WO2020246387A1 - Heat storage material composition and heat storage system for air conditioning of building - Google Patents
Heat storage material composition and heat storage system for air conditioning of building Download PDFInfo
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- WO2020246387A1 WO2020246387A1 PCT/JP2020/021352 JP2020021352W WO2020246387A1 WO 2020246387 A1 WO2020246387 A1 WO 2020246387A1 JP 2020021352 W JP2020021352 W JP 2020021352W WO 2020246387 A1 WO2020246387 A1 WO 2020246387A1
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- Prior art keywords
- heat storage
- storage material
- mass
- material composition
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- 239000000203 mixture Substances 0.000 title claims abstract description 224
- 238000005338 heat storage Methods 0.000 title claims abstract description 220
- 239000011232 storage material Substances 0.000 title claims abstract description 164
- 238000004378 air conditioning Methods 0.000 title description 3
- 238000002844 melting Methods 0.000 claims abstract description 115
- 230000008018 melting Effects 0.000 claims abstract description 115
- DGLRDKLJZLEJCY-UHFFFAOYSA-L disodium hydrogenphosphate dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].OP([O-])([O-])=O DGLRDKLJZLEJCY-UHFFFAOYSA-L 0.000 claims abstract description 57
- ASTWEMOBIXQPPV-UHFFFAOYSA-K trisodium;phosphate;dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[Na+].[O-]P([O-])([O-])=O ASTWEMOBIXQPPV-UHFFFAOYSA-K 0.000 claims abstract description 57
- XYQRXRFVKUPBQN-UHFFFAOYSA-L Sodium carbonate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]C([O-])=O XYQRXRFVKUPBQN-UHFFFAOYSA-L 0.000 claims abstract description 39
- 229940018038 sodium carbonate decahydrate Drugs 0.000 claims abstract description 39
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 claims abstract description 34
- 239000000178 monomer Substances 0.000 claims abstract description 20
- 150000003460 sulfonic acids Chemical class 0.000 claims abstract description 12
- 150000001735 carboxylic acids Chemical class 0.000 claims abstract description 6
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims abstract description 6
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 5
- 150000001408 amides Chemical class 0.000 claims abstract description 4
- 150000001298 alcohols Chemical class 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 69
- 238000001816 cooling Methods 0.000 claims description 33
- 238000010438 heat treatment Methods 0.000 claims description 31
- 239000011734 sodium Substances 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 229910052708 sodium Inorganic materials 0.000 claims description 14
- -1 sodium alkyl sulfate Chemical class 0.000 claims description 13
- 229920001577 copolymer Polymers 0.000 claims description 12
- 239000003112 inhibitor Substances 0.000 claims description 12
- CDNAUIUELRAXBC-UHFFFAOYSA-L disodium sulfate tetrahydrate Chemical compound O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O CDNAUIUELRAXBC-UHFFFAOYSA-L 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 229940047670 sodium acrylate Drugs 0.000 claims description 8
- 238000005191 phase separation Methods 0.000 claims description 7
- 235000002639 sodium chloride Nutrition 0.000 claims description 7
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 6
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 6
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 239000001814 pectin Substances 0.000 claims description 6
- 235000010987 pectin Nutrition 0.000 claims description 6
- 229920001277 pectin Polymers 0.000 claims description 6
- 239000011591 potassium Substances 0.000 claims description 6
- 229910052700 potassium Inorganic materials 0.000 claims description 6
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 claims description 6
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 6
- 238000004781 supercooling Methods 0.000 claims description 6
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 claims description 5
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 5
- 239000004909 Moisturizer Substances 0.000 claims description 5
- 230000001333 moisturizer Effects 0.000 claims description 5
- 239000000230 xanthan gum Substances 0.000 claims description 5
- 229920001285 xanthan gum Polymers 0.000 claims description 5
- 235000010493 xanthan gum Nutrition 0.000 claims description 5
- 229940082509 xanthan gum Drugs 0.000 claims description 5
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 238000010521 absorption reaction Methods 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 235000021317 phosphate Nutrition 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 3
- 229920001817 Agar Polymers 0.000 claims description 3
- 239000004254 Ammonium phosphate Substances 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- 229920002125 Sokalan® Polymers 0.000 claims description 3
- 229920002472 Starch Polymers 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000008272 agar Substances 0.000 claims description 3
- 235000010419 agar Nutrition 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 claims description 3
- 235000019270 ammonium chloride Nutrition 0.000 claims description 3
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 3
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 3
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 3
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 claims description 3
- 229910001863 barium hydroxide Inorganic materials 0.000 claims description 3
- 239000000440 bentonite Substances 0.000 claims description 3
- 229910000278 bentonite Inorganic materials 0.000 claims description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 3
- 229910021538 borax Inorganic materials 0.000 claims description 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 3
- 239000000920 calcium hydroxide Substances 0.000 claims description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- 229940105329 carboxymethylcellulose Drugs 0.000 claims description 3
- 239000000679 carrageenan Substances 0.000 claims description 3
- 235000010418 carrageenan Nutrition 0.000 claims description 3
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- 229940113118 carrageenan Drugs 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 229940094522 laponite Drugs 0.000 claims description 3
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 3
- 239000004584 polyacrylic acid Substances 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- 229920001451 polypropylene glycol Polymers 0.000 claims description 3
- 239000001103 potassium chloride Substances 0.000 claims description 3
- 235000011164 potassium chloride Nutrition 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- 150000004760 silicates Chemical class 0.000 claims description 3
- 229910021647 smectite Inorganic materials 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- 239000004317 sodium nitrate Substances 0.000 claims description 3
- 235000010344 sodium nitrate Nutrition 0.000 claims description 3
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- 239000004328 sodium tetraborate Substances 0.000 claims description 3
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- UUCCCPNEFXQJEL-UHFFFAOYSA-L strontium dihydroxide Chemical compound [OH-].[OH-].[Sr+2] UUCCCPNEFXQJEL-UHFFFAOYSA-L 0.000 claims description 3
- 229910001866 strontium hydroxide Inorganic materials 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 229920002752 Konjac Polymers 0.000 claims description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- YVIGPQSYEAOLAD-UHFFFAOYSA-L disodium;dodecyl phosphate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOP([O-])([O-])=O YVIGPQSYEAOLAD-UHFFFAOYSA-L 0.000 claims description 2
- 235000010485 konjac Nutrition 0.000 claims description 2
- 229920005610 lignin Polymers 0.000 claims description 2
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 229920003123 carboxymethyl cellulose sodium Polymers 0.000 claims 1
- 229940063834 carboxymethylcellulose sodium Drugs 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
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- 230000004927 fusion Effects 0.000 abstract description 18
- 150000007942 carboxylates Chemical class 0.000 abstract description 3
- 150000003016 phosphoric acids Chemical class 0.000 abstract description 2
- 239000003906 humectant Substances 0.000 abstract 1
- 150000003871 sulfonates Chemical class 0.000 abstract 1
- 238000010586 diagram Methods 0.000 description 40
- 101100321992 Drosophila melanogaster ABCD gene Proteins 0.000 description 13
- PCTMTFRHKVHKIS-BMFZQQSSSA-N (1s,3r,4e,6e,8e,10e,12e,14e,16e,18s,19r,20r,21s,25r,27r,30r,31r,33s,35r,37s,38r)-3-[(2r,3s,4s,5s,6r)-4-amino-3,5-dihydroxy-6-methyloxan-2-yl]oxy-19,25,27,30,31,33,35,37-octahydroxy-18,20,21-trimethyl-23-oxo-22,39-dioxabicyclo[33.3.1]nonatriaconta-4,6,8,10 Chemical compound C1C=C2C[C@@H](OS(O)(=O)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2.O[C@H]1[C@@H](N)[C@H](O)[C@@H](C)O[C@H]1O[C@H]1/C=C/C=C/C=C/C=C/C=C/C=C/C=C/[C@H](C)[C@@H](O)[C@@H](C)[C@H](C)OC(=O)C[C@H](O)C[C@H](O)CC[C@@H](O)[C@H](O)C[C@H](O)C[C@](O)(C[C@H](O)[C@H]2C(O)=O)O[C@H]2C1 PCTMTFRHKVHKIS-BMFZQQSSSA-N 0.000 description 12
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- 238000002360 preparation method Methods 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- SONHXMAHPHADTF-UHFFFAOYSA-M sodium;2-methylprop-2-enoate Chemical compound [Na+].CC(=C)C([O-])=O SONHXMAHPHADTF-UHFFFAOYSA-M 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 1
- 230000003655 tactile properties Effects 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/06—Materials undergoing a change of physical state when used the change of state being from liquid to solid or vice versa
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D20/00—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
- F28D20/02—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/24—Structural elements or technologies for improving thermal insulation
- Y02A30/244—Structural elements or technologies for improving thermal insulation using natural or recycled building materials, e.g. straw, wool, clay or used tires
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/14—Thermal energy storage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E70/00—Other energy conversion or management systems reducing GHG emissions
- Y02E70/30—Systems combining energy storage with energy generation of non-fossil origin
Definitions
- the present invention relates to a heat storage material composition and a heat storage system for heating and cooling of a building, and more particularly to a heat storage material composition suitable for a heat storage system for heating and cooling of a building and a heat storage system for heating and cooling of a building including the heat storage material composition.
- a latent heat storage material composition utilizing latent heat generated or absorbed at the time of a phase change from a liquid to a solid or a phase change from a solid to a liquid is known.
- the latent heat storage material composition is used, for example, in a heat storage system for heating and cooling a building.
- Latent heat storage material compositions generally have a large amount of heat storage, a melting point within a predetermined temperature range, long-term stability, low cost, non-toxicity, and tactile property. Characteristics such as absence are required.
- the latent heat storage material composition of the heat storage system for heating and cooling of buildings in addition to the entire latent heat of fusion H T to mean either be accumulated how much more heat per unit weight, absorption heat in a narrow temperature range It is required to dissipate heat.
- the entire latent heat of fusion H T is large, preferable because sufficient heat storage can be achieved with less amount. It is preferable that heat can be absorbed and dissipated in a narrow range because the latent heat of the material can be used in the target temperature range of the system without causing unnecessary heat absorption and heat dissipation.
- a 5 ° C. width melting latent heat H 5 is used as an index representing "characteristics capable of absorbing and radiating heat in a narrow temperature range”.
- 5 ° C width melting latent heat H 5 means "total amount of melting latent heat in a temperature range of 5 ° C", and when T is changed for the total amount Q 5 of melting latent heat in the temperature range from a certain temperature T to T + 5 ° C. It is defined as the maximum value of Q 5.
- the total latent heat of fusion H T is calculated from the peak area in the case of integrated by heat flow times measured by a differential scanning calorimeter (DSC).
- the latent heat of melting at 5 ° C. H 5 became the temperature T 1 + 5 ° C. from a certain moment (time t 1 , temperature T 1 ) in the heat flow measured by the differential scanning calorimeter (DSC).
- Time integration is performed up to the moment (time t 1 , temperature T 1 + 5), and the maximum value is derived.
- Figure 1 is a graph showing an example of the relationship between the temperature and the heat storage amount expressing latent heat of fusion of suitable latent heat storage material composition M A heat storage system for heating and cooling of buildings.
- Curve in FIG. 1 is a curve showing the preferred latent heat storage material composition M A heat storage system for heating and cooling of buildings.
- 2 is a graph showing an example of the relationship between the temperature and the heat storage amount expressing latent heat of fusion of not suitable for heat storage system for heating and cooling of buildings latent heat storage material composition M B.
- Curve in FIG. 2 is a curve showing the not suitable in the heat storage system for heating and cooling of buildings latent heat storage material composition M B.
- the temperature (melting point T m ) at which the latent heat storage material composition starts melting during heating is in the range of more than 15 ° C and less than 20 ° C, which is appropriate.
- the melting point T m is preferably in the range of 15 to 20 ° C. as shown in FIGS. 1 and 2.
- the latent heat storage material composition M A the melting point T m, the difference between the temperature (melting upper limit temperature T f) to exit the melt during heating is small, the melting maximum temperature T f is below 26 ° C.
- heat storage quantity expressed as the hatched area A 1 in FIG. 1, i.e. the heat storage material composition All of the heat storage amount originally possessed by the object can be used as cold heat.
- the latent heat storage material composition M A is, because it can exert all the heat storage amount inherent the cold, is suitable as a heat storage material composition of the heat storage system for cooling.
- the latent heat storage material composition M B as shown in FIG. 2, a large difference between the melting point T m and melting the upper limit temperature T f, the melting maximum temperature T f is higher than 26 ° C..
- the amount of heat stored in the temperature range from 26 ° C. to the upper melting limit temperature T f does not contribute to cooling. That is, in the latent heat storage material composition M B, if the external temperature exceeds 26 ° C., the heat storage amount shown in Fig. 2 as a hatched area A 2, i.e. only a portion of the heat storage amount with the heat storage material composition is originally only cold Cannot be used as.
- the latent heat storage material composition M B is not preferred as a heat storage material composition of the heat storage system for cooling.
- the heat storage material composition for a heat storage system for cooling is required to have a property of melting in a range of 15 to 20 ° C. and absorbing a large amount of heat in a narrow temperature range.
- 5 ° C. width latent heat of fusion H 5 as an index representing the "property of the heat absorbing large amounts of heat in a narrow temperature range" will be described with reference to FIGS.
- FIG. 3 is a diagram illustrating a 5 ° C. width melting latent heat H 5 of a latent heat storage material composition suitable for a heat storage system for heating and cooling of a building. Curve in FIG. 3 is a curve showing the preferred latent heat storage material composition M A heat storage system for heating and cooling of buildings.
- Figure 4 is a diagram for explaining a 5 ° C. width latent heat of fusion H 5 of the latent heat storage material composition is not suitable for heat storage system for heating and cooling of buildings.
- Curve in FIG. 4 is a curve showing the not suitable in the heat storage system for heating and cooling of buildings latent heat storage material composition M B.
- the 5 ° C. width latent heat of melting H 5 means "the total amount of latent heat of melting in the temperature range of 5 ° C.”
- T is changed for the total amount of latent heat of melting Q 5 in the temperature range from a certain temperature T to T + 5 ° C. It is defined as the maximum value of Q 5 when allowed to.
- the lower limit of the temperature at that time is defined as 5 ° C. width lower limit temperature T 5L
- the upper limit value is defined as 5 ° C. width lower limit temperature T 5H .
- the sum of the hatched areas A 1 in the latent heat storage material composition M A 3 is 5 ° C. width latent heat of fusion H 5. Since the peak of the sharp heat storage amount is present in the latent heat storage material composition M A in a narrow temperature range, resulting in 5 ° C. width latent heat of fusion H 5 indicates a large value. Similarly the sum of the shaded area A 2 in FIG. 4 also in the latent heat storage material composition M B is 5 ° C. width latent heat of fusion H 5. However, since the latent heat is gentle heat storage material composition M peak shape in B, 5 ° C. width latent heat of fusion H 5 indicates a small value.
- More heat storage material absorbs a large amount of heat at such a narrow temperature range, from 5 ° C. width latent heat of fusion H 5 to a larger value, 5 ° C. width latent heat of fusion H 5 absorbs the large amount of heat in the "narrow temperature range It can be used as an index of the characteristic of "doing".
- the phase change temperature of sodium sulfate decahydrate is about 32 ° C.
- the heat storage material composition of Patent Document 1 has a problem that the amount of heat storage is small.
- the latent heat of melting in a narrow temperature region is small because the latent heat generation region increases when water is added.
- An object of the present invention is to provide a heat storage material composition having a melting point in the range of 20 to 22.5 ° C. and a large latent heat of melting in a narrow temperature range, and a heat storage system for heating and cooling of a building.
- the heat storage material composition according to the first aspect of the present invention is composed of sodium sulfate tetrahydrate, disodium hydrogen phosphate dodecahydrate, sodium carbonate decahydrate, and trisodium phosphate dodecahydrate.
- the melting point is in the range of 20 to 22.5 ° C., and the latent heat of melting in the 5 ° C. width is 160 J / g or more.
- the heat storage material composition according to the second aspect of the present invention has a heat storage material composition according to the first aspect, wherein the content of the disodium phosphate dodecahydrate in the main agent is 4.5 to 5.
- the sodium sulfate 10 water in 100% by mass of the three-kind composition composed of the sodium sulfate decahydrate, the disodium hydrogen phosphate dodecahydrate, and the sodium carbonate decahydrate.
- the content of the Japanese product is defined as X mass%
- the content of the disodium hydrogen phosphate dodecahydrate is defined as Y mass%
- the content of the sodium carbonate decahydrate is defined as Z mass%
- X, Y and Z satisfy the following formulas (1-1) to (1-4).
- the content of the disodium phosphate dodecahydrate in the main agent is 7.0 to 8.
- the content of the Japanese product is defined as X mass%
- the content of the disodium hydrogen phosphate dodecahydrate is defined as Y mass%
- the content of the sodium carbonate decahydrate is defined as Z mass%
- X, Y and Z satisfy the following formulas (2-1) to (2-4).
- the heat storage material composition according to the fourth aspect of the present invention has a heat storage material composition according to the first aspect, wherein the content of the disodium phosphate dodecahydrate in the main agent is 9.5 to 10.
- the sodium sulfate 10 water in 100% by mass of the three-kind composition composed of the sodium sulfate decahydrate, the disodium hydrogen phosphate dodecahydrate, and the sodium carbonate decahydrate.
- the content of the Japanese product is defined as X mass%
- the content of the disodium hydrogen phosphate dodecahydrate is defined as Y mass%
- the content of the sodium carbonate decahydrate is defined as Z mass%
- X, Y and Z satisfy the following formulas (3-1) to (3-4).
- the heat storage material composition according to the fifth aspect of the present invention has a heat storage material composition according to the first aspect, wherein the content of the disodium phosphate dodecahydrate in the main agent is 14.5 to 15.
- the sodium sulfate 10 water in 100% by mass of the three-kind composition composed of the sodium sulfate decahydrate, the disodium hydrogen phosphate dodecahydrate, and the sodium carbonate decahydrate.
- the content of the Japanese product is defined as X mass%
- the content of the disodium hydrogen phosphate dodecahydrate is defined as Y mass%
- the content of the sodium carbonate decahydrate is defined as Z mass%
- X, Y and Z satisfy the following formulas (4-1) to (4-4).
- the content of the sodium sulfate decahydrate in 100% by mass of the main agent is X% by mass.
- the content of disodium hydrogen phosphate dodecahydrate is Y mass%
- the content of sodium carbonate decahydrate is Z mass%
- the content of trisodium phosphate dodecahydrate is W mass%.
- X, Y, Z, and W satisfy the following formulas (5-1) to (5-7).
- the heat storage material composition according to the seventh aspect of the present invention is an organic unsaturated carboxylic acid, an organic unsaturated sulfonic acid, and an organic unsaturated phosphoric acid in the heat storage material composition according to any one of the first to sixth aspects.
- the heat storage material composition according to the eighth aspect of the present invention is, in the heat storage material composition according to any one of the first to seventh aspects, sodium chloride, potassium chloride, sodium nitrate, sodium bromide, ammonium chloride, odor. It further comprises at least one melting point lowering agent selected from the group consisting of ammonium bromide, ammonium sulfate, ammonium nitrate, ammonium phosphate, and urea.
- Heat storage material composition according to the ninth aspect of the present invention is the heat storage material composition according to any of embodiments of the first to eighth, borax Na 2 B 4 O 5 (OH ) 4 ⁇ 8H 2 O, Calcium hydroxide, barium hydroxide, strontium hydroxide, aluminum hydroxide, graphite, aluminum, titanium dioxide, hectrite, smectite clay, bentonite, laponite, propylene glycol, ethylene glycol, glycerin, ethylenediamine tetraacetic acid, sodium alkyl sulfate, alkyl It further comprises at least one overcooling inhibitor selected from the group consisting of sodium phosphate, potassium alkyl sulfate, and potassium alkyl phosphate.
- the heat storage material composition according to the tenth aspect of the present invention is, in the heat storage material composition according to any one of the first to ninth aspects, sodium silicate, water glass, polyacrylic acid, sodium polyacrylate, poly. Carboxylate polyether polymer, sodium acrylate / maleic acid copolymer, sodium acrylate / sulfonic acid monomer copolymer, acrylamide / dimethylaminoethyl methacrylate dimethylsulfate copolymer, acrylamide / sodium acrylate copolymer , Polyethylene Glycol, Polypropylene Glycol, Highly Absorbent Resin (SAP), Carboxymethyl Cellulose (CMC), CMC Derivatives, Carrageenan, Caraginan Derivatives, Xanthan Gum, Xantan Gum Derivatives, Pectin, Pectin Derivatives, Steel, Steel Derivatives It further comprises at least one phase separation inhibitor selected from the group consisting of agar
- the heat storage system for heating and cooling a building according to the eleventh aspect of the present invention includes a heat storage material module using the heat storage material composition according to any one of the first to tenth aspects.
- the heat storage material composition according to the present embodiment contains a main agent composed of sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, sodium carbonate decahydrate, and trisodium phosphate dodecahydrate.
- a mixture consisting of sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, and sodium carbonate decahydrate in the main agent is also referred to as a three-kind composition.
- the main agent contains a predetermined amount of sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, sodium carbonate decahydrate, and trisodium phosphate dodecahydrate.
- the heat storage material composition according to the present embodiment may consist only of the main agent, but may further contain excess water if necessary.
- the heat storage material composition containing excess water in addition to this main agent will be described later.
- X, Y, and Z are the following formulas (1-1) to (1-4), (2-1) depending on the content of the trisodium phosphate dodecahydrate in the main agent. )-(2-4), (3-1)-(3-4), or (4-1)-(4-4) are preferably satisfied.
- X, Y, and Z are X mass% of the content of sodium sulfate decahydrate and Y mass% of the content of disodium hydrogen phosphate dodecahydrate in 100% by mass of the three kinds of compositions.
- the value when the content of sodium carbonate decahydrate is defined as Z mass%.
- X, Y, and Z are sodium sulfate pentahydrate, disodium hydrogen phosphate dodecahydrate, and sodium carbonate 10 in the three compositions obtained by removing trisodium phosphate dodecahydrate from the main agent.
- the content (% by mass) of each substance of hydrate is shown.
- FIG. 5 shows sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, and disodium hydrogen phosphate dodecahydrate in the three compositions when the content of trisodium phosphate dodecahydrate in the main agent is approximately 5% by mass. It is a ternary composition diagram of the content of sodium carbonate decahydrate.
- NS is 100% sodium sulfate decahydrate
- NH is 100% disodium hydrogen phosphate dodecahydrate
- NC 100% sodium carbonate decahydrate.
- Rectangle R 1 and therein shown in FIG. 5 is a range satisfying the above formula (1-1) to (1-4).
- FIG. 6 shows sodium sulfate tetrahydrate and disodium hydrogen phosphate dodecahydrate in the three compositions when the content of trisodium phosphate dodecahydrate in the main agent is approximately 7.5% by mass.
- NS, NH, and NC in FIG. 6 are the same as those in FIG.
- the rectangle R 2 shown in FIG. 6 and the inside thereof are in a range satisfying the above equations (2-1) to (2-4).
- FIG. 7 shows sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, and disodium hydrogen phosphate dodecahydrate in the three compositions when the content of trisodium phosphate dodecahydrate in the main agent is approximately 10% by mass. It is a ternary composition diagram of the content of sodium carbonate decahydrate. NS, NH, and NC in FIG. 7 are the same as those in FIG. Rectangular R 3 and inside 7 is a range satisfying the above formula (3-1) to (3-4).
- FIG. 8 shows sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, and disodium hydrogen phosphate dodecahydrate in the three compositions when the content of trisodium phosphate dodecahydrate in the main agent is approximately 15% by mass. It is a ternary composition diagram of the content of sodium carbonate decahydrate. NS, NH, and NC in FIG. 8 are the same as those in FIG. The rectangle R 4 shown in FIG. 8 and the inside thereof are in a range satisfying the above equations (4-1) to (4-4).
- X, Y, Z, and W satisfy the following formulas (5-1) to (5-7).
- the content of sodium sulfate decahydrate in 100% by mass of the main agent is X% by mass
- the content of disodium hydrogen phosphate dodecahydrate is Y% by mass
- It is a value when the content of sodium carbonate decahydrate is defined as Z mass%.
- W is a value when the content of trisodium phosphate dodecahydrate in 100% by mass of the main agent is defined as W% by mass.
- the melting point of the heat storage material composition is in the range of 20 to 22.5 ° C.
- Latent heat for melting at 5 ° C. tends to be 160 J / g or more.
- FIG. 9 is a quaternary composition diagram of the contents of sodium sulfate tetrahydrate, disodium hydrogen phosphate dodecahydrate, sodium carbonate decahydrate, and trisodium phosphate dodecahydrate in the main agent.
- FIG. 9 is a diagram showing a three-dimensional region Q satisfying equations (5-1) to (5-7).
- the three-dimensional region Q is a region satisfying equations (5-1) to (5-7).
- NS, NH, and NC are the same as in FIG. 5, and NP indicates that trisodium phosphate dodecahydrate is 100%.
- FIG. 10 is an enlarged view of the region Q in FIG.
- the region Q is a pentagonal columnar region, and has a shape in which a pentagonal plane FBCON and a plane EADPM arranged opposite to each other are surrounded by a plane ABCD, a plane DCOP, a plane MNOP, a plane EFNM, and a plane ABFE.
- the plane EFGH and the plane IJKL shown in FIG. 10 are both parallel to the plane ABCD and the plane MNOP.
- Planar ABCDs are sodium sulfate tetrahydrate, disodium hydrogen phosphate dodecahydrate, and sodium carbonate tetrahydrate when the content of trisodium phosphate dodecahydrate in the main agent is approximately 5% by mass. It is a plane in which a ternary composition diagram of the content of is present.
- Plane EFGH refers to sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, and sodium carbonate 10 water when the content of trisodium phosphate dodecahydrate in the main agent is approximately 7.5% by mass. It is a plane in which a ternary composition diagram of the content of Japanese products exists.
- Plane IJKL is a sodium sulfate tetrahydrate, a disodium hydrogen phosphate dodecahydrate, and a sodium carbonate decahydrate when the content of trisodium phosphate dodecahydrate in the main agent is approximately 10% by mass. It is a plane in which a ternary composition diagram of the content of is present.
- Planar MNOPs are sodium sulfate tetrahydrate, disodium hydrogen phosphate dodecahydrate, and sodium carbonate tetrahydrate when the content of trisodium phosphate dodecahydrate in the main agent is approximately 15% by mass. It is a plane in which a ternary composition diagram of the content of is present.
- FIG. 11 is a diagram showing only the plots on substantially the same plane as the plane ABCD of FIG. 10 among all the plots of FIG. Specifically, FIG. 11 is a diagram when the region Q is viewed from the point NP of FIG. 9 only for the plots that are substantially on the same plane as the plane ABCD of FIG. 10 among all the plots shown in FIG.
- FIG. 12 is a diagram showing only plots that are substantially on the same plane as the plane EFGH of FIG. 10 among all the plots of FIG. Specifically, FIG. 12 is a diagram when the region Q is viewed from the point NP of FIG. 9 only for the plots that are substantially on the same plane as the plane EFGH of FIG. 10 among all the plots shown in FIG.
- FIG. 13 is a diagram showing only the plots that are substantially on the same plane as the plane IJKL of FIG. 10 among all the plots of FIG. Specifically, FIG. 13 is a diagram when the area Q is viewed from the point NP of FIG. 9 only for the plots that are substantially on the same plane as the plane IJKL of FIG. 10 among all the plots shown in FIG.
- FIG. 14 is a diagram showing only the plots that are substantially on the same plane as the plane MNOP of FIG. 10 among all the plots of FIG. Specifically, FIG. 14 is a diagram when the region Q is viewed from the point NP of FIG. 9 only for the plots that are substantially on the same plane as the plane MNOP of FIG. 10 among all the plots shown in FIG.
- the heat storage material composition according to the present embodiment may further contain excess water, if necessary.
- a mixture consisting of a main agent and excess water is defined as a main agent mixture.
- excess water is usually contained in an amount of 9 parts by mass or less, preferably 3 parts by mass or less, based on 100 parts by mass of the main agent.
- the melting point of the heat storage material composition tends to be in the range of 20 to 22.5 ° C., and the latent heat of melting in a width of 5 ° C. is 160J. It tends to be / g or more. If the content of excess water in the heat storage material composition according to the present embodiment exceeds 9 parts by mass, the heat storage amount of the heat storage material composition may decrease.
- the heat storage material composition according to the present embodiment further contains a specific moisturizer because the main agent is stored under moisturizer.
- a specific moisturizer is obtained by polymerizing a specific monomer and a polyfunctional monomer.
- Specific monomers include organic unsaturated carboxylic acids, organic unsaturated sulfonic acids, organic unsaturated phosphates, organic unsaturated amides, organic unsaturated alcohols, organic unsaturated carboxylic acids, and organic unsaturated sulfonic acids. And at least one monomer selected from the group consisting of organic unsaturated phosphates is used.
