, and does not need to increase the number of lower electrode film layers and corresponding components on the basis of the prior art. Film process, and the use of a two-layer or multi-layer structure of the bottom electrode, only needs to form a pixel definition layer according to the shape of the bottom electrode, which can cut off some organic film layers and prevent crosstalk between pixel units. For the pixel definition layer formed by multiple film formation and etching, the process is simplified. In addition, at the pixel definition layer, if part of the organic film layer is not completely disconnected, a very thin continuous film layer is formed. However, because the pixel definition layer separates the organic film layer from the lower electrode, A current path with low resistance will not be formed between the upper electrode, so that light leakage will not occur, and the display effect of the organic light emitting display device is improved.
附图说明Description of the drawings
图1为现有技术中一种有机发光显示装置的示意图;FIG. 1 is a schematic diagram of an organic light emitting display device in the prior art;
图2为现有技术中另一种有机发光显示装置的示意图;2 is a schematic diagram of another organic light emitting display device in the prior art;
图3为现有技术中再一种有机发光显示装置的示意图;3 is a schematic diagram of another organic light emitting display device in the prior art;
图4本发明实施例提供的有机发光显示装置的示意图;4 is a schematic diagram of an organic light emitting display device provided by an embodiment of the present invention;
图5和图6为像素定义层形成方法的示意图;5 and 6 are schematic diagrams of a method for forming a pixel definition layer;
图7至图10为几种实施方式中下电极的结构示意图。7 to 10 are schematic diagrams of the structure of the lower electrode in several embodiments.
具体实施方式Detailed ways
下面结合附图和实施例对本发明作进一步的详细说明。可以理解的是,此处所描述的具体实施例仅仅用于解释本发明,而非对本发明的限定。另外还需要说明的是,为了便于描述,附图中仅示出了与本发明相关的部分而非全部结构。The present invention will be further described in detail below with reference to the drawings and embodiments. It can be understood that the specific embodiments described here are only used to explain the present invention, but not to limit the present invention. In addition, it should be noted that, for ease of description, the drawings only show part of the structure related to the present invention, but not all of the structure.
在本发明实施例中使用的术语是仅仅出于描述特定实施例的目的,而非旨在限制本发明。需要注意的是,本发明实施例所描述的“上”、“下”、“左”、 “右”等方位词是以附图所示的角度来进行描述的,不应理解为对本发明实施例的限定。此外在上下文中,还需要理解的是,当提到一个元件被形成在另一个元件“上”或“下”时,其不仅能够直接形成在另一个元件“上”或者“下”,也可以通过中间元件间接形成在另一元件“上”或者“下”。术语“第一”、“第二”等仅用于描述目的,并不表示任何顺序、数量或者重要性,而只是用来区分不同的组成部分。对于本领域的普通技术人员而言,可以具体情况理解上述术语在本发明中的具体含义。The terms used in the embodiments of the present invention are only for the purpose of describing specific embodiments, and are not intended to limit the present invention. It should be noted that the “up”, “down”, “left”, “right” and other directional words described in the embodiments of the present invention are described from the angle shown in the drawings, and should not be understood as implementing the present invention. Limitations of examples. In addition, in the context, it should also be understood that when it is mentioned that an element is formed "on" or "under" another element, it can not only be directly formed "on" or "under" the other element, but also It is indirectly formed "on" or "under" another element through an intermediate element. The terms "first", "second", etc. are only used for descriptive purposes, and do not indicate any order, quantity, or importance, but are only used to distinguish different components. For those of ordinary skill in the art, the specific meaning of the above-mentioned terms in the present invention can be understood in specific situations.
请参考图4,为本发明实施提供的一种有机发光显示装置的示意图,如图所示,有机发光显示装置20包括多个有机发光单元21;每个有机发光单元21包括设置于基板22上的下电极23、设置于下电极上的有机发光层24、设置于有机发光层24上的上电极25。可选地,下电极23为阳极,上电极25为阴极。Please refer to FIG. 4, which is a schematic diagram of an organic light-emitting display device provided by an implementation of the present invention. As shown in the figure, the organic light-emitting display device 20 includes a plurality of organic light-emitting units 21; each organic light-emitting unit 21 includes a substrate 22 The lower electrode 23, the organic light emitting layer 24 provided on the lower electrode, and the upper electrode 25 provided on the organic light emitting layer 24. Optionally, the lower electrode 23 is an anode, and the upper electrode 25 is a cathode.
