WO2020254677A1 - Récipient moulé par injection destiné à des produits alimentaires, ledit récipient comprenant une partie en matière plastique recyclée - Google Patents

Récipient moulé par injection destiné à des produits alimentaires, ledit récipient comprenant une partie en matière plastique recyclée Download PDF

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Publication number
WO2020254677A1
WO2020254677A1 PCT/EP2020/067287 EP2020067287W WO2020254677A1 WO 2020254677 A1 WO2020254677 A1 WO 2020254677A1 EP 2020067287 W EP2020067287 W EP 2020067287W WO 2020254677 A1 WO2020254677 A1 WO 2020254677A1
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WO
WIPO (PCT)
Prior art keywords
injection
container
injection moulded
foil
barrier layer
Prior art date
Application number
PCT/EP2020/067287
Other languages
English (en)
Inventor
Benny Nielsen
Original Assignee
Berry Superfos Randers A/S
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Berry Superfos Randers A/S filed Critical Berry Superfos Randers A/S
Publication of WO2020254677A1 publication Critical patent/WO2020254677A1/fr

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14639Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles for obtaining an insulating effect, e.g. for electrical components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/712Containers; Packaging elements or accessories, Packages
    • B29L2031/7162Boxes, cartons, cases

Definitions

  • Injection moulded container for food products said container comprising a portion of recycled plastic material
  • the current invention relates to an injection moulded container which is suitable for food products and which comprises portions of recycled plastic materials.
  • a second aspect of the current invention is to provide a plastic packaging as mentioned in the opening paragraph which has a simple manufacturing process.
  • a third aspect of the current invention is to provide a plastic packaging as mentioned in the opening paragraph which allows for many different forms.
  • an injection moulded container comprising a bottom, a sidewall extending upwardly from the bottom and an upper rim defining a container opening arranged at the upper edge of the sidewall, said container comprising an inner functional barrier layer and a first injection moulded portion, said inner functional barrier layer comprising a bottom portion and a side wall portion and said first injection moulded portion comprising a side wall portion and an upper rim portion, said first injection moulded portion being injection moulded from a food grade plastic material and being injected in a first injection moulding step to join to the inner functional barrier layer such that the inner functional barrier layer and the first injection moulded portion together provide a sealed inner surface of the injection moulded container
  • the container further comprises a second injection moulded portion, said second injection moulded portion being injection moulded in a second step, being arranged outside the inner functional barrier layer and comprising a recycled plastic material.
  • a large portion of the container can be made from non food grade recycled material.
  • recycled materials which are not food grade certified may be used in food containers if they are kept separated from food contact by a functional barrier layer.
  • the functional barrier layer could be provided by many different types of functional barrier materials as will be known to the person skilled in the art.
  • the term functional barrier material should, in the context of the current invention, be understood as a material which prevents undesired chemicals contained in the recycled plastics material of the second layer from wandering out of the recycled plastics material and through the layer with the functional barrier material in a quantity which is undesirable.
  • the functional barrier material could be different types. In a case where a light contamination is present, a rather simple functional barrier material could be provided. In a case where a more significant contamination is present, a stronger functional barrier material would be needed.
  • One typical functional barrier material would be ethylene vinyl alcohol (EVOH).
  • EVOH ethylene vinyl alcohol
  • PET PolyEster or Polyethylene terephthalate
  • PET polyethylene terephthalate
  • AIOx Aluminium Oxide
  • Other suitable films with or without suitable coatings or layers will also be known to the person skilled in the art. However, in certain cases, it might be enough to just provide a clean layer of plastic, for example Polypropylene (PP), on one or both sides of the recycled plastics material layer.
  • PP Polypropylene
  • the person skilled in the art will be able to test if a potential barrier material is suitable when considering the food product and the degree of contamination of the recycled material of the second layer.
  • the inner surface of the container is provided by the exposed surfaces of the inner functional barrier layer and the first injection moulded portion.