- organic unsaturated carboxylic acid for example, one or more unsaturated carboxylic acids selected from the group consisting of acrylic acid, methacrylic acid and itaconic acid are used, and acrylic acid is preferably used.
- the organic unsaturated sulfonic acid is, for example, one or more selected from the group consisting of 2-acrylamide-2-methylpropanesulfonic acid, p-styrenesulfonic acid, sulfoethylmethacrylate, allylsulfonic acid and metaallylsulfonic acid.
- Organic unsaturated sulfonic acid is used.
- organic unsaturated carboxylic acid salt for example, an alkali metal salt or an ammonium salt of the above unsaturated carboxylic acid is used.
- alkali metal salt of the unsaturated carboxylic acid for example, the sodium salt of the unsaturated carboxylic acid is used.
- sodium salt of the unsaturated carboxylic acid sodium acrylate and sodium methacrylate are preferably used.
- organic unsaturated sulfonic acid salt for example, an alkali metal salt or an ammonium salt of the above organic unsaturated sulfonic acid is used.
- alkali metal salt of the organic unsaturated sulfonic acid for example, the sodium salt of the organic unsaturated sulfonic acid is used.
- the polyfunctional monomer crosslinks a polymer obtained by polymerizing a specific monomer.
- the polyfunctional monomer include N, N'-methylenebisacrylamide, N, N'-methylenebismethacrylamide, N, N'-dimethylenebisacrylamide, N, N'-dimethylenebismethacrylate. Is used, preferably N, N'-methylenebisacrylamide or N, N'-methylenebismethacrylamide is used.
- the heat storage material composition according to the present embodiment further contains a specific melting point lowering agent because the melting point of the main agent is lowered.
- a specific melting point lowering agent for example, at least one melting point selected from the group consisting of sodium chloride, potassium chloride, sodium nitrate, sodium bromide, ammonium chloride, ammonium bromide, ammonium sulfate, ammonium nitrate, ammonium phosphate, and urea.
- a lowering agent is used.
- the heat storage material composition according to the present embodiment further contains a specific supercooling inhibitor because the supercooling of the main agent is suppressed.
- the supercooling inhibitor for example, borax Na 2 B 4 O 5 (OH ) 4 ⁇ 8H 2 O, calcium hydroxide, barium hydroxide, strontium hydroxide, aluminum hydroxide, graphite, aluminum, titanium dioxide, Silicon, sodium dodecyl phosphate, sodium dodecyl sulfate, sodium carboxymethyl cellulose, lignin sulfonic acid, hectrite, smectite clay, bentonite, laponite, propylene glycol, ethylene glycol, glycerin, ethylenediamine tetraacetic acid, sodium alkylsulfate, sodium alkylphosphate, At least one supercooling inhibitor selected from the group consisting of potassium alkyl sulfate and potassium alkyl phosphate is used.
- the heat storage material composition according to the present embodiment further contains a specific phase separation inhibitor because the phase separation of the main agent is suppressed.
- the phase separation inhibitor include sodium silicate, water glass, polyacrylic acid, sodium polyacrylate, polycarboxylate polyether polymer, acrylic acid / maleic acid copolymer sodium, and acrylic acid / sulfonic acid-based monomer.
- a phase separation inhibitor is used.
- the heat storage material composition according to the present embodiment has a melting point in the range of 20 to 22.5 ° C., and melting and solidification occur in a temperature range slightly lower than the general set temperature for heating and cooling of buildings. Further, the heat storage material composition according to the present embodiment has a latent heat of melting at a width of 5 ° C. of 160 J / g or more, and the latent heat of melting in a narrow temperature region is large. Therefore, the heat storage material composition according to the present embodiment is suitable as a latent heat storage material composition for a heat storage system for heating and cooling a building.
- the heat storage material composition according to the present embodiment has a 5 ° C. width melting latent heat of 160 J / g or more, preferably 170 to 220 J / g, more preferably 180 to 220 J / g, still more preferably 190 to 220 J / g, and particularly preferably. Is 200 to 220 J / g. Therefore, the heat storage material composition according to the present embodiment is suitable as a latent heat storage material composition for a heat storage system for heating and cooling a building.
- a heat storage material composition having a melting point in the range of 20 to 22.5 ° C. and a latent heat of melting in a width of 5 ° C. of 160 J / g or more can be obtained.
- the heat storage system for heating and cooling a building according to the present embodiment includes a heat storage material module using the heat storage material composition according to the present embodiment.
- the heat storage material module is composed of, for example, a heat storage material pack in which the heat storage material composition is filled in a container having sufficient sealing property, and one or more of the heat storage material packs are laminated and an appropriate flow path is provided. Modular ones are used. Examples of the container used for the heat storage material pack include an aluminum pack formed by heat-welding an aluminum pack sheet formed by laminating a resin sheet on an aluminum sheet.
- the heat storage module is installed on at least a part of the floor, wall surface, and ceiling surface that divides the space in the building.
- the heat storage material module installed in this way is stored (cold) by heat exchange between the module surface and the atmosphere that ventilates the module surface, solar heat by solar radiation, and an air conditioning system that uses nighttime power.
- the heat storage material composition in the heat storage material module is melted by the heat obtained from the space in the building, and the enthalpy corresponding to the heat is retained inside the heat storage material composition.
- the melted heat storage material composition solidifies and releases heat to the space inside the building.
- the heat storage material module is installed in the building in this way, the energy load for heating and cooling can be reduced by the action of melting and solidifying the heat storage material composition.
- heat storage material system According to the heat storage material system according to the present embodiment, heat is stored (cooled) by heat exchange between the module surface and the atmosphere in which the module surface is ventilated, solar heat by solar radiation, an air conditioning system using nighttime power, and the like.
- the energy load for can be reduced.
- Example 1 (When the content of trisodium phosphate dodecahydrate is approximately 5% by mass) (Preparation of heat storage material composition) First, Na 2 SO 4 ⁇ 10H 2 O (manufactured by Kishida Chemical Co., Ltd., special grade), Na 2 HPO 4 ⁇ 12H 2 O (manufactured by Kishida Chemical Co., Ltd., special grade), and Na 2 CO 3 ⁇ 10H 2 O (Kishida) Made by Chemical Co., Ltd., special grade) was prepared. Further, Na 3 PO 4 ⁇ 12H 2 O ( Kishida Chemical Co., Ltd., special grade) were also prepared.
- Heat storage material composition the content of Na 3 PO 4 ⁇ 12H 2 O in the main agent was prepared so as to be approximately 5% by weight.
- a heat storage material composition was obtained (Sample No. A6).
- Table 1 also shows the calculation results of the left sides of the following formulas (5-2) to (5-7) and the satisfiability of the following formulas (5-1) to (5-7).
- sample No. A6 satisfies the following equation (5-1).
- Table 1 the case where the data satisfies the following equations (5-1) to (5-7) is indicated by ⁇ , and the case where the data is not satisfied is indicated by ⁇ .
- Examples 2 to 15, Comparative Examples 1 to 5 when the content of trisodium phosphate dodecahydrate is approximately 5% by mass
- a heat storage material composition was obtained in the same manner as in Example 1 except that the blending amount of each component was changed so that the obtained heat storage material composition had the composition shown in Table 1 (Sample Nos. A1 to A5 (Comparison). Examples 1 to 5), A7 to A20 (Examples 2 to 15)).
- Heat storage material composition, the content of Na 3 PO 4 ⁇ 12H 2 O in the main agent was prepared so as to be approximately 5% by weight.
- FIG. 5 shows sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, and disodium hydrogen phosphate dodecahydrate in the three compositions when the content of trisodium phosphate dodecahydrate in the main agent is approximately 5% by mass. It is a ternary composition diagram of the content of sodium carbonate decahydrate.
- Sample No. of Example 1. Sample No. including A6. The compositions of the three compositions constituting the main component of the heat storage material compositions A1 to A20 are plotted in FIG. In FIG. 5, the sample No. The plots of the heat storage material compositions of A6 to A20 are indicated by symbols ⁇ . In addition, sample No.
- the plots of the heat storage material compositions of A1 to A5 are indicated by the symbol x.
- the rectangular region R 1 is a region satisfying the above equations (1-1) to (1-4).
- A6 ⁇ A20 are present within a rectangular region R 1.
- Examples 16 to 33, Comparative Examples 6 to 12 (when the content of trisodium phosphate dodecahydrate is approximately 7.5% by mass) Heat storage material compositions were obtained in the same manner as in Example 1 except that the blending amount of each component was changed so that the obtained heat storage material composition had the composition shown in Table 2 (Sample Nos. B1 to B7 (Comparison). Examples 6 to 12), No. B8 to B25 (Examples 16 to 33)). Heat storage material composition, the content of Na 3 PO 4 ⁇ 12H 2 O in the main agent was prepared so as to be approximately 7.5 wt%.
- Table 2 also shows the calculation results of the left sides of the above formulas (5-2) to (5-7) and the sufficiency of the above formulas (5-1) to (5-7).
- sample No. B1 to B25 satisfy the above formula (5-1).
- Table 2 the case where the data satisfies the above equations (5-1) to (5-7) is indicated by ⁇ , and the case where the data is not satisfied is indicated by ⁇ .
- FIG. 6 shows sodium sulfate tetrahydrate and disodium hydrogen phosphate dodecahydrate in the three compositions when the content of trisodium phosphate dodecahydrate in the main agent is approximately 7.5% by mass.
- a ternary composition diagram of the content of sodium carbonate decahydrate Sample No. The compositions of the three compositions constituting the main component of the heat storage material compositions of B1 to B25 are plotted in FIG. In FIG. 6, sample No. The plots of the heat storage material compositions of B8 to B25 are indicated by symbols ⁇ . In addition, sample No. The plots of the heat storage material compositions of B1 to B7 are indicated by the symbol x.
- the rectangular region R 2 is a region satisfying the above equations (2-1) to (2-4). Sample No. indicated by the symbol ⁇ . B8 ⁇ B25 is present in a rectangular region R 2.
- Examples 34 to 55 Comparative Examples 13 to 23 (when the content of trisodium phosphate dodecahydrate is approximately 10% by mass)
- a heat storage material composition was obtained in the same manner as in Example 1 except that the blending amount of each component was changed so that the obtained heat storage material composition had the compositions shown in Tables 3 and 4 (Sample Nos. C1 to C1).
- C11 Comparative Examples 13 to 23
- Sample Nos. C12 to C33 Examples 34 to 55
- Heat storage material composition the content of Na 3 PO 4 ⁇ 12H 2 O in the main agent was prepared so as to be approximately 10 wt%.
- Tables 3 and 4 also show the calculation results of the left sides of the above formulas (5-2) to (5-7) and the satisfiability of the above formulas (5-1) to (5-7). ..
- sample No. C1 to C33 satisfy the above formula (5-1).
- Tables 3 and 4 the cases where the data satisfy the above equations (5-1) to (5-7) are indicated by ⁇ , and the cases where the data are not satisfied are indicated by ⁇ .
- FIG. 7 shows sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, and disodium hydrogen phosphate dodecahydrate in the three compositions when the content of trisodium phosphate dodecahydrate in the main agent is approximately 10% by mass. It is a ternary composition diagram of the content of sodium carbonate decahydrate.
- Sample No. The compositions of the three compositions constituting the main component of the heat storage material compositions of C1 to C33 are plotted in FIG. In FIG. 7, the sample No.
- the plots of the heat storage material compositions of C12 to C33 are indicated by symbols ⁇ .
- the plots of the heat storage material compositions of C1 to C11 are indicated by the symbol x. 7, the rectangular area R 3 is an area that satisfies the above formula (3-1) to (3-4). Sample No. indicated by the symbol ⁇ . C12 ⁇ C33 are present within a rectangular area R 3.
- Table 3 samples there from Table 4 and FIG. 7, the outer region R 3 in FIG. 7 No. It was found that at least one of the melting point and the latent heat of melting at 5 ° C. was not good for C1 to C11.
- Examples 56 to 62, Comparative Examples 24 to 33 (when the content of trisodium phosphate dodecahydrate is approximately 15% by mass) Heat storage material compositions were obtained in the same manner as in Example 1 except that the blending amount of each component was changed so that the obtained heat storage material composition had the composition shown in Table 5 (Sample Nos. D1 to D10 (Comparison). Examples 24 to 33), Sample Nos. D11 to D17 (Examples 56 to 62)). Heat storage material composition, the content of Na 3 PO 4 ⁇ 12H 2 O in the main agent was prepared so as to be approximately 15 wt%.
- Table 5 also shows the calculation results of the left sides of the above formulas (5-2) to (5-7) and the satisfiability of the above formulas (5-1) to (5-7).
- sample No. D1 to D17 satisfy the above formula (5-1).
- Table 5 the case where the data satisfies the above equations (5-1) to (5-7) is indicated by ⁇ , and the case where the data is not satisfied is indicated by ⁇ .
- FIG. 8 shows sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, and disodium hydrogen phosphate dodecahydrate in the three compositions when the content of trisodium phosphate dodecahydrate in the main agent is approximately 15% by mass. It is a ternary composition diagram of the content of sodium carbonate decahydrate.
- Sample No. The compositions of the three compositions constituting the main component of the heat storage material compositions D1 to D17 are plotted in FIG. In FIG. 8, the sample No. The plots of the heat storage material compositions of D11 to D17 are indicated by symbols ⁇ . In addition, sample No. The plots of the heat storage material compositions of D1 to D10 are indicated by the symbol x. 8, a rectangular area R 4 is a region that satisfies the above formula (4-1) to (4-4). Sample No. indicated by the symbol ⁇ . D11 ⁇ D17 are present in the rectangular area R 4.
- the sample in the region R 4 in FIG. 8 No. It was found that D11 to D17 had good melting points and latent heat of melting at a width of 5 ° C. Specifically, the sample No. It was found that the heat storage material compositions of D11 to D17 had a melting point in the range of 20 to 22.5 ° C. and a latent heat of melting in a width of 5 ° C. of 160 J / g or more.
- FIG. 9 is a quaternary composition diagram of the contents of sodium sulfate tetrahydrate, disodium hydrogen phosphate dodecahydrate, sodium carbonate decahydrate, and trisodium phosphate dodecahydrate in the main agent.
- FIG. 9 shows the sample No.
- the compositions of sodium sulfate decahydrate, trisodium phosphate dodecahydrate, etc. in the main agent are shown in the quaternary composition diagram. is there.
- NS, NH, and NC are the same as in FIG.
- NP indicates that trisodium phosphate dodecahydrate is 100%. Further, in Tables 1 to 5, the sample having the “symbol in the figure” of ⁇ was plotted as ⁇ in FIG. 11, and the sample having the “symbol in the figure” of ⁇ in Tables 1 to 5 was plotted as ⁇ in FIG.
- the three-dimensional region substantially satisfying the equations (5-1) to (5-7) is shown as Q.
- the three-dimensional region Q is a region that substantially satisfies the equations (5-1) to (5-7).
- Sample No. It can be seen that among A1 to A20, B1 to B25, C1 to C33, and D1 to D17, the samples plotted with ⁇ exist within the range of region Q. Specifically, it can be seen that Examples 1 to 62 exist within the range of region Q.
- FIG. 10 is an enlarged view of the region Q in FIG.
- the region Q is a pentagonal columnar region, and has a shape in which a pentagonal plane FBCON and a plane EADPM arranged opposite to each other are surrounded by a plane ABCD, a plane DCOP, a plane MNOP, a plane EFNM, and a plane ABFE.
- the plane EFGH and the plane IJKL shown in FIG. 10 are both parallel to the plane ABCD and the plane MNOP.
- the plane ABCD is a plane composed of a collection of data in which the content of trisodium phosphate 12hydrate in the main agent is approximately 5% by mass, in the vertical direction from the point NP in FIG. 9 to the plane NS-NC-NH. It is a plane that is observed when viewed from.
- the plane EFGH is a plane composed of a collection of data in which the content of trisodium phosphate 12hydrate in the main agent is approximately 7.5% by mass, from the point NP in FIG. 9 to the plane NS-NC-NH. It is a plane observed when viewed in the vertical direction.
- the plane IJKL is a plane composed of a collection of data in which the content of trisodium phosphate 12hydrate in the main agent is approximately 10% by mass in the vertical direction from the point NP in FIG. 9 to the plane NS-NC-NH. It is a plane that is observed when viewed from.
- the plane MNOP is a plane composed of a collection of data in which the content of trisodium phosphate 12hydrate in the main agent is approximately 15% by mass in the vertical direction from the point NP in FIG. 9 to the plane NS-NC-NH. It is a plane that is observed when viewed from.
- Examples 1 to 62 exist within the range of the region Q shown in FIGS. 9 and 10.
- FIG. 11 is a diagram showing only the plots in substantially the same plane as the plane ABCD of FIG. 10 among all the plots of FIG. Specifically, the sample No. It is a plot of A1 to A20.
- the plane ABCD in FIG. 11 corresponds to the plane ABCD in FIG. Region R 5 in the plane ABCD in FIG. 11 is a region satisfying the equation (1-1) to (1-4). Sample No. Samples plotted in ⁇ Of A1 ⁇ A20 are included in the region R 5.
- FIG. 12 is a diagram showing only the plots in substantially the same plane as the plane EFGH of FIG. 10 among all the plots of FIG. Specifically, the sample No. It is a plot of B1 to B25.
- the plane EFGH in FIG. 12 corresponds to the plane EFGH in FIG.
- the region R 6 in the plane EFGH in FIG. 12 is a region satisfying equations (2-1) to (2-4). Sample No. Samples plotted in ⁇ Among B1 ⁇ B25 are included in the region R 6.
- FIG. 13 is a diagram showing only the plots in substantially the same plane as the plane IJKL of FIG. 10 among all the plots of FIG. Specifically, the sample No. It is a plot of C1 to C33.
- the plane IJKL in FIG. 13 corresponds to the plane IJKL in FIG.
- the region R 7 in the plane IJKL in FIG. 13 is a region satisfying equations (3-1) to (3-4). Sample No. Samples plotted in ⁇ Of C1 ⁇ C33 are included in the region R 7.
- FIG. 14 is a diagram showing only plots that are substantially in the same plane as the plane MNOP of FIG. 10 among all the plots of FIG. Specifically, the sample No. It is a plot of D1 to D17.
- the plane MNOP in FIG. 14 corresponds to the plane MNOP in FIG.
- the region R 8 in the plane MNOP in FIG. 14 is a region satisfying equations (4-1) to (4-4). Sample No. Samples plotted in ⁇ among D1 ⁇ D17 are included in the region R 8.
- the heat storage material composition having a melting point in the range of 20 to 22.5 ° C. and a large latent heat of melting in a narrow temperature range and a heat storage system for heating and cooling of a building. Can be provided.
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Abstract
A heat storage material composition according to the present invention contains a main component constituted by sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, sodium carbonate decahydrate, and trisodium phosphate dodecahydrate, and has a melting point in a range of 20–22.5°C and a latent heat of fusion of at least 160 J/g in a 5°C range. A heat storage system according to the present invention is provided with a heat storage material module that uses the heat storage material composition. The heat storage material composition preferably further contains a humectant obtained by polymerizing a polyfunctional monomer and at least one type of monomer selected from the group consisting of organic unsaturated carboxylic acids, organic unsaturated sulfonic acids, organic unsaturated phosphoric acids, organic unsaturated amides, organic unsaturated alcohols, organic unsaturated carboxylates, organic unsaturated sulfonates, and organic unsaturated phosphates.
Description
本発明は、蓄熱材組成物及び建築物の冷暖房用の蓄熱システムに関し、詳しくは、建造物の冷暖房の蓄熱システムに好適な蓄熱材組成物及びこれを含む建築物の冷暖房用の蓄熱システムに関する。
The present invention relates to a heat storage material composition and a heat storage system for heating and cooling of a building, and more particularly to a heat storage material composition suitable for a heat storage system for heating and cooling of a building and a heat storage system for heating and cooling of a building including the heat storage material composition.
従来、液体から固体への相変化時や固体から液体への相変化時に発生又は吸収する潜熱を利用した潜熱蓄熱材組成物が知られている。潜熱蓄熱材組成物は、例えば、建造物の冷暖房の蓄熱システムに用いられる。
Conventionally, a latent heat storage material composition utilizing latent heat generated or absorbed at the time of a phase change from a liquid to a solid or a phase change from a solid to a liquid is known. The latent heat storage material composition is used, for example, in a heat storage system for heating and cooling a building.
潜熱蓄熱材組成物には、一般的に、蓄熱量が大きいこと、融点が所定の温度領域内にあること、長期間安定であること、安価であること、毒性がないこと、腐触性がないこと等の特性が要求される。
Latent heat storage material compositions generally have a large amount of heat storage, a melting point within a predetermined temperature range, long-term stability, low cost, non-toxicity, and tactile property. Characteristics such as absence are required.
建造物の冷暖房用の蓄熱システム用の潜熱蓄熱材組成物には、単位重量当たりにどれだけ多くの熱を貯められるかを意味する全体融解潜熱ＨＴに加えて、狭い温度範囲で熱を吸放熱することが求められる。全体融解潜熱ＨＴが大きいと、少ない量で充分な蓄熱が達成できるため好ましい。狭い範囲で熱を吸放熱できると、無駄な吸放熱を起こすことなく、材料の持つ潜熱をシステムの目的とする温度範囲にて利用できるため好ましい。
The latent heat storage material composition of the heat storage system for heating and cooling of buildings, in addition to the entire latent heat of fusion H T to mean either be accumulated how much more heat per unit weight, absorption heat in a narrow temperature range It is required to dissipate heat. When the entire latent heat of fusion H T is large, preferable because sufficient heat storage can be achieved with less amount. It is preferable that heat can be absorbed and dissipated in a narrow range because the latent heat of the material can be used in the target temperature range of the system without causing unnecessary heat absorption and heat dissipation.
「狭い温度範囲で熱を吸放熱できる特性」を表す指標として例えば５℃幅融解潜熱Ｈ５が用いられる。５℃幅融解潜熱Ｈ５とは「５℃の温度幅での融解潜熱の総量」を意味し、ある温度ＴからＴ＋５℃の温度範囲における融解潜熱の総量Ｑ５について、Ｔを変化させた際のＱ５の最大値として定義される。
For example, a 5 ° C. width melting latent heat H 5 is used as an index representing "characteristics capable of absorbing and radiating heat in a narrow temperature range". 5 ° C width melting latent heat H 5 means "total amount of melting latent heat in a temperature range of 5 ° C", and when T is changed for the total amount Q 5 of melting latent heat in the temperature range from a certain temperature T to T + 5 ° C. It is defined as the maximum value of Q 5.
上記全体融解潜熱ＨＴは、示差走査熱量計（ＤＳＣ）にて測定されるヒートフローを時間で積分した場合のピーク面積から算出される。これに対し、５℃幅融解潜熱Ｈ５は、同様に示差走査熱量計（ＤＳＣ）にて測定されるヒートフローをある瞬間（時間ｔ１,温度Ｔ１）から温度Ｔ１＋５℃となった瞬間（時間ｔ１,温度Ｔ１＋５）まで時間積分し、その最大値として導出される。
The total latent heat of fusion H T is calculated from the peak area in the case of integrated by heat flow times measured by a differential scanning calorimeter (DSC). On the other hand, the latent heat of melting at 5 ° C. H 5 became the temperature T 1 + 5 ° C. from a certain moment (time t 1 , temperature T 1 ) in the heat flow measured by the differential scanning calorimeter (DSC). Time integration is performed up to the moment (time t 1 , temperature T 1 + 5), and the maximum value is derived.
図１は、建造物の冷暖房用の蓄熱システムに好適な潜熱蓄熱材組成物ＭＡにおける融解潜熱を発現する温度と蓄熱量との関係の一例を示すグラフである。図１中の曲線は、建造物の冷暖房用の蓄熱システムに好適な潜熱蓄熱材組成物ＭＡの示す曲線である。また、図２は、建造物の冷暖房用の蓄熱システムに好適でない潜熱蓄熱材組成物ＭＢにおける融解潜熱を発現する温度と蓄熱量との関係の一例を示すグラフである。図２中の曲線は、建造物の冷暖房用の蓄熱システムに好適でない潜熱蓄熱材組成物ＭＢの示す曲線である。
Figure 1 is a graph showing an example of the relationship between the temperature and the heat storage amount expressing latent heat of fusion of suitable latent heat storage material composition M A heat storage system for heating and cooling of buildings. Curve in FIG. 1 is a curve showing the preferred latent heat storage material composition M A heat storage system for heating and cooling of buildings. 2 is a graph showing an example of the relationship between the temperature and the heat storage amount expressing latent heat of fusion of not suitable for heat storage system for heating and cooling of buildings latent heat storage material composition M B. Curve in FIG. 2 is a curve showing the not suitable in the heat storage system for heating and cooling of buildings latent heat storage material composition M B.
図１及び図２に示す例では、加熱時に潜熱蓄熱材組成物が融解を開始する温度（融点Ｔm）は、１５℃を超え２０℃未満の範囲内にあり、適切である。なお、潜熱蓄熱材組成物が建造物の冷暖房の蓄熱システムに用いられる場合、潜熱蓄熱材組成物の融解下限温度が低すぎると蓄熱材を凝固させて、冷熱を貯めることが困難となる。また、潜熱蓄熱材組成物の融解下限温度が高すぎると、外気との熱の交換効率が悪くなる。したがって、潜熱蓄熱材組成物が建造物の冷暖房の蓄熱システムに用いられる場合、図１及び図２に示すように、融点Ｔmは１５～２０℃の範囲にあることが好ましい。
In the examples shown in FIGS. 1 and 2, the temperature (melting point T m ) at which the latent heat storage material composition starts melting during heating is in the range of more than 15 ° C and less than 20 ° C, which is appropriate. When the latent heat storage material composition is used in a heat storage system for heating and cooling of a building, if the lower limit temperature of melting of the latent heat storage material composition is too low, the heat storage material is solidified and it becomes difficult to store cold heat. Further, if the lower limit temperature of melting of the latent heat storage material composition is too high, the efficiency of heat exchange with the outside air deteriorates. Therefore, when the latent heat storage material composition is used in a heat storage system for heating and cooling a building, the melting point T m is preferably in the range of 15 to 20 ° C. as shown in FIGS. 1 and 2.
具体的には、図１に示すように、潜熱蓄熱材組成物ＭＡでは、融点Ｔmと、加熱時に融解を終了する温度（融解上限温度Ｔｆ）との差が小さく、融解上限温度Ｔｆが２６℃未満にある。このような場合、外部の雰囲気温度が融解上限温度Ｔｆをわずかに上回る温度（例えば２６℃）となった場合でも、図１中に斜線領域Ａ１として表される蓄熱量、すなわち蓄熱材組成物が本来有する蓄熱量の全て、を冷熱として用いることができる。このように潜熱蓄熱材組成物ＭＡは、本来有する蓄熱量の全てを冷熱として発揮できるため、冷房用の蓄熱システム用の蓄熱材組成物として好適である。
Specifically, as shown in FIG. 1, the latent heat storage material composition M A, the melting point T m, the difference between the temperature (melting upper limit temperature T f) to exit the melt during heating is small, the melting maximum temperature T f is below 26 ° C. In this case, even when the external atmospheric temperature becomes melting the upper limit temperature T f slightly greater than the temperature (e.g. 26 ° C.), heat storage quantity, expressed as the hatched area A 1 in FIG. 1, i.e. the heat storage material composition All of the heat storage amount originally possessed by the object can be used as cold heat. Thus the latent heat storage material composition M A is, because it can exert all the heat storage amount inherent the cold, is suitable as a heat storage material composition of the heat storage system for cooling.
一方、図２に示すように潜熱蓄熱材組成物ＭＢでは、融点Ｔmと融解上限温度Ｔｆとの差異が大きく、融解上限温度Ｔｆが２６℃を超える。この場合、上述と同様に外部の雰囲気温度が２６℃となったとき、２６℃から融解上限温度Ｔｆまでの温度範囲での蓄熱量は、冷房に寄与しないこととなる。すなわち、潜熱蓄熱材組成物ＭBでは、外部温度が２６℃を超える場合、図２に斜線領域Ａ２として示される蓄熱量、すなわち蓄熱材組成物が本来有する蓄熱量の一部のみ、しか冷熱として用いることができない。このように潜熱蓄熱材組成物ＭＢは、冷房用の蓄熱システム用の蓄熱材組成物として好ましくない。
On the other hand, the latent heat storage material composition M B as shown in FIG. 2, a large difference between the melting point T m and melting the upper limit temperature T f, the melting maximum temperature T f is higher than 26 ° C.. In this case, when the external ambient temperature reaches 26 ° C. as described above, the amount of heat stored in the temperature range from 26 ° C. to the upper melting limit temperature T f does not contribute to cooling. That is, in the latent heat storage material composition M B, if the external temperature exceeds 26 ° C., the heat storage amount shown in Fig. 2 as a hatched area A 2, i.e. only a portion of the heat storage amount with the heat storage material composition is originally only cold Cannot be used as. Thus the latent heat storage material composition M B is not preferred as a heat storage material composition of the heat storage system for cooling.