下电极23包括层叠设置的下电极第一部231和下电极第二部232。下电极第一部231设置于基板22上,并且下电极第一部231的侧边和基板22的夹角α1大于等于90度。下电极第二部232设置于下电极第一部231上,并且下电极第二部232的侧边和下电极第一部231的顶面的夹角α2小于90度。The lower electrode 23 includes a lower electrode first part 231 and a lower electrode second part 232 that are stacked. The bottom electrode first portion 231 is disposed on the substrate 22, and the angle α1 between the side of the bottom electrode first portion 231 and the substrate 22 is greater than or equal to 90 degrees. The second portion 232 of the lower electrode is disposed on the first portion 231 of the lower electrode, and the angle α2 between the side of the second portion 232 of the lower electrode and the top surface of the first portion 231 of the lower electrode is less than 90 degrees.
有机发光显示装置20还包括设置于多个有机发光单元21之间的像素定义层26,像素定义层26依照下电极23侧边的形状成膜并覆盖下电极23的侧边。具体地,像素定义层包括覆盖下电极第一部231的侧边的像素定义层第一部261、覆盖下电极第二部232的侧边的像素定义层第二部262。依照下电极23侧边的形状,像素定义层第一部261和基板22的夹角α1大于等于90度,像素定义层第二部262和下电极第一部231的顶面的夹角α2小于90度。The organic light emitting display device 20 further includes a pixel defining layer 26 arranged between the plurality of organic light emitting units 21, and the pixel defining layer 26 is formed into a film according to the shape of the side of the lower electrode 23 and covers the side of the lower electrode 23. Specifically, the pixel definition layer includes a pixel definition layer first part 261 covering the side of the lower electrode first part 231 and a pixel definition layer second part 262 covering the side of the lower electrode second part 232. According to the shape of the side of the bottom electrode 23, the angle α1 between the first part 261 of the pixel definition layer and the substrate 22 is greater than or equal to 90 degrees, and the angle α2 between the second part 262 of the pixel definition layer and the top surface of the first part 231 of the bottom electrode is less than 90 degrees.
如图5和图6所示,为像素定义层形成方法的示意图。像素定义层是在下电极23形成完后再形成的。首先,在下电极23的上层进行像素定义层的沉积成膜,像素定义层一般通过化学气相成膜工艺形成,成膜材料以气态形 态导入到反应腔体内,然后材料之间发生化学反应,沉积到下电极23的上层,因此可以形成覆盖下电极23的侧边并和其侧边形状一致的像素定义层260。该像素定义层260为整层结构,像素定义层260包括覆盖下电极第一部231侧边的像素定义层第一部261、覆盖下电极第二部232侧边的像素定义层第一部262,像素定义层260还包括覆盖下电极23的顶面部分和覆盖相邻两个下电极23之间间隔区域的基板22的部分。As shown in FIG. 5 and FIG. 6, a schematic diagram of a method for forming a pixel definition layer. The pixel defining layer is formed after the bottom electrode 23 is formed. First, the pixel definition layer is deposited and formed on the upper layer of the lower electrode 23. The pixel definition layer is generally formed by a chemical vapor deposition process. The film forming material is introduced into the reaction chamber in a gaseous state, and then a chemical reaction occurs between the materials to deposit The upper layer of the lower electrode 23 can therefore form a pixel definition layer 260 covering the side of the lower electrode 23 and having the same shape as the side of the lower electrode 23. The pixel definition layer 260 is a whole layer structure. The pixel definition layer 260 includes a pixel definition layer first part 261 covering the side of the lower electrode first part 231, and a pixel definition layer first part 262 covering the side of the lower electrode second part 232. The pixel definition layer 260 also includes a portion covering the top surface of the lower electrode 23 and a portion of the substrate 22 covering the space between two adjacent lower electrodes 23.
然后在整层的像素定义层260上形成光刻胶层,并对光刻胶层进行曝光显影、形成图案化光刻胶层27,图案化光刻胶层27暴露下电极23的顶面,并遮挡其他位置。以图案化光刻胶层27为掩膜刻蚀像素定义层260,去除下电极23顶面的像素定义层260,然后去除图案化光刻胶层27。刻蚀完成的像素定义层260包括覆盖下电极第一部231侧边的像素定义层第一部261、覆盖下电极第二部232侧边的像素定义层第二部262、覆盖相邻两个下电极23之间间隔区域的像素定义层第三部263。Then, a photoresist layer is formed on the entire pixel defining layer 260, and the photoresist layer is exposed and developed to form a patterned photoresist layer 27. The patterned photoresist layer 27 exposes the top surface of the lower electrode 23. And cover other positions. The pixel defining layer 260 is etched using the patterned photoresist layer 27 as a mask, the pixel defining layer 260 on the top surface of the lower electrode 23 is removed, and then the patterned photoresist layer 27 is removed. The etched pixel definition layer 260 includes a first part 261 of a pixel definition layer covering the side of the first part 231 of the lower electrode, a second part 262 of a pixel definition layer covering the side of the second part 232 of the lower electrode, and covering two adjacent ones. The third portion 263 of the pixel definition layer in the space between the lower electrodes 23.
