WO2020246947A2 - An a356 alloy that have improved mechanical properties by contribution of cerium and lanthanum master alloy - Google Patents

An a356 alloy that have improved mechanical properties by contribution of cerium and lanthanum master alloy Download PDF

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Publication number
WO2020246947A2
WO2020246947A2 PCT/TR2020/050484 TR2020050484W WO2020246947A2 WO 2020246947 A2 WO2020246947 A2 WO 2020246947A2 TR 2020050484 W TR2020050484 W TR 2020050484W WO 2020246947 A2 WO2020246947 A2 WO 2020246947A2
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WO
WIPO (PCT)
Prior art keywords
alloy
production
master
mechanical properties
cerium
Prior art date
Application number
PCT/TR2020/050484
Other languages
French (fr)
Other versions
WO2020246947A3 (en
Inventor
Uğur Aybarç
Bora YAY
Original Assignee
Cms Jant Ve Maki̇na Sanayi̇i̇ Anoni̇m Şi̇rketi̇
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Cms Jant Ve Maki̇na Sanayi̇i̇ Anoni̇m Şi̇rketi̇ filed Critical Cms Jant Ve Maki̇na Sanayi̇i̇ Anoni̇m Şi̇rketi̇
Publication of WO2020246947A2 publication Critical patent/WO2020246947A2/en
Publication of WO2020246947A3 publication Critical patent/WO2020246947A3/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/03Making non-ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • C22C21/04Modified aluminium-silicon alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60BVEHICLE WHEELS; CASTORS; AXLES FOR WHEELS OR CASTORS; INCREASING WHEEL ADHESION
    • B60B1/00Spoked wheels; Spokes thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60BVEHICLE WHEELS; CASTORS; AXLES FOR WHEELS OR CASTORS; INCREASING WHEEL ADHESION
    • B60B2360/00Materials; Physical forms thereof
    • B60B2360/10Metallic materials
    • B60B2360/104Aluminum

Definitions

  • the invention relates to A356 alloys used in the production of aluminum alloy wheels.
  • the invention relates to the enhancement of the mechanical properties of the alloy by adding the Al-La, Al-Ce and Al-La-Ce master alloys formed by different ratios of La and Ce elements for eutectic modification of eutectic Si in A356 alloy, by combining mechanical and / or ultrasonic stirring methods.
  • A356 aluminum alloy is the alloy that have been commonly used on automotive industry, which have high strength / weight ratio and superior castability. In the automotive industry, it has been observed that it is frequently used in wheel manufacturing. In addition to the mechanical properties of these alloys such as tensile, impact and fatigue strength, wear resistance is also great importance.
  • the present invention relates to the A356 alloy with improved mechanical properties.
  • Al-Sr master alloys are widely used as modifiers on the eutectic modification of the A356 alloy.
  • the high burning tendency of Sr element and burning losses during holding of molten metal in crucible cause inefficient modification in production. Therefore, in the present invention, eutectic modification is provided with master alloys produced with rare earth elements, and moreover, La-Ce included compounds are distributed homogeneously into the alloy by ultrasonic and mechanical stirring.
  • Al-Sr master alloys create intermetallic phases with grain refiner master alloys, causing undesirable impurities within the structure. The impurity problem is prevented by the master alloys used in the present invention.
  • the invention is a new A356 alloy that includes additional advantages, which the prior art is overcame and its disadvantages are eliminated.
  • the object of the invention is to introduce a new A356 alloy with improved mechanical properties and eliminated burning loss and impurity problems.
  • Another object of the invention is to provide a new A356 alloy in which the eutectic modification of the A356 alloy is achieved by the Al-La, Al-Ce and Al- La-Ce master alloys.
  • the present invention is related to the A356 alloy used in the production of metal parts, primarily for use in the production of wheels in the automotive industry, in order to achieve all the above-mentioned objectives and the following detailed description. It is characterized by the addition of 0.1 -0.9 wt. % Al-La, Al-Ce and / or Al-La-Ce master alloys, on the eutectic modification of the alloy in order to improve the mechanical properties and eliminate impurity and burning loss problems.
  • the A356 alloy subject of the invention is explained only with examples for better understanding of the subject, without any limiting effects.
  • the specification describes the A356 alloy produced by adding the Al- La, Al-Ce and Al-La-Ce master alloys formed by different ratios of La and Ce elements for the purpose of eutectic modification and by using mechanical and / or ultrasonic stirring methods together.
  • the invention includes the eutectic modification of the A356 alloy used in the production of aluminum wheels by the use of Al-La, Al-Ce and Al-La-Ce master alloys together with the use of mechanical and ultrasonic stirring methods.
  • the A356 alloy according to the invention contains 0.1 -0.9 wt. % of Al-La, Al-Ce or Al-La-Ce master alloys.
  • Al-La, Al-Ce or Al-La-Ce master alloys are added to the A356 alloy melted by any method.
  • the casting process is completed after the mixture obtained is stirred by using at least one or both of the mechanical and ultrasonic stirring methods together.
  • the efficiency of the eutectic modification was compared with the existing process by metallographic and mechanical analysis of the samples taken from the cast. Afterwards, enhancement on the mechanical properties of obtained new A356 alloy is observed.
  • Ce mentioned in the invention represents the cerium element and "La” represents the lanthanum element.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Alloys Or Alloy Compounds (AREA)
  • Dental Prosthetics (AREA)