このように冷房用の蓄熱システム用の蓄熱材組成物は、１５～２０℃の範囲にて融解し、かつ狭い温度範囲で多量の熱を吸熱する特性が求められる。ここで、「狭い温度範囲で多量の熱を吸熱する特性」を表す指標としての５℃幅融解潜熱Ｈ５について、図３及び図４を用いて説明する。図３は、建造物の冷暖房用の蓄熱システムに好適な潜熱蓄熱材組成物の５℃幅融解潜熱Ｈ５を説明する図である。図３中の曲線は、建造物の冷暖房用の蓄熱システムに好適な潜熱蓄熱材組成物ＭＡの示す曲線である。図４は、建造物の冷暖房用の蓄熱システムに好適でない潜熱蓄熱材組成物の５℃幅融解潜熱Ｈ５を説明する図である。図４中の曲線は、建造物の冷暖房用の蓄熱システムに好適でない潜熱蓄熱材組成物ＭＢの示す曲線である。
As described above, the heat storage material composition for a heat storage system for cooling is required to have a property of melting in a range of 15 to 20 ° C. and absorbing a large amount of heat in a narrow temperature range. Here, 5 ° C. width latent heat of fusion H 5 as an index representing the "property of the heat absorbing large amounts of heat in a narrow temperature range" will be described with reference to FIGS. FIG. 3 is a diagram illustrating a 5 ° C. width melting latent heat H 5 of a latent heat storage material composition suitable for a heat storage system for heating and cooling of a building. Curve in FIG. 3 is a curve showing the preferred latent heat storage material composition M A heat storage system for heating and cooling of buildings. Figure 4 is a diagram for explaining a 5 ° C. width latent heat of fusion H 5 of the latent heat storage material composition is not suitable for heat storage system for heating and cooling of buildings. Curve in FIG. 4 is a curve showing the not suitable in the heat storage system for heating and cooling of buildings latent heat storage material composition M B.
５℃幅融解潜熱Ｈ５とは前述の通り、「５℃の温度幅での融解潜熱の総量」を意味し、ある温度ＴからＴ＋５℃の温度範囲における融解潜熱の総量Ｑ５についてＴを変化させた際のＱ５の最大値として定義される。ここで、その際の温度の下限値を５℃幅下限温度Ｔ５Ｌ、上限値を５℃幅下限温度Ｔ５Ｈと定義する。
As described above, the 5 ° C. width latent heat of melting H 5 means "the total amount of latent heat of melting in the temperature range of 5 ° C.", and T is changed for the total amount of latent heat of melting Q 5 in the temperature range from a certain temperature T to T + 5 ° C. It is defined as the maximum value of Q 5 when allowed to. Here, the lower limit of the temperature at that time is defined as 5 ° C. width lower limit temperature T 5L , and the upper limit value is defined as 5 ° C. width lower limit temperature T 5H .
潜熱蓄熱材組成物ＭＡでは図３中の斜線領域Ａ１の総和が５℃幅融解潜熱Ｈ５となる。潜熱蓄熱材組成物ＭＡでは狭い温度範囲において鋭い蓄熱量のピークが存在することから、結果として５℃幅融解潜熱Ｈ５は大きな値を示す。同様に潜熱蓄熱材組成物ＭＢにおいても図４中の斜線領域Ａ２の総和が５℃幅融解潜熱Ｈ５となる。しかし、潜熱蓄熱材組成物ＭＢではピークの形状が緩やかであるため、５℃幅融解潜熱Ｈ５は小さな値を示す。
The sum of the hatched areas A 1 in the latent heat storage material composition M A 3 is 5 ° C. width latent heat of fusion H 5. Since the peak of the sharp heat storage amount is present in the latent heat storage material composition M A in a narrow temperature range, resulting in 5 ° C. width latent heat of fusion H 5 indicates a large value. Similarly the sum of the shaded area A 2 in FIG. 4 also in the latent heat storage material composition M B is 5 ° C. width latent heat of fusion H 5. However, since the latent heat is gentle heat storage material composition M peak shape in B, 5 ° C. width latent heat of fusion H 5 indicates a small value.
このように狭い温度範囲で多量の熱を吸熱する蓄熱材ほど、５℃幅融解潜熱Ｈ５は大きな値を示すことから、５℃幅融解潜熱Ｈ５を「狭い温度範囲で多量の熱を吸熱する」特性の指標として用いることができる。
More heat storage material absorbs a large amount of heat at such a narrow temperature range, from 5 ° C. width latent heat of fusion H 5 to a larger value, 5 ° C. width latent heat of fusion H 5 absorbs the large amount of heat in the "narrow temperature range It can be used as an index of the characteristic of "doing".
しかしながら、硫酸ナトリウム１０水和物は、相変化温度が約３２℃であるため、特許文献１の蓄熱材組成物では、融点を２０～２２．５℃の範囲内に調整することが困難であるという問題があった。また、特許文献１の蓄熱材組成物には、蓄熱量が小さいという問題があった。さらに、特許文献１の蓄熱材組成物では、水を加えると、潜熱発生領域が増大するため、狭い温度領域内での融解潜熱が小さいという問題があった。
However, since the phase change temperature of sodium sulfate decahydrate is about 32 ° C., it is difficult to adjust the melting point of the heat storage material composition of Patent Document 1 within the range of 20 to 22.5 ° C. There was a problem. Further, the heat storage material composition of Patent Document 1 has a problem that the amount of heat storage is small. Further, in the heat storage material composition of Patent Document 1, there is a problem that the latent heat of melting in a narrow temperature region is small because the latent heat generation region increases when water is added.
本発明は、上記課題に鑑みてなされたものである。本発明は、融点が２０～２２．５℃の範囲内にあり、狭い温度領域内での融解潜熱が大きい蓄熱材組成物及び建築物の冷暖房用の蓄熱システムを提供することを目的とする。
The present invention has been made in view of the above problems. An object of the present invention is to provide a heat storage material composition having a melting point in the range of 20 to 22.5 ° C. and a large latent heat of melting in a narrow temperature range, and a heat storage system for heating and cooling of a building.
本発明の第１の態様に係る蓄熱材組成物は、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、炭酸ナトリウム１０水和物、及び、リン酸三ナトリウム１２水和物からなる主剤を含み、融点が２０～２２．５℃の範囲内にあり、５℃幅融解潜熱が１６０Ｊ／ｇ以上である。
The heat storage material composition according to the first aspect of the present invention is composed of sodium sulfate tetrahydrate, disodium hydrogen phosphate dodecahydrate, sodium carbonate decahydrate, and trisodium phosphate dodecahydrate. The melting point is in the range of 20 to 22.5 ° C., and the latent heat of melting in the 5 ° C. width is 160 J / g or more.
本発明の第２の態様に係る蓄熱材組成物は、第１の態様に係る蓄熱材組成物において、前記主剤中における前記リン酸三ナトリウム１２水和物の含有量が４．５～５．５質量％の場合において、前記硫酸ナトリウム１０水和物、前記リン酸水素二ナトリウム１２水和物、及び前記炭酸ナトリウム１０水和物からなる三種組成物１００質量％中の、前記硫酸ナトリウム１０水和物の含有量をＸ質量％、前記リン酸水素二ナトリウム１２水和物の含有量をＹ質量％、及び前記炭酸ナトリウム１０水和物の含有量をＺ質量％と規定するとき、Ｘ、Ｙ、及びＺが下記式（１－１）～（１－４）を満たす。
［数１］
Ｘ＋Ｙ＋Ｚ＝１００ （１－１）
［数２］
Ｘ＋２．００Ｙ－１２４．２１≦０ （１－２）
［数３］
Ｘ＋２．００Ｙ－８９．４７≦０ （１－３）
［数４］
１７．８９≦Ｘ≦２９．４７ （１－４） The heat storage material composition according to the second aspect of the present invention has a heat storage material composition according to the first aspect, wherein the content of the disodium phosphate dodecahydrate in the main agent is 4.5 to 5. In the case of 5% by mass, thesodium sulfate 10 water in 100% by mass of the three-kind composition composed of the sodium sulfate decahydrate, the disodium hydrogen phosphate dodecahydrate, and the sodium carbonate decahydrate. When the content of the Japanese product is defined as X mass%, the content of the disodium hydrogen phosphate dodecahydrate is defined as Y mass%, and the content of the sodium carbonate decahydrate is defined as Z mass%, X, Y and Z satisfy the following formulas (1-1) to (1-4).
[Number 1]
X + Y + Z = 100 (1-1)
[Number 2]
X + 2.00Y-124.21 ≦ 0 (1-2)
[Number 3]
X + 2.00Y-89.47 ≦ 0 (1-3)
[Number 4]
17.89 ≤ X ≤ 29.47 (1-4)
［数１］
Ｘ＋Ｙ＋Ｚ＝１００ （１－１）
［数２］
Ｘ＋２．００Ｙ－１２４．２１≦０ （１－２）
［数３］
Ｘ＋２．００Ｙ－８９．４７≦０ （１－３）
［数４］
１７．８９≦Ｘ≦２９．４７ （１－４） The heat storage material composition according to the second aspect of the present invention has a heat storage material composition according to the first aspect, wherein the content of the disodium phosphate dodecahydrate in the main agent is 4.5 to 5. In the case of 5% by mass, the
[Number 1]
X + Y + Z = 100 (1-1)
[Number 2]
X + 2.00Y-124.21 ≦ 0 (1-2)
[Number 3]
X + 2.00Y-89.47 ≦ 0 (1-3)
[Number 4]
17.89 ≤ X ≤ 29.47 (1-4)
本発明の第３の態様に係る蓄熱材組成物は、第１の態様に係る蓄熱材組成物において、前記主剤中における前記リン酸三ナトリウム１２水和物の含有量が７．０～８．０質量％の場合において、前記硫酸ナトリウム１０水和物、前記リン酸水素二ナトリウム１２水和物、及び前記炭酸ナトリウム１０水和物からなる三種組成物１００質量％中の、前記硫酸ナトリウム１０水和物の含有量をＸ質量％、前記リン酸水素二ナトリウム１２水和物の含有量をＹ質量％、及び前記炭酸ナトリウム１０水和物の含有量をＺ質量％と規定するとき、Ｘ、Ｙ、及びＺが下記式（２－１）～（２－４）を満たす。
［数５］
Ｘ＋Ｙ＋Ｚ＝１００ （２－１）
［数６］
Ｘ＋２．００Ｙ－１２４．２１≦０ （２－２）
［数７］
Ｘ＋２．００Ｙ－８９．４７≦０ （２－３）
［数８］
１７．８９≦Ｘ≦２９．４７ （２－４） In the heat storage material composition according to the third aspect of the present invention, the content of the disodium phosphate dodecahydrate in the main agent is 7.0 to 8. In the case of 0% by mass, thesodium sulfate 10 water in 100% by mass of the three-kind composition consisting of the sodium sulfate decahydrate, the disodium hydrogen phosphate dodecahydrate, and the sodium carbonate decahydrate. When the content of the Japanese product is defined as X mass%, the content of the disodium hydrogen phosphate dodecahydrate is defined as Y mass%, and the content of the sodium carbonate decahydrate is defined as Z mass%, X, Y and Z satisfy the following formulas (2-1) to (2-4).
[Number 5]
X + Y + Z = 100 (2-1)
[Number 6]
X + 2.00Y-124.21 ≦ 0 (2-2)
[Number 7]
X + 2.00Y-89.47 ≦ 0 (2-3)
[Number 8]
17.89 ≤ X ≤ 29.47 (2-4)
［数５］
Ｘ＋Ｙ＋Ｚ＝１００ （２－１）
［数６］
Ｘ＋２．００Ｙ－１２４．２１≦０ （２－２）
［数７］
Ｘ＋２．００Ｙ－８９．４７≦０ （２－３）
［数８］
１７．８９≦Ｘ≦２９．４７ （２－４） In the heat storage material composition according to the third aspect of the present invention, the content of the disodium phosphate dodecahydrate in the main agent is 7.0 to 8. In the case of 0% by mass, the
[Number 5]
X + Y + Z = 100 (2-1)
[Number 6]
X + 2.00Y-124.21 ≦ 0 (2-2)
[Number 7]
X + 2.00Y-89.47 ≦ 0 (2-3)
[Number 8]
17.89 ≤ X ≤ 29.47 (2-4)
本発明の第４の態様に係る蓄熱材組成物は、第１の態様に係る蓄熱材組成物において、前記主剤中における前記リン酸三ナトリウム１２水和物の含有量が９．５～１０．５質量％の場合において、前記硫酸ナトリウム１０水和物、前記リン酸水素二ナトリウム１２水和物、及び前記炭酸ナトリウム１０水和物からなる三種組成物１００質量％中の、前記硫酸ナトリウム１０水和物の含有量をＸ質量％、前記リン酸水素二ナトリウム１２水和物の含有量をＹ質量％、及び前記炭酸ナトリウム１０水和物の含有量をＺ質量％と規定するとき、Ｘ、Ｙ、及びＺが下記式（３－１）～（３－４）を満たす。
［数９］
Ｘ＋Ｙ＋Ｚ＝１００ （３－１）
［数１０］
Ｘ＋２．００Ｙ－１１８．３３≦０ （３－２）
［数１１］
Ｘ＋２．００Ｙ－８９．４７≦０ （３－３）
［数１２］
１７．８９≦Ｘ≦２９．４７ （３－４） The heat storage material composition according to the fourth aspect of the present invention has a heat storage material composition according to the first aspect, wherein the content of the disodium phosphate dodecahydrate in the main agent is 9.5 to 10. In the case of 5% by mass, thesodium sulfate 10 water in 100% by mass of the three-kind composition composed of the sodium sulfate decahydrate, the disodium hydrogen phosphate dodecahydrate, and the sodium carbonate decahydrate. When the content of the Japanese product is defined as X mass%, the content of the disodium hydrogen phosphate dodecahydrate is defined as Y mass%, and the content of the sodium carbonate decahydrate is defined as Z mass%, X, Y and Z satisfy the following formulas (3-1) to (3-4).
[Number 9]
X + Y + Z = 100 (3-1)
[Number 10]
X + 2.00Y-118.33 ≦ 0 (3-2)
[Number 11]
X + 2.00Y-89.47 ≦ 0 (3-3)
[Number 12]
17.89 ≤ X ≤ 29.47 (3-4)
［数９］
Ｘ＋Ｙ＋Ｚ＝１００ （３－１）
［数１０］
Ｘ＋２．００Ｙ－１１８．３３≦０ （３－２）
［数１１］
Ｘ＋２．００Ｙ－８９．４７≦０ （３－３）
［数１２］
１７．８９≦Ｘ≦２９．４７ （３－４） The heat storage material composition according to the fourth aspect of the present invention has a heat storage material composition according to the first aspect, wherein the content of the disodium phosphate dodecahydrate in the main agent is 9.5 to 10. In the case of 5% by mass, the
[Number 9]
X + Y + Z = 100 (3-1)
[Number 10]
X + 2.00Y-118.33 ≦ 0 (3-2)
[Number 11]
X + 2.00Y-89.47 ≦ 0 (3-3)
[Number 12]
17.89 ≤ X ≤ 29.47 (3-4)
本発明の第５の態様に係る蓄熱材組成物は、第１の態様に係る蓄熱材組成物において、前記主剤中における前記リン酸三ナトリウム１２水和物の含有量が１４．５～１５．５質量％の場合において、前記硫酸ナトリウム１０水和物、前記リン酸水素二ナトリウム１２水和物、及び前記炭酸ナトリウム１０水和物からなる三種組成物１００質量％中の、前記硫酸ナトリウム１０水和物の含有量をＸ質量％、前記リン酸水素二ナトリウム１２水和物の含有量をＹ質量％、及び前記炭酸ナトリウム１０水和物の含有量をＺ質量％と規定するとき、Ｘ、Ｙ、及びＺが下記式（４－１）～（４－４）を満たす。
［数１３］
Ｘ＋Ｙ＋Ｚ＝１００ （４－１）
［数１４］
Ｘ＋２．００Ｙ－１０５．７４≦０ （４－２）
［数１５］
Ｘ＋２．００Ｙ－８９．４７≦０ （４－３）
［数１６］
１７．８９≦Ｘ≦２９．４７ （４－４） The heat storage material composition according to the fifth aspect of the present invention has a heat storage material composition according to the first aspect, wherein the content of the disodium phosphate dodecahydrate in the main agent is 14.5 to 15. In the case of 5% by mass, thesodium sulfate 10 water in 100% by mass of the three-kind composition composed of the sodium sulfate decahydrate, the disodium hydrogen phosphate dodecahydrate, and the sodium carbonate decahydrate. When the content of the Japanese product is defined as X mass%, the content of the disodium hydrogen phosphate dodecahydrate is defined as Y mass%, and the content of the sodium carbonate decahydrate is defined as Z mass%, X, Y and Z satisfy the following formulas (4-1) to (4-4).
[Number 13]
X + Y + Z = 100 (4-1)
[Number 14]
X + 2.00Y-105.74≤0 (4-2)
[Number 15]
X + 2.00Y-89.47 ≦ 0 (4-3)
[Number 16]
17.89 ≤ X ≤ 29.47 (4-4)
［数１３］
Ｘ＋Ｙ＋Ｚ＝１００ （４－１）
［数１４］
Ｘ＋２．００Ｙ－１０５．７４≦０ （４－２）
［数１５］
Ｘ＋２．００Ｙ－８９．４７≦０ （４－３）
［数１６］
１７．８９≦Ｘ≦２９．４７ （４－４） The heat storage material composition according to the fifth aspect of the present invention has a heat storage material composition according to the first aspect, wherein the content of the disodium phosphate dodecahydrate in the main agent is 14.5 to 15. In the case of 5% by mass, the
[Number 13]
X + Y + Z = 100 (4-1)
[Number 14]
X + 2.00Y-105.74≤0 (4-2)
[Number 15]
X + 2.00Y-89.47 ≦ 0 (4-3)
[Number 16]
17.89 ≤ X ≤ 29.47 (4-4)
本発明の第７の態様に係る蓄熱材組成物は、第１の態様に係る蓄熱材組成物において、前記主剤１００質量％中の、前記硫酸ナトリウム１０水和物の含有量をＸ質量％、前記リン酸水素二ナトリウム１２水和物の含有量をＹ質量％、前記炭酸ナトリウム１０水和物の含有量をＺ質量％、及び前記リン酸三ナトリウム１２水和物の含有量をＷ質量％と規定するとき、Ｘ、Ｙ、Ｚ、及びＷが下記式（５－１）～（５－７）を満たす。
［数１７］
Ｘ＋Ｙ＋Ｚ＋Ｗ＝１００ （５－１）
［数１８］
Ｘ－３．１３０４Ｙ＋５．１３０４Ｚ≧０ （５－２）
［数１９］
Ｘ－０．２１７９Ｙ－０．２１７９Ｚ≧０ （５－３）
［数２０］
Ｘ＋１０．５０００Ｙ－８．５０００Ｚ≧０ （５－４）
［数２１］
Ｘ－０．４１７９Ｙ－０．４１７９Ｚ≦０ （５－５）
［数２２］
Ｘ＋０．５８３７Ｙ＋１．４１６３Ｚ－８３．１７６≧０（５－６）
［数２３］
４．８≦Ｗ≦１５．２ （５－７） In the heat storage material composition according to the first aspect of the present invention, the content of the sodium sulfate decahydrate in 100% by mass of the main agent is X% by mass. The content of disodium hydrogen phosphate dodecahydrate is Y mass%, the content of sodium carbonate decahydrate is Z mass%, and the content of trisodium phosphate dodecahydrate is W mass%. X, Y, Z, and W satisfy the following formulas (5-1) to (5-7).
[Number 17]
X + Y + Z + W = 100 (5-1)
[Number 18]
X-3.1304Y + 5.1304Z ≧ 0 (5-2)
[Number 19]
X-0.2179Y-0.2179Z ≧ 0 (5-3)
[Number 20]
X + 10.5000Y-85000Z ≧ 0 (5-4)
[Number 21]
X-0.4179Y-0.4179Z ≦ 0 (5-5)
[Number 22]
X + 0.5837Y + 1.4163Z-83.176 ≧ 0 (5-6)
[Number 23]
4.8 ≤ W ≤ 15.2 (5-7)
［数１７］
Ｘ＋Ｙ＋Ｚ＋Ｗ＝１００ （５－１）
［数１８］
Ｘ－３．１３０４Ｙ＋５．１３０４Ｚ≧０ （５－２）
［数１９］
Ｘ－０．２１７９Ｙ－０．２１７９Ｚ≧０ （５－３）
［数２０］
Ｘ＋１０．５０００Ｙ－８．５０００Ｚ≧０ （５－４）
［数２１］
Ｘ－０．４１７９Ｙ－０．４１７９Ｚ≦０ （５－５）
［数２２］
Ｘ＋０．５８３７Ｙ＋１．４１６３Ｚ－８３．１７６≧０（５－６）
［数２３］
４．８≦Ｗ≦１５．２ （５－７） In the heat storage material composition according to the first aspect of the present invention, the content of the sodium sulfate decahydrate in 100% by mass of the main agent is X% by mass. The content of disodium hydrogen phosphate dodecahydrate is Y mass%, the content of sodium carbonate decahydrate is Z mass%, and the content of trisodium phosphate dodecahydrate is W mass%. X, Y, Z, and W satisfy the following formulas (5-1) to (5-7).
[Number 17]
X + Y + Z + W = 100 (5-1)
[Number 18]
X-3.1304Y + 5.1304Z ≧ 0 (5-2)
[Number 19]
X-0.2179Y-0.2179Z ≧ 0 (5-3)
[Number 20]
X + 10.5000Y-85000Z ≧ 0 (5-4)
[Number 21]
X-0.4179Y-0.4179Z ≦ 0 (5-5)
[Number 22]
X + 0.5837Y + 1.4163Z-83.176 ≧ 0 (5-6)
[Number 23]
4.8 ≤ W ≤ 15.2 (5-7)
本発明の第７の態様に係る蓄熱材組成物は、第１～第６のいずれかの態様に係る蓄熱材組成物において、有機不飽和カルボン酸、有機不飽和スルホン酸、有機不飽和リン酸、有機不飽和アミド、有機不飽和アルコール、有機不飽和カルボン酸塩、有機不飽和スルホン酸塩、及び有機不飽和リン酸塩からなる群より選択される少なくとも１種の単量体と、多官能性単量体と、を重合させて得られる保湿剤をさらに含む。
The heat storage material composition according to the seventh aspect of the present invention is an organic unsaturated carboxylic acid, an organic unsaturated sulfonic acid, and an organic unsaturated phosphoric acid in the heat storage material composition according to any one of the first to sixth aspects. , Organic unsaturated amide, organic unsaturated alcohol, organic unsaturated carboxylate, organic unsaturated sulfonate, and at least one monomer selected from the group consisting of organic unsaturated phosphate, and polyfunctionality. It further contains a moisturizing agent obtained by polymerizing the sex monomer.
本発明の第８の態様に係る蓄熱材組成物は、第１～第７のいずれかの態様に係る蓄熱材組成物において、塩化ナトリウム、塩化カリウム、硝酸ナトリウム、臭化ナトリウム、塩化アンモニウム、臭化アンモニウム、硫酸アンモニウム、硝酸アンモニウム、リン酸アンモニウム、及び尿素からなる群より選択される少なくとも１種の融点降下剤をさらに含む。
The heat storage material composition according to the eighth aspect of the present invention is, in the heat storage material composition according to any one of the first to seventh aspects, sodium chloride, potassium chloride, sodium nitrate, sodium bromide, ammonium chloride, odor. It further comprises at least one melting point lowering agent selected from the group consisting of ammonium bromide, ammonium sulfate, ammonium nitrate, ammonium phosphate, and urea.
本発明の第９の態様に係る蓄熱材組成物は、第１～第８のいずれかの態様に係る蓄熱材組成物において、ホウ砂Ｎａ２Ｂ４Ｏ５（ＯＨ）４・８Ｈ２Ｏ、水酸化カルシウム、水酸化バリウム、水酸化ストロンチウム、水酸化アルミニウム、黒鉛、アルミニウム、二酸化チタン、ヘクトライト、スメクタイトクレイ、ベントナイト、ラポナイト、プロピレングリコール、エチレングリコール、グリセリン、エチレンジアミン四酢酸、アルキル硫酸ナトリウム、アルキルリン酸ナトリウム、アルキル硫酸カリウム、及びアルキルリン酸カリウムからなる群より選択される少なくとも１種の過冷却抑制剤をさらに含む。
Heat storage material composition according to the ninth aspect of the present invention is the heat storage material composition according to any of embodiments of the first to eighth, borax Na 2 B 4 O 5 (OH ) 4 · 8H 2 O, Calcium hydroxide, barium hydroxide, strontium hydroxide, aluminum hydroxide, graphite, aluminum, titanium dioxide, hectrite, smectite clay, bentonite, laponite, propylene glycol, ethylene glycol, glycerin, ethylenediamine tetraacetic acid, sodium alkyl sulfate, alkyl It further comprises at least one overcooling inhibitor selected from the group consisting of sodium phosphate, potassium alkyl sulfate, and potassium alkyl phosphate.
本発明の第１０の態様に係る蓄熱材組成物は、第１～第９のいずれかの態様に係る蓄熱材組成物において、ケイ酸ナトリウム、水ガラス、ポリアクリル酸、ポリアクリル酸ナトリウム、ポリカルボキシレートポリエーテルポリマー、アクリル酸・マイレン酸共重合体ナトリウム、アクリル酸・スルホン酸系モノマー共重合体ナトリウム、アクリルアミド・ジメチルアミノエチルメタクリラートジメチル硫酸塩共重合物、アクリルアミド・アクリル酸ソーダ共重合物、ポリエチレングリコール、ポリプロピレングリコール、高吸水樹脂（ＳＡＰ）、カルボキシメチルセルロース（ＣＭＣ)、ＣＭＣの誘導体、カラギーナン、カラギーナンの誘導体、キサンタンガム、キサンタンガムの誘導体、ペクチン、ペクチンの誘導体、デンプン、デンプンの誘導体、コンニャク、寒天、層状ケイ酸塩、及びこれらの物質の複合物質からなる群より選択される少なくとも１種の相分離抑制剤をさらに含む。
The heat storage material composition according to the tenth aspect of the present invention is, in the heat storage material composition according to any one of the first to ninth aspects, sodium silicate, water glass, polyacrylic acid, sodium polyacrylate, poly. Carboxylate polyether polymer, sodium acrylate / maleic acid copolymer, sodium acrylate / sulfonic acid monomer copolymer, acrylamide / dimethylaminoethyl methacrylate dimethylsulfate copolymer, acrylamide / sodium acrylate copolymer , Polyethylene Glycol, Polypropylene Glycol, Highly Absorbent Resin (SAP), Carboxymethyl Cellulose (CMC), CMC Derivatives, Carrageenan, Caraginan Derivatives, Xanthan Gum, Xantan Gum Derivatives, Pectin, Pectin Derivatives, Steel, Steel Derivatives It further comprises at least one phase separation inhibitor selected from the group consisting of agar, layered silicates, and copolymers of these substances.
本発明の第１１の態様に係る建築物の冷暖房用の蓄熱システムは、第１～第１０のいずれかの態様に係る蓄熱材組成物を用いた蓄熱材モジュールを具備する。
The heat storage system for heating and cooling a building according to the eleventh aspect of the present invention includes a heat storage material module using the heat storage material composition according to any one of the first to tenth aspects.
以下、図面を用いて本発明の実施形態に係る蓄熱材組成物、及び蓄熱システムについて詳細に説明する。
Hereinafter, the heat storage material composition and the heat storage system according to the embodiment of the present invention will be described in detail with reference to the drawings.
［蓄熱材組成物］
本実施形態に係る蓄熱材組成物は、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、炭酸ナトリウム１０水和物、及びリン酸三ナトリウム１２水和物からなる主剤を含む。なお、主剤中、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、及び炭酸ナトリウム１０水和物からなる混合物を、三種組成物ともいう。 [Heat storage material composition]
The heat storage material composition according to the present embodiment contains a main agent composed of sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, sodium carbonate decahydrate, and trisodium phosphate dodecahydrate. A mixture consisting of sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, and sodium carbonate decahydrate in the main agent is also referred to as a three-kind composition.
本実施形態に係る蓄熱材組成物は、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、炭酸ナトリウム１０水和物、及びリン酸三ナトリウム１２水和物からなる主剤を含む。なお、主剤中、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、及び炭酸ナトリウム１０水和物からなる混合物を、三種組成物ともいう。 [Heat storage material composition]
The heat storage material composition according to the present embodiment contains a main agent composed of sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, sodium carbonate decahydrate, and trisodium phosphate dodecahydrate. A mixture consisting of sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, and sodium carbonate decahydrate in the main agent is also referred to as a three-kind composition.