参考图4,在刻蚀完成后的像素定义层上形成有机发光层24。有机发光层24包括多层有机膜层,其中至少部分有机膜层在像素定义层处断开。Referring to FIG. 4, an organic light emitting layer 24 is formed on the pixel definition layer after the etching is completed. The organic light emitting layer 24 includes multiple organic film layers, wherein at least part of the organic film layers are disconnected at the pixel definition layer.
有机发光显示装置20的多个有机发光单元21的同一层有机膜层使用开放式掩膜板在同一蒸镀工艺中形成,开放式掩膜板只遮挡显示装置的周边区域,将显示区域的多个有机发光单元区域和间隔区域都暴露出来。蒸镀工艺中,首先将有机膜层材料加热汽化,汽化后的有机膜层材料扩散到基板22上并附着。因为汽化的有机膜层材料能量低、膜层覆盖性差,因此在扩散到像素定义层第一部261、像素定义层第二部262处时,因为像素定义层第二部262遮挡了像素定义层第一部261,有机膜层材料不能连续地在像素定义层第一部261、像素定义层第二部262附着,从而形成了断开的结构。The same organic film layer of the plurality of organic light-emitting units 21 of the organic light-emitting display device 20 is formed in the same evaporation process using an open mask. The open mask only shields the peripheral area of the display device, which reduces the display area. Both the organic light emitting unit area and the spacer area are exposed. In the evaporation process, the organic film layer material is first heated and vaporized, and the vaporized organic film layer material diffuses on the substrate 22 and adheres. Because the vaporized organic film material has low energy and poor film coverage, when it diffuses to the first part 261 of the pixel definition layer and the second part 262 of the pixel definition layer, the second part 262 of the pixel definition layer blocks the pixel definition layer. In the first part 261, the organic film layer material cannot be continuously attached to the first part 261 of the pixel definition layer and the second part 262 of the pixel definition layer, thereby forming a disconnected structure.
本发明实施例中,将下电极23设置成如上所述形状,使得像素定义层26也依照下电极23侧面的形状成膜,在像素定义层26上成膜的有机膜层会在像素定义层处断开,从而消除相邻有机发光单元21之间的串扰。In the embodiment of the present invention, the lower electrode 23 is arranged in the shape described above, so that the pixel defining layer 26 is also formed into a film according to the shape of the side surface of the lower electrode 23, and the organic film layer formed on the pixel defining layer 26 will be on the pixel defining layer. , So as to eliminate crosstalk between adjacent organic light emitting units 21.
可选地,下电极第一部231的侧边和基板22的夹角α1大于135度、小于等于150度。下电极第二部232的侧边和下电极第一部231的顶面的夹角α2大于等于30度、小于等于60度。像素定义层依照下电极的形状成膜,像素定义层第一部261和基板22的夹角α1也是大于135度、小于等于150度。像素定义层第二部262和下电极第一部231的顶面的夹角α2也大于等于30度、小于等于60度,上述角度范围工艺中较容易控制,工艺稳定性好。Optionally, the included angle α1 between the side of the first part 231 of the bottom electrode and the substrate 22 is greater than 135 degrees and less than or equal to 150 degrees. The angle α2 between the side of the second portion 232 of the lower electrode and the top surface of the first portion 231 of the lower electrode is greater than or equal to 30 degrees and less than or equal to 60 degrees. The pixel definition layer is formed into a film according to the shape of the bottom electrode, and the angle α1 between the first portion 261 of the pixel definition layer and the substrate 22 is also greater than 135 degrees and less than or equal to 150 degrees. The angle α2 between the second portion 262 of the pixel definition layer and the top surface of the first portion 231 of the bottom electrode is also greater than or equal to 30 degrees and less than or equal to 60 degrees. The above-mentioned angle range process is easier to control and has good process stability.
本发明中,下电极为两层结构,下电极两层结构或者多层结构在有机发光显示装置中为常见结构。In the present invention, the lower electrode has a two-layer structure, and the two-layer structure or the multi-layer structure of the lower electrode is a common structure in organic light emitting display devices.