  • the inner functional barrier layer is provided as one or more foil elements which are folded and/or assembled into a container like shape with one or more gaps and/or one or more overlapping areas between adjacent portions of the one or more foil elements and in that the first injection moulded portion is arranged to fill the one or more gaps and/or cover the one or more overlapping areas.
  • the gaps in the barrier material are filled by a clean material.
  • the barrier layer should overlap the clean material a certain amount to ensure that contaminants in a material located adjacent the clean material does not wander through the clean material and onto the exposed surface of the clean material. Hence, it will be typical that the barrier layer overlaps the clean material a certain distance.
  • the certain distance could be at least 1 times the thickness of the container, or at least 2 times the thickness of the container or at least 3 times the thickness of the container.
  • the barrier layer can be arranged such that it overlaps itself to reduce the gap between adjacent portions of the barrier layer. However, even in these cases, in some applications it will be desireable to cover these overlapping areas with clean material to further reduce the risk of contaminants in the recycled material from passing through the overlapping areas of the barrier layer.
  • the foil elements are made from a flexible foil element. In one embodiment, the foil elements are made from a material which bonds to the material of the first injection moulded portion during the injection moulding process.
  • the first injection moulding material could comprise multiple different materials which are co-injected. In this case multiple materials are injected simultaneously via an injection nozzle to form an outer skin and an inner core.
  • the inner core could be made of a barrier material or of an oxygen scavenger material.
  • the container further comprises an outer foil layer.
  • the outer foil layer is a decorative In Mould Label (IML).
  • the outer foil layer is a functional barrier layer.
  • the outer foil layer is made from a flexible foil material.
  • the outer foil layer comprises a layer of a plastic foil material.
  • the outer foil layer has a layer made from a material which bonds to the material of the second injection moulded portion during the injection moulding process.
  • the outer surface and the inner surface of the outer foil layer are made from materials which bond together when overlapped and heated in an injection mould.
  • the outer foil layer comprises a first portion which covers a first portion of the second injection moulded portion, covers a first portion of the first injection moulded portion and covers a second portion of the outer foil layer and/or a second portion of the second injection moulded portion.
  • first portion of the outer foil layer extends across a portion of the first injection moulded portion so that it attaches to the second injection mould portion on both sides of the first injection moulded portion.
  • first injection moulded portion will be cooled by the time the outer foil layer is added.
  • the outer foil layer will not attach so well to the first injection moulded portion and having it extend across the first injection moulded portion so that it can attach to the second injection moulded portion on both sides of the first injection moulded portion ensures that the outer foil layer is firmly attached to the container without any loose edges.
  • the outer foil layer can also attach to itself if the inner and outer layers of the outer foil layer can join together when heated.
  • a layer of adhesive could be applied to the outer surface of the first injection moulded portion prior to applying the outer foil layer to the first injection moulded portion.
  • the container has a rectangular form with four rectangular sidewall portions connected by four side edge portions and in that the inner functional barrier layer covers the sidewall portions and in that the first injection moulding portion is exposed on the inside of the container at the four side edge portions.
  • the second injection moulded portion is arranged outside the inner functional barrier layer and between adjacent portions of the first injection moulded portion.
  • a method of manufacturing an injection moulded container comprising the steps of: (a) providing a first injection moulding station comprising a first injection mould cavity, (b) providing an injection mould core at the first injection moulding station, (c) providing an inner foil with functional barrier properties, (d) placing the inner foil on the injection mould core, (e) closing the first injection mould cavity with the injection mould core, (f) injecting a food grade injection moulding material into the closed first injection mould cavity to form a first injection moulded portion which is bonded to the inner foil, (g) opening the first injection mould cavity, (h) providing a second injection moulding station comprising a second injection mould cavity, (i) providing an injection mould core at the second injection moulding station, (j) moving the first injection moulded portion and the inner foil from the first injection moulding station to the second injection moulding station, (k) arranging the first injection moulded portion and the inner foil on the injection mould core or in the second injection mould cavity, (I)
