WO2020246196A1

WO2020246196A1 - Hairstyling agent composition

Info

Publication number: WO2020246196A1
Application number: PCT/JP2020/018487
Authority: WO
Inventors: 佳和橋本
Original assignee: 株式会社マンダム
Priority date: 2019-06-07
Filing date: 2020-05-07
Publication date: 2020-12-10
Also published as: KR20220005576A; JPWO2020246196A1; CN113905714A; KR102657034B1; JP7337923B2

Abstract

Provided is a hairstyling agent composition in which the viscosity increase caused by the incorporation of a clay mineral is suppressed. The hairstyling agent composition according to one aspect of the present invention comprises a component A: a clay mineral, component B: polyphosphoric acid or a salt thereof, and component C: water.

Description

Hair styling composition

The present invention relates to a hair styling product composition.

Conventionally, solid oil agents, film-based polymers, and the like have been used as components that impart hair styling power to hair styling agent compositions. However, there is a problem that an unnatural glossy texture is imparted to the hair by blending these components. In order to solve this problem and achieve both sufficient hair styling power and a matte texture, hair styling products containing clay minerals have been developed. For example, Patent Document 1 discloses a wax-like hair styling product containing kaolin, which is a kind of clay mineral. Further, Patent Document 2 discloses a hair styling product containing an oil-swellable clay mineral.

Japanese Patent Publication "Japanese Patent Laid-Open No. 2002-114652" Japanese Patent Publication "Japanese Patent Laid-Open No. 2003-026550"

However, clay minerals also have a function as a thickener. Therefore, if a large amount of clay mineral is blended, the viscosity of the intermediate solution during the preparation and the viscosity of the preparation become too high. Therefore, a composition containing a large amount of clay mineral becomes unsuitable for the production and practical use of a hair styling product composition. That is, there is a limit to the amount of clay mineral that can be blended in the preparation due to the thickening of the clay mineral.

One aspect of the present invention is to provide a hair styling composition capable of suppressing an increase in viscosity due to the blending of clay minerals and imparting a matte texture.

As a result of diligent studies by the present inventors in order to solve the above problems, according to a hair conditioner composition containing (i) clay mineral, (ii) polyphosphoric acid or a salt thereof, and (iii) water. It has been found that even when a large amount of clay mineral is blended, the increase in viscosity due to the clay mineral can be suppressed and a matte texture can be imparted.

That is, the hair styling composition according to one aspect of the present invention is a hair styling composition containing the following components A, B and C;
Component A: Clay mineral Component B: Polyphosphoric acid or a salt thereof, and Component C: Water.

One aspect of the present invention provides a hair styling composition capable of suppressing an increase in viscosity due to the blending of clay minerals and imparting a matte texture.

Hereinafter, an example of the embodiment of the present invention will be described in detail, but the present invention is not limited thereto.

Unless otherwise specified in the present specification, "AB" representing a numerical range means "A or more, B or less". Unless otherwise specified in the present specification, the mass% representing the content of the component is a value in which the mass of the entire hair styling product composition is 100% by mass.

[Each component]
The hair styling composition according to one embodiment of the present invention contains component A: clay mineral, component B: polyphosphoric acid or a salt thereof, and component C: water.

Hereinafter, each component contained in the hair styling composition according to the embodiment of the present invention will be described in order.

[Component A: Clay mineral]
Component A is a clay mineral. In the hair styling composition according to the embodiment of the present invention, the component A has a role of imparting a matte texture. As the component A, only one type may be used, or two or more types may be used in combination.

The clay mineral of component A may be a natural clay mineral, a refined natural clay mineral, or a synthesized clay mineral. The above component A is not particularly limited, but for example, natural clay minerals or refined natural clay minerals include kaolin group clay minerals, antigolite group clay minerals, pyrophyllite group clay minerals, and mica group. Examples thereof include clay minerals, smectite group clay minerals, vermiculite group clay minerals, and green mudstone group clay minerals.