可选地,下电极第一部231为增强电极和基板22接触强度的接触电极层,需要说明的是,基板22也包含已经沉积了其他膜层的基板,下电极第一部231可以增强和基板22上其他材料层接触强度的材料。下电极第一部231的材料构为从银、钕、铬、铟、锡、锌、镉、钛、铝、镁和钼构成的集合中选出的至少一种金属。下电极第二部232为导电能力强的导电金属层。Optionally, the bottom electrode first portion 231 is a contact electrode layer that enhances the contact strength between the electrode and the substrate 22. It should be noted that the substrate 22 also includes a substrate on which other film layers have been deposited. The bottom electrode first portion 231 can enhance and The other material layers on the substrate 22 are in contact with strong materials. The material of the first part 231 of the lower electrode is at least one metal selected from the group consisting of silver, neodymium, chromium, indium, tin, zinc, cadmium, titanium, aluminum, magnesium, and molybdenum. The second portion 232 of the lower electrode is a conductive metal layer with strong conductivity.
可选地,有机发光单元21为微腔结构的有机发光单元,下电极23包括反射材料,上电极25包括半反半透材料,在下电极23和上电极25之间形成谐振腔。下电极第一部231为反射金属层,如银或者含银合金。下电极第二部232为透明导电金属形成的光学调节层,比如下电极第二部232的材料可以为氧化铟锡或者氧化铟锌。Optionally, the organic light emitting unit 21 is an organic light emitting unit with a microcavity structure, the lower electrode 23 includes a reflective material, and the upper electrode 25 includes a transflective material, and a resonant cavity is formed between the lower electrode 23 and the upper electrode 25. The first part 231 of the bottom electrode is a reflective metal layer, such as silver or an alloy containing silver. The second part 232 of the lower electrode is an optical adjustment layer formed of a transparent conductive metal. For example, the material of the second part 232 of the lower electrode may be indium tin oxide or indium zinc oxide.
因为下电极两层结构或者多层结构在有机发光显示装置中为常见结构,不需要在现有技术的基础上再增加下电极膜层的数量及对应的成膜工艺,而利用两层或多层结构的下电极,只需要按照下电极的形状形成像素定义层,就可以起到断开部分有机膜层、阻止像素单元之间串扰的作用,相比于多次成膜刻蚀成型的像素定义层来说,简化了工艺。另外,如图4所示,在像素定义层处,有机膜层24如果有部分膜层没有彻底断开,形成了极薄的连续膜层,但因为有像素定义层将有机膜层24和下电极23隔开,从下电极到上电极之间不会形成电阻小的电流路径,从而在区域A处不会发生漏光的情况, 提高了有机发光显示装置的显示效果。Because the two-layer structure or multi-layer structure of the bottom electrode is a common structure in organic light-emitting display devices, there is no need to increase the number of bottom electrode film layers and the corresponding film forming process on the basis of the prior art, and use two or more layers. The bottom electrode of the layer structure only needs to form a pixel definition layer according to the shape of the bottom electrode, which can cut off part of the organic film layer and prevent crosstalk between pixel units. Compared with the pixels formed by multiple film formation and etching For the definition layer, the process is simplified. In addition, as shown in FIG. 4, at the pixel definition layer, if part of the organic film layer 24 is not completely broken, a very thin continuous film layer is formed. However, because of the pixel definition layer, the organic film layer 24 and the lower The electrodes 23 are separated, and a current path with low resistance is not formed between the lower electrode and the upper electrode, so that light leakage does not occur in the area A, and the display effect of the organic light emitting display device is improved.
可选地,下电极还可以为不同于图4所示的其他结构,请参考图7至图10,为几种实施方式中下电极的结构示意图。Optionally, the lower electrode may also have a structure other than that shown in FIG. 4. Please refer to FIGS. 7 to 10, which are schematic diagrams of the structure of the lower electrode in several embodiments.
图7为一种实施方式中下电极的结构示意图,图7中,下电极第一部231的顶面宽度小于下电极第二部232的底面的宽度,只要保证下电极第一部231、下电极第二部232的角度符合要求,下电极第一部231、下电极第二部232的宽度关系不受限制。7 is a schematic diagram of the structure of the bottom electrode in one embodiment. In FIG. 7, the width of the top surface of the first portion 231 of the bottom electrode is smaller than the width of the bottom surface of the second portion 232 of the bottom electrode. The angle of the second electrode part 232 meets the requirements, and the width relationship between the first part 231 of the bottom electrode and the second part 232 of the bottom electrode is not limited.