  • the “clean” inner layer could be the innermost surface of the container, or additional coatings/films/foils could be further applied.
  • the potentially contaminated material could form a part of the outer surface of the container, or additional coatings/films/foils could be further applied.
  • the second injection moulded material will be located outside the inner foil.
  • the steps of providing a mould core at the second injection moulding station, moving the first injection moulded portion and the inner foil from the first injection moulding station to the second injection moulding station and arranging the first injection moulded portion and the inner foil on the injection mould core comprise the step of moving the injection mould core from the first injection moulding station to the second injection moulding station without removing the first injection moulded portion and the inner foil from the injection mould core.
  • the injection mould core used at the first injection moulding station is the same as the injection mould core used at the second injection moulding station.
  • the first injection moulding station comprises a first injection mould core and the second injection moulding station comprises a second injection mould core.
  • the first injection mould core and the second injection mould core are identical.
  • the method comprises the step of moving the first injection mould core to the second injection moulding station and the step of moving the second injection mould core to the first injection moulding station.
  • the method comprises the further step of moving the first injection mould core back to the first injection moulding station and moving the second injection mould core back to the second injection moulding station.
  • the method further comprises the step of adding an outer foil to the second injection mould cavity prior to closing the second injection mould cavity.
  • the outer foil comprises functional barrier properties.
  • the step of providing the outer foil comprises the step of providing an outer foil in the form of a label having a first portion which overlaps a second portion of the label when it is placed in the mould cavity.
  • the step of injecting the food grade injection moulding material into the injection mould cavity includes injecting the food grade injection moulding material into the injection mould cavity via more than one injection nozzle.
  • the food grade material is injected via four injection nozzles, one injection nozzle located at each corner of the container.
  • the nozzles are located along a bottom surface of the container.
  • the nozzles are located at the rim portion of the container.
  • the rim portion comprises a skirt portion extending outwardly and downwardly from the upper edge of the rim portion and in that the injection points of the nozzles are located on the inside surface of the skirt portion.
  • Figure 1 shows a perspective view of a first embodiment of a container according to the current invention.
  • Figure 2 shows an exploded view of the container of figure 1.
  • Figure 3 shows a perspective view of a second embodiment of a container according to the current invention.
  • Figure 4 shows an exploded view of the container of figure 3.
  • Figure 5 shows a schematic representation of a first apparatus to make a container according to the current invention.
  • Figure 6 shows a partial schematic representation of a second apparatus to make a container according to the current invention.
  • Figure 7 shows a schematic representation of a third embodiment of a container according to the current invention showing details of one step of the manufacturing method.
  • the container 1 of figures 1 and 2 comprises a functional barrier layer in the form of a barrier foil 2, a first injection moulded portion 4 made from a food grade plastic material and a second injection moulded portion 6 made from a recycled and potentially non-food grade plastic material.
  • the inner surface 8a, 8b, 8c, 8d, 9a, 9b, 9c, 9d of the sidewall of the container and inner surface 10 of the bottom of container which would be in contact with food material in the container are made from either the barrier foil 2 or the food grade material of the first injection moulded portion 4.
  • the upper rim 12 of the container is made from the food grade material 4. The recycled material 6 will therefore not come into direct contact with food material placed in the container during use of the final container as it is hidden behind the barrier foil 2 and the food grade material 4.
  • the container is a rectangular container with four sidewall portions 8a, 8b, 8c, 8d connected by side edge portions 9a, 9b, 9c, 9d.
  • the material of the first injection moulded portion fills these gaps at the side edge portions 9a, 9b, 9c, 9d.
  • a portion of the barrier foil 2 will overlap 11 with the first injection moulded portion.