Examples of the kaolin group clay minerals include kaolin, nacrite, dikite and halosite. Examples of the antigolite group clay mineral include antigolite, amesite and cronsteadite, and examples of the pyrophilite group clay mineral include pyrophilite and talc (talc). Examples of the mica family clay minerals include illite, glauconite, ceradonite, sericite, mica (mica), muscovite, chrome muscovite and biotite. Examples of the smectite group clay minerals include bentonite, montmorillonite, smectite, biderite, nontonite, saponite and hectorite. Examples of the vermiculite group clay mineral include vermiculite and the like. Examples of the chlorite group clay mineral include chlorite.

Further, examples of the synthesized clay mineral include synthetic silicates and derivatives of synthetic silicates. The synthetic silicates and derivatives of synthetic silicates are not silicate minerals (including not a little impurities) containing naturally occurring magnesium silicate, silicate (sodium / magnesium), etc. as main components. It refers to silicates and derivatives of silicates obtained by synthesis.

Examples of the synthetic silicate and derivatives of the synthetic silicate include synthetic silicate (sodium / magnesium) (INCI name “SODIUM MAGNESIUM SILICATE”: International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, Vol. 2, CTFA. , 2012, p. 3076), Magnesium Fluorosilicate (INCI name "MAGNESIUM FLUOROSILICATE": International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, Volume 2, CTFA, 2012, p.1793) Sodium / Magnesium) (INCI name "SODIUM MAGNESIUM FLUOROSILICATE": International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, Volume 2, CTFA, 2012, p.3076), Fluorosilicate (magnesium) MAGNESIUM POTASSIUM FLUOROSILICATE ”: International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, Volume 2, CTFA, 2012, p.1799), Fluorosilicate (Magnesium / Sodium), Fluorosilicate (Magnesium / Sodium) Dictionary and Handbook, 14th Edition, Volume 2, CTFA, 2012, p.1800), Synthetic Aluminum Silicate (INCI name "ALUMINUM SILICATE": International Cosmetic Ingredient Dictionary, Handbook, Volume 14, Magnesium, Vol. 2012, p.156) and the like.

Examples of commercially available products of the synthetic silicate and derivatives of the synthetic silicate include, for example, Rockwood Co., Ltd., trade name "Laponite XLG" and trade name "Laponite XL21".

In one embodiment of the present invention, the component A is preferably at least one clay mineral selected from the group consisting of smectite group clay minerals, synthetic silicates and derivatives of synthetic silicates. This is because smectite clay minerals, synthetic silicates and derivatives of synthetic silicates have the property of swelling in water and becoming colloidal, and when applied to hair, powder floats (white powder blows). This is because it is difficult to see it. On the other hand, other clay minerals (for example, kaolin blended in the hair styling product described in Patent Document 1) tend to be relatively easy to float when applied to hair.

The lower limit of the content of the component A is preferably 1.0% by mass or more, more preferably 2.0% by mass or more, based on 100% by mass of the hair styling product composition according to the embodiment of the present invention. .0% by mass or more is more preferable. The upper limit of the content of the component A is preferably 20.0% by mass or less, more preferably 12.0% by mass or less, and more preferably 12.0% by mass or less, based on 100% by mass of the hair styling product composition according to the embodiment of the present invention. More preferably, it is 0.0% by mass or less. When the content is 1.0% by mass or more, a matte texture can be more sufficiently provided. Further, when the content is 20.0% by mass or less, the viscosity of the preparation is in a more appropriate range, and the stability of the preparation is increased.

[Component B: Polyphosphoric acid or its salt]
Component B is polyphosphoric acid or a salt thereof. Polyphosphoric acid is a compound formed by condensing two or more phosphoric acids. In the hair styling composition according to the embodiment of the present invention, the component B has a role of suppressing an increase in viscosity due to clay minerals. As the component B, only one type may be used, or two or more types may be used in combination.