图8为再一实施方式中下电极的结构示意图、图9为第三种实施方式中下电极的结构示意图,下电极还包括位于下电极第一部231下方的下电极第三部233。下电极第三部233为不同于下电极第一部231、下电极第二部232的第三导电膜层形成的。在图8中,下电极第三部233的侧边和底面的夹角小于90度。在图9中,下电极第三部233的侧边和底面的夹角大于90度。下电极第三部233的结构可以为多种形式,比如还可以设置为其侧边垂直于底面。图8、图9只是示意性地列举了两种,但本发明并不局限这两种结构,下电极第三233在不影响下电极第一部231、下电极第二部232结构的情况下,其可以为任意结构。FIG. 8 is a schematic diagram of the structure of the lower electrode in another embodiment, and FIG. 9 is a schematic diagram of the structure of the lower electrode in the third embodiment. The lower electrode further includes a third portion 233 of the lower electrode under the first portion 231 of the lower electrode. The third portion 233 of the lower electrode is formed of a third conductive film layer different from the first portion 231 of the lower electrode and the second portion 232 of the lower electrode. In FIG. 8, the angle between the side and the bottom surface of the third portion 233 of the lower electrode is less than 90 degrees. In FIG. 9, the angle between the side edge and the bottom surface of the third portion 233 of the lower electrode is greater than 90 degrees. The structure of the third part 233 of the lower electrode can be in various forms, for example, it can also be arranged such that the side edge is perpendicular to the bottom surface. Figures 8 and 9 only schematically list two structures, but the present invention is not limited to these two structures. The third bottom electrode 233 does not affect the structure of the bottom electrode first part 231 and the bottom electrode second part 232. , It can be any structure.
图10为第四种实施方式中下电极的结构示意图,下电极还包括位于下电极第二部232上方的下电极第三部233。下电极第三部233为不同于下电极第一部231、下电极第二部232的第三导电膜层形成的。优选地,下电极第三部233位于下电极第二部232上方时,下电极第三部233的底面宽度小于等于下电极第二部232的顶面宽度,并且下电极第三部233的侧面和底面的夹角小于90度,下电极第三部233的侧面为一缓坡结构,有利于位于其上的上电极成膜时能形成连续的膜层。FIG. 10 is a schematic diagram of the structure of the lower electrode in the fourth embodiment. The lower electrode further includes a third portion 233 of the lower electrode located above the second portion 232 of the lower electrode. The third portion 233 of the lower electrode is formed of a third conductive film layer different from the first portion 231 of the lower electrode and the second portion 232 of the lower electrode. Preferably, when the lower electrode third portion 233 is located above the lower electrode second portion 232, the bottom surface width of the lower electrode third portion 233 is less than or equal to the top surface width of the lower electrode second portion 232, and the side surface of the lower electrode third portion 233 The angle with the bottom surface is less than 90 degrees, and the side surface of the third part 233 of the lower electrode is a gentle slope structure, which is beneficial to the formation of a continuous film layer when the upper electrode located on it forms a film.
有机发光层24为多层膜层层叠的结构,只需要将该多层膜层中容易发生横向漏流的载流子迁移率高的膜层在各像素单元之间断开即可。具体地,如图4所示,有机发光层24可以包括第一有机膜层241、设置于第一有机膜 层241上的第二有机膜层242。第一有机膜层241中包括有载流子迁移率大容易发生横向导电的有机膜层,第二有机膜层242中的有机膜层载流子迁移率小、不容易发生横向导电。只需将第一有机膜层241在像素单元之间断开即可,而保证第二有机膜层242在像素单元之间为连续结构,进而在第二有机膜层242上形成的上电极25在连续结构的第二有机膜层242上也能形成连续结构,保证上电极信号在各个像素单元间的传输。The organic light-emitting layer 24 is a structure in which a multilayer film layer is laminated, and it is only necessary to disconnect the film layer with high carrier mobility that is prone to lateral leakage in the multilayer film layer between the pixel units. Specifically, as shown in FIG. 4, the organic light-emitting layer 24 may include a first organic film layer 241 and a second organic film layer 242 disposed on the first organic film layer 241. The first organic film layer 241 includes an organic film layer with high carrier mobility and easy lateral conduction. The organic film layer in the second organic film layer 242 has a low carrier mobility and is not prone to lateral conduction. It is only necessary to disconnect the first organic film layer 241 between the pixel units, and ensure that the second organic film layer 242 is a continuous structure between the pixel units, and then the upper electrode 25 formed on the second organic film layer 242 is A continuous structure can also be formed on the continuous structure of the second organic film layer 242 to ensure the transmission of the upper electrode signal between each pixel unit.