  • the inner barrier foil layer 2 is prepared as a blank via a cutting process.
  • the inner barrier foil layer is applied on a mould core.
  • the barrier label comprises a bottom portion 10 and four rectangular sidewall portions 8a, 8b.8c, 8d.
  • the foil can be applied to the core on the bottom portion and then the sidewall portions can be folded up.
  • the inner barrier foil layer could be folded or otherwise formed, either prior to being applied on the mould core, or during application to the mould core.
  • a first mould cavity is joined with the mould core to close the mould. Food grade plastic material is then injected into the mould to form the first injection moulded portion 4. The mould is then opened.
  • the newly injection moulded part is maintained on the mould core.
  • the mould core is then moved over to a second mould cavity.
  • the mould core is then joined with the second mould cavity and recycled material is injected into the second mould cavity.
  • the second mould is then opened and the finished container removed from the mould.
  • the newly injection moulded part is removed from the mould core after the first moulding operation.
  • the newly injection moulded part is then moved over to a second moulding station.
  • the part is then inserted into a second mould cavity or placed on a second mould core and the mould closed and then injected with recycled plastic.
  • This type of double injection moulding operations is known in the art of injection moulding as“Over moulding”. The technique will not be described in great detail here, as the person skilled in the art is well versed in the art of over moulding.
  • the plastic is injected via a single injection nozzle, in the bottom surface of the mould cavity. Plastic material will then flow into the cavity from this central location and fill channels 13 in the bottom portion and then the side edges 9a, 9b, 9c, 9d and then the rim portion 12.
  • Figures 3 and 4 show another embodiment of a container 20 according to the invention.
  • the container also comprises an inner functional barrier layer 22, a first injection moulded portion 24 made from a food grade material and a second injection moulded portion 26 made from a recycled material.
  • this second embodiment also has an outer functional barrier layer 28 also in the form of a barrier foil 28.
  • the outer functional barrier layer 28 ensures that when empty containers are stacked one inside the other, the outer surface of the second injection moulded portion of an upper container will not come into contact with the “clean” inner surface of a lower container. This ensures that contaminants in the recycled plastic material, cannot wander from the recycled material of the upper container to the inner surface of the lower container which will later come into contact with food contents.
  • an outer functional barrier layer in the form of a foil could also be provided with decoration and function as an in mould label (IML).
  • IML in mould label
  • the outer barrier layer is formed as a butterfly label.
  • the portions of the outer barrier layer which wrap around the side edges of the container are formed to be longer than in prior art applications. In this way the outer barrier layer portions will overlap in a region 30 such that the label will bond to itself during the step of injection moulding the second injection moulded portion 26.
  • the side edge portions of the label will bond to the injection moulded material during the injection moulding operation.
  • the side edge portions of the container are formed from a food grade material which was formed in a previous injection moulding operation. Hence, this material will be“cold” and the label might not bond to this material properly.
  • the side edge portions of the label are made longer, so that they overlap other portions of the label.
  • one portion of the label will be bonded to a portion of the recycled material, and another portion of the label will overlap this portion and join to itself.
  • the label instead of overlapping itself, the label could just overlap the portion of the first injection moulded material and reach a portion of the recycled material on the other side of the first injection moulded material. In this case, there would still be some exposed recycled material on the outer surface of the container, however, by placing it in a position in which it does not come into contact with other containers during stacking, this might be okay.
  • the method would further comprise the step of adding an outer barrier foil to the second mould cavity, prior to injecting the second injection moulding material.
  • an outer barrier layer was added to cover the situation where the containers are stacked.
  • the points of contact between stacked containers only occurs in the food grade certified areas.
  • the upper rim of the container is also made from a clean material.
  • stacking features can be added to the upper rim, so that the only point of contact between stacked containers occurs at the upper rim.
  • one or more outer channel(s) could be formed in the outer surfaces of the side edge portions of the food grade material of the container in the first injection moulding operation.