（主剤）
主剤は、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、炭酸ナトリウム１０水和物、及びリン酸三ナトリウム１２水和物を所定量含む。 (Main agent)
The main agent contains a predetermined amount of sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, sodium carbonate decahydrate, and trisodium phosphate dodecahydrate.
主剤は、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、炭酸ナトリウム１０水和物、及びリン酸三ナトリウム１２水和物を所定量含む。 (Main agent)
The main agent contains a predetermined amount of sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, sodium carbonate decahydrate, and trisodium phosphate dodecahydrate.
なお、本実施形態に係る蓄熱材組成物は、主剤のみからなることができるが、必要により、余剰水をさらに含んでいてもよい。この主剤に加えて余剰水を含む蓄熱材組成物については後述する。
The heat storage material composition according to the present embodiment may consist only of the main agent, but may further contain excess water if necessary. The heat storage material composition containing excess water in addition to this main agent will be described later.
＜三種組成物中の組成＞
蓄熱材組成物では、主剤中における前記リン酸三ナトリウム１２水和物の含有量に応じて、Ｘ、Ｙ、及びＺが下記式（１－１）～（１－４）、（２－１）～（２－４）、（３－１）～（３－４）、又は（４－１）～（４－４）を満たすことが好ましい。ここで、Ｘ、Ｙ、及びＺは、三種組成物１００質量％中の、硫酸ナトリウム１０水和物の含有量をＸ質量％、リン酸水素二ナトリウム１２水和物の含有量をＹ質量％、及び炭酸ナトリウム１０水和物の含有量をＺ質量％と規定するときの値である。すなわち、Ｘ、Ｙ、及びＺは、主剤からリン酸三ナトリウム１２水和物を除いた三種組成物中の、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、及び炭酸ナトリウム１０水和物の各物質の含有量（質量％）を示す。 <Composition in three kinds of compositions>
In the heat storage material composition, X, Y, and Z are the following formulas (1-1) to (1-4), (2-1) depending on the content of the trisodium phosphate dodecahydrate in the main agent. )-(2-4), (3-1)-(3-4), or (4-1)-(4-4) are preferably satisfied. Here, X, Y, and Z are X mass% of the content of sodium sulfate decahydrate and Y mass% of the content of disodium hydrogen phosphate dodecahydrate in 100% by mass of the three kinds of compositions. , And the value when the content of sodium carbonate decahydrate is defined as Z mass%. That is, X, Y, and Z are sodium sulfate pentahydrate, disodium hydrogen phosphate dodecahydrate, andsodium carbonate 10 in the three compositions obtained by removing trisodium phosphate dodecahydrate from the main agent. The content (% by mass) of each substance of hydrate is shown.
蓄熱材組成物では、主剤中における前記リン酸三ナトリウム１２水和物の含有量に応じて、Ｘ、Ｙ、及びＺが下記式（１－１）～（１－４）、（２－１）～（２－４）、（３－１）～（３－４）、又は（４－１）～（４－４）を満たすことが好ましい。ここで、Ｘ、Ｙ、及びＺは、三種組成物１００質量％中の、硫酸ナトリウム１０水和物の含有量をＸ質量％、リン酸水素二ナトリウム１２水和物の含有量をＹ質量％、及び炭酸ナトリウム１０水和物の含有量をＺ質量％と規定するときの値である。すなわち、Ｘ、Ｙ、及びＺは、主剤からリン酸三ナトリウム１２水和物を除いた三種組成物中の、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、及び炭酸ナトリウム１０水和物の各物質の含有量（質量％）を示す。 <Composition in three kinds of compositions>
In the heat storage material composition, X, Y, and Z are the following formulas (1-1) to (1-4), (2-1) depending on the content of the trisodium phosphate dodecahydrate in the main agent. )-(2-4), (3-1)-(3-4), or (4-1)-(4-4) are preferably satisfied. Here, X, Y, and Z are X mass% of the content of sodium sulfate decahydrate and Y mass% of the content of disodium hydrogen phosphate dodecahydrate in 100% by mass of the three kinds of compositions. , And the value when the content of sodium carbonate decahydrate is defined as Z mass%. That is, X, Y, and Z are sodium sulfate pentahydrate, disodium hydrogen phosphate dodecahydrate, and
［リン酸三ナトリウム１２水和物の含有量が４．５～５．５質量％の場合］
具体的には、主剤中における前記リン酸三ナトリウム１２水和物の含有量が４．５～５．５質量％、好ましくは４．８～５．２質量％の場合において、Ｘ、Ｙ、及びＺが下記式（１－１）～（１－４）を満たすことが好ましい。 [When the content of trisodium phosphate dodecahydrate is 4.5 to 5.5% by mass]
Specifically, when the content of the trisodium phosphate dodecahydrate in the main agent is 4.5 to 5.5% by mass, preferably 4.8 to 5.2% by mass, X, Y, And Z preferably satisfy the following formulas (1-1) to (1-4).
具体的には、主剤中における前記リン酸三ナトリウム１２水和物の含有量が４．５～５．５質量％、好ましくは４．８～５．２質量％の場合において、Ｘ、Ｙ、及びＺが下記式（１－１）～（１－４）を満たすことが好ましい。 [When the content of trisodium phosphate dodecahydrate is 4.5 to 5.5% by mass]
Specifically, when the content of the trisodium phosphate dodecahydrate in the main agent is 4.5 to 5.5% by mass, preferably 4.8 to 5.2% by mass, X, Y, And Z preferably satisfy the following formulas (1-1) to (1-4).
［数２４］
Ｘ＋Ｙ＋Ｚ＝１００ （１－１）
［数２５］
Ｘ＋２．００Ｙ－１２４．２１≦０ （１－２）
［数２６］
Ｘ＋２．００Ｙ－８９．４７≦０ （１－３）
［数２７］
１７．８９≦Ｘ≦２９．４７ （１－４） [Number 24]
X + Y + Z = 100 (1-1)
[Number 25]
X + 2.00Y-124.21 ≦ 0 (1-2)
[Number 26]
X + 2.00Y-89.47 ≦ 0 (1-3)
[Number 27]
17.89 ≤ X ≤ 29.47 (1-4)
Ｘ＋Ｙ＋Ｚ＝１００ （１－１）
［数２５］
Ｘ＋２．００Ｙ－１２４．２１≦０ （１－２）
［数２６］
Ｘ＋２．００Ｙ－８９．４７≦０ （１－３）
［数２７］
１７．８９≦Ｘ≦２９．４７ （１－４） [Number 24]
X + Y + Z = 100 (1-1)
[Number 25]
X + 2.00Y-124.21 ≦ 0 (1-2)
[Number 26]
X + 2.00Y-89.47 ≦ 0 (1-3)
[Number 27]
17.89 ≤ X ≤ 29.47 (1-4)
図５は、主剤におけるリン酸三ナトリウム１２水和物の含有量が略５質量％のときの、三種組成物中の、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、及び炭酸ナトリウム１０水和物の含有量の三元系組成図である。図５中、ＮＳは硫酸ナトリウム１０水和物が１００％になる点、ＮＨはリン酸水素二ナトリウム１２水和物が１００％になる点、ＮＣは炭酸ナトリウム１０水和物が１００％になる点を示す。図５に示す矩形Ｒ１及びその内部は、上記式（１－１）～（１－４）を満たす範囲である。
FIG. 5 shows sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, and disodium hydrogen phosphate dodecahydrate in the three compositions when the content of trisodium phosphate dodecahydrate in the main agent is approximately 5% by mass. It is a ternary composition diagram of the content of sodium carbonate decahydrate. In FIG. 5, NS is 100% sodium sulfate decahydrate, NH is 100% disodium hydrogen phosphate dodecahydrate, and NC is 100% sodium carbonate decahydrate. Indicates a point. Rectangle R 1 and therein shown in FIG. 5 is a range satisfying the above formula (1-1) to (1-4).
リン酸三ナトリウム１２水和物の含有量が４．５～５．５質量％の場合に、上記Ｘ、Ｙ、及びＺが式（１－１）～（１－４）を満たすと、蓄熱材組成物の融点が２０～２２．５℃の範囲内にあり、５℃幅融解潜熱が１６０Ｊ／ｇ以上になりやすい。
When the content of trisodium phosphate dodecahydrate is 4.5 to 5.5% by mass and the above X, Y, and Z satisfy the formulas (1-1) to (1-4), heat storage The melting point of the material composition is in the range of 20 to 22.5 ° C., and the latent heat of melting in the 5 ° C. width tends to be 160 J / g or more.
［リン酸三ナトリウム１２水和物の含有量が７．０～８．０質量％の場合］
具体的には、主剤中における前記リン酸三ナトリウム１２水和物の含有量が７．０～８．０質量％、好ましくは７．４～７．７質量％の場合において、Ｘ、Ｙ、及びＺが下記式（２－１）～（２－４）を満たすことが好ましい。 [When the content of trisodium phosphate dodecahydrate is 7.0 to 8.0% by mass]
Specifically, when the content of the trisodium phosphate dodecahydrate in the main agent is 7.0 to 8.0% by mass, preferably 7.4 to 7.7% by mass, X, Y, And Z preferably satisfy the following formulas (2-1) to (2-4).
具体的には、主剤中における前記リン酸三ナトリウム１２水和物の含有量が７．０～８．０質量％、好ましくは７．４～７．７質量％の場合において、Ｘ、Ｙ、及びＺが下記式（２－１）～（２－４）を満たすことが好ましい。 [When the content of trisodium phosphate dodecahydrate is 7.0 to 8.0% by mass]
Specifically, when the content of the trisodium phosphate dodecahydrate in the main agent is 7.0 to 8.0% by mass, preferably 7.4 to 7.7% by mass, X, Y, And Z preferably satisfy the following formulas (2-1) to (2-4).
［数２８］
Ｘ＋Ｙ＋Ｚ＝１００ （２－１）
［数２９］
Ｘ＋２．００Ｙ－１２４．２１≦０ （２－２）
［数３０］
Ｘ＋２．００Ｙ－８９．４７≦０ （２－３）
［数３１］
１７．８９≦Ｘ≦２９．４７ （２－４） [Number 28]
X + Y + Z = 100 (2-1)
[Number 29]
X + 2.00Y-124.21 ≦ 0 (2-2)
[Number 30]
X + 2.00Y-89.47 ≦ 0 (2-3)
[Number 31]
17.89 ≤ X ≤ 29.47 (2-4)
Ｘ＋Ｙ＋Ｚ＝１００ （２－１）
［数２９］
Ｘ＋２．００Ｙ－１２４．２１≦０ （２－２）
［数３０］
Ｘ＋２．００Ｙ－８９．４７≦０ （２－３）
［数３１］
１７．８９≦Ｘ≦２９．４７ （２－４） [Number 28]
X + Y + Z = 100 (2-1)
[Number 29]
X + 2.00Y-124.21 ≦ 0 (2-2)
[Number 30]
X + 2.00Y-89.47 ≦ 0 (2-3)
[Number 31]
17.89 ≤ X ≤ 29.47 (2-4)
図６は、主剤におけるリン酸三ナトリウム１２水和物の含有量が略７．５質量％のときの、三種組成物中の、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、及び炭酸ナトリウム１０水和物の含有量の三元系組成図である。図６中のＮＳ、ＮＨ、及びＮＣは、図５と同じである。図６に示す矩形Ｒ２及びその内部は、上記式（２－１）～（２－４）を満たす範囲である。
FIG. 6 shows sodium sulfate tetrahydrate and disodium hydrogen phosphate dodecahydrate in the three compositions when the content of trisodium phosphate dodecahydrate in the main agent is approximately 7.5% by mass. , And a ternary composition diagram of the content of sodium carbonate decahydrate. NS, NH, and NC in FIG. 6 are the same as those in FIG. The rectangle R 2 shown in FIG. 6 and the inside thereof are in a range satisfying the above equations (2-1) to (2-4).
リン酸三ナトリウム１２水和物の含有量が７．０～８．０質量％の場合に、上記Ｘ、Ｙ、及びＺが式（２－１）～（２－４）を満たすと、蓄熱材組成物の融点が２０～２２．５℃の範囲内にあり、５℃幅融解潜熱が１６０Ｊ／ｇ以上になりやすい。
When the content of trisodium phosphate dodecahydrate is 7.0 to 8.0% by mass and the above X, Y, and Z satisfy the formulas (2-1) to (2-4), heat storage The melting point of the material composition is in the range of 20 to 22.5 ° C., and the latent heat of melting at 5 ° C. tends to be 160 J / g or more.
［リン酸三ナトリウム１２水和物の含有量が９．５～１０．５質量％の場合］
具体的には、主剤中における前記リン酸三ナトリウム１２水和物の含有量が９．５～１０．５質量％、好ましくは９．９～１０．５質量％の場合において、Ｘ、Ｙ、及びＺが下記式（３－１）～（３－４）を満たすことが好ましい。 [When the content of trisodium phosphate dodecahydrate is 9.5 to 10.5% by mass]
Specifically, when the content of the trisodium phosphate dodecahydrate in the main agent is 9.5 to 10.5% by mass, preferably 9.9 to 10.5% by mass, X, Y, And Z preferably satisfy the following formulas (3-1) to (3-4).
具体的には、主剤中における前記リン酸三ナトリウム１２水和物の含有量が９．５～１０．５質量％、好ましくは９．９～１０．５質量％の場合において、Ｘ、Ｙ、及びＺが下記式（３－１）～（３－４）を満たすことが好ましい。 [When the content of trisodium phosphate dodecahydrate is 9.5 to 10.5% by mass]
Specifically, when the content of the trisodium phosphate dodecahydrate in the main agent is 9.5 to 10.5% by mass, preferably 9.9 to 10.5% by mass, X, Y, And Z preferably satisfy the following formulas (3-1) to (3-4).
［数３２］
Ｘ＋Ｙ＋Ｚ＝１００ （３－１）
［数３３］
Ｘ＋２．００Ｙ－１１８．３３≦０ （３－２）
［数３４］
Ｘ＋２．００Ｙ－８９．４７≦０ （３－３）
［数３５］
１７．８９≦Ｘ≦２９．４７ （３－４） [Number 32]
X + Y + Z = 100 (3-1)
[Number 33]
X + 2.00Y-118.33 ≦ 0 (3-2)
[Number 34]
X + 2.00Y-89.47 ≦ 0 (3-3)
[Number 35]
17.89 ≤ X ≤ 29.47 (3-4)
Ｘ＋Ｙ＋Ｚ＝１００ （３－１）
［数３３］
Ｘ＋２．００Ｙ－１１８．３３≦０ （３－２）
［数３４］
Ｘ＋２．００Ｙ－８９．４７≦０ （３－３）
［数３５］
１７．８９≦Ｘ≦２９．４７ （３－４） [Number 32]
X + Y + Z = 100 (3-1)
[Number 33]
X + 2.00Y-118.33 ≦ 0 (3-2)
[Number 34]
X + 2.00Y-89.47 ≦ 0 (3-3)
[Number 35]
17.89 ≤ X ≤ 29.47 (3-4)
図７は、主剤におけるリン酸三ナトリウム１２水和物の含有量が略１０質量％のときの、三種組成物中の、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、及び炭酸ナトリウム１０水和物の含有量の三元系組成図である。図７中のＮＳ、ＮＨ、及びＮＣは、図５と同じである。図７に示す矩形Ｒ３及びその内部は、上記式（３－１）～（３－４）を満たす範囲である。
FIG. 7 shows sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, and disodium hydrogen phosphate dodecahydrate in the three compositions when the content of trisodium phosphate dodecahydrate in the main agent is approximately 10% by mass. It is a ternary composition diagram of the content of sodium carbonate decahydrate. NS, NH, and NC in FIG. 7 are the same as those in FIG. Rectangular R 3 and inside 7 is a range satisfying the above formula (3-1) to (3-4).
リン酸三ナトリウム１２水和物の含有量が９．５～１０．５質量％の場合に、上記Ｘ、Ｙ、及びＺが式（３－１）～（３－４）を満たすと、蓄熱材組成物の融点が２０～２２．５℃の範囲内にあり、５℃幅融解潜熱が１６０Ｊ／ｇ以上になりやすい。
When the content of trisodium phosphate dodecahydrate is 9.5 to 10.5% by mass and the above X, Y, and Z satisfy the formulas (3-1) to (3-4), heat storage The melting point of the material composition is in the range of 20 to 22.5 ° C., and the latent heat of melting at 5 ° C. tends to be 160 J / g or more.
［リン酸三ナトリウム１２水和物の含有量が１４．５～１５．５質量％の場合］
具体的には、主剤中における前記リン酸三ナトリウム１２水和物の含有量が１４．５～１５．５質量％、好ましくは１４．７～１５．１質量％の場合において、Ｘ、Ｙ、及びＺが下記式（４－１）～（４－４）を満たすことが好ましい。 [When the content of trisodium phosphate dodecahydrate is 14.5 to 15.5% by mass]
Specifically, when the content of the trisodium phosphate dodecahydrate in the main agent is 14.5 to 15.5% by mass, preferably 14.7 to 15.1% by mass, X, Y, And Z preferably satisfy the following formulas (4-1) to (4-4).
具体的には、主剤中における前記リン酸三ナトリウム１２水和物の含有量が１４．５～１５．５質量％、好ましくは１４．７～１５．１質量％の場合において、Ｘ、Ｙ、及びＺが下記式（４－１）～（４－４）を満たすことが好ましい。 [When the content of trisodium phosphate dodecahydrate is 14.5 to 15.5% by mass]
Specifically, when the content of the trisodium phosphate dodecahydrate in the main agent is 14.5 to 15.5% by mass, preferably 14.7 to 15.1% by mass, X, Y, And Z preferably satisfy the following formulas (4-1) to (4-4).
［数３６］
Ｘ＋Ｙ＋Ｚ＝１００ （４－１）
［数３７］
Ｘ＋２．００Ｙ－１０５．７４≦０ （４－２）
［数３８］
Ｘ＋２．００Ｙ－８９．４７≦０ （４－３）
［数３９］
１７．８９≦Ｘ≦２９．４７ （４－４） [Number 36]
X + Y + Z = 100 (4-1)
[Number 37]
X + 2.00Y-105.74≤0 (4-2)
[Number 38]
X + 2.00Y-89.47 ≦ 0 (4-3)
[Number 39]
17.89 ≤ X ≤ 29.47 (4-4)
Ｘ＋Ｙ＋Ｚ＝１００ （４－１）
［数３７］
Ｘ＋２．００Ｙ－１０５．７４≦０ （４－２）
［数３８］
Ｘ＋２．００Ｙ－８９．４７≦０ （４－３）
［数３９］
１７．８９≦Ｘ≦２９．４７ （４－４） [Number 36]
X + Y + Z = 100 (4-1)
[Number 37]
X + 2.00Y-105.74≤0 (4-2)
[Number 38]
X + 2.00Y-89.47 ≦ 0 (4-3)
[Number 39]
17.89 ≤ X ≤ 29.47 (4-4)
図８は、主剤におけるリン酸三ナトリウム１２水和物の含有量が略１５質量％のときの、三種組成物中の、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、及び炭酸ナトリウム１０水和物の含有量の三元系組成図である。図８中のＮＳ、ＮＨ、及びＮＣは、図５と同じである。図８に示す矩形Ｒ４及びその内部は、上記式（４－１）～（４－４）を満たす範囲である。
FIG. 8 shows sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, and disodium hydrogen phosphate dodecahydrate in the three compositions when the content of trisodium phosphate dodecahydrate in the main agent is approximately 15% by mass. It is a ternary composition diagram of the content of sodium carbonate decahydrate. NS, NH, and NC in FIG. 8 are the same as those in FIG. The rectangle R 4 shown in FIG. 8 and the inside thereof are in a range satisfying the above equations (4-1) to (4-4).
リン酸三ナトリウム１２水和物の含有量が１４．５～１５．５質量％の場合に、上記Ｘ、Ｙ、及びＺが式（４－１）～（４－４）を満たすと、蓄熱材組成物の融点が２０～２２．５℃の範囲内にあり、５℃幅融解潜熱が１６０Ｊ／ｇ以上になりやすい。
When the content of trisodium phosphate dodecahydrate is 14.5 to 15.5% by mass and the above X, Y, and Z satisfy the formulas (4-1) to (4-4), heat storage The melting point of the material composition is in the range of 20 to 22.5 ° C., and the latent heat of melting at 5 ° C. tends to be 160 J / g or more.
＜主剤中の組成＞
蓄熱材組成物では、Ｘ、Ｙ、Ｚ、及びＷが下記式（５－１）～（５－７）を満たすことが好ましい。ここで、Ｘ、Ｙ、及びＺは、主剤１００質量％中の、硫酸ナトリウム１０水和物の含有量をＸ質量％、リン酸水素二ナトリウム１２水和物の含有量をＹ質量％、及び炭酸ナトリウム１０水和物の含有量をＺ質量％と規定するときの値である。また、Ｗは、主剤１００質量％中の、リン酸三ナトリウム１２水和物の含有量をＷ質量％と規定するときの値である。 <Composition in the main agent>
In the heat storage material composition, it is preferable that X, Y, Z, and W satisfy the following formulas (5-1) to (5-7). Here, for X, Y, and Z, the content of sodium sulfate decahydrate in 100% by mass of the main agent is X% by mass, the content of disodium hydrogen phosphate dodecahydrate is Y% by mass, and It is a value when the content of sodium carbonate decahydrate is defined as Z mass%. Further, W is a value when the content of trisodium phosphate dodecahydrate in 100% by mass of the main agent is defined as W% by mass.
蓄熱材組成物では、Ｘ、Ｙ、Ｚ、及びＷが下記式（５－１）～（５－７）を満たすことが好ましい。ここで、Ｘ、Ｙ、及びＺは、主剤１００質量％中の、硫酸ナトリウム１０水和物の含有量をＸ質量％、リン酸水素二ナトリウム１２水和物の含有量をＹ質量％、及び炭酸ナトリウム１０水和物の含有量をＺ質量％と規定するときの値である。また、Ｗは、主剤１００質量％中の、リン酸三ナトリウム１２水和物の含有量をＷ質量％と規定するときの値である。 <Composition in the main agent>
In the heat storage material composition, it is preferable that X, Y, Z, and W satisfy the following formulas (5-1) to (5-7). Here, for X, Y, and Z, the content of sodium sulfate decahydrate in 100% by mass of the main agent is X% by mass, the content of disodium hydrogen phosphate dodecahydrate is Y% by mass, and It is a value when the content of sodium carbonate decahydrate is defined as Z mass%. Further, W is a value when the content of trisodium phosphate dodecahydrate in 100% by mass of the main agent is defined as W% by mass.
［数４０］
Ｘ＋Ｙ＋Ｚ＋Ｗ＝１００ （５－１）
［数４１］
Ｘ－３．１３０４Ｙ＋５．１３０４Ｚ≧０ （５－２）
［数４２］
Ｘ－０．２１７９Ｙ－０．２１７９Ｚ≧０ （５－３）
［数４３］
Ｘ＋１０．５０００Ｙ－８．５０００Ｚ≧０ （５－４）
［数４４］
Ｘ－０．４１７９Ｙ－０．４１７９Ｚ≦０ （５－５）
［数４５］
Ｘ＋０．５８３７Ｙ＋１．４１６３Ｚ－８３．１７６≧０（５－６）
［数４６］
４．８≦Ｗ≦１５．２ （５－７） [Number 40]
X + Y + Z + W = 100 (5-1)
[Number 41]
X-3.1304Y + 5.1304Z ≧ 0 (5-2)
[Number 42]
X-0.2179Y-0.2179Z ≧ 0 (5-3)
[Number 43]
X + 10.5000Y-85000Z ≧ 0 (5-4)
[Number 44]
X-0.4179Y-0.4179Z ≦ 0 (5-5)
[Number 45]
X + 0.5837Y + 1.4163Z-83.176 ≧ 0 (5-6)
[Number 46]
4.8 ≤ W ≤ 15.2 (5-7)
Ｘ＋Ｙ＋Ｚ＋Ｗ＝１００ （５－１）
［数４１］
Ｘ－３．１３０４Ｙ＋５．１３０４Ｚ≧０ （５－２）
［数４２］
Ｘ－０．２１７９Ｙ－０．２１７９Ｚ≧０ （５－３）
［数４３］
Ｘ＋１０．５０００Ｙ－８．５０００Ｚ≧０ （５－４）
［数４４］
Ｘ－０．４１７９Ｙ－０．４１７９Ｚ≦０ （５－５）
［数４５］
Ｘ＋０．５８３７Ｙ＋１．４１６３Ｚ－８３．１７６≧０（５－６）
［数４６］
４．８≦Ｗ≦１５．２ （５－７） [Number 40]
X + Y + Z + W = 100 (5-1)
[Number 41]
X-3.1304Y + 5.1304Z ≧ 0 (5-2)
[Number 42]
X-0.2179Y-0.2179Z ≧ 0 (5-3)
[Number 43]
X + 10.5000Y-85000Z ≧ 0 (5-4)
[Number 44]
X-0.4179Y-0.4179Z ≦ 0 (5-5)
[Number 45]
X + 0.5837Y + 1.4163Z-83.176 ≧ 0 (5-6)
[Number 46]
4.8 ≤ W ≤ 15.2 (5-7)
蓄熱材組成物は、Ｘ、Ｙ、Ｚ、及びＷが式（５－１）～（５－７）を満たすと、蓄熱材組成物の融点が２０～２２．５℃の範囲内にあり、５℃幅融解潜熱が１６０Ｊ／ｇ以上になりやすい。
In the heat storage material composition, when X, Y, Z, and W satisfy the formulas (5-1) to (5-7), the melting point of the heat storage material composition is in the range of 20 to 22.5 ° C. Latent heat for melting at 5 ° C. tends to be 160 J / g or more.
図９は、主剤中の、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、炭酸ナトリウム１０水和物、及びリン酸三ナトリウム１２水和物の含有量の四元系組成図の一例である。具体的には、図９は、式（５－１）～（５－７）を満たす三次元領域Ｑを示す図である。図９において、三次元領域Ｑ内が、式（５－１）～（５－７）を満たす領域である。なお、図９中、ＮＳ、ＮＨ、及びＮＣは図５と同じであり、ＮＰはリン酸三ナトリウム１２水和物が１００％になる点を示す。
FIG. 9 is a quaternary composition diagram of the contents of sodium sulfate tetrahydrate, disodium hydrogen phosphate dodecahydrate, sodium carbonate decahydrate, and trisodium phosphate dodecahydrate in the main agent. This is an example. Specifically, FIG. 9 is a diagram showing a three-dimensional region Q satisfying equations (5-1) to (5-7). In FIG. 9, the three-dimensional region Q is a region satisfying equations (5-1) to (5-7). In FIG. 9, NS, NH, and NC are the same as in FIG. 5, and NP indicates that trisodium phosphate dodecahydrate is 100%.
三次元領域をＱについて、詳細に説明する。図１０は、図９中の領域Ｑを拡大した図である。領域Ｑは、五角柱状の領域であり、対向して配置された五角形の平面ＦＢＣＯＮと平面ＥＡＤＰＭとの間を、平面ＡＢＣＤ、平面ＤＣＯＰ、平面ＭＮＯＰ、平面ＥＦＮＭ及び平面ＡＢＦＥで囲んだ形状になっている。なお、図１０に示す平面ＥＦＧＨ及び平面ＩＪＫＬは、共に、平面ＡＢＣＤ及び平面ＭＮＯＰと平行な面になっている。
The three-dimensional area will be explained in detail about Q. FIG. 10 is an enlarged view of the region Q in FIG. The region Q is a pentagonal columnar region, and has a shape in which a pentagonal plane FBCON and a plane EADPM arranged opposite to each other are surrounded by a plane ABCD, a plane DCOP, a plane MNOP, a plane EFNM, and a plane ABFE. There is. The plane EFGH and the plane IJKL shown in FIG. 10 are both parallel to the plane ABCD and the plane MNOP.
平面ＡＢＣＤは、主剤におけるリン酸三ナトリウム１２水和物の含有量が略５質量％のときの、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、及び炭酸ナトリウム１０水和物の含有量の三元系組成図、が存在する平面である。
Planar ABCDs are sodium sulfate tetrahydrate, disodium hydrogen phosphate dodecahydrate, and sodium carbonate tetrahydrate when the content of trisodium phosphate dodecahydrate in the main agent is approximately 5% by mass. It is a plane in which a ternary composition diagram of the content of is present.
平面ＥＦＧＨは、主剤におけるリン酸三ナトリウム１２水和物の含有量が略７．５質量％のときの、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、及び炭酸ナトリウム１０水和物の含有量の三元系組成図、が存在する平面である。
Plane EFGH refers to sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, and sodium carbonate 10 water when the content of trisodium phosphate dodecahydrate in the main agent is approximately 7.5% by mass. It is a plane in which a ternary composition diagram of the content of Japanese products exists.