The present inventors have surprisingly found that polyphosphoric acid or a salt thereof suppresses the increase in viscosity caused by clay minerals. This mechanism is unknown in detail. However, it is presumed that the effect is not merely due to the function as a chelating agent (see Comparative Examples 2 and 3 described later).

The degree of polymerization of polyphosphoric acid may be 2 or more, for example, 2 or more and 10 or less. Examples of polyphosphoric acid include tripolyphosphoric acid, hexametaphosphoric acid, pyrophosphoric acid, trimetaphosphoric acid, tetramethaphosphoric acid, cyclopolyphosphoric acid and the like. Examples of these salts include alkali metal salts such as sodium salt and potassium salt.

The lower limit of the content of the component B is preferably 0.01% by mass or more, more preferably 0.02% by mass or more, and 0 by mass, based on 100% by mass of the hair styling product composition according to the embodiment of the present invention. .1% by mass or more is more preferable. The upper limit of the content of the component B is preferably 3.0% by mass or less, more preferably 2.0% by mass or less, based on 100% by mass of the hair styling product composition according to the embodiment of the present invention. 5.5% by mass or less is further preferable, and 1.0% by mass or less is even more preferable. When the content is 0.01% by mass or more, the increase in viscosity caused by clay minerals can be more sufficiently suppressed. It is preferable that the content is 3.0% by mass or less from the viewpoint of safety. Further, when the content exceeds 3.0% by mass, the effect of suppressing the increase in viscosity due to the clay mineral is difficult to increase.

[Component C: Water]
The component C is water. The component C is not particularly limited, but purified water is preferable. The lower limit of the content of the component C is preferably 20.0% by mass or more, more preferably 25.0% by mass or more, and more preferably 30% by mass, based on 100% by mass of the hair styling product composition according to the embodiment of the present invention. It is more preferably 0% by mass or more. The upper limit of the content of the component C is preferably 95.0% by mass or less, more preferably 90.0% by mass or less, based on 100% by mass of the hair styling product composition according to the embodiment of the present invention. It is more preferably 0% by mass or less.

[Arbitrary ingredient]
The hair styling product composition according to one embodiment of the present invention may contain components (other components) other than components A to C according to the dosage form and the like as long as the effects of the present invention are not impaired. .. The other ingredients are not particularly limited, and examples thereof include ingredients usually used in cosmetics and quasi-drugs. Specifically, for example, lower alcohols such as ethanol; oily components such as polyhydric alcohols, higher alcohols, silicone oils, ester oils, waxes, vegetable oils, hydrocarbon waxes, hydrocarbon oils, fats and oils, higher fatty acids, etc .; carboxyvinyl polymers. , Acrylic acid, thickeners such as alkyl methacrylate copolymers; surfactants; fragrances; UV absorbers; antioxidants; metal ion sequestering agents; film-forming polymer compounds such as pyrivinylpyrrolidone; kaolin, silica , Tarku and the like; pigments; pigments; dyes; vitamins; amino acids; astringents; whitening agents; animal and plant extracts; acids; alkalis and the like.

[Dosage form and manufacturing method]
The dosage form of the hair styling product composition according to the embodiment of the present invention is not particularly limited. As an example, the dosage form of the composition is gel, wax, or aqueous pomade.

[Gel]
The gel agent is, for example, a high-viscosity water-based hair styling agent in which a gel skeleton is formed by a thickener and the hair is fixed and hair-styling with a film-forming polymer or the like. When the hair styling composition according to one embodiment of the present invention is a gel agent, it preferably contains a film-forming polymer, a polyhydric alcohol, a thickener, an alcohol, and a pH adjuster in addition to the components A to C. In addition, the hair styling composition may contain a surfactant, a fragrance, and a preservative.

[wax]
The wax agent is, for example, a solid oil component (wax, hydrocarbon, etc.) that is O / W emulsified with a surfactant, and is a creamy emulsification that fixes and styling the hair with the adhesive force derived from the solid oil component. It is a type hair styling product. When the hair styling composition according to the embodiment of the present invention is a wax agent, it preferably contains an oily component and a surfactant in addition to the components A to C. In addition, the hair styling composition may contain a higher fatty acid, a higher alcohol, a polyhydric alcohol, an alcohol, and a thickener.