可选地,设置第一有机膜层241的厚度小于等于下电极第一部231的厚度,第一有机膜层241在像素定义层26处断开。设置第一有机膜层241和第二有机膜层242的厚度和大于下电极第一部231的厚度,同时因为下电极第二部232的侧边和下电极第一部231的顶面的夹角α2小于90度,像素定义层第二部262依照下电极第二部232的侧边的形状,也形成和下电极第一部231的顶面的夹角α2小于90度的结构,即像素定义层第二部262形成了一个缓坡,第二有机膜层242中各膜层在该缓坡上成膜时,会形成连续的膜层结构。Optionally, the thickness of the first organic film layer 241 is set to be less than or equal to the thickness of the first portion 231 of the lower electrode, and the first organic film layer 241 is disconnected at the pixel defining layer 26. The sum of the thicknesses of the first organic film layer 241 and the second organic film layer 242 is set to be greater than the thickness of the first portion 231 of the lower electrode, and at the same time, because the sides of the second portion 232 of the lower electrode and the top surface of the first portion 231 of the lower electrode are sandwiched The angle α2 is less than 90 degrees. The second portion 262 of the pixel definition layer also forms a structure in which the angle α2 with the top surface of the first portion 231 of the lower electrode is less than 90 degrees in accordance with the shape of the side of the second portion 232 of the lower electrode, that is, the pixel The second portion 262 of the definition layer forms a gentle slope, and when each layer of the second organic film layer 242 is formed on the gentle slope, a continuous layer structure is formed.
可选地,第一有机膜层241可以包括依次层叠设置的空穴注入层、空穴传输层。空穴注入层、空穴传输层载流子迁移率较大,容易发生像素单元之间的横向漏流,因此将空穴注入层、空穴传输层设置为断开结构。在空穴注入层、空穴传输层上层的第二有机膜层242包括其他膜层,这些膜层载流子迁移率较小,不需要将其在像素单元之间断开。如第二有机膜层242包括依次叠层设置的电子阻挡层、有机发光材料层、空穴阻挡层、电子传输层等。Optionally, the first organic film layer 241 may include a hole injection layer and a hole transport layer that are sequentially stacked. The hole injection layer and the hole transport layer have high carrier mobility and are prone to lateral leakage between pixel units. Therefore, the hole injection layer and the hole transport layer are set in a disconnected structure. The second organic film layer 242 on the hole injection layer and the hole transport layer includes other film layers, which have low carrier mobility and do not need to be disconnected between pixel units. For example, the second organic film layer 242 includes an electron blocking layer, an organic light-emitting material layer, a hole blocking layer, an electron transport layer, etc., which are sequentially stacked.
可选地,有机发光显示单元包括两个叠加的有机发光单元,每个有机发光单元都包括载流子迁移率较大的膜层,需要将这些膜层都在像素单元之间断开。比如第一有机膜层包括依次层叠设置的第一空穴注入层、第一空穴传输层、第一电子阻挡层、第一有机发光材料层、第一空穴阻挡层、电荷生成层、第二空穴注入层、第二空穴传输层。第二有机膜层包括依次叠层设置的第二电子阻挡层、第二有机发光材料层、第二空穴阻挡层、电子传输层。Optionally, the organic light-emitting display unit includes two superimposed organic light-emitting units, and each organic light-emitting unit includes a film layer with a larger carrier mobility, and these film layers need to be disconnected between the pixel units. For example, the first organic film layer includes a first hole injection layer, a first hole transport layer, a first electron blocking layer, a first organic light-emitting material layer, a first hole blocking layer, a charge generation layer, and a Two hole injection layer, second hole transport layer. The second organic film layer includes a second electron blocking layer, a second organic light-emitting material layer, a second hole blocking layer, and an electron transport layer that are sequentially stacked.
可选地,本发明实施例提供的有机发光显示装置为硅基微型有机发光显示装置。硅基微型有机发光显示装置以单晶硅芯片为基底,像素尺寸为传统显示器件的1/10,精细度远远高于传统器件,可用于形成微型显示器。硅基微型有机发光显示装置具有广阔的市场应用空间,特别适合应用于头盔显示器、立体显示镜以及眼镜式显示器等。硅基微型有机发光显示装置因像素尺寸小,有机发光层的各膜层更容易显示串扰,因此本发明实施例提供的结构更适合硅基微型有机发光显示装置,可以提高硅基微型有机发光显示装置的显示效果。Optionally, the organic light emitting display device provided by the embodiment of the present invention is a silicon-based micro organic light emitting display device. The silicon-based miniature organic light-emitting display device is based on a single crystal silicon chip, and the pixel size is 1/10 of that of the traditional display device, and the fineness is much higher than that of the traditional device, and can be used to form a micro display. Silicon-based micro organic light-emitting display devices have a broad market application space, and are particularly suitable for use in helmet-mounted displays, stereoscopic display mirrors, and glasses-type displays. Because of the small pixel size of the silicon-based micro organic light-emitting display device, each film layer of the organic light-emitting layer is easier to display crosstalk. Therefore, the structure provided by the embodiment of the present invention is more suitable for silicon-based micro organic light-emitting display devices, and can improve the silicon-based micro organic light-emitting display. The display effect of the device.