平面ＩＪＫＬは、主剤におけるリン酸三ナトリウム１２水和物の含有量が略１０質量％のときの、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、及び炭酸ナトリウム１０水和物の含有量の三元系組成図、が存在する平面である。
Plane IJKL is a sodium sulfate tetrahydrate, a disodium hydrogen phosphate dodecahydrate, and a sodium carbonate decahydrate when the content of trisodium phosphate dodecahydrate in the main agent is approximately 10% by mass. It is a plane in which a ternary composition diagram of the content of is present.
平面ＭＮＯＰは、主剤におけるリン酸三ナトリウム１２水和物の含有量が略１５質量％のときの、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、及び炭酸ナトリウム１０水和物の含有量の三元系組成図、が存在する平面である。
Planar MNOPs are sodium sulfate tetrahydrate, disodium hydrogen phosphate dodecahydrate, and sodium carbonate tetrahydrate when the content of trisodium phosphate dodecahydrate in the main agent is approximately 15% by mass. It is a plane in which a ternary composition diagram of the content of is present.
図１１は、図９の全プロットのうち、図１０の平面ＡＢＣＤと略同一平面にあるプロットのみを示した図である。具体的には、図１１は、図９に示す全プロットのうち図１０の平面ＡＢＣＤと略同一平面にあるプロットのみを、図９の点ＮＰから領域Ｑを見たときの図である。
FIG. 11 is a diagram showing only the plots on substantially the same plane as the plane ABCD of FIG. 10 among all the plots of FIG. Specifically, FIG. 11 is a diagram when the region Q is viewed from the point NP of FIG. 9 only for the plots that are substantially on the same plane as the plane ABCD of FIG. 10 among all the plots shown in FIG.
図１２は、図９の全プロットのうち、図１０の平面ＥＦＧＨと略同一平面にあるプロットのみを示した図である。具体的には、図１２は、図９に示す全プロットのうち図１０の平面ＥＦＧＨと略同一平面にあるプロットのみを、図９の点ＮＰから領域Ｑを見たときの図である。
FIG. 12 is a diagram showing only plots that are substantially on the same plane as the plane EFGH of FIG. 10 among all the plots of FIG. Specifically, FIG. 12 is a diagram when the region Q is viewed from the point NP of FIG. 9 only for the plots that are substantially on the same plane as the plane EFGH of FIG. 10 among all the plots shown in FIG.
図１３は、図９の全プロットのうち、図１０の平面ＩＪＫＬと略同一平面にあるプロットのみを示した図である。具体的には、図１３は、図９に示す全プロットのうち図１０の平面ＩＪＫＬと略同一平面にあるプロットのみを、図９の点ＮＰから領域Ｑを見たときの図である。
FIG. 13 is a diagram showing only the plots that are substantially on the same plane as the plane IJKL of FIG. 10 among all the plots of FIG. Specifically, FIG. 13 is a diagram when the area Q is viewed from the point NP of FIG. 9 only for the plots that are substantially on the same plane as the plane IJKL of FIG. 10 among all the plots shown in FIG.
図１４は、図９の全プロットのうち、図１０の平面ＭＮＯＰと略同一平面にあるプロットのみを示した図である。具体的には、図１４は、図９に示す全プロットのうち図１０の平面ＭＮＯＰと略同一平面にあるプロットのみを、図９の点ＮＰから領域Ｑを見たときの図である。
FIG. 14 is a diagram showing only the plots that are substantially on the same plane as the plane MNOP of FIG. 10 among all the plots of FIG. Specifically, FIG. 14 is a diagram when the region Q is viewed from the point NP of FIG. 9 only for the plots that are substantially on the same plane as the plane MNOP of FIG. 10 among all the plots shown in FIG.
（余剰水）
本実施形態に係る蓄熱材組成物は、必要により余剰水をさらに含んでいてもよい。本明細書では、主剤と余剰水とからなる混合物を主剤混合物と定義する。本実施形態に係る蓄熱材組成物において、余剰水は、主剤１００質量部に対して、通常９質量部以下、好ましくは３質量部以下含まれる。 (Surplus water)
The heat storage material composition according to the present embodiment may further contain excess water, if necessary. In the present specification, a mixture consisting of a main agent and excess water is defined as a main agent mixture. In the heat storage material composition according to the present embodiment, excess water is usually contained in an amount of 9 parts by mass or less, preferably 3 parts by mass or less, based on 100 parts by mass of the main agent.
本実施形態に係る蓄熱材組成物は、必要により余剰水をさらに含んでいてもよい。本明細書では、主剤と余剰水とからなる混合物を主剤混合物と定義する。本実施形態に係る蓄熱材組成物において、余剰水は、主剤１００質量部に対して、通常９質量部以下、好ましくは３質量部以下含まれる。 (Surplus water)
The heat storage material composition according to the present embodiment may further contain excess water, if necessary. In the present specification, a mixture consisting of a main agent and excess water is defined as a main agent mixture. In the heat storage material composition according to the present embodiment, excess water is usually contained in an amount of 9 parts by mass or less, preferably 3 parts by mass or less, based on 100 parts by mass of the main agent.
本実施形態に係る蓄熱材組成物における余剰水の含有量が上記範囲内にあると、蓄熱材組成物の融点が２０～２２．５℃の範囲内になりやすく、５℃幅融解潜熱が１６０Ｊ／ｇ以上になりやすい。本実施形態に係る蓄熱材組成物における余剰水の含有量が９質量部を超えると、蓄熱材組成物の蓄熱量が小さくなるおそれがある。
When the content of excess water in the heat storage material composition according to the present embodiment is within the above range, the melting point of the heat storage material composition tends to be in the range of 20 to 22.5 ° C., and the latent heat of melting in a width of 5 ° C. is 160J. It tends to be / g or more. If the content of excess water in the heat storage material composition according to the present embodiment exceeds 9 parts by mass, the heat storage amount of the heat storage material composition may decrease.
（保湿剤）
本実施形態に係る蓄熱材組成物は、特定の保湿剤をさらに含むと、主剤が保湿下で保存されるため好ましい。特定の保湿剤は、特定の単量体と、多官能性単量体と、を重合させて得られる。 (Moisturizer)
It is preferable that the heat storage material composition according to the present embodiment further contains a specific moisturizer because the main agent is stored under moisturizer. A specific moisturizer is obtained by polymerizing a specific monomer and a polyfunctional monomer.
本実施形態に係る蓄熱材組成物は、特定の保湿剤をさらに含むと、主剤が保湿下で保存されるため好ましい。特定の保湿剤は、特定の単量体と、多官能性単量体と、を重合させて得られる。 (Moisturizer)
It is preferable that the heat storage material composition according to the present embodiment further contains a specific moisturizer because the main agent is stored under moisturizer. A specific moisturizer is obtained by polymerizing a specific monomer and a polyfunctional monomer.
＜単量体＞
特定の単量体としては、有機不飽和カルボン酸、有機不飽和スルホン酸、有機不飽和リン酸、有機不飽和アミド、有機不飽和アルコール、有機不飽和カルボン酸塩、有機不飽和スルホン酸塩、及び有機不飽和リン酸塩からなる群より選択される少なくとも１種の単量体が用いられる。 <Monomer>
Specific monomers include organic unsaturated carboxylic acids, organic unsaturated sulfonic acids, organic unsaturated phosphates, organic unsaturated amides, organic unsaturated alcohols, organic unsaturated carboxylic acids, and organic unsaturated sulfonic acids. And at least one monomer selected from the group consisting of organic unsaturated phosphates is used.
特定の単量体としては、有機不飽和カルボン酸、有機不飽和スルホン酸、有機不飽和リン酸、有機不飽和アミド、有機不飽和アルコール、有機不飽和カルボン酸塩、有機不飽和スルホン酸塩、及び有機不飽和リン酸塩からなる群より選択される少なくとも１種の単量体が用いられる。 <Monomer>
Specific monomers include organic unsaturated carboxylic acids, organic unsaturated sulfonic acids, organic unsaturated phosphates, organic unsaturated amides, organic unsaturated alcohols, organic unsaturated carboxylic acids, and organic unsaturated sulfonic acids. And at least one monomer selected from the group consisting of organic unsaturated phosphates is used.
有機不飽和カルボン酸としては、例えば、アクリル酸、メタクリル酸及びイタコン酸からなる群より選択される１種以上の不飽和カルボン酸が用いられ、好ましくはアクリル酸が用いられる。
As the organic unsaturated carboxylic acid, for example, one or more unsaturated carboxylic acids selected from the group consisting of acrylic acid, methacrylic acid and itaconic acid are used, and acrylic acid is preferably used.
有機不飽和スルホン酸としては、例えば、２－アクリルアミド－２－メチルプロパンスルホン酸、ｐ－スチレンスルホン酸、スルホエチルメタクリレート、アリルスルホン酸及びメタアリルスルホン酸からなる群より選択される１種以上の有機不飽和スルホン酸が用いられる。
The organic unsaturated sulfonic acid is, for example, one or more selected from the group consisting of 2-acrylamide-2-methylpropanesulfonic acid, p-styrenesulfonic acid, sulfoethylmethacrylate, allylsulfonic acid and metaallylsulfonic acid. Organic unsaturated sulfonic acid is used.
有機不飽和カルボン酸塩としては、例えば上記不飽和カルボン酸のアルカリ金属塩やアンモニウム塩が用いられる。上記不飽和カルボン酸のアルカリ金属塩としては、例えば、上記不飽和カルボン酸のナトリウム塩が用いられる。上記不飽和カルボン酸のナトリウム塩としては、好ましくは、アクリル酸ナトリウム、メタクリル酸ナトリウムが用いられる。
As the organic unsaturated carboxylic acid salt, for example, an alkali metal salt or an ammonium salt of the above unsaturated carboxylic acid is used. As the alkali metal salt of the unsaturated carboxylic acid, for example, the sodium salt of the unsaturated carboxylic acid is used. As the sodium salt of the unsaturated carboxylic acid, sodium acrylate and sodium methacrylate are preferably used.
有機不飽和スルホン酸塩としては、例えば、上記有機不飽和スルホン酸のアルカリ金属塩やアンモニウム塩が用いられる。上記有機不飽和スルホン酸のアルカリ金属塩としては、例えば、上記有機不飽和スルホン酸のナトリウム塩が用いられる。
As the organic unsaturated sulfonic acid salt, for example, an alkali metal salt or an ammonium salt of the above organic unsaturated sulfonic acid is used. As the alkali metal salt of the organic unsaturated sulfonic acid, for example, the sodium salt of the organic unsaturated sulfonic acid is used.
上記特定の単量体は、そのまま重合すると特定の単量体が重合した重合体を形成する。
When the above-mentioned specific monomer is polymerized as it is, a polymer in which the specific monomer is polymerized is formed.
＜多官能性単量体＞
多官能性単量体は、特定の単量体が重合した重合体を架橋させるものである。多官能性単量体としては、例えば、Ｎ，Ｎ’－メチレンビスアクリルアミド、Ｎ，Ｎ’－メチレンビスメタクリルアミド、Ｎ，Ｎ’－ジメチレンビスアクリルアミド、Ｎ，Ｎ’－ジメチレンビスメタクリルアミドが用いられ、好ましくはＮ，Ｎ’－メチレンビスアクリルアミド又はＮ，Ｎ’－メチレンビスメタクリルアミドが用いられる。 <Polyfunctional monomer>
The polyfunctional monomer crosslinks a polymer obtained by polymerizing a specific monomer. Examples of the polyfunctional monomer include N, N'-methylenebisacrylamide, N, N'-methylenebismethacrylamide, N, N'-dimethylenebisacrylamide, N, N'-dimethylenebismethacrylate. Is used, preferably N, N'-methylenebisacrylamide or N, N'-methylenebismethacrylamide is used.
多官能性単量体は、特定の単量体が重合した重合体を架橋させるものである。多官能性単量体としては、例えば、Ｎ，Ｎ’－メチレンビスアクリルアミド、Ｎ，Ｎ’－メチレンビスメタクリルアミド、Ｎ，Ｎ’－ジメチレンビスアクリルアミド、Ｎ，Ｎ’－ジメチレンビスメタクリルアミドが用いられ、好ましくはＮ，Ｎ’－メチレンビスアクリルアミド又はＮ，Ｎ’－メチレンビスメタクリルアミドが用いられる。 <Polyfunctional monomer>
The polyfunctional monomer crosslinks a polymer obtained by polymerizing a specific monomer. Examples of the polyfunctional monomer include N, N'-methylenebisacrylamide, N, N'-methylenebismethacrylamide, N, N'-dimethylenebisacrylamide, N, N'-dimethylenebismethacrylate. Is used, preferably N, N'-methylenebisacrylamide or N, N'-methylenebismethacrylamide is used.
（融点降下剤）
本実施形態に係る蓄熱材組成物は、特定の融点降下剤をさらに含むと、主剤の融点が降下するため好ましい。融点降下剤としては、例えば、塩化ナトリウム、塩化カリウム、硝酸ナトリウム、臭化ナトリウム、塩化アンモニウム、臭化アンモニウム、硫酸アンモニウム、硝酸アンモニウム、リン酸アンモニウム、及び尿素からなる群より選択される少なくとも１種の融点降下剤が用いられる。 (Melting point lowering agent)
It is preferable that the heat storage material composition according to the present embodiment further contains a specific melting point lowering agent because the melting point of the main agent is lowered. As the melting point lowering agent, for example, at least one melting point selected from the group consisting of sodium chloride, potassium chloride, sodium nitrate, sodium bromide, ammonium chloride, ammonium bromide, ammonium sulfate, ammonium nitrate, ammonium phosphate, and urea. A lowering agent is used.
本実施形態に係る蓄熱材組成物は、特定の融点降下剤をさらに含むと、主剤の融点が降下するため好ましい。融点降下剤としては、例えば、塩化ナトリウム、塩化カリウム、硝酸ナトリウム、臭化ナトリウム、塩化アンモニウム、臭化アンモニウム、硫酸アンモニウム、硝酸アンモニウム、リン酸アンモニウム、及び尿素からなる群より選択される少なくとも１種の融点降下剤が用いられる。 (Melting point lowering agent)
It is preferable that the heat storage material composition according to the present embodiment further contains a specific melting point lowering agent because the melting point of the main agent is lowered. As the melting point lowering agent, for example, at least one melting point selected from the group consisting of sodium chloride, potassium chloride, sodium nitrate, sodium bromide, ammonium chloride, ammonium bromide, ammonium sulfate, ammonium nitrate, ammonium phosphate, and urea. A lowering agent is used.
（過冷却抑制剤）
本実施形態に係る蓄熱材組成物は、特定の過冷却抑制剤をさらに含むと、主剤の過冷却が抑制されるため好ましい。過冷却抑制剤としては、例えば、ホウ砂Ｎａ２Ｂ４Ｏ５（ＯＨ）４・８Ｈ２Ｏ、水酸化カルシウム、水酸化バリウム、水酸化ストロンチウム、水酸化アルミニウム、黒鉛、アルミニウム、二酸化チタン、二酸化ケイ素、リン酸ドデシルナトリウム、ドデシル硫酸ナトリウム、カルボキシメチルセルロースナトリウム、リグニンスルホン酸、ヘクトライト、スメクタイトクレイ、ベントナイト、ラポナイト、プロピレングリコール、エチレングリコール、グリセリン、エチレンジアミン四酢酸、アルキル硫酸ナトリウム、アルキルリン酸ナトリウム、アルキル硫酸カリウム、及びアルキルリン酸カリウムからなる群より選択される少なくとも１種の過冷却抑制剤が用いられる。 (Supercooling inhibitor)
It is preferable that the heat storage material composition according to the present embodiment further contains a specific supercooling inhibitor because the supercooling of the main agent is suppressed. The supercooling inhibitor, for example, borax Na 2 B 4 O 5 (OH ) 4 · 8H 2 O, calcium hydroxide, barium hydroxide, strontium hydroxide, aluminum hydroxide, graphite, aluminum, titanium dioxide, Silicon, sodium dodecyl phosphate, sodium dodecyl sulfate, sodium carboxymethyl cellulose, lignin sulfonic acid, hectrite, smectite clay, bentonite, laponite, propylene glycol, ethylene glycol, glycerin, ethylenediamine tetraacetic acid, sodium alkylsulfate, sodium alkylphosphate, At least one supercooling inhibitor selected from the group consisting of potassium alkyl sulfate and potassium alkyl phosphate is used.
本実施形態に係る蓄熱材組成物は、特定の過冷却抑制剤をさらに含むと、主剤の過冷却が抑制されるため好ましい。過冷却抑制剤としては、例えば、ホウ砂Ｎａ２Ｂ４Ｏ５（ＯＨ）４・８Ｈ２Ｏ、水酸化カルシウム、水酸化バリウム、水酸化ストロンチウム、水酸化アルミニウム、黒鉛、アルミニウム、二酸化チタン、二酸化ケイ素、リン酸ドデシルナトリウム、ドデシル硫酸ナトリウム、カルボキシメチルセルロースナトリウム、リグニンスルホン酸、ヘクトライト、スメクタイトクレイ、ベントナイト、ラポナイト、プロピレングリコール、エチレングリコール、グリセリン、エチレンジアミン四酢酸、アルキル硫酸ナトリウム、アルキルリン酸ナトリウム、アルキル硫酸カリウム、及びアルキルリン酸カリウムからなる群より選択される少なくとも１種の過冷却抑制剤が用いられる。 (Supercooling inhibitor)
It is preferable that the heat storage material composition according to the present embodiment further contains a specific supercooling inhibitor because the supercooling of the main agent is suppressed. The supercooling inhibitor, for example, borax Na 2 B 4 O 5 (OH ) 4 · 8H 2 O, calcium hydroxide, barium hydroxide, strontium hydroxide, aluminum hydroxide, graphite, aluminum, titanium dioxide, Silicon, sodium dodecyl phosphate, sodium dodecyl sulfate, sodium carboxymethyl cellulose, lignin sulfonic acid, hectrite, smectite clay, bentonite, laponite, propylene glycol, ethylene glycol, glycerin, ethylenediamine tetraacetic acid, sodium alkylsulfate, sodium alkylphosphate, At least one supercooling inhibitor selected from the group consisting of potassium alkyl sulfate and potassium alkyl phosphate is used.
（相分離抑制剤）
本実施形態に係る蓄熱材組成物は、特定の相分離抑制剤をさらに含むと、主剤の相分離が抑制されるため好ましい。相分離抑制剤としては、例えば、ケイ酸ナトリウム、水ガラス、ポリアクリル酸、ポリアクリル酸ナトリウム、ポリカルボキシレートポリエーテルポリマー、アクリル酸・マイレン酸共重合体ナトリウム、アクリル酸・スルホン酸系モノマー共重合体ナトリウム、アクリルアミド・ジメチルアミノエチルメタクリラートジメチル硫酸塩共重合物、アクリルアミド・アクリル酸ソーダ共重合物、ポリエチレングリコール、ポリプロピレングリコール、高吸水樹脂（ＳＡＰ）、カルボキシメチルセルロース（ＣＭＣ)、ＣＭＣの誘導体、カラギーナン、カラギーナンの誘導体、キサンタンガム、キサンタンガムの誘導体、ペクチン、ペクチンの誘導体、デンプン、デンプンの誘導体、コンニャク、寒天、層状ケイ酸塩、及び上記物質の複合物質からなる群より選択される少なくとも１種の相分離抑制剤が用いられる。 (Phase separation inhibitor)
It is preferable that the heat storage material composition according to the present embodiment further contains a specific phase separation inhibitor because the phase separation of the main agent is suppressed. Examples of the phase separation inhibitor include sodium silicate, water glass, polyacrylic acid, sodium polyacrylate, polycarboxylate polyether polymer, acrylic acid / maleic acid copolymer sodium, and acrylic acid / sulfonic acid-based monomer. Polymer sodium, acrylamide / dimethylaminoethyl methacrylate dimethyl sulfate copolymer, acrylamide / sodium acrylate copolymer, polyethylene glycol, polypropylene glycol, high water absorption resin (SAP), carboxymethyl cellulose (CMC), derivative of CMC, At least one selected from the group consisting of carrageenan, carrageenan derivatives, xanthan gum, xanthan gum derivatives, pectin, pectin derivatives, starch, starch derivatives, konjak, agar, layered silicates, and composites of the above substances. A phase separation inhibitor is used.
本実施形態に係る蓄熱材組成物は、特定の相分離抑制剤をさらに含むと、主剤の相分離が抑制されるため好ましい。相分離抑制剤としては、例えば、ケイ酸ナトリウム、水ガラス、ポリアクリル酸、ポリアクリル酸ナトリウム、ポリカルボキシレートポリエーテルポリマー、アクリル酸・マイレン酸共重合体ナトリウム、アクリル酸・スルホン酸系モノマー共重合体ナトリウム、アクリルアミド・ジメチルアミノエチルメタクリラートジメチル硫酸塩共重合物、アクリルアミド・アクリル酸ソーダ共重合物、ポリエチレングリコール、ポリプロピレングリコール、高吸水樹脂（ＳＡＰ）、カルボキシメチルセルロース（ＣＭＣ)、ＣＭＣの誘導体、カラギーナン、カラギーナンの誘導体、キサンタンガム、キサンタンガムの誘導体、ペクチン、ペクチンの誘導体、デンプン、デンプンの誘導体、コンニャク、寒天、層状ケイ酸塩、及び上記物質の複合物質からなる群より選択される少なくとも１種の相分離抑制剤が用いられる。 (Phase separation inhibitor)
It is preferable that the heat storage material composition according to the present embodiment further contains a specific phase separation inhibitor because the phase separation of the main agent is suppressed. Examples of the phase separation inhibitor include sodium silicate, water glass, polyacrylic acid, sodium polyacrylate, polycarboxylate polyether polymer, acrylic acid / maleic acid copolymer sodium, and acrylic acid / sulfonic acid-based monomer. Polymer sodium, acrylamide / dimethylaminoethyl methacrylate dimethyl sulfate copolymer, acrylamide / sodium acrylate copolymer, polyethylene glycol, polypropylene glycol, high water absorption resin (SAP), carboxymethyl cellulose (CMC), derivative of CMC, At least one selected from the group consisting of carrageenan, carrageenan derivatives, xanthan gum, xanthan gum derivatives, pectin, pectin derivatives, starch, starch derivatives, konjak, agar, layered silicates, and composites of the above substances. A phase separation inhibitor is used.
（特性）
本実施形態に係る蓄熱材組成物は、融点が２０～２２．５℃の範囲内にあり、建造物の冷暖房の一般的な設定温度よりやや低めの温度領域で融解・凝固が生じる。また、本実施形態に係る蓄熱材組成物は、５℃幅融解潜熱が１６０Ｊ／ｇ以上であり、狭い温度領域内での融解潜熱が大きい。このため、本実施形態に係る蓄熱材組成物は、建造物の冷暖房用の蓄熱システムの潜熱蓄熱材組成物として好適である。 (Characteristic)
The heat storage material composition according to the present embodiment has a melting point in the range of 20 to 22.5 ° C., and melting and solidification occur in a temperature range slightly lower than the general set temperature for heating and cooling of buildings. Further, the heat storage material composition according to the present embodiment has a latent heat of melting at a width of 5 ° C. of 160 J / g or more, and the latent heat of melting in a narrow temperature region is large. Therefore, the heat storage material composition according to the present embodiment is suitable as a latent heat storage material composition for a heat storage system for heating and cooling a building.
本実施形態に係る蓄熱材組成物は、融点が２０～２２．５℃の範囲内にあり、建造物の冷暖房の一般的な設定温度よりやや低めの温度領域で融解・凝固が生じる。また、本実施形態に係る蓄熱材組成物は、５℃幅融解潜熱が１６０Ｊ／ｇ以上であり、狭い温度領域内での融解潜熱が大きい。このため、本実施形態に係る蓄熱材組成物は、建造物の冷暖房用の蓄熱システムの潜熱蓄熱材組成物として好適である。 (Characteristic)
The heat storage material composition according to the present embodiment has a melting point in the range of 20 to 22.5 ° C., and melting and solidification occur in a temperature range slightly lower than the general set temperature for heating and cooling of buildings. Further, the heat storage material composition according to the present embodiment has a latent heat of melting at a width of 5 ° C. of 160 J / g or more, and the latent heat of melting in a narrow temperature region is large. Therefore, the heat storage material composition according to the present embodiment is suitable as a latent heat storage material composition for a heat storage system for heating and cooling a building.
本実施形態に係る蓄熱材組成物は、５℃幅融解潜熱が１６０Ｊ／ｇ以上、好ましくは１７０～２２０Ｊ／ｇ、より好ましくは１８０～２２０Ｊ／ｇ、さらに好ましくは１９０～２２０Ｊ／ｇ、特に好ましくは２００～２２０Ｊ／ｇである。このため、本実施形態に係る蓄熱材組成物は、建造物の冷暖房用の蓄熱システムの潜熱蓄熱材組成物として好適である。
The heat storage material composition according to the present embodiment has a 5 ° C. width melting latent heat of 160 J / g or more, preferably 170 to 220 J / g, more preferably 180 to 220 J / g, still more preferably 190 to 220 J / g, and particularly preferably. Is 200 to 220 J / g. Therefore, the heat storage material composition according to the present embodiment is suitable as a latent heat storage material composition for a heat storage system for heating and cooling a building.
（発明の効果）
本実施形態に係る蓄熱材組成物によれば、融点が２０～２２．５℃の範囲内にあり、５℃幅融解潜熱が１６０Ｊ／ｇ以上である蓄熱材組成物が得られる。 (The invention's effect)
According to the heat storage material composition according to the present embodiment, a heat storage material composition having a melting point in the range of 20 to 22.5 ° C. and a latent heat of melting in a width of 5 ° C. of 160 J / g or more can be obtained.
本実施形態に係る蓄熱材組成物によれば、融点が２０～２２．５℃の範囲内にあり、５℃幅融解潜熱が１６０Ｊ／ｇ以上である蓄熱材組成物が得られる。 (The invention's effect)
According to the heat storage material composition according to the present embodiment, a heat storage material composition having a melting point in the range of 20 to 22.5 ° C. and a latent heat of melting in a width of 5 ° C. of 160 J / g or more can be obtained.
［建築物の冷暖房用の蓄熱システム］
本実施形態に係る建築物の冷暖房用の蓄熱システムは、上記本実施形態に係る蓄熱材組成物を用いた蓄熱材モジュールを具備する。 [Heat storage system for heating and cooling of buildings]
The heat storage system for heating and cooling a building according to the present embodiment includes a heat storage material module using the heat storage material composition according to the present embodiment.
本実施形態に係る建築物の冷暖房用の蓄熱システムは、上記本実施形態に係る蓄熱材組成物を用いた蓄熱材モジュールを具備する。 [Heat storage system for heating and cooling of buildings]
The heat storage system for heating and cooling a building according to the present embodiment includes a heat storage material module using the heat storage material composition according to the present embodiment.
（蓄熱材モジュール）
蓄熱材モジュールとしては、例えば、前記蓄熱材組成物を十分な密封性を有する容器に充填させた蓄熱材パックからなり、この蓄熱材パックを単数ないしは複数積層させるとともに、適切な流路を設け、モジュール化したものが用いられる。蓄熱材パックに用いる容器としては、例えば、アルミシートに樹脂製シートを積層して形成されたアルミパックシートを熱溶着することで形成されたアルミパック等が挙げられる。蓄熱材モジュールは、建造物中の空間を区切る床面、壁面、天井面の少なくとも一部に設置される。 (Heat storage material module)
The heat storage material module is composed of, for example, a heat storage material pack in which the heat storage material composition is filled in a container having sufficient sealing property, and one or more of the heat storage material packs are laminated and an appropriate flow path is provided. Modular ones are used. Examples of the container used for the heat storage material pack include an aluminum pack formed by heat-welding an aluminum pack sheet formed by laminating a resin sheet on an aluminum sheet. The heat storage module is installed on at least a part of the floor, wall surface, and ceiling surface that divides the space in the building.
蓄熱材モジュールとしては、例えば、前記蓄熱材組成物を十分な密封性を有する容器に充填させた蓄熱材パックからなり、この蓄熱材パックを単数ないしは複数積層させるとともに、適切な流路を設け、モジュール化したものが用いられる。蓄熱材パックに用いる容器としては、例えば、アルミシートに樹脂製シートを積層して形成されたアルミパックシートを熱溶着することで形成されたアルミパック等が挙げられる。蓄熱材モジュールは、建造物中の空間を区切る床面、壁面、天井面の少なくとも一部に設置される。 (Heat storage material module)
The heat storage material module is composed of, for example, a heat storage material pack in which the heat storage material composition is filled in a container having sufficient sealing property, and one or more of the heat storage material packs are laminated and an appropriate flow path is provided. Modular ones are used. Examples of the container used for the heat storage material pack include an aluminum pack formed by heat-welding an aluminum pack sheet formed by laminating a resin sheet on an aluminum sheet. The heat storage module is installed on at least a part of the floor, wall surface, and ceiling surface that divides the space in the building.