[Aqueous pomade]
The aqueous pomade agent is, for example, a gel-like aqueous hair styling agent in which a gel skeleton is formed by a highly blended surfactant, and the hair is fixed and hair styling by the adhesive force derived from the surfactant. When the hair styling composition according to one embodiment of the present invention is an aqueous pomade agent, it preferably contains a surfactant and a polyhydric alcohol in addition to the components A to C. In addition, the hair styling composition may contain a film-forming polymer, an oily component, a pH adjuster, an alcohol, and a fragrance.

The hair styling product composition according to the embodiment of the present invention can be produced according to a conventional method.

[Use]
The use of the hair styling product composition of the present invention is not particularly limited, but for example, it may be used to improve the feel, texture, etc. of the hair in addition to fixing and setting the hair.

In addition, one embodiment of the present invention also includes the use of the following components A, B and C as a hair styling composition;
Component A: Clay mineral Component B: Polyphosphoric acid or a salt thereof, and Component C: Water.

In addition, one embodiment of the present invention also includes a production method for producing a hair styling composition containing the following components A, B and C, which comprises a step of mixing the following components A, B and C. ;
Component A: Clay mineral Component B: Polyphosphoric acid or a salt thereof, and Component C: Water.

As the "use" and "manufacturing method" according to one embodiment of the present invention, the above-mentioned descriptions of [forms for carrying out the invention] can be appropriately incorporated.

The contents described in each of the above items can be appropriately used in other items as well. The present invention is not limited to each of the above-described embodiments, and various modifications can be made within the scope of the claims. Therefore, embodiments obtained by appropriately combining the technical means disclosed in the different embodiments are also included in the technical scope of the present invention.

All academic and patent documents described in this specification are incorporated herein by reference.

The hair styling composition according to one aspect of the present invention includes the following inventions.

(1) A hair styling composition containing the following components A, B and C;
Component A: Clay mineral Component B: Polyphosphoric acid or a salt thereof, and Component C: Water.

(2) The content of the component A is 1.0% by mass to 20.0% by mass with respect to 100% by mass of the hair styling product composition.
The hair styling product composition according to (1), wherein the content of the component B is 0.01% by mass to 3.0% by mass with respect to 100% by mass of the hair styling product composition.

(3) The hair conditioning according to (1) or (2), wherein the component A is at least one clay mineral selected from the group consisting of smectite group clay minerals, synthetic silicates and derivatives of synthetic silicates. Agent composition.

Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to the following Examples. In addition, the compounding amount and content in the following Examples and Comparative Examples are the amount (mass%) converted into the pure content.

〔Evaluation item〕
(Preparability)
When the hair styling product compositions according to Tables 1 to 4 were prepared by a conventional method, the feasibility of preparation was evaluated according to the following criteria.
Possible: The hair styling product composition could be prepared without any problem.
Impossible: The hair styling composition could not be prepared because it was too thickened, or the formulation was non-uniform when each component was prepared and could not be prepared.

(Matte feeling)
1.5 g of the obtained hair styling agent composition was taken on the palm, spread on the palm, and then applied to a cut wig (manufactured by Eucalyptus Japan, trade name "A-386") to perform hair styling. The hair of the wig immediately after the hair styling was visually observed, and the "matte feeling" was evaluated according to the following criteria. The matte feeling was not evaluated for those for which the above-mentioned "Adjustability" evaluation result was not possible.

<Evaluation criteria for matte feeling>
++: There is almost no gloss on the hair, and a sufficient matte feeling is given.
+: The hair is slightly glossy, but a sufficient matte feeling is given.
-: The hair is glossy and does not have a matte feel.