本发明提供的有机发光显示装置,利用下电极两层结构或者多层结构在有机发光显示装置中为常见结构,不需要在现有技术的基础上再增加下电极膜层的数量及对应的成膜工艺,而利用两层或多层结构的下电极,只需要按照下电极的形状形成像素定义层,就可以起到断开部分有机膜层、阻止像素单元之间串扰的作用,相比于多次成膜刻蚀成型的像素定义层来说,简化了工艺。另外,在像素定义层处,有机膜层中如果有部分膜层没有彻底断开,形成了极薄的连续膜层,但因为有像素定义层将有机膜层和下电极隔开,从下电极到上电极之间不会形成电阻小的电流路径,从而不会发生漏光的情况,提高了有机发光显示装置的显示效果。The organic light-emitting display device provided by the present invention utilizes a two-layer structure or a multi-layer structure of the lower electrode, which is a common structure in organic light-emitting display devices, and does not need to increase the number of lower electrode film layers and corresponding components on the basis of the prior art. Film process, and the use of a two-layer or multi-layer structure of the bottom electrode, only needs to form a pixel definition layer according to the shape of the bottom electrode, which can cut off some organic film layers and prevent crosstalk between pixel units. For the pixel definition layer formed by multiple film formation and etching, the process is simplified. In addition, at the pixel definition layer, if part of the organic film layer is not completely disconnected, a very thin continuous film layer is formed. However, because the pixel definition layer separates the organic film layer from the lower electrode, A current path with low resistance will not be formed between the upper electrode, so that light leakage will not occur, and the display effect of the organic light emitting display device is improved.
注意,上述仅为本发明的较佳实施例及所运用技术原理。本领域技术人员会理解,本发明不限于这里所述的特定实施例,对本领域技术人员来说能够进行各种明显的变化、重新调整和替代而不会脱离本发明的保护范围。因此,虽然通过以上实施例对本发明进行了较为详细的说明,但是本发明不仅仅限于以上实施例,在不脱离本发明构思的情况下,还可以包括更多其他等效实施例,而本发明的范围由所附的权利要求范围决定。Note that the above are only the preferred embodiments of the present invention and the applied technical principles. Those skilled in the art will understand that the present invention is not limited to the specific embodiments described herein, and various obvious changes, readjustments and substitutions can be made to those skilled in the art without departing from the protection scope of the present invention. Therefore, although the present invention has been described in more detail through the above embodiments, the present invention is not limited to the above embodiments, and can also include more other equivalent embodiments without departing from the concept of the present invention. The scope of is determined by the scope of the appended claims.

Claims (11)

  1. 一种有机发光显示装置,其特征在于,所述有机发光显示装置包括多个有机发光单元;每个所述有机发光单元包括设置于基板上的下电极、设置于所述下电极上的有机发光层、设置于所述有机发光层上的上电极;An organic light emitting display device, wherein the organic light emitting display device includes a plurality of organic light emitting units; each of the organic light emitting units includes a lower electrode arranged on a substrate, and an organic light emitting device arranged on the lower electrode. Layer, an upper electrode disposed on the organic light-emitting layer;
    所述下电极包括层叠设置的下电极第一部、下电极第二部;所述下电极第一部设置于所述基板上,并且所述下电极第一部的侧边和所述基板的夹角大于等于90度;所述下电极第二部设置于所述下电极第一部上,并且所述下电极第二部的侧边和所述下电极第一部的顶面的夹角小于90度;The lower electrode includes a first portion of a lower electrode and a second portion of the lower electrode that are stacked; the first portion of the lower electrode is disposed on the substrate, and the side of the first portion of the lower electrode is The included angle is greater than or equal to 90 degrees; the second part of the bottom electrode is disposed on the first part of the bottom electrode, and the included angle between the side of the second part of the bottom electrode and the top surface of the first part of the bottom electrode Less than 90 degrees;
    还包括设置于所述多个有机发光单元之间并覆盖所述下电极侧边的像素定义层,所述像素定义层包括覆盖所述下电极第一部的侧边的像素定义层第一部、覆盖所述下电极第二部的侧边的像素定义层第二部;所述像素定义层第一部和所述基板的夹角大于等于90度;所述像素定义层第二部和所述下电极第一部的顶面的夹角小于90度;It also includes a pixel definition layer disposed between the plurality of organic light emitting units and covering the side of the lower electrode, and the pixel definition layer includes a first part of the pixel definition layer covering the side of the first part of the lower electrode The second part of the pixel definition layer covering the side of the second part of the lower electrode; the angle between the first part of the pixel definition layer and the substrate is greater than or equal to 90 degrees; the second part of the pixel definition layer and the The included angle of the top surface of the first part of the lower electrode is less than 90 degrees;
    所述多个有机发光单元的有机发光层包括多层有机膜层,至少部分所述有机膜层在所述像素定义层处断开。The organic light-emitting layer of the plurality of organic light-emitting units includes multiple organic film layers, and at least part of the organic film layers are disconnected at the pixel defining layer.