Abstract

The invention is related to the A356 alloy used in the production of metal parts, primarily for use in the production of wheels in the automotive industry. It is characterized by the addition of 0.1 -0.9 wt. % Al-La, Al-Ce and / or Al-La-Ce master alloys in eutectic modification of the alloy, in order to improve the mechanical properties and eliminate impurity and burning loss problems.

Description

SPECIFICATION
AN A356 ALLOY THAT HAVE IMPROVED MECHANICAL PROPERTIES BY CONTRIBUTION OF CERIUM AND LANTHANUM MASTER ALLOY
Technological Aspect:
The invention relates to A356 alloys used in the production of aluminum alloy wheels.
The invention relates to the enhancement of the mechanical properties of the alloy by adding the Al-La, Al-Ce and Al-La-Ce master alloys formed by different ratios of La and Ce elements for eutectic modification of eutectic Si in A356 alloy, by combining mechanical and / or ultrasonic stirring methods.
State Of The Art:
A356 aluminum alloy is the alloy that have been commonly used on automotive industry, which have high strength / weight ratio and superior castability. In the automotive industry, it has been observed that it is frequently used in wheel manufacturing. In addition to the mechanical properties of these alloys such as tensile, impact and fatigue strength, wear resistance is also great importance. The present invention relates to the A356 alloy with improved mechanical properties.
In the prior art, Al-Sr master alloys are widely used as modifiers on the eutectic modification of the A356 alloy. However, the high burning tendency of Sr element and burning losses during holding of molten metal in crucible cause inefficient modification in production. Therefore, in the present invention, eutectic modification is provided with master alloys produced with rare earth elements, and moreover, La-Ce included compounds are distributed homogeneously into the alloy by ultrasonic and mechanical stirring. Al-Sr master alloys create intermetallic phases with grain refiner master alloys, causing undesirable impurities within the structure. The impurity problem is prevented by the master alloys used in the present invention.
In US patent document US2016045986 (A1 ) encountered in the literature research, an alloy containing cerium and lanthanum is mentioned. The mentioned alloy is not an aluminum alloy. On related patent document, aluminum-free alloy is mentioned. The mentioned alloy is not an A356 alloy.
As a result, a new A356 alloy is needed where the prior art is overcame and its disadvantages are eliminated.
A Short Explanation of Invention:
The invention is a new A356 alloy that includes additional advantages, which the prior art is overcame and its disadvantages are eliminated.
The object of the invention is to introduce a new A356 alloy with improved mechanical properties and eliminated burning loss and impurity problems.
Another object of the invention is to provide a new A356 alloy in which the eutectic modification of the A356 alloy is achieved by the Al-La, Al-Ce and Al- La-Ce master alloys.
The present invention is related to the A356 alloy used in the production of metal parts, primarily for use in the production of wheels in the automotive industry, in order to achieve all the above-mentioned objectives and the following detailed description. It is characterized by the addition of 0.1 -0.9 wt. % Al-La, Al-Ce and / or Al-La-Ce master alloys, on the eutectic modification of the alloy in order to improve the mechanical properties and eliminate impurity and burning loss problems. Explanation of Invention:
In this detailed explanation, the A356 alloy subject of the invention is explained only with examples for better understanding of the subject, without any limiting effects. The specification describes the A356 alloy produced by adding the Al- La, Al-Ce and Al-La-Ce master alloys formed by different ratios of La and Ce elements for the purpose of eutectic modification and by using mechanical and / or ultrasonic stirring methods together.
The invention includes the eutectic modification of the A356 alloy used in the production of aluminum wheels by the use of Al-La, Al-Ce and Al-La-Ce master alloys together with the use of mechanical and ultrasonic stirring methods. The A356 alloy according to the invention contains 0.1 -0.9 wt. % of Al-La, Al-Ce or Al-La-Ce master alloys. Al-La, Al-Ce or Al-La-Ce master alloys are added to the A356 alloy melted by any method. The casting process is completed after the mixture obtained is stirred by using at least one or both of the mechanical and ultrasonic stirring methods together. The efficiency of the eutectic modification was compared with the existing process by metallographic and mechanical analysis of the samples taken from the cast. Afterwards, enhancement on the mechanical properties of obtained new A356 alloy is observed.
"Ce" mentioned in the invention represents the cerium element and "La" represents the lanthanum element.