[Examples 1 to 9, Comparative Examples 1 to 3]
Hair styling product compositions (gels) according to Examples 1 to 9 and Comparative Examples 1 to 3 were prepared according to the composition shown in Table 1 according to a conventional method.

Details of each component in Table 1 are as follows.
・ Bentonite: Made by Japan Organic Clay Co., Ltd., trade name "Bengel"
・ Saponite: Made by Kunimine Industries, Ltd., trade name "Smekton SA"
-Silicic acid (Na / Mg): Made by Rockwood Adaptives Limited, trade name "Laponite XLG"
-Fluorosilicic acid (Na / Mg): manufactured by Rockwood Adaptives Limited, trade name "Laponite XL21"
-Na tripolyphosphate: manufactured by Yoneyama Chemical Industry Co., Ltd., trade name "sodium tripolyphosphate"
-Na hexametaphosphate: manufactured by Taihei Kagaku Sangyo Co., Ltd., trade name "Ultraporin"
-Na pyrophosphate: manufactured by Yoneyama Chemical Industry Co., Ltd., trade name "sodium pyrophosphate (anhydrous)"
・ Disodium edetate: Made by AkzoNobel, trade name "Dizorbin NA2-S"
-Sodium erythorbate: manufactured by Fuso Chemical Industry Co., Ltd., trade name "Elbit N"
-Polymer: Made by LUBRIZOL, trade name "CARBOPOL 980 POLYMER".

[Examples 10 to 13, Comparative Example 4]
According to the composition of Table 2, the hair styling product compositions (wax) according to Examples 10 to 13 and Comparative Example 4 were prepared according to a conventional method.

Details of each component in Table 2 are as follows. The same components as in Table 1 will be omitted.
・ Carnauba wax: Made by Toa Kasei Co., Ltd., product name "TOWAX-1F8"
-Microcrystalline wax: manufactured by Nippon Seiro Co., Ltd., trade name "HI-MIC-1090"
-Mineral oil: Sonneborn Inc., trade name "CARNATION"
-Cyclopentasiloxane: Momentive Performance Materials Japan GK, product name "TSF405"
Setes-20: Croda Singapore Pte Ltd. Made, product name "SP
Bridge C20 MBAL-PA- (SG) "
-Gioless-8 sodium phosphate: manufactured by Nippon Surfartant Industry Co., Ltd., trade name "NIKKOL DOP-8NV"
-Sorbitan stearate: EVONIK NUTRITION & CARE GMBH, trade name "TEGO SMS"
-Ethylhexyl palmitate: manufactured by Koyo Fine Chemical Co., Ltd., trade name "Koyo POC"
-PEG-40 hydrogenated castor oil: manufactured by Aoki Oil & Fat Industry Co., Ltd., trade name "Brownon RCW-40".

[Example 14]
According to the composition of Table 3, the hair styling product composition (aqueous pomade) according to Example 14 was prepared according to a conventional method.

Details of each component in Table 3 are as follows. The description of the components that are the same as those in Table 1 or 2 will be omitted.
-Setes-40: Made by Aoki Oil & Fat Co., Ltd., trade name "Brownon CH-340".

〔result〕
In Examples 1 to 9 containing the components A to C, the increase in viscosity caused by the clay mineral was suppressed, and the hair styling agent composition (gel) could be prepared. On the other hand, in Comparative Examples 1 to 3 containing components A and C but not containing component B, the viscosity became too high, and the hair styling agent composition (gel) could not be prepared.

Similarly, in Examples 10 to 13 and 14 containing components A to C, an increase in viscosity due to clay minerals was suppressed, and a hair styling agent composition (wax and aqueous pomade) could be prepared. On the other hand, in Comparative Example 4, which contained component A and component C but did not contain component B, the hair styling agent composition (wax) could not be prepared.

From the above, it can be seen that by containing the component B, the increase in viscosity caused by the component A (clay mineral) is suppressed, and the hair styling agent composition can be prepared.

Further, in Comparative Examples 2 and 3, although a chelating agent was blended instead of polyphosphoric acid, an increase in the viscosity of the preparation due to clay mineral could not be suppressed.