  2. 如权利要求1所述的有机发光显示装置,其特征在于,所述下电极第一部的侧边和所述基板的夹角大于135度、小于等于150度。3. The organic light emitting display device of claim 1, wherein the angle between the side of the first part of the bottom electrode and the substrate is greater than 135 degrees and less than or equal to 150 degrees.
  3. 如权利要求1所述的有机发光显示装置,其特征在于,所述下电极第二部的侧边和所述下电极第一部的顶面的夹角大于等于30度、小于等于60度。3. The organic light emitting display device of claim 1, wherein the angle between the side of the second portion of the bottom electrode and the top surface of the first portion of the bottom electrode is greater than or equal to 30 degrees and less than or equal to 60 degrees.
  4. 如权利要求1所述的有机发光显示装置,其特征在于,所述下电极还包括设置于所述下电极第一部下方的下电极第三部。8. The organic light emitting display device of claim 1, wherein the bottom electrode further comprises a third part of the bottom electrode disposed under the first part of the bottom electrode.
  5. 如权利要求1所述的有机发光显示装置,其特征在于,所述下电极还包括设置于所述下电极第二部上方的下电极第三部。8. The organic light emitting display device of claim 1, wherein the bottom electrode further comprises a third part of the bottom electrode disposed above the second part of the bottom electrode.
  6. 如权利要求1所述的有机发光显示装置,其特征在于,所述有机发光层包括层叠的第一有机膜层、设置于所述第一有机膜层上的层叠的第二有机膜层;所述第一有机膜层在所述像素定义层处断开。5. The organic light emitting display device of claim 1, wherein the organic light emitting layer comprises a stacked first organic film layer, and a stacked second organic film layer disposed on the first organic film layer; The first organic film layer is disconnected at the pixel definition layer.
  7. 如权利要求6所述的有机发光显示装置,其特征在于,所述第一有机膜层的厚度小于等于所述下电极第一部的厚度;所述第一有机膜层和所述第二有机膜层的厚度和大于所述下电极第一部的厚度。7. The organic light emitting display device of claim 6, wherein the thickness of the first organic film layer is less than or equal to the thickness of the first portion of the lower electrode; the first organic film layer and the second organic film layer The sum of the thickness of the film layer is greater than the thickness of the first part of the lower electrode.
  8. 如权利要求7所述的有机发光显示装置,其特征在于,所述多个有机发光单元的上电极相互连接。8. The organic light emitting display device of claim 7, wherein the upper electrodes of the plurality of organic light emitting units are connected to each other.
  9. 如权利要求7所述的有机发光显示装置,其特征在于,8. The organic light emitting display device of claim 7, wherein:
    所述第一有机膜层包括依次层叠设置的空穴注入层、空穴传输层;The first organic film layer includes a hole injection layer and a hole transport layer that are stacked in sequence;
    所述第二有机膜层包括依次叠层设置的电子阻挡层、有机发光材料层、空穴阻挡层、电子传输层。The second organic film layer includes an electron blocking layer, an organic light-emitting material layer, a hole blocking layer, and an electron transport layer that are sequentially stacked.
  10. 如权利要求7所述的有机发光显示装置,其特征在于,所述第一有机膜层包括依次层叠设置的第一空穴注入层、第一空穴传输层、第一电子阻挡层、第一有机发光材料层、第一空穴阻挡层、电荷生成层、第二空穴注入层、第二空穴传输层;7. The organic light emitting display device of claim 7, wherein the first organic film layer comprises a first hole injection layer, a first hole transport layer, a first electron blocking layer, and a first An organic light-emitting material layer, a first hole blocking layer, a charge generation layer, a second hole injection layer, and a second hole transport layer;
    所述第二有机膜层包括依次叠层设置的第二电子阻挡层、第二有机发光材料层、第二空穴阻挡层、电子传输层。The second organic film layer includes a second electron blocking layer, a second organic light-emitting material layer, a second hole blocking layer, and an electron transport layer that are sequentially stacked.
  11. 如权利要求1所述的有机发光显示装置,其特征在于,所述有机发光显示装置为硅基微型有机发光显示装置。3. The organic light emitting display device of claim 1, wherein the organic light emitting display device is a silicon-based micro organic light emitting display device.
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