  • hot recycled material could flow through these channels to which the outer foil/label/barrier layer could engage.
  • the channels could be arranged such that they are placed behind the inner barrier layer.
  • the side edge portions of the food grade material are shown to be quite wide and the side gap in the inner barrier foil to also be quite wide.
  • the gap in the inner barrier foil could be made smaller. It could also be imagined that the corner portions of the container have a slightly increased wall thickness, to ensure that there is room for both a layer of barrier material, a layer of food grade material, a layer of recycled material and possibly a layer of outer label.
  • the actual apparatus to manufacture the container according to the current invention could be provided in many different forms. However, one apparatus is schematically shown in figure 5.
  • two mould cores 50 are provided on a first side 52 of a rotating fixture 54 and two mould cores 56 are provided on a second side 58 of the rotating fixture 54.
  • the mould cores are all identical in this embodiment.
  • a first fixture 60 having two first mould cavities 62 is arranged on the first side of the rotating fixture and a second fixture 64 having two second mould cavities 66 is arranged on the second side of the rotating fixture 54.
  • the first mould cavity 62 is arranged for forming the first injection moulded portion and the second mould cavity 66 is arranged for forming the second injection moulded portion.
  • the first side 52 of the apparatus could be considered a first moulding station and the second side 58 of the apparatus could be considered a second moulding station.
  • the inner barrier foil is applied on the first side to the mould core 50 and the mould closed.
  • the food grade material is then injected on the first side.
  • the mould is opened and the fixture rotated 180 degrees.
  • the injection moulded container moulded in the first step is not removed from the cores, but is just rotated with the core.
  • a new inner barrier layer is added on the first side 52 and if desired, an outer foil can be added to the second mould cavity 66.
  • the moulds are then closed again.
  • Food grade material is injected on the first side 52 and recycled material is injected on the second side 58. This time when the mould is opened, the completed container is removed on the second side. The process is then repeated.
  • an apparatus similar to the one which was schematically shown in figure 5 could be provided with any number of cores/cavities.
  • an example of one core on either side of the fixture could be provided.
  • an example of four cores arranged in a square pattern on either side of the fixture could be provided.
  • Other combinations are also possible.
  • FIG. 6 Another embodiment of an apparatus to manufacture the container according to the invention is shown in figure 6.
  • the moulding station only acts on one side.
  • the mould cavities 70,72 are all arranged on the same side of a rotating fixture 74.
  • a corresponding fixture provided with matching cores (not shown) will be provided opposite to the fixture having the mould cavities 70,72.
  • the mould cavities shown in dashed lines 70 are arranged as cavities which form the first injection moulded portion.
  • the mould cavities shown in solid lines 72 are arranged as cavities which form the second injection moulded portion.
  • the mould cores (not shown) are all identical.
  • an inner barrier foil is applied to the cores associated with the first mould cavities 70.
  • the mould is then closed and food grade material is injected into the first mould cavities.
  • the mould is then opened and the fixture is rotated 180 degrees.
  • New inner barrier foils are again applied to the cores associated with the first mould cavities 70 and if desired, outer foil layers are applied to the second mould cavities 72.
  • the mould is closed and food grade material is injected into the first mould cavities and recycled material is injected into the second mould cavities 72.
  • the mould is then opened and the finished container is removed from the second mould cavities 72.
  • the fixture is then rotated again and the procedure repeated.
  • the area shown with the dashed line 76 could be considered the first moulding station and the area shown outside the dashed line 78 could be considered the second moulding station.
  • the fixture containing the mould cavities is shown to be rotated.
  • the fixture containing the cores could be rotated instead.
  • Other forms of apparatus could also be provided as will be known to the person skilled in the art.
  • Figure 7 shows a partial exploded view of another embodiment 80 of a container according to the invention.
  • the figure shows the inner barrier label 82 and the first injection moulded portion 84 made from the food grade material.
  • the second injection moulded portion is not shown.
  • the first injection moulded portion 84 is injection moulded via four separate injection points 86 via four injection nozzles (not shown).