Claims

1- The invention is the A356 alloy used in the production of metal parts, primarily for use in the production of wheels in the automotive industry. It is characterized by the addition of 0.1 -0.9 wt.% Al-La, Al-Ce and / or Al-La-Ce master alloys to obtain eutectic modification of the alloy, in order to improve its mechanical properties and eliminate impurity and burning loss problems.
2- According to Claim 1 , the invention is an A356 alloy and it is featured as which master alloy added during the eutectic modification is the Al-La master alloy.
3- According to Claim 1 , the invention is an A356 alloy and it is featured as which master alloy added during the eutectic modification is the Al-Ce master alloy.
4- According to Claim 1 , the invention is an A356 alloy and it is featured as which master alloy added during the eutectic modification is the Al-La-Ce master alloy.
5- The invention is the production method of the A356 alloy used in the production of metal parts, primarily for use in the production of wheels in the automotive industry. The feature of the inventions are;
- Adding Al-La, Al-Ce or Al-La-Ce master alloys in melted A356 alloy, - The mixture obtained is characterized by completing the casting process, after stirring by using at least one or both of the mechanical and ultrasonic stirring methods.
PCT/TR2020/050484 2019-06-05 2020-06-03 An a356 alloy that have improved mechanical properties by contribution of cerium and lanthanum master alloy WO2020246947A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TR2019/08496 2019-06-05
TR2019/08496A TR201908496A2 (en) 2019-06-05 2019-06-05 AN A356 ALLOY WITH IMPROVED MECHANICAL PROPERTIES WITH SERIUM AND LANTHAN-CONTENTED MASTER ALLOYS

Publications (2)

Publication Number Publication Date
WO2020246947A2 true WO2020246947A2 (en) 2020-12-10
WO2020246947A3 WO2020246947A3 (en) 2020-12-30

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WO (1) WO2020246947A2 (en)

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1882753A1 (en) * 2006-07-27 2008-01-30 Fagor, S.Coop. Aluminium alloy
CN101966575B (en) * 2010-11-13 2012-08-08 河南理工大学 Process for casting aluminum alloy wheel and heat treatment process
CN104195385B (en) * 2014-08-29 2016-08-24 沈阳工业大学 Improve long-acting alterant and the preparation and application of hypoeutectic Al-Si alloy electrical conductivity
CN104975161A (en) * 2015-07-02 2015-10-14 中信戴卡股份有限公司 Thermal treatment method of casted aluminium alloy wheels

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TR201908496A2 (en) 2019-07-22

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