このように設置された蓄熱材モジュールは、モジュール表面とこのモジュール表面を通気した雰囲気との熱交換、日射による日射熱、夜間電力を利用した空調システム等によって蓄熱（蓄冷）される。例えば、昼間においては、蓄熱材モジュール中の蓄熱材組成物は、建造物中の空間から得た熱によって融解し、その分のエンタルピーを蓄熱材組成物の内部に保留する。その後、夜間に外気温度が下がってくると、融解していた蓄熱材組成物は凝固し、建造物中の空間へ熱を放出する。このように、蓄熱材モジュールを建物内に設置すると、蓄熱材組成物の融解・凝固の作用により、冷暖房のためのエネルギー負荷を低減することができる。
The heat storage material module installed in this way is stored (cold) by heat exchange between the module surface and the atmosphere that ventilates the module surface, solar heat by solar radiation, and an air conditioning system that uses nighttime power. For example, in the daytime, the heat storage material composition in the heat storage material module is melted by the heat obtained from the space in the building, and the enthalpy corresponding to the heat is retained inside the heat storage material composition. After that, when the outside air temperature drops at night, the melted heat storage material composition solidifies and releases heat to the space inside the building. When the heat storage material module is installed in the building in this way, the energy load for heating and cooling can be reduced by the action of melting and solidifying the heat storage material composition.
（発明の効果）
本実施形態に係る蓄熱材システムによれば、モジュール表面とこのモジュール表面を通気した雰囲気との熱交換、日射による日射熱、夜間電力を利用した空調システム等によって蓄熱（蓄冷）されるため、冷暖房のためのエネルギー負荷を低減することができる。 (The invention's effect)
According to the heat storage material system according to the present embodiment, heat is stored (cooled) by heat exchange between the module surface and the atmosphere in which the module surface is ventilated, solar heat by solar radiation, an air conditioning system using nighttime power, and the like. The energy load for can be reduced.
本実施形態に係る蓄熱材システムによれば、モジュール表面とこのモジュール表面を通気した雰囲気との熱交換、日射による日射熱、夜間電力を利用した空調システム等によって蓄熱（蓄冷）されるため、冷暖房のためのエネルギー負荷を低減することができる。 (The invention's effect)
According to the heat storage material system according to the present embodiment, heat is stored (cooled) by heat exchange between the module surface and the atmosphere in which the module surface is ventilated, solar heat by solar radiation, an air conditioning system using nighttime power, and the like. The energy load for can be reduced.
以下、本発明を実施例及び比較例により更に詳細に説明するが、本発明はこれら実施例に限定されるものではない。
Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited to these Examples.
［実施例１］（リン酸三ナトリウム１２水和物の含有量が略５質量％の場合）
（蓄熱材組成物の作製）
はじめに、Ｎａ２ＳＯ４・１０Ｈ２Ｏ（キシダ化学株式会社製、特級）と、Ｎａ２ＨＰＯ４・１２Ｈ２Ｏ（キシダ化学株式会社製、特級）と、Ｎａ２ＣＯ３・１０Ｈ２Ｏ（キシダ化学株式会社製、特級）とを用意した。また、Ｎａ３ＰＯ４・１２Ｈ２Ｏ（キシダ化学株式会社製、特級）も用意した。
次に、２０ｍｌのガラス製サンプル瓶に、Ｎａ２ＳＯ４・１０Ｈ２Ｏと、Ｎａ２ＨＰＯ４・１２Ｈ２Ｏと、Ｎａ２ＣＯ３・１０Ｈ２Ｏと、Ｎａ３ＰＯ４・１２Ｈ２Ｏと、純水とを、合計約５ｇになるように所定量混合した。
なお、Ｎａ２ＳＯ４・１０Ｈ２Ｏ、Ｎａ２ＨＰＯ４・１２Ｈ２Ｏ、Ｎａ２ＣＯ３・１０Ｈ２Ｏ、Ｎａ３ＰＯ４・１２Ｈ２Ｏ及び純水の量は、得られる蓄熱材組成物の組成が表１に示す組成になるような量で配合した。蓄熱材組成物は、主剤中のＮａ３ＰＯ４・１２Ｈ２Ｏの含有量が略５質量％になるように調製した。
また、三種組成物１００質量％中のＮａ２ＳＯ４・１０Ｈ２Ｏの含有量Ｘ質量％、Ｎａ２ＨＰＯ４・１２Ｈ２Ｏの含有量Ｙ質量％、及びＮａ２ＣＯ３・１０Ｈ２Ｏの含有量Ｚ質量％は、表１に示すとおりであった。
得られた混合物を５０℃以上で湯煎したところ、蓄熱材組成物が得られた（試料Ｎｏ．Ａ６）。 [Example 1] (When the content of trisodium phosphate dodecahydrate is approximately 5% by mass)
(Preparation of heat storage material composition)
First, Na 2 SO 4・ 10H 2 O (manufactured by Kishida Chemical Co., Ltd., special grade), Na 2 HPO 4・ 12H 2 O (manufactured by Kishida Chemical Co., Ltd., special grade), and Na 2 CO 3・ 10H 2 O (Kishida) Made by Chemical Co., Ltd., special grade) was prepared. Further, Na 3 PO 4 · 12H 2 O ( Kishida Chemical Co., Ltd., special grade) were also prepared.
Next, in a 20 ml glass sample bottle, Na 2 SO 4・ 10H 2 O, Na 2 HPO 4・ 12H 2 O, Na 2 CO 3・ 10H 2 O, and Na 3 PO 4・ 12H 2 O , Pure water and a predetermined amount were mixed so as to have a total of about 5 g.
The amounts of Na 2 SO 4・ 10H 2 O, Na 2 HPO 4・ 12H 2 O, Na 2 CO 3・ 10H 2 O, Na 3 PO 4・ 12H 2 O and pure water are the amounts of the obtained heat storage composition. Was blended in an amount such that the composition of was as shown in Table 1. Heat storage material composition, the content of Na 3 PO 4 · 12H 2 O in the main agent was prepared so as to be approximately 5% by weight.
The content of Na 2 SO 4 · 10H 2 O in threekinds composition 100 wt% X mass%, Na 2 HPO 4 · 12H 2 O content of Y weight percent, and Na 2 CO 3 · 10H 2 O in The content Z mass% was as shown in Table 1.
When the obtained mixture was boiled in hot water at 50 ° C. or higher, a heat storage material composition was obtained (Sample No. A6).
（蓄熱材組成物の作製）
はじめに、Ｎａ２ＳＯ４・１０Ｈ２Ｏ（キシダ化学株式会社製、特級）と、Ｎａ２ＨＰＯ４・１２Ｈ２Ｏ（キシダ化学株式会社製、特級）と、Ｎａ２ＣＯ３・１０Ｈ２Ｏ（キシダ化学株式会社製、特級）とを用意した。また、Ｎａ３ＰＯ４・１２Ｈ２Ｏ（キシダ化学株式会社製、特級）も用意した。
次に、２０ｍｌのガラス製サンプル瓶に、Ｎａ２ＳＯ４・１０Ｈ２Ｏと、Ｎａ２ＨＰＯ４・１２Ｈ２Ｏと、Ｎａ２ＣＯ３・１０Ｈ２Ｏと、Ｎａ３ＰＯ４・１２Ｈ２Ｏと、純水とを、合計約５ｇになるように所定量混合した。
なお、Ｎａ２ＳＯ４・１０Ｈ２Ｏ、Ｎａ２ＨＰＯ４・１２Ｈ２Ｏ、Ｎａ２ＣＯ３・１０Ｈ２Ｏ、Ｎａ３ＰＯ４・１２Ｈ２Ｏ及び純水の量は、得られる蓄熱材組成物の組成が表１に示す組成になるような量で配合した。蓄熱材組成物は、主剤中のＮａ３ＰＯ４・１２Ｈ２Ｏの含有量が略５質量％になるように調製した。
また、三種組成物１００質量％中のＮａ２ＳＯ４・１０Ｈ２Ｏの含有量Ｘ質量％、Ｎａ２ＨＰＯ４・１２Ｈ２Ｏの含有量Ｙ質量％、及びＮａ２ＣＯ３・１０Ｈ２Ｏの含有量Ｚ質量％は、表１に示すとおりであった。
得られた混合物を５０℃以上で湯煎したところ、蓄熱材組成物が得られた（試料Ｎｏ．Ａ６）。 [Example 1] (When the content of trisodium phosphate dodecahydrate is approximately 5% by mass)
(Preparation of heat storage material composition)
First, Na 2 SO 4・ 10H 2 O (manufactured by Kishida Chemical Co., Ltd., special grade), Na 2 HPO 4・ 12H 2 O (manufactured by Kishida Chemical Co., Ltd., special grade), and Na 2 CO 3・ 10H 2 O (Kishida) Made by Chemical Co., Ltd., special grade) was prepared. Further, Na 3 PO 4 · 12H 2 O ( Kishida Chemical Co., Ltd., special grade) were also prepared.
Next, in a 20 ml glass sample bottle, Na 2 SO 4・ 10H 2 O, Na 2 HPO 4・ 12H 2 O, Na 2 CO 3・ 10H 2 O, and Na 3 PO 4・ 12H 2 O , Pure water and a predetermined amount were mixed so as to have a total of about 5 g.
The amounts of Na 2 SO 4・ 10H 2 O, Na 2 HPO 4・ 12H 2 O, Na 2 CO 3・ 10H 2 O, Na 3 PO 4・ 12H 2 O and pure water are the amounts of the obtained heat storage composition. Was blended in an amount such that the composition of was as shown in Table 1. Heat storage material composition, the content of Na 3 PO 4 · 12H 2 O in the main agent was prepared so as to be approximately 5% by weight.
The content of Na 2 SO 4 · 10H 2 O in three
When the obtained mixture was boiled in hot water at 50 ° C. or higher, a heat storage material composition was obtained (Sample No. A6).
（融点及び５℃幅融解潜熱の測定）
蓄熱材組成物から約２０ｍｇ試料を採取し、ＤＳＣ（示差走査熱量計）を行い、蓄熱材組成物の融解下限温度Ｔｓ及び融解上限温度Ｔｆを測定した。得られた融解下限温度Ｔｓを融点とした。
また、ＤＳＣの吸熱ピークを用い、ある温度Ｔ１℃からＴ１＋５℃における蓄熱量の総量を算出した。そして、Ｔ１の値を変化させた場合の蓄熱量の総量の変化を求め、その場合の蓄熱量の総量が最大となる値を５℃幅融解潜熱とした。
融点及び５℃幅融解潜熱の結果を表１に示す。 (Measurement of melting point and latent heat of melting at 5 ° C)
Were taken about 20mg sample from the heat storage material composition, performs DSC (differential scanning calorimetry) was measured melting lower limit temperature T s and the melting maximum temperature T f of the heat storage material composition. The obtained lower limit melting temperature T s was used as the melting point.
In addition, the total amount of heat storage at a certain temperature T 1 ° C. to T 1 + 5 ° C. was calculated using the endothermic peak of DSC. Then, the change in the total amount of heat storage when the value of T 1 was changed was obtained, and the value at which the total amount of heat storage in that case was maximized was defined as the latent heat of melting at 5 ° C.
Table 1 shows the results of melting point and latent heat of melting at 5 ° C.
蓄熱材組成物から約２０ｍｇ試料を採取し、ＤＳＣ（示差走査熱量計）を行い、蓄熱材組成物の融解下限温度Ｔｓ及び融解上限温度Ｔｆを測定した。得られた融解下限温度Ｔｓを融点とした。
また、ＤＳＣの吸熱ピークを用い、ある温度Ｔ１℃からＴ１＋５℃における蓄熱量の総量を算出した。そして、Ｔ１の値を変化させた場合の蓄熱量の総量の変化を求め、その場合の蓄熱量の総量が最大となる値を５℃幅融解潜熱とした。
融点及び５℃幅融解潜熱の結果を表１に示す。 (Measurement of melting point and latent heat of melting at 5 ° C)
Were taken about 20mg sample from the heat storage material composition, performs DSC (differential scanning calorimetry) was measured melting lower limit temperature T s and the melting maximum temperature T f of the heat storage material composition. The obtained lower limit melting temperature T s was used as the melting point.
In addition, the total amount of heat storage at a certain temperature T 1 ° C. to T 1 + 5 ° C. was calculated using the endothermic peak of DSC. Then, the change in the total amount of heat storage when the value of T 1 was changed was obtained, and the value at which the total amount of heat storage in that case was maximized was defined as the latent heat of melting at 5 ° C.
Table 1 shows the results of melting point and latent heat of melting at 5 ° C.
（式（５－１）～（５－７）の充足性）
また、表１には、下記式（５－２）～（５－７）の各左辺の計算結果及び、下記式（５－１）～（５－７）の充足性についても示す。なお、試料Ｎｏ．Ａ６は、下記式（５－１）を充足している。表１では、データが下記式（５－１）～（５－７）を充足する場合を○、充足しない場合を×で示す。 (Satisfiability of equations (5-1) to (5-7))
Table 1 also shows the calculation results of the left sides of the following formulas (5-2) to (5-7) and the satisfiability of the following formulas (5-1) to (5-7). In addition, sample No. A6 satisfies the following equation (5-1). In Table 1, the case where the data satisfies the following equations (5-1) to (5-7) is indicated by ◯, and the case where the data is not satisfied is indicated by ×.
また、表１には、下記式（５－２）～（５－７）の各左辺の計算結果及び、下記式（５－１）～（５－７）の充足性についても示す。なお、試料Ｎｏ．Ａ６は、下記式（５－１）を充足している。表１では、データが下記式（５－１）～（５－７）を充足する場合を○、充足しない場合を×で示す。 (Satisfiability of equations (5-1) to (5-7))
Table 1 also shows the calculation results of the left sides of the following formulas (5-2) to (5-7) and the satisfiability of the following formulas (5-1) to (5-7). In addition, sample No. A6 satisfies the following equation (5-1). In Table 1, the case where the data satisfies the following equations (5-1) to (5-7) is indicated by ◯, and the case where the data is not satisfied is indicated by ×.
［数４７］
Ｘ＋Ｙ＋Ｚ＋Ｗ＝１００ （５－１）
［数４８］
Ｘ－３．１３０４Ｙ＋５．１３０４Ｚ≧０ （５－２）
［数４９］
Ｘ－０．２１７９Ｙ－０．２１７９Ｚ≧０ （５－３）
［数５０］
Ｘ＋１０．５０００Ｙ－８．５０００Ｚ≧０ （５－４）
［数５１］
Ｘ－０．４１７９Ｙ－０．４１７９Ｚ≦０ （５－５）
［数５２］
Ｘ＋０．５８３７Ｙ＋１．４１６３Ｚ－８３．１７６≧０（５－６）
［数５３］
４．８≦Ｗ≦１５．２ （５－７） [Number 47]
X + Y + Z + W = 100 (5-1)
[Number 48]
X-3.1304Y + 5.1304Z ≧ 0 (5-2)
[Number 49]
X-0.2179Y-0.2179Z ≧ 0 (5-3)
[Number 50]
X + 10.5000Y-85000Z ≧ 0 (5-4)
[Number 51]
X-0.4179Y-0.4179Z ≦ 0 (5-5)
[Number 52]
X + 0.5837Y + 1.4163Z-83.176 ≧ 0 (5-6)
[Number 53]
4.8 ≤ W ≤ 15.2 (5-7)
Ｘ＋Ｙ＋Ｚ＋Ｗ＝１００ （５－１）
［数４８］
Ｘ－３．１３０４Ｙ＋５．１３０４Ｚ≧０ （５－２）
［数４９］
Ｘ－０．２１７９Ｙ－０．２１７９Ｚ≧０ （５－３）
［数５０］
Ｘ＋１０．５０００Ｙ－８．５０００Ｚ≧０ （５－４）
［数５１］
Ｘ－０．４１７９Ｙ－０．４１７９Ｚ≦０ （５－５）
［数５２］
Ｘ＋０．５８３７Ｙ＋１．４１６３Ｚ－８３．１７６≧０（５－６）
［数５３］
４．８≦Ｗ≦１５．２ （５－７） [Number 47]
X + Y + Z + W = 100 (5-1)
[Number 48]
X-3.1304Y + 5.1304Z ≧ 0 (5-2)
[Number 49]
X-0.2179Y-0.2179Z ≧ 0 (5-3)
[Number 50]
X + 10.5000Y-85000Z ≧ 0 (5-4)
[Number 51]
X-0.4179Y-0.4179Z ≦ 0 (5-5)
[Number 52]
X + 0.5837Y + 1.4163Z-83.176 ≧ 0 (5-6)
[Number 53]
4.8 ≤ W ≤ 15.2 (5-7)
［実施例２～１５、比較例１～５］（リン酸三ナトリウム１２水和物の含有量が略５質量％の場合）
得られる蓄熱材組成物が表１に示す組成になるように、各成分の配合量を変えた以外は実施例１と同様にして蓄熱材組成物を得た（試料Ｎｏ．Ａ１～Ａ５（比較例１～５）、Ａ７～Ａ２０（実施例２～１５））。蓄熱材組成物は、主剤中のＮａ３ＰＯ４・１２Ｈ２Ｏの含有量が略５質量％になるように調製した。 [Examples 2 to 15, Comparative Examples 1 to 5] (when the content of trisodium phosphate dodecahydrate is approximately 5% by mass)
A heat storage material composition was obtained in the same manner as in Example 1 except that the blending amount of each component was changed so that the obtained heat storage material composition had the composition shown in Table 1 (Sample Nos. A1 to A5 (Comparison). Examples 1 to 5), A7 to A20 (Examples 2 to 15)). Heat storage material composition, the content of Na 3 PO 4 · 12H 2 O in the main agent was prepared so as to be approximately 5% by weight.
得られる蓄熱材組成物が表１に示す組成になるように、各成分の配合量を変えた以外は実施例１と同様にして蓄熱材組成物を得た（試料Ｎｏ．Ａ１～Ａ５（比較例１～５）、Ａ７～Ａ２０（実施例２～１５））。蓄熱材組成物は、主剤中のＮａ３ＰＯ４・１２Ｈ２Ｏの含有量が略５質量％になるように調製した。 [Examples 2 to 15, Comparative Examples 1 to 5] (when the content of trisodium phosphate dodecahydrate is approximately 5% by mass)
A heat storage material composition was obtained in the same manner as in Example 1 except that the blending amount of each component was changed so that the obtained heat storage material composition had the composition shown in Table 1 (Sample Nos. A1 to A5 (Comparison). Examples 1 to 5), A7 to A20 (Examples 2 to 15)). Heat storage material composition, the content of Na 3 PO 4 · 12H 2 O in the main agent was prepared so as to be approximately 5% by weight.
（融点及び５℃幅融解潜熱の測定）
試料Ｎｏ．Ａ１～Ａ５、Ａ７～Ａ２０につき、実施例１と同様にして、融点及び５℃幅融解潜熱を測定した。結果を表１に示す。 (Measurement of melting point and latent heat of melting at 5 ° C)
Sample No. For A1 to A5 and A7 to A20, the melting point and the latent heat of melting in a width of 5 ° C. were measured in the same manner as in Example 1. The results are shown in Table 1.
試料Ｎｏ．Ａ１～Ａ５、Ａ７～Ａ２０につき、実施例１と同様にして、融点及び５℃幅融解潜熱を測定した。結果を表１に示す。 (Measurement of melting point and latent heat of melting at 5 ° C)
Sample No. For A1 to A5 and A7 to A20, the melting point and the latent heat of melting in a width of 5 ° C. were measured in the same manner as in Example 1. The results are shown in Table 1.
（式（５－１）～（５－７）の充足性）
また、試料Ｎｏ．Ａ１～Ａ５、Ａ７～Ａ２０につき、実施例１と同様にして、上記式（５－２）～（５－７）の各左辺の計算結果及び、上記式（５－１）～（５－７）の充足性を調べた。なお、試料Ｎｏ．Ａ１～Ａ５、Ａ７～Ａ２０は、下記式（５－１）を充足している。結果を表１に示す。 (Satisfiability of equations (5-1) to (5-7))
In addition, sample No. For A1 to A5 and A7 to A20, the calculation results of the left sides of the above formulas (5-2) to (5-7) and the above formulas (5-1) to (5-7) are the same as in Example 1. ) Satisfiability was investigated. In addition, sample No. A1 to A5 and A7 to A20 satisfy the following formula (5-1). The results are shown in Table 1.
また、試料Ｎｏ．Ａ１～Ａ５、Ａ７～Ａ２０につき、実施例１と同様にして、上記式（５－２）～（５－７）の各左辺の計算結果及び、上記式（５－１）～（５－７）の充足性を調べた。なお、試料Ｎｏ．Ａ１～Ａ５、Ａ７～Ａ２０は、下記式（５－１）を充足している。結果を表１に示す。 (Satisfiability of equations (5-1) to (5-7))
In addition, sample No. For A1 to A5 and A7 to A20, the calculation results of the left sides of the above formulas (5-2) to (5-7) and the above formulas (5-1) to (5-7) are the same as in Example 1. ) Satisfiability was investigated. In addition, sample No. A1 to A5 and A7 to A20 satisfy the following formula (5-1). The results are shown in Table 1.
（三元系組成図）
図５は、主剤におけるリン酸三ナトリウム１２水和物の含有量が略５質量％のときの、三種組成物中の、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、及び炭酸ナトリウム１０水和物の含有量の三元系組成図である。実施例１の試料Ｎｏ．Ａ６を含めた試料Ｎｏ．Ａ１～Ａ２０の蓄熱材組成物の主剤を構成する三種組成物の組成を図５にプロットした。
図５中、試料Ｎｏ．Ａ６～Ａ２０の蓄熱材組成物のプロットを記号○で示す。また、試料Ｎｏ．Ａ１～Ａ５の蓄熱材組成物のプロットを記号×で示す。
図５において、矩形の領域Ｒ１は、上記式（１－１）～（１－４）を満たす領域である。記号○で示した試料Ｎｏ．Ａ６～Ａ２０は、矩形の領域Ｒ１内に存在する。 (Three-dimensional composition diagram)
FIG. 5 shows sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, and disodium hydrogen phosphate dodecahydrate in the three compositions when the content of trisodium phosphate dodecahydrate in the main agent is approximately 5% by mass. It is a ternary composition diagram of the content of sodium carbonate decahydrate. Sample No. of Example 1. Sample No. including A6. The compositions of the three compositions constituting the main component of the heat storage material compositions A1 to A20 are plotted in FIG.
In FIG. 5, the sample No. The plots of the heat storage material compositions of A6 to A20 are indicated by symbols ◯. In addition, sample No. The plots of the heat storage material compositions of A1 to A5 are indicated by the symbol x.
In FIG. 5, the rectangular region R 1 is a region satisfying the above equations (1-1) to (1-4). Sample No. indicated by the symbol ○. A6 ~ A20 are present within a rectangular region R 1.
図５は、主剤におけるリン酸三ナトリウム１２水和物の含有量が略５質量％のときの、三種組成物中の、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、及び炭酸ナトリウム１０水和物の含有量の三元系組成図である。実施例１の試料Ｎｏ．Ａ６を含めた試料Ｎｏ．Ａ１～Ａ２０の蓄熱材組成物の主剤を構成する三種組成物の組成を図５にプロットした。
図５中、試料Ｎｏ．Ａ６～Ａ２０の蓄熱材組成物のプロットを記号○で示す。また、試料Ｎｏ．Ａ１～Ａ５の蓄熱材組成物のプロットを記号×で示す。
図５において、矩形の領域Ｒ１は、上記式（１－１）～（１－４）を満たす領域である。記号○で示した試料Ｎｏ．Ａ６～Ａ２０は、矩形の領域Ｒ１内に存在する。 (Three-dimensional composition diagram)
FIG. 5 shows sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, and disodium hydrogen phosphate dodecahydrate in the three compositions when the content of trisodium phosphate dodecahydrate in the main agent is approximately 5% by mass. It is a ternary composition diagram of the content of sodium carbonate decahydrate. Sample No. of Example 1. Sample No. including A6. The compositions of the three compositions constituting the main component of the heat storage material compositions A1 to A20 are plotted in FIG.
In FIG. 5, the sample No. The plots of the heat storage material compositions of A6 to A20 are indicated by symbols ◯. In addition, sample No. The plots of the heat storage material compositions of A1 to A5 are indicated by the symbol x.
In FIG. 5, the rectangular region R 1 is a region satisfying the above equations (1-1) to (1-4). Sample No. indicated by the symbol ○. A6 ~ A20 are present within a rectangular region R 1.
表１及び図５より、図５の領域Ｒ１内にある試料Ｎｏ．Ａ６～Ａ２０は、融点及び５℃幅融解潜熱が良好であることが分かった。具体的には、試料Ｎｏ．Ａ６～Ａ２０の蓄熱材組成物は、融点が２０～２２．５℃の範囲内にあり、５℃幅融解潜熱が１６０Ｊ／ｇ以上になっていることが分かった。
From Table 1 and Figure 5, the sample in the region R 1 of FIG. 5 No. It was found that A6 to A20 had good melting points and latent heat of melting at a width of 5 ° C. Specifically, the sample No. It was found that the heat storage material compositions of A6 to A20 had a melting point in the range of 20 to 22.5 ° C. and a latent heat of melting in a width of 5 ° C. of 160 J / g or more.
一方、表１及び図５より、図５の領域Ｒ１外にある試料Ｎｏ．Ａ１～Ａ５は、融点及び５℃幅融解潜熱の少なくとも一方が良好でないことが分かった。
On the other hand, from Table 1 and FIG. 5, the sample is outside the region R 1 of FIG. 5 No. It was found that at least one of the melting point and the latent heat of melting at 5 ° C. was not good for A1 to A5.
［実施例１６～３３、比較例６～１２］（リン酸三ナトリウム１２水和物の含有量が略７．５質量％の場合）
得られる蓄熱材組成物が表２に示す組成になるように、各成分の配合量を変えた以外は実施例１と同様にして蓄熱材組成物を得た（試料Ｎｏ．Ｂ１～Ｂ７（比較例６～１２）、Ｎｏ．Ｂ８～Ｂ２５（実施例１６～３３））。蓄熱材組成物は、主剤中のＮａ３ＰＯ４・１２Ｈ２Ｏの含有量が略７．５質量％になるように調製した。 [Examples 16 to 33, Comparative Examples 6 to 12] (when the content of trisodium phosphate dodecahydrate is approximately 7.5% by mass)
Heat storage material compositions were obtained in the same manner as in Example 1 except that the blending amount of each component was changed so that the obtained heat storage material composition had the composition shown in Table 2 (Sample Nos. B1 to B7 (Comparison). Examples 6 to 12), No. B8 to B25 (Examples 16 to 33)). Heat storage material composition, the content of Na 3 PO 4 · 12H 2 O in the main agent was prepared so as to be approximately 7.5 wt%.
得られる蓄熱材組成物が表２に示す組成になるように、各成分の配合量を変えた以外は実施例１と同様にして蓄熱材組成物を得た（試料Ｎｏ．Ｂ１～Ｂ７（比較例６～１２）、Ｎｏ．Ｂ８～Ｂ２５（実施例１６～３３））。蓄熱材組成物は、主剤中のＮａ３ＰＯ４・１２Ｈ２Ｏの含有量が略７．５質量％になるように調製した。 [Examples 16 to 33, Comparative Examples 6 to 12] (when the content of trisodium phosphate dodecahydrate is approximately 7.5% by mass)
Heat storage material compositions were obtained in the same manner as in Example 1 except that the blending amount of each component was changed so that the obtained heat storage material composition had the composition shown in Table 2 (Sample Nos. B1 to B7 (Comparison). Examples 6 to 12), No. B8 to B25 (Examples 16 to 33)). Heat storage material composition, the content of Na 3 PO 4 · 12H 2 O in the main agent was prepared so as to be approximately 7.5 wt%.
（融点及び５℃幅融解潜熱の測定）
試料Ｎｏ．Ｂ１～Ｂ２５につき、実施例１と同様にして、融点及び５℃幅融解潜熱を測定した。結果を表２に示す。 (Measurement of melting point and latent heat of melting at 5 ° C)
Sample No. For B1 to B25, the melting point and the latent heat of melting in a width of 5 ° C. were measured in the same manner as in Example 1. The results are shown in Table 2.
試料Ｎｏ．Ｂ１～Ｂ２５につき、実施例１と同様にして、融点及び５℃幅融解潜熱を測定した。結果を表２に示す。 (Measurement of melting point and latent heat of melting at 5 ° C)
Sample No. For B1 to B25, the melting point and the latent heat of melting in a width of 5 ° C. were measured in the same manner as in Example 1. The results are shown in Table 2.