(Prescription example 1: Hair gel)
Bentonite 3.0% by mass
5 sodium tripolyphosphate 0.3% by mass
Carboxyvinyl polymer 0.2% by mass
Triethanolamine Appropriate amount Glycerin 6.0% by mass
Ethanol 15.0% by mass
(Hydroxyethyl acrylate / Methoxyethyl acrylate) copolymer 1.0% by mass
Perfume Appropriate amount of water Remaining total 100.0% by mass.

(Prescription example 2: Hair wax)
Bentonite 4.0% by mass
Sodium tripolyphosphate 0.4% by mass
Mineral oil 2.0% by mass
Ethylhexyl palmitate 5.0% by mass
Beeswax 4.0% by mass
Castor oil 4.0% by mass
Geoles-8 Sodium Phosphate 4.0% by Mass
Setes-20 4.0% by mass
PEG-40 hydrogenated castor oil 3.0% by mass
Glycerin 2.0% by mass
Stearyl alcohol 1.0% by mass
Ketoglutaric acid 0.2% by mass
Citric acid Appropriate amount Phenoxyethanol Appropriate amount Fragrance Appropriate amount Water Remaining total 100.0% by mass.

(Prescription example 3: Hair wax)
Bentonite 3.0% by mass
5 sodium tripolyphosphate 0.3% by mass
Mineral oil 2.0% by mass
Dimethicone 5.0% by mass
Ethylhexyl palmitate 5.0% by mass
Microcrystalline wax 8.0% by mass
Carnauba wax 4.0% by mass
Geoles-8 Sodium Phosphate 4.0% by Mass
Setes-20 4.0% by mass
Isopentyldiol 5.0% by mass
Glycerin 2.0% by mass
Stearyl alcohol 1.0% by mass
Diatomaceous earth 5.0% by mass
Ketoglutaric acid 0.02% by mass
Citric acid Appropriate amount Sodium benzoate Appropriate amount Fragrance Appropriate amount Water Remaining total 100.0% by mass.

(Prescription example 4: Hair wax)
Bentonite 5.0% by mass
5 sodium tripolyphosphate 0.3% by mass
Mineral oil 10.0% by mass
Dimethicone 5.0% by mass
Ethylhexyl palmitate 5.0% by mass
Microcrystalline wax 8.0% by mass
Carnauba wax 4.0% by mass
Sorbitan stearate 3.0% by mass
Setes-20 3.0% by mass
Stearyl alcohol 1.5% by mass
Glycerin 2.0% by mass
Stearic acid Appropriate amount Triethanolamine Appropriate amount Carboxyvinyl polymer 0.3% by mass
Perfume Appropriate amount of water Remaining total 100.0% by mass.

(Prescription example 5: Aqueous pomade)
Bentonite 6.0% by mass
5 sodium tripolyphosphate 0.5% by mass
Setes-40 25.0% by mass
Setes-20 5.0% by mass
Diglycerin 6.0% by mass
Sodium benzoate Appropriate amount
(Hydroxyethyl acrylate / Methoxyethyl acrylate) copolymer 4.0% by mass
Fragrance Appropriate amount Citric acid Appropriate amount Trisodium citrate Appropriate amount Water Remaining total 100.0% by mass.

The present invention can be used for hair styling composition.

Claims

A hair styling composition containing the following components A, B and C;
Component A: Clay mineral Component B: Polyphosphoric acid or a salt thereof, and Component C: Water.
The content of the component A is 1.0% by mass to 20.0% by mass with respect to 100% by mass of the hair styling product composition.
The hair styling product composition according to claim 1, wherein the content of the component B is 0.01% by mass to 3.0% by mass with respect to 100% by mass of the hair styling product composition.
The hair conditioner composition according to claim 1 or 2, wherein the component A is at least one clay mineral selected from the group consisting of smectite group clay minerals, synthetic silicates and derivatives of synthetic silicates.