Abstract

L'invention concerne un récipient moulé par injection destiné à des produits alimentaires, ledit récipient comprenant un fond, une paroi latérale s'étendant vers le haut à partir du fond et un rebord supérieur définissant une ouverture de récipient disposée au niveau du bord supérieur de la paroi latérale, ledit récipient comprenant une couche barrière fonctionnelle interne et une première partie moulée par injection, ladite couche barrière fonctionnelle interne comprenant une partie fond et une partie paroi latérale et ladite première partie moulée par injection comprenant une partie paroi latérale et une partie rebord supérieur, ladite première partie moulée par injection étant moulée par injection à partir d'une matière plastique de qualité alimentaire et étant injectée au cours d'une première étape de moulage par injection pour se fixer à la couche barrière fonctionnelle interne, de sorte que la couche barrière fonctionnelle interne et la première partie moulée par injection forment ensemble une surface interne scellée du récipient moulé par injection. Le récipient comprend en outre une seconde partie moulée par injection, ladite seconde partie moulée par injection étant moulée par injection au cours d'une seconde étape, étant disposée à l'extérieur de la couche barrière fonctionnelle interne et comprenant une matière plastique recyclée. De cette manière, il peut être fourni un récipient pouvant être fabriqué simplement avec un pourcentage important de matière recyclée de qualité non alimentaire.
PCT/EP2020/067287 2019-06-21 2020-06-22 Récipient moulé par injection destiné à des produits alimentaires, ledit récipient comprenant une partie en matière plastique recyclée WO2020254677A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA201970388 2019-06-21
DKPA201970388 2019-06-21

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WO2020254677A1 true WO2020254677A1 (fr) 2020-12-24

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL2027542B1 (en) * 2021-02-11 2022-09-12 Beekenkamp Verpakkingen B V Crate and method for manufacturing a crate
EP4296029A1 (fr) 2022-06-21 2023-12-27 MATSIM sp.z o.o. Emballage destine a etre en contact avec des aliments recyclats de polyolefine et procede de production

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19506291A1 (de) * 1995-02-23 1996-08-29 Hoesch Metall & Kunststoffwerk Verfahren zur Herstellung eines muldenförmigen Gegenstandes aus Kunststoff, insbesondere eines Sanitärgegenstandes
WO2003013843A1 (fr) * 2001-08-06 2003-02-20 Csp Technologies, Inc. Procede et composition pour un revetement dans le moule
WO2010032688A1 (fr) * 2008-09-22 2010-03-25 日本写真印刷株式会社 Procédé pour produire un article moulé multicouche et ensemble de moule pour article moulé multicouche
EP2213580A1 (fr) * 2007-10-12 2010-08-04 Yupo Corporation Récipient composite de moulage par injection et son procédé de fabrication
WO2010139566A1 (fr) * 2009-06-02 2010-12-09 Netstal-Maschinen Ag Récipient en matière plastique et procédé de fabrication
EP3453635A1 (fr) * 2017-09-12 2019-03-13 Bloom-In-Box Ltd Réceptacle pliable et moule pour sa fabrication

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19506291A1 (de) * 1995-02-23 1996-08-29 Hoesch Metall & Kunststoffwerk Verfahren zur Herstellung eines muldenförmigen Gegenstandes aus Kunststoff, insbesondere eines Sanitärgegenstandes
WO2003013843A1 (fr) * 2001-08-06 2003-02-20 Csp Technologies, Inc. Procede et composition pour un revetement dans le moule
EP2213580A1 (fr) * 2007-10-12 2010-08-04 Yupo Corporation Récipient composite de moulage par injection et son procédé de fabrication
WO2010032688A1 (fr) * 2008-09-22 2010-03-25 日本写真印刷株式会社 Procédé pour produire un article moulé multicouche et ensemble de moule pour article moulé multicouche
WO2010139566A1 (fr) * 2009-06-02 2010-12-09 Netstal-Maschinen Ag Récipient en matière plastique et procédé de fabrication
EP3453635A1 (fr) * 2017-09-12 2019-03-13 Bloom-In-Box Ltd Réceptacle pliable et moule pour sa fabrication

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL2027542B1 (en) * 2021-02-11 2022-09-12 Beekenkamp Verpakkingen B V Crate and method for manufacturing a crate
EP4296029A1 (fr) 2022-06-21 2023-12-27 MATSIM sp.z o.o. Emballage destine a etre en contact avec des aliments recyclats de polyolefine et procede de production

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