（式（５－１）～（５－７）の充足性）
また、表２には、上記式（５－２）～（５－７）の各左辺の計算結果及び、上記式（５－１）～（５－７）の充足性についても示す。なお、試料Ｎｏ．Ｂ１～Ｂ２５は、上記式（５－１）を充足している。表２では、データが上記式（５－１）～（５－７）を充足する場合を○、充足しない場合を×で示す。 (Satisfiability of equations (5-1) to (5-7))
Table 2 also shows the calculation results of the left sides of the above formulas (5-2) to (5-7) and the sufficiency of the above formulas (5-1) to (5-7). In addition, sample No. B1 to B25 satisfy the above formula (5-1). In Table 2, the case where the data satisfies the above equations (5-1) to (5-7) is indicated by ◯, and the case where the data is not satisfied is indicated by ×.
また、表２には、上記式（５－２）～（５－７）の各左辺の計算結果及び、上記式（５－１）～（５－７）の充足性についても示す。なお、試料Ｎｏ．Ｂ１～Ｂ２５は、上記式（５－１）を充足している。表２では、データが上記式（５－１）～（５－７）を充足する場合を○、充足しない場合を×で示す。 (Satisfiability of equations (5-1) to (5-7))
Table 2 also shows the calculation results of the left sides of the above formulas (5-2) to (5-7) and the sufficiency of the above formulas (5-1) to (5-7). In addition, sample No. B1 to B25 satisfy the above formula (5-1). In Table 2, the case where the data satisfies the above equations (5-1) to (5-7) is indicated by ◯, and the case where the data is not satisfied is indicated by ×.
（三元系組成図）
図６は、主剤におけるリン酸三ナトリウム１２水和物の含有量が略７．５質量％のときの、三種組成物中の、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、及び炭酸ナトリウム１０水和物の含有量の三元系組成図である。試料Ｎｏ．Ｂ１～Ｂ２５の蓄熱材組成物の主剤を構成する三種組成物の組成を図６にプロットした。
図６中、試料Ｎｏ．Ｂ８～Ｂ２５の蓄熱材組成物のプロットを記号○で示す。また、試料Ｎｏ．Ｂ１～Ｂ７の蓄熱材組成物のプロットを記号×で示す。
図６において、矩形の領域Ｒ２は、上記式（２－１）～（２－４）を満たす領域である。記号○で示した試料Ｎｏ．Ｂ８～Ｂ２５は、矩形の領域Ｒ２内に存在する。 (Three-dimensional composition diagram)
FIG. 6 shows sodium sulfate tetrahydrate and disodium hydrogen phosphate dodecahydrate in the three compositions when the content of trisodium phosphate dodecahydrate in the main agent is approximately 7.5% by mass. , And a ternary composition diagram of the content of sodium carbonate decahydrate. Sample No. The compositions of the three compositions constituting the main component of the heat storage material compositions of B1 to B25 are plotted in FIG.
In FIG. 6, sample No. The plots of the heat storage material compositions of B8 to B25 are indicated by symbols ◯. In addition, sample No. The plots of the heat storage material compositions of B1 to B7 are indicated by the symbol x.
In FIG. 6, the rectangular region R 2 is a region satisfying the above equations (2-1) to (2-4). Sample No. indicated by the symbol ○. B8 ~ B25 is present in a rectangular region R 2.
図６は、主剤におけるリン酸三ナトリウム１２水和物の含有量が略７．５質量％のときの、三種組成物中の、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、及び炭酸ナトリウム１０水和物の含有量の三元系組成図である。試料Ｎｏ．Ｂ１～Ｂ２５の蓄熱材組成物の主剤を構成する三種組成物の組成を図６にプロットした。
図６中、試料Ｎｏ．Ｂ８～Ｂ２５の蓄熱材組成物のプロットを記号○で示す。また、試料Ｎｏ．Ｂ１～Ｂ７の蓄熱材組成物のプロットを記号×で示す。
図６において、矩形の領域Ｒ２は、上記式（２－１）～（２－４）を満たす領域である。記号○で示した試料Ｎｏ．Ｂ８～Ｂ２５は、矩形の領域Ｒ２内に存在する。 (Three-dimensional composition diagram)
FIG. 6 shows sodium sulfate tetrahydrate and disodium hydrogen phosphate dodecahydrate in the three compositions when the content of trisodium phosphate dodecahydrate in the main agent is approximately 7.5% by mass. , And a ternary composition diagram of the content of sodium carbonate decahydrate. Sample No. The compositions of the three compositions constituting the main component of the heat storage material compositions of B1 to B25 are plotted in FIG.
In FIG. 6, sample No. The plots of the heat storage material compositions of B8 to B25 are indicated by symbols ◯. In addition, sample No. The plots of the heat storage material compositions of B1 to B7 are indicated by the symbol x.
In FIG. 6, the rectangular region R 2 is a region satisfying the above equations (2-1) to (2-4). Sample No. indicated by the symbol ○. B8 ~ B25 is present in a rectangular region R 2.
表２及び図６より、図６の領域Ｒ２内にある試料Ｎｏ．Ｂ８～Ｂ２５は、融点及び５℃幅融解潜熱が良好であることが分かった。具体的には、試料Ｎｏ．Ｂ８～Ｂ２５の蓄熱材組成物は、融点が２０～２２．５℃の範囲内にあり、５℃幅融解潜熱が１６０Ｊ／ｇ以上になっていることが分かった。
From Table 2 and Figure 6, the sample in the region R 2 in FIG. 6 No. It was found that B8 to B25 had good melting points and latent heat of melting at a width of 5 ° C. Specifically, the sample No. It was found that the heat storage material compositions of B8 to B25 had a melting point in the range of 20 to 22.5 ° C. and a latent heat of melting in a width of 5 ° C. of 160 J / g or more.
一方、表２及び図６より、図６の領域Ｒ２外にある試料Ｎｏ．Ｂ１～Ｂ７は、融点及び５℃幅融解潜熱の少なくとも一方が良好でないことが分かった。
On the other hand, from Table 2 and Figure 6, the sample is in the region R 2 out of 6 No. It was found that at least one of the melting point and the latent heat of melting at 5 ° C. was not good for B1 to B7.
［実施例３４～５５、比較例１３～２３］（リン酸三ナトリウム１２水和物の含有量が略１０質量％の場合）
得られる蓄熱材組成物が表３及び表４に示す組成になるように、各成分の配合量を変えた以外は実施例１と同様にして蓄熱材組成物を得た（試料Ｎｏ．Ｃ１～Ｃ１１（比較例１３～２３）、試料Ｎｏ．Ｃ１２～Ｃ３３（実施例３４～５５））。蓄熱材組成物は、主剤中のＮａ３ＰＯ４・１２Ｈ２Ｏの含有量が略１０質量％になるように調製した。 [Examples 34 to 55, Comparative Examples 13 to 23] (when the content of trisodium phosphate dodecahydrate is approximately 10% by mass)
A heat storage material composition was obtained in the same manner as in Example 1 except that the blending amount of each component was changed so that the obtained heat storage material composition had the compositions shown in Tables 3 and 4 (Sample Nos. C1 to C1). C11 (Comparative Examples 13 to 23), Sample Nos. C12 to C33 (Examples 34 to 55)). Heat storage material composition, the content of Na 3 PO 4 · 12H 2 O in the main agent was prepared so as to be approximately 10 wt%.
得られる蓄熱材組成物が表３及び表４に示す組成になるように、各成分の配合量を変えた以外は実施例１と同様にして蓄熱材組成物を得た（試料Ｎｏ．Ｃ１～Ｃ１１（比較例１３～２３）、試料Ｎｏ．Ｃ１２～Ｃ３３（実施例３４～５５））。蓄熱材組成物は、主剤中のＮａ３ＰＯ４・１２Ｈ２Ｏの含有量が略１０質量％になるように調製した。 [Examples 34 to 55, Comparative Examples 13 to 23] (when the content of trisodium phosphate dodecahydrate is approximately 10% by mass)
A heat storage material composition was obtained in the same manner as in Example 1 except that the blending amount of each component was changed so that the obtained heat storage material composition had the compositions shown in Tables 3 and 4 (Sample Nos. C1 to C1). C11 (Comparative Examples 13 to 23), Sample Nos. C12 to C33 (Examples 34 to 55)). Heat storage material composition, the content of Na 3 PO 4 · 12H 2 O in the main agent was prepared so as to be approximately 10 wt%.
（融点及び５℃幅融解潜熱の測定）
試料Ｎｏ．Ｃ１～Ｃ３３につき、実施例１と同様にして、融点及び５℃幅融解潜熱を測定した。結果を表３及び表４に示す。 (Measurement of melting point and latent heat of melting at 5 ° C)
Sample No. For C1 to C33, the melting point and the latent heat of melting at a width of 5 ° C. were measured in the same manner as in Example 1. The results are shown in Tables 3 and 4.
試料Ｎｏ．Ｃ１～Ｃ３３につき、実施例１と同様にして、融点及び５℃幅融解潜熱を測定した。結果を表３及び表４に示す。 (Measurement of melting point and latent heat of melting at 5 ° C)
Sample No. For C1 to C33, the melting point and the latent heat of melting at a width of 5 ° C. were measured in the same manner as in Example 1. The results are shown in Tables 3 and 4.
（式（５－１）～（５－７）の充足性）
また、表３及び表４には、上記式（５－２）～（５－７）の各左辺の計算結果及び、上記式（５－１）～（５－７）の充足性についても示す。なお、試料Ｎｏ．Ｃ１～Ｃ３３は、上記式（５－１）を充足している。表３及び表４では、データが上記式（５－１）～（５－７）を充足する場合を○、充足しない場合を×で示す。 (Satisfiability of equations (5-1) to (5-7))
In addition, Tables 3 and 4 also show the calculation results of the left sides of the above formulas (5-2) to (5-7) and the satisfiability of the above formulas (5-1) to (5-7). .. In addition, sample No. C1 to C33 satisfy the above formula (5-1). In Tables 3 and 4, the cases where the data satisfy the above equations (5-1) to (5-7) are indicated by ◯, and the cases where the data are not satisfied are indicated by ×.
また、表３及び表４には、上記式（５－２）～（５－７）の各左辺の計算結果及び、上記式（５－１）～（５－７）の充足性についても示す。なお、試料Ｎｏ．Ｃ１～Ｃ３３は、上記式（５－１）を充足している。表３及び表４では、データが上記式（５－１）～（５－７）を充足する場合を○、充足しない場合を×で示す。 (Satisfiability of equations (5-1) to (5-7))
In addition, Tables 3 and 4 also show the calculation results of the left sides of the above formulas (5-2) to (5-7) and the satisfiability of the above formulas (5-1) to (5-7). .. In addition, sample No. C1 to C33 satisfy the above formula (5-1). In Tables 3 and 4, the cases where the data satisfy the above equations (5-1) to (5-7) are indicated by ◯, and the cases where the data are not satisfied are indicated by ×.
（三元系組成図）
図７は、主剤におけるリン酸三ナトリウム１２水和物の含有量が略１０質量％のときの、三種組成物中の、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、及び炭酸ナトリウム１０水和物の含有量の三元系組成図である。試料Ｎｏ．Ｃ１～Ｃ３３の蓄熱材組成物の主剤を構成する三種組成物の組成を図７にプロットした。
図７中、試料Ｎｏ．Ｃ１２～Ｃ３３の蓄熱材組成物のプロットを記号○で示す。また、試料Ｎｏ．Ｃ１～Ｃ１１の蓄熱材組成物のプロットを記号×で示す。
図７において、矩形の領域Ｒ３は、上記式（３－１）～（３－４）を満たす領域である。記号○で示した試料Ｎｏ．Ｃ１２～Ｃ３３は、矩形の領域Ｒ３内に存在する。 (Three-dimensional composition diagram)
FIG. 7 shows sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, and disodium hydrogen phosphate dodecahydrate in the three compositions when the content of trisodium phosphate dodecahydrate in the main agent is approximately 10% by mass. It is a ternary composition diagram of the content of sodium carbonate decahydrate. Sample No. The compositions of the three compositions constituting the main component of the heat storage material compositions of C1 to C33 are plotted in FIG.
In FIG. 7, the sample No. The plots of the heat storage material compositions of C12 to C33 are indicated by symbols ◯. In addition, sample No. The plots of the heat storage material compositions of C1 to C11 are indicated by the symbol x.
7, the rectangular area R 3 is an area that satisfies the above formula (3-1) to (3-4). Sample No. indicated by the symbol ○. C12 ~ C33 are present within a rectangular area R 3.
図７は、主剤におけるリン酸三ナトリウム１２水和物の含有量が略１０質量％のときの、三種組成物中の、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、及び炭酸ナトリウム１０水和物の含有量の三元系組成図である。試料Ｎｏ．Ｃ１～Ｃ３３の蓄熱材組成物の主剤を構成する三種組成物の組成を図７にプロットした。
図７中、試料Ｎｏ．Ｃ１２～Ｃ３３の蓄熱材組成物のプロットを記号○で示す。また、試料Ｎｏ．Ｃ１～Ｃ１１の蓄熱材組成物のプロットを記号×で示す。
図７において、矩形の領域Ｒ３は、上記式（３－１）～（３－４）を満たす領域である。記号○で示した試料Ｎｏ．Ｃ１２～Ｃ３３は、矩形の領域Ｒ３内に存在する。 (Three-dimensional composition diagram)
FIG. 7 shows sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, and disodium hydrogen phosphate dodecahydrate in the three compositions when the content of trisodium phosphate dodecahydrate in the main agent is approximately 10% by mass. It is a ternary composition diagram of the content of sodium carbonate decahydrate. Sample No. The compositions of the three compositions constituting the main component of the heat storage material compositions of C1 to C33 are plotted in FIG.
In FIG. 7, the sample No. The plots of the heat storage material compositions of C12 to C33 are indicated by symbols ◯. In addition, sample No. The plots of the heat storage material compositions of C1 to C11 are indicated by the symbol x.
7, the rectangular area R 3 is an area that satisfies the above formula (3-1) to (3-4). Sample No. indicated by the symbol ○. C12 ~ C33 are present within a rectangular area R 3.
表３、表４及び図７より、図７の領域Ｒ３内にある試料Ｎｏ．Ｃ１２～Ｃ３３は、融点及び５℃幅融解潜熱が良好であることが分かった。具体的には、試料Ｎｏ．Ｃ１２～Ｃ３３の蓄熱材組成物は、融点が２０～２２．５℃の範囲内にあり、５℃幅融解潜熱が１６０Ｊ／ｇ以上になっていることが分かった。
Table 3, from Table 4 and FIG. 7, the sample in the region R 3 in FIG. 7 No. It was found that C12 to C33 had good melting points and latent heat of melting at a width of 5 ° C. Specifically, the sample No. It was found that the heat storage material compositions of C12 to C33 had a melting point in the range of 20 to 22.5 ° C. and a latent heat of melting in a width of 5 ° C. of 160 J / g or more.
一方、表３、表４及び図７より、図７の領域Ｒ３外にある試料Ｎｏ．Ｃ１～Ｃ１１は、融点及び５℃幅融解潜熱の少なくとも一方が良好でないことが分かった。
On the other hand, Table 3, samples there from Table 4 and FIG. 7, the outer region R 3 in FIG. 7 No. It was found that at least one of the melting point and the latent heat of melting at 5 ° C. was not good for C1 to C11.
［実施例５６～６２、比較例２４～３３］（リン酸三ナトリウム１２水和物の含有量が略１５質量％の場合）
得られる蓄熱材組成物が表５に示す組成になるように、各成分の配合量を変えた以外は実施例１と同様にして蓄熱材組成物を得た（試料Ｎｏ．Ｄ１～Ｄ１０（比較例２４～３３）、試料Ｎｏ．Ｄ１１～Ｄ１７（実施例５６～６２））。蓄熱材組成物は、主剤中のＮａ３ＰＯ４・１２Ｈ２Ｏの含有量が略１５質量％になるように調製した。 [Examples 56 to 62, Comparative Examples 24 to 33] (when the content of trisodium phosphate dodecahydrate is approximately 15% by mass)
Heat storage material compositions were obtained in the same manner as in Example 1 except that the blending amount of each component was changed so that the obtained heat storage material composition had the composition shown in Table 5 (Sample Nos. D1 to D10 (Comparison). Examples 24 to 33), Sample Nos. D11 to D17 (Examples 56 to 62)). Heat storage material composition, the content of Na 3 PO 4 · 12H 2 O in the main agent was prepared so as to be approximately 15 wt%.
得られる蓄熱材組成物が表５に示す組成になるように、各成分の配合量を変えた以外は実施例１と同様にして蓄熱材組成物を得た（試料Ｎｏ．Ｄ１～Ｄ１０（比較例２４～３３）、試料Ｎｏ．Ｄ１１～Ｄ１７（実施例５６～６２））。蓄熱材組成物は、主剤中のＮａ３ＰＯ４・１２Ｈ２Ｏの含有量が略１５質量％になるように調製した。 [Examples 56 to 62, Comparative Examples 24 to 33] (when the content of trisodium phosphate dodecahydrate is approximately 15% by mass)
Heat storage material compositions were obtained in the same manner as in Example 1 except that the blending amount of each component was changed so that the obtained heat storage material composition had the composition shown in Table 5 (Sample Nos. D1 to D10 (Comparison). Examples 24 to 33), Sample Nos. D11 to D17 (Examples 56 to 62)). Heat storage material composition, the content of Na 3 PO 4 · 12H 2 O in the main agent was prepared so as to be approximately 15 wt%.
（融点及び５℃幅融解潜熱の測定）
試料Ｎｏ．Ｄ１～Ｄ１７につき、実施例１と同様にして、融点及び５℃幅融解潜熱を測定した。結果を表５に示す。 (Measurement of melting point and latent heat of melting at 5 ° C)
Sample No. For D1 to D17, the melting point and the latent heat of melting in a width of 5 ° C. were measured in the same manner as in Example 1. The results are shown in Table 5.
試料Ｎｏ．Ｄ１～Ｄ１７につき、実施例１と同様にして、融点及び５℃幅融解潜熱を測定した。結果を表５に示す。 (Measurement of melting point and latent heat of melting at 5 ° C)
Sample No. For D1 to D17, the melting point and the latent heat of melting in a width of 5 ° C. were measured in the same manner as in Example 1. The results are shown in Table 5.
（式（５－１）～（５－７）の充足性）
また、表５には、上記式（５－２）～（５－７）の各左辺の計算結果及び、上記式（５－１）～（５－７）の充足性についても示す。なお、試料Ｎｏ．Ｄ１～Ｄ１７は、上記式（５－１）を充足している。表５では、データが上記式（５－１）～（５－７）を充足する場合を○、充足しない場合を×で示す。 (Satisfiability of equations (5-1) to (5-7))
Table 5 also shows the calculation results of the left sides of the above formulas (5-2) to (5-7) and the satisfiability of the above formulas (5-1) to (5-7). In addition, sample No. D1 to D17 satisfy the above formula (5-1). In Table 5, the case where the data satisfies the above equations (5-1) to (5-7) is indicated by ◯, and the case where the data is not satisfied is indicated by ×.
また、表５には、上記式（５－２）～（５－７）の各左辺の計算結果及び、上記式（５－１）～（５－７）の充足性についても示す。なお、試料Ｎｏ．Ｄ１～Ｄ１７は、上記式（５－１）を充足している。表５では、データが上記式（５－１）～（５－７）を充足する場合を○、充足しない場合を×で示す。 (Satisfiability of equations (5-1) to (5-7))
Table 5 also shows the calculation results of the left sides of the above formulas (5-2) to (5-7) and the satisfiability of the above formulas (5-1) to (5-7). In addition, sample No. D1 to D17 satisfy the above formula (5-1). In Table 5, the case where the data satisfies the above equations (5-1) to (5-7) is indicated by ◯, and the case where the data is not satisfied is indicated by ×.
（三元系組成図）
図８は、主剤におけるリン酸三ナトリウム１２水和物の含有量が略１５質量％のときの、三種組成物中の、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、及び炭酸ナトリウム１０水和物の含有量の三元系組成図である。試料Ｎｏ．Ｄ１～Ｄ１７の蓄熱材組成物の主剤を構成する三種組成物の組成を図８にプロットした。
図８中、試料Ｎｏ．Ｄ１１～Ｄ１７の蓄熱材組成物のプロットを記号○で示す。また、試料Ｎｏ．Ｄ１～Ｄ１０の蓄熱材組成物のプロットを記号×で示す。
図８において、矩形の領域Ｒ４は、上記式（４－１）～（４－４）を満たす領域である。記号○で示した試料Ｎｏ．Ｄ１１～Ｄ１７は、矩形の領域Ｒ４内に存在する。 (Three-dimensional composition diagram)
FIG. 8 shows sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, and disodium hydrogen phosphate dodecahydrate in the three compositions when the content of trisodium phosphate dodecahydrate in the main agent is approximately 15% by mass. It is a ternary composition diagram of the content of sodium carbonate decahydrate. Sample No. The compositions of the three compositions constituting the main component of the heat storage material compositions D1 to D17 are plotted in FIG.
In FIG. 8, the sample No. The plots of the heat storage material compositions of D11 to D17 are indicated by symbols ◯. In addition, sample No. The plots of the heat storage material compositions of D1 to D10 are indicated by the symbol x.
8, a rectangular area R 4 is a region that satisfies the above formula (4-1) to (4-4). Sample No. indicated by the symbol ○. D11 ~ D17 are present in the rectangular area R 4.
図８は、主剤におけるリン酸三ナトリウム１２水和物の含有量が略１５質量％のときの、三種組成物中の、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、及び炭酸ナトリウム１０水和物の含有量の三元系組成図である。試料Ｎｏ．Ｄ１～Ｄ１７の蓄熱材組成物の主剤を構成する三種組成物の組成を図８にプロットした。
図８中、試料Ｎｏ．Ｄ１１～Ｄ１７の蓄熱材組成物のプロットを記号○で示す。また、試料Ｎｏ．Ｄ１～Ｄ１０の蓄熱材組成物のプロットを記号×で示す。
図８において、矩形の領域Ｒ４は、上記式（４－１）～（４－４）を満たす領域である。記号○で示した試料Ｎｏ．Ｄ１１～Ｄ１７は、矩形の領域Ｒ４内に存在する。 (Three-dimensional composition diagram)
FIG. 8 shows sodium sulfate decahydrate, disodium hydrogen phosphate dodecahydrate, and disodium hydrogen phosphate dodecahydrate in the three compositions when the content of trisodium phosphate dodecahydrate in the main agent is approximately 15% by mass. It is a ternary composition diagram of the content of sodium carbonate decahydrate. Sample No. The compositions of the three compositions constituting the main component of the heat storage material compositions D1 to D17 are plotted in FIG.
In FIG. 8, the sample No. The plots of the heat storage material compositions of D11 to D17 are indicated by symbols ◯. In addition, sample No. The plots of the heat storage material compositions of D1 to D10 are indicated by the symbol x.
8, a rectangular area R 4 is a region that satisfies the above formula (4-1) to (4-4). Sample No. indicated by the symbol ○. D11 ~ D17 are present in the rectangular area R 4.
表５及び図８より、図８の領域Ｒ４内にある試料Ｎｏ．Ｄ１１～Ｄ１７は、融点及び５℃幅融解潜熱が良好であることが分かった。具体的には、試料Ｎｏ．Ｄ１１～Ｄ１７の蓄熱材組成物は、融点が２０～２２．５℃の範囲内にあり、５℃幅融解潜熱が１６０Ｊ／ｇ以上になっていることが分かった。
From Table 5 and FIG. 8, the sample in the region R 4 in FIG. 8 No. It was found that D11 to D17 had good melting points and latent heat of melting at a width of 5 ° C. Specifically, the sample No. It was found that the heat storage material compositions of D11 to D17 had a melting point in the range of 20 to 22.5 ° C. and a latent heat of melting in a width of 5 ° C. of 160 J / g or more.
一方、表５及び図８より、図８の領域Ｒ４外にある試料Ｎｏ．Ｄ１～Ｄ１０は、融点及び５℃幅融解潜熱の少なくとも一方が良好でないことが分かった。
On the other hand, from Table 5 and FIG. 8, the sample in the region R 4 outside the 8 No. It was found that at least one of the melting point and the latent heat of melting at 5 ° C. was not good for D1 to D10.
（四元系組成図）
図９は、主剤中の、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、炭酸ナトリウム１０水和物、及びリン酸三ナトリウム１２水和物の含有量の四元系組成図の一例である。具体的には、図９は、試料Ｎｏ．Ａ１～Ａ２０、Ｂ１～Ｂ２５、Ｃ１～Ｃ３３、及びＤ１～Ｄ１７について、主剤中の硫酸ナトリウム１０水和物、リン酸三ナトリウム１２水和物等の組成を四元系組成図に示したものである。なお、図９中、ＮＳ、ＮＨ、及びＮＣは図７と同じであり、ＮＰはリン酸三ナトリウム１２水和物が１００％になる点を示す。また、表１～５で「図中の記号」が○の試料を図１１で○とプロットし、表１～５で「図中の記号」が×の試料を図１１で×とプロットした。 (Quaternary composition diagram)
FIG. 9 is a quaternary composition diagram of the contents of sodium sulfate tetrahydrate, disodium hydrogen phosphate dodecahydrate, sodium carbonate decahydrate, and trisodium phosphate dodecahydrate in the main agent. This is an example. Specifically, FIG. 9 shows the sample No. For A1 to A20, B1 to B25, C1 to C33, and D1 to D17, the compositions of sodium sulfate decahydrate, trisodium phosphate dodecahydrate, etc. in the main agent are shown in the quaternary composition diagram. is there. In FIG. 9, NS, NH, and NC are the same as in FIG. 7, and NP indicates that trisodium phosphate dodecahydrate is 100%. Further, in Tables 1 to 5, the sample having the “symbol in the figure” of ○ was plotted as ○ in FIG. 11, and the sample having the “symbol in the figure” of × in Tables 1 to 5 was plotted as × in FIG.
図９は、主剤中の、硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、炭酸ナトリウム１０水和物、及びリン酸三ナトリウム１２水和物の含有量の四元系組成図の一例である。具体的には、図９は、試料Ｎｏ．Ａ１～Ａ２０、Ｂ１～Ｂ２５、Ｃ１～Ｃ３３、及びＤ１～Ｄ１７について、主剤中の硫酸ナトリウム１０水和物、リン酸三ナトリウム１２水和物等の組成を四元系組成図に示したものである。なお、図９中、ＮＳ、ＮＨ、及びＮＣは図７と同じであり、ＮＰはリン酸三ナトリウム１２水和物が１００％になる点を示す。また、表１～５で「図中の記号」が○の試料を図１１で○とプロットし、表１～５で「図中の記号」が×の試料を図１１で×とプロットした。 (Quaternary composition diagram)
FIG. 9 is a quaternary composition diagram of the contents of sodium sulfate tetrahydrate, disodium hydrogen phosphate dodecahydrate, sodium carbonate decahydrate, and trisodium phosphate dodecahydrate in the main agent. This is an example. Specifically, FIG. 9 shows the sample No. For A1 to A20, B1 to B25, C1 to C33, and D1 to D17, the compositions of sodium sulfate decahydrate, trisodium phosphate dodecahydrate, etc. in the main agent are shown in the quaternary composition diagram. is there. In FIG. 9, NS, NH, and NC are the same as in FIG. 7, and NP indicates that trisodium phosphate dodecahydrate is 100%. Further, in Tables 1 to 5, the sample having the “symbol in the figure” of ○ was plotted as ○ in FIG. 11, and the sample having the “symbol in the figure” of × in Tables 1 to 5 was plotted as × in FIG.
図９中、式（５－１）～（５－７）を略満たす三次元領域をＱとして示した。図９において、三次元領域Ｑ内が、式（５－１）～（５－７）を略満たす領域になっている。試料Ｎｏ．Ａ１～Ａ２０、Ｂ１～Ｂ２５、Ｃ１～Ｃ３３、及びＤ１～Ｄ１７のうち、○でプロットされた試料は、領域Ｑの範囲内に存在することが分かる。具体的には、実施例１～６２は、領域Ｑの範囲内に存在することが分かる。
In FIG. 9, the three-dimensional region substantially satisfying the equations (5-1) to (5-7) is shown as Q. In FIG. 9, the three-dimensional region Q is a region that substantially satisfies the equations (5-1) to (5-7). Sample No. It can be seen that among A1 to A20, B1 to B25, C1 to C33, and D1 to D17, the samples plotted with ◯ exist within the range of region Q. Specifically, it can be seen that Examples 1 to 62 exist within the range of region Q.
三次元領域をＱについて、詳細に説明する。図１０は、図９中の領域Ｑを拡大した図である。領域Ｑは、五角柱状の領域であり、対向して配置された五角形の平面ＦＢＣＯＮと平面ＥＡＤＰＭとの間を、平面ＡＢＣＤ、平面ＤＣＯＰ、平面ＭＮＯＰ、平面ＥＦＮＭ及び平面ＡＢＦＥで囲んだ形状になっている。なお、図１０に示す平面ＥＦＧＨ及び平面ＩＪＫＬは、共に、平面ＡＢＣＤ及び平面ＭＮＯＰと平行な面になっている。
The three-dimensional area will be explained in detail about Q. FIG. 10 is an enlarged view of the region Q in FIG. The region Q is a pentagonal columnar region, and has a shape in which a pentagonal plane FBCON and a plane EADPM arranged opposite to each other are surrounded by a plane ABCD, a plane DCOP, a plane MNOP, a plane EFNM, and a plane ABFE. There is. The plane EFGH and the plane IJKL shown in FIG. 10 are both parallel to the plane ABCD and the plane MNOP.
平面ＡＢＣＤは、主剤におけるリン酸三ナトリウム１２水和物の含有量が略５質量％のデータの集合体からなる平面を、図９中の点ＮＰから面ＮＳ－ＮＣ－ＮＨに対して鉛直方向に見たときに観察される平面である。
The plane ABCD is a plane composed of a collection of data in which the content of trisodium phosphate 12hydrate in the main agent is approximately 5% by mass, in the vertical direction from the point NP in FIG. 9 to the plane NS-NC-NH. It is a plane that is observed when viewed from.
平面ＥＦＧＨは、主剤におけるリン酸三ナトリウム１２水和物の含有量が略７．５質量％のデータの集合体からなる平面を、図９中の点ＮＰから面ＮＳ－ＮＣ－ＮＨに対して鉛直方向に見たときに観察される平面である。
The plane EFGH is a plane composed of a collection of data in which the content of trisodium phosphate 12hydrate in the main agent is approximately 7.5% by mass, from the point NP in FIG. 9 to the plane NS-NC-NH. It is a plane observed when viewed in the vertical direction.
平面ＩＪＫＬは、主剤におけるリン酸三ナトリウム１２水和物の含有量が略１０質量％のデータの集合体からなる平面を、図９中の点ＮＰから面ＮＳ－ＮＣ－ＮＨに対して鉛直方向に見たときに観察される平面である。
The plane IJKL is a plane composed of a collection of data in which the content of trisodium phosphate 12hydrate in the main agent is approximately 10% by mass in the vertical direction from the point NP in FIG. 9 to the plane NS-NC-NH. It is a plane that is observed when viewed from.
平面ＭＮＯＰは、主剤におけるリン酸三ナトリウム１２水和物の含有量が略１５質量％のデータの集合体からなる平面を、図９中の点ＮＰから面ＮＳ－ＮＣ－ＮＨに対して鉛直方向に見たときに観察される平面である。
The plane MNOP is a plane composed of a collection of data in which the content of trisodium phosphate 12hydrate in the main agent is approximately 15% by mass in the vertical direction from the point NP in FIG. 9 to the plane NS-NC-NH. It is a plane that is observed when viewed from.
上記のように、試料Ｎｏ．Ａ１～Ａ２０、Ｂ１～Ｂ２５、Ｃ１～Ｃ３３、及びＤ１～Ｄ１７のうち、実施例１～６２は、図９及び図１０に示す領域Ｑの範囲内に存在する。
As mentioned above, sample No. Of A1 to A20, B1 to B25, C1 to C33, and D1 to D17, Examples 1 to 62 exist within the range of the region Q shown in FIGS. 9 and 10.
＜リン酸三ナトリウム１２水和物の含有量が略５質量％の場合＞
図１１は、図９の全プロットのうち、図１０の平面ＡＢＣＤと略同一平面にあるプロットのみを示した図である。具体的には、試料Ｎｏ．Ａ１～Ａ２０をプロットしたものである。 <When the content of trisodium phosphate dodecahydrate is approximately 5% by mass>
FIG. 11 is a diagram showing only the plots in substantially the same plane as the plane ABCD of FIG. 10 among all the plots of FIG. Specifically, the sample No. It is a plot of A1 to A20.
図１１は、図９の全プロットのうち、図１０の平面ＡＢＣＤと略同一平面にあるプロットのみを示した図である。具体的には、試料Ｎｏ．Ａ１～Ａ２０をプロットしたものである。 <When the content of trisodium phosphate dodecahydrate is approximately 5% by mass>
FIG. 11 is a diagram showing only the plots in substantially the same plane as the plane ABCD of FIG. 10 among all the plots of FIG. Specifically, the sample No. It is a plot of A1 to A20.
図１１中の平面ＡＢＣＤは、図１０中の平面ＡＢＣＤに相当する。図１１中の平面ＡＢＣＤ内の領域Ｒ５は、式（１－１）～（１－４）を満たす領域である。試料Ｎｏ．Ａ１～Ａ２０のうち○でプロットされた試料は、領域Ｒ５に含まれる。
The plane ABCD in FIG. 11 corresponds to the plane ABCD in FIG. Region R 5 in the plane ABCD in FIG. 11 is a region satisfying the equation (1-1) to (1-4). Sample No. Samples plotted in ○ Of A1 ~ A20 are included in the region R 5.
＜リン酸三ナトリウム１２水和物の含有量が略７．５質量％の場合＞
図１２は、図９の全プロットのうち、図１０の平面ＥＦＧＨと略同一平面にあるプロットのみを示した図である。具体的には、試料Ｎｏ．Ｂ１～Ｂ２５をプロットしたものである。 <When the content of trisodium phosphate dodecahydrate is approximately 7.5% by mass>
FIG. 12 is a diagram showing only the plots in substantially the same plane as the plane EFGH of FIG. 10 among all the plots of FIG. Specifically, the sample No. It is a plot of B1 to B25.
図１２は、図９の全プロットのうち、図１０の平面ＥＦＧＨと略同一平面にあるプロットのみを示した図である。具体的には、試料Ｎｏ．Ｂ１～Ｂ２５をプロットしたものである。 <When the content of trisodium phosphate dodecahydrate is approximately 7.5% by mass>
FIG. 12 is a diagram showing only the plots in substantially the same plane as the plane EFGH of FIG. 10 among all the plots of FIG. Specifically, the sample No. It is a plot of B1 to B25.
図１２中の平面ＥＦＧＨは、図１０中の平面ＥＦＧＨに相当する。図１２中の平面ＥＦＧＨ内の領域Ｒ６は、式（２－１）～（２－４）を満たす領域である。試料Ｎｏ．Ｂ１～Ｂ２５のうち○でプロットされた試料は、領域Ｒ６に含まれる。
The plane EFGH in FIG. 12 corresponds to the plane EFGH in FIG. The region R 6 in the plane EFGH in FIG. 12 is a region satisfying equations (2-1) to (2-4). Sample No. Samples plotted in ○ Among B1 ~ B25 are included in the region R 6.
＜リン酸三ナトリウム１２水和物の含有量が略１０質量％の場合＞
図１３は、図９の全プロットのうち、図１０の平面ＩＪＫＬと略同一平面にあるプロットのみを示した図である。具体的には、試料Ｎｏ．Ｃ１～Ｃ３３をプロットしたものである。 <When the content of trisodium phosphate dodecahydrate is approximately 10% by mass>
FIG. 13 is a diagram showing only the plots in substantially the same plane as the plane IJKL of FIG. 10 among all the plots of FIG. Specifically, the sample No. It is a plot of C1 to C33.
図１３は、図９の全プロットのうち、図１０の平面ＩＪＫＬと略同一平面にあるプロットのみを示した図である。具体的には、試料Ｎｏ．Ｃ１～Ｃ３３をプロットしたものである。 <When the content of trisodium phosphate dodecahydrate is approximately 10% by mass>
FIG. 13 is a diagram showing only the plots in substantially the same plane as the plane IJKL of FIG. 10 among all the plots of FIG. Specifically, the sample No. It is a plot of C1 to C33.
図１３中の平面ＩＪＫＬは、図１０中の平面ＩＪＫＬに相当する。図１３中の平面ＩＪＫＬ内の領域Ｒ７は、式（３－１）～（３－４）を満たす領域である。試料Ｎｏ．Ｃ１～Ｃ３３のうち○でプロットされた試料は、領域Ｒ７に含まれる。
The plane IJKL in FIG. 13 corresponds to the plane IJKL in FIG. The region R 7 in the plane IJKL in FIG. 13 is a region satisfying equations (3-1) to (3-4). Sample No. Samples plotted in ○ Of C1 ~ C33 are included in the region R 7.
＜リン酸三ナトリウム１２水和物の含有量が略１５質量％の場合＞
図１４は、図９の全プロットのうち、図１０の平面ＭＮＯＰと略同一平面にあるプロットのみを示した図である。具体的には、試料Ｎｏ．Ｄ１～Ｄ１７をプロットしたものである。 <When the content of trisodium phosphate dodecahydrate is approximately 15% by mass>
FIG. 14 is a diagram showing only plots that are substantially in the same plane as the plane MNOP of FIG. 10 among all the plots of FIG. Specifically, the sample No. It is a plot of D1 to D17.
図１４は、図９の全プロットのうち、図１０の平面ＭＮＯＰと略同一平面にあるプロットのみを示した図である。具体的には、試料Ｎｏ．Ｄ１～Ｄ１７をプロットしたものである。 <When the content of trisodium phosphate dodecahydrate is approximately 15% by mass>
FIG. 14 is a diagram showing only plots that are substantially in the same plane as the plane MNOP of FIG. 10 among all the plots of FIG. Specifically, the sample No. It is a plot of D1 to D17.
図１４中の平面ＭＮＯＰは、図１０中の平面ＭＮＯＰに相当する。図１４中の平面ＭＮＯＰ内の領域Ｒ８は、式（４－１）～（４－４）を満たす領域である。試料Ｎｏ．Ｄ１～Ｄ１７のうち○でプロットされた試料は、領域Ｒ８に含まれる。
The plane MNOP in FIG. 14 corresponds to the plane MNOP in FIG. The region R 8 in the plane MNOP in FIG. 14 is a region satisfying equations (4-1) to (4-4). Sample No. Samples plotted in ○ among D1 ~ D17 are included in the region R 8.
特願２０１９－１０３７７６号（出願日：２０１９年６月３日）の全内容は、ここに援用される。
The entire contents of Japanese Patent Application No. 2019-103776 (application date: June 3, 2019) are incorporated here.
以上、本発明を実施例によって説明したが、本発明はこれらに限定されるものではなく、本発明の要旨の範囲内で種々の変形が可能である。
Although the present invention has been described above by way of examples, the present invention is not limited to these, and various modifications can be made within the scope of the gist of the present invention.
本実施形態に係る蓄熱材組成物によれば、融点が２０～２２．５℃の範囲内にあり、狭い温度領域内での融解潜熱が大きい蓄熱材組成物及び建築物の冷暖房用の蓄熱システムを提供することができる。
According to the heat storage material composition according to the present embodiment, the heat storage material composition having a melting point in the range of 20 to 22.5 ° C. and a large latent heat of melting in a narrow temperature range and a heat storage system for heating and cooling of a building. Can be provided.
Ｔｍ 融点
Ｔｆ 融解上限温度
Ｔ５Ｌ ５℃幅下限温度
Ｔ５Ｈ ５℃幅上限温度
ＨＴ 全体融解潜熱
Ｈ５ ５℃幅融解潜熱 T m melting point T f melting the upper limit temperature T 5L 5 ° C. width lower limit temperature T 5H 5 ° C. width maximum temperature H T total latent heat of fusion H 5 5 ° C. width latent heat of fusion
Ｔｆ 融解上限温度
Ｔ５Ｌ ５℃幅下限温度
Ｔ５Ｈ ５℃幅上限温度
ＨＴ 全体融解潜熱
Ｈ５ ５℃幅融解潜熱 T m melting point T f melting the upper limit temperature T 5L 5 ° C. width lower limit temperature T 5H 5 ° C. width maximum temperature H T total latent heat of fusion H 5 5 ° C. width latent heat of fusion
Claims (11)
- 硫酸ナトリウム１０水和物、リン酸水素二ナトリウム１２水和物、炭酸ナトリウム１０水和物、及び、リン酸三ナトリウム１２水和物からなる主剤を含み、
融点が２０～２２．５℃の範囲内にあり、
５℃幅融解潜熱が１６０Ｊ／ｇ以上であることを特徴とする蓄熱材組成物。 It contains a main agent consisting of sodium sulfate tetrahydrate, disodium hydrogen phosphate dodecahydrate, sodium carbonate decahydrate, and trisodium phosphate dodecahydrate.
It has a melting point in the range of 20-22.5 ° C and
A heat storage material composition having a latent heat of melting at a width of 5 ° C. of 160 J / g or more. - 前記主剤中における前記リン酸三ナトリウム１２水和物の含有量が４．５～５．５質量％の場合において、
前記硫酸ナトリウム１０水和物、前記リン酸水素二ナトリウム１２水和物、及び前記炭酸ナトリウム１０水和物からなる三種組成物１００質量％中の、前記硫酸ナトリウム１０水和物の含有量をＸ質量％、前記リン酸水素二ナトリウム１２水和物の含有量をＹ質量％、及び前記炭酸ナトリウム１０水和物の含有量をＺ質量％と規定するとき、Ｘ、Ｙ、及びＺが下記式（１－１）～（１－４）を満たすことを特徴とする請求項１に記載の蓄熱材組成物。
［数１］
Ｘ＋Ｙ＋Ｚ＝１００ （１－１）
［数２］
Ｘ＋２．００Ｙ－１２４．２１≦０ （１－２）
［数３］
Ｘ＋２．００Ｙ－８９．４７≦０ （１－３）
［数４］
１７．８９≦Ｘ≦２９．４７ （１－４） When the content of the trisodium phosphate dodecahydrate in the main agent is 4.5 to 5.5% by mass,
The content of the sodium sulfate decahydrate in 100% by mass of the three-kind composition consisting of the sodium sulfate decahydrate, the disodium hydrogen phosphate dodecahydrate, and the sodium carbonate decahydrate is X. When the content of mass%, the disodium hydrogen phosphate dodecahydrate is defined as Y mass%, and the content of the sodium carbonate decahydrate is Z mass%, X, Y, and Z are the following formulas. The heat storage material composition according to claim 1, wherein the heat storage material composition satisfies (1-1) to (1-4).
[Number 1]
X + Y + Z = 100 (1-1)
[Number 2]
X + 2.00Y-124.21 ≦ 0 (1-2)
[Number 3]
X + 2.00Y-89.47 ≦ 0 (1-3)
[Number 4]
17.89 ≤ X ≤ 29.47 (1-4) - 前記主剤中における前記リン酸三ナトリウム１２水和物の含有量が７．０～８．０質量％の場合において、
前記硫酸ナトリウム１０水和物、前記リン酸水素二ナトリウム１２水和物、及び前記炭酸ナトリウム１０水和物からなる三種組成物１００質量％中の、前記硫酸ナトリウム１０水和物の含有量をＸ質量％、前記リン酸水素二ナトリウム１２水和物の含有量をＹ質量％、及び前記炭酸ナトリウム１０水和物の含有量をＺ質量％と規定するとき、Ｘ、Ｙ、及びＺが下記式（２－１）～（２－４）を満たすことを特徴とする請求項１に記載の蓄熱材組成物。
［数５］
Ｘ＋Ｙ＋Ｚ＝１００ （２－１）
［数６］
Ｘ＋２．００Ｙ－１２４．２１≦０ （２－２）
［数７］
Ｘ＋２．００Ｙ－８９．４７≦０ （２－３）
［数８］
１７．８９≦Ｘ≦２９．４７ （２－４） When the content of the trisodium phosphate dodecahydrate in the main agent is 7.0 to 8.0% by mass,
The content of the sodium sulfate decahydrate in 100% by mass of the three-kind composition consisting of the sodium sulfate decahydrate, the disodium hydrogen phosphate dodecahydrate, and the sodium carbonate decahydrate is X. When the content of mass%, the disodium hydrogen phosphate dodecahydrate is defined as Y mass%, and the content of the sodium carbonate decahydrate is Z mass%, X, Y, and Z are the following formulas. The heat storage material composition according to claim 1, wherein the heat storage material composition satisfies (2-1) to (2-4).
[Number 5]
X + Y + Z = 100 (2-1)
[Number 6]
X + 2.00Y-124.21 ≦ 0 (2-2)
[Number 7]
X + 2.00Y-89.47 ≦ 0 (2-3)
[Number 8]
17.89 ≤ X ≤ 29.47 (2-4) - 前記主剤中における前記リン酸三ナトリウム１２水和物の含有量が９．５～１０．５質量％の場合において、
前記硫酸ナトリウム１０水和物、前記リン酸水素二ナトリウム１２水和物、及び前記炭酸ナトリウム１０水和物からなる三種組成物１００質量％中の、前記硫酸ナトリウム１０水和物の含有量をＸ質量％、前記リン酸水素二ナトリウム１２水和物の含有量をＹ質量％、及び前記炭酸ナトリウム１０水和物の含有量をＺ質量％と規定するとき、Ｘ、Ｙ、及びＺが下記式（３－１）～（３－４）を満たすことを特徴とする請求項１に記載の蓄熱材組成物。
［数９］
Ｘ＋Ｙ＋Ｚ＝１００ （３－１）
［数１０］
Ｘ＋２．００Ｙ－１１８．３３≦０ （３－２）
［数１１］
Ｘ＋２．００Ｙ－８９．４７≦０ （３－３）
［数１２］
１７．８９≦Ｘ≦２９．４７ （３－４） When the content of the trisodium phosphate dodecahydrate in the main agent is 9.5 to 10.5% by mass,
The content of the sodium sulfate decahydrate in 100% by mass of the three-kind composition consisting of the sodium sulfate decahydrate, the disodium hydrogen phosphate dodecahydrate, and the sodium carbonate decahydrate is X. When the content of mass%, the disodium hydrogen phosphate dodecahydrate is defined as Y mass%, and the content of the sodium carbonate decahydrate is Z mass%, X, Y, and Z are the following formulas. The heat storage material composition according to claim 1, wherein the heat storage material composition satisfies (3-1) to (3-4).
[Number 9]
X + Y + Z = 100 (3-1)
[Number 10]
X + 2.00Y-118.33 ≦ 0 (3-2)
[Number 11]
X + 2.00Y-89.47 ≦ 0 (3-3)
[Number 12]
17.89 ≤ X ≤ 29.47 (3-4) - 前記主剤中における前記リン酸三ナトリウム１２水和物の含有量が１４．５～１５．５質量％の場合において、
前記硫酸ナトリウム１０水和物、前記リン酸水素二ナトリウム１２水和物、及び前記炭酸ナトリウム１０水和物からなる三種組成物１００質量％中の、前記硫酸ナトリウム１０水和物の含有量をＸ質量％、前記リン酸水素二ナトリウム１２水和物の含有量をＹ質量％、及び前記炭酸ナトリウム１０水和物の含有量をＺ質量％と規定するとき、Ｘ、Ｙ、及びＺが下記式（４－１）～（４－４）を満たすことを特徴とする請求項１に記載の蓄熱材組成物。
［数１３］
Ｘ＋Ｙ＋Ｚ＝１００ （４－１）
［数１４］
Ｘ＋２．００Ｙ－１０５．７４≦０ （４－２）
［数１５］
Ｘ＋２．００Ｙ－８９．４７≦０ （４－３）
［数１６］
１７．８９≦Ｘ≦２９．４７ （４－４） When the content of the trisodium phosphate dodecahydrate in the main agent is 14.5 to 15.5% by mass,
The content of the sodium sulfate decahydrate in 100% by mass of the three-kind composition consisting of the sodium sulfate decahydrate, the disodium hydrogen phosphate dodecahydrate, and the sodium carbonate decahydrate is X. When the content of mass%, the disodium hydrogen phosphate dodecahydrate is defined as Y mass%, and the content of the sodium carbonate decahydrate is Z mass%, X, Y, and Z are the following formulas. The heat storage material composition according to claim 1, wherein (4-1) to (4-4) are satisfied.
[Number 13]
X + Y + Z = 100 (4-1)
[Number 14]
X + 2.00Y-105.74≤0 (4-2)
[Number 15]
X + 2.00Y-89.47 ≦ 0 (4-3)
[Number 16]
17.89 ≤ X ≤ 29.47 (4-4) - 前記主剤１００質量％中の、前記硫酸ナトリウム１０水和物の含有量をＸ質量％、前記リン酸水素二ナトリウム１２水和物の含有量をＹ質量％、前記炭酸ナトリウム１０水和物の含有量をＺ質量％、及び前記リン酸三ナトリウム１２水和物の含有量をＷ質量％と規定するとき、Ｘ、Ｙ、Ｚ、及びＷが下記式（５－１）～（５－７）を満たすことを特徴とする請求項１に記載の蓄熱材組成物。
［数１７］
Ｘ＋Ｙ＋Ｚ＋Ｗ＝１００ （５－１）
［数１８］
Ｘ－３．１３０４Ｙ＋５．１３０４Ｚ≧０ （５－２）
［数１９］
Ｘ－０．２１７９Ｙ－０．２１７９Ｚ≧０ （５－３）
［数２０］
Ｘ＋１０．５０００Ｙ－８．５０００Ｚ≧０ （５－４）
［数２１］
Ｘ－０．４１７９Ｙ－０．４１７９Ｚ≦０ （５－５）
［数２２］
Ｘ＋０．５８３７Ｙ＋１．４１６３Ｚ－８３．１７６≧０ （５－６）
［数２３］
４．８≦Ｗ≦１５．２ （５－７） The content of the sodium sulfate decahydrate in 100% by mass of the main agent is X% by mass, the content of the disodium hydrogen phosphate dodecahydrate is Y% by mass, and the content of the sodium carbonate decahydrate is contained. When the amount is defined as Z mass% and the content of the trisodium phosphate dodecahydrate is defined as W mass%, X, Y, Z, and W are the following formulas (5-1) to (5-7). The heat storage material composition according to claim 1, wherein the heat storage material composition satisfies.
[Number 17]
X + Y + Z + W = 100 (5-1)
[Number 18]
X-3.1304Y + 5.1304Z ≧ 0 (5-2)
[Number 19]
X-0.2179Y-0.2179Z ≧ 0 (5-3)
[Number 20]
X + 10.5000Y-85000Z ≧ 0 (5-4)
[Number 21]
X-0.4179Y-0.4179Z ≦ 0 (5-5)
[Number 22]
X + 0.5837Y + 1.4163Z-83.176 ≧ 0 (5-6)
[Number 23]
4.8 ≤ W ≤ 15.2 (5-7) - 有機不飽和カルボン酸、有機不飽和スルホン酸、有機不飽和リン酸、有機不飽和アミド、有機不飽和アルコール、有機不飽和カルボン酸塩、有機不飽和スルホン酸塩、及び有機不飽和リン酸塩からなる群より選択される少なくとも１種の単量体と、
多官能性単量体と、
を重合させて得られる保湿剤をさらに含むことを特徴とする請求項１～６のいずれか１項に記載の蓄熱材組成物。 From organic unsaturated carboxylic acids, organic unsaturated sulfonic acids, organic unsaturated phosphates, organic unsaturated amides, organic unsaturated alcohols, organic unsaturated carboxylic acids, organic unsaturated sulfonic acids, and organic unsaturated phosphates With at least one monomer selected from the group
With polyfunctional monomers
The heat storage material composition according to any one of claims 1 to 6, further comprising a moisturizer obtained by polymerizing. - 塩化ナトリウム、塩化カリウム、硝酸ナトリウム、臭化ナトリウム、塩化アンモニウム、臭化アンモニウム、硫酸アンモニウム、硝酸アンモニウム、リン酸アンモニウム、及び尿素からなる群より選択される少なくとも１種の融点降下剤をさらに含むことを特徴とする請求項１～７のいずれか１項に記載の蓄熱材組成物。 It is characterized by further containing at least one melting point lowering agent selected from the group consisting of sodium chloride, potassium chloride, sodium nitrate, sodium bromide, ammonium chloride, ammonium bromide, ammonium sulfate, ammonium nitrate, ammonium phosphate, and urea. The heat storage material composition according to any one of claims 1 to 7.
- ホウ砂Ｎａ２Ｂ４Ｏ５（ＯＨ）４・８Ｈ２Ｏ、水酸化カルシウム、水酸化バリウム、水酸化ストロンチウム、水酸化アルミニウム、黒鉛、アルミニウム、二酸化チタン、二酸化ケイ素、リン酸ドデシルナトリウム、ドデシル硫酸ナトリウム、カルボキシメチルセルロースナトリウム、リグニンスルホン酸、ヘクトライト、スメクタイトクレイ、ベントナイト、ラポナイト、プロピレングリコール、エチレングリコール、グリセリン、エチレンジアミン四酢酸、アルキル硫酸ナトリウム、アルキルリン酸ナトリウム、アルキル硫酸カリウム、及びアルキルリン酸カリウムからなる群より選択される少なくとも１種の過冷却抑制剤をさらに含むことを特徴とする請求項１～８のいずれか１項に記載の蓄熱材組成物。 Borax Na 2 B 4 O 5 (OH ) 4 · 8H 2 O, calcium hydroxide, barium hydroxide, strontium hydroxide, aluminum hydroxide, graphite, aluminum, titanium dioxide, silicon dioxide, sodium dodecyl phosphate, dodecyl sulfate Sodium, carboxymethyl cellulose sodium, lignin sulfonic acid, hectrite, smectite clay, bentonite, laponite, propylene glycol, ethylene glycol, glycerin, ethylenediamine tetraacetic acid, sodium alkyl sulfate, sodium alkyl phosphate, potassium alkyl sulfate, and potassium alkyl phosphate. The heat storage material composition according to any one of claims 1 to 8, further comprising at least one supercooling inhibitor selected from the group consisting of.
- ケイ酸ナトリウム、水ガラス、ポリアクリル酸、ポリアクリル酸ナトリウム、ポリカルボキシレートポリエーテルポリマー、アクリル酸・マイレン酸共重合体ナトリウム、アクリル酸・スルホン酸系モノマー共重合体ナトリウム、アクリルアミド・ジメチルアミノエチルメタクリラートジメチル硫酸塩共重合物、アクリルアミド・アクリル酸ソーダ共重合物、ポリエチレングリコール、ポリプロピレングリコール、高吸水樹脂（ＳＡＰ）、カルボキシメチルセルロース（ＣＭＣ)、ＣＭＣの誘導体、カラギーナン、カラギーナンの誘導体、キサンタンガム、キサンタンガムの誘導体、ペクチン、ペクチンの誘導体、デンプン、デンプンの誘導体、コンニャク、寒天、層状ケイ酸塩、及びこれらの物質の複合物質からなる群より選択される少なくとも１種の相分離抑制剤をさらに含むことを特徴とする請求項１～９のいずれか１項に記載の蓄熱材組成物。 Sodium silicate, water glass, polyacrylic acid, sodium polyacrylate, polycarboxylate polyether polymer, sodium acrylate / myrene copolymer, sodium acrylate / sulfonic acid monomer copolymer, acrylamide / dimethylaminoethyl Methacrate dimethyl sulfate copolymer, acrylamide / sodium acrylate copolymer, polyethylene glycol, polypropylene glycol, high water absorption resin (SAP), carboxymethyl cellulose (CMC), CMC derivative, carrageenan, carrageenan derivative, xanthan gum, xanthan gum Further comprising at least one phase separation inhibitor selected from the group consisting of derivatives of pectin, derivatives of pectin, starch, derivatives of starch, konjak, agar, layered silicates, and composites of these substances. The heat storage material composition according to any one of claims 1 to 9, wherein the heat storage material composition is characterized.
- 請求項１～１０のいずれか１項に記載の蓄熱材組成物を用いた蓄熱材モジュールを具備することを特徴とする建築物の冷暖房用の蓄熱システム。 A heat storage system for heating and cooling of a building, which comprises a heat storage material module using the heat storage material composition according to any one of claims 1 to 10.
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| JPH02132180A (en) * | 1988-07-01 | 1990-05-21 | Nok Corp | Thermal energy storing material |
| JPH0885785A (en) * | 1994-07-20 | 1996-04-02 | Sumitomo Chem Co Ltd | Prevention of latent heat storage material composition from being overcooled and latent heat storage apparatus |
| CN104479634A (en) * | 2014-12-18 | 2015-04-01 | 青海大学 | Low-temperature phase-change energy storage material |
| WO2017164304A1 (en) * | 2016-03-23 | 2017-09-28 | 株式会社カネカ | Heat storage material composition and use thereof |
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| JPH02132180A (en) * | 1988-07-01 | 1990-05-21 | Nok Corp | Thermal energy storing material |
| JPH0885785A (en) * | 1994-07-20 | 1996-04-02 | Sumitomo Chem Co Ltd | Prevention of latent heat storage material composition from being overcooled and latent heat storage apparatus |
| CN104479634A (en) * | 2014-12-18 | 2015-04-01 | 青海大学 | Low-temperature phase-change energy storage material |
| WO2017164304A1 (en) * | 2016-03-23 | 2017-09-28 | 株式会社カネカ | Heat storage material composition and use thereof |
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